Sample records for anhydrous ammonia nh

  1. Preventing Theft of Anhydrous Ammonia

    E-Print Network [OSTI]

    Smith, David

    2004-09-16T23:59:59.000Z

    Anhydrous ammonia is widely used as a fertilizer. The theft of anhydrous ammonia for use in producing illegal drugs is a growing problem. This publication describes how thieves operate and how farmers and agricultural dealers can protect themselves...

  2. Project Profile: Thermochemical Storage with Anhydrous Ammonia...

    Office of Environmental Management (EM)

    Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam Project Profile: Thermochemical Storage with Anhydrous...

  3. Degradation of untreated and anhydrous ammonia-treated wheat straw by two strains of rumen anaerobic fungi

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Degradation of untreated and anhydrous ammonia-treated wheat straw by two strains of rumen in the degradation of plant tissues. The aim of this study was to compare the degradation of untreated and anhydrous, the phloem and the parenchyma were slightly degraded and rhizoids were visible on the surface of the plant

  4. atmospheric ammonia nh3: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clusters because of their unique role Rocca, Jorge J. 208 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies

    E-Print Network [OSTI]

    Williams, James Jason

    1999-01-01T23:59:59.000Z

    Experiments were conducted to determine the quantity and conditions of electrochemical ozonation (O?) that maximize the dissolution of the lignin-cellulose complex. Combination treatments of anhydrous ammonia (NH?) and O? were also assessed...

  6. An investigation of some of the effects of anhydrous ammonia on the clay minerals montmorillonite and illite

    E-Print Network [OSTI]

    Whiteley, Eli Lamar

    1959-01-01T23:59:59.000Z

    * For most plants, it is as good a source of nitrogen as any other ammoniacal form of nitrogen. The effects of ammonia on the soil have not been worked out as clearly as the effects of ammonia on plants. In recent years deterioration of the physical... potassium but less than illite. Stanford (25) found that K+ was fixed only if the material was dried. Sohn and Peech (24.), in a study of New York soils, found the highest amounts of ammonia were fixed by acid soils containing large amounts of organic...

  7. An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal

    E-Print Network [OSTI]

    Mukhtar, Saqib

    An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Summary Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal by extracting it from liquid manure and potentially using the recovered NH3 as fertilizer. For this purpose, lab

  8. Study of NH stretching vibrations in small ammonia clusters by infrared spectroscopy in He droplets and ab initio calculations

    SciTech Connect (OSTI)

    Slipchenko, Mikhail N.; Sartakov, Boris G.; Vilesov, Andrey F.; Xantheas, Sotiris S.

    2007-08-09T23:59:59.000Z

    Infrared spectra of the NH stretching vibrations of (NH3)n clusters (n=2-4) have been obtained using the helium droplet isolation technique and first principles electronic structure anharmonic calculations. The measured spectra exhibit well-resolved bands, which have been assigned to the ?1, ?3, and 2?4 modes of the ammonia fragments in the clusters. The formation of a hydrogen bond in ammonia dimers leads to an increase of the infrared intensity by about a factor of four. In the larger clusters the infrared intensity per hydrogen bond is close to the one for dimers and approaches the value in the NH3 crystal. The intensity of the 2?4 overtone band in the trimer and tetramer increases by a factor of 10 relative to that in the monomer and dimer, and is comparable to the intensity of the ?1 and ?3 fundamental bands in larger clusters. This indicates the onset of the strong anharmonic coupling of the 2?4 and ?1 modes in larger clusters. The experimental assignments are compared to the ones obtained from first principles electronic structure anharmonic calculations for the dimer and trimer clusters. The anharmonic calculations were performed at the Møller-Plesset (MP2) level of electronic structure theory and were based on a second-order perturbative evaluation of rovibrational parameters and their effects on the vibrational spectra and average structures. In general there is excellent (<20 cm-1) agreement between the experimentally measured band origins for the N-H stretching frequencies and the calculated anharmonic vibrational frequencies. However, the calculations were found to overestimate the infrared intensities in clusters by about a factor of four. This work was supported by the Office of Basic Energy Sciences of the Department of Energy, in part by the Chemical Sciences program and in part by the Engineering and Geosciences Division. The Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  9. Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in orthorhombic ammonia borane. Quasielastic neutron scattering of -NH3 and -BH3 rotational dynamics in...

  10. Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+ ReportEnergy National Solar ThermalEnergyDepartment

  11. Spectroscopic Studies of the Phase Transition in Ammonia Borane...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studies of the Phase Transition in Ammonia Borane: Raman spectroscopy of single crystal NH3BH3 as a function of Spectroscopic Studies of the Phase Transition in Ammonia Borane:...

  12. Interaction of Lithium Hydride and Ammonia Borane in THF . |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Hydride and Ammonia Borane in THF . Interaction of Lithium Hydride and Ammonia Borane in THF . Abstract: The two-step reaction between LiH and NH3BH3 in THF leads to the...

  13. Selective Catalytic Reduction (SCR) of nitric oxide with ammonia using Cu-ZSM-5 and Va-based honeycomb monolith catalysts: effect of H2 pretreatment, NH3-to-NO ratio, O2, and space velocity 

    E-Print Network [OSTI]

    Gupta, Saurabh

    2004-09-30T23:59:59.000Z

    In this work, the steady-state performance of zeolite-based (Cu-ZSM-5) and vanadium-based honeycomb monolith catalysts was investigated in the selective catalytic reduction process (SCR) for NO removal using NH3. The aim ...

  14. Selective Catalytic Reduction (SCR) of nitric oxide with ammonia using Cu-ZSM-5 and Va-based honeycomb monolith catalysts: effect of H2 pretreatment, NH3-to-NO ratio, O2, and space velocity

    E-Print Network [OSTI]

    Gupta, Saurabh

    2004-09-30T23:59:59.000Z

    In this work, the steady-state performance of zeolite-based (Cu-ZSM-5) and vanadium-based honeycomb monolith catalysts was investigated in the selective catalytic reduction process (SCR) for NO removal using NH3. The aim was to delineate the effect...

  15. ammonia borane compound: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NH4H2PO4). (more) Gunaydin Sen, Ozge 2007-01-01 40 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. Emission factors for ammonia and particulate matter from broiler Houses

    E-Print Network [OSTI]

    Redwine, Jarah Suzanne

    2001-01-01T23:59:59.000Z

    Total suspended particulate (TSP) concentrations, ammonia (NH?) concentrations, and ventilation rates were measured in four commercial, tunnel ventilated broiler houses in June through December of 2000 in Brazos County, Texas. Particle size...

  17. Process for synthesis of ammonia borane for bulk hydrogen storage

    DOE Patents [OSTI]

    Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

    2011-03-01T23:59:59.000Z

    The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

  18. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08T23:59:59.000Z

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  19. Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators

    E-Print Network [OSTI]

    Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators to eventually optimise the reactor geometry for ammonia-based solar energy storage with troughs, which.1. Storing Solar Energy with Ammonia H2 / N2 gas liquid NH3 Heat Exchangers Power Generation (Steam Cycle

  20. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The...

  1. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at...

  2. Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a

    E-Print Network [OSTI]

    Senkan, Selim M.

    Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim, the adsorption of H2O and NH3 by H-bonding on previously H2O and NH3 dissociated systems, respectively are also considered. It is found that the adsorption energies and geometries of water and ammonia molecules on (101

  3. Evaluation of calcium chloride and ammonium thiosulfate as ammonia volatilization inhibitors for surface-applied urea

    E-Print Network [OSTI]

    Sloan, John J.

    1989-01-01T23:59:59.000Z

    (Fenn and Kissel, 1973). Ammonia exiting the soil chainber with the air-flow was captured in a boric acid indicator trap containing 40 mL of boric acid indicator solution. The boric acid indicator traps were changed every 24 h and titrated... as 90%. Calcium chloride reacts with the (NH4)2CO2 formed during urea hydrolysis in the following manner: (NH4)2CO2 + CaC12 CaCO& + 2NH4C1 Ammonium chloride is a slightly acidic product and does not produce (NH4)2CO2 in a calcareous soil. Ammonia...

  4. ELECTRONIC SOLUTION SPECTRA FOR URANIUM AND NEPTUNIUM IN OXIDATION STATES (III) TO (VI) IN ANHYDROUS HYDROGEN FLUORIDE

    E-Print Network [OSTI]

    Baluka, M.

    2013-01-01T23:59:59.000Z

    III) TO (VI) IN ANHYDROUS HYDROGEN FLUORIDE M. Baluka, N.III) TO (VI) IN ANHYDROUS HYDROGEN FLUORIDE M. Baluka(t), N.solutions in anhydrous hydrogen fluoride (AHF) of uranium

  5. Measurements of Ammonia at Blodgett Forest

    SciTech Connect (OSTI)

    Fischer, Marc L.; Littlejohn, David

    2007-04-01T23:59:59.000Z

    Ammonia is a reactive trace gas that is emitted in large quantities by animal agriculture and other sources in California, which subsequently forms aerosol particulate matter, potentially affecting visibility, climate, and human health. We performed initial measurements of NH{sub 3} at the Blodgett Forest Research Station (BFRS) during a 3 week study in June, 2006. The site is used for ongoing air quality research and is a relatively low-background site in the foothills of the Sierra Nevada. Measured NH{sub 3} mixing ratios were quite low (< 1 to {approx}2 ppb), contrasting with typical conditions in many parts of the Central Valley. Eddy covariance measurements showed NH{sub 3} fluxes that scaled with measured NH{sub 3} mixing ratio and calculated aerodynamic deposition velocity, suggesting dry deposition is a significant loss mechanism for atmospheric NH{sub 3} at BFRS. A simple model of NH{sub 3} transport to the site supports the hypothesis that NH{sub 3} is transported from the Valley to BFRS, but deposits on vegetation during the summer. Further work is necessary to determine whether the results obtained in this study can be generalized to other seasons.

  6. Characterization of the selective reduction of NO by NH/sub 3/

    SciTech Connect (OSTI)

    Lucas, D.; Brown, N.J.

    1981-04-01T23:59:59.000Z

    The selective reduction of NO by NH/sub 3/ addition has been studied in a lean-burning oil-fired laboratory combustion tunnel as a function of equivalence ratio, NH/sub 3/ injection temperature, concentration of NH/sub 3/ added, and the source of NO. Ammonia breakthrough was found to depend strongly on the NH/sub 3/ addition temperature. The total concentration of nitrogen containing species other N/sub 2/, NO, and NH/sub 3/ was measured with a variety of techniques and was found to be less than 5 ppM over the range of conditions studied.

  7. Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater

    E-Print Network [OSTI]

    remove greater than 90% of the influent ammonia (up to 19 mgLÀ1 NH3­N) in both the synthetic the reduction in space as compared to traditional activated sludge system, ease in upgrade of existing

  8. Compact anhydrous HCl to aqueous HCl conversion system

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.

    1993-06-01T23:59:59.000Z

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a [sup 196]Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  9. Compact anhydrous HCl to aqueous HCl conversion system

    SciTech Connect (OSTI)

    Grossman, Mark W. (Belmont, MA); Speer, Richard (S. Hamilton, MA)

    1993-01-01T23:59:59.000Z

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a .sup.196 Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  10. anhydrous rare earth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anhydrous rare earth First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Copper Sheath Rare Earth Material...

  11. Laboratory-measured H2SO4-H2O-NH3 ternary homogeneous nucleation rates: Initial observations

    E-Print Network [OSTI]

    Lee, Shan-Hu

    -ammonia (H2SO4-H2O-NH3) ternary homogeneous nucleation (THN), with a fast flow nucleation reactor attached. 1. Introduction [2] Nucleation is a gas-to-particle conversion process [Seinfeld and Pandis, 2006

  12. Consequence analysis of aqueous ammonia spills using an improved liquid pool evaporation model

    E-Print Network [OSTI]

    Raghunathan, Vijay

    2005-02-17T23:59:59.000Z

    of effective NOx emissions from utility boilers and combustion turbines nowadays (Pritchard et al. 1995). Its applications also include reduction of NOx emissions from diesel engines, process gas streams like nitric acid plants. The flue gas emitted from... serves the purpose of a reducing medium and is replacing anhydrous ammonia in most of the Selective catalytic reduction (SCR) units. This newly developed model can estimate the vaporization rate and net mass evaporating into the air from a...

  13. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

  14. Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

    1995-05-01T23:59:59.000Z

    This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

  15. Method of synthesis of anhydrous thorium(IV) complexes

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Cantat, Thibault

    2013-04-30T23:59:59.000Z

    Method of producing anhydrous thorium(IV) tetrahalide complexes, utilizing Th(NO.sub.3).sub.4(H.sub.2O).sub.x, where x is at least 4, as a reagent; method of producing thorium-containing complexes utilizing ThCl.sub.4(DME).sub.2 as a precursor; method of producing purified ThCl.sub.4(ligand).sub.x compounds, where x is from 2 to 9; and novel compounds having the structures: ##STR00001##

  16. Formation of hydroxylamine on dust grains via ammonia oxidation

    E-Print Network [OSTI]

    He, Jiao; Lemaire, Jean-Louis; Garrod, Robin T

    2015-01-01T23:59:59.000Z

    The quest to detect prebiotic molecules in space, notably amino acids, requires an understanding of the chemistry involving nitrogen atoms. Hydroxylamine (NH$_2$OH) is considered a precursor to the amino acid glycine. Although not yet detected, NH$_2$OH is considered a likely target of detection with ALMA. We report on an experimental investigation of the formation of hydroxylamine on an amorphous silicate surface via the oxidation of ammonia. The experimental data are then fed into a simulation of the formation of NH$_2$OH in dense cloud conditions. On ices at 14 K and with a modest activation energy barrier, NH$_2$OH is found to be formed with an abundance that never falls below a factor 10 with respect to NH$_3$. Suggestions of conditions for future observations are provided.

  17. Ammonia emission inventory for the state of Wyoming

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Maser, Colette R.; Brown, Nancy J.

    2003-12-17T23:59:59.000Z

    Ammonia (NH{sub 3}) is the only significant gaseous base in the atmosphere and it has a variety of impacts as an atmospheric pollutant, including the formation of secondary aerosol particles: ammonium sulfate and ammonium nitrate. NH{sub 3} preferentially forms ammonium sulfate; consequently ammonium nitrate aerosol formation may be limited by the availability of NH{sub 3}. Understanding the impact of emissions of oxides of sulfur and nitrogen on visibility, therefore, requires accurately determined ammonia emission inventories for use in air quality models, upon which regulatory and policy decisions increasingly depend. This report presents an emission inventory of NH{sub 3} for the state of Wyoming. The inventory is temporally and spatially resolved at the monthly and county level, and is comprised of emissions from individual sources in ten categories: livestock, fertilizer, domestic animals, wild animals, wildfires, soil, industry, mobile sources, humans, and publicly owned treatment works. The Wyoming NH{sub 3} inventory was developed using the Carnegie Mellon University (CMU) Ammonia Model as framework. Current Wyoming-specific activity data and emissions factors obtained from state agencies and published literature were assessed and used as inputs to the CMU Ammonia Model. Biogenic emissions from soils comprise about three-quarters of the Wyoming NH{sub 3} inventory, though emission factors from soils are highly uncertain. Published emission factors are scarce and based on limited measurements. In Wyoming, agricultural land, rangeland, and forests comprise 96% of the land area and essentially all of the estimated emissions from soils. Future research on emission rates of NH{sub 3} for these land categories may lead to a substantial change in the magnitude of soil emissions, a different inventory composition, and reduced uncertainty in the inventory. While many NH{sub 3} inventories include annual emissions, air quality modeling studies require finer temporal resolution. Published studies indicate higher emission rates from soils and animal wastes at higher temperatures, and temporal variation in fertilizer application. A recent inverse modeling study indicates temporal variation in regional NH{sub 3} emissions. Monthly allocation factors were derived to estimate monthly emissions from soils, livestock and wild animal waste based on annual emission estimates. Monthly resolution of NH{sub 3} emissions from fertilizers is based on fertilizer sales to farmers. Statewide NH{sub 3} emissions are highest in the late spring and early summer months.

  18. Ammonia scrubber testing during IDMS SRAT and SME processing. Revision 1

    SciTech Connect (OSTI)

    Lambert, D.P.

    1995-04-28T23:59:59.000Z

    This report summarizes results of the Integrated DWPF (Defense Waste Processing Facility) Melter System (IDMS) ammonia scrubber testing during the PX-7 run (the 7th IDMS run with a Purex type sludge). Operation of the ammonia scrubber during IDMS Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) processing has been completed. The ammonia scrubber was successful in removing ammonia from the vapor stream to achieve NH3 concentrations far below the 10 ppM vapor exist design basis during SRAT processing. However, during SME processing, vapor NH3 concentrations as high as 450 ppM were measured exiting the scrubber. Problems during the SRAT and SME testing were vapor bypassing the scrubber and inefficient scrubbing of the ammonia at the end of the SME cycle (50% removal efficiency; 99.9% is design basis efficiency).

  19. Reactor for removing ammonia

    DOE Patents [OSTI]

    Luo, Weifang (Livermore, CA); Stewart, Kenneth D. (Valley Springs, CA)

    2009-11-17T23:59:59.000Z

    Disclosed is a device for removing trace amounts of ammonia from a stream of gas, particularly hydrogen gas, prepared by a reformation apparatus. The apparatus is used to prevent PEM "poisoning" in a fuel cell receiving the incoming hydrogen stream.

  20. Theoretical study of the ammonia nitridation rate on an Fe (100) surface: A combined density functional theory and kinetic Monte Carlo study

    E-Print Network [OSTI]

    Yeo, Sang Chul

    Ammonia (NH[subscript 3]) nitridation on an Fe surface was studied by combining density functional theory (DFT) and kinetic Monte Carlo (kMC) calculations. A DFT calculation was performed to obtain the energy barriers ...

  1. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA Y. Liang1 , H. Xin2 , A. Casey10 ABSTRACT An ongoing project of monitoring ammonia (NH3) emissions from U.S. layer houses

  2. Proceedings of the Midwest Poultry Federation Convention, St. Paul, MN. March 16-18, 2004 Ammonia Emission from Iowa Layer Houses

    E-Print Network [OSTI]

    Kentucky, University of

    conversion as one of eight principles to reduce ammonia emission from layer hen houses. Research on reduction., Pittsburg, PA) for NH3 measurement and infrared sensor (0-5000 ± 20 ppm; Vaisala, Inc., Woburn, MA) for CO2 - Ammonia Emission from Iowa Layer Houses H. Xin1 , Y. Liang2 , R.S. Gates3 , E. F. Wheeler4 1 Professor

  3. Ab initio potential energy surfaces for NH,,3 -...NH,,3 -

    E-Print Network [OSTI]

    Ab initio potential energy surfaces for NH,,3 - ...­NH,,3 - ... with analytical long range Liesbeth, Poland Received 16 September 2009; accepted 7 November 2009; published online 10 December 2009; publisher error corrected 15 December 2009 We present four-dimensional ab initio potential energy surfaces

  4. An investigation of the effectiveness of anhydrous mud acid to remove damage in sandstone formations 

    E-Print Network [OSTI]

    Haase, Dalan David

    1998-01-01T23:59:59.000Z

    The goal of this experimental research was to determine the reactivity of anhydrous mud acid with clay minerals present in sandstone formations and its ability to remove damage in sandstone acidizing. Berea core flood experiments were conducted...

  5. mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the

    E-Print Network [OSTI]

    Atreya, Sushil

    1979-01-01T23:59:59.000Z

    mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the Primordial Atmosphere mixing ratio of am- monia of 10-5 or greater would provide a sufficient greenhouse effect to keep of longwave radiation NH3 could pro- duce a substantial "greenhouse effect" and maintain a surface temperature

  6. Radiation Damage in Polarized Ammonia Solids

    E-Print Network [OSTI]

    K. Slifer

    2007-11-28T23:59:59.000Z

    Solid NH3 and ND3 provide a highly polarizable, radiation resistant source of polarized protons and deuterons and have been used extensively in high luminosity experiments investigating the spin structure of the nucleon. Over the past twenty years, the UVA polarized target group has been instrumental in producing and polarizing much of the material used in these studies, and many practical considerations have been learned in this time. In this discussion, we analyze the polarization performance of the solid ammonia targets used during the recent JLab Eg4 run. Topics include the rate of polarization decay with accumulated charge, the annealing procedure for radiation damaged targets to recover polarization, and the radiation induced change in optimum microwave frequency used to polarize the sample. We also discuss the success we have had in implementing frequency modulation of the polarizing microwave frequency.

  7. Densities and viscosities of ternary ammonia/water fluids

    SciTech Connect (OSTI)

    Reiner, R.H.; Zaltash, A.

    1993-03-01T23:59:59.000Z

    The densities, viscosities, and boiling points (at barometric pressure) of solutions formed by inorganic salts dissolved in an ammonia/water (NH{sub 3}/H{sub 2}O) solvent have been measured. These ternary solutions of ammonia/water/dissolved salt are being investigated to reduce rectification requirements and to expand the temperature range of ammonia/water in advanced absorption cycles. Densities and viscosities of these fluids were measured over the temperature range of 283.15 to 343.15 K (10.0 to 70.0{degrees}C). Observed densities and viscosities were expressed as empirical functions of temperature by means of the least-squares method. The dynamic viscosities of ternary fluids were found to be three to seven times greater than those of the binary system of NH{sub 3}/H{sub 2}O, which implies that a substantial decrease in the film heat and mass transfer coefficient is possible. However, because this quantitative linkage is not well understood, direct measurements of heat and mass transfer rates in a minisorber are recommended and planned.

  8. An investigation of the effectiveness of anhydrous mud acid to remove damage in sandstone formations

    E-Print Network [OSTI]

    Haase, Dalan David

    1998-01-01T23:59:59.000Z

    with a mixture of carbon dioxide, hydrogen chloride and hydrogen fluoride. These tests were carried out with oven dried cores and cores at irreducible water saturation. Anhydrous mud acid appears to be reactive with all the cores tested. However, it does...

  9. OPTICAL CONSTANTS OF NH{sub 3} AND NH{sub 3}:N{sub 2} AMORPHOUS ICES IN THE NEAR-INFRARED AND MID-INFRARED REGIONS

    SciTech Connect (OSTI)

    Zanchet, Alexandre; Rodríguez-Lazcano, Yamilet; Gálvez, Óscar; Herrero, Víctor J.; Escribano, Rafael; Maté, Belén, E-mail: belen.mate@csic.es [Instituto de Estructura de la Materia, IEM-CSIC, Serrano 123, E-28006 Madrid (Spain)

    2013-11-01T23:59:59.000Z

    Ammonia ice has been detected on different astrophysical media ranging from interstellar medium (ISM) particles to the surface of various icy bodies of our solar system, where nitrogen is also present. We have carried out a detailed study of amorphous NH{sub 3} ice and NH{sub 3}:N{sub 2} ice mixtures, based on infrared (IR) spectra in the mid-IR (MIR) and near-IR (NIR) regions, supported by theoretical quantum chemical calculations. Spectra of varying ice thicknesses were obtained and optical constants were calculated for amorphous NH{sub 3} at 15 K and 30 K and for a NH{sub 3}:N{sub 2} mixture at 15 K over a 500-7000 cm{sup –1} spectral range. These spectra have improved accuracy over previous data, where available. Moreover, we also obtained absolute values for the band strengths of the more prominent IR features in both spectral regions. Our results indicate that the estimated NH{sub 3} concentration in ISM ices should be scaled upward by ?30%.

  10. E-Print Network 3.0 - anhydrous alcohol evaporated Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    peroxide Copper, chromium, iron, most metals or their salts, alcohols, acetone... , carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia...

  11. High-resolution energy-selected study of the reaction NH3+ -> NH2 ++H: Accurate thermo chemistry for the NH2/NH2+ and NH3/NH3 + systems

    SciTech Connect (OSTI)

    Song, Y.; Qian, X.M.; Lau, K.C.; Ng, C.Y.; Liu, J.B.; Chen, W.W.

    2001-03-01T23:59:59.000Z

    Employing the newly developed high-resolution pulsed field ionization-photoelectron (PFI-PE)-photoion coincidence (PFI-PEPICO) technique, we have examined the dissociation of energy-selected NH{sub 3}{sup +} to form NH{sub 2}{sup +} + H near its threshold. The breakdown curves for NH{sub 2}{sup +} and NH{sub 3}{sup +} thus obtained yield a value of 15.765 {+-} 0.001 eV for the 0 K dissociation threshold or appearance energy (AE) for NH{sub 2}{sup +} from NH{sub 3}. This value, together with the known ionization energy (IE=10.1864 {+-} 0.0001 eV) and 0 K bond dissociation energy (D{sub 0} = 4.6017 {+-} 0.0025 eV) for NH{sub 3}, allows the determination of the D{sub 0}(NH{sub 2}{sup +}-H) and IE(NH{sub 2}), which are 5.5786 {+-} 0.0010 and 11.1633 {+-} 0.0025 eV, respectively. Using the known 0 K heats of formation ({Delta}H{sup 0}{sub f0}) for NH{sub 3} and H and the AE(NH{sub 2}{sup +}), we obtain the {Delta}H{sup o}{sub f0}(NH{sub 2}{sup +}) = 302.60 {+-} 0.08 kcal/mol. The PFI-PE spectrum for NH{sub 3} exhibits a step-like feature at the 0 K AE(NH{sub 2}{sup +}), indicating that the dissociation of excited NH{sub 3} in high-n (n {ge} 100) Rydberg states at energies slightly above the dissociation threshold occurs on a time scale {le}10{sup -7} s. This step confirms the AE(NH{sub 2}{sup +}) value derived from the PFI-PEPICO measurements. Highly accurate energetic data with well-founded error limits, such as those obtained in the present and other studies using the PFI techniques, are expected to play an important role for the development of the next generation of ab initio quantum computation procedures. This experiment has stimulated a state-of-the-art ab initio quantum chemical calculation (Dixon et al., J. Chem. Phys., accepted). The comparison between theoretical predictions and the best experimental results for the NH{sub 2}/NH{sub 2}{sup +} and NH{sub 3}/NH{sub 3}{sup +} systems indicates that the accuracy of the computational scheme used is {le}0.4 kcal/mol.

  12. Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction

    SciTech Connect (OSTI)

    Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-01-15T23:59:59.000Z

    Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

  13. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  14. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Abstract: Ammonia...

  15. Shock temperature measurements in ammonia

    SciTech Connect (OSTI)

    Radousky, H.B.; Mitchell, A.C.; Nellis, W.J.; Ross, M.

    1985-07-01T23:59:59.000Z

    Our first shock temperature measurements on a cryogenic target are reported for NH/sub 3/. A new fast optical pyrometer and a cryogenic specimen holder for liquid NH/sub 3/ were developed to measure shock temperatures of 4400 and 3600 K at pressures of 61 and 48 GPa. These conditions correspond to those in the ice layers in Uranus and Neptune. The shock temperature data are in reasonable agreement with an equation of state based on an intermolecular potential derived from NH/sub 3/ Hugoniot data.

  16. ammonia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 18 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. Diethylamine and ammonia pretreatment of lignocellulose

    E-Print Network [OSTI]

    Holthus, Robert Earl

    1993-01-01T23:59:59.000Z

    to the diethylamine did not increase reactivity, but it allows the diethylamine to be recovered. In addition to the diethylamine experiments, ammonia was used to pretreat Coastal bermudagrass. This process involves soaking the cellulose fibers in liquid ammonia...

  18. Remediation of Uranium in the Hanford Vadose Zone Using Ammonia Gas: FY 2010 Laboratory-Scale Experiments

    SciTech Connect (OSTI)

    Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Qafoku, Nikolla; Williams, Mark D.; McKinley, James P.; Wang, Zheming; Bargar, John; Faurie, Danielle K.; Resch, Charles T.; Phillips, Jerry L.

    2010-12-01T23:59:59.000Z

    This investigation is focused on refining an in situ technology for vadose zone remediation of uranium by the addition of ammonia (NH3) gas. Objectives are to: a) refine the technique of ammonia gas treatment of low water content sediments to minimize uranium mobility by changing uranium surface phases (or coat surface phases), b) identify the geochemical changes in uranium surface phases during ammonia gas treatment, c) identify broader geochemical changes that occur in sediment during ammonia gas treatment, and d) predict and test injection of ammonia gas for intermediate-scale systems to identify process interactions that occur at a larger scale and could impact field scale implementation.Overall, NH3 gas treatment of low-water content sediments appears quite effective at decreasing aqueous, adsorbed uranium concentrations. The NH3 gas treatment is also fairly effective for decreasing the mobility of U-carbonate coprecipitates, but shows mixed success for U present in Na-boltwoodite. There are some changes in U-carbonate surface phases that were identified by surface phase analysis, but no changes observed for Na-boltwoodite. It is likely that dissolution of sediment minerals (predominantly montmorillonite, muscovite, kaolinite) under the alkaline conditions created and subsequent precipitation as the pH returns to natural conditions coat some of the uranium surface phases, although a greater understanding of these processes is needed to predict the long term impact on uranium mobility. Injection of NH3 gas into sediments at low water content (1% to 16% water content) can effectively treat a large area without water addition, so there is little uranium mobilization (i.e., transport over cm or larger scale) during the injection phase.

  19. Hydrogen production using ammonia borane

    DOE Patents [OSTI]

    Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

    2013-12-24T23:59:59.000Z

    Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

  20. Preparation of ammonia synthesis gas

    SciTech Connect (OSTI)

    Shires, P.J.; van Dijk, C.P.; Cassata, J.R.; Mandelik, B.G.

    1984-10-30T23:59:59.000Z

    Ammonia synthesis gas having excess nitrogen is produced in a reactor-exchanger primary reformer followed by an autothermal secondary reformer wherein process air for the latter is preheated by heat exchange with gas turbine exhaust and the primary reformer is heated by synthesis gas from the secondary reformer.

  1. Publisher's Note: "Ab initio potential energy surfaces for NH,,3 -...-NH,,3 -

    E-Print Network [OSTI]

    Publisher's Note: "Ab initio potential energy surfaces for NH,,3 - ...-NH,,3 - ... with analytical of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland Received 21 December 2009; published

  2. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01T23:59:59.000Z

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  3. Study of On-Board Ammonia (NH3) Generation for SCR Operation | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic Safety Goals Strategic Safety|Research with EMLithium|Summary ofof

  4. The influence of ammonia on rapid-ther al low-pressure metalorganic chemical vapor deposited TIN, films from tetrakis (dimethylamido) titanium

    E-Print Network [OSTI]

    Florida, University of

    , films from tetrakis (dimethylamido) titanium precursor onto InP A. Katz, A. Feingold, S. Nakahara, and SP, using a combined reactive chemistry of ammonia (NH,) gas and tetrakis (dimethylamido) titanium (DMATi to the preview RT-LPMOCVD TN, film deposited using only the DMATi precursor. I. INTRODUCTION Titanium nitride

  5. Vapor-liquid equilibria in the system NH{sub 3} + H{sub 2}O + LiBr. 2: Data correlation

    SciTech Connect (OSTI)

    Peters, R.; Korinth, C.; Keller, J.U. [Univ. of Siegen (Germany). Institute Fluid- and Thermodynamics

    1995-07-01T23:59:59.000Z

    The systems ammonia + water (NH{sub 3} + H{sub 2}O) and water + lithium bromide (H{sub 2}O + LiBr) provide two working pairs most often used today in air-conditioning systems and systems for reusing industrial waste heat, such as absorption heat pumps and heat transformers. A quasi-chemical reaction model has been developed to correlate vapor-liquid equilibrium data for the system ammonia (NH{sub 3}) + water (H{sub 2}O) + lithium bromide (LiBr) in the temperature range form 303.15 to 473.15 K and at pressures up to 2.0 MPa. this model assumes the formation of ion clusters, i.e., Li{sup +} and Br{sup {minus}} ions surrounded by ammonia and water molecules. Further, ammonia nd water molecules are assumed to form a second species of complexes. The activities of the various components in the liquid phase are modeled by the NRTL equation. The vapor phase, assumed to consist of ammonia and water only, is modeled by the equation of state of Ishikawa, Chung, and Lu.

  6. Ammonia Process by Pressure Swing Adsorption

    SciTech Connect (OSTI)

    Dr Felix Jegede

    2010-12-27T23:59:59.000Z

    The overall objective of the project is to design, develop and demonstrate a technically feasible and commercially viable system to produce ammonia along with recovery of the products by adsorption separation methods and significantly decrease the energy requirement in ammonia production. This is achieved through a significantly more efficient ammonia psa recovery system. The new ammonia recovery system receives the reactor effluents and achieves complete ammonia recovery, (which completely eliminates the energy intensive refrigeration and condensation system currently used in ammonia production). It also recovers the unused reactants and recycles them back to the reactor, free of potential reactor contaminants, and without the need for re-compression and re-heat of recycle stream thereby further saving more energy. The result is a significantly lower energy consumption, along with capital cost savings.

  7. Polyaniline-based optical ammonia detector

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jin, Zhe (Los Alamos, NM); Su, Yongxuan (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    Electronic absorption spectroscopy of a polyaniline film deposited on a polyethylene surface by chemical oxidation of aniline monomer at room temperature was used to quantitatively detect ammonia gas. The present optical ammonia gas detector was found to have a response time of less than 15 s, a regeneration time of less than 2 min. at room temperature, and a detection limit of 1 ppm (v/v) for ammonia, with a linear dynamic range from 180 ppm to 18,000 ppm.

  8. Geotechnical/Environmental Engineering Intern Manchester, NH

    E-Print Network [OSTI]

    Pohl, Karsten

    Geotechnical/Environmental Engineering Intern Manchester, NH POSITION DESCRIPTION The candidate will provide support for site characterization geotechnical investigations, site development, remediation include, but are not limited to: Interpreting, and presenting, environmental data; performing engineering

  9. Cylinder supplied ammonia scrubber testing in IDMS

    SciTech Connect (OSTI)

    Lambert, D.P.

    1994-08-31T23:59:59.000Z

    This report summarizes the results of the off-line testing the Integrated DWPF Melter System (IDMS) ammonia scrubbers using ammonia supplied from cylinders. Three additional tests with ammonia are planned to verify the data collected during off-line testing. Operation of the ammonia scrubber during IDMS SRAT and SME processing will be completed during the next IDMS run. The Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) scrubbers were successful in removing ammonia from the vapor stream to achieve ammonia vapor concentrations far below the 10 ppM vapor exit design basis. In most of the tests, the ammonia concentration in the vapor exit was lower than the detection limit of the analyzers so results are generally reported as <0.05 parts per million (ppM). During SRAT scrubber testing, the ammonia concentration was no higher than 2 ppM and during SME testing the ammonia concentration was no higher than 0.05 m.

  10. Impact of porous medium desiccation during anhydrous CO2 injection in deep saline aquifers: up scaling from experimental

    E-Print Network [OSTI]

    Boyer, Edmond

    flow rate and capillary properties on the desiccation mechanisms. Keywords: supercritical CO2, dryingImpact of porous medium desiccation during anhydrous CO2 injection in deep saline aquifers: up - France Abstract Injection of CO2 in geological reservoirs or deep aquifers is nowadays studied

  11. Study of an ammonia-based wet scrubbing process in a continuous flow system

    SciTech Connect (OSTI)

    Mao, James X.; Lee, Anita S.; Kitchin, John R.; Nulwala, Hunaid B.; Luebke, David R.; Damodaran, Krishnan

    2013-01-01T23:59:59.000Z

    A continuous gas and liquid flow, regenerative scrubbing process for CO{sub 2} capture was demonstrated at the bench-scale level. An aqueous ammonia-based solution captures CO{sub 2} from simulated flue gas in an absorber and releases a nearly pure stream of CO{sub 2} in the regenerator. After the regeneration, the solution of ammonium compounds is recycled to the absorber. The design of a continuous flow unit was based on earlier exploratory results from a semi-batch reactor, where a CO{sub 2} and N{sub 2} simulated flue gas mixture flowed through a well-mixed batch of ammonia-based solution. During the semi-batch tests, the solution was cycled between absorption and regeneration steps to measure the carrying capacity of the solution at various initial ammonia concentrations and temperatures. Consequentially, a series of tests were conducted on the continuous unit to observe the effect of various parameters on CO{sub 2} removal efficiency and regenerator effectiveness within the flow system. The parameters that were studied included absorber temperature, regenerator temperature, initial NH{sub 3} concentration, simulated flue gas flow rate, liquid solvent inventory in the flow system, and height of the packed-bed absorber. From this testing and subsequent testing, ammonia losses from both the absorption and regeneration steps were quantified, and attempts were made to maintain steady state during operations. Implications of experimental results with respect to process design are discussed.

  12. Layer of protection analysis applied to ammonia refrigeration systems

    E-Print Network [OSTI]

    Zuniga, Gerald Alexander

    2009-05-15T23:59:59.000Z

    Ammonia refrigeration systems are widely used in industry. Demand of these systems is expected to increase due to the advantages of ammonia as refrigerant and because ammonia is considered a green refrigerant. Therefore, it is important to evaluate...

  13. Promotion of Hydrogen Release from Ammonia Borane with Mechanically...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promotion of Hydrogen Release from Ammonia Borane with Mechanically Activated Hexagonal Boron Nitride. Promotion of Hydrogen Release from Ammonia Borane with Mechanically Activated...

