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Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


1

Project Profile: Thermochemical Storage with Anhydrous Ammonia...  

Office of Environmental Management (EM)

The system is charged when ammonia, NH3, is heated in the Endothermic reactor by the sun (Qsol) transforming it into N2 and H2. These gasses are then cooled and stored in the...

2

Retention of anhydrous ammonia as influenced by clay mineral types, cations, temperature and moisture  

E-Print Network (OSTI)

to various temperature levels . . . . . ~ 20 5a 6. 70 Ammoni. a retained sxuressed as psr cent of cation-exchange capacity for olays treated with anhydrous ammonia prior to heating to various temperature levels . ~. . . . . . ~ ~ . 21 Ammonia retained... encountered in the use of anhydrous ammoni. . . REVIEW OF LITER4TURE Some of the early work with anhydx ous ammonia was done by anderson, et al. (2), and Enderson and Eattson (3). St that t1ms anhydrous ammonia as sn inorganic source of nitrogen fertiliaer...

McBee, George G

1956-01-01T23:59:59.000Z

3

An investigation of some of the effects of anhydrous ammonia on the clay minerals montmorillonite and illite  

E-Print Network (OSTI)

with various dominant ions on the exchange complex. 2. The effect of heat in an atmosphere of steam on the (001) spacing of montmorillonite saturated with various ions and treated with anhydrous ammonia. 3. The effect of drying at 110?C. for 24. hours... on the (001) spacing of montmorillonite saturated with various dominant ions and treated with anhydrous ammonia? 4.. The effect of relative humidity and anhydrous ammonia on the (001) spacing of illite with various dominant ions on the exchange complex...

Whiteley, Eli Lamar

2013-10-04T23:59:59.000Z

4

Growth of Fe3N films via chemical vapor deposition of iron acetylacetonate and anhydrous ammonia  

Science Journals Connector (OSTI)

Polycrystalline Fe3N films have been grown via chemical vapor deposition (CVD) on 50-?m thick polycrystalline Ti substrates using iron acetylacetonate (IAA) and anhydrous ammonia (NH3) in a cold-wall vertical pancake-style reactor. X-ray diffraction data indicated that single phase Fe3N was present in films deposited at and above 600C; below this temperature no deposition occurred. The composition of the Fe3N films did not vary with changes in the deposition temperature, the NH3 flow rate or the deposition rate at a constant deposition pressure of 100 Torr. The surface macrostructure of the as-deposited films was independent of the deposition temperature and was very similar to that of the uncoated Ti substrate. The microstructure of the films was porous with a thickness variation of ?1 ?m across the surface of the films. Larger grains were produced at 600 and 800C, while smaller and more uniform grains were produced at 700C. Energy dispersive X-ray data indicated that films deposited at and above 600C contained low levels of both carbon and oxygen.

S.L. Roberson; D. Finello; A.D. Banks; R.F. Davis

1998-01-01T23:59:59.000Z

5

Rapid Ammonia Gas Transport Accounts for Futile Transmembrane Cycling under NH3/NH4  

E-Print Network (OSTI)

Rapid Ammonia Gas Transport Accounts for Futile Transmembrane Cycling under NH3/NH4 + Toxicity) seedlings is predominately of the gaseous NH3 species, rather than the NH4 + ion. Influx of 13 NH3/13 NH4 + , which exceeded 200 mmol g­1 h­1 , was not commensurate with membrane depolarization or increases in root

Britto, Dev T.

6

Study of On-Board Ammonia (NH3) Generation for SCR Operation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Study of On-Board Ammonia (NH3) Generation for SCR Operation Study of On-Board Ammonia (NH3) Generation for SCR Operation The feasibility of on-board ammonia generation was...

7

Global distributions, time series and error characterization of atmospheric ammonia (NH[subscript 3]) from IASI satellite observations  

E-Print Network (OSTI)

Ammonia (NH[subscript 3]) emissions in the atmosphere have increased substantially over the past decades, largely because of intensive livestock production and use of fertilizers. As a short-lived species, NH[subscript 3] ...

Van Damme, M.

8

Preventing Theft of Anhydrous Ammonia  

E-Print Network (OSTI)

to occur in waves, with thieves striking the same location several times. Thefts have occurred at such unlikely places as refrig- eration systems, underground pipelines and rail cars. However, most criminals steal from above-ground tanks on farms... such as bottles or tanks may be left behind; these pose a risk to anyone who comes across them and handles them. Signs of Theft Evidence of theft includes valves not tightly closed or that seem to have been tampered with, footprints in the soil, and tire...

Smith, David

2004-09-16T23:59:59.000Z

9

Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics...  

NLE Websites -- All DOE Office Websites (Extended Search)

Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in orthorhombic ammonia borane. Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in...

10

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia...  

NLE Websites -- All DOE Office Websites (Extended Search)

properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34...

11

Spectroscopic Studies of the Phase Transition in Ammonia Borane...  

NLE Websites -- All DOE Office Websites (Extended Search)

Studies of the Phase Transition in Ammonia Borane: Raman spectroscopy of single crystal NH3BH3 as a function of Spectroscopic Studies of the Phase Transition in Ammonia Borane:...

12

Selective Catalytic Reduction (SCR) of nitric oxide with ammonia using Cu-ZSM-5 and Va-based honeycomb monolith catalysts: effect of H2 pretreatment, NH3-to-NO ratio, O2, and space velocity  

E-Print Network (OSTI)

In this work, the steady-state performance of zeolite-based (Cu-ZSM-5) and vanadium-based honeycomb monolith catalysts was investigated in the selective catalytic reduction process (SCR) for NO removal using NH3. The aim was to delineate the effect...

Gupta, Saurabh

2004-09-30T23:59:59.000Z

13

Process for synthesis of ammonia borane for bulk hydrogen storage  

DOE Patents (OSTI)

The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

2011-03-01T23:59:59.000Z

14

Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators  

E-Print Network (OSTI)

Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators to eventually optimise the reactor geometry for ammonia-based solar energy storage with troughs, which.1. Storing Solar Energy with Ammonia H2 / N2 gas liquid NH3 Heat Exchangers Power Generation (Steam Cycle

15

Production of anhydrous aluminum chloride composition  

DOE Patents (OSTI)

A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

1981-10-08T23:59:59.000Z

16

How the Membrane Protein AmtB Transports Ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

How the Membrane Protein AmtB Transports Ammonia Print How the Membrane Protein AmtB Transports Ammonia Print Membrane proteins provide molecular-sized entry and exit portals for the various substances that pass into and out of cells. While life scientists have solved the structures of protein channels for ions, uncharged solutes, and even water, up to now they have only been able to guess at the precise mechanisms by which gases (such as NH3, CO2, O2, NO, N2O, etc.) cross biological membranes. But, with the first high-resolution structure of a bacterial ammonia transporter (AmtB), determined by a team in the Stroud group from the University of California, San Francisco, it is now known that this family of transporters conducts ammonia by stripping off the proton from the ammonium (NH4+) cation and conducting the uncharged NH3 "gas."

17

Study of the effects of interleakage of ammonia and seawater on corrosion and scaling of candidate materials for OTEC heat exchngers. Final report  

SciTech Connect

Assessment has been made on the effect of small concentrations of ammonia in seawater and varying concentrations of seawater in anhydrous ammonia upon corrosion and scaling of candidate OTEC heat exchanger materials - A1-5052, Alclad 3003, copper alloys 706, 715 and 722, AL-6X stainless steel and CP titanium. Results are presented. AL-6X stainless steel and CP titanium showed exceptional corrosion resistance to all test environments. Alclad alloy 3003 showed satisfactory performance in seawater and seawater plus ammonia environments. Only minimal pitting was observed and this was limited to the sacrificial cladding in seawater plus ammonia only. Cladding alloy 7072 showed unacceptable corrosion resistance in anhydrous ammonia containing low seawater concentrations. Al-5052 tubes showed unsatisfactory corrosion behavior in the presence of seawater flow with ammonia interleakage. Copper alloys considered showed unacceptable corrosion resistance in all seawater environments containing ammonia. Low pressure differentials between seawater and anhydrous ammonia in the tube testing unit resulted in scaling and moderately efficient plug seal formation at the artificial leak sites of the tubes. It is recommended that Alclad 3003, CP titanium and AL-6X stainless steel tubes be assessed for suitability in the presence of probable OTEC cleaning systems.

Grimes, W D; Schrieber, C F; Manning, J A

1980-07-01T23:59:59.000Z

18

Measurements of Ammonia at Blodgett Forest  

SciTech Connect

Ammonia is a reactive trace gas that is emitted in large quantities by animal agriculture and other sources in California, which subsequently forms aerosol particulate matter, potentially affecting visibility, climate, and human health. We performed initial measurements of NH{sub 3} at the Blodgett Forest Research Station (BFRS) during a 3 week study in June, 2006. The site is used for ongoing air quality research and is a relatively low-background site in the foothills of the Sierra Nevada. Measured NH{sub 3} mixing ratios were quite low (< 1 to {approx}2 ppb), contrasting with typical conditions in many parts of the Central Valley. Eddy covariance measurements showed NH{sub 3} fluxes that scaled with measured NH{sub 3} mixing ratio and calculated aerodynamic deposition velocity, suggesting dry deposition is a significant loss mechanism for atmospheric NH{sub 3} at BFRS. A simple model of NH{sub 3} transport to the site supports the hypothesis that NH{sub 3} is transported from the Valley to BFRS, but deposits on vegetation during the summer. Further work is necessary to determine whether the results obtained in this study can be generalized to other seasons.

Fischer, Marc L.; Littlejohn, David

2007-04-01T23:59:59.000Z

19

High-pressure storage of hydrogen fuel: ammonia borane and its related compounds  

Science Journals Connector (OSTI)

As a promising candidate material for hydrogen storage, ammonia borane (NH3BH3) has attracted significant interest in recent years due to its remarkably high hydrogen content. Subjecting this material to high pre...

Yu Lin; Wendy L. Mao

2014-09-01T23:59:59.000Z

20

Structural basis for the transformation pathways of the sodium naproxen anhydrate-hydrate system  

Science Journals Connector (OSTI)

Relationships between the crystal structures of two polymorphs of sodium naproxen dihydrate and its monohydrate and anhydrate phases provide a basis to rationalize the observed transformation pathways in the sodium (S)-naproxen anhydrate-hydrate system.

Bond, A.D.

2014-08-20T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Materials corrosion in ammonia/solid heat pump working media  

SciTech Connect

Salt/ammonia complexes will undergo thermal cycles during use as working media for heat pumps. The interaction between container materials and complexes under thermal cyclic conditions was assessed to screen possible containment materials. Aluminum alloys 3003, 1100, and 6063 and carbon steel A214 were tested against possible heat pump working media SrCl{sub 2}/NH{sub 3}, CaBr{sub 2}/NH{sub 3}, and CaCl{sub 2}/NH{sub 3}. None of the containment materials showed susceptibility to stress corrosion cracking. While all the materials demonstrated excellent general corrosion resistance to SrCl{sub 2}/NH{sub 3}, only A214 displayed good general corrosion resistance to CaCl{sub 2}/NH{sub 3}. The complex CaBr{sub 2}/NH{sub 3} was found to be subject to thermal cyclic instability and should not be used as a heat pump working medium.

Wilson, D.F.; Howell, M.; DeVan, J.H.

1992-01-01T23:59:59.000Z

22

Compact anhydrous HCl to aqueous HCl conversion system  

DOE Patents (OSTI)

The present invention is directed to an inexpensive and compact apparatus adapted for use with a .sup.196 Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

Grossman, Mark W. (Belmont, MA); Speer, Richard (S. Hamilton, MA)

1993-01-01T23:59:59.000Z

23

Effects of Microbial Litter Amendments on Broiler Performance, Litter Quality and Ammonia Production  

E-Print Network (OSTI)

. Ammonia Production in Poultry Litter Ammonia has been and continues to be a major issue within the poultry industry. Not only does NH3 have effects on farm management, it also plays a role in poultry health, which will be discussed in following...

Hinkle, Matthew

2011-02-22T23:59:59.000Z

24

Vibrational spectroscopy of the ammoniated ammonium ions NH sub 4 sup + (NH sub 3 ) sub n (n = 1-10)  

SciTech Connect

The gas-phase vibration-internal rotation spectra of mass-selected ammoniated ammonium ions, NH{sub 4}{sup +}(NH{sub 3}){sub n} (for n = 1-10), have been observed from 2600 to 4000 cm{sup {minus}1}. The spectra show vibrational features that have been assigned to modes involving both the ion core species, NH{sub 4}{sup +}, and the first shell NH{sub 3} solvent molecules. Nearly free internal rotation of the solvent molecules about their local C{sub 3} axes in the first solvation shell has been observed in the smaller clusters (n = 1-6). For the larger clusters studied (n = 7-10) the spectra converge, with little difference between clusters differing by one solvent molecule. For these clusters, the spectrum in the 3200-3500 cm{sup {minus}1} region is quite similar to that of liquid ammonia, and the entire region of 2600-3500 cm{sup {minus}1} also bears considerable resemblance to the spectra of ammonium salts dissolved in liquid ammonia under some chemical conditions. This indicates the onset of a liquidlike environment for the ion core and first shell solvent molecules in clusters as small as NH{sub 4}{sup +}(NH{sub 3}){sub 8}.

Price, J.M.; Crofton, M.W.; Lee, Y.T. (Lawrence Berkeley Lab., CA (United States) Univ. of California, Berkeley (United States))

1991-03-21T23:59:59.000Z

25

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania  

E-Print Network (OSTI)

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

Kentucky, University of

26

Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation  

SciTech Connect

This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

1995-05-01T23:59:59.000Z

27

Atmospheric Environment 42 (2008) 33153331 Measurement and analysis of ammonia and hydrogen sulfide  

E-Print Network (OSTI)

; Hydrogen sulfide; Swine barns; CAFOs 1. Introduction Changes in livestock production methods in the USAtmospheric Environment 42 (2008) 3315­3331 Measurement and analysis of ammonia and hydrogen, where NH3­N ¼ (14 17)NH3) and hydrogen sulfide (H2S) were measured from a finishing swine confinement

Aneja, Viney P.

28

IR Vibration-Rotation Spectra of the Ammonia Molecule  

Science Journals Connector (OSTI)

The IR spectrum of the ammonia inversion vibration-rotation normal mode is obtained using Fourier Transform IR Spectroscopy and analyzed using Maple, to easily obatin the relation between the N-H bond length and the H-N-H bond angle. As expected, the ...

Carl W. David

1996-01-01T23:59:59.000Z

29

.Research Module: Scheme 2. N-Benzylation of N-H Pyrazolidinones 3. 3 6. 60 Scheme 2 Procedure: N-Alkylation Using Aldehyde  

E-Print Network (OSTI)

folder. It will actually produce two NMR printouts for you. The first one will be dominated by methanol Scheme 1, add 10 mL of anhydrous methanol. · For 4-methoxy compoud 3c, add 20 mL of methanol, since the 4-Benzylation Synthesis of N-Benzyl Pyrazolidinones NH NH O R1 3a-e + H O 4 Methanol Solvent 0.05 CF3CO2H (catalyst) N N O

Jasperse, Craig P.

30

Formation of hydroxylamine on dust grains via ammonia oxidation  

E-Print Network (OSTI)

The quest to detect prebiotic molecules in space, notably amino acids, requires an understanding of the chemistry involving nitrogen atoms. Hydroxylamine (NH$_2$OH) is considered a precursor to the amino acid glycine. Although not yet detected, NH$_2$OH is considered a likely target of detection with ALMA. We report on an experimental investigation of the formation of hydroxylamine on an amorphous silicate surface via the oxidation of ammonia. The experimental data are then fed into a simulation of the formation of NH$_2$OH in dense cloud conditions. On ices at 14 K and with a modest activation energy barrier, NH$_2$OH is found to be formed with an abundance that never falls below a factor 10 with respect to NH$_3$. Suggestions of conditions for future observations are provided.

He, Jiao; Lemaire, Jean-Louis; Garrod, Robin T

2015-01-01T23:59:59.000Z

31

Efficient chemical regeneration of LiBH4NH3 spent fuel for hydrogen storage  

Science Journals Connector (OSTI)

Abstract The absence of an efficient method for the regeneration of ammine metal borohydrides (M(BH4)nxNH3, AMBs) from their dehydrogenated products has hindered their potential application as hydrogen storage materials. In this paper, we demonstrate a high-yield chemical regeneration of LiBH4NH3 based on a three step process (digestion (H+ addition), reduction (H? addition), and ammonia complexation) at ambient temperature. Our results demonstrated that LiBN polymer was digested by methanol to form LiB(OCH3)4, which can be converted into LiBH4 by using LiAlH4 in the reduction process. The generation of LiBH4NH3 in ammonia complexion step was achieved by exposing the obtained LiBH4 in an ammonia atmosphere.

Yingbin Tan; Xiaowei Chen; Guanglin Xia; Xuebin Yu

2014-01-01T23:59:59.000Z

32

Simulation of an Ar/NH{sub 3} low pressure magnetized direct current discharge  

SciTech Connect

A two-dimensional fluid model has been used to investigate the properties of plasma in an Ar/NH{sub 3} low pressure magnetized direct current discharge. We compared the simulation results with the theoretical and experimental results of the other gas discharge in which the magnetic field is considered. Results that obtained using this method are in good agreement with literature. The simulation results show that the positive ammonia ion density follows the positive argon ion density. The Ar{sub 2}{sup +} density is slightly higher than the Ar{sup +} density at 100 mTorr. The largest ammonia ion is NH{sub 3}{sup +} ion, followed by NH{sub 2}{sup +}, NH{sub 4}{sup +}, and NH{sup +} ions. The contribution of NH{sup +} ions to the density of the positive ammonia ions is marginal. The influence of pressure on the plasma discharge has been studied by simulation, and the mechanisms have been discussed. The average plasma density increases as pressure increased. The plasma density appears to be more inhomogeneous than that at the lower pressure. The ratio of charge particles changed as pressure increased. The Ar{sup +} density is slightly higher than the Ar{sub 2}{sup +} density as the pressure increased. It makes NH{sub 4}{sup +} ratio increase as pressure increased. It shows that the electron temperature drops with rising pressure by numerical calculation.

Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physiccal Science and Technical College, Dalian University, Dalian 116622 (China)

2013-01-15T23:59:59.000Z

33

Rheological Study of Mutarotation of Fructose in Anhydrous State  

SciTech Connect

Rheological measurement was employed to study the mutarotation of D-fructose in anhydrous state. By monitoring the evolution of shear viscosity with time, rate constants for mutarotation were estimated, and two different stages of this reaction were identified. One of the mutarotation stages is rapid and has a low activation energy, whereas the other is much slower and has a much higher activation energy. Possible conversions corresponding to these two phases are discussed. This work demonstrates that, in addition to the routine techniques such polarimetry and gas liquid chromatography, rheological measurement can be used as an alternative method to continuously monitor the mutarotation of sugars.

Wang, Yangyang [ORNL; Wlodarczyk, Patryk [Institute ofNon-Ferrous Metals, Sowinskiego Gliwice, POLAND; Sokolov, Alexei P [ORNL; Paluch, Marian W [ORNL

2013-01-01T23:59:59.000Z

34

Ammonia synthesis gas purification  

SciTech Connect

This patent describes the purification of a reformed gas mixture following water gas shift conversion to produce a purified ammonia synthesis gas stream. The improved processing sequence consisting essentially of: (A) Selectively catalytically oxidizing the residual carbon monoxide content of the gas mixture to carbon dioxide so as to reduce the carbon monoxide content of the gas mixture to less than about 20 ppm, the selective catalytic oxidation being carried out with an excess of air, with the excess oxygen being catalytically reacted with a small amount of hydrogen so that the residual oxygen level is reduced to less than about 3 ppm; (B) removing the bulk of the carbon dioxide content of the gas mixture by liquid absorption; (C) Removing residual amounts of carbon monoxide, carbon dioxide and water by selective adsorption on the fixed beds of a thermal swing adsorption system, a dry, purified ammonia ammonia synthesis gas stream containing less than a total of 10 ppm of carbon monoxide and carbon dioxide being recovered from the thermal swing adsorption system; (D) Passing the resulting dry, purified ammonia synthesis gas stream having a low content of methane to an ammonia production operation without intermediate passage of the ammonia synthesis gas stream to a methanation unit or to a cryogenic unit for removal of carbon monoxide and carbon dioxide therefrom; whereby the efficiency of the overall purification operation and the effective utilization of hydrogen are enhanced.

Fuderer, A.

1986-02-25T23:59:59.000Z

35

A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The  

Open Energy Info (EERE)

A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Details Activities (0) Areas (0) Regions (0) Abstract: Olivine, pyroxene and garnet are nominally anhydrous but can accommodate tens to hundreds of parts per million (ppm) H2O or "water" in the form of protons incorporated in defects in their mineral structure. This review concerns the amount of water in nominally anhydrous minerals from mantle and mantle-derived rocks: peridotites, eclogites, megacrysts, basalts and kimberlites. Trends between internal and external parameters

36

Study of the action of ammonia on phosphorus trifluoride. Density study of the two components system propylene-etylene in the liquid state.  

E-Print Network (OSTI)

??Part I: Ammonia can react with phosphorus trifluoride only at low temperature, (-78c.), to produce ammonium fluoride and phosphotriamide, P (NH2)3. This last compound is (more)

Brais, Roger.

1942-01-01T23:59:59.000Z

37

The effect of dietary protein and fiber on in vivo ammonia concentration  

E-Print Network (OSTI)

protein level, ten animals received a basal fiber-free diet, ten received the same diet diluted with 8X cellulose, and ten received the basal diet diluted with BX pectin. Cecal total ammonia (NH + NH ) concentration was highest 4 in the fiber-free high... protein and the cellulose high protein-fed rats. The proximal colon ammonia concentration was greatest in the fiber-free high protein treatment group, and the pectin-fed rats had a significantly greater concentration than the cellulose groups...

Marchant, Linda Jean

1986-01-01T23:59:59.000Z

38

mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the  

E-Print Network (OSTI)

mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the Primordial Atmosphere mixing ratio of am- monia of 10-5 or greater would provide a sufficient greenhouse effect to keep of longwave radiation NH3 could pro- duce a substantial "greenhouse effect" and maintain a surface temperature

Atreya, Sushil

39

Degradation of untreated and anhydrous ammonia-treated wheat straw by two strains of rumen anaerobic fungi  

E-Print Network (OSTI)

cellulose and xylans of hemicel- luloses, but little is known about the specif- ic role of each species, the phloem and the parenchyma were slightly degraded and rhizoids were visible on the surface of the plant frag- ments. After 24 h the mass of rhizoids on the surface of the plant fragments was so large

Paris-Sud XI, Université de

40

Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam  

Energy.gov (U.S. Department of Energy (DOE))

The Department of Energy's SunShot Initiative has made an award to University of California, Los Angeles (UCLA) through the Concentrating Solar Power: Efficiently Leveraging Equilibrium Mechanisms for Engineering New Thermochemical Storage (CSP: ELEMENTS) funding program.

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

42

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect

Work completed in this reporting period focused primarily on continuing measurements of the rate of ammonia loss from concrete, and the measurement of ammonia gas in the air above concrete and flowable fill immediately after placement. Concrete slabs were prepared to monitor the loss of ammonia during mixing, the concentration in the airspace above the slabs soon after placement, and the total quantity of ammonia evolved over a longer time period. Variables tested include temperature, ventilation rate, water:cementitious (W:C) ratio, and fly ash source. Short-term data indicate that for concrete placed in areas with poor air ventilation the fly ash NH{sub 3} concentration should not exceed about 90 to 145 mg/kg ash, depending on the water:cement ratio and the fly ash replacement rate, if a concentration of 10 ppm NH{sub 3} in the air is assumed to be the maximum acceptable level. Longer-term experiments showed that the ammonia loss rate is dependent on ammonia source (that is ammoniated ash vs. non-ammoniated ash with ammonia added to the water), and is also dependent on W:C ratio and temperature. Experiments were also conducted to study the loss of ammonia from fresh concrete during mixing. It was found that a high water:cementitious mix lost a greater percentage of ammonia than a low W:C mix, with a medium W:C mix losing an amount intermediate between these two. However, a larger batch size resulted in a smaller percentage of ammonia lost. The data suggest that a significant quantity of ammonia could be lost from Ready Mix concrete during transit, depending on the transit time, batch size, and mix proportions.

Robert F. Rathbone; Thomas L. Robl

2002-04-11T23:59:59.000Z

43

Rotational dynamics in ammonia borane: Evidence of strong isotope effects  

SciTech Connect

This work reports anelastic spectroscopy measurements on the partially deuterated (ND3BH3 and NH3BD3) and perdeuterated (ND3BD3) ammonia borane (NH3BH3) compounds. The relaxations previously reported in NH3BH3 are observed in all the samples, and are ascribed to the rotational and torsional dynamics of NH(D)3BH(D)3 complexes. A new thermally activated peak appears at 70 K (for a vibration frequency of 1 kHz) in the spectrum of NH3BD3 and ND3BD3. The peak is practically a single-time Debye process, indicating absence of interaction between the relaxing units, and has a strikingly high intensity. A secondary relaxation process is also detected around 55 K. The anelastic spectrum of the ND3BH3 only displays this less intense process at 55 K. The analysis of the peaks supplies information about the dynamics of the relaxing species, and the obtained results provide indications on the effect of partial and selective deuteration on the hydrogen (deuterium) dynamics.

Cantelli, Rosario; Paolone, Annalisa; Palumbo, Oriele; Leardini, F.; Autrey, Thomas; Karkamkar, Abhijeet J.; Luedtke, Avery T.

2013-12-15T23:59:59.000Z

44

Category:Concord, NH | Open Energy Information  

Open Energy Info (EERE)

Go Back to PV Economics By Location Go Back to PV Economics By Location Media in category "Concord, NH" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Concord NH Public Service Co of NH.png SVFullServiceRestauran... 74 KB SVHospital Concord NH Public Service Co of NH.png SVHospital Concord NH ... 75 KB SVLargeHotel Concord NH Public Service Co of NH.png SVLargeHotel Concord N... 74 KB SVLargeOffice Concord NH Public Service Co of NH.png SVLargeOffice Concord ... 76 KB SVMediumOffice Concord NH Public Service Co of NH.png SVMediumOffice Concord... 74 KB SVMidriseApartment Concord NH Public Service Co of NH.png SVMidriseApartment Con... 71 KB SVOutPatient Concord NH Public Service Co of NH.png SVOutPatient Concord N... 72 KB SVPrimarySchool Concord NH Public Service Co of NH.png

45

An ammonia refrigerator with an absorption circuit as economizer  

Science Journals Connector (OSTI)

The experimental results of a compression refrigerator with an integrated solution circuit, a so-called compression-absorption cycle, are presented. The compression refrigerator operates with ammonia (NH3) as refrigerant. The cycle is improved by two-stage throttling of the condensate and an absorption circuit which replaces the economizer compressor. The absorption circuit operates on the working pair ammonia/water (NH3/H2O). It is driven by superheat of the compressor without additional heat input from an external source. By this means the benefit of two-stage throttling, namely a reduction in compression work or an increase in refrigeration capacity, can be doubled. In the experiments an improvement of up to 9% in the efficiency of the NH3-refrigeration cycle has been attained. Compared to a simple compression refrigerator, the presented compression-absorption cycle has a payback time of only several months. Compared to a conventional economizer refrigeration cycle, the payback can be expected within the range of several months to about four years.

F Ziegler; U Spindler

1993-01-01T23:59:59.000Z

46

Fast In Situ Airborne Measurement of Ammonia Using a Mid-Infrared Off-Axis ICOS Spectrometer  

SciTech Connect

A new ammonia (NH3) spectrometer was developed based on off-axis integrated cavity output spectroscopy. Its feasibility was demonstrated in airborne test flights in the troposphere on board of the Department of Energy (DOE) Gulfstream-1 (G-1) aircraft. This ammonia gas analyzer consists of an optical cell, a quantum-cascade laser, gas sampling system, electronics for control and data acquisition, and data-analysis software. The NH3 mixing ratio is determined from high-resolution NH3 absorption line shapes by tuning the laser wavelength over the sR(3,K) transition of the fundamental vibration band near 9.67 ?m. Excellent linearity is obtained in a wide range (0- 101 ppb) during calibration. The instrument is capable of collecting data at 2 Hz. Two research flights were conducted over Sunnyside, Washington. In the first test flight, the ammonia gas sensor was used to identify signatures of feedstock from local dairy farms with high vertical spatial resolution under low wind and stable atmospheric conditions. In the second flight, the NH3 spectrometer showed high sensitivity in capturing feedstock emission signals under windy and less stable conditions. Our results demonstrate that this new ammonia spectrometer is airborne feasible and that it has the capability to provide fast in situ observations of ammonia to advance our understanding of atmospheric compositions and aerosol formation.

Leen, Brian; Yu, Xiao-Ying; Gupta, Manish; Baer, Douglas S.; Hubbe, John M.; Kluzek, Celine D.; Tomlinson, Jason M.; Hubbell, Michael R.

2013-09-17T23:59:59.000Z

47

Control of catalytic hydrotreating selectivity with ammonia. Final technical report  

SciTech Connect

The purpose of this study was to explore the possibility of control of product selectivity in the hydroprocessing of coal liquids and related substances by adding small amounts of ammonia. Quinoline was used in this study and in many others as representative of heterocyclic N compounds found in coal liquids. Coal liquids also contain hydroxy pyridines, but by studies with 8-OH quinoline, a representative compound (Part I), we demonstrated that the OH group was rapidly removed at the beginning of reaction to form quinoline, which reacted in the same manner as quinoline fed as such. In Part II we showed that in a mixture of naphthalene and quinoline, with the addition of ammonia there is an operating region in which complete HDN of quinoline can be achieved, but with greater conversion of naphthalene to tetralin instead of to decalin than was the case in the absence of added ammonia. This is of some significance to coal liquefaction since tetralin is a good hydrogen donor, but decalin is not. In Part III we showed that NH{sub 3} addition to a mixture of quinoline and phenanthrene provides an operating region where complete HDN of quinoline can be achieved with reduced formation of hydrogenated phenanthrenes and cracking to biphenyl. Part IV, a study of the hydrodeoxygenation (DHO) of dibenzofuran in the presence of naphthalene, showed that NH{sub 3} strongly inhibits HDO reactions and its effects on naphthalene here were much the same as in Part II. In Part V it was demonstrated that in the hydrotreating of propylbenzene, the addition of ammonia increased the selectivity towards ring hydrogenation (generally desired for reformulated motor fuels) and away from dealkylation (generally undesired), but the overall reaction rate at a fixed temperature drops substantially.

Satterfield, C.N.; Lee, C.; Gultekin, S.

1993-11-01T23:59:59.000Z

48

The Viscosity of Ammonia  

Science Journals Connector (OSTI)

A new representation of the viscosity of ammonia is presented. The representative equations are based on a set of experimental data selected as a result of a critical assessment of the available information. The validity of the representation extends from 196 K to the critical temperature for both liquid and vapor phases. In the supercritical region the temperature range extends to 680 K for pressures at or below ambient and to 600 K for pressures up to 50 MPa. The accuracy of the representation varies from 0.5% for the viscosity of the dilute gas phase at moderate temperatures to about 5% for the viscosity at high pressures and temperatures. Tables of the viscosity generated by the correlating equation at selected temperatures and pressures and along the saturation line are presented to provide easy reference as well as for the validation of computer codes.

A. Fenghour; William A. Wakeham; V. Vesovic; J. T. R. Watson; J. Millat; E. Vogel

1995-01-01T23:59:59.000Z

49

3-D agricultural air quality modeling: Impacts of NH3/H2S gasphase reactions and bi-directional exchange of NH3  

Science Journals Connector (OSTI)

Abstract Accurately simulating the transport and fate of reduced nitrogen (NHx=ammonia (NH3)+ammonium (NH4+))- and sulfur-containing compounds emitted from agricultural activities represents a major challenge in agricultural air quality modeling. In this study, the Community Multiscale Air Quality (CMAQ) modeling system is further developed and improved by implementing 22 ammonia (NH3)/hydrogen sulfide (H2S) related gas-phase reactions and adjusting a few key parameters (e.g., emission potential) for bi-directional exchange of NH3 fluxes. Several simulations are conducted over the eastern U.S. domain at a 12-km horizontal resolution for January and July 2002 to examine the impacts of those improved treatments on air quality. The 5th generation mesoscale model (MM5) and CMAQ predict an overall satisfactory and consistent performance with previous modeling studies, especially for 2-m temperature, 2-m relative humidity, ozone (O3), and fine particulate matter (PM2.5). High model biases exist for precipitation in July and also dry/wet depositions. The updated model treatments contribute to O3, NHx, and PM2.5 by up to 0.4ppb, 1.0?gm?3, and 1.0?gm?3 in January, respectively, and reduce O3 by up to 0.8ppb and contribute to \\{NHx\\} and PM2.5 by up to 1.2 and 1.1?gm?3 in July, respectively. The spatial distributions of O3 in both months and sulfur dioxide (SO2) in January are mainly affected by inline dry deposition velocity calculation. The spatial distributions of SO2 and sulfate (SO42?) in July are affected by both inline dry deposition velocity and NH3/H2S reactions. The variation trends of NH3, NHx, ammonium nitrate (NH4NO3), PM2.5 and total nitrogen (TN) are predominated by bi-directional exchange of NH3 fluxes. Uncertainties of NH3 emission potentials and empirical constants used in the bi-directional exchange scheme may significantly affect the concentrations of \\{NHx\\} and PM2.5, indicating that a more accurate and explicit treatment for those parameters should be considered in the future work.

Kai Wang; Yang Zhang

2014-01-01T23:59:59.000Z

50

Anhydrous Phosphoric Acid Functionalized Sintered Mesoporous Silica Nanocomposite Proton Exchange Membranes for Fuel Cells  

Science Journals Connector (OSTI)

Anhydrous Phosphoric Acid Functionalized Sintered Mesoporous Silica Nanocomposite Proton Exchange Membranes for Fuel Cells ... The cell performance and stability may be further improved through an optimization of the interfacial contact between the electrocatalytic layer and the inorganic membrane. ... polycondensation procedure was optimized for individual case of PBI synthesis in order to obtain inherent viscosity of ?1 dL/g. ...

Jie Zeng; Beibei He; Krystina Lamb; Roland De Marco; Pei Kang Shen; San Ping Jiang

2013-10-14T23:59:59.000Z

51

OPTICAL CONSTANTS OF NH{sub 3} AND NH{sub 3}:N{sub 2} AMORPHOUS ICES IN THE NEAR-INFRARED AND MID-INFRARED REGIONS  

SciTech Connect

Ammonia ice has been detected on different astrophysical media ranging from interstellar medium (ISM) particles to the surface of various icy bodies of our solar system, where nitrogen is also present. We have carried out a detailed study of amorphous NH{sub 3} ice and NH{sub 3}:N{sub 2} ice mixtures, based on infrared (IR) spectra in the mid-IR (MIR) and near-IR (NIR) regions, supported by theoretical quantum chemical calculations. Spectra of varying ice thicknesses were obtained and optical constants were calculated for amorphous NH{sub 3} at 15 K and 30 K and for a NH{sub 3}:N{sub 2} mixture at 15 K over a 500-7000 cm{sup 1} spectral range. These spectra have improved accuracy over previous data, where available. Moreover, we also obtained absolute values for the band strengths of the more prominent IR features in both spectral regions. Our results indicate that the estimated NH{sub 3} concentration in ISM ices should be scaled upward by ?30%.

Zanchet, Alexandre; Rodrguez-Lazcano, Yamilet; Glvez, scar; Herrero, Vctor J.; Escribano, Rafael; Mat, Beln, E-mail: belen.mate@csic.es [Instituto de Estructura de la Materia, IEM-CSIC, Serrano 123, E-28006 Madrid (Spain)

2013-11-01T23:59:59.000Z

52

Exergy analysis of a novel air-cooled non-adiabatic absorption refrigeration cycle with NH3NaSCN and NH3LiNO3 refrigerant solutions  

Science Journals Connector (OSTI)

Abstract This paper presents a methodology of exergy analysis for ammonia-lithium nitrate and ammonia-sodium thiocyanate absorption refrigeration cycle which applies a novel air-cooled type non-adiabatic absorber to improve both the coefficient of performance and exegetic efficiency of the system under air cooling condition. A modified entropy calculation method for NH3/NaSCN and NH3/LiNO3 solutions is presented in this literature and different results are obtained comparing to previous research. In addition to the variation of solution temperature and pressure from specific working state to the reference state, the variation of solution concentration, which was always neglected by previous researchers in ammonia/salt solution exergy calculation, has been taken into account while analyzing the least potential of ammonia/salt solution for doing useful work, and a corresponding approach for specific exergy calculation is presented. The effects of generator temperature, absorber outlet temperature, absorber efficiency and other system parameters on system exergetic efficiency have been discussed in this study. Analysis results indicate that relatively high system performance can be obtained by air-cooled type ammonia/salt absorption refrigeration cycles when non-adiabatic absorbers are applied in these systems.

Dehua Cai; Guogeng He; Qiqi Tian; Weier Tang

2014-01-01T23:59:59.000Z

53

E-Print Network 3.0 - anhydrous alcohol evaporated Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

peroxide Copper, chromium, iron, most metals or their salts, alcohols, acetone... , carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia...

54

Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved...  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Abstract: Ammonia...

55

Excimer laser photochemistry of silane-ammonia mixtures at 193 nm  

SciTech Connect

The ArF excimer laser induced photochemistry of silane-ammonia mixtures has been studied with molecular beam sampling mass spectrometry. The observed products include disilane, trisilane, and all possible aminosilanes, SiH{sub x}(NH{sub 2}){sub 4-x}, x = 0-3. These products are formed under steady-state photolysis conditions and under single-laser-pulse conditions. A mechanism for the formation of these species is proposed and quantitatively evaluated.

Beach, D.B.; Jasinski, J.M. (Thomas J. Watson Research Center, Yorktown Heights, NY (USA))

1990-04-05T23:59:59.000Z

56

Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies  

E-Print Network (OSTI)

biomass into available and /or soluble sugars and organic acids (i. e. uronic acid esters etc. ). The chemical linkages between hemicellulose and lignin may be affected by ammoniation pre-treatment. The significance of this fact is that heavily cross... by Turner et al (1995) demonstrated a significant increase in the available energy and crude protein of NH3 treated maize. Ammoniation of rice straw (Pradhan et al, 1997) bound residual ammonia to fiber and yielded an increase in the level of crude...

Williams, James Jason

1999-01-01T23:59:59.000Z

57

Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3  

E-Print Network (OSTI)

SCR of NO with NH3 Padmanabha Reddy Ettireddy a , Neeraja Ettireddy a , Sergey Mamedov b , Punit-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with ammonia as a reductantO2 supported catalysts for low temperature SCR reaction at catalyst bed temperature 175 8C under

Boolchand, Punit

58

Understanding ammonia selective catalytic reduction kinetics...  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation,...

59

Laser separation of nitrogen isotopes by the IR+UV dissociation of ammonia molecules  

SciTech Connect

The separation of nitrogen isotopes is studied upon successive single-photon IR excitation and UV dissociation of ammonia molecules. The excitation selectivity was provided by tuning a CO{sub 2} laser to resonance with {sup 14}NH{sub 3} molecules [the 9R(30) laser line] or with {sup 15}NH{sub 3} molecules [the 9R(10) laser line]. Isotopic mixtures containing 4.8% and 0.37% (natural content) of the {sup 15}NH isotope were investigated. The dependences of the selectivity and the dissociation yield for each isotopic component on the buffer gas pressure (N{sub 2}, O{sub 2}, Ar) and the ammonia pressure were obtained. In the limit of low NH{sub 3} pressures (0.5-2 Torr), the dissociation selectivity {alpha}(15/14) for {sup 15}N was 17. The selectivity mechanism of the IR+UV dissociation is discussed and the outlook is considered for the development of the nitrogen isotope separation process based on this approach. (laser isotope separation)

Apatin, V M; Klimin, S A; Laptev, V B; Lokhman, V N; Ogurok, D D; Pigul'skii, S V; Ryabov, E A [Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow region (Russian Federation)

2008-08-31T23:59:59.000Z

60

Addition of NH{sub 3} to Al{sub 3}O{sub 3}{sup -}  

SciTech Connect

Recent computational studies on the addition of ammonia (NH{sub 3}) to the Al{sub 3}O{sub 3}{sup -} cluster anion [A. Guevara-Garcia, A. Martinez, and J. V. Ortiz, J. Chem. Phys. 122, 214309 (2005)] have motivated experimental and additional computational studies, reported here. Al{sub 3}O{sub 3}{sup -} is observed to react with a single NH{sub 3} molecule to form the Al{sub 3}O{sub 3}NH{sub 3}{sup -} ion in mass spectrometric studies. This is in contrast to similarly performed studies with water, in which the Al{sub 3}O{sub 5}H{sub 4}{sup -} product was highly favored. However, the anion PE spectrum of the ammoniated species is very similar to that of Al{sub 3}O{sub 4}H{sub 2}{sup -}. The adiabatic electron affinity of Al{sub 3}O{sub 3}NH{sub 3} is determined to be 2.35(5) eV. Based on comparison between the spectra and calculated electron affinities, it appears that NH{sub 3} adds dissociatively to Al{sub 3}O{sub 3}{sup -}, suggesting that the time for the Al{sub 3}O{sub 3}{sup -}{center_dot}NH{sub 3} complex to either overcome or tunnel through the barrier to proton transfer (which is higher for NH{sub 3} than for water) is short relative to the time for collisional cooling in the experiment.

Wyrwas, Richard B.; Jarrold, Caroline Chick; Das, Ujjal; Raghavachari, Krishnan [Indiana University, Department of Chemistry, Bloomington, Indiana 47405-7102 (United States)

2006-05-28T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Two-photon optical pumping of NH/sub 3/ in a multipass cell  

SciTech Connect

A multipass cell was used in optical pumping of ammonia molecules by CO/sub 2/ laser radiation. Several new lasing lines were observed in the case of two-photon optical pumping of the NH/sub 3/ molecule at wavelengths in the range 16--35 ..mu... The output power of the various lines was in the range 10--50 kW. The divergence of the resultant radiation was diffraction-limited. A theoretical study was made of the two-photon pumping process. A stable (on the frequency scale) maximum was found in the gain profile of the output radiation. It was concluded that it should be possible to increase the energy and extend the emission spectrum of an ammonia laser pumped by double-photon absorption.

Bobrovskii, A.N.; Kiselev, V.P.; Kozhevnikov, A.V.; Likhanskii, V.V.; Mishchenko, V.A.; Myl'nikov, G.D.

