Sample records for analytical method ammonia

  1. Method for releasing hydrogen from ammonia borane

    DOE Patents [OSTI]

    Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

    2013-02-19T23:59:59.000Z

    A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

  2. ANALYTICAL METHODS in CHEMICAL ECOLOGY

    E-Print Network [OSTI]

    ANALYTICAL METHODS in CHEMICAL ECOLOGY a post graduate course (doktorandkurs) when: February 10 ­ 28, 2014 where: Chemical Ecology, Plant Protection Biology, Swedish University of Agriculture (SLU to modern analytical methods used in Chemical Ecological and Ecotoxicological research, such as: methods

  3. RADON 131 7. ANALYTICAL METHODS

    E-Print Network [OSTI]

    unknown authors

    The purpose of this chapter is to describe the analytical methods that are available for detecting, measuring, and/or monitoring radon and its progeny. The intent is not to provide an exhaustive list of analytical methods. Rather, the intention is to identify well-established methods that are used as the standard methods of analysis. Many of the analytical methods used for environmental samples are the methods approved by federal agencies and organizations such as EPA and the National Institute for Occupational Safety and Health (NIOSH). Other methods presented in this chapter are those that are approved by groups such as the Association of Official Analytical Chemists (AOAC) and the American Public Health Association (APHA). Additionally, analytical methods are included that modify previously used methods to obtain lower detection limits and/or to improve accuracy and precision. 7.1 BIOLOGICAL MATERIALS Table 7-1 lists various methods used to detect radon progeny in biological samples. Since the half-life of radon is short, its measurement in biological samples, such as serum, urine, blood, etc., is not practical. Measurements of the longer lived radon progeny 210 Pb and 210 Po in biological samples may be used as an indication of radon exposure; however, ingestion of these isotopes from food and drinking water or direct exposure from other environmental media are considered the primary sources of exposure for these

  4. Hydrogen Fuel Quality - Focus: Analytical Methods Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results...

  5. ammonia release method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. Method of identity analyte-binding peptides

    DOE Patents [OSTI]

    Kauvar, L.M.

    1990-10-16T23:59:59.000Z

    A method for affinity chromatography or adsorption of a designated analyte utilizes a paralog as the affinity partner. The immobilized paralog can be used in purification or analysis of the analyte; the paralog can also be used as a substitute for antibody in an immunoassay. The paralog is identified by screening candidate peptide sequences of 4--20 amino acids for specific affinity to the analyte. 5 figs.

  7. Method and apparatus for detecting an analyte

    DOE Patents [OSTI]

    Allendorf, Mark D. (Pleasanton, CA); Hesketh, Peter J. (Atlanta, GA)

    2011-11-29T23:59:59.000Z

    We describe the use of coordination polymers (CP) as coatings on microcantilevers for the detection of chemical analytes. CP exhibit changes in unit cell parameters upon adsorption of analytes, which will induce a stress in a static microcantilever upon which a CP layer is deposited. We also describe fabrication methods for depositing CP layers on surfaces.

  8. Secondary waste minimization in analytical methods

    SciTech Connect (OSTI)

    Green, D.W.; Smith, L.L.; Crain, J.S.; Boparai, A.S.; Kiely, J.T.; Yaeger, J.S.; Schilling, J.B. [Argonne National Lab., IL (United States). Analytical Chemistry Lab.

    1995-07-01T23:59:59.000Z

    The characterization phase of site remediation is an important and costly part of the process. Because toxic solvents and other hazardous materials are used in common analytical methods, characterization is also a source of new waste, including mixed waste. Alternative analytical methods can reduce the volume or form of hazardous waste produced either in the sample preparation step or in the measurement step. The authors are examining alternative methods in the areas of inorganic, radiological, and organic analysis. For determining inorganic constituents, alternative methods were studied for sample introduction into inductively coupled plasma spectrometers. Figures of merit for the alternative methods, as well as their associated waste volumes, were compared with the conventional approaches. In the radiological area, the authors are comparing conventional methods for gross {alpha}/{beta} measurements of soil samples to an alternative method that uses high-pressure microwave dissolution. For determination of organic constituents, microwave-assisted extraction was studied for RCRA regulated semivolatile organics in a variety of solid matrices, including spiked samples in blank soil; polynuclear aromatic hydrocarbons in soils, sludges, and sediments; and semivolatile organics in soil. Extraction efficiencies were determined under varying conditions of time, temperature, microwave power, moisture content, and extraction solvent. Solvent usage was cut from the 300 mL used in conventional extraction methods to about 30 mL. Extraction results varied from one matrix to another. In most cases, the microwave-assisted extraction technique was as efficient as the more common Soxhlet or sonication extraction techniques.

  9. System and method for determining an ammonia generation rate in a three-way catalyst

    DOE Patents [OSTI]

    Sun, Min; Perry, Kevin L; Kim, Chang H

    2014-12-30T23:59:59.000Z

    A system according to the principles of the present disclosure includes a rate determination module, a storage level determination module, and an air/fuel ratio control module. The rate determination module determines an ammonia generation rate in a three-way catalyst based on a reaction efficiency and a reactant level. The storage level determination module determines an ammonia storage level in a selective catalytic reduction (SCR) catalyst positioned downstream from the three-way catalyst based on the ammonia generation rate. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the ammonia storage level.

  10. Analytical methods for VLSI module placement

    E-Print Network [OSTI]

    Wang, Qinke

    2006-01-01T23:59:59.000Z

    in Figure 2.6. The conjugate gradient method is quite usefulIn general, the conjugate gradient method ?nds the minimumexactly. Variant of conjugate gradient methods di?er in how

  11. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  12. Data Analytics Methods in Wind Turbine Design and Operations

    E-Print Network [OSTI]

    Lee, Giwhyun

    2013-05-22T23:59:59.000Z

    This dissertation develops sophisticated data analytic methods to analyze structural loads on, and power generation of, wind turbines. Wind turbines, which convert the kinetic energy in wind into electrical power, are operated within stochastic...

  13. Data Analytics Methods in Wind Turbine Design and Operations 

    E-Print Network [OSTI]

    Lee, Giwhyun

    2013-05-22T23:59:59.000Z

    This dissertation develops sophisticated data analytic methods to analyze structural loads on, and power generation of, wind turbines. Wind turbines, which convert the kinetic energy in wind into electrical power, are operated within stochastic...

  14. Analytical homogenization method for periodic composite materials

    E-Print Network [OSTI]

    Chen, Ying

    We present an easy-to-implement technique for determining the effective properties of composite materials with periodic microstructures, as well as the field distributions in them. Our method is based on the transformation ...

  15. Statistically qualified neuro-analytic failure detection method and system

    DOE Patents [OSTI]

    Vilim, Richard B. (Aurora, IL); Garcia, Humberto E. (Idaho Falls, ID); Chen, Frederick W. (Naperville, IL)

    2002-03-02T23:59:59.000Z

    An apparatus and method for monitoring a process involve development and application of a statistically qualified neuro-analytic (SQNA) model to accurately and reliably identify process change. The development of the SQNA model is accomplished in two stages: deterministic model adaption and stochastic model modification of the deterministic model adaptation. Deterministic model adaption involves formulating an analytic model of the process representing known process characteristics, augmenting the analytic model with a neural network that captures unknown process characteristics, and training the resulting neuro-analytic model by adjusting the neural network weights according to a unique scaled equation error minimization technique. Stochastic model modification involves qualifying any remaining uncertainty in the trained neuro-analytic model by formulating a likelihood function, given an error propagation equation, for computing the probability that the neuro-analytic model generates measured process output. Preferably, the developed SQNA model is validated using known sequential probability ratio tests and applied to the process as an on-line monitoring system. Illustrative of the method and apparatus, the method is applied to a peristaltic pump system.

  16. analytical methods biodiesel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methods biodiesel First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Biodiesel analytical development and...

  17. AIR: fused Analytical and Iterative Reconstruction method for computed tomography

    E-Print Network [OSTI]

    Yang, Liu; Qi, Sharon X; Gao, Hao

    2013-01-01T23:59:59.000Z

    Purpose: CT image reconstruction techniques have two major categories: analytical reconstruction (AR) method and iterative reconstruction (IR) method. AR reconstructs images through analytical formulas, such as filtered backprojection (FBP) in 2D and Feldkamp-Davis-Kress (FDK) method in 3D, which can be either mathematically exact or approximate. On the other hand, IR is often based on the discrete forward model of X-ray transform and formulated as a minimization problem with some appropriate image regularization method, so that the reconstructed image corresponds to the minimizer of the optimization problem. This work is to investigate the fused analytical and iterative reconstruction (AIR) method. Methods: Based on IR with L1-type image regularization, AIR is formulated with a AR-specific preconditioner in the data fidelity term, which results in the minimal change of the solution algorithm that replaces the adjoint X-ray transform by the filtered X-ray transform. As a proof-of-concept 2D example of AIR, FB...

  18. Analytical Methods for Measuring Mercury in Water, Sediment and Biota

    SciTech Connect (OSTI)

    Lasorsa, Brenda K.; Gill, Gary A.; Horvat, Milena

    2012-06-07T23:59:59.000Z

    Mercury (Hg) exists in a large number of physical and chemical forms with a wide range of properties. Conversion between these different forms provides the basis for mercury's complex distribution pattern in local and global cycles and for its biological enrichment and effects. Since the 1960’s, the growing awareness of environmental mercury pollution has stimulated the development of more accurate, precise and efficient methods of determining mercury and its compounds in a wide variety of matrices. During recent years new analytical techniques have become available that have contributed significantly to the understanding of mercury chemistry in natural systems. In particular, these include ultra sensitive and specific analytical equipment and contamination-free methodologies. These improvements allow for the determination of total mercury as well as major species of mercury to be made in water, sediments and soils, and biota. Analytical methods are selected depending on the nature of the sample, the concentration levels of mercury, and what species or fraction is to be quantified. The terms “speciation” and “fractionation” in analytical chemistry were addressed by the International Union for Pure and Applied Chemistry (IUPAC) which published guidelines (Templeton et al., 2000) or recommendations for the definition of speciation analysis. "Speciation analysis is the analytical activity of identifying and/or measuring the quantities of one or more individual chemical species in a sample. The chemical species are specific forms of an element defined as to isotopic composition, electronic or oxidation state, and/or complex or molecular structure. The speciation of an element is the distribution of an element amongst defined chemical species in a system. In case that it is not possible to determine the concentration of the different individual chemical species that sum up the total concentration of an element in a given matrix, meaning it is impossible to determine the speciation, it is a useful practice to do fractionation instead. Fractionation is the process of classification of an analyte or a group of analytes from a certain sample according to physical (e.g. size, solubility) or chemical (e.g. bonding, reactivity) properties."

  19. ANALYTICAL METHODS FOR DISCRIMINATING STARDUST IN AEROGEL CAPTURE MEDIA

    E-Print Network [OSTI]

    Sean Brennan; Hope A. Ishii; John P. Bradley; Katharina Luening; Piero Pianetta

    Methods using X-ray fluorescence have been developed to identify cometary material captured in aerogel during the NASA Stardust mission to Comet 81P/Wild 2. These analytical methods are necessitated by the levels of trace contaminants present in the aerogel. The cometary material disaggregates during deceleration in the aerogel, so fluorescence mapping of the entire track (which can be several millimeters long) is necessary. Distinguishing those pixels which have cometary material and aerogel from those which have only cometary material can be very challenging. We have chosen a “dual threshold ” method, with some pixels clearly having only aerogel (plus contaminants) and other pixels clearly having cometary and aerogel material. Between these two threshold levels is a set of pixels which cannot be easily ascribed to one or the other. By leaving these pixels out of the analysis, the estimate of cometary material is improved.

  20. SASSI Analytical Methods Compared with SHAKE Results | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM615_CostNSAR -DepartmentRetailEnergy RoleAnalytical Methods Compared

  1. SASSI Analytical Methods Compared with SHAKE Free-Field Results

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergy SmallImplementing theFinancing »Future InitiativesofAnalytical Methods

  2. A method for interpreting continental and analytic epistemology

    E-Print Network [OSTI]

    McCoy, Sarah Ruth

    1999-01-01T23:59:59.000Z

    of this thesis is to investigate the feasibility and profitability of communication between analytic and continental philosophy in epistemology. Wittgenstein's concept of language games will be used to frame the issue', continental and analytic philosophers play...

  3. analytical method based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kholghi, Mahnoosh 2011-01-01 276 Comparative analysis of remaining oil saturation in waterflood patterns based on analytical modeling and simulation Texas A&M University -...

  4. NIOSH Manual of Analytical Methods (third edition). Fourth supplement

    SciTech Connect (OSTI)

    Not Available

    1990-08-15T23:59:59.000Z

    The NIOSH Manual of Analytical Methods, 3rd edition, was updated for the following chemicals: allyl-glycidyl-ether, 2-aminopyridine, aspartame, bromine, chlorine, n-butylamine, n-butyl-glycidyl-ether, carbon-dioxide, carbon-monoxide, chlorinated-camphene, chloroacetaldehyde, p-chlorophenol, crotonaldehyde, 1,1-dimethylhydrazine, dinitro-o-cresol, ethyl-acetate, ethyl-formate, ethylenimine, sodium-fluoride, hydrogen-fluoride, cryolite, sodium-hexafluoroaluminate, formic-acid, hexachlorobutadiene, hydrogen-cyanide, hydrogen-sulfide, isopropyl-acetate, isopropyl-ether, isopropyl-glycidyl-ether, lead, lead-oxide, maleic-anhydride, methyl-acetate, methyl-acrylate, methyl-tert-butyl ether, methyl-cellosolve-acetate, methylcyclohexanol, 4,4'-methylenedianiline, monomethylaniline, monomethylhydrazine, nitric-oxide, p-nitroaniline, phenyl-ether, phenyl-ether-biphenyl mixture, phenyl-glycidyl-ether, phenylhydrazine, phosphine, ronnel, sulfuryl-fluoride, talc, tributyl-phosphate, 1,1,2-trichloro-1,2,2-trifluoroethane, trimellitic-anhydride, triorthocresyl-phosphate, triphenyl-phosphate, and vinyl-acetate.

  5. Estimating Fuel Cycle Externalities: Analytical Methods and Issues, Report 2

    SciTech Connect (OSTI)

    Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

    1994-07-01T23:59:59.000Z

    The activities that produce electric power typically range from extracting and transporting a fuel, to its conversion into electric power, and finally to the disposition of residual by-products. This chain of activities is called a fuel cycle. A fuel cycle has emissions and other effects that result in unintended consequences. When these consequences affect third parties (i.e., those other than the producers and consumers of the fuel-cycle activity) in a way that is not reflected in the price of electricity, they are termed ''hidden'' social costs or externalities. They are the economic value of environmental, health and any other impacts, that the price of electricity does not reflect. How do you estimate the externalities of fuel cycles? Our previous report describes a methodological framework for doing so--called the damage function approach. This approach consists of five steps: (1) characterize the most important fuel cycle activities and their discharges, where importance is based on the expected magnitude of their externalities, (2) estimate the changes in pollutant concentrations or other effects of those activities, by modeling the dispersion and transformation of each pollutant, (3) calculate the impacts on ecosystems, human health, and any other resources of value (such as man-made structures), (4) translate the estimates of impacts into economic terms to estimate damages and benefits, and (5) assess the extent to which these damages and benefits are externalities, not reflected in the price of electricity. Each step requires a different set of equations, models and analysis. Analysts generally believe this to be the best approach for estimating externalities, but it has hardly been used! The reason is that it requires considerable analysis and calculation, and to this point in time, the necessary equations and models have not been assembled. Equally important, the process of identifying and estimating externalities leads to a number of complex issues that also have not been fully addressed. This document contains two types of papers that seek to fill part of this void. Some of the papers describe analytical methods that can be applied to one of the five steps of the damage function approach. The other papers discuss some of the complex issues that arise in trying to estimate externalities. This report, the second in a series of eight reports, is part of a joint study by the U.S. Department of Energy (DOE) and the Commission of the European Communities (EC)* on the externalities of fuel cycles. Most of the papers in this report were originally written as working papers during the initial phases of this study. The papers provide descriptions of the (non-radiological) atmospheric dispersion modeling that the study uses; reviews much of the relevant literature on ecological and health effects, and on the economic valuation of those impacts; contains several papers on some of the more complex and contentious issues in estimating externalities; and describes a method for depicting the quality of scientific information that a study uses. The analytical methods and issues that this report discusses generally pertain to more than one of the fuel cycles, though not necessarily to all of them. The report is divided into six parts, each one focusing on a different subject area.

  6. analytical modeling method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2006-11-21 396 Coupled thermodynamic-dynamic semi-analytical model of Free Piston Stirling engines CERN Preprints Summary: The study of free piston Stirling engine (FPSE)...

  7. Method to remove ammonia using a proton-conducting ceramic membrane

    DOE Patents [OSTI]

    2003-10-07T23:59:59.000Z

    An apparatus and method for decomposing NH.sub.3. A fluid containing NH.sub.3 is passed in contact with a tubular membrane that is a homogeneous mixture of a ceramic and a first metal, with the ceramic being selected from one or more of a cerate having the formula of M'Ce.sub.1-x M".sub.3-.delta., zirconates having the formula M'Zr.sub.1-x M"O.sub.3-.delta., stannates having the formula M'Sn.sub.1-x M'O.sub.3-.delta., where M' is a group IIA metal, M" is a dopant metal of one or more of Ca, Y, Yb, In, Nd, Gd or mixtures thereof and .delta. is a variable depending on the concentration of dopant and is in the range of from 0.001 to 0.5, the first metal is a group VIII or group IB element selected from the group consisting of Pt, Ag, Pd, Fe, Co, Cr, Mn, V, Ni, Au, Cu, Rh, Ru and mixtures thereof. The tubular membrane has a catalytic metal on the side thereof in contact with the fluid containing NH.sub.3 which is effective to cause NH.sub.3 to decompose to N.sub.2 and H.sub.2. When the H.sub.2 contacts the membrane H.sup.+ ions are formed which pass through the membrane driving the NH.sub.3 decomposition toward completion.

  8. Hanford environmental analytical methods: Methods as of March 1990. Volume 3, Appendix A2-I

    SciTech Connect (OSTI)

    Goheen, S.C.; McCulloch, M.; Daniel, J.L.

    1993-05-01T23:59:59.000Z

    This paper from the analytical laboratories at Hanford describes the method used to measure pH of single-shell tank core samples. Sludge or solid samples are mixed with deionized water. The pH electrode used combines both a sensor and reference electrode in one unit. The meter amplifies the input signal from the electrode and displays the pH visually.

  9. Method for Operating a Sensor to Differentiate Between Analytes in a Sample

    DOE Patents [OSTI]

    Kunt, Tekin; Cavicchi, Richard E.; Semancik, Stephen; McAvoy, Thomas J.

    1998-07-28T23:59:59.000Z

    Disclosed is a method for operating a sensor to differentiate between first and second analytes in a sample. The method comprises the steps of determining a input profile for the sensor which will enhance the difference in the output profiles of the sensor as between the first analyte and the second analyte; determining a first analyte output profile as observed when the input profile is applied to the sensor; determining a second analyte output profile as observed when the temperature profile is applied to the sensor; introducing the sensor to the sample while applying the temperature profile to the sensor, thereby obtaining a sample output profile; and evaluating the sample output profile as against the first and second analyte output profiles to thereby determine which of the analytes is present in the sample.

  10. Ammonia Process by Pressure Swing Adsorption

    SciTech Connect (OSTI)

    Dr Felix Jegede

    2010-12-27T23:59:59.000Z

    The overall objective of the project is to design, develop and demonstrate a technically feasible and commercially viable system to produce ammonia along with recovery of the products by adsorption separation methods and significantly decrease the energy requirement in ammonia production. This is achieved through a significantly more efficient ammonia psa recovery system. The new ammonia recovery system receives the reactor effluents and achieves complete ammonia recovery, (which completely eliminates the energy intensive refrigeration and condensation system currently used in ammonia production). It also recovers the unused reactants and recycles them back to the reactor, free of potential reactor contaminants, and without the need for re-compression and re-heat of recycle stream thereby further saving more energy. The result is a significantly lower energy consumption, along with capital cost savings.

  11. SASSI Analytical Methods Compared with SHAKE Free-Field Results

    Office of Environmental Management (EM)

    1210 281 400 Modified subtraction 1210 362 400 Direct Method 1210 605 400 Model Statistics 7 3D FEM Box Embedded Box Model Direct Method Model Interaction Nodes Subtraction...

  12. Manual of analytical methods for the Industrial Hygiene Chemistry Laboratory

    SciTech Connect (OSTI)

    Greulich, K.A.; Gray, C.E. (comp.)

    1991-08-01T23:59:59.000Z

    This Manual is compiled from techniques used in the Industrial Hygiene Chemistry Laboratory of Sandia National Laboratories in Albuquerque, New Mexico. The procedures are similar to those used in other laboratories devoted to industrial hygiene practices. Some of the methods are standard; some, modified to suit our needs; and still others, developed at Sandia. The authors have attempted to present all methods in a simple and concise manner but in sufficient detail to make them readily usable. It is not to be inferred that these methods are universal for any type of sample, but they have been found very reliable for the types of samples mentioned.

  13. External Quality Assurance Services (EQAS) Ethanol/Ammonia Program

    E-Print Network [OSTI]

    Rodriguez, Carlos

    External Quality Assurance Services (EQAS) Ethanol/Ammonia Program BC35 12 x 3 mL 2 Analytes QC35 12 x 3 mL Specimen Only ENGLISH INTENDED USE Bio-Rad EQAS Ethanol/Ammonia Program is designed

  14. Production Systems and Processing Effect on Phytochemicals in Citrus Fruits and Their Analytical and Isolation Methods

    E-Print Network [OSTI]

    Uckoo, Ram 1980-

    2012-12-13T23:59:59.000Z

    of these phytochemicals this dissertation describes the development of rapid analytical and isolation methods, and the effect of production systems and processing techniques on the levels of phytochemicals in citrus fruits. In the first study, a simultaneous high...

  15. A comparison of the point kinetics equations with the QUANDRY analytic nodal diffusion method

    E-Print Network [OSTI]

    Velasquez, Arthur

    1993-01-01T23:59:59.000Z

    The point kinetics equations were incorporated into QUANDRY, a nuclear reactor analysis computer program which uses the analytic nodal method to solve the neutron diffusion equation. Both the point kinetics equations, solved using the IMSL MATH...

  16. Analytical methods for estimating saturated hydraulic conductivity in a tile-drained field

    E-Print Network [OSTI]

    Selker, John

    Analytical methods for estimating saturated hydraulic conductivity in a tile-drained field David E; Saturated hydraulic conductivity; Field scale; Tile drains; Water table 1. Introduction The use of spatially

  17. analytic nodal method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    waves in two dimensions. We present a method to calculate the distribution of the number of nodal domains and the average connectivity with the help of auxiliary Potts-spins....

  18. The validity of analytical methods for predicting self burial of offshore pipelines 

    E-Print Network [OSTI]

    Hamilton, Thomas Kenwood

    1977-01-01T23:59:59.000Z

    THE VALIDITY OF ANALYTICAL METHODS FOR PREDICTING SELF BURIAL OF OFFSHORE PIPELINES A Thesis by THOMAS KENWOOD HAMILTON Submitted to the Graduate College of Texas AEM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1977 Major Subject: Civil Engineering THE VALIDITY OF ANALYTICAL METHODS FOR PREDICTING SELF BURIAL OF OFFSHORE PIPELINES A Thesis by THOMAS KENWOOD HAMILTON Approved as to style and content by: Harry M. Coyle - Chairman...

  19. Comparison of analytical methods for percent phosphorus determination in electroless nickel plate

    SciTech Connect (OSTI)

    Owens, W.W.; Sullivan, H.H.

    1982-08-13T23:59:59.000Z

    This report presents the results of the evaluation of five analytical methods for percent phosphorus determination and makes recommendations for the use of common methods to provide accurate and precise results in the field. The analytical methods are: (1) ASTM-E39 gravimetric method; (2) development colorimetric method; (3) independent colorimetric method; (4) UCC-ND alkalimetric method; (5) UCC-ND inductively coupled plasma method. Analysis of the data indicates the concentration of phosphorus in the electroless nickel plate sample to be approximately 12.1%. All of the methods evaluated demonstrated the capability of determining percent phosphorus accurately through the accumulation of a large number of readings. The primary difference among the methods is the precision capabilites of individual tests. 3 figures, 6 tables.

  20. Sampling, preservation, and analytical methods research plan - liquid redox sulfur recovery technologies: Stretford process. Topical report

    SciTech Connect (OSTI)

    Trofe, T.W.

    1986-11-01T23:59:59.000Z

    GRI has developed a sampling, preservation, and analytical (SPandA) methods research plan for developing and validating analytical methodologies for liquid redox sulfur recovery processes (e.g., Stretford process). The document describes the technical approach which will be used to direct research activities to develop SPandA methodologies to analyze gaseous, aqueous, and solid process streams from the Stretford sulfur recovery process. The primary emphasis is on developing and validating methodologies for analyzing vanadium (IV) and vanadium (V), anthraquinone disulphonic acids (ADA), polysulfide-sulfur, sulfide-sulfur, thiosulfate, sulfate, thiocyanate, total soluble sulfur, alkalinity, pH, total dissolved solids, total suspended solids, and dissolved oxygen in aqueous process streams. The document includes descriptions of the process streams and chemical species, selection of candidate analytical methods, and technical approach for methods development and validation.

  1. Analytical and numerical methods for processing Hopkinson Bar Loaded Bending test on concrete: a comparative study

    E-Print Network [OSTI]

    Boyer, Edmond

    Analytical and numerical methods for processing Hopkinson Bar Loaded Bending test on concrete on dynamic characteristics of concrete. Various techniques have been used to test concretes at high strain for concrete structures subjected to dynamic loading such as explosions or im- pacts require information

  2. Author's Copy INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS

    E-Print Network [OSTI]

    Valkó, Peter

    . Kronenberg2 1 Petroleum Engineering Department, Texas A & M University, U.S.A. 2 Department of GeologyAuthor's Copy #12;INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J Zhurina in his memory. z E-mail: p-valko@tamu.edu n Correspondence to: P. P. Valk!oo, Petroleum

  3. A novel analytical operator method to solve linear ordinary differential equations with variable coefficients

    E-Print Network [OSTI]

    Wrick Sengupta

    2009-02-05T23:59:59.000Z

    A new analytical operator method is discussed which solves linear ordinary differential equations with regular singularities. Solutions are obtained in analytic series form and also in Mellin-Barnes-type contour integral form. Exact series solution is obtained without having to calculate series coefficients by recurrence relation.Both homogeneous and inhomogeneous equations are solved identically without having to calculate the Green's function explicitly in the case of inhomogeneous equation.Closed-form solutions are obtained for all the special functions appearing in mathematical physics. For a second-order equation both the independent solutions are obtained without invoking Wronskians, even when the indices differ by an integer.

  4. INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Characterization of random fields and their impact on the

    E-Print Network [OSTI]

    Andrade, Jose

    INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Characterization inhomogeneities exist at different length scales in geomechanical problems. Two types of inhomogeneities can

  5. Comparison of analytical methods for percent phosphorous determination in electroless nickel plate. [UCC-ND alkalimetric method; UCC-ND Inductively Coupled Plasma (ICP) method; ASTM-E39 gravimetric method; development colorimetric method; independent colorimetric method

    SciTech Connect (OSTI)

    Owens, W.W.; Sullivan, H.H.

    1982-01-01T23:59:59.000Z

    Electroless nicke-plate characteristics are substantially influenced by percent phosphorous concentrations. Available ASTM analytical methods are designed for phosphorous concentrations of less than one percent compared to the 4.0 to 20.0% concentrations common in electroless nickel plate. A variety of analytical adaptations are applied through the industry resulting in poor data continuity. This paper presents a statistical comparison of five analytical methods and recommends accurate and precise procedures for use in percent phosphorous determinations in electroless nickel plate. 2 figures, 1 table.

  6. Reactor for removing ammonia

    DOE Patents [OSTI]

    Luo, Weifang (Livermore, CA); Stewart, Kenneth D. (Valley Springs, CA)

    2009-11-17T23:59:59.000Z

    Disclosed is a device for removing trace amounts of ammonia from a stream of gas, particularly hydrogen gas, prepared by a reformation apparatus. The apparatus is used to prevent PEM "poisoning" in a fuel cell receiving the incoming hydrogen stream.

  7. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

    1998-09-22T23:59:59.000Z

    A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

  8. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, B.A.; Whitlow, E.P.

    1998-09-22T23:59:59.000Z

    A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

  9. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 3, Inorganic instrumental methods

    SciTech Connect (OSTI)

    Not Available

    1993-08-01T23:59:59.000Z

    The methods cover: C in solutions, F (electrode), elements by atomic emission spectrometry, inorganic anions by ion chromatography, Hg in water/solids/sludges, As, Se, Bi, Pb, data calculations for SST (single shell tank?) samples, Sb, Tl, Ag, Pu, O/M ratio, ignition weight loss, pH value, ammonia (N), Cr(VI), alkalinity, U, C sepn. from soil/sediment/sludge, Pu purif., total N, water, C and S, surface Cl/F, leachable Cl/F, outgassing of Ge detector dewars, gas mixing, gas isotopic analysis, XRF of metals/alloys/compounds, H in Zircaloy, H/O in metals, inpurity extraction, reduced/total Fe in glass, free acid in U/Pu solns, density of solns, Kr/Xe isotopes in FFTF cover gas, H by combustion, MS of Li and Cs isotopes, MS of lanthanide isotopes, GC operation, total Na on filters, XRF spectroscopy QC, multichannel analyzer operation, total cyanide in water/solid/sludge, free cyanide in water/leachate, hydrazine conc., ICP-MS, {sup 99}Tc, U conc./isotopes, microprobe analysis of solids, gas analysis, total cyanide, H/N{sub 2}O in air, and pH in soil.

  10. INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal. Meth. Geomech. 2011; 00:116

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal Methods in Geomechanics (2012) 19 pages" DOI : 10.1002/nag.1138 #12;2 B. NEDJAR AND R. LE ROY asymptotic

  11. A two-dimensional, semi-analytic expansion method for nodal calculations

    SciTech Connect (OSTI)

    Palmtag, S.P. [Univ. of Missouri, Rolla, MO (United States). Dept. of Nuclear Engineering

    1995-08-01T23:59:59.000Z

    Most modern nodal methods used today are based upon the transverse integration procedure in which the multi-dimensional flux shape is integrated over the transverse directions in order to produce a set of coupled one-dimensional flux shapes. The one-dimensional flux shapes are then solved either analytically or by representing the flux shape by a finite polynomial expansion. While these methods have been verified for most light-water reactor applications, they have been found to have difficulty predicting the large thermal flux gradients near the interfaces of highly-enriched MOX fuel assemblies. A new method is presented here in which the neutron flux is represented by a non-seperable, two-dimensional, semi-analytic flux expansion. The main features of this method are (1) the leakage terms from the node are modeled explicitly and therefore, the transverse integration procedure is not used, (2) the corner point flux values for each node are directly edited from the solution method, and a corner-point interpolation is not needed in the flux reconstruction, (3) the thermal flux expansion contains hyperbolic terms representing analytic solutions to the thermal flux diffusion equation, and (4) the thermal flux expansion contains a thermal to fast flux ratio term which reduces the number of polynomial expansion functions needed to represent the thermal flux. This new nodal method has been incorporated into the computer code COLOR2G and has been used to solve a two-dimensional, two-group colorset problem containing uranium and highly-enriched MOX fuel assemblies. The results from this calculation are compared to the results found using a code based on the traditional transverse integration procedure.

  12. AMMONIA THE OTHER HYDROGEN Rebecca Dunn, Keith Lovegrove

    E-Print Network [OSTI]

    -synthesised to provide energy transport and storage for solar thermal power generation. When the concept was first-dissociation-based solar thermal storage method. AMMONIA-BASED SOLAR ENERGY STORAGE Fig. 1: An overview of energy storage of concentrating solar thermal energy to produce ammonia as an alternative to using this same energy to generate

  13. Preventing Theft of Anhydrous Ammonia

    E-Print Network [OSTI]

    Smith, David

    2004-09-16T23:59:59.000Z

    Anhydrous ammonia is widely used as a fertilizer. The theft of anhydrous ammonia for use in producing illegal drugs is a growing problem. This publication describes how thieves operate and how farmers and agricultural dealers can protect themselves...

  14. Coherent states with classical motion: from an analytic method complementary to group theory

    SciTech Connect (OSTI)

    Nieto, M.M.

    1982-01-01T23:59:59.000Z

    From the motivation of Schroedinger, that of finding states which follow the motion which a classical particle would have in a given potential, we discuss generalizations of the coherent states of the harmonic oscillator. We focus on a method which is the analytic complement to the group theory point of view. It uses a minimum uncertainty formalism as its basis. We discuss the properties and time evolution of these states, always keeping in mind the desire to find quantum states which follow the classical motion.

  15. An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons

    E-Print Network [OSTI]

    Stohl, A.

    A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

  16. Evaluation of analytical methods to interpret ground deformations due to soft ground tunneling

    E-Print Network [OSTI]

    Zymnis, Despina M

    2009-01-01T23:59:59.000Z

    An in depth study was undertaken to evaluate the effectiveness of analytical solutions in describing ground movements induced by soft ground tunneling. The analytical solutions that were examined consider both isotropic ...