  14. Trends in on-road vehicle emissions of ammonia

    E-Print Network [OSTI]

    Kean, A.J.

    2009-01-01T23:59:59.000Z

    calculation of diesel truck emission factors proceeded viaheavy-duty diesel truck ammonia emission rates prior to SCRto the diesel truck ammonia emission factor, the light-duty

  15. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

  16. Potential of High-Throughput Experimentation with Ammonia Borane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation) Potential of High-Throughput Experimentation with Ammonia Borane Solid...

  17. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

  18. Method for releasing hydrogen from ammonia borane

    DOE Patents [OSTI]

    Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

    2013-02-19T23:59:59.000Z

    A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

  19. Simultaneous removal of H{sub 2}S and NH{sub 3} from coal gas. Final report

    SciTech Connect (OSTI)

    Gangwal, S.K.; Portzer, J.W.

    1998-05-01T23:59:59.000Z

    Hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) are the primary sulfur and nitrogen contaminants released when coal is gasified. Before coal gas can be utilized in an integrated gasification combined cycle (IGCC) plant to produce electricity, these contaminants need to be removed. The objective of this research was to develop sorbent-catalysts with the ability to simultaneously remove H{sub 2}S and NH{sub 3} from coal gas. Microreactor tests with HART-49, a zinc-based sorbent-catalyst with Ni, Co, and Mo as catalyst additives, showed that this material had the potential to remove 90% NH{sub 3} and reduce H{sub 2}S to <20 ppmv at 1 atm and 550 to 700 C. HART-49 was prepared in attrition-resistant fluidizable form (HART-56) using up to 75 wt% binder. Bench-scale fluidized-bed multicycle tests were conducted with the attrition-resistant sorbent-catalyst, HART-56, at 20 atm and 550 C. The H{sub 2}S and NH{sub 3} removal performance over the first two cycles was good in the presence of 5% steam but deteriorated thereafter when steam level was increased to 15%. The results point to a complex mechanism for simultaneous H{sub 2}S and NH{sub 3} removal, potentially involving both chemisorption and catalytic decomposition of NH{sub 3}. Further research and development is needed to develop a sorbent-catalyst for simultaneous H{sub 2}S and NH{sub 3} removal at IGCC hot-gas cleanup conditions.

  20. Co NMR Study of the Co States in Superconducting and Anhydrous Cobaltates I. R. Mukhamedshin,1,* H. Alloul,1,

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    59 Co NMR Study of the Co States in Superconducting and Anhydrous Cobaltates I. R. Mukhamedshin,1-sur-Yvette, France (Received 11 February 2005; published 20 June 2005) 59Co NMR spectra in oriented powders of Na0:35CoO2 and in its hydrated superconducting (HSC) phase Na0:35CoO2; 1:3H2O reveal a single electronic Co

  1. High-pressure studies of ammonia hydrates 

    E-Print Network [OSTI]

    Wilson, Craig W.

    2014-06-28T23:59:59.000Z

    Ammonia and water are major components of many planetary bodies, from comets and icy moons such as Saturn's Titan to the interiors of the planets Neptune and Uranus. Under a range of high pressures and/or low temperatures known ...

  2. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, Alfred J. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

  3. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, A.J.

    1993-11-30T23:59:59.000Z

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

  4. Ammonia fiber explosion (AFEX) treatment of grass

    E-Print Network [OSTI]

    Ashok, Ganesh

    1991-01-01T23:59:59.000Z

    solution), high-temperature treatment, and freezing in water suspensions at -75 C (Millett, Baker, and Satter, 1975), Chemical pretreatments include alkali and ammonia swelling, dilute acid extraction, NO with alkali, explosive steam decompression, wet... for ruminants. Ammonia explosion pulping has been investigated as an approach to fiber separation in wood chips (O' Connor, 1971). Recent work on pretreatment techniques includes: pretreatment of cedar with peracetic acid and steam explosion to improve...

  5. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

    1998-09-22T23:59:59.000Z

    A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

  6. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, B.A.; Whitlow, E.P.

    1998-09-22T23:59:59.000Z

    A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

  7. Measurement and Modeling of Spatial NH3 Storage Distributions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NH3 Storage Distributions in a Commercial Small Port Cu Zeolite Urea SCR Catalyst Measurement and Modeling of Spatial NH3 Storage Distributions in a Commercial Small Port Cu...

  8. Model Catalysis of Ammonia Synthesis ad Iron-Water Interfaces - ASum Frequency Generation Vibrational Spectroscopic Study of Solid-GasInterfaces and Anion Photoelectron Spectroscopic Study of Selected Anionclusters

    SciTech Connect (OSTI)

    Ferguson, Michael James

    2005-12-15T23:59:59.000Z

    The ammonia synthesis reaction has been studied using single crystal model catalysis combined with sum frequency generation (SFG) vibrational spectroscopy. The adsorption of gases N{sub 2}, H{sub 2}, O{sub 2} and NH{sub 3} that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH{sub 2} ({approx}3325 cm{sup -1}) and NH ({approx}3235 cm{sup -1}) under high pressure of ammonia or equilibrium concentrations of reactants and products on Fe(111) surfaces. Special attention was paid to understand how potassium promotion of the iron catalyst affects the intermediates of ammonia synthesis. An Fe(111) surface promoted with 0.2 monolayers of potassium red shifts the vibrational frequencies of the reactive surface intermediates, NH and NH{sub 2}, providing evidence for weakened the nitrogen-hydrogen bonds relative to clean Fe(111). Spectral features of these surface intermediates persisted to higher temperatures for promoted iron surfaces than for clean Fe(111) surfaces implying that nitrogen-iron bonds are stronger for the promoted surface. The ratio of the NH to NH{sub 2} signal changed for promoted surfaces in the presence of equilibrium concentrations of reactants and products. The order of adding oxygen and potassium to promoted surfaces does not alter the spectra indicating that ammonia induces surface reconstruction of the catalyst to produce the same surface morphology. When oxygen is co-adsorbed with nitrogen, hydrogen, ammonia or potassium on Fe(111), a relative phase shift of the spectra occurs as compared to the presence of adsorbates on clean iron surfaces. Water adsorption on iron was also probed using SFG vibrational spectroscopy. For both H{sub 2}O and D{sub 2}O, the only spectral feature was in the range of the free OH or free OD. From the absence of SFG spectra of ice-like structure we conclude that surface hydroxides are formed and no liquid water is present on the surface. Other than model catalysis, gas phase anion photoelectron spectroscopy of the Cl + H{sub 2} van der Waals well, silicon clusters, germanium clusters, aluminum oxide clusters and indium phosphide clusters were studied. The spectra help to map out the neutral potential energy surfaces of the clusters. For aluminum oxide, the structures of the anions and neutrals were explored and for silicon, germanium and indium phosphide the electronic structure of larger clusters was mapped out.

  9. ammonia removal vpcar: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 32 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. ammonia monooxygenase genes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. ammonia negative ion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 127 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  12. ammonia oxidising bacteria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 35 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  13. ammonia gas cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 96 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. archaeal ammonia oxidizers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    showed a strong correlation with ammonia Kamat, Vineet R. 85 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. aqueous ammonia process: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. ammonia release method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. ammonia dimethylamine trimethylamine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 30 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. ammonia removal reagent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 52 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. ammonia stress monitored: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 33 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  20. ammonia lyase microcompartment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 44 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  1. ammonia nitrous oxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 154 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  2. ammonia channel amtb: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 33 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  3. aqueous ammonia solution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 244 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  4. ammonia nitrous oxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 154 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia fluxes obtained: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 36 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. archaeal ammonia monooxygenase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 74 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. ammonia oxidizing bacteria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 75 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. Design and performance of an ammonia measurement system

    E-Print Network [OSTI]

    Boriack, Cale Nolan

    2007-04-25T23:59:59.000Z

    Ammonia emissions from animal feeding operations (AFOs) have recently come under increased scrutiny. The US Environmental Protection Agency (EPA) has come under increased pressure from special interest groups to regulate ammonia. Regulation...

  9. FTIR and kinetic studies of the mechanism of Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalyst for selective catalytic reduction of NO with ammonia

    SciTech Connect (OSTI)

    Long, R.Q.; Yang, R.T.

    2000-02-15T23:59:59.000Z

    A series of FTIR spectroscopic and kinetic studies of the selective catalytic reduction (SCR) of nitric oxide by ammonia were conducted on Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay (Fe-TiO{sub 2}-PILC) catalyst. It was found that No molecules were absorbed on the fresh Fe-TiO{sub 2}-PILC catalyst and then oxidized by O{sub 2} to adsorbed NO{sub 2} and nitrate species. These NO{sub x} adspecies could be reduced by NH{sub 3} at high temperatures. NH{sub 3} molecules could also be adsorbed on the Broensted acid and Lewis acid sites on the Fe-TiO{sub 2}-PILC catalyst to generate, respectively, NH{sup +}{sub 4} ions and coordinated NH{sub 3} species. These NH{sub 3} adspecies were active in reacting with NO, NO + O{sub 2} and NO{sub 2}, but the reaction rates of NH{sub 3} + NO + O{sub 2} and NH{sub 3} + NO{sub 2} were much higher than that of NNO + NH{sub 3}. However, under reaction conditions, the surface of Fe-TiO{sub 2}-PILC was mainly covered by NH{sup +}{sub 4} ions and coordinated NH{sub 3}, and no NO{sub x} adspecies were detected. This is in agreement with the zero-order for the SCR reaction with respect to NH{sub 3}. A possible reaction scheme for the SCR reaction on Fe-TiO{sub 2}-PILC was proposed. NO reduction initially involved the reaction between NO{sub 2} and pairs of NH{sub 3} adspecies to form an active intermediate, which finally reacted with gaseous or weakly adsorbed NO to produce N{sub 2} and H{sub 2}O.

  10. Ammonia Results Review for Retained Gas Sampling

    SciTech Connect (OSTI)

    Mahoney, Lenna A.

    2000-09-20T23:59:59.000Z

    This report was prepared as part of a task supporting the deployment of the retained gas sampler (RGS) system in Flammable Gas Watch List Tanks. The emphasis of this report is on presenting supplemental information about the ammonia measurements resulting from retained gas sampling of Tanks 241-AW-101, A-101, AN-105, AN-104, AN-103, U-103, S-106, BY-101, BY-109, SX-106, AX-101, S-102, S-111, U-109, and SY-101. This information provides a better understanding of the accuracy of past RGS ammonia measurements, which will assist in determining flammable and toxicological hazards.

  11. Potential Roles of Ammonia in a Hydrogen Economy

    E-Print Network [OSTI]

    Potential Roles of Ammonia in a Hydrogen Economy A Study of Issues Related to the Use Ammonia economy, particularly with regard to the viability of ammonia as an on-board hydrogen carrier for fuel for On-Board Vehicular Hydrogen Storage U.S. Department of Energy #12;#12;Primary Authors: George Thomas1

  12. Removal of ammonia from tarry water using a tubular furnace

    SciTech Connect (OSTI)

    V.V. Grabko; V.A. Kofanova; V.M. Li; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    An ammonia-processing system without the use of live steam from OAO Alchevskkoks plant's supply network is considered. Steam obtained from the wastewater that leaves the ammonia column is used to process the excess tarry water, with the release of volatile ammonia.

  13. PREPARATION OF ANHYDROUS F-18 FLUORIDE, T. Tewson. Journal of Labelled Compounds and Radiopharmaceuticals S165; 52, Supplement 1 2009

    SciTech Connect (OSTI)

    Tewson, T.

    2009-07-01T23:59:59.000Z

    The original specific aims of the grant where cut back considerably as the study section reduced both the time and the budget for the project. The objective of the grant was to show that fluorine-18 fluoride could be prepared completely anhydrous and thus substantially more reactive than conventionally dried fluoride using the method of Sun and DiMagno. This method involved using conventionally dried fluoride to prepare an aromatic fluoride in which the aromatic ring is substituted with electron withdrawing groups. The aryl fluoride is then dried and purified and the fluoride is displaced with an anhydrous nucleophile. Using fluorine-19 and macroscopic scale reactions the reactions work well and give anhydrous fluoride salts that are both more reactive and more selective in their reactions than conventionally dried fluoride. The original substrate chosen for the reaction was bromopentacyanobenzene (1). This compound proved to be easy to make but very hard to purify. As an alternative hexabromobenzene, which is commercially available in high purity, was tried. This reacted cleanly with conventionally dried F-18 fluoride in acetonitrile to give [{sup 18}F]-fluoropentabromobenzene (2), which could be dried by passage of the solution over alumina, which also removed any unreacted fluoride. The fluorine-18 fluoride could be liberated from (2) by displacement with an anhydrous nucleophilic tetra-alkylammonium salt but the anion had to be chosen with considerable care. The reaction is potentially reversible especially as, on the no carrier added scale, there is inevitably an excess of hexabromobenzene and so the displacing nucleophile is chosen to deactivate the aromatic compound to further nucleophilic displacement reactions. To this end tetrabutylammonium azide and tetrabutylammonium phenolate have been tried. Both work but the phenolate is probably the better choice. The F-18 fluoride produced by this process is substantially more reactive than conventionally dried fluoride. A solution of the 3'-anhydrothymidine-5-benzoate (3) was added to the fluoride solution and 30% of the fluoride was incorporated in less than 3 minutes at room temperature were as conventionally dried fluoride requires 10 minutes at 160 C and gives {approx}10% incorporation. These results are encouraging in that they show that the objective of truly anhydrous fluoride is worth pursuing but the problem is that you end up with too much 'stuff' in the solution. Four to five milligrams of hexabromobenzene are used for the initial fluorination reaction and enough of the tetra-alkylammonium salt has to be added to react with a substantial number of those bromides. No attempt has been made to optimize these amounts but there is clearly a lot of material in the solution before the final substrate is added. To avoid these difficulties experiments involving a different, low boiling carrier of the fluoride which can be distilled from the initial fluorination mixture have been tried. Phenyltrifluoromethane sulfonate reacts with fluoride to give trifluoromethane sulfonyl fluoride which boils at -20 C as shown. This reaction works with conventionally dried fluorine-18 fluoride and the no carrier added trifluoromethane sulphonyl fluoride distills out of the reaction as it forms. The choice of nucleophile to react it with to liberate the fluoride is limited and the obvious choice is tetrabutylammonium azide as the resulting trifluoromethane sulfonyl azide is unreactive. We have shown that this works in principle but the experimental details have not been explored.

  14. AMMONIA CONCENTRATION IN SALTSTONE HEADSPACE SUMMARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J; Alex Cozzi, A

    2008-09-26T23:59:59.000Z

    The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar into Tank 50. Saltstone samples were prepared with an 'MCU' type salt solution spiked with ammonia. The ammonia released from the saltstone was captured and analyzed. The ammonia concentration found in the headspace of samples maintained at 95 C and 1 atm was, to 95% confidence, less than or equal to 3.9 mg/L. Tank 50 is fed by several influent streams. The salt solution from Tank 50 is pumped to the salt feed tank (SFT) in the Saltstone Production Facility (SPF). The premix materials cement, slag and fly ash are blended together prior to transfer to the grout mixer. The premix is fed to the grout mixer in the SPF and the salt solution is incorporated into the premix in the grout mixer, yielding saltstone slurry. The saltstone slurry drops into a hopper and then is pumped to the vault. The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar{reg_sign} L into Tank 50. Waste Solidification-Engineering requested that the Savannah River National Laboratory (SRNL) perform testing to characterize the release of ammonia in curing saltstone at 95 C. The test temperature represents the maximum allowable temperature in the Saltstone Disposal Facility (SDF). Ammonia may be present in the salt solution and premix materials, or may be produced by chemical reactions when the premix and salt solution are combined. A final report (SRNS-STI-2008-00120, Rev. 0) will be issued that will cover in more depth the information presented in this report.

  15. ,"Pittsburg, NH Natural Gas Pipeline Imports From Canada (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Pittsburg, NH...

  16. COMPACT QEPAS SENSOR FOR TRACE METHANE AND AMMONIA DETECTION IN IMPURE HYDROGEN

    SciTech Connect (OSTI)

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S

    2011-11-02T23:59:59.000Z

    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  17. ELECTRONIC SOLUTION SPECTRA FOR URANIUM AND NEPTUNIUM IN OXIDATION STATES (III) TO (VI) IN ANHYDROUS HYDROGEN FLUORIDE

    SciTech Connect (OSTI)

    Baluka, M.; Edelstein, N.; O'Donnell, T. A.

    1980-10-01T23:59:59.000Z

    Spectra have been recorded for solutions in anhydrous hydrogen fluoride (AHF) of uranium and neptunium in oxidation states (III) to (VI). The spectra for U(III), Np(III) and Np(IV) in AHF are very similar to those in acidified aqueous solution, but that for U(IV) suggests that the cationic species is UF{sub 2}{sup 2+}. The AHF spectra for the elements in oxidation states (V) and (VI) are not comparable with those of the formally analogous aqueous solutions, where the elements exist as well-defined dioxo-cations. However, the AHF spectra can be related to spectra in the gas phase, in the solid state or in non-aqueous solvents for each element in its appropriate oxidation state.

  18. A Parametric Study for Regenerative Ammonia-Based Scrubbing for the Capture of CO2

    SciTech Connect (OSTI)

    Resnik, K.P.; Garber, W.; Hreda, D.C.; Yeh, J.T.; Pennline, H.W.

    2006-09-01T23:59:59.000Z

    A continuous gas and liquid flow, regenerative scrubbing process for CO2 capture is currently being demonstrated at the bench-scale level. An aqueous ammonia-based solution captures CO2 from simulated flue gas in an absorber and releases a nearly pure stream of CO2 in the regenerator. After the regeneration, the solution of ammonium compounds is recycled to the absorber. The design of the continuous flow unit was based on earlier exploratory results from a semi-batch reactor, where a CO2 and N2 gas mixture flowed through a well-mixed batch of ammonia-based solution. Recently, a series of tests have been conducted on the continuous unit to observe the effect of various parameters on CO2 removal efficiency and regenerator effectiveness within the flow system. The parameters that were studied include absorber temperature, regenerator temperature, initial NH3 concentration, simulated flue gas flow rate, liquid solvent inventory in the flow system, and height of the packed-bed absorber. Results from this current testing campaign conducted in the continuous scrubbing unit as well as test results from a 5-cycle semi-batch reactor will be discussed.

  19. Worried About High N Prices? Keith A Kelling and Larry G Bundy

    E-Print Network [OSTI]

    Balser, Teri C.

    .S. natural gas prices · Record increase in world nitrogen capacity · China's ban on urea imports · Collapse Nitrate Nitric AcidAmmonia Natural Gas Anhydrous Ammonia (NH3) Carbon Dioxide (CO2) Liquid Urea (UR) Prill gas prices NYMEX Natural Gas Prices 0 1 2 3 4 5 6 7 8 9 10 11 Jan-99 Apr-99 Jul-99 O ct-99 Jan-00 Apr

  20. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I. (Santa Fe, NM); Jones, Claude R. (Los Alamos, NM); Nelson, Leonard Y. (Seattle, WA)

    1982-01-01T23:59:59.000Z

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  1. Studies of Rotational Energy Transfer (RET) in long-range NH3-NH3 collisions in the gas phase (*)

    E-Print Network [OSTI]

    Boyer, Edmond

    L-477 Studies of Rotational Energy Transfer (RET) in long-range NH3-NH3 collisions in the gas phase-780 Pozna0144, Poland (Refu le 2 mars 1982, accepte le 14 mai 1982) Résumé. 2014 Le champ du dipôle- polarizability, only). From the dispersional part of the total interaction energy, we extract the RET

  2. acute ammonia intoxication: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    functional gene microarray showed a diverse Ward, Bess 35 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  3. ammonia policy context: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and online drugstores. Index Terms Reeves, Douglas S. 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  4. anaerobic ammonia oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and its derivatives, have demonstrated Angenent, Lars T. 89 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia gas sensor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C. P. Wong; Manos M. Tentzeris; Senior Member 158 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. ammonia percolated wheat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Centre, University Saskatchewan, University of 236 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. acute ammonia stress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importantly... Steelman, Andrew Jonathan 2009-05-15 44 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. ammonia fiber expansion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Krzysztof Sadlej; Eligiusz Wajnryb 2011-10-06 39 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  9. ammonia magnesium phosphate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Schrhoff, Torsten; Samanta, Chhanda 2014-01-01 51 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. acute ammonia challenge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    functional gene microarray showed a diverse Ward, Bess 25 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer

    Broader source: Energy.gov (indexed) [DOE]

    On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

  12. Process for releasing ammonia bound in coal water

    SciTech Connect (OSTI)

    Laufhutte, D.; Weber, H.

    1981-11-24T23:59:59.000Z

    A process for releasing ammonia which is bound in coal water using a pre-desulfurization plant having ammonia and hydrogen sulfide scrubbers through which crude coking plant gas is passed comprises circulating the crude coke oven gases through the hydrogen sulfide scrubber and the ammonia scrubber in succession, directing the coal water first through the ammonia scrubber while the crude coking plant gases are being also circulated therethrough after passing it first through the hydrogen sulfide scrubber. An alkali solution is also circulated through the ammonia scrubber to enrich the solution with acid components and to liberate ammonia bound in the coal water directing the coal water which has been enriched from the ammonia scrubber into the hydrogen sulfide scrubber. The process is characterized by the fact that the alkali solution which has first served for the hydrogen sulfide scrubber is added to the ammonia hydrogen sulfide scrubber. 80 to 90% of the total alkali solution is charged to the hydrogen sulfide after-washery and then on the hydrogen sulfide pre-washery and the rest is charged to an ammonia expulsion apparatus.

  13. Decomposition Pathway of Ammonia Borane on the Surface of nano...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano-BN. Abstract: Ammonia borane (AB) is under significant investigation as a possible hydrogen storage material. While many chemical additives have been demonstrated to have a...

  14. ammonia fuel cells: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bit.21687 ABSTRACT: Ammonia losses during swine wastewater treatment were examined using manure; electricity; power generation Introduction Wastewater treatment using microbial...

  15. Trends in on-road vehicle emissions of ammonia

    SciTech Connect (OSTI)

    Kean, A.J.; Littlejohn, D.; Ban-Weiss, G.A.; Harley, R.A.; Kirchstetter, T.W.; Lunden, M. M.

    2008-07-15T23:59:59.000Z

    Motor vehicle emissions of ammonia have been measured at a California highway tunnel in the San Francisco Bay area. Between 1999 and 2006, light-duty vehicle ammonia emissions decreased by 38 {+-} 6%, from 640 {+-} 40 to 400 {+-} 20 mg kg{sup -1}. High time resolution measurements of ammonia made in summer 2001 at the same location indicate a minimum in ammonia emissions correlated with slower-speed driving conditions. Variations in ammonia emission rates track changes in carbon monoxide more closely than changes in nitrogen oxides, especially during later evening hours when traffic speeds are highest. Analysis of remote sensing data of Burgard et al. (Environ Sci. Technol. 2006, 40, 7018-7022) indicates relationships between ammonia and vehicle model year, nitrogen oxides, and carbon monoxide. Ammonia emission rates from diesel trucks were difficult to measure in the tunnel setting due to the large contribution to ammonia concentrations in a mixed-traffic bore that were assigned to light-duty vehicle emissions. Nevertheless, it is clear that heavy-duty diesel trucks are a minor source of ammonia emissions compared to light-duty gasoline vehicles.

  16. Use and recovery of ammonia in power plant cycles

    SciTech Connect (OSTI)

    Pflug, H.D.; Bettenworth, H.J.; Syring, H.A. [Preussen Elektra AG, Hanover (Germany)

    1995-01-01T23:59:59.000Z

    The paper presents some practical and theoretical aspects of the use of ammonia in power plant water/steam cycles. The plants considered are fully automated units with once-through boilers, which operate under complex conditions and are subject to frequent starts and load changes. The boilers are chemically conditioned with combined oxygen ammonia treatment and the condensate polishing plant is only operated during start-up, in the event of a condenser leak or to remove excess ammonia. The paper also covers the recovery of ammonia from the condensate polishing plant waste regenerants and reuse for conditioning the feedwater. In particular, the paper deals with the following points: theoretical analysis of the chemical equilibrium of ammonia and carbon dioxide in water, including calculation of the concentrations from the parameters normally measured, such as conductivities and pH; equipment for monitoring and controlling the amount of ammonia fed to the water/steam cycle, including the optimum positioning of the sampling and feed-points, the parameters suitable for feed control and their temperature dependence; the partial pressure and distribution coefficient of ammonia; the consumption and losses of ammonia through the water/steam cycle during operation; the recovery of ammonia from condensate polishing plant waste regenerants by steam stripping. The paper should be of interest to both planning engineers and plant operators.

  17. Characterization of atmospheric ammonia near Fort Worth, TX Part I. Dynamics of gaseous ammonia

    E-Print Network [OSTI]

    effects, and influence11 the cloud albedo and lifetime via indirect effects. The largest uncertainties among all12 radiative forcing components in global climate models are associated with PM [IPCC, 2007 its potential effects on the20 local and regional air quality.21 Keywords: ammonia, air quality

  18. Catalysts for Dehydrogenation of ammonia boranes

    SciTech Connect (OSTI)

    Heinekey, Dennis M.

    2014-12-19T23:59:59.000Z

    Several effective homogeneous catalysts for the dehydrogenation of amine boranes have been developed. The best catalyst uses an iridium complex, and is capable of dehydrogenating H3NBH3 (AB) and CH3NH2BH3 (MeAB) at comparable rates. Thermodynamic measurements using this catalyst demonstrate that the dehydrogenation of AB and MeAB is substantially exothermic, which has important implications for regeneration.

  19. EPR and IR studies of [Ru(NH?)?]³+-Y and [Ru(NH?)?N?]²+-Y type zeolites

    E-Print Network [OSTI]

    Leubner, Raymond Leon

    1973-01-01T23:59:59.000Z

    EPR AND IR STUDIES OF [Ru(NH ) ] -Y 3 6 AND [Ru(NE ) N ] -Y TYPE ZEOLITES 2+ A Thesis by RAYMOND LEON LEUBNER Submitted to the Graduate College of Texas A&M University in partia1 fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1973 Major Subject: Chemistry EPR AND IR STUDIES OF [Ru(NH3) ] -Y 3+ AND [Ru(NH3) N ) -Y TYPE ZEOLITES 2+ 3&2 A Thesis by RAYMOND LEON LEUBNER Approved as to style and content by: (Chairman of Committ (Head of Department) (Memb...

  20. Jere Chase Ocean Engineering Lab, Durham, NH Directions & Parking

    E-Print Network [OSTI]

    Jere Chase Ocean Engineering Lab, Durham, NH Directions & Parking Jere Chase Ocean Engineering Lab of the University of New Hampshire. Parking is available at the Jere A. Chase Ocean Engineering Building. Directions

  1. AMMONIA THE OTHER HYDROGEN Rebecca Dunn, Keith Lovegrove

    E-Print Network [OSTI]

    -synthesised to provide energy transport and storage for solar thermal power generation. When the concept was first-dissociation-based solar thermal storage method. AMMONIA-BASED SOLAR ENERGY STORAGE Fig. 1: An overview of energy storage of concentrating solar thermal energy to produce ammonia as an alternative to using this same energy to generate

  2. First satellite observations of lower tropospheric ammonia and methanol

    E-Print Network [OSTI]

    First satellite observations of lower tropospheric ammonia and methanol Reinhard Beer,1 Mark W) and methanol (CH3OH), well above the normal background levels. This is the first time that these molecules have. Citation: Beer, R., et al. (2008), First satellite observations of lower tropospheric ammonia and methanol

  3. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  4. Analysis of Instability in an Industrial Ammonia Reactor

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Instability in an Industrial Ammonia Reactor John C. Morud and Sigurd Skogestad Dept point for this study was an incident in an industrial plant, where the ammonia synthesis reactor became used to analyze the stability, but a more care@1 analysis for this reactor system reveals

  5. External Quality Assurance Services (EQAS) Ethanol/Ammonia Program

    E-Print Network [OSTI]

    Rodriguez, Carlos

    External Quality Assurance Services (EQAS) Ethanol/Ammonia Program BC35 12 x 3 mL 2 Analytes QC35 12 x 3 mL Specimen Only ENGLISH INTENDED USE Bio-Rad EQAS Ethanol/Ammonia Program is designed

  6. Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.

    E-Print Network [OSTI]

    Scoggins, Lacey E

    1959-01-01T23:59:59.000Z

    LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

  7. Proton transfer dynamics of the reaction H3O ,,NH3 ,H2O...NH4

    E-Print Network [OSTI]

    Farrar, James M.

    , Rochester, New York 14627 Received 29 September 2003; accepted 8 October 2003 The proton transfer reaction of H3O and NH3 was studied using the crossed molecular beam technique at relative energies of 0.41, 0.81, and 1.27 eV. At all three energies, the center-of-mass flux distribution of the product ion NH4 exhibits

  8. AMMONIA RECEIVER DESIGN FOR A 500m2 Rebecca Dunn, Keith Lovegrove, and Greg Burgess

    E-Print Network [OSTI]

    decomposition of ammonia to store solar energy. Ammonia passes alternately between energy-storing (dissociationAMMONIA RECEIVER DESIGN FOR A 500m2 DISH Rebecca Dunn, Keith Lovegrove, and Greg Burgess Solar 0200, Australia. Phone: +61 2 6125 4046. rebecca.dunn@anu.edu.au Abstract Previous ammonia receiver

  9. Ammonia volatilization from N fertilizers surface applied on bermudagrass

    E-Print Network [OSTI]

    Panossian, Jack B.

    1980-01-01T23:59:59.000Z

    . The biological activity was measured by trapping the CO in NaOH (0. 422 N). The NH3 which was volatilized from the urea was trapped in boric acid according to Bremner (1965). Volatilized NH and evolved CO were measured daily by titrating the boric acid and 13... was passed over the soil surface, then bubbled into boric acid to trap volatilized NH (Bremner, 1965). Humidified air was used to prevent rapid soil drying which would retard NH volatilization (Ernst and Massey, 1960). The apparatus is diagrammed in Fig. 1...

  10. Retrofits: A Means for Reducing Energy Consumption in Ammonia Manufacture

    E-Print Network [OSTI]

    LeBlanc, J. R.; Moore, D. O.; Schneider, R. V., III

    1982-01-01T23:59:59.000Z

    , be fore we proceed to that discussion, it would be help ful to make a purely theoretical analysis of what the potential energy savings might be. The reaction of methane with steam and air to form ammonia is shown below. CH4 + 1.3974H20'+ 0.301302 + 1... on an ammonia production rate of 1000 STPD using natural gas feed. The process is divided into the following three sections with utilities included as an additional section: Reforming and shift C02 removal and methanation Compression and ammonia synthesis...

  11. Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process

    SciTech Connect (OSTI)

    Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

    1983-01-01T23:59:59.000Z

    The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

  12. Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2013-09-06T23:59:59.000Z

    SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

  13. Ammonia volatilization from surface application of ammonium sulfate to carbonate systems

    E-Print Network [OSTI]

    Feagley, Sam Edward

    1976-01-01T23:59:59.000Z

    from surface application of' ammonium fertilizers to calcareous soils 7 Ammonia Volatilization from Limed, Acid Soil Comparison of ammonia vole, tilization from different ammonium fertilizers Other factors affecting ammonia volatilization 10...-Newman-Keul's multiple range analysis of ammonia volatilization from a limed, acid soil supporting Coastal bermudagrass as affected by calcium carbonate . 58 Student-Newman-Keul's multiple range analysis of ammonia volatilization i'rom a limed. , acid soil supporting...

  14. ammonia chemical ionization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionization processes (more) Ozawa, Takashi 2007-01-01 69 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. ammonia positron emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 185 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. ammonia emission factors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 103 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. ammonia compensation point: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    not only a unique opportunity to gain both Ghosh, Joydeep 54 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. ammonia fibre expansion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    John M; Genty, Goery; Murdoch, Stuart G 2014-01-01 73 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. ammonia borane complex: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    w x5-7 . Borane-triethylamine complex Boo, Jin-Hyo 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  20. ammonia electronic resource: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is not required such as with rehires Ronquist, Fredrik 63 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  1. ammonia final technical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 41 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  2. agricultural ammonia emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 113 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  3. ammonia triggers exocytotic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beauchemin, P; The ATLAS collaboration 2010-01-01 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  4. acid ammonia lyase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to forest health in the region. Sarah Jovan; Bruce Mccune 73 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia emission estimates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 153 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. ammonia gas sensing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donovan; Egusa, F; Momose, R; Robitaille, T P 2012-01-01 94 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. ammonia detection based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 357 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. ammonia oxidizer 16s: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16S ribosomal RNA (rRNA) is a central Walter, Nils G. 77 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  9. ammonia binding sites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    et al., 2009). A mRNA can Paris-Sud XI, Universit de 247 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. ammonia acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to forest health in the region. Sarah Jovan; Bruce Mccune 86 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. ammonia based co2: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time where tower levels 1-3 become Stanier, Charlie 418 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  12. ammonia solution activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be in excellent agreement with our recent Goodman, Wayne 57 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  13. ammonia emission trends: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 89 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. ammonia results review: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    requiring that 1m j m fl 0m ? 144 Me 109 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. ammonia synthesis catalyst: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    we are developing and promoting science-based methods 113 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. ammonia oxidizer community: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to nitrate. No organism in culture is known Ward, Bess 62 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. adsorb aqueous ammonia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has (more) Willett, Thomas Clifford 2009-01-01 39 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. ammonia mass transfer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    papers in the field of heat transfer Kandlikar, Satish 236 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. ammonia emission rate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 153 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  20. ammonia oxidizing bacterium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laszlo B. Kish; Maria D. King; Chiman Kwan 2009-01-20 63 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  1. ammonia emission inventories: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experience and Test Results From An Ammonia-Based DryWet Cooling System For Electric Power Stations Texas A&M University - TxSpace Summary: . In this concept, the reject...

  2. ammonia emission inventory: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experience and Test Results From An Ammonia-Based DryWet Cooling System For Electric Power Stations Texas A&M University - TxSpace Summary: . In this concept, the reject...

  3. Atmospheric ammonia and particulate inorganic nitrogen over the United States

    E-Print Network [OSTI]

    Heald, Colette L.

    We use in situ observations from the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network, the Midwest Ammonia Monitoring Project, 11 surface site campaigns as well as Infrared Atmospheric Sounding ...

  4. Energy Saving in Ammonia Plant by Using Gas Turbine 

    E-Print Network [OSTI]

    Uji, S.; Ikeda, M.

    1981-01-01T23:59:59.000Z

    An ammonia plant, in which the IHI-SULZER Type 57 Gas Turbine is integrated in order to achieve energy saving, has started successful operation. Tile exhaust gas of the gas turbine has thermal energy of relatively high temperature, therefore...

  5. Energy Saving in Ammonia Plant by Using Gas Turbine

    E-Print Network [OSTI]

    Uji, S.; Ikeda, M.

    1981-01-01T23:59:59.000Z

    An ammonia plant, in which the IHI-SULZER Type 57 Gas Turbine is integrated in order to achieve energy saving, has started successful operation. Tile exhaust gas of the gas turbine has thermal energy of relatively high temperature, therefore...

  6. How the Membrane Protein AmtB Transports Ammonia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Membrane Protein AmtB Transports Ammonia Print Membrane proteins provide molecular-sized entry and exit portals for the various substances that pass into and out of cells. While...

  7. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    P-20 UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Gi-Heon Kim, Matthew Thornton National Renewable Energy Laboratory...

  8. ammonia fuel cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ali as hydrogen (H2) storage compounds for fuel cell applications. Identify the pros and cons of using ammoniaBNH3) as a chemical hydrogen storage medium on-board fuel cell...

  9. Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2015-01-01T23:59:59.000Z

    Cu-SAPO-34 catalysts are synthesized using two methods: solid-state ion exchange (SSIE) and one-pot synthesis. SSIE is conducted by calcining SAPO-34/CuO mixtures at elevated temperatures. For the one-pot synthesis method, Cu-containing chemicals (CuO and CuSO4) are added during gel preparation. A high-temperature calcination step is also needed for this method. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies, and scanning electron microscopy (SEM). Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. In Cu-SAPO-34 samples formed using SSIE, Cu presents both as isolated Cu2+ ions and unreacted CuO. The former is highly active and selective in NH3-SCR, while the latter catalyzes a side reaction; notably, the non-selective oxidation of NH3 above 350 ºC. Using the one-pot method followed by a high-temperature aging treatment, it is possible to form Cu SAPO-34 samples with predominately isolated Cu2+ ions at low Cu loadings. However at much higher Cu loadings, isolated Cu2+ ions that bind weakly with the CHA framework and CuO clusters also form. These Cu moieties are very active in catalyzing non-selective NH3 oxidation above 350 ºC. Low-temperature reaction kinetics indicate that Cu-SAPO-34 samples formed using SSIE have core-shell structures where Cu is enriched in the shell layers; while Cu is more evenly distributed within the one-pot samples. Reaction kinetics also suggest that at low temperatures, the local environment next to Cu2+ ion centers plays little role on the overall catalytic properties. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle under contract number DE-AC05-76RL01830. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc. and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated.

