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Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Method for releasing hydrogen from ammonia borane  

DOE Patents [OSTI]

A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

2013-02-19T23:59:59.000Z

2

ANALYTICAL METHODS in CHEMICAL ECOLOGY  

E-Print Network [OSTI]

ANALYTICAL METHODS in CHEMICAL ECOLOGY a post graduate course (doktorandkurs) when: February 10 ­ 28, 2014 where: Chemical Ecology, Plant Protection Biology, Swedish University of Agriculture (SLU to modern analytical methods used in Chemical Ecological and Ecotoxicological research, such as: methods

3

Hydrogen Fuel Quality - Focus: Analytical Methods Development...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results Hydrogen Fuel Quality - Focus: Analytical Methods Development & Hydrogen Fuel Quality Results...

4

Analytical methods under emergency conditions  

SciTech Connect (OSTI)

This lecture discusses methods for the radiochemical determination of internal contamination of the body under emergency conditions, here defined as a situation in which results on internal radioactive contamination are needed quickly. The purpose of speed is to determine the necessity for medical treatment to increase the natural elimination rate. Analytical methods discussed include whole-body counting, organ counting, wound monitoring, and excreta analysis. 12 references. (ACR)

Sedlet, J.

1983-01-01T23:59:59.000Z

5

E-Print Network 3.0 - ammonia release method Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lovegrove Summary: -dissociation-based solar thermal storage method. AMMONIA-BASED SOLAR ENERGY STORAGE Fig. 1: An overview of energy storage... chloride or calcium chloride -...

6

Method of identity analyte-binding peptides  

DOE Patents [OSTI]

A method for affinity chromatography or adsorption of a designated analyte utilizes a paralog as the affinity partner. The immobilized paralog can be used in purification or analysis of the analyte; the paralog can also be used as a substitute for antibody in an immunoassay. The paralog is identified by screening candidate peptide sequences of 4--20 amino acids for specific affinity to the analyte. 5 figs.

Kauvar, L.M.

1990-10-16T23:59:59.000Z

7

Nuclear analytical methods: Past, present and future  

SciTech Connect (OSTI)

The development of nuclear analytical methods as an analytical tool began in 1936 with the publication of the first paper on neutron activation analysis (NAA). This year, 1996, marks the 60th anniversary of that event. This paper attempts to look back at the nuclear analytical methods of the past, to look around and to see where the technology is right now, and finally, to look ahead to try and see where nuclear methods as an analytical technique (or as a group of analytical techniques) will be going in the future. The general areas which the author focuses on are: neutron activation analysis; prompt gamma neutron activation analysis (PGNAA); photon activation analysis (PAA); charged-particle activation analysis (CPAA).

Becker, D.A. [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

1996-12-31T23:59:59.000Z

8

Neutron noise calculations using the Analytical Nodal Method and comparisons with analytical solutions  

E-Print Network [OSTI]

Neutron noise calculations using the Analytical Nodal Method and comparisons with analytical Available online 28 December 2010 Keywords: Neutron noise ANM Power reactor approximation 2-Group theory Diffusion theory a b s t r a c t In this study, the neutron noise, i.e. the stationary fluctuations

Demazière, Christophe

9

Improving Electrochemical Methods of Producing Hydrogen in Alkaline Media via Ammonia and Urea Electrolysis.  

E-Print Network [OSTI]

?? Theoretically, ammonia electrolysis consumes 95% less energy than its major competitor water electrolysis and offers an economical, environmental, and efficient means for reducing nitrate (more)

Boggs, Bryan Kenneth

2010-01-01T23:59:59.000Z

10

System and method for determining an ammonia generation rate in a three-way catalyst  

SciTech Connect (OSTI)

A system according to the principles of the present disclosure includes a rate determination module, a storage level determination module, and an air/fuel ratio control module. The rate determination module determines an ammonia generation rate in a three-way catalyst based on a reaction efficiency and a reactant level. The storage level determination module determines an ammonia storage level in a selective catalytic reduction (SCR) catalyst positioned downstream from the three-way catalyst based on the ammonia generation rate. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the ammonia storage level.

Sun, Min; Perry, Kevin L; Kim, Chang H

2014-12-30T23:59:59.000Z

11

Quality by Design Compliant Analytical Method Validation  

Science Journals Connector (OSTI)

To lighten the workload, impurities and degradation products could be ranked following a risk analysis such as failure mode and effects analysis (FMEA). ... These sources could be valuably selected from a risk analysis such as FMEA performed during the method development phase. ...

E. Rozet; E. Ziemons; R.D. Marini; B. Boulanger; Ph. Hubert

2011-11-22T23:59:59.000Z

12

Analytical techniques for instrument design -- Matrix methods  

SciTech Connect (OSTI)

The authors take the traditional Cooper-Nathans approach, as has been applied for many years for steady-state triple-axis spectrometers, and consider its generalization to other inelastic scattering spectrometers. This involves a number of simple manipulations of exponentials of quadratic forms. In particular, they discuss a toolbox of matrix manipulations that can be performed on the 6-dimensional Cooper-Nathans matrix. They show how these tools can be combined to solve a number of important problems, within the narrow-band limit and the gaussian approximation. They will argue that a generalized program that can handle multiple different spectrometers could (and should) be written in parallel to the Monte-Carlo packages that are becoming available. They also discuss the complementarity between detailed Monte-Carlo calculations and the approach presented here. In particular, Monte-Carlo methods traditionally simulate the real experiment as performed in practice, given a model scattering law, while the Cooper-Nathans method asks the inverse question: given that a neutron turns up in a particular spectrometer configuration (e.g. angle and time of flight), what is the probability distribution of possible scattering events at the sample? The Monte-Carlo approach could be applied in the same spirit to this question.

Robinson, R.A.

1997-12-31T23:59:59.000Z

13

Simple Analytical and Graphical Tools for Carrier Based PWM Methods  

E-Print Network [OSTI]

energy conversion. Shown in Figure 1, the classical VSI generates a low frequency output voltage with conSimple Analytical and Graphical Tools for Carrier Based PWM Methods Ahmet M. Hava y Russel J tools for the study, performance evaluation, and design of the modern carrier based PWM methods which

Hava, Ahmet

14

Validation of Analytic Methods for Biomarkers Used in Drug Development  

Science Journals Connector (OSTI)

...quasi-quantitative Regulatory requirement GLP...requires a systematic review of the analyte stability...method validation plan, a biomarker assay...intends to pave a regulatory pathway for biomarkers...validation as well as regulatory pathways for efficient...Journal Article Review | U01 GM063340-07...

Cindy H. Chau; Olivier Rixe; Howard McLeod; and William D. Figg

2008-10-01T23:59:59.000Z

15

SASSI Analytical Methods Compared with SHAKE Free-Field Results  

Broader source: Energy.gov (indexed) [DOE]

Analytical Methods Analytical Methods Compared with SHAKE Results Structural Mechanics - SRS October 4, 2011 1 Objective This study presents a methodology for validating SASSI for use with a particular site profile, foundation size, and embedment depth. Two case studies are presented: 1) a deep soil site at the Savannah River Site (SRS) 2) a shallow stiff soil site at the Hanford Waste Treatment Plant (WTP). Embedded box in SASSI is evaluated with Direct Method and (Modified) Subtraction method. 2 * Ground motion at the surface is deconvolved in SHAKE to the bottom of the soil column and then brought back to the surface in a SASSI embedded box model. * SASSI response spectra at the ground and foundation levels are

16

E-Print Network 3.0 - analytical methods flambagem Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

continuous calibration verification for analytical instruments use of method blanks... procedures, and NOAA's Analytical Quality Assurance Project Plan (QAPP). Samples were sent...

17

Estimating Fuel Cycle Externalities: Analytical Methods and Issues, Report 2  

SciTech Connect (OSTI)

The activities that produce electric power typically range from extracting and transporting a fuel, to its conversion into electric power, and finally to the disposition of residual by-products. This chain of activities is called a fuel cycle. A fuel cycle has emissions and other effects that result in unintended consequences. When these consequences affect third parties (i.e., those other than the producers and consumers of the fuel-cycle activity) in a way that is not reflected in the price of electricity, they are termed ''hidden'' social costs or externalities. They are the economic value of environmental, health and any other impacts, that the price of electricity does not reflect. How do you estimate the externalities of fuel cycles? Our previous report describes a methodological framework for doing so--called the damage function approach. This approach consists of five steps: (1) characterize the most important fuel cycle activities and their discharges, where importance is based on the expected magnitude of their externalities, (2) estimate the changes in pollutant concentrations or other effects of those activities, by modeling the dispersion and transformation of each pollutant, (3) calculate the impacts on ecosystems, human health, and any other resources of value (such as man-made structures), (4) translate the estimates of impacts into economic terms to estimate damages and benefits, and (5) assess the extent to which these damages and benefits are externalities, not reflected in the price of electricity. Each step requires a different set of equations, models and analysis. Analysts generally believe this to be the best approach for estimating externalities, but it has hardly been used! The reason is that it requires considerable analysis and calculation, and to this point in time, the necessary equations and models have not been assembled. Equally important, the process of identifying and estimating externalities leads to a number of complex issues that also have not been fully addressed. This document contains two types of papers that seek to fill part of this void. Some of the papers describe analytical methods that can be applied to one of the five steps of the damage function approach. The other papers discuss some of the complex issues that arise in trying to estimate externalities. This report, the second in a series of eight reports, is part of a joint study by the U.S. Department of Energy (DOE) and the Commission of the European Communities (EC)* on the externalities of fuel cycles. Most of the papers in this report were originally written as working papers during the initial phases of this study. The papers provide descriptions of the (non-radiological) atmospheric dispersion modeling that the study uses; reviews much of the relevant literature on ecological and health effects, and on the economic valuation of those impacts; contains several papers on some of the more complex and contentious issues in estimating externalities; and describes a method for depicting the quality of scientific information that a study uses. The analytical methods and issues that this report discusses generally pertain to more than one of the fuel cycles, though not necessarily to all of them. The report is divided into six parts, each one focusing on a different subject area.

Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

1994-07-01T23:59:59.000Z

18

Advancing Analytical Methods for Characterization of Anionic Carbohydrate Biopolymers  

E-Print Network [OSTI]

here a heparin disaccharide), IPR and C18 stationary phase;of a C18 column with the IPR which separates analytes via anseparation of tinzaparin where IPR used in A) TrBA, B) DBA,

Langeslay, Derek Joseph

2013-01-01T23:59:59.000Z

19

E-Print Network 3.0 - analytical chemistry methods Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: analytical chemistry methods Page: << < 1 2 3 4 5 > >> 1 Department of Chemistry Three Year Projection...

20

Hanford environmental analytical methods: Methods as of March 1990. Volume 3, Appendix A2-I  

SciTech Connect (OSTI)

This paper from the analytical laboratories at Hanford describes the method used to measure pH of single-shell tank core samples. Sludge or solid samples are mixed with deionized water. The pH electrode used combines both a sensor and reference electrode in one unit. The meter amplifies the input signal from the electrode and displays the pH visually.

Goheen, S.C.; McCulloch, M.; Daniel, J.L.

1993-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

A comparison of the point kinetics equations with the QUANDRY analytic nodal diffusion method  

E-Print Network [OSTI]

The point kinetics equations were incorporated into QUANDRY, a nuclear reactor analysis computer program which uses the analytic nodal method to solve the neutron diffusion equation. Both the point kinetics equations, solved using the IMSL MATH...

Velasquez, Arthur

2012-06-07T23:59:59.000Z

22

An analytic electromagnetic calculation method for performance evolution of doubly fed induction generators for wind turbines  

Science Journals Connector (OSTI)

An analytic electromagnetic calculation method for doubly fed induction generator (DFIG) in wind turbine system was presented. ... steady state equivalent circuit and basic equations of DFIG, the modeling for ele...

Wen-juan Zhang ???; Shou-dao Huang ???; Jian Gao ??

2013-10-01T23:59:59.000Z

23

Analytical Method for Yrast Line States in Interacting Bose-Einstein Condensates  

Science Journals Connector (OSTI)

We propose a method to investigate the energy eigenvalue problem and corresponding yrast line for harmonically trapped interacting N-boson systems. This method is particularly simple and effective to obtain the explicit analytical expressions of low-L energy eigenstates with L denoting systems' total angular momentum but with an arbitrarily large N. We have derived the explicit analytical results for L=0,1,,9 and discussed the yrast line for these low- L energy eigenstates.

Ying Wu; Xiaoxue Yang; Yi Xiao

2001-03-12T23:59:59.000Z

24

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect (OSTI)

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

25

Analytical method of spectra calculations in the Bargmann representation  

E-Print Network [OSTI]

We formulate a universal method for solving an arbitrary quantum system which, in the Bargmann representation, is described by a system of linear equations with one independent variable, such as one- and multi-photon Rabi models, or $N$ level systems interacting with a single mode of the electromagnetic field and their various generalizations. We explain three types of conditions that determine the spectrum and show their usage for two deformations of the Rabi model. We prove that the spectra of both models are just zeros of transcendental functions, which in one case are given explicitly in terms of confluent Heun functions.

Andrzej J. Maciejewski; Maria Przybylska; Tomasz Stachowiak

2014-10-31T23:59:59.000Z

26

Waste Tank Organic Safety Program: Analytical methods development. Progress report, FY 1994  

SciTech Connect (OSTI)

The objectives of this task are to develop and document extraction and analysis methods for organics in waste tanks, and to extend these methods to the analysis of actual core samples to support the Waste Tank organic Safety Program. This report documents progress at Pacific Northwest Laboratory (a) during FY 1994 on methods development, the analysis of waste from Tank 241-C-103 (Tank C-103) and T-111, and the transfer of documented, developed analytical methods to personnel in the Analytical Chemistry Laboratory (ACL) and 222-S laboratory. This report is intended as an annual report, not a completed work.

Campbell, J.A.; Clauss, S.A.; Grant, K.E. [and others

1994-09-01T23:59:59.000Z

27

Analytical Chemistry Laboratory (ACL) procedure compendium. Volume 4, Organic methods  

SciTech Connect (OSTI)

This interim notice covers the following: extractable organic halides in solids, total organic halides, analysis by gas chromatography/Fourier transform-infrared spectroscopy, hexadecane extracts for volatile organic compounds, GC/MS analysis of VOCs, GC/MS analysis of methanol extracts of cryogenic vapor samples, screening of semivolatile organic extracts, GPC cleanup for semivolatiles, sample preparation for GC/MS for semi-VOCs, analysis for pesticides/PCBs by GC with electron capture detection, sample preparation for pesticides/PCBs in water and soil sediment, report preparation, Florisil column cleanup for pesticide/PCBs, silica gel and acid-base partition cleanup of samples for semi-VOCs, concentrate acid wash cleanup, carbon determination in solids using Coulometrics` CO{sub 2} coulometer, determination of total carbon/total organic carbon/total inorganic carbon in radioactive liquids/soils/sludges by hot persulfate method, analysis of solids for carbonates using Coulometrics` Model 5011 coulometer, and soxhlet extraction.

Not Available

1993-08-01T23:59:59.000Z

28

External Quality Assurance Services (EQAS) Ethanol/Ammonia Program  

E-Print Network [OSTI]

External Quality Assurance Services (EQAS) Ethanol/Ammonia Program BC35 12 x 3 mL 2 Analytes QC35 12 x 3 mL Specimen Only ENGLISH INTENDED USE Bio-Rad EQAS Ethanol/Ammonia Program is designed

Rodriguez, Carlos

29

The use of a semi-analytical method for matching aquifer influence functions  

E-Print Network [OSTI]

of water-drive gas reservoirs. The method is suitable for hand calculation. Fetkovich ", in 1971, presented an approach that utilizes the "stabilized", or pseudosteady-state aquifer productivity index and an aquifer material balance to represent...THE USE OF A SEMI-ANALYTICAL METHOD FOR MATCHING AQUIFER INFLUENCE FUNCTIONS A Thesis by SHENG DING Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

Ding, Sheng

1990-01-01T23:59:59.000Z

30

Selection of analytical methods for mixed waste analysis at the Hanford Site  

SciTech Connect (OSTI)

This document describes the process that the US Department of Energy (DOE), Richland Operations Office (RL) and contractor laboratories use to select appropriate or develop new or modified analytical methods. These methods are needed to provide reliable mixed waste characterization data that meet project-specific quality assurance (QA) requirements while also meeting health and safety standards for handling radioactive materials. This process will provide the technical basis for DOE`s analysis of mixed waste and support requests for regulatory approval of these new methods when they are used to satisfy the regulatory requirements of the Hanford Federal Facility Agreement and Consent Order (Tri-party Agreement) (Ecology et al. 1992).