  17. Pulsed voltage electrospray ion source and method for preventing analyte electrolysis

    DOE Patents [OSTI]

    Kertesz, Vilmos (Knoxville, TN); Van Berkel, Gary (Clinton, TN)

    2011-12-27T23:59:59.000Z

    An electrospray ion source and method of operation includes the application of pulsed voltage to prevent electrolysis of analytes with a low electrochemical potential. The electrospray ion source can include an emitter, a counter electrode, and a power supply. The emitter can include a liquid conduit, a primary working electrode having a liquid contacting surface, and a spray tip, where the liquid conduit and the working electrode are in liquid communication. The counter electrode can be proximate to, but separated from, the spray tip. The power system can supply voltage to the working electrode in the form of a pulse wave, where the pulse wave oscillates between at least an energized voltage and a relaxation voltage. The relaxation duration of the relaxation voltage can range from 1 millisecond to 35 milliseconds. The pulse duration of the energized voltage can be less than 1 millisecond and the frequency of the pulse wave can range from 30 to 800 Hz.

  18. ammonia synthesis catalyst: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    we are developing and promoting science-based methods 113 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. Bioluminescent bioreporter integrated circuit detection methods

    DOE Patents [OSTI]

    Simpson, Michael L.; Paulus, Michael J.; Sayler, Gary S.; Applegate, Bruce M.; Ripp, Steven A.

    2005-06-14T23:59:59.000Z

    Disclosed are monolithic bioelectronic devices comprising a bioreporter and an OASIC. These bioluminescent bioreporter integrated circuit are useful in detecting substances such as pollutants, explosives, and heavy-metals residing in inhospitable areas such as groundwater, industrial process vessels, and battlefields. Also disclosed are methods and apparatus for detection of particular analytes, including ammonia and estrogen compounds.

  20. Ion mobility spectrometer, spectrometer analyte detection and identification verification system, and method

    DOE Patents [OSTI]

    Atkinson, David A. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    Methods and apparatus for ion mobility spectrometry and analyte detection and identification verification system are disclosed. The apparatus is configured to be used in an ion mobility spectrometer and includes a plurality of reactant reservoirs configured to contain a plurality of reactants which can be reacted with the sample to form adducts having varying ion mobilities. A carrier fluid, such as air or nitrogen, is used to carry the sample into the spectrometer. The plurality of reactants are configured to be selectively added to the carrier stream by use inlet and outlet manifolds in communication with the reagent reservoirs, the reservoirs being selectively isolatable by valves. The invention further includes a spectrometer having the reagent system described. In the method, a first reactant is used with the sample. Following a positive result, a second reactant is used to determine whether a predicted response occurs. The occurrence of the second predicted response tends to verify the existence of a component of interest within the sample. A third reactant can also be used to provide further verification of the existence of a component of interest. A library can be established of known responses of compounds of interest with various reactants and the results of a specific multi-reactant survey of a sample can be compared against the library to determine whether a component detected in the sample is likely to be a specific component of interest.

  1. Process for synthesis of ammonia borane for bulk hydrogen storage

    DOE Patents [OSTI]

    Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

    2011-03-01T23:59:59.000Z

    The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

  2. INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal. Meth. Geomech. 2009; 33:285308

    E-Print Network [OSTI]

    Peirce, Anthony

    INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal of engineering applications such as pavement design, stress analysis of mining excavations, and hydraulic. In the petroleum industry, hydraulic fractures are deliberately created in oil and gas reservoirs to substantially

  3. A low-frequency fast multipole boundary element method based on analytical integration of the hypersingular integral for 3D acoustic problems

    E-Print Network [OSTI]

    Liu, Yijun

    A low-frequency fast multipole boundary element method based on analytical integration Fast multipole method Analytical singular integral Acoustics a b s t r a c t A low-frequency fast multipole boundary element method (FMBEM) for 3D acoustic problems is proposed in this paper. The FMBEM

  4. Characterization of Geosynthetic Clay Liner Bentonite using Micro-analytical Methods

    SciTech Connect (OSTI)

    Lange, K.; Rowe, R; Jamieson, H; Flemming, R; Lanzirotti, A

    2010-01-01T23:59:59.000Z

    In barrier design, familiarity of the structure and composition of the soil material at the micron scale is necessary for delineating the retention mechanisms of introduced metals, such as the formation of new mineral phases. In this study, the mineralogical and chemical makeup of the bentonite from a geosynthetic clay liner (GCL) was extensively characterized using a combination of conventional benchtop X-ray diffraction (XRD) and micro X-ray diffraction ({mu}XRD) with synchrotron-generated micro X-ray fluorescence ({mu}XRF) elemental mapping and {mu}XRD (S-{mu}XRD). These methods allow for the non-destructive, in situ investigation of a sample, with {micro}m spatial resolution. Synchrotron-based hard X-ray microprobes are specifically advantageous to the study of trace metals due to higher spatial resolution (<10 {micro}m) and higher analytical sensitivity (femtogram detection) than is possible using normal laboratory-based instruments. Minerals comprising less than 5% of the total bentonite sample such as gypsum, goethite and pyrite were identified that were not accessible by other conventional methods for the same GCL bentonite. Two dimensional General Area Diffraction Detector System (GADDS) images proved to be particularly advantageous in differentiating between the microcrystalline clay, which appeared as homogeneous Debye rings, and the 'spotty' or 'grainy' appearance of primary, more-coarsely-crystalline, accessory minerals. For S-{mu}XRD, the tunability of the synchrotron X-rays allowed for efficient distinction of both clay minerals at low scattering angles and in identifying varying Fe oxide minerals at higher angles. GCL samples permeated with metal-bearing mining solutions were also examined in order to consider how mechanisms of metal attenuation may be identified using the same techniques. In addition to the cation exchange capacity from the montmorillonite clay, tests showed how minerals comprising only 1-2% of the bentonite such as goethite could potentially play a significant role in sequestering a range of metals, specifically Ni, Zn and Cu.

  5. The Kinetics and Thermodynamics of CO2 Capture by Aqueous Ammonia Derived Using Meta-GGA Density Functional Theory and Wavefunction-Based Model Chemistry Methods

    SciTech Connect (OSTI)

    Beste, Ariana [ORNL; Attalla, Moetaz [CSIRO ICT Center, Australia; Jackson, Phil [CSIRO ICT Center, Australia

    2012-01-01T23:59:59.000Z

    A meta GGA-DFT study of CO{sub 2} activation in aqueous ammonia solutions, with an emphasis on the reaction barrier and molecularity, has been undertaken using the M06-2X functional with an augmented triple-zeta split-valence basis set (6-311++G(d,p)). Up to five base molecules were treated explicitly in order to establish the effects of solvent catalysis in the chemical capture process. Aqueous free energies of solvation were determined for optimized reactant and transition structures using SM8/M06-2X/6-311++G(d,p). The concept of the solvent pre-complex as presented by Dixon and coworkers (Nguyen, M. T.; Matus, M. H.; Jackson, V. E.; Ngan, V. T.; Rustad, J. R.; Dixon, D. A. J. Phys. Chem. A 2008, 112, 10386-10398) was exploited to account for the energetics of disruption of the hydrogen-bonding solvent nano-network prior to the CO{sub 2} activation step. Selected gas- and aqueous-phase thermodynamic quantities have also been derived.

  6. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A

    2009-05-27T23:59:59.000Z

    Method validation is the process of evaluating whether an analytical method is acceptable for its intended purpose. For pharmaceutical methods, guidelines from the United States Pharmacopeia (USP), International Conference on Harmonisation (ICH), and the United States Food and Drug Administration (USFDA) provide a framework for performing such valications. In general, methods for regulatory compliance must include studies on specificity, linearity, accuracy, precision, range, detection limit, quantitation limit, and robustness. Elements of these guidelines are readily adapted to the issue of validation for beryllium sampling and analysis. This document provides a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers and books reviewed is given in the Appendix. Available validation documents and guides are listed therein; each has a brief description of application and use. In the referenced sources, there are varying approches to validation and varying descriptions of the valication process at different stages in method development. This discussion focuses on valication and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all referenced documents were published in English.

  7. The development and application of advanced analytical methods to commercial ICF reactor chambers. Final report

    SciTech Connect (OSTI)

    Cousseau, P.; Engelstad, R.; Henderson, D.L. [and others

    1997-10-01T23:59:59.000Z

    Progress is summarized in this report for each of the following tasks: (1) multi-dimensional radiation hydrodynamics computer code development; (2) 2D radiation-hydrodynamic code development; (3) ALARA: analytic and Laplacian adaptive radioactivity analysis -- a complete package for analysis of induced activation; (4) structural dynamics modeling of ICF reactor chambers; and (5) analysis of self-consistent target chamber clearing.

  8. 1997 BNL Site Environmental Report C -1 INSTRUMENTATION AND ANALYTICAL METHODS

    E-Print Network [OSTI]

    analyses. The analytical laboratory is certified by NYS- DOH for the radiological and nonradiological. If the samples are effluent or surface stream samples from locations DA, EA, HM or HQ, or Building 535B daily and surface stream samples from locations DA, EA, HM, or HQ, or Building 535B daily- process samples as well

  9. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Abstract: Ammonia...

  10. Semi-analytic equations to the Cox-Thompson inverse scattering method at fixed energy for special cases

    E-Print Network [OSTI]

    Tamas Palmai; Miklos Horvath; Barnabas Apagyi

    2011-11-25T23:59:59.000Z

    Solution of the Cox-Thompson inverse scattering problem at fixed energy [1,2,3] is reformulated resulting in semi-analytic equations. The new set of equations for the normalization constants and the nonphysical (shifted) angular momenta are free of matrix inversion operations. This simplification is a result of treating only the input phase shifts of partial waves of a given parity. Therefore, the proposed method can be applied for identical particle scattering of the bosonic type (or for certain cases of identical fermionic scattering). The new formulae are expected to be numerically more efficient than the previous ones. Based on the semi-analytic equations an approximate method is proposed for the generic inverse scattering problem, when partial waves of arbitrary parity are considered.

  11. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21T23:59:59.000Z

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  12. VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS

    SciTech Connect (OSTI)

    Ekechukwu, A.

    2008-12-17T23:59:59.000Z

    This document proposes to provide a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers, and books reviewed is given in Appendix 1. Available validation documents and guides are listed in the appendix; each has a brief description of application and use. In the referenced sources, there are varying approaches to validation and varying descriptions of validation at different stages in method development. This discussion focuses on validation and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all documents were published in English.

  13. Assessment of research and development (R and D) needs in ammonia safety and environmental control

    SciTech Connect (OSTI)

    Brenchley, D.L.; Athey, G.F.; Bomelburg, H.J.

    1981-09-01T23:59:59.000Z

    This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)

  14. Ammonia-treated phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Brow, R.K.; Day, D.E.

    1991-09-03T23:59:59.000Z

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  15. ammonia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 18 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. Diethylamine and ammonia pretreatment of lignocellulose

    E-Print Network [OSTI]

    Holthus, Robert Earl

    1993-01-01T23:59:59.000Z

    to the diethylamine did not increase reactivity, but it allows the diethylamine to be recovered. In addition to the diethylamine experiments, ammonia was used to pretreat Coastal bermudagrass. This process involves soaking the cellulose fibers in liquid ammonia...

  17. DEVELOPMENT OF ANALYTICAL METHODS FOR DETERMINING SUPPRESSOR CONCENTRATION IN THE MCU NEXT GENERATION SOLVENT (NGS)

    SciTech Connect (OSTI)

    Taylor-Pashow, K.; Fondeur, F.; White, T.; Diprete, D.; Milliken, C.

    2013-07-31T23:59:59.000Z

    Savannah River National Laboratory (SRNL) was tasked with identifying and developing at least one, but preferably two methods for quantifying the suppressor in the Next Generation Solvent (NGS) system. The suppressor is a guanidine derivative, N,N',N"-tris(3,7-dimethyloctyl)guanidine (TiDG). A list of 10 possible methods was generated, and screening experiments were performed for 8 of the 10 methods. After completion of the screening experiments, the non-aqueous acid-base titration was determined to be the most promising, and was selected for further development as the primary method. {sup 1}H NMR also showed promising results from the screening experiments, and this method was selected for further development as the secondary method. Other methods, including {sup 36}Cl radiocounting and ion chromatography, also showed promise; however, due to the similarity to the primary method (titration) and the inability to differentiate between TiDG and TOA (tri-n-ocytlamine) in the blended solvent, {sup 1}H NMR was selected over these methods. Analysis of radioactive samples obtained from real waste ESS (extraction, scrub, strip) testing using the titration method showed good results. Based on these results, the titration method was selected as the method of choice for TiDG measurement. {sup 1}H NMR has been selected as the secondary (back-up) method, and additional work is planned to further develop this method and to verify the method using radioactive samples. Procedures for analyzing radioactive samples of both pure NGS and blended solvent were developed and issued for the both methods.

  18. Project Profile: Thermochemical Storage with Anhydrous Ammonia...

    Office of Environmental Management (EM)

    Storage with Anhydrous Ammonia: Optimizing the Synthesis Reactor for Direct Production of Supercritical Steam Project Profile: Thermochemical Storage with Anhydrous...

  19. SRC-1 quarterly technical report, April-June 1981. [Review of analytical methods needed in SRC Demonstration plants

    SciTech Connect (OSTI)

    Not Available

    1981-10-01T23:59:59.000Z

    Twenty-three papers involving the design, materials and equipment for the SRC-1 demonstration coal liquefaction plant near Newman, Daviess County, Kentucky, have been entered individually into EDB and ERA. A number of the papers deal also with the analytical methodology required for the plant, including a rather detailed evaluation of the accuracy requirements and careful evaluation of several methods such as gas chromatography, mass spectroscopy, nuclear magnetic resonance, etc. Flexibility of design is stressed so that products can be optimized for the market and charged if the market requires different products. (LTN)

  20. Hydrogen production using ammonia borane

    DOE Patents [OSTI]

    Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

    2013-12-24T23:59:59.000Z

    Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

  1. Preparation of ammonia synthesis gas

    SciTech Connect (OSTI)

    Shires, P.J.; van Dijk, C.P.; Cassata, J.R.; Mandelik, B.G.

    1984-10-30T23:59:59.000Z

    Ammonia synthesis gas having excess nitrogen is produced in a reactor-exchanger primary reformer followed by an autothermal secondary reformer wherein process air for the latter is preheated by heat exchange with gas turbine exhaust and the primary reformer is heated by synthesis gas from the secondary reformer.

  2. Coal liquefaction process streams characterization and evaluation. Topical report: Analytical methods for application to coal-derived resids, A literature survey

    SciTech Connect (OSTI)

    Brandes, S.D.

    1993-06-01T23:59:59.000Z

    This literature survey was conducted to address an important question: What are the methods available in the realm of analytical chemistry that may have potential usefulness to the development of coal liquefaction technology? In an attempt to answer to that question, the emphasis of this survey was directed at analytical techniques which would be applicable to the high molecular weight, non-distillable residue of coal-derived liquids. It is this material which is most problematic to the analytical investigator and the developer of direct coal liquefaction processes. A number of comprehensive analytical reviews of literature dealing with coal and other fossil fuels are available. This literature survey will (1) be limited to articles published between 1980--1991, with some exceptions; (2) be limited to the use of analytical methods for high molecular weight, primarily nondistillable, fossil fuel-derived materials, except where the application of an analytical method to coals or distillates may show promise for application to non-distillable coal-derived materials; and (3) demonstrate the potential usefulness of an analytical method by showing how the method has been applied to high molecular weight, non-distillable materials, if not specifically to coal liquids. The text is divided by type of methodology, i.e. spectroscopy, microscopy, etc. Each section will be essentially free-standing. An historical background is provided.

  3. Adding Environmental Gas Physics to the Semi-Analytic Method for Galaxy Formation: Gravitational Heating

    E-Print Network [OSTI]

    S. Khochfar; J. P. Ostriker

    2008-02-12T23:59:59.000Z

    We present results of an attempt to include more detailed gas physics motivated from hydrodynamical simulations within semi-analytic models (SAM) of galaxy formation, focusing on the role that environmental effects play. The main difference to previous SAMs is that we include 'gravitational' heating of the intra-cluster medium (ICM) by the net surplus of gravitational potential energy released from gas that has been stripped from infalling satellites. Gravitational heating appears to be an efficient heating source able to prevent cooling in environments corresponding to dark matter halos more massive than $\\sim 10^{13} $M$_{\\odot}$. The energy release by gravitational heating can match that by AGN-feedback in massive galaxies and can exceed it in the most massive ones. However, there is a fundamental difference in the way the two processes operate. Gravitational heating becomes important at late times, when the peak activity of AGNs is already over, and it is very mass dependent. This mass dependency and time behaviour gives the right trend to recover down-sizing in the star-formation rate of massive galaxies. Abridged...

  4. Analysis of the semianalytical method for matching aquifer influence functions using an analytical model 

    E-Print Network [OSTI]

    Vega, Leonardo

    1998-01-01T23:59:59.000Z

    For a heterogeneous aquifer of unknown size and shape, ics. Aquifer Influence Functions (AIF) can be used to model the aquifer pressure behavior from field production and pressure data. Two methods have been used in the past to accomplish this...

  5. A comparison of an analytical and two electric analogy methods of hydraulic flow analysis 

    E-Print Network [OSTI]

    Hoffman, Joe Douglas

    1959-01-01T23:59:59.000Z

    ~ THE LINEAR RESISTANCE EIKCTRIC ANAIOGY METHOD . . . . . . 57 IX ~ THE NON-LINEAR RESISTANCE ELECTRIC ANALOGY METHOD, . 75 Xo DISCUSSION OF RESULTS XIo CONCLUSIONS APPENDIX BIBLIOGRAPHY 95 101 104 109 I, INTRODUCTION Although networks of hydraulic... pipelines are used throughout the world, the analysis of their steady state performance is a difficult and time consuming process . The work involved in ana- lysing a network of pipelines to determine flow rates and energy losses throughout the network...

  6. INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal. Meth. Geomech. 2005; 29:11271155 Prepared using nagauth.cls [Version: 2002/09/18 v1.02

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal and Analytical Methods in Geomechanics 29, 11 (2005) 1127-1155" DOI : 10.1002/nag.453 #12;1128 J.-M. PEREIRA ET

  7. Development of Analytical Methods for the Determination of Methylarginines in Serum

    E-Print Network [OSTI]

    Linz, Thomas

    2013-05-31T23:59:59.000Z

    .4.1 Nitric Oxide Analysis……………………………….………………..……20 2.4.2 Methylarginine Analysis……………………………….…………….…….21 2.4.2.1 Antibody-Based Analyses………………………………….…….21 2.4.2.2 Separations-Based Analyses………………………………….….23 ix 2.4.2.2.1 Liquid Chromatography... Identification and Peak Capacity Improvement……..…60 3.3.3.1 Dimethylsulfoxide Addition……………………………….…….62 3.3.4 CE-LIF Method Characterization………………………………….………67 3.3.5 NDA Derivatization……………………………….…………….…………71 3.3.6 Other Separation Considerations...

  8. Redox control of electric melters with complex feed compositions. Part I: analytical methods and models

    SciTech Connect (OSTI)

    Bickford, D F; Diemer, Jr, R B

    1985-01-01T23:59:59.000Z

    The redox state of glass from electric melters with complex feed compositions is determined by balance between gases above the melt, and transition metals and organic compounds in the feed. Part I discusses experimental and computational methods of relating flowrates and other melter operating conditions to the redox state of glass, and composition of the melter offgas. Computerized thermodynamic computational methods are useful in predicting the sequence and products of redox reactions and in assessing individual process variations. Melter redox state can be predicted by combining monitoring of melter operating conditions, redox measurement of fused melter feed samples, and periodic redox measurement of product. Mossbauer spectroscopy, and other methods which measure Fe(II)/Fe(III) in glass, can be used to measure melter redox state. Part II develops preliminary operating limits for the vitrification of High-Level Radioactive Waste. Limits on reducing potential to preclude the accumulation of combustible gases, accumulation of sulfides and selenides, and degradation of melter components are the most critical. Problems associated with excessively oxidizing conditions, such as glass foaming and potential ruthenium volatility, are controlled when sufficient formic acid is added to adjust melter feed rheology.

  9. An analytical method to calculate equivalent fields to irregular symmetric and asymmetric photon fields

    SciTech Connect (OSTI)

    Tahmasebi Birgani, Mohamad J. [Department of Radiation Therapy, Golestan Hospital, JondiShapour University of Medical Science, Ahvaz (Iran, Islamic Republic of); Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of); Chegeni, Nahid, E-mail: nchegen@yahoo.com [Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of); Zabihzadeh, Mansoor; Hamzian, Nima [Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of)

    2014-04-01T23:59:59.000Z

    Equivalent field is frequently used for central axis depth-dose calculations of rectangular- and irregular-shaped photon beams. As most of the proposed models to calculate the equivalent square field are dosimetry based, a simple physical-based method to calculate the equivalent square field size was used as the basis of this study. The table of the sides of the equivalent square or rectangular fields was constructed and then compared with the well-known tables by BJR and Venselaar, et al. with the average relative error percentage of 2.5 ± 2.5% and 1.5 ± 1.5%, respectively. To evaluate the accuracy of this method, the percentage depth doses (PDDs) were measured for some special irregular symmetric and asymmetric treatment fields and their equivalent squares for Siemens Primus Plus linear accelerator for both energies, 6 and 18 MV. The mean relative differences of PDDs measurement for these fields and their equivalent square was approximately 1% or less. As a result, this method can be employed to calculate equivalent field not only for rectangular fields but also for any irregular symmetric or asymmetric field.

  10. Modeling of selective catalytic reduction (SCR) of nitric oxide with ammonia using four modern catalysts

    E-Print Network [OSTI]

    Sharma, Giriraj

    2005-11-01T23:59:59.000Z

    values of the SCR process parameters, namely temperature, inlet oxygen concentration and inlet ammonia concentration. The NOx emission, its formation and control methods are discussed briefly and then the fundamentals of the SCR process are described...

  11. Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 2, Sample preparation methods

    SciTech Connect (OSTI)

    Not Available

    1993-08-01T23:59:59.000Z

    This volume contains the interim change notice for sample preparation methods. Covered are: acid digestion for metals analysis, fusion of Hanford tank waste solids, water leach of sludges/soils/other solids, extraction procedure toxicity (simulate leach in landfill), sample preparation for gamma spectroscopy, acid digestion for radiochemical analysis, leach preparation of solids for free cyanide analysis, aqueous leach of solids for anion analysis, microwave digestion of glasses and slurries for ICP/MS, toxicity characteristic leaching extraction for inorganics, leach/dissolution of activated metal for radiochemical analysis, extraction of single-shell tank (SST) samples for semi-VOC analysis, preparation and cleanup of hydrocarbon- containing samples for VOC and semi-VOC analysis, receiving of waste tank samples in onsite transfer cask, receipt and inspection of SST samples, receipt and extrusion of core samples at 325A shielded facility, cleaning and shipping of waste tank samplers, homogenization of solutions/slurries/sludges, and test sample preparation for bioassay quality control program.

  12. Polyaniline-based optical ammonia detector

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jin, Zhe (Los Alamos, NM); Su, Yongxuan (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    Electronic absorption spectroscopy of a polyaniline film deposited on a polyethylene surface by chemical oxidation of aniline monomer at room temperature was used to quantitatively detect ammonia gas. The present optical ammonia gas detector was found to have a response time of less than 15 s, a regeneration time of less than 2 min. at room temperature, and a detection limit of 1 ppm (v/v) for ammonia, with a linear dynamic range from 180 ppm to 18,000 ppm.

  13. Cylinder supplied ammonia scrubber testing in IDMS

    SciTech Connect (OSTI)

    Lambert, D.P.

    1994-08-31T23:59:59.000Z

    This report summarizes the results of the off-line testing the Integrated DWPF Melter System (IDMS) ammonia scrubbers using ammonia supplied from cylinders. Three additional tests with ammonia are planned to verify the data collected during off-line testing. Operation of the ammonia scrubber during IDMS SRAT and SME processing will be completed during the next IDMS run. The Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) scrubbers were successful in removing ammonia from the vapor stream to achieve ammonia vapor concentrations far below the 10 ppM vapor exit design basis. In most of the tests, the ammonia concentration in the vapor exit was lower than the detection limit of the analyzers so results are generally reported as <0.05 parts per million (ppM). During SRAT scrubber testing, the ammonia concentration was no higher than 2 ppM and during SME testing the ammonia concentration was no higher than 0.05 m.

  14. Layer of protection analysis applied to ammonia refrigeration systems

    E-Print Network [OSTI]

    Zuniga, Gerald Alexander

    2009-05-15T23:59:59.000Z

    Ammonia refrigeration systems are widely used in industry. Demand of these systems is expected to increase due to the advantages of ammonia as refrigerant and because ammonia is considered a green refrigerant. Therefore, it is important to evaluate...

  15. Promotion of Hydrogen Release from Ammonia Borane with Mechanically...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promotion of Hydrogen Release from Ammonia Borane with Mechanically Activated Hexagonal Boron Nitride. Promotion of Hydrogen Release from Ammonia Borane with Mechanically Activated...

  16. Trends in on-road vehicle emissions of ammonia

    E-Print Network [OSTI]

    Kean, A.J.

    2009-01-01T23:59:59.000Z

    calculation of diesel truck emission factors proceeded viaheavy-duty diesel truck ammonia emission rates prior to SCRto the diesel truck ammonia emission factor, the light-duty

  17. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

  18. Potential of High-Throughput Experimentation with Ammonia Borane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation) Potential of High-Throughput Experimentation with Ammonia Borane Solid...

  19. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

  20. Toxicologic evaluation of analytes from Tank 241-C-103

    SciTech Connect (OSTI)

    Mahlum, D.D.; Young, J.Y.; Weller, R.E.

    1994-11-01T23:59:59.000Z

    Westinghouse Hanford Company requested PNL to assemble a toxicology review panel (TRP) to evaluate analytical data compiled by WHC, and provide advice concerning potential health effects associated with exposure to tank-vapor constituents. The team`s objectives would be to (1) review procedures used for sampling vapors from tanks, (2) identify constituents in tank-vapor samples that could be related to symptoms reported by workers, (3) evaluate the toxicological implications of those constituents by comparison to establish toxicological databases, (4) provide advice for additional analytical efforts, and (5) support other activities as requested by WHC. The TRP represents a wide range of expertise, including toxicology, industrial hygiene, and occupational medicine. The TRP prepared a list of target analytes that chemists at the Oregon Graduate Institute/Sandia (OGI), Oak Ridge National Laboratory (ORNL), and PNL used to establish validated methods for quantitative analysis of head-space vapors from Tank 241-C-103. this list was used by the analytical laboratories to develop appropriate analytical methods for samples from Tank 241-C-103. Target compounds on the list included acetone, acetonitrile, ammonia, benzene, 1, 3-butadiene, butanal, n-butanol, hexane, 2-hexanone, methylene chloride, nitric oxide, nitrogen dioxide, nitrous oxide, dodecane, tridecane, propane nitrile, sulfur oxide, tributyl phosphate, and vinylidene chloride. The TRP considered constituent concentrations, current exposure limits, reliability of data relative to toxicity, consistency of the analytical data, and whether the material was carcinogenic or teratogenic. A final consideration in the analyte selection process was to include representative chemicals for each class of compounds found.

  1. Method of and apparatus for determining the similarity of a biological analyte from a model constructed from known biological fluids

    DOE Patents [OSTI]

    Robinson, Mark R. (Albuquerque, NM); Ward, Kenneth J. (Albuquerque, NM); Eaton, Robert P. (Albuquerque, NM); Haaland, David M. (Albuquerque, NM)

    1990-01-01T23:59:59.000Z

    The characteristics of a biological fluid sample having an analyte are determined from a model constructed from plural known biological fluid samples. The model is a function of the concentration of materials in the known fluid samples as a function of absorption of wideband infrared energy. The wideband infrared energy is coupled to the analyte containing sample so there is differential absorption of the infrared energy as a function of the wavelength of the wideband infrared energy incident on the analyte containing sample. The differential absorption causes intensity variations of the infrared energy incident on the analyte containing sample as a function of sample wavelength of the energy, and concentration of the unknown analyte is determined from the thus-derived intensity variations of the infrared energy as a function of wavelength from the model absorption versus wavelength function.

  2. Adsorption analysis of ammonia in an aqueous solution

    SciTech Connect (OSTI)

    Arman, B.; Panchal, C.B.

    1993-08-01T23:59:59.000Z

    An analysis is carried out to determine the effects of the diffusional resistance on the rate of the adsorption of ammonia in an aqueous solution. A performance prediction model is developed to calculate the local rate of heat and mass transfer, including physical and thermodynamic property calculations of the mixture. An algorithm is developed for calculating the interfacial conditions. The local heat- and mass-transfer calculation is then incorporated into the performance prediction method for adsorption for a given geometry.

  3. INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal. Meth. Geomech., 2002; 26: 925944 (DOI: 10.1002/nag.223)

    E-Print Network [OSTI]

    Hamann, Bernd

    INTERNATIONAL JOURNAL FOR NUMERICAL AND ANALYTICAL METHODS IN GEOMECHANICS Int. J. Numer. Anal geomechanics Boris Jeremi!cc1, *,y , Gerik Scheuermann2,3 , Jan Frey3 , Zhaohui Yang1 , Bernd Hamann2 , Kenneth is the visualization of stress tensors resulting from 3D numerical simulations in computational geomechanics

  4. A Modified Analytical Method for Simulating Cyclic Operation of Vertical U-Tube Ground-Coupled Heat Pumps 

    E-Print Network [OSTI]

    Dobson, M. K.; O'Neal, D. L.; Aldred, W.

    1994-01-01T23:59:59.000Z

    A modified analytical model is presented which discretizes the ground-coupled heat exchanger of a ground-coupled heat pump and utilized a separate cylindrical source solution for each element. First law expressions are utilized for each element...

  5. Physics of Aquatic Systems II, 12. Analytical Methods Universitt HeidelbergInstitut fr Umweltphysik Physics of Aquatic Systems II

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    techniques ­ Mass spectrometry ­ AMS · Lab tour ­ Noble gas mass spectrometry ­ Stable isotope mass spectrometry ­ Radiocarbon · Literature: Mook (2001), Vol. 1, ch. 10 & 11 Physics of Aquatic Systems II, 12 fundamental analytical techniques · Radiometry (decay counting, radioisotopes) · Mass spectrometry (mass

  6. Method and apparatus for processing a test sample to concentrate an analyte in the sample from a solvent in the sample

    DOE Patents [OSTI]

    Turner, T.D.; Beller, L.S.; Clark, M.L.; Klingler, K.M.

    1997-10-14T23:59:59.000Z

    A method of processing a test sample to concentrate an analyte in the sample from a solvent in the sample includes: (a) boiling the test sample containing the analyte and solvent in a boiling chamber to a temperature greater than or equal to the solvent boiling temperature and less than the analyte boiling temperature to form a rising sample vapor mixture; (b) passing the sample vapor mixture from the boiling chamber to an elongated primary separation tube, the separation tube having internal sidewalls and a longitudinal axis, the longitudinal axis being angled between vertical and horizontal and thus having an upper region and a lower region; (c) collecting the physically transported liquid analyte on the internal sidewalls of the separation tube; and (d) flowing the collected analyte along the angled internal sidewalls of the separation tube to and pass the separation tube lower region. The invention also includes passing a turbulence inducing wave through a vapor mixture to separate physically transported liquid second material from vaporized first material. Apparatus is also disclosed for effecting separations. Further disclosed is a fluidically powered liquid test sample withdrawal apparatus for withdrawing a liquid test sample from a test sample container and for cleaning the test sample container. 8 figs.

  7. High-pressure studies of ammonia hydrates 

    E-Print Network [OSTI]

    Wilson, Craig W.

    2014-06-28T23:59:59.000Z

    Ammonia and water are major components of many planetary bodies, from comets and icy moons such as Saturn's Titan to the interiors of the planets Neptune and Uranus. Under a range of high pressures and/or low temperatures known ...

  8. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, Alfred J. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

  9. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, A.J.

    1993-11-30T23:59:59.000Z

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

  10. Ammonia fiber explosion (AFEX) treatment of grass

    E-Print Network [OSTI]

    Ashok, Ganesh

    1991-01-01T23:59:59.000Z

    solution), high-temperature treatment, and freezing in water suspensions at -75 C (Millett, Baker, and Satter, 1975), Chemical pretreatments include alkali and ammonia swelling, dilute acid extraction, NO with alkali, explosive steam decompression, wet... for ruminants. Ammonia explosion pulping has been investigated as an approach to fiber separation in wood chips (O' Connor, 1971). Recent work on pretreatment techniques includes: pretreatment of cedar with peracetic acid and steam explosion to improve...

  11. Densities and viscosities of ternary ammonia/water fluids

    SciTech Connect (OSTI)

    Reiner, R.H.; Zaltash, A.

    1993-03-01T23:59:59.000Z

    The densities, viscosities, and boiling points (at barometric pressure) of solutions formed by inorganic salts dissolved in an ammonia/water (NH{sub 3}/H{sub 2}O) solvent have been measured. These ternary solutions of ammonia/water/dissolved salt are being investigated to reduce rectification requirements and to expand the temperature range of ammonia/water in advanced absorption cycles. Densities and viscosities of these fluids were measured over the temperature range of 283.15 to 343.15 K (10.0 to 70.0{degrees}C). Observed densities and viscosities were expressed as empirical functions of temperature by means of the least-squares method. The dynamic viscosities of ternary fluids were found to be three to seven times greater than those of the binary system of NH{sub 3}/H{sub 2}O, which implies that a substantial decrease in the film heat and mass transfer coefficient is possible. However, because this quantitative linkage is not well understood, direct measurements of heat and mass transfer rates in a minisorber are recommended and planned.

  12. A Modified Analytical Method for Simulating Cyclic Operation of Vertical U-Tube Ground-Coupled Heat Pumps

    E-Print Network [OSTI]

    Dobson, M. K.; O'Neal, D. L.; Aldred, W.