1983-11-01T23:59:59.000Z

62

Evaluation of calcium chloride and ammonium thiosulfate as ammonia volatilization inhibitors for surface-applied urea  

E-Print Network (OSTI)

million tons Total fertilizer Total N NH4NOs Anhydrous NHs N solutions Urea 22. 7 24. 9 42. 5 52. 8 41. 8 50. 1 1. 6 2. 74 8. 60 11. 4 9. 13 11. 1 1. 12 1. 23 2. 80 2. 63 2. 15 2. 19 0. 35 0. 71 4. 02 5. 48 3. 84 4. 71 0. 21 0. 65 4. 11 6. 67 6...-12 10-12 10-12 0-2 12-14 0-2 120 144 96 24 36 24 261 3128 218 1878 225 3104 In general, three major effects were observed: 1) The lag phase of NHs volatilization was delayed or lengthened. 2) The maximum N loss rate occurred later...

Sloan, John J.

1989-01-01T23:59:59.000Z

63

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect

The Clean Air Act Amendments of 1990 require large reductions in emissions of NO{sub x} from coal-fired electric utility boilers. This will necessitate the use of ammonia injection, such as in selective catalytic reduction (SCR), in many power plants, resulting in the deposition of ammonia on the fly ash. The presence of ammonia could create a major barrier to fly ash utilization in concrete because of odor concerns. Although there have been limited studies of ammonia emission from concrete, little is known about the quantity of ammonia emitted during mixing and curing, and the kinetics of ammonia release. This is manifested as widely varying opinions within the concrete and ash marketing industry regarding the maximum acceptable levels of ammonia in fly ash. Therefore, practical guidelines for using ammoniated fly ash are needed in advance of the installation of many more SCR systems. The goal of this project was to develop practical guidelines for the handling and utilization of ammoniated fly ash in concrete, in order to prevent a decrease in the use of fly ash for this application. The objective was to determine the amount of ammonia that is released, over the short- and long-term, from concrete that contains ammoniated fly ash. The technical approach in this project was to measure the release of ammonia from mortar and concrete during mixing, placement, and curing. Work initially focused on laboratory mortar experiments to develop fundamental data on ammonia diffusion characteristics. Larger-scale laboratory experiments were then conducted to study the emission of ammonia from concrete containing ammoniated fly ash. The final phase comprised monitoring ammonia emissions from large concrete slabs. The data indicated that, on average, 15% of the initial ammonia was lost from concrete during 40 minutes of mixing, depending on the mix proportions and batch size. Long-term experiments indicated that ammonia diffusion from concrete was relatively slow, with greater than 50% of the initial ammonia content remaining in an 11cm thick concrete slab after 1 month. When placing concrete in an enclosed space, with negligible ventilation, it is recommended that the ammonia concentration in the concrete mix water should not exceed 110 mg NH{sub 3}/L, if the NIOSH exposure limit of 25 ppm in the air is not to be exceeded. If even a modicum of ventilation is present, then the ammonia concentration in the concrete water should be less than 170 mg/L. The maximum level of ammonia in the fly ash can then be calculated using these limits if the concrete mix proportions are known. In general, during the mixing and placement of ammonia-laden concrete, no safety concerns were encountered. The only location where the ammonia concentration attained high levels (i.e. > 25 ppm in the air) was within the concrete mixing drum.

Robert F. Rathbone; Thomas L. Robl

2002-10-30T23:59:59.000Z

64

Production of anhydrous aluminum chloride composition and process for electrolysis thereof  

DOE Patents (OSTI)

A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

1983-01-01T23:59:59.000Z

65

Molecular dynamics simulation of anhydrous lithium acetate: crystalline and molten phases  

Science Journals Connector (OSTI)

The results of molecular dynamics simulations of the crystalline and molten phase of anhydrous lithium acetate are presented. The potential parameters were obtained from empirical fitting to the crystalline phases of the material. The simulations were carried out for 216 molecules in an NPT ensemble using the DLPOLY program. A structural model is proposed for both the crystalline and molten phases of lithium acetate. Calculated values of the melting point, diffusion coefficient and structural parameters of lithium acetate are in reasonable agreement with experimental results.

L.S. Barreto; K.A. Mort; R.A. Jackson; O.L. Alves

2002-01-01T23:59:59.000Z

66

Company Name: JobsInNH.com  

E-Print Network (OSTI)

Company Name: JobsInNH.com Web Site: www.jobsinnh.com Industry: Advertising & Marketing Brief Company Overview: "Since 2002, JobsInNH.com has been New Hampshire?s #1 employment resource. As recruiting and accelerate your job search. Connect with the best employers in the state who are hiring now" Majors

New Hampshire, University of

67

Optimizing the efficiency of anhydrous ethanol purification via regenerable molecular sieve  

Science Journals Connector (OSTI)

Abstract In response to the global energy development trend and greenhouse effects, bio-energy applications are gradually being taken seriously. Gasohol is an alternative fuel that consists of anhydrous ethanol (purity 99.3wt% or higher) blended with gasoline, which produces less air pollution than standard car fuels. A system was constructed for bio-ethanol production from molasses feedstock. The molasses was fermented and then distilled using a distillation tower, producing up to 90wt% ethanol concentration. This sample was further concentrated using 3A-type molecular sieves to adsorb water from the ethanol samples until saturated. The sieves were then regenerated for reuse via continuous heating by high-temperature nitrogen. The response surface methodology was applied to determine an optimized operational model for regeneration of molecular sieves. The results indicate that the cost of molecular sieve regeneration (unit energy yield was 0.283L/kWh) which can stand comparison with other purify methods. The optimal parameters were at a temperature of 193C and a heating time of 7h. 40min. The results also demonstrated that a yield of 60L anhydrous ethanol required energy consumption of 212.1kWh.

Wei-Cheng Chen; Chung-Teh Sheng; Yu-Cheng Liu; Wei-Jen Chen; Wen-Luh Huang; Shih-Hsien Chang; Wei-Che Chang

2014-01-01T23:59:59.000Z

68

Polyaniline-based optical ammonia detector  

DOE Patents (OSTI)

Electronic absorption spectroscopy of a polyaniline film deposited on a polyethylene surface by chemical oxidation of aniline monomer at room temperature was used to quantitatively detect ammonia gas. The present optical ammonia gas detector was found to have a response time of less than 15 s, a regeneration time of less than 2 min. at room temperature, and a detection limit of 1 ppm (v/v) for ammonia, with a linear dynamic range from 180 ppm to 18,000 ppm.

Duan, Yixiang (Los Alamos, NM); Jin, Zhe (Los Alamos, NM); Su, Yongxuan (Los Alamos, NM)

2002-01-01T23:59:59.000Z

69

DOE - Office of Legacy Management -- R Brew Co - NH 01  

NLE Websites -- All DOE Office Websites (Extended Search)

R Brew Co - NH 01 R Brew Co - NH 01 FUSRAP Considered Sites Site: R. BREW CO. (NH.01 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Concord , New Hampshire NH.01-1 Evaluation Year: 1994 NH.01-2 Site Operations: Conducted vacuum furnace tests using uranium and copper billets. NH.01-1 NH.01-3 Site Disposition: Eliminated - Potential for contamination remote NH.01-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium NH.01-1 NH.01-3 Radiological Survey(s): Yes - radiological monitoring during operations NH.01-3 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to R. BREW CO. NH.01-1 - Memorandum/Checklist; Landis to File; Subject: R. Brew

70

Layer of protection analysis applied to ammonia refrigeration systems  

E-Print Network (OSTI)

Ammonia refrigeration systems are widely used in industry. Demand of these systems is expected to increase due to the advantages of ammonia as refrigerant and because ammonia is considered a green refrigerant. Therefore, it is important to evaluate...

Zuniga, Gerald Alexander

2009-05-15T23:59:59.000Z

71

Decomposition Pathway of Ammonia Borane on the Surface of nano...  

NLE Websites -- All DOE Office Websites (Extended Search)

Decomposition Pathway of Ammonia Borane on the Surface of nano-BN. Decomposition Pathway of Ammonia Borane on the Surface of nano-BN. Abstract: Ammonia borane (AB) is under...

72

Urea/Ammonia Distribution Optimization in an SCR Emission Control...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

73

Geochemical and Geophysical Changes during Ammonia Gas Treatment...  

NLE Websites -- All DOE Office Websites (Extended Search)

Geophysical Changes during Ammonia Gas Treatment of Vadose Zone Sediments for Uranium Remediation. Geochemical and Geophysical Changes during Ammonia Gas Treatment of Vadose Zone...

74

Potential of High-Throughput Experimentation with Ammonia Borane...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potential of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation) Potential of High-Throughput Experimentation with Ammonia Borane...

75

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

76

Polymorphism and optical properties in [NH{sub 4}][InSe{sub 2}  

SciTech Connect

The solvothermal synthesis and characterization of two indium selenides with stoichiometry [NH{sub 4}][InSe{sub 2}] is described. Yellow [NH{sub 4}][InSe{sub 2}] (1), which exhibits a layered structure, was initially prepared in an aqueous solution of trans-1,4-diaminocyclohexane, and subsequently using a concentrated ammonia solution. A red polymorph of one-dimensional character, [NH{sub 4}][InSe{sub 2}] (2), was obtained using 3,5-dimethylpyridine as solvent. [NH{sub 4}][InSe{sub 2}] (1) crystallizes in the non-centrosymmetric space group Cc (a=11.5147(6), b=11.3242(6), c=15.9969(9) and ?=100.354(3)). The structural motif of the layers is the In{sub 4}Se{sub 10} adamantane unit, composed of four corner-linked InSe{sub 4} tetrahedra. These units are linked by their corners, forming [InSe{sub 2}]{sup ?} layers which are stacked back to back along the c-direction, and interspaced by [NH{sub 4}]{sup +}cations. The one-dimensional polymorph, (2), crystallizes in the tetragonal space group, I4/mcm (a=8.2519(16), c=6.9059 (14) ). This structure contains infinite chains of edge-sharing InSe{sub 4} tetrahedra separated by [NH{sub 4}]{sup +} cations. - Graphical abstract: Two polymorphic forms of [NH{sub 4}][InSe{sub 2}], which are yellow and red, have been prepared and their optical properties investigated. Highlights: Two new indium selenides prepared by a solvothermal method. Depending on synthesis conditions, two polymorphic forms of [NH{sub 4}][InSe{sub 2}] prepared. Layered polymorph contains In{sub 4}Se{sub 10} adamantane clusters, linked by their corners. One-dimensional polymorph contains [InSe{sub 2}]{sup ?} chains of edge-sharing tetrahedra. Non-centrosymmetric layered polymorph shows a second harmonic generation response.

Ewing, Sarah J. [Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, Scotland EH14 4AS (United Kingdom); Woodward, David I. [Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Powell, Anthony V. [Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, Scotland EH14 4AS (United Kingdom); Vaqueiro, Paz, E-mail: P.Vaqueiro-Rodriguez@hw.ac.uk [Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, Scotland EH14 4AS (United Kingdom)

2013-08-15T23:59:59.000Z

77

Ammonia Solubility in High Concentration Salt Solutions  

SciTech Connect

Solubility data for ammonia in water and various dilute solutions are abundant in the literature. However, there is a noticeable lack of ammonia solubility data for high salt, basic solutions of various mixtures of salts including those found in many of the Hanford Washington underground waste tanks. As a result, models based on solubility data for dilute salt solutions have been used to extrapolate to high salt solutions. These significant extrapolations need to be checked against actual laboratory data. Some indirect vapor measurements have been made. A more direct approach is to determine the ratio of solubility of ammonia in water to its solubility in high salt solutions. In various experiments, pairs of solutions, one of which is water and the other a high salt solution, are allowed to come to equilibrium with a common ammonia vapor pressure. The ratio of concentrations of ammonia in the two solutions is equal to the ratio of the respective ammonia solubilities (Henry's Law constants) at a given temperature. This information can then be used to refine the models that predict vapor space compositions of ammonia. Ammonia at Hanford is of concern because of its toxicity in the environment and its contribution to the flammability of vapor space gas mixtures in waste tanks.

HEDENGREN, D.C.

2000-02-01T23:59:59.000Z

78

Method for releasing hydrogen from ammonia borane  

DOE Patents (OSTI)

A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

2013-02-19T23:59:59.000Z

79

Hydrogen Storage in Ammonia and Aminoborane Complexes  

E-Print Network (OSTI)

Hydrogen Storage in Ammonia and Aminoborane Complexes Ali Raissi Florida Solar Energy Center;Advantages of Ammonia Costs about $150 per short ton or less than $6.25 per million BTU of H2 contained and utilization Stores 30% more energy by liquid volume than LH2 Easily reformed using 16% of the energy

80

Characterization of Chemically Vapor Deposited Silicon Nitride Films from Disilane and Ammonia  

Science Journals Connector (OSTI)

Amorphous silicon nitride films a:SiNx were prepared by low pressure chemical vapor deposition (LPCVD) from disilane ( Si2H6) and ammonia ( NH3). Most of the depositions were performed at 600 C with various NH3/Si2H6 gas ratios ranging from 4 to 50. Different deposits with composition (x= N/Si) ranging from silicon-rich to stoichiometric silicon nitride were characterized by means of infrared spectroscopy (FTIR), ellipsometry, electron energy loss spectroscopy (EELS), and their structure analysed by transmission electron microscopy (TEM). Transmission infrared measurements showed low hydrogen content (x= N/Si) and density of the films were correlated with their refractive index and discussed.

Redhouane Henda; Larbi Laanab; Emmanuel Scheid; Robert Fourmeaux

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Reaction of iron clusters with ammonia. I. Compositions of the ammoniated products and their implications for cluster structure  

SciTech Connect

Studies are described of the chemisorption of ammonia on isolated neutral iron clusters Fe/sub n/ for 2less than or equal tonless than or equal to165. Clusters are generated by laser vaporization in a continuous-flow-tube reactor, and reaction products are detected by laser-ionization time-of-flight mass spectrometry. Ammonia is found to chemisorb nondissociatively on cluster surfaces on the 1 ms time scale of these experiments. Measurements of ammonia uptake provide information on adsorption kinetics and on the number and nature of the binding sites. The ammonia binding energy is found to decrease with increasing cluster coverage. For chemically saturated clusters, the ratio of adsorbed NH/sub 3/ molecules to surface iron atoms is found to decrease with increasing cluster size, going from >1/3 for small clusters to <1/3 for n>100. Ammonia chemisorption is accompanied by a large decrease in cluster ionization potentials, as much as 2 eV for saturated clusters. At sufficiently high exposure the beginning of the formation of a second, physisorbed layer of molecules is seen. Detailed measurements of product composition under different exposure conditions give evidence for numerous changes in cluster structure throughout the growth sequence from small to large clusters. Often these structural changes involve particularly stable reaction products. Evidence for the existence of metastable structures is presented. Several possibilities for cluster structure are suggested.

Parks, E.K.; Nieman, G.C.; Pobo, L.G.; Riley, S.J.

1988-05-15T23:59:59.000Z

82

Apple Tree, NH Big Tree for May By Anne Krantz, NH Big Tree Team,  

E-Print Network (OSTI)

Apple Tree, NH Big Tree for May By Anne Krantz, NH Big Tree Team, UNH Cooperative Extension The explosion of apple blossoms in May transforms the most gnarled old tree into a delicate cloud of beauty (1817-1862) in his essay "The Wild Apple Tree," described the blossoms perfectly: `The flowers

New Hampshire, University of

83

Process for ammonia syngas manufacture  

SciTech Connect

This patent describes an improved process for reforming hydrocarbons to obtain a synthesis gas containing an approximately stoichiometric amount of hydrogen and nitrogen from which ammonia may be formed in which a hydrocarbon is reacted with steam and air in a reforming operation to obtain a first effluent. This effluent consists of hydrogen, nitrogen and carbon monoxide. The carbon monoxide is reacted in a shift conversion stage to produce a second effluent consisting of hydrogen, nitrogen, and carbon dioxide. The improved process has the additional steps of separating the second effluent into a first stream and a second stream. The first stream is reacted with air in a fuel cell to produce a byproduct stream and a product stream which is passed through a de-oxygenation stage to produce a purified stream. The second stream and the purified stream is passed into a pressure swing adsorption unit in which the synthesis gas and a waste fuel stream are separated.

Jungerhans, R.R.J.

1986-03-25T23:59:59.000Z

84

Electronic band?shape calculations in ammonia  

Science Journals Connector (OSTI)

The vibronic nature of the lowest energy electronic absorption and of the lowest energy photoelectron spectrum of NH3 are investigated theoretically. Two?dimensional FranckCondon factor calculations are performed and theoretical spectra are constructed including the effect of vibronic linewidth. The comparison of the experimental with theoretical spectra computed under various assumptions leads to several conclusions. The conspicuous continuum underlying the ??? transition is seen to arise from the overlapping tails of vibronic line shapes. There is no need to attribute the continuum to a second electronic transition. The ?1 NH stretching mode is excited in both the electronic absorption and photoelectron spectrum. The ? state of NH3 may be able to support two quanta of ?1. The planar NH3 + ion has a NH bond longer than in the ground state NH3 by about 0.06 .

Phaedon Avouris; A. R. Rossi; A. C. Albrecht

1981-01-01T23:59:59.000Z

85

Ammonia evolution during oil shale pyrolysis  

Science Journals Connector (OSTI)

Ammonia evolution during oil shale pyrolysis ... Parallel pyrolytic studies were carried out on an immature, ultralaminae-rich, type I kerogen (Gynk oil shale kerogen) and a related algaenan (isolated from the extant green microalga Scenedesmus communis). ...

Myongsook S. Oh; Robert W. Taylor; Thomas T. Coburn; Richard W. Crawford

1988-01-01T23:59:59.000Z

86

Determination of the ( Ammonium (NH4  

E-Print Network (OSTI)

, paleoclimate history, biologic cycling of nutrients, ground-water contamination, and natural remediation contributed to understanding of water-supply sustainability, ground-water/surface-water interactionsDetermination of the ( 15 N/ 14 N) of Ammonium (NH4 + ) in Water: RSIL Lab Code 2898 Chapter 15

87

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents (OSTI)

A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

Phillips, B.A.; Whitlow, E.P.

1998-09-22T23:59:59.000Z

88

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents (OSTI)

A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

1998-09-22T23:59:59.000Z

89

E-Print Network 3.0 - ammonia gas cell Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

HYDROGEN Rebecca Dunn, Keith Lovegrove Summary: state ammonia synthesis, direct ammonia fuel-cells, combustion characterisation of ammonia... . The only products of the complete...

90

NH House Committee_April27 2005  

NLE Websites -- All DOE Office Websites (Extended Search)

Mercury Control Mercury Control Technology R&D Program for Coal-Fired Boilers Working Session of the New Hampshire House Science, Technology, & Energy Committee April 26, 2005 Concord, New Hampshire Thomas J. Feeley, III thomas.feeley@netl.doe.gov National Energy Technology Laboratory NH House Committee_April 2005 Mercury Control Technology Field Testing Program Performance/Cost Objectives * Have technologies ready for commercial demonstration by 2007 for all coals * Reduce "uncontrolled" Hg emissions by 50-70% * Reduce cost by 25-50% compared to baseline cost estimates Baseline Costs: $50,000 - $70,000 / lb Hg Removed 2000 Year Cost NH House Committee_April 2005 Stages of Mercury Control Technology Development DOE RD&D Model Lab/Bench/Pilot-Scale Testing Field Testing

91

Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems  

E-Print Network (OSTI)

This paper presents case studies of two moderately sized ammonia refrigeration systems retrofitted for floating head pressure control. It also presents a parametric analysis to assist in selecting appropriate pressures in an ammonia refrigeration...

Barrer, P. J.; Jones, S. M.

92

Emission factors for ammonia and particulate matter from broiler Houses  

E-Print Network (OSTI)

of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids. volatile amines, indole, phenol, sulfur-containing compounds). Ammonia is produced from the microbial breakdown of uric acid in poultry manure. The decomposition... sulfate (Barthelmie and Pryor, 1998). Additionally, ammonia is an odorant and conditions conducive to the production of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids, volatile amines, indole, phenol, sulfur...

Redwine, Jarah Suzanne

2001-01-01T23:59:59.000Z

93

Local ammonia storage and ammonia inhibition in a monolithic copper-beta zeolite SCR catalyst  

SciTech Connect

Selective catalytic reduction of NO with NH{sub 3} was studied on a Cu-beta zeolite catalyst, with specific focus on the distributed NH{sub 3} capacity utilization and inhibition. In addition, several other relevant catalyst parameter distributions were quantified including the SCR zone, or catalyst region where SCR occurs, and NO and NH{sub 3} oxidation. We show that the full NH{sub 3} capacity (100% coverage) is used within the SCR zone for a range of temperatures. By corollary, unused NH{sub 3} capacity exists downstream of the SCR zone. Consequently, the unused capacity relative to the total capacity is indicative of the portion of the catalyst unused for SCR. Dynamic NH{sub 3} inhibition distributions, which create local transient conversion inflections, are measured. Dynamic inhibition is observed where the gas phase NH{sub 3} and NO concentrations are high, driving rapid NH{sub 3} coverage buildup and SCR. Accordingly, we observe dynamic inhibition at low temperatures and in hydrothermally aged states, but predict its existence very near the catalyst front in higher conversion conditions where we did not specifically monitor its impact. While this paper addresses some general distributed SCR performance parameters including Oxidation and SCR zone, our major new contributions are associated with the NH{sub 3} capacity saturation within the SCR zone and dynamic inhibition distributions and the associated observations. These new insights are relevant to developing accurate models, designs and control strategies for automotive SCR catalyst applications.

Auvray, Xavier P [Chalmers University of Technology, Sweden; Partridge Jr, William P [ORNL; Choi, Jae-Soon [ORNL; Pihl, Josh A [ORNL; Yezerets, Alex [Cummins, Inc; Kamasamudram, Krishna [Cummins, Inc; Currier, Neal [Cummins, Inc; Olsson, Louise [Chalmers University of Technology, Sweden

2012-01-01T23:59:59.000Z

94

Trends in On-Road Vehicle Emissions of Ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

Trends in On-Road Vehicle Emissions of Ammonia Trends in On-Road Vehicle Emissions of Ammonia Title Trends in On-Road Vehicle Emissions of Ammonia Publication Type Journal Article Year of Publication 2008 Authors Kean, Andrew J., David Littlejohn, George Ban-Weiss, Robert A. Harley, Thomas W. Kirchstetter, and Melissa M. Lunden Journal Atmospheric Environment Abstract Motor vehicle emissions of ammonia have been measured at a California highway tunnel in the San Francisco Bay area. Between 1999 and 2006, light-duty vehicle ammonia emissions decreased by 38 ± 6%, from 640 ± 40 to 400 ± 20 mg kg-1. High time resolution measurements of ammonia made in summer 2001 at the same location indicate a minimum in ammonia emissions correlated with slower-speed driving conditions. Variations in ammonia emission rates track changes in carbon monoxide more closely than changes in nitrogen oxides, especially during later evening hours when traffic speeds are highest. Analysis of remote sensing data of Burgard et al. (Environ Sci. Technol. 2006, 40, 7018-7022) indicates relationships between ammonia and vehicle model year, nitrogen oxides, and carbon monoxide. Ammonia emission rates from diesel trucks were difficult to measure in the tunnel setting due to the large contribution to ammonia concentrations in a mixed-traffic bore that were assigned to light-duty vehicle emissions. Nevertheless, it is clear that heavy-duty diesel trucks are a minor source of ammonia emissions compared to light-duty gasoline vehicles.

95

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES  

E-Print Network (OSTI)

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES A DISSERTATION SUBMITTED;ABSTRACT Autotrophic ammonia oxidation has been documented for the first time in deep- sea hydrothermal autotrophic ammonia oxidation at ~ 91 nM d-1 , and potentially produces de novo organic carbon at a rate (0

Luther, Douglas S.

96

Removal of ammonia from tarry water using a tubular furnace  

SciTech Connect

An ammonia-processing system without the use of live steam from OAO Alchevskkoks plant's supply network is considered. Steam obtained from the wastewater that leaves the ammonia column is used to process the excess tarry water, with the release of volatile ammonia.

V.V. Grabko; V.A. Kofanova; V.M. Li; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

97

FTIR and kinetic studies of the mechanism of Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalyst for selective catalytic reduction of NO with ammonia  

SciTech Connect

A series of FTIR spectroscopic and kinetic studies of the selective catalytic reduction (SCR) of nitric oxide by ammonia were conducted on Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay (Fe-TiO{sub 2}-PILC) catalyst. It was found that No molecules were absorbed on the fresh Fe-TiO{sub 2}-PILC catalyst and then oxidized by O{sub 2} to adsorbed NO{sub 2} and nitrate species. These NO{sub x} adspecies could be reduced by NH{sub 3} at high temperatures. NH{sub 3} molecules could also be adsorbed on the Broensted acid and Lewis acid sites on the Fe-TiO{sub 2}-PILC catalyst to generate, respectively, NH{sup +}{sub 4} ions and coordinated NH{sub 3} species. These NH{sub 3} adspecies were active in reacting with NO, NO + O{sub 2} and NO{sub 2}, but the reaction rates of NH{sub 3} + NO + O{sub 2} and NH{sub 3} + NO{sub 2} were much higher than that of NNO + NH{sub 3}. However, under reaction conditions, the surface of Fe-TiO{sub 2}-PILC was mainly covered by NH{sup +}{sub 4} ions and coordinated NH{sub 3}, and no NO{sub x} adspecies were detected. This is in agreement with the zero-order for the SCR reaction with respect to NH{sub 3}. A possible reaction scheme for the SCR reaction on Fe-TiO{sub 2}-PILC was proposed. NO reduction initially involved the reaction between NO{sub 2} and pairs of NH{sub 3} adspecies to form an active intermediate, which finally reacted with gaseous or weakly adsorbed NO to produce N{sub 2} and H{sub 2}O.

Long, R.Q.; Yang, R.T.

2000-02-15T23:59:59.000Z

98

Properties of nitrogen doped silicon films deposited by low pressure chemical vapour deposition from disilane and ammonia  

Science Journals Connector (OSTI)

Nitrogen doped silicon films have been deposited by low pressure chemical vapour deposition from disilane Si2H6 and ammonia NH3. Deposition kinetics is investigated, pointing out the influences of the deposition temperature, the total pressure and the gas flow rates. According to the Bruggeman theory, variations of the NH3/Si2H6 gaseous ratio allow for a wide range of the SiNx stoichiometry as well as a good control of the film nitrogen doping. The different behaviours of the nitrogen atom in silicon films are discussed and an overview of the nitrogen doped silicon physical properties (optical, mechanical and electrical) is proposed for the development of boron-doped polysilicon gates.

P Temple-Boyer; L Jalabert; E Couderc; E Scheid; P Fadel; B Rousset

2002-01-01T23:59:59.000Z

99

Elementary steps of the catalytic NO{sub x} reduction with NH{sub 3}: Cluster studies on reaction paths and energetics at vanadium oxide substrate  

SciTech Connect

We consider different reaction scenarios of the selective catalytic reduction (SCR) of NO in the presence of ammonia at perfect as well as reduced vanadium oxide surfaces modeled by V{sub 2}O{sub 5}(010) without and with oxygen vacancies. Geometric and energetic details as well as reaction paths are evaluated using extended cluster models together with density-functional theory. Based on earlier work of adsorption, diffusion, and reaction of the different surface species participating in the SCR we confirm that at Brnsted acid sites (i.e., OH groups) of the perfect oxide surface nitrosamide, NH{sub 2}NO, forms a stable intermediate. Here adsorption of NH{sub 3} results in NH{sub 4} surface species which reacts with gas phase NO to produce the intermediate. Nitrosamide is also found as intermediate of the SCR near Lewis acid sites of the reduced oxide surface (i.e., near oxygen vacancies). However, here the adsorbed NH{sub 3} species is dehydrogenated to surface NH{sub 2} before it reacts with gas phase NO to produce the intermediate. The calculations suggest that reaction barriers for the SCR are overall higher near Brnsted acid sites of the perfect surface compared with Lewis acid sites of the reduced surface, examined for the first time in this work. The theoretical results are consistent with experimental findings and confirm the importance of surface reduction for the SCR process.

Gruber, M.; Hermann, K. [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin (Germany)] [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin (Germany)

2013-12-28T23:59:59.000Z

100

Metal-nonmetal transition in metal-ammonia solutions  

Science Journals Connector (OSTI)

In this paper we present a coherent physical picture of the metal-nonmetal transition in metal-ammonia solutions in the intermediate concentration range. We propose that in Li-NH3 and Na-NH3 solutions the metallic propagation regime is separated from a nonmetallic regime by a microscopically inhomogeneous regime in which the concentration fluctuates locally about either of two well-defined values M0 and M1, M0>M1, the local concentration remaining near M0 or M1 over radii approximately equal to the Debye short correlation length b for concentration fluctuations. Provided that the concentration-fluctuation decay length is much smaller than b, we can define a percolation problem in which a volume fraction C of the material is occupied by metallic regions of concentration M0, the remainder containing the low concentration M1 of dissociated electron-cation complexes. M0 and M1 constitute the upper and the lower bounds of the inhomogeneous regime, respectively, while C exhibits a linear dependence on M. This physical picture is borne out by concentration-fluctuation determinations based on chemical-potential measurements in Li and Na solutions and by small-angle x-ray and neutron scattering in Li solutions. Assuming that the phase-coherence length of the conduction electrons is shorter than b and having demonstrated that tunneling corrections are negligible, we can define local electronic structure and transport properties. The limits of the inhomogeneous regime were determined from a combination of concentration-fluctuation measurements, electrical conductivity, Hall effect, and paramagnetic susceptibility data to be M0=9 mole percent metal (MPM) and M1=2(13) MPM, which yield the C scale, C=[M-2(13)]6(23), for both Li-NH3 at 223K and for Na-NH3 at 240K. We have also established the consistency of our picture with the available magnetic data for Na solutions. An analysis of the electronic and the thermal transport properties was carried out in terms of an effective-medium theory, modified to account for scattering from the boundaries of the metallic clusters. For low values of the conductivity ratio (? 10-3) between the nonmetallic and the metallic regions the modified effective-medium theory is valid for C>0.4. In an attempt to mimic the features of continuous percolation, we have carried out numerical simulations of the conductivity in a simple cubic lattice incorporating correlation between metallic bonds. An excellent fit of the experimental conductivity data for Li and Na with the results of the numerical simulations has been obtained over a three order of magnitude variation of the conductivity throughout the entire inhomogeneous regime. A small systematic negative deviation of the conductivity from the predictions of the effective-medium theory for C>0.4 can be properly accounted for in terms of boundary scattering corrections resulting in b?15 for Li at 223K and b?32 for Na at 240K. The overall agreement of the experimental Hall effect, Hall mobility, thermalconductivity, and thermoelectric-power data with the effective-medium theory is good. The proposed inhomogeneous regime in Li and Na solutions resembles a macroscopic mixed phase at a concentration inside a coexistence curve but with mixing on a microscopic scale. The concentration fluctuations in the inhomogeneous state have nothing to do with critical fluctuations; nevertheless, this state seems to be closely associated with the occurrence of a phase separation.

Joshua Jortner and Morrel H. Cohen

1976-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Characterization of atmospheric ammonia near Fort Worth, TX Part I. Dynamics of gaseous ammonia  

E-Print Network (OSTI)

May ­ 30 June) using a 10.4-µm external cavity4 quantum cascade laser-based sensor employing, biogenic (primarily vegetation and soil) emissions were major contributors to16 gas-phase NH3 levels-related activities) also was expected to be a potentially18 significant source of NH3 based on the nature

102

Ab initio molecular dynamics investigations on the SN2 reactions of OH? with NH2F and \\{NH2Cl\\}  

Science Journals Connector (OSTI)

The bimolecular nucleophilic substitution (SN2) reactions of hydroxide anion (OH?) with fluoroamine (NH2F) and chloramine (NH2Cl) have been investigated with ab initio molecular dynamics simulations. For the SN2 reaction of OH? with NH2F, there are two main dynamic reaction pathways after passing the [HONH2F]? barrier. The first one is that the [HONH2F]? transition state directly dissociates to the products of F? and NH2OH without involving any dynamic intermediate complex, and on the contrary, the other one involves the dynamic hydrogen bond F?H?NH?OH and/or F?H?O?NH2 intermediate complexes. As to the SN2 reaction of OH? with NH2Cl, there is only one dominant dynamic reaction pathway, which leads to the products of Cl? and NH2OH directly. According to our calculations, the statistical theories including the RiceRamspergerKasselMarcus (RRKM) theory and transition state (TS) theory cannot be utilized to model the reaction kinetics for these two SN2 reactions.

Feng Yu; Lei Song; Xiaoguo Zhou

2011-01-01T23:59:59.000Z

103

NH4-smectite: Characterization, hydration properties and hydro mechanical behaviour  

E-Print Network (OSTI)

NH4-smectite: Characterization, hydration properties and hydro mechanical behaviour M. Gautier a and drive to environmental problems. The purpose of this study was to understand the hydro- physical changes the pressure on small amounts of samples, proved the strong increase of the permeability of NH4-smectite

Paris-Sud XI, Université de

104

NH Clean Power Act (New Hampshire) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

NH Clean Power Act (New Hampshire) NH Clean Power Act (New Hampshire) NH Clean Power Act (New Hampshire) < Back Eligibility Agricultural Commercial Industrial Investor-Owned Utility Municipal/Public Utility Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State New Hampshire Program Type Environmental Regulations Provider NH Department of Environmental Services The Act calls for annual reductions of multiple pollutants, including SO2, Nox, CO2, and mercury. The Act calls for an 87% reduction in SO2 emissions and a 70% reduction in Nox emissions from 1999 levels. CO2 emissions are to be reduced to 1990 levels by the end of 2006. Act is implemented under NH Rules Env-A 2900. This act applies specifically to three existing fossil

105

How the Membrane Protein AmtB Transports Ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

side of the membrane that recruits NH4+ and a narrower 20--long hydrophobic channel midway through the membrane that lowers the dissociation constant of NH4+, thereby forming...

106

Ammonia Capture in Porous Organic Polymers Densely Functionalized...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brnsted Acid Groups Previous Next List Jeffrey F. Van Humbeck, Thomas M. McDonald, Xiaofei Jing, Brian M....

107

Release of ammonia from HAN-type PHA  

SciTech Connect

A preliminary design basis for ammonia scrubbers in the DWPF has been issued. This design basis is based on a theoretical model of ammonia evolution from the SRAT, SME and RCT. It is desirable to acquire actual process data on ammonia evolution prior to performing detailed design of scrubbers for DWPF. The evolution of ammonia from the SRAT and SME in the Integrated DWPF Melter System (IDMS) was investigated during the HM4 run. In this run, Precipitate Hydrolysis Aqueous (PHA), which was made in the Precipitate Hydrolysis Experimental Facility (PHEF) using the HAN (hydroxylamine nitrate) process was used, thus resulting in PHA with a high concentration of ammonium ion.

Zamecnik, J.R.

1992-06-10T23:59:59.000Z

108

Use and recovery of ammonia in power plant cycles  

SciTech Connect

The paper presents some practical and theoretical aspects of the use of ammonia in power plant water/steam cycles. The plants considered are fully automated units with once-through boilers, which operate under complex conditions and are subject to frequent starts and load changes. The boilers are chemically conditioned with combined oxygen ammonia treatment and the condensate polishing plant is only operated during start-up, in the event of a condenser leak or to remove excess ammonia. The paper also covers the recovery of ammonia from the condensate polishing plant waste regenerants and reuse for conditioning the feedwater. In particular, the paper deals with the following points: theoretical analysis of the chemical equilibrium of ammonia and carbon dioxide in water, including calculation of the concentrations from the parameters normally measured, such as conductivities and pH; equipment for monitoring and controlling the amount of ammonia fed to the water/steam cycle, including the optimum positioning of the sampling and feed-points, the parameters suitable for feed control and their temperature dependence; the partial pressure and distribution coefficient of ammonia; the consumption and losses of ammonia through the water/steam cycle during operation; the recovery of ammonia from condensate polishing plant waste regenerants by steam stripping. The paper should be of interest to both planning engineers and plant operators.

Pflug, H.D.; Bettenworth, H.J.; Syring, H.A. [Preussen Elektra AG, Hanover (Germany)

1995-01-01T23:59:59.000Z

109

Potential of High-Throughput Experimentation with Ammonia Borane...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials Jonathan L. Male Pacific Northwest National Laboratory June 26, 2006 US Department of Energy...

110

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

111

Catalysts for Dehydrogenation of ammonia boranes  

SciTech Connect

Several effective homogeneous catalysts for the dehydrogenation of amine boranes have been developed. The best catalyst uses an iridium complex, and is capable of dehydrogenating H3NBH3 (AB) and CH3NH2BH3 (MeAB) at comparable rates. Thermodynamic measurements using this catalyst demonstrate that the dehydrogenation of AB and MeAB is substantially exothermic, which has important implications for regeneration.

Heinekey, Dennis M.

2014-12-19T23:59:59.000Z

112

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas...

113

E-Print Network 3.0 - ammonia-oxidizing archaea diversity Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Environmental Sciences and Ecology 4 Ammonia oxidation kinetics determine niche separation of nitrifying Archaea and Bacteria Summary: LETTERS Ammonia oxidation kinetics...

114

E-Print Network 3.0 - ammonia gas sensing Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

This paper reports the first detection of methanol and ammonia from nadir viewing remote sensing instruments... First satellite observations of lower tropospheric ammonia and...

115

External Quality Assurance Services (EQAS) Ethanol/Ammonia Program  

E-Print Network (OSTI)

External Quality Assurance Services (EQAS) Ethanol/Ammonia Program BC35 12 x 3 mL 2 Analytes QC35 12 x 3 mL Specimen Only ENGLISH INTENDED USE Bio-Rad EQAS Ethanol/Ammonia Program is designed

Rodriguez, Carlos

116

EPR and IR studies of [Ru(NH?)?]+-Y and [Ru(NH?)?N?]+-Y type zeolites  

E-Print Network (OSTI)

EPR AND IR STUDIES OF [Ru(NH ) ] -Y 3 6 AND [Ru(NE ) N ] -Y TYPE ZEOLITES 2+ A Thesis by RAYMOND LEON LEUBNER Submitted to the Graduate College of Texas A&M University in partia1 fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1973 Major Subject: Chemistry EPR AND IR STUDIES OF [Ru(NH3) ] -Y 3+ AND [Ru(NH3) N ) -Y TYPE ZEOLITES 2+ 3&2 A Thesis by RAYMOND LEON LEUBNER Approved as to style and content by: (Chairman of Committ (Head of Department) (Memb...

Leubner, Raymond Leon

2012-06-07T23:59:59.000Z

117

Measurement and Modeling of Spatial NH3 Storage Distributions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

in a Commercial Small Port Cu Zeolite Urea SCR Catalyst Measurement and Modeling of Spatial NH3 Storage Distributions in a Commercial Small Port Cu Zeolite Urea SCR Catalyst...

118

Effects of gaseous NH{sub 3} and SO{sub 2} on the concentration profiles of PCDD/F in flyash under post-combustion zone conditions  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Influence of NH{sub 3} and SO{sub 2} on 2378-PCDD/F in flyash and flue gases was investigated. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 34-75% in the flyash. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 21-40% from the flue gases. Black-Right-Pointing-Pointer SO{sub 2} led to 99% PCDD and 93% PCDF reductions in the flyash. Black-Right-Pointing-Pointer SO{sub 2} led to 89% PCDD and 76% PCDF reductions in the flue gases. - Abstract: The influence of gaseous ammonia and sulphur dioxide on the formation of 2378-substituted PCDD/F on a reference flyash from a municipal waste incinerator has been investigated using a laboratory scale fixed-bed reactor. The reference flyash samples (BCR-490) was reacted under a simulated flue gas stream at temperatures of 225 and 375 Degree-Sign C for 96 h. The experiments were carried out in two series: first with simulated flue gas alone, and then with injection of NH{sub 3} or SO{sub 2} gas into the flue gas just before the reactor inlet. It was found that the injection of gaseous ammonia into the flue gas could decrease the concentration of both PCDD and PCDF by 34-75% from the solid phase and by 21-40% from the gas phase. Converting the results to I-TEQ values, it could reduce the total I-TEQ values of PCDD and PCDF in the sum of the flyash and exhaust flue gas by 42-75% and 24-57% respectively. The application of SO{sub 2} led to 99% and 93% reductions in the PCDD and PCDF average congener concentrations, respectively in the solid phase. In the gas phase, the total reductions were 89% and 76% for PCDD and PCDF, respectively. Moreover, addition of SO{sub 2} reduced the total I-TEQ value of PCDD and PCDF in the flyash and exhaust flue gas together by 60-86% and 72-82% respectively. Sulphur dioxide was more effective than ammonia in suppressing PCDD/F formation in flyash under the conditions investigated.

Hajizadeh, Yaghoub; Onwudili, Jude A. [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom); Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom)

2012-07-15T23:59:59.000Z

119

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network (OSTI)

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

120

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Ammonia-Free NOx Control System  

SciTech Connect

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

122

Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment  

Energy.gov (U.S. Department of Energy (DOE))

Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at low temperatures

123

Proton transfer dynamics of the reaction H3O ,,NH3 ,H2O...NH4  

E-Print Network (OSTI)

reactions.1,2 Water and ammonia are both small molecules that can form hydrogen bonds because they con- tain molecular beam technique Yue Li and James M. Farrara) Department of Chemistry, University of Rochester3 ­H­H2O is about 100 fs. Proton transfer occurs early on the reaction coordinate, when

Farrar, James M.

124

Passive Ammonia SCR for Lean Burn SIDI Engines  

Energy.gov (U.S. Department of Energy (DOE))

Passive NH3 SCR has been demonstrated as a high efficiency and low cost alternative lean NOx aftertreatment technology for stratified gasoline engines.

125

Emission computed tomography of /sup 18/F-fluorodeoxyglucose and /sup 13/N-ammonia in stroke and epilepsy  

SciTech Connect

The ECAT Positron Tomograph was used to scan normal control subjects, stroke patients at various times during recovery, and patients with partial epilepsy during EEG monitoring. /sup 18/F-fluorodeoxyglucose (/sup 18/FDG) and /sup 13/N-Ammonia (/sup 13/NH/sub 3/) were used as indicators of abnormalities in local cerebral glucose utilization (LCMR/sub glc/) and relative perfusion, respectively. Hypometabolism, due to deactivation or minimal damage, was demonstrated with the /sup 18/FDG scan in deep structures and broad zones of cerebral cortex which appeared normal on x-ray CT (XCT) and /sup 99m/Tc pertechnetate scans. In patients with partial epilepsy, who had unilateral or focal electrical abnormalities, interictal /sup 18/FDG scan patterns clearly showed localized regions of decreased (20 to 50%) LCMR/sub glc/, which correlated anatomically with the eventual EEG localization.

Kuhl, D.E.; Phelps, M.E.; Engel, J. Jr.