  10. Kinetics Study of Solid Ammonia Borane Hydrogen Release – Modeling and Experimental Validation for Chemical Hydrogen Storage

    SciTech Connect (OSTI)

    Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

    2014-02-24T23:59:59.000Z

    Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200°C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300°C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20°C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

  11. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31T23:59:59.000Z

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  12. On rotational dynamics of an NH4+ ion in water

    SciTech Connect (OSTI)

    Chang, Tsun-Mei (University of Wisconsin-Parkside); Dang, Liem X. (BATTELLE (PACIFIC NW LAB))

    2003-05-15T23:59:59.000Z

    We used molecular dynamics simulations to characterize the rotational dynamics of the NH4+ ion in liquid water. The polarizable potential models were to describe the ion-water and water-water interactions. This study complements the work of Karim and Haymet (J. Chem. Phys., 93, 5961, 1990), who employed effective pir potential models. The computed rotational diffusion coefficients of the NH4+ ion in water, which were determined from the angular momentum autocorrelation function and the angular mean-square displacement, are 0.093 x 1012 rad2/s and 0.067 x 1012 rad2/s, repectively. These results are in good agreement with the 0.075 x 1012 rad2/s value determined from the nuclear magnetic resonance (NMR) spectroscopy studies of Perrin and Gipe (J. Am. Chem. Soc., 108, 1088, 1986; Science, 238, 1393, 1987).

  13. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Abstract: Multiple catalytic functions...

  14. Ammonia-treated phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Brow, R.K.; Day, D.E.

    1991-09-03T23:59:59.000Z

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  15. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Energy Savers [EERE]

    Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

  16. 3rd Generation SCR System Using Solid Ammonia Storage and Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

  17. Computer simulation and economic analysis for ammonia fiber explosion (AFEX) pretreatment process

    E-Print Network [OSTI]

    Wang, Lin

    1996-01-01T23:59:59.000Z

    The ammonia fiber explosion (AFFECT) process is a promising new pretreatment for enhancing the reactivity of lignocerulose materials with many advantages over existing processes. The material is soaked in high-pressure liquid ammonia for a few...

  18. Field measurements of ammonia volatilization from surface applications of nitrogen fertilizers to a calcareous soil

    E-Print Network [OSTI]

    Hargrove, W. L

    1977-01-01T23:59:59.000Z

    to measure volatilized NH3 in the labora- tory. A) Vacuum pump, B) Boric acid trap to collect volatilized NH ~ C) NH3 volatilization chamber, D) Trkp to re- move NH3 from incoming air . . . . . . . . . . . 21 A schematic of the apparatus used to make... direct measurements of NH losses in the field. A) Vacuum pum), B) Boric acid trap, C) NH volatilization chamber, consisting of metal cylinder and plexi- glass top The cumulative NH losses over time for four rates of' a)plication of urea...

  19. Energy Savings for CO2 Removal in Ammonia Plants

    E-Print Network [OSTI]

    Pouilliart, R.; Van Hecke, F. C.

    1981-01-01T23:59:59.000Z

    An exergy analysis of carbonate solution C02 removal systems which use solution flashing shows that there is no energy saving by using a mechanical thermocompressor instead of a steam-jet ejector. In a 1000 ShT/D ammonia plant an energy saving...

  20. Corrosion protection of steel in ammonia/water heat pumps

    DOE Patents [OSTI]

    Mansfeld, Florian B.; Sun, Zhaoli

    2003-10-14T23:59:59.000Z

    Corrosion of steel surfaces in a heat pump is inhibited by adding a rare earth metal salt to the heat pump's ammonia/water working fluid. In preferred embodiments, the rare earth metal salt includes cerium, and the steel surfaces are cerated to enhance the corrosion-inhibiting effects.

  1. Membrane Based intensification of ammonia removal from wastewater

    E-Print Network [OSTI]

    Almutairi, Azel

    2011-12-31T23:59:59.000Z

    .25, and 0.03 Kg N/(m3day) depending on the type of the experiment. For the bacteria-free silicon membrane column, the inlet ammonia concentration, bed height, and inlet flowrate were examined. Biologically activated silicon membrane column exhibited...

  2. Original article Ammonia treatment of lucerne and cocksfoot

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Ammonia treatment of lucerne and cocksfoot harvested at two growth stages: Effect and the end of first growth. Lucerne and cocksfoot samples were treated with 30 g ammo- nia per kg DM for 4 and pepsin-cellulase digestibilities of dry matter (DM) and cell walls (CW). Lucerne had a very different CW

  3. Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part II. Recovery of Ammonia from Sour Waters

    E-Print Network [OSTI]

    Poole, L.J.

    2008-01-01T23:59:59.000Z

    oil the or HzS compounds to injection of NH 3 fractionator overhead systems neutralize and thereby prevent corrosion

  4. Ammonia availability shapes the seasonal distribution and activity of archaeal and bacterial ammonia oxidizers in the Puget Sound Estuary

    E-Print Network [OSTI]

    de la Torre, José R.

    ammonia oxidizers in the Puget Sound Estuary Hidetoshi Urakawa,1,a,* Willm Martens-Habbena,1 Carme Huguet, a fjord within the Puget Sound, Washington State estuary system. A greater contribution of AOA numbers of AOA in Hood Canal, a fjord in the Puget Sound estuary system (Urakawa et al. 2010; Horak et al

  5. Array-type NH.sub.3 sensor

    DOE Patents [OSTI]

    West, David Lawrence; Montgomery, Frederick Charles; Armstrong, Timothy R; Warmack, Robert J

    2013-12-31T23:59:59.000Z

    An array-type sensor that senses NH.sub.3 includes non-Nernstian sensing elements constructed from metal and/or metal-oxide electrodes on an O.sub.2 ion conducting substrate. In one example sensor, one electrode may be made of platinum, another electrode may be made of manganese (III) oxide (Mn.sub.2O.sub.3), and another electrode may be made of tungsten trioxide (WO.sub.3). Some sensing elements may further include an electrode made of La.sub.0.6Sr.sub.0.4Co.sub.0.2Fe.sub0.8O.sub.3 and another electrode made of LaCr.sub.0.95.Mg.sub.0.05O.sub.3.

  6. Indium and impurity incorporation in InGaN films on polar, nonpolar, and semipolar GaN orientations grown by ammonia molecular beam epitaxy

    SciTech Connect (OSTI)

    Browne, David A.; Young, Erin C.; Lang, Jordan R.; Hurni, Christophe A.; Speck, James S. [Materials Department, University of California Santa Barbara, Santa Barbara, California 93106 (United States)

    2012-07-15T23:59:59.000Z

    The effects of NH{sub 3} flow, group III flux, and substrate growth temperature on indium incorporation and surface morphology have been investigated for bulk InGaN films grown by ammonia molecular beam epitaxy. The incorporation of unintentional impurity elements (H, C, O) in InGaN films was studied as a function of growth temperature for growth on polar (0001) GaN on sapphire templates, nonpolar (1010) bulk GaN, and semipolar (1122), (2021) bulk GaN substrates. Enhanced indium incorporation was observed on both (1010) and (2021) surfaces relative to c-plane, while reduced indium incorporation was observed on (1122) for co-loaded conditions. Indium incorporation was observed to increase with decreasing growth temperature for all planes, while being relatively unaffected by the group III flux rates for a 1:1 Ga:In ratio. Indium incorporation was found to increase at the expense of a decreased growth rate for higher ammonia flows; however, smooth surface morphology was consistently observed for growth on semipolar orientations. Increased concentrations of oxygen and hydrogen were observed on semipolar and nonpolar orientations with a clear trend of increased hydrogen incorporation with indium content.

  7. Toxicity and acclimation to ammonia by Tilapia aurea

    E-Print Network [OSTI]

    Redner, Barry Duncan

    1978-01-01T23:59:59.000Z

    operations (Spoti:e, 1970). Sroart (1976) noticed rela . i. vely m'. nor histopathological changes in the gill" of trout when given an acute dcse of ammonia. Ch onic ammonia poI. sosI. ng, however, may d?seg the tissues of the gilI, , kin, 1!&testiue, I... of urine pro- &8&orion declined until it aporoack. ed a rate on!y slightly, :oat& r "han tii& pret sc; slue. , The rr suits were due, tl. . ey '1&cerise&i, t o redo?e k tissue p&trm-abihity wr;tch at loi. 8 th& fi . ki to to'tera'e c&&u ritrat 1 oos...

  8. NH3 generation over commercial Three-Way Catalysts and Lean-NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Emissions Control for Lean Gasoline Engines Emissions Control for Lean Gasoline Engines Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and...

  9. Adsorption analysis of ammonia in an aqueous solution

    SciTech Connect (OSTI)

    Arman, B.; Panchal, C.B.

    1993-08-01T23:59:59.000Z

    An analysis is carried out to determine the effects of the diffusional resistance on the rate of the adsorption of ammonia in an aqueous solution. A performance prediction model is developed to calculate the local rate of heat and mass transfer, including physical and thermodynamic property calculations of the mixture. An algorithm is developed for calculating the interfacial conditions. The local heat- and mass-transfer calculation is then incorporated into the performance prediction method for adsorption for a given geometry.

  10. Ammonia volatilization from soils with surface rice straw residue

    E-Print Network [OSTI]

    Barghassa, Peyam

    1995-01-01T23:59:59.000Z

    rice residue and related factors on NH3 volatilization from an acid Beaumont clay (pH 5.4) and an alkaline Lake Charles clay (pH 7.4). The treatments in the greenhouse and lab consisted of all possible combinations of the following variables: surface...

  11. Continued investigations of the catalytic reduction of N? to NH? by molybdenum triamidoamine complexes

    E-Print Network [OSTI]

    Hanna, Brian S. (Brian Stewart)

    2011-01-01T23:59:59.000Z

    A study of the effects of employing different solvents and the introduction of dihydrogen during the catalytic reduction of dinitrogen to ammonia with [HIPTN 3N]Mo complexes was completed. During a catalytic reaction, the ...

  12. SYSTEMS MODELING OF AMMONIA BORANE BEAD REACTOR FOR OFF-BOARD REGENERABLE HYDROGEN STORAGE IN PEM FUEL CELL APPLICATIONS

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; King, Dale A.; Herling, Darrell R.

    2010-06-01T23:59:59.000Z

    Out of the materials available for chemical hydrogen storage in PEM fuel cell applications, ammonia borane (AB, NH3BH3) has a high hydrogen storage capacity (upto 19.6% by weight for the release of three hydrogen molecules). Therefore, AB was chosen in our chemical hydride simulation studies. A model for the AB bead reactor system was developed to study the system performance and determine the energy, mass and volume requirements for off-board regenerable hydrogen storage. The system includes hot and cold augers, ballast tank and reactor, product tank, H2 burner and a radiator. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure in the reactor system. Control signals to various components are governed by a control system which is modeled as an independent subsystem. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. Preliminary system simulation results for a start-up case and for a transient drive cycle indicate accurate trends in the reactor system dynamics.

  13. The effect of dietary protein and fiber on in vivo ammonia concentration

    E-Print Network [OSTI]

    Marchant, Linda Jean

    1986-01-01T23:59:59.000Z

    diffusion (65, 85), the more acidic the colonic contents the less absorption of ammonia should occur. In theory, then, it may be possible to counteract the potentially negative effects of a high protein diet by the addition of the appropriate type... ammonia concentration, possibly through the deamination of ingested protein. Although deamination of dietary protein by the intestinal microflora is the primary determinant of ammonia production, Krebs (45) demonstrated the presence of an L-amino acid...

  14. Proposed replacement and operation of the anhydrous hydrogen fluoride supply and fluidized-bed chemical processing systems at Building 9212, Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The US Department of Energy (DOE) proposes to replace the existing anhydrous hydrogen fluoride (AHF) supply and fluidized-bed reactor systems for the Weapons Grade Highly Enriched Uranium Chemical Recovery and Recycle Facility, Building 9212, which is located within the Y-12 Plant on DOE`s Oak Ridge Reservation in Oak Ridge, Tennessee. The proposed replacement system would be based upon modern design criteria and safety analyses. The replacement AHF supply and distribution system equipment would be located on the existing Dock 8/8A at Building 9212. Utilities would be extended to the dock to service the process equipment. The following process equipment modules would be prefabricated for installation at the modified dock: an AHF cylinder enclosure, an AHF supply manifold and vaporizer module, an AHF sump tank and transfer skid, and an AHF supply off-gas scrubber assembly module. The fluidized-bed reactor system would be constructed in an area adjacent to the existing system in Building 9212. The replacement equipment would consist of a new reduction fluidized-bed reactor, a hydrofluorination fluidized-bed reactor, and associated air emission control equipment. The no-action alternative, which is the continued operation of the existing AHF supply and fluidized-bed reactor systems, was also evaluated.

  15. Inhibition effects of N,N-dimethylalkylamines and octanethiol on iron corrosion in anhydrous acetonitrile solution containing FeCl{sub 3}

    SciTech Connect (OSTI)

    Aramaki, Kunitsugu; Kikuchi, Takeshi

    2000-05-01T23:59:59.000Z

    Polarization and impedance measurements were carried out on an iron electrode in an anhydrous acetonitrile solution of 0.1 M LiClO{sub 4} and 0.01 M FeCl{sub 3} containing organic corrosion inhibitors. The inhibitors investigated were N,N-dimethylalkylamines C{sub n}H{sub 2n+1}N(CH{sub 3}){sub 2} (C{sub n}DMA, n = 8, 12, 16, and 18) and octanethiol C{sub 8}H{sub 17}SH (C{sub 8}T). These compounds suppressed both cathodic and anodic processes of iron corrosion in the acetonitrile solution. The double-layer capacitances obtained from impedance data for the electrode inhibited with C{sub n}DMA were markedly lower in the potential region of the cathodic polarization curve than those for the uninhibited electrode. Ultraviolet and visible spectra of the FeCl{sub 3} acetonitrile solution containing C{sub n}DMA revealed the formation of a Fe{sup 3+} complex cation with C{sub n}DMA, and joint adsorption of the complex cation with Cl{sup {minus}} on the iron surface was substantiated by X-ray photoelectron spectroscopy of the surface treated with the solution. A surface thiolate of C{sub 8}T was formed by its chemisorption on the iron surface, resulting in a decrease in the double-layer capacitance and the cathodic and anodic current densities, respectively.

  16. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, andor CaH2) Composite Systems. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

  17. ammonia oxidation pt pd rd: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    research into controlling nanocrystal Castell, Martin 216 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling On-Board Measurement of...

  19. System and method for determining an ammonia generation rate in a three-way catalyst

    DOE Patents [OSTI]

    Sun, Min; Perry, Kevin L; Kim, Chang H

    2014-12-30T23:59:59.000Z

    A system according to the principles of the present disclosure includes a rate determination module, a storage level determination module, and an air/fuel ratio control module. The rate determination module determines an ammonia generation rate in a three-way catalyst based on a reaction efficiency and a reactant level. The storage level determination module determines an ammonia storage level in a selective catalytic reduction (SCR) catalyst positioned downstream from the three-way catalyst based on the ammonia generation rate. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the ammonia storage level.

  20. The Fusion Curve of Ammonia and Ethyl Alcohol

    E-Print Network [OSTI]

    Broderson, H.J.

    1911-01-01T23:59:59.000Z

    ’ Center for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the Graduate School of the University of Kansas for partial completion of Master of Arts. THE FUSION CURVE OF AMMONIA AND ETHYL ALCOHOL H. J. BRODERSON THE 2?03IOH CUHVB OP... AMMOHIA AND ETHXL ALCOHOL. A part of the requirement for the lh A. 2)egree. By K. J. Brodereon, University of Kangaa, May 1911, THE PUSIOB CURVS OP AliKOHlA AHD ETHYL ALCOHOL* Only within tho last fow ycara has any worlc boon done on tho fusion...

  1. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    DTIC Review: Energy Supply Alternatives: ADA433359, 2004.Ammonia as an Alternative Energy Storage Medium for Hydrogen2007 Ammonia As an Alternative Energy Storage Medium for

  2. Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic and anthropogenic precursors

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic t aerosols change color from white to brown in pres- ence of ammonia. occurs for a wide range of biogenic and anthropogenic aerosols.

  3. Interaction of far-infrared and mid-infrared laser transitions in the ammonia laser

    SciTech Connect (OSTI)

    Nelson, L.Y.; Buchwald, M.I.; Jones, C.R.

    1980-01-01T23:59:59.000Z

    Mid-infrared laser emission in ammonia is usually observed on a P(J + 2) transition when a CO/sub 2/ laser is used to optically pump a near resonant R(J) absorption feature. However, by generating simultaneous FIR ammonia laser emission in the same optical cavity, mid-infrared emission is obtained exclusively on the P(J) transition.

  4. Sub-lethal ammonia toxicity in largemouth bass C.D. Suski a,,1

    E-Print Network [OSTI]

    Suski, Cory David

    . Exposure to 100 M Tamm impaired the ability of largemouth bass to recover from exercise relative to fishSub-lethal ammonia toxicity in largemouth bass C.D. Suski a,,1 , J.D. Kieffer b , S.S. Killen a,2 Available online 24 November 2006 Abstract Guidelines for ammonia toxicity in fish are often determined

  5. Anaerobic digestion for methane generation and ammonia reforming for hydrogen production

    E-Print Network [OSTI]

    ,000,000 digesters, 2000 [14]), among other places [15,16]. These digesters operate to generate biogas, comprisingAnaerobic digestion for methane generation and ammonia reforming for hydrogen production Accepted 24 May 2013 Available online Keywords: Anaerobic digestion Ammonia Bioenergy Bioammonia Hydrogen

  6. Assessment of research and development (R and D) needs in ammonia safety and environmental control

    SciTech Connect (OSTI)

    Brenchley, D.L.; Athey, G.F.; Bomelburg, H.J.

    1981-09-01T23:59:59.000Z

    This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)

  7. Measurement of Ammonia Emissions from Laying Hen Houses , Y. Liang2

    E-Print Network [OSTI]

    Kentucky, University of

    Measurement of Ammonia Emissions from Laying Hen Houses H. Xin1 , Y. Liang2 , R.S. Gates3 , E. F be included in the measurement to make the results representative of the production practices; relatively the sustainability of the animal industry. This paper describes measurement and some preliminary results of ammonia

  8. Studies of the Ammonia-soluble Organic Matter of the Soil.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Hamner, N.C.

    1910-01-01T23:59:59.000Z

    to Remove Clay 15 ........................................ Precipitation of the Humic Acid 17 ................................... Effect of Extended Washing with Acid 18 ................................. Effect of Various Strengths of Ammonia 19 PART... Salts 36 .................................................... Effect of Ammonia 37 .............................. Effect of Carbonates of Lime and Magnesia '37 .............................................. Hydrolysis of Humic Acid 38...

  9. ammonia-water absorption cycle: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ammonia-water absorption cycle First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 AN AMMONIA-WATER...

  10. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20T23:59:59.000Z

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  11. On-board ammonia generation and exhaust after treatment system using same

    DOE Patents [OSTI]

    Driscoll, Josh (Dunlap, IL); Robel, Wade J. (Peoria, IL); Brown, Cory A. (Pekin, IL); Urven, Jr., Roger L. (Colona, IL)

    2010-03-30T23:59:59.000Z

    Often NOx selective catalysts that use ammonia to reduce NOx within exhaust to a harmless gas require on-board storage of ammonia which can be hazardous and inconvenient. In order to generate ammonia in exhaust, the present disclosure increases a NOx concentration in exhaust from at least one combustion chamber, at least in part, by injecting fuel in a predetermined increased NOx generation sequence that includes a first injection during non-auto ignition conditions and a second injection during auto ignition conditions. At least a portion of the NOx is converted to ammonia by passing at least a portion of the exhaust with the increased NOx concentration over an ammonia-producing catalyst.

  12. Experimental and theoretical studies of reactions of neutral vanadium and tantalum oxide clusters with NO and NH3

    E-Print Network [OSTI]

    Rocca, Jorge J.

    molecules on the respective clusters. A gas mixture of NO:NH3 9:1 is also added into the fast flow reactor oxide clusters with NO, NH3, and an NO/NH3 mixture in a fast flow reactor are investigated by time, a complete elucidation of the reaction mechanism has not been achieved, and very few, if any, gas phase

  13. Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)

    SciTech Connect (OSTI)

    You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

    2014-11-19T23:59:59.000Z

    We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

  14. Characterization of Cu-SSZ-13 NH3 SCR Catalysts: an in situ FTIR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cu-SSZ-13 NH3 SCR Catalysts: an in situ FTIR Study. Abstract: The adsorption of CO and NO over Cu-SSZ-13 zeolite catalysts, highly active in the selective...

  15. Fe/SSZ-13 as an NH3-SCR Catalyst: A Reaction Kinetics andFTIR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as an NH3-SCR Catalyst: A Reaction Kinetics and FTIRMssbauer Spectroscopic Study."Applied Catalysis. B, Environmental 164:407-419. doi:10.1016j.apcatb.2014.09.031 Authors:...

  16. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hu, JH Kwak, and Z Yang.2009."Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System."International Journal of Hydrogen Energy 34(10):4331-4339. doi:10.1016...

  17. Structures of the Kplus and NH4 Forms of Linde J

    SciTech Connect (OSTI)

    R Broach; R Kirchner

    2011-12-31T23:59:59.000Z

    The aluminosilicate zeolite Linde J has a unique topology. The structures of the K{sup +} and NH{sub 4}{sup +} forms of Linde J ([X{sub 2}(H{sub 2}O)][Si{sub 2}Al{sub 2}O{sub 8}] where X = K or NH{sub 4}) are identical except for slight cell size and positional differences due to NH{sub 4}{sup +} being larger than K{sup +} cations. The space group is P2{sub 1}2{sub 1}2{sub 1}. Cell dimensions are: K{sup +} Linde J, a = 9.4577(2) {angstrom}, b = 9.5573(2) {angstrom}, c = 9.9429(2) {angstrom}; NH{sub 4}{sup +} Linde J, a = 9.6324(4) {angstrom}, b = 9.6423(3) {angstrom}, c = 10.0230(3) {angstrom}. Zigzag 8-ring channels intersect giving a 2-D pore system.

  18. Structures of the K[superscript +] and NH[subscript 4 superscript +] forms of Linde J

    SciTech Connect (OSTI)

    Broach, Robert W.; Kirchner, Richard M. (UOP); (Manhattan C)

    2011-11-17T23:59:59.000Z

    The aluminosilicate zeolite Linde J has a unique topology. The structures of the K{sup +} and NH{sub 4}{sup +} forms of Linde J ([X{sub 2}(H{sub 2}O)][Si{sub 2}Al{sub 2}O{sub 8}] where X = K or NH{sub 4}) are identical except for slight cell size and positional differences due to NH{sub 4}{sup +} being larger than K{sup +} cations. The space group is P2{sub 1}2{sub 1}2{sub 1}. Cell dimensions are: K{sup +} Linde J, a = 9.4577(2) {angstrom}, b = 9.5573(2) {angstrom}, c = 9.9429(2) {angstrom}; NH{sub 4}{sup +} Linde J, a = 9.6324(4) {angstrom}, b = 9.6423(3) {angstrom}, c = 10.0230(3) {angstrom}. Zigzag 8-ring channels intersect giving a 2-D pore system.

  19. Rare Earth ? N = N* fs fGHZ fp nH fl

    E-Print Network [OSTI]

    Walter, Frederick M.

    Rare Earth ? #12;N to date N = N* fs fGHZ fp nH fl ·N* = 4 x 1011 ·fs = 0.2 ·fGHZ = 0.1 ·fp = 0.8 ·nH = 2 ·fl = 1.0 N = 1.3 x 1010 #12;The Goldilocks Effect Earth is "Just Right" Yes, life on Earth has adapted to Earth, but ... Earth has just the right mass to be ·Tectonically-active ·Retain

  20. Breath gating of cardiac PET using 13N-NH3: An optimization

    E-Print Network [OSTI]

    was carried out using 13 N-NH3 on two dierent PET/CT scanners: a Siemens Biograph 64 and a Siemens mCT PET. In this project the breath-motion was estimated using an ane transformation on the obtained images, from which- jekt er udført ved brug af 13 N-NH3 på to skannere, henholdsvis en Siemens Biograph 64 og en Siemens m

  1. Direct measurement of the reactivity of NH and OH on a silicon nitride surface

    SciTech Connect (OSTI)

    Buss, R.J.; Ho, P.; Breiland, W.G. [Sandia National Labs., Albuquerque, NM (United States); Fisher, E.R. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Chemistry

    1993-12-31T23:59:59.000Z

    In order to understand and successfully model the plasma processing used in device fabrication, it is important to determine the role played by plasma-generated radicals. The authors have used the IRIS technique (Imaging of Radicals Interacting Surfaces) to obtain the reactivity of NH (X{sup 3}S{sup {minus}}) and OH (X{sup 2}P) at a silicon nitride film surface while the film is exposed to a plasma-type environment. The reactivity of NH was found to be zero both during exposure of the surface to an NH{sub 3} plasma and during active deposition of silicon nitride from a SiH{sub 4}/NH{sub 3} plasma. No NH surface reaction was detectable for any rotational states of NH and over a surface temperature range of 300--700 K. OH radicals generated in an H{sub 2}O plasma were found to have a reactivity of 0.57 on a room temperature oxidized silicon nitride surface. The OH reactivity falls to zero as the temperature of the substrate is raised.

  2. Exhaust purification with on-board ammonia production

    DOE Patents [OSTI]

    Robel, Wade J. (Peoria, IL); Driscoll, James J. (Dunlap, IL); Coleman, Gerald N. (Peterborough, GB); Knox, Kevin J. (Peoria, IL)

    2009-06-30T23:59:59.000Z

    A power source is provided for use with selective catalytic reduction systems for exhaust-gas purification. The power source includes a first cylinder group with a first air-intake passage and a first exhaust passage, and a second cylinder group with a second air-intake passage and a second exhaust passage. The second air-intake passage is fluidly isolated from the first air-intake passage. A fuel-supply device may be configured to supply fuel into the first exhaust passage, and a catalyst may be disposed downstream of the fuel-supply device to convert at least a portion of the exhaust stream in the first exhaust passage into ammonia.

  3. Correlating Particle Size and Shape of Supported Ru/-Al2O3 Catalysts with NH3 Decomposition Activity

    E-Print Network [OSTI]

    Frenkel, Anatoly

    decomposi- tion as a CO-free source of hydrogen for fuel cells. In addition, ammonia is a good hydrogen to be responsible for the observed activity. 1. Introduction There has been an increasing interest in ammonia the chemistry happening primarily on B5-type step (active) sites.8,12 Yet, limited direct information exists

  4. Recovery of anhydrous hydrogen iodide

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); McCorkle, Jr., Kenneth H. (Del Mar, CA); de Graaf, Johannes D. (The Hague, NL)

    1982-01-01T23:59:59.000Z

    Relatively dry hydrogen iodide can be recovered from a mixture of HI, I.sub.2 and H.sub.2 O. After the composition of the mixture is adjusted so that the amounts of H.sub.2 O and I.sub.2 do not exceed certain maximum limits, subjection of the mixture to superatmospheric pressure in an amount equal to about the vapor pressure of HI at the temperature in question causes distinct liquid phases to appear. One of the liquid phases contains HI and not more than about 1 weight percent water. Often the adjustment in the composition will include the step of vaporization, and the distinct layers appear following the increase in pressure of the vapor mixture. Adjustment in the composition may also include the addition of an extraction agent, such as H.sub.3 PO.sub.4, and even though the adjusted composition mixture contains a significant amount of such an agent, the creation of the distinct liquid phases is not adversely affected.

  5. Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii

    E-Print Network [OSTI]

    Llobrera, Jose Alvarez

    1979-01-01T23:59:59.000Z

    , [Ammonia-N] = the measured concentration of total ammonia as nitrogen, pK' = the mixed acidity-constant of the reaction, pH = the measured pH of the solution. The pK ' value for 12 ppt salinity solutions can be a computed using the procedure outlined...TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM R OSENBERGI I A Thesis by JOSE ALVAREZ LLOBRERA Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree...

  6. Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts

    SciTech Connect (OSTI)

    Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

    1999-09-10T23:59:59.000Z

    Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

  7. Fixed Bed Adsorption of Acetone and Ammonia onto Oxidized Activated Carbon Fibers

    E-Print Network [OSTI]

    Braatz, Richard D.

    Fixed Bed Adsorption of Acetone and Ammonia onto Oxidized Activated Carbon Fibers Christian L a fixed bed configuration. An oxidation treatment with nitric and sulfuric acids resulted in a significant

  8. Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions

    E-Print Network [OSTI]

    Zender, Charles

    1 Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions Chao Luo1 , Charles S. Zender1 , Huisheng Bian2 , Swen Metzger3 Abstract We use an inorganic aerosol thermodynamic equilibrium model

  9. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01T23:59:59.000Z

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  10. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  11. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  12. Carbon Capture by a Continuous, Regenerative Ammonia-Based Scrubbing Process

    SciTech Connect (OSTI)

    Resnik, K.P.; Yeh, J.T.; Pennline, H.W.

    2006-10-01T23:59:59.000Z

    Overview: To develop a knowledge/data base to determine whether an ammonia-based scrubbing process is a viable regenerable-capture technique that can simultaneously remove carbon dioxide, sulfur dioxide, nitric oxides, and trace pollutants from flue gas.

  13. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    2014: Robust Nitrogen oxideAmmonia Sensors for Vehicle on-board Emissions Control CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  14. Ris-R-1504(EN) Safety assessment of ammonia as a

    E-Print Network [OSTI]

    as part of the EU supported project "Ammonia Cracking for Clean Electric Power Technology" The study scenarios 17 2.4 Comparison with LPG driven vehicles 17 2.5 Comparison with gasoline-driven cars 18 2

  15. Effects of lysine nutrition on production characteristics and ammonia excretion of red drum Sciaenops ocellatus

    E-Print Network [OSTI]

    Webb, Kenneth Ashley

    2002-01-01T23:59:59.000Z

    satiation twice daily for 6 weeks after which total ammonia nitrogen (TAN) excretion at 4-h postprandial was determined. Diets supplemented with crystalline amino acids supported similar weight gain (94 - 98%) as that obtained by fish fed control diets...

  16. Modeling of selective catalytic reduction (SCR) of nitric oxide with ammonia using four modern catalysts

    E-Print Network [OSTI]

    Sharma, Giriraj

    2005-11-01T23:59:59.000Z

    values of the SCR process parameters, namely temperature, inlet oxygen concentration and inlet ammonia concentration. The NOx emission, its formation and control methods are discussed briefly and then the fundamentals of the SCR process are described...

  17. Bioassimilation versus nitrification for the removal of ammonia in aquaculture biofilters

    E-Print Network [OSTI]

    Kamps, Ray Herbert

    1996-01-01T23:59:59.000Z

    not receive an organic load, the glucose-loaded biofilters tended to accumulate more biomass. However, that the difference in the fraction of ammonia converted to biomass was non-significant indicates that a third process, heterotrophic nitrification-denitrification...

  18. A Complete Survey of the Central Molecular Zone in NH3

    E-Print Network [OSTI]

    Takumi Nagayama; Toshihiro Omodaka; Toshihiro Handa; Hayati Bebe Hajra Iahak; Tsuyoshi Sawada; Takeshi Miyaji; Yasuhiro Koyama

    2007-07-06T23:59:59.000Z

    We present a map of the major part of the central molecular zone (CMZ) of simultaneous observations in the NH3 (J,K) = (1,1) and (2,2) lines using the Kagoshima 6-m telescope. The mapped area is -1.000 80 K contain 75% and 25% of the total NH3 flux, respectively. These temperatures indicate that the dense molecular gas in the CMZ is dominated by gas that is warmer than the majority of the dust present there. A comparison with the CO survey by Sawada et al. (2001) shows that the NH3 emitting region is surrounded by a high pressure region on the l-v plane. Although NH3 emission traces dense gas, it is not extended into a high pressure region. Therefore, the high pressure region is less dense and has to be hotter. This indicates that the molecular cloud complex in the Galactic center region has a ``core'' of dense and warm clouds which are traced by the NH3 emission, and an ``envelope'' of less dense and hotter gas clouds. Besides heating by ambipolar diffusion, the hot plasma gas emitting the X-ray emission may heat the hot ``envelope''.

  19. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction

    SciTech Connect (OSTI)

    Schmieg, Steven J.; Oh, Se H.; Kim, Chang H.; Brown, David B.; Lee, Jong H.; Peden, Charles HF; Kim, Do Heui

    2012-04-30T23:59:59.000Z

    Multiple catalytic functions (NOx conversion, NO and NH3 oxidation, NH3 storage) of a commercial Cu-zeolite urea/NH3-SCR catalyst were assessed in a laboratory fixed-bed flow reactor system after differing degrees of hydrothermal aging. Catalysts were characterized by using x-ray diffraction (XRD), 27Al solid state nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) / energy dispersive X-ray (EDX) spectroscopy to develop an understanding of the degradation mechanisms during catalyst aging. The catalytic reaction measurements of laboratory-aged catalysts were performed, which allows us to obtain a universal curve for predicting the degree of catalyst performance deterioration as a function of time at each aging temperature. Results show that as the aging temperature becomes higher, the zeolite structure collapses in a shorter period of time after an induction period. The decrease in SCR performance was explained by zeolite structure destruction and/or Cu agglomeration, as detected by XRD/27Al NMR and by TEM/EDX, respectively. Destruction of the zeolite structure and agglomeration of the active phase also results in a decrease in the NO/NH3 oxidation activity and the NH3 storage capacity of the catalyst. Selected laboratory aging conditions (16 h at 800oC) compare well with a 135,000 mile vehicle-aged catalyst for both performance and characterization criteria.

  20. Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Llobrera, Jose Alvarez

    1979-01-01T23:59:59.000Z

    TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM R OSENBERGI I A Thesis by JOSE ALVAREZ LLOBRERA Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE May 1979 Major Subject: Wildlife and Fisheries Sciences TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM ROSENBERGI I A Thesis JOSE ALVAREZ LLOBRERA Approved as to style and content by: (Chairman...

  1. Development of an ammonia emission protocol and preliminary emission factor for a central Texas dairy

    E-Print Network [OSTI]

    Rose, Adam Joseph

    2004-09-30T23:59:59.000Z

    dairies. The Texas Commission on Environmental Quality (TCEQ), the Texas SAPRA, does not currently use an emission factor to permit or regulate emitted ammonia for the dairy industry. ________________________ This thesis follows the style..., and is subject to gas-phase reaction with photochemically produced hydroxyl (-OH) radicals, reaction with gaseous nitric acid (to form particulate ammonium nitrate), and with aerosols to form ammonium salts (Singh et al., 2001). Ammonia that does not react...

  2. Simulation and performance analysis of basic GAX and advanced GAX cycles with ammonia/water and ammonia/water/LiBr absorption fluids

    SciTech Connect (OSTI)

    Zaltash, A.; Grossman, G.

    1996-03-01T23:59:59.000Z

    The generator-absorber heat exchange (GAX) and branched GAX cycles are generally considered with NH{sub 3}/H{sub 2}O as their working fluid. The potential consequences of using a ternary mixture of NH{sub 3}/H{sub 2}O/LiBr (advanced fluids) in the GAX and Branched GAX (advanced cycles) are discussed in this study. A modular steady state absorption simulation model(ABSIM) was used to investigate the potential of combining the above advanced cycles with the advanced fluids. ABSIM is capable of modeling varying cycle configurations with different working fluids. Performance parameters of the cycles, including coefficient of performance (COP) and heat duties, were investigated as functions of different operating parameters in the cooling mode for both the NH {sub 3}/H{sub 2}O binary and the NH{sub 3}/H{sub 2}O/LiBr ternary mixtures. High performance potential of GAX and branched GAX cycles using the NH{sub 3}/H{sub 2}O/LiBr ternary fluid mixture was achieved especially at the high range of firing temperatures exceeding 400{degrees}F. The cooling COP`s have been improved by approximately 21% over the COP achieved with the NH{sub 3}/H{sub 2}O binary mixtures. These results show the potential of using advanced cycles with advanced fluid mixtures (ternary or quaternary fluid mixtures).

  3. Characterization of ammonia emissions from ground level area sources at central texas dairies

    E-Print Network [OSTI]

    Mutlu, Atilla

    2009-05-15T23:59:59.000Z

    ) to potentially develop source specific NH3 emission control strategies. The GLAS including open-lots, free-stall barns, separated solids, primary and secondary lagoons and milking parlor were sampled to estimate NH3 emissions. In the first study, assessment...

  4. A Review & Assessment of Current Operating Conditions Allowable Stresses in ASME Section III Subsection NH

    SciTech Connect (OSTI)

    R. W. Swindeman

    2009-12-14T23:59:59.000Z

    The current operating condition allowable stresses provided in ASME Section III, Subsection NH were reviewed for consistency with the criteria used to establish the stress allowables and with the allowable stresses provided in ASME Section II, Part D. It was found that the S{sub o} values in ASME III-NH were consistent with the S values in ASME IID for the five materials of interest. However, it was found that 0.80 S{sub r} was less than S{sub o} for some temperatures for four of the materials. Only values for alloy 800H appeared to be consistent with the criteria on which S{sub o} values are established. With the intent of undertaking a more detailed evaluation of issues related to the allowable stresses in ASME III-NH, the availabilities of databases for the five materials were reviewed and augmented databases were assembled.