    1994-01-01T23:59:59.000Z

    as a heat source/sink for heat pumps. Using the soil rather than the ambient air as the heat source in 1 heating and the heat sink in cooling offers potential thermodynamic advantages since the earth is normally at a more favorable temperature for heat...-coupled heat exchangers have proceeded in two different directions: (1) numerical solutions of the heat diffusion equation in the soil and the ground-coil [Mei and Fischer, 1984] and (2) modified analytical solutions [Al- Juwayhel, 1981; Bose et al., 1985...

  13. ammonia removal vpcar: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 32 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. ammonia monooxygenase genes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. ammonia negative ion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 127 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. ammonia oxidising bacteria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 35 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. ammonia gas cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 96 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. archaeal ammonia oxidizers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    showed a strong correlation with ammonia Kamat, Vineet R. 85 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. aqueous ammonia process: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  20. ammonia dimethylamine trimethylamine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 30 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  1. ammonia removal reagent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 52 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  2. ammonia stress monitored: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 33 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  3. ammonia lyase microcompartment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 44 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  4. ammonia nitrous oxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 154 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia channel amtb: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 33 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. aqueous ammonia solution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 244 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. ammonia nitrous oxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 154 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. ammonia fluxes obtained: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 36 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  9. archaeal ammonia monooxygenase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 74 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. ammonia oxidizing bacteria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1E-1 mgm 3 (0.14 ppm) for ammonia based unknown authors 75 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. Spectroscopic Studies of the Phase Transition in Ammonia Borane...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studies of the Phase Transition in Ammonia Borane: Raman spectroscopy of single crystal NH3BH3 as a function of Spectroscopic Studies of the Phase Transition in Ammonia Borane:...

  12. Interaction of Lithium Hydride and Ammonia Borane in THF . |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Hydride and Ammonia Borane in THF . Interaction of Lithium Hydride and Ammonia Borane in THF . Abstract: The two-step reaction between LiH and NH3BH3 in THF leads to the...

  13. Design and performance of an ammonia measurement system

    E-Print Network [OSTI]

    Boriack, Cale Nolan

    2007-04-25T23:59:59.000Z

    Ammonia emissions from animal feeding operations (AFOs) have recently come under increased scrutiny. The US Environmental Protection Agency (EPA) has come under increased pressure from special interest groups to regulate ammonia. Regulation...

  14. Ammonia Results Review for Retained Gas Sampling

    SciTech Connect (OSTI)

    Mahoney, Lenna A.

    2000-09-20T23:59:59.000Z

    This report was prepared as part of a task supporting the deployment of the retained gas sampler (RGS) system in Flammable Gas Watch List Tanks. The emphasis of this report is on presenting supplemental information about the ammonia measurements resulting from retained gas sampling of Tanks 241-AW-101, A-101, AN-105, AN-104, AN-103, U-103, S-106, BY-101, BY-109, SX-106, AX-101, S-102, S-111, U-109, and SY-101. This information provides a better understanding of the accuracy of past RGS ammonia measurements, which will assist in determining flammable and toxicological hazards.

  15. Towards a wave--extraction method for numerical relativity: III. Analytical examples for the Beetle--Burko radiation scalar

    E-Print Network [OSTI]

    Lior M. Burko; Thomas W. Baumgarte; Christopher Beetle

    2005-11-18T23:59:59.000Z

    Beetle and Burko recently introduced a background--independent scalar curvature invariant for general relativity that carries information only about the gravitational radiation in generic spacetimes, in cases where such radiation is incontrovertibly defined. In this paper we adopt a formalism that only uses spatial data as they are used in numerical relativity and compute the Beetle--Burko radiation scalar for a number of analytical examples, specifically linearized Einstein--Rosen cylindrical waves, linearized quadrupole waves, the Kerr spacetime, Bowen--York initial data, and the Kasner spacetime. These examples illustrate how the Beetle--Burko radiation scalar can be used to examine the gravitational wave content of numerically generated spacetimes, and how it may provide a useful diagnostic for initial data sets.

  16. Potential Roles of Ammonia in a Hydrogen Economy

    E-Print Network [OSTI]

    Potential Roles of Ammonia in a Hydrogen Economy A Study of Issues Related to the Use Ammonia economy, particularly with regard to the viability of ammonia as an on-board hydrogen carrier for fuel for On-Board Vehicular Hydrogen Storage U.S. Department of Energy #12;#12;Primary Authors: George Thomas1

  17. Removal of ammonia from tarry water using a tubular furnace

    SciTech Connect (OSTI)

    V.V. Grabko; V.A. Kofanova; V.M. Li; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    An ammonia-processing system without the use of live steam from OAO Alchevskkoks plant's supply network is considered. Steam obtained from the wastewater that leaves the ammonia column is used to process the excess tarry water, with the release of volatile ammonia.

  18. Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

    1995-05-01T23:59:59.000Z

    This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

  19. AMMONIA CONCENTRATION IN SALTSTONE HEADSPACE SUMMARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J; Alex Cozzi, A

    2008-09-26T23:59:59.000Z

    The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar into Tank 50. Saltstone samples were prepared with an 'MCU' type salt solution spiked with ammonia. The ammonia released from the saltstone was captured and analyzed. The ammonia concentration found in the headspace of samples maintained at 95 C and 1 atm was, to 95% confidence, less than or equal to 3.9 mg/L. Tank 50 is fed by several influent streams. The salt solution from Tank 50 is pumped to the salt feed tank (SFT) in the Saltstone Production Facility (SPF). The premix materials cement, slag and fly ash are blended together prior to transfer to the grout mixer. The premix is fed to the grout mixer in the SPF and the salt solution is incorporated into the premix in the grout mixer, yielding saltstone slurry. The saltstone slurry drops into a hopper and then is pumped to the vault. The Saltstone Facility Documented Safety Analysis (DSA) is under revision to accommodate changes in the Composite Lower Flammability Limit (CLFL) from the introduction of Isopar{reg_sign} L into Tank 50. Waste Solidification-Engineering requested that the Savannah River National Laboratory (SRNL) perform testing to characterize the release of ammonia in curing saltstone at 95 C. The test temperature represents the maximum allowable temperature in the Saltstone Disposal Facility (SDF). Ammonia may be present in the salt solution and premix materials, or may be produced by chemical reactions when the premix and salt solution are combined. A final report (SRNS-STI-2008-00120, Rev. 0) will be issued that will cover in more depth the information presented in this report.

  20. Development of A Cryogenic Drift Cell Spectrometer and Methods for Improving the Analytical Figures of Merit for Ion Mobility-Mass Spectrometry Analysis 

    E-Print Network [OSTI]

    May, Jody C.

    2010-10-12T23:59:59.000Z

    A cryogenic (325-80 K) ion mobility-mass spectrometer was designed and constructed in order to improve the analytical figures-of-merit for the chemical analysis of small mass analytes using ion mobility-mass spectrometry. ...

  1. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I. (Santa Fe, NM); Jones, Claude R. (Los Alamos, NM); Nelson, Leonard Y. (Seattle, WA)

    1982-01-01T23:59:59.000Z

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  2. Analytical platform evaluation for quantification of ERG in prostate cancer using protein and mRNA detection methods

    SciTech Connect (OSTI)

    He, Jintang; Schepmoes, Athena A.; Shi, Tujin; Wu, Chaochao; Fillmore, Thomas L.; Gao, Yuqian; Smith, Richard D.; Qian, Weijun; Rodland, Karin D.; Liu, Tao; Camp, David G.; Rastogi, Anshu; Tan, Shyh-Han; Yan, Wusheng; Mohamed, Ahmed A.; Huang, Wei; Banerjee, Sreedatta; Kagan, Jacob; Srivastava, Sudhir; McLeod, David; Srivastava, Shiv; Petrovics, Gyorgy; Dobi, Albert; Srinivasan, Alagarsamy

    2015-01-01T23:59:59.000Z

    Background: The established methods for detecting prostate cancer (CaP) are based on tests using PSA (blood), PCA3 (urine), and AMACR (tissue) as biomarkers in patient samples. The demonstration of ERG oncoprotein overexpression due to gene fusion in CaP has thus provided ERG as an additional biomarker. Based on this, we hypothesized that ERG protein quantification methods can be of use in the diagnosis of prostate cancer. Methods: Therefore, an antibody-free assay for ERG3 protein detection was developed based on PRISM (high-pressure high-resolution separations with intelligent selection and multiplexing)-SRM (selected reaction monitoring) mass spectrometry. We utilized TMPRSS2-ERG positive VCaP and TMPRSS2-ERG negative LNCaP cells to simulate three different sample types (cells, tissue, and post-DRE urine sediment). Results: Recombinant ERG3 protein spiked into LNCaP cell lysates could be detected at levels as low as 20 pg by PRISM-SRM analysis. The sensitivity of the PRISM-SRM assay was around approximately 10,000 VCaP cells in a mixed cell population model of VCaP and LNCaP cells. Interestingly, ERG protein could be detected in as few as 600 VCaP cells spiked into female urine. The sensitivity of the in-house enzyme-linked immunosorbent assay (ELISA) was similar to the PRISM-SRM assay, with detection of 30 pg of purified recombinant ERG3 protein and 10,000 VCaP cells. On the other hand, qRT-PCR exhibited a higher sensitivity, as TMPRSS2-ERG transcripts were detected in as few as 100 VCaP cells, in comparison to NanoString methodologies which detected ERG from 10,000 cells. Conclusions: Based on this data, we propose that the detection of both ERG transcriptional products with RNA-based assays, as well as protein products of ERG using PRISM-SRM assays, may be of clinical value in developing diagnostics and prognostics assays for prostate cancer given their sensitivity, specificity, and reproducibility.

  3. Analytical study of bound states in graphene nano-ribbons and carbon nanotubes: The variable phase method and the relativistic Levinson theorem

    E-Print Network [OSTI]

    D. S. Miserev

    2014-08-24T23:59:59.000Z

    The problem of localized states in 1D systems with the relativistic spectrum, namely, graphene stripes and carbon nanotubes, has been analytically studied. The bound state as a superposition of two chiral states is completely described by their relative phase. The criteria of bound states appearance have been obtained based on the variable phase method (VPM) and the relativistic Levinson theorem developed via the VPM. The problem of bound states is reduced to the analysis of singularities of some vector field where the Levinson theorem appears as the Poincare indices theorem for closed trajectories of this field. The reduction of the VPM equation to the non-relativistic and semi-classical limits has been done. The limit of the small momentum p_y of the transverse quantization is applicable to arbitrary integrable potential. In this case the only confined mode is predicted.

  4. acute ammonia intoxication: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    functional gene microarray showed a diverse Ward, Bess 35 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia policy context: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and online drugstores. Index Terms Reeves, Douglas S. 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. anaerobic ammonia oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and its derivatives, have demonstrated Angenent, Lars T. 89 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. ammonia gas sensor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C. P. Wong; Manos M. Tentzeris; Senior Member 158 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. ammonia percolated wheat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Centre, University Saskatchewan, University of 236 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  9. acute ammonia stress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importantly... Steelman, Andrew Jonathan 2009-05-15 44 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. ammonia fiber expansion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Krzysztof Sadlej; Eligiusz Wajnryb 2011-10-06 39 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. ammonia magnesium phosphate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Schrhoff, Torsten; Samanta, Chhanda 2014-01-01 51 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  12. acute ammonia challenge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    functional gene microarray showed a diverse Ward, Bess 25 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  13. On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer

    Broader source: Energy.gov (indexed) [DOE]

    On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

  14. Process for releasing ammonia bound in coal water

    SciTech Connect (OSTI)

    Laufhutte, D.; Weber, H.

    1981-11-24T23:59:59.000Z

    A process for releasing ammonia which is bound in coal water using a pre-desulfurization plant having ammonia and hydrogen sulfide scrubbers through which crude coking plant gas is passed comprises circulating the crude coke oven gases through the hydrogen sulfide scrubber and the ammonia scrubber in succession, directing the coal water first through the ammonia scrubber while the crude coking plant gases are being also circulated therethrough after passing it first through the hydrogen sulfide scrubber. An alkali solution is also circulated through the ammonia scrubber to enrich the solution with acid components and to liberate ammonia bound in the coal water directing the coal water which has been enriched from the ammonia scrubber into the hydrogen sulfide scrubber. The process is characterized by the fact that the alkali solution which has first served for the hydrogen sulfide scrubber is added to the ammonia hydrogen sulfide scrubber. 80 to 90% of the total alkali solution is charged to the hydrogen sulfide after-washery and then on the hydrogen sulfide pre-washery and the rest is charged to an ammonia expulsion apparatus.

  15. Decomposition Pathway of Ammonia Borane on the Surface of nano...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano-BN. Abstract: Ammonia borane (AB) is under significant investigation as a possible hydrogen storage material. While many chemical additives have been demonstrated to have a...

  16. ammonia fuel cells: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bit.21687 ABSTRACT: Ammonia losses during swine wastewater treatment were examined using manure; electricity; power generation Introduction Wastewater treatment using microbial...

  17. Trends in on-road vehicle emissions of ammonia

    SciTech Connect (OSTI)

    Kean, A.J.; Littlejohn, D.; Ban-Weiss, G.A.; Harley, R.A.; Kirchstetter, T.W.; Lunden, M. M.

    2008-07-15T23:59:59.000Z

    Motor vehicle emissions of ammonia have been measured at a California highway tunnel in the San Francisco Bay area. Between 1999 and 2006, light-duty vehicle ammonia emissions decreased by 38 {+-} 6%, from 640 {+-} 40 to 400 {+-} 20 mg kg{sup -1}. High time resolution measurements of ammonia made in summer 2001 at the same location indicate a minimum in ammonia emissions correlated with slower-speed driving conditions. Variations in ammonia emission rates track changes in carbon monoxide more closely than changes in nitrogen oxides, especially during later evening hours when traffic speeds are highest. Analysis of remote sensing data of Burgard et al. (Environ Sci. Technol. 2006, 40, 7018-7022) indicates relationships between ammonia and vehicle model year, nitrogen oxides, and carbon monoxide. Ammonia emission rates from diesel trucks were difficult to measure in the tunnel setting due to the large contribution to ammonia concentrations in a mixed-traffic bore that were assigned to light-duty vehicle emissions. Nevertheless, it is clear that heavy-duty diesel trucks are a minor source of ammonia emissions compared to light-duty gasoline vehicles.

  18. Use and recovery of ammonia in power plant cycles

    SciTech Connect (OSTI)

    Pflug, H.D.; Bettenworth, H.J.; Syring, H.A. [Preussen Elektra AG, Hanover (Germany)

    1995-01-01T23:59:59.000Z

    The paper presents some practical and theoretical aspects of the use of ammonia in power plant water/steam cycles. The plants considered are fully automated units with once-through boilers, which operate under complex conditions and are subject to frequent starts and load changes. The boilers are chemically conditioned with combined oxygen ammonia treatment and the condensate polishing plant is only operated during start-up, in the event of a condenser leak or to remove excess ammonia. The paper also covers the recovery of ammonia from the condensate polishing plant waste regenerants and reuse for conditioning the feedwater. In particular, the paper deals with the following points: theoretical analysis of the chemical equilibrium of ammonia and carbon dioxide in water, including calculation of the concentrations from the parameters normally measured, such as conductivities and pH; equipment for monitoring and controlling the amount of ammonia fed to the water/steam cycle, including the optimum positioning of the sampling and feed-points, the parameters suitable for feed control and their temperature dependence; the partial pressure and distribution coefficient of ammonia; the consumption and losses of ammonia through the water/steam cycle during operation; the recovery of ammonia from condensate polishing plant waste regenerants by steam stripping. The paper should be of interest to both planning engineers and plant operators.

  19. Data Analytics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContract Management Fermi SitePARTOfficeOctoberDaniel Wood DarkDataAnalytics

  20. Characterization of atmospheric ammonia near Fort Worth, TX Part I. Dynamics of gaseous ammonia

    E-Print Network [OSTI]

    effects, and influence11 the cloud albedo and lifetime via indirect effects. The largest uncertainties among all12 radiative forcing components in global climate models are associated with PM [IPCC, 2007 its potential effects on the20 local and regional air quality.21 Keywords: ammonia, air quality

  1. First satellite observations of lower tropospheric ammonia and methanol

    E-Print Network [OSTI]

    First satellite observations of lower tropospheric ammonia and methanol Reinhard Beer,1 Mark W) and methanol (CH3OH), well above the normal background levels. This is the first time that these molecules have. Citation: Beer, R., et al. (2008), First satellite observations of lower tropospheric ammonia and methanol

  2. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  3. Analysis of Instability in an Industrial Ammonia Reactor

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Instability in an Industrial Ammonia Reactor John C. Morud and Sigurd Skogestad Dept point for this study was an incident in an industrial plant, where the ammonia synthesis reactor became used to analyze the stability, but a more care@1 analysis for this reactor system reveals

  4. SU-E-I-01: A Fast, Analytical Pencil Beam Based Method for First Order X-Ray Scatter Estimation of Kilovoltage Cone Beam X-Rays

    SciTech Connect (OSTI)

    Liu, J; Bourland, J [Wake Forest University, Winston-salem, NC (United States)

    2014-06-01T23:59:59.000Z

    Purpose: To analytically estimate first-order x-ray scatter for kV cone beam x-ray imaging with high computational efficiency. Methods: In calculating first-order scatter using the Klein-Nishina formula, we found that by integrating the point-to-point scatter along an interaction line, a “pencil-beam” scatter kernel (BSK) can be approximated to a quartic expression when the imaging field is small. This BSK model for monoenergetic, 100keV x-rays has been verified on homogeneous cube and cylinder water phantoms by comparing with the exact implementation of KN formula. For heterogeneous medium, the water-equivalent length of a BSK was acquired with an improved Siddon's ray-tracing algorithm, which was also used in calculating pre- and post- scattering attenuation. To include the electron binding effect for scattering of low-kV photons, the mean corresponding scattering angle is determined from the effective point of scattered photons of a BSK. The behavior of polyenergetic x-rays was also investigated for 120kV x-rays incident to a sandwiched infinite heterogeneous slab phantom, with the electron binding effect incorporated. Exact computation and Monte Carlo simulations were performed for comparisons, using the EGSnrc code package. Results: By reducing the 3D volumetric target (o(n{sup 3})) to 2D pencil-beams (o(n{sup 2})), the computation expense can be generally lowered by n times, which our experience verifies. The scatter distribution on a flat detector shows high agreement between the analytic BSK model and exact calculations. The pixel-to-pixel differences are within (-2%, 2%) for the homogeneous cube and cylinder phantoms and within (0, 6%) for the heterogeneous slab phantom. However, the Monte Carlo simulation shows increased deviation of the BSK model toward detector periphery. Conclusion: The proposed BSK model, accommodating polyenergetic x-rays and electron binding effect at low kV, shows great potential in efficiently estimating the first-order scatter from small imaging fields. We are investigating more thoroughly to improve performance and explore applications.

  5. Milk is a common ingredient in many fried foods. Allergen cross contact can occur through the use of shared frying oil. Analytical methods are needed to determine the level of protein contamination in re-used oil. This study

    E-Print Network [OSTI]

    Heller, Barbara

    the use of shared frying oil. Analytical methods are needed to determine the level of protein contamination in re-used oil. This study evaluated the performance of four ELISA test kits in comparison with a total protein assay for detection of milk protein residues in spiked oils that have been subjected

  6. Radiation Damage in Polarized Ammonia Solids

    E-Print Network [OSTI]

    K. Slifer

    2007-11-28T23:59:59.000Z

    Solid NH3 and ND3 provide a highly polarizable, radiation resistant source of polarized protons and deuterons and have been used extensively in high luminosity experiments investigating the spin structure of the nucleon. Over the past twenty years, the UVA polarized target group has been instrumental in producing and polarizing much of the material used in these studies, and many practical considerations have been learned in this time. In this discussion, we analyze the polarization performance of the solid ammonia targets used during the recent JLab Eg4 run. Topics include the rate of polarization decay with accumulated charge, the annealing procedure for radiation damaged targets to recover polarization, and the radiation induced change in optimum microwave frequency used to polarize the sample. We also discuss the success we have had in implementing frequency modulation of the polarizing microwave frequency.

  7. AMMONIA RECEIVER DESIGN FOR A 500m2 Rebecca Dunn, Keith Lovegrove, and Greg Burgess

    E-Print Network [OSTI]

    decomposition of ammonia to store solar energy. Ammonia passes alternately between energy-storing (dissociationAMMONIA RECEIVER DESIGN FOR A 500m2 DISH Rebecca Dunn, Keith Lovegrove, and Greg Burgess Solar 0200, Australia. Phone: +61 2 6125 4046. rebecca.dunn@anu.edu.au Abstract Previous ammonia receiver

  8. Retrofits: A Means for Reducing Energy Consumption in Ammonia Manufacture

    E-Print Network [OSTI]

    LeBlanc, J. R.; Moore, D. O.; Schneider, R. V., III

    1982-01-01T23:59:59.000Z

    , be fore we proceed to that discussion, it would be help ful to make a purely theoretical analysis of what the potential energy savings might be. The reaction of methane with steam and air to form ammonia is shown below. CH4 + 1.3974H20'+ 0.301302 + 1... on an ammonia production rate of 1000 STPD using natural gas feed. The process is divided into the following three sections with utilities included as an additional section: Reforming and shift C02 removal and methanation Compression and ammonia synthesis...

  9. Ammonia volatilization from surface application of ammonium sulfate to carbonate systems

    E-Print Network [OSTI]

    Feagley, Sam Edward

    1976-01-01T23:59:59.000Z

    from surface application of' ammonium fertilizers to calcareous soils 7 Ammonia Volatilization from Limed, Acid Soil Comparison of ammonia vole, tilization from different ammonium fertilizers Other factors affecting ammonia volatilization 10...-Newman-Keul's multiple range analysis of ammonia volatilization from a limed, acid soil supporting Coastal bermudagrass as affected by calcium carbonate . 58 Student-Newman-Keul's multiple range analysis of ammonia volatilization i'rom a limed. , acid soil supporting...

  10. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

    2007-08-14T23:59:59.000Z

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  11. ammonia chemical ionization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionization processes (more) Ozawa, Takashi 2007-01-01 69 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  12. ammonia positron emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 185 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  13. ammonia emission factors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 103 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. ammonia compensation point: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    not only a unique opportunity to gain both Ghosh, Joydeep 54 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. ammonia fibre expansion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    John M; Genty, Goery; Murdoch, Stuart G 2014-01-01 73 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. atmospheric ammonia nh3: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clusters because of their unique role Rocca, Jorge J. 208 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. ammonia borane complex: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    w x5-7 . Borane-triethylamine complex Boo, Jin-Hyo 43 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. ammonia electronic resource: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is not required such as with rehires Ronquist, Fredrik 63 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. ammonia final technical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 41 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  20. agricultural ammonia emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 113 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  1. ammonia triggers exocytotic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beauchemin, P; The ATLAS collaboration 2010-01-01 46 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  2. acid ammonia lyase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to forest health in the region. Sarah Jovan; Bruce Mccune 73 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  3. ammonia emission estimates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 153 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  4. ammonia gas sensing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donovan; Egusa, F; Momose, R; Robitaille, T P 2012-01-01 94 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  5. ammonia detection based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 357 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  6. ammonia oxidizer 16s: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16S ribosomal RNA (rRNA) is a central Walter, Nils G. 77 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  7. ammonia binding sites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    et al., 2009). A mRNA can Paris-Sud XI, Universit de 247 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  8. ammonia acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to forest health in the region. Sarah Jovan; Bruce Mccune 86 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  9. ammonia based co2: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time where tower levels 1-3 become Stanier, Charlie 418 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  10. ammonia solution activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be in excellent agreement with our recent Goodman, Wayne 57 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  11. ammonia emission trends: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 89 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  12. ammonia borane compound: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NH4H2PO4). (more) Gunaydin Sen, Ozge 2007-01-01 40 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  13. ammonia results review: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    requiring that 1m j m fl 0m ? 144 Me 109 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. ammonia oxidizer community: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to nitrate. No organism in culture is known Ward, Bess 62 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  15. adsorb aqueous ammonia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has (more) Willett, Thomas Clifford 2009-01-01 39 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  16. ammonia mass transfer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    papers in the field of heat transfer Kandlikar, Satish 236 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  17. ammonia emission rate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nakai; Kentarou Kawaguchi; Toshiaki Takano 2000-10-25 153 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  18. ammonia oxidizing bacterium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laszlo B. Kish; Maria D. King; Chiman Kwan 2009-01-20 63 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  19. ammonia emission inventories: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experience and Test Results From An Ammonia-Based DryWet Cooling System For Electric Power Stations Texas A&M University - TxSpace Summary: . In this concept, the reject...

  20. ammonia emission inventory: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experience and Test Results From An Ammonia-Based DryWet Cooling System For Electric Power Stations Texas A&M University - TxSpace Summary: . In this concept, the reject...

  1. Emission factors for ammonia and particulate matter from broiler Houses

    E-Print Network [OSTI]

    Redwine, Jarah Suzanne

    2001-01-01T23:59:59.000Z

    Total suspended particulate (TSP) concentrations, ammonia (NH?) concentrations, and ventilation rates were measured in four commercial, tunnel ventilated broiler houses in June through December of 2000 in Brazos County, Texas. Particle size...

  2. Atmospheric ammonia and particulate inorganic nitrogen over the United States

    E-Print Network [OSTI]

    Heald, Colette L.

    We use in situ observations from the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network, the Midwest Ammonia Monitoring Project, 11 surface site campaigns as well as Infrared Atmospheric Sounding ...

  3. Energy Saving in Ammonia Plant by Using Gas Turbine 

    E-Print Network [OSTI]

    Uji, S.; Ikeda, M.

    1981-01-01T23:59:59.000Z

    An ammonia plant, in which the IHI-SULZER Type 57 Gas Turbine is integrated in order to achieve energy saving, has started successful operation. Tile exhaust gas of the gas turbine has thermal energy of relatively high temperature, therefore...

  4. Energy Saving in Ammonia Plant by Using Gas Turbine

    E-Print Network [OSTI]

    Uji, S.; Ikeda, M.

    1981-01-01T23:59:59.000Z

    An ammonia plant, in which the IHI-SULZER Type 57 Gas Turbine is integrated in order to achieve energy saving, has started successful operation. Tile exhaust gas of the gas turbine has thermal energy of relatively high temperature, therefore...

  5. How the Membrane Protein AmtB Transports Ammonia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Membrane Protein AmtB Transports Ammonia Print Membrane proteins provide molecular-sized entry and exit portals for the various substances that pass into and out of cells. While...

  6. Urea/Ammonia Distribution Optimization in an SCR Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    P-20 UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Gi-Heon Kim, Matthew Thornton National Renewable Energy Laboratory...

  7. ammonia fuel cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ali as hydrogen (H2) storage compounds for fuel cell applications. Identify the pros and cons of using ammoniaBNH3) as a chemical hydrogen storage medium on-board fuel cell...

  8. Derivation of general analytic gradient expressions for density-fitted post-Hartree-Fock methods: An efficient implementation for the density-fitted second-order Møller–Plesset perturbation theory

    SciTech Connect (OSTI)

    Bozkaya, U?ur, E-mail: ugur.bozkaya@atauni.edu.tr [Department of Chemistry, Atatürk University, Erzurum 25240, Turkey and Department of Chemistry, Middle East Technical University, Ankara 06800 (Turkey)

    2014-09-28T23:59:59.000Z

    General analytic gradient expressions (with the frozen-core approximation) are presented for density-fitted post-HF methods. An efficient implementation of frozen-core analytic gradients for the second-order Møller–Plesset perturbation theory (MP2) with the density-fitting (DF) approximation (applying to both reference and correlation energies), which is denoted as DF-MP2, is reported. The DF-MP2 method is applied to a set of alkanes, conjugated dienes, and noncovalent interaction complexes to compare the computational cost of single point analytic gradients with MP2 with the resolution of the identity approach (RI-MP2) [F. Weigend and M. Häser, Theor. Chem. Acc. 97, 331 (1997); R. A. Distasio, R. P. Steele, Y. M. Rhee, Y. Shao, and M. Head-Gordon, J. Comput. Chem. 28, 839 (2007)]. In the RI-MP2 method, the DF approach is used only for the correlation energy. Our results demonstrate that the DF-MP2 method substantially accelerate the RI-MP2 method for analytic gradient computations due to the reduced input/output (I/O) time. Because in the DF-MP2 method the DF approach is used for both reference and correlation energies, the storage of 4-index electron repulsion integrals (ERIs) are avoided, 3-index ERI tensors are employed instead. Further, as in case of integrals, our gradient equation is completely avoid construction or storage of the 4-index two-particle density matrix (TPDM), instead we use 2- and 3-index TPDMs. Hence, the I/O bottleneck of a gradient computation is significantly overcome. Therefore, the cost of the generalized-Fock matrix (GFM), TPDM, solution of Z-vector equations, the back transformation of TPDM, and integral derivatives are substantially reduced when the DF approach is used for the entire energy expression. Further application results show that the DF approach introduce negligible errors for closed-shell reaction energies and equilibrium bond lengths.

  9. Functionalized magnetic nanoparticle analyte sensor

    DOE Patents [OSTI]

    Yantasee, Wassana; Warner, Maryin G; Warner, Cynthia L; Addleman, Raymond S; Fryxell, Glen E; Timchalk, Charles; Toloczko, Mychailo B

    2014-03-25T23:59:59.000Z

    A method and system for simply and efficiently determining quantities of a preselected material in a particular solution by the placement of at least one superparamagnetic nanoparticle having a specified functionalized organic material connected thereto into a particular sample solution, wherein preselected analytes attach to the functionalized organic groups, these superparamagnetic nanoparticles are then collected at a collection site and analyzed for the presence of a particular analyte.

  10. Storm Water Analytical Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection Obeying Environmental Laws Individual Permit Storm Water Analytical Period Storm Water Analytical Period The Individual Permit authorizes the discharge of storm...

  11. Measurements of Ammonia at Blodgett Forest

    SciTech Connect (OSTI)

    Fischer, Marc L.; Littlejohn, David

    2007-04-01T23:59:59.000Z

    Ammonia is a reactive trace gas that is emitted in large quantities by animal agriculture and other sources in California, which subsequently forms aerosol particulate matter, potentially affecting visibility, climate, and human health. We performed initial measurements of NH{sub 3} at the Blodgett Forest Research Station (BFRS) during a 3 week study in June, 2006. The site is used for ongoing air quality research and is a relatively low-background site in the foothills of the Sierra Nevada. Measured NH{sub 3} mixing ratios were quite low (< 1 to {approx}2 ppb), contrasting with typical conditions in many parts of the Central Valley. Eddy covariance measurements showed NH{sub 3} fluxes that scaled with measured NH{sub 3} mixing ratio and calculated aerodynamic deposition velocity, suggesting dry deposition is a significant loss mechanism for atmospheric NH{sub 3} at BFRS. A simple model of NH{sub 3} transport to the site supports the hypothesis that NH{sub 3} is transported from the Valley to BFRS, but deposits on vegetation during the summer. Further work is necessary to determine whether the results obtained in this study can be generalized to other seasons.

  12. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31T23:59:59.000Z

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  13. Safe and compact ammonia storage/delivery systems for SCR-DeNOX...

    Energy Savers [EERE]

    Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

  14. 3rd Generation SCR System Using Solid Ammonia Storage and Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

  15. Computer simulation and economic analysis for ammonia fiber explosion (AFEX) pretreatment process

    E-Print Network [OSTI]

    Wang, Lin

    1996-01-01T23:59:59.000Z

    The ammonia fiber explosion (AFFECT) process is a promising new pretreatment for enhancing the reactivity of lignocerulose materials with many advantages over existing processes. The material is soaked in high-pressure liquid ammonia for a few...

  16. Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators

    E-Print Network [OSTI]

    Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators to eventually optimise the reactor geometry for ammonia-based solar energy storage with troughs, which.1. Storing Solar Energy with Ammonia H2 / N2 gas liquid NH3 Heat Exchangers Power Generation (Steam Cycle

  17. An analytical coarse-graining method which preserves the free energy, structural correlations, and thermodynamic state of polymer melts from the atomistic to the mesoscale

    E-Print Network [OSTI]

    J. McCarty; A. J. Clark; J. Copperman; M. G. Guenza

    2014-07-03T23:59:59.000Z

    Structural and thermodynamic consistency of coarse-graining models across multiple length scales is essential for the predictive role of multi-scale modeling and molecular dynamic simulations that use mesoscale descriptions. Our approach is a coarse-grained model based on integral equation theory, which can represent polymer chains at variable levels of chemical details. The model is analytical and depends on molecular and thermodynamic parameters of the system under study, as well as on the direct correlation function in the k --> 0 limit, c0. A numerical solution to the PRISM integral equations is used to determine c0, by adjusting the value of the effective hard sphere diameter, d, to agree with the predicted equation of state. This single quantity parameterizes the coarse-grained potential, which is used to perform mesoscale simulations that are directly compared with atomistic-level simulations of the same system. We test our coarse-graining formalism by comparing structural correlations, isothermal compressibility, equation of state, Helmholtz and Gibbs free energies, and potential energy and entropy using both united atom and coarse-grained descriptions. We find quantitative agreement between the analytical formalism for the thermodynamic properties, and the results of Molecular Dynamics simulations, independent of the chosen level of representation. In the mesoscale description, the potential energy of the soft-particle interaction becomes a free energy in the coarse-grained coordinates which preserves the excess free energy from an ideal gas across all levels of description. The structural consistency between the united-atom and mesoscale descriptions means the relative entropy between descriptions has been minimized without any variational optimization parameters. The approach is general and applicable to any polymeric system in different thermodynamic conditions.