Morant, P.M.

1994-09-01T23:59:59.000Z

31

SRC-I demonstration plant analytical laboratory methods manual. Final technical report  

SciTech Connect (OSTI)

This manual is a compilation of analytical procedures required for operation of a Solvent-Refined Coal (SRC-I) demonstration or commercial plant. Each method reproduced in full includes a detailed procedure, a list of equipment and reagents, safety precautions, and, where possible, a precision statement. Procedures for the laboratory's environmental and industrial hygiene modules are not included. Required American Society for Testing and Materials (ASTM) methods are cited, and ICRC's suggested modifications to these methods for handling coal-derived products are provided.

Klusaritz, M.L.; Tewari, K.C.; Tiedge, W.F.; Skinner, R.W.; Znaimer, S.

1983-03-01T23:59:59.000Z

32

Analytic solution of nonlinear fractional Burgers-type equation by invariant subspace method  

E-Print Network [OSTI]

In this paper we study the analytic solutions of Burgers-type nonlinear fractional equations by means of the Invariant Subspace Method. We first study a class of nonlinear equations directly related to the time-fractional Burgers equation. Some generalizations linked to the forced time-fractional Burgers equations and variable-coefficient diffusion are also considered. Finally we study a Burgers-type equation involving both space and time-fractional derivatives.

P. Artale Harris; R. Garra

2013-06-08T23:59:59.000Z

33

The validity of analytical methods for predicting self burial of offshore pipelines  

E-Print Network [OSTI]

penetration of ~. D H drostatic ressure test hase, - Prior to placing a pipeline into service, it is necessary to perform a pressure test to insure that the structural integrity of the pipe was maintained during construction and to check for leaks...THE VALIDITY OF ANALYTICAL METHODS FOR PREDICTING SELF BURIAL OF OFFSHORE PIPELINES A Thesis by THOMAS KENWOOD HAMILTON Submitted to the Graduate College of Texas AEM University in partial fulfillment of the requirement for the degree...

Hamilton, Thomas Kenwood

2012-06-07T23:59:59.000Z

34

Thrust measurement method verification and analytical studies on a liquid-fueled pulse detonation engine  

Science Journals Connector (OSTI)

Abstract In order to test the feasibility of a new thrust stand system based on impulse thrust measurement method, a liquid-fueled pulse detonation engine (PDE) is designed and built. Thrust performance of the engine is obtained by direct thrust measurement with a force transducer and indirect thrust measurement with an eddy current displacement sensor (ECDS). These two sets of thrust data are compared with each other to verify the accuracy of the thrust performance. Then thrust data measured by the new thrust stand system are compared with the verified thrust data to test its feasibility. The results indicate that thrust data from the force transducer and ECDS system are consistent with each other within the range of measurement error. Though the thrust data from the impulse thrust measurement system is a litter lower than that from the force transducer due to the axial momentum losses of the detonation jet, the impulse thrust measurement method is valid when applied to measure the averaged thrust of PDE. Analytical models of PDE are also discussed in this paper. The analytical thrust performance is higher than the experimental data due to ignoring the losses during the deflagration to detonation transition process. Effect of equivalence ratio on the engine thrust performance is investigated by utilizing the modified analytical model. Thrust reaches maximum at the equivalence ratio of about 1.1.

Jie Lu; Longxi Zheng; Zhiwu Wang; Changxin Peng; Xinggu Chen

2014-01-01T23:59:59.000Z

35

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents [OSTI]

A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

Phillips, B.A.; Whitlow, E.P.

1998-09-22T23:59:59.000Z

36

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents [OSTI]

A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

1998-09-22T23:59:59.000Z

37

Ammonia synthesis gas purification  

SciTech Connect (OSTI)

This patent describes the purification of a reformed gas mixture following water gas shift conversion to produce a purified ammonia synthesis gas stream. The improved processing sequence consisting essentially of: (A) Selectively catalytically oxidizing the residual carbon monoxide content of the gas mixture to carbon dioxide so as to reduce the carbon monoxide content of the gas mixture to less than about 20 ppm, the selective catalytic oxidation being carried out with an excess of air, with the excess oxygen being catalytically reacted with a small amount of hydrogen so that the residual oxygen level is reduced to less than about 3 ppm; (B) removing the bulk of the carbon dioxide content of the gas mixture by liquid absorption; (C) Removing residual amounts of carbon monoxide, carbon dioxide and water by selective adsorption on the fixed beds of a thermal swing adsorption system, a dry, purified ammonia ammonia synthesis gas stream containing less than a total of 10 ppm of carbon monoxide and carbon dioxide being recovered from the thermal swing adsorption system; (D) Passing the resulting dry, purified ammonia synthesis gas stream having a low content of methane to an ammonia production operation without intermediate passage of the ammonia synthesis gas stream to a methanation unit or to a cryogenic unit for removal of carbon monoxide and carbon dioxide therefrom; whereby the efficiency of the overall purification operation and the effective utilization of hydrogen are enhanced.

Fuderer, A.

1986-02-25T23:59:59.000Z

38

Exploring Liquid Sequential Injection Chromatography To Teach Fundamentals of Separation Methods: A Very Fast Analytical Chemistry Experiment  

Science Journals Connector (OSTI)

Exploring Liquid Sequential Injection Chromatography To Teach Fundamentals of Separation Methods: A Very Fast Analytical Chemistry Experiment ... Design of experiments (DOE) was used to find the suitable condition for optimal separation in short chromatographic runs. ...

Jose? C. Penteado; Jorge Ce?sar Masini

2010-12-09T23:59:59.000Z

39

An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons  

E-Print Network [OSTI]

A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

Stohl, A.

40

Solar flux distribution on central receivers: A projection method from analytic function  

Science Journals Connector (OSTI)

Abstract This paper presents a methodology to project the flux distribution from the image plane into the panels of any central receiver in Solar Power Tower plants. Since analytic functions derived from the convolution approach are conveniently defined on the image plane, its oblique projection solves the distorted spot found in actual receivers. Because of its accuracy describing the flux distribution due to rectangular focusing heliostats, we make use of the analytic function on the image plane by Collado etal. (1986). Based on the projection method, we have developed a computer code successfully confronted against PSA measurements and SolTrace software, either for flat plate or multi-panel cylindrical receivers. The validated model overcomes the computation time limitation associated to Monte Carlo technique, with a similar accuracy and even higher level of resolution. For each heliostat in a field, the spillage is computed besides the rest of optical losses; parallel projection is used for shading and blocking. The resulting optical performance tool generates the flux map caused by a whole field of heliostats. A multi-aiming strategy is investigated on the basis of the radius of the reflected beams, estimated from error cone angles.

Alberto Snchez-Gonzlez; Domingo Santana

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

E-Print Network 3.0 - analytical methods ii Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Calculus with Analytic Geometry I 4 MAC x312 Calculus with Analytic Geometry II 4 PHY x048 General Physics... CHM 2211+L Organic Chemistry II 5 MAC 1105 College Algebra 3...

42

Advanced organic analysis and analytical methods development: FY 1995 progress report. Waste Tank Organic Safety Program  

SciTech Connect (OSTI)

This report describes the work performed during FY 1995 by Pacific Northwest Laboratory in developing and optimizing analysis techniques for identifying organics present in Hanford waste tanks. The main focus was to provide a means for rapidly obtaining the most useful information concerning the organics present in tank waste, with minimal sample handling and with minimal waste generation. One major focus has been to optimize analytical methods for organic speciation. Select methods, such as atmospheric pressure chemical ionization mass spectrometry and matrix-assisted laser desorption/ionization mass spectrometry, were developed to increase the speciation capabilities, while minimizing sample handling. A capillary electrophoresis method was developed to improve separation capabilities while minimizing additional waste generation. In addition, considerable emphasis has been placed on developing a rapid screening tool, based on Raman and infrared spectroscopy, for determining organic functional group content when complete organic speciation is not required. This capability would allow for a cost-effective means to screen the waste tanks to identify tanks that require more specialized and complete organic speciation to determine tank safety.

Wahl, K.L.; Campbell, J.A.; Clauss, S.A. [and others

1995-09-01T23:59:59.000Z

43

Golden Day Comparison of Methods to Retrieve ET (Kc?NDVI, Kc?analytical, MSSEBS, METRIC)  

Science Journals Connector (OSTI)

This works presents the results from the application of four different remote sensing?based evapotranspiration models to an agricultural area of Castilla?La Mancha Spain. The models that were analyzed are: (1) the Kc?NDVI approach (2) the Kc?analytical method (3) the Multi Scale Surface Energy Balance System MSSEBS and (4) the Mapping Evapotranspiration at High Resolution and with Internalized Calibration METRIC procedure. Models (1) and (2) provide daily maps of crop water requirements and do not require the use of a thermal image. Whereas models (3) and (4) are surface energy balance models that supply instantaneous and daily calculations of actual evapotranspiration and require a thermal image in addition to short wave images. A Landsat 5 image of the studied area for July 15 2003 was used to derive the various products together with weather and ground vegetation data. The comparison between models was performed in terms of crop coefficients and demonstrated the agreement between methods according to theory. Quantitative description of the differences between models for land uses of the area is provided. This research illustrates the potential of these approaches for routine and operational estimation of water demand and water consumption on a daily scale.

E. Rubio; J. Colin; G. DUrso; R. Trezza; R. Allen; A. Calera; J. Gonzlez; A. Jochum; M. Menenti; M. Tasumi; C. Kelly; F. Vuolo

2006-01-01T23:59:59.000Z

44

E-Print Network 3.0 - analytical method development Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Symposium, Hans-Johann Glock, What is Analytic Philosophy? Christopher Pincock, Department of Philosophy, University of Missouri...

45

E-Print Network 3.0 - analytical methods development Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Symposium, Hans-Johann Glock, What is Analytic Philosophy? Christopher Pincock, Department of Philosophy, University of Missouri...

46

E-Print Network 3.0 - analytical method based Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

based Page: << < 1 2 3 4 5 > >> 1 Symposium, Hans-Johann Glock, What is Analytic Philosophy? Christopher Pincock, Department of Philosophy, University of Missouri...

47

Equipment configurations for use of ammonia in supermarket applications. Report for September 1992-May 1994  

SciTech Connect (OSTI)

The paper discusses equipment configurations for the use of ammonia in supermarket refrigeration applications. This paper identifies the optimal design for ammonia-secondary fluid systems and compares their performance to that of R22 systems. Three methods of staging the compression were compared for both refrigerants. Six secondary fluids were evaluated for use with ammonia in a supermarket system. Overall system performance of the ammonia-secondary fluid refrigeration system is governed by a large set of design parameters. The influence of these parameters on overall system performance was studied systematically. From this parametric study, design rules were developed, leading to optimum ammonia-secondary fluid systems.

McDowell, T.P.; Mitchell, J.W.; Klein, S.A.

1996-12-31T23:59:59.000Z

48

MonteCarlo and Analytical Methods for Forced Outage Rate Calculations of Peaking Units  

E-Print Network [OSTI]

(unavailability) of such units. This thesis examines the representation of peaking units using a four-state model and performs the analytical calculations and Monte Carlo simulations to examine whether such a model does indeed represent the peaking units...

Rondla, Preethi 1988-

2012-10-26T23:59:59.000Z

49

Analytical energy gradient based on spin-free infinite-order Douglas-Kroll-Hess method with local unitary transformation  

SciTech Connect (OSTI)

In this study, the analytical energy gradient for the spin-free infinite-order Douglas-Kroll-Hess (IODKH) method at the levels of the Hartree-Fock (HF), density functional theory (DFT), and second-order Mller-Plesset perturbation theory (MP2) is developed. Furthermore, adopting the local unitary transformation (LUT) scheme for the IODKH method improves the efficiency in computation of the analytical energy gradient. Numerical assessments of the present gradient method are performed at the HF, DFT, and MP2 levels for the IODKH with and without the LUT scheme. The accuracies are examined for diatomic molecules such as hydrogen halides, halogen dimers, coinage metal (Cu, Ag, and Au) halides, and coinage metal dimers, and 20 metal complexes, including the fourthsixth row transition metals. In addition, the efficiencies are investigated for one-, two-, and three-dimensional silver clusters. The numerical results confirm the accuracy and efficiency of the present method.

Nakajima, Yuya; Seino, Junji [Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Tokyo 169-8555 (Japan)] [Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Tokyo 169-8555 (Japan); Nakai, Hiromi, E-mail: nakai@waseda.jp [Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Tokyo 169-8555 (Japan) [Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Tokyo 169-8555 (Japan); Research Institute for Science and Engineering, Waseda University, Tokyo 169-8555 (Japan); CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, Katsura, Kyoto 615-8520 (Japan)

2013-12-28T23:59:59.000Z

50

INVESTIGATION OF THE TOTAL ORGANIC HALOGEN ANALYTICAL METHOD AT THE WASTE SAMPLING AND CHARACTERIZATION FACILITY  

SciTech Connect (OSTI)

Total organic halogen (TOX) is used as a parameter to screen groundwater samples at the Hanford Site. Trending is done for each groundwater well, and changes in TOX and other screening parameters can lead to costly changes in the monitoring protocol. The Waste Sampling and Characterization Facility (WSCF) analyzes groundwater samples for TOX using the United States Environmental Protection Agency (EPA) SW-S46 method 9020B (EPA 1996a). Samples from the Soil and Groundwater Remediation Project (SGRP) are submitted to the WSCF for analysis without information regarding the source of the sample; each sample is in essence a ''blind'' sample to the laboratory. Feedback from the SGRP indicated that some of the WSCF-generated TOX data from groundwater wells had a number of outlier values based on the historical trends (Anastos 200Sa). Additionally, analysts at WSCF observed inconsistent TOX results among field sample replicates. Therefore, the WSCF lab performed an investigation of the TOX analysis to determine the cause of the outlier data points. Two causes were found that contributed to generating out-of-trend TOX data: (1) The presence of inorganic chloride in the groundwater samples: at inorganic chloride concentrations greater than about 10 parts per million (ppm), apparent TOX values increase with increasing chloride concentration. A parallel observation is the increase in apparent breakthrough of TOX from the first to the second activated-carbon adsorption tubes with increasing inorganic chloride concentration. (2) During the sample preparation step, excessive purging of the adsorption tubes with oxygen pressurization gas after sample loading may cause channeling in the activated carbon bed. This channeling leads to poor removal of inorganic chloride during the subsequent wash step with aqueous potassium nitrate. The presence of this residual inorganic chloride then produces erroneously high TOX values. Changes in sample preparation were studied to more effectively remove inorganic chloride from the activated-carbon adsorption tubes. With the TOX sample preparation equipment and TOX analyzers at WSCF, the nitrate wash recommended by EPA SW-846 method 9020B was found to be inadequate to remove inorganic chloride interference. Increasing the nitrate wash concentration from 10 grams per liter (g/L) to 100 giL potassium nitrate and increasing the nitrate wash volume from 3 milliliters (mL) to 10 mL effectively removed the inorganic chloride up to at least 100 ppm chloride in the sample matrix. Excessive purging of the adsorption tubes during sample preparation was eliminated. These changes in sample preparation have been incorporated in the analytical procedure. The results using the revised sample preparation procedure show better agreement of TOX values both for replicate analyses of single samples and for the analysis of replicate samples acquired from the same groundwater well. Furthermore, less apparent adsorption tube breakthrough now occurs with the revised procedure. One additional modification made to sample preparation was to discontinue the treatment of groundwater samples with sodium bisulfite. Sodium bisulfite is used to remove inorganic chlorine from the sample; inorganic chlorine is not expected to be a constituent in these groundwater samples. Several other factors were also investigated as possible sources of anomalous TOX results: (1) Instrument instability: examination of the history of results for TOX laboratory control samples and initial calibration verification standards indicate good long-term precision for the method and instrument. Determination of a method detection limit of 2.3 ppb in a deionized water matrix indicates the method and instrumentation have good stability and repeatability. (2) Non-linear instrument response: the instrument is shown to have good linear response from zero to 200 parts per billion (ppb) TOX. This concentration range encompasses the majority of samples received at WSCF for TOX analysis. Linear response was checked using both non-volatile TOX species (trichlorophenol) an

