National Library of Energy BETA

Sample records for anhydrous alcohol ethanol

  1. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis ...

  2. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols

    Broader source: Energy.gov [DOE]

    Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II.

  3. Autothermal Partial Oxidation of Ethanol and Alcohols - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Autothermal Partial Oxidation of Ethanol and Alcohols Syngas from Autothermal Reforming of Ethanol DOE Grant Recipients University of Minnesota Contact University of Minnesota About This Technology Technology Marketing Summary Autothermal Reforming of Ethanol and Alcohols into Syngas Ethanol and alcohols can be converted into syngas using a robust autothermal reforming process. Syngas is a mixture of carbon

  4. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synthesis of Lignocellulosic Biomass | Department of Energy Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012. PDF icon Thermochemical Ethanol via

  5. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

    Broader source: Energy.gov [DOE]

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

  6. Alcohol injection cuts diesel consumption on turbocharged tractors

    SciTech Connect (OSTI)

    Edson, D.V.

    1980-07-21

    M and W Gear Co. of Gibson City, IL, are marketing a new alcohol- injection system that permits turbocharged diesel engines to burn alcohol and claims to cut diesel consumption by 30% and more. The alcohol fuel, a blend of alcohol and water, does not meet the diesel fuel until the alcohol has been atomized and sprayed through the intake manifold into the cylinders. It permits farmers to use home- still-produced ethanol without the added expense of refining to anhydrous composition.

  7. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass S. Phillips, A. Aden, J. Jechura, and D. Dayton National Renewable Energy Laboratory T. Eggeman Neoterics International, Inc. Technical Report NREL/TP-510-41168 April 2007 NREL is operated by Midwest Research Institute â—Ź Battelle Contract No. DE-AC36-99-GO10337 Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass S. Phillips, A. Aden, J.

  8. Ethanol metabolism, oxidative stress, and endoplasmic reticulum stress responses in the lungs of hepatic alcohol dehydrogenase deficient deer mice after chronic ethanol feeding

    SciTech Connect (OSTI)

    Kaphalia, Lata; Boroumand, Nahal; Hyunsu, Ju; Kaphalia, Bhupendra S.; Calhoun, William J.

    2014-06-01

    Consumption and over-consumption of alcoholic beverages are well-recognized contributors to a variety of pulmonary disorders, even in the absence of intoxication. The mechanisms by which alcohol (ethanol) may produce disease include oxidative stress and prolonged endoplasmic reticulum (ER) stress. Many aspects of these processes remain incompletely understood due to a lack of a suitable animal model. Chronic alcohol over-consumption reduces hepatic alcohol dehydrogenase (ADH), the principal canonical metabolic pathway of ethanol oxidation. We therefore modeled this situation using hepatic ADH-deficient deer mice fed 3.5% ethanol daily for 3 months. Blood ethanol concentration was 180 mg% in ethanol fed mice, compared to < 1.0% in the controls. Acetaldehyde (oxidative metabolite of ethanol) was minimally, but significantly increased in ethanol-fed vs. pair-fed control mice. Total fatty acid ethyl esters (FAEEs, nonoxidative metabolites of ethanol) were 47.6 ?g/g in the lungs of ethanol-fed mice as compared to 1.5 ?g/g in pair-fed controls. Histological and immunohistological evaluation showed perivascular and peribronchiolar lymphocytic infiltration, and significant oxidative injury, in the lungs of ethanol-fed mice compared to pair-fed controls. Several fold increases for cytochrome P450 2E1, caspase 8 and caspase 3 found in the lungs of ethanol-fed mice as compared to pair-fed controls suggest role of oxidative stress in ethanol-induced lung injury. ER stress and unfolded protein response signaling were also significantly increased in the lungs of ethanol-fed mice. Surprisingly, no significant activation of inositol-requiring enzyme-1? and spliced XBP1 was observed indicating a lack of activation of corrective mechanisms to reinstate ER homeostasis. The data suggest that oxidative stress and prolonged ER stress, coupled with formation and accumulation of cytotoxic FAEEs may contribute to the pathogenesis of alcoholic lung disease. - Highlights: • Chronic ethanol feeding causes oxidative stress, ER stress and inflammation in lungs of ADH– deer mice. • Chronic ethanol feeding generates FAEEs (nonoxidative metabolites of ethanol) in lungs of ADH– deer mice. • Chronic ethanol feeding induces CYP2E1 in the lungs of ADH– deer mice. • Lack of ER homeostasis due to a prolonged ethanol feeding could trigger inflammation.

  9. Molecular control of the induction of alcohol dehydrogenase by ethanol in Drosophila melanogaster larvae

    SciTech Connect (OSTI)

    Kapoun, A.M.; Geer, B.W.; Heinstra, P.W.H. ); Corbin, V. ); McKechnie, S.W. )

    1990-04-01

    The activity of alcohol dehydrogenase, the initial enzyme in the major pathway for ethanol degradation, is induced in Drosophila melanogaster larvae by low concentrations of dietary ethanol. Two lines of evidence indicate that the metabolic products of the ADH pathway for ethanol degradation are not directly involved in the induction of Adh. First, the accumulation of the proximal transcript in Adh{sup n2} larvae was increased when the intracellular level of ethanol was elevated. In addition, the ADH activity, the proximal Adh mRNA, and the intracellular concentration of ethanol were elevated coordinately in wild-type larvae fed hexadeuterated-ethanol, which is metabolized more slowly than normal ethanol.l An examination of P element transformant lines with specific deletions in the 5{prime} regulatory DNA of the Adh gene showed that the DNA sequence between +604 and +634 of the start site of transcription from the distal promoter was essential for this induction. The DNA sequence between {minus}660 and about {minus}5,000 of the distal transcript start site was important for the down-regulation of the induction response.

  10. Feasibility study of fuel grade ethanol plant for Alcohol Fuels of Mississippi, Inc. , Vicksburg, Mississippi

    SciTech Connect (OSTI)

    None

    1981-01-01

    The results are presented of a feasibility study performed to determine the technical and economic viability of constructing an alcohol plant utilizing the N.Y.U. continuous acid hydrolysis process to convert wood wastes to fuel grade alcohol. The following is a summary of the results: (1) The proposed site in the Vicksburg Industrial Foundation Corporation Industrial Park is adequate from all standpoints, for all plant capacities envisioned. (2) Local hardwood sawmills can provide adequate feedstock for the facility. The price per dry ton varies between $5 and $15. (3) Sale of fuel ethanol would be made primarily through local distributors and an adequate market exists for the plant output. (4) With minor modifications to the preparation facilities, other waste cellulose materials can also be utilized. (5) There are no anticipated major environmental, health, safety or socioeconomic risks related to the construction and operation of the proposed facility. (6) The discounted cash flow and rate of return analysis indicated that the smallest capacity unit which should be built is the 16 million gallon per year plant, utilizing cogeneration. This facility has a 3.24 year payback. (7) The 25 million gallon per year plant utilizing cogeneration is an extremely attractive venture, with a zero interest break-even point of 1.87 years, and with a discounted rate of return of 73.6%. (8) While the smaller plant capacities are unattractive from a budgetary viewpoint, a prudent policy would dictate that a one million gallon per year plant be built first, as a demonstration facility. This volume contains process flowsheets and maps of the proposed site.

  11. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W. (Marietta, GA)

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  12. Thermochemical ethanol via indirect gasification and mixed alcohol synthesis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012.

  13. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012.

  14. Thermochemical Design Report: Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot-unit level by 2012.

  15. Thermochemical Ethanol via Direct Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Dutta, A.; Phillips, S. D.

    2009-07-01

    This report evaluates process design and technoeconomic criteria for a direct gasification process for conversion of biomass to ethanol. Follow-up to NREL/TP-510-41168.

  16. Prenatal ethanol exposure programs an increased susceptibility of non-alcoholic fatty liver disease in female adult offspring rats

    SciTech Connect (OSTI)

    Shen, Lang; Liu, Zhongfen; Gong, Jun; Zhang, Li; Wang, Linlong; Magdalou, Jacques; Chen, Liaobin; Wang, Hui

    2014-01-15

    Prenatal ethanol exposure (PEE) induces dyslipidemia and hyperglycemia in fetus and adult offspring. However, whether PEE increases the susceptibility to non-alcoholic fatty liver disease (NAFLD) in offspring and its underlying mechanism remain unknown. This study aimed to demonstrate an increased susceptibility to high-fat diet (HFD)-induced NAFLD and its intrauterine programming mechanisms in female rat offspring with PEE. Rat model of intrauterine growth retardation (IUGR) was established by PEE, the female fetus and adult offspring that fed normal diet (ND) or HFD were sacrificed. The results showed that, in PEE + ND group, serum corticosterone (CORT) slightly decreased and insulin-like growth factor-1 (IGF-1) and glucose increased with partial catch-up growth; In PEE + HFD group, serum CORT decreased, while serum IGF-1, glucose and triglyceride (TG) increased, with notable catch-up growth, higher metabolic status and NAFLD formation. Enhanced liver expression of the IGF-1 pathway, gluconeogenesis, and lipid synthesis as well as reduced expression of lipid output were accompanied in PEE + HFD group. In PEE fetus, serum CORT increased while IGF-1 decreased, with low body weight, hyperglycemia, and hepatocyte ultrastructural changes. Hepatic IGF-1 expression as well as lipid output was down-regulated, while lipid synthesis significantly increased. Based on these findings, we propose a “two-programming” hypothesis for an increased susceptibility to HFD-induced NAFLD in female offspring of PEE. That is, the intrauterine programming of liver glucose and lipid metabolic function is “the first programming”, and postnatal adaptive catch-up growth triggered by intrauterine programming of GC-IGF1 axis acts as “the second programming”. - Highlights: • Prenatal ethanol exposure increase the susceptibility of NAFLD in female offspring. • Prenatal ethanol exposure reprograms fetal liver’s glucose and lipid metabolism . • Prenatal ethanol exposure cause the adaptive change of glucocorticoid-IGF1 axis.

  17. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  18. Ethanol-induced impairment of polyamine homeostasis – A potential cause of neural tube defect and intrauterine growth restriction in fetal alcohol syndrome

    SciTech Connect (OSTI)

    Haghighi Poodeh, Saeid; Alhonen, Leena; Salonurmi, Tuire; Savolainen, Markku J.

    2014-03-28

    Highlights: • Polyamine pools in embryonic and extraembryonic tissues are developmentally regulated. • Alcohol administration perturbs polyamine levels in the tissues with various patterns. • Total absence of polyamines in the embryo head at 9.5 dpc is critical for development. • The deficiency is associated with reduction in endothelial cell sprouting in the head. • Retarded migration of neural crest cells may cause development of neural tube defect. - Abstract: Introduction: Polyamines play a fundamental role during embryogenesis by regulating cell growth and proliferation and by interacting with RNA, DNA and protein. The polyamine pools are regulated by metabolism and uptake from exogenous sources. The use of certain inhibitors of polyamine synthesis causes similar defects to those seen in alcohol exposure e.g. retarded embryo growth and endothelial cell sprouting. Methods: CD-1 mice received two intraperitoneal injections of 3 g/kg ethanol at 4 h intervals 8.75 days post coitum (dpc). The fetal head, trunk, yolk sac and placenta were collected at 9.5 and 12.5 dpc and polyamine concentrations were determined. Results: No measurable quantity of polyamines could be detected in the embryo head at 9.5 dpc, 12 h after ethanol exposure. Putrescine was not detectable in the trunk of the embryo at that time, whereas polyamines in yolk sac and placenta were at control level. Polyamine deficiency was associated with slow cell growth, reduction in endothelial cell sprouting, an altered pattern of blood vessel network formation and consequently retarded migration of neural crest cells and growth restriction. Discussion: Our results indicate that the polyamine pools in embryonic and extraembryonic tissues are developmentally regulated. Alcohol administration, at the critical stage, perturbs polyamine levels with various patterns, depending on the tissue and its developmental stage. The total absence of polyamines in the embryo head at 9.5 dpc may explain why this stage is so vulnerable to the development of neural tube defect, and growth restriction, the findings previously observed in fetal alcohol syndrome.

  19. Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol: Thermochemical Pathway by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Dutta, A.; Talmadge, M.; Hensley, J.; Worley, M.; Dudgeon, D.; Barton, D.; Groendijk, P.; Ferrari, D.; Stears, B.; Searcy, E. M.; Wright, C. T.; Hess, J. R.

    2011-05-01

    This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing. The design features a processing capacity of 2,205 U.S. tons (2,000 metric tonnes) of dry biomass per day and an ethanol yield of 83.8 gallons per dry U.S. ton of feedstock. The ethanol selling price corresponding to this design is $2.05 per gallon in 2007 dollars, assuming a 30-year plant life and 40% equity financing with a 10% internal rate of return and the remaining 60% debt financed at 8% interest. This ethanol selling price corresponds to a gasoline equivalent price of $3.11 per gallon based on the relative volumetric energy contents of ethanol and gasoline.

  20. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Environmental Management (EM)

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol...

  1. Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Synthesis Reactor for Direct Production of Supercritical Steam | Department of Energy Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam Project Profile: Thermochemical Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam UCLA Logo The University of California, Los Angeles (UCLA), through the Concentrating Solar Power: Efficiently Leveraging

  2. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  3. A Review Of Water Contents Of Nominally Anhydrous Natural Minerals...

    Open Energy Info (EERE)

    Of Water Contents Of Nominally Anhydrous Natural Minerals In The Mantles Of Earth, Mars And The Moon Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  4. ESE Alcohol | Open Energy Information

    Open Energy Info (EERE)

    ESE Alcohol Jump to: navigation, search Name: ESE Alcohol Place: Leoti, Kansas Zip: 67861 Product: Owner of a 6.6m litre per year ethanol plant Coordinates: 38.481425,...

  5. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  6. Method and apparatus for synthesizing anhydrous HNO.sub.3

    DOE Patents [OSTI]

    Coon, Clifford L. (Fremont, CA); Harrar, Jackson E. (Castro Valley, CA); Pearson, Richard K. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

    1984-01-01

    A method and apparatus for electrochemically synthesizing anhydrous HNO.sub.3 from an aqueous solution of HNO.sub.3 includes oxidizing a solution of N.sub.2 O.sub.4 /aqueous HNO.sub.3 at an anode, while maintaining a controlled potential between the N.sub.2 O.sub.4 /aqueous HNO.sub.3 solution and the anode. A potential of about 1.80V vs. SCE is preferred. Anhydrous or aqueous HNO.sub.3 may be disposed at the cathode within the electrochemical cell. Aqueous HNO.sub.3 having a water content of up to about 12% by weight is utilized to synthesize anhydrous HNO.sub.3.

  7. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1980-05-21

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by-product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  8. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1981-09-24

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium, ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  9. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

    1983-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  10. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

    1981-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  11. Compact anhydrous HCl to aqueous HCl conversion system

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (S. Hamilton, MA)

    1993-01-01

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a .sup.196 Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  12. Compact anhydrous HCl to aqueous HCl conversion system

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.

    1993-06-01

    The present invention is directed to an inexpensive and compact apparatus adapted for use with a [sup 196]Hg isotope separation process and the conversion of anhydrous HCl to aqueous HCl without the use of air flow to carry the HCl vapor into the converter system.

  13. Method of synthesis of anhydrous thorium(IV) complexes

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Cantat, Thibault

    2013-04-30

    Method of producing anhydrous thorium(IV) tetrahalide complexes, utilizing Th(NO.sub.3).sub.4(H.sub.2O).sub.x, where x is at least 4, as a reagent; method of producing thorium-containing complexes utilizing ThCl.sub.4(DME).sub.2 as a precursor; method of producing purified ThCl.sub.4(ligand).sub.x compounds, where x is from 2 to 9; and novel compounds having the structures: ##STR00001##

  14. Ethanol Basics

    SciTech Connect (OSTI)

    2015-01-30

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  15. Transesterification of waste vegetable oil under pulse sonication using ethanol, methanol and ethanol–methanol mixtures

    SciTech Connect (OSTI)

    Martinez-Guerra, Edith; Gude, Veera Gnaneswar

    2014-12-15

    Highlights: • Pulse sonication effect on transesterification of waste vegetable oil was studied. • Effects of ethanol, methanol, and alcohol mixtures on FAMEs yield were evaluated. • Effect of ultrasonic intensity, power density, and its output rates were evaluated. • Alcohol mixtures resulted in higher biodiesel yields due to better solubility. - Abstract: This study reports on the effects of direct pulse sonication and the type of alcohol (methanol and ethanol) on the transesterification reaction of waste vegetable oil without any external heating or mechanical mixing. Biodiesel yields and optimum process conditions for the transesterification reaction involving ethanol, methanol, and ethanol–methanol mixtures were evaluated. The effects of ultrasonic power densities (by varying sample volumes), power output rates (in W), and ultrasonic intensities (by varying the reactor size) were studied for transesterification reaction with ethanol, methanol and ethanol–methanol (50%-50%) mixtures. The optimum process conditions for ethanol or methanol based transesterification reaction of waste vegetable oil were determined as: 9:1 alcohol to oil ratio, 1% wt. catalyst amount, 1–2 min reaction time at a power output rate between 75 and 150 W. It was shown that the transesterification reactions using ethanol–methanol mixtures resulted in biodiesel yields as high as >99% at lower power density and ultrasound intensity when compared to ethanol or methanol based transesterification reactions.

  16. Ethanol production in recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal; Barbosa-Alleyne, Maria D.

    2005-02-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  17. Nucleic acid molecules conferring enhanced ethanol tolerance and microorganisms having enhanced tolerance to ethanol

    DOE Patents [OSTI]

    Brown, Steven; Guss, Adam; Yang, Shihui; Karpinets, Tatiana; Lynd, Lee; Shao, Xiongjun

    2014-01-14

    The present invention provides isolated nucleic acid molecules which encode a mutant acetaldehyde-CoA/alcohol dehydrogenase or mutant alcohol dehydrogenase and confer enhanced tolerance to ethanol. The invention also provides related expression vectors, genetically engineered microorganisms having enhanced tolerance to ethanol, as well as methods of making and using such genetically modified microorganisms for production of biofuels based on fermentation of biomass materials.

  18. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Fowler, David E.; Horton, Philip G.; Ben-Bassat, Arie

    1996-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  19. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O.; Beall, David S.; Burchhardt, Gerhard F. H.; Guimaraes, Walter V.; Ohta, Kazuyoshi; Wood, Brent E.; Shanmugam, Keelnatham T.

    1995-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  20. Pacific Ethanol, Inc | Department of Energy

    Energy Savers [EERE]

    Pacific Ethanol, Inc

  1. Ethanol Basics (Fact Sheet), Clean Cities, Energy Efficiency & Renewable Energy (EERE)

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Basics Ethanol is a widely used, domesti- cally produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Fuel ethanol contains the same chemical compound as beverage alcohol, but it is denatured with a small amount of gasoline or other chemicals during the production process, making it unsafe for human consumption. Ethanol's primary market drivers are the Federal Renewable Fuel Standard requiring its use and

  2. Running Line-Haul Trucks on Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    I magine driving a 55,000-pound tractor- trailer that runs on corn! If you find it difficult to imagine, you can ask the truck drivers for Archer Daniels Midland (ADM) what it's like. For the past 4 years, they have been piloting four trucks powered by ethyl alcohol, or "ethanol," derived from corn. Several advantages to operating trucks on ethanol rather than on conventional petro- leum diesel fuel present themselves. Because ethanol can be produced domestically, unlike most of our

  3. Greater Ohio Ethanol LLC GO Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ohio Ethanol LLC GO Ethanol Jump to: navigation, search Name: Greater Ohio Ethanol, LLC (GO Ethanol) Place: Lima, Ohio Zip: OH 45804 Product: GO Ethanol is a pure play ethanol...

  4. Experiences from Introduction of Ethanol Buses and Ethanol Fuel...

    Open Energy Info (EERE)

    of Ethanol Buses and Ethanol Fuel Station Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Introduction of Ethanol Buses and Ethanol Fuel Station Agency...

  5. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1999-06-29

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  6. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1996-01-09

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  7. Ethanol production in gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal (Gainesville, FL); Barbosa-Alleyne, Maria D. F. (Gainesville, FL)

    1999-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  8. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal (Gainesville, FL); Barbosa-Alleyne, Maria D. F. (Gainesville, FL)

    1996-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  9. Method and apparatus for synthesizing anhydrous HNO/sub 3/. [Patent application

    DOE Patents [OSTI]

    Coon, C.L.; Harrar, J.E.; Pearson, R.K.; McGuire, R.R.

    1982-07-20

    A method and apparatus for electrochemically synthesizing anhydrous HNO/sub 3/ from an aqueous solution of HNO/sub 3/- includes oxidizing a solution of N/sub 2/O/sub 4//aqueous HNO/sub 3/ at an anode, while maintaining a controlled potential between the N/sub 2/O/sub 4//aqueous HNO/sub 3/ solution and the anode. A potential of about 1.80V vs. SCE is preferred. Anhydrous or aqueous HNO/sub 3/ may be disposed at the cathode within the electrochemical cell. Aqueous HNO/sub 3/ having a water content of up to about 12% by weight is utilized to synthesize anhydrous HNO/sub 3/.

  10. Alcohol synthesis from CO or CO.sub.2

    DOE Patents [OSTI]

    Hu, Jianli [Kennewick, WA; Dagle, Robert A [Richland, WA; Holladay, Jamelyn D [Kennewick, WA; Cao, Chunshe [Houston, TX; Wang, Yong [Richland, WA; White, James F [Richland, WA; Elliott, Douglas C [Richland, WA; Stevens, Don J [Richland, WA

    2010-12-28

    Methods for producing alcohols from CO or CO.sub.2 and H.sub.2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C.sub.2+ oxygenates can produced utilizing Rh--Mn or a Fisher-Tropsch catalyst.

  11. Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Add description and move this content to a more appropriate page name (like "List of ethanol incentives") List of Ethanol Incentives E85 Standards Retrieved from "http:...

  12. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol This...

  13. Southridge Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Southridge Ethanol Place: Dallas, Texas Zip: 75219 Sector: Renewable Energy Product: Southridge Ethanol is a renewable energy company...

  14. Diversified Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Diversified Ethanol Place: Northbrook, Illinois Zip: 60062 Product: A division of OTCBB-traded ONYI that is building an ethanol plant in...

  15. Ace Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Ace Ethanol Place: Stanley, Wisconsin Zip: 54768 Product: Producer of corn-based ethanol in Wisconsin. Coordinates: 44.958844,...

  16. Dakota Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Dakota Ethanol Place: Wentworth, South Dakota Zip: 57075 Product: Farmer Coop owner of a 189m litres per year ethanol plant Coordinates:...

  17. Cellulosic ethanol | Open Energy Information

    Open Energy Info (EERE)

    Cellulosic ethanol Jump to: navigation, search Cellethanol.jpg Cellulosic ethanol is identical to first generation bio ethanol except that it can be derived from agricultural...

  18. Cold-Start Performance and Emissions Behavior of Alcohol Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Discusses results of cold- and hot-start transient tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol) PDF icon deer11ickes.pdf More ...

  19. Byone Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Byone Ethanol Jump to: navigation, search Name: Byone Ethanol Place: Brazil Product: Ethanol Producer References: Byone Ethanol1 This article is a stub. You can help OpenEI by...

  20. Highwater Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Highwater Ethanol Jump to: navigation, search Name: Highwater Ethanol Place: Lamberton, Minnesota Zip: MN 56152 Product: Highwater Ethanol LLC is the SPV behind the 195mLpa ethanol...

  1. More Efficient Ethanol Production from Mixed Sugars Using Spathaspora Yeast

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal More Efficient Ethanol Production from Mixed Sugars Using Spathaspora Yeast Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing SummaryEthanol obtained from the fermentation of grains and sugars is being blended with gasoline to bolster dwindling petroleum supplies. The alcohol increases combustion efficiency and octane value, and can be fermented from renewable corn cobs, stalks, cane and grasses. Still, it is essential

  2. Alternative Fuels Data Center: Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol to someone by E-mail Share Alternative Fuels Data Center: Ethanol on Facebook Tweet about Alternative Fuels Data Center: Ethanol on Twitter Bookmark Alternative Fuels Data Center: Ethanol on Google Bookmark Alternative Fuels Data Center: Ethanol on Delicious Rank Alternative Fuels Data Center: Ethanol on Digg Find More places to share Alternative Fuels Data Center: Ethanol on AddThis.com... More

  3. Ethanol Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2015-01-01

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  4. Pacific Ethanol, Inc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pacific Ethanol, Inc Pacific Ethanol, Inc Design and build a demonstration cellulosic ethanol plant in Boardman. PDF icon pacificethanol_fact_sheet_040308.pdf More Documents & Publications Pacific Ethanol, Inc Pacific Ethanol, Inc Pacific Ethanol, Inc

  5. Conversion of Methanol, Ethanol and Propanol over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-04

    Renewable fuel from lignocellulosic biomass has recently attracted more attention due to its environmental and the potential economic benefits over the crude oil [1]. In particular the production of fuel range hydrocarbon (HC) from alcohol generated lots of interest since the alcohol can be produced from biomass via thermochemical [2] (mixed alcohol from gasification derived synthesis gas) as well as the biochemical routes [3] (alcohol fermentation). Along with the development of ZSM5 synthesis and the discovery of methanol-to-gasoline (MTG) process by Mobil in 1970’s triggered lots of interest in research and development arena to understand the reaction mechanisms of alcohols over zeolites in particular ZSM5 [4]. More detailed research on methanol conversion was extensively reported [5] and in recent times the research work can be found on ethanol [6] and other alcohols as well but comprehensive comparison of catalyst activity and the deactivation mechanism of the conversion of various alcohols over zeolites has not been reported. The experiments were conducted on smaller alcohols such as methanol, ethanol and 1-propanol over HZSM5. The experimental results on the catalyst activity and the catalyst deactivation mechanism will be discussed.

  6. Sioux River Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    River Ethanol LLC Jump to: navigation, search Name: Sioux River Ethanol LLC Place: Hudson, South Dakota Zip: 57034 Product: Farmer owned ethanol producer, Sioux River Ethanol is...

  7. Cardinal Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Cardinal Ethanol LLC Place: Winchester, Indiana Zip: 47394 Product: Cardinal Ethanol is in the process of building an ethanol plant in...

  8. Phelps County Ethanol | Open Energy Information

    Open Energy Info (EERE)

    County Ethanol Jump to: navigation, search Name: Phelps County Ethanol Place: Nebraska Product: Focused on ethanol production. References: Phelps County Ethanol1 This article is...

  9. Alcohol fuels program technical review

    SciTech Connect (OSTI)

    1981-07-01

    The last issue of the Alcohol Fuels Process R/D Newsletter contained a work breakdown structure (WBS) of the SERI Alcohol Fuels Program that stressed the subcontracted portion of the program and discussed the SERI biotechnology in-house program. This issue shows the WBS for the in-house programs and contains highlights for the remaining in-house tasks, that is, methanol production research, alcohol utilization research, and membrane research. The methanol production research activity consists of two elements: development of a pressurized oxygen gasifier and synthesis of catalytic materials to more efficiently convert synthesis gas to methanol and higher alcohols. A report is included (Finegold et al. 1981) that details the experimental apparatus and recent results obtained from the gasifier. The catalysis research is principally directed toward producing novel organometallic compounds for use as a homogeneous catalyst. The utilization research is directed toward the development of novel engine systems that use pure alcohol for fuel. Reforming methanol and ethanol catalytically to produce H/sub 2/ and CO gas for use as a fuel offers performance and efficiency advantages over burning alcohol directly as fuel in an engine. An application of this approach is also detailed at the end of this section. Another area of utilization is the use of fuel cells in transportation. In-house researchers investigating alternate electrolyte systems are exploring the direct and indirect use of alcohols in fuel cells. A workshop is being organized to explore potential applications of fuel cells in the transportation sector. The membrane research group is equipping to evaluate alcohol/water separation membranes and is also establishing cost estimation and energy utilization figures for use in alcohol plant design.

  10. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  11. Fermentation method producing ethanol

    DOE Patents [OSTI]

    Wang, Daniel I. C. (Belmont, MA); Dalal, Rajen (Chicago, IL)

    1986-01-01

    Ethanol is the major end product of an anaerobic, thermophilic fermentation process using a mutant strain of bacterium Clostridium thermosaccharolyticum. This organism is capable of converting hexose and pentose carbohydrates to ethanol, acetic and lactic acids. Mutants of Clostridium thermosaccharolyticum are capable of converting these substrates to ethanol in exceptionally high yield and with increased productivity. Both the mutant organism and the technique for its isolation are provided.