  18. An analytical coarse-graining method which preserves the free energy, structural correlations, and thermodynamic state of polymer melts from the atomistic to the mesoscale

    SciTech Connect (OSTI)

    McCarty, J.; Clark, A. J.; Copperman, J.; Guenza, M. G., E-mail: mguenza@uoregon.edu [Department of Chemistry and Biochemistry, and Institute of Theoretical Science, University of Oregon, Eugene, Oregon 97403 (United States)

    2014-05-28T23:59:59.000Z

    Structural and thermodynamic consistency of coarse-graining models across multiple length scales is essential for the predictive role of multi-scale modeling and molecular dynamic simulations that use mesoscale descriptions. Our approach is a coarse-grained model based on integral equation theory, which can represent polymer chains at variable levels of chemical details. The model is analytical and depends on molecular and thermodynamic parameters of the system under study, as well as on the direct correlation function in the k ? 0 limit, c{sub 0}. A numerical solution to the PRISM integral equations is used to determine c{sub 0}, by adjusting the value of the effective hard sphere diameter, d{sub HS}, to agree with the predicted equation of state. This single quantity parameterizes the coarse-grained potential, which is used to perform mesoscale simulations that are directly compared with atomistic-level simulations of the same system. We test our coarse-graining formalism by comparing structural correlations, isothermal compressibility, equation of state, Helmholtz and Gibbs free energies, and potential energy and entropy using both united atom and coarse-grained descriptions. We find quantitative agreement between the analytical formalism for the thermodynamic properties, and the results of Molecular Dynamics simulations, independent of the chosen level of representation. In the mesoscale description, the potential energy of the soft-particle interaction becomes a free energy in the coarse-grained coordinates which preserves the excess free energy from an ideal gas across all levels of description. The structural consistency between the united-atom and mesoscale descriptions means the relative entropy between descriptions has been minimized without any variational optimization parameters. The approach is general and applicable to any polymeric system in different thermodynamic conditions.

  19. Analytical formulas for gravitational lensing

    E-Print Network [OSTI]

    Paolo Amore; Santiago Arceo Diaz

    2006-03-21T23:59:59.000Z

    In this paper we discuss a new method which can be used to obtain arbitrarily accurate analytical expressions for the deflection angle of light propagating in a given metric. Our method works by mapping the integral into a rapidly convergent series and provides extremely accurate approximations already to first order. We have derived a general first order formula for a generic spherically symmetric static metric tensor and we have tested it in four different cases.

  20. Energy Savings for CO2 Removal in Ammonia Plants

    E-Print Network [OSTI]

    Pouilliart, R.; Van Hecke, F. C.

    1981-01-01T23:59:59.000Z

    An exergy analysis of carbonate solution C02 removal systems which use solution flashing shows that there is no energy saving by using a mechanical thermocompressor instead of a steam-jet ejector. In a 1000 ShT/D ammonia plant an energy saving...

  1. Corrosion protection of steel in ammonia/water heat pumps

    DOE Patents [OSTI]

    Mansfeld, Florian B.; Sun, Zhaoli

    2003-10-14T23:59:59.000Z

    Corrosion of steel surfaces in a heat pump is inhibited by adding a rare earth metal salt to the heat pump's ammonia/water working fluid. In preferred embodiments, the rare earth metal salt includes cerium, and the steel surfaces are cerated to enhance the corrosion-inhibiting effects.

  2. Membrane Based intensification of ammonia removal from wastewater

    E-Print Network [OSTI]

    Almutairi, Azel

    2011-12-31T23:59:59.000Z

    .25, and 0.03 Kg N/(m3day) depending on the type of the experiment. For the bacteria-free silicon membrane column, the inlet ammonia concentration, bed height, and inlet flowrate were examined. Biologically activated silicon membrane column exhibited...

  3. Original article Ammonia treatment of lucerne and cocksfoot

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Ammonia treatment of lucerne and cocksfoot harvested at two growth stages: Effect and the end of first growth. Lucerne and cocksfoot samples were treated with 30 g ammo- nia per kg DM for 4 and pepsin-cellulase digestibilities of dry matter (DM) and cell walls (CW). Lucerne had a very different CW

  4. Example risk management plan and offsite consequence analysis for power plant aging using ammonia and chlorine

    SciTech Connect (OSTI)

    McCann, R.C. Jr.

    1998-07-01T23:59:59.000Z

    This paper provides an example of a risk management plan (RMP) for a utility power plant required under Title III of the 1990 Clean Air Act Amendments (CAAA). Under Title III, certain facilities are required to identify hazards associated with chemicals used to prevent accidental releases, and to minimize consequences of releases. Ammonia is used to reduce nitrogen oxides (NO{sub x}) emissions and is injected in the post-combustion system based on the selective catalyst reduction (SCR) process. Chlorine is used in the potable water treatment process. This paper provides an overview of the elements required in the RMP and specific methods and procedures currently recommended by the EPA for estimating hazardous air pollutant emissions and impacts related to the ammonia and chlorination processes cited in this paper. Information is presented that addresses the potential extent of a pollutant's impacts, including methods and assumptions designed to over-estimate concentrations. Alternative approaches are used to estimate more realistic but still conservative concentrations. Based on the results of these analyses, strategies are recommended that the plant could incorporate to reduce the level of potential impacts and, therefore, program requirements under RMP.

  5. Ammonia availability shapes the seasonal distribution and activity of archaeal and bacterial ammonia oxidizers in the Puget Sound Estuary

    E-Print Network [OSTI]

    de la Torre, José R.

    ammonia oxidizers in the Puget Sound Estuary Hidetoshi Urakawa,1,a,* Willm Martens-Habbena,1 Carme Huguet, a fjord within the Puget Sound, Washington State estuary system. A greater contribution of AOA numbers of AOA in Hood Canal, a fjord in the Puget Sound estuary system (Urakawa et al. 2010; Horak et al

  6. Development and analytical validation of a gas chromatography-mass spectrometry method for the assessment of gastrointestinal permeability and intestinal absorptive capacity in dogs

    E-Print Network [OSTI]

    Rodriguez Frausto, Heriberto

    2009-05-15T23:59:59.000Z

    , xylose (X) and 3-O-methylglucose (M) for the evaluation of intestinal absorptive capacity, and sucrose (S) for the assessment of gastric permeability. Traditionally, various methods have been used to quantify these markers in the urine after orogastric...

  7. 50 IEEE TRANSACTIONS ON MAGNETICS, VOL. 40, NO. 1, JANUARY 2004 Analytical Method for Predicting the Air-Gap Flux of

    E-Print Network [OSTI]

    Mi, Chunting "Chris"

    the Air-Gap Flux of Interior-Type Permanent-Magnet Machines Chunting Mi, Senior Member, IEEE, Mariano method to calcu- late the air-gap magnetic flux of interior-type permanent-magnet (IPM) machines taking INTERIOR-TYPE permanent-magnet (IPM) motors are used in a wide range of industrial applications due

  8. Toxicity and acclimation to ammonia by Tilapia aurea

    E-Print Network [OSTI]

    Redner, Barry Duncan

    1978-01-01T23:59:59.000Z

    operations (Spoti:e, 1970). Sroart (1976) noticed rela . i. vely m'. nor histopathological changes in the gill" of trout when given an acute dcse of ammonia. Ch onic ammonia poI. sosI. ng, however, may d?seg the tissues of the gilI, , kin, 1!&testiue, I... of urine pro- &8&orion declined until it aporoack. ed a rate on!y slightly, :oat& r "han tii& pret sc; slue. , The rr suits were due, tl. . ey '1&cerise&i, t o redo?e k tissue p&trm-abihity wr;tch at loi. 8 th& fi . ki to to'tera'e c&&u ritrat 1 oos...

  9. Effect of Thermal Annealing in Ammonia on the Properties of InGaN Nanowires with Different Indium Concentrations

    SciTech Connect (OSTI)

    Hahn, Cristopher; Cordones, Amy; Andrews, Sean; Gao, Hanwei; Fu, Anthony; Leone, Stephen; Yang, Peidong

    2012-10-02T23:59:59.000Z

    The utility of an annealing procedure in ammonia ambient is investigated for improving the optical characteristics of InxGa1?xN nanowires (0.07 ? x ? 0.42) grown on c-Al2O3 using a halide chemical vapor deposition method. Morphological studies using scanning electron microscopy confirm that the nanowire morphology is retained after annealing in ammonia at temperatures up to 800 ?C. However, significant indium etching and composition inhomogeneities are observed for higher indium composition nanowires (x = 0.28, 0.42), as measured by energy-dispersive X-ray spectroscopy and Z-contrast scanning transmission electron microscopy. Structural analyses, using X-ray diffraction and high-resolution transmission electron microscopy, indicate that this is a result of the greater thermal instability of higher indium composition nanowires. The effect of these structural changes on the optical quality of InGaN nanowires is examined using steady-state and time-resolved photoluminescence measurements. Annealing in ammonia enhances the integrated photoluminescence intensity of InxGa1?xN nanowires by up to a factor of 4.11 ? 0.03 (for x = 0.42) by increasing the rate of radiative recombination. Fitting of photoluminescence decay curves to a Kohlrausch stretched exponential indicates that this increase is directly related to a larger distribution of recombination rates from composition inhomogeneities caused by annealing. The results demonstrate the role of thermal instability on the improved optical properties of InGaN nanowires annealed in ammonia.

  10. The effect of dietary protein and fiber on in vivo ammonia concentration

    E-Print Network [OSTI]

    Marchant, Linda Jean

    1986-01-01T23:59:59.000Z

    diffusion (65, 85), the more acidic the colonic contents the less absorption of ammonia should occur. In theory, then, it may be possible to counteract the potentially negative effects of a high protein diet by the addition of the appropriate type... ammonia concentration, possibly through the deamination of ingested protein. Although deamination of dietary protein by the intestinal microflora is the primary determinant of ammonia production, Krebs (45) demonstrated the presence of an L-amino acid...

  11. Analytic bootstrap at large spin

    E-Print Network [OSTI]

    Apratim Kaviraj; Kallol Sen; Aninda Sinha

    2015-03-24T23:59:59.000Z

    We use analytic conformal bootstrap methods to determine the anomalous dimensions and OPE coefficients for large spin operators in general conformal field theories in four dimensions containing a scalar operator of conformal dimension $\\Delta_\\phi$. It is known that such theories will contain an infinite sequence of large spin operators with twists approaching $2\\Delta_\\phi+2n$ for each integer $n$. By considering the case where such operators are separated by a twist gap from other operators at large spin, we analytically determine the $n$, $\\Delta_\\phi$ dependence of the anomalous dimensions. We find that for all $n$, the anomalous dimensions are negative for $\\Delta_\\phi$ satisfying the unitarity bound, thus extending the Nachtmann theorem to non-zero $n$. In the limit when $n$ is large, we find agreement with the AdS/CFT prediction corresponding to the Eikonal limit of a 2-2 scattering with dominant graviton exchange.

  12. Analytic bootstrap at large spin

    E-Print Network [OSTI]

    Kaviraj, Apratim; Sinha, Aninda

    2015-01-01T23:59:59.000Z

    We use analytic conformal bootstrap methods to determine the anomalous dimensions and OPE coefficients for large spin operators in general conformal field theories in four dimensions containing a scalar operator of conformal dimension $\\Delta_\\phi$. It is known that such theories will contain an infinite sequence of large spin operators with twists approaching $2\\Delta_\\phi+2n$ for each integer $n$. By considering the case where such operators are separated by a twist gap from other operators at large spin, we analytically determine the $n$, $\\Delta_\\phi$ dependence of the anomalous dimensions. We find that for all $n$, the anomalous dimensions are negative for $\\Delta_\\phi$ satisfying the unitarity bound, thus extending the Nachtmann theorem to non-zero $n$. In the limit when $n$ is large, we find agreement with the AdS/CFT prediction corresponding to the Eikonal limit of a 2-2 scattering with dominant graviton exchange.

  13. ammonia oxidation pt pd rd: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    research into controlling nanocrystal Castell, Martin 216 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  14. On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling On-Board Measurement of...

  15. Extreme Scale Visual Analytics

    SciTech Connect (OSTI)

    Steed, Chad A [ORNL] [ORNL; Potok, Thomas E [ORNL] [ORNL; Pullum, Laura L [ORNL] [ORNL; Ramanathan, Arvind [ORNL] [ORNL; Shipman, Galen M [ORNL] [ORNL; Thornton, Peter E [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Given the scale and complexity of today s data, visual analytics is rapidly becoming a necessity rather than an option for comprehensive exploratory analysis. In this paper, we provide an overview of three applications of visual analytics for addressing the challenges of analyzing climate, text streams, and biosurveilance data. These systems feature varying levels of interaction and high performance computing technology integration to permit exploratory analysis of large and complex data of global significance.

  16. Biomass treatment method

    DOE Patents [OSTI]

    Friend, Julie (Claymont, DE); Elander, Richard T. (Evergreen, CO); Tucker, III; Melvin P. (Lakewood, CO); Lyons, Robert C. (Arvada, CO)

    2010-10-26T23:59:59.000Z

    A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

  17. Sol-gel matrices for direct colorimetric detection of analytes

    DOE Patents [OSTI]

    Charych, Deborah H. (Albany, CA); Sasaki, Darryl (Albuquerque, NM); Yamanaka, Stacey (Dallas, TX)

    2000-01-01T23:59:59.000Z

    The present invention relates to methods and compositions for the direct detection of analytes using color changes that occur in immobilized biopolymeric material in response to selective binding of analytes to their surface. In particular, the present invention provides methods and compositions related to the encapsulation of biopolymeric material into metal oxide glass using the sol-gel method.

  18. analytical mass spectrometry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analytical methods for solving a variety of molecular structure problems. Among high. Extension of mass spectrometry to the analysis of high molecular weight materials,...

  19. analytical modeling approach: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nonperturbative analytical relativistic models of magnetars. With this purpose in mind we first develop a method for generating exact interior solutions to the static and...

  20. analytical ion microscope: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Field-theoretical method is proposed, that yields analytical expression for lateral pressure distribution across hydrophobic core of a bilayer lipid membrane. Lipid molecule,...

  1. Biodiesel Utilization: Update on Recent Analytical Techniques (Presentation)

    SciTech Connect (OSTI)

    Alleman, T. L.; Fouts, L.; Luecke, J.; Thornton, M.; McAlpin, C.

    2009-05-01T23:59:59.000Z

    To understand and increase the use of biodiesel, analytical methods need to be shared and compared to ensure that accurate data are gathered on this complex fuel.

  2. Preconcentration and separation of analytes in microchannels

    DOE Patents [OSTI]

    Hatch, Anson (Tracy, CA); Singh, Anup K. (Danville, CA); Herr, Amy E. (Fremont, CA); Throckmorton, Daniel J. (Tracy, CA)

    2010-11-09T23:59:59.000Z

    Disclosed herein are methods and devices for preconcentrating and separating analytes such as proteins and polynucleotides in microchannels. As disclosed, at least one size-exclusion polymeric element is adjacent to processing area or an assay area in a microchannel which may be porous polymeric element. The size-exclusion polymeric element may be used to manipulate, e.g. concentrate, analytes in a sample prior to assaying in the assay area.

  3. The Fusion Curve of Ammonia and Ethyl Alcohol

    E-Print Network [OSTI]

    Broderson, H.J.

    1911-01-01T23:59:59.000Z

    ’ Center for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the Graduate School of the University of Kansas for partial completion of Master of Arts. THE FUSION CURVE OF AMMONIA AND ETHYL ALCOHOL H. J. BRODERSON THE 2?03IOH CUHVB OP... AMMOHIA AND ETHXL ALCOHOL. A part of the requirement for the lh A. 2)egree. By K. J. Brodereon, University of Kangaa, May 1911, THE PUSIOB CURVS OP AliKOHlA AHD ETHYL ALCOHOL* Only within tho last fow ycara has any worlc boon done on tho fusion...

  4. Ammonia emission inventory for the state of Wyoming

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Maser, Colette R.; Brown, Nancy J.

    2003-12-17T23:59:59.000Z

    Ammonia (NH{sub 3}) is the only significant gaseous base in the atmosphere and it has a variety of impacts as an atmospheric pollutant, including the formation of secondary aerosol particles: ammonium sulfate and ammonium nitrate. NH{sub 3} preferentially forms ammonium sulfate; consequently ammonium nitrate aerosol formation may be limited by the availability of NH{sub 3}. Understanding the impact of emissions of oxides of sulfur and nitrogen on visibility, therefore, requires accurately determined ammonia emission inventories for use in air quality models, upon which regulatory and policy decisions increasingly depend. This report presents an emission inventory of NH{sub 3} for the state of Wyoming. The inventory is temporally and spatially resolved at the monthly and county level, and is comprised of emissions from individual sources in ten categories: livestock, fertilizer, domestic animals, wild animals, wildfires, soil, industry, mobile sources, humans, and publicly owned treatment works. The Wyoming NH{sub 3} inventory was developed using the Carnegie Mellon University (CMU) Ammonia Model as framework. Current Wyoming-specific activity data and emissions factors obtained from state agencies and published literature were assessed and used as inputs to the CMU Ammonia Model. Biogenic emissions from soils comprise about three-quarters of the Wyoming NH{sub 3} inventory, though emission factors from soils are highly uncertain. Published emission factors are scarce and based on limited measurements. In Wyoming, agricultural land, rangeland, and forests comprise 96% of the land area and essentially all of the estimated emissions from soils. Future research on emission rates of NH{sub 3} for these land categories may lead to a substantial change in the magnitude of soil emissions, a different inventory composition, and reduced uncertainty in the inventory. While many NH{sub 3} inventories include annual emissions, air quality modeling studies require finer temporal resolution. Published studies indicate higher emission rates from soils and animal wastes at higher temperatures, and temporal variation in fertilizer application. A recent inverse modeling study indicates temporal variation in regional NH{sub 3} emissions. Monthly allocation factors were derived to estimate monthly emissions from soils, livestock and wild animal waste based on annual emission estimates. Monthly resolution of NH{sub 3} emissions from fertilizers is based on fertilizer sales to farmers. Statewide NH{sub 3} emissions are highest in the late spring and early summer months.

  5. An Analytic Method for Predicting Simulation Parallelism

    E-Print Network [OSTI]

    Teo, Yong-Meng

    of the test-bed and its execution platform. Berry et al. [3] introduced critical path analysis of paral- lel, 8, 5, 10, 12, 15, 23]. Ferscha et al. [5] proposed a test-bed (called N-MAP) for performance, synchronization protocols and execution platforms, and performance prediction is dependent on the implementation

  6. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    valve~ allowing the energy of the sun in, but not letting itwe used the stored energy of the sun in the form of wood (awhich could use the energy of the sun to create liquid fuel

  7. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    commercially by the petrochemical industry, plus manyfor materials for the petrochemical industry,· The methanol

  8. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    breeding, commercial rubber production has been raised toused in the production of synthetic rubber the availa-

  9. V. ANALYTICAL METHODS G. Quantitative Urinary Porphobilinogen

    E-Print Network [OSTI]

    in a 250-ml brown glass bottle: (a) P-dimethylaminobenzaldehyde, 2.0 g Sigma; protect from light (b) HCl at -20 °C. at 2-8 °C. For longer 3. Reagents. Supplies. and Equipment a. Glass test tubes, disposable: 16 hood): (a) Glacial acetic acid 57 ml (b) Reagent water type I QS to 1 L (2) Transfer to brown glass

  10. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    or natural gas or even oil shale (which represents anotherto transform the coal or oil shale or gaseous, fuel. There

  11. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01T23:59:59.000Z

    K. P. "The Energy Profile of Brazil". Profiles". Science,to capture and store solar energy, is Brazil S decision to

  12. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    DTIC Review: Energy Supply Alternatives: ADA433359, 2004.Ammonia as an Alternative Energy Storage Medium for Hydrogen2007 Ammonia As an Alternative Energy Storage Medium for

  13. Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic and anthropogenic precursors

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Formation of brown carbon via reactions of ammonia with secondary organic aerosols from biogenic t aerosols change color from white to brown in pres- ence of ammonia. occurs for a wide range of biogenic and anthropogenic aerosols.

  14. An Analytic Holographic Superconductor

    E-Print Network [OSTI]

    Christopher P. Herzog

    2011-01-16T23:59:59.000Z

    We investigate a holographic superconductor that admits an analytic treatment near the phase transition. In the dual 3+1 dimensional field theory, the phase transition occurs when a scalar operator of scaling dimension two gets a vacuum expectation value. We calculate current-current correlation functions along with the speed of second sound near the critical temperature. We also make some remarks about critical exponents. An analytic treatment is possible because an underlying Heun equation describing the zero mode of the phase transition has a polynomial solution. Amusingly, the treatment here may generalize for an order parameter with any integer spin, and we propose a Lagrangian for a spin two holographic superconductor.

  15. Interaction of far-infrared and mid-infrared laser transitions in the ammonia laser

    SciTech Connect (OSTI)

    Nelson, L.Y.; Buchwald, M.I.; Jones, C.R.

    1980-01-01T23:59:59.000Z

    Mid-infrared laser emission in ammonia is usually observed on a P(J + 2) transition when a CO/sub 2/ laser is used to optically pump a near resonant R(J) absorption feature. However, by generating simultaneous FIR ammonia laser emission in the same optical cavity, mid-infrared emission is obtained exclusively on the P(J) transition.

  16. Sub-lethal ammonia toxicity in largemouth bass C.D. Suski a,,1

    E-Print Network [OSTI]

    Suski, Cory David

    . Exposure to 100 M Tamm impaired the ability of largemouth bass to recover from exercise relative to fishSub-lethal ammonia toxicity in largemouth bass C.D. Suski a,,1 , J.D. Kieffer b , S.S. Killen a,2 Available online 24 November 2006 Abstract Guidelines for ammonia toxicity in fish are often determined

  17. Anaerobic digestion for methane generation and ammonia reforming for hydrogen production

    E-Print Network [OSTI]

    ,000,000 digesters, 2000 [14]), among other places [15,16]. These digesters operate to generate biogas, comprisingAnaerobic digestion for methane generation and ammonia reforming for hydrogen production Accepted 24 May 2013 Available online Keywords: Anaerobic digestion Ammonia Bioenergy Bioammonia Hydrogen

  18. Measurement of Ammonia Emissions from Laying Hen Houses , Y. Liang2

    E-Print Network [OSTI]

    Kentucky, University of

    Measurement of Ammonia Emissions from Laying Hen Houses H. Xin1 , Y. Liang2 , R.S. Gates3 , E. F be included in the measurement to make the results representative of the production practices; relatively the sustainability of the animal industry. This paper describes measurement and some preliminary results of ammonia

  19. Studies of the Ammonia-soluble Organic Matter of the Soil.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Hamner, N.C.

    1910-01-01T23:59:59.000Z

    to Remove Clay 15 ........................................ Precipitation of the Humic Acid 17 ................................... Effect of Extended Washing with Acid 18 ................................. Effect of Various Strengths of Ammonia 19 PART... Salts 36 .................................................... Effect of Ammonia 37 .............................. Effect of Carbonates of Lime and Magnesia '37 .............................................. Hydrolysis of Humic Acid 38...

  20. ammonia-water absorption cycle: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ammonia-water absorption cycle First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 AN AMMONIA-WATER...

  1. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20T23:59:59.000Z

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  2. Ammonia scrubber testing during IDMS SRAT and SME processing. Revision 1

    SciTech Connect (OSTI)

    Lambert, D.P.

    1995-04-28T23:59:59.000Z

    This report summarizes results of the Integrated DWPF (Defense Waste Processing Facility) Melter System (IDMS) ammonia scrubber testing during the PX-7 run (the 7th IDMS run with a Purex type sludge). Operation of the ammonia scrubber during IDMS Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) processing has been completed. The ammonia scrubber was successful in removing ammonia from the vapor stream to achieve NH3 concentrations far below the 10 ppM vapor exist design basis during SRAT processing. However, during SME processing, vapor NH3 concentrations as high as 450 ppM were measured exiting the scrubber. Problems during the SRAT and SME testing were vapor bypassing the scrubber and inefficient scrubbing of the ammonia at the end of the SME cycle (50% removal efficiency; 99.9% is design basis efficiency).

  3. On-board ammonia generation and exhaust after treatment system using same

    DOE Patents [OSTI]

    Driscoll, Josh (Dunlap, IL); Robel, Wade J. (Peoria, IL); Brown, Cory A. (Pekin, IL); Urven, Jr., Roger L. (Colona, IL)

    2010-03-30T23:59:59.000Z

    Often NOx selective catalysts that use ammonia to reduce NOx within exhaust to a harmless gas require on-board storage of ammonia which can be hazardous and inconvenient. In order to generate ammonia in exhaust, the present disclosure increases a NOx concentration in exhaust from at least one combustion chamber, at least in part, by injecting fuel in a predetermined increased NOx generation sequence that includes a first injection during non-auto ignition conditions and a second injection during auto ignition conditions. At least a portion of the NOx is converted to ammonia by passing at least a portion of the exhaust with the increased NOx concentration over an ammonia-producing catalyst.

  4. Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)

    SciTech Connect (OSTI)

    You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

    2014-11-19T23:59:59.000Z

    We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

  5. Using analytic continuation for the hadronic vacuum polarization computation

    SciTech Connect (OSTI)

    Feng, Xu; Hashimoto, Shoji; Hotzel, Grit; Jansen, Karl; Petschlies, Marcus; Renner Dru B

    2014-11-01T23:59:59.000Z

    We present two examples of applications of the analytic continuation method for computing the hadronic vacuum polarization function in space- and time-like momentum regions. These examples are the Adler function and the leading order hadronic contribution to the muon anomalous magnetic moment. We comment on the feasibility of the analytic continuation method and provide an outlook for possible further applications.

  6. Method for Improving Mg Doping During Group-III Nitride MOCVD

    DOE Patents [OSTI]

    Creighton, J. Randall (Albuquerque, NM); Wang, George T. (Albuquerque, NM)

    2008-11-11T23:59:59.000Z

    A method for improving Mg doping of Group III-N materials grown by MOCVD preventing condensation in the gas phase or on reactor surfaces of adducts of magnesocene and ammonia by suitably heating reactor surfaces between the location of mixing of the magnesocene and ammonia reactants and the Group III-nitride surface whereon growth is to occur.

  7. Requirements for Predictive Analytics

    SciTech Connect (OSTI)

    Troy Hiltbrand

    2012-03-01T23:59:59.000Z

    It is important to have a clear understanding of how traditional Business Intelligence (BI) and analytics are different and how they fit together in optimizing organizational decision making. With tradition BI, activities are focused primarily on providing context to enhance a known set of information through aggregation, data cleansing and delivery mechanisms. As these organizations mature their BI ecosystems, they achieve a clearer picture of the key performance indicators signaling the relative health of their operations. Organizations that embark on activities surrounding predictive analytics and data mining go beyond simply presenting the data in a manner that will allow decisions makers to have a complete context around the information. These organizations generate models based on known information and then apply other organizational data against these models to reveal unknown information.

  8. Formation of hydroxylamine on dust grains via ammonia oxidation

    E-Print Network [OSTI]

    He, Jiao; Lemaire, Jean-Louis; Garrod, Robin T

    2015-01-01T23:59:59.000Z

    The quest to detect prebiotic molecules in space, notably amino acids, requires an understanding of the chemistry involving nitrogen atoms. Hydroxylamine (NH$_2$OH) is considered a precursor to the amino acid glycine. Although not yet detected, NH$_2$OH is considered a likely target of detection with ALMA. We report on an experimental investigation of the formation of hydroxylamine on an amorphous silicate surface via the oxidation of ammonia. The experimental data are then fed into a simulation of the formation of NH$_2$OH in dense cloud conditions. On ices at 14 K and with a modest activation energy barrier, NH$_2$OH is found to be formed with an abundance that never falls below a factor 10 with respect to NH$_3$. Suggestions of conditions for future observations are provided.

  9. Exhaust purification with on-board ammonia production

    DOE Patents [OSTI]

    Robel, Wade J. (Peoria, IL); Driscoll, James J. (Dunlap, IL); Coleman, Gerald N. (Peterborough, GB); Knox, Kevin J. (Peoria, IL)

    2009-06-30T23:59:59.000Z

    A power source is provided for use with selective catalytic reduction systems for exhaust-gas purification. The power source includes a first cylinder group with a first air-intake passage and a first exhaust passage, and a second cylinder group with a second air-intake passage and a second exhaust passage. The second air-intake passage is fluidly isolated from the first air-intake passage. A fuel-supply device may be configured to supply fuel into the first exhaust passage, and a catalyst may be disposed downstream of the fuel-supply device to convert at least a portion of the exhaust stream in the first exhaust passage into ammonia.

  10. Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii

    E-Print Network [OSTI]

    Llobrera, Jose Alvarez

    1979-01-01T23:59:59.000Z

    , [Ammonia-N] = the measured concentration of total ammonia as nitrogen, pK' = the mixed acidity-constant of the reaction, pH = the measured pH of the solution. The pK ' value for 12 ppt salinity solutions can be a computed using the procedure outlined...TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM R OSENBERGI I A Thesis by JOSE ALVAREZ LLOBRERA Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree...

  11. Analytical Chemistry Laboratory: Progress report for FY 1988

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Graczyk, D.G.; Lindahl, P.C.; Erickson, M.D.

    1988-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for fiscal year 1988 (October 1987 through September 1988). The Analytical Chemistry Laboratory is a full-cost recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. In addition, the ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques.

  12. Analytical Chemistry Laboratory progress report for FY 1991

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Graczyk, D.G.; Lindahl, P.C.; Boparai, A.S.

    1991-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year 1991 (October 1990 through September 1991). This is the eighth annual report for the ACL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. In addition, the ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques.

  13. Analytical Chemistry Laboratory progress report for FY 1989

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Graczyk, D.G.; Lindahl, P.C.; Erickson, M.D.

    1989-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year 1989 (October 1988 through September 1989). The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. In addition, the ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques.

  14. Enhancing Law Enforcement Using Data & Visual Analytics

    E-Print Network [OSTI]

    Authority of New York and New Jersey (PA NY/NJ), Pacific Northwest National Labs (PNNL), Intuidex will integrate visual analytics methods developed at PNNL to mine valuable links between entities in order Authority of New York and New Jersey (PA NY/NJ) · Pacific Northwest National Laboratory (PNNL) · Intuidex

  15. NERSC Job Logs and Analytics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Users Job Logs & Analytics Job Logs & Analytics Queue Status A listing of jobs running and waiting in the queues (NERSC login required). Queue Wait Times Batch Queue Wait...

  16. Data and Analytics Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration wouldDECOMPOSITION OFSupplementalC. L. Martin andand Analytics Strategy --- 1

  17. Fixed Bed Adsorption of Acetone and Ammonia onto Oxidized Activated Carbon Fibers

    E-Print Network [OSTI]

    Braatz, Richard D.

    Fixed Bed Adsorption of Acetone and Ammonia onto Oxidized Activated Carbon Fibers Christian L a fixed bed configuration. An oxidation treatment with nitric and sulfuric acids resulted in a significant

  18. Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions

    E-Print Network [OSTI]

    Zender, Charles

    1 Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions Chao Luo1 , Charles S. Zender1 , Huisheng Bian2 , Swen Metzger3 Abstract We use an inorganic aerosol thermodynamic equilibrium model

  19. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01T23:59:59.000Z

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  20. Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies

    E-Print Network [OSTI]

    Williams, James Jason

    1999-01-01T23:59:59.000Z

    Experiments were conducted to determine the quantity and conditions of electrochemical ozonation (O?) that maximize the dissolution of the lignin-cellulose complex. Combination treatments of anhydrous ammonia (NH?) and O? were also assessed...

  1. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  2. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  3. Carbon Capture by a Continuous, Regenerative Ammonia-Based Scrubbing Process

    SciTech Connect (OSTI)

    Resnik, K.P.; Yeh, J.T.; Pennline, H.W.

    2006-10-01T23:59:59.000Z

    Overview: To develop a knowledge/data base to determine whether an ammonia-based scrubbing process is a viable regenerable-capture technique that can simultaneously remove carbon dioxide, sulfur dioxide, nitric oxides, and trace pollutants from flue gas.

  4. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    2014: Robust Nitrogen oxideAmmonia Sensors for Vehicle on-board Emissions Control CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  5. Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater

    E-Print Network [OSTI]

    remove greater than 90% of the influent ammonia (up to 19 mgLÀ1 NH3­N) in both the synthetic the reduction in space as compared to traditional activated sludge system, ease in upgrade of existing

  6. Ris-R-1504(EN) Safety assessment of ammonia as a

    E-Print Network [OSTI]

    as part of the EU supported project "Ammonia Cracking for Clean Electric Power Technology" The study scenarios 17 2.4 Comparison with LPG driven vehicles 17 2.5 Comparison with gasoline-driven cars 18 2

  7. Effects of lysine nutrition on production characteristics and ammonia excretion of red drum Sciaenops ocellatus

    E-Print Network [OSTI]

    Webb, Kenneth Ashley

    2002-01-01T23:59:59.000Z

    satiation twice daily for 6 weeks after which total ammonia nitrogen (TAN) excretion at 4-h postprandial was determined. Diets supplemented with crystalline amino acids supported similar weight gain (94 - 98%) as that obtained by fish fed control diets...

  8. Bioassimilation versus nitrification for the removal of ammonia in aquaculture biofilters

    E-Print Network [OSTI]

    Kamps, Ray Herbert

    1996-01-01T23:59:59.000Z

    not receive an organic load, the glucose-loaded biofilters tended to accumulate more biomass. However, that the difference in the fraction of ammonia converted to biomass was non-significant indicates that a third process, heterotrophic nitrification-denitrification...