  5. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

    2007-08-14T23:59:59.000Z

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  6. Nitridation under ammonia of high surface area vanadium aerogels

    SciTech Connect (OSTI)

    Merdrignac-Conanec, Odile [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)]. E-mail: odile.merdrignac@univ-rennes1.fr; El Badraoui, Khadija [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); L'Haridon, Paul [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

    2005-01-15T23:59:59.000Z

    Vanadium pentoxide gels have been obtained from decavanadic acid prepared by ion exchange on a resin from ammonium metavanadate solution. The progressive removal of water by solvent exchange in supercritical conditions led to the formation of high surface area V{sub 2}O{sub 5}, 1.6H{sub 2}O aerogels. Heat treatment under ammonia has been performed on these aerogels in the 450-900 deg. C temperature range. The oxide precursors and oxynitrides have been characterized by XRD, SEM, TGA, BET. Nitridation leads to divided oxynitride powders in which the fibrous structure of the aerogel is maintained. The use of both very low heating rates and high surface area aerogel precursors allows a higher rate and a lower threshold of nitridation than those reported in previous works. By adjusting the nitridation temperature, it has been possible to prepare oxynitrides with various nitrogen enrichment and vanadium valency states. Whatever the V(O,N) composition, the oxidation of the oxynitrides in air starts between 250 and 300 deg. C. This determines their potential use as chemical gas sensors at a maximum working temperature of 250 deg. C.

  7. High-power terahertz optically pumped NH{sub 3} laser for plasma diagnostics

    SciTech Connect (OSTI)

    Mishchenko, V. A.; Petrushevich, Yu. V.; Sobolenko, D. N.; Starostin, A. N. [Troitsk Institute for Innovation and Fusion Research (Russian Federation)

    2012-06-15T23:59:59.000Z

    The parameter of a terahertz (THz) laser intended for plasma diagnostics in electrodynamic accelerators and tokamaks with a strong magnetic field are discussed. Generation of THz radiation in an ammonia laser under the action of high-power pulsed optical pumping by the radiation of a 10P(32) CO{sub 2} laser is simulated numerically. The main characteristics of the output radiation, such as its spectrum, peak intensity, time dependence, and total energy, are calculated.

  8. Synthesis and Characterization of Th2N2(NH) Isomorphous to Th2N3

    SciTech Connect (OSTI)

    Silva, G W Chinthaka M [ORNL; Yeamans, Charles B. [University of California, Berkeley; Hunn, John D [ORNL; Sattelberger, Alfred P [Argonne National Laboratory (ANL); Czerwinski, Ken R. [University of Nevada, Las Vegas; Weck, Dr. Phil F [University of Nevada, Las Vegas

    2012-01-01T23:59:59.000Z

    Using a new, low-temperature, fluoride-based process, thorium nitride imide of the chemical formula Th{sub 2}N{sub 2}(NH) was synthesized from thorium dioxide via an ammonium thorium fluoride intermediate. The resulting product phase was characterized by powder X-ray diffraction (XRD) analysis and was found to be crystallographically similar to Th{sub 2}N{sub 3}. Its unit cell was hexagonal with a space group of P3m{bar 1} and lattice parameters of a = b = 3.886(1) and c = 6.185(2) {angstrom}. The presence of -NH in the nitride phase was verified by Fourier transform infrared spectroscopy (FTIR). Total energy calculations performed using all-electron scalar relativistic density functional theory (DFT) showed that the hydrogen atom in the Th{sub 2}N{sub 2}(NH) prefers to bond with nitrogen atoms occupying 1a Wyckoff positions of the unit cell. Lattice fringe disruptions observed in nanoparticle areas of the nitride species by high-resolution transmission electron microscopic (HRTEM) images also displayed some evidence for the presence of -NH group. As ThO{sub 2} was identified as an impurity, possible reaction mechanisms involving its formation are discussed.

  9. Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of CuSAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis."Applied Catalysis. B, Environmental 162:501-514. doi:10.1016j.apcatb.2014.07.029 Authors:...

  10. Determination of structure and phase transition of light element nanocomposites in mesoporous silica: case study of NH3BH3 in MCM-41

    SciTech Connect (OSTI)

    Kim, Hyun Jeong; Karkamkar, Abhijeet J.; Autrey, Thomas; Chupas, Peter; Proffen, Thomas E.

    2009-09-30T23:59:59.000Z

    The structure of ammonia borane (AB), NH3BH3, infused in mesoporous silica MCM-41 and its evolution over the temperature range of 80 to 300 K was investigated using the atomic pair distribution function (PDF) analysis of synchrotron X-ray powder diffraction data in order to understand the origin of improved dehydrogenation properties of the system. Our study shows how X-ray PDF analysis can be used to elucidate the structure of light guest species loaded in mesoporous silica materials despite of its low scattering power of composed elements (N, B, and H) compared to its host (SiO2). PDF analyses of two AB-loaded compositions with weight ratio AB:MCM-41=1:1 and 3:1 provide a strong evidence that AB aggregate, previously found in AB:MCM-41?1:1 samples, is same species as neat AB. For both of them an orthorhombic to tetragonal structural phase transition occurs at 225 K on warming. On the other hand, AB residing inside meso-pores, which is found in AB:MCM-41=1:2 sample, does not undergo such phase transition. It rather stays in tetragonal phase over a wide temperature range of 110 to 240 K and starts to lose structural correlation above 240 K. This strongly suggests that nano-confinement of AB inside meso-pores stabilizes high temperature tetragonal phase at much lower temperature. These results provide important clues to two critical questions: why nan-compositions of AB leads dehydrogenation to lower temperature and why the neat AB like propoerties are recovered at high AB loading samples. This work was supported by the US Department of Energy Office of Basic Energy Sciences, Chemical Sciences program. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  11. A Continuous Solar Thermochemical Hydrogen Production Plant Design

    E-Print Network [OSTI]

    Luc, Wesley Wai

    transport of gaseous mixtures containing ammonia and was labeled NH3-COLD.transport of gaseous mixtures containing ammonia and were labeled NH3-HOT, NH3HOT1, and NH3 COLD.

  12. STRUCTURE OF PENTAKIS (UREA) DIOXOURANIUM(VI)NITRATE LUO2 (OC (NH2)2)5 (NO3) 2

    E-Print Network [OSTI]

    Zalkin, Allan

    2011-01-01T23:59:59.000Z

    2(OC(NH 2 )2)5](N0 3 )2 by Allan Zalkin*, Helena Ruben andU0 2 (OC(NH 2)2)5](N0 3)2 by Allan Zalkin, Hel~na Ruben and

  13. The system ammonium fluoride - cupric fluoride - water at zero degrees centigrade: A program for calculating the rotational spectrum of an asymmetric-top molecule in the microwave region on the IBM 650 digital computer. 

    E-Print Network [OSTI]

    Beal, James Burton

    1959-01-01T23:59:59.000Z

    incomplete and left much to be desired. In addition to this, it was desirable to have a means of comparing the solvents anhydrous hydroflu- oric acid and water. Therefore, the system NH P-Cuy2-H20 at 0 C was ohosen so that it might be compared... to analyze for copper and a modified KJeldahl method for ammonia. The Sohreinemaker wet residue method was also employed~ this method is discussed by Purdon and Hister {2). ZXPBRII 1i' (T ~J PROC RDURE Baker Analyzed Reagent amLonium fluoride (BH4F...

  14. Use of ammonia to reduce the viscosity of bottoms streams produced in hydroconversion processes

    DOE Patents [OSTI]

    Zaczepinski, Sioma (Houston, TX); Billimoria, Rustom M. (Houston, TX); Tao, Frank (Baytown, TX); Lington, Christopher G. (Houston, TX); Plumlee, Karl W. (Baytown, TX)

    1984-01-01T23:59:59.000Z

    Coal, petroleum residuum and similar carbonaceous feed materials are subjected to hydroconversion in the presence of molecular hydrogen to produce a hydroconversion effluent which is then subjected to one or more separation steps to remove lower molecular weight liquids and produce a heavy bottoms stream containing high molecular weight liquids and unconverted carbonaceous material. The viscosity of the bottoms streams produced in the separation step or steps is prevented from increasing rapidly by treating the feed to the separation step or steps with ammonia gas prior to or during the separation step or steps. The viscosity of the heavy bottoms stream produced in the final separation step is also controlled by treating these bottoms with ammonia gas. In a preferred embodiment of the invention, the effluent from the hydroconversion reactor is subjected to an atmospheric distillation followed by a vacuum distillation and the feeds to these distillations are contacted with ammonia during the distillations.

  15. Heat transfer in the plate heat exchanger of an ammonia-synthesis column

    SciTech Connect (OSTI)

    Obolentsev, Y.G.; Chus', M.S.; Norobchanskii, O.A.; Teplitshi, Y.S.; Tovazhnyanskii, L.L.

    1983-01-01T23:59:59.000Z

    The planning and construction of high-capacity synthetic ammonia plants requires the development and fabrication of unique, high unit-power equipment with high technical and economic characteristics. In foreign and domestic practice, tubular heat exchangers with relatively low heat-transfer coefficients are used. Plate heat exchangers are a promising alternative. They are compact and have a high heat energy efficiency and a relatively small metal content. To make an experimental check of the operating capability of a plate heat exchanger under ammonia production conditions, a welded plate heat exchanger was designed for an ammonia synthesis column 800mm in diameter. On prolonged testing (four years), the device provided an autothermal operating mode in the column and the heat transfer coefficient was practically constant for fixed space velocities. Consequently, the heat exchange surface was not contaminated significantly with catalyst dust, confirmed by visual observation of the heat exchanger after disassembly.

  16. Accurate Prediction of the Ammonia Probes of a Variable Proton-to-Electron Mass Ratio

    E-Print Network [OSTI]

    Owens, Alec; Thiel, Walter; Špirko, Vladimir

    2015-01-01T23:59:59.000Z

    A comprehensive study of the mass sensitivity of the vibration-rotation-inversion transitions of $^{14}$NH$_3$, $^{15}$NH$_3$, $^{14}$ND$_3$, and $^{15}$ND$_3$ is carried out variationally using the TROVE approach. Variational calculations are robust and accurate, offering a new way to compute sensitivity coefficients. Particular attention is paid to the $\\Delta k=\\pm 3$ transitions between the accidentally coinciding rotation-inversion energy levels of the $\

  17. A dsorption of H2 S or SO2 on an activated carbon cloth modified by ammonia treatment

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    by treatment with ammonia/air at 300 8 C or with ammonia/steam at 800 8 C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X granular activated carbons with similar pore size distribution [3]. However, the cost of ACFs makes

  18. Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal

    E-Print Network [OSTI]

    Peters, Robert Edgar

    1972-01-01T23:59:59.000Z

    . The total nitrogen losses in the limed treatments were believed to be caused by the high solubility of organic matter in high pH solutions followed by chemical volatilization of nitrogen as ammonia. Most of this ammonia was believed to have remained... as par t of the soil air and was lost when the soil samples were taken from the columns. Denitrification was believed to be responsible for losses in the unlimed treatments. Comparison of final organic and total inorganic nitrogen concen- trationss...

  19. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    6 Autothermal Reforming ofHacker and Kordesch, 2003 Autothermal ammonia decompositionenergy needed for their autothermal reformer and also

  20. Planetary fluids He and NH/sub 3/ at high shock pressures and temperatures

    SciTech Connect (OSTI)

    Nellis, W.J.; Radousky, H.B.; Mitchell, A.C.; Holmes, N.C.; Ross, M.; Young, D.A.

    1985-04-01T23:59:59.000Z

    Liquid He at 4.3 K and 1 atm was shocked to 16 GPa (160 kbar) and 12,000 K and double-shocked to 56 GPa and 21,000 K. Liquid perturbation theory was used to determine an effective interatomic potential from which the equation of state of He can be obtained over a wide range of densities and temperatures in the envelopes of the outer planets. A new fast optical pyrometer and a cryogenic specimen holder for liquid NH/sub 3/ were developed to measure shock temperatures of 4400 and 3600 K at pressures of 59 and 48 GPa. These conditions correspond to those in the ice layers in Uranus and Neptune. The shock temperature data are in reasonable agreement with an equation of state by Ree based on an intermolecular potential derived from NH/sub 3/ Hugoniot data.

  1. Tracing the evolutionary stage of Bok globules: CCS and NH3

    E-Print Network [OSTI]

    Marka, C; Launhardt, R; Semenov, D A; Henning, Th

    2011-01-01T23:59:59.000Z

    We pursue the investigation of a previously proposed correlation between chemical properties and physical evolutionary stage of isolated low-mass star-forming regions. In the past, the NH3/CCS abundance ratio was suggested to be a potentially useful indicator for the evolutionary stage of cloud cores. We aim to study its applicability for isolated Bok globules. A sample of 42 Bok globules with and without signs of current star formation was searched for CCS(2-1) emission, the observations were complemented with NH3 measurements available in the literature and own observations. The abundance ratio of both molecules is discussed with respect to the evolutionary stage of the objects and in the context of chemical models. The NH3/CCS ratio could be assessed for 18 Bok globules and is found to be moderately high and roughly similar across all evolutionary stages from starless and prestellar cores towards internally heated cores harbouring protostars of Class 0, Class I or later. Bok globules with extremely high CC...

  2. Removal of ammonia from contaminated air in a biotrickling filter Denitrifying bioreactor combination system

    E-Print Network [OSTI]

    Removal of ammonia from contaminated air in a biotrickling filter ­ Denitrifying bioreactor of a biotrickling filter, a deni- trification reactor and a polishing bioreactor for the trickling liquid by accumulating nitrate and nitrite and avoiding generation of contaminated water. All bioreactors were packed

  3. Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light

    E-Print Network [OSTI]

    Denver, University of

    ) or directly through adsorbed nitrogen and hydrogen atoms (11, 12). Ammonia emissions from tunnel studies have mea- surements than all other data combined. Sulfur compounds in gasoline combust in the engine to help facilitate the stringent 2007 diesel engine emission requirements. These reductions

  4. Chemical Engineering Journal 113 (2005) 205214 A detailed model of a biofilter for ammonia removal

    E-Print Network [OSTI]

    2005-01-01T23:59:59.000Z

    Chemical Engineering Journal 113 (2005) 205­214 A detailed model of a biofilter for ammonia removal Manresa, Spain b Department of Chemical and Environmental Engineering, University of California, Riverside, 92521 CA, USA c Department of Chemical Engineering, Universitat Aut`onoma de Barcelona, Edifici C, 08193

  5. The use of the photo-electric cell in the determination of ammonia

    E-Print Network [OSTI]

    Adams, Leon Milton

    1934-01-01T23:59:59.000Z

    , especially in the form of' ammonia or ammonium compounds, is, . enerclly 1ndicative of tho degree of polut1on. Of tho various prooodurcs that have been dovolopod for tho determination of the amount sf nitro;. , on pro:;ant as srmonla, the nethod usia...

  6. AN AMMONIA-WATER ABSORPTION-HIAT-PUMP CYCLE Donald Kuhlenschmidt, Member ASHRAE

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    to an air-source heating- only heat-pump cycle which delivers its heat in- doors via circulating liquid,000 Btuh) input unit reported. KLY WORDS Absorption Heat-pump Air conditioning heating Ammonia Donald conditioning chillers. The authors are involved in a project to use this cycle in an air source heat pump

  7. Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs of organisms capable of ni- trogen fixation in geothermal communities. These observations help to explain-to-alkaline geothermal springs. All life requires fixed sources of nitrogen (N), and its availabil- ity often limits

  8. Interaction between temperature and ammonia in mesophilic digesters for animal waste treatment

    E-Print Network [OSTI]

    Angenent, Lars T.

    and agricultural processing, centralized and decentralized wastewater treatment plants, and solid waste recoveryInteraction between temperature and ammonia in mesophilic digesters for animal waste treatment, and their interconnectivity on the methane yield of anaerobic processes for animal waste treatment. During period 1 (day 0

  9. Measurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles in Eastern North

    E-Print Network [OSTI]

    Aneja, Viney P.

    ).2­4 Gas-to-particle conversion can be accomplished by condensation, which adds mass onto preMeasurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles acid gas con- centrations of 0.23 g/m3 hydrochloric acid (standard deviation [SD] 0.2 g/m3 ); 1.14 g/m3

  10. Presented in Conway, Lee, Merrimack and Plymouth, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Spring 2013

    E-Print Network [OSTI]

    New Hampshire, University of

    , as well as, conduct geospatial analysis. Participants will learn to: symbolize GIS data; add labelsPresented in Conway, Lee, Merrimack and Plymouth, NH by the UNHCE Geospatial Outreach Program Arc

  11. Presented in Concord, Merrimack and West Lebanon, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Fall 2012

    E-Print Network [OSTI]

    New Hampshire, University of

    , as well as, conduct geospatial analysis. Participants will learn to: symbolize GIS data; add labelsPresented in Concord, Merrimack and West Lebanon, NH by the UNHCE Geospatial Outreach Program Arc

  12. Presented in Lee and Concord, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Winter 2013

    E-Print Network [OSTI]

    New Hampshire, University of

    .1 to produce effective maps, edit and create GIS data, as well as, conduct geospatial analysis. ParticipantsPresented in Lee and Concord, NH by the UNHCE Geospatial Outreach Program ArcGIS Workshops Winter

  13. Enhanced anaerobic treatment of CSTR-digested effluent from chicken manure: The effect of ammonia inhibition

    SciTech Connect (OSTI)

    Liu Zhanguang; Zhou Xuefei [Key Laboratory of Yangtze Water Environment of Ministry of Education, State Key Laboratory of Pollution and Resource Reuse, Tongji University, Shanghai 200092 (China); Zhang Yalei, E-mail: zhangyalei2003@163.com [Key Laboratory of Yangtze Water Environment of Ministry of Education, State Key Laboratory of Pollution and Resource Reuse, Tongji University, Shanghai 200092 (China); Zhu Hongguang [Institute of Modern Agricultural Science and Engineering, National Engineering Research Center of Protected Agriculture, Tongji University, Shanghai 200092 (China)

    2012-01-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Enhanced anaerobic treatment of CSTR-digested effluent from chicken manure. Black-Right-Pointing-Pointer The SCOD/TAN (soluble COD/total ammonia nitrogen) ratio was key controlling factor. Black-Right-Pointing-Pointer The threshold of the SCOD/TAN ratio was 2.4 at an influent pH of 8.5-9. - Abstract: The effect of ammonia inhibition was evaluated during the enhanced anaerobic treatment of digested effluent from a 700 m{sup 3} chicken-manure continuous stirred tank reactor (CSTR). A 12.3 L internal circulation (IC) reactor inoculated with an anaerobic granular sludge and operated at 35 {+-} 1 Degree-Sign C was employed for the investigation. With a corresponding organic loading rate of 1.5-3.5 kg-COD/m{sup 3} d over a hydraulic retention time of 1.5 d, a maximum volumetric biogas production rate of 1.2 m{sup 3}/m{sup 3} d and TCOD (total COD) removal efficiency ranging from 70% to 80% was achieved. However, the continual increase in the influent TAN content led to ammonia inhibition in the methanogenesis system. The SCOD/TAN (soluble COD/total ammonia nitrogen) ratio was presented to be the key controlling factor for the anaerobic treatment of semi-digested chicken manure, and further validation through shock loading and ammonia inhibition experiments was conducted. The threshold value of the SCOD/TAN ratio was determined to be 2.4 (corresponding to a TAN of 1250 mg/L) at an influent pH of 8.5-9.

  14. Dissolved carbonic anhydrase for enhancing post-combustion carbon dioxide hydration in aqueous ammonia

    SciTech Connect (OSTI)

    Collett, James R.; Heck, Robert W.; Zwoster, Andy

    2011-04-01T23:59:59.000Z

    Aqueous ammonia solvents that capture CO2 as ionic complexes of carbonates with ammonium have recently been advanced as alternatives to amine-based solvents due to their lower energy requirements for thermal regeneration. In ammonia based solvents, the hydration of CO2 to form bicarbonate may become a rate-limiting step as the CO2 loading increases and the resulting pH level of the solvent decreases. Variants of the enzyme carbonic anhydrase can accelerate the reversible hydration of CO2 to yield bicarbonate by more than 10(6)-fold. The possible benefit of bovine carbonic anhydrase (BCA) addition to solutions of aqueous ammonia to enhance CO2 hydration was investigated in semi-batch reactions within continuously stirred tank reactors or in a bubble column gas-liquid contactor. Adding 154 mg/liter of BCA to 2 M aqueous ammonia provided a 34.1% overall increase in the rate of CO2 hydration (as indicated by the production of [H+]) as the pH declined from 9.6 to 8.6 during sparging with a 15% CO2, 85% N-2 gas at a flow rate of 3 lpm. The benefits of adding BCA to enhance CO2 hydration were only discernable below similar to pH 9. The implications of the apparent pH limitations on the utility of BCA are discussed in the context of absorber unit operation design. Possible embodiments of carbonic anhydrase as either an immobilized catalyst or as a dissolved, recirculating catalyst in potential plant scale aqueous ammonia systems are considered as well. (C) 2010 Published by Elsevier Ltd.

  15. Method to remove ammonia using a proton-conducting ceramic membrane

    DOE Patents [OSTI]

    2003-10-07T23:59:59.000Z

    An apparatus and method for decomposing NH.sub.3. A fluid containing NH.sub.3 is passed in contact with a tubular membrane that is a homogeneous mixture of a ceramic and a first metal, with the ceramic being selected from one or more of a cerate having the formula of M'Ce.sub.1-x M".sub.3-.delta., zirconates having the formula M'Zr.sub.1-x M"O.sub.3-.delta., stannates having the formula M'Sn.sub.1-x M'O.sub.3-.delta., where M' is a group IIA metal, M" is a dopant metal of one or more of Ca, Y, Yb, In, Nd, Gd or mixtures thereof and .delta. is a variable depending on the concentration of dopant and is in the range of from 0.001 to 0.5, the first metal is a group VIII or group IB element selected from the group consisting of Pt, Ag, Pd, Fe, Co, Cr, Mn, V, Ni, Au, Cu, Rh, Ru and mixtures thereof. The tubular membrane has a catalytic metal on the side thereof in contact with the fluid containing NH.sub.3 which is effective to cause NH.sub.3 to decompose to N.sub.2 and H.sub.2. When the H.sub.2 contacts the membrane H.sup.+ ions are formed which pass through the membrane driving the NH.sub.3 decomposition toward completion.

  16. Thermal Stability of MOCVD and HVPE GaN Layers in H2, HCl, NH3 and N2

    E-Print Network [OSTI]

    Anderson, Timothy J.

    GaN, and the black is the sapphire substrate. At 900 C nearly 1/4 of the film has sublimated leavingThermal Stability of MOCVD and HVPE GaN Layers in H2, HCl, NH3 and N2 M. A. Mastro1 ) (a), O. M.60.Dv; 81.15.Gh; S7.14 This work represents a complete study of GaN annealed in H2, HCl, NH3 and N2

  17. Structural transitions of ternary imide Li{sub 2}Mg(NH){sub 2} for hydrogen storage

    SciTech Connect (OSTI)

    Liang, C. [College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Gao, M. X.; Pan, H. G., E-mail: hgpan@zju.edu.cn; Liu, Y. F. [State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

    2014-08-25T23:59:59.000Z

    Phase transitions and energetic properties of Li{sub 2}Mg(NH){sub 2} with different crystal structures are investigated by experiments and first-principles calculations. The Li{sub 2}Mg(NH){sub 2} with the primitive cubic and orthorhombic structure is obtained by dynamically dehydrogenating a Mg(NH{sub 2}){sub 2}-2LiH mixture up to 280?°C under an initial vacuum and 9.0?bars H{sub 2}, respectively. It is found that the obtained orthorhombic Li{sub 2}Mg(NH){sub 2} is converted to a primitive cubic structure as the dehydrogenation temperature is further increased to 400?°C or performed by a 36?h of high-energetic ball milling. Moreover, the primitive cubic phase can be converted to an orthorhombic phase after heating at 280?°C under 9.0?bars H{sub 2} for 1?h. Thermodynamic calculations show that the orthorhombic phase is the ground state structure of Li{sub 2}Mg(NH){sub 2}. The mechanism for phase transitions of Li{sub 2}Mg(NH){sub 2} is also discussed from the angle of energy.

  18. Ocean thermal plantships for production of ammonia as the hydrogen carrier.

    SciTech Connect (OSTI)

    Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

    2009-12-02T23:59:59.000Z

    Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

  19. Metallicity of InN and GaN surfaces exposed to NH{sub 3}.

    SciTech Connect (OSTI)

    Walkosz, W.; Zapol, P.; Stephenson, G. B. (Materials Science Division)

    2012-01-01T23:59:59.000Z

    A systematic study of energies and structures of InN and GaN (0001) surfaces exposed to NH{sub 3} and its decomposition products was performed with first-principles methods. A phenomenological model including electron counting contributions is developed based on calculated DFT energies and is used to identify low-energy structures. These predictions are checked with additional DFT calculations. The equilibrium phase diagrams are found to contain structures that violate the electron counting rule. Densities of states for these structures indicate n-type conductivity, consistent with available experimental results.

  20. Influence of fuel sulfur on the selective reduction of NO by NH/sub 3/

    SciTech Connect (OSTI)

    Lucas, D.; Brown, N.J.

    1981-10-01T23:59:59.000Z

    The selective reduction of NO by NH/sub 3/ addition has been studied in a lean-burning oil fired laboratory combustion tunnel with pyridine and thiophene added to the fuel oil. Two distinct, but interrelated effects were observed. The conversion of a fixed amount of fuel nitrogen to NO in the flame increased as the fuel sulfur concentration increased. In the post-combustion gases, there was a shift in the temperature dependence of the reduction process when the sulfur combustion products were present. The extent of the NO reduction was not significantly altered, but the optimum temperature for reduction shifted to higher values as the sulfur concentration increased.

  1. Effects of Microbial Litter Amendments on Broiler Performance, Litter Quality and Ammonia Production

    E-Print Network [OSTI]

    Hinkle, Matthew

    2011-02-22T23:59:59.000Z

    of the poultry industry. The goal of amendments is to lower levels of NH3 by decreasing litter pH.. This can be accomplished through the use of acidifiers such as alum (aluminum sulfate), Poultry Litter Treatment (PLT), Poultry GuardTM, ferric sulfate... and urea conversion into NH3, which is then, vented utilizing rearing facility ventilation. Unfortunately, at this time there is no scientific data to validate the claims of proposed effectiveness of microbial litter amendments. 14 Alum (Al2(SO4...

  2. Operating Experience and Test Results From An Ammonia-Based Dry/Wet Cooling System For Electric Power Stations

    E-Print Network [OSTI]

    Allemann, R. T.; Werry, E. V.; Fricke, H. D.; Price, R. E.; Bartz, J. A.

    1982-01-01T23:59:59.000Z

    tower by heat rejection to the atmosphere. The condenser/ reboiler features Union carbide's doubly enhanced heat transfer tubing to boil ammonia on the inside and to condense the steam externally. System description and performance characteristics...

  3. Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution

    E-Print Network [OSTI]

    Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

    A first-of-its-kind Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP™) was installed by Planetec Utility Services Co., Inc. in partnership with Energy Concepts Co. at Ultramar Diamond Shamrock's 30,000 barrel per day refinery in Denver...

  4. Diffusive and rotational dynamics of condensed n-H2 confined in MCM-41

    SciTech Connect (OSTI)

    Prisk, Timothy R [ORNL; Bryan, Matthew [Indiana University; Sokol, Paul E [ORNL

    2014-01-01T23:59:59.000Z

    In this paper, we report an inelastic neutron scattering study of liquid and solid n-H2 confined within MCM-41. This is a high surface area, mesoporous silica glass with a narrow pore size distribution centered at 3.5 nm. The scattering data provides information about the diffusive and rotational dynamics of the adsorbed n-H2 at low temperatures. In the liquid state, the neutron scattering data demonstrates that only a fraction of the adsorbed o-H2 is mobile on the picosecond time scale. This mobile fraction undergoes liquid-like jump diffusion, and values for the residence time t and effective mean-squared displacement hu2i are reported as a function of pore filling. In the solid state, the rotational energy levels of adsorbed H2 are strongly perturbed from their free quantum rotor behavior in the bulk solid. The underlying orientational potential of the hindered rotors is due to the surface roughness and heterogeneity of the MCM-41 pore walls. This potential is compared to the hindering potential of other porous silicas, such as Vycor. Strong selective adsorption makes the interfacial layer rich in o-H2, leaving the inner core volume consisting of a depleted mixture of o-H2 and p-H2.

  5. PHYSICAL CONDITIONS AROUND 6.7 GHz METHANOL MASERS. I. AMMONIA

    SciTech Connect (OSTI)

    Pandian, J. D. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Dr., Honolulu, HI 96822 (United States); Wyrowski, F.; Menten, K. M., E-mail: jagadheep@iist.ac.in [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, 53121 Bonn (Germany)

    2012-07-01T23:59:59.000Z

    Methanol masers at 6.7 GHz are known to be tracers of high-mass star formation in our Galaxy. In this paper, we study the large-scale physical conditions in the star-forming clumps/cores associated with 6.7 GHz methanol masers using observations of the (1, 1), (2, 2), and (3, 3) inversion transitions of ammonia with the Effelsberg telescope. The gas kinetic temperature is found to be higher than in infrared dark clouds, highlighting the relatively evolved nature of the maser sources. Other than a weak correlation between maser luminosity and the ammonia line width, we do not find any differences between low- and high-luminosity methanol masers.

  6. The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes

    E-Print Network [OSTI]

    Oates, Margaret Deron

    1979-01-01T23:59:59.000Z

    . Jack H. Lunsford The catalytic activity of tetraamminecopper(II) complexes in aque- ous solution in the reduction of nitric oxide with ammonia nas been in- vestigated. Kinetic data for the nitric oxide reduction reaction were determined in a closed... circulating system. Electron paramagnetic reso- spectroscopy was used to determine the zelative quantity of copper in the +2 oxidation state at different temperatures. A reaction mechanism is proposed from these experimental investigations in order...

  7. Correlation of ammonia clearance with classical liver function tests in normal and liver-damaged sheep

    E-Print Network [OSTI]

    Hansson, Lucille Ann

    1984-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE May 1984 Major Subject: Veterinary Toxicology CORRELATION OF AMMONIA CLEARANCE WITH CLASSICAL LIVER FUNCTION TESTS IN NORMAL AND LIVER-DAMAGED SHEEP A Thesis LUCILLE ANN HANSSON Approved as to style and content by... together. The United States Department of Agriculture, Veterinary Toxicology and . Entomology Research Laboratory, Bryan, Texas for providing the research sheep, analysis of research samples, and the funding for this research project. TABLE OF CONTENTS...

  8. Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia

    DOE Patents [OSTI]

    Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

    1980-01-01T23:59:59.000Z

    Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

  9. INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS

    SciTech Connect (OSTI)

    G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

    2000-11-01T23:59:59.000Z

    This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

  10. Energy-efficiency comparison of advanced ammonia heat-exchanger types

    SciTech Connect (OSTI)

    Panchal, C.; Rabas, T.

    1990-01-01T23:59:59.000Z

    Ammonia is the most cost-effective working fluid for many Rankine power cycles and is widely utilized in industrial refrigeration applications. For example, it was selected as the most advantageous working fluid for the comprehensive closed-cycle Ocean Thermal Energy Conversion investigations where the heat source and sink are the warm, surface seawater and the cold, deep seawater, respectively. An essential part of this investigation was to measure the performance of many advanced heat-exchanger types using ammonia as the working fluid and to compare these results with those for conventional shell-and-tube designs. This paper presents an overview of these experiments and their potential significance for improved energy efficiency for industrial refrigeration applications. The heat exchangers used for industrial refrigeration systems account for about 50% of the equipment cost. However, current practice is to use state-of-the-art designs -- the shell-and-tube type without enhanced tubes. Substantial energy savings are possible through the use of advanced ammonia evaporator and condenser heat-exchanger types. 31 refs., 10 figs., 6 tabs.

  11. Experimental verification of the high pressure crystal structures in NH{sub 3}BH{sub 3}

    SciTech Connect (OSTI)

    Huang, Yanping; Huang, Xiaoli; Zhao, Zhonglong; Li, Wenbo; Jiang, Shuqing; Duan, Defang; Bao, Kuo; Zhou, Qiang; Liu, Bingbing; Cui, Tian, E-mail: cuitian@jlu.edu.cn [State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012 (China)

    2014-06-28T23:59:59.000Z

    A detailed high-pressure study on NH{sub 3}BH{sub 3} has been carried out using in situ synchrotron X-ray diffraction (XRD) and Raman scattering with a diamond anvil cell up to 20 and 33 GPa, respectively. The Rietveld refinement based on the XRD pattern and analysis of Raman data indicate two first-order phase transitions from the ambient pressure I4 mm structure (?-NH{sub 3}BH{sub 3}) to a high pressure Cmc2{sub 1} phase (?-NH{sub 3}BH{sub 3}) at 2.14 GPa, and further into a monoclinic P2{sub 1} (Z = 2) phase (?-NH{sub 3}BH{sub 3}) at 9.67 GPa. Fitting the measured volumetric compression data to the third order Birch-Murnaghan equation of state reveals a bulk modulus of B{sub 0} = 9.9 ± 0.5 and 17.0 ± 3.0 GPa (with fixed B{sub 0}{sup ?} = 4) for the ?-NH{sub 3}BH{sub 3} below and above 5 GPa, respectively. Still, with the splitting of the NBH rock mode in Raman experiment, it is concluded that a second-order isostructural phase transition occurs at 5 GPa. By analyzing the dihydrogen bonding framework, the origin of the isostructural phase transition is attributed to the number of dihydrogen bondings per molecule in the Cmc2{sub 1} phase increasing from 12 to 14 at 5 GPa.

  12. Functional analysis of the NH{sub 2}-terminal hydrophobic region and BRICHOS domain of GKN1

    SciTech Connect (OSTI)

    Yoon, Jung Hwan; Choi, Yoo Jin; Choi, Won Suk; Nam, Suk Woo; Lee, Jung Young; Park, Won Sang, E-mail: wonsang@catholic.ac.kr

    2013-11-01T23:59:59.000Z

    Highlights: •NH{sub 2}-terminal and BRICHOS domain of GKN1 inhibited tumor cell growth. •NH{sub 2}-terminal and BRICHOS domain of GKN1 regulated cell cycle. •NH{sub 2}-terminal and BRICHOS domain of GKN1 inhibited epigenetic regulators. -- Abstract: Gastrokine 1 (GKN1) protects the gastric antral mucosa and promotes healing by facilitating restitution and proliferation after injury. GKN1 is down-regulated in Helicobacter pylori-infected gastric epithelial cells and loss of GKN1 expression is tightly associated with gastric carcinogenesis. However, the underlying mechanisms as a tumor suppressor are largely unknown. Presently, the hydrophobic region and BRICHOS domain of GKN1, pGKN1{sup D13N}, pGKN1{sup ?68–199}, and pGKN1{sup ?1–67,165–199} were shown to suppress gastric cancer cell growth and recapitulate GKN1 functions. As well, the hydrophobic region and BRICHOS domain of GKN1 had a synergistic anti-cancer effect with 5-FU on tumor cell growth, implying that the NH{sub 2}-terminal hydrophobic region and BRICHOS domain of GKN1 are sufficient for tumor suppression, thereby suggesting a therapeutic intervention for gastric cancer. Also, its domain inducing endogenous miR-185 directly targeted the epigenetic effectors DNMT1 and EZH2 in gastric cancer cells. Our results suggest that the NH{sub 2}-terminal hydrophobic region and BRICHOS domain of GKN1 are sufficient for its tumor suppressor activities.

  13. Preparation of hexagonal WO{sub 3} from hexagonal ammonium tungsten bronze for sensing NH{sub 3}

    SciTech Connect (OSTI)

    Szilagyi, Imre Miklos [Materials Structure and Modeling Research Group of the Hungarian Academy of Sciences, Budapest University of Technology and Economics, H-1111 Budapest, Szt. Gellert ter 4 (Hungary)], E-mail: imre.szilagyi@mail.bme.hu; Wang Lisheng; Gouma, Pelagia-Irene [Department of Materials Science and Engineering, 314 Old Engineering Building, SUNY, Stony Brook, NY 11794-2275 (United States); Balazsi, Csaba [Ceramics and Nanocomposites Laboratory, Research Institute for Technical Physics and Materials Science, H-1121 Budapest, Konkoly-Thege ut 29-33 (Hungary); Madarasz, Janos; Pokol, Gyoergy [Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, H-1111 Budapest, Szt. Gellert ter 4 (Hungary)

    2009-03-05T23:59:59.000Z

    Hexagonal tungsten oxide (h-WO{sub 3}) was prepared by annealing hexagonal ammonium tungsten bronze, (NH{sub 4}){sub 0.07}(NH{sub 3}){sub 0.04}(H{sub 2}O){sub 0.09}WO{sub 2.95}. The structure, composition and morphology of h-WO{sub 3} were studied by XRD, XPS, Raman, {sup 1}H MAS (magic angle spinning) NMR, scanning electron microscopy (SEM), and BET-N{sub 2} specific surface area measurement, while its thermal stability was investigated by in situ XRD. The h-WO{sub 3} sample was built up by 50-100 nm particles, had an average specific surface area of 8.3 m{sup 2}/g and was thermally stable up to 450 deg. C. Gas sensing tests showed that h-WO{sub 3} was sensitive to various levels (10-50 ppm) of NH{sub 3}, with the shortest response and recovery times (1.3 and 3.8 min, respectively) to 50 ppm NH{sub 3}. To this NH{sub 3} concentration, the sensor had significantly higher sensitivity than h-WO{sub 3} samples prepared by wet chemical methods.