JG DOUGLAS; HK MEZNARICH, PHD; JR OLSEN; GA ROSS PHD; M STAUFFER

2009-02-13T23:59:59.000Z

51

INVESTIGATION OF THE TOTAL ORGANIC HALOGEN ANALYTICAL METHOD AT THE WASTE SAMPLING CHARACTERIZATION FACILITY (WSCF)  

SciTech Connect (OSTI)

Total organic halogen (TOX) is used as a parameter to screen groundwater samples at the Hanford Site. Trending is done for each groundwater well, and changes in TOX and other screening parameters can lead to costly changes in the monitoring protocol. The Waste Sampling and Characterization Facility (WSCF) analyzes groundwater samples for TOX using the United States Environmental Protection Agency (EPA) SW-846 method 9020B (EPA 1996a). Samples from the Soil and Groundwater Remediation Project (S&GRP) are submitted to the WSCF for analysis without information regarding the source of the sample; each sample is in essence a 'blind' sample to the laboratory. Feedback from the S&GRP indicated that some of the WSCF-generated TOX data from groundwater wells had a number of outlier values based on the historical trends (Anastos 2008a). Additionally, analysts at WSCF observed inconsistent TOX results among field sample replicates. Therefore, the WSCF lab performed an investigation of the TOX analysis to determine the cause of the outlier data points. Two causes were found that contributed to generating out-of-trend TOX data: (1) The presence of inorganic chloride in the groundwater samples: at inorganic chloride concentrations greater than about 10 parts per million (ppm), apparent TOX values increase with increasing chloride concentration. A parallel observation is the increase in apparent breakthrough of TOX from the first to the second activated-carbon adsorption tubes with increasing inorganic chloride concentration. (2) During the sample preparation step, excessive purging of the adsorption tubes with oxygen pressurization gas after sample loading may cause channeling in the activated-carbon bed. This channeling leads to poor removal of inorganic chloride during the subsequent wash step with aqueous potassium nitrate. The presence of this residual inorganic chloride then produces erroneously high TOX values. Changes in sample preparation were studied to more effectively remove inorganic chloride from the activated carbon adsorption tubes. With the TOX sample preparation equipment and TOX analyzers at WSCF, the nitrate wash recommended by EPA SW-846 method 9020B was found to be inadequate to remove inorganic chloride interference. Increasing the nitrate wash concentration from 10 grams per liter (g/L) to 100 g/L potassium nitrate and increasing the nitrate wash volume from 3 milliliters (mL) to 10 mL effectively removed the inorganic chloride up to at least 100 ppm chloride in the sample matrix. Excessive purging of the adsorption tubes during sample preparation was eliminated. These changes in sample preparation have been incorporated in the analytical procedure. The results using the revised sample preparation procedure show better agreement of TOX values both for replicate analyses of single samples and for the analysis of replicate samples acquired from the same groundwater well. Furthermore, less apparent column breakthrough now occurs with the revised procedure. One additional modification made to sample preparation was to discontinue the treatment of groundwater samples with sodium bisulfite. Sodium bisulfite is used to remove inorganic chlorine from the sample; inorganic chlorine is not expected to be a constituent in these groundwater samples. Several other factors were also investigated as possible sources of anomalous TOX results: (1) Instrument instability: examination of the history of results for TOX laboratory control samples and initial calibration verification standards indicate good long-term precision for the method and instrument. Determination of a method detection limit of 2.3 ppb in a deionized water matrix indicates the method and instrumentation have good stability and repeatability. (2) Non-linear instrument response: the instrument is shown to have good linear response from zero to 200 parts per billion (ppb) TOX. This concentration range encompasses the majority of samples received at WSCF for TOX analysis. (3) Improper sample preservation: ion-chromatographic analysis of several samples wit

DOUGLAS JG; MEZNARICH HD, PHD; OLSEN JR; ROSS GA; STAUFFER M

2008-09-30T23:59:59.000Z

52

Multi-component Removal in Flue Gas by Aqua Ammonia  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

component Removal in Flue Gas by Aqua Ammonia component Removal in Flue Gas by Aqua Ammonia Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 7,255,842 entitled "Multi-component Removal in Flue Gas by Aqua Ammonia." This patent discloses a method for the removal of potential environmental-impacting compounds from flue gas streams. The method oxidizes some or all of the acid precursors such as sulfur dioxide (SO 2 ) and nitric oxides (NO x ) into sulfur trioxide and nitrogen dioxide, respectively. Following this step, the gas stream is then treated with aqua ammonia or ammonium hydroxide to capture the compounds via chemical absorption through acid-base or neutralization reactions where a fertilizer is formed.

53

Process for synthesis of ammonia borane for bulk hydrogen storage  

DOE Patents [OSTI]

The present invention discloses new methods for synthesizing ammonia borane (NH.sub.3BH.sub.3, or AB). Ammonium borohydride (NH.sub.4BH.sub.4) is formed from the reaction of borohydride salts and ammonium salts in liquid ammonia. Ammonium borohydride is decomposed in an ether-based solvent that yields AB at a near quantitative yield. The AB product shows promise as a chemical hydrogen storage material for fuel cell powered applications.

Autrey, S Thomas [West Richland, WA; Heldebrant, David J [Richland, WA; Linehan, John C [Richland, WA; Karkamkar, Abhijeet J [Richland, WA; Zheng, Feng [Richland, WA

2011-03-01T23:59:59.000Z

54

VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS  

SciTech Connect (OSTI)

Method validation is the process of evaluating whether an analytical method is acceptable for its intended purpose. For pharmaceutical methods, guidelines from the United States Pharmacopeia (USP), International Conference on Harmonisation (ICH), and the United States Food and Drug Administration (USFDA) provide a framework for performing such valications. In general, methods for regulatory compliance must include studies on specificity, linearity, accuracy, precision, range, detection limit, quantitation limit, and robustness. Elements of these guidelines are readily adapted to the issue of validation for beryllium sampling and analysis. This document provides a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers and books reviewed is given in the Appendix. Available validation documents and guides are listed therein; each has a brief description of application and use. In the referenced sources, there are varying approches to validation and varying descriptions of the valication process at different stages in method development. This discussion focuses on valication and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all referenced documents were published in English.

Ekechukwu, A

2009-05-27T23:59:59.000Z

55

The Viscosity of Ammonia  

Science Journals Connector (OSTI)

A new representation of the viscosity of ammonia is presented. The representative equations are based on a set of experimental data selected as a result of a critical assessment of the available information. The validity of the representation extends from 196 K to the critical temperature for both liquid and vapor phases. In the supercritical region the temperature range extends to 680 K for pressures at or below ambient and to 600 K for pressures up to 50 MPa. The accuracy of the representation varies from 0.5% for the viscosity of the dilute gas phase at moderate temperatures to about 5% for the viscosity at high pressures and temperatures. Tables of the viscosity generated by the correlating equation at selected temperatures and pressures and along the saturation line are presented to provide easy reference as well as for the validation of computer codes.

A. Fenghour; William A. Wakeham; V. Vesovic; J. T. R. Watson; J. Millat; E. Vogel

1995-01-01T23:59:59.000Z

56

Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers  

DOE Patents [OSTI]

A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

Harvey, Scott D [Kennewick, WA

2011-06-21T23:59:59.000Z

57

The analytic gradient of the perturbative triplet excitations correction to the Brueckner doubles method  

Science Journals Connector (OSTI)

To determine correlated properties accurately, it is necessary to go beyond the level of single and double excitations from a single determinant and include the effects of the connected triple excitations. A formula for the analytic gradient of the closed-shell perturbative triple excitations correction is presented for the Brueckner doubles varinat of coupled cluster theory. Optimised geometries and harmonic frequencies are presented for H2O and the multiple bonded systems HCN, NNO and O3. For these molecules, the use of Brueckner orbitals and the triples contribution show significant effects.

Rika Kobayashi; Roger D. Amos; Nicholas C. Handy

1991-01-01T23:59:59.000Z

58

VALIDATION OF ANALYTICAL METHODS AND INSTRUMENTATION FOR BERYLLIUM MEASUREMENT: REVIEW AND SUMMARY OF AVAILABLE GUIDES, PROCEDURES, AND PROTOCOLS  

SciTech Connect (OSTI)

This document proposes to provide a listing of available sources which can be used to validate analytical methods and/or instrumentation for beryllium determination. A literature review was conducted of available standard methods and publications used for method validation and/or quality control. A comprehensive listing of the articles, papers, and books reviewed is given in Appendix 1. Available validation documents and guides are listed in the appendix; each has a brief description of application and use. In the referenced sources, there are varying approaches to validation and varying descriptions of validation at different stages in method development. This discussion focuses on validation and verification of fully developed methods and instrumentation that have been offered up for use or approval by other laboratories or official consensus bodies such as ASTM International, the International Standards Organization (ISO) and the Association of Official Analytical Chemists (AOAC). This review was conducted as part of a collaborative effort to investigate and improve the state of validation for measuring beryllium in the workplace and the environment. Documents and publications from the United States and Europe are included. Unless otherwise specified, all documents were published in English.

Ekechukwu, A.

2008-12-17T23:59:59.000Z

59

Production Systems and Processing Effect on Phytochemicals in Citrus Fruits and Their Analytical and Isolation Methods  

E-Print Network [OSTI]

performance liquid chromatography (HPLC) method for the rapid analysis of amines and organic acids was developed. The simultaneous extraction and analysis of samples provides an economical method for analyzing a large number of samples. In the second study...

Uckoo, Ram 1980-

2012-12-13T23:59:59.000Z

60

Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for Improved Hydrogen Storage. Abstract: Ammonia...

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Adding Environmental Gas Physics to the Semi-Analytic Method for Galaxy Formation: Gravitational Heating  

E-Print Network [OSTI]

We present results of an attempt to include more detailed gas physics motivated from hydrodynamical simulations within semi-analytic models (SAM) of galaxy formation, focusing on the role that environmental effects play. The main difference to previous SAMs is that we include 'gravitational' heating of the intra-cluster medium (ICM) by the net surplus of gravitational potential energy released from gas that has been stripped from infalling satellites. Gravitational heating appears to be an efficient heating source able to prevent cooling in environments corresponding to dark matter halos more massive than $\\sim 10^{13} $M$_{\\odot}$. The energy release by gravitational heating can match that by AGN-feedback in massive galaxies and can exceed it in the most massive ones. However, there is a fundamental difference in the way the two processes operate. Gravitational heating becomes important at late times, when the peak activity of AGNs is already over, and it is very mass dependent. This mass dependency and time behaviour gives the right trend to recover down-sizing in the star-formation rate of massive galaxies. Abridged...

S. Khochfar; J. P. Ostriker

2007-04-18T23:59:59.000Z

62

Development of Analytical Methods Coupled to Microdialysis Sampling for Studying Biomarkers of Oxidative Stress  

E-Print Network [OSTI]

generation would increase in biological systems due to induced oxidative stress. In one investigation, a capillary electrophoresis (CE) method with ultra-violet (UV) detection was developed employing pH-mediated stacking, an on-column preconcentration...

Hoque, Md Ehsanul

2007-12-18T23:59:59.000Z

63

Development and application of an analytical method using gas chromatography/triple quadrupole mass spectrometry for  

E-Print Network [OSTI]

. Hayworth and T. P. Clement* Environmental Engineering Program, Department of Civil Engineering, Auburn under full-scan and product-ion scan conditions. The calibration curves used were in the linear range full-scan and product-ion scan data was combined with literature data to develop a GC/MS/MS method

Clement, Prabhakar

64

Variable rate analysis of transient well test data using semi-analytical methods  

E-Print Network [OSTI]

. 4. 2. 1 Fetkovich and Vienot Data. . 4. 2. 2 Streltsova Data . 4. 2. 3 Low Productivity Gas Well DS-1 4. 2. 4 Low Productivity Gas Well CSW-1. 4. 2. 5 Low Productivity Gas Well AC-6. . 4. 2. 6 Low Productivity Gas Well TGA-21 4. 2. 7 Low... with the Material Balance Deconvolution Method and Calculated Sandface Rates . . . . . . . . . . . . . . . . . . 75 4. 1 Reservoir and Fluid Properties and Comparison of Analysis Results for Rate Normalization and Material Balance Deconvolution - Fetkovich...

Johnston, Jennifer L.

1992-01-01T23:59:59.000Z

65

An analytical method to calculate equivalent fields to irregular symmetric and asymmetric photon fields  

SciTech Connect (OSTI)

Equivalent field is frequently used for central axis depth-dose calculations of rectangular- and irregular-shaped photon beams. As most of the proposed models to calculate the equivalent square field are dosimetry based, a simple physical-based method to calculate the equivalent square field size was used as the basis of this study. The table of the sides of the equivalent square or rectangular fields was constructed and then compared with the well-known tables by BJR and Venselaar, et al. with the average relative error percentage of 2.5 2.5% and 1.5 1.5%, respectively. To evaluate the accuracy of this method, the percentage depth doses (PDDs) were measured for some special irregular symmetric and asymmetric treatment fields and their equivalent squares for Siemens Primus Plus linear accelerator for both energies, 6 and 18 MV. The mean relative differences of PDDs measurement for these fields and their equivalent square was approximately 1% or less. As a result, this method can be employed to calculate equivalent field not only for rectangular fields but also for any irregular symmetric or asymmetric field.

Tahmasebi Birgani, Mohamad J. [Department of Radiation Therapy, Golestan Hospital, JondiShapour University of Medical Science, Ahvaz (Iran, Islamic Republic of); Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of); Chegeni, Nahid, E-mail: nchegen@yahoo.com [Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of); Zabihzadeh, Mansoor; Hamzian, Nima [Department of Medical Physics, JondiShapour University of Medical Sciences, Ahvaz (Iran, Islamic Republic of)

2014-04-01T23:59:59.000Z

66

Understanding ammonia selective catalytic reduction kinetics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation,...

67

Wind-powered ammonia fuel production for remote islands: A case study  

Science Journals Connector (OSTI)

Abstract This work investigates the prospect of producing ammonia from a wind turbine in order to displace diesel fuel requirements on isolated islands. In the proposed system, wind power is used to produce carbon-free ammonia fuel directly from water and air using traditional air separation units, alkaline electrolyzers, mechanical vapor compression desalination and a HaberBosch synthesis loop. The ability to produce synthetic fuel on site is potentially valuable both because it mitigates fuel transportation costs and insulates islanders from oil price fluctuations. A general overview of the process and required components is given. The analytical model used to calculate the technical and economic performance is summarized. Monhegan Island in Maine is used as a case study for a wind-powered ammonia production facility to demonstrate the potential of ammonia fuel production. Actual wind data and electrical load data from Monhegan Island are incorporated to determine the expected ammonia production. The results are compared to the existing system in which all fuels and electricity are ultimately derived from petroleum-based fuel. Total lifetime system costs are calculated with the results normalized so that the wind-ammonia system can be directly compared to a conventional diesel-only system. A breakeven diesel price is calculated at which wind-powered ammonia production becomes competitive.

Eric Morgan; James Manwell; Jon McGowan

2014-01-01T23:59:59.000Z

68

Thermal performance of an ammonia-water refrigeration system  

SciTech Connect (OSTI)

The conservation and efficient use of energy has led to alternate methods for air conditioning in buildings. Presently, two types of absorption air conditioning systems are widely used: the lithium-bromide-water system and the ammonia-water system. The first type is typically a water fired absorption chiller while the second one is a gas fired chiller. Some of the lithium-bromide-water systems use as a source of heat a stream of hot water supplied from solar collectors at a temperature level of the order of 95-100 {degrees}C. The purpose of this paper is to explore the possibilities to use solar energy to operate an ammonia-water system and to predict its thermodynamic performance. The results indicate that it is feasible to use solar energy to operate an ammonia-water absorption-refrigeration system.

Manrique, J.A. (Inst. Tecnologico y de Estudios Superiores de Monterrey, Dept. of Thermal Engineering, Monterrey, NL (MX))

1991-11-01T23:59:59.000Z

69

Nuclear safeguard protocol construction for nuclear power plants using analytic hierarchy process with zero-sum method  

Science Journals Connector (OSTI)

A nuclear safeguard protocol (NSP) is constructed for the nuclear material flow in the operation of nuclear power plants (NPPs). Secure plant operation is one of critical issues against the risk of possible terrorism. The basic event of the related incidents is quantified by the random sampling of the Monte-Carlo method incorporating a zero-sum method. The analytic hierarchy process is developed as the maximum pair values with multiplications which are decided by the matrix-form analysis used to compare five types of NPPs of interest. Using the life cycle of 60 years, the range of the secure operation is between 0.0166000 and 0.0209531 as relative numbers. This means that the highest value in the range of secure power operation is about 1.26 times higher than the lowest one in this study. Consistency in terms of Consistency Index (CI) and Consistency Ratio (CR) is the highest in the 24th and the 54th years. Therefore, the NSP is constructed for successful safe operation.