  9. Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Llobrera, Jose Alvarez

    1979-01-01T23:59:59.000Z

    TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM R OSENBERGI I A Thesis by JOSE ALVAREZ LLOBRERA Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE May 1979 Major Subject: Wildlife and Fisheries Sciences TOXICITY OF AMMONIA TO LARVAE OF THE FRESHWATER SHRIMP, MACR OBRACHIUM ROSENBERGI I A Thesis JOSE ALVAREZ LLOBRERA Approved as to style and content by: (Chairman...

  10. Development of an ammonia emission protocol and preliminary emission factor for a central Texas dairy

    E-Print Network [OSTI]

    Rose, Adam Joseph

    2004-09-30T23:59:59.000Z

    dairies. The Texas Commission on Environmental Quality (TCEQ), the Texas SAPRA, does not currently use an emission factor to permit or regulate emitted ammonia for the dairy industry. ________________________ This thesis follows the style..., and is subject to gas-phase reaction with photochemically produced hydroxyl (-OH) radicals, reaction with gaseous nitric acid (to form particulate ammonium nitrate), and with aerosols to form ammonium salts (Singh et al., 2001). Ammonia that does not react...

  11. The Analytical Sciences Digital Library (ASDL)

    E-Print Network [OSTI]

    Larive, Cynthia K.

    2009-01-01T23:59:59.000Z

    Analytical Sciences Digital Library (http://www.asdlib.org).Analytical Sciences Digital Library (ASDL) Cynthia K. LariveAnalytical Sciences Digital Library (ASDL) is a collection

  12. Nitridation under ammonia of high surface area vanadium aerogels

    SciTech Connect (OSTI)

    Merdrignac-Conanec, Odile [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)]. E-mail: odile.merdrignac@univ-rennes1.fr; El Badraoui, Khadija [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France); L'Haridon, Paul [Laboratoire Verres et Ceramiques, UMR CNRS 6512, Institut de Chimie de Rennes, Universite de Rennes 1, Campus de Beaulieu, F-35042 Rennes Cedex (France)

    2005-01-15T23:59:59.000Z

    Vanadium pentoxide gels have been obtained from decavanadic acid prepared by ion exchange on a resin from ammonium metavanadate solution. The progressive removal of water by solvent exchange in supercritical conditions led to the formation of high surface area V{sub 2}O{sub 5}, 1.6H{sub 2}O aerogels. Heat treatment under ammonia has been performed on these aerogels in the 450-900 deg. C temperature range. The oxide precursors and oxynitrides have been characterized by XRD, SEM, TGA, BET. Nitridation leads to divided oxynitride powders in which the fibrous structure of the aerogel is maintained. The use of both very low heating rates and high surface area aerogel precursors allows a higher rate and a lower threshold of nitridation than those reported in previous works. By adjusting the nitridation temperature, it has been possible to prepare oxynitrides with various nitrogen enrichment and vanadium valency states. Whatever the V(O,N) composition, the oxidation of the oxynitrides in air starts between 250 and 300 deg. C. This determines their potential use as chemical gas sensors at a maximum working temperature of 250 deg. C.

  13. Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration

    E-Print Network [OSTI]

    Bau, Domenico A.

    Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration of Geological Carbon Sequestration Article Type: Manuscript Keywords: Semi-Analytical Modeling; Iterative Methods; Geological Carbon Sequestration; Injection Site Assessment Corresponding Author: Brent Cody

  14. Intensity-based Valuation of Residential Mortgages: an Analytically Tractable Model

    E-Print Network [OSTI]

    MacIver, Malcolm A.

    Intensity-based Valuation of Residential Mortgages: an Analytically Tractable Model Vyacheslav in Mathematical Finance Abstract This paper presents an analytically tractable valuation model for residential. Our solution method is based on explicitly constructing an eigenfunction expansion of the pricing

  15. Analytical Chemistry Laboratory progress report for FY 1985

    SciTech Connect (OSTI)

    Green, D.W.; Heinrich, R.R.; Jensen, K.J.

    1985-12-01T23:59:59.000Z

    The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of technical support services to the scientific and engineering programs at ANL. In addition, ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques. The purpose of this report is to summarize the technical and administrative activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year 1985 (October 1984 through September 1985). This is the second annual report for the ACL. 4 figs., 1 tab.

  16. STRICTLY CONVERGENT ANALYTIC STRUCTURES 1 ...

    E-Print Network [OSTI]

    2015-02-03T23:59:59.000Z

    We study a new notion of strictly convergent analytic structure (consisting of .... the solutions of certain systems of equations may have power series solutions ...

  17. Sandia National Laboratories: advanced analytics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analytics Caterpillar, Sandia CRADA Opens Door to Multiple Research Projects On April 17, 2013, in Capabilities, Computational Modeling & Simulation, CRF, Materials Science,...

  18. Analytical Chemistry Core Capability Assessment - Preliminary Report

    SciTech Connect (OSTI)

    Barr, Mary E. [Los Alamos National Laboratory; Farish, Thomas J. [Los Alamos National Laboratory

    2012-05-16T23:59:59.000Z

    The concept of 'core capability' can be nebulous one. Even at a fairly specific level, where core capability equals maintaining essential services, it is highly dependent upon the perspective of the requestor. Samples are submitted to analytical services because the requesters do not have the capability to conduct adequate analyses themselves. Some requests are for general chemical information in support of R and D, process control, or process improvement. Many analyses, however, are part of a product certification package and must comply with higher-level customer quality assurance requirements. So which services are essential to that customer - just those for product certification? Does the customer also (indirectly) need services that support process control and improvement? And what is the timeframe? Capability is often expressed in terms of the currently utilized procedures, and most programmatic customers can only plan a few years out, at best. But should core capability consider the long term where new technologies, aging facilities, and personnel replacements must be considered? These questions, and a multitude of others, explain why attempts to gain long-term consensus on the definition of core capability have consistently failed. This preliminary report will not try to define core capability for any specific program or set of programs. Instead, it will try to address the underlying concerns that drive the desire to determine core capability. Essentially, programmatic customers want to be able to call upon analytical chemistry services to provide all the assays they need, and they don't want to pay for analytical chemistry services they don't currently use (or use infrequently). This report will focus on explaining how the current analytical capabilities and methods evolved to serve a variety of needs with a focus on why some analytes have multiple analytical techniques, and what determines the infrastructure for these analyses. This information will be useful in defining a roadmap for what future capability needs to look like.

  19. Analytical modeling of contaminant transport and horizontal well hydraulics

    E-Print Network [OSTI]

    Park, Eungyu

    2004-09-30T23:59:59.000Z

    transport from one-, two-, and three-dimensional finite sources in a finite-thickness aquifer using Green's function method. A library of unpublished analytical solutions with different finite source geometry is provided. A graphically integrated software...

  20. Method for reducing nitrogen oxides in combustion effluents

    DOE Patents [OSTI]

    Zauderer, Bert (Merion Station, PA)

    2000-01-01T23:59:59.000Z

    Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

  1. Summative Mass Analysis of Algal Biomass - Integration of Analytical Procedures: Laboratory Analytical Procedure (LAP)

    SciTech Connect (OSTI)

    Laurens, L. M. L.

    2013-12-01T23:59:59.000Z

    This procedure guides the integration of laboratory analytical procedures to measure algal biomass constituents in an unambiguous manner and ultimately achieve mass balance closure for algal biomass samples. Many of these methods build on years of research in algal biomass analysis.

  2. ANALYTIC COMPLETION (DRAFT) CHARLES REZK

    E-Print Network [OSTI]

    Rezk, Charles

    "Ext-p completion", and is well-known to be closely linked to computing the homotopy groups of p-completionsANALYTIC COMPLETION (DRAFT) CHARLES REZK Abstract. This is an expository treatment of what we call "analytic completion" of R- modules, which is a kind of completion defined in terms of quotients of power

  3. An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal

    E-Print Network [OSTI]

    Mukhtar, Saqib

    An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Summary Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal by extracting it from liquid manure and potentially using the recovered NH3 as fertilizer. For this purpose, lab

  4. Use of ammonia to reduce the viscosity of bottoms streams produced in hydroconversion processes

    DOE Patents [OSTI]

    Zaczepinski, Sioma (Houston, TX); Billimoria, Rustom M. (Houston, TX); Tao, Frank (Baytown, TX); Lington, Christopher G. (Houston, TX); Plumlee, Karl W. (Baytown, TX)

    1984-01-01T23:59:59.000Z

    Coal, petroleum residuum and similar carbonaceous feed materials are subjected to hydroconversion in the presence of molecular hydrogen to produce a hydroconversion effluent which is then subjected to one or more separation steps to remove lower molecular weight liquids and produce a heavy bottoms stream containing high molecular weight liquids and unconverted carbonaceous material. The viscosity of the bottoms streams produced in the separation step or steps is prevented from increasing rapidly by treating the feed to the separation step or steps with ammonia gas prior to or during the separation step or steps. The viscosity of the heavy bottoms stream produced in the final separation step is also controlled by treating these bottoms with ammonia gas. In a preferred embodiment of the invention, the effluent from the hydroconversion reactor is subjected to an atmospheric distillation followed by a vacuum distillation and the feeds to these distillations are contacted with ammonia during the distillations.

  5. Heat transfer in the plate heat exchanger of an ammonia-synthesis column

    SciTech Connect (OSTI)

    Obolentsev, Y.G.; Chus', M.S.; Norobchanskii, O.A.; Teplitshi, Y.S.; Tovazhnyanskii, L.L.

    1983-01-01T23:59:59.000Z

    The planning and construction of high-capacity synthetic ammonia plants requires the development and fabrication of unique, high unit-power equipment with high technical and economic characteristics. In foreign and domestic practice, tubular heat exchangers with relatively low heat-transfer coefficients are used. Plate heat exchangers are a promising alternative. They are compact and have a high heat energy efficiency and a relatively small metal content. To make an experimental check of the operating capability of a plate heat exchanger under ammonia production conditions, a welded plate heat exchanger was designed for an ammonia synthesis column 800mm in diameter. On prolonged testing (four years), the device provided an autothermal operating mode in the column and the heat transfer coefficient was practically constant for fixed space velocities. Consequently, the heat exchange surface was not contaminated significantly with catalyst dust, confirmed by visual observation of the heat exchanger after disassembly.

  6. Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a

    E-Print Network [OSTI]

    Senkan, Selim M.

    Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim, the adsorption of H2O and NH3 by H-bonding on previously H2O and NH3 dissociated systems, respectively are also considered. It is found that the adsorption energies and geometries of water and ammonia molecules on (101

  7. A dsorption of H2 S or SO2 on an activated carbon cloth modified by ammonia treatment

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    by treatment with ammonia/air at 300 8 C or with ammonia/steam at 800 8 C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X granular activated carbons with similar pore size distribution [3]. However, the cost of ACFs makes

  8. Evaluation of calcium chloride and ammonium thiosulfate as ammonia volatilization inhibitors for surface-applied urea

    E-Print Network [OSTI]

    Sloan, John J.

    1989-01-01T23:59:59.000Z

    (Fenn and Kissel, 1973). Ammonia exiting the soil chainber with the air-flow was captured in a boric acid indicator trap containing 40 mL of boric acid indicator solution. The boric acid indicator traps were changed every 24 h and titrated... as 90%. Calcium chloride reacts with the (NH4)2CO2 formed during urea hydrolysis in the following manner: (NH4)2CO2 + CaC12 CaCO& + 2NH4C1 Ammonium chloride is a slightly acidic product and does not produce (NH4)2CO2 in a calcareous soil. Ammonia...

  9. Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal

    E-Print Network [OSTI]

    Peters, Robert Edgar

    1972-01-01T23:59:59.000Z

    . The total nitrogen losses in the limed treatments were believed to be caused by the high solubility of organic matter in high pH solutions followed by chemical volatilization of nitrogen as ammonia. Most of this ammonia was believed to have remained... as par t of the soil air and was lost when the soil samples were taken from the columns. Denitrification was believed to be responsible for losses in the unlimed treatments. Comparison of final organic and total inorganic nitrogen concen- trationss...

  10. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    6 Autothermal Reforming ofHacker and Kordesch, 2003 Autothermal ammonia decompositionenergy needed for their autothermal reformer and also

  11. Electrospray ion source with reduced analyte electrochemistry

    DOE Patents [OSTI]

    Kertesz, Vilmos; Van Berkel, Gary J

    2013-07-30T23:59:59.000Z

    An electrospray ion (ESI) source and method capable of ionizing an analyte molecule without oxidizing or reducing the analyte of interest. The ESI source can include an emitter having a liquid conduit, a working electrode having a liquid contacting surface, a spray tip, a secondary working electrode, and a charge storage coating covering partially or fully the liquid contacting surface of the working electrode. The liquid conduit, the working electrode and the secondary working electrode can be in liquid communication. The electrospray ion source can also include a counter electrode proximate to, but separated from, said spray tip. The electrospray ion source can also include a power system for applying a voltage difference between the working electrodes and a counter-electrode. The power system can deliver pulsed voltage changes to the working electrodes during operation of said electrospray ion source to minimize the surface potential of the charge storage coating.

  12. Electrospray ion source with reduced analyte electrochemistry

    DOE Patents [OSTI]

    Kertesz, Vilmos [Knoxville, TN; Van Berkel, Gary [Clinton, TN

    2011-08-23T23:59:59.000Z

    An electrospray ion (ESI) source and method capable of ionizing an analyte molecule without oxidizing or reducing the analyte of interest. The ESI source can include an emitter having a liquid conduit, a working electrode having a liquid contacting surface, a spray tip, a secondary working electrode, and a charge storage coating covering partially or fully the liquid contacting surface of the working electrode. The liquid conduit, the working electrode and the secondary working electrode can be in liquid communication. The electrospray ion source can also include a counter electrode proximate to, but separated from, said spray tip. The electrospray ion source can also include a power system for applying a voltage difference between the working electrodes and a counter-electrode. The power system can deliver pulsed voltage changes to the working electrodes during operation of said electrospray ion source to minimize the surface potential of the charge storage coating.

  13. Analytic equivalence relations and bi-embeddability

    E-Print Network [OSTI]

    Ros, Luca Motto

    Analytic equivalence relations and bi-embeddability Luca Motto Ros Kurt G¨odel Research Center Analytic equivalence relations and bi-embeddability #12;Analytic equivalence relations A subset of a Polish Analytic equivalence relations and bi-embeddability #12;Analytic equivalence relations A subset of a Polish

  14. Method for silicon nitride precursor solids recovery

    DOE Patents [OSTI]

    Crosbie, Gary M. (Dearborn, MI); Predmesky, Ronald L. (Livonia, MI); Nicholson, John M. (Wayne, MI)

    1992-12-15T23:59:59.000Z

    Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

  15. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

  16. Analytical Chemistry Laboratory, progress report for FY 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1993 (October 1992 through September 1993). This annual report is the tenth for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has research programs in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require development or modification of methods and adaption of techniques to obtain useful analytical data. The ACL is administratively within the Chemical Technology Division (CMT), its principal ANL client, but provides technical support for many of the technical divisions and programs at ANL. The ACL has four technical groups--Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis--which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL.

  17. analytical glow discharge: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29 Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup Texas A&M University - TxSpace Summary: ......

  18. COLLEGE OF SCIENCE Computational Modeling & Data Analytics

    E-Print Network [OSTI]

    Crawford, T. Daniel

    COLLEGE OF SCIENCE Computational Modeling & Data Analytics COLLEGE OF SCIENCE Computational Modeling & Data Analytics The Bachelor of Science in Computational Modeling and Data Analytics (CMDA mathematics. It imparts the unique blend of skills from Statistics, Mathematics, and Computer Science needed

  19. Catalyst and method for production of methylamines

    DOE Patents [OSTI]

    Klier, Kamil (Bethlehem, PA); Herman, Richard G. (Whitehall, PA); Vedage, Gamini A. (Bethlehem, PA)

    1987-01-01T23:59:59.000Z

    This invention relates to an improved catalyst and method for the selective production of methylamines. More particularly, it is concerned with the preparation of stable highly active catalysts for producing methylamines by a catalytic reaction of ammonia or substituted amines and binary synthesis gas (CO+H.sub.2).

  20. Ultrasonic analyte concentration and application in flow cytometry

    DOE Patents [OSTI]

    Kaduchak, Gregory; Goddard, Greg; Salzman, Gary; Sinha, Dipen; Martin, John C.; Kwiatkowski, Christopher; Graves, Steven

    2014-07-22T23:59:59.000Z

    The present invention includes an apparatus and corresponding method for concentrating analytes within a fluid flowing through a tube using acoustic radiation pressure. The apparatus includes a function generator that outputs a radio frequency electrical signal to a transducer that transforms the radio frequency electric signal to an acoustic signal and couples the acoustic signal to the tube. The acoustic signal is converted within the tube to acoustic pressure that concentrates the analytes within the fluid.

  1. Ultrasonic analyte concentration and application in flow cytometry

    DOE Patents [OSTI]

    Kaduchak, Gregory (Los Alamos, NM); Goddard, Greg (Los Alamos, NM); Salzman, Gary (White Rock, NM); Sinha, Dipen (Los Alamos, NM); Martin, John C. (Los Alamos, NM); Kwiatkowski, Christopher (Los Alamos, NM); Graves, Steven (San Juan Pueblo, NM)

    2008-03-11T23:59:59.000Z

    The present invention includes an apparatus and corresponding method for concentrating analytes within a fluid flowing through a tube using acoustic radiation pressure. The apparatus includes a function generator that outputs a radio frequency electrical signal to a transducer that transforms the radio frequency electric signal to an acoustic signal and couples the acoustic signal to the tube. The acoustic signal is converted within the tube to acoustic pressure that concentrates the analytes within the fluid.

  2. Removal of ammonia from contaminated air in a biotrickling filter Denitrifying bioreactor combination system

    E-Print Network [OSTI]

    Removal of ammonia from contaminated air in a biotrickling filter ­ Denitrifying bioreactor of a biotrickling filter, a deni- trification reactor and a polishing bioreactor for the trickling liquid by accumulating nitrate and nitrite and avoiding generation of contaminated water. All bioreactors were packed

  3. Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light

    E-Print Network [OSTI]

    Denver, University of

    ) or directly through adsorbed nitrogen and hydrogen atoms (11, 12). Ammonia emissions from tunnel studies have mea- surements than all other data combined. Sulfur compounds in gasoline combust in the engine to help facilitate the stringent 2007 diesel engine emission requirements. These reductions

  4. mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the

    E-Print Network [OSTI]

    Atreya, Sushil

    1979-01-01T23:59:59.000Z

    mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the Primordial Atmosphere mixing ratio of am- monia of 10-5 or greater would provide a sufficient greenhouse effect to keep of longwave radiation NH3 could pro- duce a substantial "greenhouse effect" and maintain a surface temperature

  5. Chemical Engineering Journal 113 (2005) 205214 A detailed model of a biofilter for ammonia removal

    E-Print Network [OSTI]

    2005-01-01T23:59:59.000Z

    Chemical Engineering Journal 113 (2005) 205­214 A detailed model of a biofilter for ammonia removal Manresa, Spain b Department of Chemical and Environmental Engineering, University of California, Riverside, 92521 CA, USA c Department of Chemical Engineering, Universitat Aut`onoma de Barcelona, Edifici C, 08193

  6. The use of the photo-electric cell in the determination of ammonia

    E-Print Network [OSTI]

    Adams, Leon Milton

    1934-01-01T23:59:59.000Z

    , especially in the form of' ammonia or ammonium compounds, is, . enerclly 1ndicative of tho degree of polut1on. Of tho various prooodurcs that have been dovolopod for tho determination of the amount sf nitro;. , on pro:;ant as srmonla, the nethod usia...

  7. AN AMMONIA-WATER ABSORPTION-HIAT-PUMP CYCLE Donald Kuhlenschmidt, Member ASHRAE

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    to an air-source heating- only heat-pump cycle which delivers its heat in- doors via circulating liquid,000 Btuh) input unit reported. KLY WORDS Absorption Heat-pump Air conditioning heating Ammonia Donald conditioning chillers. The authors are involved in a project to use this cycle in an air source heat pump

  8. Study of an ammonia-based wet scrubbing process in a continuous flow system

    SciTech Connect (OSTI)

    Mao, James X.; Lee, Anita S.; Kitchin, John R.; Nulwala, Hunaid B.; Luebke, David R.; Damodaran, Krishnan

    2013-01-01T23:59:59.000Z

    A continuous gas and liquid flow, regenerative scrubbing process for CO{sub 2} capture was demonstrated at the bench-scale level. An aqueous ammonia-based solution captures CO{sub 2} from simulated flue gas in an absorber and releases a nearly pure stream of CO{sub 2} in the regenerator. After the regeneration, the solution of ammonium compounds is recycled to the absorber. The design of a continuous flow unit was based on earlier exploratory results from a semi-batch reactor, where a CO{sub 2} and N{sub 2} simulated flue gas mixture flowed through a well-mixed batch of ammonia-based solution. During the semi-batch tests, the solution was cycled between absorption and regeneration steps to measure the carrying capacity of the solution at various initial ammonia concentrations and temperatures. Consequentially, a series of tests were conducted on the continuous unit to observe the effect of various parameters on CO{sub 2} removal efficiency and regenerator effectiveness within the flow system. The parameters that were studied included absorber temperature, regenerator temperature, initial NH{sub 3} concentration, simulated flue gas flow rate, liquid solvent inventory in the flow system, and height of the packed-bed absorber. From this testing and subsequent testing, ammonia losses from both the absorption and regeneration steps were quantified, and attempts were made to maintain steady state during operations. Implications of experimental results with respect to process design are discussed.

  9. Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs of organisms capable of ni- trogen fixation in geothermal communities. These observations help to explain-to-alkaline geothermal springs. All life requires fixed sources of nitrogen (N), and its availabil- ity often limits

  10. Interaction between temperature and ammonia in mesophilic digesters for animal waste treatment

    E-Print Network [OSTI]

    Angenent, Lars T.

    and agricultural processing, centralized and decentralized wastewater treatment plants, and solid waste recoveryInteraction between temperature and ammonia in mesophilic digesters for animal waste treatment, and their interconnectivity on the methane yield of anaerobic processes for animal waste treatment. During period 1 (day 0

  11. Measurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles in Eastern North

    E-Print Network [OSTI]

    Aneja, Viney P.

    ).2­4 Gas-to-particle conversion can be accomplished by condensation, which adds mass onto preMeasurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles acid gas con- centrations of 0.23 g/m3 hydrochloric acid (standard deviation [SD] 0.2 g/m3 ); 1.14 g/m3

  12. Enhanced anaerobic treatment of CSTR-digested effluent from chicken manure: The effect of ammonia inhibition

    SciTech Connect (OSTI)

    Liu Zhanguang; Zhou Xuefei [Key Laboratory of Yangtze Water Environment of Ministry of Education, State Key Laboratory of Pollution and Resource Reuse, Tongji University, Shanghai 200092 (China); Zhang Yalei, E-mail: zhangyalei2003@163.com [Key Laboratory of Yangtze Water Environment of Ministry of Education, State Key Laboratory of Pollution and Resource Reuse, Tongji University, Shanghai 200092 (China); Zhu Hongguang [Institute of Modern Agricultural Science and Engineering, National Engineering Research Center of Protected Agriculture, Tongji University, Shanghai 200092 (China)

    2012-01-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Enhanced anaerobic treatment of CSTR-digested effluent from chicken manure. Black-Right-Pointing-Pointer The SCOD/TAN (soluble COD/total ammonia nitrogen) ratio was key controlling factor. Black-Right-Pointing-Pointer The threshold of the SCOD/TAN ratio was 2.4 at an influent pH of 8.5-9. - Abstract: The effect of ammonia inhibition was evaluated during the enhanced anaerobic treatment of digested effluent from a 700 m{sup 3} chicken-manure continuous stirred tank reactor (CSTR). A 12.3 L internal circulation (IC) reactor inoculated with an anaerobic granular sludge and operated at 35 {+-} 1 Degree-Sign C was employed for the investigation. With a corresponding organic loading rate of 1.5-3.5 kg-COD/m{sup 3} d over a hydraulic retention time of 1.5 d, a maximum volumetric biogas production rate of 1.2 m{sup 3}/m{sup 3} d and TCOD (total COD) removal efficiency ranging from 70% to 80% was achieved. However, the continual increase in the influent TAN content led to ammonia inhibition in the methanogenesis system. The SCOD/TAN (soluble COD/total ammonia nitrogen) ratio was presented to be the key controlling factor for the anaerobic treatment of semi-digested chicken manure, and further validation through shock loading and ammonia inhibition experiments was conducted. The threshold value of the SCOD/TAN ratio was determined to be 2.4 (corresponding to a TAN of 1250 mg/L) at an influent pH of 8.5-9.

  13. Dissolved carbonic anhydrase for enhancing post-combustion carbon dioxide hydration in aqueous ammonia

    SciTech Connect (OSTI)

    Collett, James R.; Heck, Robert W.; Zwoster, Andy

    2011-04-01T23:59:59.000Z

    Aqueous ammonia solvents that capture CO2 as ionic complexes of carbonates with ammonium have recently been advanced as alternatives to amine-based solvents due to their lower energy requirements for thermal regeneration. In ammonia based solvents, the hydration of CO2 to form bicarbonate may become a rate-limiting step as the CO2 loading increases and the resulting pH level of the solvent decreases. Variants of the enzyme carbonic anhydrase can accelerate the reversible hydration of CO2 to yield bicarbonate by more than 10(6)-fold. The possible benefit of bovine carbonic anhydrase (BCA) addition to solutions of aqueous ammonia to enhance CO2 hydration was investigated in semi-batch reactions within continuously stirred tank reactors or in a bubble column gas-liquid contactor. Adding 154 mg/liter of BCA to 2 M aqueous ammonia provided a 34.1% overall increase in the rate of CO2 hydration (as indicated by the production of [H+]) as the pH declined from 9.6 to 8.6 during sparging with a 15% CO2, 85% N-2 gas at a flow rate of 3 lpm. The benefits of adding BCA to enhance CO2 hydration were only discernable below similar to pH 9. The implications of the apparent pH limitations on the utility of BCA are discussed in the context of absorber unit operation design. Possible embodiments of carbonic anhydrase as either an immobilized catalyst or as a dissolved, recirculating catalyst in potential plant scale aqueous ammonia systems are considered as well. (C) 2010 Published by Elsevier Ltd.

  14. Analytical Chemistry Laboratory Progress Report for FY 1994

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L. [and others

    1994-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1994 (October 1993 through September 1994). This annual report is the eleventh for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has a research program in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. The ACL has four technical groups -- Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis -- which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL. The Chemical Analysis Group uses wet- chemical and instrumental methods for elemental, compositional, and isotopic determinations in solid, liquid, and gaseous samples and provides specialized analytical services. Major instruments in this group include an ion chromatograph (IC), an inductively coupled plasma/atomic emission spectrometer (ICP/AES), spectrophotometers, mass spectrometers (including gas-analysis and thermal-ionization mass spectrometers), emission spectrographs, autotitrators, sulfur and carbon determinators, and a kinetic phosphorescence uranium analyzer.

  15. Analytical solutions to matrix diffusion problems

    SciTech Connect (OSTI)

    Kekäläinen, Pekka, E-mail: pekka.kekalainen@helsinki.fi [Laboratory of Radiochemistry, Department of Chemistry, P.O. Box 55, FIN-00014 University of Helsinki (Finland)

    2014-10-06T23:59:59.000Z

    We report an analytical method to solve in a few cases of practical interest the equations which have traditionally been proposed for the matrix diffusion problem. In matrix diffusion, elements dissolved in ground water can penetrate the porous rock surronuding the advective flow paths. In the context of radioactive waste repositories this phenomenon provides a mechanism by which the area of rock surface in contact with advecting elements is greatly enhanced, and can thus be an important delay mechanism. The cases solved are relevant for laboratory as well for in situ experiments. Solutions are given as integral representations well suited for easy numerical solution.

  16. Electrolysis of Humus Solutions: An Improved Method for the Estimation of Humus.

    E-Print Network [OSTI]

    Rather, J. B. (James Burness)

    1911-01-01T23:59:59.000Z

    after electrolysis, though absent from the original solntions. Apparently the .current had produced nitric nitrogen. Nitrates mere determined colorimctrically by the phenolsulphuric acid method, a blank on the original solution being run with each... from lime and magnesia by washing with acid, with coarse and ancl placed them in a small funnel, at the bottom of which were fragments of porcelain. This was moistened with ammonia and allowed to digest for several hours. The ammonia...

  17. Analytic equivalence of geometric transitions

    E-Print Network [OSTI]

    Michele Rossi

    2014-08-28T23:59:59.000Z

    In this paper \\emph{analytic equivalence} of geometric transition is defined in such a way that equivalence classes of geometric transitions turn out to be the \\emph{arrows} of the \\cy web. Then it seems natural and useful, both from the mathematical and physical point of view, look for privileged arrows' representatives, called \\emph{canonical models}, laying the foundations of an \\emph{analytic} classification of geometric transitions. At this purpose a numerical invariant, called \\emph{bi--degree}, summarizing the topological, geometric and physical changing properties of a geometric transition, is defined for a large class of geometric transitions.

  18. An investigation of some of the effects of anhydrous ammonia on the clay minerals montmorillonite and illite

    E-Print Network [OSTI]

    Whiteley, Eli Lamar

    1959-01-01T23:59:59.000Z

    * For most plants, it is as good a source of nitrogen as any other ammoniacal form of nitrogen. The effects of ammonia on the soil have not been worked out as clearly as the effects of ammonia on plants. In recent years deterioration of the physical... potassium but less than illite. Stanford (25) found that K+ was fixed only if the material was dried. Sohn and Peech (24.), in a study of New York soils, found the highest amounts of ammonia were fixed by acid soils containing large amounts of organic...

  19. Ocean thermal plantships for production of ammonia as the hydrogen carrier.

    SciTech Connect (OSTI)

    Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

    2009-12-02T23:59:59.000Z

    Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

  20. SociAL Sensor Analytics: Measuring Phenomenology at Scale

    SciTech Connect (OSTI)

    Corley, Courtney D.; Dowling, Chase P.; Rose, Stuart J.; McKenzie, Taylor K.

    2013-06-04T23:59:59.000Z

    The objective of this paper is to present a system for interrogating immense social media streams through analytical methodologies that characterize topics and events critical to tactical and strategic planning. First, we propose a conceptual framework for interpreting social media as a sensor network. Time-series models and topic clustering algorithms are used to implement this concept into a functioning analytical system. Next, we address two scientific challenges: 1) to understand, quantify, and baseline phenomenology of social media at scale, and 2) to develop analytical methodologies to detect and investigate events of interest. This paper then documents computational methods and reports experimental findings that address these challenges. Ultimately, the ability to process billions of social media posts per week over a period of years enables the identification of patterns and predictors of tactical and strategic concerns at an unprecedented rate through SociAL Sensor Analytics (SALSA).

  1. From Metaphor to Analytic Tool

    E-Print Network [OSTI]

    Process Tracing From Metaphor to Analytic Tool Edited by ANDREW BENNETT and JEFFREY T. CHECKEL process tracing." Andrew Bennett is Professor of Government at Georgetown Uni versity. He is also: © VvoeVale/iStock.com series cover design: sue watson "Bennett and Checkel have assembled an im- pressive

  2. Analytical Plan for Roman Glasses

    SciTech Connect (OSTI)

    Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

    2011-01-01T23:59:59.000Z

    Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent “experiment” that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

  3. Black Hole Collisions, Analytic Continuation, and Cosmic Censorship

    E-Print Network [OSTI]

    Dieter R. Brill

    1995-03-27T23:59:59.000Z

    Exact solutions of the Einstein-Maxwell equations that describe moving black holes in a cosmological setting are discussed with the aim of discovering the global structure and testing cosmic censorship. Continuation beyond the horizons present in these solutions is necessary in order to identify the global structure. Therefore the possibilities and methods of analytic extension of geometries are briefly reviewed. The global structure of the Reissner-Nordstr\\"om-de Sitter geometry is found by these methods. When several black holes are present, the exact solution is no longer everywhere analytic, but less smooth extensions satisfying the Einstein equations everywhere are possible. Some of these provide counterexamples to cosmic censorship.

  4. Operating Experience and Test Results From An Ammonia-Based Dry/Wet Cooling System For Electric Power Stations

    E-Print Network [OSTI]

    Allemann, R. T.; Werry, E. V.; Fricke, H. D.; Price, R. E.; Bartz, J. A.

    1982-01-01T23:59:59.000Z

    tower by heat rejection to the atmosphere. The condenser/ reboiler features Union carbide's doubly enhanced heat transfer tubing to boil ammonia on the inside and to condense the steam externally. System description and performance characteristics...

  5. Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution

    E-Print Network [OSTI]

    Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

    A first-of-its-kind Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP™) was installed by Planetec Utility Services Co., Inc. in partnership with Energy Concepts Co. at Ultramar Diamond Shamrock's 30,000 barrel per day refinery in Denver...

  6. Sky coverage of orbital detectors. Analytical approach

    E-Print Network [OSTI]

    Diego Casadei

    2005-12-28T23:59:59.000Z

    Orbital detectors without pointing capability have to keep their field of view axis laying on their orbital plane, to observe the largest sky fraction. A general approach to estimate the exposure of each sky element for such detectors is a valuable tool in the R&D phase of a project, when the detector characteristics are still to be fixed. An analytical method to estimate the sky exposure is developed, which makes only few very reasonable approximations. The formulae obtained with this method are used to compute the histogram of the sky exposure of a hypothetical gamma-ray detector installed on the ISS. The C++ code used in this example is freely available on the http://cern.ch/casadei/software.html web page.