  14. Influence of fuel sulfur on the selective reduction of NO by NH/sub 3/

    SciTech Connect (OSTI)

    Lucas, D.; Brown, N.J.

    1981-01-01T23:59:59.000Z

    More intensive regulations of the emissions of nitrogen oxides from stationary combustion sources have prompted the innovation and characterization of new control technologies suitable for applications in utilities. One of the more recent and attractive abatement technologies is the Thermal DeNO/sub x/ process which has been described by Lyon and Longwell. This process removes NO by selectively reducing it with NH/sub 3/ added to the post-combustion gases containing excess oxygen. This process is thus independent of the NO formation mechanism and makes no distinction between thermal and fuel NO. The present study is concerned with characterizing the selective reduction process for light distillate oil fuel admixed with variable amounts of pyridene and thiophene in a laboratory scale combustion tunnel under a variety of experimental conditions. This paper reports on those aspects of the study concerned with the investigation of possible synergistic effects between the sulfur and selective reduction chemistry.

  15. Mechanistic studies of the CVD of silicon nitride from SiF{sub 4} and NH{sub 3}

    SciTech Connect (OSTI)

    Buss, R.J.; Ho, P.

    1992-12-01T23:59:59.000Z

    An industrial process for the CVD of silicon nitride from SiF{sub 4} and NH{sub 3} was studied with a wide variety of techniques, ranging from numerical models of the coupled chemistry and fluid mechanics to experimental studies of chemical reactions. The latter includes a set of molecular beam experiments that probed the temperature and flux dependencies of the reaction of SiF{sub 4} and NH{sub 3} at the surface. These experiments showed that the CVD reactor chemistry was dominated by surface kinetics rather than gas-phase decomposition.

  16. Mechanistic studies of the CVD of silicon nitride from SiF[sub 4] and NH[sub 3

    SciTech Connect (OSTI)

    Buss, R J; Ho, P

    1992-01-01T23:59:59.000Z

    An industrial process for the CVD of silicon nitride from SiF[sub 4] and NH[sub 3] was studied with a wide variety of techniques, ranging from numerical models of the coupled chemistry and fluid mechanics to experimental studies of chemical reactions. The latter includes a set of molecular beam experiments that probed the temperature and flux dependencies of the reaction of SiF[sub 4] and NH[sub 3] at the surface. These experiments showed that the CVD reactor chemistry was dominated by surface kinetics rather than gas-phase decomposition.

  17. Laser studies of the reactivity of NH(X{sup 3}{Sigma}{sup {minus}}) with the surface of silicon nitride

    SciTech Connect (OSTI)

    Fisher, E.R.; Ho, P.; Breiland, W.G.; Buss, R.J. [Sandia National Labs., Albuquerque, NM (United States)

    1992-11-26T23:59:59.000Z

    The reactivity of NH(X{sup 3}{Sigma}{sup {minus}}) with the surface of both a silicon nitride film and a depositing hydrogenated silicon nitride film has been measured to be essentially zero with an upper limit of 0.1 for substrate temperatures of 300-700 K. The reactivity was directly determined using spatially resolved laser-induced fluorescence of NH in a plasma-generated molecular beam incident on the surface. The NH adsorbs and then desorbs from the surface with a a spatial distribution consistent with a cosine angular distribution. No dependence of reactivity on rotational state of the NH was observed. 27 refs., 8 figs.

  18. Access Management in Multi-Administration Networks S. P. Lord, N.H. Pope, and Susan Stepney

    E-Print Network [OSTI]

    Stepney, Susan

    Access Management in Multi-Administration Networks S. P. Lord, N.H. Pope, and Susan Stepney GEC of linking together networks controlled by different administrations, and allowing these administrations and representations. S. P. Lord, N. H. Pope, and Susan Stepney. Access Management in multi-administration networks

  19. Effective interactions between the N-H bond orientations in lithium imide and a proposed ground-state structure

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Effective interactions between the N-H bond orientations in lithium imide and a proposed ground Received 28 February 2006; revised manuscript received 17 July 2006; published 4 October 2006 Lithium imide in the structure. By searching an effective Hamiltonian in which the energy of lithium imide is expressed

  20. The nitrate to ammonia and ceramic (NAC) process -- a newly developed low-temperature technology

    SciTech Connect (OSTI)

    Mattus, A.J.; Lee, D.D.

    1993-06-01T23:59:59.000Z

    Bench-top feasibility studies with Hanford single-shell tank (SST) simulants, using a new low-temperature (50-60C) process for converting nitrate to ammonia and ceramic (NAC), showed that between 90 and 99% of the nitrate at Hanford can be readily converted to ammonia. Aluminum powders or shot can be used to convert alkaline, nitrate-based supernate to ammonia and an alumina-silica-based ceramic solid. The process may utilize already contaminated aluminum scrap metal from various DOE sites to effect the conversion. The final nitrate-free ceramic product can be calcined, pressed, and sintered like any other ceramic. Based on starting volumes of 6.2 and 3.1 M sodium nitrate solution (probable supernate concentrations resulting from salt-cake/sludge removal from Hanford SSTs), volume reductions as high as 70% are currently obtained, compared with an expected 40 to 50% volume increase if the Hanford supernate were grouted. Engineering data indicate that the process will be very economical. Data were used to cost a batch facility with a production rate of 1200 kilograms of nitrate per hour for processing all the Hanford SST waste over 20 years. Process cost analysis indicates that between $2.01 and 2.66 will be required to convert each kilogram of nitrate. These costs are one-third to one-half of the processing costs for electrolytic and thermal processes. The ceramic waste form offers other cost savings associated with a smaller volume of waste as well as eliminates other process steps such as grouting. Silica added to the reactor, based upon the total sodium in the waste, permits us to actually bind the sodium in a nepheline phase of the final ceramic structure as well as bind most metals and nonmetals in the ceramic.

  1. Ammonia inhalation toxicity in cats: a study of acute and chronic respiratory dysfunction

    E-Print Network [OSTI]

    Dodd, Kenneth Travis

    1978-01-01T23:59:59.000Z

    Chairman of Advisory Committee: Dr. David R. Gross Twenty healthy cats were exposed to 1000 ppm of ammonia gas for a period of ten minutes. Pulmonary function tests were performed and lung samples for pathologic evaluation taken on days 0, 1, 7, 21... overdose. The lungs were removed in toto and pressure infused with buf- fered formalin until distended to in vivo size. All re- maining animals were reanesthetized and retested on days 7, 21 and 35 post-exposure. After each of these remeasurements...

  2. Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate

    E-Print Network [OSTI]

    Czarnecki, Lawrence Joseph

    1988-01-01T23:59:59.000Z

    in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

  3. Verification of Allowable Stresses In ASME Section III Subsection NH For Grade 91 Steel & Alloy 800H

    SciTech Connect (OSTI)

    R. W. Swindeman; M. J. Swindeman; B. W. Roberts; B. E. Thurgood; D. L. Marriott

    2007-11-30T23:59:59.000Z

    The database for the creep-rupture of 9Cr-1Mo-V (Grade 91) steel was collected and reviewed to determine if it met the needs for recommending time-dependent strength values, S{sub t}, for coverage in ASME Section III Subsection NH (ASME III-NH) to 650 C (1200 F) and 600,000 hours. The accumulated database included over 300 tests for 1% total strain, nearly 400 tests for tertiary creep, and nearly 1700 tests to rupture. Procedures for analyzing creep and rupture data for ASME III-NH were reviewed and compared to the procedures used to develop the current allowable stress values for Gr 91 for ASME II-D. The criteria in ASME III-NH for estimating S{sub t} included the average strength for 1% total strain for times to 600,000 hours, 80% of the minimum strength for tertiary creep for times to 600,000 hours, and 67% of the minimum rupture strength values for times to 600,000 hours. Time-temperature-stress parametric formulations were selected to correlate the data and make predictions of the long-time strength. It was found that the stress corresponding to 1% total strain and the initiation of tertiary creep were not the controlling criteria over the temperature-time range of concern. It was found that small adjustments to the current values in III-NH could be introduced but that the existing values were conservative and could be retained. The existing database was found to be adequate to extend the coverage to 600,000 hours for temperatures below 650 C (1200 F).

  4. Update and Improve Subsection NH –– Alternative Simplified Creep-Fatigue Design Methods

    SciTech Connect (OSTI)

    Tai Asayama

    2009-10-26T23:59:59.000Z

    This report described the results of investigation on Task 10 of DOE/ASME Materials NGNP/Generation IV Project based on a contract between ASME Standards Technology, LLC (ASME ST-LLC) and Japan Atomic Energy Agency (JAEA). Task 10 is to Update and Improve Subsection NH -- Alternative Simplified Creep-Fatigue Design Methods. Five newly proposed promising creep-fatigue evaluation methods were investigated. Those are (1) modified ductility exhaustion method, (2) strain range separation method, (3) approach for pressure vessel application, (4) hybrid method of time fraction and ductility exhaustion, and (5) simplified model test approach. The outlines of those methods are presented first, and predictability of experimental results of these methods is demonstrated using the creep-fatigue data collected in previous Tasks 3 and 5. All the methods (except the simplified model test approach which is not ready for application) predicted experimental results fairly accurately. On the other hand, predicted creep-fatigue life in long-term regions showed considerable differences among the methodologies. These differences come from the concepts each method is based on. All the new methods investigated in this report have advantages over the currently employed time fraction rule and offer technical insights that should be thought much of in the improvement of creep-fatigue evaluation procedures. The main points of the modified ductility exhaustion method, the strain range separation method, the approach for pressure vessel application and the hybrid method can be reflected in the improvement of the current time fraction rule. The simplified mode test approach would offer a whole new advantage including robustness and simplicity which are definitely attractive but this approach is yet to be validated for implementation at this point. Therefore, this report recommends the following two steps as a course of improvement of NH based on newly proposed creep-fatigue evaluation methodologies. The first step is to modify the current approach by incorporating the partial advantages the new method offer, and the second step is to replace the current method by the simplified test approach when it has become technically mature enough. The recommendations are basically in line with the work scope of the Task Force on Creep-Fatigue of the Subgroup on Elevated Temperature Design of the Standards Committee of the ASME Boiler and Pressure Vessel Committee Section III.

  5. Measurements of NH3 and CO2 with distributed-feedback diode lasers near 2.0 m in bioreactor vent gases

    E-Print Network [OSTI]

    Measurements of NH3 and CO2 with distributed-feedback diode lasers near 2.0 m in bioreactor vent K. Hanson Measurements of NH3 and CO2 were made in bioreactor vent gases with distributed3 and CO2 concentration in bioreactor vent gases that were recorded at NASA Johnson Space Center

  6. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  7. Fast vibrational relaxation of OH(v 9) by ammonia Sergey A. Nizkorodov, Warren W. Harper, David J. Nesbitt *

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    , H2, H2S, etc.) by high-resolu- tion direct absorption infrared spectroscopy. In the course-resolution direct infrared absorption detection of OH in the v 11 2 9 band. OH(v 9) removal by O3 occurs with a nearly gas-kinetic rate kO3 1:3715 Â 10À10 cm3 =s. Collisional removal by NH3 kNH3 7:6050 Â 10À10 cm3

  8. Biophysical studies of anhydrous peptide structure

    E-Print Network [OSTI]

    McLean, Janel Renee

    2009-05-15T23:59:59.000Z

    -section. Collision cross-sections measured using IM-MS are correlated with theoretical models generated using simulated annealing and allow for assignment of the overall ion structural motif (e.g. helix vs. chargesolvated globule). Here, two series of model peptides...

  9. Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex Christopher A. Endicott, Herbert L. Strauss,* Chambers C. Hughes, and Dirk Trauner

    E-Print Network [OSTI]

    Trauner, Dirk

    Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex Christopher A. Endicott-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethyl- phenol has a unique structure, and to investigate the nature of the hydrogen bonding, we carried out infrared

  10. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter Kenneth D a comprehensive database of ammonia emission rates (ER) from US poultry facilities. The influence of common

  11. Example risk management plan and offsite consequence analysis for power plant aging using ammonia and chlorine

    SciTech Connect (OSTI)

    McCann, R.C. Jr.

    1998-07-01T23:59:59.000Z

    This paper provides an example of a risk management plan (RMP) for a utility power plant required under Title III of the 1990 Clean Air Act Amendments (CAAA). Under Title III, certain facilities are required to identify hazards associated with chemicals used to prevent accidental releases, and to minimize consequences of releases. Ammonia is used to reduce nitrogen oxides (NO{sub x}) emissions and is injected in the post-combustion system based on the selective catalyst reduction (SCR) process. Chlorine is used in the potable water treatment process. This paper provides an overview of the elements required in the RMP and specific methods and procedures currently recommended by the EPA for estimating hazardous air pollutant emissions and impacts related to the ammonia and chlorination processes cited in this paper. Information is presented that addresses the potential extent of a pollutant's impacts, including methods and assumptions designed to over-estimate concentrations. Alternative approaches are used to estimate more realistic but still conservative concentrations. Based on the results of these analyses, strategies are recommended that the plant could incorporate to reduce the level of potential impacts and, therefore, program requirements under RMP.

  12. Nano-Scaffold Mediates Hydrogen Release and Reactivity of Ammonia Borane

    SciTech Connect (OSTI)

    Gutowska, Anna; Li, Liyu; Shin, Yongsoon; Wang, Chong M.; Li, Xiaohong S.; Linehan, John C.; Smith, R. Scott; Kay, Bruce D.; Schmid, Benjamin A.; Shaw, Wendy J.; Gutowski, Maciej S.; Autrey, Thomas

    2005-06-06T23:59:59.000Z

    One of the imposing barriers to realizing the promise of an energy economy based on hydrogen is onboard hydrogen storage for fuel-cell-powered vehicles. New materials that enable the release of dense, plentiful and pure hydrogen at temperatures less than 85 ºC are necessary to move the world from an oil-based economy to a hydrogen economy. We report a novel approach in which we deposit a hydrogen-rich material into a nanoporous scaffold. The role of the scaffold is to impose a nano-phase structure on the hydrogen-rich material thus providing an additional handle on the kinetics and thermodynamics of hydrogen release. We demonstrate on the example of ammonia borane infused in the nanoporous silica that the kinetics of hydrogen release is improved while the purity of hydrogen is increased in comparison with the release from bulk ammonia borane. These findings suggest that hydrogen rich materials infused in nanoscaffolds offer the most promising approach to date for onboard hydrogen storage

  13. Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing

    SciTech Connect (OSTI)

    Bauer, H.K.; Otte, E.A.W.

    1984-10-16T23:59:59.000Z

    A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

  14. Topologically identical, but geometrically isomeric layers in hydrous ?-, ?-Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})]·H{sub 2}O and anhydrous Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})

    SciTech Connect (OSTI)

    Yu, Na; Klepov, Vladislav V. [Forschungszentrum Jülich GmbH, Institute for Energy and Climate Research (IEK-6), 52428 Jülich (Germany); Villa, Eric M. [Department of Chemistry, Creighton University, 2500 California Plaza, Omaha NE 68178 (United States); Bosbach, Dirk [Forschungszentrum Jülich GmbH, Institute for Energy and Climate Research (IEK-6), 52428 Jülich (Germany); Suleimanov, Evgeny V. [Department of Chemistry, Lobachevsky State University of Nizhny Novgorod, 603950 Nizhny Novgorod (Russian Federation); Depmeier, Wulf [Institut für Geowissenschaften, Universität zu Kiel, 24118 Kiel (Germany); Albrecht-Schmitt, Thomas E., E-mail: albrecht-schmitt@chem.fsu.edu [Department of Chemistry and Biochemistry, Florida State University, 102 Varsity Way, Tallahassee, FL 32306-4390 (United States); Alekseev, Evgeny V., E-mail: e.alekseev@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute for Energy and Climate Research (IEK-6), 52428 Jülich (Germany); Institut für Kristallographie, RWTH Aachen University, 52066 Aachen (Germany)

    2014-07-01T23:59:59.000Z

    The hydrothermal reaction of uranyl nitrate with rubidium nitrate and arsenic (III) oxide results in the formation of polymorphic ?- and ?-Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})]·H{sub 2}O (?-, ?-RbUAs) and the anhydrous phase Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})] (RbUAs). These phases were structurally, chemically and spectroscopically characterized. The structures of all three compounds are based upon topologically identical, but geometrically isomeric layers. The layers are linked with each other by means of the Rb cations and hydrogen bonding. Dehydration experiments demonstrate that water deintercalation from hydrous ?- and ?-RbUAs yields anhydrous RbUAs via topotactic reactions. - Graphical abstract: Three different layer geometries observed in the structures of Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})] and ?- and ?- Rb[UO{sub 2}(AsO{sub 3}OH)(AsO{sub 2}(OH){sub 2})]·H{sub 2}O. Two different coordination environments of uranium polyhedra (types I and II) are shown schematically on the top of the figure. - Highlights: • Three new uranyl arsenates were synthesized from the hydrothermal reactions. • The phases consist of the topologically identical but geometrically different layers. • Topotactic transitions were observed in the processes of mono-hyrates dehydration.

  15. RELAP5 assessment using semiscale SBLOCA test S-NH-1. International Agreement Report

    SciTech Connect (OSTI)

    Lee, E.J.; Chung, B.D.; Kim, H.J. [Korea Inst. of Nuclear Safety, Taejon (Korea, Republic of)

    1993-06-01T23:59:59.000Z

    2-inch cold leg break test S-NH-1, conducted at the 1/1705 volume scaled facility Semiscale was analyzed using RELAP5/MOD2 Cycle 36.04 and MOD3 Version 5m5. Loss of HPIS was assumed, and reactor trip occurred on a low PZR pressure signal (13.1 MPa), and pumps began an unpowered coastdown on SI signal (12.5 MPa). The system was recovered by opening ADV`s when the PCT became higher than 811 K. Accumulator was finally injected into the system when the primary system pressure was less than 4.0 MPa. The experiment was terminated when the pressure reached the LPIS actuation set point RELAP5/MOD2 analysis demonstrated its capability to predict, with a sufficient accuracy, the main phenomena occurring in the depressurization transient, both from a qualitative and quantitative points of view. Nevertheless, several differences were noted regarding the break flow rate and inventory distribution due to deficiencies in two-phase choked flow model, horizontal stratification interfacial drag, and a CCFL model. The main reason for the core to remain nearly fully covered with the liquid was the under-prediction of the break flow by the code. Several sensitivity calculations were tried using the MOD2 to improve the results by using the different options of break flow modeling (downward, homogeneous, and area increase). The break area compensating concept based on ``the integrated break flow matching`` gave the best results than downward junction and homogeneous options. And the MOD3 showed improvement in predicting a CCFL in SG and a heatup in the core.

  16. General basic and coordination catalysis in reactions of haloaromatic compounds with ammonia in the presence of copper(I) compounds

    SciTech Connect (OSTI)

    Chumak, V.T.; Shein, S.M.

    1985-11-01T23:59:59.000Z

    This paper presents a study made to detect general basic catalysis by ammonia (reagent) in reactions of ammonolysis of haloaromatic compounds in the presence of Cu/sup +/ ions, as well as to determine the generality of the mechanisms of the catalytic replacement of a halogen atom by an amino group in the anthraquinone and benzene series.

  17. Saturn's Great Storm of 2010-2011: Evidence for ammonia and water ices from analysis of VIMS spectra

    E-Print Network [OSTI]

    Sromovsky, Lawrence; Fry, Patrick

    2015-01-01T23:59:59.000Z

    Our analysis of Cassini/VIMS near-infrared spectra of Saturn's Great Storm of 2010-2011 reveals a multi-component aerosol composition comprised primarily of ammonia ice, with a significant component of water ice. The most likely third component is ammonium hydrosulfide or some weakly absorbing material similar to what dominates visible clouds outside the storm region. Horizontally heterogeneous models favor ammonium hydrosulfide as the third component, while horizontally uniform models favor the weak absorber. Both models rely on water ice absorption to compensate for residual spectral gradients produced by ammonia ice from 3.0 microns to 3.1 microns and need the third component to fill in the sharp ammonia ice absorption peak near 2.96 microns. The best heterogeneous model has spatial coverage fractions of 55% ammonia ice, 22% water ice, and 23% ammonium hydrosulfide. The best homogeneous model has an optically thin layer of weakly absorbing particles above an optically thick layer of water ice particles coa...

  18. The conserved carboxy-terminal region of the ammonia channel AmtB plays a critical role in channel function

    E-Print Network [OSTI]

    Merrick, Mike

    The conserved carboxy-terminal region of the ammonia channel AmtB plays a critical role in channel-terminal residues can have very marked effects. Using the Escherichia coli AmtB protein as a model system for Amt that are best explained in terms of two distinct effects of the C-terminal region on AmtB activity. Residues

  19. An interpretation of the vibrational and rotational structure of the 2167A? system of ammonia

    E-Print Network [OSTI]

    Landrum, Bobby Lee

    1959-01-01T23:59:59.000Z

    . The Ground State o f NH 3 and N D ^ ............................ 16 C. The E le ctron ic T ransition A sso c ia ted With the 2167A0 System and Another P o ss ib le S y s t em... OF FIGURES la The N orm a l M odes o f V ib r a t io n .................................... .. 13 lb The Ground State P oten tia l F u n c t io n ............................ 18 2 Short Path O p tica l S y s t em...

  20. Time-Resolved XAFS Spectroscopic Studies of B-H and N-H Oxidative Addition to Transition Metal Catalysts Relevant to Hydrogen Storage

    SciTech Connect (OSTI)

    Bitterwolf, Thomas E. [University of Idaho

    2014-12-09T23:59:59.000Z

    Successful catalytic dehydrogenation of aminoborane, H3NBH3, prompted questions as to the potential role of N-H oxidative addition in the mechanisms of these processes. N-H oxidative addition reactions are rare, and in all cases appear to involve initial dative bonding to the metal by the amine lone pairs followed by transfer of a proton to the basic metal. Aminoborane and its trimethylborane derivative block this mechanism and, in principle, should permit authentic N-H oxidative attrition to occur. Extensive experimental work failed to confirm this hypothesis. In all cases either B-H complexation or oxidative addition of solvent C-H bonds dominate the chemistry.

  1. Multifaceted regulations of gateway enzyme phenylalanine ammonia-lyase in the biosynthesis of phenylpropanoids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Xuebin; Liu, Chang-Jun

    2015-01-01T23:59:59.000Z

    Phenylpropanoid biosynthesis in plants engenders a vast variety of aromatic metabolites critically important for their growth, development, and environmental adaptation. Some of these aromatic compounds have high economic value. Phenylalanine ammonia-lyase (PAL) is the first committed enzyme in the pathway; it diverts the central flux of carbon from primary metabolism to the synthesis of myriad phenolics. Over the decades, many studies have shown that exquisite regulatory mechanisms at multiple levels control the transcription and the enzymatic activity of PALs. In this review, we present a current overview on our understanding of the complicated regulatory mechanisms governing PAL's activity; we particularlymore »highlight recent progresses in unraveling its post-translational modifications, its metabolite feedback regulation, and its enzyme organization.« less

  2. Solvated electron yields in liquid and supercritical ammonia-A statistical mechanical treatment

    SciTech Connect (OSTI)

    Schiller, Robert; Horvath, Akos [Centre for Energy Research, P.O.B. 49, Budapest H-1525 (Hungary)

    2012-12-07T23:59:59.000Z

    Earlier the geminate recombination of ions and solvated electrons, produced by ionizing radiation or laser light, was theoretically treated by a model which consisted of a Rydberg atom interacting with the thermodynamic fluctuations of the medium [R. Schiller, J. Chem. Phys. 92, 5527 (1990)]. The theory was applied to liquid-to-supercritical water [R. Schiller and A. Horvath, J. Chem. Phys. 135, 084510 (2011)]. Now it is compared with recent experiments performed on liquid-to-supercritical ammonia [J. Urbanek, A. Dahmen, J. Torres-Alacan, P. Koenigshoven, J. Lindner, and P. Voehringer, J. Phys. Chem. B 116, 2223 (2012)]. The agreement between theory and experiment seems to be reasonable. The treatment is critically assessed.

  3. Evaluation of a solar intermittent refrigeration system for ice production operating with ammonia/lithium nitrate

    SciTech Connect (OSTI)

    Rivera, W.; Moreno-Quintanar, G.; Best, R. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, A.P. 34, 62580 Temixco, Mor. (Mexico); Rivera, C.O.; Martinez, F. [Facultad de Ingenieria Campus Coatzacoalcos, Universidad Veracruzana, Av. Universidad Km 7.5, 96530 Coatzacoalcos, Ver. (Mexico)

    2011-01-15T23:59:59.000Z

    A novel solar intermittent refrigeration system for ice production developed in the Centro de Investigacion en Energia of the Universidad Nacional Autonoma de Mexico is presented. The system operates with the ammonia/lithium nitrate mixture. The system developed has a nominal capacity of 8 kg of ice/day. It consists of a cylindrical parabolic collector acting as generator-absorber. Evaporator temperatures as low as -11 C were obtained for several hours with solar coefficients of performance up to 0.08. It was found that the coefficient of performance increases with the increment of solar radiation and the solution concentration. A dependency of the coefficient of performance was not founded against the cooling water temperature. Also it was found that the maximum operating pressure increases meanwhile the generation temperature decreases with an increase of the solution concentration. (author)

  4. Measuring the Boltzmann constant by mid-infrared laser spectroscopy of ammonia

    E-Print Network [OSTI]

    Mejri, S; Kozlova, O; Ayari, C; Tokunaga, Sean; Chardonnet, C; Briaudeau, S; Darquié, B; Rohart, F; Daussy, C

    2015-01-01T23:59:59.000Z

    We report on our ongoing effort to measure the Boltzmann constant, $k_B,$ using the Doppler broadening technique on ammonia. This paper presents some of the improvements made to the mid-infrared spectrometer including the use of a phase-stabilized quantum cascade laser, a lineshape analysis based on a refined physical model and an improved fitting program 2 increasing the confidence in our estimates of the relevant molecular parameters, and a first evaluation of the saturation parameter and its impact on the measurement of k B. A summary of the systematic effects contributing to the measurement is given and the optimal experimental conditions for mitigating those effects in order to reach a competitive measurement of $k_B$ at a part per million accuracy level are outlined.

  5. Measuring the Boltzmann constant by mid-infrared laser spectroscopy of ammonia

    E-Print Network [OSTI]

    S. Mejri; Papa Sow; O. Kozlova; C. Ayari; Sean Tokunaga; C. Chardonnet; S. Briaudeau; B. Darquié; F. Rohart; C. Daussy

    2015-06-05T23:59:59.000Z

    We report on our ongoing effort to measure the Boltzmann constant, $k_B,$ using the Doppler broadening technique on ammonia. This paper presents some of the improvements made to the mid-infrared spectrometer including the use of a phase-stabilized quantum cascade laser, a lineshape analysis based on a refined physical model and an improved fitting program 2 increasing the confidence in our estimates of the relevant molecular parameters, and a first evaluation of the saturation parameter and its impact on the measurement of k B. A summary of the systematic effects contributing to the measurement is given and the optimal experimental conditions for mitigating those effects in order to reach a competitive measurement of $k_B$ at a part per million accuracy level are outlined.

  6. Multifaceted regulations of gateway enzyme phenylalanine ammonia-lyase in the biosynthesis of phenylpropanoids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Xuebin [Brookhaven National Lab. (BNL), Upton, NY (United States); Liu, Chang-Jun [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    Phenylpropanoid biosynthesis in plants engenders a vast variety of aromatic metabolites critically important for their growth, development, and environmental adaptation. Some of these aromatic compounds have high economic value. Phenylalanine ammonia-lyase (PAL) is the first committed enzyme in the pathway; it diverts the central flux of carbon from primary metabolism to the synthesis of myriad phenolics. Over the decades, many studies have shown that exquisite regulatory mechanisms at multiple levels control the transcription and the enzymatic activity of PALs. In this review, we present a current overview on our understanding of the complicated regulatory mechanisms governing PAL's activity; we particularly highlight recent progresses in unraveling its post-translational modifications, its metabolite feedback regulation, and its enzyme organization.

  7. Evaluation of Aqua-Ammonia Chiller Technologies and Field Site Installation

    SciTech Connect (OSTI)

    Zaltash, Abdolreza [ORNL

    2007-09-01T23:59:59.000Z

    The Naval Facilities Engineering Service Center (NFESC) has sponsored Oak Ridge National Laboratory (ORNL) to review, select, and evaluate advanced, gas-fired, 5-ton, aqua-ammonia, chiller technologies. The selection criteria was that units have COP values of 0.67 or better at Air-conditioning and Refrigeration Institute (ARI) 95 F outdoor rating conditions, an active refrigerant flow control, and a variable-speed condenser fan. These features are expected to allow these units to operate at higher ambient temperatures (up to the maximum operating temperature of 110 F) with minimal degradation in performance. ORNL evaluated three potential manufacturers of advanced, gas-fired, 5-ton, aqua-ammonia chillers-Robur, Ambian, and Cooling Technologies. Unfortunately, Robur did not meet the COP requirements and Cooling Technologies could not deliver a unit to be tested at the U.S. Department of Energy (DOE)-ORNL environmental chamber testing facility for thermally activated heat pumps. This eliminated these two technologies from further consideration, leaving only the Ambian chillers for evaluation. Two Ambian chillers were evaluated at the DOE-ORNL test facility. Overall these chillers operated well over a wide range of ambient conditions with minimal degradation in performance due to several control strategies used such as a variable speed condenser fan, a modulating burner, and active refrigerant flow control. These Ambian pre-commercial units were selected for installation and field testing at three federal facilities. NFESC worked with ORNL to assist with the site selection for installation and evaluation of these chillers. Two sites (ORNL and Naval Surface Warfare Center [NSWC] Corona) had a single chiller unit installed; and at one site (Naval Amphibious Base [NAB] Little Creek), two 5-ton chillers linked together were installed to provide 10 tons of cooling. A chiller link controller developed under this project was evaluated in the field test at Little Creek.

  8. Scale-Up Information for Gas-Phase Ammonia Treatment of Uranium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Thomle, Jonathan N.; Johnson, Timothy C.

    2014-09-01T23:59:59.000Z

    Uranium is present in the vadose zone at the Hanford Central Plateau and is of concern for protection of groundwater. The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau identified gas-phase treatment and geochemical manipulation as potentially effective treatment approaches for uranium and technetium in the Hanford Central Plateau vadose zone. Based on laboratory evaluation, use of ammonia vapor was selected as the most promising uranium treatment candidate for further development and field testing. While laboratory tests have shown that ammonia treatment effectively reduces the mobility of uranium, additional information is needed to enable deployment of this technology for remediation. Of importance for field applications are aspects of the technology associated with effective distribution of ammonia to a targeted treatment zone, understanding the fate of injected ammonia and its impact on subsurface conditions, and identifying effective monitoring approaches. In addition, information is needed to select equipment and operational parameters for a field design. As part of development efforts for the ammonia technology for remediation of vadose zone uranium contamination, field scale-up issues were identified and have been addressed through a series of laboratory and modeling efforts. This report presents a conceptual description for field application of the ammonia treatment process, engineering calculations to support treatment design, ammonia transport information, field application monitoring approaches, and a discussion of processes affecting the fate of ammonia in the subsurface. The report compiles this information from previous publications and from recent research and development activities. The intent of this report is to provide technical information about these scale-up elements to support the design and operation of a field test for the ammonia treatment technology.

  9. Environmental effects of dredging: Naturally occurring levels of ammonia and sulfide in pore water: An assessment of the literature. Technical notes

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Ammonia and sulfide are natural constituents of sediment. Both are very toxic to aquatic organisms. Consequently, their presence may bias dredged material toxicity bioassays that are designed to evaluate the toxicity of persistent contaminants such as heavy metals and petroleum and chlorinated hydrocarbons. The purpose of this technical note is to summarize published information on sediment pore water ammonia and sulfide concentrations that occur in situ. In a subsequent technical note, this exposure information will be coupled with ammonia and sulfide toxicity data to estimate the potential influence of these constituents on dredged material toxicity bioassays.

  10. Supporting Information Surface Electric Fields of Aqueous Solutions of NH4NO3, Mg(NO3)2, NaNO3,

    E-Print Network [OSTI]

    S1 Supporting Information Surface Electric Fields of Aqueous Solutions of NH4NO3, Mg(NO3)2, NaNO3 interfaces of (a) 1.0 M and 2.0 M LiNO3, (b) 1.0 M and 1.7 M NaNO3, (c) 1.0 M and 1.6 M NH4NO3, and (d) 1.0 M water 1.0 M NaNO3 1.7 M NaNO3 c water 1.0 M NH4 NO3 1.6 M NH4 NO3 | (2) | 2 (10 3 arb.units) Wavenumber

  11. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    as a fuel in solid oxide fuel cells,” J. Power Sources 118:L. and Bloomfield, D.P. , “Ammonia Cracker for Fuel Cells”,1998 Fuel Cell Seminar Abstracts, November 16-19, Palm

  12. Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [Os(III)(tpy)(Cl)(NH=CHCH3)(NSAr)

    SciTech Connect (OSTI)

    Ess, Daniel H.; Schauer, Cynthia; Meyer, Thomas J.

    2010-01-01T23:59:59.000Z

    Quantum mechanical analysis reveals that carbonyl reduction of aldehydes and ketones by the imine-based reductant cis-[Os{sup III}(tpy)(Cl)(NH?CHCH{sub 3})(NSAr)] (2), which is accessible by reduction of the analogous nitrile, occurs by hydride-proton transfer (HPT) involving both the imine and sulfilimido ligands. In carbonyl reduction, water or alcohol is necessary to significantly lower the barrier for proton shuttling between ligands. The ?N(H)SAr group activates the carbonyl group through hydrogen bonding while the ?NC(H)CH{sub 3} ligand delivers the hydride.

  13. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

    SciTech Connect (OSTI)

    Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

    2010-10-01T23:59:59.000Z

    Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOE’s 2010 and 2015 targets for system wt%.

  14. Effect of Thermal Annealing in Ammonia on the Properties of InGaN Nanowires with Different Indium Concentrations

    SciTech Connect (OSTI)

    Hahn, Cristopher; Cordones, Amy; Andrews, Sean; Gao, Hanwei; Fu, Anthony; Leone, Stephen; Yang, Peidong

    2012-10-02T23:59:59.000Z

    The utility of an annealing procedure in ammonia ambient is investigated for improving the optical characteristics of InxGa1?xN nanowires (0.07 ? x ? 0.42) grown on c-Al2O3 using a halide chemical vapor deposition method. Morphological studies using scanning electron microscopy confirm that the nanowire morphology is retained after annealing in ammonia at temperatures up to 800 ?C. However, significant indium etching and composition inhomogeneities are observed for higher indium composition nanowires (x = 0.28, 0.42), as measured by energy-dispersive X-ray spectroscopy and Z-contrast scanning transmission electron microscopy. Structural analyses, using X-ray diffraction and high-resolution transmission electron microscopy, indicate that this is a result of the greater thermal instability of higher indium composition nanowires. The effect of these structural changes on the optical quality of InGaN nanowires is examined using steady-state and time-resolved photoluminescence measurements. Annealing in ammonia enhances the integrated photoluminescence intensity of InxGa1?xN nanowires by up to a factor of 4.11 ? 0.03 (for x = 0.42) by increasing the rate of radiative recombination. Fitting of photoluminescence decay curves to a Kohlrausch stretched exponential indicates that this increase is directly related to a larger distribution of recombination rates from composition inhomogeneities caused by annealing. The results demonstrate the role of thermal instability on the improved optical properties of InGaN nanowires annealed in ammonia.

  15. Proceedings of the Iowa Egg Industry Symposium, Ames, IA November 7, 2003 Updates on Ammonia Emission from Iowa Layer Houses

    E-Print Network [OSTI]

    Kentucky, University of

    -200±3 ppm; Pac III, Dräeger Safety, Inc., Pittsburg, PA) for NH3 measurement and infrared sensor (0 there is a pressing need for research-based data on aerial emissions and evaluation of mitigation techniques under representative U.S. poultry houses and evaluate the efficacy of certain management practices. Selected layer

  16. Technical and economic assessment of the use of ammonia expanders for energy recovery in air-cooled power plants

    SciTech Connect (OSTI)

    Hauser, S.G.; Hane, G.J.; Johnson, B.M.