Taeho Woo

2011-01-01T23:59:59.000Z

70

Investigations of ammonia-secondary fluid systems in supermarket refrigeration systems  

SciTech Connect (OSTI)

International agreements have legislated the phaseout of many refrigerants, including R-502 and R-12, which are commonly used in supermarket refrigeration systems. R-22 and ammonia (R-717) are candidate replacement refrigerants having appropriate thermodynamic properties. The toxicity of ammonia at low concentrations required that it be confined to the equipment room, so a secondary fluid is needed to distribute cooling to the refrigerated cases. This paper investigates ammonia-secondary fluid systems and compares their performance with equivalent R-22 systems. Both R-22 and ammonia have high compressor discharge temperatures, necessitating staged compression. Three methods of staging the compression were compared for both refrigerants. Six secondary fluids were evaluated for use with ammonia in the supermarket system. The overall system performance of the ammonia-secondary fluid refrigeration system, including both compressor and secondary fluid pump power, is governed by a large set of design parameters. The influence of these parameters on the overall system performance was studied in a systematic manner. From this parametric study, design rules leading to optimal ammonia-secondary fluid systems were developed. The performance of well-designed ammonia-secondary fluid systems was found to be 4% to 10% lower than that of R-22 systems operating under similar conditions.

McDowell, T.P. [Thermal Storage Applications Research Center, Madison, WI (United States); Mitchell, J.W.; Klein, S.A. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Mechanical Engineering

1995-12-31T23:59:59.000Z

71

Polyaniline-based optical ammonia detector  

DOE Patents [OSTI]

Electronic absorption spectroscopy of a polyaniline film deposited on a polyethylene surface by chemical oxidation of aniline monomer at room temperature was used to quantitatively detect ammonia gas. The present optical ammonia gas detector was found to have a response time of less than 15 s, a regeneration time of less than 2 min. at room temperature, and a detection limit of 1 ppm (v/v) for ammonia, with a linear dynamic range from 180 ppm to 18,000 ppm.

Duan, Yixiang (Los Alamos, NM); Jin, Zhe (Los Alamos, NM); Su, Yongxuan (Los Alamos, NM)

2002-01-01T23:59:59.000Z

72

A Modified Analytical Method for Simulating Cyclic Operation of Vertical U-Tube Ground-Coupled Heat Pumps  

E-Print Network [OSTI]

A modified analytical model is presented which discretizes the ground-coupled heat exchanger of a ground-coupled heat pump and utilized a separate cylindrical source solution for each element. First law expressions are utilized for each element...

Dobson, M. K.; O'Neal, D. L.; Aldred, W.

1994-01-01T23:59:59.000Z

73

Ammonia-Activated Mesoporous Carbon Membranes for Gas Separations  

SciTech Connect (OSTI)

Porous carbon membranes, which generally show improved chemical and thermal stability compared to polymer membranes, have been used in gas separations for many years. In this work, we show that the post-synthesis ammonia treatment of porous carbon at elevated temperature can improve the permeance and selectivity of these membranes for the separation of carbon dioxide and hydrocarbons from permanent gases. Hierarchically structured porous carbon membranes were exposed to ammonia gas at temperatures ranging from 850 C to 950 C for up to 10 min and the N{sub 2}, CO{sub 2}, and C{sub 3}H{sub 6} permeances were measured for these different membranes. Higher treatment temperatures and longer exposure times resulted in higher gas permeance values. In addition, CO{sub 2}/N{sub 2} and C{sub 3}H{sub 6}/N{sub 2} selectivities increased by a factor of 2 as the treatment temperature and time increased up to a temperature and time of 900 C, 10 min. Higher temperatures showed increased permeance but decreased selectivity indicating excess pore activation. Nitrogen adsorption measurements show that the ammonia treatment increased the porosity of the membrane while elemental analysis revealed the presence of nitrogen-containing surface functionalities in the treated carbon membranes. Thus, ammonia treatment at high temperature provides a controlled method to introduce both added microporosity and surface functionality to enhance gas separations performance of porous carbon membranes.

Mahurin, Shannon Mark [ORNL; Lee, Jeseung [ORNL; Wang, Xiqing [ORNL; Dai, Sheng [ORNL

2011-01-01T23:59:59.000Z

74

Layer of protection analysis applied to ammonia refrigeration systems  

E-Print Network [OSTI]

Ammonia refrigeration systems are widely used in industry. Demand of these systems is expected to increase due to the advantages of ammonia as refrigerant and because ammonia is considered a green refrigerant. Therefore, it is important to evaluate...

Zuniga, Gerald Alexander

2009-05-15T23:59:59.000Z

75

Decomposition Pathway of Ammonia Borane on the Surface of nano...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Decomposition Pathway of Ammonia Borane on the Surface of nano-BN. Decomposition Pathway of Ammonia Borane on the Surface of nano-BN. Abstract: Ammonia borane (AB) is under...

76

Urea/Ammonia Distribution Optimization in an SCR Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis UreaAmmonia Distribution Optimization in an SCR Emission Control System...

77

Geochemical and Geophysical Changes during Ammonia Gas Treatment...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geophysical Changes during Ammonia Gas Treatment of Vadose Zone Sediments for Uranium Remediation. Geochemical and Geophysical Changes during Ammonia Gas Treatment of Vadose Zone...

78

Potential of High-Throughput Experimentation with Ammonia Borane...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Potential of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials (presentation) Potential of High-Throughput Experimentation with Ammonia Borane...

79

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

80

Ammonia Solubility in High Concentration Salt Solutions  

SciTech Connect (OSTI)

Solubility data for ammonia in water and various dilute solutions are abundant in the literature. However, there is a noticeable lack of ammonia solubility data for high salt, basic solutions of various mixtures of salts including those found in many of the Hanford Washington underground waste tanks. As a result, models based on solubility data for dilute salt solutions have been used to extrapolate to high salt solutions. These significant extrapolations need to be checked against actual laboratory data. Some indirect vapor measurements have been made. A more direct approach is to determine the ratio of solubility of ammonia in water to its solubility in high salt solutions. In various experiments, pairs of solutions, one of which is water and the other a high salt solution, are allowed to come to equilibrium with a common ammonia vapor pressure. The ratio of concentrations of ammonia in the two solutions is equal to the ratio of the respective ammonia solubilities (Henry's Law constants) at a given temperature. This information can then be used to refine the models that predict vapor space compositions of ammonia. Ammonia at Hanford is of concern because of its toxicity in the environment and its contribution to the flammability of vapor space gas mixtures in waste tanks.

HEDENGREN, D.C.

2000-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Hydrogen Storage in Ammonia and Aminoborane Complexes  

E-Print Network [OSTI]

Hydrogen Storage in Ammonia and Aminoborane Complexes Ali Raissi Florida Solar Energy Center;Advantages of Ammonia Costs about $150 per short ton or less than $6.25 per million BTU of H2 contained and utilization Stores 30% more energy by liquid volume than LH2 Easily reformed using 16% of the energy

82

Process for ammonia syngas manufacture  

SciTech Connect (OSTI)

This patent describes an improved process for reforming hydrocarbons to obtain a synthesis gas containing an approximately stoichiometric amount of hydrogen and nitrogen from which ammonia may be formed in which a hydrocarbon is reacted with steam and air in a reforming operation to obtain a first effluent. This effluent consists of hydrogen, nitrogen and carbon monoxide. The carbon monoxide is reacted in a shift conversion stage to produce a second effluent consisting of hydrogen, nitrogen, and carbon dioxide. The improved process has the additional steps of separating the second effluent into a first stream and a second stream. The first stream is reacted with air in a fuel cell to produce a byproduct stream and a product stream which is passed through a de-oxygenation stage to produce a purified stream. The second stream and the purified stream is passed into a pressure swing adsorption unit in which the synthesis gas and a waste fuel stream are separated.

Jungerhans, R.R.J.

1986-03-25T23:59:59.000Z

83

Approximate analytical method and its use for calculation of phase velocities of acoustic plane waves in crystals for example LiNbO3  

E-Print Network [OSTI]

By means of the offered analytical method the determinant relation for a phase velocities of elastic waves for an arbitrary propagation directions in a piezoelectric crystal are received. The phase velocities of three normal elastic waves for the crystal of LiNbO3 are calculated. Results of this calculation for each of waves are presented graphically in the form of the cards allowing easily to define phase velocities in any given direction in crystal.

A. A. Golubeva

2010-07-26T23:59:59.000Z

84

A literature review of methods of analysis of organic analytes in radioactive wastes with an emphasis on sources from the United Kingdom  

SciTech Connect (OSTI)

This report, compiled by Pacific Northwest Laboratory (PNL), examines literature originating through the United Kingdom (UK) nuclear industry relating to the analyses of organic constituents of radioactive waste. Additionally, secondary references from the UK and other counties, including the United States, have been reviewed. The purpose of this literature review was to find analytical methods that would apply to the mixed-waste matrices found at Hanford.

Clauss, S.A.; Bean, R.M.

1993-09-01T23:59:59.000Z

85

Analytic Feminism: A Brief Introduction  

E-Print Network [OSTI]

This essay introduces the subject of this special issue by offering a characterization of analytic feminism in terms of its context, methods, and problem areas. I argue that analytic feminism is a legitimate sub-field both ...

Cudd, Ann E.

1995-01-01T23:59:59.000Z

86

Ammonia evolution during oil shale pyrolysis  

Science Journals Connector (OSTI)

Ammonia evolution during oil shale pyrolysis ... Parallel pyrolytic studies were carried out on an immature, ultralaminae-rich, type I kerogen (Gynk oil shale kerogen) and a related algaenan (isolated from the extant green microalga Scenedesmus communis). ...

Myongsook S. Oh; Robert W. Taylor; Thomas T. Coburn; Richard W. Crawford

1988-01-01T23:59:59.000Z

87

Project Profile: Thermochemical Storage with Anhydrous Ammonia...  

Office of Environmental Management (EM)

The system is charged when ammonia, NH3, is heated in the Endothermic reactor by the sun (Qsol) transforming it into N2 and H2. These gasses are then cooled and stored in the...

88

Development of an analytical method and its quick algorithm to calculate the solar energy collected by a heliostat field in a year  

Science Journals Connector (OSTI)

Abstract In this paper, we firstly propose an analytical equation to calculate the energy collected by the heliostat field. A ray tracing method is developed based on the analytical equation. Then we introduce three approximations to reduce computation spending, and estimate the errors caused by these approximations. A fast and accurate algorithm is developed with the three approximations to calculate the energy collected by the heliostat field over a year. It was compared with the ray tracing results, which shows good consistency with them. With the method, the energy collected and efficiency of each heliostat in a year can be computed exactly and rapidly, the difference between the method and ray tracing method is less than 0.1% for the energy collected by a heliostat over a day. It needs only about 0.1% computation time used by ray tracing method to calculate the intercept factor of a heliostat at a moment, and 2.67h to compute the annual collected energy of PS10 heliostat field by using one CPU of i3 processor when the time span for integration is 5min and each heliostat is calculated.

Weidong Huang; Qian Xu

2014-01-01T23:59:59.000Z

89

The analytical energy gradient scheme in the Gaussian based Hartree-Fock and density functional theory for two-dimensional systems using fast multipole method  

SciTech Connect (OSTI)

The analytical total energy gradient scheme for the Hartree-Fock and density functional crystalline orbital theory is formulated for infinitely extended periodic systems of general dimensions and implemented for those of two dimensions. Two major differences between the analytical gradient scheme for extended systems and that for molecular systems are described in detail. The first is the treatment of the long-range Coulomb interactions, which arises due to the infinite nature of the systems. The long-range effect is efficiently included by the multipole expansion technique and its extension, the fast multipole method The use of the fast multipole method enables us to include the long range effect up to the order of micro meter to millimeter region around the reference unit cell by virtue of the logarithmic cost scaling of the algorithm achieved by regrouping distant multipoles together and reducing the number of pairwise interactions. The second is the formulation of analytical gradient expressions with respect to unit cell parameters. In the HF theory they can be calculated by accumulating forces acting on atoms multiplied by some appropriate factors, while there is an extra term which requires a special numerical treatment in grid-based density functional theory. Specifically, it is shown that the quadrature weight derivatives do not vanish even in the limit of infinitely fine grid, when calculating the gradients with respect to unit cell parameters, and are essential in evaluating those gradients. Combining the analytical gradient scheme and an efficient inclusion of the long-range interaction makes it feasible to perform a full geometry optimization of extended systems at ab initio levels.

Tobita, Motoi; Hirata, So; Bartlett, Rodney J.

2003-04-01T23:59:59.000Z

90

E-Print Network 3.0 - ammonia gas cell Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

HYDROGEN Rebecca Dunn, Keith Lovegrove Summary: state ammonia synthesis, direct ammonia fuel-cells, combustion characterisation of ammonia... . The only products of the complete...

91

An uncovered XIII century icon: Particular use of organic pigments and gilding techniques highlighted by analytical methods  

Science Journals Connector (OSTI)

Abstract The restoration of a panel painting depicting a Madonna and Child listed as an unknown Tuscan artist of the nineteenth century, permitted the hidden original version, a XIII century Medieval icon to be uncovered. It is discovery provided the opportunity for an extensive in situ campaign of non-invasive analytical investigations by portable imaging and spectroscopic techniques (infrared, X-ray fluorescence and diffraction, UVVis absorption and emission), followed by aimed micro-destructive investigations (Raman and SEMEDS). This approach permitted characterization of the original ground and paint layers by complementary techniques. Furthermore, this protocol allowed supplementary particularities of great interest to be highlighted. Namely, numerous original gilding techniques have been accentuated in diverse areas and include the use of surrogate gold (disulphur tin), orpiment as a further false gold and an area with an original silver rich layer. Moreover, pigments including azurite mixed with indigo have been non-invasively identified. Micro-invasive analyses also allowed the diagnosis of organic colorants, namely, an animal anthraquinone lake, kermes and an unusual vegetal chalcone pigment, possibly safflower. The identification of the latter is extremely rare as a painting pigment and has been identified using an innovative adaption to surface enhanced Raman techniques on a cross-section. The resulting data contributes new hypotheses to the historic and artistic knowledge of materials and techniques utilized in XIII century icon paintings and ultimately provides scientific technical support of the recent restoration.

Alessia Daveri; Brenda Doherty; Patrizia Moretti; Chiara Grazia; Aldo Romani; Enrico Fiorin; Brunetto Giovanni Brunetti; Manuela Vagnini

2015-01-01T23:59:59.000Z

92

Spectroscopic Studies of the Phase Transition in Ammonia Borane...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Studies of the Phase Transition in Ammonia Borane: Raman spectroscopy of single crystal NH3BH3 as a function of Spectroscopic Studies of the Phase Transition in Ammonia Borane:...

93

Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems  

E-Print Network [OSTI]

This paper presents case studies of two moderately sized ammonia refrigeration systems retrofitted for floating head pressure control. It also presents a parametric analysis to assist in selecting appropriate pressures in an ammonia refrigeration...

Barrer, P. J.; Jones, S. M.

94

Emission factors for ammonia and particulate matter from broiler Houses  

E-Print Network [OSTI]

of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids. volatile amines, indole, phenol, sulfur-containing compounds). Ammonia is produced from the microbial breakdown of uric acid in poultry manure. The decomposition... sulfate (Barthelmie and Pryor, 1998). Additionally, ammonia is an odorant and conditions conducive to the production of ammonia will probably result in the emission of other odorants (e. g. volatile fatty acids, volatile amines, indole, phenol, sulfur...