  12. Pacific Ethanol, Inc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pacific Ethanol, Inc. Corporate HQ: Sacramento, CA Proposed Facility Location: Boardman, OR Description: The team will design and build a demonstration cellulosic ethanol plant in Boardman, Oregon, expanding the production of ethanol beyond the Midwest U.S. CEO or Equivalent: Neil Koehler, CEO Participants: BioGasol, LLC; and U.S. Department of Energy's (DOE) Joint Bioenergy Institute (DOE's Lawrence Berkeley National Laboratory and Sandia National Laboratories) Production: * Capacity of 2.7

  13. BlueFire Ethanol

    Broader source: Energy.gov [DOE]

    Construct and operate a facility that converts green waste and lignocellulosic fractions diverted from landfills or Southern California Materials Recovery Facilities to ethanol and other products.

  14. Liver proteomics in progressive alcoholic steatosis

    SciTech Connect (OSTI)

    Fernando, Harshica; Wiktorowicz, John E.; Soman, Kizhake V.; Kaphalia, Bhupendra S.; Khan, M. Firoze; Shakeel Ansari, G.A.

    2013-02-01

    Fatty liver is an early stage of alcoholic and nonalcoholic liver disease (ALD and NALD) that progresses to steatohepatitis and other irreversible conditions. In this study, we identified proteins that were differentially expressed in the livers of rats fed 5% ethanol in a Lieber–DeCarli diet daily for 1 and 3 months by discovery proteomics (two-dimensional gel electrophoresis and mass spectrometry) and non-parametric modeling (Multivariate Adaptive Regression Splines). Hepatic fatty infiltration was significantly higher in ethanol-fed animals as compared to controls, and more pronounced at 3 months of ethanol feeding. Discovery proteomics identified changes in the expression of proteins involved in alcohol, lipid, and amino acid metabolism after ethanol feeding. At 1 and 3 months, 12 and 15 different proteins were differentially expressed. Of the identified proteins, down regulation of alcohol dehydrogenase (? 1.6) at 1 month and up regulation of aldehyde dehydrogenase (2.1) at 3 months could be a protective/adaptive mechanism against ethanol toxicity. In addition, betaine-homocysteine S-methyltransferase 2 a protein responsible for methionine metabolism and previously implicated in fatty liver development was significantly up regulated (1.4) at ethanol-induced fatty liver stage (1 month) while peroxiredoxin-1 was down regulated (? 1.5) at late fatty liver stage (3 months). Nonparametric analysis of the protein spots yielded fewer proteins and narrowed the list of possible markers and identified D-dopachrome tautomerase (? 1.7, at 3 months) as a possible marker for ethanol-induced early steatohepatitis. The observed differential regulation of proteins have potential to serve as biomarker signature for the detection of steatosis and its progression to steatohepatitis once validated in plasma/serum. -- Graphical abstract: The figure shows the Hierarchial cluster analysis of differentially expressed protein spots obtained after ethanol feeding for 1 (1–3) and 3 (4–6) months. C and E represent pair-fed control and ethanol-fed rats, respectively. Highlights: ? Proteins related to ethanol-induced steatosis and mild steatohepatitis are identified. ? ADH1C and ALDH2 involved in alcohol metabolism are differentially expressed at 1 and 3 months. ? Discovery proteomics identified a group of proteins to serve as potential biomarkers. ? Using nonparametric analysis DDT is identified as a possible marker for liver damage.

  15. Bushmills Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Bushmills Ethanol Jump to: navigation, search Name: Bushmills Ethanol Place: Atwater, Minnesota Zip: 56209 Product: A group of local agricultural producers and investors working to...

  16. Northstar Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Northstar Ethanol Jump to: navigation, search Name: Northstar Ethanol Place: Lake Crystal, Minnesota Zip: 56055 Product: Corn-base bioethanol producer in Minnesotta References:...

  17. Sunnyside Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Sunnyside Ethanol Place: Pittsburgh, Pennsylvania Zip: PA 15237 Product: Pennsylvania based company created for the specific purpose of...

  18. Ethanol India | Open Energy Information

    Open Energy Info (EERE)

    India Jump to: navigation, search Name: Ethanol India Place: Kolhapur, Maharashtra, India Sector: Biofuels Product: Maharashtra-based biofuels consultancy firm. References: Ethanol...

  19. Pacific Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Pacific Ethanol Address: 400 Capitol Mall, Suite 2060 Place: Sacramento, California Zip: 95814 Region: Bay Area Sector: Biofuels Product: Ethanol production Website:...

  20. Pacific Ethanol, Inc | Department of Energy

    Energy Savers [EERE]

    Major DOE Biofuels Project Locations Pacific Ethanol, Inc Pacific Ethanol, Inc

  1. Solid state fermentation system for production of ethanol from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.; Lee, C.Y.; Woodams, E.E.

    1982-01-01

    A solid state fermentation system for the production of ethanol from apple pomace with a Montrachet strain of Saccharomyces cerevisiae is described. The yields of ethanol varied from about 29 g to more than 40 g/kg of apple pomace, depending on the samples fermented. Separation of up to 99% of the ethanol from spent qpple pomace was achieved with a rotary vacuum evaporator. Alcohol fermentation of apple pomace might be an efficient method of alleviating waste disposal problems with the concomitant production of ethanol.

  2. Alcohol conversion

    DOE Patents [OSTI]

    Wachs, Israel E. (Bridgewater, NJ); Cai, Yeping (Louisville, KY)

    2002-01-01

    Preparing an aldehyde from an alcohol by contacting the alcohol in the presence of oxygen with a catalyst prepared by contacting an intimate mixture containing metal oxide support particles and particles of a catalytically active metal oxide from Groups VA, VIA, or VIIA, with a gaseous stream containing an alcohol to cause metal oxide from the discrete catalytically active metal oxide particles to migrate to the metal oxide support particles and to form a monolayer of catalytically active metal oxide on said metal oxide support particles.

  3. Catalyst Activity Comparison of Alcohols over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-01-01

    Alcohol transformation to transportation fuel range hydrocarbon on HZSM-5 (SiO2 / Al2O3 = 30) catalyst was studied at 360oC and 300psig. Product distributions and catalyst life were compared using methanol, ethanol, 1-propanol or 1-butanol as a feed. The catalyst life for 1-propanol and 1-butanol was more than double compared to that for methanol and ethanol. For all the alcohols studied, the product distributions (classified to paraffin, olefin, napthene, aromatic and naphthalene compounds) varied with time on stream (TOS). At 24 hours TOS, liquid product from 1-propanol and 1-butanol transformation primarily contains higher olefin compounds. The alcohol transformation process to higher hydrocarbon involves a complex set of reaction pathways such as dehydration, oligomerization, dehydrocyclization, and hydrogenation. Compared to ethylene generated from methanol and ethanol, oligomerization of propylene and butylene has a lower activation energy and can readily take place on weaker acidic sites. On the other hand, dehydrocyclization of propylene and butylene to form the cyclic compounds requires the sits with stronger acid strength. Combination of the above mentioned reasons are the primary reasons for olefin rich product generated in the later stage of the time on stream and for the extended catalyst life time for 1 propanol and 1 butanol compared to methanol and ethanol conversion over HZSM-5.

  4. Large-scale production of anhydrous nitric acid and nitric acid solutions of dinitrogen pentoxide

    DOE Patents [OSTI]

    Harrar, Jackson E. (Castro Valley, CA); Quong, Roland (Oakland, CA); Rigdon, Lester P. (Livermore, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-01-01

    A method and apparatus are disclosed for a large scale, electrochemical production of anhydrous nitric acid and N.sub.2 O.sub.5. The method includes oxidizing a solution of N.sub.2 O.sub.4 /aqueous-HNO.sub.3 at the anode, while reducing aqueous HNO.sub.3 at the cathode, in a flow electrolyzer constructed of special materials. N.sub.2 O.sub.4 is produced at the cathode and may be separated and recycled as a feedstock for use in the anolyte. The process is controlled by regulating the electrolysis current until the desired products are obtained. The chemical compositions of the anolyte and catholyte are monitored by measurement of the solution density and the concentrations of N.sub.2 O.sub.4.

  5. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    state. In France, ethanol is produced from grapes that are of insufficient quality for wine production. Prompted by the increase in oil prices in the 1970s, Brazil introduced a...

  6. A model system for QTL analysis: Effects of alcohol dehydrogenase genotype on alcohol pharmacokinetics

    SciTech Connect (OSTI)

    Martin, N.G.; Nightingale, B.; Whitfield, J.B.

    1994-09-01

    There is much interest in the detection of quantitative trait loci (QTL) - major genes which affect quantitative phenotypes. The relationship of polymorphism at known alcohol metabolizing enzyme loci to alcohol pharmacokinetics is a good model system. The three class I alcohol dehydrogenase genes are clustered on chromosome 4 and protein electrophoresis has revealed polymorphisms at the ADH2 and ADH3 loci. While different activities of the isozymes have been demonstrated in vitro, little work has been done in trying to relate ADH polymorphism to variation in ethanol metabolism in vivo. We previously measured ethanol metabolism and psychomotor reactivity in 206 twin pairs and demonstrated that most of the repeatable variation was genetic. We have now recontacted the twins to obtain DNA samples and used PCR with allele specific primers to type the ADH2 and ADH3 polymorphisms in 337 individual twins. FISHER has been used to estimate fixed effects of typed polymorphisms simultaneously with remaining linked and unlinked genetic variance. The ADH2*1-2 genotypes metabolize ethanol faster and attain a lower peak blood alcohol concentration than the more common ADH2*1-1 genotypes, although less than 3% of the variance is accounted for. There is no effect of ADH3 genotype. However, sib-pair linkage analysis suggests that there is a linked polymorphism which has a much greater effect on alcohol metabolism that those typed here.

  7. Ethanol production from lignocellulose

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Wood, Brent E. (Gainesville, FL)

    2001-01-01

    This invention presents a method of improving enzymatic degradation of lignocellulose, as in the production of ethanol from lignocellulosic material, through the use of ultrasonic treatment. The invention shows that ultrasonic treatment reduces cellulase requirements by 1/3 to 1/2. With the cost of enzymes being a major problem in the cost-effective production of ethanol from lignocellulosic material, this invention presents a significant improvement over presently available methods.

  8. BlueFire Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BlueFire Ethanol, Inc. Corporate HQ: Irvine, California Proposed Facility Location: Mecca, California Description: The project will construct and operate a facility that will convert green waste and lignocellulosic fractions diverted from landfills or Southern California Materials Recovery Facilities to ethanol and other products. CEO or Equivalent: Arnold Klann, CEO Participants: Burrtec Waste Industries, JGC Corporation, Brinderson, Roelsien, MECS Inc. NAES, PetroDiamond Production: 19 million

  9. Cloning and sequencing of the alcohol dehydrogenase II gene from Zymomonas mobilis

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Conway, Tyrrell (Gainesville, FL)

    1992-01-01

    The alcohol dehydrogenase II gene from Zymomonas mobilis has been cloned and sequenced. This gene can be expressed at high levels in other organisms to produce acetaldehyde or to convert acetaldehyde to ethanol.

  10. Catalyst for producing lower alcohols

    DOE Patents [OSTI]

    Rathke, Jerome W. (Bolingbrook, IL); Klingler, Robert J. (Woodridge, IL); Heiberger, John J. (Glen Ellyn, IL)

    1987-01-01

    A process and system for the production of the lower alcohols such as methanol, ethanol and propanol involves the reaction of carbon monoxide and water in the presence of a lead salt and an alkali metal formate catalyst combination. The lead salt is present as solid particles such as lead titanate, lead molybdate, lead vanadate, lead zirconate, lead tantalate and lead silicates coated or in slurry within molten alkali metal formate. The reactants, carbon monoxide and steam are provided in gas form at relatively low pressures below 100 atmospheres and at temperatures of 200-400.degree. C. The resulted lower alcohols can be separated into boiling point fractions and recovered from the excess reactants by distillation.

  11. Millennium Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Millennium Ethanol, LLC Place: Marion, South Dakota Zip: 57043 Product: Millennium Ethanol is a group of more than 900 South Dakotan...

  12. East Coast Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: East Coast Ethanol Place: Columbia, South Carolina Zip: 29202 Product: East Coast Ethanol was formed in August 2007 through a merger...

  13. Marysville Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Marysville Ethanol LLC Jump to: navigation, search Name: Marysville Ethanol LLC Place: Marysville, Michigan Zip: 48040 Product: Developing a 50m gallon ethanol plant in Marysville,...

  14. Great Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Valley Ethanol LLC Jump to: navigation, search Name: Great Valley Ethanol LLC Place: Bakersfield, California Product: Developing a 63m gallon ethanol plant in Hanford, CA...

  15. Central Indiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Indiana Ethanol LLC Jump to: navigation, search Name: Central Indiana Ethanol LLC Place: Marion, Indiana Zip: 46952 Product: Ethanol producer developina a 151 mlpa plant in Marion,...

  16. SRSL Ethanol Limited | Open Energy Information

    Open Energy Info (EERE)

    SRSL Ethanol Limited Jump to: navigation, search Name: SRSL Ethanol Limited Place: Mumbai, Maharashtra, India Product: Mumbai-based ethanol subsidiary of Shree Renuka Sugars...

  17. Kansas Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Kansas Ethanol LLC Place: Lyons, Kansas Zip: 67554 Product: Constructing a 55m gallon ethanol plant in Rice County, Kansas...

  18. Chief Ethanol Fuels Inc | Open Energy Information

    Open Energy Info (EERE)

    Fuels Inc Jump to: navigation, search Name: Chief Ethanol Fuels Inc Place: Hastings, Nebraska Product: Ethanol producer and supplier References: Chief Ethanol Fuels Inc1 This...

  19. Heartland Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Heartland Ethanol LLC Place: Knoxville, Tennessee Zip: 37929 Product: Knoxville, TN based ethanol developer. Coordinates: 35.960495,...

  20. Standard Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Standard Ethanol LLC Place: Nebraska Product: Nebraska based ethanol producer that operates two plants References: Standard Ethanol LLC1 This article is a stub. You can help...

  1. Ethanol Capital Funding | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Capital Funding Jump to: navigation, search Name: Ethanol Capital Funding Place: Atlanta, Georgia Zip: 30328 Product: Provides funding for ethanol and biodiesel plants....

  2. Michigan Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Michigan Ethanol LLC Place: Caro, Michigan Zip: 48723-8804 Product: Ethanol productor in Caro, Michigan. Coordinates: 43.488705,...

  3. Siouxland Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Siouxland Ethanol LLC Place: Jackson, Nebraska Zip: 68743 Product: Startup hoping to build a USD 80m ethanol manufacturing plant near...

  4. Platinum Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Platinum Ethanol LLC Jump to: navigation, search Name: Platinum Ethanol LLC Place: Arthut, Iowa Product: Developed a 110m gallon (416m litre) ethanol plant in Arthur, IA....

  5. Nedak Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Nedak Ethanol LLC Jump to: navigation, search Name: Nedak Ethanol LLC Place: Atkinson, Nebraska Zip: 68713 Product: NEDAK Ethanol, LLC is a Nebraska limited liability company,...

  6. North Country Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Country Ethanol LLC Jump to: navigation, search Name: North Country Ethanol LLC Place: Rosholt, South Dakota Zip: 57260 Product: 20mmgy (75.7m litresy) ethanol producer....

  7. South Louisiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    South Louisiana Ethanol LLC Place: Louisiana Product: Ethanol production equipment provider. References: South Louisiana Ethanol LLC1 This article is a stub. You can help OpenEI...

  8. Show Me Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Show Me Ethanol LLC Jump to: navigation, search Name: Show Me Ethanol, LLC Place: Carrollton, Missouri Zip: 64633 Product: Developing an ethanol project in Carrollton, Missouri....

  9. Western Ethanol Company LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Company LLC Jump to: navigation, search Name: Western Ethanol Company LLC Place: Placentia, California Zip: 92871 Product: California-based fuel ethanol distribution and...

  10. Ethanol Tolerant Yeast for Improved Production of Ethanol from Biomass -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Ethanol Tolerant Yeast for Improved Production of Ethanol from Biomass Inventors: Audrey Gasch, Jeffrey Lewis Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing SummaryEthanol production from cellulosic biomass can make a significant contribution toward decreasing our dependence on fossil fuels. However, the fermentation of biomass can be problematic. One bottleneck in this process is the toxicity of ethanol to microbes

  11. Design Case Summary: Production of Mixed Alcohols from Municipal Solid

    Office of Environmental Management (EM)

    Waste via Gasification | Department of Energy Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification The Bioenergy Technologies Office develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and

  12. Separation and concentration of lower alcohols from dilute aqueous solutions

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Eakin, David E. (Kennewick, WA); Baker, Eddie G. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1991-01-01

    A process for producing, from a dilute aqueous solution of a lower (C.sub.1 -C.sub.5) alcohol, a concentrated liquid solution of the alcohol in an aromatic organic solvent is disclosed. Most of the water is removed from the dilute aqueous solution of alcohol by chilling sufficiently to form ice crystals. Simultaneously, the remaining liquid is extracted at substantially the same low temperature with a liquid organic solvent that is substantially immiscible in aqueous liquids and has an affinity for the alcohol at that temperature, causing the alcohol to transfer to the organic phase. After separating the organic liquid from the ice crystals, the organic liquid can be distilled to enrich the concentration of alcohol therein. Ethanol so separated from water and concentrated in an organic solvent such as toluene is useful as an anti-knock additive for gasoline.

  13. Ethanol 2000 | Open Energy Information

    Open Energy Info (EERE)

    Ethanol 2000 Place: Bingham lake, Minnesota Zip: 56118 Product: Farmer-owned bioethanol producer References: Ethanol 20001 This article is a stub. You can help OpenEI by...

  14. Orion Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Orion Ethanol Place: Pratt, Kansas Zip: 67124 Product: A Kansas-based ethanol producer. Coordinates: 38.209925, -81.383804 Show Map Loading map... "minzoom":false,"mappingserv...

  15. Ozark Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ozark Ethanol Place: Missouri Zip: 64762 Product: Missouri-based bioethanol producer planning to develop a 204m-litre per year ethanol plant in Vernon County. References: Ozark...

  16. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    emissions using steady-state and transient test procedures | Department of Energy ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Alcohols as gasoline blending agent at up to 85 vol-% levels were evaluated in a 2.2L direct injection SI engine for combustion, engine efficiency, and

  17. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15

  18. Use of alcohol in farming applications: alternative fuels utilization program

    SciTech Connect (OSTI)

    Borman, G.L.; Foster, D.E.; Uyehara, O.A.; McCallum, P.W.; Timbario, T.J.

    1980-11-01

    The use of alcohol with diesel fuel has been investigated as a means of extending diesel fuel supplies. The ability to use ethanol in diesel-powered farm equipment could provide the means for increasing the near-term fuels self-sufficiency of the American farmer. In the longer term, the potential availability of methanol (from coal) in large quantities could serve to further decrease the dependency on diesel fuel. This document gives two separate overviews of the use of alcohols in farm equipment. Part I of this document compares alcohol with No. 1 and No. 2 diesel fuels and describes several techniques for using alcohol in farm diesels. Part II of this document discusses the use of aqueous ethanol in diesel engines, spark ignition engines and provides some information on safety and fuel handling of both methanol and ethanol. This document is not intended as a guide for converting equipment to utilize alcohol, but rather to provide information such that the reader can gain insight on the advantages and disadvantages of using alcohol in existing engines currently used in farming applications.

  19. Pacific Ethanol, Inc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Verenium Biofuels Corporation Corporate HQ: Cambridge, Massachusetts Proposed Facility Location: Jennings, Louisiana Description: Operation and maintenance of a demonstration-scale facility in Jennings, Louisiana with some capital additions. CEO or Equivalent: Carlos A. Riva, President, Chief Executive Officer and Director Participants: Only Verenium Biofuels Corporation Production: * Capacity of 1.5 million gallons per year of cellulosic ethanol biofuel Technology and Feedstocks: *

  20. Ethanol Myths Fact Sheet

    SciTech Connect (OSTI)

    2009-10-27

    Ethanol is a clean, renewable fuel that is helping to reduce our nation’s dependence on oil and can offer additional economic and environmental benefits in the future. This fact sheet is intended to address some common misconceptions about this important alternative fuel.

  1. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Jeff Dahlberg, Ph D; Ed Wolfrum, Ph D

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called "dedicated bioenergy crops" including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  2. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Dahlberg, Jeff; Wolfrum, Ed

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called �dedicated bioenergy crops� including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  3. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  4. Alcohol Fuels Program technical review, Spring 1984

    SciTech Connect (OSTI)

    Not Available

    1984-10-01

    The alcohol fuels program consists of in-house and subcontracted research for the conversion of lignocellulosic biomass into fuel alcohols via thermoconversion and bioconversion technologies. In the thermoconversion area, the SERI gasifier has been operated on a one-ton per day scale and produces a clean, medium-Btu gas that can be used to manufacture methanol with a relatively small gas-water shift reaction requirement. Recent research has produced catalysts that make methanol and a mixture of higher alcohols from the biomass-derived synthetic gas. Three hydrolysis processes have emerged as candidates for more focused research. They are: a high-temperature, dilute-acid, plug-flow approach based on the Dartmouth reactor; steam explosion pretreatment followed by hydrolysis using the RUT-C30 fungal organism; and direct microbial conversion of the cellulose to ethanol using bacteria in a single or mixed culture. Modeling studies, including parametric and sensitivity analyses, have recently been completed. The results of these studies will lead to a better definition of the present state-of-the-art for these processes and provide a framework for establishing the research and process engineering issues that still need resolution. In addition to these modeling studies, economic feasibility studies are being carried out by commercial engineering firms. Their results will supplement and add commercial validity to the program results. The feasibility contractors will provide input at two levels: Technical and economic assessment of the current state-of-the-art in alcohol production from lignocellulosic biomass via thermoconversion to produce methanol and higher alcohol mixtures and bioconversion to produce ethanol; and identification of research areas having the potential to significantly reduce the cost of production of alcohols.

  5. Weekly Ethanol Production

    Gasoline and Diesel Fuel Update (EIA)

    Ethanol Plant Production (Thousand Barrels per Day) Period: Weekly 4-Week Average Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Product/Region 02/05/16 02/12/16 02/19/16 02/26/16 03/04/16 03/11/16 View History Fuel Ethanol 969 975 994 987 978 999 2010-2016 East Coast (PADD 1) W W W W W W 2010-2016 Midwest (PADD 2) 889 892 913 904 897 917 2010-2016 Gulf Coast (PADD 3) W W W W W W 2010-2016 Rocky Mountain (PADD 4) W W W W W W

  6. Alternative Fuels Data Center: Ethanol Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Ethanol Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Ethanol Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center: Ethanol Vehicle

  7. Alternative Fuels Data Center: Ethanol Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol Related Links to someone by E-mail Share Alternative Fuels Data Center: Ethanol Related Links on Facebook Tweet about Alternative Fuels Data Center: Ethanol Related Links on Twitter Bookmark Alternative Fuels Data Center: Ethanol Related Links on Google Bookmark Alternative Fuels Data Center: Ethanol Related Links on Delicious Rank Alternative Fuels Data Center: Ethanol Related Links on Digg Find

  8. National Ethanol Conference

    Broader source: Energy.gov [DOE]

    The National Ethanol Conference was held Feb. 15—17 in New Orleans, Louisiana. Bioenergy Technologies Office Technology Manager Alicia Lindauer was in attendance to help communicate the goals of the Energy Department’s Fuel-Engine Co-Optimization (formerly known as Optima) initiative. She participated in a panel titled "A Conversation About the Future of U.S. Biofuels Policy," where she discussed the environmental and economic benefits of the initiative.

  9. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf PDF icon EffectsIntermediateEthanolBlends.pdf More Documents &...

  10. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Lynd, Lee R; Shao, Xiongjun; Raman, Babu; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Zhu, Mingjun

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1 2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  11. Protective effect of tetrahydrocoptisine against ethanol-induced gastric ulcer in mice

    SciTech Connect (OSTI)

    Li, Weifeng Huang, Huimin; Niu, Xiaofeng Fan, Ting; Mu, Qingli; Li, Huani

    2013-10-01

    Excessive alcohol consumption can lead to gastric ulcer and the present work was aimed to examine the protective effect of tetrahydrocoptisine (THC) in the model of ethanol-induced gastric ulcer in mice. Fasted mice treated with ethanol 75% (0.5 ml/100 g) were pre-treated with THC (10 or 20 mg/kg, ip), cimetidine (100 mg/kg, ip) or saline in different experimental sets for a period of 3 days, and animals were euthanized 4 h after ethanol ingestion. Gross and microscopic lesions, immunological and biochemical parameters were taken into consideration. The results showed that ethanol induced gastric damage, improving nitric oxide (NO) level, increased pro-inflammatory cytokine (TNF-? and IL-6) levels and myeloperoxidase (MPO) activity, as well as the expression of nuclear factor-?B (NF-?B) in the ethanol group. Pretreatment of THC at doses of 10 and 20 mg/kg bodyweight significantly attenuated the gastric lesions as compared to the ethanol group. These results suggest that the gastroprotective activity of THC is attributed to reducing NO production and adjusting the pro-inflammatory cytokine, inhibited neutrophil accumulation and NF-?B expression. - Highlights: • THC decreased ethanol-induced pro-inflammatory cytokine release. • THC inhibited the production of NO in serum and gastric tissue. • THC reduced NF-?B expression and MPO accumulation in ethanol-induced gastric tissue.

  12. Direct Conversion of Plant Biomass to Ethanol by Engineered Caldicellulosiruptor bescii

    SciTech Connect (OSTI)

    Chung, Daehwan; Cha, Minseok; Guss, Adam M; Westpheling, Janet

    2014-01-01

    Ethanol is the most widely used renewable transportation biofuel in the United States, with the production of 13.3 billion gallons in 2012 [John UM (2013) Contribution of the Ethanol Industry to the Economy of the United States]. Despite considerable effort to produce fuels from lignocellulosic biomass, chemical pretreatment and the addition of saccharolytic enzymes before microbial bioconversion remain economic barriers to industrial deployment [Lynd LR, et al. (2008) Nat Biotechnol 26(2):169-172]. We began with the thermophilic, anaerobic, cellulolytic bacterium Caldicellulosiruptor bescii, which efficiently uses unpretreated biomass, and engineered it to produce ethanol. Here we report the direct conversion of switchgrass, a nonfood, renewable feedstock, to ethanol without conventional pretreatment of the biomass. This process was accomplished by deletion of lactate dehydrogenase and heterologous expression of a Clostridium thermocellum bifunctional acetaldehyde/alcohol dehydrogenase. Whereas wild-type C. bescii lacks the ability to make ethanol, 70% of the fermentation products in the engineered strain were ethanol [12.8 mM ethanol directly from 2% (wt/vol) switchgrass, a real-world substrate] with decreased production of acetate by 38% compared with wild-type. Direct conversion of biomass to ethanol represents a new paradigm for consolidated bioprocessing, offering the potential for carbon neutral, cost-effective, sustainable fuel production.

  13. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Shao, Xiongjun; Raman, Babu; Zhu, Mingjun; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Lynd, Lee R

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1-2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  14. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up

  15. Fuel Ethanol Oxygenate Production

    Gasoline and Diesel Fuel Update (EIA)

    Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area Jul-15 Aug-15 Sep-15 Oct-15 Nov-15 Dec-15 View History U.S. 30,256 29,621 28,543 30,139 29,594 31,075 1981-2015 East Coast (PADD 1) 876 854 692 664 664

  16. Effect of acute treatment with cadmium on ethanol anesthesia, body termperature, and synaptosomal Na/sup +/-K/sup +/-ATPase of rat brain

    SciTech Connect (OSTI)

    Magour, S.; Kristof, V.; Baumann, M.; Assmann, G.

    1981-12-01

    The effect of a single intraperitoneal dose of 0.56, 1.12, and 1.68 mg cadmium/kg on the duration of ethanol-induced sleep was investigated in male rats. Cadmium potentiated ethanol sleeping time in a dose dependent manner up to 300% over controls. No significant difference in the elimination rate of ethanol from blood and brain and observed between control and cadmium-pretreated rats. Cadmium slightly inhibited the hepatic alcohol dehydrogenase in vivo and also potentiated ethanol hypothermia but these changes did not play a significant role in the observed prolongation of ethanol sleeping time. However, cadmium and ethanol additively inhibited brain synaptosomal Na/sup +/-K/sup +/-ATPase in a noncompetitive manner. The results so far indicate that cadmium may increase brain responsiveness toward ethanol partly through inhibition of snaptosomal Na/sup +/-K/sup +/-ATPase.

  17. Vehicle Technologies Office: Intermediate Ethanol Blends

    Broader source: Energy.gov [DOE]

    Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

  18. Northern Lights Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Lights Ethanol LLC Jump to: navigation, search Name: Northern Lights Ethanol LLC Place: Big Stone City, South Dakota Zip: 57216 Product: 75mmgy (283.9m litresy) ethanol producer....

  19. Prairie Creek Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Prairie Creek Ethanol LLC Place: Goldfield, Iowa Zip: 50542 Product: Prairie Creek Ethanol, LLC had planned to build a 55m gallon...