    1982-07-01T23:59:59.000Z

    Binary cycle power plants have been the subject of much discussion among engineers and scientists for nearly 100 years. Current economic and environmental concerns have stimulated new interest and research. Ammonia has been recommended by other studies as the leading contender for use as simply the heat rejection medium in an air-cooled power plant. This study investigates the technical feasibility and economic potential of including an expander in the heat rejection system of an air-cooled power plant. The expander would be used during certain parts of the year to increase the total output of the power plant. Five different plant locations (Miami, San Francisco, Bakersfield, Chicago, Anchorage) were investigated to show the effect which climate has on the economic potential of this ammonia bottoming cycle. The study shows that the expected energy costs for the bottoming cycle only will be less than 50 mills/kWh for any of the five plant locations. This cost assumes that an ammonia phase-change heat rejection system is already a part of the existing plant. The colder climates of Chicago and Anchorage demonstrate an even smaller energy cost of less than 15 mills/kWh. Further investigation of the concept is merited to substantiate these costs and determine the needed technology.

  17. Massive quiescent cores in Orion. IV. Their supercritical state revealed by high resolution ammonia maps

    E-Print Network [OSTI]

    Li, D; Zhang, Q; Chen, W

    2012-01-01T23:59:59.000Z

    We present combined VLA and GBT images of \\ammonia\\ inversion transitions (1,1) and (2,2) toward OMC2 and OMC3. We focus on the relatively quiescent Orion cores, which are away from the Trapezium cluster and have no sign of massive protostars nor evolved star formation, such as IRAS source, water maser, and methanol maser. The 5\\arcsec\\ angular resolution and $0.6 \\rm{}km s^{-1}$ velocity resolution of these data enable us to study the thermal and dynamic state of these cores at $\\sim{}0.02 \\rm{}pc$ scales, comparable to or smaller than those of the current dust continuum surveys. We measure temperatures for a total of 30 cores, with average masses and radii of $11 \\Ms$ and $0.039 \\rm{}pc$, respectively. Compared to other Gould Belt dense cores, the Orion cores have an unusually high gravitational-to-inetic energy ratio (virial mass ratio $R_{vir} > >1$), resembling results for other clouds forming high--mass stars. This results from Orion cores having velocity dispersions similar to those in, e.g., Perseus a...

  18. 4D Density Determination of NH Radicals in an MSE Microplasma Combining Planar Laser Induced Fluorescence and Cavity Ring-Down Spectroscopy

    SciTech Connect (OSTI)

    Visser, Martin; Schenk, Andreas; Gericke, Karl-Heinz [Technische Universitaet Braunschweig, Institut fuer Physikalische und Theoretische Chemie Hans-Sommer-Str. 10, 38106 Braunschweig (Germany)

    2010-10-13T23:59:59.000Z

    An application of microplasmas is surface modification under mild conditions and of small, well defined areas. For this, an understanding of the plasma composition is of importance. First results of our work on the production and detection of NH radicals in a capacitively coupled radio frequency (RF) microplasma are presented. A microstructured comb electrode was used to generate a glow discharge in a hydrogen/nitrogen gas mixture by applying 13.56 MHz RF voltage. The techniques of planar laser induced fluorescence (PLIF) and cavity ring-down spectroscopy (CRDS) are used for space and time resolved, quantitative detection of the NH radical in the plasma. The rotational temperature was determined to be 820 K and, the density 5.1x10{sup 12} cm{sup 3}. Also, time dependent behaviour of the NH production was observed.

  19. Unusual defect physics in CH{sub 3}NH{sub 3}PbI{sub 3} perovskite solar cell absorber

    SciTech Connect (OSTI)

    Yin, Wan-Jian, E-mail: wanjian.yin@utoledo.edu; Shi, Tingting; Yan, Yanfa, E-mail: yanfa.yan@utoledo.edu [Department of Physics and Astronomy and Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606 (United States)

    2014-02-10T23:59:59.000Z

    Thin-film solar cells based on Methylammonium triiodideplumbate (CH{sub 3}NH{sub 3}PbI{sub 3}) halide perovskites have recently shown remarkable performance. First-principle calculations show that CH{sub 3}NH{sub 3}PbI{sub 3} has unusual defect physics: (i) Different from common p-type thin-film solar cell absorbers, it exhibits flexible conductivity from good p-type, intrinsic to good n-type depending on the growth conditions; (ii) Dominant intrinsic defects create only shallow levels, which partially explain the long electron-hole diffusion length and high open-circuit voltage in solar cell. The unusual defect properties can be attributed to the strong Pb lone-pair s orbital and I p orbital antibonding coupling and the high ionicity of CH{sub 3}NH{sub 3}PbI{sub 3}.

  20. Encapsulation of titanium (IV) silsesquioxane into the NH{sub 4}USY zeolite: Preparation, characterization and application

    SciTech Connect (OSTI)

    Ribeiro do Carmo, Devaney [Faculdade de Engenharia de Ilha Solteira (UNESP), Departamento de Fisica e Quimica, Av. Brasil Centro, 56 CEP 15385-000, Ilha Solteira, SP (Brazil)], E-mail: docarmo@dfq.feis.unesp.br; Dias Filho, Newton Luiz [Faculdade de Engenharia de Ilha Solteira (UNESP), Departamento de Fisica e Quimica, Av. Brasil Centro, 56 CEP 15385-000, Ilha Solteira, SP (Brazil); Ramos Stradiotto, Nelson [Universidade Estadual Paulista, UNESP, Instituto de Quimica PO Box, Araraquara, SP (Brazil)

    2007-10-02T23:59:59.000Z

    This work describes the encapsulation of titanium (IV) silsesquioxane into the supercavities of NH{sub 4}USY ultra stabilized zeolite, after chemical treatment. The modified zeolite was characterized by Fourier transform infrared spectra, Nuclear magnetic resonance, scanning electronic microscopy, X-ray diffraction and thermogravity. This encapsulated titanium (IV) silsesquioxane can adsorb Azure A chloride after treatment with H{sub 3}PO{sub 4}, without modifier leaching problems. In an electrochemical study, the cyclic voltammograms of the graphite paste modified electrode, shows two redox couples with formal potential (E{sup 0}') -0.1 V and 0.21 V to I and II redox couples respectively (v=700mVs{sup -1}; Britton Robinson buffer (B-R) solution, pH 3) versus SCE ascribed to a monomer and dimmer of azure. This paper shows the use of ultra stabilized zeolite in the electrochemical field as host for molecules with nanometric dimensions.

  1. A low-temperature process for the denitration of Hanford single-shell tank, nitrate-based waste utilizing the nitrate to ammonia and ceramic (NAC) or nitrate to ammonia and glass (NAG) process: Phase 2 report

    SciTech Connect (OSTI)

    Mattus, A.J.; Walker, J.F. Jr.; Youngblood, E.L.; Farr, L.L.; Lee, D.D.; Dillow, T.A.; Tiegs, T.N.

    1994-12-01T23:59:59.000Z

    Continuing benchtop studies using Hanford single-shell tank (SST) simulants and actual Oak Ridge National Laboratory (ORNL) low-level waste (LLW), employing a new denitration process for converting nitrate to ammonia and ceramic (NAC), have conclusively shown that between 85 and 99% of the nitrate can be readily converted to gaseous ammonia. In this process, aluminum powders can be used to convert alkaline, nitrate-based supernate to ammonia and an aluminum oxide-sodium aluminate-based solid. The process may be able to use contaminated aluminum scrap metal from DOE sites to effect the conversion. The final, nitrate-free ceramic product can be pressed and sintered like other ceramics or silica and/or fluxing agents can be added to form a glassy ceramic or a flowable glass product. Based upon the starting volumes of 6.2 and 3.1 M sodium nitrate solution, volume reductions of 50 to 70% were obtained for the waste form produced. Sintered pellets produced from supernate from Melton Valley Storage Tanks (MVSTs) have been leached in accordance with the 16.1 leach test for the radioelements {sup 85}Sr and {sup 137}Cs. Despite lengthy counting times, {sup 85}Sr could not be detected in the leachates. {sup 137}Cs was only slightly above background and corresponded to a leach index of 12.2 to 13.7 after 8 months of leaching. Leach testing of unsintered and sintered reactor product spiked with hazardous metals proved that both sintered and unsintered product passed the Toxicity Characteristic Leaching Procedure (TCLP) test. Design of the equipment and flowsheet for a pilot demonstration-scale system to prove the nitrate destruction portion of the NAC process and product formation is under way.

  2. INCOMPATIBLE CHEMICAL LIST PRUDENT PRACTICES FOR HANDLING CHEMICALS IN LABORATORIES

    E-Print Network [OSTI]

    Cho, Junghyun

    tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia (anhydrous) Mercury (in oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals, sulfur tetrachloride, carbon dioxide, water Potassium chlorate Sulfuric and other acids Potassium perchlorate (see also

  3. Solvent extraction of Li+, H3O+ and NH4+ into nitrobenzene by using sodium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)

    SciTech Connect (OSTI)

    Makrlik, Emanuel [Czech University of Life Sciences, Prague, Kamy´cká; Selucky, P. [Nuclear Research Institute, Rez, Czech Republic; Vanura, Petr [Institute of Chemical Technology, Prague, Czech Republic; Moyer, Bruce A [ORNL

    2013-01-01T23:59:59.000Z

    From extraction experiments and c-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + NaL+ (nb) , ML+ (nb) + Na+ (aq) taking place in the two-phase water nitrobenzene system (M+ = Li+, H3O+, NH+4; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: zH3O+ < Li+ < NH+4.

  4. Phase Transformations of the Ternary System (NH4)2SO4-H2SO4-H2O and the Implications for Cirrus Cloud Formation

    E-Print Network [OSTI]

    the presence of NH4 + ions in the aerosol of the upper troposphere. Low-temperature ternary phase diagrams distribution alters the cloud's radiative properties, persistence, and surface area available for heterogeneous radiation, which insulates or warms Earth, and scattering the sun's visible radiation upward, thus cooling

  5. Mixed quantum/classical investigation of the photodissociation of NH3,,A~ ... and a practical method for maintaining zero-point energy

    E-Print Network [OSTI]

    Truhlar, Donald G

    with a classical mechanical treatment of nuclear motion on coupled potential-energy surfaces. Whereas older mixedMixed quantum/classical investigation of the photodissociation of NH3,,A~ ... and a practical method for maintaining zero-point energy in classical trajectories David Bonhommeaua and Donald G

  6. Structural And Biochemical Characterization of the Therapeutic A. Variabilis Phenylalanine Ammonia Lyase

    SciTech Connect (OSTI)

    Wang, L.; Gamez, A.; Archer, H.; Abola, E.E.; Sarkissian, C.N.; Fitzpatrick, P.; Wendt, D.; Zhang, Y.; Vellard, M.; Bliesath, J.; Bell, S.; Lemont, J.; Scriver, C.R.; Stevens, R.C.

    2009-05-26T23:59:59.000Z

    We have recently observed promising success in a mouse model for treating the metabolic disorder phenylketonuria with phenylalanine ammonia lyase (PAL) from Rhodosporidium toruloides and Anabaena variabilis. Both molecules, however, required further optimization in order to overcome problems with protease susceptibility, thermal stability, and aggregation. Previously, we optimized PAL from R. toruloides, and in this case we reduced aggregation of the A. variabilis PAL by mutating two surface cysteine residues (C503 and C565) to serines. Additionally, we report the structural and biochemical characterization of the A. variabilis PAL C503S/C565S double mutant and carefully compare this molecule with the R. toruloides engineered PAL molecule. Unlike previously published PAL structures, significant electron density is observed for the two active-site loops in the A. variabilis C503S/C565S double mutant, yielding a complete view of the active site. Docking studies and N-hydroxysuccinimide-biotin binding studies support a proposed mechanism in which the amino group of the phenylalanine substrate is attacked directly by the 4-methylidene-imidazole-5-one prosthetic group. We propose a helix-to-loop conformational switch in the helices flanking the inner active-site loop that regulates accessibility of the active site. Differences in loop stability among PAL homologs may explain the observed variation in enzyme efficiency, despite the highly conserved structure of the active site. A. variabilis C503S/C565S PAL is shown to be both more thermally stable and more resistant to proteolytic cleavage than R. toruloides PAL. Additional increases in thermal stability and protease resistance upon ligand binding may be due to enhanced interactions among the residues of the active site, possibly locking the active-site structure in place and stabilizing the tetramer. Examination of the A. variabilis C503S/C565S PAL structure, combined with analysis of its physical properties, provides a structural basis for further engineering of residues that could result in a better therapeutic molecule.

  7. JOURNAL DE PHYSIQUE CoZZoque C8, suppZ6ment aa n o 8, Tome 42, amAt 2980, page C8-32 NMR STUD1ES OF CONCENTRATED LITHIUM-AMMONIA SOLUTIONS

    E-Print Network [OSTI]

    Boyer, Edmond

    OF CONCENTRATED LITHIUM-AMMONIA SOLUTIONS Y. Nakamura, M. Niibe and M . Shimoji Deparhent o f Chemistry, FaeuZty o in liquid ammonia show very interesting properties with varying metal concentration; from electrolytic results of the Knight shift, KLi, and the spin-lattice relaxation tine, T1, of 7 ~ i in the lithium

  8. Effects of constraints in general branched molecules: A quantitative ab initio study in HCO-L-Ala-NH2

    E-Print Network [OSTI]

    Pablo Echenique; J. L. Alonso; Ivan Calvo

    2006-12-04T23:59:59.000Z

    A general approach to the design of accurate classical potentials for protein folding is described. It includes the introduction of a meaningful statistical measure of the differences between approximations of the same potential energy, the definition of a set of Systematic and Approximately Separable and Modular Internal Coordinates (SASMIC), much convenient for the simulation of general branched molecules, and the imposition of constraints on the most rapidly oscillating degrees of freedom. All these tools are used to study the effects of constraints in the Conformational Equilibrium Distribution (CED) of the model dipeptide HCO-L-Ala-NH2. We use ab initio Quantum Mechanics calculations including electron correlation at the MP2 level to describe the system, and we measure the conformational dependence of the correcting terms to the naive CED based in the Potential Energy Surface (PES) without any simplifying assumption. These terms are related to mass-metric tensors determinants and also occur in the Fixman's compensating potential. We show that some of the corrections are non-negligible if one is interested in the whole Ramachandran space. On the other hand, if only the energetically lower region, containing the principal secondary structure elements, is assumed to be relevant, then, all correcting terms may be neglected up to peptides of considerable length. This is the first time, as far as we know, that the analysis of the conformational dependence of these correcting terms is performed in a relevant biomolecule with a realistic potential energy function.

  9. MOSE: zooming on the Meso-NH mesoscale model performances at the surface layer at ESO sites (Paranal and Armazones)

    E-Print Network [OSTI]

    Lascaux, Franck; di Arcetri, INAF / Osservatorio Astrofisico; 10.1117/12.925934

    2012-01-01T23:59:59.000Z

    In the context of the MOSE project, in this contribution we present a detailed analysis of the Meso-NH mesoscale model performances and their dependency on the model and orography horizontal resolutions in proximity of the ground. The investigated sites are Cerro Paranal (site of the ESO Very Large Telescope - VLT) and Cerro Armazones (site of the ESO European Extremely Large Telescope - E-ELT), in Chile. At both sites, data from a rich statistical sample of different nights are available - from AWS (Automated Weather Stations) and masts - giving access to wind speed, wind direction and temperature at different levels near the ground (from 2 m to 30 m above the ground). In this study we discuss the use of a very high horizontal resolution (dX=0.1 km) numerical configuration that overcomes some specific limitations put in evidence with a standard configuration with dX=0.5 km. In both sites results are very promising. The study is co-funded by ESO and INAF.

  10. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  11. Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts 

    E-Print Network [OSTI]

    Oh, Hyuk Jin

    2004-09-30T23:59:59.000Z

    The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow ...

  12. Estimation of ammonia volatilization from surface-applied urea as indicated by bermudagrass N-use efficiency 

    E-Print Network [OSTI]

    Drwal, John Matthew

    1986-01-01T23:59:59.000Z

    contrasting physical and chemical characteristics; an acid Lufkin fine sandy loam, and a calcareous Ships clay. A treatment of urea amended with CaC1& in solution form was also applied to determine if CaC12 inhibited NH3 loss, as other researchers have... in 1984 and 8 in 1985) . 31 Dry matter yield of Coastal bermudagrass on Ships soil as affected by N source (100 kg N ha ). Values are the means of multiple experiments (6 in 1984 and 6 in 1985) . . . . . . . . . . . . . . ~ ~ 33 Dry matter yield of S...

  13. Direct Observation of Long Electron-Hole Diffusion Distance beyond 1 Micrometer in CH3NH3PbI3 Perovskite Thin Film

    E-Print Network [OSTI]

    Li, Yu; Li, Yunlong; Wang, Wei; Bian, Zuqiang; Xiao, Lixin; Wang, Shufeng; Gong, Qihuang

    2015-01-01T23:59:59.000Z

    In high performance perovskite based on CH3NH3PbI3, the formerly reported short charge diffusion distance is a confliction to thick working layer in solar cell devices. We carried out a study on charge diffusion in spin-coated CH3NH3PbI3 perovskite thin film by transient fluorescent spectroscopy. A thickness-dependent fluorescent lifetime was found. This effect correlates to the defects at crystal grain boundaries. By coating the film with electron or hole transfer layer, PCBM or Spiro-OMeTAD respectively, we observed the charge transfer directly through the fluorescent decay. One-dimensional diffusion model was applied to obtain long charge diffusion distances, which is ~1.3 micron for electrons and ~5.2 micron for holes. This study gives direct support to the high performance of perovskite solar cells.

  14. Effect of NH{sub 3} on the low pressure chemical vapor deposition of TiO{sub 2} film at low temperature using tetrakis(diethylamino)titanium and oxygen

    SciTech Connect (OSTI)

    Song Xuemei; Takoudis, Christos G. [Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607 (United States); Department of Chemical Engineering, University of Illinois at Chicago, Chicago, Illinois 60607 and Department of Bioengineering, University of Illinois at Chicago, Chicago, Illinois 60607 (United States)

    2007-03-15T23:59:59.000Z

    The effect of NH{sub 3} on TiO{sub 2} film deposition using tetrakis(diethylamino)titanium (TDEAT) and O{sub 2} as source gases in a low pressure chemical vapor deposition reactor was studied at low temperatures ranging from 100 to 250 deg. C. TiO{sub 2} film is traditionally deposited at temperature above 300 deg. C using oxygen-based Ti precursors, such as titanium tetraisopropoxide. In this study, the authors demonstrate that a combination of both reactive precursors, i.e., TDEAT and NH{sub 3}, is an effective technique for TiO{sub 2} film deposition at lower temperatures, albeit with some nitrogen incorporation. It was found that films can be formed at temperatures as low as 100 deg. C when NH{sub 3} is used. At higher temperatures, the growth rate of TiO{sub 2} films deposited using NH{sub 3} is higher than that of films deposited without NH{sub 3} by up to one order of magnitude. X-ray photoelectron spectroscopy data show that NH{sub 3} enhances the formation of TiNO and TiN, and x-ray diffraction analysis shows that all as-deposited films have amorphous structure. Both x-ray photoelectron spectroscopy and secondary ion mass spectroscopy depth profiles show that nitrogen, carbon, and oxygen are uniformly distributed throughout the film. The mechanism of enhancement of growth rate using NH{sub 3} is also discussed.

  15. Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

  16. Tiu Ch Chn La D n Khi Phc Sm Vo ngy 21 thng 4 nm 2011, cc y Vin nh Gi Tn Hi

    E-Print Network [OSTI]

    con ngi bng cách khôi phc, phc hi môi trng sng, thay th, hoc thu gom mt lng tng ng vi ngun tài nguyên thiên nhiên có cht lng, giá tr sinh thái hoc dân dng tng ng n bù các tài nguyên và dch v b tn hi t s c, nhng vn c chp nhn và hu ích giúp sàng lc mt s lng ln các d án có tim nng. Không mt yu t nào c s dng nh

  17. Energetics of H and NH2 on GaN,,1010... and implications for the origin of nanopipe defects John E. Northrup and R. Di Felice

    E-Print Network [OSTI]

    Energetics of H and NH2 on GaN,,101¯0... and implications for the origin of nanopipe defects John E-terminated GaN 101¯0 surfaces. The calculations indicate that H adsorption on GaN 101¯0 will proceed. The implications of these results for the origin of nanopipe defects in GaN are examined. S0163-1829 97 51832

  18. Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part I. Regeneration of Amine-Carboxylic Acid Extracts

    SciTech Connect (OSTI)

    Poole, L.J.; King, C.J.

    1990-03-01T23:59:59.000Z

    Two novel regenerated solvent extraction processes are examined. The first process has the potential to reduce the energy costs inherent in the recovery of low-volatility carboxylic acids from dilute aqueous solutions. The second process has the potential for reducing the energy costs required for separate recovery of ammonia and acid gases (e.g. CO{sub 2} and H{sub 2}S) from industrial sour waters. The recovery of carboxylic acids from dilute aqueous solution can be achieved by extraction with tertiary amines. An approach for regeneration and product recovery from such extracts is to back-extract the carboxylic acid with a water-soluble, volatile tertiary amine, such as trimethylamine. The resulting trimethylammonium carboxylate solution can be concentrated and thermally decomposed, yielding the product acid and the volatile amine for recycle. Experimental work was performed with lactic acid, succinic acid, and fumaric acid. Equilibrium data show near-stoichiometric recovery of the carboxylic acids from an organic solution of Alamine 336 into aqueous solutions of trimethylamine. For fumaric and succinic acids, partial evaporation of the aqueous back extract decomposes the carboxylate and yields the acid product in crystalline form. The decomposition of aqueous solutions of trimethylammonium lactates was not carried out to completion, due to the high water solubility of lactic acid and the tendency of the acid to self-associate. The separate recovery of ammonia and acid gases from sour waters can be achieved by combining steam-stripping of the acid gases with simultaneous removal of ammonia by extraction with a liquid cation exchanger. The use of di-2,4,4-trimethylpentyl phosphinic acid as the liquid cation exchanger is explored in this work. Batch extraction experiments were carried out to measure the equilibrium distribution ratio of ammonia between an aqueous buffer solution and an organic solution of the phosphinic acid (0.2N) in Norpar 12. The concentration-based distribution ratios increase from 0.11 to 0.46 as the aqueous phase pH increases from 7.18 to 8.15. Regeneration of the organic extractant solution was carried out by stripping at elevated temperatures to remove the ammonia, with 99% recovery of the ammonia being obtained at 125 C.

  19. The Effect of HF/NH4F Etching on the Morphology of Surface Fractures on Fused Silica

    SciTech Connect (OSTI)

    Wong, L; Suratwala, T; Feit, M D; Miller, P E; Steele, R A

    2008-04-03T23:59:59.000Z

    The effects of HF/NH{sub 4}F, wet chemical etching on the morphology of individual surface fractures (indentations, scratches) and of an ensemble of surface fractures (ground surfaces) on fused silica glass has been characterized. For the individual surface fractures, a series of static or dynamic (sliding) Vickers and Brinnell indenters were used to create radial, lateral, Hertzian cone and trailing indentation fractures on a set of polished fused silica substrates which were subsequently etched. After short etch times, the visibility of both surface and subsurface cracks is significantly enhanced when observed by optical microscopy. This is attributed to the removal of the polishing-induced Bielby layer and the increased width of the cracks following etching allowing for greater optical scatter at the fracture interface. The removal of material during etching was found to be isotropic except in areas where the etchant has difficulty penetrating or in areas that exhibit significant plastic deformation/densification. Isolated fractures continue to etch, but will never be completely removed since the bottom and top of the crack both etch at the same rate. The etching behavior of ensembles of closely spaced cracks, such as those produced during grinding, has also been characterized. This was done using a second set of fused silica samples that were ground using either fixed or loose abrasives. The resulting samples were etched and both the etch rate and the morphology of the surfaces were monitored as a function of time. Etching results in the formation of a series of open cracks or cusps, each corresponding to the individual fractures originally on the surface of the substrate. During extended etching, the individual cusps coalesce with one another, providing a means of reducing the depth of subsurface damage and the peak-to-valley roughness. In addition, the material removal rate of the ground surfaces was found to scale with the surface area of the cracks as a function of etch time. The initial removal rate for the ground surface was typically 3.5 x the bulk etch rate. The evolving morphology of ground surfaces during etching was simulated using an isotropic finite difference model. This model illustrates the importance that the initial distributions of fracture sizes and spatial locations have on the evolution of roughness and the rate at which material is removed during the etching process. The etching of ground surfaces can be used during optical fabrication to convert subsurface damage into surface roughness thereby reducing the time required to produce polished surfaces that are free of subsurface damage.

  20. Iron oxide and chromia supported on titania-pillared clay for selective catalytic reduction of nitric oxide with ammonia

    SciTech Connect (OSTI)

    Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States)] [State Univ. of New York, Buffalo, NY (United States); Ning Chen [Univ. of Michigan, Ann Arbor, MI (United States)] [Univ. of Michigan, Ann Arbor, MI (United States)

    1996-11-01T23:59:59.000Z

    TiO{sub 2}-pillard clay (PILC) with high surface area, large pore volume, and large interlayer spacing was used as the support for mixed Fe{sub 2}O{sub 3} and Cr{sub 2}O{sub 3} as the catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3}. The Fe/Cr ratio was varied at a fixed total amount of oxide dopant of 10% (wt). The Fe-Cr/TiO{sub 2}-PILC with Fe/Cr=3 showed the highest activity. Compared with commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts, the activity (on a per gram basis) of the doped pillared clay was approximately twice as high under H{sub 2}O- and SO{sub 2}-free conditions and was approximately 40% higher under conditions with H{sub 2}O and SO{sub 2}. In addition, its activity for SO{sub 2} oxidation was only 20%-25% of that of the V{sub 2}O{sub 5}-based catalysts. TPD of NH{sub 3} on the Fe-Cr/TiO{sub 2}-PILC catalyst showed that both M=O and M-OH (M=Fe or Cr) were necessary for the SCR reaction. In situ IR spectra of NH{sub 3} showed that there was a higher Bronsted acidity than the Lewis acidity on the surface under reaction conditions and that there existed a direct correlation between the SCR activity and the Bronsted acidity among pillared clays with different Fe/Cr ratios. These results, along with the transient response to O{sub 2}, indicated that a similar mechanism to that on the V{sub 2}O{sub 5} catalyst was operative. The TiO{sub 2}-pillared clay used as the support also contributed to the high activity of the Fe-Cr catalyst. The TiO{sub 2} pillars combined with the tetrahedral SiO{sub 2} surfaces of the clay apparently gave rise to a high dispersion of Fe{sub 2}O{sub 3}. 52 refs., 10 figs., 5 tabs.

  1. This book describes the responsibilities of show personnel and outlines the job descriptions of various positions for the NH 4-H State Horse Show (or any other 4-H horse show).

    E-Print Network [OSTI]

    New Hampshire, University of

    of various positions for the NH 4-H State Horse Show (or any other 4-H horse show). June 2013 #12;Table of Contents Organizing a 4-H Horse Show ........................................................................................... 1 State 4-H Horse Show Philosophy................................................................ 1

  2. Sorption of carboxylic acid from carboxylic salt solutions at pHs close to or above the pK[sub a] of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine

    DOE Patents [OSTI]

    King, C.J.; Tung, L.A.

    1992-07-21T23:59:59.000Z

    Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH[sub a] into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. The acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carboxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia. 8 figs.

  3. Heteroepitaxial growth of GaN/Si (111) junctions in ammonia-free atmosphere: Charge transport, optoelectronic, and photovoltaic properties

    SciTech Connect (OSTI)

    Saron, K. M. A.; Hashim, M. R. [Nano-Optoelectronics Research and Technology Laboratory, School of Physics, Universiti Sains Malaysia, Penang 11800 (Malaysia); Allam, Nageh K. [Energy Materials Laboratory (EML), Department of Physics, School of Sciences and Engineering, The American University in Cairo, New Cairo 11835 (Egypt)

    2013-03-28T23:59:59.000Z

    We report the catalyst-free growth of gallium nitride (GaN) nanostructures on n-Si (111) substrates using physical vapor deposition via thermal evaporation of GaN powder at 1150 Degree-Sign C in the absence of NH{sub 3} gas. Scanning electron microscopy and energy dispersive x-ray analysis indicate that the growth rate of GaN nanostructures varies with deposition time. Photoluminescence spectra showed the suppression of the UV emission and the enhancement of the visible band emission with increasing the deposition time. The fabricated GaN nanostructures exhibited p-type behavior at the GaN/Si interface, which can be related to the diffusion of Ga into the Si substrate. The obtained lowest reflection and highest transmittance over a wide wavelength range (450-750 nm) indicate the high quality of the fabricated GaN films. Hall-effect measurements showed that all fabricated films have p-type behavior with decreasing electron concentration from 10{sup 21} to 10{sup 12} cm{sup -3} and increasing the electron mobility from 50 to 225 cm{sup 2}/V s with increasing the growth time. The fabricated solar cell based on the 1 h-deposited GaN nanostructures on n-Si (111) substrate showed a well-defined rectifying behavior with a rectification ratio larger than 8.32 Multiplication-Sign 10{sup 3} in dark. Upon illumination (30 mW/cm{sup 2}), the 1 h-deposited heterojunction solar cell device showed a conversion efficiency of 5.78%. The growth of GaN in the absence of NH{sub 3} gas has strong effect on the morphological, optical, and electrical properties and consequently on the efficiency of the solar cell devices made of such layers.

  4. Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts

    E-Print Network [OSTI]

    Oh, Hyuk Jin

    2004-09-30T23:59:59.000Z

    % and NH3 > 87%) about 50°C. An increase in heating area decreased the reaction temperature of the maximum NO reduction from 350 to 300°C, and caused the active reaction temperature window (between 250 and 400°C) to shift toward 50°C lower reaction...

  5. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04T23:59:59.000Z

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as a reductant. Oxidized Green River oil shale heated at 10{degree}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppM/4000 ppM) with a gas residence time of {approximately}0.6 sec removed NO between 250 and 500{degree}C, with maximum removal of 70% at {approximately}400{degree}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH{sub 3} as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant. Parameters calculated for implementing oxidized oil shale for NO{sub x} remediation on the current HRS retort indicate an abatement device is practical to construct.

  6. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 2

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1993-01-04T23:59:59.000Z

    Oxidized oil shale from the combustor in the LLNL Hot-Recycled-Solids (HRS) oil shale retorting process has been found to be a catalyst for removing nitrogen oxides from laboratory gas streams using NH[sub 3] as a reductant. Oxidized Green River oil shale heated at 10[degree]C/min in an Ar/O[sub 2]/NO/NH[sub 3] mixture ([approximately]93%/6%/2000 ppM/4000 ppM) with a gas residence time of [approximately]0.6 sec removed NO between 250 and 500[degree]C, with maximum removal of 70% at [approximately]400[degree]C. Under isothermal conditions with the same gas mixture, the maximum NO removal was [approximately]64%. When CO[sub 2] was added to the gas mixture at [approximately]8%, the NO removal dropped to [approximately]50%. However, increasing the gas residence time to [approximately]1.2 sec, increased NO removal to 63%. Nitrogen balances of these experiments suggest selective catalytic reduction of NO is occurring using NH[sub 3] as the reductant. These results are not based on completely optimized process conditions, but indicate oxidized oil shale is an effective catalyst for NO removal from combustion gas streams using NH[sub 3] as the reductant. Parameters calculated for implementing oxidized oil shale for NO[sub x] remediation on the current HRS retort indicate an abatement device is practical to construct.

  7. Regulatory Safety Issues in the Structural Design Criteria of ASME Section III Subsection NH and for Very High Temperatures for VHTR & GEN IV

    SciTech Connect (OSTI)

    William J. O’Donnell; Donald S. Griffin

    2007-05-07T23:59:59.000Z

    The objective of this task is to identify issues relevant to ASME Section III, Subsection NH [1], and related Code Cases that must be resolved for licensing purposes for VHTGRs (Very High Temperature Gas Reactor concepts such as those of PBMR, Areva, and GA); and to identify the material models, design criteria, and analysis methods that need to be added to the ASME Code to cover the unresolved safety issues. Subsection NH was originally developed to provide structural design criteria and limits for elevated-temperature design of Liquid Metal Fast Breeder Reactor (LMFBR) systems and some gas-cooled systems. The U.S. Nuclear Regulatory Commission (NRC) and its Advisory Committee for Reactor Safeguards (ACRS) reviewed the design limits and procedures in the process of reviewing the Clinch River Breeder Reactor (CRBR) for a construction permit in the late 1970s and early 1980s, and identified issues that needed resolution. In the years since then, the NRC and various contractors have evaluated the applicability of the ASME Code and Code Cases to high-temperature reactor designs such as the VHTGRs, and identified issues that need to be resolved to provide a regulatory basis for licensing. This Report describes: (1) NRC and ACRS safety concerns raised during the licensing process of CRBR , (2) how some of these issues are addressed by the current Subsection NH of the ASME Code; and (3) the material models, design criteria, and analysis methods that need to be added to the ASME Code and Code Cases to cover unresolved regulatory issues for very high temperature service.

  8. Preparation of Single Phase Films of CH3NH3Pb(I1-xBrx)3 with Sharp Optical Band Edges

    E-Print Network [OSTI]

    Sadhanala, Aditya; Deschler, Felix; Thomas, Tudor H; Dutton, Siân E.; Goedel, Karl C.; Hanusch, Fabian C.; Lai, May L.; Steiner, Ullrich; Bein, Thomas; Docampo, Pablo; Cahen, David; Friend, Richard H.

    2014-07-09T23:59:59.000Z

    ?inorganic perovskite (CH3NH3PbI3?xClx) solar cells now show photovoltaic (PV) performance1?4 approaching 18%,5,6 and high charge-carrier mobilities.7 Perovskite films have also shown promising photoluminescence quantum efficiencies (PLQEs) of more than 70% and lasing... .; Grat?zel, M.; Mhaisalkar, S.; Sum, T. C. Low-Temperature Solution- Processed Wavelength-Tunable Perovskites for Lasing. Nat. Mater. 2014, 13, 476?480. (9) Deschler, F.; Price, M.; Pathak, S.; Klintberg, L. E.; Jarausch, D.- D.; Higler, R.; Hu?ttner, S...

  9. anhydrous interplanetary dust: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J. A. M. McDonnell; Kalle Bunte; Hakan Svedhem; Gerhard Drolshagen 2006-09-13 3 Fractal Signatures in Analogs of Interplanetary Dust Particles CERN Preprints Summary:...

  10. anhydrous hydrogen fluoride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effect of Hydrogen Booster System on exhaust gases emissions of an internal combustion engine. The hydrogen booster produces hydrogen and oxygen using six water fuel cells and...

  11. anhydrous hydrogen peroxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with diesel. Main focus of this research is to investigate the performance of diesel engine by injecting hydrogen peroxide as blends with diesel at 2%, 5% and 10 %...

  12. anhydrous li uranyl: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crystal structure and thermal behavior are reported herein. Experimental Synthesis Uranyl nitrate (UO2(NO31 Hydrothermal synthesis, structure and thermal stability of...

  13. anhydrous magnesium chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 16...

  14. anhydrous uranyl chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 60...

  15. anhydrous transcurium halides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of metal halide lamps are investigated, including acoustic resonance, spectral energy, and luminous efficacy. To operate metal halide lamps at intended conditions, (more)...

  16. anhydrous portland cements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    present in hardened cement blends in the long term Sheffield, University of 318 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  17. AFFECTS OF MECHANICAL MILLING AND METAL OXIDE ADDITIVES ON SORPTION KINETICS OF 1:1 LiNH2/MgH2 MIXTURE

    SciTech Connect (OSTI)

    Erdy, C.; Anton, D.; Gray, J.

    2010-12-08T23:59:59.000Z

    The destabilized complex hydride system composed of LiNH{sub 2}:MgH{sub 2} (1:1 molar ratio) is one of the leading candidates of hydrogen storage with a reversible hydrogen storage capacity of 8.1 wt%. A low sorption enthalpy of {approx}32 kJ/mole H{sub 2} was first predicted by Alapati et al. utilizing first principle density function theory (DFT) calculations and has been subsequently confirmed empirically by Lu et al. through differential thermal analysis (DTA). This enthalpy suggests that favorable sorption kinetics should be obtainable at temperatures in the range of 160 C to 200 C. Preliminary experiments reported in the literature indicate that sorption kinetics are substantially lower than expected in this temperature range despite favorable thermodynamics. Systematic isothermal and isobaric sorption experiments were performed using a Sievert's apparatus to form a baseline data set by which to compare kinetic results over the pressure and temperature range anticipated for use of this material as a hydrogen storage media. Various material preparation methods and compositional modifications were performed in attempts to increase the kinetics while lowering the sorption temperatures. This paper outlines the results of these systematic tests and describes a number of beneficial additions which influence kinetics as well as NH{sub 3} formation.