Redwine, Jarah Suzanne

2001-01-01T23:59:59.000Z

95

Trends in On-Road Vehicle Emissions of Ammonia  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trends in On-Road Vehicle Emissions of Ammonia Trends in On-Road Vehicle Emissions of Ammonia Title Trends in On-Road Vehicle Emissions of Ammonia Publication Type Journal Article Year of Publication 2008 Authors Kean, Andrew J., David Littlejohn, George Ban-Weiss, Robert A. Harley, Thomas W. Kirchstetter, and Melissa M. Lunden Journal Atmospheric Environment Abstract Motor vehicle emissions of ammonia have been measured at a California highway tunnel in the San Francisco Bay area. Between 1999 and 2006, light-duty vehicle ammonia emissions decreased by 38 ± 6%, from 640 ± 40 to 400 ± 20 mg kg-1. High time resolution measurements of ammonia made in summer 2001 at the same location indicate a minimum in ammonia emissions correlated with slower-speed driving conditions. Variations in ammonia emission rates track changes in carbon monoxide more closely than changes in nitrogen oxides, especially during later evening hours when traffic speeds are highest. Analysis of remote sensing data of Burgard et al. (Environ Sci. Technol. 2006, 40, 7018-7022) indicates relationships between ammonia and vehicle model year, nitrogen oxides, and carbon monoxide. Ammonia emission rates from diesel trucks were difficult to measure in the tunnel setting due to the large contribution to ammonia concentrations in a mixed-traffic bore that were assigned to light-duty vehicle emissions. Nevertheless, it is clear that heavy-duty diesel trucks are a minor source of ammonia emissions compared to light-duty gasoline vehicles.

96

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES  

E-Print Network [OSTI]

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES A DISSERTATION SUBMITTED;ABSTRACT Autotrophic ammonia oxidation has been documented for the first time in deep- sea hydrothermal autotrophic ammonia oxidation at ~ 91 nM d-1 , and potentially produces de novo organic carbon at a rate (0

Luther, Douglas S.

97

Removal of ammonia from tarry water using a tubular furnace  

SciTech Connect (OSTI)

An ammonia-processing system without the use of live steam from OAO Alchevskkoks plant's supply network is considered. Steam obtained from the wastewater that leaves the ammonia column is used to process the excess tarry water, with the release of volatile ammonia.

V.V. Grabko; V.A. Kofanova; V.M. Li; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

98

Analytical Dashboards  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytical Dashboards Analytical Dashboards Public Final Occurrence Reports: Searchable information on DOE's Final Occurrence Reports since 2009, available to the public and updated daily. Computerized Accident Incident Reporting System (CAIRS) - Injury and Illness Dashboard: The Injury and Illness Dashboard is a tool that allows users to easily explore DOE occupational safety and health injury and illness information. Its features include: Graphical and tabular depictions of injury and illness information Calendar year and fiscal year incidence rates for DOE and DOE contractor total recordable cases (TRC) of injuries and illnesses and cases involving days away from work or on job transfer or restriction (DART) due to injury or illness Incidence rates of injuries and illnesses by DOE program

99

Capture and evolution of dust in planetary mean-motion resonances: a fast, semi-analytic method for generating resonantly trapped disk images  

E-Print Network [OSTI]

Dust grains migrating under Poynting-Robertson drag may be trapped in mean-motion resonances with planets. Such resonantly trapped grains are observed in the solar system. In extrasolar systems, the exozodiacal light produced by dust grains is expected to be a major obstacle to future missions attempting to directly image terrestrial planets. The patterns made by resonantly trapped dust, however, can be used to infer the presence of planets, and the properties of those planets, if the capture and evolution of the grains can be modelled. This has been done with N-body methods, but such methods are computationally expensive, limiting their usefulness when considering large, slowly evolving grains, and for extrasolar systems with unknown planets and parent bodies, where the possible parameter space for investigation is large. In this work, we present a semi-analytic method for calculating the capture and evolution of dust grains in resonance, which can be orders of magnitude faster than N-body methods. We calibr...

Shannon, Andrew; Wyatt, Mark

2015-01-01T23:59:59.000Z

100

Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation  

SciTech Connect (OSTI)

This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

1995-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Analytical study of bound states in graphene nano-ribbons and carbon nanotubes: The variable phase method and the relativistic Levinson theorem  

E-Print Network [OSTI]

The problem of localized states in 1D systems with the relativistic spectrum, namely, graphene stripes and carbon nanotubes, has been analytically studied. The bound state as a superposition of two chiral states is completely described by their relative phase. The criteria of bound states appearance have been obtained based on the variable phase method (VPM) and the relativistic Levinson theorem developed via the VPM. The problem of bound states is reduced to the analysis of singularities of some vector field where the Levinson theorem appears as the Poincare indices theorem for closed trajectories of this field. The reduction of the VPM equation to the non-relativistic and semi-classical limits has been done. The limit of the small momentum p_y of the transverse quantization is applicable to arbitrary integrable potential. In this case the only confined mode is predicted.

D. S. Miserev

2014-08-24T23:59:59.000Z

102

Atmospheric Environment 42 (2008) 33153331 Measurement and analysis of ammonia and hydrogen sulfide  

E-Print Network [OSTI]

; Hydrogen sulfide; Swine barns; CAFOs 1. Introduction Changes in livestock production methods in the USAtmospheric Environment 42 (2008) 3315­3331 Measurement and analysis of ammonia and hydrogen, where NH3­N ¼ (14 17)NH3) and hydrogen sulfide (H2S) were measured from a finishing swine confinement

Aneja, Viney P.

103

Development of A Cryogenic Drift Cell Spectrometer and Methods for Improving the Analytical Figures of Merit for Ion Mobility-Mass Spectrometry Analysis  

E-Print Network [OSTI]

A cryogenic (325-80 K) ion mobility-mass spectrometer was designed and constructed in order to improve the analytical figures-of-merit for the chemical analysis of small mass analytes using ion mobility-mass spectrometry. The instrument incorporates...

May, Jody C.

2010-10-12T23:59:59.000Z

104

Ammonia Capture in Porous Organic Polymers Densely Functionalized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brnsted Acid Groups Previous Next List Jeffrey F. Van Humbeck, Thomas M. McDonald, Xiaofei Jing, Brian M....

105

Release of ammonia from HAN-type PHA  

SciTech Connect (OSTI)

A preliminary design basis for ammonia scrubbers in the DWPF has been issued. This design basis is based on a theoretical model of ammonia evolution from the SRAT, SME and RCT. It is desirable to acquire actual process data on ammonia evolution prior to performing detailed design of scrubbers for DWPF. The evolution of ammonia from the SRAT and SME in the Integrated DWPF Melter System (IDMS) was investigated during the HM4 run. In this run, Precipitate Hydrolysis Aqueous (PHA), which was made in the Precipitate Hydrolysis Experimental Facility (PHEF) using the HAN (hydroxylamine nitrate) process was used, thus resulting in PHA with a high concentration of ammonium ion.

Zamecnik, J.R.

1992-06-10T23:59:59.000Z

106

Use and recovery of ammonia in power plant cycles  

SciTech Connect (OSTI)

The paper presents some practical and theoretical aspects of the use of ammonia in power plant water/steam cycles. The plants considered are fully automated units with once-through boilers, which operate under complex conditions and are subject to frequent starts and load changes. The boilers are chemically conditioned with combined oxygen ammonia treatment and the condensate polishing plant is only operated during start-up, in the event of a condenser leak or to remove excess ammonia. The paper also covers the recovery of ammonia from the condensate polishing plant waste regenerants and reuse for conditioning the feedwater. In particular, the paper deals with the following points: theoretical analysis of the chemical equilibrium of ammonia and carbon dioxide in water, including calculation of the concentrations from the parameters normally measured, such as conductivities and pH; equipment for monitoring and controlling the amount of ammonia fed to the water/steam cycle, including the optimum positioning of the sampling and feed-points, the parameters suitable for feed control and their temperature dependence; the partial pressure and distribution coefficient of ammonia; the consumption and losses of ammonia through the water/steam cycle during operation; the recovery of ammonia from condensate polishing plant waste regenerants by steam stripping. The paper should be of interest to both planning engineers and plant operators.

Pflug, H.D.; Bettenworth, H.J.; Syring, H.A. [Preussen Elektra AG, Hanover (Germany)

1995-01-01T23:59:59.000Z

107

Potential of High-Throughput Experimentation with Ammonia Borane...  

Broader source: Energy.gov (indexed) [DOE]

of High-Throughput Experimentation with Ammonia Borane Solid Hydrogen Storage Materials Jonathan L. Male Pacific Northwest National Laboratory June 26, 2006 US Department of Energy...

108

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

109

Industrial Analytics Corporation  

SciTech Connect (OSTI)

The lost foam casting process is sensitive to the properties of the EPS patterns used for the casting operation. In this project Industrial Analytics Corporation (IAC) has developed a new low voltage x-ray instrument for x-ray radiography of very low mass EPS patterns. IAC has also developed a transmitted visible light method for characterizing the properties of EPS patterns. The systems developed are also applicable to other low density materials including graphite foams.

Industrial Analytics Corporation

2004-01-30T23:59:59.000Z

110

Study of On-Board Ammonia (NH3) Generation for SCR Operation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Study of On-Board Ammonia (NH3) Generation for SCR Operation Study of On-Board Ammonia (NH3) Generation for SCR Operation The feasibility of on-board ammonia generation was...

111

Estimation of Carbon Monoxide and Carbon Dioxide at Sub-ppm Level Concentrations in Ammonia Synthesis Gas  

Science Journals Connector (OSTI)

......can be handled per analysis. The ammonia synthesis...conditioning of I2O5 reactors or to marginal flow...20%. Thus, the reliability of the method depends...practice for the analysis of trace impurities...estimated from a single analysis the method of converting...to CO2 using I2O5 reactor (11) after its......

K. Annaji Rao; K.K. Pushpa; Hari Mohan; R.M. Iyer

1978-07-01T23:59:59.000Z

112

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34...

113

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas...

114

E-Print Network 3.0 - ammonia-oxidizing archaea diversity Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 4 Ammonia oxidation kinetics determine niche separation of nitrifying Archaea and Bacteria Summary: LETTERS Ammonia oxidation kinetics...

115

E-Print Network 3.0 - ammonia gas sensing Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

This paper reports the first detection of methanol and ammonia from nadir viewing remote sensing instruments... First satellite observations of lower tropospheric ammonia and...

116

RDF analytics: lenses over semantic graphs  

Science Journals Connector (OSTI)

The development of Semantic Web (RDF) brings new requirements for data analytics tools and methods, going beyond querying to semantics-rich analytics through warehouse-style tools. In this work, we fully redesign, from the bottom up, core data analytics ... Keywords: OLAP, RDF, data warehouse

Dario Colazzo, Franois Goasdou, Ioana Manolescu, Alexandra Roati?

2014-04-01T23:59:59.000Z

117

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the January 1 to March 31, 2004 time period.

S. Wu; Z. Fan; R. Herman

2004-03-31T23:59:59.000Z

118

Ammonia-Free NOx Control System  

SciTech Connect (OSTI)

Research is being conducted under United States Department of Energy (DOE) Contract DEFC26-03NT41865 to develop a new technology to achieve very low levels of NOx emissions from pulverized coal fired boiler systems by employing a novel system level integration between the PC combustion process and the catalytic NOx reduction with CO present in the combustion flue gas. The combustor design and operating conditions will be optimized to achieve atypical flue gas conditions. This approach will not only suppress NOx generation during combustion but also further reduce NOx over a downstream catalytic reactor that does not require addition of an external reductant, such as ammonia. This report describes the work performed during the October 1 to December 31, 2003 time period.

S. Wu

2003-12-31T23:59:59.000Z

119

Multi-component removal in flue gas by aqua ammonia  

DOE Patents [OSTI]

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

2007-08-14T23:59:59.000Z

120

How the Membrane Protein AmtB Transports Ammonia  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How the Membrane Protein AmtB Transports Ammonia Print How the Membrane Protein AmtB Transports Ammonia Print Membrane proteins provide molecular-sized entry and exit portals for the various substances that pass into and out of cells. While life scientists have solved the structures of protein channels for ions, uncharged solutes, and even water, up to now they have only been able to guess at the precise mechanisms by which gases (such as NH3, CO2, O2, NO, N2O, etc.) cross biological membranes. But, with the first high-resolution structure of a bacterial ammonia transporter (AmtB), determined by a team in the Stroud group from the University of California, San Francisco, it is now known that this family of transporters conducts ammonia by stripping off the proton from the ammonium (NH4+) cation and conducting the uncharged NH3 "gas."

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Design and performance of an ammonia measurement system  

E-Print Network [OSTI]

emissions. The task cannot be completed without equipment that can efficiently and accurately compare emissions. To complete this task, a measurement system was developed and performance tested to measure ammonia. Performance tests included uncertainty...

2007-04-25T23:59:59.000Z

122

Ammonia Sensor for SCR NOX Reduction | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sensor for SCR NOX Reduction Ammonia Sensor for SCR NOX Reduction Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,...

123

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Broader source: Energy.gov (indexed) [DOE]

Fuel LNT (Generates Ammonia) Exhaust Selective Catalytic DPF Valve Reduction Catalyst (SCR) 2 DEER 2007 Bypass V2 LNT V1 Reformer SCR Bypass V2 LNT V1 SCR Reformer * NOx storage...

124

Urea/Ammonia Distribution Optimization in an SCR Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

P-20 UreaAmmonia Distribution Optimization in an SCR Emission Control System Through the Use of CFD Analysis Gi-Heon Kim, Matthew Thornton National Renewable Energy Laboratory...

125

Delphi On-board Ammonia Generation (OAG) | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Reductant Utilization in a LNT + SCR System Application of a Diesel Fuel Reformer for Tier 2 Bin 5 Emissions...

126

Potential Roles of Ammonia in a Hydrogen Economy  

Broader source: Energy.gov [DOE]

Produced in February 2006 by the U.S. Department of Energy, this report focuses on the key issues and advantages and disadvantages associated with using ammonia for on-board vehicular hydrogen storage.

127

Effect of ammonia plasma treatment on graphene oxide LB monolayers  

SciTech Connect (OSTI)

Graphene oxide monolayer sheets were transferred on Si and SiO{sub 2}/Si substrates by Langmuir-Blodgett technique and were exposed to ammonia plasma at room temperature. The monolayer character of both graphene oxide and plasma treated graphene oxide sheets were ascertained by atomic force microscopy. X-ray photoelectron spectroscopy and Raman spectroscopy revealed that ammonia plasma treatment results in enhancement of graphitic carbon content along with the incorporation of nitrogen. The conductivity of graphene oxide monolayers, which was in the range of 10{sup -6}-10{sup -7} S/cm, increased to 10{sup -2}-10{sup -3} S/cm after the ammonia plasma treatment. These results indicate that the graphene oxide was simultaneously reduced and N-doped during ammonia plasma treatment, without affecting the morphological stability of sheets.

Singh, Gulbagh; Botcha, V. Divakar; Narayanam, Pavan K.; Sutar, D. S.; Talwar, S. S.; Major, S. S. [Department of Physics, Indian Institute of Technology Bombay, Mumbai - 400076 (India); Srinivasa, R. S. [Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai - 400076 (India)

2013-02-05T23:59:59.000Z

128

Membrane Based intensification of ammonia removal from wastewater  

E-Print Network [OSTI]

The aim of this research was to study a novel membrane based oxygen intensification system to enhance a biological wastewater treatment process for ammonia removal. Specifically, this work is concerned with the biological nitrification process which...

Almutairi, Azel

2011-12-31T23:59:59.000Z

129

Measurements of Ammonia at Blodgett Forest  

SciTech Connect (OSTI)

Ammonia is a reactive trace gas that is emitted in large quantities by animal agriculture and other sources in California, which subsequently forms aerosol particulate matter, potentially affecting visibility, climate, and human health. We performed initial measurements of NH{sub 3} at the Blodgett Forest Research Station (BFRS) during a 3 week study in June, 2006. The site is used for ongoing air quality research and is a relatively low-background site in the foothills of the Sierra Nevada. Measured NH{sub 3} mixing ratios were quite low (< 1 to {approx}2 ppb), contrasting with typical conditions in many parts of the Central Valley. Eddy covariance measurements showed NH{sub 3} fluxes that scaled with measured NH{sub 3} mixing ratio and calculated aerodynamic deposition velocity, suggesting dry deposition is a significant loss mechanism for atmospheric NH{sub 3} at BFRS. A simple model of NH{sub 3} transport to the site supports the hypothesis that NH{sub 3} is transported from the Valley to BFRS, but deposits on vegetation during the summer. Further work is necessary to determine whether the results obtained in this study can be generalized to other seasons.