  20. Tharaldson Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Tharaldson Ethanol LLC Jump to: navigation, search Name: Tharaldson Ethanol LLC Place: Casselton, North Dakota Zip: 58012 Product: Owner of a USD 200m 120m-gallon ethanol plant in...

  1. United Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    United Ethanol LLC Place: Wisconsin Product: Developed a 43m gallon ethanol plant in Milton, Wisconsin. References: United Ethanol LLC1 This article is a stub. You can help...

  2. Horizon Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Horizon Ethanol LLC Place: Jewell, Iowa Zip: 50130 Product: 60mmgy (227.1m litrey) ethanol producers in Jewell, Iowa. Coordinates:...

  3. First United Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: First United Ethanol LLC Place: Camilla, Georgia Zip: 31730 Product: First United Ethanol LLC (FUEL) was formed to construct a 100 MGY...

  4. Hydrogen bond dynamics in bulk alcohols

    SciTech Connect (OSTI)

    Shinokita, Keisuke; Cunha, Ana V.; Jansen, Thomas L. C.; Pshenichnikov, Maxim S.

    2015-06-07

    Hydrogen-bonded liquids play a significant role in numerous chemical and biological phenomena. In the past decade, impressive developments in multidimensional vibrational spectroscopy and combined molecular dynamics–quantum mechanical simulation have established many intriguing features of hydrogen bond dynamics in one of the fundamental solvents in nature, water. The next class of a hydrogen-bonded liquid—alcohols—has attracted much less attention. This is surprising given such important differences between water and alcohols as the imbalance between the number of hydrogen bonds, each molecule can accept (two) and donate (one) and the very presence of the hydrophobic group in alcohols. Here, we use polarization-resolved pump-probe and 2D infrared spectroscopy supported by extensive theoretical modeling to investigate hydrogen bond dynamics in methanol, ethanol, and isopropanol employing the OH stretching mode as a reporter. The sub-ps dynamics in alcohols are similar to those in water as they are determined by similar librational and hydrogen-bond stretch motions. However, lower density of hydrogen bond acceptors and donors in alcohols leads to the appearance of slow diffusion-controlled hydrogen bond exchange dynamics, which are essentially absent in water. We anticipate that the findings herein would have a potential impact on fundamental chemistry and biology as many processes in nature involve the interplay of hydrophobic and hydrophilic groups.

  5. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  6. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  7. Alternative Fuels Data Center: Ethanol Feedstocks

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Feedstocks to someone by E-mail Share Alternative Fuels Data Center: Ethanol Feedstocks on Facebook Tweet about Alternative Fuels Data Center: Ethanol Feedstocks on Twitter Bookmark Alternative Fuels Data Center: Ethanol Feedstocks on Google Bookmark Alternative Fuels Data Center: Ethanol Feedstocks on Delicious Rank Alternative Fuels Data Center: Ethanol Feedstocks on Digg Find More places to share Alternative Fuels Data Center: Ethanol Feedstocks on AddThis.com... More in this section...

  8. Alternative Fuels Data Center: Ethanol Production

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Production to someone by E-mail Share Alternative Fuels Data Center: Ethanol Production on Facebook Tweet about Alternative Fuels Data Center: Ethanol Production on Twitter Bookmark Alternative Fuels Data Center: Ethanol Production on Google Bookmark Alternative Fuels Data Center: Ethanol Production on Delicious Rank Alternative Fuels Data Center: Ethanol Production on Digg Find More places to share Alternative Fuels Data Center: Ethanol Production on AddThis.com... More in this section...

  9. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  10. Bioenergy Impacts Â… Cellulosic Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for its cellulosic ethanol biorefinery. Farmers earned additional revenue from selling their leftover corn husks, stalks, and leaves to the POET-DSM biorefinery for production of cellulosic ethanol-a type of biofuel. Biofuels have created extra revenue for farmers

  11. Early life ethanol exposure causes long-lasting disturbances in rat mesenchymal stem cells via epigenetic modifications

    SciTech Connect (OSTI)

    Leu, Yu-Wei; Chu, Pei-Yi; Chen, Chien-Min; Yeh, Kun-Tu; Liu, Yu Ming; Lee, Yen-Hui; Kuo, Shan-Tsu; Hsiao, Shu-Huei

    2014-10-24

    Highlights: • Ethanol exposure alters proliferation and differentiation of MSCs. • Ethanol exposure suppresses osteogenesis and adipogenesis of MSCs. • H3K27me3-associated genes/pathways are affected in ethanol-exposed MSCs. • Expression of lineage-specific genes is dysregulated in ethanol-exposed MSCs. - Abstract: Fetal alcohol syndrome (FAS) is a birth defect due to maternal alcohol consumption during pregnancy. Because mesenchymal stem cells (MSCs) are the main somatic stem cells in adults and may contribute to tissue homeostasis and repair in adulthood, we investigated whether early life ethanol exposure affects MSCs and contributes to the propensity for disease onset in later life. Using a rodent model of FAS, we found that ethanol exposure (5.25 g/kg/day) from postnatal days 4 to 9 in rat pups (mimic of human third trimester) caused long-term anomalies in bone marrow-derived MSCs. MSCs isolated from ethanol-exposed animals were prone to neural induction but resistant to osteogenic and adipogenic inductions compared to their age-matched controls. The altered differentiation may contribute to the severe trabecular bone loss seen in ethanol-exposed animals at 3 months of age as well as overt growth retardation. Expression of alkaline phosphatase, osteocalcin, aP2, and PPAR? were substantially inhibited, but BDNF was up-regulated in MSCs isolated from ethanol-exposed 3 month-old animals. Several signaling pathways were distorted in ethanol-exposed MSCs via altered trimethylation at histone 3 lysine 27. These results demonstrate that early life ethanol exposure can have long-term impacts in rat MSCs by both genetic and epigenetic mechanisms.

  12. Center Ethanol Company LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Jump to: navigation, search Name: Center Ethanol Company LLC Place: Illinois Product: Illinois based company building a 54m gallon ethanol plant in Sauget, IL. References:...

  13. US Ethanol Vehicle Coalition | Open Energy Information

    Open Energy Info (EERE)

    Vehicle Coalition Jump to: navigation, search Name: US Ethanol Vehicle Coalition Place: Jefferson City, Missouri Zip: 65109 Product: The National Ethanol Vehicle Coalition is the...

  14. Louisiana: Verenium Cellulosic Ethanol Demonstration Facility...

    Energy Savers [EERE]

    Louisiana: Verenium Cellulosic Ethanol Demonstration Facility Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium...

  15. Ethanol Capital Management | Open Energy Information

    Open Energy Info (EERE)

    Management Jump to: navigation, search Name: Ethanol Capital Management Place: Tucson, Arizona Zip: 85711 Product: Manages funds investing in Ethanol plants in the US Coordinates:...

  16. Blue Flint Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Flint Ethanol Jump to: navigation, search Name: Blue Flint Ethanol Place: Underwood, North Dakota Zip: ND 58576 Product: Joint Venture bentween Great River Energy and Headwaters...

  17. Prairie Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Prairie Ethanol LLC Place: Loomis, South Dakota Product: Farmer owned bioethanol project development and managment team. Coordinates:...

  18. Great Plains Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Jump to: navigation, search Name: Great Plains Ethanol Place: Chancellor, South Dakota Zip: 57015 Product: Limited liability company owned by its 500 members which owns and...

  19. Chief Ethanol Fuels | Open Energy Information

    Open Energy Info (EERE)

    Fuels Jump to: navigation, search Name: Chief Ethanol Fuels Place: Hastings, NE Website: www.chiefethanolfuels.com References: Chief Ethanol Fuels1 Information About Partnership...

  20. Ethanol production in non-recombinant hosts

    DOE Patents [OSTI]

    Kim, Youngnyun; Shanmugam, Keelnatham; Ingram, Lonnie O.

    2013-06-18

    Non-recombinant bacteria that produce ethanol as the primary fermentation product, associated nucleic acids and polypeptides, methods for producing ethanol using the bacteria, and kits are disclosed.

  1. Evergreen Securities formerly Ethanol Investments | Open Energy...

    Open Energy Info (EERE)

    Securities formerly Ethanol Investments Jump to: navigation, search Name: Evergreen Securities (formerly Ethanol Investments) Place: London, England, United Kingdom Zip: EC2V 5DE...

  2. Missouri Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Missouri Ethanol LLC Place: Laddonia, Missouri Product: 45mmgy (170.3m litresy) ethanol producer. Coordinates: 39.24073, -91.645599 Show Map Loading map......

  3. BlueFire Ethanol | Open Energy Information

    Open Energy Info (EERE)

    BlueFire Ethanol Jump to: navigation, search Name: BlueFire Ethanol Place: Irvine, California Zip: 92618 Sector: Hydro Product: US biofuel producer that utilises a patented...

  4. Badger State Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    State Ethanol LLC Jump to: navigation, search Name: Badger State Ethanol LLC Place: Monroe, Wisconsin Zip: 53566 Product: Dry-mill bioethanol producer References: Badger State...

  5. Iowa Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Iowa Ethanol LLC Place: Hanlontown, Iowa Zip: 50451 Product: Corn-base bioethanol producer in Iowa Coordinates: 43.28456,...

  6. James Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    James Valley Ethanol LLC Place: Gronton, South Dakota Zip: 57445 Product: Farmers owned cooperative that built and operates an ethanol production facility. Coordinates: 29.72369,...

  7. Algodyne Ethanol Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    Algodyne Ethanol Energy Inc Jump to: navigation, search Name: Algodyne Ethanol Energy Inc Place: Las Vegas, Nevada Zip: 89145 Sector: Biofuels Product: Holds proprietary...

  8. Tall Corn Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Tall Corn Ethanol LLC Jump to: navigation, search Name: Tall Corn Ethanol LLC Place: Coon Rapids, Iowa Zip: 50058 Product: Farmer owned bioethanol production company which owns a...

  9. Frontier Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Frontier Ethanol LLC Place: Gowrie, Iowa Product: Owner and operator of a bioethanol plant near Gowrie, Iowa. Coordinates: 42.28227,...

  10. Ethanol Management Company | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Management Company Place: Colorado Product: Biofuel blender located in Denver, Colorado. References: Ethanol Management Company1 This article is a stub. You can help...

  11. Ethanol Grain Processors LLC | Open Energy Information

    Open Energy Info (EERE)

    Processors LLC Jump to: navigation, search Name: Ethanol Grain Processors, LLC Place: Obion, Tennessee Zip: TN 38240 Product: Tennessee-based ethanol producer. Coordinates:...

  12. Kaapa Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Kaapa Ethanol LLC Jump to: navigation, search Name: Kaapa Ethanol LLC Place: Minden, Nebraska Zip: 68959 Product: Bioethanol producer using corn as feedstock Coordinates:...

  13. Gulf Ethanol Corp | Open Energy Information

    Open Energy Info (EERE)

    Gulf Ethanol Corp Jump to: navigation, search Name: Gulf Ethanol Corp Place: Houston, Texas Zip: 77055 Sector: Biomass Product: Focused on developing biomass preprocessing...

  14. Didion Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Didion Ethanol LLC Jump to: navigation, search Name: Didion Ethanol LLC Place: Cambria, Wisconsin Zip: 53923 Product: Also Didion Milling LLC, Grand River Distribution LLC....

  15. Atlantic Ethanol Capital | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Capital Jump to: navigation, search Name: Atlantic Ethanol Capital Place: Washington, Washington, DC Product: Biofuel Investor in Caribbean and Central American region....

  16. Platte Valley Fuel Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Valley Fuel Ethanol Jump to: navigation, search Name: Platte Valley Fuel Ethanol Place: Central City, Nebraska Product: Bioethanol producer using corn as feedstock References:...

  17. Pacific Ethanol, Inc | Department of Energy

    Energy Savers [EERE]

    Verenium Biofuels Fact Sheet Pacific Ethanol, Inc Verenium Pilot- and Demonstration-Scale Biorefinery

  18. Ethanol Ventures | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Ventures Place: London, England, United Kingdom Zip: W1D 3SQ Product: Company aims to deliver at least 378 million litres a year of bioethanol from two Facilities in...

  19. Lipidomic changes in rat liver after long-term exposure to ethanol

    SciTech Connect (OSTI)

    Fernando, Harshica; Bhopale, Kamlesh K.; Kondraganti, Shakuntala; Kaphalia, Bhupendra S.; Shakeel Ansari, G.A.

    2011-09-01

    Alcoholic liver disease (ALD) is a serious health problem with significant morbidity and mortality. In this study we examined the progression of ALD along with lipidomic changes in rats fed ethanol for 2 and 3 months to understand the mechanism, and identify possible biomarkers. Male Fischer 344 rats were fed 5% ethanol or caloric equivalent of maltose-dextrin in a Lieber-DeCarli diet. Animals were killed at the end of 2 and 3 months and plasma and livers were collected. Portions of the liver were fixed for histological and immunohistological studies. Plasma and the liver lipids were extracted and analyzed by nuclear magnetic resonance (NMR) spectroscopy. A time dependent fatty infiltration was observed in the livers of ethanol-fed rats. Mild inflammation and oxidative stress were observed in some ethanol-fed rats at 3 months. The multivariate and principal component analysis of proton and phosphorus NMR spectroscopy data of extracted lipids from the plasma and livers showed segregation of ethanol-fed groups from the pair-fed controls. Significant hepatic lipids that were increased by ethanol exposure included fatty acids and triglycerides, whereas phosphatidylcholine (PC) decreased. However, both free fatty acids and PC decreased in the plasma. In liver lipids unsaturation of fatty acyl chains increased, contrary to plasma, where it decreased. Our studies confirm that over-accumulation of lipids in ethanol-induced liver steatosis accompanied by mild inflammation on long duration of ethanol exposure. Identified metabolic profile using NMR lipidomics could be further explored to establish biomarker signatures representing the etiopathogenesis, progression and/or severity of ALD. - Highlights: > Long term exposure to ethanol was studied. > A nuclear magnetic resonance (NMR) spectroscopy based lipidomic approach was used. > We examined the clustering pattern of the NMR data with principal component analysis. > NMR data were compared with histology and immunohistochemistry data. > Biochemical parameters were compared with the observed NMR lipid data.

  20. Response of rat brain protein synthesis to ethanol and sodium barbital

    SciTech Connect (OSTI)

    Tewari, S.; Greenberg, S.A.; Do, K.; Grey, P.A.

    1987-01-01

    Central nervous system (CNS) depressants such as ethanol and barbiturates under acute or chronic conditions can induce changes in rat brain protein synthesis. While these data demonstrate the individual effects of drugs on protein synthesis, the response of brain protein synthesis to alcohol-drug interactions is not known. The goal of the present study was to determine the individual and combined effects of ethanol and sodium barbital on brain protein synthesis and gain an understanding of the mechanisms by which these alterations in protein synthesis are produced. Specifically, the in vivo and in vitro effects of sodium barbital (one class of barbiturates which is not metabolized by the hepatic tissue) were examined on brain protein synthesis in rats made physically dependent upon ethanol. Using cell free brain polysomal systems isolated from Control, Ethanol and 24 h Ethanol Withdrawn rats, data show that sodium barbital, when intubated intragastrically, inhibited the time dependent incorporation of /sup 14/C) leucine into protein by all three groups of ribosomes. Under these conditions, the Ethanol Withdrawn group displayed the largest inhibition of the /sup 14/C) leucine incorporation into protein when compared to the Control and Ethanol groups. In addition, sodium barbital when added at various concentrations in vitro to the incubation medium inhibited the incorporation of /sup 14/C) leucine into protein by Control and Ethanol polysomes. The inhibitory effects were also obtained following preincubation of ribosomes in the presence of barbital but not cycloheximide. Data suggest that brain protein synthesis, specifically brain polysomes, through interaction with ethanol or barbital are involved in the functional development of tolerance. These interactions may occur through proteins or polypeptide chains or alterations in messenger RNA components associated with the ribosomal units.

  1. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  2. HD Applications of Significantly Downsized SI Engines Using Alcohol DI for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Knock Avoidance | Department of Energy Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding knock in turbocharged, high-compression ratio spark-ignited engines that could replace diesels in certain vocational applications. PDF icon deer08_blumberg.pdf More Documents &

  3. Ascorbic acid suppresses endotoxemia and NF-?B signaling cascade in alcoholic liver fibrosis in guinea pigs: A mechanistic approach

    SciTech Connect (OSTI)

    Abhilash, P.A.; Harikrishnan, R.; Indira, M.

    2014-01-15

    Alcohol consumption increases the small intestinal bacterial overgrowth (SIBO) and intestinal permeability of endotoxin. The endotoxin mediated inflammatory signaling plays a major role in alcoholic liver fibrosis. We evaluated the effect of ascorbic acid (AA), silymarin and alcohol abstention on the alcohol induced endotoxemia and NF-?B activation cascade pathway in guinea pigs (Cavia porcellus). Guinea pigs were administered ethanol at a daily dose of 4 g/kg b.wt for 90 days. After 90 days, ethanol administration was stopped. The ethanol treated animals were divided into abstention, silymarin (250 mg/kg b.wt) and AA (250 mg/kg b.wt) supplemented groups and maintained for 30 days. The SIBO, intestinal permeability and endotoxin were significantly increased in the ethanol group. The mRNA expressions of intestinal proteins claudin, occludin and zona occludens-1 were significantly decreased in ethanol group. The mRNA levels of inflammatory receptors, activity of IKK? and the protein expressions of phospho-I?B?, NF-?B, TNF-?, TGF-?{sub 1} and IL-6 were also altered in ethanol group. The expressions of fibrosis markers ?-SMA, ?{sub 1} (I) collagen and sirius red staining in the liver revealed the induction of fibrosis. But the supplementation of AA could induce greater reduction of ethanol induced SIBO, intestinal barrier defects, NF-?B activation and liver fibrosis than silymarin. The possible mechanism may be the inhibitory effect of AA on SIBO, intestinal barrier defect and IKK?, which decreased the activation of NF-?B and synthesis of cytokines. This might have led to suppression of HSCs activation and liver fibrosis. - Highlights: • Alcohol increases intestinal bacterial overgrowth and permeability of endotoxin. • Endotoxin mediated inflammation plays a major role in alcoholic liver fibrosis. • Ascorbic acid reduces endotoxemia, NF-?B activation and proinflammatory cytokines. • AA's action is by inhibition of SIBO, IKK? and alteration of intestinal permeability. • This might have led to suppression of HSCs activation and liver fibrosis.

  4. The role of acetate in alcohol-induced alterations of uterine glucose metabolism in the mouse during pregnancy

    SciTech Connect (OSTI)

    Simm, B. ); Murdoch, R.N. )

    1990-01-01

    The acute exposure of mice to ethanol during post-implantation pregnancy has been reported to cause alterations in the levels of several glycolytic intermediates in the uterus, suggesting a possible indirect mechanism of alcohol embryo-toxicity. The present study was undertaken to assess whether the ethanol metabolite, acetate is implicated in this phenomenon. Blood and uterine alcohol concentrations in day 9 - pregnant Quackenbush Swiss mice were maximal 15 minutes after the intraperitoneal injection of ethanol, and fell to almost negligible levels 6 hours later. In response to this treatment, the levels of blood and uterine acetate increased, liver glycogen decreased, plasma glucose increased, and uterine glucose, glucose-6-phosphate (G-6-P), fructose-6-phosphate (F-6-P), and citrate increased. When acetate was administered to pregnant mice in amounts approximating those generated by exposure to alcohol, the levels of uterine F-6-P and citrate increased while other metabolic parameters remained unaffected. The administration of 4-methylpyrazole to mice subsequently treated with alcohol produced conditions of alcohol exposure in the absence of ethanol-derived acetate and depressed the ethanol-induced rise in uterine G-6-P and citrate.

  5. California Ethanol Power CE P | Open Energy Information

    Open Energy Info (EERE)

    Power CE P Jump to: navigation, search Name: California Ethanol & Power (CE+P) Place: Florida Product: US ethanol project developer. References: California Ethanol & Power...

  6. Conesul Sugar and Ethanol Plant | Open Energy Information

    Open Energy Info (EERE)

    Conesul Sugar and Ethanol Plant Jump to: navigation, search Name: Conesul Sugar and Ethanol Plant Place: Brazil Product: Brazilian ethanol producer References: Conesul Sugar and...

  7. Agri Ethanol Products LLC AEPNC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Products LLC AEPNC Jump to: navigation, search Name: Agri-Ethanol Products LLC (AEPNC) Place: Raleigh, North Carolina Zip: 27615 Product: Ethanol producer and project...

  8. Grupo Maris Capital ethanol refinery | Open Energy Information

    Open Energy Info (EERE)

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  9. Midwest Ethanol Producers Inc MEPI | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Producers Inc MEPI Jump to: navigation, search Name: Midwest Ethanol Producers Inc (MEPI) Place: O'Neill, Nebraska Zip: 68763 Product: Focused on ethanol production....

  10. Baicheng Tingfeng Ethanol Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Tingfeng Ethanol Co Ltd Jump to: navigation, search Name: Baicheng Tingfeng Ethanol Co Ltd Place: Baicheng, Jilin Province, China Zip: 137000 Product: The company is a ethanol...

  11. DuPont Danisco Cellulosic Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Danisco Cellulosic Ethanol Jump to: navigation, search Name: DuPont Danisco Cellulosic Ethanol Place: Itasca, Illinois Zip: 60143 Product: DuPont Danisco Cellulosic Ethanol is a...

  12. Tampa Bay Area Ethanol Consortium | Open Energy Information

    Open Energy Info (EERE)

    Bay Area Ethanol Consortium Jump to: navigation, search Name: Tampa Bay Area Ethanol Consortium Place: Tampa, Florida Sector: Biomass Product: Consortium researching ethanol from...

  13. National Ethanol Vehicle Coalition NEVC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Vehicle Coalition NEVC Jump to: navigation, search Name: National Ethanol Vehicle Coalition (NEVC) Place: Jefferson City, Missouri Zip: 65109 Product: The National Ethanol...

  14. Ethanol Fuel Basics | Department of Energy

    Office of Environmental Management (EM)

    Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials collectively known as "biomass." Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that

  15. Role of Nrf2 in preventing ethanol-induced oxidative stress and lipid accumulation

    SciTech Connect (OSTI)

    Wu, Kai Connie; Liu, Jie; Klaassen, Curtis D.

    2012-08-01

    Oxidative stress and lipid accumulation play important roles in alcohol-induced liver injury. Previous reports showed that, in livers of nuclear factor erythroid 2-related factor 2 (Nrf2)-activated mice, genes involved in antioxidant defense are induced, whereas genes involved in lipid biosynthesis are suppressed. To investigate the role of Nrf2 in ethanol-induced hepatic alterations, Nrf2-null mice, wild-type mice, kelch-like ECH-associated protein 1-knockdown (Keap1-KD) mice with enhanced Nrf2, and Keap1-hepatocyte knockout (Keap1-HKO) mice with maximum Nrf2 activation, were treated with ethanol (5 g/kg, po). Blood and liver samples were collected 6 h thereafter. Ethanol increased alanine aminotransferase and lactate dehydrogenase activities as well as thiobarbituric acid reactive substances in serum of Nrf2-null and wild-type mice, but not in Nrf2-enhanced mice. After ethanol administration, mitochondrial glutathione concentrations decreased markedly in Nrf2-null mice but not in Nrf2-enhanced mice. H{sub 2}DCFDA staining of primary hepatocytes isolated from the four genotypes of mice indicates that oxidative stress was higher in Nrf2-null cells, and lower in Nrf2-enhanced cells than in wild-type cells. Ethanol increased serum triglycerides and hepatic free fatty acids in Nrf2-null mice, and these increases were blunted in Nrf2-enhanced mice. In addition, the basal mRNA and nuclear protein levels of sterol regulatory element-binding protein 1(Srebp-1) were decreased with graded Nrf2 activation. Ethanol further induced Srebp-1 mRNA in Nrf2-null mice but not in Nrf2-enhanced mice. In conclusion, Nrf2 activation prevented alcohol-induced oxidative stress and accumulation of free fatty acids in liver by increasing genes involved in antioxidant defense and decreasing genes involved in lipogenesis. -- Highlights: ? Ethanol depleted mitochondrial GSH in Nrf2-null mice but not in Keap1-KD mice. ? Ethanol increased ROS in hepatocytes isolated from Nrf2-null and wild-type mice. ? Nrf2 blunted ethanol-induced increase of triglycerides and free fatty acids. ? The mRNA and nuclear protein of Srebp-1 were decreased with Nrf2 activation. ? The mRNA of Scd1 was increased in Nrf2-null mice after ethanol exposure.

  16. Ethanol Demand in United States Gasoline Production

    SciTech Connect (OSTI)

    Hadder, G.R.

    1998-11-24

    The Oak Ridge National Laboratory (OWL) Refinery Yield Model (RYM) has been used to estimate the demand for ethanol in U.S. gasoline production in year 2010. Study cases examine ethanol demand with variations in world oil price, cost of competing oxygenate, ethanol value, and gasoline specifications. For combined-regions outside California summer ethanol demand is dominated by conventional gasoline (CG) because the premised share of reformulated gasoline (RFG) production is relatively low and because CG offers greater flexibility for blending high vapor pressure components like ethanol. Vapor pressure advantages disappear for winter CG, but total ethanol used in winter RFG remains low because of the low RFG production share. In California, relatively less ethanol is used in CG because the RFG production share is very high. During the winter in California, there is a significant increase in use of ethanol in RFG, as ethanol displaces lower-vapor-pressure ethers. Estimated U.S. ethanol demand is a function of the refiner value of ethanol. For example, ethanol demand for reference conditions in year 2010 is 2 billion gallons per year (BGY) at a refiner value of $1.00 per gallon (1996 dollars), and 9 BGY at a refiner value of $0.60 per gallon. Ethanol demand could be increased with higher oil prices, or by changes in gasoline specifications for oxygen content, sulfur content, emissions of volatile organic compounds (VOCS), and octane numbers.

  17. Ethanol production method and system

    DOE Patents [OSTI]

    Chen, M.J.; Rathke, J.W.

    1983-05-26

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  18. Enabling High Efficiency Ethanol Engines

    SciTech Connect (OSTI)

    Szybist, J.; Confer, K.

    2011-03-01

    Delphi Automotive Systems and ORNL established this CRADA to explore the potential to improve the energy efficiency of spark-ignited engines operating on ethanol-gasoline blends. By taking advantage of the fuel properties of ethanol, such as high compression ratio and high latent heat of vaporization, it is possible to increase efficiency with ethanol blends. Increasing the efficiency with ethanol-containing blends aims to remove a market barrier of reduced fuel economy with E85 fuel blends, which is currently about 30% lower than with petroleum-derived gasoline. The same or higher engine efficiency is achieved with E85, and the reduction in fuel economy is due to the lower energy density of E85. By making ethanol-blends more efficient, the fuel economy gap between gasoline and E85 can be reduced. In the partnership between Delphi and ORNL, each organization brought a unique and complementary set of skills to the project. Delphi has extensive knowledge and experience in powertrain components and subsystems as well as overcoming real-world implementation barriers. ORNL has extensive knowledge and expertise in non-traditional fuels and improving engine system efficiency for the next generation of internal combustion engines. Partnering to combine these knowledge bases was essential towards making progress to reducing the fuel economy gap between gasoline and E85. ORNL and Delphi maintained strong collaboration throughout the project. Meetings were held regularly, usually on a bi-weekly basis, with additional reports, presentations, and meetings as necessary to maintain progress. Delphi provided substantial hardware support to the project by providing components for the single-cylinder engine experiments, engineering support for hardware modifications, guidance for operational strategies on engine research, and hardware support by providing a flexible multi-cylinder engine to be used for optimizing engine efficiency with ethanol-containing fuels.

  19. US Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Place: Vancouver, Washington State Zip: 98660 Product: Ethanol producer in the north-west. References: US Ethanol LLC1 This article is a stub. You can help OpenEI by...

  20. Elkhorn Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Elkhorn Valley Ethanol LLC Place: Norfolk, Nebraska Zip: 68701 Product: Operates a 40m gallon ethanol plant in Norfolk, Nebraska. Coordinates: 36.846825, -76.285069 Show Map...

  1. Brazil Ethanol Inc | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Inc Jump to: navigation, search Name: Brazil Ethanol Inc. Place: New York, New York Zip: 10021 Product: A New York City-based firm that had raised USD 10.4m as of 1 May...

  2. JH Kelly LLC Ethanol | Open Energy Information

    Open Energy Info (EERE)

    JH Kelly LLC Ethanol Jump to: navigation, search Name: JH Kelly LLC Ethanol Place: Longview, Washington State Zip: 98632 Product: A joint venture company between JH Kelly and and...

  3. Farmers Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Jump to: navigation, search Name: Farmers' Ethanol LLC Place: Adamsville, Ohio Zip: OH 43802 Product: An association of farmers registered on July 12,2002 with a goal...