1980-01-01T23:59:59.000Z

126

Multi-component Removal in Flue Gas by Aqua Ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

component Removal in Flue Gas by Aqua Ammonia component Removal in Flue Gas by Aqua Ammonia Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,255,842 entitled "Multi-component Removal in Flue Gas by Aqua Ammonia." This patent discloses a method for the removal of potential environmental-impacting compounds from flue gas streams. The method oxidizes some or all of the acid precursors such as sulfur dioxide (SO 2 ) and nitric oxides (NO x ) into sulfur trioxide and nitrogen dioxide, respectively. Following this step, the gas stream is then treated with aqua ammonia or ammonium hydroxide to capture the compounds via chemical absorption through acid-base or neutralization reactions where a fertilizer is formed.

127

Design and performance of an ammonia measurement system  

E-Print Network (OSTI)

emissions. The task cannot be completed without equipment that can efficiently and accurately compare emissions. To complete this task, a measurement system was developed and performance tested to measure ammonia. Performance tests included uncertainty...

2007-04-25T23:59:59.000Z

128

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

129

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel LNT (Generates Ammonia) Exhaust Selective Catalytic DPF Valve Reduction Catalyst (SCR) 2 DEER 2007 Bypass V2 LNT V1 Reformer SCR Bypass V2 LNT V1 SCR Reformer * NOx storage...

130

Urea/Ammonia Distribution Optimization in an SCR Emission Control...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

P-20 UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Gi-Heon Kim, Matthew Thornton National Renewable Energy Laboratory...

131

Delphi On-board Ammonia Generation (OAG) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Reductant Utilization in a LNT + SCR System Application of a Diesel Fuel Reformer for Tier 2 Bin 5 Emissions...

132

Potential Roles of Ammonia in a Hydrogen Economy  

Energy.gov (U.S. Department of Energy (DOE))

Produced in February 2006 by the U.S. Department of Energy, this report focuses on the key issues and advantages and disadvantages associated with using ammonia for on-board vehicular hydrogen storage.

133

Effect of ammonia plasma treatment on graphene oxide LB monolayers  

SciTech Connect

Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S. [Department of Physics, Indian Institute of Technology Bombay, Mumbai - 400076 (India); Srinivasa, R. S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai - 400076 (India)

2013-02-05T23:59:59.000Z

134

Membrane Based intensification of ammonia removal from wastewater  

E-Print Network (OSTI)

The aim of this research was to study a novel membrane based oxygen intensification system to enhance a biological wastewater treatment process for ammonia removal. Specifically, this work is concerned with the biological nitrification process which...

Almutairi, Azel

2011-12-31T23:59:59.000Z

135

Public Service Co of NH | Open Energy Information  

Open Energy Info (EERE)

NH NH (Redirected from PSNH) Jump to: navigation, search Name Public Service Co of NH Place New Hampshire Service Territory New Hampshire Website www.psnh.com Green Button Landing Page www.psnh.com/SaveEnergyMo Green Button Reference Page www.psnh.com/SaveEnergyMo Green Button Implemented Yes Utility Id 15472 Utility Location Yes Ownership I NERC Location NPCC NERC NPCC Yes ISO NE Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Retail Marketing Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] Energy Information Administration Form 826[2] LinkedIn Connections

136

Sequential optical pumping of a far-infrared ammonia laser  

SciTech Connect

We present a novel technique for resonantly pumping a continuous-wave far-infrared NH{sub 3} laser with a line-tunable mid-infrared NH{sub 3} laser that is optically pumped by a CO{sub 2} laser. In this two-step process we first convert 10-{mu}m CO{sub 2} laser photons into 11{endash}13-{mu}m NH{sub 3} laser photons, which are then converted into 60{endash}400-{mu}m photons in a far-infrared NH{sub 3} laser. Continuous-wave laser action on 10 far-infrared lines of {sup 15}NH{sub 3}, including four new ones, has been obtained with a single CO{sub 2} laser pump line. {copyright} {ital 1996 Optical Society of America.}

Tachikawa, M.; Evenson, K.M. [Time and Frequency Division, National Institute of Standards and Technology, 325 Broadway, Boulder, Colorado 80303 (United States)

1996-08-01T23:59:59.000Z

137

PORTSMOUTH HARBOR AND PISCATAQUA RIVER, NH & ME NAVIGATION IMPROVEMENT PROJECT  

E-Print Network (OSTI)

the states of New Hampshire and Maine. The existing project consists of 35-foot deep entrance channel, with a minimum width of 400 feet, extending about 6.2 miles from deep water at the harbor entrance upriverPORTSMOUTH HARBOR AND PISCATAQUA RIVER, NH & ME NAVIGATION IMPROVEMENT PROJECT 21 August 2014

US Army Corps of Engineers

138

Kinetics Study of Solid Ammonia Borane Hydrogen Release Modeling and Experimental Validation for Chemical Hydrogen Storage  

SciTech Connect

Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

2014-02-24T23:59:59.000Z

139

The preparation and analysis of ammonia base sulfite pulping liquor  

E-Print Network (OSTI)

NH3 Concentrations . . . . . , ~ . ~ . . ~ ~ . ~ q IV The Distribution of S02 in a 2. 82$ RR3 Solution for Various Total SO2 Concentrations . . . . . . , . . . ~ . . . 31 FIGURES l. Variation of pH with Percent NH3 in Solution. . . . . ~. . . 25... 2. Variation of pH with S02 Concentration in Solutions of Various NH Concentrations . . . . ~ . . . ~ . ~ o ~ . o . ~ 27 3 ~ Composition of Solutions to give a Constant pH of T and 2. 5 , ~ 2Q 4. The Variation of the Ratio of Free S02 to Total SO2...

Honstead, John Frederick

1950-01-01T23:59:59.000Z

140

Thermal performance of an ammonia-water refrigeration system  

SciTech Connect

The conservation and efficient use of energy has led to alternate methods for air conditioning in buildings. Presently, two types of absorption air conditioning systems are widely used: the lithium-bromide-water system and the ammonia-water system. The first type is typically a water fired absorption chiller while the second one is a gas fired chiller. Some of the lithium-bromide-water systems use as a source of heat a stream of hot water supplied from solar collectors at a temperature level of the order of 95-100 {degrees}C. The purpose of this paper is to explore the possibilities to use solar energy to operate an ammonia-water system and to predict its thermodynamic performance. The results indicate that it is feasible to use solar energy to operate an ammonia-water absorption-refrigeration system.

Manrique, J.A. (Inst. Tecnologico y de Estudios Superiores de Monterrey, Dept. of Thermal Engineering, Monterrey, NL (MX))

1991-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Public Service Co of NH | Open Energy Information  

Open Energy Info (EERE)

Name Public Service Co of NH Name Public Service Co of NH Place New Hampshire Service Territory New Hampshire Website www.psnh.com Green Button Landing Page www.psnh.com/SaveEnergyMo Green Button Reference Page www.psnh.com/SaveEnergyMo Green Button Implemented Yes Utility Id 15472 Utility Location Yes Ownership I NERC Location NPCC NERC NPCC Yes ISO NE Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Retail Marketing Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] Energy Information Administration Form 826[2] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now!

142

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Lean-burn SIDI...

143

3rd Generation SCR System Using Solid Ammonia Storage and Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

144

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

145

Optimal Energy Recovery from Ammonia Synthesis in a Solar Thermal Power Plant  

Science Journals Connector (OSTI)

This work estimates the optimal performance, and evaluates a process modification to approach optimal ammonia production and subsequent energy produced, in the ammonia synthesis heat recovery system for a 10MW(e...

S. Siddiq; S. Khushnood; Z. U. Koreshi

2013-09-01T23:59:59.000Z

146

Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset Evaluation of NH3-SCR Catalyst Technology on a 250-kW Stationary Diesel Genset 2005 Diesel Engine Emissions...

147

Structure-Activity Relationships in NH3-SCR over Cu-SSZ-13 as...  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure-Activity Relationships in NH3-SCR over Cu-SSZ-13 as Probed by Reaction Kinetics and EPR Studies. Structure-Activity Relationships in NH3-SCR over Cu-SSZ-13 as Probed by...

148

EECBG Success Story: Grants to Help N.H. Towns Conserve Energy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grants to Help N.H. Towns Conserve Energy EECBG Success Story: Grants to Help N.H. Towns Conserve Energy March 19, 2010 - 4:17pm Addthis New Hampshire has a plan to lower expenses...

149

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

use by sector * cars light trucks 3 Managed by UT-Battelle for the U.S. Department of Energy Why NH 3 -generation on TWCs? * Zeolite-based NH 3 -SCR has been shown to have very...

150

E-Print Network 3.0 - ammonia synthesis gas Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

for ... Source: Australian National University, Department of Engineering, Solar Energy Program Collection: Renewable Energy ; Engineering 2 Solid State Ammonia Synthesis...

151

3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing  

Energy.gov (U.S. Department of Energy (DOE))

SCR system provides direct ammonia gas dosing for optimal SCR performance with simplified and flexible exhaust layout.

152

Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...  

NLE Websites -- All DOE Office Websites (Extended Search)

Milling of the LiNH2 + LiH Hydrogen Storage System. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System. Abstract: Ball milling of the LiNH2 + LiH storage system was...

153

Removal of ammonia from contaminated air in a biotrickling filter Denitrifying bioreactor combination system  

E-Print Network (OSTI)

, and loadings below 56 g m?3 h?1 resulted in essentially complete removal of ammonia. In addition, concenRemoval of ammonia from contaminated air in a biotrickling filter ­ Denitrifying bioreactor Nitrification Denitrification a b s t r a c t The removal of gaseous ammonia in a system consisting

154

Evaluation of the potential for significant ammonia releases from Hanford waste tanks  

SciTech Connect

Ammonia is ubiquitous as a component of the waste stored in the Hanford Site single-shell tanks (SSTs) and double-shell tanks (DSTs). Because ammonia is both flammable and toxic, concerns have been raised about the amount of ammonia stored in the tanks and the possible mechanisms by which it could be released from the waste into the head space inside the tanks as well as into the surrounding atmosphere. Ammonia is a safety issue for three reasons. As already mentioned, ammonia is a flammable gas and may contribute to a flammability hazard either directly, if it reaches a high enough concentration in the tank head space, or by contributing to the flammability of other flammable gases such as hydrogen (LANL 1994). Ammonia is also toxic and at relatively low concentrations presents a hazard to human health. The level at which ammonia is considered Immediately Dangerous to Life or Health (IDLH) is 300 ppm (WHC 1993, 1995). Ammonia concentrations at or above this level have been measured inside the head space in a number of SSTs. Finally, unlike hydrogen and nitrous oxide, ammonia is highly soluble in aqueous solutions, and large amounts of ammonia can be stored in the waste as dissolved gas. Because of its high solubility, ammonia behaves in a qualitatively different manner from hydrogen or other insoluble gases. A broader range of scenarios must be considered in modeling ammonia storage and release.

Palmer, B.J.; Anderson, C.M.; Chen, G.; Cuta, J.M.; Ferryman, T.A.; Terrones, G.

1996-07-01T23:59:59.000Z

155

Ammonia-Activated Mesoporous Carbon Membranes for Gas Separations  

SciTech Connect

Porous carbon membranes, which generally show improved chemical and thermal stability compared to polymer membranes, have been used in gas separations for many years. In this work, we show that the post-synthesis ammonia treatment of porous carbon at elevated temperature can improve the permeance and selectivity of these membranes for the separation of carbon dioxide and hydrocarbons from permanent gases. Hierarchically structured porous carbon membranes were exposed to ammonia gas at temperatures ranging from 850 C to 950 C for up to 10 min and the N{sub 2}, CO{sub 2}, and C{sub 3}H{sub 6} permeances were measured for these different membranes. Higher treatment temperatures and longer exposure times resulted in higher gas permeance values. In addition, CO{sub 2}/N{sub 2} and C{sub 3}H{sub 6}/N{sub 2} selectivities increased by a factor of 2 as the treatment temperature and time increased up to a temperature and time of 900 C, 10 min. Higher temperatures showed increased permeance but decreased selectivity indicating excess pore activation. Nitrogen adsorption measurements show that the ammonia treatment increased the porosity of the membrane while elemental analysis revealed the presence of nitrogen-containing surface functionalities in the treated carbon membranes. Thus, ammonia treatment at high temperature provides a controlled method to introduce both added microporosity and surface functionality to enhance gas separations performance of porous carbon membranes.

Mahurin, Shannon Mark [ORNL; Lee, Jeseung [ORNL; Wang, Xiqing [ORNL; Dai, Sheng [ORNL

2011-01-01T23:59:59.000Z

156

Transportable automated ammonia sensor based on a pulsed thermoelectrically cooled  

E-Print Network (OSTI)

Transportable automated ammonia sensor based on a pulsed thermoelectrically cooled quantum single-frequency, thermoelectrically cooled, pulsed quantum-cascade laser with an embedded distributed absorption spectroscopy with a pulsed QC DFB laser was reported in Ref. 3, where wavelength modulation

157

EVALUATION OF AEROSOL EMISSIONS DOWNSTREAM OF AN AMMONIA-BASED SO2 SCRUBBER  

SciTech Connect

Depending on the size and type of boiler, the 1990 Clean Air Act Amendments required specific reductions in SO{sub 2} emissions from coal-fired electric utilities. To meet these requirements, SO{sub 2} reduction strategies have included installing scrubbing technology, switching to a more expensive low-sulfur coal, or purchasing SO{sub 2} allowances. It is expected that over the next 10 years there will be an increase in the price of low-sulfur coals, but that higher-sulfur coal costs will remain the same. Technologies must be strongly considered that allow the use of high-sulfur fuels while at the same time meeting current and future SO{sub 2} emission limits. One such technology is the ammonia based flue gas desulfurization (FGD) (NH{sub 3}-based FGD) system manufactured by Marsulex Environmental Technologies (MET). The MET scrubber is a patented NH{sub 3}-based FGD process that efficiently converts SO{sub 2} (>95%) into a fertilizer product, ammonium sulfate ([NH{sub 4}]{sub 2}SO{sub 4}). A point of concern for the MET technology, as well as other FGD systems, is the emission of sulfuric acid/SO{sub 3} aerosols that could result in increased opacity at the stack. This is a direct result of firing high-sulfur fuels that naturally generate more SO{sub 3} than do low-sulfur coals. SO{sub 3} is formed during the coal combustion process. SO{sub 3} is converted to gaseous H{sub 2}SO{sub 4} by homogeneous condensation, leading to a submicron acid fume that is very difficult to capture in a dry electrostatic precipitator (ESP). The condensed acid can also combine with the fly ash in the duct and scale the duct wall, potentially resulting in corrosion of both metallic and nonmetallic surfaces. Therefore, SO{sub 3} in flue gas can have a significant impact on the performance of coal-fired utility boilers, air heaters, and ESPs. In addition to corrosion problems, excess SO{sub 3} emissions can result in plume opacity problems. Thus the Energy & Environmental Research Center (EERC) was contracted by MET and the U.S. Department of Energy (DOE) to evaluate the potential of a wet ESP for reducing SO{sub 3} emissions. The work consisted of pilot-scale tests using the EERC's slagging furnace system (SFS) to determine the effectiveness of a wet ESP to control SO{sub 3}/H{sub 2}SO{sub 4} aerosol emissions in conjunction with a dry ESP and MET's NH{sub 3}-based FGD. Because these compounds are in the form of fine particles, it is speculated that a relatively small, highly efficient wet ESP following the MET scrubber would remove these fine aerosol particles. The performance target for the wet ESP was a particulate mass collection efficiency of >90%; this level of performance would likely ensure a stack opacity of <10%.

Dennis L. Laudal

2002-04-01T23:59:59.000Z

158

Equipment configurations for use of ammonia in supermarket applications. Report for September 1992-May 1994  

SciTech Connect

The paper discusses equipment configurations for the use of ammonia in supermarket refrigeration applications. This paper identifies the optimal design for ammonia-secondary fluid systems and compares their performance to that of R22 systems. Three methods of staging the compression were compared for both refrigerants. Six secondary fluids were evaluated for use with ammonia in a supermarket system. Overall system performance of the ammonia-secondary fluid refrigeration system is governed by a large set of design parameters. The influence of these parameters on overall system performance was studied systematically. From this parametric study, design rules were developed, leading to optimum ammonia-secondary fluid systems.

McDowell, T.P.; Mitchell, J.W.; Klein, S.A.

1996-12-31T23:59:59.000Z

159

Ammonia-dimethylchloramine system: kinetic approach in an aqueous medium and comparison with the mechanism involving in liquid ammonia  

E-Print Network (OSTI)

-351" #12;2 The dimethylchloramine/ammonia interaction corresponds to a SN2 bimolecular mechanism (k4 = 0- methylmethanimine, 1,3,5-trimethylhexahydrotriazine, formaldehyde and methylamine. The kinetics of this reaction and chlorinated derivative. The reaction is of the second order and obeys an E2 mechanism (k1 = 4.2 ? 10-5 M-1 s-1

Paris-Sud XI, Université de

160

A synchroton single crystal X-ray structure determination of (NH4)3Mo4P3O16: A microporous molybdenum phosphate with Mo4O6+4 cubes  

Science Journals Connector (OSTI)

Reaction of MoO3, Mo, (NH4)2HPO4, H3PO4, and H2O in a mole ratio of 1.4:1:3.6:6:120 at 360C for 16 hr gives a nearly quantitative yield of black cubes of (NH4)3Mo4P3O16 (1). The structure of (1) was solved from data collected on a 30 30 30 ?m3 crystal at the National Synchrotron Light Source at Brookhaven National Laboratory. The compound is cubic, space group P43m, with a = 7.736(2) , and was refined to residuals of R(Rw) = 0.035(0.049). Phosphate (1) is isotypic with Cs3Mo4P3O16 and is related to the iron arsenate mineral pharmacosiderite. Unlike the Cs+ compound, (1) can be rendered microporous by thermal removal of the NH+4 cations to give ammonia with the charge compensating proton remaining behind in the lattice. Water absorption isotherms show the reversible uptake of 5.6 wt% water, which corresponds to over 15 vol% void space in (1) after the NH3 removal. The framework consists of Mo4O6+4 cubes, with six Mo?Mo contacts of 2.570(4) , joined together together by (PO4)62 along ?100? to form a 3-D network composed of tetramers of triply edge-sharing Mo-centered octahedra and phosphate groups alternating along all ?100? directions. The windows and cavities in (1) are large enough that the NH+4 cations occupy several different positions in the unit cell.

H.E. King Jr.; Linda A. Mundi; Karl G. Strohmaier; Robert C. Haushalter

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Understanding ammonia selective catalytic reduction kinetics over Cu-SSZ-13 from motion of the Cu ions  

SciTech Connect

Cu-SSZ-13 catalysts with three Si/Al ratios, at 6, 12 and 35, are synthesized with solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation, and standard ammonia selective catalytic reduction (NH3-SCR) reactions. By varying Si/Al ratios and Cu loadings, it is possible to synthesize catalysts with one dominant type of isolated Cu2+ ion species. Prior to full dehydration of the zeolite catalyst, hydrated Cu2+ ions are found to be very mobile as judged from EPR. NO oxidation is catalyzed by O-bridged Cu-dimer species that form at relatively high Cu loadings and in the presence of O2. For NH3 oxidation and standard SCR reactions, transient Cu-dimers even form at much lower Cu loadings; and these are proposed to be the active sites for reaction temperatures ? 350 C. These dimer species can be viewed as in equilibrium with monomeric Cu ion complexes. Between ~250 and 350 C, these moieties become less stable causing SCR reaction rates to decrease. At temperatures above 350 C and at low Cu loadings, Cu-dimers completely dissociate to regenerate isolated Cu2+ monomers that then locate at ion-exchange sites of the zeolite lattice. At low Cu loadings, these Cu species are the high-temperature active SCR catalytic centers. At high Cu loadings, on the other hand, both Cu-dimers and monomers are highly active in the high temperature kinetic regime, yet Cu-dimers are less selective in SCR. Brnsted acidity is also very important for SCR reactivity in the high-temperature regime. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOEs Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

Gao, Feng; Walter, Eric D.; Kollar, Marton; Wang, Yilin; Szanyi, Janos; Peden, Charles HF

2014-11-01T23:59:59.000Z

162

Theoretical study of the ammoniated NH/sub 4/ radical and related structures  

SciTech Connect

The ground- and some of the excited-state surfaces for the reaction of the Rydberg radical NH/sub 4/ to give either NH/sub 3/ + H or NH/sub 2/ + H/sub 2/ are computed. The preferred ground reaction channel is that observed experimentally, the formation of NH/sub 3/ + H. The Rydberg character, as well as the low barrier for fragmentation, is rationalized using a Rydberg extended-state structure correlation diagram. The excited-state surfaces show deep potential wells whose forms are also rationalized using this correlation diagram. Calculations on the surface of tetramethylammonium radical show no enhanced stability due to alkyl substitution. Comparative calculations on the complexation energies of HN/sub 4//sup +/ (NH/sub 3/)/sub n/ and NH/sub 4/(NH/sub 3/)/sub n/, n = 1-6, show the semiionic character of the Rydberg radical. The variation of stepwise complexation energies with n for the Rydberg species is not completely understood. The stability of solvated NH/sub 4/ radical in liquid NH/sub 3/ is estimated to be of the same order as (NH/sub 4//sup +/)/sub s/ + (e/sup -/)/sub s/.

Kassab, E.; Evleth, E.M.

1987-03-18T23:59:59.000Z

163

Electron Spin Resonance in Metals and Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

Electron spin resonance measurements have been made at 300 Mc/sec on frozen metal ammonia solutions, liquid metal ammonia solutions, and liquid metals. The experiments on frozen solutions have shown that the metal is precipitated out in small particles. Nuclear resonance experiments have corroborated this finding. The frozen solutions are used as a convenient source of small particles, and observations have been made of relaxation times in Na, Li, K, and Cs. Resonances in the liquid ammonia solutions of Li, Na, K, Rb, Cs, and Ca, and also in a solution of Li in methylamine were observed. The data are consistent with the theoretical model of Kraus, Ogg, and Kaplan and Kittel. Bulk metal resonances were observed to temperatures above the melting points on lithium and sodium. The results for sodium corroborate the Elliott theory of relaxation, and the lithium results indicate resistivity-dependent relaxation time. No resonance was observed in bulk K, Rb, and Cs carried to temperatures above their melting points.

R. A. Levy

1956-04-01T23:59:59.000Z

164

Array-type NH.sub.3 sensor  

SciTech Connect

An array-type sensor that senses NH.sub.3 includes non-Nernstian sensing elements constructed from metal and/or metal-oxide electrodes on an O.sub.2 ion conducting substrate. In one example sensor, one electrode may be made of platinum, another electrode may be made of manganese (III) oxide (Mn.sub.2O.sub.3), and another electrode may be made of tungsten trioxide (WO.sub.3). Some sensing elements may further include an electrode made of La.sub.0.6Sr.sub.0.4Co.sub.0.2Fe.sub0.8O.sub.3 and another electrode made of LaCr.sub.0.95.Mg.sub.0.05O.sub.3.

West, David Lawrence; Montgomery, Frederick Charles; Armstrong, Timothy R; Warmack, Robert J

2013-12-31T23:59:59.000Z

165

A review of "The Restoration: England in the 1660s." by N.H. Keeble  

E-Print Network (OSTI)

80 SEVENTEENTH-CENTURY NEWS N.H. Keeble. The Restoration: England in the 1660s. History of Early Modern England series. Oxford: Blackwell, 2002. xvi + 270 pp. $34.95. Review by TY M. REESE, UNIVERSITY OF NORTH DAKOTA. N.H. Keeble...80 SEVENTEENTH-CENTURY NEWS N.H. Keeble. The Restoration: England in the 1660s. History of Early Modern England series. Oxford: Blackwell, 2002. xvi + 270 pp. $34.95. Review by TY M. REESE, UNIVERSITY OF NORTH DAKOTA. N.H. Keeble...

Ty M. Reese

2003-01-01T23:59:59.000Z

166

SYSTEMS MODELING OF AMMONIA BORANE BEAD REACTOR FOR OFF-BOARD REGENERABLE HYDROGEN STORAGE IN PEM FUEL CELL APPLICATIONS  

SciTech Connect

Out of the materials available for chemical hydrogen storage in PEM fuel cell applications, ammonia borane (AB, NH3BH3) has a high hydrogen storage capacity (upto 19.6% by weight for the release of three hydrogen molecules). Therefore, AB was chosen in our chemical hydride simulation studies. A model for the AB bead reactor system was developed to study the system performance and determine the energy, mass and volume requirements for off-board regenerable hydrogen storage. The system includes hot and cold augers, ballast tank and reactor, product tank, H2 burner and a radiator. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure in the reactor system. Control signals to various components are governed by a control system which is modeled as an independent subsystem. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. Preliminary system simulation results for a start-up case and for a transient drive cycle indicate accurate trends in the reactor system dynamics.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; King, Dale A.; Herling, Darrell R.

2010-06-01T23:59:59.000Z

167

E-Print Network 3.0 - ammonia release method Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Lovegrove Summary: -dissociation-based solar thermal storage method. AMMONIA-BASED SOLAR ENERGY STORAGE Fig. 1: An overview of energy storage... chloride or calcium chloride -...

168

E-Print Network 3.0 - ammonia emission trends Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

5 Satellite Observations of Tropospheric Ammonia Mark W.Shephard, Karen E. Cady-Pereira, Vivienne H.Payne Summary: differences likely driven by uncertainty in emissions...

169

E-Print Network 3.0 - acute ammonia challenge Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Asia (coastal China, Korea and Japan) and Western Europe - experienced most acutely... Germany and the UK were also the world's leading producers of ammonia recovered from coke...

170

E-Print Network 3.0 - ammonia emission rate Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

season... catalyst systems. The ammonia emission rate is not a design criterion for automobile catalyst systems... Atmospheric Environment 37 (2003) ... Source: Aneja, Viney P. -...

171

Improving Electrochemical Methods of Producing Hydrogen in Alkaline Media via Ammonia and Urea Electrolysis.  

E-Print Network (OSTI)

?? Theoretically, ammonia electrolysis consumes 95% less energy than its major competitor water electrolysis and offers an economical, environmental, and efficient means for reducing nitrate (more)

Boggs, Bryan Kenneth

2010-01-01T23:59:59.000Z

172

E-Print Network 3.0 - ammonia negative ion Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

AND INTERSTELLAR ICES Summary: recently, it has been shown that the impact of 252Cf fis- sion fragments on solid ammonia produced negative... dissociative ionization of the...

173

E-Print Network 3.0 - ammonia borane compound Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion and Utilization ; Renewable Energy 2 Borane-Ammonia Complexes...

174

E-Print Network 3.0 - ammonia fluxes obtained Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Oak Ridge National Laboratory Fossil Energy Program Collection: Fossil Fuels 2 MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE...

175

E-Print Network 3.0 - ammonia oxidizing bacteria Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

made of the generous search support... THE ALLOWABLE AMMONIA CONCENTRATIONS IN WASTEWATER TREATMENT PLANT DISCHARGE TO ... Source: Canberra, University of - Institute for...

176

E-Print Network 3.0 - ammonia-oxidizing bacterial communities...  

NLE Websites -- All DOE Office Websites (Extended Search)

List Advanced Search Sample search results for: ammonia-oxidizing bacterial communities Page: << < 1 2 3 4 5 > >> 1 AQUATIC MICROBIAL ECOLOGY Aquat Microb Ecol Summary: AA...

177

System and method for determining an ammonia generation rate in a three-way catalyst  

SciTech Connect

A system according to the principles of the present disclosure includes a rate determination module, a storage level determination module, and an air/fuel ratio control module. The rate determination module determines an ammonia generation rate in a three-way catalyst based on a reaction efficiency and a reactant level. The storage level determination module determines an ammonia storage level in a selective catalytic reduction (SCR) catalyst positioned downstream from the three-way catalyst based on the ammonia generation rate. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the ammonia storage level.

Sun, Min; Perry, Kevin L; Kim, Chang H

2014-12-30T23:59:59.000Z

178

Theoretical studies of the structures and electronic properties of U(NH{sub 2}){sub 3} and Np(NH{sub 2}){sub 3}  

SciTech Connect

The electronic structure of the model compounds U(NH{sub 2}){sub 3} and Np(NH{sub 2}){sub 3} is investigated with the aid of ab initio electronic structure techniques. The electronic ground states and equilibrium geometries of these complexes are determined using multi-configuration SCF techniques. Comparisons are made to their counterparts U(CH{sub 3}){sub 3} and Np(CH{sub 3}){sub 3}.

Hay, P.J.; Martin, R.L.

1993-10-01T23:59:59.000Z

179

Obligate autotrophy in the ammonia oxidizing bacterium Nitrosomonas europaea.  

SciTech Connect

Closing report for project DOE-FG02-03ER15436. The project studied obligate autotrophy in the ammonia oxidizing bacterium Nitrosomonas europaea. Nitrosomonas europaea can obtain all of its energy and reductant for growth from the oxidation of ammonia to nitrite and is, therefore, classified as a chemolithotroph. This bacterium is also an autotroph, which can derive all cellular carbon from carbon dioxide. N. europaea seems incapable of growth with other carbon or energy sources. This restricted capability is surprising given that ammonia is a poor energy source. The main goal of the project was to examine the basis of autotrophy in N. europaea or, thought of another way, to determine the barriers to heterotrophy. The approach was enabled by the N. europaea genome sequence, stimulating new ways of thinking about this physiological paradoxan insistence on a single, albeit poor, energy source. Objective 1 was to examine the expression and regulation of the genes coding for alpha-ketoglutarate dehydrogenase, determine if the enzymes activity is present, and determine whether alteration of the expression levels influences autotrophic growth. Although Nitrosomonas europaea lacks measurable alpha-ketoglutarate dehydrogenase activity, the genome sequence revealed the presence of the genes encoding the enzyme. A knockout mutation was created in the sucA gene encoding the E1 subunit. Compared to wild-type cells, the mutant strain showed an accelerated loss of ammonia monooxygenase and hydroxylamine oxidoreductase activities upon entering stationary phase. In addition, unlike wild-type cells, the mutant strain showed a marked lag in the ability to resume growth in response to pH adjustments in late stationary phase. The results were published in Hommes N.G., Kurth E. G., Sayavedra-Soto L.A., and Arp D.J. (2006) Disruption of sucA, which encodes a subunit of alpha-ketoglutarate dehydrogenase, affects the survival of Nitrosomonas europaea in stationary phase. Journal of Bacteriology 188:343-347. Objective 2 was to determine the basis of fructose stimulation of growth on ammonia, examine fructose metabolism, and determine the impact of other compounds on growth on ammonia. Previous studies showed that N. europaea can utilize limited amounts of certain organic compounds, including amino acids, pyruvate, and acetate, although no organic compound has been reported to support the growth of N. europaea. The genomic sequence of N. europaea revealed a potential permease for fructose. N. europaea utilized fructose and other compounds as carbon sources to support growth. Cultures were incubated in the presence of fructose or other organic compounds in sealed bottles purged of CO(2). In these cultures, addition of either fructose or pyruvate as the sole carbon source resulted in a two- to threefold increase in optical density and protein content in 3 to 4 days. Studies with [(14)C]fructose showed that >90% of the carbon incorporated by the cells during growth was derived from fructose. Cultures containing mannose, glucose, glycerol, mannitol, citrate, or acetate showed little or no growth. N. europaea was not able to grow with fructose as an energy source, although the presence of fructose did provide an energy benefit to the cells. These results show that N. europaea can be grown in carbon dioxide free medium by using fructose and pyruvate as carbon sources and may now be considered a facultative chemolithoorganotroph. The results were published in Hommes N.G., Sayavedra-Soto L.A. and Arp. D.J. (2003). Chemolithotrophic growth of Nitrosomonas europaea on fructose. Journal of Bacteriology. 185:6809-2773. Objective 3 attempted to grow N. europaea heterotrophically through pathways predicted by the genome. Experiments with mutant strains and complementation studies were performed to test whether N. europaea can utilize other carbon sources. N. europaea was not able to grow heterotrophically in the conditions tested in this objective.

Daniel James Arp; Luis Alberto Sayavedra-Soto

2006-01-01T23:59:59.000Z

180

Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, andor CaH2) Composite Systems. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

July 2013 GIS Workshops in Lee, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

July 2013 GIS Workshops in Lee, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED Registration://gisworkshops.org email: gis@unh.edu Presented at the NH Sea Grant Extension Offices in Lee by the UNHCE Geospatial Outreach Program Workshop summary: Participants learn the basics of Geographic Information System (GIS

New Hampshire, University of

182

Futile transmembrane NH4 cycling: A cellular hypothesis to explain ammonium  

E-Print Network (OSTI)

4 to be preferred by plants, as its assimilation requires less energy than that of NO3 (1), only with intensive agriculture and cultivation of livestock, where high levels of NH3 emission, and subsequent NH4 is exceeded by as much as 10-fold, and damage to forest and agricultural crops alike has been attributed

Britto, Dev T.

183

Graphite Oxide/Polyoxometalate Nanocomposites as Adsorbents of Ammonia  

Science Journals Connector (OSTI)

Growing concerns about environmental problems lead researchers to look for efficient ways to adsorb various pollutants, as for instance ammonia. ... Since a good adsorbent for removal of toxic gases is characterized not only by the amount of gas adsorbed but also by the strength involved in its interactions with the pollutant gas, a reversible adsorption is obviously not a desired feature. ... The presence of water, either in the challenging gas or on the surface of the adsorbent, seems to have a different influence on the performance of the adsorbents. ...

Camille Petit; Teresa J. Bandosz

2009-02-06T23:59:59.000Z

184

Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed reactor system at Building 9212. Draft environmental assessment  

SciTech Connect

The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is Iocated within the Y-12 Plant on DOE`s Oak Ridge Reservation in Oak Ridge, Tennessee. The current AHF supply and fluidized-bed reactor systems were designed and constructed more than 40 years ago. Because of their deteriorating condition, the corrosive nature of the materials processed, and the antiquated design philosophy upon which they are based, their long-term reliability cannot be assured. The current AHF supply system cannot mitigate an accidental release of AHF and vents fugitive AHF directly to the atmosphere during operations. the proposed action would reduce the risk of exposing the Y-12 Plant work force, the public, and the environment to an accidental release of AHF and would ensure the continuing ability of the Y-12 Plant to manufacture highly enriched uranium metal and process uranium from retired weapons for storage.

NONE

1995-03-01T23:59:59.000Z

185

Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed chemical processing systems at Building 9212, Y-12 Plant, Oak Ridge, Tennessee  

SciTech Connect

The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is located within the Y-12 Plant on DOE`s Oak Ridge Reservation in Oak Ridge, Tennessee. The proposed replacement system would be based upon modern design criteria and safety analyses. The replacement AHF supply and distribution system equipment would be located on the existing Dock 8/8A at Building 9212. Utilities would be extended to the dock to service the process equipment. The following process equipment modules would be prefabricated for installation at the modified dock: an AHF cylinder enclosure, an AHF supply manifold and vaporizer module, an AHF sump tank and transfer skid, and an AHF supply off-gas scrubber assembly module. The fluidized-bed reactor system would be constructed in an area adjacent to the existing system in Building 9212. The replacement equipment would consist of a new reduction fluidized-bed reactor, a hydrofluorination fluidized-bed reactor, and associated air emission control equipment. The no-action alternative, which is the continued operation of the existing AHF supply and fluidized-bed reactor systems, was also evaluated.

NONE

1995-09-01T23:59:59.000Z

186

Investigations of ammonia-secondary fluid systems in supermarket refrigeration systems  

SciTech Connect

International agreements have legislated the phaseout of many refrigerants, including R-502 and R-12, which are commonly used in supermarket refrigeration systems. R-22 and ammonia (R-717) are candidate replacement refrigerants having appropriate thermodynamic properties. The toxicity of ammonia at low concentrations required that it be confined to the equipment room, so a secondary fluid is needed to distribute cooling to the refrigerated cases. This paper investigates ammonia-secondary fluid systems and compares their performance with equivalent R-22 systems. Both R-22 and ammonia have high compressor discharge temperatures, necessitating staged compression. Three methods of staging the compression were compared for both refrigerants. Six secondary fluids were evaluated for use with ammonia in the supermarket system. The overall system performance of the ammonia-secondary fluid refrigeration system, including both compressor and secondary fluid pump power, is governed by a large set of design parameters. The influence of these parameters on the overall system performance was studied in a systematic manner. From this parametric study, design rules leading to optimal ammonia-secondary fluid systems were developed. The performance of well-designed ammonia-secondary fluid systems was found to be 4% to 10% lower than that of R-22 systems operating under similar conditions.

McDowell, T.P. [Thermal Storage Applications Research Center, Madison, WI (United States); Mitchell, J.W.; Klein, S.A. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Mechanical Engineering

1995-12-31T23:59:59.000Z

187

Ris-R-1504(EN) Safety assessment of ammonia as a  

E-Print Network (OSTI)

as part of the EU supported project "Ammonia Cracking for Clean Electric Power Technology" The study addresses the following activities: safety of operation of the ammonia-powered vehicle under normal.6 Comparison with methanol-powered vehicles 19 2.7 Comparison with hydrogen-powered vehicles 19 2.8 Comparison

188

Competition for Ammonia Influences the Structure of Chemotrophic1 Communities in Geothermal Springs2  

E-Print Network (OSTI)

Competition for Ammonia Influences the Structure of Chemotrophic1 Communities in Geothermal Springs in geothermal communities. These observations help to47 explain the strong pattern in the co-distribution of ammonia-oxidizing archaea and diazotrophs in48 circum-neutral to alkaline geothermal springs.49 50

de la Torre, José R.

189

Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal  

E-Print Network (OSTI)

RESEARCH INSTALLATION, EQUIPMENT, AND PROCEDURES Research Installation Equipment . Soil Water Equipment Redox Potential Equipment . . . . . . . . . . . . . , . , Laboratory Equipment Procedures Soil Column Installation Procedure Ammonia and Carbon... Dioxide Collection Procedure Redox Potential Measurement Procedure . . . . Irrigation and Soil Water Content Measurement Procedure . . . . . . . . . . . , , . . . . Sampling and Sample Handling and Storage Procedure . Ammonia and Carbon Dioxide...

Peters, Robert Edgar

2012-06-07T23:59:59.000Z

190

Analysis of a commercial absorption-refrigeration water-ammonia (ARWA) cycle using Aspen Plus simulator  

Science Journals Connector (OSTI)

The Robur absorption-refrigeration-water-ammonia (ARWA) cycle is analyzed using Aspen Plus flowsheet simulator. The results are compared with experimental and some manufacturer data reported in the open literature. Among performance parameters analyzed ... Keywords: Aspen, COP, absorption, ammonia, refrigeration, simulation, water

N. A. Darwish; S. H. Al-Hashimi; A. S. Al-Mansoori

2008-08-01T23:59:59.000Z

191

Analysis of Ammonia Loss Mechanisms in Microbial Fuel Cells Treating Animal Wastewater  

E-Print Network (OSTI)

ARTICLE Analysis of Ammonia Loss Mechanisms in Microbial Fuel Cells Treating Animal Wastewater Jung.interscience.wiley.com). DOI 10.1002/bit.21687 ABSTRACT: Ammonia losses during swine wastewater treatment were examined using manure; electricity; power generation Introduction Wastewater treatment using microbial fuel cells (MFCs

192

Process and apparatus for ammonia synthesis gas production  

SciTech Connect

An improved process is described for the production of ammonia synthesis gas which consists of: (a) catalytically reacting a hydrocarbon feed stream with steam in a primary reforming unit to form a primary reformed gas mixture containing hydrogen and carbon monoxide; (b) passing the primary reformed gas mixture to a secondary reforming unit for reaction of unconverted methane present therein with air, the amount of the air introduced to the secondary reforming unit being considerably in excess of that required to furnish the stoichiometric amount of nitrogen required for reaction with hydrogen for the ammonia synthesis; (c) subjecting the secondary reformed gas mixture to water gas shift conversion to convert most of the carbon monoxide present in the reformed gas mixture to hydrogen and carbon dioxide; (d) passing the thus-shifted gas mixture containing hydrogen, carbon dioxide, residual carbon monoxide, methane, argon and the excess nitrogen, without necessary treatment for removal of a major portion of the carbon dioxide content thereof and without methanation to remove carbon oxides to low levels, to a pressure swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from the hydrogen and from a portion of the nitrogen present in the gas passed to the system.

Fuderer, A.

1986-06-03T23:59:59.000Z

193

Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery  

SciTech Connect

An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

2008-06-20T23:59:59.000Z

194

Ammonia and urea treatment of wheat straw and corn stover JP Fontenot E Gallo Llorente, JM Obamahinti, VG Allen  

E-Print Network (OSTI)

by ammoniation directly or by urea treatment, but the improvement appears to be greater for ammonia than urea

Boyer, Edmond

195

Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)  

SciTech Connect

We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

2014-11-19T23:59:59.000Z

196

Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, and/or CaH2) Composite Systems  

SciTech Connect

Ammonia borane (AB = NH3BH3) is one of the most attractive materials for chemical hydrogen storage due to its high hydrogen contents of 19.6 wt.%, however, impurity levels of borazine, ammonia and diborane in conjunction with foaming and exothermic hydrogen release calls for finding ways to mitigate the decomposition reactions. In this paper we present a solution by mixing AB with metal hydrides (TiH2, ZrH2, MgH2 and CaH2) which have endothermic hydrogen release in order to control the heat release and impurity levels from AB upon decomposition. The composite materials were prepared by mechanical ball milling, and their H2 release properties were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The formation of volatile products from decomposition side reactions, such as borazine (N3B3H6) was determined by mass spectrometry (MS). Sieverts type pressure-composition-temperature (PCT) gas-solid reaction instrument was adopted to observe the kinetics of the H2 release reactions of the combined systems and neat AB. In situ 11B MAS-NMR revealed a destabilized decomposition pathway. We found that by adding specific metal hydrides to AB we can eliminate the impurities and mitigate the heat release.

Choi, Young Joon; Xu, Yimin; Shaw, Wendy J.; Ronnebro, Ewa

2012-04-19T23:59:59.000Z

197

MISE EN VIDENCE D'UN ORDRE A COURTE DISTANCE DANS LA PHASE II DES CRISTAUX DE NH4Cl,  

E-Print Network (OSTI)

respectivement au point tricritique et au point de transition phase II - phase IV pour les cristaux de NH4Cl. Phase IV : phase cubique ordonnée ; tous les ions NH4 sont dans la configuration 1. Phase II : phase configuration 2. Phase III : phase tétragonale ordonnée ; les ions NH4 sont alternativement dans la

Boyer, Edmond

198

Ammonia volatilization from N fertilizers surface applied on bermudagrass  

E-Print Network (OSTI)

- vestigate the feasibility of CaC1 as a urea hydrolysis depressant. Laboratory In a simple nonaerated experiment in air-tight jars, CaCl ad- 2 ditive with urea depressed urea hydrolysis as measured by reduction in NH3 volatilization N loss from 48 to 3...% as a result of inhibiting bio- logical activity. This depression likely resulted from retarded micro- bial activity because CaC12 salt induced high osmotic pressure. In an aerated experiment which circulated air over treated soil, more similar...

Panossian, Jack B.