  7. PHYSICAL CONDITIONS AROUND 6.7 GHz METHANOL MASERS. I. AMMONIA

    SciTech Connect (OSTI)

    Pandian, J. D. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Dr., Honolulu, HI 96822 (United States); Wyrowski, F.; Menten, K. M., E-mail: jagadheep@iist.ac.in [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, 53121 Bonn (Germany)

    2012-07-01T23:59:59.000Z

    Methanol masers at 6.7 GHz are known to be tracers of high-mass star formation in our Galaxy. In this paper, we study the large-scale physical conditions in the star-forming clumps/cores associated with 6.7 GHz methanol masers using observations of the (1, 1), (2, 2), and (3, 3) inversion transitions of ammonia with the Effelsberg telescope. The gas kinetic temperature is found to be higher than in infrared dark clouds, highlighting the relatively evolved nature of the maser sources. Other than a weak correlation between maser luminosity and the ammonia line width, we do not find any differences between low- and high-luminosity methanol masers.

  8. The preparation and analysis of ammonia base sulfite pulping liquor

    E-Print Network [OSTI]

    Honstead, John Frederick

    1950-01-01T23:59:59.000Z

    much better check between results obtained by two different operators testing the same sample, and using the Palm- rose method. In a mill the liquor is test d b? shift men as the liquor is being prepared, and also by technicians in the laboratory...

  9. Analyte detection using an active assay

    DOE Patents [OSTI]

    Morozov, Victor (Manassas, VA); Bailey, Charles L. (Cross Junction, VA); Evanskey, Melissa R. (Potomac Falls, VA)

    2010-11-02T23:59:59.000Z

    Analytes using an active assay may be detected by introducing an analyte solution containing a plurality of analytes to a lacquered membrane. The lacquered membrane may be a membrane having at least one surface treated with a layer of polymers. The lacquered membrane may be semi-permeable to nonanalytes. The layer of polymers may include cross-linked polymers. A plurality of probe molecules may be arrayed and immobilized on the lacquered membrane. An external force may be applied to the analyte solution to move the analytes towards the lacquered membrane. Movement may cause some or all of the analytes to bind to the lacquered membrane. In cases where probe molecules are presented, some or all of the analytes may bind to probe molecules. The direction of the external force may be reversed to remove unbound or weakly bound analytes. Bound analytes may be detected using known detection types.

  10. Consequence analysis of aqueous ammonia spills using an improved liquid pool evaporation model

    E-Print Network [OSTI]

    Raghunathan, Vijay

    2005-02-17T23:59:59.000Z

    of effective NOx emissions from utility boilers and combustion turbines nowadays (Pritchard et al. 1995). Its applications also include reduction of NOx emissions from diesel engines, process gas streams like nitric acid plants. The flue gas emitted from... serves the purpose of a reducing medium and is replacing anhydrous ammonia in most of the Selective catalytic reduction (SCR) units. This newly developed model can estimate the vaporization rate and net mass evaporating into the air from a...

  11. The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes

    E-Print Network [OSTI]

    Oates, Margaret Deron

    1979-01-01T23:59:59.000Z

    . Jack H. Lunsford The catalytic activity of tetraamminecopper(II) complexes in aque- ous solution in the reduction of nitric oxide with ammonia nas been in- vestigated. Kinetic data for the nitric oxide reduction reaction were determined in a closed... circulating system. Electron paramagnetic reso- spectroscopy was used to determine the zelative quantity of copper in the +2 oxidation state at different temperatures. A reaction mechanism is proposed from these experimental investigations in order...

  12. Correlation of ammonia clearance with classical liver function tests in normal and liver-damaged sheep

    E-Print Network [OSTI]

    Hansson, Lucille Ann

    1984-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE May 1984 Major Subject: Veterinary Toxicology CORRELATION OF AMMONIA CLEARANCE WITH CLASSICAL LIVER FUNCTION TESTS IN NORMAL AND LIVER-DAMAGED SHEEP A Thesis LUCILLE ANN HANSSON Approved as to style and content by... together. The United States Department of Agriculture, Veterinary Toxicology and . Entomology Research Laboratory, Bryan, Texas for providing the research sheep, analysis of research samples, and the funding for this research project. TABLE OF CONTENTS...

  13. Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia

    DOE Patents [OSTI]

    Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

    1980-01-01T23:59:59.000Z

    Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

  14. INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS

    SciTech Connect (OSTI)

    G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

    2000-11-01T23:59:59.000Z

    This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

  15. Energy-efficiency comparison of advanced ammonia heat-exchanger types

    SciTech Connect (OSTI)

    Panchal, C.; Rabas, T.

    1990-01-01T23:59:59.000Z

    Ammonia is the most cost-effective working fluid for many Rankine power cycles and is widely utilized in industrial refrigeration applications. For example, it was selected as the most advantageous working fluid for the comprehensive closed-cycle Ocean Thermal Energy Conversion investigations where the heat source and sink are the warm, surface seawater and the cold, deep seawater, respectively. An essential part of this investigation was to measure the performance of many advanced heat-exchanger types using ammonia as the working fluid and to compare these results with those for conventional shell-and-tube designs. This paper presents an overview of these experiments and their potential significance for improved energy efficiency for industrial refrigeration applications. The heat exchangers used for industrial refrigeration systems account for about 50% of the equipment cost. However, current practice is to use state-of-the-art designs -- the shell-and-tube type without enhanced tubes. Substantial energy savings are possible through the use of advanced ammonia evaporator and condenser heat-exchanger types. 31 refs., 10 figs., 6 tabs.

  16. Analytical Chemistry Laboratory. Progress report for FY 1996

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1996-12-01T23:59:59.000Z

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1996. This annual report is the thirteenth for the ACL. It describes effort on continuing and new projects and contributions of the ACL staff to various programs at ANL. The ACL operates in the ANL system as a full-cost-recovery service center, but has a mission that includes a complementary research and development component: The Analytical Chemistry Laboratory will provide high-quality, cost-effective chemical analysis and related technical support to solve research problems of our clients -- Argonne National Laboratory, the Department of Energy, and others -- and will conduct world-class research and development in analytical chemistry and its applications. Because of the diversity of research and development work at ANL, the ACL handles a wide range of analytical chemistry problems. Some routine or standard analyses are done, but the ACL usually works with commercial laboratories if our clients require high-volume, production-type analyses. It is common for ANL programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. Thus, much of the support work done by the ACL is very similar to our applied analytical chemistry research.

  17. A calculation of the rotational constants of ammonia 

    E-Print Network [OSTI]

    Trickey, Samuel B

    1966-01-01T23:59:59.000Z

    the vibrational + + quantum number, 0, 0, 1, 1, ~ ~ ~, where the super- script shows the parity. Explicitly, (N even), (II-6 ) and upon choosing N we may either compute the a nv by the methods of Ref ~ 6 or we may use the tables of these coefficients... produced by those authors to de- termine our wave functions. (Use of the tables is dependent on the amount of interpolation error which is tolerable. ) We have chosen to compute the a nv and have used N 32 throughout. (See Appendix IV for a tabulation...

  18. Analytic study on backreacting holographic superconductors with dark matter sector

    E-Print Network [OSTI]

    Lukasz Nakonieczny; Marek Rogatko

    2014-11-04T23:59:59.000Z

    The variational method for Sturm-Liouville eigenvalue problem was employed to study analytically properties of the holographic superconductor with dark matter sector, in which a coupling between Maxwell field and another U(1)-gauge field was considered. The backreaction of the dark matter sector on gravitational background in question was also examined.

  19. Arguments for an Alternative Account of Analyticity

    E-Print Network [OSTI]

    Sexton, Clark Alan

    2009-11-09T23:59:59.000Z

    This dissertation presents an alternative account of analyticity, as well as arguments for that account. Although an analysis and interpretation of previous accounts of analyticity are presented, the focus is on the analysis ...

  20. RESEARCH ENGINEER IN ADVANCED ANALYTICAL ELECTRON MICROSCOPY

    E-Print Network [OSTI]

    Gilchrist, James F.

    RESEARCH ENGINEER IN ADVANCED ANALYTICAL ELECTRON MICROSCOPY Department of Materials Science. #12;Job Description (for website) Job Title: Research Engineer in Advanced Analytical Electron or an engineering discipline and four years of demonstrated experience in electron microscopy. Requirements

  1. Developer Dashboards: The Need For Qualitative Analytics

    E-Print Network [OSTI]

    Godfrey, Michael W.

    Developer Dashboards: The Need For Qualitative Analytics Olga Baysal, Reid Holmes, and Michael W-to-day development tasks. I. SOFTWARE ANALYTICS IN PRACTICE Many organizations have adopted data-driven decision

  2. PLEAEERUSH ANALYTICAL DA-~-A SHEET

    Office of Legacy Management (LM)

    ' PLEAEERUSH ANALYTICAL DA--A SHEET ' ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlON 1956 Industrial Hygiene or Medical Dept. 1. H.Sample Nos. 3 --Date Collectedby-CESS-.Route...

  3. RBS' New BAIT Major: Business Analytics and

    E-Print Network [OSTI]

    :623:386) ­ Analytics / decision making and planning ­ Building mathematical models of business situations ­ Also builds · 33:623:485 Time Series Modeling for Business · 33:623:400 Business Decision Analytics underRBS' New BAIT Major: Business Analytics and Information Technology "Introducing the New Business

  4. SUSS PM 5 Analytic Probe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited ReleaseWelcome ton n uSTEM-A SANCHEZSUSS PM 5 Analytic

  5. Analytical effective tensor for flow-through composites

    DOE Patents [OSTI]

    Sviercoski, Rosangela De Fatima (Los Alamos, NM)

    2012-06-19T23:59:59.000Z

    A machine, method and computer-usable medium for modeling an average flow of a substance through a composite material. Such a modeling includes an analytical calculation of an effective tensor K.sup.a suitable for use with a variety of media. The analytical calculation corresponds to an approximation to the tensor K, and follows by first computing the diagonal values, and then identifying symmetries of the heterogeneity distribution. Additional calculations include determining the center of mass of the heterogeneous cell and its angle according to a defined Cartesian system, and utilizing this angle into a rotation formula to compute the off-diagonal values and determining its sign.

  6. Neutron noise calculations using the Analytical Nodal Method and comparisons with analytical solutions

    E-Print Network [OSTI]

    Demazière, Christophe

    Available online 28 December 2010 Keywords: Neutron noise ANM Power reactor approximation 2-Group theory, 2004). The reactor transfer function was calculated in 2- group diffusion theory for 2D systems using of Technology, Department of Nuclear Engineering, SE-412 96 Gothenburg, Sweden a r t i c l e i n f o Article

  7. Analytical applications for delayed neutrons

    SciTech Connect (OSTI)

    Eccleston, G.W.

    1983-01-01T23:59:59.000Z

    Analytical formulations that describe the time dependence of neutron populations in nuclear materials contain delayed-neutron dependent terms. These terms are important because the delayed neutrons, even though their yields in fission are small, permit control of the fission chain reaction process. Analytical applications that use delayed neutrons range from simple problems that can be solved with the point reactor kinetics equations to complex problems that can only be solved with large codes that couple fluid calculations with the neutron dynamics. Reactor safety codes, such as SIMMER, model transients of the entire reactor core using coupled space-time neutronics and comprehensive thermal-fluid dynamics. Nondestructive delayed-neutron assay instruments are designed and modeled using a three-dimensional continuous-energy Monte Carlo code. Calculations on high-burnup spent fuels and other materials that contain a mix of uranium and plutonium isotopes require accurate and complete information on the delayed-neutron periods, yields, and energy spectra. A continuing need exists for delayed-neutron parameters for all the fissioning isotopes.

  8. Method of determining the extent to which a nickel structure has been attached by a fluorine-containing gas

    DOE Patents [OSTI]

    Brusie, James P. (Oak Ridge, TN)

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  9. Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas

    DOE Patents [OSTI]

    Brusie, James P.

    2004-07-13T23:59:59.000Z

    The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

  10. A simple analytical model to study and control azimuthal instabilities in annular combustion chambers

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A simple analytical model to study and control azimuthal instabilities in annular combustion analytical method to compute the azimuthal modes appearing in annular combustion chambers and help analyzing exper- imental, acoustic and LES (Large Eddy Simulation) data obtained in these combustion chambers

  11. Analytic Continuation of Harmonic Sums

    E-Print Network [OSTI]

    S. Albino

    2009-03-06T23:59:59.000Z

    We present a method for calculating any (nested) harmonic sum to arbitrary accuracy for all complex values of the argument. The method utilizes the relation between harmonic sums and (derivatives of) Hurwitz zeta functions, which allows a harmonic sum to be calculated as an expansion valid for large values of its argument. A program for implementing this method is also provided.

  12. The nitrate to ammonia and ceramic (NAC) process -- a newly developed low-temperature technology

    SciTech Connect (OSTI)

    Mattus, A.J.; Lee, D.D.

    1993-06-01T23:59:59.000Z

    Bench-top feasibility studies with Hanford single-shell tank (SST) simulants, using a new low-temperature (50-60C) process for converting nitrate to ammonia and ceramic (NAC), showed that between 90 and 99% of the nitrate at Hanford can be readily converted to ammonia. Aluminum powders or shot can be used to convert alkaline, nitrate-based supernate to ammonia and an alumina-silica-based ceramic solid. The process may utilize already contaminated aluminum scrap metal from various DOE sites to effect the conversion. The final nitrate-free ceramic product can be calcined, pressed, and sintered like any other ceramic. Based on starting volumes of 6.2 and 3.1 M sodium nitrate solution (probable supernate concentrations resulting from salt-cake/sludge removal from Hanford SSTs), volume reductions as high as 70% are currently obtained, compared with an expected 40 to 50% volume increase if the Hanford supernate were grouted. Engineering data indicate that the process will be very economical. Data were used to cost a batch facility with a production rate of 1200 kilograms of nitrate per hour for processing all the Hanford SST waste over 20 years. Process cost analysis indicates that between $2.01 and 2.66 will be required to convert each kilogram of nitrate. These costs are one-third to one-half of the processing costs for electrolytic and thermal processes. The ceramic waste form offers other cost savings associated with a smaller volume of waste as well as eliminates other process steps such as grouting. Silica added to the reactor, based upon the total sodium in the waste, permits us to actually bind the sodium in a nepheline phase of the final ceramic structure as well as bind most metals and nonmetals in the ceramic.

  13. Ammonia inhalation toxicity in cats: a study of acute and chronic respiratory dysfunction

    E-Print Network [OSTI]

    Dodd, Kenneth Travis

    1978-01-01T23:59:59.000Z

    Chairman of Advisory Committee: Dr. David R. Gross Twenty healthy cats were exposed to 1000 ppm of ammonia gas for a period of ten minutes. Pulmonary function tests were performed and lung samples for pathologic evaluation taken on days 0, 1, 7, 21... overdose. The lungs were removed in toto and pressure infused with buf- fered formalin until distended to in vivo size. All re- maining animals were reanesthetized and retested on days 7, 21 and 35 post-exposure. After each of these remeasurements...

  14. Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate

    E-Print Network [OSTI]

    Czarnecki, Lawrence Joseph

    1988-01-01T23:59:59.000Z

    in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

  15. Graph Analytics for Signature Discovery

    SciTech Connect (OSTI)

    Hogan, Emilie A.; Johnson, John R.; Halappanavar, Mahantesh; Lo, Chaomei

    2013-06-01T23:59:59.000Z

    Within large amounts of seemingly unstructured data it can be diffcult to find signatures of events. In our work we transform unstructured data into a graph representation. By doing this we expose underlying structure in the data and can take advantage of existing graph analytics capabilities, as well as develop new capabilities. Currently we focus on applications in cybersecurity and communication domains. Within cybersecurity we aim to find signatures for perpetrators using the pass-the-hash attack, and in communications we look for emails or phone calls going up or down a chain of command. In both of these areas, and in many others, the signature we look for is a path with certain temporal properties. In this paper we discuss our methodology for finding these temporal paths within large graphs.

  16. Analytical instrument with apparatus and method for sample concentrating

    DOE Patents [OSTI]

    Zaromb, S.

    1986-08-04T23:59:59.000Z

    A system for analysis of trace concentrations of contaminants in air includes a portable liquid chromatograph and a preconcentrator for the contaminants to be analyzed. The preconcentrator includes a sample bag having an inlet valve and an outlet valve for collecting an air sample. When the sample is collected the sample bag is connected in series with a sorbing apparatus in a recirculation loop. The sorbing apparatus has an inner gas-permeable container containing a sorbent material and an outer gas-impermeable container. The sample is circulated through the outer container and around the inner container for trapping and preconcentrating the contaminants in the sorbent material. The sorbent material may be a liquid having the same composition as the mobile phase of the chromatograph for direct injection thereinto. Alternatively, the sorbent material may be a porous, solid body, to which mobile phase liquid is added after preconcentration of the contaminants for dissolving the contaminants, the liquid solution then being withdrawn for injection into the chromatograph.

  17. Structural reliability of brittle materials - an analytical method

    E-Print Network [OSTI]

    Shields, Charles Burch

    1967-01-01T23:59:59.000Z

    on observed failure stress can be ex?la!ned. Pre~. ". cl (1) ?resents an example of this effect which illustrates the. mar'ked decrease in fai1ure. 'tran- th &7ith increasing test e1cment size z'hich is ob. . c;rved1. Testing of clem ni. . of varying... and Reliability of- Iic. chanlcal Systcr!s, Especially Ai craft Struct:ur es Aeronautical Syst. ems Div. , Al. SC, USA'& IIPAPB, Ohf o& (July 1961). 34 AI'!-";. I" D I X AN EX!DiPLE PPOBI, r:, &I '3'he comipuLcr programs presentecl in this paper do not...

  18. analytical production methods: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lucas Hackl; Jan Plefka; Theodor Schuster; Peter Uwer 2012-06-11 178 Approximate life-cycle assessment of product concepts using learning systems MIT - DSpace Summary:...

  19. BENCHMARKING THE INVARIANT EMBEDDING METHOD AGAINST ANALYTICAL SOLUTIONS IN

    E-Print Network [OSTI]

    Pázsit, Imre

    is demonstrated in three different areas. The first is the calculation of the energy spectrum of sputtered dependence were treated. The second application concerns the calculation of the path length distribution Calculation of the flux reflected back from a bounded region or from a half-space induced by an incoming

  20. analytical method comparisons: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the quantum decoherence CERN Preprints Summary: The dynamics of a qubit in a structured environment is investigated theoretically. One point of view of the model is the...

  1. Early Test Facilities and Analytic Methods for Radiation Shielding

    SciTech Connect (OSTI)

    Ingersoll, D.T.

    1992-01-01T23:59:59.000Z

    This report represents a compilation of eight papers presented at the 1992 American Nuclear Society/European Nuclear Society International Meeting held in Chicago, Illinois on November 15 20,1992. The meeting is of special significance since it commemorates the 50th anniversary of the first controlled nuclear chain reaction, which occurred, not coincidentally, in Chicago. The papers contained in this report were presented in a special session organized by the Radiation Protection and Shielding Division in keeping with the historical theme of the meeting.

  2. COMPARISON OF ANALYTICAL METHODS FOR CHARACTERIZATION OF THE THERMOCHROMIC

    E-Print Network [OSTI]

    Euler, William B.

    , electrochromic materials, and sensors.1 Another interesting property of many conjugated polymers utilized for the characterization of the electrochromic properties of conjugated polymers.7 Investigation

  3. OIL AND GREASE: A PROPOSED ANALYTICAL METHOD FOR

    E-Print Network [OSTI]

    because a slight oil residue may carryover into the oil fraction. Blend about 100 parts of Celite (vol) PE, filter and apply suction until reasonably dry. Air dry and store in a jar. Filter paper dispersion: Blend 20 7-cm filter paper disks (Whatman 1 or 40) with distilled water in a blender for 5 - 10

  4. analytic method tested: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are in line with those reported by ... Kessens, Judith M; Wester, Mirjam; Cucchiarini, Catia; Strik, Helmer 1997-01-01 158 Analysis and Modeling of Microstructured Fiber Using...

  5. analytical laboratories method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    observations Geosciences Websites Summary: Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA Christa D. Peters Environmental...

  6. analytical method validation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UV-Visible detector. The mobile phase consisting of Phosphate Buffer p H 5.0 and Acetonitrile in the ratio of 90:10VV was used. The flow rate was 1mlmin and the effluent was...

  7. analytical methods validation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UV-Visible detector. The mobile phase consisting of Phosphate Buffer p H 5.0 and Acetonitrile in the ratio of 90:10VV was used. The flow rate was 1mlmin and the effluent was...

  8. Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e& FuelInvitedinEnergyFuel Cells

  9. Composition and method to remove asbestos

    DOE Patents [OSTI]

    Block, J.

    1998-05-19T23:59:59.000Z

    A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed. The composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a hexafluorosilicate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.

  10. Composition and method to remove asbestos

    DOE Patents [OSTI]

    Block, J.

    1998-05-19T23:59:59.000Z

    A composition for transforming a chrysotile asbestos-containing material into a non-asbestos material is disclosed. The composition comprises water, at least about 30% by weight of an inorganic acid, and from about 0.1 to about 4% by weight of a tetrafluoroborate of ammonia, an alkali metal or an alkaline earth metal. A method of transforming the asbestos-containing material into a non-asbestos material using the present composition also is disclosed.

  11. Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex Christopher A. Endicott, Herbert L. Strauss,* Chambers C. Hughes, and Dirk Trauner

    E-Print Network [OSTI]

    Trauner, Dirk

    Infrared Hole Burning and Conformational Change in a Borane-Ammonia Complex Christopher A. Endicott-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethyl- phenol has a unique structure, and to investigate the nature of the hydrogen bonding, we carried out infrared

  12. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter Kenneth D a comprehensive database of ammonia emission rates (ER) from US poultry facilities. The influence of common

  13. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA Y. Liang1 , H. Xin2 , A. Casey10 ABSTRACT An ongoing project of monitoring ammonia (NH3) emissions from U.S. layer houses

  14. Proceedings of the Midwest Poultry Federation Convention, St. Paul, MN. March 16-18, 2004 Ammonia Emission from Iowa Layer Houses

    E-Print Network [OSTI]

    Kentucky, University of

    conversion as one of eight principles to reduce ammonia emission from layer hen houses. Research on reduction., Pittsburg, PA) for NH3 measurement and infrared sensor (0-5000 ± 20 ppm; Vaisala, Inc., Woburn, MA) for CO2 - Ammonia Emission from Iowa Layer Houses H. Xin1 , Y. Liang2 , R.S. Gates3 , E. F. Wheeler4 1 Professor

  15. A Parametric Study for Regenerative Ammonia-Based Scrubbing for the Capture of CO2

    SciTech Connect (OSTI)

    Resnik, K.P.; Garber, W.; Hreda, D.C.; Yeh, J.T.; Pennline, H.W.

    2006-09-01T23:59:59.000Z

    A continuous gas and liquid flow, regenerative scrubbing process for CO2 capture is currently being demonstrated at the bench-scale level. An aqueous ammonia-based solution captures CO2 from simulated flue gas in an absorber and releases a nearly pure stream of CO2 in the regenerator. After the regeneration, the solution of ammonium compounds is recycled to the absorber. The design of the continuous flow unit was based on earlier exploratory results from a semi-batch reactor, where a CO2 and N2 gas mixture flowed through a well-mixed batch of ammonia-based solution. Recently, a series of tests have been conducted on the continuous unit to observe the effect of various parameters on CO2 removal efficiency and regenerator effectiveness within the flow system. The parameters that were studied include absorber temperature, regenerator temperature, initial NH3 concentration, simulated flue gas flow rate, liquid solvent inventory in the flow system, and height of the packed-bed absorber. Results from this current testing campaign conducted in the continuous scrubbing unit as well as test results from a 5-cycle semi-batch reactor will be discussed.

  16. Nano-Scaffold Mediates Hydrogen Release and Reactivity of Ammonia Borane

    SciTech Connect (OSTI)

    Gutowska, Anna; Li, Liyu; Shin, Yongsoon; Wang, Chong M.; Li, Xiaohong S.; Linehan, John C.; Smith, R. Scott; Kay, Bruce D.; Schmid, Benjamin A.; Shaw, Wendy J.; Gutowski, Maciej S.; Autrey, Thomas

    2005-06-06T23:59:59.000Z

    One of the imposing barriers to realizing the promise of an energy economy based on hydrogen is onboard hydrogen storage for fuel-cell-powered vehicles. New materials that enable the release of dense, plentiful and pure hydrogen at temperatures less than 85 ºC are necessary to move the world from an oil-based economy to a hydrogen economy. We report a novel approach in which we deposit a hydrogen-rich material into a nanoporous scaffold. The role of the scaffold is to impose a nano-phase structure on the hydrogen-rich material thus providing an additional handle on the kinetics and thermodynamics of hydrogen release. We demonstrate on the example of ammonia borane infused in the nanoporous silica that the kinetics of hydrogen release is improved while the purity of hydrogen is increased in comparison with the release from bulk ammonia borane. These findings suggest that hydrogen rich materials infused in nanoscaffolds offer the most promising approach to date for onboard hydrogen storage

  17. Analytic calculation of properties of holographic superconductors

    E-Print Network [OSTI]

    George Siopsis; Jason Therrien

    2010-03-22T23:59:59.000Z

    We calculate analytically properties of holographic superconductors in the probe limit. We analyze the range $1/2 3/2$. We also obtain the frequency dependence of the conductivity by solving analytically the wave equation of electromagnetic perturbations. We show that the real part of the DC conductivity behaves as $e^{-\\Delta_g /T}$ and estimate the gap $\\Delta_g$ analytically. Our results are in good agreement with numerical results.

  18. Strategies for Choosing Analytics and Visualization Software...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be interchangeable. Visualization Analytics Visit Matlab Python tools: Numpy, Scipy, iPython, matplotlib Paraview Mathematica Perl IDL Python TCLTK AVSExpress R SQL ImageJFiji...

  19. Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards a reagentless sensor

    E-Print Network [OSTI]

    Mailhes, Corinne

    Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex, France Keywords: Molybdenum Silicate Reagentless developed a semi-autonomous method to detect silicate in aqueous samples. Molybdenum oxidation was used

  20. Ocean thermal energy conversion plants : experimental and analytical study of mixing and recirculation

    E-Print Network [OSTI]

    Jirka, Gerhard H.

    Ocean thermal energy conversion (OTEC) is a method of generating power using the vertical temperature gradient of the tropical ocean as an energy source. Experimental and analytical studies have been carried out to determine ...

  1. Storage option an Analytic approach

    E-Print Network [OSTI]

    Dmitry Lesnik

    2012-05-28T23:59:59.000Z

    The mathematical problem of the static storage optimisation is formulated and solved by means of a variational analysis. The solution obtained in implicit form is shedding light on the most important features of the optimal exercise strategy. We show how the solution depends on different constraint types including carry cost and cycling constraint. We investigate the relation between intrinsic and stochastic solutions. In particular we give another proof that the stochastic problem has a "bang-bang" optimal exercise strategy. We also show why the optimal stochastic exercise decision is always close to the intrinsic one. In the second half we develop a perturbation analysis to solve the stochastic optimisation problem. The obtained approximate solution allows us to estimate the time value of the storage option. In particular we find an answer to rather academic question of asymptotic time value for the mean reversion parameter approaching zero or infinity. We also investigate the differences between swing and storage problems. The analytical results are compared with numerical valuations and found to be in a good agreement.

  2. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M. (Scotia, NY)

    1989-01-01T23:59:59.000Z

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  3. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M. (Scotia, NY)

    1990-01-01T23:59:59.000Z

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  4. Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing

    SciTech Connect (OSTI)

    Bauer, H.K.; Otte, E.A.W.

    1984-10-16T23:59:59.000Z

    A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

  5. Resonance ionization for analytical spectroscopy

    DOE Patents [OSTI]

    Hurst, George S. (Oak Ridge, TN); Payne, Marvin G. (Harriman, TN); Wagner, Edward B. (Burchfield Heights, TN)

    1976-01-01T23:59:59.000Z

    This invention relates to a method for the sensitive and selective analysis of an atomic or molecular component of a gas. According to this method, the desired neutral component is ionized by one or more resonance photon absorptions, and the resultant ions are measured in a sensitive counter. Numerous energy pathways are described for accomplishing the ionization including the use of one or two tunable pulsed dye lasers.

  6. Analytical Chemistry Division's sample transaction system

    SciTech Connect (OSTI)

    Stanton, J.S.; Tilson, P.A.

    1980-10-01T23:59:59.000Z

    The Analytical Chemistry Division uses the DECsystem-10 computer for a wide range of tasks: sample management, timekeeping, quality assurance, and data calculation. This document describes the features and operating characteristics of many of the computer programs used by the Division. The descriptions are divided into chapters which cover all of the information about one aspect of the Analytical Chemistry Division's computer processing.

  7. Visual Analytics at the Pacific Northwest

    E-Print Network [OSTI]

    customers. The success of PNNL's information visualization software, such as IN-SPIRETM and StarlightTM, and publications in top visualization journals and conference proceedings are the results of PNNL researchers with a focus on analytical reasoning facilitated by interactive visual interfaces. PNNL's visual analytics team

  8. Microfabricated field calibration assembly for analytical instruments

    DOE Patents [OSTI]

    Robinson, Alex L. (Albuquerque, NM); Manginell, Ronald P. (Albuquerque, NM); Moorman, Matthew W. (Albuquerque, NM); Rodacy, Philip J. (Albuquerque, NM); Simonson, Robert J. (Cedar Crest, NM)

    2011-03-29T23:59:59.000Z

    A microfabricated field calibration assembly for use in calibrating analytical instruments and sensor systems. The assembly comprises a circuit board comprising one or more resistively heatable microbridge elements, an interface device that enables addressable heating of the microbridge elements, and, in some embodiments, a means for positioning the circuit board within an inlet structure of an analytical instrument or sensor system.

  9. The Evolving Leadership Path of Visual Analytics

    SciTech Connect (OSTI)

    Kluse, Michael; Peurrung, Anthony J.; Gracio, Deborah K.

    2012-01-02T23:59:59.000Z

    This is a requested book chapter for an internationally authored book on visual analytics and related fields, coordianted by a UK university and to be published by Springer in 2012. This chapter is an overview of the leadship strategies that PNNL's Jim Thomas and other stakeholders used to establish visual analytics as a field, and how those strategies may evolve in the future.

  10. General basic and coordination catalysis in reactions of haloaromatic compounds with ammonia in the presence of copper(I) compounds

    SciTech Connect (OSTI)

    Chumak, V.T.; Shein, S.M.

    1985-11-01T23:59:59.000Z

    This paper presents a study made to detect general basic catalysis by ammonia (reagent) in reactions of ammonolysis of haloaromatic compounds in the presence of Cu/sup +/ ions, as well as to determine the generality of the mechanisms of the catalytic replacement of a halogen atom by an amino group in the anthraquinone and benzene series.

  11. Saturn's Great Storm of 2010-2011: Evidence for ammonia and water ices from analysis of VIMS spectra

    E-Print Network [OSTI]

    Sromovsky, Lawrence; Fry, Patrick

    2015-01-01T23:59:59.000Z

    Our analysis of Cassini/VIMS near-infrared spectra of Saturn's Great Storm of 2010-2011 reveals a multi-component aerosol composition comprised primarily of ammonia ice, with a significant component of water ice. The most likely third component is ammonium hydrosulfide or some weakly absorbing material similar to what dominates visible clouds outside the storm region. Horizontally heterogeneous models favor ammonium hydrosulfide as the third component, while horizontally uniform models favor the weak absorber. Both models rely on water ice absorption to compensate for residual spectral gradients produced by ammonia ice from 3.0 microns to 3.1 microns and need the third component to fill in the sharp ammonia ice absorption peak near 2.96 microns. The best heterogeneous model has spatial coverage fractions of 55% ammonia ice, 22% water ice, and 23% ammonium hydrosulfide. The best homogeneous model has an optically thin layer of weakly absorbing particles above an optically thick layer of water ice particles coa...

  12. Degradation of untreated and anhydrous ammonia-treated wheat straw by two strains of rumen anaerobic fungi

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Degradation of untreated and anhydrous ammonia-treated wheat straw by two strains of rumen in the degradation of plant tissues. The aim of this study was to compare the degradation of untreated and anhydrous, the phloem and the parenchyma were slightly degraded and rhizoids were visible on the surface of the plant

  13. The conserved carboxy-terminal region of the ammonia channel AmtB plays a critical role in channel function

    E-Print Network [OSTI]

    Merrick, Mike

    The conserved carboxy-terminal region of the ammonia channel AmtB plays a critical role in channel-terminal residues can have very marked effects. Using the Escherichia coli AmtB protein as a model system for Amt that are best explained in terms of two distinct effects of the C-terminal region on AmtB activity. Residues

  14. Analytical Estimation of CO2 Storage Capacity in Depleted Oil and Gas Reservoirs Based on Thermodynamic State Functions

    E-Print Network [OSTI]

    Valbuena Olivares, Ernesto

    2012-02-14T23:59:59.000Z

    Numerical simulation has been used, as common practice, to estimate the CO2 storage capacity of depleted reservoirs. However, this method is time consuming, expensive and requires detailed input data. This investigation proposes an analytical method...