  4. Furfuryl alcohol cellular product

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-05-26

    Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

  5. Design Case Summary. Production of Mixed Alcohols from Municipal Solid Waste via Gasification

    SciTech Connect (OSTI)

    Valkenburg, C.; Zhu, Y.; Walton, C. W.; Thompson, B. L.; Gerber, M. A.; Jones, S. B.; Stevens, D. J.

    2010-03-01

    The Biomass Program develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and other mixed alcohols via gasification.

  6. Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Using Transient Hardware-In-Loop Test Meth | Department of Energy Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth Discusses results of cold- and hot-start transient tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol) PDF icon deer11_ickes.pdf More Documents

  7. Ethanol's Effect on Grain Supply and Prices

    SciTech Connect (OSTI)

    2008-01-01

    This document provides graphical information about ethanol's effect on grain supply and prices, uses of corn, and grain price trends.

  8. Re-engineering bacteria for ethanol production

    DOE Patents [OSTI]

    Yomano, Lorraine P; York, Sean W; Zhou, Shengde; Shanmugam, Keelnatham; Ingram, Lonnie O

    2014-05-06

    The invention provides recombinant bacteria, which comprise a full complement of heterologous ethanol production genes. Expression of the full complement of heterologous ethanol production genes causes the recombinant bacteria to produce ethanol as the primary fermentation product when grown in mineral salts medium, without the addition of complex nutrients. Methods for producing the recombinant bacteria and methods for producing ethanol using the recombinant bacteria are also disclosed.

  9. Four Cellulosic Ethanol Breakthroughs | Department of Energy

    Office of Environmental Management (EM)

    Four Cellulosic Ethanol Breakthroughs Four Cellulosic Ethanol Breakthroughs September 3, 2014 - 1:11pm Addthis Cellulosic ethanol biorefinery 1 of 10 Cellulosic ethanol biorefinery The mechanical building (front), solid/liquid separation building (left), and anaerobic digestion building (back) at POET-DSM's Project LIBERTY biorefinery in Emmetsburg, Iowa. Image: Courtesy of POET-DSM Stacking up biomass 2 of 10 Stacking up biomass The biomass stackyard, where corn waste is stored at POET-DSM's

  10. Hige Compression Ratio Turbo Gasoline Engine Operation Using Alcohol Enhancement

    SciTech Connect (OSTI)

    Heywood, John; Jo, Young Suk; Lewis, Raymond; Bromberg, Leslie; Heywood, John

    2015-10-31

    The overall objective of this project was to quantify the potential for improving the performance and efficiency of gasoline engine technology by use of alcohols to suppress knock. Knock-free operation is obtained by direct injection of a second “anti-knock” fuel such as ethanol, which suppresses knock when, with gasoline fuel, knock would occur. Suppressing knock enables increased turbocharging, engine downsizing, and use of higher compression ratios throughout the engine’s operating map. This project combined engine testing and simulation to define knock onset conditions, with different mixtures of gasoline and alcohol, and with this information quantify the potential for improving the efficiency of turbocharged gasoline spark-ignition engines, and the on-vehicle fuel consumption reductions that could then be realized. The more focused objectives of this project were therefore to: Determine engine efficiency with aggressive turbocharging and downsizing and high compression ratio (up to a compression ratio of 13.5:1) over the engine’s operating range; Determine the knock limits of a turbocharged and downsized engine as a function of engine speed and load; Determine the amount of the knock-suppressing alcohol fuel consumed, through the use of various alcohol-gasoline and alcohol-water gasoline blends, for different driving cycles, relative to the gasoline consumed; Determine implications of using alcohol-boosted engines, with their higher efficiency operation, in both light-duty and medium-duty vehicle sectors.

  11. BlueFire Ethanol, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BlueFire Ethanol, Inc. BlueFire Ethanol, Inc. A proposal issued by BlueFire Ethanol Inc,describing a project that will give DOE understanding of a new biological fermentation process not using enzymes. PDF icon BlueFire Ethanol, Inc. More Documents & Publications Applicant Organization: BlueFire Ethanol Pacific Ethanol, Inc

  12. Preliminary energy balance and economic of a farm-scale ethanol plant

    SciTech Connect (OSTI)

    Jantzen, D.; McKinnon, T.

    1980-05-01

    A small-scale ethanol plant was designed, built, tested, and modified over the past 18 months. The plant currently operating is the second design. A third, and probably final, design will be installed and operating within a few months. The current plant produces approximately 30 gal/hr of 190-proof alcohol on a continuous basis. The new plant will produce 50 gal/hr of 200-proof alcohol. A key feature is the relatively low process heat requirement, which is achieved by extensive use of waste-heat recovery heat exchangers. This is manifested in the low temperatures of the process output streams. Acting on the request of the Office of Alcohol Fuels, US Department of Energy, and at the invitation of the owners, representatives from the Solar Energy Research Institute evaluated the energy balance on the plant. The objective was to help clear up the controversy surrounding the net energy benefit of ethanol production. Although the study was site-specific to the plant and limited in scope, it is indicative of the potential performance of grain-to-ethanol plants in general.

  13. Extracting alcohols from aqueous solutions

    DOE Patents [OSTI]

    Compere, Alicia L.; Googin, John M.; Griffith, William L.

    1984-01-01

    Hydrocarbon and surfactants are contacted with a solution of alcohol and water to extract the alcohol into the hydrocarbon-surfactant mixture.

  14. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  15. Ethanol annual report FY 1990

    SciTech Connect (OSTI)

    Texeira, R.H.; Goodman, B.J.

    1991-01-01

    This report summarizes the research progress and accomplishments of the US Department of Energy (DOE) Ethanol from Biomass Program, field managed by the Solar Energy Research Institute, during FY 1990. The report includes an overview of the entire program and summaries of individual research projects. These projects are grouped into the following subject areas: technoeconomic analysis; pretreatment; cellulose conversion; xylose fermentation; and lignin conversion. Individual papers have been indexed separately for inclusion on the data base.

  16. Enabling High Efficiency Ethanol Engines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Efficiency Ethanol Engines (VSSP 12) Presented by Robert Wagner Oak Ridge National Laboratory 2009 DOE Hydrogen Program and Vehicle Technologies Annual Merit Review This presentation does not contain any proprietary, confidential, or otherwise restricted information. May 20, 2009 Lee Slezak Vehicle Technologies U.S. Department of Energy David Smith Sentech Inc Keith Confer, John MacBain Delphi Automotive Systems Project ID: vssp_12_wagner 2 Managed by UT-Battelle for the U.S. Department of

  17. Mid-Level Ethanol Blends

    Office of Environmental Management (EM)

    Mid-Level Ethanol Blends Test Program DOE, NREL, and ORNL Team Presented by Keith Knoll Work supported by DOE/EERE Vehicle Technologies Program Annual Merit Review and Peer Evaluation meeting May 19, 2009 Kevin Stork Vehicle Technologies Program Shab Fardanesh and Joan Glickman Office of the Biomass Program This presentation does not contain any proprietary or classified information Project ID: ft_05_knoll Collaborators Kevin Stork DOE OVT Shab Fardanesh DOE OBP Joan Glickman DOE OBP Wendy Clark

  18. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  19. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    Oxygenate Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Captive Refinery Oxygenate Plants Oxygenate production facilities located within or adjacent to a refinery complex. Fuel Ethanol An anhydrous denatured aliphatic alcohol intended for gasoline blending as described in Oxygenates definition. Gasohol A blend of finished motor gasoline containing alcohol (generally ethanol but sometimes methanol) at a concentration of 10 percent or less by volume.

  20. Elimination of hydrogenase post-translational modification blocks H2 production and increases ethanol yield in Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Zheng, Tianyong; Olson, Daniel G.; Lynd, Lee R; Guss, Adam M

    2015-01-01

    The native ability of Clostridium thermocellum to rapidly consume cellulose and produce ethanol makes it a leading candidate for a consolidated bioprocessing (CBP) biofuel production strategy. C. thermocellum also synthesizes lactate, formate, acetate, H2, and amino acids that compete with ethanol production for carbon and electrons. Elimination of H2 production could redirect carbon flux towards ethanol production by making more electrons available for acetyl-CoA reduction to ethanol. C. thermocellum encodes four hydrogenases and rather than delete each individually, we targeted a hydrogenase maturase gene (hydG), involved in converting the three [FeFe] hydrogenase apoenzymes into holoenzymes. Further deletion of the [NiFe] hydrogenase (ech) resulted in a mutant that functionally lacks all four hydrogenases. H2 production in hydG ech was undetectable and ethanol yield increased nearly 2-fold compared to wild type. Interestingly, mutant growth improved upon the addition of acetate, which led to increased expression of genes related to sulfate metabolism, suggesting these mutants may use sulfate as a terminal electron acceptor to balance redox reactions. Genomic analysis of hydG revealed a mutation in adhE, resulting in a strain with both NADH- and NADPH-dependent alcohol dehydrogenase activities. While this same adhE mutation is found in ethanol tolerant C. thermocellum strain E50C, hydG and hydG ech are not more ethanol tolerant than wild type, illustrating the complicated interactions between redox balancing and ethanol tolerance in C. thermocellum. The dramatic increase in ethanol production here suggests that targeting protein post-translational modification is a promising new approach for inactivation of multiple enzymes simultaneously for metabolic engineering.

  1. Activation of farnesoid X receptor attenuates hepatic injury in a murine model of alcoholic liver disease

    SciTech Connect (OSTI)

    Wu, Weibin; Institutes of Biomedical Science, Fudan University, Shanghai 200032 ; Zhu, Bo; Peng, Xiaomin; Zhou, Meiling; Jia, Dongwei; Gu, Jianxin; Institutes of Biomedical Science, Fudan University, Shanghai 200032

    2014-01-03

    Highlights: •FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. •Activation of FXR attenuated alcohol-induced liver injury and steatosis. •Activation of FXR attenuated cholestasis and oxidative stress in mouse liver. -- Abstract: Alcoholic liver disease (ALD) is a common cause of advanced liver disease, and considered as a major risk factor of morbidity and mortality worldwide. Hepatic cholestasis is a pathophysiological feature observed in all stages of ALD. The farnesoid X receptor (FXR) is a member of the nuclear hormone receptor superfamily, and plays an essential role in the regulation of bile acid, lipid and glucose homeostasis. However, the role of FXR in the pathogenesis and progression of ALD remains largely unknown. Mice were fed Lieber-DeCarli ethanol diet or an isocaloric control diet. We used a specific agonist of FXR WAY-362450 to study the effect of pharmacological activation of FXR in alcoholic liver disease. In this study, we demonstrated that FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. Activation of FXR by specific agonist WAY-362450 protected mice from the development of ALD. We also found that WAY-362450 treatment rescued FXR activity, suppressed ethanol-induced Cyp2e1 up-regulation and attenuated oxidative stress in liver. Our results highlight a key role of FXR in the modulation of ALD development, and propose specific FXR agonists for the treatment of ALD patients.

  2. The Role of Cellulosic Ethanol in Transportation

    SciTech Connect (OSTI)

    Robert M. Neilson, Jr.

    2007-10-01

    Petroleum provides essentially all of the energy used today in the transportation sector. To reduce this dependence on fossil energy, other fuels are beginning to be used, notably ethanol and biodiesel. Almost all fuel ethanol is produced by the conversion of corn grain to starch with subsequent fermentation to ethanol. In 2006, almost 5 billion gallons of fuel ethanol were produced, which used 17% of domestic corn production. The DOE has a goal to displace 30% of motor gasoline demand or 60 billion gallons per year by 2030. To achieve this goal, production of ethanol from lignocellulosic sources (e.g., agricultural residues, forest residues, and dedicated energy crops) is needed. This paper will describe the production of cellulosic ethanol as well as the issues and benefits associated with its production.

  3. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  4. Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Infrastructure

  5. Project LIBERTY Biorefinery Starts Cellulosic Ethanol Production |

    Energy Savers [EERE]

    Department of Energy Project LIBERTY Biorefinery Starts Cellulosic Ethanol Production Project LIBERTY Biorefinery Starts Cellulosic Ethanol Production September 3, 2014 - 12:05pm Addthis News Media Contact 202-586-4940 WASHINGTON - Project LIBERTY, the nation's first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock, announced the start of production today. Once operating at full, commercial-scale, the biorefinery in Emmetsburg, Iowa will produce 25 million gallons

  6. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol BIOENERGIZEME INFOGRAPHIC CHALLENGE: Cellulosic Ethanol This infographic was created by students from Williamsburg HS for Architecture and Design in Brooklyn, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge encourages young people to improve their foundational understanding of bioenergy, which is a broad and complex topic. The ideas

  7. Louisiana: Verenium Cellulosic Ethanol Demonstration Facility | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Louisiana: Verenium Cellulosic Ethanol Demonstration Facility Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium Corporation received EERE funds to operate a 1.4 million gallon per year demonstration plant in Jennings, Louisiana, to convert agricultural residues and energy crops to cellulosic ethanol. The project's goal was to implement a technology that had been demonstrated in a laboratory at commercial scale. The plant

  8. Kinder Morgan Central Florida Pipeline Ethanol Project

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    KINDER MORGAN CENTRAL FLORIDA PIPELINE ETHANOL PROJECT ď‚· In December 2008, Kinder Morgan began transporting commercial batches of denatured ethanol along with gasoline shipments in its 16-inch Central Florida Pipeline (CFPL) from Tampa to Orlando, making CFPL the first transmarket gasoline pipeline in the United States to do so. The 16-inch pipeline previously only transported regular and premium gasoline. ď‚· Kinder Morgan invested approximately $10 million to modify the line for ethanol

  9. US Ethanol Holdings | Open Energy Information

    Open Energy Info (EERE)

    Holdings Jump to: navigation, search Name: US Ethanol Holdings Place: New York, New York Zip: 10022 Product: Subsidiary of boutique investment bank and advisory firm, Geneva...

  10. Ethanol: Producting Food, Feed, and Fuel

    Broader source: Energy.gov [DOE]

    At the August 7, 2008 joint quarterly Web conference of DOE's Biomass and Clean Cities programs, Todd Sneller (Nebraska Ethanol Board) discussed the food versus fuel issue.

  11. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, Lars G.; Carriera, Laura H.

    1983-01-01

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  12. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, L.G.; Carriera, L.H.

    1983-05-24

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  13. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  14. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  15. Algenol Announces Commercial Algal Ethanol Fuel Partnership ...

    Energy Savers [EERE]

    This funding allowed Algenol to successfully scale up its production of algal biofuel from ... Ethanol Fuel Partnership Making Algal Biofuel Production More Efficient, Less Expensive ...

  16. Mixed waste paper to ethanol fuel

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  17. Mississippi Ethanol Gasification Project, Final Scientific / Technical Report

    SciTech Connect (OSTI)

    Pearson, Larry, E.

    2007-04-30

    The Mississippi Ethanol (ME) Project is a comprehensive effort to develop the conversion of biomass to ethanol utilizing a proprietary gasification reactor technology developed by Mississippi Ethanol, LLC. Tasks were split between operation of a 1/10 scale unit at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) of Mississippi State University (MSU) and the construction, development, and operation of a full scale pilot unit located at the ME facility in Winona, Mississippi. In addition to characterization of the ME reactor gasification system, other areas considered critical to the operational and economic viability of the overall ME concept were evaluated. These areas include syngas cleanup, biological conversion of syngas to alcohol, and effects of gasification scale factors. Characterization of run data from the Pre-Pilot and Pilot Units has allowed development of the factors necessary for scale-up from the small unit to the larger unit. This scale range is approximately a factor of 10. Particulate and tar sampling gave order of magnitude values for preliminary design calculations. In addition, sampling values collected downstream of the ash removal system show significant reductions in observed loadings. These loading values indicate that acceptable particulate and tar loading rates could be attained with standard equipment additions to the existing configurations. Overall operation both the Pre-Pilot and Pilot Units proceeded very well. The Pilot Unit was operated as a system, from wood receiving to gas flaring, several times and these runs were used to address possible production-scale concerns. Among these, a pressure feed system was developed to allow feed of material against gasifier system pressure with little or no purge requirements. Similarly, a water wash system, with continuous ash collection, was developed, installed, and tested. Development of a biological system for alcohol production was conducted at Mississippi State University with much progress. However, the current state of biological technology is not deemed to be ready commercially. A preliminary estimate of capital and operating costs of a 12000 gallon per day gasification/biological facility was developed for comparison purposes. In addition, during the biological organism screening and testing, some possible alternative products were identified. One such possibility is the biological production of bio-diesel. Additional research is necessary for further evaluation of all of the biological concepts.

  18. Alternative Fuels Data Center: Ethanol Benefits and Considerations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Benefits and Considerations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Benefits and Considerations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Benefits and Considerations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Benefits and Considerations on Google Bookmark Alternative Fuels Data Center: Ethanol Benefits and Considerations on Delicious Rank Alternative Fuels Data Center: Ethanol Benefits and Considerations on Digg Find More

  19. Alternative Fuels Data Center: Ethanol Laws and Incentives

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol Laws and Incentives to someone by E-mail Share Alternative Fuels Data Center: Ethanol Laws and Incentives on Facebook Tweet about Alternative Fuels Data Center: Ethanol Laws and Incentives on Twitter Bookmark Alternative Fuels Data Center: Ethanol Laws and Incentives on Google Bookmark Alternative Fuels Data Center: Ethanol Laws and Incentives on Delicious Rank Alternative Fuels Data Center:

  20. Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Flexible Fuel Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Ethanol Flexible Fuel

  1. Ethanol production using engineered mutant E. coli

    DOE Patents [OSTI]

    Ingram, Lonnie O.; Clark, David P.

    1991-01-01

    The subject invention concerns novel means and materials for producing ethanol as a fermentation product. Mutant E. coli are transformed with a gene coding for pyruvate decarboxylase activity. The resulting system is capable of producing relatively large amounts of ethanol from a variety of biomass sources.

  2. DuPont Cellulosic Ethanol Biorefinery Opening

    Broader source: Energy.gov [DOE]

    The DuPont cellulosic ethanol facility, opening in Nevada, Iowa, on October 30, will be the largest cellulosic ethanol plant in the world. The U.S. Department of Energy Bioenergy Technologies Office Director, Jonathan Male, alongside senior government officials, DuPont leaders and staff, and local farmers will attend the grand opening ceremony and plant tour.

  3. Outlook for Biomass Ethanol Production and Demand

    Reports and Publications (EIA)

    2000-01-01

    This paper presents a midterm forecast for biomass ethanol production under three different technology cases for the period 2000 to 2020, based on projections developed from the Energy Information Administration's National Energy Modeling System. An overview of cellulose conversion technology and various feedstock options and a brief history of ethanol usage in the United States are also presented.

  4. Experiences from Ethanol Buses and Fuel Station Report - Nanyang...

    Open Energy Info (EERE)

    Nanyang Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Ethanol Buses and Fuel Station Report - Nanyang AgencyCompany Organization: BioEthanol for...

  5. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B:...

  6. Henan Tianguan Fuel Ethanol Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Tianguan Fuel Ethanol Co Ltd Jump to: navigation, search Name: Henan Tianguan Fuel Ethanol Co Ltd Place: Nanyang, Henan Province, China Product: Project developer of a bioethanol...

  7. Biochemical Production of Ethanol from Corn Stover: 2007 State...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model An update to...

  8. Utica Energy LLC formerly Algoma Ethanol | Open Energy Information

    Open Energy Info (EERE)

    Utica Energy LLC formerly Algoma Ethanol Jump to: navigation, search Name: Utica Energy LLC (formerly Algoma Ethanol) Place: Oshkosh, Wisconsin Product: Utica Energy, founded by 5...

  9. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery Groundbreaking Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery...

  10. Levelland Hockley County Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Levelland Hockley County Ethanol LLC Jump to: navigation, search Name: LevellandHockley County Ethanol LLC Place: Levelland, Texas Zip: 79336 Product: LevellandHockley County...

  11. Ethanol Oil Recovery Systems EORS | Open Energy Information

    Open Energy Info (EERE)

    Systems EORS Jump to: navigation, search Name: Ethanol Oil Recovery Systems (EORS) Place: Clayton, Georgia Product: Ethanol Oil Recovery Systems (EORS), a green technology...

  12. AE Biofuels Inc formerly American Ethanol Inc | Open Energy Informatio...

    Open Energy Info (EERE)

    AE Biofuels Inc formerly American Ethanol Inc Jump to: navigation, search Name: AE Biofuels Inc. (formerly American Ethanol Inc.) Place: Cupertino, California Zip: CA 95014...

  13. Dispensing Equipment Testing With Mid-Level Ethanol/Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid The National Renewable Energy...

  14. Review of Recent Pilot Scale Cellulosic Ethanol Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Opening Plenary Session: Celebrating Successes-The...

  15. Central Minnesota Ethanol Cooperative CMEC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol Cooperative CMEC Jump to: navigation, search Name: Central Minnesota Ethanol Cooperative (CMEC) Place: Minnesota Zip: 56345 Sector: Hydro Product: CMEC produces 200 proof...

  16. Experiences from Ethanol Buses and Fuel Station Report - La Spezia...

    Open Energy Info (EERE)

    Experiences from Ethanol Buses and Fuel Station Report - La Spezia Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Experiences from Ethanol Buses and Fuel Station Report...

  17. Green Renewable Energy Ethanol and Nutrition Holding LLC | Open...

    Open Energy Info (EERE)

    Ethanol and Nutrition Holding LLC Jump to: navigation, search Name: Green Renewable Energy Ethanol and Nutrition-Holding, LLC Place: Palm, Pennsylvania Zip: 18070 Product: A local...

  18. Pacific Ethanol Inc formerly Accessity Corporation | Open Energy...

    Open Energy Info (EERE)

    Ethanol Inc formerly Accessity Corporation Jump to: navigation, search Name: Pacific Ethanol Inc (formerly Accessity Corporation) Place: Fresno, California Zip: 93711 Product:...

  19. Report to Congress: Dedicated Ethanol Pipeline Feasability Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report to Congress: Dedicated Ethanol Pipeline Feasability Study - Energy Independence and Security Act of 2007 Section 243 Report to Congress: Dedicated Ethanol Pipeline...

  20. Belize-OAS Cellulosic Ethanol Market Assessment | Open Energy...

    Open Energy Info (EERE)

    OAS Cellulosic Ethanol Market Assessment Jump to: navigation, search Name Belize-OAS Cellulosic Ethanol Market Assessment AgencyCompany Organization Organization of American...

  1. Gateway Ethanol LLC formerly Wildcat Bio Energy LLC | Open Energy...

    Open Energy Info (EERE)

    Ethanol LLC formerly Wildcat Bio Energy LLC Jump to: navigation, search Name: Gateway Ethanol LLC (formerly Wildcat Bio-Energy LLC) Place: Pratt, Kansas Zip: 67124 Product:...

  2. Infrastructure Requirements for an Expanded Fuel Ethanol Industry

    SciTech Connect (OSTI)

    Reynolds, Robert E.

    2002-01-15

    This report provides technical information specifically related to ethanol transportation, distribution, and marketing issues. This report required analysis of the infrastructure requirements for an expanded ethanol industry.

  3. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  4. Biofuel alternatives to ethanol: pumping the microbial well ...

    Office of Scientific and Technical Information (OSTI)

    Biofuel alternatives to ethanol: pumping the microbial well Citation Details In-Document Search Title: Biofuel alternatives to ethanol: pumping the microbial well Engineered ...

  5. Genes and Mechanisms for Improving Cellulosic Ethanol Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fuels and chemicals faster and cheaper is vital for biofuel and biorefining applications. ... biomass, and ethanol tolerance is important for the production of ethanol as a biofuel. ...

  6. Reaction Rates and Catalysts in Ethanol Production (1 Activity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reaction Rates and Catalysts in Ethanol Production (1 Activity) Reaction Rates and Catalysts in Ethanol Production (1 Activity) Below is information about the student activity...

  7. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  8. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution.

  9. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution. (Refs. 6).

  10. Fermentative alcohol production

    DOE Patents [OSTI]

    Wilke, Charles R. (El Cerrito, CA); Maiorella, Brian L. (Berkeley, CA); Blanch, Harvey W. (Berkeley, CA); Cysewski, Gerald R. (Kennewick, WA)

    1982-01-01

    An improved fermentation process for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using "water load balancing" (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  11. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, P.T.

    1996-09-24

    A process is provided for the production of branched C{sub x} oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  12. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, Paul T. (Arlington Heights, IL)

    1996-01-01

    A process is provided for the production of branched C.sub.4+ oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  13. Alcoholes Biocarburantes de Extremadura Albiex | Open Energy...

    Open Energy Info (EERE)

    search Name: Alcoholes Biocarburantes de Extremadura (Albiex) Place: Spain Product: Spanish bioethanol producer building a plant in Extremadura. References: Alcoholes...

  14. Actual versus predicted impacts of three ethanol plants on aquatic and terrestrial resources

    SciTech Connect (OSTI)

    Eddlemon, G.K.; Webb, J.W.; Hunsaker, D.B. Jr.; Miller, R.L.

    1993-03-15

    To help reduce US dependence on imported petroleum, Congress passed the Energy Security Act of 1980 (public Law 96-294). This legislation authorized the US Department of Energy (DOE) to promote expansion of the fuel alcohol industry through, among other measures, its Alcohol Fuels Loan Guarantee Program. Under this program, selected proposals for the conversion of plant biomass into fuel-grade ethanol would be granted loan guarantees. of 57 applications submitted for loan guarantees to build and operate ethanol fuel projects under this program, 11 were considered by DOE to have the greatest potential for satisfying DOE`s requirements and goals. In accordance with the National Environmental Policy Act (NEPA), DOE evaluated the potential impacts of proceeding with the Loan Guarantee Program in a programmatic environmental assessment (DOE 1981) that resulted in a finding of no significant impact (FANCY) (47 Federal Register 34, p. 7483). The following year, DOE conducted site-specific environmental assessments (EAs) for 10 of the proposed projects. These F-As predicted no significant environmental impacts from these projects. Eventually, three ethanol fuel projects received loan guarantees and were actually built: the Tennol Energy Company (Tennol; DOE 1982a) facility near Jasper in southeastern Tennessee; the Agrifuels Refining Corporation (Agrifuels; DOE 1985) facility near New Liberia in southern Louisiana; and the New Energy Company of Indiana (NECI; DOE 1982b) facility in South Bend, Indiana. As part of a larger retrospective examination of a wide range of environmental effects of ethanol fuel plants, we compared the actual effects of the three completed plants on aquatic and terrestrial resources with the effects predicted in the NEPA EAs several years earlier. A secondary purpose was to determine: Why were there differences, if any, between actual effects and predictions? How can assessments be improved and impacts reduced?

  15. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T.

    2011-08-01

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

  16. Environmental analysis of biomass-ethanol facilities

    SciTech Connect (OSTI)

    Corbus, D.; Putsche, V.

    1995-12-01

    This report analyzes the environmental regulatory requirements for several process configurations of a biomass-to-ethanol facility. It also evaluates the impact of two feedstocks (municipal solid waste [MSW] and agricultural residues) and three facility sizes (1000, 2000, and 3000 dry tons per day [dtpd]) on the environmental requirements. The basic biomass ethanol process has five major steps: (1) Milling, (2) Pretreatment, (3) Cofermentation, (4) Enzyme production, (5) Product recovery. Each step could have environmental impacts and thus be subject to regulation. Facilities that process 2000 dtpd of MSW or agricultural residues would produce 69 and 79 million gallons of ethanol, respectively.

  17. Structure and thermodynamics of core-softened models for alcohols

    SciTech Connect (OSTI)

    Munaň, Gianmarco; Urbic, Tomaz

    2015-06-07

    The phase behavior and the fluid structure of coarse-grain models for alcohols are studied by means of reference interaction site model (RISM) theory and Monte Carlo simulations. Specifically, we model ethanol and 1-propanol as linear rigid chains constituted by three (trimers) and four (tetramers) partially fused spheres, respectively. Thermodynamic properties of these models are examined in the RISM context, by employing closed formulć for the calculation of free energy and pressure. Gas-liquid coexistence curves for trimers and tetramers are reported and compared with already existing data for a dimer model of methanol. Critical temperatures slightly increase with the number of CH{sub 2} groups in the chain, while critical pressures and densities decrease. Such a behavior qualitatively reproduces the trend observed in experiments on methanol, ethanol, and 1-propanol and suggests that our coarse-grain models, despite their simplicity, can reproduce the essential features of the phase behavior of such alcohols. The fluid structure of these models is investigated by computing radial distribution function g{sub ij}(r) and static structure factor S{sub ij}(k); the latter shows the presence of a low?k peak at intermediate-high packing fractions and low temperatures, suggesting the presence of aggregates for both trimers and tetramers.