1980-01-01T23:59:59.000Z

199

Consequences of Substituting 2NH2A for a in Synthetic DNAS  

Science Journals Connector (OSTI)

Chemical and spectroscopic consequences of replacing A with 2NH2A have been examined in a variety of synthetic DNAs. This substitution, which permits formation...m elevation, however, is much smaller in the deox...

Frank B. Howard; H. Todd Miles

1983-01-01T23:59:59.000Z

200

NH3 generation over commercial Three-Way Catalysts and Lean-NOx...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

formulations and operation for the in-situ generation of NH3, storage on a downstream SCR catalyst, and utilized to reduce the remaining NOx deer12toops.pdf More Documents &...

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Wind-powered ammonia fuel production for remote islands: A case study  

Science Journals Connector (OSTI)

Abstract This work investigates the prospect of producing ammonia from a wind turbine in order to displace diesel fuel requirements on isolated islands. In the proposed system, wind power is used to produce carbon-free ammonia fuel directly from water and air using traditional air separation units, alkaline electrolyzers, mechanical vapor compression desalination and a HaberBosch synthesis loop. The ability to produce synthetic fuel on site is potentially valuable both because it mitigates fuel transportation costs and insulates islanders from oil price fluctuations. A general overview of the process and required components is given. The analytical model used to calculate the technical and economic performance is summarized. Monhegan Island in Maine is used as a case study for a wind-powered ammonia production facility to demonstrate the potential of ammonia fuel production. Actual wind data and electrical load data from Monhegan Island are incorporated to determine the expected ammonia production. The results are compared to the existing system in which all fuels and electricity are ultimately derived from petroleum-based fuel. Total lifetime system costs are calculated with the results normalized so that the wind-ammonia system can be directly compared to a conventional diesel-only system. A breakeven diesel price is calculated at which wind-powered ammonia production becomes competitive.

Eric Morgan; James Manwell; Jon McGowan

2014-01-01T23:59:59.000Z

202

Studies of the Ammonia-soluble Organic Matter of the Soil.  

E-Print Network (OSTI)

to represent the - decomposed organic matter of the soil, and, therefore, if the theory cited above is correct, the more valuable organic matter. The.relation between the hvo forms of organic matter is largely a matter of color; while the ammonia does nct... oxtract all the organic matter from the soil, it does extract prad,ically all the black organic matter, leaving the soil residue near]? white. The organic matter of the soil soluble in ammonia is termed humus in America. The fact that the ammonia...

Fraps, G. S. (George Stronach); Hamner, N.C.

1910-01-01T23:59:59.000Z

203

Volume 130, number 6 CHEMICAL PHYSICS LETTERS 24 October1986 VIBRATIONAL DEPENDENCE OF THE NH,+ (v2)+NO AND NO+(v) +NH,  

E-Print Network (OSTI)

Volume 130, number 6 CHEMICAL PHYSICS LETTERS 24 October1986 VIBRATIONAL DEPENDENCE OF THE NH,+ (v2 of an electron by the ion as it passes by its neutral collision partner. Such so-called charge transfer reactions reactions would suggest a fast rate controlled by the Langevin capture cross section [ 61. This in turn

Zare, Richard N.

204

Ammonia volatilization from surface application of ammonium sulfate to carbonate systems  

E-Print Network (OSTI)

correspond- 3 ed to the simultaneous loss of H 0 and NH . Jewitt (1942) showed that as H 0 loss increased due to evaporation the amount of NH volatilized increased on four alkaline Sudan soils when (NHL?) 2SOL? was surface appli- ed. He proposed...?OH, (IKt) CO , or NH~HCO depending upon the factors mentioned above. This suggests a rather complicated reaction mechanism. Duplessis and Kroontje (1964) also supported Jewitt's (1942) mechanism. In their experiment, (NHL?) SOL? wes surface applied...

Feagley, Sam Edward

1976-01-01T23:59:59.000Z

205

Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts  

SciTech Connect

Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1999-09-10T23:59:59.000Z

206

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Chang H. Kim, Kevin Perry, Wei Li, Kushal Narayanaswamy, and Michael Viola Global Research &...

207

Computer simulation and economic analysis for ammonia fiber explosion (AFEX) pretreatment process  

E-Print Network (OSTI)

simulation and cost analysis. In this study, a steady state computer simulation package was developed for the AFEX process. Corn fiber was used as the representative biomass treated by AFEX. Different ammonia loadings, water loadings, temperatures...

Wang, Lin

2012-06-07T23:59:59.000Z

208

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment  

Energy.gov (U.S. Department of Energy (DOE))

This case study describes how Terra Nitrogen Company saved 497,000 MMBtu and $3.5 million yearly after upgrading the steam system in its ammonia plant in Verdigris, Oklahoma.

209

Hydrogen production from the reaction of solvated electrons with benzene in water-ammonia mixtures  

SciTech Connect

Product analysis data for the reaction of the ammoniated electron with benzene-water mixtures in liquid ammonia show that the dominant product is evolved hydrogen and not 1,4-cyclohexadiene.

Dewald, R.R.; Jones, S.R.; Schwartz, B.S.

1980-11-27T23:59:59.000Z

210

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents (OSTI)

Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C.J.; Mackenzie, P.D.

1982-09-03T23:59:59.000Z

211

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents (OSTI)

Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

1985-01-01T23:59:59.000Z

212

Carbon Capture by a Continuous, Regenerative Ammonia-Based Scrubbing Process  

SciTech Connect

Overview: To develop a knowledge/data base to determine whether an ammonia-based scrubbing process is a viable regenerable-capture technique that can simultaneously remove carbon dioxide, sulfur dioxide, nitric oxides, and trace pollutants from flue gas.

Resnik, K.P.; Yeh, J.T.; Pennline, H.W.

2006-10-01T23:59:59.000Z

213

E-Print Network 3.0 - agricultural ammonia emission Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Division Ir Lid., 1998 Summary: THE ALLOWABLE AMMONIA CONCENTRATIONS IN WASTEWATER TREATMENT PLANT DISCHARGE TO ENSURE PROTECl'ION OF AQUATIC... Box4395QQ.Melbourne VA3(XX)...

214

Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product  

DOE Patents (OSTI)

Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

Davis, Benjamin L; Rekken, Brian D

2014-04-01T23:59:59.000Z

215

Ammonia inhalation toxicity in cats: a study of acute and chronic respiratory dysfunction  

E-Print Network (OSTI)

AMMONIA INHALATION TOXICITY IN CATS A STUDY OF ACUTE AND CHRONIC RESPIRATORY DYSFUNCTION A Thesis by KENNETH TRAVIS DODD Submitted to the Graduate College of Texas A)M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1978 Major Subject: Veterinary Physiology AMMONIA INHALATION TOXICITY IN CATS A STUDY OF ACUTE AND CHRONIC RESPIRATORY DYSFUNCTION A Thesis by KENNETH TRAVIS DODD Approved as to style and content by: (Chairman...

Dodd, Kenneth Travis

2012-06-07T23:59:59.000Z

216

The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes  

E-Print Network (OSTI)

THE CATALETIC REDUCTION OF NITRIC OXIDE NITH AMMONIA OVER TETRARPMINECOPPER(11) COMPLEXES A Thesis by Margaret Deron Oates Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1979 Major Subject: Chemistry THE CATALYTIC REDUCTION OF NITRIC OXIDE WITH AMMONIA OVER TETRAAMMINECOPPER(IZ) COMPLEXES A Thesis by Margaret Deron Dates Approved as to style and content by: (Chairman of Committe (Member...

Oates, Margaret Deron

1979-01-01T23:59:59.000Z

217

A Nonparametrized Ab Initio Determination of the Heat of Formation of Hydroxylamine, NH2OH  

SciTech Connect

Large basis set coupled cluster calculations through noniterative triple excitations were used to compute optimized structures, harmonic vibrational frequencies, atomization energies at 0 K and heats of formation at 298 K for hydroxylamine (NH2OH) and three related compounds (NH3, HNO and H2O2). The use of basis sets as large as augmented sextuple zeta resulted in small extrapolations to the complete basis set limit in order to achieve chemical accuracy ( 1 kcal/mol) in the thermodynamic properties. Complete basis set estimates were determined from several simple extrapolation formulas. In addition, four other corrections were applied to the frozen core atomization energies, (1) a zero point vibrational correction: (2) a core/valence correlation correction; (3) a Douglas-Kroll-Hess scalar relativistic correction; and (4) a first order atomic spin-orbit correction. For NH3 and HNO we incorporated a fifth correction term intended to approximate the difference between coupled cluster theory and the full configuration interact result. This correction was based on coupled cluster theory through iterative quadruple excitations (CCSDTQ). Excellent agreement with experiment was found for the heats of formation of NH3, HNO and H2O2. For NH2OH the best current estimate of the heat of formation at 298 K is 10.1 0.3 kcal/mol, which falls roughly midway between two experimental values at 12.0 2.4 and 7.9 1.5 kcal/mol.

Feller, David F.; Dixon, David A.

2003-12-04T23:59:59.000Z

218

Characterization of ammonia emissions from ground level area sources at central texas dairies  

E-Print Network (OSTI)

) to potentially develop source specific NH3 emission control strategies. The GLAS including open-lots, free-stall barns, separated solids, primary and secondary lagoons and milking parlor were sampled to estimate NH3 emissions. In the first study, assessment...

Mutlu, Atilla

2009-05-15T23:59:59.000Z

219

Multi-component removal in flue gas by aqua ammonia  

DOE Patents (OSTI)

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

2007-08-14T23:59:59.000Z

220

Grants to Help N.H. Towns Conserve Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy March 19, 2010 - 4:17pm Addthis New Hampshire has a plan to lower expenses and create jobs, all while conserving energy. In all, the state has received $17.3 million in Energy Efficiency and Conservation Block Grant (EECBG) funding. Of that, $9.6 million has been sent to the New Hampshire Office of Energy and Planning (NHOEP) to launch several energy saving projects. NHOEP established a subgrant program to award $6.6 million of the EECBG grant funding to local municipalities and counties. New Hampshire municipalities and counties submitted over 270 applications, totaling over $21 million in grant requests. "Substantial energy efficiency improvements will be made throughout the

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Grants to Help N.H. Towns Conserve Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy Grants to Help N.H. Towns Conserve Energy March 19, 2010 - 4:17pm Addthis New Hampshire has a plan to lower expenses and create jobs, all while conserving energy. In all, the state has received $17.3 million in Energy Efficiency and Conservation Block Grant (EECBG) funding. Of that, $9.6 million has been sent to the New Hampshire Office of Energy and Planning (NHOEP) to launch several energy saving projects. NHOEP established a subgrant program to award $6.6 million of the EECBG grant funding to local municipalities and counties. New Hampshire municipalities and counties submitted over 270 applications, totaling over $21 million in grant requests. "Substantial energy efficiency improvements will be made throughout the

222

A Review & Assessment of Current Operating Conditions Allowable Stresses in ASME Section III Subsection NH  

SciTech Connect

The current operating condition allowable stresses provided in ASME Section III, Subsection NH were reviewed for consistency with the criteria used to establish the stress allowables and with the allowable stresses provided in ASME Section II, Part D. It was found that the S{sub o} values in ASME III-NH were consistent with the S values in ASME IID for the five materials of interest. However, it was found that 0.80 S{sub r} was less than S{sub o} for some temperatures for four of the materials. Only values for alloy 800H appeared to be consistent with the criteria on which S{sub o} values are established. With the intent of undertaking a more detailed evaluation of issues related to the allowable stresses in ASME III-NH, the availabilities of databases for the five materials were reviewed and augmented databases were assembled.

R. W. Swindeman

2009-12-14T23:59:59.000Z

223

Superionicity in the hydrogen storage material Li2NH: Molecular dynamics simulations  

Science Journals Connector (OSTI)

We have employed ab initio molecular dynamics simulations in an attempt to study a temperature-induced order-disorder structural phase transformation that occurs in Li2NH at about 385 K. A structural phase transition was observed by us in the temperature range 300400 K, in good agreement with experiment. This transition is associated with a melting of the cation sublattice (Li+), giving rise to a superionic phase, which in turn is accompanied by an order-disorder transition of the N-H bond orientation. The results obtained here can contribute to a better understanding of the hydrogen storage reactions involving Li2NH and furthermore broaden its possible technological applications toward batteries and fuel cells.

C. Moyss Arajo; Andreas Blomqvist; Ralph H. Scheicher; Ping Chen; Rajeev Ahuja

2009-05-08T23:59:59.000Z

224

Measurement of Hyperfine Structure in the Infrared Rotation-Vibration Spectrum of NH-  

Science Journals Connector (OSTI)

Hyperfine structure (hfs) has been observed in the P, Q, and R branches of the fundamental rotation-vibration spectrum of the X?2 electronic state of the molecular anion NH-. A coaxial ion-beam-laser-beam spectrometer is employed in which rotation-vibration transitions are induced by a color-center laser operating near 3000 cm-1. The vibrationally excited ions autodetach, and the fast neutral NH is detected. The structure has been analyzed and the magnetic dipole hfs parameters obtained in both N14H- and N15H-. This is the first analyzed case of hfs in any molecular anion.

Harold C. Miller; Mohammad Al-Za'al; John W. Farley

1987-05-18T23:59:59.000Z

225

Sludge processors have wide choice of solutions for waste ammonia problems  

SciTech Connect

The Ocean Dumping Act of 1988 phased out dumping of sewage sludge into the ocean. To use sewage sludge beneficially, facilities treat and process it using such techniques as digestion, dewatering, composting, thermal drying and chemical stabilization. All of these processes create waste discharges containing high concentrations of nitrogen, mainly in the form of ammonia. When nitrification occurs in receiving waters, ammonia is oxidized to nitrate and can lower dissolved oxygen levels in the water. Excess ammonia also is toxic to fish and other aquatic life. Nitrogen reduction alternatives for sludge dewatering and processing waste discharges include the following: air stripping; steam stripping; breakpoint chlorination; selective ion exchange; reverse osmosis; and chemical precipitation. To remove wastewater nitrogen using biological processes, ammonia and organic nitrogen first are oxidized aerobically (nitrification) to nitrate nitrogen, which then is converted biologically to nitrogen gas (denitrification) under zero or low dissolved oxygen (anoxic) conditions. Because sludge treatment discharges contain valuable quantities of ammonia, they may be considered for reuse as supplemental fertilizer for land application or for reclamation through spraying or injection into soil. Such discharges also may be used in combustion processes.

Chen, Y.S.R.; Samela, D. (Stone and Webster Engineering Corp., Boston, MA (United States). Environmental Technology and Services Div.); Kaylor, F.

1994-09-01T23:59:59.000Z

226

Coupled-surface investigation of the photodissociation of NH{sub 3}(A-tilde): Effect of exciting the symmetric and antisymmetric stretching modes  

SciTech Connect

Using previously developed potential energy surfaces and their couplings, non-Born-Oppenheimer trajectory methods are used to study the state-selected photodissociation of ammonia, prepared with up to six quanta of vibrational excitation in the symmetric ({nu}{sub 1}) or antisymmetric ({nu}{sub 3}) stretching modes of NH{sub 3}(A-tilde). The predicted dynamics is mainly electronically nonadiabatic (that is, it produces ground electronic state amino radicals). The small probability of forming the excited-state amino radical is found, for low excitations, to increase with total energy and to be independent of whether the symmetric or antisymmetric stretch is excited; however some selectivity with respect to exciting the antisymmetric stretch is found when more than one quantum of excitation is added to the stretches, and more than 50% of the amino radical are found to be electronically excited when six quanta are placed in the antisymmetric stretch. These results are in contrast to the mechanism inferred in recent experimental work, where excitation of the antisymmetric stretch by a single quantum was found to produce significant amounts of excited-state products via adiabatic dissociation at total energies of about 7.0 eV. Both theory and experiment predict a broad range of translational energies for the departing H atoms when the symmetric stretch is excited, but the present simulations do not reproduce the experimental translational energy profiles when the antisymmetric stretch is excited. The sensitivity of the predicted results to several aspects of the calculation is considered in detail, and the analysis leads to insight into the nature of the dynamics that is responsible for mode selectivity.

Bonhommeau, David; Valero, Rosendo; Truhlar, Donald G. [Department of Chemistry and Supercomputing Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455-0431 (United States); Jasper, Ahren W. [Combustion Research Facility, Sandia National Laboratories, P.O. Box 969, Livermore, California 94551-0969 (United States)

2009-06-21T23:59:59.000Z

227

Vol. 92 Concord, NH, Wednesday, November 6, 2013 No. 37 Weekly Market Bulletin  

E-Print Network (OSTI)

to recruit new members and future customers for the full-service cooperative grocery store the group plans sustainability. The cooperative- ly owned business "strives to serve the North Country of New HampshireVol. 92 Concord, NH, Wednesday, November 6, 2013 No. 37 Weekly Market Bulletin State of New

New Hampshire, University of

228

Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

levels 10 PSI laboratory test apparatus Computer FIC FIC FIC FIC FIC N 2 O 2 NO NH 3 TIC TIC TI MCT Detector TI TIC N 2 TI IR Source 2 3 4 3 3 3 5 6 7 8 9 10 heated gas line...

229

March 2012 GIS Workshops in Concord, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

March 2012 GIS Workshops in Concord, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED. phone: 603.862.1029 web: http://gisworkshops.org email: gis@unh.edu GIS 101: Learning to Map in the Digital Age March 27th, 9am to noon Topics covered: basic GIS concepts types of GIS data types of GIS

New Hampshire, University of

230

May 2012 GIS Workshops in Plymouth, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

May 2012 GIS Workshops in Plymouth, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED Registration. phone: 603.862.1029 web: http://gisworkshops.org email: gis@unh.edu GIS 101: Learning to Map in the Digital Age May 10, 9am to noon Topics covered: basic GIS concepts types of GIS data types of GIS software

New Hampshire, University of

231

April 2012 GIS Workshops in Conway, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

April 2012 GIS Workshops in Conway, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED Registration.862.1029 web: http://gisworkshops.org email: gis@unh.edu GIS 101: Learning to Map in the Digital Age April 18, 9am to noon Topics covered: basic GIS concepts types of GIS data types of GIS software $49 Skill

New Hampshire, University of

232

January 2012 GIS Workshops in Durham, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

January 2012 GIS Workshops in Durham, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED.862.1029 web: http://gisworkshops.org email: gis@unh.edu GIS 101: Learning to Map in the Digital Age January 10th, 9am to noon Topics covered: basic GIS concepts types of GIS data types of GIS software $49 Skill

New Hampshire, University of

233

June 2013 GIS Workshops in Plymouth, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

June 2013 GIS Workshops in Plymouth, NH SPACE IS LIMITED - PRE-REGISTRATION IS REQUIRED. phone: 603.862.1029 web: http://gisworkshops.org email: gis@unh.edu Presented at the Whole Village: Participants learn the basics of Geographic Information System (GIS) mapping software and explore a variety

New Hampshire, University of

234

Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4?-bipy, bpa)  

Science Journals Connector (OSTI)

The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixedvalence complexes [(NH3)5Ru-L- Ru(NH3)5]5+ (L = N2,pyz, bipy, pym, bpa) is analyzed by the semiempirical CINDO +...

O. V. Sizova; V. I. Baranovskii; A. I. Panin

235

Intramolecular electron transfer in mixed-valence complexes [(NH3)5Ru-L-Ru(NH3)5]5+ (L = N2, pyz, pym, 4,4-bipy, bpa)  

Science Journals Connector (OSTI)

The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixed-valence complexes [NH3)5Ru -L-Ru(NH3)5]5+ (L = N2, pyz, bipy, pym, bpa) is analyzed by the semiempiri...

O. V. Sizova; V. I. Baranovskii; A. I. Panin

2002-02-01T23:59:59.000Z

236

Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part II. Recovery of Ammonia from Sour Waters  

SciTech Connect

Two novel regenerated solvent extraction processes are examined. The first process has the potential to reduce the energy costs inherent in the recovery of low-volatility carboxylic acids from dilute aqueous solutions. The second process has the potential for reducing the energy costs required for separate recovery of ammonia and acid gases (e.g. CO{sub 2} and H{sub 2}S) from industrial sour waters. The recovery of carboxylic acids from dilute aqueous solution can be achieved by extraction with tertiary amines. An approach for regeneration and product recovery from such extracts is to back-extract the carboxylic acid with a water-soluble, volatile tertiary amine, such as trimethylamine. The resulting trimethylammonium carboxylate solution can be concentrated and thermally decomposed, yielding the product acid and the volatile amine for recycle. Experimental work was performed with lactic acid, SUCCiOlC acid, and fumaric acid. Equilibrium data show near-stoichiometric recovery of the carboxylic acids from an organic solution of Alamine 336 into aqueous solutions of trimethylamine. For fumaric and succinic acids, partial evaporation of the aqueous back extract decomposes the carboxylate and yields the acid product in crystalline form. The decomposition of aqueous solutions of trimethylammonium lactates was not carried out to completion, due to the high water solubility of lactic acid and the tendency of the acid to self-associate. The separate recovery of ammonia and acid gases from sour waters can be achieved by combining steam-stripping of the acid gases with simultaneous removal of ammonia by extraction with a liquid cation exchanger. The use of di-2,4,4-trimethylpentyl phosphinic acid as the liquid cation exchanger is explored in this work. Batch extraction experiments were carried out to measure the equilibrium distribution ratio of ammonia between an aqueous buffer solution and an organic solution of the phosphinic acid (0.2N) in Norpar 12. The concentration-based distribution ratios increase from 0.11 to 0.46 as the aqueous phase pH increases from 7.18 to 8.15. Regeneration of the organic extractant solution was carried out by stripping at elevated temperatures to remove the ammonia, with 99% recovery of the ammonia being obtained at 125 C.

Poole, L.J.; King, C.J.

1990-03-01T23:59:59.000Z

237

Use of ammonia to reduce the viscosity of bottoms streams produced in hydroconversion processes  

DOE Patents (OSTI)

Coal, petroleum residuum and similar carbonaceous feed materials are subjected to hydroconversion in the presence of molecular hydrogen to produce a hydroconversion effluent which is then subjected to one or more separation steps to remove lower molecular weight liquids and produce a heavy bottoms stream containing high molecular weight liquids and unconverted carbonaceous material. The viscosity of the bottoms streams produced in the separation step or steps is prevented from increasing rapidly by treating the feed to the separation step or steps with ammonia gas prior to or during the separation step or steps. The viscosity of the heavy bottoms stream produced in the final separation step is also controlled by treating these bottoms with ammonia gas. In a preferred embodiment of the invention, the effluent from the hydroconversion reactor is subjected to an atmospheric distillation followed by a vacuum distillation and the feeds to these distillations are contacted with ammonia during the distillations.

Zaczepinski, Sioma (Houston, TX); Billimoria, Rustom M. (Houston, TX); Tao, Frank (Baytown, TX); Lington, Christopher G. (Houston, TX); Plumlee, Karl W. (Baytown, TX)

1984-01-01T23:59:59.000Z

238

Presented in Concord, Merrimack and West Lebanon, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Fall 2012  

E-Print Network (OSTI)

Drivers Permit 10 1-day, 9am to 4pm To be announced Topics covered: ArcGIS 10 Exploring GIS maps Basic GIS Lebanon, NH December 4-6, Merrimack, NH Topics covered: ArcGIS 10 Creating GIS maps GIS techniques GIS and applications, participants learn how to use ArcGIS 10 to produce effective maps, edit and create GIS data

New Hampshire, University of

239

CHNG 5 CHNG TRNH KHI PHC SM XUT: PHT TRIN V NH GI CC GII PHP ...............................................................................................................................................................1  

E-Print Network (OSTI)

Lng Môi Trng(CEQ) v vic thc hin Chính Sách Lut Môi Trng Quc Gia (NEPA) cng hng dn các t chc nghiên cu hp lý nu áp ng c mc tiêu và yêu cu ra, khôi phc hoc làm tng cht lng môi trng nhân sinh, và phòng tránh hoc gim thiu các hiu ng tiêu cc t hành ng ca các t chc ti cht lng môi trng nhân sinh (40 C

240

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Resonance and Low Pressure Sampling A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO...

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Towards a climate-dependent paradigm of ammonia emission and deposition  

Science Journals Connector (OSTI)

...sources, including a global application for seabird...estimate suggests that 5C warming would increase emissions...anthropogenic activity, global NH3 emissions may increase...low-efficiency domestic coal burning [2]. fRescaled by global population increase...

2013-01-01T23:59:59.000Z

242

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst surface  

E-Print Network (OSTI)

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst for the selective catalytic reduction (SCR) of nitric oxide by ammonia on (0 1 0) V2O5 surface represented by a V2O9/6-31G** level. The computations indicated that SCR reaction consisted of three main parts

Senkan, Selim M.

243

Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a  

E-Print Network (OSTI)

to the surface properties and the adsorption reactions of titanium dioxide-anatase surface. Lin and Bai [3 reserved. Keywords: TiO2; Anatase; Adsorption; Water; Ammonia; DFT 1. Introduction Titanium oxides are usedAdsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim

Senkan, Selim M.

244

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect

Work completed in this reporting period focused on the measurement of the rate of ammonia loss from mortar and concrete, and the measurement of ammonia gas in the air above the materials immediately after placement. The majority of mortar experiments have been completed, and testing has begun on concrete. The mortar experiments indicate that the rate of ammonia loss is greater in mortars prepared using a higher water content and water:cement (W:C) ratio, although the higher rate is primarily observed within the first 2 days, after which the loss rates are nearly the same. The source of low-calcium (Class F) fly ash exerted a negligible influence on the loss rate. However, mortar prepared using a higher-calcium fly ash evolved ammonia at a slightly slower rate than the Class F ash mortars. The data also indicate that an increase in ventilation increases the ammonia loss rate from mortar, and suggest that a well-ventilated space could substantially increase the loss of ammonia from mortar and, by inference, a concrete slab. Analysis of ammonia concentrations in the air above freshly-placed mortars in an enclosed space indicate that the fly ash ammonia concentration should not exceed 100 mg N/kg ash in confined space applications. For most other applications with some ventilation the maximum acceptable concentration would be approximately 200 mg/kg. Early results from experiments on concrete suggest that, under similar conditions, ammonia diffusion from concrete occurs at a higher rate than in mortar. In addition, increasing the slump of concrete through the use of chemical admixtures has only a minor effect on the ammonia loss rate.

Robert F. Rathbone; Thomas L. Robl

2001-10-11T23:59:59.000Z

245

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network (OSTI)

energy conversion (OTEC) systems, where plant ships could then bring the ammonia to shore as an energy carrier (

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

246

General Working Principles of CH3NH3PbX3 Perovskite Solar Cells  

Science Journals Connector (OSTI)

General Working Principles of CH3NH3PbX3 Perovskite Solar Cells ... Organometal halide perovskite-based solar cells have recently realized large conversion efficiency over 15% showing great promise for a new large scale cost-competitive photovoltaic technology. ... Using impedance spectroscopy measurements we are able to separate the physical parameters of carrier transport and recombination in working devices of the two principal morphologies and compositions of perovskite solar cells, viz. ...

Victoria Gonzalez-Pedro; Emilio J. Juarez-Perez; Waode-Sukmawati Arsyad; Eva M. Barea; Francisco Fabregat-Santiago; Ivan Mora-Sero; Juan Bisquert

2014-01-07T23:59:59.000Z

247

Midinfrared interferometry on spectral lines: III. Ammonia and Silane around IRC +10216 and VY CMa  

E-Print Network (OSTI)

J. D. Monnier 1 , W. C. Danchi 2 , D. S. Hale, P. G. Tuthill 3 , C. H. Townes Space Sciences beyond both the dust formation and gas acceleration zones. Specifically, ammonia was found to form before silane in a region of decaying gas turbulence ( ? ¸ 20 R ? ), while the silane is produced in a region

Monnier, John D.

248

Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs  

E-Print Network (OSTI)

Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs of organisms capable of ni- trogen fixation in geothermal communities. These observations help to explain-to-alkaline geothermal springs. All life requires fixed sources of nitrogen (N), and its availabil- ity often limits

Ahmad, Sajjad

249

MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE  

E-Print Network (OSTI)

- izers, emission from soils, biomass burning, and domestic animal waste (Bouwman et al., 1997MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE animals ( 32 Tg N -1yr-1). Waste storage and treatment lagoons are used to treat the excreta of hogs

Aneja, Viney P.

250

Solar absorption aqua-ammonia absorption system simulation base on climate of Malaysia  

Science Journals Connector (OSTI)

Solar energy is one of the most well known green sources of energy. This research presents a feasibility study of evacuated solar thermal collector by aqua-ammonia ejector absorption systems as a small scale air conditioning unit. The modeling has been ... Keywords: ejector, evacuated tubes, solar assisted absorption system

Poorya Ooshaksaraei; Sohif Mat; M. Yahya; Ahmad Mahir Razali; Azami Zaharim; K. Sopian

2010-01-01T23:59:59.000Z

251

Complete Genome Sequence of the Marine, Chemolithoautotrophic, Ammonia-Oxidizing Bacterium Nitrosococcus oceani ATCC 19707  

Science Journals Connector (OSTI)

...hypothetical genes; pale green, structural RNAs...electron acceptors (green). The two inner circles...their involvement in energy metabolism (ATP, pmf...Springer Science and Business Media, Inc., New York...oxidation of ammonia as an energy source in bacteria in...

Martin G. Klotz; Daniel J. Arp; Patrick S. G. Chain; Amal F. El-Sheikh; Loren J. Hauser; Norman G. Hommes; Frank W. Larimer; Stephanie A. Malfatti; Jeanette M. Norton; Amisha T. Poret-Peterson; Lisa M. Vergez; Bess B. Ward

2006-09-01T23:59:59.000Z

252

NETL: Gasification Systems - Warm Gas Multi-Contaminant Removal System  

NLE Websites -- All DOE Office Websites (Extended Search)

Warm Gas Multi-Contaminant Removal System Warm Gas Multi-Contaminant Removal System Project Number: DE-SC00008243 TDA Research, Inc. is developing a high-capacity, low-cost sorbent that removes anhydrous ammonia (NH3), mercury (Hg), and trace contaminants from coal- and coal/biomass-derived syngas. The clean-up system will be used after the bulk warm gas sulfur removal step, and remove NH3 and Hg in a regenerable manner while irreversibly capturing all other trace metals (e.g., Arsenic, Selenium) reducing their concentrations to sub parts per million (ppm) levels. Current project plans include identifying optimum chemical composition and structure that provide the best sorbent performance for removing trace contaminants, determining the effect of operating parameters, conducting multiple-cycle experiments to test the life of the sorbent for NH3 and Hg removal, and conducting a preliminary design of the sorbent reactor.

253

Complete genome sequence of Nitrosomonas sp. Is79, an ammonia oxidizing bacterium adapted to low ammonium concentrations  

SciTech Connect

Nitrosomonas sp. Is79 is a chemolithoautotrophic ammonia-oxidizing bacterium that belongs to the family Nitrosomonadaceae within the phylum Proteobacteria. Ammonia oxidation is the first step of nitrification, an important process in the global nitrogen cycle ultimately resulting in the production of nitrate. Nitrosomonas sp. Is79 is an ammonia oxidizer of high interest because it is adapted to low ammonium and can be found in freshwater environments around the world. The 3,783,444-bp chromosome with a total of 3,553 protein coding genes and 44 RNA genes was sequenced by the DOE-Joint Genome Institute Program CSP 2006.

Bollmann, Annette [Miami University, Oxford, OH; Sedlacek, Christopher J [Miami University, Oxford, OH; Laanbroek, Hendrikus J [Netherlands Institute of Ecology (NIOO-KNAW); Suwa, Yuichi [Chuo University, Tokyo, Japan; Stein, Lisa Y [University of California, Riverside; Klotz, Martin G [University of Louisville, Louisville; Arp, D J [Oregon State University; Sayavedra-Soto, LA [Oregon State University; Lu, Megan [Los Alamos National Laboratory (LANL); Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Han, James [U.S. Department of Energy, Joint Genome Institute; Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Pennacchio, Len [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Huntemann, Marcel [U.S. Department of Energy, Joint Genome Institute; Deshpande, Shweta [U.S. Department of Energy, Joint Genome Institute; Han, Cliff [Los Alamos National Laboratory (LANL); Chen, Amy [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Mavromatis, K [U.S. Department of Energy, Joint Genome Institute; Markowitz, Victor [U.S. Department of Energy, Joint Genome Institute; Szeto, Ernest [U.S. Department of Energy, Joint Genome Institute; Ivanova, N [U.S. Department of Energy, Joint Genome Institute; Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Pagani, Ioanna [U.S. Department of Energy, Joint Genome Institute; Pati, Amrita [U.S. Department of Energy, Joint Genome Institute; Peters, Lin [U.S. Department of Energy, Joint Genome Institute; Ovchinnikova, Galina [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL)

2013-01-01T23:59:59.000Z

254

Solar fuels and chemicals system design study (ammonia/nitric acid production process). Volume 2. Conceptual design. Final report  

SciTech Connect

As part of the Solar Central Receiver Fuels and Chemicals Program, Foster Wheeler Solar Development Corporation (FWSDC), under contract to Sandia National Laboratories-Livermore (SNLL), developed a conceptual design of a facility to produce ammonia and nitric acid using solar energy as the principal external source of process heat. In the selected process, ammonia is produced in an endothermic reaction within a steam methane (natural gas) reformer. The heat of reaction is provided by molten carbonate salt heated by both a solar central receiver and an exothermic ammonia-fired heater. After absorption by water, the product of the latter reaction is nitric acid.

Not Available

1986-06-01T23:59:59.000Z

255

Measurement and Modeling of Spatial NH3 Storage Distributions in a Commercial Small Port Cu Zeolite Urea SCR Catalyst  

Energy.gov (U.S. Department of Energy (DOE))

A modified Spaci-IR technique can measure transient NH3 and NOx concentrations; data have been used to calibrate and validate an SCR model, with good agreement between experiments and simulations.

256

SPECTROSCOPIC INVESTIGATION OF (NH4)2S TREATED GaSeTe FOR RADIATION DETECTOR APPLICATIONS  

SciTech Connect

The surface of the layered III-VI chalcogenide semiconductor GaSeTe was treated with (NH{sub 4}){sub 2}S at 60 C to modify the surface chemistry and determine the effect on transport properties. Room temperature photoluminescence (PL) measurements were used to assess the effect of the (NH{sub 4}){sub 2}S treatment on surface defect states. Evaluation of the subsequent surface chemistry was performed with high-resolution core-level photoemission measurements. Metal overlayers were deposited on the (NH{sub 4}){sub 2}S treated surfaces and the I-V characteristics were measured. The measurements were correlated to understand the effect of (NH{sub 4}){sub 2}S modification of the interfacial electronic structure with the goal of optimizing the metal/GaSeTe interface for radiation detector devices.

Nelson, A; Laurence, T; Conway, A; Behymer, E; Sturm, B; Voss, L; Nikolic, R; Payne, S; Mertiri, A; Pabst, G; Mandal, K; Burger, A

2009-08-04T23:59:59.000Z

257

Ocean thermal plantships for production of ammonia as the hydrogen carrier.  

SciTech Connect

Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

2009-12-02T23:59:59.000Z

258

Field measurements of ammonia volatilization from surface applications of nitrogen fertilizers to a calcareous soil  

E-Print Network (OSTI)

hydrolysis study . . . . . . . . . . . , . . . . . . 71 Table 14 Effect of added soil water and added urease on loss of NH3 from Solution 32 applied at a rate of 224 kg N/ha in the field Page 72 15 Effect of method of application and added urease... on loss of NH from Solution 32 applied at a r2te of 112 kg N/ha in the field . . . . . . . . . . 74 16 Some physical and chemical characteris- tics of Houston Black clay . . . . . . . . 89 LIST OF FIGURES Figure Page A schematic of the apparatus used...

Hargrove, W. L

2012-06-07T23:59:59.000Z

259

Oxygen sorption and thermal regeneration of sorption centers on catalysts of ammonia synthesis in helium and hydrogen flow  

Science Journals Connector (OSTI)

The interaction of oxygen with catalysts for ammonia synthesis in helium and hydrogen flow has been studied. Various catalysts sorb from 7 to 12 oxygen layers. 2 to 4 layers can be removed by thermal activatio...

A. V. Krylova; V. V. Morozov; S. S. Lachinov

260

Estimation of ammonia volatilization from surface-applied urea as indicated by bermudagrass N-use efficiency  

E-Print Network (OSTI)

ESTIMATION OF AMMONIA VOLATILIZATION FROM SURFACE-APPLIED UREA AS INDICATED BY BERMUDAGRASS N-USE EFFICIENCY A Thesis by JOHN MATTHEW DRWAL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1986 Major Subject: Soil Science ESTIMATION OF AMMONIA VOLATILIZATION FROM SURFACE-APPLIED UREA AS INDICATED BY BERMUDAGRASS N-USE EFFICIENCY A Thesis by JOHN MATTHEW DRWAL Approved as to style and content by...

Drwal, John Matthew

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Process for treating ammonia and nitrite containing waters to prevent nitric oxide emissions therefrom  

SciTech Connect

This patent describes a process for controlling the emission of nitrogen dioxide from, and the amount of one or more organisms, selected from the group consisting of fungi, algae and bacteria, growing in a system for handling a flow of condensate of steam, the condensate containing ammonia, ammonia precursors, or a mixture thereof. It comprises contacting the condensate in a substantially continuous manner with an amount of an oxidizing biocide which substantially prevents the emission of nitrogen dioxide from the condensate handling system but which does not substantially inhibit the growth of the organisms in the condensate handling system; and periodically contacting the condensate with an amount of a second biocide which substantially reduces the amount of the organisms.

Gallup, D.L.; Featherstone, J.L.

1991-07-16T23:59:59.000Z

262

Sequential addition of H2O, CH3OH, and NH3 to Al3O3 : A theoretical study  

E-Print Network (OSTI)

, Al3O3 H2O 2 - and Al3O3 CH3OH 2 - , that are produced by the addition of two water or methanol be approximated by collisions between AlxOy - clusters and molecules of water, methanol, and ammonia. Products the photoelectron spectra of anions formed with two but not one molecules of water and methanol resemble

Simons, Jack

263

Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii  

E-Print Network (OSTI)

to larval and juvenile shrimps (Armstrong et al. , 1976; Wickins, 1976) and to fish (Russo et al. , 1974", Smith and Williams, 1974", Smith and Russo' 1975; Crawford and Allen, 1977; Thurston et al. , 1978; Wedemeyer and Yasutake, 1978) and can.... Although the toxicity of ammonia to freshwater shrimp larvae has been reported by Armstrong et al. (1978), other aspects require further investigation before a reliable estimate of safe concentrations can be esta'blished. This study, which examines...

Llobrera, Jose Alvarez

1979-01-01T23:59:59.000Z

264

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents (OSTI)

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

265

Retail refrigeration systems -- The use of ammonia and two-level secondary refrigeration  

SciTech Connect

The concept of a secondary refrigeration system for high-temperature use as investigated in 1991, and a design for a full high-temperature system was completed the following year. In late 1992, a supermarket chain commissioned a study of the feasibility of turning the design into a practical application and assisted the project in 1993 by commissioning a test facility for single-temperature secondary refrigeration at one of the company`s factory sites. Results and conclusions from this trial work pointed toward the need for a total secondary refrigeration system, including a low-temperature system for frozen food display cases, and the possibility of utilizing environmentally friendly ammonia as the primary refrigerant. Therefore, in late 1993/early 1994, a low-temperature system was developed and commissioned at the test facility. Full collaboration between the supermarket company and the contractor resulted in the funding of practical trial work and feasibility studies for both secondary refrigeration and a fully detailed proposal for the use of ammonia in a public retail environment. In May 1995, the first UK ammonia and two-level secondary refrigeration system began operation in a supermarket in Horsham, Sussex England.

Thomas, A.S. [Westward Refrigeration, Gloucester (United Kingdom)

1998-10-01T23:59:59.000Z

266

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

267

Flue gas cleaning with ammonia reduces SO{sub 2} emission  

SciTech Connect

This paper describes the technical and commercial development and basis for application in North America for wet flue gas desulfurization (FGD) of the AMASOX{reg_sign} (i.e. Ammonia Absorbs Sulfur Oxides) Process of Krupp Uhde (Germany) employing ammonia reagent. This process technology has been emerging slowly and stepwise over a twenty-year period in reaching the present stage of commercial applicability. The discussion herein considers the need for accommodating to and advantageously addressing the increasing number of applications with high and ultra-high flue-gas concentrations of SO{sub 2} at the boiler outlet accompanied by significant levels of other pollutants. Key measures in accomplishing this include use of important process innovations. This, as well, calls for the effective use, when applicable, of wet electrostatic precipitator mist-elimination means to gain low/minimum-opacity stack plume trailoff in wet scrubber use together with reduction of air toxics to low concentrations. With cost-effectiveness in electric utility service, detailed herein, superior to FGD processes commonly used to date in high-sulfur service, utilization of this technology is expanding. Important, potentially trend-setting types of powerplant applications of ammonia FGD are reviewed to identify foreseen market sectors and procurement trends that will at the same time serve to substantially broaden lowest-cost coal utilization.

Emish, G.J. [Krupp Wilputte Corp., Bridgeville, PA (United States); Schulte, W. [Krupp Uhde GmbH, Dortmund (Germany); Ellison, W. [Ellison Consultants, Monrovia, MD (United States)

1997-12-31T23:59:59.000Z

268

Stress-corrosion cracking of steels in ammonia with consideration given to OTEC design: a survey  

SciTech Connect

Carbon steel, alloy steel, and high-strength, quenched and tempered steel, when under applied or residual stress and especially when cold formed and/or welded without subsequent thermal stress relief, are subject to failure by stress-corrosion cracking (SCC) in air-contaminated dry ammonia. Water as well as hydrazine when present in small amounts have been shown to be effective inhibitors in an all steel system. Galvanic corrosion between dissimilar metals and/or accelerated failure by SCC of stressed steel as a result of galvanic coupling may be of concern. Where water has proven effective as an inhibitor of SCC in an all steel system, it may not be adequate in a mixed metal system. With aluminum tubes, the tube sheet will either have to be solid aluminum, aluminum clad steel or some nonconductive coating will be necessary to effectively remove the cathodic alloy from the galvanic circuit. Research is required to determine the severity of the coupling effect between dissimilar alloys in ammonia under OTEC conditions; especially the possibility of accelerated SCC failures of stressed steel where the presence of an inhibitor in the ammonia may not be sufficient to override the galvanic coupling effect.

Teel, R.B.

1980-03-01T23:59:59.000Z

269

Diffusive and rotational dynamics of condensed n-H2 confined in MCM-41  

SciTech Connect

In this paper, we report an inelastic neutron scattering study of liquid and solid n-H2 confined within MCM-41. This is a high surface area, mesoporous silica glass with a narrow pore size distribution centered at 3.5 nm. The scattering data provides information about the diffusive and rotational dynamics of the adsorbed n-H2 at low temperatures. In the liquid state, the neutron scattering data demonstrates that only a fraction of the adsorbed o-H2 is mobile on the picosecond time scale. This mobile fraction undergoes liquid-like jump diffusion, and values for the residence time t and effective mean-squared displacement hu2i are reported as a function of pore filling. In the solid state, the rotational energy levels of adsorbed H2 are strongly perturbed from their free quantum rotor behavior in the bulk solid. The underlying orientational potential of the hindered rotors is due to the surface roughness and heterogeneity of the MCM-41 pore walls. This potential is compared to the hindering potential of other porous silicas, such as Vycor. Strong selective adsorption makes the interfacial layer rich in o-H2, leaving the inner core volume consisting of a depleted mixture of o-H2 and p-H2.