Fischer, Marc L.; Littlejohn, David

2007-04-01T23:59:59.000Z

130

Welcome to Analytical Labs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Services Services Our Capabilities Analytical Laboratories at the SRS performs analyses on a wide range of materials, including soil, water, gases, foodstuffs, decommissioning debris, waste, urine, fecal matter and process control samples. The laboratories maintain certifications and qualifications through a variety of governing bodies, which allows multiple applications of our services. Each year, we process over 200,000 samples and over half a million determinations, with an error-free rate better than 99.99%. Our Services We offer a full complement of nuclear counting and chemical processing methods, including microwave/hot block digestion of solids; alpha pulse height analyzer (PHA), gamma PHA and liquid scintillation counter, diode array spectrophotometer, ICP emission spectrometer, ICP mass spectrometer, thermal ionization mass spectrometer, chemical titrators, and IR analyzer. In addition, we offer unique environmental and industrial hygiene analytical services, including rapid analysis of radiological contaminants in water, soil, and human matrices; Radiological American Industrial Hygiene Association-accredited beryllium, lead, other metals, hexavalent chromium, and asbestos analyses.

131

100-B/C Target Analyte List Development for Soil  

SciTech Connect (OSTI)

This report documents the process used to identify source area target analytes in support of the 100-B/C remedial investigation/feasibility study addendum to DOE/RL-2008-46. This report also establishes the analyte exclusion criteria applicable for 100-B/C use and the analytical methods needed to analyze the target analytes.

R.W. Ovink

2010-03-18T23:59:59.000Z

132

Glow Discharge Enhanced Chemical Reaction: Application in Ammonia Synthesis and Hydrocarbon Gas Cleanup  

E-Print Network [OSTI]

technologies, such as the selective catalytic reduction (SCR) methods have been studied for the cleaning of diesel engine exhaust. The SCR system, in which ammonia is used as a reducing agent, is thought to be one of the most promising methods for emissions... of methane, it can also include ethane, propane, butane and pentane. The composition of natural gas can vary widely, but Table 1 below outlines the typical makeup of natural gas before it is refined. 3 Table 1. Typical composition of natural gas...

Ming, Pingjia

2014-06-05T23:59:59.000Z

133

An analytical coarse-graining method which preserves the free energy, structural correlations, and thermodynamic state of polymer melts from the atomistic to the mesoscale  

SciTech Connect (OSTI)

Structural and thermodynamic consistency of coarse-graining models across multiple length scales is essential for the predictive role of multi-scale modeling and molecular dynamic simulations that use mesoscale descriptions. Our approach is a coarse-grained model based on integral equation theory, which can represent polymer chains at variable levels of chemical details. The model is analytical and depends on molecular and thermodynamic parameters of the system under study, as well as on the direct correlation function in the k ? 0 limit, c{sub 0}. A numerical solution to the PRISM integral equations is used to determine c{sub 0}, by adjusting the value of the effective hard sphere diameter, d{sub HS}, to agree with the predicted equation of state. This single quantity parameterizes the coarse-grained potential, which is used to perform mesoscale simulations that are directly compared with atomistic-level simulations of the same system. We test our coarse-graining formalism by comparing structural correlations, isothermal compressibility, equation of state, Helmholtz and Gibbs free energies, and potential energy and entropy using both united atom and coarse-grained descriptions. We find quantitative agreement between the analytical formalism for the thermodynamic properties, and the results of Molecular Dynamics simulations, independent of the chosen level of representation. In the mesoscale description, the potential energy of the soft-particle interaction becomes a free energy in the coarse-grained coordinates which preserves the excess free energy from an ideal gas across all levels of description. The structural consistency between the united-atom and mesoscale descriptions means the relative entropy between descriptions has been minimized without any variational optimization parameters. The approach is general and applicable to any polymeric system in different thermodynamic conditions.

McCarty, J.; Clark, A. J.; Copperman, J.; Guenza, M. G., E-mail: mguenza@uoregon.edu [Department of Chemistry and Biochemistry, and Institute of Theoretical Science, University of Oregon, Eugene, Oregon 97403 (United States)

2014-05-28T23:59:59.000Z

134

Nanochannel and its application in analytical chemistry  

Science Journals Connector (OSTI)

The nanochannels method for the separation and detection of analytes plays an important role in the analytical chemistry and is exhibiting the great potential advantages and promising future. In this review we bring together and discuss a number of nanochannels ... Keywords: applications, nanochannels, preparation, separation

Zenglian Yue; Guoqing Zhao; Bin Peng; Shasheng Huang

2009-12-01T23:59:59.000Z

135

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Lean-burn SIDI...

136

3rd Generation SCR System Using Solid Ammonia Storage and Direct...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

137

Safe and compact ammonia storage/delivery systems for SCR-DeNOX...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Safe and compact ammonia storagedelivery systems for SCR-DeNOX in automotive units Presentation...

138

Optimal Energy Recovery from Ammonia Synthesis in a Solar Thermal Power Plant  

Science Journals Connector (OSTI)

This work estimates the optimal performance, and evaluates a process modification to approach optimal ammonia production and subsequent energy produced, in the ammonia synthesis heat recovery system for a 10MW(e...

S. Siddiq; S. Khushnood; Z. U. Koreshi

2013-09-01T23:59:59.000Z

139

Analytical Chemistry Applied Mathematics  

E-Print Network [OSTI]

Analytical Chemistry Applied Mathematics Architectural Engineering Architecture Architecture Electricity Markets Environmental Engineering Food Process Engineering Food Safety & Technology Architecture Information Technology & Management Integrated Building Delivery Landscape Architecture Management

Heller, Barbara

140

E-Print Network 3.0 - ammonia synthesis gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for ... Source: Australian National University, Department of Engineering, Solar Energy Program Collection: Renewable Energy ; Engineering 2 Solid State Ammonia Synthesis...

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing  

Broader source: Energy.gov [DOE]

SCR system provides direct ammonia gas dosing for optimal SCR performance with simplified and flexible exhaust layout.

142

Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators  

E-Print Network [OSTI]

Baseload Solar Power for California? Ammonia-based Solar Energy Storage Using Trough Concentrators to eventually optimise the reactor geometry for ammonia-based solar energy storage with troughs, which.1. Storing Solar Energy with Ammonia H2 / N2 gas liquid NH3 Heat Exchangers Power Generation (Steam Cycle

143

Removal of ammonia from contaminated air in a biotrickling filter Denitrifying bioreactor combination system  

E-Print Network [OSTI]

, and loadings below 56 g m?3 h?1 resulted in essentially complete removal of ammonia. In addition, concenRemoval of ammonia from contaminated air in a biotrickling filter ­ Denitrifying bioreactor Nitrification Denitrification a b s t r a c t The removal of gaseous ammonia in a system consisting

144

Evaluation of the potential for significant ammonia releases from Hanford waste tanks  

SciTech Connect (OSTI)

Ammonia is ubiquitous as a component of the waste stored in the Hanford Site single-shell tanks (SSTs) and double-shell tanks (DSTs). Because ammonia is both flammable and toxic, concerns have been raised about the amount of ammonia stored in the tanks and the possible mechanisms by which it could be released from the waste into the head space inside the tanks as well as into the surrounding atmosphere. Ammonia is a safety issue for three reasons. As already mentioned, ammonia is a flammable gas and may contribute to a flammability hazard either directly, if it reaches a high enough concentration in the tank head space, or by contributing to the flammability of other flammable gases such as hydrogen (LANL 1994). Ammonia is also toxic and at relatively low concentrations presents a hazard to human health. The level at which ammonia is considered Immediately Dangerous to Life or Health (IDLH) is 300 ppm (WHC 1993, 1995). Ammonia concentrations at or above this level have been measured inside the head space in a number of SSTs. Finally, unlike hydrogen and nitrous oxide, ammonia is highly soluble in aqueous solutions, and large amounts of ammonia can be stored in the waste as dissolved gas. Because of its high solubility, ammonia behaves in a qualitatively different manner from hydrogen or other insoluble gases. A broader range of scenarios must be considered in modeling ammonia storage and release.

Palmer, B.J.; Anderson, C.M.; Chen, G.; Cuta, J.M.; Ferryman, T.A.; Terrones, G.

1996-07-01T23:59:59.000Z

145

CHARLOTTE: BIG DATA & ANALYTICS  

E-Print Network [OSTI]

CHARLOTTE: BIG DATA & ANALYTICS #12;Charlotte: Big Data & Analytics charlottechamber.com2 Many Corp. Carolina Handling, LLC Carolina Legal Staffing, LLC Compass Group North America DiscoverReady LLC Leader: Allen Naidoo, Carolinas HealthCare System . . . . . . . . 10 Thought Leader: Kelly Ross, Lowe

Raja, Anita

146

Analytical Services Program  

Broader source: Energy.gov [DOE]

The Analytical Services Program (ASP) works to assure DOE managers, workers and the public that the data results acquired from analytical environmental laboratories are valid, reliable, defensible, and that treatment and disposal of DOE low-level radioactive and mixed waste is accomplished in accordance with all applicable regulations and in a manner protective of human health and the environment.

147

Transportable automated ammonia sensor based on a pulsed thermoelectrically cooled  

E-Print Network [OSTI]

Transportable automated ammonia sensor based on a pulsed thermoelectrically cooled quantum single-frequency, thermoelectrically cooled, pulsed quantum-cascade laser with an embedded distributed absorption spectroscopy with a pulsed QC DFB laser was reported in Ref. 3, where wavelength modulation

148

IR Vibration-Rotation Spectra of the Ammonia Molecule  

Science Journals Connector (OSTI)

The IR spectrum of the ammonia inversion vibration-rotation normal mode is obtained using Fourier Transform IR Spectroscopy and analyzed using Maple, to easily obatin the relation between the N-H bond length and the H-N-H bond angle. As expected, the ...

Carl W. David

1996-01-01T23:59:59.000Z

149

Ammonia-dimethylchloramine system: kinetic approach in an aqueous medium and comparison with the mechanism involving in liquid ammonia  

E-Print Network [OSTI]

-351" #12;2 The dimethylchloramine/ammonia interaction corresponds to a SN2 bimolecular mechanism (k4 = 0- methylmethanimine, 1,3,5-trimethylhexahydrotriazine, formaldehyde and methylamine. The kinetics of this reaction and chlorinated derivative. The reaction is of the second order and obeys an E2 mechanism (k1 = 4.2 ? 10-5 M-1 s-1

Paris-Sud XI, Université de

150

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas  

Science Journals Connector (OSTI)

Lewis Base Adduct Stabilized Organogallium Azides:? Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas ... Solvents were dried under argon according to standard methods; n-pentane and toluene were stored over Na/K alloy, and diethyl ether and thf over potassium benzophenoate (residual water solubility in other solvents than thf. ...

Alexander Miehr; Mike R. Mattner; Roland A. Fischer

1996-04-16T23:59:59.000Z

151

Field Analytical Chemistry  

Science Journals Connector (OSTI)

She has authored and coauthored 90 research articles, reviews, or book chapters and is active in the AOAC International as a General Referee for the Committee on Environmental Quality. ... Immediate analytical information on the level of success of a cleanup project can eliminate the need to return to a site to complete the cleanup after analytical data are finally returned from a traditional off-site laboratory. ... Two type of passive detectors were reported for the measurement of indoor radon (G3). ...

Viorica Lopez-Avila; Herbert H. Hill

1997-06-15T23:59:59.000Z

152

About Analytical Labs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LOOKING FOR THE RIGHT MIX IN ANALYTICAL SERVICES? LOOKING FOR THE RIGHT MIX IN ANALYTICAL SERVICES? Let's break it down. Analytical Laboratories at the SRS offers a wide-range of analytical capabilities; extensive and highly-specialized facilities; in-depth talent; and an unsurpassed record for providing our customers with the highest quality of service. We've served our nation for more than 50 years. Now, we're ready to provide those same services to you. Call us when you are looking for the right proportion of capabilities, facilities, talent and commitment to excellence. Our Facilities Analytical Laboratories at the SRS offers a wide-range of analytical capabilities; extensive and highly-specialized facilities; in-depth talent; and an unsurpassed record for providing our customers with the highest quality of service. We've served our nation for more than 50 years. Now, we're ready to provide those same services to you. Call us when you are looking for the right proportion of capabilities, facilities, talent and commitment to excellence.

153

An analytical investigation of the sideslip maneuver  

E-Print Network [OSTI]

. 1970 ABSTBACT An Analytical Investigation of the Sideslip Maneuver. (Augu. t 1970) John Mark Alvis, 8 . S . , Texas A&M College Directed by: Professor Alfred g. Crcnk An analytical study of a-high wing, single engine aircraft in a sideslip... maneuver is presented to determine the crosswind land- ing capabilities of light, single engine aircraft. Por the purpose of this study it is assumed that all aircraft of the same type studied have similar crosswind capabilities. A method is shown...

Alvis, John Mark

1970-01-01T23:59:59.000Z

154

Biodiesel Utilization: Update on Recent Analytical Techniques (Presentation)  

SciTech Connect (OSTI)

To understand and increase the use of biodiesel, analytical methods need to be shared and compared to ensure that accurate data are gathered on this complex fuel.

Alleman, T. L.; Fouts, L.; Luecke, J.; Thornton, M.; McAlpin, C.

2009-05-01T23:59:59.000Z

155

E-Print Network 3.0 - analytical magnetohydrostatic equilibria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

force free fields and analytic solutions are not generally available. We... based on an MHD relaxation method if both codes are applied to the reconstruction of a...

156

Control of catalytic hydrotreating selectivity with ammonia. Final technical report  

SciTech Connect (OSTI)

The purpose of this study was to explore the possibility of control of product selectivity in the hydroprocessing of coal liquids and related substances by adding small amounts of ammonia. Quinoline was used in this study and in many others as representative of heterocyclic N compounds found in coal liquids. Coal liquids also contain hydroxy pyridines, but by studies with 8-OH quinoline, a representative compound (Part I), we demonstrated that the OH group was rapidly removed at the beginning of reaction to form quinoline, which reacted in the same manner as quinoline fed as such. In Part II we showed that in a mixture of naphthalene and quinoline, with the addition of ammonia there is an operating region in which complete HDN of quinoline can be achieved, but with greater conversion of naphthalene to tetralin instead of to decalin than was the case in the absence of added ammonia. This is of some significance to coal liquefaction since tetralin is a good hydrogen donor, but decalin is not. In Part III we showed that NH{sub 3} addition to a mixture of quinoline and phenanthrene provides an operating region where complete HDN of quinoline can be achieved with reduced formation of hydrogenated phenanthrenes and cracking to biphenyl. Part IV, a study of the hydrodeoxygenation (DHO) of dibenzofuran in the presence of naphthalene, showed that NH{sub 3} strongly inhibits HDO reactions and its effects on naphthalene here were much the same as in Part II. In Part V it was demonstrated that in the hydrotreating of propylbenzene, the addition of ammonia increased the selectivity towards ring hydrogenation (generally desired for reformulated motor fuels) and away from dealkylation (generally undesired), but the overall reaction rate at a fixed temperature drops substantially.

Satterfield, C.N.; Lee, C.; Gultekin, S.

1993-11-01T23:59:59.000Z

157

Electron Spin Resonance in Metals and Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

Electron spin resonance measurements have been made at 300 Mc/sec on frozen metal ammonia solutions, liquid metal ammonia solutions, and liquid metals. The experiments on frozen solutions have shown that the metal is precipitated out in small particles. Nuclear resonance experiments have corroborated this finding. The frozen solutions are used as a convenient source of small particles, and observations have been made of relaxation times in Na, Li, K, and Cs. Resonances in the liquid ammonia solutions of Li, Na, K, Rb, Cs, and Ca, and also in a solution of Li in methylamine were observed. The data are consistent with the theoretical model of Kraus, Ogg, and Kaplan and Kittel. Bulk metal resonances were observed to temperatures above the melting points on lithium and sodium. The results for sodium corroborate the Elliott theory of relaxation, and the lithium results indicate resistivity-dependent relaxation time. No resonance was observed in bulk K, Rb, and Cs carried to temperatures above their melting points.

R. A. Levy

1956-04-01T23:59:59.000Z

158

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

E-Print Network [OSTI]

or natural gas or even oil shale (which represents anotherto transform the coal or oil shale or gaseous, fuel. There

Calvin, Melvin

2013-01-01T23:59:59.000Z

159

Supplementary Information Method for Analyte Identification Using  

E-Print Network [OSTI]

an example where 2-nitrophenol and 2,4,6-trichlorophenol are simultaneously detected using the fluorescent-nitrophenol and 2,4,6-trichlorophenol Below we present typical data showing m

Santiago, Juan G.