  18. Ethanol Production, Distribution, and Use: Discussions on Key Issues (Presentation)

    SciTech Connect (OSTI)

    Harrow, G.

    2008-05-14

    From production to the environment, presentation discusses issues surrounding ethanol as a transportation fuel.

  19. Ethanol Pathways in the 2050 North American Transportation Futures Study

    SciTech Connect (OSTI)

    2009-01-18

    A paper discussing the various ethanol pathways in the 2050 North American Transportation Futures Study

  20. Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Safety Testing Underwriters Laboratories Ethanol Dispenser Safety Testing to someone by E-mail Share Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Facebook Tweet about Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Twitter Bookmark Alternative Fuels Data Center: Underwriters Laboratories Ethanol Dispenser Safety Testing on Google Bookmark Alternative Fuels Data Center: Underwriters Laboratories

  1. Hepatic lipid profiling of deer mice fed ethanol using {sup 1}H and {sup 31}P NMR spectroscopy: A dose-dependent subchronic study

    SciTech Connect (OSTI)

    Fernando, Harshica; Bhopale, Kamlesh K.; Boor, Paul J.; Ansari, G.A. Shakeel; Kaphalia, Bhupendra S.

    2012-11-01

    Chronic alcohol abuse is a 2nd major cause of liver disease resulting in significant morbidity and mortality. Alcoholic liver disease (ALD) is characterized by a wide spectrum of pathologies starting from fat accumulation (steatosis) in early reversible stage to inflammation with or without fibrosis and cirrhosis in later irreversible stages. Previously, we reported significant steatosis in the livers of hepatic alcohol dehydrogenase (ADH)-deficient (ADH{sup ?}) vs. hepatic ADH-normal (ADH{sup +}) deer mice fed 4% ethanol daily for 2 months [Bhopale et al., 2006, Alcohol 39, 179–188]. However, ADH{sup ?} deer mice fed 4% ethanol also showed a significant mortality. Therefore, a dose-dependent study was conducted to understand the mechanism and identify lipid(s) involved in the development of ethanol-induced fatty liver. ADH{sup ?} and ADH{sup +} deer mice fed 1, 2 or 3.5% ethanol daily for 2 months and fatty infiltration in the livers were evaluated by histology and by measuring dry weights of extracted lipids. Lipid metabolomic changes in extracted lipids were determined by proton ({sup 1}H) and {sup 31}phosphorus ({sup 31}P) nuclear magnetic resonance (NMR) spectroscopy. The NMR data was analyzed by hierarchical clustering (HC) and principle component analysis (PCA) for pattern recognition. Extensive vacuolization by histology and significantly increased dry weights of total lipids found only in the livers of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls suggest a dose-dependent formation of fatty liver in ADH{sup ?} deer mouse model. Analysis of NMR data of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls shows increases for total cholesterol, esterified cholesterol, fatty acid methyl esters (FAMEs), triacylglycerides and unsaturation, and decreases for free cholesterol, phospholipids and allylic and diallylic protons. Certain classes of neutral lipids (cholesterol esters, fatty acyl chain (-COCH{sub 2}-) and FAMEs) were also mildly increased in ADH{sup ?} deer mice fed 1 or 2% ethanol. Only small increases were observed for allylic and diallylic protons, FAMEs and unsaturations in ADH{sup +} deer mice fed 3.5% ethanol vs. pair-fed controls. PCA of NMR data showed increased clustering by gradual separation of ethanol-fed ADH{sup ?} deer mice groups from their respective pair-fed control groups and corresponding ethanol-fed ADH{sup +} deer mice groups. Our data indicate that dose of ethanol and hepatic ADH deficiency are two key factors involved in initiation and progression of alcoholic fatty liver disease. Further studies on characterization of individual lipid entities and associated metabolic pathways altered in our deer mouse model after different durations of ethanol feeding could be important to delineate mechanism(s) and identify potential biomarker candidate(s) of early stage ALD. -- Highlights: ? Dose-dependent ethanol-induced fatty liver was studied in deer mouse model. ? A NMR-based lipidomic approach with histology and dry lipid weights was used. ? We used principal component analysis (PCA) to analyze the NMR lipidomic data. ? Dose-dependent clustering patterns by PCA were compared among the groups.

  2. Structural and phase transition changes of sodium dodecyl sulfate micellar solution in alcohols probed by small-angle neutron scattering (SANS)

    SciTech Connect (OSTI)

    Putra, Edy Giri Rachman; Patriati, Arum

    2015-04-16

    Small-angle neutron scattering (SANS) measurements on 0.3M sodium dodecyl sulfate (SDS) micellar solutions have been performed in the presence of n-alcohols, from ethanol to decanol at different alcohol concentrations, 2–10 wt%. The ellipsoid micellar structure which occurred in the 0.3M SDS in aqueous solution with the size range of 30–50 Ĺ has different behavior at various hydrocarbon chain length and concentration of alcohols. At low concentration and short chain-length of alcohols, such as ethanol, propanol, and butanol, the size of micelles reduced and had a spherical-like structure. The opposite effect occurred as medium to long chain alcohols, such as hexanol, octanol and decanol was added into the 0.3M SDS micellar solutions. The micelles structure changed to be more elongated in major axis and then crossed the critical phase transition from micellar solution into liquid crystal phase as lamellar structure emerged by further addition of alcohols. The inter-lamellar distances were also depending on the hydrocarbon chain length and concentration of alcohols. In the meantime, the persistent micellar structures occurred in addition of medium chain of n-alcohol, pentanol at all concentrations.

  3. Sterling Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    Ethanol LLC Place: Colorado Product: Owned by local investors including farmers, ranchers and business people that primarily reside in north-west Colorado, and set up to build and...

  4. QER- Comment of ND Ethanol Council

    Broader source: Energy.gov [DOE]

    To whom it may concern, Attached please find comments from the North Dakota Ethanol Council regarding infrastructure constraints in preparation for the OER Public Meeting, which will be held in Bismarck, N.D., on August 8. Sincerely, Deana Wies

  5. Treatment of biomass to obtain ethanol

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Elander, Richard T. (Evergreen, CO); Tucker, III, Melvin P. (Lakewood, CO); Hennessey, Susan Marie (Avondale, PA)

    2011-08-16

    Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  6. Guide to commercial-scale ethanol production and financing

    SciTech Connect (OSTI)

    1980-11-01

    This document is designed to lead the potential investor through all the steps necessary to develop a business plan and prepare a feasibility analysis for a site-specific project. Emphasis is placed on marketing, financing, management, and incentives rather than primarily technical matters. The introduction provides an overview of the perspectives and issues in the alcohol fuels industry. Chapter II seeks to surface factors which affect the decisionmaking process. The chapter attempts to lead the investor step-by-step through the series of decisions and choices to be made before reaching the final decision to enter the business. Chapter III describes the types of feedstocks available and relates them to areas within the United States. Trends and fluctuations in the price of the major grain feedstocks are also discussed in terms of their potential use and value compared to other feeds. Chapter IV discusses the market potential of ethanol and its coproducts, and examines how the location of the ethanol markets in relation to those of the feedstock supplies may influence selection of a plant site. Various aspects of plant design are discussed. A 50 million gallon per year plant is analyzed to provide the general technical background and costing data required in analyzing plants of various sizes and designs. Safety aspects and environmental concerns are treated in Chapters VI and VII. The regulations are reviewed and their impact on plant design and operation is discussed. The basic elements of a business plan are described which lead to an approach for development of the feasibility study. Other information on financial assistance, regulations, current legislation, and reference material is given in the Appendices.

  7. Mid-Level Ethanol Blends Test Program | Department of Energy

    Office of Environmental Management (EM)

    Mid-Level Ethanol Blends Test Program Mid-Level Ethanol Blends Test Program 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft005_west_2010_o.pdf More Documents & Publications Mid-Level Ethanol Blends Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Â… Updated Feb 2009 EffectsIntermediateEthanolBlends.pdf

  8. Alternative Fuels Data Center: Ethanol Fueling Station Locations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Station Locations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Station Locations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Station Locations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Station Locations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Station Locations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Station Locations on Digg Find More places to share Alternative

  9. Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol to someone by E-mail Share Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Facebook Tweet about Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Twitter Bookmark Alternative Fuels Data Center: Federal Laws and Incentives for Ethanol on Google Bookmark Alternative Fuels Data Center: Federal Laws and Incentives for

  10. High Speed/ Low Effluent Process for Ethanol

    SciTech Connect (OSTI)

    M. Clark Dale

    2006-10-30

    n this project, BPI demonstrated a new ethanol fermentation technology, termed the High Speed/ Low Effluent (HS/LE) process on both lab and large pilot scale as it would apply to wet mill and/or dry mill corn ethanol production. The HS/LE process allows very rapid fermentations, with 18 to 22% sugar syrups converted to 9 to 11% ethanol ‘beers’ in 6 to 12 hours using either a ‘consecutive batch’ or ‘continuous cascade’ implementation. This represents a 5 to 8X increase in fermentation speeds over conventional 72 hour batch fermentations which are the norm in the fuel ethanol industry today. The ‘consecutive batch’ technology was demonstrated on a large pilot scale (4,800 L) in a dry mill corn ethanol plant near Cedar Rapids, IA (Xethanol Biofuels). The pilot demonstrated that 12 hour fermentations can be accomplished on an industrial scale in a non-sterile industrial environment. Other objectives met in this project included development of a Low Energy (LE) Distillation process which reduces the energy requirements for distillation from about 14,000 BTU/gal steam ($0.126/gal with natural gas @ $9.00 MCF) to as low as 0.40 KW/gal electrical requirements ($0.022/gal with electricity @ $0.055/KWH). BPI also worked on the development of processes that would allow application of the HS/LE fermentation process to dry mill ethanol plants. A High-Value Corn ethanol plant concept was developed to produce 1) corn germ/oil, 2) corn bran, 3) ethanol, 4) zein protein, and 5) nutritional protein, giving multiple higher value products from the incoming corn stream.

  11. Role of water activity in ethanol fermentations

    SciTech Connect (OSTI)

    Jones, R.P.; Greenfield, P.F.

    1986-01-01

    A separate role for water activity in the conversion of sugars to ethanol by two strains of yeast is identified. During fermentation of both single and mixed sugar substrates, the water activity was shown to remain constant during the logarithmic growth phase. This is despite the changes in concentration of substrates and production, the constancy reflecting the fact that the greater influence of ethanol on the solution activity is counterbalanced, in the early stages of the fermentation, by its low yield. The end of the log phase of growth coincides with the start of a period of gradually decreasing water activity. For the more ethanol-tolerant strain UQM66Y, growth was found to cease at a constant value of water activity while that for the less tolerant strain UQM70Y depended on both ethanol concentration and water activity. It is argued that water activity is a more appropriate variable than ethanol concentration for describing some of the nonspecific inhibitory effects apparent in ethanol fermentations. A straightforward method for the calculation of water activity during such fermentations based on the use of solution osmolarity is presented.

  12. Hydrogen Atom Reactivity toward Aqueous tert-Butyl Alcohol

    SciTech Connect (OSTI)

    Lymar S. V.; Schwarz, H.A.

    2012-02-09

    Through a combination of pulse radiolysis, purification, and analysis techniques, the rate constant for the H + (CH{sub 3}){sub 3}COH {yields} H{sub 2} + {sm_bullet}CH{sub 2}C(CH{sub 3}){sub 2}OH reaction in aqueous solution is definitively determined to be (1.0 {+-} 0.15) x 10{sup 5} M{sup -1} s{sup -1}, which is about half of the tabulated number and 10 times lower than the more recently suggested revision. Our value fits on the Polanyi-type, rate-enthalpy linear correlation ln(k/n) = (0.80 {+-} 0.05){Delta}H + (3.2 {+-} 0.8) that is found for the analogous reactions of other aqueous aliphatic alcohols with n equivalent abstractable H atoms. The existence of such a correlation and its large slope are interpreted as an indication of the mechanistic similarity of the H atom abstraction from {alpha}- and {beta}-carbon atoms in alcohols occurring through the late, product-like transition state. tert-Butyl alcohol is commonly contaminated by much more reactive secondary and primary alcohols (2-propanol, 2-butanol, ethanol, and methanol), whose content can be sufficient for nearly quantitative scavenging of the H atoms, skewing the H atom reactivity pattern, and explaining the disparity of the literature data on the H + (CH{sub 3}){sub 3}COH rate constant. The ubiquitous use of tert-butyl alcohol in pulse radiolysis for investigating H atom reactivity and the results of this work suggest that many other previously reported rate constants for the H atom, particularly the smaller ones, may be in jeopardy.

  13. Fuel alcohol opportunities for Indiana

    SciTech Connect (OSTI)

    Greenglass, Bert

    1980-08-01

    Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

  14. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, Charles S. [Ames, IA; Chriswell, Colin D. [Slater, IA

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%.

  15. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, C.S.; Chriswell, C.D.

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%. 5 figs.

  16. A comparative experimental and computational study of methanol, ethanol, and n-butanol flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N.; Westbrook, Charles K.

    2010-10-15

    Laminar flame speeds and extinction strain rates of premixed methanol, ethanol, and n-butanol flames were determined experimentally in the counterflow configuration at atmospheric pressure and elevated unburned mixture temperatures. Additional measurements were conducted also to determine the laminar flame speeds of their n-alkane/air counterparts, namely methane, ethane, and n-butane in order to compare the effect of alkane and alcohol molecular structures on high-temperature flame kinetics. For both propagation and extinction experiments the flow velocities were determined using the digital particle image velocimetry method. Laminar flame speeds were derived through a non-linear extrapolation approach based on direct numerical simulations of the experiments. Two recently developed detailed kinetics models of n-butanol oxidation were used to simulate the experiments. The experimental results revealed that laminar flame speeds of ethanol/air and n-butanol/air flames are similar to those of their n-alkane/air counterparts, and that methane/air flames have consistently lower laminar flame speeds than methanol/air flames. The laminar flame speeds of methanol/air flames are considerably higher compared to both ethanol/air and n-butanol/air flames under fuel-rich conditions. Numerical simulations of n-butanol/air freely propagating flames, revealed discrepancies between the two kinetic models regarding the consumption pathways of n-butanol and its intermediates. (author)

  17. Largest Cellulosic Ethanol Plant in the World Opened in October |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Largest Cellulosic Ethanol Plant in the World Opened in October Largest Cellulosic Ethanol Plant in the World Opened in October November 30, 2015 - 2:07pm Addthis The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The

  18. An Indirect Route for Ethanol Production

    SciTech Connect (OSTI)

    Eggeman, T.; Verser, D.; Weber, E.

    2005-04-29

    The ZeaChem indirect method is a radically new approach to producing fuel ethanol from renewable resources. Sugar and syngas processing platforms are combined in a novel way that allows all fractions of biomass feedstocks (e.g. carbohydrates, lignins, etc.) to contribute their energy directly into the ethanol product via fermentation and hydrogen based chemical process technologies. The goals of this project were: (1) Collect engineering data necessary for scale-up of the indirect route for ethanol production, and (2) Produce process and economic models to guide the development effort. Both goals were successfully accomplished. The projected economics of the Base Case developed in this work are comparable to today's corn based ethanol technology. Sensitivity analysis shows that significant improvements in economics for the indirect route would result if a biomass feedstock rather that starch hydrolyzate were used as the carbohydrate source. The energy ratio, defined as the ratio of green energy produced divided by the amount of fossil energy consumed, is projected to be 3.11 to 12.32 for the indirect route depending upon the details of implementation. Conventional technology has an energy ratio of 1.34, thus the indirect route will have a significant environmental advantage over today's technology. Energy savings of 7.48 trillion Btu/yr will result when 100 MMgal/yr (neat) of ethanol capacity via the indirect route is placed on-line by the year 2010.

  19. Ethanol from biomass: A status report

    SciTech Connect (OSTI)

    Walker, R.

    1996-12-31

    Programmatic and technical activities of SWAN Biomass, a company formed by Amoco Corporation and Stone & Webster, to convert non-grain biomass material to ethanol, are highlighted in this presentation. The potential ethanol markets identified are: (1) fuel oxygenate and octane additive, and (2) waste reduction in the agricultural and forestry industries and in municipal waste streams. Differences in the SWAN process from that used in corn-based ethanol facilities include more intense pretreatment of lignocellulosic biomass, different enzymes, hydrolysis and fermentation of sugar polymers is performed in the same vessel, and a typical solid residue of lignin. The major market and technical risks have been assessed as being manageable. 8 figs., 8 tabs.

  20. Coupling of alcohols to ethers: The dominance of the surface S{sub N}2 reaction pathway

    SciTech Connect (OSTI)

    Klier, K.; Feeley, O.C.; Johansson, M.; Herman, R.G.

    1996-12-31

    Coupling of alcohols to ethers, important high value oxygenates, proceeds on acid catalysts via general pathways that uniquely control product composition, oxygen retention, chirality inversion, and kinetics. The dominant pathway is the S{sub N}2 reaction with competition of the alcohols for the surface acid sites. This is exemplified by formation of methyl(ethyl) isobutylether (M(E)IBE) from methanol(ethanol)/isobutanol mixtures, retention of oxygen ({sup 18}O) of the heavier alcohol, and optimum rate as a function of concentration of either reactant alcohol. The S{sub N}2 pathway in the confinement of zeolite pores exhibits additional features of a near-100% selectivity to dimethylether (DME) in H-mordenite and a near-100% selectivity to chiral inversion in 2-pentanol/ethanol coupling to 2-ethoxypentane in HZSM-5. A minor reaction pathway entails olefin or carbenium intermediates, as exemplified by the formation of methyl tertiarybutyl ether (MTBE) from methanol/isobutanol mixtures with oxygen retention of the lighter alcohol. Calculations of transition state and molecular modeling of the oxonium-involving pathways dramatically demonstrate how the reaction path selects the products.

  1. Chippewa Valley Ethanol Company CVEC | Open Energy Information

    Open Energy Info (EERE)

    CVEC Jump to: navigation, search Name: Chippewa Valley Ethanol Company (CVEC) Place: NW Benson, Minnesota Zip: 56215 Product: Owns 57.0m litres a year dry mill ethanol plant....

  2. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Broader source: Energy.gov (indexed) [DOE]

    Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009...

  3. State-level workshops on ethanol for transportaton

    SciTech Connect (OSTI)

    Graf, Angela

    2004-01-01

    The Ethanol Workshop Series (EWS) was intended to provide a forum for interest groups to gather and discuss what needs to be accomplished to facilitate ethanol production in-state using local biomass resources.

  4. Research Advances Cellulosic Ethanol, NREL Leads the Way (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2007-03-01

    This brochure highlights NREL's recent advances in cellulosic ethanol production. Research at NREL addresses both biochemical and thermochemical processes.

  5. Ethanol Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01

    This document lists codes and standards typically used for U.S. ethanol vehicle and infrastructure projects.

  6. Fact Sheet: Effects of Intermediate Ethanol Blends | Department of Energy

    Energy Savers [EERE]

    Effects of Intermediate Ethanol Blends Fact Sheet: Effects of Intermediate Ethanol Blends October 7, 2008 - 4:14pm Addthis In August 2007, the U.S. Department of Energy (DOE) initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program focuses specifically on the effects of intermediate blends of E15 and E20-gasoline blended with 15 and 20 percent ethanol, respectively-on

  7. Mid-Level Ethanol Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Mid-Level Ethanol Blends 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_05_knoll.pdf More Documents & Publications Mid-Level Ethanol Blends Test Program Biofuels Quality Surveys Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Â… Updated Feb 2009

  8. Renewable Fuels Association’s National Ethanol Conference

    Broader source: Energy.gov [DOE]

    Mark Elless, a BETO technology manager, will be representing BETO at the 20th anniversary of the National Ethanol Conference.

  9. Clean Cities: Ethanol Basics, Fact Sheet, October 2008

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    Document answers frequently asked questions about ethanol as a transportation fuel, including those on production, environmental effects, and vehicles.

  10. Alternative Fuels Data Center: Pennsylvania's Ethanol Corridor Project

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Surpasses 1 Million Gallons Pennsylvania's Ethanol Corridor Project Surpasses 1 Million Gallons to someone by E-mail Share Alternative Fuels Data Center: Pennsylvania's Ethanol Corridor Project Surpasses 1 Million Gallons on Facebook Tweet about Alternative Fuels Data Center: Pennsylvania's Ethanol Corridor Project Surpasses 1 Million Gallons on Twitter Bookmark Alternative Fuels Data Center: Pennsylvania's Ethanol Corridor Project Surpasses 1 Million Gallons on Google Bookmark Alternative

  11. Alternative Fuels Data Center: Status Update: Ethanol Blender Pump

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Dispenser Certified (August 2010) Ethanol Blender Pump Dispenser Certified (August 2010) to someone by E-mail Share Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Facebook Tweet about Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Twitter Bookmark Alternative Fuels Data Center: Status Update: Ethanol Blender Pump Dispenser Certified (August 2010) on Google Bookmark Alternative

  12. EA-1694: Department of Energy Loan Guarantee to Highlands Ethanol, LLC, for the Cellulosic Ethanol Facility in Highlands County, Florida

    Office of Energy Efficiency and Renewable Energy (EERE)

    This EA will evaluate the environmental impacts of a proposal to issue a Federal loan guarantee to Highlands Ethanol, LLC, for a cellulosic ethanol facility in Highlands County, Florida. This EA is on hold.

  13. Palladium nanoparticles anchored on graphene nanosheets: Methanol, ethanol oxidation reactions and their kinetic studies

    SciTech Connect (OSTI)

    Nagaraju, D.H.; Devaraj, S.; Balaya, P.

    2014-12-15

    Highlights: • Palladium nanoparticles decorated graphene is synthesized in a single step. • Electro-catalytic activity of Gra/Pd toward alcohol oxidation is evaluated. • 1:1 Gra/Pd exhibits good electro-catalytic activity and efficient electron transfer. - Abstract: Palladium nanoparticles decorated graphene (Gra/Pd nanocomposite) was synthesized by simultaneous chemical reduction of graphene oxide and palladium salt in a single step. The negatively charged graphene oxide (GO) facilitates uniform distribution of Pd{sup 2+} ions onto its surface. The subsequent reduction by hydrazine hydrate provides well dispersed Pd nanoparticles decorated graphene. Different amount of Pd nanoparticles on graphene was synthesized by changing the volume to weight ratio of GO to PdCl{sub 2}. X-ray diffraction studies showed FCC lattice of Pd with predominant (1 1 1) plane. SEM and TEM studies revealed that thin graphene nanosheets are decorated by Pd nanoparticles. Raman spectroscopic studies revealed the presence of graphene nanosheets. The electro-catalytic activity of Gra/Pd nanocomposites toward methanol and ethanol oxidation in alkaline medium was evaluated by cyclic voltammetric studies. 1:1 Gra/Pd nanocomposite exhibited good electro-catalytic activity and efficient electron transfer. The kinetics of electron transfer was studied using chronoamperometry. Improved electro-catalytic activity of 1:1 Gra/Pd nanocomposite toward alcohol oxidation makes it as a potential anode for the alcohol fuel cells.

  14. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  15. NREL Proves Cellulosic Ethanol Can Be Cost Competitive (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    Ethanol from non-food sources - known as "cellulosic ethanol" - is a near-perfect transportation fuel: it is clean, domestic, abundant, and renewable, and it can potentially replace 30% of the petroleum consumed in the United States, but its relatively high cost has limited its market. That changed in 2012, when the National Renewable Energy Laboratory (NREL) demonstrated the technical advances needed to produce cellulosic ethanol at a minimum ethanol selling price of $2.15/gallon (in 2007 dollars). Through a multi-year research project involving private industry, NREL has proven that cellulosic ethanol can be cost competitive with other transportation fuels.

  16. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  17. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  18. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  19. Ethanol extraction of phytosterols from corn fiber

    DOE Patents [OSTI]

    Abbas, Charles (Champaign, IL); Beery, Kyle E. (Decatur, IL); Binder, Thomas P. (Decatur, IL); Rammelsberg, Anne M. (Decatur, IL)

    2010-11-16

    The present invention provides a process for extracting sterols from a high solids, thermochemically hydrolyzed corn fiber using ethanol as the extractant. The process includes obtaining a corn fiber slurry having a moisture content from about 20 weight percent to about 50 weight percent solids (high solids content), thermochemically processing the corn fiber slurry having high solids content of 20 to 50% to produce a hydrolyzed corn fiber slurry, dewatering the hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, washing the residual corn fiber, dewatering the washed, hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, and extracting the residual corn fiber with ethanol and separating at least one sterol.

  20. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  1. Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

    SciTech Connect (OSTI)

    James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

    2011-07-29

    The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing at realistic conditions (e.g., elevated pressures) and differential conversions (to measure true kinetics, to avoid deactivation, and to avoid condensable concentrations of products in the outlet gas).

  2. Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beste, Ariana; Overbury, Steven

    2015-01-01

    We have performed computations to better understand how surface structure affects selectivity in dehydrogenation and dehydration reactions of alcohols. Ethanol reactions on the (111) and (100) ceria surfaces were studied starting from the dominant surface species, ethoxy. We used DFT (PBE+U) to explore reaction pathways leading to ethylene and acetaldehyde and calculated estimates of rate constants employing transition state theory. To assess pathway contributions, we carried out kinetic analysis. Our results show that intermediate and transition state structures are stabilized on the (100) surface compared to the (111) surface. Formation of acetaldehyde over ethylene is kinetically and thermodynamically preferred onmore » both surfaces. Our results are consistent with temperature programmed surface reaction and steady-state experiments, where acetaldehyde was found as the main product and evidence was presented that ethylene formation at higher temperature originates from changes in adsorbate and surface structure.« less

  3. Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces

    SciTech Connect (OSTI)

    Beste, Ariana; Overbury, Steven {Steve} H

    2015-01-01

    We have performed computations to better understand how surface structure affects selectivity in dehydrogenation and dehydration reactions of alcohols. Ethanol reactions on the (111) and (100) ceria surfaces were studied starting from the dominant surface species, ethoxy. We used DFT (PBE+U) to explore reaction pathways leading to ethylene and acetaldehyde and calculated estimates of rate constants employing transition state theory. To assess pathway contributions, we carried out kinetic analysis. Our results show that intermediate and transition state structures are stabilized on the (100) surface compared to the (111) surface. Formation of acetaldehyde over ethylene is kinetically and thermodynamically preferred on both surfaces. Our results are consistent with temperature programmed surface reaction and steady-state experiments, where acetaldehyde was found as the main product and evidence was presented that ethylene formation at higher temperature originates from changes in adsorbate and surface structure.

  4. Pathway engineering to improve ethanol production by thermophilic bacteria

    SciTech Connect (OSTI)

    Lynd, L.R.

    1998-12-31

    Continuation of a research project jointly funded by the NSF and DOE is proposed. The primary project goal is to develop and characterize strains of C. thermocellum and C. thermosaccharolyticum having ethanol selectivity similar to more convenient ethanol-producing organisms. An additional goal is to document the maximum concentration of ethanol that can be produced by thermophiles. These goals build on results from the previous project, including development of most of the genetic tools required for pathway engineering in the target organisms. As well, we demonstrated that the tolerance of C. thermosaccharolyticum to added ethanol is sufficiently high to allow practical utilization should similar tolerance to produced ethanol be demonstrated, and that inhibition by neutralizing agents may explain the limited concentrations of ethanol produced in studies to date. Task 1 involves optimization of electrotransformation, using either modified conditions or alternative plasmids to improve upon the low but reproducible transformation, frequencies we have obtained thus far.

  5. Recovery of anhydrous hydrogen iodide

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); McCorkle, Jr., Kenneth H. (Del Mar, CA); de Graaf, Johannes D. (The Hague, NL)

    1982-01-01

    Relatively dry hydrogen iodide can be recovered from a mixture of HI, I.sub.2 and H.sub.2 O. After the composition of the mixture is adjusted so that the amounts of H.sub.2 O and I.sub.2 do not exceed certain maximum limits, subjection of the mixture to superatmospheric pressure in an amount equal to about the vapor pressure of HI at the temperature in question causes distinct liquid phases to appear. One of the liquid phases contains HI and not more than about 1 weight percent water. Often the adjustment in the composition will include the step of vaporization, and the distinct layers appear following the increase in pressure of the vapor mixture. Adjustment in the composition may also include the addition of an extraction agent, such as H.sub.3 PO.sub.4, and even though the adjusted composition mixture contains a significant amount of such an agent, the creation of the distinct liquid phases is not adversely affected.

  6. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore » its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  7. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  8. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biorefinery Groundbreaking | Department of Energy Touts Importance of Cellulosic Ethanol at Georgia Biorefinery Groundbreaking Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery Groundbreaking October 6, 2007 - 4:21pm Addthis SOPERTON, GA - U.S. Secretary of Energy Samuel W. Bodman today attended a groundbreaking ceremony for Range Fuels' biorefinery - one of the nation's first commercial-scale cellulosic ethanol biorefineries - and made the following statement.