  15. ANALYTIC EQUIVALENCE OF NORMAL CROSSING FUNCTIONS ON A REAL ANALYTIC MANIFOLD

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ANALYTIC EQUIVALENCE OF NORMAL CROSSING FUNCTIONS ON A REAL ANALYTIC MANIFOLD Goulwen Fichou crossing singularities after a modification. We focus on the analytic equivalence of such functions with only normal crossing singularities. We prove that for such functions C right equivalence implies

  16. Multimedia Analytics Canopy is a visual analytic software suite, developed by researchers at Battelle's

    E-Print Network [OSTI]

    Multimedia Analytics Canopy is a visual analytic software suite, developed by researchers to efficiently analyze massive amounts of multimedia data. Canopy incorporates cutting-edge extraction techniques is a multimedia analytics software platform that combines cutting-edge extraction techniques, state

  17. Analytical energy spectrum for hybrid mechanical systems

    E-Print Network [OSTI]

    Honghua Zhong; Qiongtao Xie; Xiwen Guan; Murray T. Batchelor; Kelin Gao; Chaohong Lee

    2013-11-07T23:59:59.000Z

    We investigate the energy spectrum for hybrid mechanical systems described by non-parity-symmetric quantum Rabi models. A set of analytical solutions in terms of the confluent Heun functions and their analytical energy spectrum are obtained. The analytical energy spectrum includes regular and exceptional parts, which are both confirmed by direct numerical simulation. The regular part is determined by the zeros of the Wronskian for a pair of analytical solutions. The exceptional part is relevant to the isolated exact solutions and its energy eigenvalues are obtained by analyzing the truncation conditions for the confluent Heun functions. By analyzing the energy eigenvalues for exceptional points, we obtain the analytical conditions for the energy-level-crossings, which correspond to two-fold energy degeneracy.

  18. Waste minimization in analytical chemistry through innovative sample preparation techniques.

    SciTech Connect (OSTI)

    Smith, L. L.

    1998-05-28T23:59:59.000Z

    Because toxic solvents and other hazardous materials are commonly used in analytical methods, characterization procedures result in significant and costly amount of waste. We are developing alternative analytical methods in the radiological and organic areas to reduce the volume or form of the hazardous waste produced during sample analysis. For the radiological area, we have examined high-pressure, closed-vessel microwave digestion as a way to minimize waste from sample preparation operations. Heated solutions of strong mineral acids can be avoided for sample digestion by using the microwave approach. Because reactivity increases with pressure, we examined the use of less hazardous solvents to leach selected contaminants from soil for subsequent analysis. We demonstrated the feasibility of this approach by extracting plutonium from a NET reference material using citric and tartaric acids with microwave digestion. Analytical results were comparable to traditional digestion methods, while hazardous waste was reduced by a factor often. We also evaluated the suitability of other natural acids, determined the extraction performance on a wider variety of soil types, and examined the extraction efficiency of other contaminants. For the organic area, we examined ways to minimize the wastes associated with the determination of polychlorinated biphenyls (PCBs) in environmental samples. Conventional methods for analyzing semivolatile organic compounds are labor intensive and require copious amounts of hazardous solvents. For soil and sediment samples, we have a method to analyze PCBs that is based on microscale extraction using benign solvents (e.g., water or hexane). The extraction is performed at elevated temperatures in stainless steel cells containing the sample and solvent. Gas chromatography-mass spectrometry (GC/MS) was used to quantitate the analytes in the isolated extract. More recently, we developed a method utilizing solid-phase microextraction (SPME) for natural water samples. In this SPME technique, a fused-silica fiber coated with a polymeric film is exposed to the sample, extraction is allowed to take place, and then the analytes are thermally desorbed for GC analysis. Unlike liquid-liquid extraction or solid-phase extraction, SPME consumes all of the extracted sample in the analysis, significantly reducing the required sample volume.

  19. NOx adsorber and method of regenerating same

    DOE Patents [OSTI]

    Endicott, Dennis L. (Peoria, IL); Verkiel, Maarten (Metamora, IL); Driscoll, James J. (Dunlap, IL)

    2007-01-30T23:59:59.000Z

    New technologies, such as NOx adsorber catalytic converters, are being used to meet increasingly stringent regulations on undesirable emissions, including NOx emissions. NOx adsorbers must be periodically regenerated, which requires an increased fuel consumption. The present disclosure includes a method of regenerating a NOx adsorber within a NOx adsorber catalytic converter. At least one sensor positioned downstream from the NOx adsorber senses, in the downstream exhaust, at least one of NOx, nitrous oxide and ammonia concentrations a plurality of times during a regeneration phase. The sensor is in communication with an electronic control module that includes a regeneration monitoring algorithm operable to end the regeneration phase when a time rate of change of the at least one of NOx, nitrous oxide and ammonia concentrations is after an expected plateau region begins.

  20. Remediation of Uranium in the Hanford Vadose Zone Using Ammonia Gas: FY 2010 Laboratory-Scale Experiments

    SciTech Connect (OSTI)

    Szecsody, James E.; Truex, Michael J.; Zhong, Lirong; Qafoku, Nikolla; Williams, Mark D.; McKinley, James P.; Wang, Zheming; Bargar, John; Faurie, Danielle K.; Resch, Charles T.; Phillips, Jerry L.

    2010-12-01T23:59:59.000Z

    This investigation is focused on refining an in situ technology for vadose zone remediation of uranium by the addition of ammonia (NH3) gas. Objectives are to: a) refine the technique of ammonia gas treatment of low water content sediments to minimize uranium mobility by changing uranium surface phases (or coat surface phases), b) identify the geochemical changes in uranium surface phases during ammonia gas treatment, c) identify broader geochemical changes that occur in sediment during ammonia gas treatment, and d) predict and test injection of ammonia gas for intermediate-scale systems to identify process interactions that occur at a larger scale and could impact field scale implementation.Overall, NH3 gas treatment of low-water content sediments appears quite effective at decreasing aqueous, adsorbed uranium concentrations. The NH3 gas treatment is also fairly effective for decreasing the mobility of U-carbonate coprecipitates, but shows mixed success for U present in Na-boltwoodite. There are some changes in U-carbonate surface phases that were identified by surface phase analysis, but no changes observed for Na-boltwoodite. It is likely that dissolution of sediment minerals (predominantly montmorillonite, muscovite, kaolinite) under the alkaline conditions created and subsequent precipitation as the pH returns to natural conditions coat some of the uranium surface phases, although a greater understanding of these processes is needed to predict the long term impact on uranium mobility. Injection of NH3 gas into sediments at low water content (1% to 16% water content) can effectively treat a large area without water addition, so there is little uranium mobilization (i.e., transport over cm or larger scale) during the injection phase.

  1. ARPEFS as an analytic technique

    SciTech Connect (OSTI)

    Schach von Wittenau, A.E.

    1991-04-01T23:59:59.000Z

    Two modifications to the ARPEFS technique are introduced. These are studied using p(2 {times} 2)S/Cu(001) as a model system. The first modification is the obtaining of ARPEFS {chi}(k) curves at temperatures as low as our equipment will permit. While adding to the difficulty of the experiment, this modification is shown to almost double the signal-to-noise ratio of normal emission p(2 {times} 2)S/Cu(001) {chi}(k) curves. This is shown by visual comparison of the raw data and by the improved precision of the extracted structural parameters. The second change is the replacement of manual fitting of the Fourier filtered {chi}(k) curves by the use of the simplex algorithm for parameter determination. Again using p(2 {times} 2)S/Cu(001) data, this is shown to result in better agreement between experimental {chi}(k) curves and curves calculated based on model structures. The improved ARPEFS is then applied to p(2 {times} 2)S/Ni(111) and ({radical}3 {times} {radical}3) R30{degree}S/Ni(111). For p(2 {times} 2)S/Cu(001) we find a S-Cu bond length of 2.26 {Angstrom}, with the S adatom 1.31 {Angstrom} above the fourfold hollow site. The second Cu layer appears to be corrugated. Analysis of the p(2 {times} 2)S/Ni(111) data indicates that the S adatom adatom adsorbs onto the FCC threefold hollow site 1.53 {Angstrom} above the Ni surface. The S-Ni bond length is determined to be 2.13 {Angstrom}, indicating an outwards shift of the first layer Ni atoms. We are unable to assign a unique structure to ({radical}3 {times} {radical}3)R30{degree}S/Ni(111). An analysis of the strengths and weaknesses of ARPEFS as an experimental and analytic technique is presented, along with a summary of problems still to be addressed.

  2. Multifaceted regulations of gateway enzyme phenylalanine ammonia-lyase in the biosynthesis of phenylpropanoids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Xuebin; Liu, Chang-Jun

    2015-01-01T23:59:59.000Z

    Phenylpropanoid biosynthesis in plants engenders a vast variety of aromatic metabolites critically important for their growth, development, and environmental adaptation. Some of these aromatic compounds have high economic value. Phenylalanine ammonia-lyase (PAL) is the first committed enzyme in the pathway; it diverts the central flux of carbon from primary metabolism to the synthesis of myriad phenolics. Over the decades, many studies have shown that exquisite regulatory mechanisms at multiple levels control the transcription and the enzymatic activity of PALs. In this review, we present a current overview on our understanding of the complicated regulatory mechanisms governing PAL's activity; we particularlymore »highlight recent progresses in unraveling its post-translational modifications, its metabolite feedback regulation, and its enzyme organization.« less

  3. Solvated electron yields in liquid and supercritical ammonia-A statistical mechanical treatment

    SciTech Connect (OSTI)

    Schiller, Robert; Horvath, Akos [Centre for Energy Research, P.O.B. 49, Budapest H-1525 (Hungary)

    2012-12-07T23:59:59.000Z

    Earlier the geminate recombination of ions and solvated electrons, produced by ionizing radiation or laser light, was theoretically treated by a model which consisted of a Rydberg atom interacting with the thermodynamic fluctuations of the medium [R. Schiller, J. Chem. Phys. 92, 5527 (1990)]. The theory was applied to liquid-to-supercritical water [R. Schiller and A. Horvath, J. Chem. Phys. 135, 084510 (2011)]. Now it is compared with recent experiments performed on liquid-to-supercritical ammonia [J. Urbanek, A. Dahmen, J. Torres-Alacan, P. Koenigshoven, J. Lindner, and P. Voehringer, J. Phys. Chem. B 116, 2223 (2012)]. The agreement between theory and experiment seems to be reasonable. The treatment is critically assessed.

  4. COMPACT QEPAS SENSOR FOR TRACE METHANE AND AMMONIA DETECTION IN IMPURE HYDROGEN

    SciTech Connect (OSTI)

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S

    2011-11-02T23:59:59.000Z

    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  5. Evaluation of a solar intermittent refrigeration system for ice production operating with ammonia/lithium nitrate

    SciTech Connect (OSTI)

    Rivera, W.; Moreno-Quintanar, G.; Best, R. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, A.P. 34, 62580 Temixco, Mor. (Mexico); Rivera, C.O.; Martinez, F. [Facultad de Ingenieria Campus Coatzacoalcos, Universidad Veracruzana, Av. Universidad Km 7.5, 96530 Coatzacoalcos, Ver. (Mexico)

    2011-01-15T23:59:59.000Z

    A novel solar intermittent refrigeration system for ice production developed in the Centro de Investigacion en Energia of the Universidad Nacional Autonoma de Mexico is presented. The system operates with the ammonia/lithium nitrate mixture. The system developed has a nominal capacity of 8 kg of ice/day. It consists of a cylindrical parabolic collector acting as generator-absorber. Evaporator temperatures as low as -11 C were obtained for several hours with solar coefficients of performance up to 0.08. It was found that the coefficient of performance increases with the increment of solar radiation and the solution concentration. A dependency of the coefficient of performance was not founded against the cooling water temperature. Also it was found that the maximum operating pressure increases meanwhile the generation temperature decreases with an increase of the solution concentration. (author)

  6. Measuring the Boltzmann constant by mid-infrared laser spectroscopy of ammonia

    E-Print Network [OSTI]

    Mejri, S; Kozlova, O; Ayari, C; Tokunaga, Sean; Chardonnet, C; Briaudeau, S; Darquié, B; Rohart, F; Daussy, C

    2015-01-01T23:59:59.000Z

    We report on our ongoing effort to measure the Boltzmann constant, $k_B,$ using the Doppler broadening technique on ammonia. This paper presents some of the improvements made to the mid-infrared spectrometer including the use of a phase-stabilized quantum cascade laser, a lineshape analysis based on a refined physical model and an improved fitting program 2 increasing the confidence in our estimates of the relevant molecular parameters, and a first evaluation of the saturation parameter and its impact on the measurement of k B. A summary of the systematic effects contributing to the measurement is given and the optimal experimental conditions for mitigating those effects in order to reach a competitive measurement of $k_B$ at a part per million accuracy level are outlined.

  7. Measuring the Boltzmann constant by mid-infrared laser spectroscopy of ammonia

    E-Print Network [OSTI]

    S. Mejri; Papa Sow; O. Kozlova; C. Ayari; Sean Tokunaga; C. Chardonnet; S. Briaudeau; B. Darquié; F. Rohart; C. Daussy

    2015-06-05T23:59:59.000Z

    We report on our ongoing effort to measure the Boltzmann constant, $k_B,$ using the Doppler broadening technique on ammonia. This paper presents some of the improvements made to the mid-infrared spectrometer including the use of a phase-stabilized quantum cascade laser, a lineshape analysis based on a refined physical model and an improved fitting program 2 increasing the confidence in our estimates of the relevant molecular parameters, and a first evaluation of the saturation parameter and its impact on the measurement of k B. A summary of the systematic effects contributing to the measurement is given and the optimal experimental conditions for mitigating those effects in order to reach a competitive measurement of $k_B$ at a part per million accuracy level are outlined.

  8. Multifaceted regulations of gateway enzyme phenylalanine ammonia-lyase in the biosynthesis of phenylpropanoids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Xuebin [Brookhaven National Lab. (BNL), Upton, NY (United States); Liu, Chang-Jun [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    Phenylpropanoid biosynthesis in plants engenders a vast variety of aromatic metabolites critically important for their growth, development, and environmental adaptation. Some of these aromatic compounds have high economic value. Phenylalanine ammonia-lyase (PAL) is the first committed enzyme in the pathway; it diverts the central flux of carbon from primary metabolism to the synthesis of myriad phenolics. Over the decades, many studies have shown that exquisite regulatory mechanisms at multiple levels control the transcription and the enzymatic activity of PALs. In this review, we present a current overview on our understanding of the complicated regulatory mechanisms governing PAL's activity; we particularly highlight recent progresses in unraveling its post-translational modifications, its metabolite feedback regulation, and its enzyme organization.

  9. Robust Accurate Non-Invasive Analyte Monitor

    DOE Patents [OSTI]

    Robinson, Mark R. (1603 Solano NE., Albuquerque, NM 87110)

    1998-11-03T23:59:59.000Z

    An improved method and apparatus for determining noninvasively and in vivo one or more unknown values of a known characteristic, particularly the concentration of an analyte in human tissue. The method includes: (1) irradiating the tissue with infrared energy (400 nm-2400 nm) having at least several wavelengths in a given range of wavelengths so that there is differential absorption of at least some of the wavelengths by the tissue as a function of the wavelengths and the known characteristic, the differential absorption causeing intensity variations of the wavelengths incident from the tissue; (2) providing a first path through the tissue; (3) optimizing the first path for a first sub-region of the range of wavelengths to maximize the differential absorption by at least some of the wavelengths in the first sub-region; (4) providing a second path through the tissue; and (5) optimizing the second path for a second sub-region of the range, to maximize the differential absorption by at least some of the wavelengths in the second sub-region. In the preferred embodiment a third path through the tissue is provided for, which path is optimized for a third sub-region of the range. With this arrangement, spectral variations which are the result of tissue differences (e.g., melanin and temperature) can be reduced. At least one of the paths represents a partial transmission path through the tissue. This partial transmission path may pass through the nail of a finger once and, preferably, twice. Also included are apparatus for: (1) reducing the arterial pulsations within the tissue; and (2) maximizing the blood content i the tissue.

  10. Evaluation of Aqua-Ammonia Chiller Technologies and Field Site Installation

    SciTech Connect (OSTI)

    Zaltash, Abdolreza [ORNL

    2007-09-01T23:59:59.000Z

    The Naval Facilities Engineering Service Center (NFESC) has sponsored Oak Ridge National Laboratory (ORNL) to review, select, and evaluate advanced, gas-fired, 5-ton, aqua-ammonia, chiller technologies. The selection criteria was that units have COP values of 0.67 or better at Air-conditioning and Refrigeration Institute (ARI) 95 F outdoor rating conditions, an active refrigerant flow control, and a variable-speed condenser fan. These features are expected to allow these units to operate at higher ambient temperatures (up to the maximum operating temperature of 110 F) with minimal degradation in performance. ORNL evaluated three potential manufacturers of advanced, gas-fired, 5-ton, aqua-ammonia chillers-Robur, Ambian, and Cooling Technologies. Unfortunately, Robur did not meet the COP requirements and Cooling Technologies could not deliver a unit to be tested at the U.S. Department of Energy (DOE)-ORNL environmental chamber testing facility for thermally activated heat pumps. This eliminated these two technologies from further consideration, leaving only the Ambian chillers for evaluation. Two Ambian chillers were evaluated at the DOE-ORNL test facility. Overall these chillers operated well over a wide range of ambient conditions with minimal degradation in performance due to several control strategies used such as a variable speed condenser fan, a modulating burner, and active refrigerant flow control. These Ambian pre-commercial units were selected for installation and field testing at three federal facilities. NFESC worked with ORNL to assist with the site selection for installation and evaluation of these chillers. Two sites (ORNL and Naval Surface Warfare Center [NSWC] Corona) had a single chiller unit installed; and at one site (Naval Amphibious Base [NAB] Little Creek), two 5-ton chillers linked together were installed to provide 10 tons of cooling. A chiller link controller developed under this project was evaluated in the field test at Little Creek.

  11. Landau Free Energy and Analytic Tricritical Point in Holographic Superfluid

    E-Print Network [OSTI]

    Wung-Hong Huang

    2015-02-24T23:59:59.000Z

    We investigate the analytical method in studying the holographic superfluid model which is described by Maxwell field minimally coupling to a charged scalar field in a fixed AdS black hole background. We propose a method that enables us to find exact value of coefficient in the solution and thus obtain higher-order expansion of the associated Landau free energy of the holographic superfluid with flow. We determine the critical value of superfluid velocity at the tricritical point of holographic superfluid and compare it with the numerical value.

  12. Scale-Up Information for Gas-Phase Ammonia Treatment of Uranium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Thomle, Jonathan N.; Johnson, Timothy C.

    2014-09-01T23:59:59.000Z

    Uranium is present in the vadose zone at the Hanford Central Plateau and is of concern for protection of groundwater. The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau identified gas-phase treatment and geochemical manipulation as potentially effective treatment approaches for uranium and technetium in the Hanford Central Plateau vadose zone. Based on laboratory evaluation, use of ammonia vapor was selected as the most promising uranium treatment candidate for further development and field testing. While laboratory tests have shown that ammonia treatment effectively reduces the mobility of uranium, additional information is needed to enable deployment of this technology for remediation. Of importance for field applications are aspects of the technology associated with effective distribution of ammonia to a targeted treatment zone, understanding the fate of injected ammonia and its impact on subsurface conditions, and identifying effective monitoring approaches. In addition, information is needed to select equipment and operational parameters for a field design. As part of development efforts for the ammonia technology for remediation of vadose zone uranium contamination, field scale-up issues were identified and have been addressed through a series of laboratory and modeling efforts. This report presents a conceptual description for field application of the ammonia treatment process, engineering calculations to support treatment design, ammonia transport information, field application monitoring approaches, and a discussion of processes affecting the fate of ammonia in the subsurface. The report compiles this information from previous publications and from recent research and development activities. The intent of this report is to provide technical information about these scale-up elements to support the design and operation of a field test for the ammonia treatment technology.

  13. Environmental effects of dredging: Naturally occurring levels of ammonia and sulfide in pore water: An assessment of the literature. Technical notes

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Ammonia and sulfide are natural constituents of sediment. Both are very toxic to aquatic organisms. Consequently, their presence may bias dredged material toxicity bioassays that are designed to evaluate the toxicity of persistent contaminants such as heavy metals and petroleum and chlorinated hydrocarbons. The purpose of this technical note is to summarize published information on sediment pore water ammonia and sulfide concentrations that occur in situ. In a subsequent technical note, this exposure information will be coupled with ammonia and sulfide toxicity data to estimate the potential influence of these constituents on dredged material toxicity bioassays.

  14. Process Analytical Technology in biopharmaceutical manufacturing

    E-Print Network [OSTI]

    Cosby, Samuel T. (Samuel Thomas)

    2013-01-01T23:59:59.000Z

    Process Analytical Technology (PAT) became a well-defined concept within the pharmaceutical industry as a result of a major initiative by the FDA called "Pharmaceutical cGMPs for the 21st Century: A Risk-Based Approach." ...

  15. Sensor for detecting and differentiating chemical analytes

    DOE Patents [OSTI]

    Yi, Dechang (Metuchen, NJ); Senesac, Lawrence R. (Knoxville, TN); Thundat, Thomas G. (Knoxville, TN)

    2011-07-05T23:59:59.000Z

    A sensor for detecting and differentiating chemical analytes includes a microscale body having a first end and a second end and a surface between the ends for adsorbing a chemical analyte. The surface includes at least one conductive heating track for heating the chemical analyte and also a conductive response track, which is electrically isolated from the heating track, for producing a thermal response signal from the chemical analyte. The heating track is electrically connected with a voltage source and the response track is electrically connected with a signal recorder. The microscale body is restrained at the first end and the second end and is substantially isolated from its surroundings therebetween, thus having a bridge configuration.

  16. Implicit costs of data and analytics

    E-Print Network [OSTI]

    Kapicka, Bryan A. (Bryan Anderson)

    2014-01-01T23:59:59.000Z

    Firms have been able to utilize data and analytics to achieve a variety of economic benefits. To realize this value, firms have to invest in the necessary information technology, process updates, and employee training. ...

  17. Analytical Layer Planning for Nanometer VLSI Designs 

    E-Print Network [OSTI]

    Chang, Chi-Yu

    2012-10-19T23:59:59.000Z

    i ANALYTICAL LAYER PLANNING FOR NANOMETER VLSI DESIGNS A Thesis by CHI-YU CHANG Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 2012 Major Subject: Electrical Engineering ii ANALYTICAL LAYER PLANNING FOR NANOMETER VLSI DESIGNS A Thesis by CHI-YU CHANG Submitted to the Office of Graduate Studies of Texas A&M University in partial...

  18. Building up the elliptic flow: analytical insights

    E-Print Network [OSTI]

    Yoshitaka Hatta; Bo-Wen Xiao

    2014-07-15T23:59:59.000Z

    In this paper, we present a fully analytical description of the early-stage formation of elliptic flow in relativistic viscous hydrodynamics. We first construct an elliptic deformation of Gubser flow which is a boost invariant solution of the Navier-Stokes equation with a nontrivial transverse profile. We then analytically calculate the momentum anisotropy of the flow as a function of time and discuss the connection with the empirical formula by Bhalerao {\\it et al.} regarding the viscosity dependence of elliptic flow.

  19. Analytic Coleman-de Luccia Geometries

    SciTech Connect (OSTI)

    Dong, Xi; /Stanford U., ITP /Stanford U., Phys. Dept. /SLAC; Harlow, Daniel; /Stanford U., ITP /Stanford U., Phys. Dept.

    2012-02-16T23:59:59.000Z

    We present the necessary and sufficient conditions for a Euclidean scale factor to be a solution of the Coleman-de Luccia equations for some analytic potential V ({psi}), with a Lorentzian continuation describing the growth of a bubble of lower-energy vacuum surrounded by higher-energy vacuum. We then give a set of explicit examples that satisfy the conditions and thus are closed-form analytic examples of Coleman-de Luccia geometries.

  20. Enhancing the analytical performance of laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Cremers, D.A.; Chinni, R.C.; Pichahchy, A.E.; Thornquist, H.K.

    1998-12-31T23:59:59.000Z

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objective of this work is to enhance the analytical capabilities of laser-induced breakdown spectroscopy (LIBS). LIBS is a method of elemental analysis in which powerful laser pulses are focused on a sample to form a microplasma. LIBS is perhaps the most versatile elemental analysis method, applicable to a variety of different real-world analysis problems. Therefore, it is important to enhance the capabilities of the method as much as possible. Accomplishments include: (1) demonstration of signal enhancements of 5--30 times from soils and metals using a double pulse method; (2) development of a model of the observed enhancement obtained using double pulses; (3) demonstration that the analytical performance achievable using low laser-pulse energies (10 and 25 mJ) can match that achievable using an energy of 100 mJ; and (4) demonstration that time-gated detection is not necessary with LIBS.

  1. Theoretical study of the ammonia nitridation rate on an Fe (100) surface: A combined density functional theory and kinetic Monte Carlo study

    E-Print Network [OSTI]

    Yeo, Sang Chul

    Ammonia (NH[subscript 3]) nitridation on an Fe surface was studied by combining density functional theory (DFT) and kinetic Monte Carlo (kMC) calculations. A DFT calculation was performed to obtain the energy barriers ...

  2. Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report

    E-Print Network [OSTI]

    Lipman, Tim; Shah, Nihar

    2007-01-01T23:59:59.000Z

    as a fuel in solid oxide fuel cells,” J. Power Sources 118:L. and Bloomfield, D.P. , “Ammonia Cracker for Fuel Cells”,1998 Fuel Cell Seminar Abstracts, November 16-19, Palm

  3. Method and apparatus for forming conformal SiN.sub.x films

    DOE Patents [OSTI]

    Wang, Qi (Littleton, CO)

    2007-11-27T23:59:59.000Z

    A silicon nitride film formation method includes: Heating a substrate to be subjected to film formation to a substrate temperature; heating a wire to a wire temperature; supplying silane, ammonia, and hydrogen gases to the heating member; and forming a silicon nitride film on the substrate.

  4. IEEE TRANSACTIONS ON MAGNETICS, VOL. 42, NO. 7, JULY 2006 1861 Analytical Design of Permanent-Magnet

    E-Print Network [OSTI]

    Mi, Chunting "Chris"

    IEEE TRANSACTIONS ON MAGNETICS, VOL. 42, NO. 7, JULY 2006 1861 Analytical Design of Permanent-Magnet Traction-Drive Motors Chunting Chris Mi Department of Electrical and Computer Engineering, University of Michigan, Dearborn, MI 48128 USA This paper presents an analytical method for the design of permanent-magnet

  5. Detection of Low Volatility Organic Analytes on Soils Using Infrared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Volatility Organic Analytes on Soils Using Infrared Reflection Spectroscopy. Detection of Low Volatility Organic Analytes on Soils Using Infrared Reflection Spectroscopy....

  6. analytical system involving: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analytics. Desired: Successful completion of graduate courses in general linear models or statistical quality control Shepp, Larry 3 Analytic reconstruction of some...

  7. An Analytical Approach for Tail-Pipe Emissions Estimation with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Analytical Approach for Tail-Pipe Emissions Estimation with Coupled Engine and Aftertreatment System An Analytical Approach for Tail-Pipe Emissions Estimation with Coupled...

  8. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

    SciTech Connect (OSTI)

    Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

    2010-10-01T23:59:59.000Z

    Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOE’s 2010 and 2015 targets for system wt%.

  9. BUSINESS ANALYTICS CONCENTRATION FOR UNDERGRADUATES The business analytics concentration, like a major, focuses on using information to develop business

    E-Print Network [OSTI]

    Salama, Khaled

    their business models. Possible Job Titles Data scientist, business analytics specialist, customer relationshipBUSINESS ANALYTICS CONCENTRATION FOR UNDERGRADUATES The business analytics concentration, like a major, focuses on using information to develop business insights and influence decision

  10. Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction

    SciTech Connect (OSTI)

    Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-01-15T23:59:59.000Z

    Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

  11. Technical and economic assessment of the use of ammonia expanders for energy recovery in air-cooled power plants

    SciTech Connect (OSTI)

    Hauser, S.G.; Hane, G.J.; Johnson, B.M.

    1982-07-01T23:59:59.000Z

    Binary cycle power plants have been the subject of much discussion among engineers and scientists for nearly 100 years. Current economic and environmental concerns have stimulated new interest and research. Ammonia has been recommended by other studies as the leading contender for use as simply the heat rejection medium in an air-cooled power plant. This study investigates the technical feasibility and economic potential of including an expander in the heat rejection system of an air-cooled power plant. The expander would be used during certain parts of the year to increase the total output of the power plant. Five different plant locations (Miami, San Francisco, Bakersfield, Chicago, Anchorage) were investigated to show the effect which climate has on the economic potential of this ammonia bottoming cycle. The study shows that the expected energy costs for the bottoming cycle only will be less than 50 mills/kWh for any of the five plant locations. This cost assumes that an ammonia phase-change heat rejection system is already a part of the existing plant. The colder climates of Chicago and Anchorage demonstrate an even smaller energy cost of less than 15 mills/kWh. Further investigation of the concept is merited to substantiate these costs and determine the needed technology.

  12. Computing combustion noise by combining Large Eddy Simulations with analytical models for the propagation of waves

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Computing combustion noise by combining Large Eddy Simulations with analytical models +++++ Presented by Ignacio Duran Abstract Two mechanisms control combustion noise generation as shown by Marble. A method to calculate combustion-generated noise has been implemented in a tool called CHORUS. The method

  13. Analytical solution of electronic transport through a benzene molecule using lattice Green's functions

    E-Print Network [OSTI]

    E. J. C. Dias; N. M. R. Peres

    2015-02-25T23:59:59.000Z

    Using a Green's function formalism we derive analytical expressions for the electronic transmittance through a benzene ring. To motivate the approach we first solve the resonant level system and then extend the method to the benzene case. These results can be used to validate numerical methods.

  14. Semantic Interaction for Visual Analytics: Toward Coupling Cognition and Computation

    SciTech Connect (OSTI)

    Endert, Alexander

    2014-07-01T23:59:59.000Z

    The dissertation discussed in this article [1] was written in the midst of an era of digitization. The world is becoming increasingly instrumented with sensors, monitoring, and other methods for generating data describing social, physical, and natural phenomena. Thus, data exist with the potential of being analyzed to uncover, or discover, the phenomena from which it was created. However, as the analytic models leveraged to analyze these data continue to increase in complexity and computational capability, how can visualizations and user interaction methodologies adapt and evolve to continue to foster discovery and sensemaking?

  15. The cosmological model with an analytic exit from inflation

    E-Print Network [OSTI]

    S. V. Chervon; V. M. Zhuravlev

    1999-07-14T23:59:59.000Z

    A cosmological model of homogeneous and isotropic spatially flat Universe with gravitating self-interacting scalar field is considered. The exact solution, admitting an analytical exit from inflationary stage into a radiation era and a matter dominated epoch, is obtained by virtue of ``fine turning of the potential'' method. We found that an inflationary stage is supported by decay of higgs bosons in the framework of the solution obtained. Freidmann's regim is associated with adiabatical expantion of the Universe, filled by the matter with special equation of state. Thus we presented the exact solution which solve the problem of transition from an inflationary to a radiation eras or long standing `exit' problem.

  16. Data driven analytic continuation for one particle spectral functions

    SciTech Connect (OSTI)

    Liu, Jun [Ames Laboratory

    2013-01-01T23:59:59.000Z

    In this proceeding, an idea is outlined suggesting a generic treatment on any type of input data for a numerical analytic continuation problem, which is needed when dynamical information is to be extracted from a calculationally convenient one particle imaginary time Green function. The quality of the resulting spectral function will rely only on the data to be treated, viz, data-driven. This is different from the Maximum Entropy or the Stochastic method which relies on an entropy term to guide convergence of the resulting spectral function.

  17. Massive quiescent cores in Orion. IV. Their supercritical state revealed by high resolution ammonia maps

    E-Print Network [OSTI]

    Li, D; Zhang, Q; Chen, W

    2012-01-01T23:59:59.000Z

    We present combined VLA and GBT images of \\ammonia\\ inversion transitions (1,1) and (2,2) toward OMC2 and OMC3. We focus on the relatively quiescent Orion cores, which are away from the Trapezium cluster and have no sign of massive protostars nor evolved star formation, such as IRAS source, water maser, and methanol maser. The 5\\arcsec\\ angular resolution and $0.6 \\rm{}km s^{-1}$ velocity resolution of these data enable us to study the thermal and dynamic state of these cores at $\\sim{}0.02 \\rm{}pc$ scales, comparable to or smaller than those of the current dust continuum surveys. We measure temperatures for a total of 30 cores, with average masses and radii of $11 \\Ms$ and $0.039 \\rm{}pc$, respectively. Compared to other Gould Belt dense cores, the Orion cores have an unusually high gravitational-to-inetic energy ratio (virial mass ratio $R_{vir} > >1$), resembling results for other clouds forming high--mass stars. This results from Orion cores having velocity dispersions similar to those in, e.g., Perseus a...

  18. Kinetics Study of Solid Ammonia Borane Hydrogen Release – Modeling and Experimental Validation for Chemical Hydrogen Storage

    SciTech Connect (OSTI)

    Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

    2014-02-24T23:59:59.000Z

    Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200°C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300°C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20°C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

  19. Supernova neutrino oscillations: A simple analytical approach

    E-Print Network [OSTI]

    G. L. Fogli; E. Lisi; D. Montanino; A. Palazzo

    2001-11-15T23:59:59.000Z

    Analyses of observable supernova neutrino oscillation effects require the calculation of the electron (anti)neutrino survival probability P_ee along a given supernova matter density profile. We propose a simple analytical prescription for P_ee, based on a double-exponential form for the crossing probability and on the concept of maximum violation of adiabaticity. In the case of two-flavor transitions, the prescription is shown to reproduce accurately, in the whole neutrino oscillation parameter space, the results of exact numerical calculations for generic (realistic or power-law) profiles. The analytical approach is then generalized to cover three-flavor transitions with (direct or inverse) mass spectrum hierarchy, and to incorporate Earth matter effects. Compact analytical expressions, explicitly showing the symmetry properties of P_ee, are provided for practical calculations.