  18. A comparison of the catalytic effect of anhydrous ferric chloride and anhydrous aluminum chloride in Friedel and Crafts reactions

    E-Print Network [OSTI]

    Weddell, William MacNelley

    1941-01-01T23:59:59.000Z

    tAy8 N, aX 84?8 XX+V Sle5 48+8 84ol Se8 88e5 Qy8 88~8 M+0 XSq5 XV j8 'NA' 88i5 N~Q 80+8 P@g Ce~ NeX4 88+% 44s5 85p8 85g8 ~seep 4eggeey Agc'io eMoxtds grows 'ho 5s a @ovy effkoie54 ea4e~ ~st Ce %be coso yf %he Xo&se csA gatko 4... keoioyheeoee 8golheXe eel, eg kye4le ye~ +~%NO I 4 9 'Q + 1 0 4 '4 4. I If + 4 $, t, III 5 0 4f 0 4 4 l8 ZXX+ Rll94'LS 4f 84950$405080 @$5'Ch0848 g s +, s a 1 Xa k0455J4j5051 &4@5 k04tgI @kX@FXC@ y s e y e' e y: * e e e 1I XXw k95%1gltI5050 AOA AHIRO @kg...

  19. Calculation of exact vibrational spectra for P{sub 2}O and CH{sub 2}NH using a phase space wavelet basis

    SciTech Connect (OSTI)

    Halverson, Thomas, E-mail: tom.halverson@ttu.edu; Poirier, Bill [Department of Chemistry and Biochemistry and Department of Physics, Texas Tech University, P.O. Box 41061, Lubbock, Texas 79409-1061 (United States)

    2014-05-28T23:59:59.000Z

    ‘‘Exact” quantum dynamics calculations of vibrational spectra are performed for two molecular systems of widely varying dimensionality (P{sub 2}O and CH{sub 2}NH), using a momentum-symmetrized Gaussian basis. This basis has been previously shown to defeat exponential scaling of computational cost with system dimensionality. The calculations were performed using the new “SWITCHBLADE” black-box code, which utilizes both dimensionally independent algorithms and massive parallelization to compute very large numbers of eigenstates for any fourth-order force field potential, in a single calculation. For both molecules considered here, many thousands of vibrationally excited states were computed, to at least an “intermediate” level of accuracy (tens of wavenumbers). Future modifications to increase the accuracy to “spectroscopic” levels, along with other potential future improvements of the new code, are also discussed.

  20. Crystal structure and electric properties of the organic–inorganic hybrid: [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}

    SciTech Connect (OSTI)

    Mostafa, M.F., E-mail: Mohga40@Yahoo.com; El-khiyami, S.S.

    2014-01-15T23:59:59.000Z

    The new organic-inorganic hybrid [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}, M{sub r}=325.406 crystallized in a triclinic, P1¯, a=7.2816 (5) Å, b=10.0996 (7) Å, c=10.0972 (7) Å, ?=74.368 (4)°, ?=88.046 (4)°, ?=85.974 (3)°, V=713.24 (9) Å{sup 3} and Z=2, D{sub x}=1.486 Mg m{sup ?3}. Differential thermal scanning and x-ray powder diffraction, permittivity and ac conductivity indicated three phase transitions. Conduction takes place via correlated barrier hopping. - Graphical abstract: Display Omitted.

  1. High external quantum efficiency and fill-factor InGaN/GaN heterojunction solar cells grown by NH{sub 3}-based molecular beam epitaxy

    SciTech Connect (OSTI)

    Lang, J. R.; Hurni, C. A.; Cruz, S. C.; Matioli, E.; Speck, J. S. [Department of Materials, University of California, Santa Barbara, California 93106 (United States); Neufeld, C. J.; Mishra, U. K. [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

    2011-03-28T23:59:59.000Z

    High external quantum efficiency (EQE) p-i-n heterojunction solar cells grown by NH{sub 3}-based molecular beam epitaxy are presented. EQE values including optical losses are greater than 50% with fill-factors over 72% when illuminated with a 1 sun AM0 spectrum. Optical absorption measurements in conjunction with EQE measurements indicate an internal quantum efficiency greater than 90% for the InGaN absorbing layer. By adjusting the thickness of the top p-type GaN window contact layer, it is shown that the short-wavelength (<365 nm) quantum efficiency is limited by the minority carrier diffusion length in highly Mg-doped p-GaN.

  2. Catalytic activity of oxidized (combusted) oil shale for removal of nitrogen oxides with ammonia as a reductant in combustion gas streams, Part 1

    SciTech Connect (OSTI)

    Reynolds, J.G.; Taylor, R.W.; Morris, C.J.

    1992-06-10T23:59:59.000Z

    Oxidized oil shale from the combustor in the LLNL hot recycle solids oil shale retorting process has been studied as a catalyst for removing nitrogen oxides from laboratory gas streams using NH{sub 3} as areductant. Combusted Green River oil shale heated at 10{degrees}C/min in an Ar/O{sub 2}/NO/NH{sub 3} mixture ({approximately}93%/6%/2000 ppm/4000 ppm) with a gas residence time of {approximately}0.6 sec exhibited NO removal between 250 and 500{degrees}C, with maximum removal of 70% at {approximately}400{degrees}C. Under isothermal conditions with the same gas mixture, the maximum NO removal was found to be {approximately}64%. When CO{sub 2} was added to the gas mixture at {approximately}8%, the NO removal dropped to {approximately}50%. However, increasing the gas residence time to {approximately}1.2 sec, increased NO removal to 63%. These results are not based on optimized process conditions, but indicate oxidized (combusted) oil shale is an effective catalyst for NO removal from combustion gas streams using NH{sub 3} as the reductant.

  3. Si (111) substrates as highly effective pseudomasks for selective growth of GaN material and devices by ammonia-molecular-beam epitaxy

    SciTech Connect (OSTI)

    Tang, H.; Haffouz, S.; Bardwell, J.A. [Institute for Microstructural Sciences, National Research Council of Canada, Ottawa, Ontario K1A 0R6 (Canada)

    2006-04-24T23:59:59.000Z

    The unique property of Si (111) as effective pseudomask substrate for selective growth of GaN by ammonia-molecular-beam epitaxy is reported. The critical nucleation temperature of GaN on Si (111) surface is found to be as low as 700 deg. C, much lower than that on sapphire or AlN surface. As a result, selective growth of GaN is possible by ammonia-molecular-beam epitaxy on Si (111) substrates using a patterned AlN buffer layer. The wide range of growth temperatures (700-900 deg. C) available for selective growth is a critical advantage for control and optimization of the facet characteristics of the selectively grown GaN patterns as required for potential fabrication of site-specific GaN or InGaN quantum dots. The demonstrated ease of selective growth of GaN on silicon has also implications in potential on-chip integration of GaN devices with silicon devices.

  4. Structure of duplex DNA containing the cisplatin 1,2-{Pt(NH3)2}[superscript 2]+-d(GpG) crosslink at 1.77 [Angstrom] resolution

    E-Print Network [OSTI]

    Todd, Ryan C.

    We report the 1.77-Å resolution X-ray crystal structure of a dodecamer DNA duplex with the sequence 5?-CCTCTGGTCTCC-3? that has been modified to contain a single engineered 1,2-cis-{Pt(NH3)2}2+-d(GpG) cross-link, the major ...

  5. Experimental and Theoretical EPR Study of Jahn?Teller-Active [HIPTN[subscript 3]N]MoL Complexes (L = N[subscript 2], CO, NH[subscript 3])

    E-Print Network [OSTI]

    McNaughton, Rebecca L.

    The trigonally symmetric Mo(III) coordination compounds [HIPTN[subscript 3]N]MoL (L = N[subscript 2], CO, NH[subscript 3]; [HIPTN3N]Mo = [(3,5-(2,4,6-i-Pr[subscript 3]C[subscript 6]H[subscript 2])[subscript 2]C[subscript ...

  6. Synthesis of nanostructured materials in supercritical ammonia: nitrides, metals and oxides Desmoulins-Krawiec S., Aymonier C., Loppinet-Serani A., Weill F., Grosse S., Etourneau J., Cansell F.

    E-Print Network [OSTI]

    Boyer, Edmond

    N in supercritical cryogenic nitrogen by self-propagating-high- temperature synthesis (6.21 MPa, ­141 °C);19 (ii) GaSynthesis of nanostructured materials in supercritical ammonia: nitrides, metals and oxides. Abstract : In this study, the synthesis of nanostructured particles of nitrides (Cr2N, Co2N, Fe4N, Cu3N, Ni

  7. Application of x-ray tomography to optimization of new NOx/NH3 mixed potential sensors for vehicle on-board emissions control

    SciTech Connect (OSTI)

    Nelson, Mark A [Los Alamos National Laboratory; Brosha, Eric L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Garzon, Fernando H [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Mixed potential sensors for the detection of hydrocarbons, NO{sub x}, and NH{sub 3} have been previously developed at Los Alamos National Laboratory (LANL). The LANL sensors have a unique design incorporating dense ceramic-pelletlmetal-wire electrodes and porous electrolytes. The performance of current-biased sensors using an yttria-stabilized zirconia (YSZ) electrolyte and platinum and La{sub 0.8}Sr{sub 0.2}CrO{sub 3} electrodes is reported. X-ray tomography has been applied to non-destructively examine internal structures of these sensors. NO{sub x} and hydrocarbon response of the sensors under various bias conditions is reported, and very little NO{sub x} response hysteresis was observed. The application of a 0.6 {mu}A bias to these sensors shifts the response from a hydrocarbon response to a NO{sub x} response equal for both NO and NO{sub 2} species at approximately 500 {sup o}C in air.

  8. MOSE: a feasibility study for optical turbulence forecasts with the Meso-Nh mesoscale model to support AO facilities at ESO sites (Paranal and Armazones)

    E-Print Network [OSTI]

    Masciadri, E; 10.1117/12.925924

    2012-01-01T23:59:59.000Z

    We present very encouraging preliminary results obtained in the context of the MOSE project, an on-going study aiming at investigating the feasibility of the forecast of the optical turbulence and meteorological parameters (in the free atmosphere as well as in the boundary and surface layer) at Cerro Paranal (site of the Very Large Telescope - VLT) and Cerro Armazones (site of the European Extremely Large Telescope - E-ELT), both in Chile. The study employs the Meso-Nh atmospheric mesoscale model and aims at supplying a tool for optical turbulence forecasts to support the scheduling of the scientific programs and the use of AO facilities at the VLT and the E-ELT. In this study we take advantage of the huge amount of measurements performed so far at Paranal and Armazones by ESO and the TMT consortium in the context of the site selection for the E-ELT and the TMT to constraint/validate the model. A detailed analysis of the model performances in reproducing the atmospheric parameters (T, V, p, H, ...) near the g...

  9. The superionic phase transitions in (NH{sub 4}){sub 3}H(SeO{sub 4}){sub 2} under hydrostatic pressure up to 400?MPa

    SciTech Connect (OSTI)

    Lindner, ?.; Zdanowska-Fr?czek, M., E-mail: mzf@ifmpan.poznan.pl; Paw?owski, A.; Fr?czek, Z. J. [Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, Pozna? 60-179 (Poland)

    2014-10-28T23:59:59.000Z

    The effect of hydrostatic pressure on proton conductivity of (NH{sub 4}){sub 3}H(SeO{sub 4}){sub 2} superionic crystal was studied in a wide temperature range and different isobaric conditions by means of impedance spectroscopy method. The measurements were performed along the trigonal c axis of the crystal, i.e., along the direction perpendicular to the plane in which, in the superionic phases, a dynamically disordered H-bond network is formed. The obtained pressure-temperature phase diagram is linear with increasing pressure. The triple point, which is the point of coexistence of the three phases: ferroelastic phase IV, ferroelastic phase III, and superionic phase II was found at p?=?116.3?MPa and T?=?287.3?K. High pressure leads to increase in the temperature range of stability of both superionic phases and to a drastic decrease in the temperature width of the ferroelastic phase III. With increasing pressure, the range of the superionic phase II expands at the expense of the range of the ferroelastic phase III, which is unstable and vanishes at the triple point.

  10. LOW-TEMPERATURE ION TRAP STUDIES OF N{sup +}({sup 3} P{sub ja} ) + H{sub 2}(j) {yields} NH{sup +} + H

    SciTech Connect (OSTI)

    Zymak, I.; Hejduk, M.; Mulin, D.; Plasil, R.; Glosik, J.; Gerlich, D. [Faculty of Mathematics and Physics, Charles University, Prague (Czech Republic)

    2013-05-01T23:59:59.000Z

    Using a low-temperature 22-pole ion trap apparatus, detailed measurements for the title reaction have been performed between 10 K and 100 K in order to get some state specific information about this fundamental hydrogen abstraction process. The relative population of the two lowest H{sub 2} rotational states, j = 0 and 1, has been varied systematically. NH{sup +} formation is nearly thermo-neutral; however, to date, the energetics are not known with the accuracy required for low-temperature astrochemistry. Additional complications arise from the fact that, so far, there is no reliable theoretical or experimental information on how the reactivity of the N{sup +} ion depends on its fine-structure (FS) state {sup 3} P{sub ja} . Since in the present trapping experiment, thermalization of the initially hot FS population competes with hydrogen abstraction, the evaluation of the decay of N{sup +} ions over long storage times and at various He and H{sub 2} gas densities provides information on these processes. First assuming strict adiabatic behavior, a set of state specific rate coefficients is derived from the measured thermal rate coefficients. In addition, by recording the disappearance of the N{sup +} ions over several orders of magnitude, information on nonadiabatic transitions is extracted including FS-changing collisions.

  11. Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2005-09-30T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition. A series of spectral simulations was performed using the HITRAN code to investigate the potential sensitivity of absorption measurements of ammonia in different spectral regions. It was concluded that ammonia absorption features in the 3000-nm spectral region would be hard to measure due to water vapor interferences. We will concentrate on the spectral region near 1530 nm, where other researchers have had some success in measuring ammonia.

  12. Dilution effects in the dynamics of ammonia oxidation on platinum with an inert or a product species in the feed mixture

    SciTech Connect (OSTI)

    Takoudis, C.G.; Schmidt, L.D.

    1983-11-01T23:59:59.000Z

    In most experiments, the autothermal catalyst temperature was monitored, i.e., the temperature resulting from the combined effects of heat dissipation to the environment and heat generation by reaction. The results of these experiments have revealed stable steady states, sustained periodic oscillations and nonperiodic states. An excess of nitrogen in the feed gas stream leads to simpler single-peaked catalyst temperature oscillations of increasing periods of time - up to 5 min. Small amounts of water vapor produced nonperiodic states at all times. These factors indicate that an interplay of heat and mass transfer, convection, and a heterogeneous mechanism is the cause of the phenomena observed during the oxidation of ammonia by air on platinum, at atmospheric pressure. Catalyst memory may also contribute to these phenomena. 25 references, 4 figures.

  13. A low-temperature process for the denitration of Hanford single-shell tank, nitrate-based waste utilizing the nitrate to ammonia and ceramic (NAC) process

    SciTech Connect (OSTI)

    Mattus, A.J.; Lee, D.D.; Dillow, T.A.; Farr, L.L.; Loghry, S.L.; Pitt, W.W.; Gibson, M.R.

    1994-12-01T23:59:59.000Z

    Bench-top feasibility studies with Hanford single-shell tank (SST) simulants, using a new, low-temperature (50 to 60C) process for converting nitrate to ammonia and ceramic (NAC), have conclusively shown that between 85 to 99% of the nitrate can be readily converted. In this process, aluminum powders or shot can be used to convert alkaline, nitrate-based supernate to ammonia and an aluminum oxide-sodium aluminate-based solid which might function as its own waste form. The process may actually be able to utilize already contaminated aluminum scrap metal from various DOE sites to effect the conversion. The final, nearly nitrate-free ceramic-like product can be pressed and sintered like other ceramics. Based upon the starting volumes of 6.2 and 3.1 M sodium nitrate solution, volume reductions of 50 to 55% were obtained for the waste form produced, compared to an expected 35 to 50% volume increase if the Hanford supernate were grouted. Engineering data extracted from bench-top studies indicate that the process will be very economical to operate, and data were used to cost a batch, 1,200-kg NO{sub 3}/h plant for working off Hanford SST waste over 20 years. Their total process cost analysis presented in the appendix, indicates that between $2.01 to 2.66 per kilogram of nitrate converted will be required. Additionally, data on the fate of select radioelements present in solution are presented in this report as well as kinetic, operational, and control data for a number of experiments. Additionally, if the ceramic product functions as its own waste form, it too will offer other cost savings associated with having a smaller volume of waste form as well as eliminating other process steps such as grouting.

  14. Testing the Specificity of Primers to Environmental Ammonia Monooxygenase (amoA) Genes in Groundwater Treated with Urea to Promote Calcite Precipitation

    SciTech Connect (OSTI)

    Freeman, S.; Reed, D.W.; Fujita, Y.

    2006-01-01T23:59:59.000Z

    Bacterial ammonia monooxygenase (amoA) genes in DNA isolated from microorganisms in groundwater were characterized by amplification of amoA DNA using polymerase chain reaction (PCR), Restriction Fragment Length Polymorphism (RFLP) analysis, and sequencing. The amoA gene is characteristic of ammonia oxidizing bacteria (AOB). The DNA extracts were acquired from an experiment where dilute molasses and urea were sequentially introduced into a well in the Eastern Snake River Plain Aquifer (ESRPA) in Idaho to examine whether such amendments could stimulate enhanced ureolytic activity. The hydrolysis of urea into ammonium and carbonate serves as the basis for a potential remediation technique for trace metals and radionuclide contaminants that can co-precipitate in calcite. The ammonium ion resulting from ureolysis can promote the growth of AOB. The goal of this work was to investigate the effectiveness of primers designed for quantitative PCR of environmental amoA genes and to evaluate the effect of the molasses and urea amendments upon the population diversity of groundwater AOB. PCR primers designed to target a portion of the amoA gene were used to amplify amoA gene sequences in the groundwater DNA extracts. Following PCR, amplified gene products were cloned and the clones were characterized by RFLP, a DNA restriction technique that can distinguish different DNA sequences, to gauge the initial diversity. Clones exhibiting unique RFLP patterns were subjected to DNA sequencing. Initial sequencing results suggest that the primers were successful at specific detection of amoA sequences and the RFLP analyses indicated that the diversity of detected amoA sequences in the ESRPA decreased with the additions of molasses and urea.

  15. Three sandglass-type molybdophosphates obtained via a new route: Synthesis and characterization of X{sub 7}[PMo{sub 8}O{sub 30}] (X=Na{sup +}, K{sup +}, NH{sub 4}{sup +})

    SciTech Connect (OSTI)

    Bai Yanchun; Liu Liping; Yan Xingjuan; Chu Wei; Zhu Yingying; Song Yuting [Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081 (China); Huang Rudan [Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081 (China)], E-mail: huangrudan1@bit.edu.cn

    2009-01-15T23:59:59.000Z

    Three new polyoxometalates X{sub 7}[PMo{sub 8}O{sub 30}] (X=Na{sup +}, 1; K{sup +}, 2; NH{sub 4}{sup +}, 3) have been synthesized with the classical Keggin and/or Dawson heteropolymolybdophosphates and PCl{sub 5} in acetonitrile-water solutions via hydrothermal treatment. The three compounds were characterized by different analyses including IR, {sup 31}P NMR spectroscopy, elemental analysis, electrochemistry, thermogravimetric analysis (TGA) and powder X-ray diffraction (XRD). Single crystal X-ray analyses were carried out on Na{sub 7}[PMo{sub 8}O{sub 30}] (1) and (NH{sub 4}){sub 7}[PMo{sub 8}O{sub 30}] (3). Compound 1 and 3 crystallize in the orthorhombic system. The structure of compound 2 was confirmed by the IR spectra and powder XRD. All the three compounds contain the same octamolybdophosphate polyoxoanion [PMo{sub 8}O{sub 30}]{sup 7-}, which consists of two Mo{sub 4}O{sub 15} moieties linked by one central PO{sub 4} tetrahedron, leading to a remarkable sandglass-like structure. - Graphical Abstract: with the Keggin and/or Dawson heteropolymolybdophosphates and PCl{sub 5} in acetonitrile-water solutions via hydrothermal treatment, three new polyoxometalates X{sub 7}[PMo{sub 8}O{sub 30}] (X=Na{sup +}, 1; K{sup +}, 2; NH{sub 4}{sup +}, 3) have been synthesized and characterized. Single crystal X-ray analyses were carried out on Na{sub 7}[PMo{sub 8}O{sub 30}] (1) and (NH{sub 4}){sub 7}[PMo{sub 8}O{sub 30}] (3). All the three compounds contain the new sandglass-like structure [PMo{sub 8}O{sub 30}]{sup 7-}.

  16. Thng 9, 2011 Xu t b n b i O ce of International A airs M i thng tin trong t ri ny u c trn m ng. c thng tin chi ti t v c p nh t, xin vui lng

    E-Print Network [OSTI]

    Wu, Yih-Min

    Tháng 9, 2011 Xu t b n b i O ce of International A airs M i thông tin trong t ri này u có trên m ng. có thông tin chi ti t và c p nh t, xin vui lòng tra c u t i website c a chúng tôi : httpThông tin nhanh NTU, tr ng i h c t ng h p l n nh t và lâu i nh t ài Loan, ã thông báo các chng trình ào

  17. Supporting Online Material for H. Yu et al. "Effects of Amines on Formation of Sub-3 nm Particles and their Subsequent Growth" Table S1. Concentrations of impurity NH3, methylamine, dimethylamine, and trimethylamine in the nucleation system detected by CI

    E-Print Network [OSTI]

    Lee, Shan-Hu

    as the following: 10 ccm H2O vapor (in OH generator), 3 lpm N2, 100 ccm SO2, 60 ccm O2, 50 ccm amine or NH3, 5 lpm

  18. Process for the treatment of lignocellulosic biomass

    DOE Patents [OSTI]

    Dale, Bruce E.

    2014-07-08T23:59:59.000Z

    A process for the treatment of biomass to render structural carbohydrates more accessible and/or digestible using concentrated ammonium hydroxide with or without anhydrous ammonia addition, is described. The process preferably uses steam to strip ammonia from the biomass for recycling. The process yields of monosaccharides from the structural carbohydrates are good, particularly as measured by the enzymatic hydrolysis of the structural carbohydrates. The monosaccharides are used as animal feeds and energy sources for ethanol production.

  19. Process for the treatment of lignocellulosic biomass

    DOE Patents [OSTI]

    Dale, Bruce E.; Lynd, Lee R.; Laser, Mark

    2013-03-12T23:59:59.000Z

    A process for the treatment of biomass to render structural carbohydrates more accessible and/or digestible using concentrated ammonium hydroxide with or without anhydrous ammonia addition, is described. The process preferably uses steam to strip ammonia from the biomass for recycling. The process yields of monosaccharides from the structural carbohydrates are good, particularly as measured by the enzymatic hydrolysis of the structural carbohydrates. The monosaccharides are used as animal feeds and energy sources for ethanol production.

  20. Protein extraction in the refinement of Coastal Bermudagrass

    E-Print Network [OSTI]

    De La Rosa Perez, Luis Bernardo

    1992-01-01T23:59:59.000Z

    , phosphoric acid, gaseous hydrochloric acid, anhydrous ammonia and ethylendiamine (Chang et aL, 1981; Wylie and Steen, 1988). Also the use of organic solvents such as hexane or cadoxen ([Cd(ethylendiamine)3](OH)2, cadmium ethylendiamine) (Ladisch et al... and lignin. Integrated conversion of the entire "barrel of biomass" (also referred to as biomass refining), is essential to obtain good system economics. This study evaluated the use of the Ammonia Fiber Explosion (AFEX) process in an integrated conversion...

  1. 13286 J. Phys. Chem. 1994,98, 13286-13293 Kinetics of Ti(a3F,a5F)and V(a4F,a6D)Depletion by NH3 and H2S

    E-Print Network [OSTI]

    Clemmer, David E.

    ) and V(a6D) upon interactions with NH3 and HzS are studied in a fast-flow reactor at a He pressure of 0) x Introduction Information about the gas-phase kinetics for the reactions of simple molecules studied the activation of NH3 and H2S by neutral titanium and vanadium atoms. In addition to the gas

  2. The Kinetics and Thermodynamics of CO2 Capture by Aqueous Ammonia Derived Using Meta-GGA Density Functional Theory and Wavefunction-Based Model Chemistry Methods

    SciTech Connect (OSTI)

    Beste, Ariana [ORNL; Attalla, Moetaz [CSIRO ICT Center, Australia; Jackson, Phil [CSIRO ICT Center, Australia

    2012-01-01T23:59:59.000Z

    A meta GGA-DFT study of CO{sub 2} activation in aqueous ammonia solutions, with an emphasis on the reaction barrier and molecularity, has been undertaken using the M06-2X functional with an augmented triple-zeta split-valence basis set (6-311++G(d,p)). Up to five base molecules were treated explicitly in order to establish the effects of solvent catalysis in the chemical capture process. Aqueous free energies of solvation were determined for optimized reactant and transition structures using SM8/M06-2X/6-311++G(d,p). The concept of the solvent pre-complex as presented by Dixon and coworkers (Nguyen, M. T.; Matus, M. H.; Jackson, V. E.; Ngan, V. T.; Rustad, J. R.; Dixon, D. A. J. Phys. Chem. A 2008, 112, 10386-10398) was exploited to account for the energetics of disruption of the hydrogen-bonding solvent nano-network prior to the CO{sub 2} activation step. Selected gas- and aqueous-phase thermodynamic quantities have also been derived.

  3. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15T23:59:59.000Z

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  4. High-electron-mobility GaN grown on free-standing GaN templates by ammonia-based molecular beam epitaxy

    SciTech Connect (OSTI)

    Kyle, Erin C. H., E-mail: erinkyle@umail.ucsb.edu; Kaun, Stephen W.; Burke, Peter G.; Wu, Feng; Speck, James S. [Materials Department, University of California, Santa Barbara, California 93106 (United States); Wu, Yuh-Renn [Institute of Photonics and Optoelectronics, and Department of Electrical Engineering, National Taiwan University, Taipei City 10617, Taiwan (China)

    2014-05-21T23:59:59.000Z

    The dependence of electron mobility on growth conditions and threading dislocation density (TDD) was studied for n{sup ?}-GaN layers grown by ammonia-based molecular beam epitaxy. Electron mobility was found to strongly depend on TDD, growth temperature, and Si-doping concentration. Temperature-dependent Hall data were fit to established transport and charge-balance equations. Dislocation scattering was analyzed over a wide range of TDDs (?2?×?10{sup 6}?cm{sup ?2} to ?2?×?10{sup 10}?cm{sup ?2}) on GaN films grown under similar conditions. A correlation between TDD and fitted acceptor states was observed, corresponding to an acceptor state for almost every c lattice translation along each threading dislocation. Optimized GaN growth on free-standing GaN templates with a low TDD (?2?×?10{sup 6}?cm{sup ?2}) resulted in electron mobilities of 1265 cm{sup 2}/Vs at 296?K and 3327 cm{sup 2}/Vs at 113?K.

  5. DEVELOPMENT OF ALL-SOLID-STATE SENSORS FOR MEASUREMENT OF NITRIC OXIDE AND AMMONIA CONCENTRATIONS BY OPTICAL ABSORPTION IN PARTICLE-LADEN COMBUSTION EXHAUST STREAMS

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2004-09-30T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2 described in this progress report, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. A series of spectral simulations was performed using the HITRAN code to investigate the potential sensitivity of absorption measurements of ammonia in different spectral regions. It was concluded that ammonia absorption features in the 3000-nm spectral region would be hard to measure due to water vapor interferences.

  6. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section V. Integrated Hydrogen and Fuel Cell

    E-Print Network [OSTI]

    (NH3) as a chemical carrier for H2. · Evaluate the viability of autothermal NH3 reformation onSage Program to calculate and optimize the performance parameters for the autothermal reformation of ammonia Thermochemistry to determine the performance parameters for the autothermal reformation of NH3 gas to hydrogen

  7. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    None

    1980-10-01T23:59:59.000Z

    This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in fiscal Year (FY)-1979 and early FY-1980. Volume 3 contains reports from 6 government contractors on LPG, anhydrous ammonia, and hydrogen energy systems. Report subjects include: simultaneous boiling and spreading of liquefied petroleum gas (LPG) on water; LPG safety research; state-of-the-art of release prevention and control technology in the LPG industry; ammonia: an introductory assessment of safety and environmental control information; ammonia as a fuel, and hydrogen safety and environmental control assessment.

  8. Hydrogen storage in a combined M.sub.xAlH.sub.6/M'.sub.y(NH.sub.2).sub.z system and methods of making and using the same

    DOE Patents [OSTI]

    Lu, Jun (Salt Lake City, UT); Fang, Zhigang Zak (Salt Lake City, UT); Sohn, Hong Yong (Salt Lake City, UT)

    2012-04-03T23:59:59.000Z

    As a promising clean fuel for vehicles, hydrogen can be used for propulsion, either directly or in fuel cells. Hydrogen storage compositions having high storage capacity, good dehydrogenation kinetics, and hydrogen release and uptake reactions which are reversible are disclosed and described. Generally a hydrogen storage composition of a metal aluminum hexahydride and a metal amide can be used. A combined system (Li.sub.3AIH.sub.6/3LiNH.sub.2) with a very high inherent hydrogen capacity (7.3 wt %) can be carried out at moderate temperatures, and with approximately 95% of that inherent hydrogen storage capacity (7.0%) is reversible over repeated cycling of release and uptake.

  9. Centrosymmetric [N(CH{sub 3}){sub 4}]{sub 2}TiF{sub 6} vs. noncentrosymmetric polar [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6}: A hydrogen-bonding effect on the out-of-center distortion of TiF{sub 6} octahedra

    SciTech Connect (OSTI)

    Kim, Eun-ah [Department of Chemistry Education, Chung-Ang University, Seoul 156-756 (Korea, Republic of)] [Department of Chemistry Education, Chung-Ang University, Seoul 156-756 (Korea, Republic of); Lee, Dong Woo [Department of Chemistry, Chung-Ang University, Seoul 156-756 (Korea, Republic of)] [Department of Chemistry, Chung-Ang University, Seoul 156-756 (Korea, Republic of); Ok, Kang Min, E-mail: kmok@cau.ac.kr [Department of Chemistry, Chung-Ang University, Seoul 156-756 (Korea, Republic of)

    2012-11-15T23:59:59.000Z

    The syntheses, structures, and characterization of organically templated zero-dimensional titanium fluoride materials, A{sub 2}TiF{sub 6} (A=[N(CH{sub 3}){sub 4}] or [C(NH{sub 2}){sub 3}]), are reported. Phase pure samples of A{sub 2}TiF{sub 6} were synthesized by either solvothermal reaction method or a simple mixing method. While [N(CH{sub 3}){sub 4}]{sub 2}TiF{sub 6} crystallizes in a centrosymmetric space group, R-3, [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6} crystallizes in a noncentrosymmetric polar space group, Cm. The asymmetric out-of-center distortion of TiF{sub 6} octahedra in polar [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6} are attributable to the hydrogen-bonding interactions between the fluorine atoms in TiF{sub 6} octahedra and the nitrogen atoms in the [C(NH{sub 2}){sub 3}]{sup +} cation. Powder second-harmonic generation (SHG) measurements on the [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6}, using 1064 nm radiation, indicate the material has SHG efficiency of 25 Multiplication-Sign that of {alpha}-SiO{sub 2}, which indicates an average nonlinear optical susceptibility, Left-Pointing-Angle-Bracket d{sub eff} Right-Pointing-Angle-Bracket {sub exp} of 2.8 pm/V. Additional SHG measurements reveal that the material is not phase-matchable (Type 1). The magnitudes of out-of-center distortions and dipole moment calculations for TiF{sub 6} octahedra will be also reported. - Graphical abstract: The out-of-center distortion of TiF{sub 6} octahedron in the polar noncentrosymmetric [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6} is attributable to the hydrogen-bonding interactions between the F in TiF{sub 6} octahedron and the H-N in the [C(NH{sub 2}){sub 3}]{sup +}. Highlights: Black-Right-Pointing-Pointer Two titanium fluorides materials have been synthesized in high yields. Black-Right-Pointing-Pointer Hydrogen-bonds are crucial for the out-of-center distortion of TiF{sub 6} octahedra. Black-Right-Pointing-Pointer [C(NH{sub 2}){sub 3}]{sub 2}TiF{sub 6} has a SHG efficiency of 25 Multiplication-Sign that of {alpha}-SiO{sub 2}.

  10. Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2006-12-31T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

  11. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai, E-mail: Kai.Zhu@nrel.gov [Chemical and Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2014-05-26T23:59:59.000Z

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  12. Accurate ab initio-based adiabatic global potential energy surface for the 2{sup 2}A? state of NH{sub 2} by extrapolation to the complete basis set limit

    SciTech Connect (OSTI)

    Li, Y. Q.; Ma, F. C. [Department of Physics, Liaoning University, Shenyang 110036 (China)] [Department of Physics, Liaoning University, Shenyang 110036 (China); Sun, M. T. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2013-10-21T23:59:59.000Z

    A full three-dimensional global potential energy surface is reported first time for the title system, which is important for the photodissociation processes. It is obtained using double many-body expansion theory and an extensive set of accurate ab initio energies extrapolated to the complete basis set limit. Such a work can be recommended for dynamics studies of the N({sup 2}D) + H{sub 2} reaction, a reliable theoretical treatment of the photodissociation dynamics and as building blocks for constructing the double many-body expansion potential energy surface of larger nitrogen/hydrogen containing systems. In turn, a preliminary theoretical study of the reaction N({sup 2}D)+H{sub 2}(X{sup 1}?{sub g}{sup +})(?=0,j=0)?NH(a{sup 1}?)+H({sup 2}S) has been carried out with the method of quasi-classical trajectory on the new potential energy surface. Integral cross sections and thermal rate constants have been calculated, providing perhaps the most reliable estimate of the integral cross sections and the rate constants known thus far for such a reaction.

  13. UNCORRECTED 2 A thermochemical analysis of the production of anhydrous MgCl2

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    With a density of 1:74 g=cm3 magnesium is 4.5 times 15 lighter than steel and 1.6 times lighter than aluminum 16 [1]. The mechanical properties of magnesium castings 17 make them competitive with aluminum castings The expectation of increased utilization of magne- 23 sium in automotive applications has stimulated renewed 24

  14. Low-pressure phase equilibria of anhydrous anorthite-bearing mafic magmas

    E-Print Network [OSTI]

    Kurapov, Alexander

    -spinel; geochemistry; oceanic crust. Index Terms: 3630 Mineralogy and Petrology: Experimental mineralogy and petrology; 3640 Mineralogy and Petrology: Igneous petrology; 3620 Mineralogy and Petrology: Crystal chemistry; 3035 Marine Geology and Geophysics: Midocean ridge processes; 3655 Mineralogy and Petrology: Major

  15. Partition coefficients of substrates and products and solvent selection for biocatalysis under nearly anhydrous conditions

    SciTech Connect (OSTI)

    Yang, Zhen; Robb, D.A. (Univ. of Strathclyde, Glasgow (United Kingdom). Dept. of Bioscience and Biotechnology)

    1994-03-05T23:59:59.000Z

    The effect of solvent on the activity of mushroom tyrosinase toward three substrates was studied at a constant water activity of either 0.74 or 0.86. No simple correlation was observed between enzyme activity and log P, but partition coefficients of substrate (P[sub s]) and product (P[sub p]) gave systematic relations with enzyme activity. When initial reaction rates were considered, there was a bell-shaped relationship between enzyme and P[sub s] with an optimal P[sub s] for each substrate. This can be explained by assuming that the solvent affected the enzyme activity primarily by affecting the substrate concentration in the aqueous layer around the catalyst where the enzymic reaction occurs. When long-term reaction rates were considered, a high P[sub p]/P[sub s] ratio was consistent with preservation of enzyme activity.

  16. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals In The

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1 WindtheEnergy InformationOf TheLtdJalisco,FinancialMantles

  17. Red emission from Eu-doped GaN luminescent films grown by metalorganic chemical vapor deposition

    E-Print Network [OSTI]

    Steckl, Andrew J.

    chemical vapor deposition on GaN/Al2O3 substrates. Trimethylgallium TMGa , ammonia (NH3), and europium 2 europium doping was performed utilizing a europium beta-diketonate, eu- ropium 2,2,4,4-tetramethyl-3

  18. NH Acid Rain Control Act (New Hampshire)

    Broader source: Energy.gov [DOE]

    The Act is implemented under New Hampshire's acid deposition control program established under the Rules to Control Air Pollution in Chapter Env-A 400. The goal of the Act is to reduce emissions...

  19. Improvement of ASME NH for Grade 91

    SciTech Connect (OSTI)

    Bernard Riou

    2007-10-09T23:59:59.000Z

    This report has been prepared in the context of Task 3 of the ASME/DOE Gen IV material project. It has been identified that creep-fatigue evaluation procedures presently available in ASME (1) and RCC-MR (2) have been mainly developed for austenitic stainless steels and may not be suitable for cyclic softening materials such as mod 9 Cr 1 Mo steel (grade 91). The aim of this document is, starting from experimental test results, to perform a review of the procedures and, if necessary, provide recommendations for their improvements.