  9. Dissociative electron attachments to ethanol and acetaldehyde: A combined

    Office of Scientific and Technical Information (OSTI)

    experimental and simulation study (Journal Article) | SciTech Connect Dissociative electron attachments to ethanol and acetaldehyde: A combined experimental and simulation study Citation Details In-Document Search Title: Dissociative electron attachments to ethanol and acetaldehyde: A combined experimental and simulation study Dissociation dynamics of the temporary negative ions of ethanol and acetaldehyde formed by the low-energy electron attachments is investigated by using the anion

  10. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-04-01

    A number of different yeasts are now recognized as being capable of fermenting the pentose sugar, D-xylose, into ethanol. The most prominent among these are Pachysolen tannophilus and several Candida species. D-Xylose is found principally in lignocellulosic materials where it occurs as the main constitutent of the hemicellulosic xylans (1,4-..beta..-D-heteroxylans). With the exception of Candida XF-217, the conversion yields of xylose into ethanol for most yeasts were generally low (less than 70% of theoretical when grown on at least 50 g/l xylose). The low ethanol yields are attributable to a number of factors: 1) fermentation was not performed under conditions that maximize ethanol formation; 2) ethanol was not the major fermentation end-product, (e.g., acetic acid xylitol, and arabinitol are also known products, 3) ethanol toxicity; 4) ethanol is assimilated when the substrate becomes limiting; 4.8 and 5) osmotic sensitivity to high substrate levels, i.e. substrate inhibition. Attempts to increase ethanol yields of yeasts by adding exogenous lipids (e.g., oleic and linoleic acids, or ergosterol or its ester, lipid mixtures, or protein-lipid mixtures) to nutrient medium have succeeded in improving ethanol yields and also in reducing fermentation times. These lipids, when added to the nutrient medium, were incorporated into the yeast's cellular membrane. The protective action of these lipids was to alleviate the inhibitory effect of ethanol which then allowed the cells to tolerate higher ethanol levels. This communication reports on improved ethanol yields arising from the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. 17 references.

  11. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-01-01

    This paper reports improved ethanol yields following the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. Profiles for ethanol production from 45 g/L xylose when grown on a medium containing ergosterol, linoleic acid, Tween-80, a mixture of the three lipids and no lipids (control) are presented. The enhancement in the amount of ethanol produced was most pronounced after 72 h fermentation.

  12. Mid-Blend Ethanol Fuels - Implementation Perspectives | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Mid-Blend Ethanol Fuels - Implementation Perspectives Mid-Blend Ethanol Fuels - Implementation Perspectives Breakout Session 2: Frontiers and Horizons Session 2-B: End Use and Fuel Certification Bill Woebkenberg, Fuels Technical and Regulatory Affairs Senior Engineer, Mercedes-Benz PDF icon b13_woebkenberg_2-b.pdf More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With

  13. NOx Aftertreatment Using Ethanol as Reductant | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment Using Ethanol as Reductant NOx Aftertreatment Using Ethanol as Reductant The hydrocarbon-SCR that was developed using ethanol and E85 as the reductant showed high NOx reduction, no need for thawing, use of existing infrastructure, and reduced system cost making it a viable alternative to urea-based SCR PDF icon deer10_diewald.pdf More Documents & Publications Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future SCR-DPF Integrations

  14. The Current State of Technology for Cellulosic Ethanol | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The Current State of Technology for Cellulosic Ethanol The Current State of Technology for Cellulosic Ethanol At the February 12, 2009 joint Web conference of DOE's Biomass and Clean Cities programs, Andy Aden (National Renewable Energy Laboratory) discussed the current state of technology for cellulosic ethanol - How close are we? PDF icon aden_20090212.pdf More Documents & Publications Integrated Biorefinery Process Process Design and Economics for Biochemical Conversion of

  15. Florida Project Produces Nation's First Cellulosic Ethanol at

    Office of Environmental Management (EM)

    Commercial-Scale | Department of Energy Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale Florida Project Produces Nation's First Cellulosic Ethanol at Commercial-Scale July 31, 2013 - 1:37pm Addthis News Media Contact (202) 586-4940 WASHINGTON - The Energy Department today recognized the nation's first commercial-scale cellulosic ethanol production at INEOS Bio's Indian River BioEnergy Center in Vero Beach, Florida. Developed through a joint venture between

  16. Alternative Fuels Data Center: Status Update: Clarification of Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Limits for Legacy Equipment (December 2008) Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) to someone by E-mail Share Alternative Fuels Data Center: Status Update: Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) on Facebook Tweet about Alternative Fuels Data Center: Status Update: Clarification of Ethanol Certification Limits for Legacy Equipment (December 2008) on Twitter Bookmark Alternative Fuels Data

  17. EERE Success Story-Louisiana: Verenium Cellulosic Ethanol Demonstration

    Office of Environmental Management (EM)

    Facility | Department of Energy Louisiana: Verenium Cellulosic Ethanol Demonstration Facility EERE Success Story-Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium Corporation received EERE funds to operate a 1.4 million gallon per year demonstration plant in Jennings, Louisiana, to convert agricultural residues and energy crops to cellulosic ethanol. The project's goal was to implement a technology that had been demonstrated in a

  18. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  19. Preliminary evaluation of alternative ethanol/water separation processes

    SciTech Connect (OSTI)

    Eakin, D.E.; Donovan, J.M.; Cysewski, G.R.; Petty, S.E.; Maxham, J.V.

    1981-05-01

    Preliminary evaluation indicates that separation of ethanol and water can be accomplished with less energy than is now needed in conventional distillation processes. The state of development for these methods varies from laboratory investigation to commercially available processes. The processes investigated were categorized by type of separation depending on their ability to achieve varying degrees of ethanol/water separation. The following methods were investigated: ethanol extraction with CO/sub 2/ (the A.D. Little process); solvent extraction of ethanol; vacuum distillation; vapor recompression distillation; dehydration with fermentable grains; low temperature blending with gasoline; molecular sieve adsorption; and reverse osmosis.

  20. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark...

  1. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  2. Issues and Methods for Estimating the Percentage Share of Ethanol...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Energy Information Administration 1 Issues and Methods for Estimating the Share of Ethanol in the Motor Gasoline Supply U.S. Energy Information Administration October 6, 2011...

  3. Ethanol Usage in Urban Public Transportation - Presentation of...

    Open Energy Info (EERE)

    - Presentation of Results Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Ethanol Usage in Urban Public Transportation - Presentation of Results AgencyCompany...

  4. Ethanol Extraction Technologies Inc EETI | Open Energy Information

    Open Energy Info (EERE)

    Extraction Technologies Inc EETI Jump to: navigation, search Name: Ethanol Extraction Technologies Inc (EETI) Place: New York, New York Zip: 10036-2601 Product: New York-based...

  5. International Ethanol Trade Association IETHA | Open Energy Informatio...

    Open Energy Info (EERE)

    Trade Association IETHA Jump to: navigation, search Name: International Ethanol Trade Association (IETHA) Place: Sao Paulo, Sao Paulo, Brazil Product: Association of 48 globally...

  6. Pacific Ethanol Inc the former | Open Energy Information

    Open Energy Info (EERE)

    Inc the former Jump to: navigation, search Name: Pacific Ethanol Inc (the former) Place: Fresno, California Zip: 93711 Product: California-based developer of bioethanol plants....

  7. Ask a scientist: Ethanol & car performance | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 issue of Argonne Now, the laboratory science magazine. Ask a scientist: Ethanol & car performance September 13, 2013 Tweet EmailPrint Does ethanol extend or decrease your gas mileage? -Tommy Holly, via Facebook JEHLIK: In a one-to-one comparison in a regular engine, ethanol will decrease your mileage. This is because the energy content of a gallon of ethanol is lower than the energy in a gallon of gasoline-it only has about 70% of the energy. The reason why is purely chemical: the chemical

  8. Lignocellulosic Biomass to Ethanol Process Design and Economics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover Lignocellulosic Biomass to ...

  9. U.S. Fuel Ethanol Plant Production Capacity

    Gasoline and Diesel Fuel Update (EIA)

    All Petrolem Reports U.S. Fuel Ethanol Plant Production Capacity Release Date: June 23, 2015 | Next Release Date: June 2016 Previous Issues Year: 2015 2014 2013 2012 2011 Go This is the fifth release of U.S. Energy Information Administration data on fuel ethanol production capacity. EIA first reported fuel ethanol production capacities as of January 1, 2011 on November 29, 2011. This new report contains production capacity data for all operating U.S. fuel ethanol production plants as of January

  10. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  11. NREL Industry Partners Move Cellulosic Ethanol Technology Forward...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Industry Partners Move Cellulosic Ethanol Technology Forward Lab Contributes Scientific Foundation for Making Biofuel from Non-Food Sources May 15, 2008 Collaborative ...

  12. Largest Cellulosic Ethanol Plant in the World Opened in October...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... representative from biofuels company POET-DSM stand between square and round bales of corn stover stock piled outside of POET-DSM's Project LIBERTY cellulosic ethanol biorefinery. ...

  13. Appendix D: 2012 Cellulosic Ethanol Success, Bioenergy Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    produce cellulosic ethanol at commercial-scale costs that are competitive with gasoline production at 110barrel of crude oil. Many industry partners are also demonstrating...

  14. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small

    Office of Environmental Management (EM)

    Non-Road Engines, Report 1 Â… Updated Feb 2009 | Department of Energy Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Â… Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Â… Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Â… Updated Feb 2009 PDF

  15. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  16. Alcohol Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Fuels Alcohol Fuels Goals Advance a multiscale approach to collaborative reaction kinetic model development and validation, by focusing team efforts on particular alcohol fuels. The team's initial focus has been on n-butanol. This has recently broadened to include detailed kinetic modeling of other isomeric butanols, plus some comparisons with smaller alcohols and the corresponding ketones, aldehydes, and enols. In the future we expect to use what we have learned from the butanol study

  17. Low and intermediate temperature oxidation of ethanol and ethanol-PRF blends: An experimental and modeling study

    SciTech Connect (OSTI)

    Haas, Francis M.; Chaos, Marcos; Dryer, Frederick L.

    2009-12-15

    In this brief communication, we present new experimental species profile measurements for the low and intermediate temperature oxidation of ethanol under knock-prone conditions. These experiments show that ethanol exhibits no global low temperature reactivity at these conditions, although we note the heterogeneous decomposition of ethanol to ethylene and water. Similar behavior is reported for an E85 blend in n-heptane. Kinetic modeling results are presented to complement these experiments and elucidate the interaction of ethanol and primary reference fuels undergoing cooxidation. (author)

  18. Current State of the U S Ethanol Industry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... for each gallon sold to an alcohol blender that is in excess of the producer's base ... to an alcohol blender may receive 0.075 for each gallon sold, up to 15,000,000 gallons. ...

  19. Ethanol fuel modification for highway vehicle use. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A number of problems that might occur if ethanol were used as a blending stock or replacement for gasoline in present cars are identified and characterized as to the probability of occurrence. The severity of their consequences is contrasted to those found with methanol in a previous contract study. Possibilities for correcting several problems are reported. Some problems are responsive to fuel modifications but others require or are better dealt with by modification of vehicles and the bulk fuel distribution system. In general, problems with ethanol in blends with gasoline were found to be less severe than those with methanol. Phase separation on exposure to water appears to be the major problem with ethanol/gasoline blends. Another potentially serious problem with blends is the illict recovery of ethanol for beverage usage, or bootlegging, which might be discouraged by the use of select denaturants. Ethanol blends have somewhat greater tendency to vapor lock than base gasoline but less than methanol blends. Gasoline engines would require modification to operate on fuels consisting mostly of ethanol. If such modifications were made, cold starting would still be a major problem, more difficult with ethanol than methanol. Startability can be provided by adding gasoline or light hydrocarbons. Addition of gasoline also reduces the explosibility of ethanol vapor and furthermore acts as denaturant.

  20. Greenhouse gases in the corn-to-fuel ethanol pathway.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-06-18

    Argonne National Laboratory (ANL) has applied its Greenhouse gas, Regulated Emissions and Energy in Transportation (GREET) full-fuel-cycle analysis model to examine greenhouse gas (GHG) emissions of corn-feedstock ethanol, given present and near-future production technology and practice. On the basis of updated information appropriate to corn farming and processing operations in the four principal corn- and ethanol-producing states (Illinois, Iowa, Minnesota, and Nebraska), the model was used to estimate energy requirements and GHG emissions of corn farming; the manufacture, transportation to farms, and field application of fertilizer and pesticide; transportation of harvested corn to ethanol plants; nitrous oxide emissions from cultivated cornfields; ethanol production in current average and future technology wet and dry mills; and operation of cars and light trucks using ethanol fuels. For all cases examined on the basis of mass emissions per travel mile, the corn-to-ethanol fuel cycle for Midwest-produced ethanol used in both E85 and E10 blends with gasoline outperforms conventional (current) and reformulated (future) gasoline with respect to energy use and GHG production. Also, GHG reductions (but not energy use) appear surprisingly sensitive to the value chosen for combined soil and leached N-fertilizer conversion to nitrous oxide. Co-product energy-use attribution remains the single key factor in estimating ethanol's relative benefits because this value can range from 0 to 50%, depending on the attribution method chosen.

  1. Investigation of Bio-Ethanol Steam Reforming over Cobalt-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Presented at the 2007...

  2. Making Better Use of Ethanol as a Transportation Fuel With "Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Breakout...

  3. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007...

  4. The U.S. Dry-Mill Ethanol Industry: Biobased Products and Bioenergy Initiative Success Stories

    SciTech Connect (OSTI)

    2009-10-28

    This fact sheet provides an overview of the history of ethanol production in the United States and describes innovations in dry-mill ethanol production.

  5. A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Pre-Treatment Model for Ethanol Production Using a Colorimetric Analysis of Starch Solutions (1 Activity) A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

  6. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  7. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  8. Increase in ethanol yield via elimination of lactate production in an ethanol-tolerant mutant of Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Prabhu, Sandeep; Lynd, Lee R; Guss, Adam M

    2014-01-01

    Large-scale production of lignocellulosic biofuel is a potential solution to sustainably meet global energy needs. One-step consolidated bioprocessing (CBP) is a potentially advantageous approach for the production of biofuels, but requires an organism capable of hydrolyzing biomass to sugars and fermenting the sugars to ethanol at commercially viable titers and yields. Clostridium thermocellum, a thermophilic anaerobe, can ferment cellulosic biomass to ethanol and organic acids, but low yield, low titer, and ethanol sensitivity remain barriers to industrial production. Here, we deleted the hypoxanthine phosphoribosyltransferase gene in ethanol tolerant strain of C. thermocellum adhE*(EA) in order to allow use of previously developed gene deletion tools, then deleted lactate dehydrogenase (ldh) to redirect carbon flux towards ethanol. Upon deletion of ldh, the adhE*(EA) ldh strain produced 30% more ethanol than wild type on minimal medium. The adhE*(EA) ldh strain retained tolerance to 5% v/v ethanol, resulting in an ethanol tolerant platform strain of C. thermocellum for future metabolic engineering efforts.

  9. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO)

    1999-02-09

    A method for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process.

  10. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, C.E.

    1999-02-09

    A method is described for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process. 2 figs.

  11. Syngas Mixed Alcohol Cost Validation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2013 DOE Bioenergy Technologies Office: Project Peer Review Syngas Mixed Alcohol Cost Validation Abhijit Dutta, NREL This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Enable research and development of cost-competitive biomass to liquid fuels by providing: - Techno-economic analysis (TEA) - Feedback to the research efforts Specific objective in 2012: Provide TEA and validate DOE BETO's goal to demonstrate technologies capable

  12. Sugar-Based Ethanol Biorefinery: Ethanol, Succinic Acid and By-Product Production

    SciTech Connect (OSTI)

    Donal F. Day

    2009-03-31

    The work conducted in this project is an extension of the developments itemized in DE-FG-36-04GO14236. This program is designed to help the development of a biorefinery based around a raw sugar mill, which in Louisiana is an underutilized asset. Some technical questions were answered regarding the addition of a biomass to ethanol facility to existing sugar mills. The focus of this work is on developing technology to produce ethanol and valuable by-products from bagasse. Three major areas are addressed, feedstock storage, potential by-products and the technology for producing ethanol from dilute ammonia pre-treated bagasse. Sugar mills normally store bagasse in a simple pile. During the off season there is a natural degradation of the bagasse, due to the composting action of microorganisms in the pile. This has serious implications if bagasse must be stored to operate a bagasse/biorefinery for a 300+ day operating cycle. Deterioration of the fermentables in bagasse was found to be 6.5% per month, on pile storage. This indicates that long term storage of adequate amounts of bagasse for year-round operation is probably not feasible. Lignin from pretreatment seemed to offer a potential source of valuable by-products. Although a wide range of phenolic compounds were present in the effluent from dilute ammonia pretreatment, the concentrations of each (except for benzoic acid) were too low to consider for extraction. The cellulosic hydrolysis system was modified to produce commercially recoverable quantities of cellobiose, which has a small but growing market in the food process industries. A spin-off of this led to the production of a specific oligosaccharide which appears to have both medical and commercial implications as a fungal growth inhibitor. An alternate use of sugars produced from biomass hydrolysis would be to produce succinic acid as a chemical feedstock for other conversions. An organism was developed which can do this bioconversion, but the economics of succinic acid production were such that it could not compete with current commercial practice. To allow recovery of commercial amounts of ethanol from bagasse fermentation, research was conducted on high solids loading fermentations (using S. cerevisiae) with commercial cellulase on pretreated material. A combination of SHF/SSF treatment with fed-batch operation allowed fermentation at 30% solids loading. Supplementation of the fermentation with a small amount of black-strap molasses had results beyond expectation. There was an enhancement of conversion as well as production of ethanol levels above 6.0% w/w, which is required both for efficient distillation as well as contaminant repression. The focus of fermentation development was only on converting the cellulose to ethanol, as this yeast is not capable of fermenting both glucose and xylose (from hemicellulose). In anticipation of the future development of such an organism, we screened the commercially available xylanases to find the optimum mix for conversion of both cellulose and hemicellulose. A different mixture than the spezyme/novozyme mix used in our fermentation research was found to be more efficient at converting both cellulose and hemicellulose. Efforts were made to select a mutant of Pichia stipitis for ability to co-ferment glucose and xylose to ethanol. New mutation technology was developed, but an appropriate mutant has not yet been isolated. The ability to convert to stillage from biomass fermentations were determined to be suitable for anaerobic degradation and methane production. An economic model of a current sugar factory was developed in order to provide a baseline for the cost/benefit analysis of adding cellulosic ethanol production.

  13. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos (Oak Ridge, TN); Graves, Ronald Lee (Knoxville, TN); Storey, John Morse Elliot (Oak Ridge, TN); Lewis, Sr., Samuel Arthur (Andersonville, TN); Sluder, Charles Scott (Knoxville, TN); Thomas, John Foster (Powell, TN)

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  14. Grain ethanol as a petroleum substitute: a perspective

    SciTech Connect (OSTI)

    Alston, T.G.

    1980-04-01

    Present tax exemptions for gasohol are more than sufficient to move ethanol into the gasoline market in a number of states. The principal near-term response to this profit opportunity, production of ethanol from feed grains, matches a limited biomass resource to an enormous market. This report estimates upper-bound prices for feed grains resulting from gasohol tax exemptions and concludes that grain price increases could be substantial. As shown else-where by Alston and Asbury, industrial uses constitute a more economical market for grain ethanol, one in which the product is now competitive with ethanol derived from petroleum and natural gas liquids. Without tax exemptions for gasohol, grain ethanol would now be displacing petroleum in the industrial market at a net economic gain, rather than in the fuel market at a net economic loss. The present analysis indicates that this industrial market for ethanol could grow significantly, principally by use of grain ethanol as an intermediate in production of chemicals now derived from petroleum and natural gas.

  15. Recombinant host cells and media for ethanol production

    DOE Patents [OSTI]

    Wood, Brent E; Ingram, Lonnie O; Yomano, Lorraine P; York, Sean W

    2014-02-18

    Disclosed are recombinant host cells suitable for degrading an oligosaccharide that have been optimized for growth and production of high yields of ethanol, and methods of making and using these cells. The invention further provides minimal media comprising urea-like compounds for economical production of ethanol by recombinant microorganisms. Recombinant host cells in accordance with the invention are modified by gene mutation to eliminate genes responsible for the production of unwanted products other than ethanol, thereby increasing the yield of ethanol produced from the oligosaccharides, relative to unmutated parent strains. The new and improved strains of recombinant bacteria are capable of superior ethanol productivity and yield when grown under conditions suitable for fermentation in minimal growth media containing inexpensive reagents. Systems optimized for ethanol production combine a selected optimized minimal medium with a recombinant host cell optimized for use in the selected medium. Preferred systems are suitable for efficient ethanol production by simultaneous saccharification and fermentation (SSF) using lignocellulose as an oligosaccharide source. The invention also provides novel isolated polynucleotide sequences, polypeptide sequences, vectors and antibodies.

  16. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    1992-01-01

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H.sub.2 O and/or CO.sub.2 and H.sub.2 in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate.

  17. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, J.L.; Clausen, E.C.

    1992-12-22

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H[sub 2]O and/or CO[sub 2] and H[sub 2] in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate. 3 figs.

  18. Comparison of ethanol production by different Zymomonas strains

    SciTech Connect (OSTI)

    Skotnicki, M.L.; Lee, K.J.; Tribe, D.E.; Rogers, P.L.

    1981-04-01

    A comparison of the rates of growth and ethanol production by 11 different strains of Zymomonas revealed a wide range of characteristics, with some strains being more tolerant of high sugar or ethanol concentrations and high incubation temperatures than others. Some strains were unable to utilize sucrose; others produced large amounts of levan, and one strain grew well but produced no levan. One strain, CP4, was considerably better in all respects than most of the other strains and was chosen as a starting strain for genetic improvement of ethanol production.

  19. Plants in Your Gas Tank: From Photosynthesis to Ethanol

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    With ethanol becoming more prevalent in the media and in gas tanks, it is important for students to know from where it comes. This module uses a series of activities to show how energy and mass are converted from one form to another. It focuses on the conversion of light energy into chemical energy via photosynthesis. It then goes on to show how the chemical energy in plant sugars can be fermented to produce ethanol. Finally, the reasons for using ethanol as a fuel are discussed.

  20. Nicotinic acid increases the lipid content of rat brain synaptosomes. [Ethanol effects

    SciTech Connect (OSTI)

    Basilio, C.; Flores, M.

    1989-02-09

    Chronic administration of nicotinic acid (NA) increase hepatic lipids and potentiates a similar effect induced by ethanol. The amethystic properties of NA promoted us to study its effects on the lipid content of brain synaptosomes of native and ethanol treated rats. Groups of 10 Sprague-Dawley female rats received i.p. either saline, ethanol (4g/kg), NA (50mg/kg), or a mixture of both compounds once a week during 3 weeks. The sleeping time (ST) of the animals receiving ethanol was recorded, brain synaptosomes of all groups were prepared and total lipids (TL) and cholesterol (Chol) content were determined. NA, ethanol and ethanol + NA markedly increased both TL and Chol of synaptosomes. Animals treated with ethanol or ethanol + NA developed tolerance. The group treated with ethanol-NA showed the highest Chol content and slept significantly less than the one treated with ethanol alone indicating that the changes induced by NA favored the appearance of tolerance.

  1. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  2. Formation of alcohol conversion catalysts

    DOE Patents [OSTI]

    Wachs, Israel E. (Bridgewater, NJ); Cai, Yeping (Louisville, KY)

    2001-01-01

    The method of the present invention involves a composition containing an intimate mixture of (a) metal oxide support particles and (b) a catalytically active metal oxide from Groups VA, VIA, or VIIA, its method of manufacture, and its method of use for converting alcohols to aldehydes. During the conversion process, catalytically active metal oxide from the discrete catalytic metal oxide particles migrates to the oxide support particles and forms a monolayer of catalytically active metal oxide on the oxide support particle to form a catalyst composition having a higher specific activity than the admixed particle composition.

  3. Pressure dispensable gelled alcohol fuel

    SciTech Connect (OSTI)

    Monick, J.A.

    1982-12-28

    A pressurized fuel gel composition particularly suitable for igniting wood and charcoal consisting essentially of, by weight, 42-90% of at least one c1-c6 monohydric alcohol, 0.5-6% of water-soluble gelling agent, up to about 24% water and a correlated amount of propellant from 0.5% to 30% characterized by a gel structure which forms a shape retaining mass upon contact with wood or charcoal that is maintained during the burning of said composition. Also within the scope of the invention is an aerosol product comprising said pressurized composition enclosed within a pressure-tight container having valve means for expelling the composition.

  4. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ethanol production in place * U.S. 13.4 billion galsyear mostly from corn starch * Brazil 6.3 billion galsyear from cane sugar * Rest of world 2.8 billion galsyear *...

  5. Continuous production of ethanol by use of flocculent zymomonas mobilis

    DOE Patents [OSTI]

    Arcuri, Edward J. (Del Mar, CA); Donaldson, Terrence L. (Lenoir City, TN)

    1983-01-01

    Ethanol is produced by means of a floc-forming strain of Zymomonas mobilis bacteria. Gas is vented along the length of a column containing the flocculent bacteria to preclude disruption of liquid flow.

  6. Understanding the Growth of the Cellulosic Ethanol Industry

    SciTech Connect (OSTI)

    Sandor, D.; Wallace, R.; Peterson, S.

    2008-04-01

    This report identifies, outlines, and documents a set of plausible scenarios for producing significant quantities of lignocellulosic ethanol in 2017. These scenarios can provide guidance for setting government policy and targeting government investment to the areas with greatest potential impact.

  7. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization

    Broader source: Energy.gov [DOE]

    Oak Ridge National Laboratory published an article in Scientific Reports on its new method to directly convert biomass-derived ethanol to a hydrocarbon blendstock and is continuing work with...

  8. Methods for increasing the production of ethanol from microbial fermentation

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Arora, Dinesh K. (Fayetteville, AR); Ko, Ching-Whan (Fayetteville, AR); Phillips, John Randall (Fayetteville, AR); Basu, Rahul (Bethlehem, PA); Wikstrom, Carl V. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    2007-10-23

    A stable continuous method for producing ethanol from the anaerobic bacterial fermentation of a gaseous substrate containing at least one reducing gas involves culturing a fermentation bioreactor anaerobic, acetogenic bacteria in a liquid nutrient medium; supplying the gaseous substrate to the bioreactor; and manipulating the bacteria in the bioreactor by reducing the redox potential, or increasing the NAD(P)H TO NAD(P) ratio, in the fermentation broth after the bacteria achieves a steady state and stable cell concentration in the bioreactor. The free acetic acid concentration in the bioreactor is maintained at less than 5 g/L free acid. This method allows ethanol to be produced in the fermentation broth in the bioreactor at a productivity greater than 10 g/L per day. Both ethanol and acetate are produced in a ratio of ethanol to acetate ranging from 1:1 to 20:1.

  9. Commercial Ethanol Turns Dross to Dollars for Rural Iowans

    Broader source: Energy.gov [DOE]

    U.S. Energy Secretary Steven Chu Sept. 23 announced the Department finalized a $105 million loan guarantee to support the development of one of the nation's first commercial-scale cellulosic ethanol plants.

  10. Current State of the U.S. Ethanol Industry

    SciTech Connect (OSTI)

    Urbanchuk, John

    2010-11-30

    The objective of this study is to provide a comprehensive overview of the state of the U.S. ethanol industry and to outline the major forces that will affect the development of the industry over the next decade.

  11. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses Citation Details In-Document Search Title: Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses Zymomonas mobilis ZM4 is a capable ethanogenic bacterium with high ethanol productivity and high level of ethanol tolerance. Previous studies indicated that several stress-related proteins and changes in the ZM4 membrane lipid composition may contribute to ethanol

  12. Enabling High Efficiency Ethanol Engines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enabling High Efficiency Ethanol Engines Enabling High Efficiency Ethanol Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon vssp_12_wagner.pdf More Documents & Publications Ignition Control for HCCI High-Efficiency Clean Combustion in Light-Duty Multi-Cylinder Diesel Engines Expanding Robust HCCI Operation (Delphi CRADA)

  13. Effects of ethanol on small engines and the environment

    SciTech Connect (OSTI)

    Bettis, M.D.

    1995-01-09

    With the support of the Missouri Corn Merchandising Council and the Department of Energy, Northwest Missouri State University conducted an applied research project to investigate the effects of the commercially available ethanol/gasoline fuel blend on small engines. The study attempted to identify any problems when using the 10% ethanol/gasoline blend in engines designed for gasoline and provide solutions to the problems identified. Fuel economy, maximum power, internal component wear, exhaust emissions and engine efficiency were studied.