  20. Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts

    SciTech Connect (OSTI)

    Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

    1999-09-10T23:59:59.000Z

    Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

  1. Analytical modeling of balloon launch dynamics

    E-Print Network [OSTI]

    Strganac, Thomas W

    1980-01-01T23:59:59.000Z

    Subject; Aerospace Engineer1ng ANALYTICAL MODELING OF BALLOON LAUNCH DYNAMICS A Thesis by THOMAS WILLIAM STRGANAC Approved as to sty1e and content by: (Chairman of Committee) (Member) (Member) (Head of Dep rtment) December 1980 ABSTRACT Analyt1... aerodynam1cs. Actual fl1ght data has been used to qualify the model via comparisons of the launch trans1ent configurations. DEDICATION To my father. . THOMAS JOHN STRGANAC 1922-1980 . . . who provided me the examp1e to fo1Iow in life. ACKNOWLEDGEMENTS...

  2. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  3. Notes on analytical study of holographic superconductors with Lifshitz scaling in external magnetic field

    E-Print Network [OSTI]

    Zixu Zhao; Qiyuan Pan; Jiliang Jing

    2014-07-21T23:59:59.000Z

    We employ the matching method to analytically investigate the holographic superconductors with Lifshitz scaling in an external magnetic field. We discuss systematically the restricted conditions for the matching method and find that this analytic method is not always powerful to explore the effect of external magnetic field on the holographic superconductors unless the matching point is chosen in an appropriate range and the dynamical exponent $z$ satisfies the relation $z=d-1$ or $z=d-2$. From the analytic treatment, we observe that Lifshitz scaling can hinder the condensation to be formed, which can be used to back up the numerical results. Moreover, we study the effect of Lifshitz scaling on the upper critical magnetic field and reproduce the well-known relation obtained from Ginzburg-Landau theory.

  4. Guide to Savannah River Laboratory Analytical Services Group

    SciTech Connect (OSTI)

    Not Available

    1990-04-01T23:59:59.000Z

    The mission of the Analytical Services Group (ASG) is to provide analytical support for Savannah River Laboratory Research and Development Programs using onsite and offsite analytical labs as resources. A second mission is to provide Savannah River Site (SRS) operations with analytical support for nonroutine material characterization or special chemical analyses. The ASG provides backup support for the SRS process control labs as necessary.

  5. NERSC Analytics Program Status and Update

    E-Print Network [OSTI]

    Geddes, Cameron Guy Robinson

    spanning all aspects of analytics, high performance computing, and many science domains. · SGI Altix ­ 32, application, and deployment of a diverse array of technologies spanning the domains of high performance computing, data management, data analysis and visualization, and workflow management. #12;DOE CGF April 29

  6. Software Analytics: Achievements and Challenges Dongmei Zhang

    E-Print Network [OSTI]

    Xie, Tao

    , USA Email: xie@csc.ncsu.edu Abstract--A huge wealth of various data exist in the practice of software insightful and actionable information; such information is used for completing various tasks around software and challenges of research and practice on principles, techniques, and applications of soft- ware analytics

  7. Analytical Study of Thermonuclear Reaction Probability Integrals

    E-Print Network [OSTI]

    M. A. Chaudhry; H. J. Haubold; A. M. Mathai

    2000-01-16T23:59:59.000Z

    An analytic study of the reaction probability integrals corresponding to the various forms of the slowly varying cross-section factor $S(E)$ is attempted. Exact expressions for reaction probability integrals are expressed in terms of the extended gamma functions.

  8. A low-temperature process for the denitration of Hanford single-shell tank, nitrate-based waste utilizing the nitrate to ammonia and ceramic (NAC) or nitrate to ammonia and glass (NAG) process: Phase 2 report

    SciTech Connect (OSTI)

    Mattus, A.J.; Walker, J.F. Jr.; Youngblood, E.L.; Farr, L.L.; Lee, D.D.; Dillow, T.A.; Tiegs, T.N.

    1994-12-01T23:59:59.000Z

    Continuing benchtop studies using Hanford single-shell tank (SST) simulants and actual Oak Ridge National Laboratory (ORNL) low-level waste (LLW), employing a new denitration process for converting nitrate to ammonia and ceramic (NAC), have conclusively shown that between 85 and 99% of the nitrate can be readily converted to gaseous ammonia. In this process, aluminum powders can be used to convert alkaline, nitrate-based supernate to ammonia and an aluminum oxide-sodium aluminate-based solid. The process may be able to use contaminated aluminum scrap metal from DOE sites to effect the conversion. The final, nitrate-free ceramic product can be pressed and sintered like other ceramics or silica and/or fluxing agents can be added to form a glassy ceramic or a flowable glass product. Based upon the starting volumes of 6.2 and 3.1 M sodium nitrate solution, volume reductions of 50 to 70% were obtained for the waste form produced. Sintered pellets produced from supernate from Melton Valley Storage Tanks (MVSTs) have been leached in accordance with the 16.1 leach test for the radioelements {sup 85}Sr and {sup 137}Cs. Despite lengthy counting times, {sup 85}Sr could not be detected in the leachates. {sup 137}Cs was only slightly above background and corresponded to a leach index of 12.2 to 13.7 after 8 months of leaching. Leach testing of unsintered and sintered reactor product spiked with hazardous metals proved that both sintered and unsintered product passed the Toxicity Characteristic Leaching Procedure (TCLP) test. Design of the equipment and flowsheet for a pilot demonstration-scale system to prove the nitrate destruction portion of the NAC process and product formation is under way.

  9. Hanford Environmental Analytical Methods (methods of of March 1990). Volume 1

    SciTech Connect (OSTI)

    Goheen, S.C.; McCulloch, M.; Daniel, J.L.

    1993-05-01T23:59:59.000Z

    Techniques in use at the Hanford Reservation as of March, 1990 for the analysis of liquids and radioactive effluents are described. Limitations and applications of the techniques are included.

  10. Trace Analytical Techniques for Nuclear Forensics

    SciTech Connect (OSTI)

    Halverson, J.E.

    1999-04-28T23:59:59.000Z

    Over the history of the Savannah River Site, the Savannah River Technology Center (SRTC) has developed high sensitivity analytical capabilities in support of the Site's Environmental Monitoring Program and nuclear material protection process. Many of these techniques are applicable to the developing need for nuclear forensic analysis capabilities. Radiological and critically control procedures are in place at the SRTC, as well as clean room practices, to minimize the potential for a radiological evidentiary sample to contaminate personnel and the facility, as well as to minimize contaminating the sample thus rendering it useless by law enforcement agencies. Some of the trace analytical techniques available at the SRTC include ultra-low-level gamma and alpha spectrometry, high-sensitivity thermal ionization mass spectrometry, time-of-flight secondary ion mass spectrometry and trace organic analyses. These techniques have been tested during a planned domestic smuggling exercise and in the analysis of an unknown sample.In the event of an interdiction involving the illegal use or movement of radioactive material by U.S. law enforcement agencies (local, state or federal) forensic analyses will be used in developing and building a legal case against the perpetrators. The Savannah River Technology Center (SRTC) at the U.S. Department of Energy's Savannah River Site, a former nuclear production site currently conducting nuclear material stabilization missions, located in Aiken South Carolina, has a long history of performing trace analytical analyses for environmental monitoring. Many of these techniques are also applicable to nuclear forensic analyses. A summary of the trace analytical techniques used at the SRTC, which are applicable to Nuclear Forensics, is presented in this paper.Contamination control, of facilities and personnel involved in the analytical analyses, as well as preventing contamination of the sample, is a unique challenge for nuclear forensic analyses. A discussion of sample handling and contamination control procedures is included in this paper. Some of the applicable analytical techniques available at the SRTC for nuclear forensic analyses include: ultra-low-level gamma and alpha spectroscopy, high-sensitivity thermal-ionization mass spectrometry (TIMS), time-of-flight secondary ion mass spectrometry (TOF-SIMS), and trace organic analyses. Results from analyses of special nuclear material (SNM) standards, materials from nuclear smuggling exercises, and materials of unknown origin will be presented.

  11. An Analytical Solution on Convective and Diffusive Transport of Analyte in Laminar Flow of Microfluidic Slit

    E-Print Network [OSTI]

    Chen, X.

    Microfluidic devices could find applications in many areas, such as BioMEMs, miniature fuel cells and microfluidic cooling of electronic circuitry. One of the important considerations of microfluidic device in analytical ...

  12. Comparison of open source visual analytics toolkits.

    SciTech Connect (OSTI)

    Crossno, Patricia Joyce; Harger, John R.

    2010-11-01T23:59:59.000Z

    We present the results of the first stage of a two-stage evaluation of open source visual analytics packages. This stage is a broad feature comparison over a range of open source toolkits. Although we had originally intended to restrict ourselves to comparing visual analytics toolkits, we quickly found that very few were available. So we expanded our study to include information visualization, graph analysis, and statistical packages. We examine three aspects of each toolkit: visualization functions, analysis capabilities, and development environments. With respect to development environments, we look at platforms, language bindings, multi-threading/parallelism, user interface frameworks, ease of installation, documentation, and whether the package is still being actively developed.

  13. Analytical model for Stirling cycle machine design

    E-Print Network [OSTI]

    Formosa, Fabien; 10.1016/j.enconman.2010.02.010

    2013-01-01T23:59:59.000Z

    In order to study further the promising free piston Stirling engine architecture, there is a need of an analytical thermodynamic model which could be used in a dynamical analysis for preliminary design. To aim at more realistic values, the models have to take into account the heat losses and irreversibilities on the engine. An analytical model which encompasses the critical flaws of the regenerator and furthermore the heat exchangers effectivenesses has been developed. This model has been validated using the whole range of the experimental data available from the General Motor GPU-3 Stirling engine prototype. The effects of the technological and operating parameters on Stirling engine performance have been investigated. In addition to the regenerator influence, the effect of the cooler effectiveness is underlined.

  14. An Analytical Study of Thermophoretic Particulate Deposition in Turbulent Pipe Flows

    SciTech Connect (OSTI)

    Abarham, Mehdi [University of Michigan; Hoard, John W. [University of Michigan; Assanis, Dennis [University of Michigan; Styles, Dan [Ford Motor Company; Sluder, Scott [ORNL; Storey, John Morse [ORNL

    2010-01-01T23:59:59.000Z

    The presence of a cold surface in non-isothermal pipe flows conveying submicron particles causes thermophoretic particulate deposition. In this study, an analytical method is developed to estimate thermophoretic particulate deposition efficiency and its effect on overall heat transfer coefficient of pipe flows in transition and turbulent flow regimes. The proposed analytical solution has been validated against experiments conducted at Oak Ridge National Laboratory. Exhaust gas carrying submicron soot particles was passed through pipes with a constant wall temperature and various designed boundary conditions to correlate transition and turbulent flow regimes. Prediction of the reduction in heat transfer coefficient and particulate mass deposited has been compared with experiments. The results of the analytical method are in a reasonably good agreement with experiments.

  15. Radiochemical method development

    SciTech Connect (OSTI)

    Erickson, M.D.; Aldstadt, J.H.; Alvarado, J.S.; Crain, J.S.; Orlandini, K.A.; Smith, L.L.

    1994-09-01T23:59:59.000Z

    The authors have developed methods for chemical characterization of the environment under a multitask project that focuses on improvement of radioanalytical methods with an emphasis on faster and cheaper routine methods. The authors have developed improved methods for separation of environmental levels of technetium-99, radium, and actinides from soil and water; separation of actinides from soil and water matrix interferences; and isolation of strontium. They are also developing methods for simultaneous detection of multiple isotopes (including nonradionuclides) by using a new instrumental technique, inductively coupled plasma-mass spectrometry (ICP-MS). The new ICP-MS methods have greater sensitivity and efficiency and could replace many radiometric techniques. They are using flow injection analysis to integrate and automate the separation methods with the ICP-MS methodology. The final product of all activities will be methods that are available (published in the U.S. Department of Energy`s analytical methods compendium) and acceptable for use in regulatory situations.

  16. Analytical evaluation of onion flavor and pungency

    E-Print Network [OSTI]

    Fitzgerald, James Wallace

    1980-01-01T23:59:59.000Z

    Major Subject: Food Science and Technology ANALYTICAL EVALUATION OF ONION FLAVOR AND PUNGENCY A Thesis by James Wallace Fitzgerald Approved as to st le and content by: Chairman of Committee He d of Departmen Member Member December 1980..., and love. It is to these special people that this manuscr1pt 1s dedicated. TABLE OF CONTENTS Abstract . Acknowledgements Table of Contents List of Tables . List of Figures Introduction . Objectives Literature Review History . Food Value Flavor...

  17. Experimental and analytical study of rotating cavitation

    SciTech Connect (OSTI)

    Kamijo, Kenjiro; Shimura, Takashi; Tsujimoto, Yoshinobu [National Aerospace Lab., Miyagi (Japan). Kakuda Research Center

    1994-12-31T23:59:59.000Z

    This paper describes experimental and analytical results of rotating cavitation. There are four major sections in this paper. The first section presents the main characteristics of rotating cavitation which was found in the inducer test using a water tunnel. The second section describes the rotating cavitation which occurred in the development test of an LE-7 liquid oxygen pump for the H-II rocket. Also described in this section is how the rotating cavitation was suppressed. The rotating cavitation was the cause of both super synchronous shaft vibration and an unstable head coefficient curve. The third section presents how the theory of rotating cavitation was developed. The final section shows the measured cavitation compliance and mass flow gain factor of the LE-7 pump inducer for comparison of the experimental and analytical results of the rotating cavitation of the LE-7 pump inducer. Almost all the information presented in this paper has already been reported by Kamijo et al. (1977, 1980, 1993, 1993) and by Shimura (1993). In the present paper, the authors attempt to combine and give a clear overview of the experimental and analytical results described in the previous papers to systematically show their experience and findings on rotating cavitation.

  18. Method of multiplexed analysis using ion mobility spectrometer

    DOE Patents [OSTI]

    Belov, Mikhail E. (Richland, WA); Smith, Richard D. (Richland, WA)

    2009-06-02T23:59:59.000Z

    A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.

  19. Validation of the SASSI2010 Subtraction Method Using Full Scale...

    Office of Environmental Management (EM)

    & Publications SASSI Analytical Methods Compared with SHAKE Results SASSI Breakout Session Application of the Computer Program SASSI for Seismic SSI Analysis of WTP Facilities...

  20. Structural And Biochemical Characterization of the Therapeutic A. Variabilis Phenylalanine Ammonia Lyase

    SciTech Connect (OSTI)

    Wang, L.; Gamez, A.; Archer, H.; Abola, E.E.; Sarkissian, C.N.; Fitzpatrick, P.; Wendt, D.; Zhang, Y.; Vellard, M.; Bliesath, J.; Bell, S.; Lemont, J.; Scriver, C.R.; Stevens, R.C.

    2009-05-26T23:59:59.000Z

    We have recently observed promising success in a mouse model for treating the metabolic disorder phenylketonuria with phenylalanine ammonia lyase (PAL) from Rhodosporidium toruloides and Anabaena variabilis. Both molecules, however, required further optimization in order to overcome problems with protease susceptibility, thermal stability, and aggregation. Previously, we optimized PAL from R. toruloides, and in this case we reduced aggregation of the A. variabilis PAL by mutating two surface cysteine residues (C503 and C565) to serines. Additionally, we report the structural and biochemical characterization of the A. variabilis PAL C503S/C565S double mutant and carefully compare this molecule with the R. toruloides engineered PAL molecule. Unlike previously published PAL structures, significant electron density is observed for the two active-site loops in the A. variabilis C503S/C565S double mutant, yielding a complete view of the active site. Docking studies and N-hydroxysuccinimide-biotin binding studies support a proposed mechanism in which the amino group of the phenylalanine substrate is attacked directly by the 4-methylidene-imidazole-5-one prosthetic group. We propose a helix-to-loop conformational switch in the helices flanking the inner active-site loop that regulates accessibility of the active site. Differences in loop stability among PAL homologs may explain the observed variation in enzyme efficiency, despite the highly conserved structure of the active site. A. variabilis C503S/C565S PAL is shown to be both more thermally stable and more resistant to proteolytic cleavage than R. toruloides PAL. Additional increases in thermal stability and protease resistance upon ligand binding may be due to enhanced interactions among the residues of the active site, possibly locking the active-site structure in place and stabilizing the tetramer. Examination of the A. variabilis C503S/C565S PAL structure, combined with analysis of its physical properties, provides a structural basis for further engineering of residues that could result in a better therapeutic molecule.

  1. Accelerator waste - A new challenge for radio-analytics

    SciTech Connect (OSTI)

    Schumann, Dorothea; Neuhausen, Joer; Wohlmuther, Michaelg [Paul Scherrer Institute 5232, Villigen PSI (Switzerland)

    2007-07-01T23:59:59.000Z

    The Paul Scherrer Institute (PSI) at Villigen (Switzerland) operates the most powerful accelerator facility in Europe. Due to the increasing quantities of accelerator waste with almost unknown radionuclide inventory, the development of new radio-analytical methods is an urgent task. Besides the characterization by {gamma}-measurements and dose rate determinations, also the investigation of long-lived radionuclides, being probably essential for a final disposal, is required from Swiss authorities. Chemical separation is necessary for the determination of the majority of these isotopes. As a representative example for such studies, the analytics of a beam dump assembly is introduced. Samples were taken from the target E beam dump station from the 590 MeV proton accelerator facility. The content of several radionuclides with half-lives between 2 and 10{sup 7} years was determined by {gamma}-spectrometry and, after chemical separation, by Liquid Scintillation Counting (LSC) as well as Accelerator Mass Spectrometry (AMS). The results are compared with theoretical predictions. Long-term object of these studies is the elaboration of nuclide vectors, which allow the estimation of nuclide inventories by simple calculations. (authors)

  2. Predicting Student Success using Analytics in Course Learning Management Systems

    SciTech Connect (OSTI)

    Olama, Mohammed M [ORNL] [ORNL; Thakur, Gautam [ORNL] [ORNL; McNair, Wade [ORNL] [ORNL; Sukumar, Sreenivas R [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Educational data analytics is an emerging discipline, concerned with developing methods for exploring the unique types of data that come from the educational context. For example, predicting college student performance is crucial for both the student and educational institutions. It can support timely intervention to prevent students from failing a course, increasing efficacy of advising functions, and improving course completion rate. In this paper, we present the efforts carried out at Oak Ridge National Laboratory (ORNL) toward conducting predictive analytics to academic data collected from 2009 through 2013 and available in one of the most commonly used learning management systems, called Moodle. First, we have identified the data features useful for predicting student outcomes such as students scores in homework assignments, quizzes, exams, in addition to their activities in discussion forums and their total GPA at the same term they enrolled in the course. Then, Logistic Regression and Neural Network predictive models are used to identify students as early as possible that are in danger of failing the course they are currently enrolled in. These models compute the likelihood of any given student failing (or passing) the current course. Numerical results are presented to evaluate and compare the performance of the developed models and their predictive accuracy.

  3. Chemical microreactor and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan

    2005-11-01T23:59:59.000Z

    A chemical microreactor suitable for generation of hydrogen fuel from liquid sources such as ammonia, methanol, and butane through steam reforming processes when mixed with an appropriate amount of water contains capillary microchannels with integrated resistive heaters to facilitate the occurrence of catalytic steam reforming reactions. One such microreactor employs a packed catalyst capillary microchannel and at least one porous membrane. Another employs a porous membrane with a large surface area or a porous membrane support structure containing a plurality of porous membranes having a large surface area in the aggregate, i.e., greater than about 1 m.sup.2 /cm.sup.3. The packed catalyst capillary microchannels, porous membranes and porous membrane support structures may be formed by a variety of methods.

  4. Model and Analytic Processes for Export License Assessments

    SciTech Connect (OSTI)

    Thompson, Sandra E.; Whitney, Paul D.; Weimar, Mark R.; Wood, Thomas W.; Daly, Don S.; Brothers, Alan J.; Sanfilippo, Antonio P.; Cook, Diane; Holder, Larry

    2011-09-29T23:59:59.000Z

    This paper represents the Department of Energy Office of Nonproliferation Research and Development (NA-22) Simulations, Algorithms and Modeling (SAM) Program's first effort to identify and frame analytical methods and tools to aid export control professionals in effectively predicting proliferation intent; a complex, multi-step and multi-agency process. The report focuses on analytical modeling methodologies that alone, or combined, may improve the proliferation export control license approval process. It is a follow-up to an earlier paper describing information sources and environments related to international nuclear technology transfer. This report describes the decision criteria used to evaluate modeling techniques and tools to determine which approaches will be investigated during the final 2 years of the project. The report also details the motivation for why new modeling techniques and tools are needed. The analytical modeling methodologies will enable analysts to evaluate the information environment for relevance to detecting proliferation intent, with specific focus on assessing risks associated with transferring dual-use technologies. Dual-use technologies can be used in both weapons and commercial enterprises. A decision-framework was developed to evaluate which of the different analytical modeling methodologies would be most appropriate conditional on the uniqueness of the approach, data availability, laboratory capabilities, relevance to NA-22 and Office of Arms Control and Nonproliferation (NA-24) research needs and the impact if successful. Modeling methodologies were divided into whether they could help micro-level assessments (e.g., help improve individual license assessments) or macro-level assessment. Macro-level assessment focuses on suppliers, technology, consumers, economies, and proliferation context. Macro-level assessment technologies scored higher in the area of uniqueness because less work has been done at the macro level. An approach to developing testable hypotheses for the macro-level assessment methodologies is provided. The outcome of this works suggests that we should develop a Bayes Net for micro-level analysis and continue to focus on Bayes Net, System Dynamics and Economic Input/Output models for assessing macro-level problems. Simultaneously, we need to develop metrics for assessing intent in export control, including the risks and consequences associated with all aspects of export control.

  5. Neutron Noise Calculations in Hexagonal Geometry and Comparison with Analytical Solutions

    E-Print Network [OSTI]

    Demazière, Christophe

    for addressing the noise calculations of light water reactors ~LWRs! in Cartesian geometries.3 This tool instability, etc. Extension of the noise calculation method to other reactor types such as Russian VVERsNeutron Noise Calculations in Hexagonal Geometry and Comparison with Analytical Solutions Hoai Nam

  6. Analytical solutions to a hillslope-storage kinematic wave equation for subsurface flow

    E-Print Network [OSTI]

    Loon, E. Emiel van

    Analytical solutions to a hillslope-storage kinematic wave equation for subsurface flow Peter Troch­617] to describe the bedrock slope, we derive more general solutions to the hillslope-storage kinematic wave reserved. Keywords: Hillslope hydrology; Subsurface flow; Kinematic wave approximation; Method

  7. JOURNAL DE PHYSIQUE CoZZoque C8, suppZ6ment aa n o 8, Tome 42, amAt 2980, page C8-32 NMR STUD1ES OF CONCENTRATED LITHIUM-AMMONIA SOLUTIONS

    E-Print Network [OSTI]

    Boyer, Edmond

    OF CONCENTRATED LITHIUM-AMMONIA SOLUTIONS Y. Nakamura, M. Niibe and M . Shimoji Deparhent o f Chemistry, FaeuZty o in liquid ammonia show very interesting properties with varying metal concentration; from electrolytic results of the Knight shift, KLi, and the spin-lattice relaxation tine, T1, of 7 ~ i in the lithium

  8. An Interactive Visual Analytics Framework for Multi-Field Data...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactive Visual Analytics Framework for Multi-Field Data in a Geo-Spatial Context. An Interactive Visual Analytics Framework for Multi-Field Data in a Geo-Spatial Context....

  9. analytical tool supporting: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an Analytical Tool for Track Component Response (I-TRACK) Thiago B. do Carmo, J, NV 7 October 2013 12;Slide 2Simplified Analytical Tool and Parametric Analysis Outline ...

  10. Analytical modeling of contaminant transport and horizontal well hydraulics 

    E-Print Network [OSTI]

    Park, Eungyu

    2004-09-30T23:59:59.000Z

    This dissertation is composed of three parts of major contributions. In Chapter II, we discuss analytical study of contaminant transport from a finite source in a finite-thickness aquifer. This chapter provides analytical solutions of contaminant...

  11. Recent results on analytical plasma turbulence theory: Realizability, intermittency, submarginal

    E-Print Network [OSTI]

    Recent results on analytical plasma turbulence theory: Realizability, intermittency, submarginal Phys. Control. Fusion 1. Introduction Two fundamental challenges in the systematic analytical theory as f . = # # f # for n = 1, where . = denotes definition and #. . .# denotes an ensemble average) #12

  12. Immunoassay, biosensors and other nonchromatographic methods

    E-Print Network [OSTI]

    Hammock, Bruce D.

    . Gee and Bruce D. Hammock pp. 623­679 in Handbook of Residue Analytical Methods for Agrochemicals (ISBN for Agrochemicals. C 2003 John Wiley & Sons Ltd. #12;624 Recent advances in analytical technology, immunoassay the potential for ELISA for agrochemicals and environmental pollutants. Since then, the use of immunoassay

  13. An analytically solvable, axially non-homogeneous reactor model

    E-Print Network [OSTI]

    Pázsit, Imre

    and Glasstone,1970) and analytically in 1-D noise problems (Kosa ly et al., 1977). The general conclusion

  14. Development of analytical cell support for vitrification at the West Valley Demonstration Project. Topical report

    SciTech Connect (OSTI)

    Barber, F.H.; Borek, T.T.; Christopher, J.Z. [and others

    1997-12-01T23:59:59.000Z

    Analytical and Process Chemistry (A&PC) support is essential to the high-level waste vitrification campaign at the West Valley Demonstration Project (WVDP). A&PC characterizes the waste, providing information necessary to formulate the recipe for the target radioactive glass product. High-level waste (HLW) samples are prepared and analyzed in the analytical cells (ACs) and Sample Storage Cell (SSC) on the third floor of the main plant. The high levels of radioactivity in the samples require handling them in the shielded cells with remote manipulators. The analytical hot cells and third floor laboratories were refurbished to ensure optimal uninterrupted operation during the vitrification campaign. New and modified instrumentation, tools, sample preparation and analysis techniques, and equipment and training were required for A&PC to support vitrification. Analytical Cell Mockup Units (ACMUs) were designed to facilitate method development, scientist and technician training, and planning for analytical process flow. The ACMUs were fabricated and installed to simulate the analytical cell environment and dimensions. New techniques, equipment, and tools could be evaluated m in the ACMUs without the consequences of generating or handling radioactive waste. Tools were fabricated, handling and disposal of wastes was addressed, and spatial arrangements for equipment were refined. As a result of the work at the ACMUs the remote preparation and analysis methods and the equipment and tools were ready for installation into the ACs and SSC m in July 1995. Before use m in the hot cells, all remote methods had been validated and four to eight technicians were trained on each. Fine tuning of the procedures has been ongoing at the ACs based on input from A&PC technicians. Working at the ACs presents greater challenges than had development at the ACMUs. The ACMU work and further refinements m in the ACs have resulted m in a reduction m in analysis turnaround time (TAT).

  15. Method and apparatus for simultaneous spectroelectrochemical analysis

    DOE Patents [OSTI]

    Chatterjee, Sayandev; Bryan, Samuel A; Schroll, Cynthia A; Heineman, William R

    2013-11-19T23:59:59.000Z

    An apparatus and method of simultaneous spectroelectrochemical analysis is disclosed. A transparent surface is provided. An analyte solution on the transparent surface is contacted with a working electrode and at least one other electrode. Light from a light source is focused on either a surface of the working electrode or the analyte solution. The light reflected from either the surface of the working electrode or the analyte solution is detected. The potential of the working electrode is adjusted, and spectroscopic changes of the analyte solution that occur with changes in thermodynamic potentials are monitored.

  16. EQUIVALENCE RELATIONS FOR TWO VARIABLE REAL ANALYTIC FUNCTION GERMS

    E-Print Network [OSTI]

    EQUIVALENCE RELATIONS FOR TWO VARIABLE REAL ANALYTIC FUNCTION GERMS SATOSHI KOIKE & ADAM PARUSI´NSKI Abstract. For two variable real analytic function germs we compare the blow- analytic equivalence in the sense of Kuo to the other natural equivalence relations. Our main theorem states that C1 equivalent

  17. Analytic models of plausible gravitational lens potentials

    E-Print Network [OSTI]

    Edward A. Baltz; Phil Marshall; Masamune Oguri

    2008-12-11T23:59:59.000Z

    Gravitational lenses on galaxy scales are plausibly modelled as having ellipsoidal symmetry and a universal dark matter density profile, with a Sersic profile to describe the distribution of baryonic matter. Predicting all lensing effects requires knowledge of the total lens potential: in this work we give analytic forms for that of the above hybrid model. Emphasising that complex lens potentials can be constructed from simpler components in linear combination, we provide a recipe for attaining elliptical symmetry in either projected mass or lens potential. We also provide analytic formulae for the lens potentials of Sersic profiles for integer and half-integer index. We then present formulae describing the gravitational lensing effects due to smoothly-truncated universal density profiles in cold dark matter model. For our isolated haloes the density profile falls off as radius to the minus fifth or seventh power beyond the tidal radius, functional forms that allow all orders of lens potential derivatives to be calculated analytically, while ensuring a non-divergent total mass. We show how the observables predicted by this profile differ from that of the original infinite-mass NFW profile. Expressions for the gravitational flexion are highlighted. We show how decreasing the tidal radius allows stripped haloes to be modelled, providing a framework for a fuller investigation of dark matter substructure in galaxies and clusters. Finally we remark on the need for finite mass halo profiles when doing cosmological ray-tracing simulations, and the need for readily-calculable higher order derivatives of the lens potential when studying catastrophes in strong lenses.

  18. Analytic models of plausible gravitational lens potentials

    SciTech Connect (OSTI)

    Baltz, Edward A.; Marshall, Phil; Oguri, Masamune, E-mail: eabaltz@slac.stanford.edu, E-mail: pjm@physics.ucsb.edu, E-mail: oguri@slac.stanford.edu [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, PO Box 20450, MS29, Stanford, CA 94309 (United States)] [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, PO Box 20450, MS29, Stanford, CA 94309 (United States)

    2009-01-15T23:59:59.000Z

    Gravitational lenses on galaxy scales are plausibly modelled as having ellipsoidal symmetry and a universal dark matter density profile, with a Sersic profile to describe the distribution of baryonic matter. Predicting all lensing effects requires knowledge of the total lens potential: in this work we give analytic forms for that of the above hybrid model. Emphasising that complex lens potentials can be constructed from simpler components in linear combination, we provide a recipe for attaining elliptical symmetry in either projected mass or lens potential. We also provide analytic formulae for the lens potentials of Sersic profiles for integer and half-integer index. We then present formulae describing the gravitational lensing effects due to smoothly-truncated universal density profiles in cold dark matter model. For our isolated haloes the density profile falls off as radius to the minus fifth or seventh power beyond the tidal radius, functional forms that allow all orders of lens potential derivatives to be calculated analytically, while ensuring a non-divergent total mass. We show how the observables predicted by this profile differ from that of the original infinite-mass NFW profile. Expressions for the gravitational flexion are highlighted. We show how decreasing the tidal radius allows stripped haloes to be modelled, providing a framework for a fuller investigation of dark matter substructure in galaxies and clusters. Finally we remark on the need for finite mass halo profiles when doing cosmological ray-tracing simulations, and the need for readily-calculable higher order derivatives of the lens potential when studying catastrophes in strong lenses.

  19. Analytic Models of Plausible Gravitational Lens Potentials

    SciTech Connect (OSTI)

    Baltz, Edward A.; Marshall, Phil; Oguri, Masamune

    2007-05-04T23:59:59.000Z

    Gravitational lenses on galaxy scales are plausibly modeled as having ellipsoidal symmetry and a universal dark matter density profile, with a Sersic profile to describe the distribution of baryonic matter. Predicting all lensing effects requires knowledge of the total lens potential: in this work we give analytic forms for that of the above hybrid model. Emphasizing that complex lens potentials can be constructed from simpler components in linear combination, we provide a recipe for attaining elliptical symmetry in either projected mass or lens potential.We also provide analytic formulae for the lens potentials of Sersic profiles for integer and half-integer index. We then present formulae describing the gravitational lensing effects due to smoothly-truncated universal density profiles in cold dark matter model. For our isolated haloes the density profile falls off as radius to the minus fifth or seventh power beyond the tidal radius, functional forms that allow all orders of lens potential derivatives to be calculated analytically, while ensuring a non-divergent total mass. We show how the observables predicted by this profile differ from that of the original infinite-mass NFW profile. Expressions for the gravitational flexion are highlighted. We show how decreasing the tidal radius allows stripped haloes to be modeled, providing a framework for a fuller investigation of dark matter substructure in galaxies and clusters. Finally we remark on the need for finite mass halo profiles when doing cosmological ray-tracing simulations, and the need for readily-calculable higher order derivatives of the lens potential when studying catastrophes in strong lenses.

  20. Photovoltaic Degradation Rates -- An Analytical Review

    SciTech Connect (OSTI)

    Jordan, D. C.; Kurtz, S. R.

    2012-06-01T23:59:59.000Z

    As photovoltaic penetration of the power grid increases, accurate predictions of return on investment require accurate prediction of decreased power output over time. Degradation rates must be known in order to predict power delivery. This article reviews degradation rates of flat-plate terrestrial modules and systems reported in published literature from field testing throughout the last 40 years. Nearly 2000 degradation rates, measured on individual modules or entire systems, have been assembled from the literature, showing a median value of 0.5%/year. The review consists of three parts: a brief historical outline, an analytical summary of degradation rates, and a detailed bibliography partitioned by technology.