Prisk, Timothy R [ORNL; Bryan, Matthew [Indiana University; Sokol, Paul E [ORNL

2014-01-01T23:59:59.000Z

270

Two-reagent reactions of iron clusters with ammonia and deuterium: Saturated compositions and the kinetics of reactions of deuterium with ammoniated clusters  

SciTech Connect

Studies of two-reagent reactions of iron clusters with ammonia and deuterium are described. The compositions of clusters saturated with both ammonia and deuterium have been determined, and indicate that the ammonia binds nondissociatively to iron clusters and to different sites than the deuterium. Rate constants for the reaction of the first deuterium molecule with ammoniated clusters have been measured. In general, low ammonia coverage (one to three molecules) has either little effect on cluster reactivity, or in the case of unreactive bare clusters, increases reactivity dramatically. Clusters saturated with ammonia show general reactivity decreases, although again the least reactive bare clusters show dramatic increases in reactivity when covered with ammonia molecules. Interesting cluster activation and deactivation effects are seen. Possible mechanisms for these reactions are discussed.

Hoffman W.F. III; Parks, E.K.; Riley, S.J.

1989-02-01T23:59:59.000Z

271

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network (OSTI)

or hydro-powered water electrolysis. Ammonia as a HydrogenV for conventional water electrolysis (Cooper and Botte,electricity required for water electrolysis under standard

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

272

Small capacity absorption systems for cooling and power with a scroll expander and ammonia based working fluids  

Science Journals Connector (OSTI)

Abstract Up to now, the use of ammonia/water absorption cycles has been mainly limited to the production of refrigeration or air conditioning but due to the relatively high generator pressure some authors have proposed the integration in parallel of an expander to produce cooling and power simultaneously. This feature could provide many benefits in the future such as the use of solar thermal energy to partially cover the heating, cooling and electricity demand of a building. In the other hand the life cycle cost of the absorption system is improved because of the increase in the number of running hours in periods in which there is no demand for cooling but the demand for electrical power is still important. This paper shows a new combined absorption system using a scroll expander and three different working fluids using ammonia as refrigerant: ammonia/water, ammonia/lithium nitrate and ammonia/sodium thiocyanate. The scroll expander performance maps were obtained experimentally and modeled to predict the power production, rotational speed and exhaust temperature of the expander and included in the complete absorption cycle model build using Engineering Equation Solver (EES) Software. This system produces different amounts of cooling and power at the desired power/cooling ratio to cover varying demand profiles.

Luis Carlos Mendoza; Dereje S. Ayou; Joaqun Navarro-Esbr; Joan Carles Bruno; Alberto Coronas

2014-01-01T23:59:59.000Z

273

Analysis of vibrational structure and Jahn?Teller effects in the electron spectrum of ammonia  

Science Journals Connector (OSTI)

The electron spectra of the 2 A 1 ? 1 A 1 and the 2 E? 1 A 1 transitions of ammonia have been measured with sufficient resolution to observe considerable fine structure. The first transition 2 A 1 ? 1 A 1 contains two vibrational progressions which are assigned to the ?2 bending mode. The second transition 2 E? 1 A 1 consists of two overlapping electron bands due to Jahn?Teller splitting of the 2 E state. The vibronic structure accompanying this transition has been partially resolved and compared to the results of model calculations.

J. W. Rabalais; L. Karlsson; L. O. Werme; T. Bergmark; K. Siegbahn

1973-01-01T23:59:59.000Z

274

Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate  

E-Print Network (OSTI)

in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

Czarnecki, Lawrence Joseph

1988-01-01T23:59:59.000Z

275

Modeling of selective catalytic reduction (SCR) of nitric oxide with ammonia using four modern catalysts  

E-Print Network (OSTI)

and Ammonia and Oxygen Exponents for V Catalyst........................ 36 Table 6.20 Experimental Data at 150 o C for V-Ti Based PILC Catalyst [28].................................. 40 Table 6.21 Experimental Data at 200 o C for V-Ti Based PILC Catalyst... [28].................................. 40 Table 6.22 Experimental Data at 250 o C for V-Ti Based PILC Catalyst [28].................................. 40 Table 6.23 Experimental Data at 300 o C for V-Ti Based PILC Catalyst [28...

Sharma, Giriraj

2005-11-01T23:59:59.000Z

276

Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup  

E-Print Network (OSTI)

technologies, such as the selective catalytic reduction (SCR) methods have been studied for the cleaning of diesel engine exhaust. The SCR system, in which ammonia is used as a reducing agent, is thought to be one of the most promising methods for emissions... of methane, it can also include ethane, propane, butane and pentane. The composition of natural gas can vary widely, but Table 1 below outlines the typical makeup of natural gas before it is refined. 3 Table 1. Typical composition of natural gas...

Ming, Pingjia

2014-06-05T23:59:59.000Z

277

An investigation of the effect of ammonia and amines on the recovery of oil  

E-Print Network (OSTI)

AE INVESTIGATION OF THE EFFECT OF AMMONIA A?D ANIEES OE THE RECOVERT OF OIL A Thesis EF~ %0 JAMES MP RICHARDSON Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE ~J1 8 Na)or Subject: Petroleum En carin AE IEVESTIGATIOE OF TEE EFFECT OF AMMOBIA AED AMIEES OE TRE RECOVERY OF OIL JAMES M, RICRARDSOE Approve& as to sty1e aad eoateat by". Cha1rsan o CeeeeAt e Read of Departaeat J~18...

Richardson, James Malone

2012-06-07T23:59:59.000Z

278

Near-infrared photometry of Y dwarfs: low ammonia abundance and the onset of water clouds  

E-Print Network (OSTI)

We present new near-infrared photometry for seven late-type T dwarfs and nine Y-type dwarfs, and lower limit magnitudes for a tenth Y dwarf, obtained at Gemini Observatory. We also present a reanalysis of H-band imaging data from the Keck Observatory Archive, for an eleventh Y dwarf. These data are combined with earlier MKO-system photometry, Spitzer and WISE mid-infrared photometry, and available trigonometric parallaxes, to create a sample of late-type brown dwarfs which includes ten T9-T9.5 dwarfs or dwarf systems, and sixteen Y dwarfs. We compare the data to our models which include updated H_2 and NH_3 opacity, as well as low-temperature condensate clouds. The models qualitatively reproduce the trends seen in the observed colors, however there are discrepancies of around a factor of two in flux for the Y0-Y1 dwarfs, with T_eff~350-400K. At T_eff~400K, the problems could be addressed by significantly reducing the NH_3 absorption, for example by halving the abundance of NH_3 possibly by vertical mixing. At...

Leggett, S K; Marley, M S; Saumon, D

2014-01-01T23:59:59.000Z

279

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3  

E-Print Network (OSTI)

Closed-loop control of a SCR system using a NOx sensor cross-sensitive to NH3 A.Bonfils , Y. Creff for an automotive selective catalytic reduction (SCR) system, for which the feedback is based on a NOx sensor the variety of en- countered technologies, selective catalytic reduction (SCR) is one of the most appealing

280

Adapted from laboratory protocols of the Center for Freshwater Biology, University of New Hampshire, Durham, N.H. 2010  

E-Print Network (OSTI)

, Durham, N.H. 2010 UNH CFB Protocol for the Monitoring of Cyanobacteria & Microcystins in Drinking Water delivery to UNH CFB lab. 5. Freeze the sample if delivery/ drop-off time exceeds 12 hours. Analyses: a, Quantiplate-ELISA Kit, (Portland, Me) with increased sensitivity (UNH, CFB). Results will be reported as ng

New Hampshire, University of

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Effects of \\{NH4Cl\\} and MgCl2 on pretreatment and xylan hydrolysis of miscanthus straw  

Science Journals Connector (OSTI)

This study investigated the effects of \\{NH4Cl\\} and MgCl2 on pretreatment and xylan hydrolysis of miscanthus straw for biofuels production. It was observed that increasing the pretreatment temperature decreased the remaining solid, increased the enzymatic digestibility, and increased the xylan removal. When 0.25.0% \\{NH4Cl\\} and MgCl2 were employed in pretreatments, increasing the inorganic salt concentration slightly diminished the remaining solid, though the enzymatic digestibility was enhanced. Under the higher-than-2% condition, no xylan remained in the solid residues after pretreatment. With pretreatment time, the remaining solid slightly decreased, but the enzymatic digestibility was increased. Moreover, xylan removal was linearly increased to 15min, after which it was completely hydrolyzed. Overall, these results indicated that pretreatment by 2% \\{NH4Cl\\} or MgCl2 at 185C for 15min completely hydrolyzes the xylan of miscanthus straw. In scanning electron microscopy (SEM) images, the physical surface of the miscanthus straw showed an apparently damaged surface area and exposure of the internal structure after pretreatment with \\{NH4Cl\\} and MgCl2 by SEM.

Kyeong Eop Kang; Don-Hee Park; Gwi-Taek Jeong

2013-01-01T23:59:59.000Z

282

Coal ash as an absorbent to remove SO2, and its activity change in NO?NH3 reaction  

Science Journals Connector (OSTI)

After being activated with NaOH aqueous solution, coal ash showed a maximal sorption capacity of about...3 SO2/g ash. Catalytic activity of coal ash for the NO?NH3 reaction was gradually depressed by the presence...

F. Nozaki; O. Watanabe; T. Sodesawa

1984-01-01T23:59:59.000Z

283

Presented in Lee and Concord, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Winter 2013  

E-Print Network (OSTI)

, 9am to 4pm January 17, 2013 Lee, NH Topics covered: ArcGIS 10.1 Exploring GIS maps Basic GIS: ArcGIS 10 Creating GIS maps.1 GIS techniques GIS data maintenance $495 standard, $349 reduced Skill.1 to produce effective maps, edit and create GIS data, as well as, conduct geospatial analysis. Participants

New Hampshire, University of

284

An AlGaAsGaAs quantum cascade laser operating with a thermoelectric cooler for spectroscopy of NH3  

E-Print Network (OSTI)

out using a compact thermo-electrically cooled laser package. The QCL described here is designedAn AlGaAs­GaAs quantum cascade laser operating with a thermoelectric cooler for spectroscopy of NH3. Langford b a Department of Electronics and Electrical Engineering, Rankine Building, University of Glasgow

285

Chemical analysis of HfO{sub 2}/Si (100) film systems exposed to NH{sub 3} thermal processing  

SciTech Connect

Nitrogen incorporation in HfO{sub 2}/SiO{sub 2} films utilized as high-k gate dielectric layers in advanced metal-oxide-semiconductor field effect transistors has been investigated. Thin HfO{sub 2} blanket films deposited by atomic layer deposition on either SiO{sub 2} or NH{sub 3} treated Si (100) substrates have been subjected to NH{sub 3} and N{sub 2} anneal processing. Several high resolution techniques including electron microscopy with electron energy loss spectra, grazing incidence x-ray diffraction, and synchrotron x-ray photoelectron spectroscopy have been utilized to elucidate chemical composition and crystalline structure differences between samples annealed in NH{sub 3} and N{sub 2} ambients as a function of temperature. Depth profiling of core level binding energy spectra has been obtained by using variable kinetic energy x-ray photoelectron spectroscopy with tunable photon energy. An 'interface effect' characterized by a shift of the Si{sup 4+} feature to lower binding energy at the HfO{sub 2}/SiO{sub 2} interface has been detected in the Si 1s spectra; however, no corresponding chemical state change has been observed in the Hf 4f spectra acquired over a broad range of electron take-off angles and surface sensitivities. The Si 2p spectra indicate Si-N bond formation beneath the HfO{sub 2} layer in the samples exposed to NH{sub 3} anneal. The NH{sub 3} anneal ambient is shown to produce a metastable Hf-N bond component corresponding to temperature driven dissociation kinetics. These findings are consistent with elemental profiles across the HfO{sub 2}/Si(100) interface determined by electron energy loss spectroscopy measurements. X-ray diffraction measurements on similarly treated films identify the structural changes resulting from N incorporation into the HfO{sub 2} films.

Lysaght, Patrick S.; Barnett, Joel; Bersuker, Gennadi I.; Woicik, Joseph C.; Fischer, Daniel A.; Foran, Brendan; Tseng, Hsing-Huang; Jammy, Raj [Front End Process Division, SEMATECH, 2706 Montopolis Drive, Austin, Texas 78741-6499 (United States); National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Physical Characterization Laboratory, Advanced Technology Development Facility, 2706 Montopolis Drive, Austin, Texas 78741-6499 (United States); Front End Process Division, SEMATECH, 2706 Montopolis Drive, Austin, Texas 78741-6499 (United States)

2007-01-15T23:59:59.000Z

286

Investigation of ammonia equipment configurations for supermarket refrigeration applications (for microcomputers). Software  

SciTech Connect

This product gives results of a project to quantify the advantages and disadvantages of using ammonia with a secondary brine refrigerant compared to R-22 in supermarket refrigeration applications. Project objectives were achieved by numerical experiments using simulations. Mechanistic models of refrigeration system components were used, based on fundamental principles, accepted heat transfer/pressure drop correlations, and available manufacturers` data. Available thermodynamic and transport property data correlations for ammonia and R-22 were used in the models. The parameters of these models were varied to determine their effect on system performance and locate optimum values. A modular approach was used in which each component was separately modeled, allowing simple changes in system configurations. The combined component models resulted in a large set of coupled nonlinear algebraic equations for the quasi-steady systems that did not involve brine storage. The system involved differential and algebraic equations. These equations were solved using the general-purpose simulation programs EES and TRNSYS. EES is a robust nonlinear equation-solving program with built-in thermophysical property data. TRNSYS is a sequential modular simulation program that uses schemes to solve coupled algebraic and differential equations.

NONE

1995-02-01T23:59:59.000Z

287

Reactions of cobalt clusters with water and ammonia: Implications for cluster structure  

SciTech Connect

Reactions of cobalt clusters in the 6 to 150 atom size range with water and ammonia are used to probe cluster geometrical structure. Clusters saturated with ammonia are found in several isomeric forms in much of this size region, including a structure based on icosahedral packing for clusters having 50 to 120 atoms. The variations with cluster size of the binding energy for a single water molecule provide evidence for icosahedral structure of the bare cobalt clusters in the same size range seen for the ammoniated clusters. However, both probes suggest that in many cases the bare clusters also have multiple isomers. The evidence for icosahedral structure in the bare and ammoniated clusters disappears above [similar to]120 atoms and is clearly not seen at the third icosahedral shell closing at 147 atoms. Comparison with earlier studies of hydrogenated cobalt clusters and with bare and hydrogenated nickel clusters is made. Reasons for the failure to form the closed-shell 147 atom icosahedral cluster are discussed.

Parks, E.K.; Klots, T.D.; Winter, B.J.; Riley, S.J. (Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States))

1993-10-15T23:59:59.000Z

288

Theoretical study on a novel ammoniawater cogeneration system with adjustable cooling to power ratios  

Science Journals Connector (OSTI)

Abstract A novel ammoniawater cogeneration system with adjustable cooling to power ratios is proposed and investigated. In the combined system, a modified Kalina subcycle and an ammonia absorption cooling subcycle are interconnected by mixers, splitters, absorbers and heat exchangers. The proposed system can adjust its cooling to power ratios from the separate mode without splitting/mixing processes in the two subcycles to the combined operation modes which can produce different ratios of cooling and power. Simulation analysis is conducted to investigate the effects of operation parameter on system performance. The results indicate that the combined system efficiency can reach the maximum values of 37.79% as SR1 (split ratio 1) is equal to 1. Compared with the separate system, the combined efficiency and COP values of the proposed system can increase by 6.6% and 100% with the same heat input, respectively. In addition, the cooling to power ratios of the proposed system can be adjusted in the range of 1.83.6 under the given operating conditions.

Zeting Yu; Jitian Han; Hai Liu; Hongxia Zhao

2014-01-01T23:59:59.000Z

289

64Cu-1,4,7-Triazacyclononane-1,4-diacetic acid-para-aminobenzoic acid-Gln-Trp-Ala-Val-Gly-His-Leu-Met-NH2  

E-Print Network (OSTI)

, 14). Prasanphanich et al. recently reported that the NOTA-based 64Cu-NOTA-8-Aoc-BBN(7­14) NH2 conjugate (where 8-Aoc = 8-aminooctanoic acid) exhibited decreased accumulation in hepatic tissue and maintain the good pharmacokinetic properties of the 64Cu-NOTA-8-Aoc-BBN(7­14)NH2 conjugate, Lane et al

Levin, Judith G.

290

Measurements of NH3 and CO2 with distributed-feedback diode lasers near 2.0 m in bioreactor vent gases  

E-Print Network (OSTI)

absorption transition at 5016.977 cm 1 was selected for trace gas monitoring. For CO2, an isolated transition of a diode-laser sensor used to record gas-phase NH3 and CO2 mole fractions, ex- plain the motivation for NH3 and 40 ppm for CO2, which is suitable for the expected vent gas concentrations. 2. Theory

291

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate  

E-Print Network (OSTI)

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

Goddard III, William A.

292

Thermodynamic modelling of three-stage combined cycle power systems utilising ammonia-water mixture as a working fluid in bottoming cycle  

Science Journals Connector (OSTI)

In this study, two three-stage combined power cycles with ammonia-water mixture in bottoming cycle are introduced; one with variable ammonia fraction and the other with constant ammonia fraction. Energy and exergy analyses are carried out and optimal parameters of the proposed cycles are compared with the conventional power cycles. The second law efficiency of three-stage cycles with variable and constant ammonia fraction are 4.71% and 5.15% higher than steam-gas combined power cycle, respectively. Exergy flow diagram for each cycle is presented and exergy destruction of all components is investigated. Results quantitatively highlight the thermodynamic advantages of the proposed cycles in comparison with the conventional cycles. Three-stage cycle with constant ammonia fraction has the best performance in comparison with the others.

Amin Momeni; Hossein Shokouhmand

2014-01-01T23:59:59.000Z

293

Effects of Hydrothermal Aging on NH3-SCR reaction over Cu/zeolites  

SciTech Connect

The effects of hydrothermal treatment on model Cu/zeolite catalysts were investigated to better understand the nature of Cu species for the selective catalytic reduction of NO{sub x} by NH{sub 3}. After hydrothermal aging at 800 C for 16 h, the NO{sub x} reduction performance of Cu-ZSM-5 and Cu-beta were significantly reduced at low temperatures, while that of Cu-SSZ-13 was not affected. When the zeolite framework aluminum species were probed using solid state {sup 27}Al-NMR, significant reduction in the intensities of the tetrahedral aluminum peak was observed for Cu-ZSM-5 and Cu-beta, although no increase in the intensities of the octahedral aluminum peak was observed. When the redox behavior of Cu species was examined using H{sub 2}-TPR, it was found that Cu{sup 2+} could be reduced to Cu{sup +} and to Cu{sup 0} fir Cu-ZSM-5 and Cu-beta catalysts, while Cu{sup 2+} could be reduced to Cu{sup +} only for Cu-SSZ-13. After hydrothermal aging, CuO and Cu-aluminate species were found to form in Cu-ZSM-5 and Cu-beta, while little changes were observed for Cu-SSZ-13.

Kwak, Ja Hun; Tran, Diana N.; Burton, Sarah D.; Szanyi, Janos; Lee, Jong H.; Peden, Charles HF

2012-02-06T23:59:59.000Z

294

S urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia and steam  

E-Print Network (OSTI)

-based activated carbon fibers (ACF) to optimize the oxidative retention of up to 5000 ppmv of SO2 in moist air suitable for the recovery of sulfuric acid at room temperature than granular activated carbon becauseS urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia

Paris-Sud XI, Université de

295

Estimation of Carbon Monoxide and Carbon Dioxide at Sub-ppm Level Concentrations in Ammonia Synthesis Gas  

Science Journals Connector (OSTI)

......can be handled per analysis. The ammonia synthesis...conditioning of I2O5 reactors or to marginal flow...20%. Thus, the reliability of the method depends...practice for the analysis of trace impurities...estimated from a single analysis the method of converting...to CO2 using I2O5 reactor (11) after its......

K. Annaji Rao; K.K. Pushpa; Hari Mohan; R.M. Iyer

1978-07-01T23:59:59.000Z

296

nh Gi Thit Hi Ti Nguyn Thin Nhin ca V Trn Du Deepwater Horizon Cc D n Khu Vc  

E-Print Network (OSTI)

Lng Sò ip Nhm Tng C Hi ánh Bt Gii Trí Trong Vùng Cán Xong Florida s c thc hin Qun Bay (h thng Vnh St Okaloosa và Walton. Lý tng ra thì bng cách thc hin d án này,s lng sò ip ti các a im c can thip cui cùng có th s tng lên ti các mc t duy trì bn vng c cho vic ánh bt gii trí. S lng sò ip các Qun Gulf và

297

Electronic Structure of TiO2/CH3NH3PbI3 Perovskite Solar Cell Interfaces  

Science Journals Connector (OSTI)

The last two decades, the research on different types of mesoscopic solar cells has grown enormously, largely because this family of solar cells can be controlled in many different ways and for their easy production. ... Recently, the use of soluble semiconductors such as organicinorganic perovskites has shown great promise as light absorbers in solid-state mesoscopic solar cells. ... We report for the first time on a hole conductor-free mesoscopic methylammonium lead iodide (CH3NH3PbI3) perovskite/TiO2 heterojunction solar cell, produced by deposition of perovskite nanoparticles from a soln. of CH3NH3I and PbI2 in ?-butyrolactone on a 400 nm thick film of TiO2 (anatase) nanosheets exposing (001) facets. ...

Rebecka Lindblad; Dongqin Bi; Byung-wook Park; Johan Oscarsson; Mihaela Gorgoi; Hans Siegbahn; Michael Odelius; Erik M. J. Johansson; Hkan Rensmo

2014-01-24T23:59:59.000Z

298

Characteristics of V2O5/Ti-PILC catalyst for the reduction of NO by NH3  

Science Journals Connector (OSTI)

Titania-pillared clay (Ti-PILC) as a catalyst support exhibited peculiar physicochemical characteristics compared to that of titania for the reduction of NO by NH3. The morphological variation of Ti-PILC was examined with respect to the preparation method. For the freeze-dried Ti-PILC, the development of needle-like crystallites, which may reveal the formation of a house-of-cards structure by delamination of Ti-PILC, has been observed. Ti-PILC catalyst contains high surface acidity examined by NH3 TPD. Without the impregnation of WO3 and MoO3 on V2O5/Ti-PILC catalyst as a promoter, the catalyst exhibits competitive NO removal performance to a commercial V2O5-WO3/TiO2 catalyst. In addition, Ti-PILC catalyst also exhibits the strong sulfur tolerance mainly attributed to the unique pore structure of the catalyst.

Ho Jeong Chae; In-Sik Nam; Young Gul Kim; Hee Sung Yang; Hyun Chul Choi{rk; Seok Lyong Song{rk

1999-01-01T23:59:59.000Z

299

Thermal Stability and Hydrogen Release Kinetics of Ammonia Borane Under Vehicle Storage Conditions  

SciTech Connect

Ammonia borane (AB) is a promising chemical hydrogen storage material for H2 powered fuel-cell vehicles (FCVs) owing to its considerable hydrogen density and stability under typical ambient conditions. U.S. Department of Energy (DOE) Technical Targets for on-board hydrogen storage systems in 2015 provide a requirement for operating temperatures in full-sun exposure as high as 60C (50C by 2010) [1]. The purpose of this work is to investigate the thermal stability of solid AB during storage on-board a FCV at 40 to 60C. Calorimeter measurements and calculation models are used to estimate AB thermal stability and H2 release kinetics under isothermal, adiabatic, and cooled storage conditions as a function of storage time, temperature, and AB purity.

Rassat, Scot D.; Smith, R. Scott; Aardahl, Christopher L.; Autrey, Thomas; Chin, Arthur A.; Magee, Joseph W.; VanSciver, Gary R.; Lipiecki, Frank J.

2006-09-01T23:59:59.000Z

300

Calculations on spin-paired species in metal-ammonia solutions  

SciTech Connect

In this paper we show that the spin-paired species in ammonia is consistent with a cluster of two single-electron ammoniated cavity species held together by a cation, also probably solvated. With the electronic part of the wave functions for the ammoniated electron as determined by Newton, the ground-state electronic configuration is a singlet and the singlet-triplet separation is calculated to be about 0.1 eV. The spectrum of the individual cavity species is only shifted by a few hundredths of an electronvolt based on perturbation calculations. These data are consistent with the experimental values recently found by Schindewolf and Werner, who have other data which support the particular species studied in this paper.

Kestner, N.R.; Rao, B.K.; Finley, C.W.

1983-04-14T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Evaluation of a solar intermittent refrigeration system for ice production operating with ammonia/lithium nitrate  

SciTech Connect

A novel solar intermittent refrigeration system for ice production developed in the Centro de Investigacion en Energia of the Universidad Nacional Autonoma de Mexico is presented. The system operates with the ammonia/lithium nitrate mixture. The system developed has a nominal capacity of 8 kg of ice/day. It consists of a cylindrical parabolic collector acting as generator-absorber. Evaporator temperatures as low as -11 C were obtained for several hours with solar coefficients of performance up to 0.08. It was found that the coefficient of performance increases with the increment of solar radiation and the solution concentration. A dependency of the coefficient of performance was not founded against the cooling water temperature. Also it was found that the maximum operating pressure increases meanwhile the generation temperature decreases with an increase of the solution concentration. (author)

Rivera, W.; Moreno-Quintanar, G.; Best, R. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, A.P. 34, 62580 Temixco, Mor. (Mexico); Rivera, C.O.; Martinez, F. [Facultad de Ingenieria Campus Coatzacoalcos, Universidad Veracruzana, Av. Universidad Km 7.5, 96530 Coatzacoalcos, Ver. (Mexico)

2011-01-15T23:59:59.000Z

302

Evaluation of Aqua-Ammonia Chiller Technologies and Field Site Installation  

SciTech Connect

The Naval Facilities Engineering Service Center (NFESC) has sponsored Oak Ridge National Laboratory (ORNL) to review, select, and evaluate advanced, gas-fired, 5-ton, aqua-ammonia, chiller technologies. The selection criteria was that units have COP values of 0.67 or better at Air-conditioning and Refrigeration Institute (ARI) 95 F outdoor rating conditions, an active refrigerant flow control, and a variable-speed condenser fan. These features are expected to allow these units to operate at higher ambient temperatures (up to the maximum operating temperature of 110 F) with minimal degradation in performance. ORNL evaluated three potential manufacturers of advanced, gas-fired, 5-ton, aqua-ammonia chillers-Robur, Ambian, and Cooling Technologies. Unfortunately, Robur did not meet the COP requirements and Cooling Technologies could not deliver a unit to be tested at the U.S. Department of Energy (DOE)-ORNL environmental chamber testing facility for thermally activated heat pumps. This eliminated these two technologies from further consideration, leaving only the Ambian chillers for evaluation. Two Ambian chillers were evaluated at the DOE-ORNL test facility. Overall these chillers operated well over a wide range of ambient conditions with minimal degradation in performance due to several control strategies used such as a variable speed condenser fan, a modulating burner, and active refrigerant flow control. These Ambian pre-commercial units were selected for installation and field testing at three federal facilities. NFESC worked with ORNL to assist with the site selection for installation and evaluation of these chillers. Two sites (ORNL and Naval Surface Warfare Center [NSWC] Corona) had a single chiller unit installed; and at one site (Naval Amphibious Base [NAB] Little Creek), two 5-ton chillers linked together were installed to provide 10 tons of cooling. A chiller link controller developed under this project was evaluated in the field test at Little Creek.

Zaltash, Abdolreza [ORNL

2007-09-01T23:59:59.000Z

303

DRIFT study of manganese/titania-based catalysts for low-temperature selective catalytic reduction of NO with NH{sub 3}  

SciTech Connect

Manganese oxides and iron-manganese oxides supported on TiO{sub 2} were prepared by the sol-gel method and used for low-temperature selective catalytic reduction (SCR) of NO with NH{sub 3}. Based on the previous study, Mn(0.4)/TiO{sub 2} and Fe(0.1)-Mn(0.4)/TiO{sub 2} were then selected to carry out the in situ diffuse reflectance infrared transform spectroscopy (DRIFT) investigation for revealing the reaction mechanism. The DRIFT spectroscopy for the adsorption of NH{sub 3} indicated the presence of coordinated NH{sub 3} and NH{sub 4}{sup +} on both of the two catalysts. When NO was introduced, the coordinated NH{sub 3} on the catalyst surface was consumed rapidly, indicating these species could react with NO effectively. When NH{sub 3} was introduced into the sample preadsorbed with NO + O{sub 2}, SCR reaction would not proceed on Mn(0.4)/TiO{sub 2}. However, for Fe(0.1)-Mn(0.4)/TiO{sub 2} the bands due to coordinated NH{sub 3} on Fe{sub 2}O{sub 3} were formed. Simultaneously, the bidentate nitrates were transformed to monodentate nitrates and NH{sub 4}{sup +} was detected. NO{sub 2} from the oxidation of NO on catalyst could react with NH{sub 4}{sup +} leading to the reduction of NO. Therefore, it was suggested that the SCR reaction on Fe(0.1)-Mn(0.4)/TiO{sub 2} could also take place in a different way from the reactions on Mn(0.4)/TiO{sub 2} proposed by other researchers. Furthermore, the SCR reaction steps for these two kinds of catalysts were proposed. 29 refs., 9 figs.

Zhongbiao Wu; Boqiong Jiang; Yue Liu; Haiqiang Wang; Ruiben Jin [Zhejiang University, Hangzhou (China). Dept. of Environmental Engineering

2007-08-15T23:59:59.000Z

304

Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl2  

E-Print Network (OSTI)

water 1 M Na2 CO3 1 M Na2 SO4 1 M (NH4 )2 SO4 2 M CaCl2 2 M NaCl Re (2) (a.u.) Incident Infrared (cm -1.8 M CaCl2, 1.8 M NaCl, 1.1 M Na2CO3, 1.1 M Na2SO4, and 1.1 M (NH4)2SO4 salt solutions. ExperimentalS1 Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl

305

Time-Resolved XAFS Spectroscopic Studies of B-H and N-H Oxidative Addition to Transition Metal Catalysts Relevant to Hydrogen Storage  

SciTech Connect

Successful catalytic dehydrogenation of aminoborane, H3NBH3, prompted questions as to the potential role of N-H oxidative addition in the mechanisms of these processes. N-H oxidative addition reactions are rare, and in all cases appear to involve initial dative bonding to the metal by the amine lone pairs followed by transfer of a proton to the basic metal. Aminoborane and its trimethylborane derivative block this mechanism and, in principle, should permit authentic N-H oxidative attrition to occur. Extensive experimental work failed to confirm this hypothesis. In all cases either B-H complexation or oxidative addition of solvent C-H bonds dominate the chemistry.

Bitterwolf, Thomas E. [University of Idaho

2014-12-09T23:59:59.000Z

306

Multicomponent Remote Sensing of Vehicle Exhaust by Dispersive Absorption Spectroscopy. 2. Direct On-Road Ammonia Measurements  

Science Journals Connector (OSTI)

The quantitative ecological impacts resulting from anthropogenic NH3 emissions are still riddled with uncertainties, but evidence is mounting (28, 29) that dry and wet deposition of NH3 and its salts can adversely affect terrestrial (30?39) and aquatic (40?42) ecosystems. ... The vehicles in our study were travelling under load, due to the moderate incline of the on-ramp, and at high velocities, explaining the relatively high NO concentrations in the vehicle exhaust plumes. ... Between 1990 and 1998, vehicular NH3 emissions are believed to have increased from 198 to 260 thousand short tons (54), probably due to a reduction of the noncatalyst, oxidation catalyst, and dual-bed catalyst vehicle portion of the on-road fleet. ...

Marc M. Baum; Eileen S. Kiyomiya; Sasi Kumar; Anastasios M. Lappas; Vadym A. Kapinus; Harry C. Lord III

2001-08-09T23:59:59.000Z

307

The discovery of [Ru(NH3)5N2]2+: A case of serendipity and the scientific method  

Science Journals Connector (OSTI)

In this paper the author provides a personal account of the events leading up to the realization [Ru9NH3)5N2]2+ is a real species.

Caesar V. Senoff

1990-01-01T23:59:59.000Z

308

Pillared smectite modified with carbon and manganese as catalyst for SCR of NOx with NH3. Part I. General characterization and catalyst screening  

Science Journals Connector (OSTI)

Carbon- and manganese-modified zirconia-pillared smectites were prepared, characterized (XRD, BET and pore analysis, XPS) and tested in selective catalytic reduction of NOx with NH3. Both untreated and acidic pre...

Lucjan Chmielarz; Roman Dziembaj; Teresa Grzybek; Jerzy Klinik

309

Experimental trial of a hollow-core waveguide used as an absorption cell for concentration measurement of NH3 gas with a CO2 laser  

Science Journals Connector (OSTI)

The basic idea of using a hollow-core waveguide as an absorption cell in a spectroscopic gas measurement system is proposed. Measurements of NH3 gas concentration were made...

Saito, Yasunori; Kanaya, Tatsunori; Nomura, Akio; Kano, Tetsuo

1993-01-01T23:59:59.000Z

310

Supporting Information Surface Electric Fields of Aqueous Solutions of NH4NO3, Mg(NO3)2, NaNO3,  

E-Print Network (OSTI)

S1 Supporting Information Surface Electric Fields of Aqueous Solutions of NH4NO3, Mg(NO3)2, NaNO3 interfaces of (a) 1.0 M and 2.0 M LiNO3, (b) 1.0 M and 1.7 M NaNO3, (c) 1.0 M and 1.6 M NH4NO3, and (d) 1.0 M water 1.0 M NaNO3 1.7 M NaNO3 c water 1.0 M NH4 NO3 1.6 M NH4 NO3 | (2) | 2 (10 3 arb.units) Wavenumber

311

Biofuels from Bacteria, Electricity, and CO2: Biofuels from CO2 Using Ammonia or Iron-Oxidizing Bacteria in Reverse Microbial Fuel Cells  

SciTech Connect

Electrofuels Project: Electrofuels Project: Columbia University is using carbon dioxide (CO2) from ambient air, ammoniaan abundant and affordable chemical, and a bacteria called N. europaea to produce liquid fuel. The Columbia University team is feeding the ammonia and CO2 into an engineered tank where the bacteria live. The bacteria capture the energy from ammonia and then use that energy to convert CO2 into a liquid fuel. When the bacteria use up all the ammonia, renewable electricity can regenerate it and pump it back into the systemcreating a continuous fuel-creation cycle. In addition, Columbia University is also working with the bacteria A. ferrooxidans to capture and use energy from ferrous iron to produce liquid fuels from CO2.

None

2010-07-01T23:59:59.000Z

312

64Cu-1,4,7-Triazacyclononane-1,4-diacetic acid-6-aminohexanoic acid-Gln-Trp-Ala-Val-Gly-His-Leu-Met-NH2  

E-Print Network (OSTI)

. recently reported that the NOTA-based 64Cu-NOTA-8-Aoc-BBN(7­14) NH2 conjugate (where 8-Aoc = 8 pharmacokinetic properties of the 64Cu-NOTA-8-Aoc-BBN(7­14)NH2 conjugate, Lane et al. synthesized a new group of conjugates with the NOTA derivative NO2A and replaced the spacer 8-Aoc with an aliphatic or aromatic linking

Levin, Judith G.

313

64Cu-1,4,7-Triazacyclononane-1,4-diacetic acid-9-aminonanoic acid-Gln-Trp-Ala-Val-Gly-His-Leu-Met-NH2  

E-Print Network (OSTI)

. recently reported that the NOTA-based 64Cu-NOTA-8-Aoc-BBN(7­14) NH2 conjugate (where 8-Aoc = 8 pharmacokinetic properties of the 64Cu-NOTA-8-Aoc-BBN(7­14)NH2 conjugate, Lane et al. synthesized a new group of conjugates with the NOTA derivative NO2A and replaced the spacer 8-Aoc with an aliphatic or aromatic linking

Levin, Judith G.

314

Ammonia-Borane and Related N-B-H Compounds and Materials: Safety Aspects, Properties, and Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

Ammonia-Borane and Related N-B-H Compounds and Materials: Ammonia-Borane and Related N-B-H Compounds and Materials: Safety Aspects, Properties and Applications (A survey completed as part of a project for the DOE Chemical Hydrogen Storage Center of Excellence, Contract # DE-FC36-05GO15060) Clinton F. Lane Department of Chemistry and Biochemistry Northern Arizona University PO Box 5698 Flagstaff, AZ 86011-5698 Phone: 928-523-6296 e-mail: clint.lane@nau.edu Outline 1. Introduction 2. Safety Aspects 3. Synthesis 4. Physical Properties 5. Theoretical Studies 6. Chemical Properties 7. Synthetic Applications 8. Industrial Applications 9. Conclusions 10. References 1. Introduction Amine-borane complexes have great potential for use as a key component in hydrogen storage fuels due to their stability and the high gravimetric content of hydrogen in these

315

Development of a 5 kW Cooling Capacity Ammonia-water Absorption Chiller for Solar Cooling Applications  

Science Journals Connector (OSTI)

The development of a small capacity absorption chiller and the numerical and experimental results are presented in this paper. The prototype is a thermally driven ammonia-water absorption chiller of 5kW cooling capacity for solar cooling applications. The chiller was developed in an industrial perspective with a goal of overall compactness and using commercially available components. In order to characterize various component technologies and different optimization components, the prototype is monitored with temperature, pressure and mass flow rate accurate sensors. The resulting chiller, characterized by a reduced load in ammonia-water solution and the use of brazed plate heat exchanger, has shown good performance during the preliminary tests. A comparison with the expected numerical results is given.

Franois Boudhenn; Hlne Demasles; Jol Wyttenbach; Xavier Jobard; David Chze; Philippe Papillon

2012-01-01T23:59:59.000Z

316

Integration of an Ammonia-water Absorption Refrigeration System with a Marine Diesel Engine: A Thermodynamic Study  

Science Journals Connector (OSTI)

This paper examines through a thermodynamic analysis the feasibility of using waste heat from marine Diesel engines to drive an ammonia-water absorption refrigeration system. An energy balance of a diesel engine shows that sufficient waste heat is provided. The results illustrate that higher performance of the system is obtained at high generator and evaporator temperatures and also at low condenser and absorber temperatures.

Ahmed Ouadha; Youcef El-Gotni

2013-01-01T23:59:59.000Z

317

Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution  

E-Print Network (OSTI)

Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARp?) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution Benjamin Brant Sabine Brueske Donald Erickson Riyaz Papar Planetec Planetec Energy Concepts Company Energy... in Denver, Colorado. The Waste Heat Ammo nia Absorption Refrigeration Plant (WHAARP?) is based on a patented process and cycle design developed by Energy Concepts Co. (ECC) to cost effectively re cover 73,000 barrels a year of salable LPGs and gasoline...

Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

318

Evaluation of autotrophic growth of ammonia-oxidizers associated with granular activated carbon used for drinking water purification byDNA-stable isotope probing  

Science Journals Connector (OSTI)

Abstract Nitrification is an important biological function of granular activated carbon (GAC) used in advanced drinking water purification processes. Newly discovered ammonia-oxidizing archaea (AOA) have challenged the traditional understanding of ammonia oxidation, which considered ammonia-oxidizing bacteria (AOB) as the sole ammonia-oxidizers. Previous studies demonstrated the predominance of AOA on GAC, but the contributions of AOA and AOB to ammonia oxidation remain unclear. In the present study, DNA-stable isotope probing (DNA-SIP) was used to investigate the autotrophic growth of AOA and AOB associated with GAC at two different ammonium concentrations (0.14mgN/L and 1.4mgN/L). GAC samples collected from three full-scale drinking water purification plants in Tokyo, Japan, had different abundance of AOA and AOB. These samples were fed continuously with ammonium and 13C-bicarbonate for 14 days. The DNA-SIP analysis demonstrated that only AOA assimilated 13C-bicarbonate at low ammonium concentration, whereas AOA and AOB exhibited autotrophic growth at high ammonium concentration. This indicates that a lower ammonium concentration is preferable for AOA growth. Since AOA could not grow without ammonium, their autotrophic growth was coupled with ammonia oxidation. Overall, our results point towards an important role of AOA in nitrification in GAC filters treating low concentration of ammonium.

Jia Niu; Ikuro Kasuga; Futoshi Kurisu; Hiroaki Furumai; Takaaki Shigeeda

2013-01-01T23:59:59.000Z

319

Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [Os(III)(tpy)(Cl)(NH=CHCH3)(NSAr)  

SciTech Connect

Quantum mechanical analysis reveals that carbonyl reduction of aldehydes and ketones by the imine-based reductant cis-[Os{sup III}(tpy)(Cl)(NH?CHCH{sub 3})(NSAr)] (2), which is accessible by reduction of the analogous nitrile, occurs by hydride-proton transfer (HPT) involving both the imine and sulfilimido ligands. In carbonyl reduction, water or alcohol is necessary to significantly lower the barrier for proton shuttling between ligands. The ?N(H)SAr group activates the carbonyl group through hydrogen bonding while the ?NC(H)CH{sub 3} ligand delivers the hydride.

Ess, Daniel H.; Schauer, Cynthia; Meyer, Thomas J.

2010-01-01T23:59:59.000Z

320

Collision-induced desorption of ammonia chemisorbed on Pt^111: From direct measurement of the threshold energy to determination  

E-Print Network (OSTI)

metal surface by a beam of neutral, energetic Ar atoms. From direct measurement of the threshold energy for NH3 desorption at one-quarter of a monolayer coverage were measured for Ar beam energies up to 3 e surface well depth from a collision-induced desorption experiment is measurement of the threshold energy

Levis, Robert J.

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Production of silica aerogel microparticles loaded with ammonia borane by batch and semicontinuous supercritical drying techniques  

Science Journals Connector (OSTI)

Abstract Silica aerogel microparticles were prepared by supercritical drying and used as support for hydrogen-storing ammonia borane (AB). The formation of aerogel microparticles was done using two different processes: batch supercritical fluid extraction and a semicontinuous drying process. Silica aerogel microparticles with a surface area ranging from 400 to 800m2/g, a volume of pores of 1cm3/g, and a mean particle diameter ranging from 12 to 27?m were produced using the two drying techniques. The particle size distribution (PSD) of the microparticles was influenced by shear rate, amount of catalyst, hydrophilichydrophobic solvent ratio and hydrophobic surface modification. In particular, irregular aerogel particles were obtained from hydrophilic gels, while regular, spherical particles with smooth surfaces were obtained from hydrophobic gels. AB was loaded into silica aerogel microparticles in concentrations ranging from 1% till 5% wt. Hydrogen release kinetics from the hydride-loaded aerogel was analyzed with a volumetric cell at 80C. By stabilization of AB into the silica aerogel microparticles, an improvement of the release rate of hydrogen from AB was observed.