160

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

SciTech Connect (OSTI)

We have suggested that certain plants rich in hydrocarbon-like materials might be cultivated for renewable photosynthetic products. Two species were selected for experimental plantations: Euphorbia lathyris, an annual from seed and Euphorbia tirucalli, a perennial from cuttings, The yield from each species is over 10 barrels of oil/acre/year without genetic or agronomic improvement. In addition to plants, there are trees, such as species of Copaifera in Brazil and other tropical areas, which produce a diesel-like oil upon tapping. Each tree produces approximately 40 liters of hydrocarbon per year, and this material can be used directly by a diesel-powered car. Further efforts to develop plants as alternate energy sources are underway, as well as a continuing search for additional plant species throughout the world which have a similar capability.

Calvin, Melvin

1980-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Biomass treatment method  

DOE Patents [OSTI]

A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

Friend, Julie (Claymont, DE); Elander, Richard T. (Evergreen, CO); Tucker, III; Melvin P. (Lakewood, CO); Lyons, Robert C. (Arvada, CO)

2010-10-26T23:59:59.000Z

162

E-Print Network 3.0 - ammonia emission trends Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Satellite Observations of Tropospheric Ammonia Mark W.Shephard, Karen E. Cady-Pereira, Vivienne H.Payne Summary: differences likely driven by uncertainty in emissions...

163

E-Print Network 3.0 - acute ammonia challenge Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Asia (coastal China, Korea and Japan) and Western Europe - experienced most acutely... Germany and the UK were also the world's leading producers of ammonia recovered from coke...

164

E-Print Network 3.0 - ammonia emission rate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

season... catalyst systems. The ammonia emission rate is not a design criterion for automobile catalyst systems... Atmospheric Environment 37 (2003) ... Source: Aneja, Viney P. -...

165

Retention of anhydrous ammonia as influenced by clay mineral types, cations, temperature and moisture  

E-Print Network [OSTI]

to various temperature levels . . . . . ~ 20 5a 6. 70 Ammoni. a retained sxuressed as psr cent of cation-exchange capacity for olays treated with anhydrous ammonia prior to heating to various temperature levels . ~. . . . . . ~ ~ . 21 Ammonia retained... encountered in the use of anhydrous ammoni. . . REVIEW OF LITER4TURE Some of the early work with anhydx ous ammonia was done by anderson, et al. (2), and Enderson and Eattson (3). St that t1ms anhydrous ammonia as sn inorganic source of nitrogen fertiliaer...

McBee, George G

1956-01-01T23:59:59.000Z

166

E-Print Network 3.0 - ammonia negative ion Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AND INTERSTELLAR ICES Summary: recently, it has been shown that the impact of 252Cf fis- sion fragments on solid ammonia produced negative... dissociative ionization of the...

167

E-Print Network 3.0 - ammonia borane compound Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion and Utilization ; Renewable Energy 2 Borane-Ammonia Complexes...

168

E-Print Network 3.0 - ammonia fluxes obtained Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oak Ridge National Laboratory Fossil Energy Program Collection: Fossil Fuels 2 MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE...

169

E-Print Network 3.0 - ammonia oxidizing bacteria Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made of the generous search support... THE ALLOWABLE AMMONIA CONCENTRATIONS IN WASTEWATER TREATMENT PLANT DISCHARGE TO ... Source: Canberra, University of - Institute for...

170

E-Print Network 3.0 - ammonia-oxidizing bacterial communities...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

List Advanced Search Sample search results for: ammonia-oxidizing bacterial communities Page: << < 1 2 3 4 5 > >> 1 AQUATIC MICROBIAL ECOLOGY Aquat Microb Ecol Summary: AA...

171

Obligate autotrophy in the ammonia oxidizing bacterium Nitrosomonas europaea.  

SciTech Connect (OSTI)

Closing report for project DOE-FG02-03ER15436. The project studied obligate autotrophy in the ammonia oxidizing bacterium Nitrosomonas europaea. Nitrosomonas europaea can obtain all of its energy and reductant for growth from the oxidation of ammonia to nitrite and is, therefore, classified as a chemolithotroph. This bacterium is also an autotroph, which can derive all cellular carbon from carbon dioxide. N. europaea seems incapable of growth with other carbon or energy sources. This restricted capability is surprising given that ammonia is a poor energy source. The main goal of the project was to examine the basis of autotrophy in N. europaea or, thought of another way, to determine the barriers to heterotrophy. The approach was enabled by the N. europaea genome sequence, stimulating new ways of thinking about this physiological paradoxan insistence on a single, albeit poor, energy source. Objective 1 was to examine the expression and regulation of the genes coding for alpha-ketoglutarate dehydrogenase, determine if the enzymes activity is present, and determine whether alteration of the expression levels influences autotrophic growth. Although Nitrosomonas europaea lacks measurable alpha-ketoglutarate dehydrogenase activity, the genome sequence revealed the presence of the genes encoding the enzyme. A knockout mutation was created in the sucA gene encoding the E1 subunit. Compared to wild-type cells, the mutant strain showed an accelerated loss of ammonia monooxygenase and hydroxylamine oxidoreductase activities upon entering stationary phase. In addition, unlike wild-type cells, the mutant strain showed a marked lag in the ability to resume growth in response to pH adjustments in late stationary phase. The results were published in Hommes N.G., Kurth E. G., Sayavedra-Soto L.A., and Arp D.J. (2006) Disruption of sucA, which encodes a subunit of alpha-ketoglutarate dehydrogenase, affects the survival of Nitrosomonas europaea in stationary phase. Journal of Bacteriology 188:343-347. Objective 2 was to determine the basis of fructose stimulation of growth on ammonia, examine fructose metabolism, and determine the impact of other compounds on growth on ammonia. Previous studies showed that N. europaea can utilize limited amounts of certain organic compounds, including amino acids, pyruvate, and acetate, although no organic compound has been reported to support the growth of N. europaea. The genomic sequence of N. europaea revealed a potential permease for fructose. N. europaea utilized fructose and other compounds as carbon sources to support growth. Cultures were incubated in the presence of fructose or other organic compounds in sealed bottles purged of CO(2). In these cultures, addition of either fructose or pyruvate as the sole carbon source resulted in a two- to threefold increase in optical density and protein content in 3 to 4 days. Studies with [(14)C]fructose showed that >90% of the carbon incorporated by the cells during growth was derived from fructose. Cultures containing mannose, glucose, glycerol, mannitol, citrate, or acetate showed little or no growth. N. europaea was not able to grow with fructose as an energy source, although the presence of fructose did provide an energy benefit to the cells. These results show that N. europaea can be grown in carbon dioxide free medium by using fructose and pyruvate as carbon sources and may now be considered a facultative chemolithoorganotroph. The results were published in Hommes N.G., Sayavedra-Soto L.A. and Arp. D.J. (2003). Chemolithotrophic growth of Nitrosomonas europaea on fructose. Journal of Bacteriology. 185:6809-2773. Objective 3 attempted to grow N. europaea heterotrophically through pathways predicted by the genome. Experiments with mutant strains and complementation studies were performed to test whether N. europaea can utilize other carbon sources. N. europaea was not able to grow heterotrophically in the conditions tested in this objective.

Daniel James Arp; Luis Alberto Sayavedra-Soto

2006-01-01T23:59:59.000Z

172

Graphite Oxide/Polyoxometalate Nanocomposites as Adsorbents of Ammonia  

Science Journals Connector (OSTI)

Growing concerns about environmental problems lead researchers to look for efficient ways to adsorb various pollutants, as for instance ammonia. ... Since a good adsorbent for removal of toxic gases is characterized not only by the amount of gas adsorbed but also by the strength involved in its interactions with the pollutant gas, a reversible adsorption is obviously not a desired feature. ... The presence of water, either in the challenging gas or on the surface of the adsorbent, seems to have a different influence on the performance of the adsorbents. ...

Camille Petit; Teresa J. Bandosz

2009-02-06T23:59:59.000Z

173

Hanford analytical services quality assurance requirements documents  

SciTech Connect (OSTI)

Hanford Analytical Services Quality Assurance Requirements Document (HASQARD) is issued by the Analytical Services, Program of the Waste Management Division, US Department of Energy (US DOE), Richland Operations Office (DOE-RL). The HASQARD establishes quality requirements in response to DOE Order 5700.6C (DOE 1991b). The HASQARD is designed to meet the needs of DOE-RL for maintaining a consistent level of quality for sampling and field and laboratory analytical services provided by contractor and commercial field and laboratory analytical operations. The HASQARD serves as the quality basis for all sampling and field/laboratory analytical services provided to DOE-RL through the Analytical Services Program of the Waste Management Division in support of Hanford Site environmental cleanup efforts. This includes work performed by contractor and commercial laboratories and covers radiological and nonradiological analyses. The HASQARD applies to field sampling, field analysis, and research and development activities that support work conducted under the Hanford Federal Facility Agreement and Consent Order Tri-Party Agreement and regulatory permit applications and applicable permit requirements described in subsections of this volume. The HASQARD applies to work done to support process chemistry analysis (e.g., ongoing site waste treatment and characterization operations) and research and development projects related to Hanford Site environmental cleanup activities. This ensures a uniform quality umbrella to analytical site activities predicated on the concepts contained in the HASQARD. Using HASQARD will ensure data of known quality and technical defensibility of the methods used to obtain that data. The HASQARD is made up of four volumes: Volume 1, Administrative Requirements; Volume 2, Sampling Technical Requirements; Volume 3, Field Analytical Technical Requirements; and Volume 4, Laboratory Technical Requirements. Volume 1 describes the administrative requirements applicable to each of the other three volumes and is intended to be used in conjunction with the technical volumes.

Hyatt, J.E.

1997-09-25T23:59:59.000Z

174

Effects of Microbial Litter Amendments on Broiler Performance, Litter Quality and Ammonia Production  

E-Print Network [OSTI]

. Ammonia Production in Poultry Litter Ammonia has been and continues to be a major issue within the poultry industry. Not only does NH3 have effects on farm management, it also plays a role in poultry health, which will be discussed in following...

Hinkle, Matthew

2011-02-22T23:59:59.000Z

175

Ris-R-1504(EN) Safety assessment of ammonia as a  

E-Print Network [OSTI]

as part of the EU supported project "Ammonia Cracking for Clean Electric Power Technology" The study addresses the following activities: safety of operation of the ammonia-powered vehicle under normal.6 Comparison with methanol-powered vehicles 19 2.7 Comparison with hydrogen-powered vehicles 19 2.8 Comparison

176

Competition for Ammonia Influences the Structure of Chemotrophic1 Communities in Geothermal Springs2  

E-Print Network [OSTI]

Competition for Ammonia Influences the Structure of Chemotrophic1 Communities in Geothermal Springs in geothermal communities. These observations help to47 explain the strong pattern in the co-distribution of ammonia-oxidizing archaea and diazotrophs in48 circum-neutral to alkaline geothermal springs.49 50

de la Torre, José R.

177

Ammonia volatilization and nitrogen transformations in high pH soils used for beef manure disposal  

E-Print Network [OSTI]

RESEARCH INSTALLATION, EQUIPMENT, AND PROCEDURES Research Installation Equipment . Soil Water Equipment Redox Potential Equipment . . . . . . . . . . . . . , . , Laboratory Equipment Procedures Soil Column Installation Procedure Ammonia and Carbon... Dioxide Collection Procedure Redox Potential Measurement Procedure . . . . Irrigation and Soil Water Content Measurement Procedure . . . . . . . . . . . , , . . . . Sampling and Sample Handling and Storage Procedure . Ammonia and Carbon Dioxide...

Peters, Robert Edgar

2012-06-07T23:59:59.000Z

178

Analysis of a commercial absorption-refrigeration water-ammonia (ARWA) cycle using Aspen Plus simulator  

Science Journals Connector (OSTI)

The Robur absorption-refrigeration-water-ammonia (ARWA) cycle is analyzed using Aspen Plus flowsheet simulator. The results are compared with experimental and some manufacturer data reported in the open literature. Among performance parameters analyzed ... Keywords: Aspen, COP, absorption, ammonia, refrigeration, simulation, water

N. A. Darwish; S. H. Al-Hashimi; A. S. Al-Mansoori

2008-08-01T23:59:59.000Z

179

Analysis of Ammonia Loss Mechanisms in Microbial Fuel Cells Treating Animal Wastewater  

E-Print Network [OSTI]

ARTICLE Analysis of Ammonia Loss Mechanisms in Microbial Fuel Cells Treating Animal Wastewater Jung.interscience.wiley.com). DOI 10.1002/bit.21687 ABSTRACT: Ammonia losses during swine wastewater treatment were examined using manure; electricity; power generation Introduction Wastewater treatment using microbial fuel cells (MFCs

180

Process and apparatus for ammonia synthesis gas production  

SciTech Connect (OSTI)

An improved process is described for the production of ammonia synthesis gas which consists of: (a) catalytically reacting a hydrocarbon feed stream with steam in a primary reforming unit to form a primary reformed gas mixture containing hydrogen and carbon monoxide; (b) passing the primary reformed gas mixture to a secondary reforming unit for reaction of unconverted methane present therein with air, the amount of the air introduced to the secondary reforming unit being considerably in excess of that required to furnish the stoichiometric amount of nitrogen required for reaction with hydrogen for the ammonia synthesis; (c) subjecting the secondary reformed gas mixture to water gas shift conversion to convert most of the carbon monoxide present in the reformed gas mixture to hydrogen and carbon dioxide; (d) passing the thus-shifted gas mixture containing hydrogen, carbon dioxide, residual carbon monoxide, methane, argon and the excess nitrogen, without necessary treatment for removal of a major portion of the carbon dioxide content thereof and without methanation to remove carbon oxides to low levels, to a pressure swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from the hydrogen and from a portion of the nitrogen present in the gas passed to the system.

Fuderer, A.

1986-06-03T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery  

SciTech Connect (OSTI)

An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

2008-06-20T23:59:59.000Z

182

An ammonia refrigerator with an absorption circuit as economizer  

Science Journals Connector (OSTI)

The experimental results of a compression refrigerator with an integrated solution circuit, a so-called compression-absorption cycle, are presented. The compression refrigerator operates with ammonia (NH3) as refrigerant. The cycle is improved by two-stage throttling of the condensate and an absorption circuit which replaces the economizer compressor. The absorption circuit operates on the working pair ammonia/water (NH3/H2O). It is driven by superheat of the compressor without additional heat input from an external source. By this means the benefit of two-stage throttling, namely a reduction in compression work or an increase in refrigeration capacity, can be doubled. In the experiments an improvement of up to 9% in the efficiency of the NH3-refrigeration cycle has been attained. Compared to a simple compression refrigerator, the presented compression-absorption cycle has a payback time of only several months. Compared to a conventional economizer refrigeration cycle, the payback can be expected within the range of several months to about four years.

F Ziegler; U Spindler

1993-01-01T23:59:59.000Z

183

Ammonia and urea treatment of wheat straw and corn stover JP Fontenot E Gallo Llorente, JM Obamahinti, VG Allen  

E-Print Network [OSTI]

by ammoniation directly or by urea treatment, but the improvement appears to be greater for ammonia than urea

Boyer, Edmond

184

CRAIG G. FRASER"' LAGRANGE'S ANALYTICAL MATHEMATICS,  

E-Print Network [OSTI]

CRAIG G. FRASER"' LAGRANGE'S ANALYTICAL MATHEMATICS, ITS CARTESIAN ORIGINS AND RECEPTION IN COMTE to the mathematical methods developed in the preceding century by Euler and Lagrange. In the course of his discussion. . . . All his mathematical compositions are remarkable for a singular elegance, by the symmetry of forms

Fraser, Craig

185

Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)  

SciTech Connect (OSTI)

We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

2014-11-19T23:59:59.000Z

186

Method for Improving Mg Doping During Group-III Nitride MOCVD  

DOE Patents [OSTI]

A method for improving Mg doping of Group III-N materials grown by MOCVD preventing condensation in the gas phase or on reactor surfaces of adducts of magnesocene and ammonia by suitably heating reactor surfaces between the location of mixing of the magnesocene and ammonia reactants and the Group III-nitride surface whereon growth is to occur.