  20. Determination of the ( Ammonium (NH4

    E-Print Network [OSTI]

    of methods of the RSIL, including routine analytical methods called standard operating procedures (SOPs), along with safety guidelines, maintenance procedures, and other information about the operation

  1. Chitosan (polysaccharide) Cationic polyelectrolyte (NH3

    E-Print Network [OSTI]

    Rubloff, Gary W.

    deposition and biofunctionalization Packaging - Polycarbonate packaging material - Leak free packaging by top and bottom polycarbonate pieces Robust sealing technology Biofunctionalization in microfluidic

  2. NH Clean Power Act (New Hampshire)

    Broader source: Energy.gov [DOE]

    The Act calls for annual reductions of multiple pollutants, including SO2, Nox, CO2, and mercury. The Act calls for an 87% reduction in SO2 emissions and a 70% reduction in Nox emissions from...

  3. Category:Concord, NH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:Power LPInformationCashton Greens Jump Lease.UT"OH"

  4. Pittsburg, NH Natural Gas Exports to Canada

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial Consumers (NumberThousandby thePricePricetheTable 1. U.S.9 2010 2011 2012

  5. THE JOURNAL OF CHEMICAL PHYSICS 134, 214501 (2011) Nanoconfinement effects on the reversibility of hydrogen storage

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    of hydrogen storage in ammonia borane: A first-principles study Kiseok Chang,1 Eunja Kim,2 Philippe F. Weck,3-state materials capable of storing hydrogen, the NH3BH3 compound called ammonia borane (AB), with an ideal storage2 kg-1 ) density targets specified by the U.S. Department of Energy for on-board hydrogen storage.4

  6. The influence of nitrogen rate and source on plant and soil properties

    E-Print Network [OSTI]

    Fisher, Flake Leroy

    1959-01-01T23:59:59.000Z

    . Anhydrous ammonia caused the lea s t a lteration of pH in the su r face , but it caused the greatest acid ity in the subso i l . The lev e ls of nitrates in the so il w ere exp re s sed by quadratic equa? tions with co rre la t ion coe ff ic... , and and are the annual rate of nitrogen in pounds p er a c r e app lied as ammonium nitrate and anhydrous ammonia, r e sp e c t iv e ly . P red ic ted maximum y ields com pared favorab ly with the actual m aximum y ie lds o f 1 9 , 9 9 0 and 15, 850 pounds...

  7. Reactive formulations for a neutralization of toxic industrial chemicals

    DOE Patents [OSTI]

    Tucker, Mark D. (Albuqueruqe, NM); Betty, Rita G. (Rio Rancho, NM)

    2006-10-24T23:59:59.000Z

    Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.

  8. Strain states of AlN/GaN-stress mitigating layer and their effect on GaN buffer layer grown by ammonia molecular beam epitaxy on 100-mm Si(111)

    SciTech Connect (OSTI)

    Ravikiran, L.; Radhakrishnan, K.; Agrawal, M. [NOVITAS-Nanoelectronics Centre of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore)] [NOVITAS-Nanoelectronics Centre of Excellence, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Dharmarasu, N.; Munawar Basha, S. [Temasek Laboratories, Nanyang Technological University, Singapore 637553 (Singapore)] [Temasek Laboratories, Nanyang Technological University, Singapore 637553 (Singapore)

    2013-09-28T23:59:59.000Z

    The effect of strain states of AlN/GaN-stress mitigating layer (SML) on buried crack density and its subsequent influence on the residual stresses in GaN buffer layers grown using ammonia-molecular beam epitaxy on 100-mm Si(111) substrate has been investigated. Different stages involved in the formation of buried cracks, which are crack initialization, growth of relaxed AlN layer, and subsequent lateral over growth, are identified using in-situ curvature measurements. While the increase of GaN thickness in AlN/GaN-SML enhanced its compressive strain relaxation and resulted in reduced buried crack spacing, the variation of AlN thickness did not show any effect on the crack spacing. Moreover, the decrease in the crack spacing (or increase in the buried crack density) was found to reduce the residual compression in 1st and 2nd GaN layers of AlN/GaN-SML structure. The higher buried crack density relaxed the compressive strain in 1st GaN layer, which further reduced its ability to compensate the tensile stress generated during substrate cool down, and hence resulted in lower residual compressive stress in 2nd GaN layer.

  9. Atmos. Chem. Phys., 13, 84578470, 2013 www.atmos-chem-phys.net/13/8457/2013/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    sulfur dioxide (SO2) and ammonia (NH3) emissions. Daytime PM2.5 sam- ples were collected during summer 2010 using conditional sampling approaches based on pre-defined high and low SO2 or NH3 thresholds/EI-MS) and ultra perfor- mance liquid chromatography coupled to electrospray ion- ization high

  10. Fuel NOx pollution production during the combustion of a low caloric value fuel gas

    E-Print Network [OSTI]

    Caraway, John Phillip

    1995-01-01T23:59:59.000Z

    of NOx is modeled by the kinetic and turbulent mixed destruction of ammonia (NH3). The destruction of NH3 is described using equations developed in prior experiments. The influences of the method of distribution of the inlet flow on the temperature...

  11. Research Unit on Biosphere -Aerosol -Cloud -Climate Interactions

    E-Print Network [OSTI]

    both reduced and oxidised forms of nitrogen where co-emitted pollutants (such as ammonia (NH3 The purpose of this study is to quantify N gas concentrations in the city of Copenhagen and at a downwind site the city (i.e. the relative importance of deposition and gas-particle partitioning). Measurements of NH3

  12. rsta.royalsocietypublishing.org Cite this article: Zeebe RE and Zachos JC.

    E-Print Network [OSTI]

    Zeebe, Richard E.

    fossil fuel 2013 The Author(s) Published by the Royal Society. All rights reserved. on September 16, 2013 of CO2 in the Earth's atmosphere by approximately 40%. The combined fossil fuel and cement emissions on metal speciation, reduced NH3/NH4 + ratios (probably affecting ammonia oxidation rates), the marine

  13. 2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene

    E-Print Network [OSTI]

    Ellison, Barney

    2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene Gustavo E. Davico ion with benzene and phenide ion with ammonia: c&6 +NH2- C6H5- +NH3. The ratio of these rate constants for derived. The enthalpy of deprotonationof benzene, the C-H bond dissociationenergy, and the electron

  14. Adv. Space Res. Vol. 7, No. 12, pp. (12)79--(12)85, 1987 0273--1177/87 $0.00 + .50 Printed in Great Britain. All rights reserved. Copyright 1987 COSPAR

    E-Print Network [OSTI]

    Atreya, Sushil

    , H 20, H2S and NH3 would condense at the 2-5, 1.5-2.5 and 0.7-0.4 bar pressure levels respectively of an aqueous-ammonia solution cloud and an H2S-ice cloud are also expected. Despite the recent Voyager flyby to the solar N/H ratio (8.7 x 10-s) is most likely due to the removal of 75 to 95% of NH3 in an aqueous

  15. Crystal structure and magnetic properties of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' containing residual {alpha}-Fe prepared by low-temperature ammonia nitridation

    SciTech Connect (OSTI)

    Yamashita, S.; Masubuchi, Y. [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan)] [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan); Nakazawa, Y.; Okayama, T.; Tsuchiya, M. [Automobile R and D Center, Tochigi, Honda R and D Co. LTD., Shimotakanezawa 4630, Haga, Tochigi 321-3393 (Japan)] [Automobile R and D Center, Tochigi, Honda R and D Co. LTD., Shimotakanezawa 4630, Haga, Tochigi 321-3393 (Japan); Kikkawa, S., E-mail: kikkawa@eng.hokudai.ac.jp [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan)

    2012-10-15T23:59:59.000Z

    Slight enhancement of saturation magnetization to 219 A m{sup 2} kg{sup -1} was observed from 199 A m{sup 2} kg{sup -1} for the original {alpha}-Fe on the intermediate nitrided mixture of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' with residual {alpha}-Fe among the low temperature ammonia nitridation products under 5 T magnetic field at room temperature. The value changed not linearly against the yield as had been expected. Crystal structure refinement indicated that the phase similar to {alpha} Prime Prime -Fe{sub 16}N{sub 2} had deviations on its lattice constants and positional parameters, compared to previously reported values for {alpha} Prime Prime -Fe{sub 16}N{sub 2}. Spin-polarized total energy calculations were performed using the projector-augmented wave method as implemented in the Vienna ab-initio simulation package (VASP) to calculate magnetic moment on the refined crystal structure of the intermediate '{alpha} Prime Prime -Fe{sub 16}N{sub 2}'. The calculations supported the observed magnetization enhancement in the intermediate nitridation product. - Graphical abstract: Crystal structural parameters slightly change in the intermediate nitrided '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' from those in {alpha} Prime Prime -Fe{sub 16}N{sub 2} to show the magnetization maxima in the mixture of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' and the residual {alpha}-F. Highlights: Black-Right-Pointing-Pointer Larger magnetization was observed than the value of Fe{sub 16}N{sub 2} on its intermediate nitrided mixture with residual {alpha}-Fe. Black-Right-Pointing-Pointer The enhancement was related to the crystal structural deviation from Fe{sub 16}N{sub 2} on the intermediate nitride. Black-Right-Pointing-Pointer It was supported by spin-polarized total energy calculation using the deviated structure.

  16. Bulk gold catalyzed oxidation reactions of amines and isocyanides and iron porphyrin catalyzed N-H and O-H bond insertion/cyclization reactions of diamines and aminoalcohols

    SciTech Connect (OSTI)

    Klobukowski, Erik

    2011-12-29T23:59:59.000Z

    This work involves two projects. The first project entails the study of bulk gold as a catalyst in oxidation reactions of isocyanides and amines. The main goal of this project was to study the activation and reactions of molecules at metal surfaces in order to assess how organometallic principles for homogeneous processes apply to heterogeneous catalysis. Since previous work had used oxygen as an oxidant in bulk gold catalyzed reactions, the generality of gold catalysis with other oxidants was examined. Amine N-oxides were chosen for study, due to their properties and use in the oxidation of carbonyl ligands in organometallic complexes. When amine N-oxides were used as an oxidant in the reaction of isocyanides with amines, the system was able to produce ureas from a variety of isocyanides, amines, and amine N-oxides. In addition, the rate was found to generally increase as the amine N-oxide concentration increased, and decrease with increased concentrations of the amine. Mechanistic studies revealed that the reaction likely involves transfer of an oxygen atom from the amine N-oxide to the adsorbed isocyanide to generate an isocyanate intermediate. Subsequent nucleophilic attack by the amine yields the urea. This is in contrast to the bulk gold-catalyzed reaction mechanism of isocyanides with amines and oxygen. Formation of urea in this case was proposed to proceed through a diaminocarbene intermediate. Moreover, formation of the proposed isocyanate intermediate is consistent with the reactions of metal carbonyl ligands, which are isoelectronic to isocyanides. Nucleophilic attack at coordinated CO by amine N-oxides produces CO{sub 2} and is analogous to the production of an isocyanate in this gold system. When the bulk gold-catalyzed oxidative dehydrogenation of amines was examined with amine N-oxides, the same products were afforded as when O{sub 2} was used as the oxidant. When the two types of oxidants were directly compared using the same reaction system and conditions, it was found that the oxidative dehydrogenation of dibenzylamine to Nbenzylidenebenzylamine, with N-methylmorpholine N-oxide (NMMO), was nearly quantitative (96%) within 24 h. However, the reaction with oxygen was much slower, with only a 52% yield of imine product over the same time period. Moreover, the rate of reaction was found to be influenced by the nature of the amine N-oxide. For example, the use of the weakly basic pyridine N-oxide (PyNO) led to an imine yield of only 6% after 24 h. A comparison of amine N-oxide and O2 was also examined in the oxidation of PhCH{sub 2}OH to PhCHO catalyzed by bulk gold. In this reaction, a 52% yield of the aldehyde was achieved when NMMO was used, while only a 7% product yield was afforded when O{sub 2} was the oxidant after 48 h. The bulk gold-catalyzed oxidative dehydrogenation of cyclic amines generates amidines, which upon treatment with Aerosil and water were found to undergo hydrolysis to produce lactams. Moreover, 5-, 6-, and 7-membered lactams could be prepared through a one-pot reaction of cyclic amines by treatment with oxygen, water, bulk gold, and Aerosil. This method is much more atom economical than industrial processes, does not require corrosive acids, and does not generate undesired byproducts. Additionally, the gold and Aerosil catalysts can be readily separated from the reaction mixture. The second project involved studying iron(III) tetraphenylporphyrin chloride, Fe(TPP)Cl, as a homogeneous catalyst for the generation of carbenes from diazo reagents and their reaction with heteroatom compounds. Fe(TPP)Cl, efficiently catalyzed the insertion of carbenes derived from methyl 2-phenyldiazoacetates into O-H bonds of aliphatic and aromatic alcohols. Fe(TPP)Cl was also found to be an effective catalyst for tandem N-H and O-H insertion/cyclization reactions when 1,2-diamines and 1,2-alcoholamines were treated with diazo reagents. This approach provides a one-pot process for synthesizing piperazinones and morpholinones and related analogues such as quinoxalinones and benzoxazin-2-ones.

  17. Ammonia-Soluable Inorganic Soil Colloids.

    E-Print Network [OSTI]

    Fraps, G. S.

    1914-01-01T23:59:59.000Z

    ....................................................................................................... Term expires 1915 GOVERNING BOARD, STATE SUBSTATIONS tW iL L H. U 2 Y 1 I N President, Brownwood....................................................................... Term expires 1915 P. L. X M 9 E I N Vice-President, Temple... Inspector K t . t H M C 1 - I N Deputy Feed Inspector P t . t P M M s N Deputy Feed Inspector y t . t P M 5 S 1 - I N Deputy Feed Inspector H t , t L 7 5 BE C 1 - N Deputy Feed Inspector SUBSTATION NO. 1: Beeville, Bee County L t L t , BE W M...

  18. -Ammonia Borane (3) -Polyether ammnonia borane (AB)

    E-Print Network [OSTI]

    Hong, Deog Ki

    ( 7) [3]. 7. AB . [1] Kim, Y.; Kim, Y.; Yeo, S.; Kim, K.; Koh, K. J.-E.; Seo, J.-E.; Shin, S. J.; Choi, D.-K.; Yoon, C. W.; Nam, S. W. J. Power Sources 2013, 229, 170. [2] Seo, J.-E et al. J. Power

  19. Hydrogen Storage in Ammonia and Aminoborane Complexes

    E-Print Network [OSTI]

    -board reformation to liberate hydrogen ­ autothermal reformation is one approach #12;Chemical Hydrides (CHs

  20. Diethylamine and ammonia pretreatment of lignocellulose 

    E-Print Network [OSTI]

    Holthus, Robert Earl

    1993-01-01T23:59:59.000Z

    This thesis describes a process for pretreating bagasse with diethylamine to enhance lignocellulose reactivity. The bagasse was soaked in diethylamine for 1, 3, 6, 12 and 24 hour time intervals, and the pressure was released slowly. The treated...

  1. Anhydrous ferric chloride as an alkylation catalyst: The condensation of 2-methylpropene and benzene, preparation and identification of several fractions.

    E-Print Network [OSTI]

    Mommessin, Pierre Robert

    1950-01-01T23:59:59.000Z

    Lg T: I snoop /~qua ep ? polio mn'[IunIp snoop. &qua 'op:zonI. xzg uo'oq 'oppxc+uad snzoqdsoqd 'pgoa o-?zngIos 'ap-=onIg ue3ozpZq sa qons 'sos. . Ie'=- plo'-' 1 c acTTa e Jd aqua uQ suoqgT oogppq ot )gmo Te qf~ $ese J IIT+ sane&Ia g&qq. emI~ amos... -uesezo. Qq~ , T eosazuao, qq. . ~ aueguq Pua . ue~::nod ~o uotgus -ueP too ev", PetPuq s Pixatsvnoty, Puu 'B?og 'Butuatip Q' "g J. elQ J euagnq-u erg qgtsp. Qe. ~-. aqqa eZV. SgtuSa Zattmtg Ouasueo. -tfiouo--. , see-tap pu- euez, :aqtfi. ?nq...

  2. Figure 1: Functionalization of TiO2 by anhydrous chemical vapor deposition of trifunctional siloxane adsorbates.

    E-Print Network [OSTI]

    siloxanes form only 2 covalent bonds, in a `bridge' mode with adjacent Ti4+ ions on the TiO2 surface of binding enthalpies at the DFT B3LYP/(LACVP/6-31G**) level of theory indicating that the `bridge' binding optical, electrical, magnetic and mechanical properties of semiconductor materials. For example, dye

  3. A novel, easily synthesized, anhydrous derivative of phosphoric acid for use with electrolyte in phosphoric acid-based fuel cells.

    E-Print Network [OSTI]

    Angell, C. Austen

    ] such as polybenzimidazole, into a very promising and cost-competitive alternative[4] to the Nafion fuel cell[5, 6 in phosphoric acid-based fuel cells. Younes Ansari, Telpriore Tucker, and C. Austen Angell* Dept. of Chemistry as a fuel cell electrolyte, by designing a variant of the molecular acid that has increased temperature

  4. A study of the condensation of propene and isobutene with benzene in the presence of anhydrous ferric chloride

    E-Print Network [OSTI]

    Carpenter, Louis Linden

    1938-01-01T23:59:59.000Z

    . Distillsdioa of Csadeasaiioa Products osiag Porrio Chlosido aa4 JGaajaaa Chlox'ido ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ IC II. Kssillatioa of Polyaorkxaaioa Pzodue1s asiad Povris Chio&do sad Aloaiaaa Chlos ido ~ e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ e l... (lygs) ~ due te the higher parity ef the slhoao whish was eeadeaood with tho areastio hfdrsearboa. lsobatsae pr?yare4 bf the dehydratiea ef tertiarf batrl sloohel is reported te have a parity greater thea 99 yer coat Qsiag oqaiaelsr ssswats...

  5. A COMBINED EXPERIMENTAL AND THEORETICAL STUDY OF THE REACTION OF DICARBON (C2) WITH D1-ACETYLENE (HCCD): POSSIBLE MECHANISMS FOR DEUTERIUM ENRICHMENT

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    ), D-ammonia (NH2D; Millar & Brown 1989; Saito et al. 2000; Hatchell 2003), D-methanol (CH2DOH; Parise + . D2-formaldehyde (D2CO; Ceccarelli et al. 2002), D2- methanol (CHD2OH; Parise et al. 2002), D2 deuterated molecules D3-ammonia (ND3; van der Tak et al. 2002) and D3-methanol (CD3OH; Parise et al. 2004

  6. Synthesis and crystal structure of a new open-framework iron phosphate (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}]: Novel linear trimer of corner-sharing Fe(III) octahedra

    SciTech Connect (OSTI)

    Mi, Jin-Xiao, E-mail: jxmi@xmu.edu.c [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Wang, Cheng-Xin [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Chen, Ning [Canadian Light Source, University of Saskatchewan, Saskatoon, SK, Canada S7N 0X4 (Canada); Department of Geological Sciences, University of Saskatchewan, Saskatoon, SK, Canada S7N 5E2 (Canada); Li, Rong [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Department of Geological Sciences, University of Saskatchewan, Saskatoon, SK, Canada S7N 5E2 (Canada); Pan, Yuanming [Department of Geological Sciences, University of Saskatchewan, Saskatoon, SK, Canada S7N 5E2 (Canada)

    2010-12-15T23:59:59.000Z

    A new iron phosphate (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}] has been synthesized hydrothermally at HF concentrations from 0.5 to 1.2 mL. Single-crystal X-ray diffraction analysis reveals its three-dimensional open-framework structure (monoclinic, space group P2{sub 1}/n (No. 14), a=6.2614(13) A, b=9.844(2) A, c=14.271(3) A, {beta}=92.11(1){sup o}, V=879.0(3) A{sup 3}). This structure is built from isolated linear trimers of corner-sharing Fe(III) octahedra, which are linked by (PO{sub 4}) groups to form ten-membered-ring channels along [1 0 0]. This isolated, linear trimer of corner-sharing Fe(III) octahedra, [(FeO{sub 4}){sub 3}(OH){sub 2}F{sub 2}], is new and adds to the diverse linkages of Fe polyhedra as secondary building units in iron phosphates. The trivalent iron at octahedral sites for the title compound has been confirmed by synchrotron Fe K-edge XANES spectra and magnetic measurements. Magnetic measurements also show that this compound exhibit a strong antiferromagnetic exchange below T{sub N}=17 K, consistent with superexchange interactions expected for the linear trimer of ferric octahedra with the Fe-F-Fe angle of 132.5{sup o}. -- Graphical abstract: The three-dimensional open-framework structure of (NH{sub 4}){sub 4}Fe{sub 3}(OH){sub 2}F{sub 2}[H{sub 3}(PO{sub 4}){sub 4}] is built from a novel isolated, linear (FeO{sub 4}){sub 3}(OH){sub 2}F{sub 2} trimer of corner-sharing Fe(III) octahedra linked by PO{sub 4} tetrahedra. Display Omitted

  7. Impacts of anisotropic lattice relaxation on crystal mosaicity and luminescence spectra of m-plane Al{sub x}Ga{sub 1-x}N films grown on m-plane freestanding GaN substrates by NH{sub 3} source molecular beam epitaxy

    SciTech Connect (OSTI)

    Hoshi, T.; Hazu, K.; Ohshita, K.; Kagaya, M.; Onuma, T.; Chichibu, S. F. [CANTech, Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba, Sendai 980-8577 (Japan); Fujito, K. [Optoelectronics Laboratory, Mitsubishi Chemical Corporation, 1000 Higashi-Mamiana, Ushiku 300-1295 (Japan); Namita, H. [Mitsubishi Chemical Group Science and Technology Research Center, Inc., 8-3-1 Chuo, Ami, Inashiki 300-0332 (Japan)

    2009-02-16T23:59:59.000Z

    In-plane anisotropic lattice relaxation was correlated with the crystal mosaicity and luminescence spectra for m-plane Al{sub x}Ga{sub 1-x}N films grown on a freestanding GaN substrate by NH{sub 3}-source molecular beam epitaxy. The homoepitaxial GaN film exhibited A- and B-excitonic emissions at 8 K, which obeyed the polarization selection rules. For Al{sub x}Ga{sub 1-x}N overlayers, the m-plane tilt mosaic along c-axis was the same as the substrate as far as coherent growth was maintained (x{<=}0.25). However, it became more severe than along the a-axis for lattice-relaxed films (x{>=}0.52). The results are explained in terms of anisotropic lattice and thermal mismatches between the film and the substrate. Nonetheless, all the Al{sub x}Ga{sub 1-x}N films exhibited a near-band-edge emission peak and considerably weak deep emission at room temperature.

  8. "the most valuable birds in the world": International Conservation Science and the Revival of Peru's Guano Industry, 1909-1965

    E-Print Network [OSTI]

    Cushman, Gregory T.

    2005-01-01T23:59:59.000Z

    of the most arid, least productive natural environments in the world. This dryness inhibits both the microbiological breakdown of uric acid (C5H4N3O3) and the leaching of water-soluble ammonia (NH3) and ammonium salts (NH4 +) from guano deposits and makes... under his command. Farmers also received propaganda and scientific studies from CAG that promoted scientific agriculture, including a monthly illustrated Boletín (1925– 1967). These publications provided a vital public outlet for scientific research...

  9. Development of a composite repair system for reinforcing offshore risers 

    E-Print Network [OSTI]

    Alexander, Christopher Richard

    2009-05-15T23:59:59.000Z

    of the riser pipe and under extreme conditions failure can result in the form of either leaks or ruptures. Most pipeline design and operating codes, such as ASME B31.4, Liquid Transportation Systems for Hydrocarbons, Liquid Petroleum Gas, Anhydrous Ammonia..., and Alcohols [1] and ASME B31.8, Gas Transmission and Distribution Piping System [2] have procedures for assessing the severity of corrosion. The procedures in these codes are based primarily on ASME B31G, Method for Determining the Remaining Strength...

  10. Production of the ammonium salt of 3,5-dinitro-1,2,4-triazole by solvent extraction

    DOE Patents [OSTI]

    Lee, Kien Y. (Los Alamos, NM); Ott, Donald G. (Los Alamos, NM)

    1980-01-01T23:59:59.000Z

    The ammonium salt of 3,5-dinitro-1,2,4-triazole has utility as a chemical explosive. In accordance with the present invention, it may readily be produced by solvent extraction using high-molecular weight, water-insoluble amines followed by amination with anhydrous ammonia gas. The aqueous reaction mixture produced in the synthesis of the parent compound, 3,5-dinitro-1,2,4-triazole, is quite suitable--and indeed is preferred--for use as the feed material in the process of the invention.

  11. aphanizomenon sp nh-5: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 2004 U.S. Department of Commerce Donald L. Evans 58 Solar Physics & Space Plasma Research Center (SP2RC) Geosciences Websites Summary: Solar Physics & Space Plasma...

  12. ARSENIC IN PRIVATE WELLS IN NH YEAR 1 FINAL REPORT

    E-Print Network [OSTI]

    Bucci, David J.

    performed geospatial analysis of the well water arsenic estimates and survey results and produced the maps............................................................................................... 8 Well water treatment .................................................................................................. 7 Well water quality

  13. Structures and Energetics of Some Potential Intermediates in Titanium Nitride Chemical Vapor Deposition: TiClm(NH2)n, TiClm(NH2)nNH, and TiClm(NH2)nN. An ab Initio

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Structures and Energetics of Some Potential Intermediates in Titanium Nitride Chemical Vapor with these basis sets augmented by multiple sets of polarization and diffuse functions using the B3LYP optimized geometries. Bond dissociation energies, heats of atomization, heats of formation, and entropies have been

  14. PORTSMOUTH HARBOR AND PISCATAQUA RIVER, NH & ME NAVIGATION IMPROVEMENT PROJECT

    E-Print Network [OSTI]

    US Army Corps of Engineers

    on the terminals located above Interstate 95. Cargoes include petroleum fuels, cement, gypsum, and liquid propane. The study evaluated project benefits based on reduction in transportation costs generated from a shift. The Recommended Plan will generate significant economic benefits for the nation, and is the National Economic

  15. Lead Screening for NH Soils: Minimizing Health Risks

    E-Print Network [OSTI]

    New Hampshire, University of

    family. On your soil test report, if the lead screening levels are elevated, you will receive in populated areas include the use of lead paint around homes (pre- 1970s), the use of lead-arsenate for pest does a "lead screening" test that indicates whether or not lead could pose a health risk for your

  16. Public Service Co of NH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook icon TwitterZip JumpProwind GmbHPublic

  17. Pittsburg, NH Natural Gas Pipeline Imports From Canada (Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar AprYear JanPricePrice5,594.9Decade Year-0Thousand

  18. Pittsburg, NH Natural Gas Pipeline Imports From Canada (Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar AprYear JanPricePrice5,594.9Decade

  19. DOE - Office of Legacy Management -- R Brew Co - NH 01

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -

  20. Public Service Co of NH | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethod Jump to:ThisPublic Power & Utility, Inc.Public Service

  1. Pittsburg, NH Natural Gas Imports by Pipeline from Canada

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial Consumers (NumberThousandby thePricePricetheTable 1. U.S.9 2010 2011

  2. System and method for selective catalytic reduction of nitrogen oxides in combustion exhaust gases

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly; Rossin, Joseph A

    2014-04-08T23:59:59.000Z

    A multi-stage selective catalytic reduction (SCR) unit (32) provides efficient reduction of NOx and other pollutants from about 50-550.degree. C. in a power plant (19). Hydrogen (24) and ammonia (29) are variably supplied to the SCR unit depending on temperature. An upstream portion (34) of the SCR unit catalyzes NOx+NH.sub.3 reactions above about 200.degree. C. A downstream portion (36) catalyzes NOx+H.sub.2 reactions below about 260.degree. C., and catalyzes oxidation of NH.sub.3, CO, and VOCs with oxygen in the exhaust above about 200.degree. C., efficiently removing NOx and other pollutants over a range of conditions with low slippage of NH.sub.3. An ammonia synthesis unit (28) may be connected to the SCR unit to provide NH.sub.3 as needed, avoiding transport and storage of ammonia or urea at the site. A carbonaceous gasification plant (18) on site may supply hydrogen and nitrogen to the ammonia synthesis unit, and hydrogen to the SCR unit.

  3. Complete composition tunability of InGaN nanowires using a combinatorial approach

    E-Print Network [OSTI]

    Yang, Peidong

    a horizontal, single-zone tube furnace and two independently controlled heating elements. InCl3, GaCl3 and NH3, particularly for In-rich nitride alloys, which has led to the need for increasingly high ammonia flow rates

  4. Marvell NanoLab Member login Lab Manual Contents MercuryWeb Berkeley Microlab Chapter 5.15

    E-Print Network [OSTI]

    Healy, Kevin Edward

    with nitrogen or un- doped. It can process both 4" and 6" wafers. Materials Policy: The following materials), low temperature oxide (Furnace LTO), metals with melting points above 1500C (i.e titanium, tungsten for Methylsilane (MS), Dichlorosilane (DCS), Ammonia (NH3), Hydrogen (H2) and Nitrogen (N2) (copies in Lobby). 4

  5. Corresponding author: Tel: +33 2 23 23 81 57 ; Fax: +33 2 23 23 81 99 : Email-address: pierre-francois.biard@ensc-rennes.fr (PF BIARD) Overview of mass transfer

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of interest, hydrogen sulfide H2S, methyl mercaptan CH3SH and ammonia NH3, for different scenarii to assess for hydrophobic compounds. This is typically the case for hydrogen sulfide (H2S) [6]. The mass transfer e transfer is widely used in environmental engineering for pollutant removal [1-4]. This unit operation

  6. TEST 3Version 1 EARTH, LIFE, AND TIME

    E-Print Network [OSTI]

    Kah, Linda

    ) representation of relationship based on total number of shared traits (10) _____ ediacara (j) genetic material, except: (a) NH3 (ammonia) (b) CO2 (carbon dioxide) (c) O2 (oxygen) (d) CH4 (methane) PART 2 ­ SHORT be the significance of finding evidence for eukaryotic life if you were trying to decipher the chemical composition

  7. An experimental investigation of the urea-water decomposition and selective catalytic reduction (SCR) of nitric oxides with urea using V2O5-WO3-TiO2 catalyst.

    E-Print Network [OSTI]

    Johar, Jasmeet Singh

    2005-11-01T23:59:59.000Z

    ) stream. The decomposition experiments were conducted with a number of oxygen (O2) compositions (0, 1, 10, and 15%) over the temperature range of 227oC to 477oC. The study showed ammonia (NH3), carbon-dioxide (CO2) and nitric oxide (NO) as the major...

  8. Fresh clouds: A parameterized updraft method for calculating cloud densities in one-dimensional models

    E-Print Network [OSTI]

    Atreya, Sushil

    . Mihalka a a Department of Atmospheric, Oceanic, and Space Science, University of Michigan, Ann Arbor, MI 48109-2143, USA b Astronomy Department, University of California, Berkeley, CA 97420-3411, USA c NASA clouds com- posed of ammonia ice, ammonium hydrosulfide or other com- pounds formed by NH3 and H2S, water

  9. Development of a Fully-Integrated Ultrasensitive Wireless Sensor Utilizing Carbon Nanotubes and Surface Plasmon Theory

    E-Print Network [OSTI]

    Tentzeris, Manos

    of a direct physical contact. CNT mixtures/composites were found to have electrical properties highly sensitive to extremely small quantities of gases, such as ammonia (NH3), carbon dioxide (CO2), nitrogen require a high temperature for operating conditions. Therefore, a gas sensor that can operate at room

  10. A Novel "Green" Fully-integrated Ultrasensitive RFID-enabled Gas Sensor Utilizing Inkjet-printed Antennas and Carbon Nanotubes

    E-Print Network [OSTI]

    Tentzeris, Manos

    -cost paper substrate. Carbon nanotube composites change their electric properties (e.g. resistance. Single-Walled Carbon Nanotube (SWCNT) composites were found to have electrical properties highly sensitive to extremely small quantities of gases, such as ammonia (NH3), carbon dioxide (C02), nitrogen

  11. MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1

    E-Print Network [OSTI]

    Boyer, Edmond

    2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

  12. Below is an example script that could be used while engaging in the Comet Building activity. Created by Elisabeth Mills, Astronomy graduate student, UCLA,

    E-Print Network [OSTI]

    Williams, Gary A.

    planets farther away from the sun than earth? Nope. Mars has ice caps, but even those are mostly dry ice? Water? H2O. Ammonia? NH3. Methane? CH4. At this point, everything is in our mixing bowl but the dry ice's lifecycle: Frozen with no tail, comes in toward sun and melts a bit, forms a progressively larger tail

  13. 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim phys. stat. sol. (b) 242, No. 3, R21R23 (2005) / DOI 10.1002/pssb.200409089

    E-Print Network [OSTI]

    Nabben, Reinhard

    2005-01-01T23:59:59.000Z

    the intensity of the lines originating of the GaN substrate decreases due to the higher absorption of the Zn] and a good resistance to electron [2] and proton [3] irradiation makes it a potential competitor for GaN was introduced by the thermal decomposition of ammonia (NH3 ). The films were depos- ited on GaN

  14. ANOMALOUS NITROGEN ISOTOPIC COMPOSITIONS IN THE STARDUST-RICH ANTARCTIC MICROMETEORITE T98G8: AFFINITIES TO PRIMITIVE CR CHONDRITES AND ANHYDROUS

    E-Print Network [OSTI]

    ANOMALOUS NITROGEN ISOTOPIC COMPOSITIONS IN THE STARDUST-RICH ANTARCTIC MICROMETEORITE T98G8, T98G8, exhibits high abundances of silicate stardust grains and also contains several C report on C and N isotopic distributions in T98G8 and explore the relationship of this micrometeorite

  15. A study of the condensation of primary, secondary, and tertiary butyl alcohols with benzene in the presence of anhydrous ferric chloride

    E-Print Network [OSTI]

    Dodson, Ralph Jordan

    1939-01-01T23:59:59.000Z

    A PKDT Qt THE COND%SATION QE PRECUT, SSQGNDART~ AND T~ NOTCL ALCOHOLS NITH SEEZEEE IN THE ~E GF ANBIINKU8 mRIQ CHLORIDE Asm 1959 4 et Chea1stxy and 0 A STOSX Gf THE OQtGRWSATIOR Of PRXRARX, SWOORBARX ARRI TCBTXARX WTXL ALQOBOLB WITH 8%%ESSE IR... THS F58XWOR Of AWHXQREUS FERRIC CBLORISR A STUART OF TBR CNRRGATTGR OF PIIRSGKo SROOP~e ARD TRRTZART RDTTL ALCOHOLS RITE ~R ZN TKR FRRSRBCR OP ARBTDROUS PRIBKC OHLORTDR A Theete Parttal Palfileaat cf the ReRNLreewate Ter the aeggso cf Rse4e et...

  16. Kinetics Study of Solid Ammonia Borane Hydrogen Release &ndash...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we...

  17. Staging Rankine Cycles Using Ammonia for OTEC Power Production

    SciTech Connect (OSTI)

    Bharathan, D.

    2011-03-01T23:59:59.000Z

    Recent focus on renewable power production has renewed interest in looking into ocean thermal energy conversion (OTEC) systems. Early studies in OTEC applicability indicate that the island of Hawaii offers a potential market for a nominal 40-MWe system. a 40-MWe system represents a large leap in the current state of OTEC technology. Lockheed Martin Inc. is currently pursuing a more realistic goal of developing a 10-MWe system under U.S. Navy funding (Lockheed 2009). It is essential that the potential risks associated with the first-of-its-kind plant should be minimized for the project's success. Every means for reducing costs must also be pursued without increasing risks. With this in mind, the potential for increasing return on the investment is assessed both in terms of effective use of the seawater resource and of reducing equipment costs.

  18. Ammonia fiber explosion (AFEX) pretreatment of municipal solid waste components

    E-Print Network [OSTI]

    Lundeen, Joseph Eric

    1991-01-01T23:59:59.000Z

    as follows: Combine 50 mL pH 4. 6 1. 0 M citrate buffer 500 mL distilled H, O 1. 8939 g Genencor 300P cellulase or Cytolase 300 5. 695 mL NOVOZYM Beta-glucosidase 03 g sodium azide Complete to 1 L with HrO Adjust pH to 4. 8 with 1. 0 M Na... is found in Appendix 8. 2. Novozym 188 cellobiose with an activity of 250 CBU/mL was added giving a loading of 285 CBU/g dry substrate. Both enzymes contain some sugars that must be subtracted from the sugar yields. A complete procedure is given...

  19. Potential of High-Throughput Experimentation with Ammonia Borane...

    Broader source: Energy.gov (indexed) [DOE]

    and theory - Materials Discovery DOE BES Hydrogen Fuel Initiative * Structure and dynamics (Neutron and NMR) - Experimental and computational studies of di- hydrogen bonding...

  20. Energy Savings for CO2 Removal in Ammonia Plants 

    E-Print Network [OSTI]

    Pouilliart, R.; Van Hecke, F. C.

    1981-01-01T23:59:59.000Z

    of approx. 27 GJ/h (GHV) of natural gas is possible by using exhaust steam from a back pressure turbine instead of L.T. shift gas as the heat supply source for a Carsol C02 removal system....