Miriam Rueda; Luis Miguel Sanz-Moral; Antonio Nieto-Mrquez; Pablo Longone; Facundo Mattea; ngel Martn

2014-01-01T23:59:59.000Z

322

Growth of InGaN HBTs by MOCVD THEODORE CHUNG,1,5  

E-Print Network (OSTI)

. Trimethylgallium (TMGa), trimethylindium (TMIn), and ammonia (NH3) are used as the sour- ces, while disilane (Si2H6

Asbeck, Peter M.

323

4D Density Determination of NH Radicals in an MSE Microplasma Combining Planar Laser Induced Fluorescence and Cavity Ring-Down Spectroscopy  

SciTech Connect

An application of microplasmas is surface modification under mild conditions and of small, well defined areas. For this, an understanding of the plasma composition is of importance. First results of our work on the production and detection of NH radicals in a capacitively coupled radio frequency (RF) microplasma are presented. A microstructured comb electrode was used to generate a glow discharge in a hydrogen/nitrogen gas mixture by applying 13.56 MHz RF voltage. The techniques of planar laser induced fluorescence (PLIF) and cavity ring-down spectroscopy (CRDS) are used for space and time resolved, quantitative detection of the NH radical in the plasma. The rotational temperature was determined to be 820 K and, the density 5.1x10{sup 12} cm{sup 3}. Also, time dependent behaviour of the NH production was observed.

Visser, Martin; Schenk, Andreas; Gericke, Karl-Heinz [Technische Universitaet Braunschweig, Institut fuer Physikalische und Theoretische Chemie Hans-Sommer-Str. 10, 38106 Braunschweig (Germany)

2010-10-13T23:59:59.000Z

324

Unusual defect physics in CH{sub 3}NH{sub 3}PbI{sub 3} perovskite solar cell absorber  

SciTech Connect

Thin-film solar cells based on Methylammonium triiodideplumbate (CH{sub 3}NH{sub 3}PbI{sub 3}) halide perovskites have recently shown remarkable performance. First-principle calculations show that CH{sub 3}NH{sub 3}PbI{sub 3} has unusual defect physics: (i) Different from common p-type thin-film solar cell absorbers, it exhibits flexible conductivity from good p-type, intrinsic to good n-type depending on the growth conditions; (ii) Dominant intrinsic defects create only shallow levels, which partially explain the long electron-hole diffusion length and high open-circuit voltage in solar cell. The unusual defect properties can be attributed to the strong Pb lone-pair s orbital and I p orbital antibonding coupling and the high ionicity of CH{sub 3}NH{sub 3}PbI{sub 3}.

Yin, Wan-Jian, E-mail: wanjian.yin@utoledo.edu; Shi, Tingting; Yan, Yanfa, E-mail: yanfa.yan@utoledo.edu [Department of Physics and Astronomy and Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606 (United States)

2014-02-10T23:59:59.000Z

325

INCOMPATIBLE CHEMICAL LIST PRUDENT PRACTICES FOR HANDLING CHEMICALS IN LABORATORIES  

E-Print Network (OSTI)

tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia (anhydrous) Mercury (in oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals, sulfur tetrachloride, carbon dioxide, water Potassium chlorate Sulfuric and other acids Potassium perchlorate (see also

Cho, Junghyun

326

CX-012111: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam CX(s) Applied: A9 Date: 05/06/2014 Location(s): California Offices(s): Golden Field Office

327

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH  

Gasoline and Diesel Fuel Update (EIA)

NOIlVUlSININdV NOIlVWdOdNI AOd3N3 NOIlVUlSININdV NOIlVWdOdNI AOd3N3 ACTO3NH 0661 This publication may be purchased from the Superintendent of Documents, U.S. Government Printing Office. Purchasing in formation for this or other Energy Information Administration (EIA) publications may be obtained from the Government Printing Office or ElA's National Energy Information Center. Questions on energy statistics should be directed to the Center by mail, telephone, or telecommunications device for the hearing impaired. Addresses, telephone numbers, and hours are as follows: National Energy Information Center Energy Information Administration Forrestal Building, Room 1F-048 Washington, DC 20585 (202) 586-8800 Telecommunications Device for the Hearing Impaired Only: (202) 586-1181 8 a.m. - 5 p.m., eastern time, M-F

328

nh Gi Thit Hi Ti Nguyn Thin Nhin ca V Trn Du Deepwater Horizon Cc D n Qun Franklin  

E-Print Network (OSTI)

Công Viên Bald Point Ca Tiu Bangc xut s xây dng các mái che cm tri, các li i lót ván, và mt nhà v sinh vi h thng x lý bng khí và bãi thi ti Công Viên Bald Point ca Tiu bang Alligator Point. Ngoài ra u xe kèm theo ti Cash Bayou. Xut Ci To Công Viên và Dc Th Thuyn Qun Franklin: D án Công Viên Indian

329

Kinetics of GaAs Dissolution in H2O2?NH4OH?H2O Solutions  

Science Journals Connector (OSTI)

Gallium arsenide and other group III?V semiconductors have found numerous applications in the electronics industry because of such characteristics as the direct band gap and higher electron mobility, which make them more suitable than silicon in the fabrication of optoelectronic and high-frequency devices. ... For example, the solubilities of both As2O3 and As2O5 in water increase between 15 and 40 C (Perry and Phillips, 1995), while Ga2O3 and Ga(OH)3 are insoluble in water and no data are available on the temperature dependence of their solubility at higher pH. ... Both Sheka et al. (1966) and Sidgwick (1950) confirm that gallium hydroxides are particularly soluble in NH4OH. ...

Christine Bryce; Dimitrios Berk

1996-12-04T23:59:59.000Z

330

Ammonia-Borane under High Pressure - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Jiuhua Chen (Primary Contact), Shah Najiba, Yongzhou Sun, Jennifer Girard, Vadym Drozd Center for the Study of Matters at Extreme Conditions Department of Mechanical and Materials Engineering Florida International University 11200 SW 8 th Street Miami, FL 33199 Phone: (305) 348-3140 Email: chenj@fiu.edu DOE Program Officer: Dr. Lane Wilson Phone: (301) 903-5877 Email: Lane.Wilson@science.doe.gov Subcontractor: Wendy Mao, Stanford University Objectives Understand pressure influence on the structure, phase * stability, dehydrogenation of ammonia borane and its

331

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling  

Energy.gov (U.S. Department of Energy (DOE))

A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO under various driving conditions.

332

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

333

Structure-Activity Relationships in NH3-SCR over Cu-SSZ-13 as Probed by Reaction Kinetics and EPR Studies  

SciTech Connect

Cu-SSZ-13 catalysts with various Cu loadings were prepared via solution ion exchange. The hydrated samples were studied with Electron Paramagnetic Resonance (EPR). Cu2+ ion coordination numbers were obtained by analyzing the hyperfine structures while Cu-Cu distances were estimated from line broadening of the EPR features. By coupling EPR and temperature-programmed reduction (TPR) results, two Cu2+ ion locations were suggested. Standard and fast NH3-SCR, as well as non-selective NH3 oxidation reactions were carried out over these catalysts at high space velocities. For the SCR reaction, intra-particle diffusion limitation was found throughout the reaction temperatures investigated. Although clear structure-activity relationships cannot be derived, the reaction results allow for reactant diffusivities and Cu2+ ion locations to be estimated. The slower NH3 oxidation reaction, on the other hand, is kinetically limited at low temperatures, and, therefore, allows for a correlation between Cu2+ ion location and reaction kinetics to be made. Furthermore, the dynamic Cu2+ ion motion as a function of temperature could also be derived from the NH3 oxidation kinetics.

Gao, Feng; Walter, Eric D.; Karp, Eric M.; Luo, Jin-Yong; Tonkyn, Russell G.; Kwak, Ja Hun; Szanyi, Janos; Peden, Charles HF

2013-04-01T23:59:59.000Z

334

Phase Transformations of the Ternary System (NH4)2SO4-H2SO4-H2O and the Implications for Cirrus Cloud Formation  

E-Print Network (OSTI)

the presence of NH4 + ions in the aerosol of the upper troposphere. Low-temperature ternary phase diagrams distribution alters the cloud's radiative properties, persistence, and surface area available for heterogeneous radiation, which insulates or warms Earth, and scattering the sun's visible radiation upward, thus cooling

335

Detailed modeling and laser-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame  

E-Print Network (OSTI)

non-premixed methane/air flame John B. Bell, Marcus S. Day, Joseph F. Grcar Computing Sciences-induced fluorescence imaging of nitric oxide in a NH3-seeded non-premixed methane/air flame Abstract In this paper we study the formation of NO in laminar, nitrogen diluted methane diffusion flames that are seeded

Bell, John B.

336

Interactions of elevated CO2, NH3 and O3 on mycorrhizal infection, gas exchange and N metabolism in saplings of Scots pine  

Science Journals Connector (OSTI)

Four-year-old saplings of Scots pine (Pinus sylvestris) (L.) were exposed for 11 weeks in controlled-environment chambers to charcoad-filtered air, or to charcoal-filtered air supplemented with NH3 (40 ?g m?3), O

Marta Prez-Soba; Thomas A Dueck; Gigliola Puppi; Pieter J. C. Kuiper

1995-09-01T23:59:59.000Z

337

Inelastic Neutron Scattering Study of the Specific Features of the Phase Transitions in (NH4)2WO2F4  

SciTech Connect

Oxyfluoride (NH4)2WO2F4 has been studied by the inelastic neutron scattering method over a wide temperature range 10 300 K at two initial neutron energies of 15 and 60 meV. The role of tetrahedral ammonium groups in the mechanism of sequential phase transitions at T1 = 201 K and T2 = 160 K has been discussed.

Smirnov, Lev S [Alikhanov Institute for Theoretical and Experimental Physics, Moscow, Russia; Kolesnikov, Alexander I [ORNL; Flerov, I. N. [Kirensky Institute of Physics, Krasnoyarsk, Russia; Laptash, N. M. [Institute of Chemistry, Vladivostok, Russia

2009-01-01T23:59:59.000Z

338

Mixed quantum/classical investigation of the photodissociation of NH3,,A~ ... and a practical method for maintaining zero-point energy  

E-Print Network (OSTI)

with a classical mechanical treatment of nuclear motion on coupled potential-energy surfaces. Whereas older mixedMixed quantum/classical investigation of the photodissociation of NH3,,A~ ... and a practical method for maintaining zero-point energy in classical trajectories David Bonhommeaua and Donald G

Truhlar, Donald G

339

Thermochemistry of Lewis Adducts of BH3 and Nucleophilic Substitution of Triethylamine on NH3BH3 in Tetrahydrofuran  

SciTech Connect

The thermochemistry of the formation of Lewis adducts of BH3 in tetrahydrofuran (THF) solution and the gas phase and the kinetics of substitution on ammonia borane (AB) by triethylamine are reported. The dative bond energy of Lewis adducts were predicted using density functional theory at the B3LYP/DZVP2 and B3LYP/6-311+G** levels and correlated ab initio molecular orbital theories, including MP2, G3(MP2), and G3(MP2)B3LYP, and compared with available experimental data and CCSD(T)/CBS theory results. The analysis showed that the G3 methods using either the MP2 or B3LYP geometries reproduce the benchmark results usually to within ~1 kcal/mol. Energies calculated at the MP2/aug-cc-pVTZ level for geometries optimized at the B3LYP/DZVP2 or B3LYP/6-311+G** levels give dative bond energies 2-4 kcal/mol larger than benchmark values. The enthalpies for forming adducts in THF were determined by calorimetry and compared with the calculated energies for the gas phase reaction: THF:BH3 + L ? L:BH3 + THF. The formation of AB in THF was observed to yield significantly more heat than the reaction in gas phase, consistent with strong solvation of AB. Substitution of NEt3 on AB is an equilibrium process in THF solution (K ? 0.2 at 25 C). The reaction obeys a reversible bimolecular kinetic rate law with the Arrhenius parameters: log A = 14.7 1.1 and Ea = 28.1 1.5 kcal/mol. Simulation of the mechanism using the SM8 continuum solvation model shows the reaction most likely proceeds primarily by a classical SN2 mechanism. Pacific Northwest National Laboratory is operated by Battelle for the USDOE.

Potter, Robert G.; Camaioni, Donald M.; Vasiliu, Monica; Dixon, David A.

2010-11-15T23:59:59.000Z

340

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents (OSTI)

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

J. Phys.: Condens. Matter 11 (1999) 833845. Printed in the UK PII: S0953-8984(99)96581-5 Structural and magnetic properties of ammonia-nitrided  

E-Print Network (OSTI)

J. Phys.: Condens. Matter 11 (1999) 833­845. Printed in the UK PII: S0953-8984(99)96581-5 Structural and magnetic properties of ammonia-nitrided Y2Fe17 N X Shen, J I Budnick, W A Hines, Y D Zhang, D of Connecticut, Storrs, CT 06269, USA Department of Physics, College of the Holy Cross, Worcester, MA 01610, USA

Yang, De-Ping

342

Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts  

E-Print Network (OSTI)

The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow reactor was investigated...

Oh, Hyuk Jin

2004-09-30T23:59:59.000Z

343

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas  

Science Journals Connector (OSTI)

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas ... Solvents were dried under argon according to standard methods; n-pentane and toluene were stored over Na/K alloy, and diethyl ether and thf over potassium benzophenoate (residual water solubility in other solvents than thf. ...

Alexander Miehr; Mike R. Mattner; Roland A. Fischer

1996-04-16T23:59:59.000Z

344

Terahertz Vibration?Rotation?Tunneling Spectroscopy of the Ammonia Dimer. II. A?E States of an Out-of-Plane Vibration and an In-Plane Vibration  

Science Journals Connector (OSTI)

Terahertz Vibration?Rotation?Tunneling Spectroscopy of the Ammonia Dimer. ... In order to proceed toward the ultimate goal of determining an accurate intermolecular potential surface like what has been done for the water dimer, it is necessary to thoroughly characterize the intermolecular vibrations. ... The ab initio harmonic vibrational frequencies are known to be often too high for the weakly bound systems. ...

Wei Lin; Jia-xiang Han; Lynelle K. Takahashi; Jennifer G. Loeser; Richard J. Saykally

2007-09-07T23:59:59.000Z

345

Cost and Performance Baseline for Fossil Energy Plants Volume 2: Coal to Synthetic Natural Gas and Ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

Cost and Performance Cost and Performance Baseline for Fossil Energy Plants Volume 2: Coal to Synthetic Natural Gas and Ammonia July 5, 2011 DOE/NETL- 2010/1402 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or

346

Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia  

SciTech Connect

Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

NONE

1995-09-01T23:59:59.000Z

347

Frequency stabilization of 1. 5-. mu. m InGaAsP distributed feedback laser to NH/sub 3/ absorption lines  

SciTech Connect

NH/sub 3/ absorption lines due to vibration-rotation transitions are observed at 1.50--1.54 ..mu..m by using an InGaAsP superluminescent diode. A 1.5-..mu..m InGaAsP distributed feedback (DFB) laser is frequency stabilized to an NH/sub 3/ linear absorption line at 15196 A. Frequency stability of sigma(2,tau) = 8 x 10/sup -11/tau/sup -1/ is achieved for an averaging time range of 10 ms< or =tau< or =1 s. Such an absolute frequency-stabilized DFB laser is useful for coherent optical system applications, since it is free from the longitudinal mode jumping which results from a wide range of temperature changes and long-term device degradation.

Yanagawa, T.; Saito, S.; Yamamoto, Y.

1984-10-15T23:59:59.000Z

348

Phase transitions in C2O4H NH4 1/2H2O : a light scattering study of the high pressure phase  

E-Print Network (OSTI)

1711 Phase transitions in C2O4H NH4 1/2H2O : a light scattering study of the high pressure phase J) Résumé. 2014 AHO présente, à la pression ordinaire, une transition de phase ferroélastique du deuxième phase III soit, comme la phase II, due à une mise en ordre des ions ammoniums : leur orientation serait

Paris-Sud XI, Université de

349

Hydrothermal synthesis and structure of an open framework Co0.7Zn1.3(PO4)2(NH3CH2CH2NH3) and Co6.2(OH)4(PO4)4Zn1.80, a new adamite type phase  

Science Journals Connector (OSTI)

The hydrothermal reaction of cobalt(II)oxalate di-hydrate, zinc oxide, and triethyl-orthophosphate, using 1,2-diaminoethane as structure directing template in water, produced two major crystal phases in almost equal amount: the purple crystals of [NH3CH2CH2NH3][Co0.7Zn1.3(PO4)2] (1) and the red burgundy crystals of Co6.2(OH)4(PO4)4Zn1.80 (2), a new adamite type phase. The structure of [NH3CH2CH2NH3] [Co0.7Zn1.3(PO4)2] (1) exhibits a 3D open framework built from PO4 and (Co/Zn)O4 tetrahedra, and (Co/Zn)O5 trigonal bipyramids, forming two major channels, an 8-membered ring channel and a 16-membered ring channel, that host the ethanediammonium ions. The Co6.2(OH)4(PO4)4Zn1.80 (2) is isomorphous with adamite-type M2(OH)XO4 structure, with a condensed vertex and edge sharing network of (Co/Zn)O5, and distorted CoO6, and PO4 subunits. The cobalt preference for higher coordination numbers is displayed in this structure, where the octahedral sites are wholly occupied by cobalt. Thermal analysis confirmed that these compounds display high thermal stability.

Aderemi Oki; Matthias Zeller; Yaneth Coranza; Jose Luevano; Allen D. Hunter

2007-01-01T23:59:59.000Z

350

THE c2d SPITZER SPECTROSCOPIC SURVEY OF ICES AROUND LOW-MASS YOUNG STELLAR OBJECTS. IV. NH{sub 3} AND CH{sub 3}OH  

SciTech Connect

NH{sub 3} and CH{sub 3}OH are key molecules in astrochemical networks leading to the formation of more complex N- and O-bearing molecules, such as CH{sub 3}CN and CH{sub 3}OCH{sub 3}. Despite a number of recent studies, little is known about their abundances in the solid state. This is particularly the case for low-mass protostars, for which only the launch of the Spitzer Space Telescope has permitted high-sensitivity observations of the ices around these objects. In this work, we investigate the {approx}8-10 {mu}m region in the Spitzer IRS (InfraRed Spectrograph) spectra of 41 low-mass young stellar objects (YSOs). These data are part of a survey of interstellar ices in a sample of low-mass YSOs studied in earlier papers in this series. We used both an empirical and a local continuum method to correct for the contribution from the 10 {mu}m silicate absorption in the recorded spectra. In addition, we conducted a systematic laboratory study of NH{sub 3}- and CH{sub 3}OH-containing ices to help interpret the astronomical spectra. We clearly detect a feature at {approx}9 {mu}m in 24 low-mass YSOs. Within the uncertainty in continuum determination, we identify this feature with the NH{sub 3} {nu}{sub 2} umbrella mode and derive abundances with respect to water between {approx}2% and 15%. Simultaneously, we also revisited the case of CH{sub 3}OH ice by studying the {nu}{sub 4} C-O stretch mode of this molecule at {approx}9.7 {mu}m in 16 objects, yielding abundances consistent with those derived by Boogert et al. based on a simultaneous 9.75 and 3.53 {mu}m data analysis. Our study indicates that NH{sub 3} is present primarily in H{sub 2}O-rich ices, but that in some cases, such ices are insufficient to explain the observed narrow FWHM. The laboratory data point to CH{sub 3}OH being in an almost pure methanol ice, or mixed mainly with CO or CO{sub 2}, consistent with its formation through hydrogenation on grains. Finally, we use our derived NH{sub 3} abundances in combination with previously published abundances of other solid N-bearing species to find that up to 10%-20% of nitrogen is locked up in known ices.

Bottinelli, Sandrine; Van Dishoeck, Ewine F.; Lahuis, Fred [Leiden Observatory, Leiden University, P.O. Box 9513, NL 2300 RA Leiden (Netherlands); Boogert, A. C. Adwin [IPAC, NASA Herschel Science Center, Mail Code 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Bouwman, Jordy; Beckwith, Martha; Oeberg, Karin I.; Linnartz, Harold [Raymond and Beverly Sackler Laboratory for Astrophysics, Leiden Observatory, Leiden University, P.O. Box 9513, NL 2300 RA Leiden (Netherlands); Pontoppidan, Klaus M.; Blake, Geoffrey A. [California Institute of Technology, Division of Geological and Planetary Sciences, Pasadena, CA 91125 (United States); Evans, Neal J., E-mail: sandrine.bottinelli@cesr.f [Department of Astronomy, University of Texas at Austin, 1 University Station C1400, Austin, TX 78712-0259 (United States)

2010-08-01T23:59:59.000Z

351

Iron oxide and chromia supported on titania-pillared clay for selective catalytic reduction of nitric oxide with ammonia  

SciTech Connect

TiO{sub 2}-pillard clay (PILC) with high surface area, large pore volume, and large interlayer spacing was used as the support for mixed Fe{sub 2}O{sub 3} and Cr{sub 2}O{sub 3} as the catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3}. The Fe/Cr ratio was varied at a fixed total amount of oxide dopant of 10% (wt). The Fe-Cr/TiO{sub 2}-PILC with Fe/Cr=3 showed the highest activity. Compared with commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts, the activity (on a per gram basis) of the doped pillared clay was approximately twice as high under H{sub 2}O- and SO{sub 2}-free conditions and was approximately 40% higher under conditions with H{sub 2}O and SO{sub 2}. In addition, its activity for SO{sub 2} oxidation was only 20%-25% of that of the V{sub 2}O{sub 5}-based catalysts. TPD of NH{sub 3} on the Fe-Cr/TiO{sub 2}-PILC catalyst showed that both M=O and M-OH (M=Fe or Cr) were necessary for the SCR reaction. In situ IR spectra of NH{sub 3} showed that there was a higher Bronsted acidity than the Lewis acidity on the surface under reaction conditions and that there existed a direct correlation between the SCR activity and the Bronsted acidity among pillared clays with different Fe/Cr ratios. These results, along with the transient response to O{sub 2}, indicated that a similar mechanism to that on the V{sub 2}O{sub 5} catalyst was operative. The TiO{sub 2}-pillared clay used as the support also contributed to the high activity of the Fe-Cr catalyst. The TiO{sub 2} pillars combined with the tetrahedral SiO{sub 2} surfaces of the clay apparently gave rise to a high dispersion of Fe{sub 2}O{sub 3}. 52 refs., 10 figs., 5 tabs.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States)] [State Univ. of New York, Buffalo, NY (United States); Ning Chen [Univ. of Michigan, Ann Arbor, MI (United States)] [Univ. of Michigan, Ann Arbor, MI (United States)

1996-11-01T23:59:59.000Z

352

Sorption of carboxylic acid from carboxylic salt solutions at pHs close to or above the pK[sub a] of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents (OSTI)

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH[sub a] into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. The acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carboxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia. 8 figs.

King, C.J.; Tung, L.A.

1992-07-21T23:59:59.000Z

353

Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents (OSTI)

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.

King, C. Judson (Kensington, CA); Tung, Lisa A. (El Cerrito, CA)

1992-01-01T23:59:59.000Z

354

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

355

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1993-01-04T23:59:59.000Z

356

Recovery and removal of ammonianitrogen and phosphate from swine wastewater by internal recycling of struvite chlorination product  

Science Journals Connector (OSTI)

Abstract The recovery of the total orthophosphate (PT) and removal of the total ammonianitrogen (TAN) from swine wastewater were investigated through a combined technology of using bittern as the magnesium source in struvite precipitation along with internal recycling of the chlorination product of the recovered struvite. Results revealed that the PT recovery efficiency and the struvite purity was mainly depended on the wastewater pH and the Mg:PT molar ratio. Co-precipitations of Mg3(PO4)2, MgKPO4, Ca3(PO4)2, and Mg(OH)2 (pH>9) were confirmed to be responsible for the decrease in the purity of struvite. The decomposition of recovered struvite by sodium hypochlorite (NaClO) was feasible. The TAN concentration of the swine wastewater was decreased to 63mg/L by internal recycling of the chlorination decomposition product for seven cycles. An economic evaluation showed that 37% of the treatment cost of the proposed process could be saved as compared with struvite precipitation using pure chemicals.

Haiming Huang; Jiang Yang; Ding Li

2014-01-01T23:59:59.000Z

357

Mitigation of Hydrogen Capacity Losses during Pressure Cycling of the Li3NH System by the Addition of Nitrogen  

Science Journals Connector (OSTI)

Mitigation of Hydrogen Capacity Losses during Pressure Cycling of the Li3NH System by the Addition of Nitrogen ... We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (?Go = ?98.7 kJ/mol) is more negative than that of LiH (?Go = ?50.3 ... This triggered intensive research on hydrogen as a renewable fuel because the exhaust gases in hydrogen-powered vehicles mainly contain water vapor. ...

Joshua Lamb; Dhanesh Chandra; Wen-Ming Chien; Delphine Phanon; Nicolas Penin; Radovan C?erny?; Klaus Yvon

2011-06-13T23:59:59.000Z

358

Frequency stabilization of an InGaAsP distributed feedback laser to an NH/sub 3/ absorption line at 15137 A with an external frequency modulator  

SciTech Connect

The oscillation frequency of a 1.5-..mu..m InGaAsP distributed feedback laser is stabilized to an NH/sub 3/ linear absorption line at 15137 A. A LiNbO/sub 3/ external frequency modulator is used instead of direct frequency modulation of the laser to extract error signals. An effective bandwidth of 100 kHz for the feedback loop is obtained through this external modulation scheme. Frequency stability of sigma(2,tau) = 4 x 10/sup -11/ is achieved for an averaging time of 1 s< or =tau< or =100 s.

Yanagawa, T.; Saito, S.; Machida, S.; Yamamoto, Y.; Noguchi, Y.

1985-11-15T23:59:59.000Z

359

Critical properties at the field-induced Bose-Einstein condensation on NiCl2-4SC(NH2)2  

SciTech Connect

We report new magnetization measurements on the spin-gap compound NiCl{sub 2}-4SC(NH{sub 2}){sub 2} at the low-field boundary of the magnetic field induced ordering. The critical density of the magnetization is analyzed in terms of a Bose-Einstein condensation (BEC) of bosonic quasiparticles. The analysis of the magnetization at the transition leads to the conclusion for the preservation of the U(1) symmetry, as required for BEC. The experimental data are well described by quantum Monte Carlo simulations.

Sengupta, Pinaki [Los Alamos National Laboratory; Al-hassenieh, Khaled A [Los Alamos National Laboratory; Jaime, Macelo [Los Alamos National Laboratory; Paduan-filho, Armando [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

360

Characteristics of vanadia on the surface of V2O5/Ti-PILC catalyst for the reduction of \\{NOx\\} by NH3  

Science Journals Connector (OSTI)

A series of vanadia catalysts impregnated on titania pillared interlayered clays (Ti-PILCs) were prepared to identify the characteristics of vanadia on the surface of Ti-PILC for the selective catalytic reduction (SCR) of NO by NH3. V2O5/Ti-PILC exhibited superior performance as a novel SCR catalyst compared to conventional catalysts including V2O5/TiO2 and V2O5/Al2O3. NO removal activity over the supported vanadia catalyst is strongly influenced by the structure of vanadia species on the catalyst surface. The structure of vanadia species on various supports including TiO2, Al2O3, and SiO2 along with Ti-PILC has been examined by XRD, NMR and Raman analyses for the comparative study. Increasing the content of vanadia up to the monolayer coverage of the surface of Ti-PILC catalyst enhanced the ratio of the polymerized surface vanadia species to the isolated ones. These results are well correlated with TOF of vanadia on the catalyst surface for the reduction of NO by NH3.

Ho Jeong Chae; In-Sik Nam; Sung-Won Ham; Suk Bong Hong

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Comparison of the efficiency of N2 and NH3 plasma treatments to improve the adhesion of PP films to in situ deposited Al coatings. Study of ageing phenomena in terms of acid-base properties  

Science Journals Connector (OSTI)

This paper reports on the characteristics of polypropylene (PP) treated at two different frequencies, 70 kHz and 13.56 MHz, in two plasma atmospheres, NH3 and N2 plasmas. Chemical modifications created on the plasma-treated material were investigated by different complementary surface analytical techniques (X-ray photoelectron spectroscopy (XPS) and contact angle measurements), which revealed a higher reactivity of the NH3 plasma. The incorporation of nitrogen plays an important role as revealed by the adhesion study of thermally evaporated aluminium with treated PP: the measured peel strengths were two times higher for NH3-treated surfaces than for N2-treated ones, with XPS measurements showing a sharper increase of N/C ratio as a function of treatment time for the former treatment. Ageing of the PP pretreated in NH3 was also studied in terms of surface acid-base properties. The work of adhesion, calculated from contact angle measurements, showed a distinct dependence on the pH value of the test liquids and good correlations were obtained with peel test results. The basic character of the NH3-treated PP disappears with ageing, leading to an amphoteric surface.

M. Tatoulian; F. Arefi-Khonsari; N. Shahidzadeh-Ahmadi; J. Amouroux

1995-01-01T23:59:59.000Z

362

METALLICITIES, DUST, AND MOLECULAR CONTENT OF A QSO-DAMPED Ly{alpha} SYSTEM REACHING log N(H I) = 22: AN ANALOG TO GRB-DLAs  

SciTech Connect

We present the elemental abundance and H{sub 2} content measurements of a damped Ly{alpha} (DLA) system with an extremely large H I column density, log N(H I) (cm{sup -2}) = 22.0 {+-} 0.10, at z{sub abs} = 3.287 toward the QSO SDSS J081634+144612. We measure column densities of H{sub 2}, C I, C I*, Zn II, Fe II, Cr II, Ni II, and Si II from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 {+-} 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of Almost-Equal-To 52 km s{sup -1}) in rotational levels up to J = 3. We derive a total H{sub 2} column density of log N(H{sub 2}) (cm{sup -2}) = 18.66 and a mean molecular fraction of f = 2N(H{sub 2})/[2N(H{sub 2}) + N(H I)] = 10{sup -3.04{+-}0.37}, typical of known H{sub 2}-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the interstellar medium of this galaxy, with an enhanced abundance in the H{sub 2}-bearing clouds. However, the total amount of dust along the line of sight is not large and does not produce any significant reddening of the background QSO. The physical conditions in the H{sub 2}-bearing clouds are constrained directly from the column densities of H{sub 2} in different rotational levels, C I and C I*. The kinetic temperature is found to be T Almost-Equal-To 75 K and the particle density lies in the range n{sub H} = 50-80 cm{sup -3}. The neutral hydrogen column density of this DLA is similar to the mean H I column density of DLAs observed at the redshift of {gamma}-ray bursts (GRBs). We explore the relationship between GRB-DLAs and the high column density end of QSO-DLAs finding that the properties (metallicity and depletion) of DLAs with log N(H I) > 21.5 in the two populations do not appear to be significantly different.

Guimaraes, R. [Programa de Modelagem Computacional-SENAI-Cimatec, 41650-010 Salvador, Bahia (Brazil); Noterdaeme, P.; Petitjean, P. [UPMC-CNRS, UMR7095, Institut d'Astrophysique de Paris, 98bis Blvd. Arago, F-75014 Paris (France); Ledoux, C. [European Southern Observatory, Alonso de Cordova 3107, Casilla 19001, Vitacura, Santiago 19 (Chile); Srianand, R.; Rahmani, H. [Inter-University Centre for Astronomy and Astrophysics, Post Bag 4, Ganeshkhind, Pune 411007 (India); Lopez, S., E-mail: rguimara@eso.org [Departamento de Astronomia, Universidad de Chile, Casilla 36-D, Santiago (Chile)

2012-06-15T23:59:59.000Z

363

Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1  

SciTech Connect

Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

1992-06-10T23:59:59.000Z

364

Tiu Ch Chn La D n Khi Phc Sm Vo ngy 21 thng 4 nm 2011, cc y Vin nh Gi Tn Hi  

E-Print Network (OSTI)

con ngi bng cách khôi phc, phc hi môi trng sng, thay th, hoc thu gom mt lng tng ng vi ngun tài nguyên thiên nhiên có cht lng, giá tr sinh thái hoc dân dng tng ng n bù các tài nguyên và dch v b tn hi t s c, nhng vn c chp nhn và hu ích giúp sàng lc mt s lng ln các d án có tim nng. Không mt yu t nào c s dng nh

365

Techno-economic evaluation of an ammonia-based post-combustion process integrated with a state-of-the-art coal-fired power plant  

Science Journals Connector (OSTI)

Abstract A techno-economic evaluation of the application of an ammonia-based post-combustion CO2 capture system to an existing, state-of-the-art, coal-fired power plant. The study comprised an assessment of the ammonia-based capture process together with a detailed cost analysis, based on which the overall design of the capture process is presented, including a power plant integration strategy and estimates of the specific CO2 capture cost (/tCO2). The evaluations of the power plant and the CO2 capture plant were based on process modeling. The cost analysis was based on the installed cost of each unit in the equipment list derived from the process simulation, which was determined using detailed-factor estimation. We show that the steam required for a CO2 capture efficiency of 90% lowers the electric output from 408.0MWel to 341.8MWel. The capital expenditure related to the retrofit of the reference power plant with CO2 capture is 230M and the operating expenditure is determined to be 66.5M/year, corresponding to a relative capture cost of 35/tCO2. Furthermore, the present work proposes design improvements that may reduce the cost of capture to 31/tCO2.

Henrik Jilvero; Nils-Henrik Eldrup; Fredrik Normann; Klas Andersson; Filip Johnsson; Ragnhild Skagestad

2014-01-01T23:59:59.000Z

366

GREEN BANK TELESCOPE OBSERVATIONS OF THE NH{sub 3} (3, 3) AND (6, 6) TRANSITIONS TOWARD SAGITTARIUS A MOLECULAR CLOUDS  

SciTech Connect

Ammonia (3, 3) and (6, 6) transitions have been observed using the Green Bank Telescope toward the Sgr A region. The gas is mainly concentrated in 50 km s{sup -1} and 20 km s{sup -1} clouds located in a plane inclined to the galactic plane. These 'main' clouds appear to be virialized and influenced by the expansion of the supernova remnant Sgr A East. The observed emission shows very complicated features in the morphology and velocity structure. Gaussian multi-component fittings of the observed spectra revealed that various 'streaming' gas components exist all over the observed region. These components include those previously known as 'streamers' and 'ridges', but most of these components appear not to be directly connected to the major gas condensations (the 50 km s{sup -1} and 20 km s{sup -1} clouds). They are apparently located out of the galactic plane, and they may have a different origin than the major gas condensations. Some of the streaming components are expected to be sources that feed the circumnuclear disk of our Galactic center directly and episodically. They may also evolve differently than major gas condensations under the influence of the activities of the Galactic center.

Minh, Young Chol [Korea Astronomy and Space Science Institute, Daeduk-daero 776, Yuseong, Daejeon 305-348 (Korea, Republic of); Liu, Hauyu Baobab; Ho, Paul T. P.; Hsieh, Pei-Ying; Su, Yu-Nung [Institute of Astronomy and Astrophysics, Academia Sinica, P.O. Box 23-141, Taipei 10617, Taiwan (China); Kim, Sungsoo S. [Department of Astronomy and Space Science, Kyung Hee University, Yongin, Kyungki-do 446-701 (Korea, Republic of); Wright, Melvyn [Radio Astronomy Laboratory, University of California, Berkeley, 601 Campbell Hall, Berkeley, CA 94720 (United States)

2013-08-10T23:59:59.000Z

367

Zeolite?Based Algae Biofilm Rotating Photobioreactor for Algae and Biomass Production.  

E-Print Network (OSTI)

?? Alkaline conditions induced by algae growth in wastewater stabilization ponds create deprotonated ammonium ions that result in ammonia gas (NH3) volatilization. If algae are (more)

Young, Ashton M.

2011-01-01T23:59:59.000Z

368

Polyaniline Nanothin Film Chemiresistive Gas Sensors  

E-Print Network (OSTI)

for monitoring ozone and nitrogen dioxide. Analytica ChimicaNH 3 ) [2], nitrogen dioxide (NO 2 ) [3], hydrogen (H 2 ) [work include ammonia, nitrogen dioxide, formaldehyde, carbon

Srinives, Sira

2012-01-01T23:59:59.000Z

369

Experimental and Theoretical EPR Study of Jahn?Teller-Active [HIPTN[subscript 3]N]MoL Complexes (L = N[subscript 2], CO, NH[subscript 3])  

E-Print Network (OSTI)

The trigonally symmetric Mo(III) coordination compounds [HIPTN[subscript 3]N]MoL (L = N[subscript 2], CO, NH[subscript 3]; [HIPTN3N]Mo = [(3,5-(2,4,6-i-Pr[subscript 3]C[subscript 6]H[subscript 2])[subscript 2]C[subscript ...

McNaughton, Rebecca L.

370

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman, Gary Bishop, Allison Peddle, University of Denver Department of Chemistry and Biochemistry Denver CO 80208. www.feat.biochem.du.edu  

E-Print Network (OSTI)

On-Road Motor Vehicle Emissions including Ammonia, Sulfur Dioxide and Nitrogen Dioxide Don Stedman Nitrogen dioxide: Less than 5% of the NOx BUT with an outstanding peak for the 2007 MY in Fresno 0. Nitrogen dioxide: less than 5% of NOx except the Fresno fleet containing the 2007 Sprinter ambulances. #12;

Denver, University of

371

Increasing cellulose accessibility is more important than removing lignin: A comparison of cellulose solventbased lignocellulose fractionation and soaking in aqueous ammonia  

NLE Websites -- All DOE Office Websites (Extended Search)

Increasing Increasing Cellulose Accessibility Is More Important Than Removing Lignin: A Comparison of Cellulose Solvent-Based Lignocellulose Fractionation and Soaking in Aqueous Ammonia Joseph A. Rollin, 1 Zhiguang Zhu, 1 Noppadon Sathitsuksanoh, 1,2 Y.-H. Percival Zhang 1,2,3 1 Biological Systems Engineering Department, Virginia Polytechnic Institute and State University, 210-A Seitz Hall, Blacksburg, Virginia 24061; telephone: 1-540-231-7414; fax: þ1- 540-231-3199; e-mail: ypzhang@vt.edu 2 Institute for Critical Technology and Applied Sciences (ICTAS), Virginia Polytechnic Institute and State University, Blacksburg, Virginia 3 DOE BioEnergy Science Center (BESC), Oak Ridge, Tennessee Received 18 May 2010; revision received 11 August 2010; accepted 17 August 2010 Published online 1 September 2010 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/bit.22919

372

Production of elemental sulfur and ammonium thiosulfate by the oxidation of H2S containing water vapor and ammonia over V/Zr-PILC catalysts  

Science Journals Connector (OSTI)

The catalytic oxidation of hydrogen sulfide in the presence of water and ammonia was studied over V2O5 supported on Zr-pillared clay catalysts (V/Zr-PILCs). The synthesized catalysts were examined using a variety of characterization techniques. A catalytic performance study using V/Zr-PILC catalysts showed that H2S was successfully converted to elemental sulfur and ammonium thiosulfate (ATS) without considerable emission of sulfur dioxide. The H2S conversion over V/Zr-PILCs increased with increasing the content of vanadia up to 6wt.%. This superior catalytic performance might be related to the uniform dispersion of vanadia species on the Zr-PILC support.

Kanattukara Vijayan Bineesh; Moon-il Kim; Goo-Hwa Lee; Manickam Selvaraj; Kyu Hyun; Dae-Won Park

2012-01-01T23:59:59.000Z

373

Application of x-ray tomography to optimization of new NOx/NH3 mixed potential sensors for vehicle on-board emissions control  

SciTech Connect

Mixed potential sensors for the detection of hydrocarbons, NO{sub x}, and NH{sub 3} have been previously developed at Los Alamos National Laboratory (LANL). The LANL sensors have a unique design incorporating dense ceramic-pelletlmetal-wire electrodes and porous electrolytes. The performance of current-biased sensors using an yttria-stabilized zirconia (YSZ) electrolyte and platinum and La{sub 0.8}Sr{sub 0.2}CrO{sub 3} electrodes is reported. X-ray tomography has been applied to non-destructively examine internal structures of these sensors. NO{sub x} and hydrocarbon response of the sensors under various bias conditions is reported, and very little NO{sub x} response hysteresis was observed. The application of a 0.6 {mu}A bias to these sensors shifts the response from a hydrocarbon response to a NO{sub x} response equal for both NO and NO{sub 2} species at approximately 500 {sup o}C in air.

Nelson, Mark A [Los Alamos National Laboratory; Brosha, Eric L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Garzon, Fernando H [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

374

The Surface Texturing of Monocrystalline Silicon with NH4OH and Ion Implantation for Applications in Solar Cells Compatible with CMOS Technology  

Science Journals Connector (OSTI)

Abstract This work presents the development of photovoltaic cells based on p+/n junction in Si substrates, aimed at compatibility with fabrication processes with CMOS technology. The compatible processes, which are developed in this study, are the techniques: i) Si surface texturing, with the textured surface reflection of 15% obtained by the formation of micro-pyramids (heights between 3 and 7?m) using NH4OH (ammonium hydroxide) alkaline solution, which is free of undesirable contamination by Na+ and K+ ions, when NaOH and KOH traditional solutions are used, respectively, and ii) of the ECR-CVD (Electron Cyclotron Resonance - Chemical Vapor Deposition) deposition of SiNx (silicon nitride) anti-reflective coating (ARC), which is carried out at room temperature and can be performed after the end of cell fabrication without damage on metallic tracks and without variation of p+/n junction depth. The ARC coating characterization presented that the silicon nitride has a refractive index of 1.92 and a minimum reflectance of 1.03%, which is an excellent result for application in solar (or photovoltaic) cells. For the formation of the pn junction was used ion implantation process with 11B+, E=20KeV, dose of 1x1015cm2 and four rotations of 90 to get uniformity on texturized surfaces.

A.R. Silva; J. Miyoshi; J.A. Diniz; I. Doi; J. Godoy

2014-01-01T23:59:59.000Z

375

A photoemission study of Au, Ge, and O{sub 2} deposition on NH{sub 4}F etched Si(111)  

SciTech Connect

We have studied the interaction of a metal, Au, a semiconductor, Ge, and a non-metal, O{sub 2}, with the NH{sub 4}F etched Si(111) surface with photoemission spectroscopy. Two components were present in Si 2p core level spectra from the H-terminated surface. We observed the flat band condition from the as-etched, n-type, Si(111) surface. We performed stepwise depositions of Au and measured the band bending with photoemission spectroscopy. The Fermi level pinned near mid-gap as Au was deposited onto the as-etched surface. After the deposition of 1 ML of Au, a Au-silicide layer formed. This interfacial component indicated that the passivating H layer was compromised. As the Au coverage was increased, layers of pure Au formed between the bulk silicon and the Au-silicide layer. The observed behavior was nearly identical to that of Au deposition on the Si(111) 7 {times} 7 surface. Next, we tested the ability of the monohydride layer to sustain surfactant assisted growth of Ge. Ge islanding was observed at 400{degree}C indicating that good surfactant growth was not obtained. Although the monohydride layer was not a good surfactant for the Si(111) surface at this temperature, further study at different temperatures is needed to determine the ability of the ideal monohydride layer to act as a surfactant. Finally, we observed no oxidation of the as-etched surface at room temperature upon exposure to molecular oxygen.