  14. Report to Congress: Dedicated Ethanol Pipeline Feasability Study - Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Independence and Security Act of 2007 Section 243 | Department of Energy Report to Congress: Dedicated Ethanol Pipeline Feasability Study - Energy Independence and Security Act of 2007 Section 243 Report to Congress: Dedicated Ethanol Pipeline Feasability Study - Energy Independence and Security Act of 2007 Section 243 This study was prepared by the U.S. Department of Energy (DOE) in response to Section 243 of the Energy Independence and Security Act of 2007 (EISA). Section 243 directs DOE

  15. The ethanol heavy-duty truck fleet demonstration project

    SciTech Connect (OSTI)

    1997-06-01

    This project was designed to test and demonstrate the use of a high- percentage ethanol-blended fuel in a fleet of heavy-duty, over-the- road trucks, paying particular attention to emissions, performance, and repair and maintenance costs. This project also represents the first public demonstration of the use of ethanol fuels as a viable alternative to conventional diesel fuel in heavy-duty engines.

  16. Evolved strains of Scheffersomyces stipitis achieving high ethanol

    Office of Scientific and Technical Information (OSTI)

    productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading (Journal Article) | SciTech Connect Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Citation Details In-Document Search Title: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Lignocellulosic biomass is

  17. Evolved strains of Scheffersomyces stipitis achieving high ethanol

    Office of Scientific and Technical Information (OSTI)

    productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading (Journal Article) | DOE PAGES DOE PAGES Search Results Accepted Manuscript: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Title: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Lignocellulosic biomass

  18. Evolved strains of Scheffersomyces stipitis achieving high ethanol

    Office of Scientific and Technical Information (OSTI)

    productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading (Journal Article) | SciTech Connect Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Citation Details In-Document Search Title: Evolved strains of Scheffersomyces stipitis achieving high ethanol productivity on acid- and base-pretreated biomass hydrolyzate at high solids loading Ă— You are accessing a

  19. Review of Recent Pilot Scale Cellulosic Ethanol Demonstration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Opening Plenary Session: Celebrating Successes-The Foundation of an Advanced Bioindustry Cellulosic Technology Advances-Thomas Foust, Director, National Bioenergy Center, National Renewable Energy Laboratory PDF icon b13_foust_op-1.pdf More Documents & Publications Advanced Bio-based Jet Fuel Cross-cutting Technologies for Advanced Biofuels Process Design

  20. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B: End Use and Fuel Certification Paul Machiele, Center Director for Fuel Programs, Office of Transportation & Air Quality, U.S. Environmental Protection Agency PDF icon b13_machiele_2-b.pdf More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels The

  1. Biochemical Production of Ethanol from Corn Stover: 2007 State of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Model | Department of Energy Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model Biochemical Production of Ethanol from Corn Stover: 2007 State of Technology Model An update to the FY 2005 assessment of the state of technical research progress toward biochemical process goals. This assessment containins research results from 2006 and 2007. PDF icon 43205.pdf More Documents & Publications Process Design and Economics for Biochemical Conversion of

  2. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization |

    Office of Environmental Management (EM)

    Department of Energy Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization December 16, 2015 - 2:23pm Addthis Dr. Chaitanya Narula led analysis of an Oak Ride National Laboratory biofuel-to-hydrocarbon conversion technology to explain the underlying process. Photo courtesy Oak Ride National Laboratory. Dr. Chaitanya Narula led analysis of an Oak Ride National Laboratory biofuel-to-hydrocarbon conversion

  3. Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover | Department of Energy Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis For Corn Stover This report is an update of NREL's ongoing process design and economic analyses of

  4. NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol

    Office of Environmental Management (EM)

    from Algae | Department of Energy NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 - 5:07pm Addthis A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) with funding from the U.S. Department of Energy's Bioenergy Technologies Office (BETO) has proven to be significantly more effective at

  5. Gel electrophoretic analysis of Zymomonas mobilis glycolytic and fermentative enzymes: Identification of alcohol dehydrogenase II as a stress protein

    SciTech Connect (OSTI)

    Haejung An; Keshav, K.F.; Ingram, L.O. ); Scopes, R.K.; Rodriguez, M. )

    1991-10-01

    The 13 major enzymes which compose the glycolytic and fermentative pathways in Zymomonas mobilis are particularly abundant and represent one-half of the soluble protein in exponential-phase cells. One- and two-dimensional polyacrylamide gel electrophoresis maps were developed for 12 of these enzymes. Assignments were made by comigration with purified proteins, comparison with overexpressed genes in recombinant strains, and Western blots (immunoblots). Although most glycolytic enzymes appeared resistant to turnover and accumulated in stationary-phase cells, the protein levels of pyruvate kinase, alcohol dehydrogenase I, and glucokinase declined. Alcohol dehydrogenase II was identified as a major stress protein and was induced both by exposure to ethanol and by elevated temperature (45C). This enzyme, encoded by the adhB gene, is expressed from tandem promoters which share partial sequence identity with Escherichia coli consensus sequence for heat shock proteins.

  6. Ethanol Dehydration to Ethylene in a Stratified Autothermal Millisecond Reactor

    SciTech Connect (OSTI)

    Skinner, MJ; Michor, EL; Fan, W; Tsapatsis, M; Bhan, A; Schmidt, LD

    2011-08-10

    The concurrent decomposition and deoxygenation of ethanol was accomplished in a stratified reactor with 50-80 ms contact times. The stratified reactor comprised an upstream oxidation zone that contained Pt-coated Al(2)O(3) beads and a downstream dehydration zone consisting of H-ZSM-5 zeolite films deposited on Al(2)O(3) monoliths. Ethanol conversion, product selectivity, and reactor temperature profiles were measured for a range of fuel:oxygen ratios for two autothermal reactor configurations using two different sacrificial fuel mixtures: a parallel hydrogen-ethanol feed system and a series methane-ethanol feed system. Increasing the amount of oxygen relative to the fuel resulted in a monotonic increase in ethanol conversion in both reaction zones. The majority of the converted carbon was in the form of ethylene, where the ethanol carbon-carbon bonds stayed intact while the oxygen was removed. Over 90% yield of ethylene was achieved by using methane as a sacrificial fuel. These results demonstrate that noble metals can be successfully paired with zeolites to create a stratified autothermal reactor capable of removing oxygen from biomass model compounds in a compact, continuous flow system that can be configured to have multiple feed inputs, depending on process restrictions.

  7. Conversion of bagasse cellulose into ethanol

    SciTech Connect (OSTI)

    Cuzens, J.E.

    1997-11-19

    The study conducted by Arkenol was designed to test the conversion of feedstocks such as sugar cane bagasse, sorghum, napier grass and rice straw into fermentable sugars, and then ferment these sugars using natural yeasts and genetically engineered Zymomonis mobilis bacteria (ZM). The study did convert various cellulosic feedstocks into fermentable sugars utilizing the patented Arkenol Concentrated Acid Hydrolysis Process and equipment at the Arkenol Technology Center in Orange, California. The sugars produced using this process were in the concentration range of 12--15%, much higher than the sugar concentrations the genetically engineered ZM bacteria had been developed for. As a result, while the ZM bacteria fermented the produced sugars without initial inhibition, the completion of high sugar concentration fermentations was slower and at lower yield than predicted by the National Renewable Energy Laboratory (NREL). Natural yeasts performed as expected by Arkenol, similar to the results obtained over the last four years of testing. Overall, at sugar concentrations in the 10--13% range, yeast produced 850090% theoretical ethanol yields and ZM bacteria produced 82--87% theoretical yields in 96 hour fermentations. Additional commercialization work revealed the ability to centrifugally separate and recycle the ZM bacteria after fermentation, slight additional benefits from mixed culture ZM bacteria fermentations, and successful utilization of defined media for ZM bacteria fermentation nutrients in lieu of natural media.

  8. Production of alcohol from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.; Lee, C.Y.; Woodams, E.E.; Cooley, H.J.

    1981-12-01

    Production of ethyl alcohol from apple pomace with a Montrachet strain of Saccharomyces cerevisiae is described. More than 43 grams of the ethyl alcohol could be produced per kg of apple pomace fermented at 30 degrees Celcius in 24 hours. The fermentation efficiency of this process was approximately 89%. (Refs. 9).

  9. Process for the synthesis of unsaturated alcohols

    DOE Patents [OSTI]

    Maughon, Bob R.; Burdett, Kenneth A.; Lysenko, Zenon

    2007-02-13

    A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

  10. HD Applications of Significantly Downsized SI Engines Using Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance ...

  11. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via ...

  12. Jilin Fuel Alcohol Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    Alcohol Company Ltd Jump to: navigation, search Name: Jilin Fuel Alcohol Company Ltd Place: Jilin, Jilin Province, China Zip: 132011 Product: One of the four Chinese government...

  13. Effect of alcohols on aqueous lysozyme-lysozyme interactions...

    Office of Scientific and Technical Information (OSTI)

    Effect of alcohols on aqueous lysozyme-lysozyme interactions from static light-scattering measurements Citation Details In-Document Search Title: Effect of alcohols on aqueous...

  14. Imaging the condensation and evaporation of molecularly thin ethanol films with surface forces apparatus

    SciTech Connect (OSTI)

    Zhao, Gutian; Tan, Qiyan; Xiang, Li; Zhang, Di; Ni, Zhonghua E-mail: yunfeichen@seu.edu.cn; Yi, Hong; Chen, Yunfei E-mail: yunfeichen@seu.edu.cn

    2014-01-15

    A new method for imaging condensation and evaporation of molecularly thin ethanol films is reported. It is found that the first adsorbed layer of ethanol film on mica surface behaves as solid like structure that cannot flow freely. With the increase of exposure time, more ethanol molecules condense over the mica surface in the saturated ethanol vapor condition. The first layer of adsorbed ethanol film is about 3.8 Ĺ thick measured from the surface forces apparatus, which is believed to be the average diameter of ethanol molecules while they are confined in between two atomically smooth mica surfaces.

  15. Fact #679: June 13, 2011 U.S. Imports of Fuel Ethanol Drop Sharply |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 9: June 13, 2011 U.S. Imports of Fuel Ethanol Drop Sharply Fact #679: June 13, 2011 U.S. Imports of Fuel Ethanol Drop Sharply U.S. imports of fuel ethanol were low until 2004 when imports began to rise sharply. By 2006 imports of fuel ethanol reached a record high of 735.8 million gallons. As domestic supply of fuel ethanol increased to meet demand, imports of fuel ethanol began to drop after 2006. By 2010, imports declined to pre-2004 levels. Annual U.S. Imports of Fuel

  16. Largest Cellulosic Ethanol Plant in the World Opens October 30 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Largest Cellulosic Ethanol Plant in the World Opens October 30 Largest Cellulosic Ethanol Plant in the World Opens October 30 October 26, 2015 - 2:52pm Addthis The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The DuPont cellulosic

  17. EERE Success Story-Largest Cellulosic Ethanol Plant in the World Opened

    Office of Environmental Management (EM)

    in October | Department of Energy Largest Cellulosic Ethanol Plant in the World Opened in October EERE Success Story-Largest Cellulosic Ethanol Plant in the World Opened in October November 30, 2015 - 2:07pm Addthis The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year. Photo courtesy of DuPont. The DuPont cellulosic ethanol facility in Nevada, Iowa, will produce about 30 million gallons of cellulosic ethanol per year.

  18. Analysis of Fuel Ethanol Transportation Activity and Potential Distribution Constraints

    SciTech Connect (OSTI)

    Das, Sujit; Peterson, Bruce E; Chin, Shih-Miao

    2010-01-01

    This paper provides an analysis of fuel ethanol transportation activity and potential distribution constraints if the total 36 billion gallons of renewable fuel use by 2022 is mandated by EPA under the Energy Independence and Security Act (EISA) of 2007. Ethanol transport by domestic truck, marine, and rail distribution systems from ethanol refineries to blending terminals is estimated using Oak Ridge National Laboratory s (ORNL s) North American Infrastructure Network Model. Most supply and demand data provided by EPA were geo-coded and using available commercial sources the transportation infrastructure network was updated. The percentage increases in ton-mile movements by rail, waterways, and highways in 2022 are estimated to be 2.8%, 0.6%, and 0.13%, respectively, compared to the corresponding 2005 total domestic flows by various modes. Overall, a significantly higher level of future ethanol demand would have minimal impacts on transportation infrastructure. However, there will be spatial impacts and a significant level of investment required because of a considerable increase in rail traffic from refineries to ethanol distribution terminals.

  19. Fermentation pattern of sucrose to ethanol conversions by Zymomonas mobilis

    SciTech Connect (OSTI)

    Lyness, E.; Doelle, H.W.

    1981-07-01

    General patterns of sucrose fermentation by two strains of Zymomonas mobilis, designated Z7 and Z10, were established using sucrose concentrations from 50 to 200 g/liter. Strain Z7 showed a higher invertase activity than Z10. Strain Z10 showed a reduced specific growth rate at high sucrose concentrations while Z7 was unaffected. High sucrose hydrolyzing activity in strain Z7 lead to glucose accumulation in the medium at high sucrose concentrations. Ethanol production and fermentation time depend on the rate of catabolism of the products of sucrose hydrolysis, glucose and fructose. The metabolic quotients for sucrose utilization, qs, and ethanol production, qp (g/g.hr), are unsuitable for describing sucrose utilization by Zymomonas mobilis as the logarithmic phase of growth precedes the phase of highest substrate utilization (g/liter.hr) and ethanol production (g/liter.hr) in batch culture. (Refs. 10).

  20. Treatment of addiction to ethanol and addictive-related behavior

    DOE Patents [OSTI]

    Dewey, Stephen L. (Manorville, NY); Brodie, Jonathan D. (Cos Cob, CT); Ashby, Jr., Charles R. (Miller Place, NY)

    2001-01-01

    The present invention provides a highly efficient method for treating alcohol addiction and for changing addiction-related behavior of a mammal suffering from alcohol addiction. The method includes administering to a mammal an effective amount of gamma vinylGABA or a pharmaceutically acceptable salt thereof. In one embodiment, the method of the present invention includes administering to the mammal an effective amount of a composition which increase central nervous system GABA levels wherein the effective amount is sufficient to diminish, inhibit or eliminate behavior associated with craving or use of alcohol.

  1. Certification of the Cessna 152 on 100% ethanol

    SciTech Connect (OSTI)

    Shauck, M.E.; Zanin, M.G.

    1997-12-31

    In June 1996, the Renewable Aviation Fuels Development Center (RAFDC) at Baylor University in Waco, Texas, received a Supplemental Type Certificate (STC) for the use of 100% ethanol as a fuel for the Cessna 152, the most popular training aircraft in the world. This is the first certification granted by the Federal Aviation Administration (FAA) for a non-petroleum fuel. Certification of an aircraft on a new fuel requires a certification of the engine followed by a certification of the airframe/engine combination. This paper will describe the FAA airframe certification procedure, the tests required and their outcome using ethanol as an aviation fuel in a Cessna 152.

  2. EERE Success Story-Algenol Announces Commercial Algal Ethanol Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Partnership | Department of Energy Algenol Announces Commercial Algal Ethanol Fuel Partnership EERE Success Story-Algenol Announces Commercial Algal Ethanol Fuel Partnership October 21, 2015 - 10:35am Addthis Algenol is a company located in Fort Myers, FL that is working with its unique photosynthetic algae to take carbon dioxide that is in the atmosphere and produce a variety of affordable and sustainable biofuels. The scale-up of this work by Algenol was funded in part by the U.S.

  3. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-in-the-Loop | Department of Energy Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon vss049_shidore_2011_o.pdf More Documents & Publications Evaluation of the Fuel Economy Impacts of Low Temperature Combustion (LTC) using Engine-in-the-Loop Cold-Start Performance and

  4. Algenol Announces Commercial Algal Ethanol Fuel Partnership | Department of

    Energy Savers [EERE]

    Energy Algenol Announces Commercial Algal Ethanol Fuel Partnership Algenol Announces Commercial Algal Ethanol Fuel Partnership October 2, 2015 - 11:28am Addthis Algenol is a company located in Fort Myers, FL that is working with its unique photosynthetic algae to take carbon dioxide that is in the atmosphere and produce a variety of affordable and sustainable biofuels. The scale-up of this work by Algenol was funded in part by the U.S. Department of Energy Bioenergy Technology Office's

  5. Algenol Announces Commercial Algal Ethanol Fuel Partnership | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Algenol Announces Commercial Algal Ethanol Fuel Partnership Algenol Announces Commercial Algal Ethanol Fuel Partnership October 21, 2015 - 10:35am Addthis Algenol is a company located in Fort Myers, FL that is working with its unique photosynthetic algae to take carbon dioxide that is in the atmosphere and produce a variety of affordable and sustainable biofuels. The scale-up of this work by Algenol was funded in part by the U.S. Department of Energy Bioenergy Technology Office's

  6. EA-1848: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran, Storey County, NV EA-1848: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran, Storey County, NV June 1, 2011 EA-1848:...

  7. Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the...

  8. Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs...

    Broader source: Energy.gov (indexed) [DOE]

    1,000-hour performance runs of its patent-pending Generation 2.0 Co-Located Cellulosic Ethanol process at its cellulosic ethanol pilot plant in St. Joseph, Missouri. This is an...

  9. Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs

    Broader source: Energy.gov [DOE]

    ICM Inc. announced successful completion of two 1,000-hour performance runs of its patent-pending Generation 2.0 Co-Located Cellulosic Ethanol process at its cellulosic ethanol pilot plant in St....

  10. ZeaChem Pilot Project: High-Yield Hybrid Cellulosic Ethanol Process...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ZeaChem Pilot Project: High-Yield Hybrid Cellulosic Ethanol Process Using High-Impact Feedstock for Commercialization ZeaChem Pilot Project: High-Yield Hybrid Cellulosic Ethanol...

  11. Third international symposium on alcohol fuels technology

    SciTech Connect (OSTI)

    1980-04-01

    At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

  12. Ethanol Vehicle and Infrastructure Codes and Standards Chart (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01

    This chart shows the SDOs responsible for leading the support and development of key codes and standards for ethanol.

  13. Light-Induced Passivation of Si by Iodine Ethanol Solution: Preprint

    SciTech Connect (OSTI)

    Sopori, B.; Rupnowski, P.; Appel, J.; Guhaabiswas, D.; Anderson-Jackson, L.

    2009-02-01

    We report on our observations of light-activated passivation of silicon surfaces by iodine-ethanol solution.

  14. Department of Energy Delivers on R&D Targets around Cellulosic Ethanol |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Delivers on R&D Targets around Cellulosic Ethanol Department of Energy Delivers on R&D Targets around Cellulosic Ethanol April 19, 2013 - 11:24am Addthis In September 2012, scientists at DOE national laboratories successfully demonstrated technical advances required to produce cellulosic ethanol that is cost competitive with petroleum. Cellulosic ethanol is fuel produced from the inedible, organic material abundant in agricultural waste, including grasses, farm

  15. Alternative Fuels Data Center: Goss' Garage Provides Tips for Using Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    in Classic Cars Goss' Garage Provides Tips for Using Ethanol in Classic Cars to someone by E-mail Share Alternative Fuels Data Center: Goss' Garage Provides Tips for Using Ethanol in Classic Cars on Facebook Tweet about Alternative Fuels Data Center: Goss' Garage Provides Tips for Using Ethanol in Classic Cars on Twitter Bookmark Alternative Fuels Data Center: Goss' Garage Provides Tips for Using Ethanol in Classic Cars on Google Bookmark Alternative Fuels Data Center: Goss' Garage Provides

  16. Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    A1: Tank Manufacturer Compatibility with Ethanol Blends. September 2013. Tank Manufacturer Compatibility with Ethanol Blends Manufacturer Compatibility Statement Fiberglass 1 Containment Solutions Tanks manufactured after January 1, 1995 are all compatible with ethanol blends up to 100% (E100) (UL Listed) Owens Corning Single Wall Tanks Tanks manufactured between 1965 and 1994 are approved to store up to 10% ethanol (E10) Double Wall Tanks Tanks manufactured between 1965 and July 1, 1990 are

  17. Water Footprints of Cassava- and Molasses-Based Ethanol Production in Thailand

    SciTech Connect (OSTI)

    Mangmeechai, Aweewan; Pavasant, Prasert

    2013-12-15

    The Thai government has been promoting renewable energy as well as stimulating the consumption of its products. Replacing transport fuels with bioethanol will require substantial amounts of water and enhance water competition locally. This study shows that the water footprint (WF) of molasses-based ethanol is less than that of cassava-based ethanol. The WF of molasses-based ethanol is estimated to be in the range of 1,510-1,990 L water/L ethanol, while that of cassava-based ethanol is estimated at 2,300-2,820 L water/L ethanol. Approximately 99% of the water in each of these WFs is used to cultivate crops. Ethanol production requires not only substantial amounts of water but also government interventions because it is not cost competitive. In Thailand, the government has exploited several strategies to lower ethanol prices such as oil tax exemptions for consumers, cost compensation for ethanol producers, and crop price assurances for farmers. For the renewable energy policy to succeed in the long run, the government may want to consider promoting molasses-based ethanol production as well as irrigation system improvements and sugarcane yield-enhancing practices, since molasses-based ethanol is more favorable than cassava-based ethanol in terms of its water consumption, chemical fertilizer use, and production costs.

  18. Ethanol Fuels Incentives Applied in the U.S.: Reviewed from California's Perspective

    SciTech Connect (OSTI)

    MacDonald, Tom

    2004-01-01

    This report describes measures employed by state governments and by the federal government to advance the production and use of ethanol fuel in the United States. The future of ethanol as an alternative transportation fuel poses a number of increasingly-important issues and decisions for California government, as the state becomes a larger consumer, and potentially a larger producer, of ethanol.

  19. Contribution of the Ethanol Industry to the Economy of the United States

    SciTech Connect (OSTI)

    Urbanchuk, John M.

    2008-02-20

    Despite the challenges to profitability the ethanol industry continues to expand. Total ethanol production for 2007 is estimated at nearly 6.5 billion gallons, 33 percent more than 2006. This study estimates the contribution of the ethanol industry to the American economy in 2007.

  20. Ethanol production with dilute acid hydrolysis using partially dried lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A. (Chesterfield, MO); Keller, Fred A. (Lakewood, CO); Tucker, Melvin P. (Lakewood, CO)

    2003-12-09

    A process of converting lignocellulosic biomass to ethanol, comprising hydrolyzing lignocellulosic materials by subjecting dried lignocellulosic material in a reactor to a catalyst comprised of a dilute solution of a strong acid and a metal salt to lower the activation energy (i.e., the temperature) of cellulose hydrolysis and ultimately obtain higher sugar yields.

  1. Comparing Scales of Environmental Effects from Gasoline and Ethanol Production

    SciTech Connect (OSTI)

    Parish, Esther S; Kline, Keith L; Dale, Virginia H; Efroymson, Rebecca Ann; McBride, Allen; Johnson, Timothy L; Hilliard, Michael R; Bielicki, Dr Jeffrey M

    2013-01-01

    Understanding the environmental effects of alternative fuel production is critical to characterizing the sustainability of energy resources to inform policy and regulatory decisions. The magnitudes of these environmental effects vary according to the intensity and scale of fuel production along each step of the supply chain. We compare the scales (i.e., spatial extent and temporal duration) of ethanol and gasoline production processes and environmental effects based on a literature review, and then synthesize the scale differences on space-time diagrams. Comprehensive assessment of any fuel-production system is a moving target, and our analysis shows that decisions regarding the selection of spatial and temporal boundaries of analysis have tremendous influences on the comparisons. Effects that strongly differentiate gasoline and ethanol supply chains in terms of scale are associated with when and where energy resources are formed and how they are extracted. Although both gasoline and ethanol production may result in negative environmental effects, this study indicates that ethanol production traced through a supply chain may impact less area and result in more easily reversed effects of a shorter duration than gasoline production.

  2. An Update on Ethanol Production and Utilization in Thailand, 2014

    SciTech Connect (OSTI)

    Bloyd, Cary N.; Foster, Nikolas A.F.

    2014-09-01

    In spite of the recent political turmoil, Thailand has continued to develop its ethanol based alternative fuel supply and demand infrastructure. Its support of production and sales of ethanol contributed to more than doubling the production over the past five years alone. In April 2014, average consumption stood at 3.18 million liter per day- more than a third on its way to its domestic consumption goal of 9 million liters per day by 2021. Strong government incentives and the phasing out of non-blended gasoline contributed substantially. Concurrently, exports dropped significantly to their lowest level since 2011, increasing the pressure on Thai policy makers to best balance energy independency goals with other priorities, such as Thailand’s trade balance and environmental aspirations. Utilization of second generation biofuels might have the potential to further expand Thailand’s growing ethanol market. Thailand has also dramatically increased its higher ethanol blend vehicle fleet, with all new vehicles sold in the Thai market now being E20 capable and the number of E85 vehicles increasing three fold in the last year from 100,000 in 2013 to 300,000 in 2014.

  3. Ethanol production in fermentation of mixed sugars containing xylose

    DOE Patents [OSTI]

    Viitanen, Paul V.; Mc Cutchen, Carol M.; Li; Xu; Emptage, Mark; Caimi, Perry G.; Zhang, Min; Chou, Yat-Chen; Franden, Mary Ann

    2009-12-08

    Xylose-utilizing Z. mobilis strains were found to have improved ethanol production when grown in medium containing mixed sugars including xylose if sorbitol or mannitol was included in the medium. The effect was seen in concentrations of mixed sugars where no growth lag period occurs, as well as in higher sugars concentrations.

  4. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for gasoline, which is knock-prone at these high CR, in order to maintain compatibility. By using EIVC and LIVC strategies, good efficiency is maintained with gasoline, but power is reduced by about 34%.

  5. Fair Oaks Dairy Farms Cellulosic Ethanol Technology Review Summary

    SciTech Connect (OSTI)

    Andrew Wold; Robert Divers

    2011-06-23

    At Fair Oaks Dairy, dried manure solids (''DMS'') are currently used as a low value compost. United Power was engaged to evaluate the feasibility of processing these DMS into ethanol utilizing commercially available cellulosic biofuels conversion platforms. The Fair Oaks Dairy group is transitioning their traditional ''manure to methane'' mesophilic anaerobic digester platform to an integrated bio-refinery centered upon thermophilic digestion. Presently, the Digested Manure Solids (DMS) are used as a low value soil amendment (compost). United Power evaluated the feasibility of processing DMS into higher value ethanol utilizing commercially available cellulosic biofuels conversion platforms. DMS was analyzed and over 100 potential technology providers were reviewed and evaluated. DMS contains enough carbon to be suitable as a biomass feedstock for conversion into ethanol by gasification technology, or as part of a conversion process that would include combined heat and power. In the first process, 100% of the feedstock is converted into ethanol. In the second process, the feedstock is combusted to provide heat to generate electrical power supporting other processes. Of the 100 technology vendors evaluated, a short list of nine technology providers was developed. From this, two vendors were selected as finalists (one was an enzymatic platform and one was a gasification platform). Their selection was based upon the technical feasibility of their systems, engineering expertise, experience in commercial or pilot scale operations, the ability or willingness to integrate the system into the Fair Oaks Biorefinery, the know-how or experience in producing bio-ethanol, and a clear path to commercial development.

  6. Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs October 19, 2015 - 12:38pm Addthis ICM Inc. announced successful completion of two 1,000-hour performance runs of its patent-pending Generation 2.0 Co-Located Cellulosic Ethanol process at its cellulosic ethanol pilot plant in St. Joseph, Missouri. This is an important step toward the commercialization of cellulosic ethanol from switchgrass and energy sorghum.

  7. Analysis of the Efficiency of the U.S. Ethanol Industry 2007 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Analysis of the Efficiency of the U.S. Ethanol Industry 2007 Analysis of the Efficiency of the U.S. Ethanol Industry 2007 The survey covers plant operations in corn dry mills, wet mills,plant type, ownership structure, capacity, feedstocks, production volumes, coproducts, PDF icon anl_ethanol_analysis_2007.pdf More Documents & Publications Current State of the U.S. Ethanol Industry Contribution of the Ethanol Industry to the Economy of the United States EA-1628: Final

  8. Alcohol as a fuel for farm and construction equipment

    SciTech Connect (OSTI)

    Borman, G L; Foster, D E; Meyers, P S; Uyehara, O A

    1982-06-01

    Work in three areas dealing with the utilization of ethanol as fuel for farm and construction diesels is summarized. The first part is a review of what is known about the retrofitting of diesels for use of ethanol and the combustion problems involved. The second part is a discussion of the work that has been done under the contract on the performance of a single-cylinder, open-chamber diesel using solutions and emulsions of diesel fuel with ethanol. Data taken include performance, emissions and cylinder pressure-time for diesel fuel with zero to forty percent ethanol by volume. Analysis of the data includes calculation of heat release rates using a single zone model. The third part is a discussion of work done retrofitting a multicylinder turbocharged farm tractor diesel to use ethanol by fumigation. Three methods of ethanol introduction are discussed; spraying ethanol upstream and downstream of the compressor and prevaporization of the ethanol. Data on performance and emissions are given for the last two methods. A three zone heat release model is described and results from the model are given. A correlation of the ignition delay using prevaporized ethanol fumigation data is also given. Comparisons are made between fumigation in DI and IDI engines.