Terry, J.; Cao, R.; Wigren, C.; Pianetta, P.

1994-03-01T23:59:59.000Z

376

Thermochemical treatments based on NH3/O2 for improved graphite-based fiber electrodes in vanadium redox flow batteries  

Science Journals Connector (OSTI)

Abstract Electrochemical behavior of the polyacrylonitrile (PAN)-based graphite as a low cost electrode material for vanadium based redox batteries (VFB) in sulfuric acid medium has been improved by means of the successful introduction of nitrogen and oxygen-containing groups at the graphite surface by thermal activation under NH3/O2 (1:1) atmosphere. Influence of the temperature and treatment duration times have been studied towards the positive reaction of VFB. The structure, composition, and electrochemical properties of the treated samples have been characterized with field emission scanning electron microscopy, X-ray photoelectron spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy. The estimation of electrochemical surface area has also been evaluated. The treatment of PAN graphite material at 773K for 24-h leads to electrode materials with the best electrochemical activity towards the VO 2 + /VO2+ redox couple. This method produces an increase of the nitrogen and oxygen content at the surface up to 8% and 32%, respectively, and is proved to be a straightforward and cost-effective methodology. This improvement of the electrochemical properties is attributed to the incorporation of the nitrogen and oxygen-containing groups that facilitate the electron transfer through the electrode/electrolyte interface for both oxidation and reduction processes.

Cristina Flox; Javier Rubio-Garca; Marcel Skoumal; Teresa Andreu; Juan Ramn Morante

2013-01-01T23:59:59.000Z

377

Ab initio potential energy surfaces for NH,,3 -...NH,,3 -  

E-Print Network (OSTI)

.1063/1.3268920 I. INTRODUCTION The field of cold T 1 K and ultracold 1 mK molecules has attracted great interest in the last few years. The production of such ultra cold species may find impor- tant applications,11 There are, in principle, two different strate- gies for producing molecular samples at ultra low tempera

378

NH_50m_Wind  

NLE Websites -- All DOE Office Websites (Extended Search)

Metadata also available as Metadata: IdentificationInformation DataQualityInformation SpatialDataOrganizationInformation SpatialReferenceInformation EntityandAttributeI...

379

Radiochemical investigations of 177Lu-DOTA-8-Aoc-BBN[7-14]NH2: an in vitro/in vivo assessment of the targeting ability of this new radiopharmaceutical for PC-3 human prostate cancer cells  

Science Journals Connector (OSTI)

Bombesin (BBN), a 14 amino acid peptide, is an analogue of human gastrin releasing peptide (GRP) that binds to GRP receptors (GRPr) with high affinity and specificity. The \\{GRPr\\} is over expressed on a variety of human cancer cells including prostate, breast, lung, and pancreatic cancers. The specific aim of this study was to identify a BBN analogue that can be radiolabeled with 177Lu and maintains high specificity for \\{GRPr\\} positive prostate cancer tumors in vivo. A preselected synthetic sequence via solid phase peptide synthesis (SPPS) was designed to produce a DOTA-BBN (DOTA = 1,4,7,10-tetraazacyclododecane-N,N?,N??,N???-tetraacetic acid) conjugate with the following general structure: DOTA-X-Q-W-A-V-G-H-L-M-(NH2), where the spacer group, X = ?-NH2(CH2)7COOH (8-Aoc). The BBN-construct was purified by reversed phase-HPLC (RP-HPLC). Electrospray Mass Spectrometry (ES-MS) was used to characterize both metallated and non-metallated BBN-conjugates. The new DOTA-conjugate was metallated with 177Lu(III)Cl3 or non-radioactive Lu(III)Cl3. The 177Lu(III)- and non-radiolabeled Lu(III)-conjugates exhibit the same retention times under identical RP-HPLC conditions. The 177Lu-DOTA-8-Aoc-BBN[7-14]NH2 conjugate was found to exhibit optimal pharmacokinetic properties in CF-1 normal mice. In vitro and in vivo models demonstrated the ability of the 177Lu-DOTA-8-Aoc-BBN[7-14]NH2 conjugate to specifically target GRP receptors expressed on PC-3 human prostate cancer cells.

C.Jeffrey Smith; Hariprasad Gali; Gary L. Sieckman; Donald L. Hayes; Nellie K. Owen; Dana G. Mazuru; Wynn A. Volkert; Timothy J. Hoffman

2003-01-01T23:59:59.000Z

380

Synthesis of HA-Seeded TTCP (Ca4(PO4)2O) Powders at 12301C from Ca(CH3COO)2 . H2O and NH4H2PO4  

E-Print Network (OSTI)

Synthesis of HA-Seeded TTCP (Ca4(PO4)2O) Powders at 12301C from Ca(CH3COO)2 . H2O and NH4H2PO4 University, Clemson, South Carolina 29634 Tetracalcium phosphate (TTCP) Ca4(PO4)2O is one of the major powder- state process by soaking Ca- and P-containing precursors be- tween 13501 and 15001C. Such procedures

Tas, A. Cuneyt

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381

Refinement of the crystal structure of the high-temperature phase G0 in (NH4)2WO2F4 (powder, x-ray, and neutron scattering)  

SciTech Connect

The (NH4)2WO2F4 compound undergoes a series of phase transitions: G0 -> 201 K -> G1 -> 160 K -> G2, with a significant change in entropy ( S1 ~ Rln10 at the G0 -> G1 transition), which indicates significant orientational disordering in the G0 phase and the order disorder type of the phase transition. X-ray diffraction is used to identify the crystal structure of the G0 phase as rhombohedral (sp. gr. Cmcm, Z = 4), determine the lattice parameters and the positions of all atoms (except hydrogen), and show that [WO2F4]2 ions can form a superposition of dynamic and static orientational disorders in the anionic sublattice. A determination of the orientational position of [NH4]+ ions calls for the combined method of elastic and inelastic neutron scattering. Inelastic neutron scattering is used to determine the state of hindered rotation for ammonium ions in the G0 phase. Powder neutron diffraction shows that the orientational disorder of NH4 ions can adequately be described within the free rotation approximation.

Novak, D. M. [Joint Institute for Nuclear Research, Dubna, Russia; Smirnov, Lev S [Alikhanov Institute for Theoretical and Experimental Physics, Moscow, Russia; Kolesnikov, Alexander I [ORNL; Voronin, Vladimir [Institute of Metal Physics, Russia; Berger, I. F. [Institute of Metal Physics, Russia; Laptash, N. M. [Institute of Chemistry, Vladivostok, Russia; Vasil'ev, N. M. [Kirensky Institute of Physics, Krasnoyarsk, Russia; Flerov, I. N. [Kirensky Institute of Physics, Krasnoyarsk, Russia

2013-01-01T23:59:59.000Z

382

Solgel synthesis of iron(III) oxyhydroxide nanostructured monoliths using Fe(NO3)39H2O/CH3CH2OH/NH4OH ternary system  

Science Journals Connector (OSTI)

Iron(III) oxyhydroxide xerogels were prepared through solgel technology, using iron(III) nitrate nonahydrate as precursor, ethanol as solvent and ammonium hydroxide as gelation agent. This base is used for propylene oxide substitution, which was the gelation agent in previous works. Synthesis of a gel using NH4OH as a gelation agent is an innovative result with this type of precursor, since with metal salts the addition of a strong base commonly results in precipitation of the solid. The gel synthesis was achieved by controlling the base addition time. The dried material has a residual amount of organic impurities, in contrast with the significant amount detected in xerogels prepared using propylene oxide. The iron phase prevailing in the produced xerogels can be defined as ?-FeO(OH) (lepidocrocite), according to FTIR and Mssbauer analyses. The xerogels are formed by large clusters of well connected nanocrystallites of this phase. XRD revealed a crystalline phase retained inside the iron oxyhydroxide amorphous structure, which corresponds to NH4NO3 and results from the combination of NO3? and NH4+ ions in solution. The produced xerogel has a promising composition to be an oxidizing composite for the energetic materials area.

Lusa Dures; Orlando Oliveira; Leandro Benedini; Benilde F.O. Costa; Ana Matos Beja; Antnio Portugal

2011-01-01T23:59:59.000Z

383

Refinement of the crystal structure of the high-temperature phase G{sub 0} in (NH{sub 4}){sub 2}WO{sub 2}F{sub 4} (powder, X-ray, and neutron scattering)  

SciTech Connect

The (NH{sub 4}){sub 2}WO{sub 2}F{sub 4} compound undergoes a series of phase transitions: G{sub 0} {yields} 201, K {yields} G{sub 1} {yields} 160, and K {yields} G{sub 2}, with a significant change in entropy ({Delta}S{sub 1} {approx} Rln10 at the G{sub 0} {yields} G{sub 1} transition), which indicates significant orientational disordering in the G{sub 0} phase and the order-disorder type of the phase transition. X-ray diffraction is used to identify the crystal structure of the G{sub 0} phase as rhombohedral (sp. gr. Cmcm, Z = 4), determine the lattice parameters and the positions of all atoms (except hydrogen), and show that [WO{sub 2}F{sub 4}]{sup 2-} ions can form a superposition of dynamic and static orientational disorders in the anionic sublattice. A determination of the orientational position of [NH{sub 4}]{sup +} ions calls for the combined method of elastic and inelastic neutron scattering. Inelastic neutron scattering is used to determine the state of hindered rotation for ammonium ions in the G{sub 0} phase. Powder neutron diffraction shows that the orientational disorder of NH{sub 4} ions can adequately be described within the free-rotation approximation.

Novak, D. M., E-mail: dmn@nf.jinr.ru; Smirnov, L. S. [Joint Institute for Nuclear Research, Frank Neutron Physics Laboratory (Russian Federation)] [Joint Institute for Nuclear Research, Frank Neutron Physics Laboratory (Russian Federation); Kolesnikov, A. I. [Oak Ridge National Laboratory, Neutron Scattering Sciences Division (United States)] [Oak Ridge National Laboratory, Neutron Scattering Sciences Division (United States); Voronin, V. I.; Berger, I. F. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation); Laptash, N. M. [Russian Academy of Sciences, Institute of Chemistry, Far Eastern Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Chemistry, Far Eastern Branch (Russian Federation); Vasil'ev, A. D.; Flerov, I. N. [Russian Academy of Sciences, Kirensky Institute of Physics, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Kirensky Institute of Physics, Siberian Branch (Russian Federation)

2013-01-15T23:59:59.000Z

384

Process for the treatment of lignocellulosic biomass  

SciTech Connect

A process for the treatment of biomass to render structural carbohydrates more accessible and/or digestible using concentrated ammonium hydroxide with or without anhydrous ammonia addition, is described. The process preferably uses steam to strip ammonia from the biomass for recycling. The process yields of monosaccharides from the structural carbohydrates are good, particularly as measured by the enzymatic hydrolysis of the structural carbohydrates. The monosaccharides are used as animal feeds and energy sources for ethanol production.

Dale, Bruce E.

2014-07-08T23:59:59.000Z

385

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

386

Experimental and theoretical investigations of the reactions NH(X {sup 3}{sigma}{sup -})+D({sup 2}S){yields}ND(X {sup 3}{sigma}{sup -})+H({sup 2}S) and NH(X {sup 3}{sigma}{sup -})+D({sup 2}S){yields}N({sup 4}S)+HD(X {sup 1}{sigma}{sub g}{sup +})  

SciTech Connect

The rate coefficient of the reaction NH(X {sup 3}{sigma}{sup -})+D({sup 2}S){yields}{sup k{sub 1}}products (1) is determined in a quasistatic laser-flash photolysis, laser-induced fluorescence system at low pressures. The NH(X) radicals are produced by quenching of NH(a {sup 1}{delta}) (obtained in the photolysis of HN{sub 3}) with Xe and the D atoms are generated in a D{sub 2}/He microwave discharge. The NH(X) concentration profile is measured in the presence of a large excess of D atoms. The room-temperature rate coefficient is determined to be k{sub 1}=(3.9{+-}1.5)x10{sup 13} cm{sup 3} mol{sup -1} s{sup -1}. The rate coefficient k{sub 1} is the sum of the two rate coefficients, k{sub 1a} and k{sub 1b}, which correspond to the reactions NH(X {sup 3}{sigma}{sup -})+D({sup 2}S){yields}{sup k{sub 1a}}ND(X {sup 3}{sigma}{sup -})+H({sup 2}S) (1a) and NH(X {sup 3}{sigma}{sup -})+D({sup 2}S){yields}{sup k{sub 1b}}N({sup 4}S)+HD(X {sup 1}{sigma}{sub g}{sup +}) (1b), respectively. The first reaction proceeds via the {sup 2}A{sup ''} ground state of NH{sub 2} whereas the second one proceeds in the {sup 4}A{sup ''} state. A global potential energy surface is constructed for the {sup 2}A{sup ''} state using the internally contracted multireference configuration interaction method and the augmented correlation consistent polarized valence quadrupte zeta atomic basis. This potential energy surface is used in classical trajectory calculations to determine k{sub 1a}. Similar trajectory calculations are performed for reaction (1b) employing a previously calculated potential for the {sup 4}A{sup ''} state. The calculated room-temperature rate coefficient is k{sub 1}=4.1x10{sup 13} cm{sup 3} mol{sup -1} s{sup -1} with k{sub 1a}=4.0x10{sup 13} cm{sup 3} mol{sup -1} s{sup -1} and k{sub 1b}=9.1x10{sup 11} cm{sup 3} mol{sup -1} s{sup -1}. The theoretically determined k{sub 1} shows a very weak positive temperature dependence in the range 250{<=}T/K{<=}1000. Despite the deep potential well, the exchange reaction on the {sup 2}A{sup ''} ground-state potential energy surface is not statistical.

Qu, Z.-W.; Zhu, H.; Schinke, R.; Adam, L.; Hack, W. [Max-Planck-Institut fuer Dynamik und Selbstorganisation, D-37073 Goettingen (Germany); Max-Planck-Institut fuer biophysikalische Chemie, D-37077 Goettingen (Germany)

2005-05-22T23:59:59.000Z

387

Ocean Energy: Forms and Prospects  

Science Journals Connector (OSTI)

...be relatively simple-turbines, paddle wheels, and...others. For example, if wind is forced to move through...and to interact with turbines of much re-duced dimensions...anhydrous ammonia) for turbine operation is the common...Systems envisaged are huge offshore floating or near-surface...

John D. Isaacs; Walter R. Schmitt

1980-01-18T23:59:59.000Z

388

Morphology control of open-framework zinc phosphate Zn{sub 4}(H{sub 3}O)(NH{sub 4}){sub 3}(PO{sub 4}){sub 4} via microwave-assisted technique  

SciTech Connect

Open-framework zinc phosphates were synthesized by microwave-assisted technique, and it was shown that the morphology of as-prepared materials could be easily tailored by changing synthesis temperature, reaction time and pH value. During the synthesis, when the reaction temperature increases from 130 C to 220 C, the products transformed from hexagonal prisms to polyhedron along with the disappearance of the hexagonal prisms vertical plane. Simultaneously, both the reaction time and pH value could promote the nucleation and growth of crystal particles. More interestingly, the target products with different morphologies could be obtained by varying the usage of NaOH or NH{sub 3}H{sub 2}O at 130 C during the microwave synthesis process. - Graphical abstract: Zinc phosphates with variable morphologies can be obtained by simply tuning the microwave-heating temperatures. Display Omitted - Highlights: Synthesis of open-framework Zn{sub 4} (H{sub 3}O) (NH{sub 4}){sub 3}(PO{sub 4}){sub 4} compounds employing microwave technique. Dependence of morphology on the reaction conditions. Morphology transformation from hexagonal prisms to polyhedron was observed.

Ding, Ling [School of Textile and Material Science, Dalian Polytechnic University, Dalian 116034 (China); Song, Yu, E-mail: songyu@dlpu.edu.cn [School of Textile and Material Science, Dalian Polytechnic University, Dalian 116034 (China); Yang, Wei; Xue, Run-Miao [School of Textile and Material Science, Dalian Polytechnic University, Dalian 116034 (China); Zhai, Shang-Ru [Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034 (China); An, Qing-Da, E-mail: anqingda@dlpu.edu.cn [Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034 (China)

2013-08-15T23:59:59.000Z

389

DOI: 10.1007/s003400100751 Appl. Phys. B 74, 8593 (2002)  

E-Print Network (OSTI)

and real-time detection of NH3 and CO2 using a tunable diode-laser-based trace gas sensor [1-Verlag 2001 ABSTRACT A Kalman filtering technique is applied to the sim- ultaneous detection of NH3 and CO2 NH3 and CO2 concentration measure- ments and utilizing it to monitor varying ammonia and carbon

390

Ion mobility and phase transitions in heptafluorodiantimonates(III) Cs(1?x)(NH4)xSb2F7 and K0.4Rb0.6Sb2F7 according to NMR and DSC data  

Science Journals Connector (OSTI)

Abstract Ion mobility and phase transitions in heptafluorodiantimonates(III) Cs1?x(NH4)xSb2F7 (x=0.2; 0.6) and K0.4Rb0.6Sb2F7 were studied by the 19F, 1H NMR and DSC. The character of ionic motions in fluoride and ammonium sublattices with temperature variations was investigated. Types of ion motions and temperature ranges in which they are observed were determined. It was found that the predominant form of ionic motions in high-temperature modifications is a diffusion of fluorine atoms, whereas the number of diffusing ammonium ions depends on the sample composition. The observed phase transitions in heptafluorodiantimonates(III) of cesiumammonium and potassiumrubidium with a formation of high-temperature modifications are transitions into a superionic state (?>10?3S/cm above 450K).

V.Ya. Kavun; M.M. Polyantsev; L.A. Zemnukhova; A.B. Slobodyuk; V.I. Sergienko

2014-01-01T23:59:59.000Z

391

1H NMR investigation of the spin dynamics of the spin-frustrated trinuclear Fe cluster (NH4)[Fe3(?3-OH)(H2L)3(HL)3]?(H3L=orotic acid)  

Science Journals Connector (OSTI)

Proton nuclear-magnetic-resonance (NMR) measurements have been performed in the cluster (NH4)[Fe3(?3-OH)(H2L)3(HL)3]?(H3L=orotic acid) in order to investigate the electron spin dynamics of the Fe trinuclear unit. The proton NMR spectra and spin-lattice relaxation times T1 have been measured at temperatures between 3 K and room temperature. The 1/T1 rate exhibits a broad maximum around 50 K, which is attributed to slow local-field fluctuations of the electronic spin system of the order of the Larmor period, associated with magnetic excitations between the discrete low-lying energy levels of the cluster. The observation and relaxation analysis of the 1/T1 maximum provide an independent measurement of the energy difference between the ground and the first-excited state of the trinuclear unit and corroborates the results of previous static susceptibility measurements.

M. Fardis; G. Diamantopoulos; M. Karayianni; G. Papavassiliou; V. Tangoulis; A. Konsta

2001-11-30T23:59:59.000Z

392

Hydrogen storage in a combined M.sub.xAlH.sub.6/M'.sub.y(NH.sub.2).sub.z system and methods of making and using the same  

DOE Patents (OSTI)

As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.

Lu, Jun (Salt Lake City, UT); Fang, Zhigang Zak (Salt Lake City, UT); Sohn, Hong Yong (Salt Lake City, UT)

2012-04-03T23:59:59.000Z

393

Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams  

SciTech Connect

An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

2006-12-31T23:59:59.000Z

394

Characterization and performance of Cu/ZnO/Al2O3 catalysts prepared via decomposition of M(Cu, Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H2 and CO2  

Science Journals Connector (OSTI)

Methanol synthesis from hydrognation of CO2 is investigated over Cu/ZnO/Al2O3 catalysts prepared by decomposition of M(Cu, Zn)-ammonia complexes (DMAC) at various temperatures. The catalysts were characterized in detail, including X-ray diffraction, N2 adsorption-desorption, N2O chemisorption, temperature-programmed reduction and evolved gas analyses. The influences of DMAC temperature, reaction temperature and specific Cu surface area on catalytic performance are investigated. It is considered that the aurichalcite phase in the precursor plays a key role in improving the physiochemical properties and activities of the final catalysts. The catalyst from rich-aurichalcite precursor exhibits large specific Cu surface area and high space time yield of methanol (212 g/(Lcat h); T = 513 K, p = 3 MPa, SV = 12000 h?1).

Danjun Wang; Jun Zhao; Huanling Song; Lingjun Chou

2011-01-01T23:59:59.000Z

395

Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells  

SciTech Connect

We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai, E-mail: Kai.Zhu@nrel.gov [Chemical and Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

2014-05-26T23:59:59.000Z

396

Methods to estimate on-field nitrogen emissions from crop production as an input to LCA studies in the agricultural sector  

Science Journals Connector (OSTI)

Nitrogen compounds emitted from the field are usually considered in Life Cycle Assessments (LCA) of agricultural products or processes. The environmentally most important of these N emissions are ammonia (NH3), n...

Frank Brentrup; Jrgen Ksters

2000-11-01T23:59:59.000Z

397

Laboratory, in sacco and in vivo assessment of various treatment conditions affecting  

E-Print Network (OSTI)

and in vivo digestibilities of untreated and ammonia (NH3) treated wheat straw. Wheat straw and gas ammoniated digestibility trial with 5 sheep per treatment. Lowest NDF values for ammoniated straw were recorded with the 2

Paris-Sud XI, Université de

398

Pulsed quantum cascade laser instrument with compact design for rapid, high sensitivity measurements of trace gases in air  

Science Journals Connector (OSTI)

We have developed a compact instrument for sensitive, rapid and continuous measurement of trace gases in air, with results presented here for methane (CH4), nitric oxide (NO), nitrous oxide (N2O) and ammonia (NH3

J.B. McManus; J.H. Shorter; D.D. Nelson; M.S. Zahniser; D.E. Glenn

2008-09-01T23:59:59.000Z

399

Nominally anhydrous minerals and Earth's deep water cycle Joseph R. Smyth* and Steven D. Jacobsen  

E-Print Network (OSTI)

on the surface, hence oceans and dry land, almost as far back as we can see in geologic time. Oxygen isotope after accretion and differentiation from relatively D-enriched comets [Robert, 2001; Delsemme, 1999

Smyth, Joseph R.

400

E-Print Network 3.0 - anhydrous portland cements Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sustainability of Concrete Construction Tarun R. Naik, F.ASCE1 Summary: , a greenhouse gas GHG ; production of one ton of portland cement produces about one ton of CO2 and other...

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

E-Print Network 3.0 - anhydrous phospholipidic membranes Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

manipulation, liposomal membranes adhered to each other only in a certain range of CaCl2... to and add positive charges to the lipids, and that membranes are separated and...

402

Water Transport in Polymer Electrolyte Membrane Electrolyzers Used to Recycle Anhydrous HCl  

E-Print Network (OSTI)

is car- ried out in an electrolyzer similar to a H2-O2 polymer electrolyte membrane PEM fuel cell. The Du-coated Nafion 115 membrane was measured as a function of HCl flow rate and temperature at a constant cell 50% of the chlorine used in the chemical industry ends up as hydrogen chloride, a waste byproduct.2

Weidner, John W.

403

E-Print Network 3.0 - anhydrous silicate melt Sample Search Results  

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glass... transition fragility The viscosity of silicate ... Source: Russell, Kelly - Department of Earth and Ocean Sciences, University of British Columbia Collection:...

404

E-Print Network 3.0 - anhydrous magnesium chloride Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

magnesium ion concentration dependence of strand exchange... M Tris-acetate or Tris-HCI (pH 7.5), IO mM magnesium acetate or magnesium chloride, 3.7% glycerol, 1 m... and...

405

An investigation of the effectiveness of anhydrous mud acid to remove damage in sandstone formations  

E-Print Network (OSTI)

. DISCUSSION OF EXPERIMENT NO. 3. DISCUSSION OF EXPERIMENT NO. 4. . . DISCUSSION OF EXPERIMENT NO. 5. CONCLUSIONS AND RECOMMENDATIONS. . . . . Conclusions. . Recommendations. REFERENCES. APPENDIX A. Page 1V Vl vln 1X 18 20 22 24 26 28 28 29... Class 8536 Size 00 thru 4 Type S NEMA Starters (Internal Connsdion) Fedory Vrdre p n 4 5I I STOP Il 6 L J N. C. Contests + COIL 4, 3 Wire Control Separate Source Overload Contact Thermal Unit 3 Required X2 4 r""l 4 (Ground If Used) F F (If...

Haase, Dalan David

1998-01-01T23:59:59.000Z

406

14 Engineering Drive Hanover, NH 03755  

E-Print Network (OSTI)

of their sponsors, the CEDC staff, faculty advisors and mentors, and the technical staff of Thayer's CAD facility Formula Racing Dartmouth Organic Farm Graphicast Maponics Norwich Technologies Optra Inc. Dr. Joseph Technologies Terry Smith Solaflect Energy Matt Strand Victor Technologies Walvisstaart B.V. Dr. Mitchell Wolf

407

THE JOURNAL OF CHEMICAL PHYSICS 134, 214501 (2011) Nanoconfinement effects on the reversibility of hydrogen storage  

E-Print Network (OSTI)

of hydrogen storage in ammonia borane: A first-principles study Kiseok Chang,1 Eunja Kim,2 Philippe F. Weck,3-state materials capable of storing hydrogen, the NH3BH3 compound called ammonia borane (AB), with an ideal storage2 kg-1 ) density targets specified by the U.S. Department of Energy for on-board hydrogen storage.4

408

Department of Homeland Security Inventory DHS_inventory_form_revision_4_2011.doc Page 1 of 5  

E-Print Network (OSTI)

-90-3 Phosphorus oxychloride 10025-87-3 Phosphorus trichloride 7719-12-2 Thiodiglycol 111-48-8 #12;Department feet) Acetylene 74-86-2 Ammonia (anhydrous) 7664-41-7 Arsine 7784-42-1 Boron trichloride 10294-77-4 Diborane 19287-45-7 Dichlorosilane 4109-96-0 Dinitrogen tetroxide 10544-72-6 Fluorine 7782-41-4 Germane

Pawlowski, Wojtek

409

BN Bonded BN fiber article and method of manufacture  

DOE Patents (OSTI)

A boron nitride bonded boron nitride fiber article and the method for its manufacture which comprises forming a shaped article with a composition comprising a bonding compound selected from boron oxide and boric acid and a structural fiber selected from the group consisting of boron oxide, boron nitride and partially nitrided boron oxide fibers, heating the composition in an anhydrous gas to a temperature above the melting point of the compound and nitriding the resulting article in ammonia gas.

Hamilton, Robert S. (Youngstown, NY)

1981-08-18T23:59:59.000Z

410

Cooling Towers, Energy Conservation Strategies  

E-Print Network (OSTI)

undersized due to the low bidder syndrome (1). 4. New plant expansion needs colder temperatures off the tower. State of the Art Upgrading Users of cooling towers are not par ticularly concerned with the thermal analysis involving calculus, or delving... HISTORY I Anhydrous Ammonia Plant The Hawkeye Chemical Corporation, a subsidiary of the Getty Oil Company, pro jected a 50% expansion of their anhydroug ammonia output from 120,000 tons (1.09 Kg) per year to ~ production level of 225,000 tons (2...

Burger, R.

1983-01-01T23:59:59.000Z

411

Glutamine Synthetase in the Phloem Plays a Major Role in Controlling Proline Production  

Science Journals Connector (OSTI)

...nitrogen cycle in response to an excess of ammonia (). Interestingly...be a means of assimilating excess ammonium, acting as an additional...Biotronik, Maintel, Germany lithium citrate buffers and ninhydrin...14NH4 + solution to eliminate excess 15NH4 + and grown for an additional...

Norbert Brugière; Frédéric Dubois; Anis M. Limami; Maud Lelandais; Yvette Roux; Rajbir S. Sangwan; Bertrand Hirel

412

Nitrogen Deposition in the Southern High Plains Nitrogen is necessary for life on earth, but  

E-Print Network (OSTI)

to the environment. Dinitrogen contains two nitrogen atoms held together by one of nature's strongest chemical bonds in the environment include ammonia (NH3) and its related compounds, amines (NH2), nitrite (NO2) and nitrate (NO3 responsible for producing 500 million tons of nitrogen fertilizer each year, combines dinitro- gen

Mukhtar, Saqib

413

Journal of Catalysis 241 (2006) 235242 www.elsevier.com/locate/jcat  

E-Print Network (OSTI)

because NH3 can poison the catalyst used in PEM fuel cells; however, an NH3 adsorbent can be used microreactor; Silicon carbide; Hydrogen production; Ammonia decomposition; Fuel reforming 1. Introduction]. Higher energy densities can be obtained by using hydrogen gas in polymer electrolyte membrane (PEM) fuel

Kenis, Paul J. A.

414

In vitro and in vivo analysis of [64Cu-NO2A-8-Aoc-BBN(714)NH2]: a site-directed radiopharmaceutical for positron-emission tomography imaging of T-47D human breast cancer tumors  

Science Journals Connector (OSTI)

Introduction Human breast cancer, from which the T-47D cell line was derived, is known to overexpress the gastrin-releasing peptide receptor (GRPR) in some cases. Bombesin (BBN), an agonist for the GRPR, has been appended with a radionuclide capable of positron-emission tomography (PET) imaging and therapy. 64Cu-NO2A-8-Aoc-BBN(714)NH2 (NO2A=1,4,7-triazacyclononane-1,4-diacetate) has produced high-quality microPET images of GRPR-positive breast cancer xenografted tumors in mice. Methods The imaging probe was synthesized by solid-phase peptide synthesis followed by manual conjugation of the 1,4,7-triazacyclononane-1,4,7-triacetic acid (NOTA) bifunctional chelator and radiolabeling in aqueous solution. The radiolabeled conjugate was subjected to in vitro and in vivo studies to determine its specificity for the GRPR and its pharmacokinetic profile. A T-47D tumor-bearing mouse was imaged with microPET/CT and microMRI imaging. Results The 64Cu-NO2A-8-Aoc-BBN(714)NH2 targeting vector was determined to specifically localize in GRPR-positive tissue. Accumulation was observed in the tumor in sufficient quantities to allow for identification of tumors in microPET imaging procedures. For example, uptake and retention in T-47D xenografts at 1, 4 and 24 h were determined to be 2.270.08, 1.350.14 and 0.280.07 % ID/g, respectively. Conclusions The 64Cu-NO2A-8-Aoc-BBN(714)NH2 produced high-quality microPET images. The pharmacokinetic profile justifies investigation of this bioconjugate as a potentially useful diagnostic/therapeutic agent. Additionally, the bioconjugate would serve as a good starting point for modification and optimization of similar agents to maximize tumor uptake and minimize nontarget accumulation.

Adam F. Prasanphanich; Lauren Retzloff; Stephanie R. Lane; Prasant K. Nanda; Gary L. Sieckman; Tammy L. Rold; Lixin Ma; Said D. Figueroa; Samantha V. Sublett; Timothy J. Hoffman; Charles J. Smith

2009-01-01T23:59:59.000Z

415

Composition of saturn's atmosphere at northern temperate latitudes from Voyager iris spectra: NH/sub 3/, PH/sub 3/, C/sub 2/H/sub 2/, C/sub 2/H/sub 6/, CH/sub 3/D, CH/sub 4/, and the saturnian D/H isotopic ratio  

SciTech Connect

The abundances of minor atmospheric constituents at northern Saturnian latitudes have been inferred from infrared emission spectra recorded by Voyager. The NH/sub 3/, PH/sub 3/, C/sub 2/H/sub 2/, and C/sub 2/H/sub 6/ vertical distributions have been determined from spectra selected in a cloud-free region centered approximately at the latitude of the Voyager 2 radio-occultation point (36.5 N). The NH/sub 3/ mixing ratio in the upper troposphere is found to be compatible with the saturated partial pressure. The inferred PH/sub 3//H/sub 2/ ratio of 1.4 +- 0.8 x 10/sup -6/ is higher than the value derived from the solar P/H ratio, and the PH/sub 3/ vertical profile may extend somewhat into the stratosphere, up to a few millibars. The stratospheric C/sub 2/H/sub 2//H/sub 2/ and C/sub 2/H/sub 6//H/sub 2/ ratios are, respectively, 2.1 +- 1.4 x 10/sup -7/ and 3.0 x 1.1 x 10/sup -6/; the latter decreases sharply below the 20-50 mbar level. A larger selection of spectra yields CH/sub 3/D/H/sub 2/ = 3.9 +- 2.5 x 10/sup -7/ and CH/sub 4//H/sub 2/ = 4.5/sup +2.4//sub -1.9/ x 10/sup -3/. This result implies an enrichment of Saturn's upper atmosphere is carbon by at least a factor of 3 over the solar abundance. The D/H value resulting from our CH/sub 3/D/CH/sub 4/ ratio is 1.6/sup +1.3//sub -1.2/ x 10/sup -5/, significantly lower than previous determinations obtained from HD lines; it is also less than half of the IRIS-inferred Jovian value. Finally, the interpretation of two NH/sub 3/ lines in the 5 ..mu..m window suggests a NH/sub 3/H/sub 2/ ratio at the 2 bar level below the solar value.

Courtin, R.; Gautier, D.; Marten, A.; Bezard, B.; Hanel, R.

1984-12-15T23:59:59.000Z

416

Rfrigration solaire par simulation en absorption sche J. Flchon et F. Machizaud  

E-Print Network (OSTI)

tracé dans une précédente publication [4] le réseau (1/T, Log P) du couple frigorigène CaCl2-NH3 pour, Log P) of the frigorigene couple CaCl2-NH3 for different concentrations in ammonia, by simulation we. Parmi les couples susceptibles d'un emploi efficace, CaCl2, NH3 a fait l'objet de réalisations

Boyer, Edmond

417

PHYSICAL REVIEW A 83, 022713 (2011) Cold and ultracold NH-NH collisions in magnetic fields  

E-Print Network (OSTI)

.022713 PACS number(s): 34.50.Cx, 37.10.Mn, 37.10.Pq I. INTRODUCTION Cold (T mK challenges is to produce molecules in the ultra- cold regime, which requires a second-stage cooling method

418

FAQ 32-What are the potential health risks from conversion of depleted  

NLE Websites -- All DOE Office Websites (Extended Search)

conversion of depleted uranium hexafluoride to other forms? conversion of depleted uranium hexafluoride to other forms? What are the potential health risks from conversion of depleted uranium hexafluoride to other forms? Accidental release of UF6 during processing activities could result in injuries. The most immediate hazard from a release would be lung injury or death from inhalation of hydrogen fluoride (HF), a highly corrosive gas formed when UF6 reacts with moisture in air. Uranyl fluoride is also formed. Uranyl fluoride is a particulate that can be dispersed in air and inhaled. Once inhaled, uranyl fluoride is easily absorbed into the bloodstream because it is soluble. If large quantities are inhaled, kidney toxicity will result. Conversion of uranium hexafluoride to oxide or metal may involve hazardous chemicals in addition to UF6; specifically, ammonia (NH3) may be used in the process, and HF may be produced from the process. In the PEIS, the conversion accidents estimated to have the largest potential consequences were accidents involving the rupture of tanks containing either anhydrous HF or ammonia. Such an accident could be caused by a large earthquake. The probability of large earthquakes depends on the location of the facility, and the probability of damage depends on the structural characteristics of the buildings. In the PEIS, the estimated frequency of this type of accident was less than once in one million years. However, if such an extremely unlikely accident did occur, it was estimated that up to 41,000 members of the general public around the conversion facility might experience adverse effects from chemical exposures (mostly mild and temporary effects, such as respiratory irritation or temporary decrease in kidney function). Of these, up to 1,700 individuals might experience irreversible adverse effects (such as lung damage or kidney damage), with the potential for about 30 fatalities. In addition, irreversible or fatal effects among workers very near the accident scene would be possible. (Note: The actual numbers of injuries among the general public would depend on the size and proximity of the population around the conversion facility).

419

Ammonia scrubbing technology for CO2 capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Low-Cost CCS Technologies Low-Cost CCS Technologies at Coal-Fired Power Plant in China Dr. Zhao Bo Prof. Chen Changhe Assoc. Prof. WANG Shujuan The Research Group of Emission Control and New Energy Department of Thermal Engineering, Tsinghua University May 30, 2008 Group Members Academician, Prof. XU Xuchang Prof. CHEN Changhe Assoc. Prof. LI Yan Assoc. Prof. ZHUO Yuqun Assoc. Prof. TONG Huiling Assoc. Prof. WANG Shujuan Lecturer ZHAO Bo Research Interests * Emission Control - The formation mechanisms and removal technologies of all the major pollutants from coal combustion, including SO 2 , NOx, and trace elements (Hg, As, Se, etc.); - Sustainable utilization of emission control byproduct; * New Energy - Utilization of solar and geothermal energy; - Hydrogen energy infrastructure development;

420

Ammonia at Blodgett Forest, Sierra Nevada, USA  

E-Print Network (OSTI)

of covariance in vertical wind speed with sonic temperature,of covariance in vertical wind speed with sonic temperature,

Fischer, Marc L.; Littlejohn, David

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Diethylamine and ammonia pretreatment of lignocellulose  

E-Print Network (OSTI)

material was dried for 12 hours to remove the amine and then hydrolyzed for 72 hours with a mixture of cellulose enzymes. Six specially designed reactor vessels, and a temperature-controlled water bath were built to perform these experiments. This allows...

Holthus, Robert Earl

2012-06-07T23:59:59.000Z

422

Ammonia fiber explosion (AFEX) treatment of grass  

E-Print Network (OSTI)

and steam explosion (Playne, 1984), pretreatment of cane bagasse with alkaline hydrogen peroxide (Azzam, 1989), alkali treatment of soybean straw to improve digestibility (Felix, Hill, and Diarra, 14 1990), ammoniation of wheat straw to improve nutritive...

Ashok, Ganesh

1991-01-01T23:59:59.000Z

423

Ammonia-Soluable Inorganic Soil Colloids.  

E-Print Network (OSTI)

....................................................................................................... Term expires 1915 GOVERNING BOARD, STATE SUBSTATIONS tW iL L H. U 2 Y 1 I N President, Brownwood....................................................................... Term expires 1915 P. L. X M 9 E I N Vice-President, Temple... Inspector K t . t H M C 1 - I N Deputy Feed Inspector P t . t P M M s N Deputy Feed Inspector y t . t P M 5 S 1 - I N Deputy Feed Inspector H t , t L 7 5 BE C 1 - N Deputy Feed Inspector SUBSTATION NO. 1: Beeville, Bee County L t L t , BE W M...

Fraps, G. S.

1914-01-01T23:59:59.000Z

424

Ammonia at Blodgett Forest, Sierra Nevada, USA  

E-Print Network (OSTI)

Forest, Sierra Nevada, USA Marc L. Fischer and DavidRd. , Berkeley CA, 94720, USA Corresponding author address:

Fischer, Marc L.; Littlejohn, David

2007-01-01T23:59:59.000Z

425

The University of Chicago, Chicago, I  

NLE Websites -- All DOE Office Websites (Extended Search)

.** .** # [Contribution from the George Herbert Jones Laboratory, The University of Chicago, Chicago, I l l i n o i s ] ffjl j t18 The Isotopic Discrimination of Some Solutes in Liquid Ammonia YQHJCLY ItHbEASABLS Arlen Viste and Henry Taube (1) ( a ) Department of Chemistry, Augustana College, Sioux F a l l s , South Dakota; (b) Department of Chemistry, Stanford University, Stanford, California. Abstract The nitrogen isotopic discrimination of some s a l t s and metals, studied in liquid ammonia solution at -50°C, decreases in magnitude in the order Pb , Ca , Li , Ag , Na , Li, K , Na, K. The i s o t o p i c discrimination appears t o provide q u a l i t a t i v e information about the strength of the cation-solvent i n t e r a c t i o n in liquid ammonia. Introduction Dissolving an anhydrous s

426

Impact of porous medium desiccation during anhydrous CO2 injection in deep saline aquifers: up scaling from experimental  

E-Print Network (OSTI)

into the atmosphere. CO2 is captured from exhaust gas in power plants or industrial units and then stored of the saturation profile evolution with two phase flow model integrating thermal effects. An up scaling on recent experiments and numerical simulations, the near-well injection zone is identified

Boyer, Edmond

427

A study of the condensation of propene and isobutene with benzene in the presence of anhydrous ferric chloride  

E-Print Network (OSTI)

A STUDT Qt THE OCNZESlSATIQS OP PHQP%SE ASO ZSOSOTESE SZTH EEWZCEE IH THE ~QE Qp ASHTCEOUS WEEHZQ OHX QEISE Lewis Lialea Qarpeater Jwas 1ESS Approval as to style aa4 contest rsec~alehi H Q o t 0 p rtasat o Ohealstrr ma Qh~ A STUDI Of THE O... of the 44rlsaltaral an4 Hsshaaf sal Oolloso ef Texas Partial Falfilmoat of ihs Reqairsasats for the BeSres of Raster of Solsaae Ha Jor Sab)eot s Ohematsal Eagaoerlsg By Loafs Lla4sa OarPsa'tor yea? LOSS ) zzP 7 gest-& The writer ?%shee ae express...

Carpenter, Louis Linden

1938-01-01T23:59:59.000Z

428

Anhydrous ferric chloride as an alkylation catalyst: The condensation of 2-methylpropene and benzene, preparation and identification of several fractions.  

E-Print Network (OSTI)

-butylbe!!zeno. i':o tri-t-buty''oe:&zones ar, fo& ~ ed d!&r-'n~ t ! &. s &. en c't i c&n 24. . ? Dej", e, J. . 'r . Ch. !-. oc. , 60 2079 , lot&7) 25. ? Price an Cir):o;;. .-:. ' i, ibid. , (0, 2! 9o (lo3&&) 26. ? Fairbrother, Trans. Fa~ra av '~oc. , 37, 7'. 3...

Mommessin, Pierre Robert

2012-06-07T23:59:59.000Z

429

In-situ observations during chemical vapor deposition of hexagonal boron nitride on polycrystalline copper  

E-Print Network (OSTI)

-characterised the Cu catalyst exposed to ammonia (NH3, i.e. a nitrogen and hydrogen source without B) instead of borazine under similar pressures. For this ammonia exposure no expansion in the Cu lattice constant is found. As ammonia is known to dissociate on Cu... 1s (Figure 5a,b,c) and valence band (Supporting Figure S4) regions.12 We find that before CVD the as loaded Cu foil surface is heavily oxidized due to storage and transportation in ambient air (before step 1).12 Following an anneal (step 2) in H2...

Kidambi, Piran R.; Blume, Raoul; Kling, Jens; Wagner, Jakob B.; Baehtz, Carsten; Weatherup, Robert S.; Schlgl, Robert; Bayer, Bernhard C.; Hofmann, Stephan

2014-10-20T23:59:59.000Z

430

SCR SYSTEMS FOR HEAVY DUTY TRUCKS: PROGRESS TOWARDS MEETING EURO 4 EMISSION STANDARDS IN 2005  

SciTech Connect

Emissions of diesel engines contain some components, which support the generation of smog and which are classified hazardous. Exhaust gas aftertreatment is a powerful tool to reduce the NOx and Particulate emissions. The NOx-emission can be reduced by the SCR technology. SCR stands for Selective Catalytic Reduction. A reduction agent has to be injected into the exhaust upstream of a catalyst. On the catalyst the NOx is reduced to N2 (Nitrogen) and H2O (Water). This catalytic process was developed in Japan about 30 years ago to reduce the NOx emission of coal-fired power plants. The first reduction agent used was anhydrous ammonia (NH3). SCR technology was used with diesel engines starting mid of the 80s. First applications were stationary operating generator-sets. In 1991 a joint development between DaimlerChrysler, MAN, IVECO and Siemens was started to use SCR technology for the reduction of heavy duty trucks. Several fleet tests demonstrated the durability of the systems. To day, SCR technology is the most promising technology to fulfill the new European Regulations EURO 4 and EURO 5 being effective Oct. 2005 and Oct. 2008. The efficient NOx reduction of the catalyst allows an engine calibration for low fuel consumption. DaimlerChrysler decided to use the SCR technology on every heavy duty truck and bus in Europe and many other truck manufacturers will introduce SCR technology to fulfill the 2005 emission regulation. The truck manufacturers in Europe agreed to use aqueous solution of Urea as reducing agent. The product is called AdBlue. AdBlue is a non toxic, non smelling liquid. The consumption is about 5% of the diesel fuel consumption to reduce the NOx emissions. A small AdBlue tank has to be installed to the vehicle. With an electronically controlled dosing system the AdBlue is injected into the exhaust. The dosing system is simple and durable. It has proven its durability during winter and summer testing as well as in fleet tests. The infrastructure for AdBlue is under evaluation in Europe by Urea Producers and Mineral Oil companies to be readily available in time. Urea is one of the most common chemical products in the world and the production and the distribution very much experienced. However, a pure grade is needed for automotive application and requires special attention.

Frank, W; Huethwohl, G; Maurer, B

2003-08-24T23:59:59.000Z

431

NH 4-H Leader Enrollment Form County Club Name  

E-Print Network (OSTI)

: **************************************************************************************************************************************** New Hampshire 4-H Project List E-Mail Address Residence: Please check all projects you are planning to select county office below) University of New Hampshire Cooperative Extension is an equal opportunity1) Swine (ASW1) Veterinary Science (AVS1) Citizenship Community Service (CCS1) Citizenship (CCZ1

New Hampshire, University of

432

Detonation of Nitrogen Iodide, NI3NH3  

Science Journals Connector (OSTI)

... the other hand, the substance can be completely decomposed into iodine and permanent gases without detonation occurring if the pressure of the permanent gases be not allowed to fall below 2 ... state is reached, on subjecting the residue to a hard vacuum it detonates. On detonation, the amount of permanent gas produced is only 3050 per cent of that ...

W. E. GARNER; W. E. LATCHEM

1935-05-18T23:59:59.000Z

433

Dendritic Anion Hosts: Perchlorate Uptake by G5-NH2  

E-Print Network (OSTI)

may limit their utilization in drinking water treatment. Reverse osmosis (RO), nanofiltration (NF), and electrodialysis (ED) are also not cost-effective or efficient at recovering perchlorate from contaminated water

Goddard III, William A.

434

ARSENIC IN PRIVATE WELLS IN NH YEAR 1 FINAL REPORT  

E-Print Network (OSTI)

performed geospatial analysis of the well water arsenic estimates and survey results and produced the maps .................................................................................................. 7 Well water quality...................................................................................................... 7 Well water testing

Bucci, David J.

435

NH 4-H Youth Group Enrollment Form Name of Program  

E-Print Network (OSTI)

Yes No Farm Rural Town 10K-50K Suburb City 50K+ Hispanic Non-Hispanic White White Black Black American - ATV's (NSE1) Other Science /Technology (MST1) Woodworking (MWW1) Wind Power (MWP1) GPS (MGP1) Electricity/Energy (MEL1) Computers (MCS1) Bicycle Safety (MBS1) Aerospace & Rocketry (MAR1) Science

New Hampshire, University of

436

The effects of NH4 on growth, resource  

E-Print Network (OSTI)

of Phragmites australis and Glyceria maxima Edita Tylova-Munzarova a,*, Bent Lorenzen b , Hans Brix b , Olga kinetics of two common helophytes Phragmites australis (Cav.) Trin. ex Steudel and Glyceria maxima (Hartm of 34 mM the growth rate of Phragmites was not affected by the N form (mean RGR = 35.4 mg g?1 d?1

Brix, Hans

437

Generation of Nanopores during Desorption of NH3 from Mg(NH3)6Cl2  

Science Journals Connector (OSTI)

Center for Atomic-Scale Materials Physics (CAMP), Department of Physics, Building 307, Technical University of Denmark, DK-2800 Lyngby, Denmark, Amminex A/S, Kemitorvet, Building 206, DK-2800 Lyngby, Denmark, and Center for Sustainable and Green Chemistry, Department of Chemistry, Building 206, Technical University of Denmark, DK-2800 Lyngby, Denmark ... Metal ammine complexes have been known for more than a century,1 but they still turn out to have new and interesting properties. ...

Jens S. Hummelshj; Rasmus Zink Srensen; Marina Yu. Kustova; Tue Johannessen; Jens K. Nrskov; Claus Hviid Christensen

2005-12-09T23:59:59.000Z

438

Moderate Dispersion Spectra of NH2 in Comet Hale-Bopp: Analysis of Population Distribution in State of NH2  

Science Journals Connector (OSTI)

......follows a Boltzmann distribution at a temperature of Trot 2. The...1 AU from the Sun, because the heliocentric...on the Boltzmaim distribution at a temperature of 60 K (shown...follow the Boltzmann distribution at Trot of 40......

Hideyo Kawakita; Kazuya Ayani; Tetsuya Kawabata

2000-10-01T23:59:59.000Z

439

System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases  

DOE Patents (OSTI)

A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

Sobolevskiy, Anatoly; Rossin, Joseph A

2014-04-08T23:59:59.000Z

440

MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1  

E-Print Network (OSTI)

2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

Boyer, Edmond

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Satellites of the Outer Planets: Thermal Models  

Science Journals Connector (OSTI)

...sta-bility of hydrates of ammonia and...given to known phase transi-zwn melting behavior of the NH.5-HeO...in which known phase transitions in...profile and melting behavior within such an...chlo-ride-treated sand to hills, curves...

John S. Lewis

1971-06-11T23:59:59.000Z

442

The Formation of Nitriles in Hydrocarbon-Rich Atmospheres  

E-Print Network (OSTI)

of the light elements hydrogen and helium;2 polyatomic molecules methane (CH4), ammonia (NH3), water (H2O at an early stage. As a consequence, the study of the chemistry of Titan's atmosphere offers the unique, Technical University Chemnitz, 09107 Chemnitz, Germany, and Department of Chemistry, University of York

Kaiser, Ralf I.

443

The sound of Titan a role for acoustics in space exploration  

E-Print Network (OSTI)

's Venera missions to Venus). in early 2005 will undertake a 2.5 hour parachute descent However, were is generated the features associated with the terrestrial water cycle: seas, by environmental processes breakdown of ammonia (NH3) deposited from comets, producing N2 and hydrogen (which is sufficiently light

Sóbester, András

444

Supporting Information for Impact of Chlorine Emissions from Sea-Salt Aerosol on Coastal Urban Ozone  

E-Print Network (OSTI)

DIOXIDE H2O2 HYDROGEN PEROXIDE NH3 AMMONIA NIT AEROSOL NITRATE SO2 SULFUR DIOXIDE SO3 SULFUR TRIOXIDE OSD extensions* NO NITRIC OXIDE NO2 NITROGEN DIOXIDE O3 OZONE HONO NITROUS ACID HNO3 NITRIC ACID HNO4 PERNITRIC ACID N2O5 NITROGEN PENTOXIDE NO3 NITRATE RADICAL HO2 HYDROPEROXY RADICAL CO CARBON MONOXIDE CO2 CARBON

Dabdub, Donald

445

Atmos. Chem. Phys., 11, 88098823, 2011 www.atmos-chem-phys.net/11/8809/2011/  

E-Print Network (OSTI)

of the particulate matter were carbonaceous materials, such as humic acid, water sol- uble organics, and less soluble in public concern regarding the emission of atmospheric pollutants, including gas phase and particulate from livestock include methane (CH4), ammonia (NH3), nitrogen oxides (NOx), and nitrous oxide (N2O

Meskhidze, Nicholas

446

Simple approaches for measuring dry atmospheric nitrogen deposition to watersheds  

E-Print Network (OSTI)

'' and spatial variations of gaseous dry N deposition (i.e., nitrogen dioxide (NO2) and ammonia (NH3)), thoughSimple approaches for measuring dry atmospheric nitrogen deposition to watersheds Heather E. Golden the effects of atmospheric nitrogen (N) deposition on surface water quality requires accurate accounts

Elliott, Emily M.

447

Page 1 of 7 Installation Name ____________________________________________________________  

E-Print Network (OSTI)

chlorine q liquid flow q ammonia (NH3) q other: _______________ q gas velocity q carbon dioxide (CO2) q other: _______________ q liquid velocity q carbon monoxide (CO) q other: _______________ b) Have any modular q loop q other:______________ #12;06/07/99 Page 3 of 7 c) The system is q 4-20 mA control wiring q

US Army Corps of Engineers

448

Meteorology and Atmospheric ISSN 0177-7971  

E-Print Network (OSTI)

of precipitation scav- enging are calculated for wet removal of sulfur dioxide (SO2) and ammonia (NH3) using of soluble trace gas in gaseous and liquid phases, mole l-1 c(G) Concentration of soluble trace gas Raindrop diameter, m DG Coefficient of diffusion in a gaseous phase, cm2 s-1 HA Henry's law constant, mole

Elperin, Tov

449

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

450

Industrial Heat Pumps Using Solid/Vapor Working Fluids  

E-Print Network (OSTI)

. Hygroscopic substances such as AICl3 or CaCIZ readily adsorb water when they are exposed to ambient air. In technical: pro cesses it is often impossible to preserve these salts absolutely anhydrous. There fore ammines consisting of a hygroscopic salt... of the central molecule. Applying the above ratio rule leads to NH3 and H20 as the most promising ligands. The ex istence of a complex compound, however, depends on the adsorbent as well as the adsorbate. For practical applications, the price, the toxicity...

Rockenfeller, U.

451

Retrofits: A Means for Reducing Energy Consumption in Ammonia Manufacture  

E-Print Network (OSTI)

preheated using process waste heat and then passed through the expander before flowing to the fuel system. About 1000-1500 BHP can be developed de pending on fuel gas pressure, waste heat availa bility, and other factors. This power can be used to drive... boiler. A gas turbine is more attractive and more easily in tegrated into the system when export steam is de sired. When power cost is low, it may be desirable to change small, inefficient steam turbine drives to electric motor drives. Naturally...

LeBlanc, J. R.; Moore, D. O.; Schneider, R. V., III

1982-01-01T23:59:59.000Z

452

Ammonia fiber explosion (AFEX) pretreatment of municipal solid waste components  

E-Print Network (OSTI)

as follows: Combine 50 mL pH 4. 6 1. 0 M citrate buffer 500 mL distilled H, O 1. 8939 g Genencor 300P cellulase or Cytolase 300 5. 695 mL NOVOZYM Beta-glucosidase 03 g sodium azide Complete to 1 L with HrO Adjust pH to 4. 8 with 1. 0 M Na... is found in Appendix 8. 2. Novozym 188 cellobiose with an activity of 250 CBU/mL was added giving a loading of 285 CBU/g dry substrate. Both enzymes contain some sugars that must be subtracted from the sugar yields. A complete procedure is given...

Lundeen, Joseph Eric

2012-06-07T23:59:59.000Z

453

DETERMINATION OF AMMONIA IN NATURAL WATERS BY THE ...  

Science Journals Connector (OSTI)

NOTES AND COMMENT. 799 and a suspension of resin in water poured into an ion exchange column ( 8 x 0.5 cm),. After settling, it was washed with three.

2000-02-12T23:59:59.000Z

454

Detection of Ammonia Slip Using NOx Sensor Signal Processing  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

455

Design and Construction of a Small Ammonia Heat Pump.  

E-Print Network (OSTI)

?? In view of the fact that most of the synthetic refrigerants, in case of leakage or release, are harmful to the environment by contributing (more)

A Monfared, Behzad

2010-01-01T23:59:59.000Z

456

Toxicity and acclimation to ammonia by Tilapia aurea  

E-Print Network (OSTI)

occur when the increasing permeability of the ti. sauce exceeds the maximus susI ai ned rate of urine production (approximately 12 ml!Eg/hr for rainbow trout). Chronic ratI'er than acute ammoni. a poisoning, is a major problem in som f" sh cul. ture.... 374 30. 268 27. 209 49. 768 48. 365 48. 424 6. 2-31. 7 4. . 2-30. 5 7. 0-33. 0 5. 7-30. 5 2. 9-35. 5 11. 5-31. 7 3. 0-31. 7 3. 0-33. 0 0. 1-0. 8 0. 1-0. 7 0. 1-0. 4 10 able 5. ? On-ionized ammoni. (mg/1 N) means for first pre...

Redner, Barry Duncan

1978-01-01T23:59:59.000Z

457

Biodegradation of bisphenol a and ibuprofen by ammonia oxidizing bacteria  

E-Print Network (OSTI)

Bisphenol A (BPA) is a compound that is commonly used in the manufacture of epoxy resins and plastics. Because of large scale production and widespread usages, BPA is released into the atmosphere through air, land, and water. BPA is weakly...

Subramanya, Nethra T.

2007-09-17T23:59:59.000Z

458

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

459

NOx Measurement Errors in Ammonia-Containing Exhaust  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

460

Ammonia Pollution From Farming May Exact Hefty Health Costs  

Science Journals Connector (OSTI)

...agriculture, although it can also come from vehicles and wildfires. Emissions are growing worldwide and are largely unregulated...says air quality modeler Daven Henze of the University of Colorado, Boulder. Paulot and Jacob used their model to calculate...

Erik Stokstad

2014-01-17T23:59:59.000Z

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Energy Savings for CO2 Removal in Ammonia Plants  

E-Print Network (OSTI)

of power recovery tur bines. The heat removal in the coolers requires the expenditure of mechanical energy which is used either in air-cooler fans or in cooling water pumps. For the sake of simplicity it has been assu med that electric motor drives.... The L.T. shift effluent which leaves a BFW heater at 1900C is used as the heat supply source in a steam-kettle to pro duce motive steam for the steam-jet thermo compressor before entering the solution re boiler, where it is further cooled to 122?C...

Pouilliart, R.; Van Hecke, F. C.

1981-01-01T23:59:59.000Z

462

Ammonia Triborane: Theoretical Study of the Mechanism of Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Triborane: Theoretical Study of the Mechanism of Hydrogen Release. Abstract: High-level electronic structure calculations have been used to predict the thermodynamic stability of...

463

Calculated electronic transitions of the water ammonia complex  

Science Journals Connector (OSTI)

We have calculated vertical excitation energies and oscillator strengths of the low lying electronic transitions in H 2 O N H 3 and H 2 O ? N H 3 using a hierarchy of coupled cluster response functions [coupled cluster singles (CCS) second order approximate coupled cluster singles and doubles (CC2) coupled cluster singles and doubles (CCSD) and third order approximate coupled cluster singles doubles and triples (CC3)] and correlation consistent basis functions (n-aug-cc-pVXZ where n = s d t and X = D T Q ). Our calculations indicate that significant changes in the absorption spectra of the photodissociative states of H 2 O and N H 3 monomers occur upon complexation. In particular we find that the electronic transitions originating from N H 3 are blueshifted whereas the electronic transitions originating from H 2 O are redshifted.

Joseph R. Lane; Veronica Vaida; Henrik G. Kjaergaard

2008-01-01T23:59:59.000Z

464

A calculation of the rotational constants of ammonia  

E-Print Network (OSTI)

) YMU = 3 ' ??ZMASSIXZMASSZ IF &I?GTel) GO TO 702 PHI A = 0 ~ 0 GINCR = 0 ' 5+DELQ A=AUX(ZMU?YMU?CANS ~ PMFAN?PHIA?GINCR ~ BONO) PHIA = 0. 5~A B=AUX(ZMU?YMUeCANiS?PMFAN ~ PHIA?GINCR?BOND& PHIA = 0?5KB C... ~ PHIA ~ DFLO, BOND& PHIA = AANGLE(I ? I& + 0 5?lB C=AUX(ZMU ~ YMU?CANS?PMEAN?PHIA ~ DELQ?BOILED) PHIA = AANGLE(I ? I) + C D=AUX(ZMU ~ YMU?CANST PiMEAN?PHIA?DELQ?BONO) AANGLF&I&= AANGL?=(I ? 1) +&A +2, ??B + 2 ?C +D)X6, 710 TRIG1 = SIN...

Trickey, Samuel B

1966-01-01T23:59:59.000Z

465

Diversity, Physiology, and Niche Differentiation of Ammonia-Oxidizing Archaea  

Science Journals Connector (OSTI)

...toxicity of NO and N2O as well as gaseous nitrogen dioxide...have been retrieved from geothermal habitats at up to 97C. Many...chemolithotrophic reactions in two geothermal springs demonstrated that...ancestor of Thaumarchaeota and a geothermal origin of archaeal AO (20...

Roland Hatzenpichler

2012-08-24T23:59:59.000Z

466

Development of electrochemical denitrification from waste water containing ammonium nitrate  

SciTech Connect

The authors developed processes to dentrify waste water containing ammonium nitrate discharged from the nuclear fuel manufacturing works and to recover nitric acid and ammonia. For denitrification they applied the operating method and the conditions of operation to make 0.4mM or less from NH{sub 4}NO{sub 3} waste water of 1.5 M by 3 stages of electrodialysis cells. To recover nitric acid and ammonium water, they separated HNO{sub 3} solution of 6 M and NH{sub 4}OH solution with one unit of electrolysis cell, then absorbed NH{sub 3} gas from NH{sub 4}OH solution with water and applied the condition of operation to recover 8 M NH{sub 4}OH solution. The authors demonstrated that treatment and recovery can be carried out stably with actual waste water with a system through the combination of previously mentioned electrodialysis cells, electrolysis cells and an ammonia gas absorber. At present they are planning a plant where NH{sub 4}NO{sub 3} waste water of 4,500 mol can be treated per day.

Sawa, Toshio; Hirose, Yasuo; Ishii, Yoshinori; Takatsudo, Atsushi; Wakasugi, Kazuhico; Hayashi, Hiroshi

1995-12-31T23:59:59.000Z

467

NEWTON, Ask a Scientist at Argonne National Labs  

NLE Websites -- All DOE Office Websites (Extended Search)

Acid, Gasses and Enzymes Acid, Gasses and Enzymes Name: Anirudh Status: student Grade: 9-12 Location: NY Country: India Date: Winter 2011-2012 Question: We were synthesizing Ammonia gas using HCl acid, as a part of the class experiment, for studying its chemical properties and that's when it hit me! Our body produces gases and acids like these (eg: Urea) during various metabolic process, which seems impossible because these gases & acids require very high temperatures (~200'C) for their synthesis and the maximum our body can do is 37'C. So how a human body is able to produce gasses and acids like Ammonia, Hydrogen Sulfide, HCl and others at body temperature? Replies: It would help to know the reaction you are using to synthesize ammonia gas (NH3), a base, using HCl, an acid. But putting that aside, realize that there are many reactions that have ammonia as a product. Some of these reactions require high temperature, but many other reactions do not require elevated temperature. What I believe you are thinking about is the reaction of formation of a compound, that is, the formation of a compound, in this case NH3, from its constituent elements -- N2 and H2 -- 1/2 N2 + 3/2 H2 = NH3.

468

Inhibition of Ammonia Oxidation in Nitrosomonas europaea by Sulfur Compounds: Thioethers Are Oxidized to Sulfoxides by Ammonia Monooxygenase  

Science Journals Connector (OSTI)

...sulfides and sulfoxides, except for tetrahydrothiophene sulfoxide, were purchased from...Co., Inc., Milwaukee, Wis. Tetrahydrothiophene sulfoxide was purchased from American...the cell suspensions with either tetrahydrothiophene or methylphenylsulfide were also...

Lisa Y. Juliette; Michael R. Hyman; Daniel J. Arp

1993-11-01T23:59:59.000Z

469

/ www.sciencexpress.org / 24 September 2009 / Page 1 / 10.1126/science.1178658 The search for water on the surface of the anhydrous  

E-Print Network (OSTI)

is an ongoing surficial process. OH/H2O production processes may feed polar cold traps and make the lunar regolith a candidate source of volatiles for human exploration. The Moon has been believed to be quite dry

Perfect, Ed

470

Melt Inclusion Formation Mechanisms and Compositional Effects in High-An Feldspar and High-Fo Olivine in Anhydrous Mafic Silicate Liquids  

E-Print Network (OSTI)

in a single 1 cm phenocryst (Sinton et al., 1993; Nielsen et al., 1995; Johnson et al, 1996; Sours-Page et al or enriched in particular major, minor or trace elements (Sinton et al., 1993; Nielsen et al., 1995; Saal et

Kurapov, Alexander

471

Enthalpy of Solution for Anhydrous VOSO4 and Estimated Enthalpy of Reaction for Formation of the Ion Pair [VOSO4]0  

Science Journals Connector (OSTI)

The vanadium redox flow battery (VRB) is showing great promise as an efficient new energy-storage system for a wide range of applications. ... Oriji, G.; Katayama, Y.; Miura, T. Investigation on V(IV)/V(V) species in a vanadium redox flow battery Electrochim. ... Investigation on V(IV)/V(V) species in a vanadium redox flow battery ...

Jian-Guo Liu; Wei-Feng Xue; Ye Qin; Chuan-Wei Yan; Jia-Zhen Yang

2009-04-01T23:59:59.000Z

472

Infrared spectroscopy of ionic clusters  

SciTech Connect

This thesis describes new experiments wherein the infrared vibrational predissociation spectra of a number of mass-selected ionic cluster systems have been obtained and analyzed in the 2600 to 4000 cm{sup {minus}1} region. The species studied include: the hydrated hydronium ions, H{sub 3}O{sup +} (H{sub 2}O){sub 3 {minus}10}, ammoniated ammonium ions, NH{sub 4}{sup +}(NH{sub 3}){sub 1 {minus}10} and cluster ions involving both water and ammonia around an ammonium ion core, (mixed clusters) NH{sub 4}{sup +}(NH{sub 3}){sub n}(H{sub 2}O){sub m} (n+m=4). In each case, the spectra reveal well resolved structures that can be assigned to transitions arising from the vibrational motions of both the ion core of the clusters and the surrounding neutral solvent molecules. 154 refs., 19 figs., 8 tabs.

Price, J.M. (California Univ., Berkeley, CA (USA). Dept. of Chemistry Lawrence Berkeley Lab., CA (USA))

1990-11-01T23:59:59.000Z

473

E-Print Network 3.0 - acetoacetic acid Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Chapter 2 Synthesis Chapter 2 Synthesis of Labelled Inhibitors Summary: (anhydrous) Lithium aluminium hydride THF (anhydrous) Thionyl chloride Hydrochloric acid Methanol n......

474

Heat driven heat pump using paired ammoniated salts  

SciTech Connect

A cycle for a heat driven heat pump using two salts CaCl/sup 2/.8NH/sup 3/, and ZnCl/sup 2/.4NH3 which may reversibly react with ammonia with the addition or evolution of heat. These salts were chosen so that both ammoniation processes occur at the same temperature so that the heat evolved may be used for comfort heating. The heat to drive the system need only be slightly hotter than 122 C. The low temperature source need only be slightly warmer than 0 C.

Dunlap, R.M.

1980-08-29T23:59:59.000Z

475

Quantification of Fossil Fuel CO2 Emissions on the Building/Street Scale for a Large U.S. City  

Science Journals Connector (OSTI)

In order to advance the scientific understanding of carbon exchange with the land surface, build an effective carbon monitoring system, and contribute to quantitatively based U.S. climate change policy interests, fine spatial and temporal quantification of fossil fuel CO2 emissions, the primary greenhouse gas, is essential. ... Ammonia (NH3) is a key precursor species to atmospheric fine particulate matter with strong implications for regional air quality and global climate change. ...

Kevin R. Gurney; Igor Razlivanov; Yang Song; Yuyu Zhou; Bedrich Benes; Michel Abdul-Massih

2012-08-15T23:59:59.000Z

476

Urban air pollution from private vehicles has been declining since the 1970s (1012) even as the number of vehicles and vehicle miles  

E-Print Network (OSTI)

), volatile organic compounds (VOC), and ammonia (NH3)] cost 1.3 to 1.4 cents per VMT for automobiles using from 1.1 to 1.2 cents per VMT for compressed nat- ural gas to 1.5 to 1.6 cents per VMT for hybrid-electric vehicles. For 2007, the American Automobile Association (AAA) estimated that the average cost of automobile

Jaramillo, Paulina

477

sample abstract for 2005 WOCA  

NLE Websites -- All DOE Office Websites (Extended Search)

Release of Ammonia from SCR / SNCR Fly Ashes Release of Ammonia from SCR / SNCR Fly Ashes Carol Cardone, Ann Kim and Karl Schroeder U.S. Dept. of Energy, NETL, PO Box 10940, Pittsburgh, PA 15236 KEYWORDS: fly ash, ammoniated fly ash, leaching Abstract One of the goals of the Department of Energy is to increase the utilization of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NO x control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip (un-reacted NH

478

NETL: Gasifipedia  

NLE Websites -- All DOE Office Websites (Extended Search)

SNG from Coal: Process & Commercialization SNG from Coal: Process & Commercialization The Great Plains Synfuels Plant in Beulah, North Dakota source: Dakota Gasification Great Plains Synfuels Plant The Great Plains Synfuels Plant (GPSP) in Beulah, North Dakota has been in operation producing synthetic natural gas (SNG) from lignite coal for 25 years and remains the only coal-to-SNG facility in the United States. In addition to the production of SNG, the plant also produces high purity carbon dioxide (CO2), which is distributed through a pipeline to end users in Canada for enhanced oil recovery (EOR) operations. The plant also produces and sells anhydrous ammonia, as well as the following byproducts: ammonium sulfate, krypton, xenon, dephenolized cresylic acid, liquid nitrogen, phenol, and naphtha, most of the last of which is burned as fuel

479

Microwave imaging of Saturn's deep atmosphere and rings  

SciTech Connect

An analysis of microwave images of Saturn's atmosphere and rings is presented. Interferometer observations at wavelengths of 0.27, 2.01, 6.17, and 20.13 cm, and precise application of synthesis imaging techniques yielded brightness and polarization maps of unsurpassed resolution and sensitivity. Linear polarization is detected from the ring ansea, and brightness variations in the deep atmosphere and the rings are revealed. The disk-integrated spectrum of Saturn is interpreted within the context of a radiative transfer model that requires the NH{sub 3} mixing ratio to take on a value of 0.9 to 1.1 x 10{sup -} directly below the ammonia ice cloud at a pressure of 1.4 bar. The NH{sub 3} mixing ratio increases with depth to a value of 5.0 to 6.5 x 10{sup -} at a pressure of 6 bar. The variation of NH{sub 3} with depth can be entirely accounted for by the presence of 11 to 14 times solar abundance of H{sub 2}S, which reacts with NH{sub 3} to produce a substantial NH{sub 4}SH cloud. Latitudinal variations in brightness temperature indicate that the saturated vapor abundance of ammonia decreases by 50 percent from equator to pole within the cloud deck. At greater depths, the latitudinal variations of ammonia are consistent with alternating zones of concentration and depletion caused by vertical motions. An apparent depletion in northern mid-lattitudes is well-correlated with a decrease in infrared opacity and depressed cloud top levels, indicating deep-seated downwelling. The size, composition, and shape of particles comprising the rings of Saturn are constrained by modeling the emission, scattering, and extinction of radiation by the rings. Azimuthal variations in brightness and linear polarization favor a model in which the particles are irregularly shaped.

Grossman, A.W.

1990-01-01T23:59:59.000Z

480

DOI: 10.1002/adma.200501918 Multiwalled Carbon Nanotubes Beaded with ZnO Nanoparticles  

E-Print Network (OSTI)

(SDS) followed by reaction of zinc acetate with lithium hy- droxide monohydrate in anhydrous ethanol

Wei, Ji

Note: This page contains sample records for the topic "anhydrous ammonia nh" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Absolute measurements of nitric acid by kilometer pathlength FT-IR (Fourier transform infrared) spectroscopy and their intercomparison with other measurement methods. Final report  

SciTech Connect

Measurements of ambient nitric acid (HNO/sub 3/) and ammonia (NH/sub 3/) concentrations were conducted using a Fourier transform infrared (FT-IR) spectrometer interfaced to an open-path, multiple-reflection optical system. These measurements provided benchmark data for gaseous HNO/sub 3/ and NH/sub 3/ during a field study, held at Claremont, California, September 11-19, 1985, which compared current analytical methods for determining nitrogenous species concentrations in the atmosphere. Hourly average concentrations of HNO/sub 3/ and NH/sub 3/ are reported, along with the calculated average concentrations for the sampling periods designated for the majority of the other measurement methods.

Winer, A.M.; Tuazon, E.C.; Biermann, H.W.; Wallington, T.J.

1986-05-01T23:59:59.000Z

482

Evidence for polyicosahedral structure in ammoniated iron, cobalt, and nickel clusters  

SciTech Connect

Experimental evidence is presented that small (19- to 34-atom) clusters of iron, cobalt, and nickel tend to adopt polyicosahedral structure when saturated with ammonia. Clusters in the polyicosahedral series (having 19, 23, 26, 29, 32, and 34 atoms) often saturate with 12 NH{sub 3} molecules, the expected number for polyicosahedral structure. Other clusters in this size range, which do not have an obvious number of NH{sub 3} binding sites, generally do not show a clear saturation. Adsorbate-induced structural changes are also seen, and suggest that for larger clusters in the series there is a transformation to an alternate structure that binds more than 12 NH{sub 3} molecules.

Parks, E.K.; Winter, B.J.; Klots, T.D.; Riley, S.J. (Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States))

1992-06-01T23:59:59.000Z

483

Year Month U.S. Average PAD District I Average CT ME MA NH RI  

Gasoline and Diesel Fuel Update (EIA)

1994 January ........................... 89.6 91.0 90.2 83.8 88.4 80.4 87.3 88.8 92.1 102.5 February ......................... 92.9 94.6 93.8 90.4 91.3 86.6 91.4 92.3 91.5 105.5 March .............................. 91.4 92.5 92.1 85.9 88.3 83.6 89.4 91.0 91.2 102.0 April ................................ 88.2 89.0 89.4 80.8 86.0 78.2 85.1 88.3 89.2 93.7 May ................................. 86.1 86.6 85.4 76.8 85.1 75.4 83.3 86.7 84.4 83.1 June ................................ 85.2 85.6 86.1 75.6 83.7 73.1 82.3 84.6 82.0 W July ................................. 82.7 83.1 84.2 75.6 82.1 71.8 81.6 83.0 80.5 W August ............................ 82.1 82.4 79.7 78.0 78.7 72.8 84.0 83.8 82.3 81.9 September ...................... 83.2 83.7 80.5 78.5 81.1 72.9 84.7 83.3 83.1 86.2 October ........................... 84.7

484

Up-Hill ET in (NH3)5Ru(III)-Modified Ferrocytochrome c  

NLE Websites -- All DOE Office Websites (Extended Search)

Up-Hill Electron Transfer in Pentaammineruthenium(III)-Modified Up-Hill Electron Transfer in Pentaammineruthenium(III)-Modified Ferrocytochrome c: Rates, Thermodynamics, and the Mediating Role of the Ruthenium Moiety Ji Sun, James F. Wishart, and Stephan S. Isied Inorg. Chem. 34, 3998-4000 (1995) Abstract: At moderate to high ionic strengths (>0.1 M), Co(oxalate)33- oxidizes native cytochrome c very slowly, however it undergoes a rapid reaction with pendant ruthenium complexes covalently attached to the surface of the protein. Under these conditions, the rate of the thermodynamically unfavorable (up-hill) FeII-to-RuIII electron transfer process in pentaammineruthenium-modified horse-heart cytochrome c can be revealed using sufficiently high Co(oxalate) 33- concentrations. Rate measurements performed over a wide range of CoIII concentrations confirm the proposed

485

Year Month U.S. Average PAD District I Average CT ME MA NH RI  

Gasoline and Diesel Fuel Update (EIA)

1993 January ........................... 94.3 95.7 94.9 85.2 94.0 87.1 91.7 93.4 91.2 105.2 February ......................... 94.6 95.9 96.2 85.4 94.4 86.9 91.8 93.3 90.8 106.8 March .............................. 95.4 96.5 96.7 86.4 94.8 86.6 92.4 93.7 92.4 108.5 April ................................ 92.6 93.4 93.6 83.0 91.5 84.5 90.4 91.2 91.6 106.7 May ................................. 91.1 91.7 91.6 81.7 91.1 83.9 90.7 91.3 89.4 104.3 June ................................ 88.9 89.4 88.6 81.1 88.6 82.4 87.6 89.7 90.6 100.4 July ................................. 85.6 85.9 86.5 78.5 83.9 78.3 85.2 85.5 86.4 100.2 August ............................ 84.1 84.6 84.0 77.4 83.4 76.0 82.7 85.6 83.5 96.1 September ...................... 85.5 85.8 84.2 78.3 83.8 74.9 84.8 86.6 84.6 95.5 October ...........................

486

Year Month U.S. Average PAD District I Average CT ME MA NH RI  

Gasoline and Diesel Fuel Update (EIA)

1995 January ........................... 86.9 87.6 86.7 77.8 84.8 78.4 87.3 85.7 88.4 102.4 February ......................... 87.4 88.2 87.8 77.4 84.9 78.5 87.3 85.9 88.5 103.4 March .............................. 86.6 87.3 87.0 76.3 82.5 77.7 87.0 85.6 87.6 103.3 April ................................ 85.4 85.8 85.2 76.7 81.9 76.6 86.5 84.8 87.0 100.0 May ................................. 86.4 86.9 86.5 78.7 84.7 75.8 86.1 84.5 85.2 93.2 June ................................ 84.6 85.2 84.2 78.1 82.5 74.5 83.2 83.9 83.0 NA July ................................. 82.0 82.4 79.4 76.9 80.6 72.9 81.7 81.7 80.0 85.1 August ............................ 80.7 81.1 77.4 76.7 80.9 73.0 85.3 81.7 82.1 W September ...................... 82.3 82.7 79.2 76.2 81.7 73.8 84.9 82.5 82.4 86.1 October ...........................

487

Year Month U.S. Average PAD District I Average CT ME MA NH RI  

Gasoline and Diesel Fuel Update (EIA)

1997 January ........................... 107.9 109.0 108.6 105.2 106.5 102.1 107.0 104.4 106.5 130.4 February ......................... 105.1 106.0 105.2 102.2 103.4 101.0 104.5 103.5 104.2 127.0 March .............................. 101.6 102.5 99.3 94.3 97.7 98.6 100.4 103.1 100.7 121.4 April ................................ 99.2 100.3 97.6 90.9 95.9 95.2 99.4 100.4 100.1 116.3 May ................................. 96.4 97.1 93.4 90.6 93.0 91.9 97.3 97.7 96.4 108.6 June ................................ 92.3 92.9 89.9 88.1 89.1 89.1 93.3 92.9 90.8 99.9 July ................................. 88.3 88.7 83.7 86.7 87.5 85.6 91.6 91.1 88.8 W August ............................ 86.9 86.8 84.2 85.8 84.7 85.3 91.0 92.7 89.2 W September ...................... 88.7 89.0 85.5 87.0 87.0 86.3 91.2 91.7 88.5 NA October ...........................

488

Year Month U.S. Average PAD District I Average CT ME MA NH RI  

Gasoline and Diesel Fuel Update (EIA)

1996 January ........................... 94.6 96.1 94.5 93.0 92.0 89.1 94.9 92.6 94.7 111.7 February ......................... 95.9 97.5 96.2 93.2 93.8 90.8 95.6 93.7 94.4 112.9 March .............................. 99.1 100.6 99.6 96.7 99.3 93.8 99.7 97.3 96.1 117.7 April ................................ 101.5 102.7 102.1 98.7 101.5 96.5 98.8 100.3 100.7 115.9 May ................................. 97.8 98.1 96.8 95.4 95.9 93.6 94.9 98.8 98.0 109.7 June ................................ 91.0 91.3 88.8 90.1 87.9 87.2 88.7 92.2 91.9 102.5 July ................................. 87.9 88.0 84.9 87.5 87.5 83.6 87.7 88.5 91.0 97.3 August ............................ 88.1 88.2 84.0 89.5 89.0 85.1 88.3 89.0 91.0 99.2 September ...................... 94.5 94.4 92.5 96.4 93.1 91.9 96.6 94.4 95.3 106.2 October ...........................

489

NH Long Range Reconnaissance Imager (LORRI) images (17). This same feature appears in the HST/  

E-Print Network (OSTI)

. Pearl et al., Nature 280, 755 (1979). 4. W. M. Sinton, C. Kaminski, Icarus 75, 207 (1988). 5. J. R

Abramov, Oleg

490

Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis  

Energy.gov (U.S. Department of Energy (DOE))

Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms potential for formulation of Euro 6 SCR catalysts

491

Details in Semiconductors Gordon Conference, New London, NH, August 3-8, 2008  

SciTech Connect

Continuing its tradition of excellence, this Gordon Conference will focus on research at the forefront of the field of defects in homogeneous and structured semiconductors. The conference will have a strong emphasis on the control of defects during growth and processing, with an increases emphasis on nanostructures as compared to previous conferences. Electronic, magnetic, and optical properties of bulk, thin film, and nanoscale semiconductors will be discussed in detail. In contrast to many conferences, which tend to focus on specific semiconductors, this conference deals with defects in a broad range of bulk and nanoscale electronic materials. This approach has proved to be extremely fruitful for advancing fundamental understanding in emerging materials such as wide-band-gap semiconductors, doped nanoparticles, and organic semiconductors. Presentations of state-of-the-art theoretical methods will contribute to a fundamental understanding of atomic-scale phenomena. The program consists of about twenty invited talks, with plenty of discussion time, and a number of contributed poster sessions. Because of the large amount of discussion time, the conference provides an ideal forum for dealing with topics that are new and/or controversial.

Shengbai Zhang and Nancy Ryan Gray

2009-09-16T23:59:59.000Z

492

STUDENTS' SUMMER RESEARCH PRESENTED AT UNH CONFERENCE Leitzel Center and NH EPSCOR Host Summer Symposium  

E-Print Network (OSTI)

of developing educators' thorough knowledge of science, mathematics, and engineering concepts and human learning ________________________________________________________________________ The Joan and James Leitzel Center for Mathematics, Science, and Engineering Education Parsons Hall at Morse Hall on UNH's Durham campus and featured 28 poster presentations. Undergraduate students from

New Hampshire, University of

493

Extreme Back Angle Nh-2 Elastic-Scattering at 794 Mev  

E-Print Network (OSTI)

). J. S. Sharma and A. N. Mitra, Phys. Rev. D 9, 2547 (1974). N. S. Craigie and C. Wilkin, Nucl. Phys. B14, 477 (1969); G. W. Barry, Ann. Phys. (N.Y.) 73, 482 (1972); V. M. Kolybasov and N. Ya. Smorodinskaya, Yad. Fiz. 17, 1211 (1973) [Sov. J. Nucl...: University of Wyoming, c/o LAMPF Visitors Center, Los Alamos, New Mexico 87545. 5Present address: Science Applications, Inc. , LaJolla, California 92037. A. K. Kerman and L. S. Kisslinger, Phys. Rev. 180, 1483 (1969). See for example: H. Braun et al...

Bonner, BE; Simmons, J. E.; Evans, M. L.; Glass, G.; Hiebert, John C.; Jain, M.; Northcliffe, L. C.; Bjork, C. W.; Riley, P. J.; Cassapakis, C. G.

1978-01-01T23:59:59.000Z

494

Optimization of NH3 Decomposition by Control of Discharge Mode in a Rotating Arc  

Science Journals Connector (OSTI)

In this study, the characteristic behavior of a rotating arc was investigated. Various modes, depending on the electric power supplied, can be observed in a rotating arc. Each mode produces different discharge ch...

Dae Hoon Lee; Kwan-Tae Kim; Hee Seok Kang

2014-01-01T23:59:59.000Z

495

Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

mixed oxides as promising new SCR catalyst materials and results of engine bench testing of full-size SCR prototype confirms Details progress on non-zeolitic zirconia-based...

496

Quantum Monte Carlo Study of the Retinal Minimal Model C5H6NH2  

E-Print Network (OSTI)

the signal cascade leading to vision.[4,8] Such cis/trans isomerization represents one of the faster ($200 fs) and efficient (quantum yield of $0.65) chemical processes in nature,[4,7,9] and the role of the protein experimental and theoretical investigations, has been produced over the last 15 years on gas phase retinal

Guidoni, Leonardo

497

Selective catalytic reduction of NO by NH3 on titanium pillared montmorillonite  

Science Journals Connector (OSTI)

The acidity of a titanium pillared montmorillonite (Ti-PILC) has been modified by two methods of...3 with or without SO2 has been investigated. For the three titanium pillared clays, a high resistance to SO2 pres...

H. L. del Castillo; A. Gil; P. Grange

1996-01-01T23:59:59.000Z

498

NH3-Selective Catalytic Reduction over Ag/Al2O3 Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

DRIFT spectroscopy used together with flow reactor experiments to investigate the role of H2 for SCR over Ag/Al2O3

499

S t r e e t Old Concord Rd-NH155A  

E-Print Network (OSTI)

Hewitt Rudman Service Building Combined Heat & Power Plant Zais Chase Ocean Engineering Lord New England

500

September 2013 GIS Workshops in Concord, NH SPACE IS LIMITED -PRE-REGISTRATION IS REQUIRED  

E-Print Network (OSTI)

the basics of Geographic Information System (GIS) mapping software and explore a variety of free GIS pro, become fluent in GIS jargon, explore the variety of free GIS and mapping software, understand both the basics of the programs, including how to create maps, edit GIS data and do basic geo- processing

New Hampshire, University of