  9. Improved fermentative alcohol production. [Patent application

    DOE Patents [OSTI]

    Wilke, C.R.; Maiorella, B.L.; Blanch, H.W.; Cysewski, G.R.

    1980-11-26

    An improved fermentation process is described for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using water load balancing (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  10. Microbial fuel cell treatment of ethanol fermentation process water

    DOE Patents [OSTI]

    Borole, Abhijeet P. (Knoxville, TN)

    2012-06-05

    The present invention relates to a method for removing inhibitor compounds from a cellulosic biomass-to-ethanol process which includes a pretreatment step of raw cellulosic biomass material and the production of fermentation process water after production and removal of ethanol from a fermentation step, the method comprising contacting said fermentation process water with an anode of a microbial fuel cell, said anode containing microbes thereon which oxidatively degrade one or more of said inhibitor compounds while producing electrical energy or hydrogen from said oxidative degradation, and wherein said anode is in electrical communication with a cathode, and a porous material (such as a porous or cation-permeable membrane) separates said anode and cathode.

  11. Siting Evaluation for Biomass-Ethanol Production in Hawaii

    SciTech Connect (OSTI)

    Kinoshita, C.M.; Zhou, J.

    2000-10-15

    This report examines four Hawaiian islands, Oahu, Hawaii, Maui, and Kauai, to identify three best combinations of potential sites and crops for producing dedicated supplies of biomass for conversion to ethanol. Key technical and economic factors considered in the siting evaluation include land availability (zoning and use), land suitability (agronomic conditions), potential quantities and costs of producing biomass feedstocks, infrastructure (including water and power supplies), transportation, and potential bioresidues to supplement dedicated energy crops.

  12. An Update on Ethanol Production and Utilization in Thailand

    SciTech Connect (OSTI)

    Bloyd, Cary N.

    2009-10-01

    Thailand has continued to promote domestic biofuel utilization. Production and consumption of biofuel in Thailand have continued to increase at a fast rate due to aggressive policies of the Thai government in reducing foreign oil import and increasing domestic renewable energy utilization. This paper focuses on ethanol production and consumption, and the use of gasohol in Thailand. The paper is an update on the previous paper--Biofuel Infrastructure Development and Utilization in Thailand--in August 2008.

  13. Pilot Integrated Cellulosic Biorefinery Operations to Fuel Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office(BETO) IBR Project Peer Review *© 2015 ICM, Inc. All Rights Reserved. *1 Recovery Act: Pilot Integrated Cellulosic Biorefinery Operations to Fuel Ethanol Award Number: DE-EE0002875 March 23, 2015 Demonstration and Market Transformation Program Douglas B. Rivers, Ph.D. ICM, Inc. Project Goal Statement  Leverage its existing pilot plant  Operate the pilot cellulosic integrated biorefinery using a biochemical platform with pretreatment and enzymatic hydrolysis technology coupled with

  14. Conversion of Lignocellulosic Biomass to Ethanol Butyl Acrylate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion of Lignocellulosic Biomass to Ethanol and Butyl Acrylate March 25, 2015 Principal Investigator Thomas P. Binder ARCHER DANIELS MIDLAND COMPANY 2 Where does ADM fit with the IBR? * Ensuring a supply of technology for future growth is a priority for ADM Research * Corn stover utilization may enable continued growth in starch supply while starting a new industry around a currently underutilized material James R Randall Research Center Decatur, IL ARCHER DANIELS MIDLAND COMPANY 3 Quad

  15. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High-Octane Mid-Level Ethanol Blend Market Assessment Caley Johnson, Emily Newes, Aaron Brooker, and Robert McCormick National Renewable Energy Laboratory Steve Peterson Lexidyne, LLC Paul Leiby, Rocio Uria Martinez, and Gbadebo Oladosu Oak Ridge National Laboratory Maxwell L. Brown Colorado School of Mines Technical Report NREL/TP-5400-63698 December 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance

  16. Alcohols as hydrogen-donor solvents for treatment of coal

    DOE Patents [OSTI]

    Ross, David S. (Palo Alto, CA); Blessing, James E. (Menlo Park, CA)

    1981-01-01

    A method for the hydroconversion of coal by solvent treatment at elevated temperatures and pressure wherein an alcohol having an .alpha.-hydrogen atom, particularly a secondary alcohol such as isopropanol, is utilized as a hydrogen donor solvent. In a particular embodiment, a base capable of providing a catalytically effective amount of the corresponding alcoholate anion under the solvent treatment conditions is added to catalyze the alcohol-coal reaction.

  17. Microbes Produce High Yields of Fatty Alcohols From Glucose - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Microbes Produce High Yields of Fatty Alcohols From Glucose Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Fatty alcohols are used in detergents, emulsifiers, lubricants and personal care items. More than 1.3 million tons of fatty alcohols are used worldwide each year, representing a $3 billion market. Currently, fatty alcohols are produced either through the processing of natural fats and oils or from petrochemicals.

  18. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

  19. Cellulosic Biomass Feedstocks and Logistics for Ethanol Production

    SciTech Connect (OSTI)

    J. Richard Hess; Christopher T. Wright; Kevin L. Kenney

    2007-10-01

    The economic competitiveness of cellulosic ethanol production is highly dependent on feedstock cost, which constitutes 35–50% of the total ethanol production cost, depending on various geographical factors and the types of systems used for harvesting, collecting, preprocessing, transporting, and handling the material. Consequently, as the deployment of cellulosic ethanol biorefi neries approaches, feedstock cost and availability are the driving factors that infl uence pioneer biorefi nery locations and will largely control the rate at which this industry grows. Initial scenarios were postulated to develop a pioneer dry feedstock supply system design case as a demonstration of the current state of technology. Based on this pioneer design, advanced scenarios were developed to determine key cost barriers, needed supply system improvements, and technology advancements to achieve government and private sector cost targets. Analysis of the pioneer supply system resulted in a delivered feedstock cost to the throat of the pretreatment reactor of $37.00 per dry tonne (2002 $). Pioneer supply systems will start by using current infrastructure and technologies and be individually designed for biorefi neries using specifi c feedstock types and varieties based on local geographic conditions. As the industry develops and cost barriers are addressed, the supply systems will incorporate advanced technologies that will eliminate downstream diversity and provide a uniform, tailored feedstock for multiple biorefi neries located in different regions.

  20. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  1. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Valkenburt, Corinne

    2009-05-01

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). However, biomass is not always available in sufficient quantity at a price compatible with fuels production. Municipal solid waste (MSW) on the other hand is readily available in large quantities in some communities and is considered a partially renewable feedstock. Furthermore, MSW may be available for little or no cost. This report provides a techno-economic analysis of the production of mixed alcohols from MSW and compares it to the costs for a wood based plant. In this analysis, MSW is processed into refuse derived fuel (RDF) and then gasified in a plant co-located with a landfill. The resulting syngas is then catalytically converted to mixed alcohols. At a scale of 2000 metric tons per day of RDF, and using current technology, the minimum ethanol selling price at a 10% rate of return is approximately $1.85/gallon ethanol (early 2008 $). However, favorable economics are dependent upon the toxicity characteristics of the waste streams and that a market exists for the by-product scrap metal recovered from the RDF process.

  2. Biogas and alcohol fuels production. Proceedings of the Seminar on Biomass, Energy for City, Farm, and Industry, Chicago, IL, October 25, 26, 1979

    SciTech Connect (OSTI)

    Goldstein, J.

    1980-01-01

    Basic principles of anaerobic digestion are considered along with the status of the Imperial Valley Biogas Project, the Department of Energy program for the recovery of energy and materials from urban waste, the principles of alcohol production from wastes, the mechanical recovery of a refuse-derived cellulosic feedstock for ethanol production, and the production of ethanol from cellulosic biomass. Attention is given to on-farm alcohol fuel production, the current status and future role of gasohol production, methane generation from small scale farms, farmsite installations of energy harvester anaerobic digesters, biogas/composting and landfill recovery, farm-scale composting as an option to anaerobic digestion, designing a high-quality biogas system, and methane as fuel of the future. A description is presented of subjects which are related to landfill gas recovery, biogas purification with permselective membranes, and anaerobic digestion of marine biomass. Other topics studied include the application of biogas technology in India, biogas production in China, biogasification of organic wastes in the Republic of the Philippines, and economics and operational experience of full-scale anaerobic dairy manure digester.

  3. Feasibility study for a 10-MM-GPY fuel ethanol plant, Brady Hot Springs, Nevada. Volume 1. Process and plant design

    SciTech Connect (OSTI)

    Not Available

    1980-09-01

    An investigation was performed to determine the technical and economic viability of constructing and operating a geothermally heated, biomass, motor fuel alcohol plant at Brady's Hot Springs. The results of the study are positive, showing that a plant of innovative, yet proven design can be built to adapt current commerical fermentation-distillation technology to the application of geothermal heat energy. The specific method of heat production from the Brady's Hot Spring wells has been successful for some time at an onion drying plant. Further development of the geothermal resource to add the capacity needed for an ethanol plant is found to be feasible for a plant sized to produce 10 million gallons of motor fuel grade ethanol per year. A very adequate supply of feedgrains is found to be available for use in the plant without impact on the local or regional feedgrain market. The effect of diverting supplies from the animal feedlots in Northern Nevada and California will be mitigated by the by-product output of high-protein feed supplements that the plant will produce. The plant will have a favorable impact on the local farming economies of Fallon, Lovelock, Winnemucca and Elko, Nevada. It will make a positive and significant socioeconomic contribution to Churchill County, providing direct employment for an additional 61 persons. Environmental impact will be negligible, involving mostly a moderate increase in local truck traffic and railroad siding activity. The report is presented in two volumes. Volume 1 deals with the technical design aspects of the plant. The second volume addresses the issue of expanded geothermal heat production at Brady's Hot Springs, goes into the details of feedstock supply economics, and looks at the markets for the plant's primary ethanol product, and the markets for its feed supplement by-products. The report concludes with an analysis of the economic viability of the proposed project.

  4. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses

    SciTech Connect (OSTI)

    Yang, Shihui; Pan, Chongle; Tschaplinski, Timothy J; Hurst, Gregory {Greg} B; Engle, Nancy L; Zhou, Wen; Dam, Phuongan; Xu, Ying; Dice, Lezlee T; Davison, Brian H; Brown, Steven D

    2013-01-01

    Zymomonas mobilis ZM4 is a capable ethanogenic bacterium with high ethanol productivity and high level of ethanol tolerance. Previous studies indicated that several stress-related proteins and changes in the ZM4 membrane lipid composition may contribute to ethanol tolerance. However, the molecular mechanisms of ethanol stress response have not been elucidated fully. In this study, ethanol stress responses were investigated using systems biology tools. Medium supplementation with an initial 47.3 g/L (6% v/v) ethanol reduced Z. mobilis ZM4 glucose consumption, growth rate and ethanol productivity compared to that of untreated controls. Metabolomic profiling showed that ethanol-treated ZM4 cells accumulated greater amounts of glycerol during the entire fermentation process, which may indicate an important role for this metabolite. A proteomic analysis of early exponential growth identified about one thousand proteins, or approximately 56% of the predicted ZM4 proteome. Proteins related to metabolism and stress response such as chaperones and key regulators were more abundant in the early ethanol stress condition. Transcriptomic studies indicated the response of ZM4 to ethanol is dynamic, complex and involves many genes from all the different functional categories. There were fewer genes significantly differentially expressed in the exponential phase compared to that of stationary phase and early stationary phase. Most down-regulated genes were related to translation and ribosome biogenesis, while the ethanol-upregulated genes were mostly related to cellular processes and metabolism. Correlations among the transcriptomics, proteomics and metabolism were examined and among significantly expressed genes or proteins, we observe higher correlation coefficients when fold-change values are higher. This systems biology study elucidates key Z. mobilis ZM4 metabolites, genes and proteins that form the foundation of its distinctive physiology and its multifaceted response to ethanol stress.

  5. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Presentation) | Department of Energy Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. PDF icon 04_h2gen_low-cost_h2_distributed_production_systems.pdf More Documents & Publications Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

  6. Method for producing ethanol and co-products from cellulosic biomass

    DOE Patents [OSTI]

    Nguyen, Quang A

    2013-10-01

    The present invention generally relates to processes for production of ethanol from cellulosic biomass. The present invention also relates to production of various co-products of preparation of ethanol from cellulosic biomass. The present invention further relates to improvements in one or more aspects of preparation of ethanol from cellulosic biomass including, for example, improved methods for cleaning biomass feedstocks, improved acid impregnation, and improved steam treatment, or "steam explosion."

  7. Ethanol production using a soy hydrolysate-based medium or a yeast autolysate-based medium

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL)

    2000-01-01

    This invention presents a method for the production of ethanol that utilizes a soy hydrolysate-based nutrient medium or a yeast autolysate-based medium nutrient medium in conjunction with ethanologenic bacteria and a fermentable sugar for the cost-effective production of ethanol from lignocellulosic biomass. The invention offers several advantages over presently available media for use in ethanol production, including consistent quality, lack of toxins and wide availability.

  8. Leaders in Future and Current Technology Teaming Up to Improve Ethanol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production Leaders in Future and Current Technology Teaming Up to Improve Ethanol Production For more information contact: Gary Schmitz, 303-275-4050 email: Gary Schmitz Golden, Colo., May 30, 2001 - Under a cooperative research and development agreement, the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) is teaming with Broin and Associates, Inc., a major ethanol producer, to develop new technologies to improve the efficiency of U.S. ethanol production. The

  9. Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Characterized particulate emissions from U.S.-legal stoichiometric GDI and European certified lean-burn GDI vehicles operating on ethanol blends PDF icon deer11_storey.pdf More Documents & Publications Measurement and Characterization of Unregulated Emissions from Advanced Technologies Measurement and Characterization of Unregulated Emissions from Advanced

  10. Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  11. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and

  12. Project Profile: Thermochemical Storage with Anhydrous Ammonia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One of the key aims of the research is to design and build a synthesis reactor that is optimized for the direct production of supercritical steam at 650C. Approach Ammonia ...

  13. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  14. 2007 Year in Review - U.S. Ethanol Industry: The Next Inflection Point

    SciTech Connect (OSTI)

    Curtis, Brian

    2008-05-01

    This report provides an objective view of the evolving ethanol industry and many of its key participants. This report covers the period Jan 2007–Feb 2008.

  15. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  16. Process for producing ethanol from plant biomass using the fungus Paecilomyces sp

    DOE Patents [OSTI]

    Wu, J.F.

    1985-08-08

    A process for producing ethanol from plant biomass is disclosed. The process includes forming a substrate from the biomass with the substrate including hydrolysates of cellulose and hemicellulose. A species of the fungus Paecilomyces which has the ability to ferment both cellobiose and xylose to ethanol is then selected and isolated. The substrate is inoculated with this fungus, and the inoculated substrate is then fermented under conditions favorable for cell viability and conversion of hydrolysates to ethanol. Finally, ethanol is recovered from the fermented substrate. 5 figs., 3 tabs.

  17. Process for producing ethanol from plant biomass using the fungus paecilomyces sp.

    DOE Patents [OSTI]

    Wu, Jung Fu

    1989-01-01

    A process for producing ethanol from plant biomass is disclosed. The process in cludes forming a substrate from the biomass with the substrate including hydrolysates of cellulose and hemicellulose. A species of the fungus Paecilomyces, which has the ability to ferment both cellobiose and xylose to ethanol, is then selected and isolated. The substrate is inoculated with this fungus, and the inoculated substrate is then fermented under conditions favorable for cell viability and conversion of hydrolysates to ethanol. Finally, ethanol is recovered from the fermented substrate.

  18. Biochemical Production of Ethanol from Corn Stover: 2008 State of Technology Model

    SciTech Connect (OSTI)

    Humbird, D.; Aden, A.

    2009-08-01

    An update to the FY 2007 assessment of the state of technical research progress toward biochemical process goals, quantified in terms of Minimum Ethanol Selling Price.

  19. Key Benefits in Using Ethanol-Diesel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Verifying the Benefits and Resolving the Issues in the Commercialization of Ethanol Containing Diesel Fuels Biodiesel Basics (Fact Sheet), Vehicle Technologies Program (VTP) ...

  20. Fact #588: September 14, 2009 Fuel Economy Changes Due to Ethanol Content |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 8: September 14, 2009 Fuel Economy Changes Due to Ethanol Content Fact #588: September 14, 2009 Fuel Economy Changes Due to Ethanol Content The fuel economy of a vehicle is dependent on many things, one of which is the fuel used in the vehicle. Two National Laboratories recently studied the effects that ethanol blends have on the fuel economy of light vehicles. The results are not surprising, since a gallon of ethanol does not have as much energy as a gallon of gasoline.

  1. Mixed waste paper to ethanol fuel. A technology, market, and economic assessment for Washington

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The objectives of this study were to evaluate the use of mixed waste paper for the production of ethanol fuels and to review the available conversion technologies, and assess developmental status, current and future cost of production and economics, and the market potential. This report is based on the results of literature reviews, telephone conversations, and interviews. Mixed waste paper samples from residential and commercial recycling programs and pulp mill sludge provided by Weyerhauser were analyzed to determine the potential ethanol yields. The markets for ethanol fuel and the economics of converting paper into ethanol were investigated.

  2. Current State of the U.S. Ethanol Industry | Department of Energy

    Office of Environmental Management (EM)

    Current State of the U.S. Ethanol Industry Current State of the U.S. Ethanol Industry "The objective of this study is to provide a comprehensive overview of the state of the U.S. ethanol industry and to outline the major forces that will affect the development of the industry over the next decade. " PDF icon Current State of the U.S. Ethanol Industry More Documents & Publications U.S. Biofuels Industry: Mind the Gap Before the Subcommittee on Energy and Power - Committee on Energy

  3. DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the

    Office of Environmental Management (EM)

    Advanced Biofuels Industry | Department of Energy DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels Industry DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels Industry November 20, 2015 - 12:49pm Addthis DuPont’s cellulosic ethanol biorefinery in Nevada, Iowa, opened on October 30, 2015. | Photo courtesy of DuPont DuPont's cellulosic ethanol biorefinery in Nevada, Iowa, opened on October 30, 2015. | Photo courtesy

  4. EA-1848: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran, Storey

    Office of Environmental Management (EM)

    County, NV | Department of Energy 8: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran, Storey County, NV EA-1848: Fulcrum Sierra Waste-to-Ethanol Facility in McCarran, Storey County, NV June 1, 2011 EA-1848: Final Environmental Assessment Loan Guarantee To Fulcrum Sierra Biofuels, LLC For A Waste-To-Ethanol Facility In Mccarran, Storey County, Nevada June 21, 2011 EA-1848: Finding of No Significant Impact Loan Guarantee to Fulcrum Sierra Biofuels, LLC for Waste-to-Ethanol Facility in

  5. EERE Success Story-Pilot Plant Completes Two 1,000-Hour Ethanol

    Office of Environmental Management (EM)

    Performance Runs | Department of Energy Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs EERE Success Story-Pilot Plant Completes Two 1,000-Hour Ethanol Performance Runs January 22, 2016 - 11:01am Addthis ICM Inc. announced successful completion of two 1,000-hour performance runs of its patent-pending Generation 2.0 Co-Located Cellulosic Ethanol process at its cellulosic ethanol pilot plant in St. Joseph, Missouri. This is an important step toward the commercialization of

  6. Surface-induced anisotropic orientations of interfacial ethanol molecules at air/sapphire (1-102) and ethanol/sapphire (1-102) interfaces

    SciTech Connect (OSTI)

    Sung, J.; Waychunas, G. A.; Shen, Y. R.

    2011-06-01

    Sum frequency vibrational spectroscopy was used to study the interfacial arrangement of ethanol molecules at the vapor/α-Al{sub 2}O{sub 3} (1{bar 1}02 ) and α-Al{sub 2}O{sub 3} (1{bar 1}02 )/ethanol liquid interfaces. The spectra in the C-H range show that ethanol molecules adsorbed from vapor onto α-Al{sub 2}O{sub 3} (1{bar 1}02 ) surface have a welldefined anisotropic arrangement following the structure of the α-Al{sub 2}O{sub 3} (1{bar 1}02 ) surface. The arrangement can be explained by the formation of two specific hydrogen bonds between the adsorbed ethanol molecule and hydroxyls on the sapphire surface. At the α-Al{sub 2}O{sub 3} (1{bar 1}02 )/ethanol liquid interface, the first ethanol monolayer assumes a similar anisotropic arrangement as in the case of an ethanol monolayer on the dry sapphire surface. The second monolayer has a rather broad orientation distribution that is azimuthally nearly isotropic, but with molecules flipped 180 degrees with respect to those in the first monolayer.

  7. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However, the strength of the secondary flow is found nearly the same behind the first and the second vortex generator pair as well as far from the second vortex generator pair in the case of Duct2. Both ducts are able to create a counter-rotating and a second set of twin foci. Duct2 is able to create the second set of twin foci in an earlier streamwise location than Duct1, as these foci are well-known to their heat transfer augmentation. A larger vortex formation area and a greater induced vorticity field between vortex pairs are observed for Duct2 compared with Duct1. As the induced flow field between the vortex pairs increases the heat transfer, and as the flow field between the vortex cores is found larger in the case of Duct2, therefore, it is expected to obtain better heat transfer characteristics for Duct2 compared with Duct1. (author)

  8. Limonene and tetrahydrofurfuryl alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, G.W.; Carter, R.D.; Hand, T.E.; Powers, M.T.

    1997-10-21

    The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  9. Limonene and tetrahydrofurfurly alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Carter, Richard D. (Lee's Summit, MO); Hand, Thomas E. (Lee's Summit, MO); Powers, Michael T. (Santa Rosa, CA)

    1997-10-21

    The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  10. Limonene and tetrahydrofurfuryl alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Carter, Richard D. (Lee's Summit, MO); Hand, Thomas E. (Lee's Summit, MO); Powers, Michael T. (Santa Rosa, CA)

    1996-05-07

    The present invention is a tetrahydrofurfuryl alcohol and limonene or terpineol cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  11. Fermentation pattern of sucrose to ethanol conversions by Zymomonas mobilis

    SciTech Connect (OSTI)

    Lyness, Ed.; Doelle, H.W.

    1981-07-01

    General patterns of sucrose fermentation by two strains of Zymomonas mobilis, designated Z7 and Z10, were established using sucrose concentrations from 50 to 200 g/liter. Strain Z7 showed a higher invertase activity than Z10. Strain Z10 showed a reduced specific growth rate a high sucrose concentrations while Z7 was unaffected. High sucrose hydrolyzing activity in strain Z7 lead to glucose accumulation in the medium at high sucrose concentrations. Ethanol production and fermentation time depend on the rate of catabolism of the products of sucrose hydrolysis, glucose and fructose. 10 refs.

  12. Demonstration of alcohol as an aviation fuel

    SciTech Connect (OSTI)

    1996-07-01

    A recently funded Southeastern Regional Biomass Energy Program (SERBEP) project with Baylor University will demonstrate the effectiveness of ethanols as an aviation fuel while providing several environmental and economic benefits. Part of this concern is caused by the petroleum industry. The basis for the petroleum industry to find an alternative aviation fuel will be dictated mainly by economic considerations. Three other facts compound the problem. First is the disposal of oil used in engines burning leaded fuel. This oil will contain too much lead to be burned in incinerators and will have to be treated as a toxic waste with relatively high disposal fees. Second, as a result of a greater demand for alkalites to be used in the automotive reformulated fuel, the costs of these components are likely to increase. Third, the Montreal Protocol will ban in 1998 the use of Ethyl-Di-Bromide, a lead scavenger used in leaded aviation fuel. Without a lead scavenger, leaded fuels cannot be used. The search for alternatives to leaded aviation fuels has been underway by different organizations for some time. As part of the search for alternatives, the Renewable Aviation Fuels Development Center (RAFDC) at Baylor University in Waco, Texas, has received a grant from the Federal Aviation Administration (FAA) to improve the efficiencies of ethanol powered aircraft engines and to test other non-petroleum alternatives to aviation fuel.

  13. Ethanol increases matrix metalloproteinase-12 expression via NADPH oxidase-dependent ROS production in macrophages

    SciTech Connect (OSTI)

    Kim, Mi Jin; Nepal, Saroj; Lee, Eung-Seok; Jeong, Tae Cheon; Kim, Sang-Hyun; Park, Pil-Hoon

    2013-11-15

    Matrix metalloproteinase-12 (MMP-12), an enzyme responsible for degradation of extracellular matrix, plays an important role in the progression of various diseases, including inflammation and fibrosis. Although most of those are pathogenic conditions induced by ethanol ingestion, the effect of ethanol on MMP-12 has not been explored. In the present study, we investigated the effect of ethanol on MMP-12 expression and its potential mechanisms in macrophages. Here, we demonstrated that ethanol treatment increased MMP-12 expression in primary murine peritoneal macrophages and RAW 264.7 macrophages at both mRNA and protein levels. Ethanol treatment also significantly increased the activity of nicotinamide adenine dinucleotide (NADPH) oxidase and the expression of NADPH oxidase-2 (Nox2). Pretreatment with an anti-oxidant (N-acetyl cysteine) or a selective inhibitor of NADPH oxidase (diphenyleneiodonium chloride (DPI)) prevented ethanol-induced MMP-12 expression. Furthermore, knockdown of Nox2 by small interfering RNA (siRNA) prevented ethanol-induced ROS production and MMP-12 expression in RAW 264.7 macrophages, indicating a critical role for Nox2 in ethanol-induced intracellular ROS production and MMP-12 expression in macrophages. We also showed that ethanol-induced Nox2 expression was suppressed by transient transfection with dominant negative I?B-? plasmid or pretreatment with Bay 11-7082, a selective inhibitor of NF-?B, in RAW 264.7 macrophages. In addition, ethanol-induced Nox2 expression was also attenuated by treatment with a selective inhibitor of p38 MAPK, suggesting involvement of p38 MAPK/NF-?B pathway in ethanol-induced Nox2 expression. Taken together, these results demonstrate that ethanol treatment elicited increase in MMP-12 expression via increase in ROS production derived from Nox2 in macrophages. - Highlights: • Ethanol increases ROS production through up-regulation of Nox2 in macrophages. • Enhanced oxidative stress contributes to ethanol-induced MMP-12 expression. • p38 MAPK/NF-?B signaling pathway modulates ethanol-induced Nox2 expression.

  14. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  15. Economic contribution of lignins to ethanol production from biomass

    SciTech Connect (OSTI)

    Chum, H.L.; Parker, S.K.; Feinberg, D.A.; Wright, J.D.; Rice, P.A.; Sinclair, S.A.; Glasser, W.G.

    1985-05-01

    Lignin, one of the three major polymeric components of biomass (16% to 33% by weight in wood), has the highest specific heat content. Therefore, it can be burned for process fuel. Compared to coal, its fuel value is 2.2 cents/lb. This report investigates markets for lignin utilization of higher value. After lignin isolation from the process, purchase of replacement fuel (coal was analyzed), lignin sale for the manufacture of solid materials or higher value octane enhancers was evaluated. Polymeric applications evaluated were: surfactants, asphalt, carbon black, adhesives, and lignin plastics; agricultural applications were briefly reviewed. These lignins would generate coproduct credits of 25 cents to 150 cents/gallon of ethanol respectively for 7.5 cents to 60 cents/lb lignin value (isolation and eventual modification costs were taken into account). Overall markets for these polymeric applications were projected at 11 billion lb/year by the year 2000. These projections are intensities of demand and not actual shipments of lignins. In addition, this report investigates the possibility of converting lignins into mixtures of methyls aryl ethers and methyl substituted-aryl ethers which are high value octane enhancers, fully compatible with gasoline. The report intends to show that if fuel ethanol production in the billions of gallons scale occurs lignin markets would not be saturated. 10 refs., 14 figs., 36 tabs.

  16. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene

    SciTech Connect (OSTI)

    Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

    2014-09-18

    The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

  17. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  18. Cellulosic Ethanol Technology on Track to Being Competitive With Other Transportation Fuels (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01

    Researchers at the National Renewable Energy Laboratory (NREL) have been driving down the cost of cellulosic ethanol and overcoming the technical challenges that surround it-major milestones toward the Department of Energy (DOE) goal of making cellulosic ethanol cost-competitive by 2012.

  19. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Book)

    SciTech Connect (OSTI)

    Moriarty, K.

    2013-09-01

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  20. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends

    SciTech Connect (OSTI)

    2013-09-17

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.