Creighton, J. Randall (Albuquerque, NM); Wang, George T. (Albuquerque, NM)

2008-11-11T23:59:59.000Z

187

Analytical Modeling | Open Energy Information  

Open Energy Info (EERE)

Analytical Modeling Analytical Modeling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Analytical Modeling Details Activities (1) Areas (1) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Data and Modeling Techniques Exploration Sub Group: Modeling Techniques Parent Exploration Technique: Modeling Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Analytical Modeling: A mathematical modeling technique used for simulating, explaining, and making predictions about the mechanisms involved in complex physical processes. Other definitions:Wikipedia Reegle Introduction Analytical models are mathematical models that have a closed form solution. Or in other words the solution to the equations used to describe changes in

188

Welcome to Analytical Labs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nuclear Material Dissolution from Destructive Analysis Measurements Nuclear Material Dissolution from Destructive Analysis Measurements Overview The Savannah River Site F/H Laboratories perform nuclear material dissolution of Pu/U oxides and metals plus Np oxide to support site productions/remediation projects. Nuclear material dissolutions are performed in glovebox containment via microwaves, hot blocks and hot plates. Resulting solutions are aliquotted for a variety of elemental and compound analyses. Features Varying sample size (100 mg - 30 g) High temperature digestions up to 200°C computer-controlled temperature and pressure dissolutions Excellent analyte recovery in destructive analysis Commercially-available electronic equipment with trained operators capable of handling high alpha activity levels (facility source term limit of 310 Alpha Curies)

189

PIA - Industrial Hygiene Analytical System (IHAS) | Department...  

Broader source: Energy.gov (indexed) [DOE]

Hygiene Analytical System (IHAS) PIA - Industrial Hygiene Analytical System (IHAS) PIA - Industrial Hygiene Analytical System (IHAS) More Documents & Publications PIA - INL...

190

Phase-Transfer Catalysis in Analytical Chemistry  

Science Journals Connector (OSTI)

In analytical chemistry, analytes must sometimes be reacted with derivatizing reagents to facilitate analysis. Derivatization is needed when the analytes, without modification, cannot be easily separated using...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

191

Formation of hydroxylamine on dust grains via ammonia oxidation  

E-Print Network [OSTI]

The quest to detect prebiotic molecules in space, notably amino acids, requires an understanding of the chemistry involving nitrogen atoms. Hydroxylamine (NH$_2$OH) is considered a precursor to the amino acid glycine. Although not yet detected, NH$_2$OH is considered a likely target of detection with ALMA. We report on an experimental investigation of the formation of hydroxylamine on an amorphous silicate surface via the oxidation of ammonia. The experimental data are then fed into a simulation of the formation of NH$_2$OH in dense cloud conditions. On ices at 14 K and with a modest activation energy barrier, NH$_2$OH is found to be formed with an abundance that never falls below a factor 10 with respect to NH$_3$. Suggestions of conditions for future observations are provided.

He, Jiao; Lemaire, Jean-Louis; Garrod, Robin T

2015-01-01T23:59:59.000Z

192

Materials corrosion in ammonia/solid heat pump working media  

SciTech Connect (OSTI)

Salt/ammonia complexes will undergo thermal cycles during use as working media for heat pumps. The interaction between container materials and complexes under thermal cyclic conditions was assessed to screen possible containment materials. Aluminum alloys 3003, 1100, and 6063 and carbon steel A214 were tested against possible heat pump working media SrCl{sub 2}/NH{sub 3}, CaBr{sub 2}/NH{sub 3}, and CaCl{sub 2}/NH{sub 3}. None of the containment materials showed susceptibility to stress corrosion cracking. While all the materials demonstrated excellent general corrosion resistance to SrCl{sub 2}/NH{sub 3}, only A214 displayed good general corrosion resistance to CaCl{sub 2}/NH{sub 3}. The complex CaBr{sub 2}/NH{sub 3} was found to be subject to thermal cyclic instability and should not be used as a heat pump working medium.

Wilson, D.F.; Howell, M.; DeVan, J.H.

1992-01-01T23:59:59.000Z

193

Studies of the Ammonia-soluble Organic Matter of the Soil.  

E-Print Network [OSTI]

to represent the - decomposed organic matter of the soil, and, therefore, if the theory cited above is correct, the more valuable organic matter. The.relation between the hvo forms of organic matter is largely a matter of color; while the ammonia does nct... oxtract all the organic matter from the soil, it does extract prad,ically all the black organic matter, leaving the soil residue near]? white. The organic matter of the soil soluble in ammonia is termed humus in America. The fact that the ammonia...

Fraps, G. S. (George Stronach); Hamner, N.C.

1910-01-01T23:59:59.000Z

194

Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration  

E-Print Network [OSTI]

Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration of Geological Carbon Sequestration Article Type: Manuscript Keywords: Semi-Analytical Modeling; Iterative Methods; Geological Carbon Sequestration; Injection Site Assessment Corresponding Author: Brent Cody

Bau, Domenico A.

195

Analytical Chemistry Core Capability Assessment - Preliminary Report  

SciTech Connect (OSTI)

The concept of 'core capability' can be nebulous one. Even at a fairly specific level, where core capability equals maintaining essential services, it is highly dependent upon the perspective of the requestor. Samples are submitted to analytical services because the requesters do not have the capability to conduct adequate analyses themselves. Some requests are for general chemical information in support of R and D, process control, or process improvement. Many analyses, however, are part of a product certification package and must comply with higher-level customer quality assurance requirements. So which services are essential to that customer - just those for product certification? Does the customer also (indirectly) need services that support process control and improvement? And what is the timeframe? Capability is often expressed in terms of the currently utilized procedures, and most programmatic customers can only plan a few years out, at best. But should core capability consider the long term where new technologies, aging facilities, and personnel replacements must be considered? These questions, and a multitude of others, explain why attempts to gain long-term consensus on the definition of core capability have consistently failed. This preliminary report will not try to define core capability for any specific program or set of programs. Instead, it will try to address the underlying concerns that drive the desire to determine core capability. Essentially, programmatic customers want to be able to call upon analytical chemistry services to provide all the assays they need, and they don't want to pay for analytical chemistry services they don't currently use (or use infrequently). This report will focus on explaining how the current analytical capabilities and methods evolved to serve a variety of needs with a focus on why some analytes have multiple analytical techniques, and what determines the infrastructure for these analyses. This information will be useful in defining a roadmap for what future capability needs to look like.

Barr, Mary E. [Los Alamos National Laboratory; Farish, Thomas J. [Los Alamos National Laboratory

2012-05-16T23:59:59.000Z

196

Analytical Chemistry Laboratory progress report for FY 1985  

SciTech Connect (OSTI)

The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of technical support services to the scientific and engineering programs at ANL. In addition, ACL conducts a research program in analytical chemistry, works on instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems, from routine standard analyses to unique problems that require significant development of methods and techniques. The purpose of this report is to summarize the technical and administrative activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year 1985 (October 1984 through September 1985). This is the second annual report for the ACL. 4 figs., 1 tab.

Green, D.W.; Heinrich, R.R.; Jensen, K.J.

1985-12-01T23:59:59.000Z

197

Analytical modeling of contaminant transport and horizontal well hydraulics  

E-Print Network [OSTI]

transport from one-, two-, and three-dimensional finite sources in a finite-thickness aquifer using Green's function method. A library of unpublished analytical solutions with different finite source geometry is provided. A graphically integrated software...

Park, Eungyu

2004-09-30T23:59:59.000Z

198

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI...  

Broader source: Energy.gov (indexed) [DOE]

Catalyst Design for Urea-less Passive Ammonia SCR Lean-Burn SIDI Aftertreatment System Chang H. Kim, Kevin Perry, Wei Li, Kushal Narayanaswamy, and Michael Viola Global Research &...

199

Computer simulation and economic analysis for ammonia fiber explosion (AFEX) pretreatment process  

E-Print Network [OSTI]

simulation and cost analysis. In this study, a steady state computer simulation package was developed for the AFEX process. Corn fiber was used as the representative biomass treated by AFEX. Different ammonia loadings, water loadings, temperatures...

Wang, Lin

2012-06-07T23:59:59.000Z

200

Terra Nitrogen Company, L.P.: Ammonia Plant Greatly Reduces Natural Gas Consumption After Energy Assessment  

Broader source: Energy.gov [DOE]

This case study describes how Terra Nitrogen Company saved 497,000 MMBtu and $3.5 million yearly after upgrading the steam system in its ammonia plant in Verdigris, Oklahoma.

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Hydrogen production from the reaction of solvated electrons with benzene in water-ammonia mixtures  

SciTech Connect (OSTI)

Product analysis data for the reaction of the ammoniated electron with benzene-water mixtures in liquid ammonia show that the dominant product is evolved hydrogen and not 1,4-cyclohexadiene.

Dewald, R.R.; Jones, S.R.; Schwartz, B.S.

1980-11-27T23:59:59.000Z

202

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents [OSTI]

Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C.J.; Mackenzie, P.D.

1982-09-03T23:59:59.000Z

203

Process for removal of ammonia and acid gases from contaminated waters  

DOE Patents [OSTI]

Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

1985-01-01T23:59:59.000Z

204

Carbon Capture by a Continuous, Regenerative Ammonia-Based Scrubbing Process  

SciTech Connect (OSTI)

Overview: To develop a knowledge/data base to determine whether an ammonia-based scrubbing process is a viable regenerable-capture technique that can simultaneously remove carbon dioxide, sulfur dioxide, nitric oxides, and trace pollutants from flue gas.

Resnik, K.P.; Yeh, J.T.; Pennline, H.W.

2006-10-01T23:59:59.000Z

205

E-Print Network 3.0 - agricultural ammonia emission Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Division Ir Lid., 1998 Summary: THE ALLOWABLE AMMONIA CONCENTRATIONS IN WASTEWATER TREATMENT PLANT DISCHARGE TO ENSURE PROTECl'ION OF AQUATIC... Box4395QQ.Melbourne VA3(XX)...

206

Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product  

DOE Patents [OSTI]

Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

Davis, Benjamin L; Rekken, Brian D

2014-04-01T23:59:59.000Z

207

High-pressure storage of hydrogen fuel: ammonia borane and its related compounds  

Science Journals Connector (OSTI)

As a promising candidate material for hydrogen storage, ammonia borane (NH3BH3) has attracted significant interest in recent years due to its remarkably high hydrogen content. Subjecting this material to high pre...

Yu Lin; Wendy L. Mao

2014-09-01T23:59:59.000Z

208

Analytical laboratory quality audits  

SciTech Connect (OSTI)

Analytical Laboratory Quality Audits are designed to improve laboratory performance. The success of the audit, as for many activities, is based on adequate preparation, precise performance, well documented and insightful reporting, and productive follow-up. Adequate preparation starts with definition of the purpose, scope, and authority for the audit and the primary standards against which the laboratory quality program will be tested. The scope and technical processes involved lead to determining the needed audit team resources. Contact is made with the auditee and a formal audit plan is developed, approved and sent to the auditee laboratory management. Review of the auditee's quality manual, key procedures and historical information during preparation leads to better checklist development and more efficient and effective use of the limited time for data gathering during the audit itself. The audit begins with the opening meeting that sets the stage for the interactions between the audit team and the laboratory staff. Arrangements are worked out for the necessary interviews and examination of processes and records. The information developed during the audit is recorded on the checklists. Laboratory management is kept informed of issues during the audit so there are no surprises at the closing meeting. The audit report documents whether the management control systems are effective. In addition to findings of nonconformance, positive reinforcement of exemplary practices provides balance and fairness. Audit closure begins with receipt and evaluation of proposed corrective actions from the nonconformances identified in the audit report. After corrective actions are accepted, their implementation is verified. Upon closure of the corrective actions, the audit is officially closed.

Kelley, William D.

2001-06-11T23:59:59.000Z

209

Ammonia inhalation toxicity in cats: a study of acute and chronic respiratory dysfunction  

E-Print Network [OSTI]

AMMONIA INHALATION TOXICITY IN CATS A STUDY OF ACUTE AND CHRONIC RESPIRATORY DYSFUNCTION A Thesis by KENNETH TRAVIS DODD Submitted to the Graduate College of Texas A)M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1978 Major Subject: Veterinary Physiology AMMONIA INHALATION TOXICITY IN CATS A STUDY OF ACUTE AND CHRONIC RESPIRATORY DYSFUNCTION A Thesis by KENNETH TRAVIS DODD Approved as to style and content by: (Chairman...

Dodd, Kenneth Travis

2012-06-07T23:59:59.000Z

210

The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes  

E-Print Network [OSTI]

THE CATALETIC REDUCTION OF NITRIC OXIDE NITH AMMONIA OVER TETRARPMINECOPPER(11) COMPLEXES A Thesis by Margaret Deron Oates Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1979 Major Subject: Chemistry THE CATALYTIC REDUCTION OF NITRIC OXIDE WITH AMMONIA OVER TETRAAMMINECOPPER(IZ) COMPLEXES A Thesis by Margaret Deron Dates Approved as to style and content by: (Chairman of Committe (Member...

Oates, Margaret Deron

1979-01-01T23:59:59.000Z

211

Insulator-based DEP with impedance measurements for analyte detection  

DOE Patents [OSTI]

Disclosed herein are microfluidic devices for assaying at least one analyte specie in a sample comprising at least one analyte concentration area in a microchannel having insulating structures on or in at least one wall of the microchannel which provide a nonuniform electric field in the presence of an electric field provided by off-chip electrodes; and a pair of passivated sensing electrodes for impedance detection in a detection area. Also disclosed are assay methods and methods of making.

Davalos, Rafael V. (Blacksburg, VA); Simmons, Blake A. (San Francisco, CA); Crocker, Robert W. (Fremont, CA); Cummings, Eric B. (Livermore, CA)

2010-03-16T23:59:59.000Z

212

Welcome to Analytical Labs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METHODS OF INTEREST METHODS OF INTEREST Microwave/hot block digestion of solids Alpha spectroscopy Gamma spectroscopy (fixed and portable) Neutron and gamma ray measurements Gas proportional counting Gas chromatography Liquid scintillation counting Uranium and plutonium concentration and isotopic abundance by thermal ionization mass spectrometry Low mass, high resolution gas analysis by mass spectrometry Metallic impurities by inductively coupled plasma emission spectrometry and mass spectrometry Anion analysis by ion selective electrode and ion chromatography Wet chemistry analysis: pH, conductivity, density, turbidity, acid/base titrations Mercury analysis Carbon analysis Low-level uranium analysis by kinetic phosphorescence Volatile organics by gas chromatography with mass spectrometer detector/GC-MS

213

Rotational dynamics in ammonia borane: Evidence of strong isotope effects  

SciTech Connect (OSTI)

This work reports anelastic spectroscopy measurements on the partially deuterated (ND3BH3 and NH3BD3) and perdeuterated (ND3BD3) ammonia borane (NH3BH3) compounds. The relaxations previously reported in NH3BH3 are observed in all the samples, and are ascribed to the rotational and torsional dynamics of NH(D)3BH(D)3 complexes. A new thermally activated peak appears at 70 K (for a vibration frequency of 1 kHz) in the spectrum of NH3BD3 and ND3BD3. The peak is practically a single-time Debye process, indicating absence of interaction between the relaxing units, and has a strikingly high intensity. A secondary relaxation process is also detected around 55 K. The anelastic spectrum of the ND3BH3 only displays this less intense process at 55 K. The analysis of the peaks supplies information about the dynamics of the relaxing species, and the obtained results provide indications on the effect of partial and selective deuteration on the hydrogen (deuterium) dynamics.

Cantelli, Rosario; Paolone, Annalisa; Palumbo, Oriele; Leardini, F.; Autrey, Thomas; Karkamkar, Abhijeet J.; Luedtke, Avery T.

2013-12-15T23:59:59.000Z

214

Absolute measurements of nitric acid by kilometer pathlength FT-IR (Fourier transform infrared) spectroscopy and their intercomparison with other measurement methods. Final report  

SciTech Connect (OSTI)

Measurements of ambient nitric acid (HNO/sub 3/) and ammonia (NH/sub 3/) concentrations were conducted using a Fourier transform infrared (FT-IR) spectrometer interfaced to an open-path, multiple-reflection optical system. These measurements provided benchmark data for gaseous HNO/sub 3/ and NH/sub 3/ during a field study, held at Claremont, California, September 11-19, 1985, which compared current analytical methods for determining nitrogenous species concentrations in the atmosphere. Hourly average concentrations of HNO/sub 3/ and NH/sub 3/ are reported, along with the calculated average concentrations for the sampling periods designated for the majority of the other measurement methods.

Winer, A.M.; Tuazon, E.C.; Biermann, H.W.; Wallington, T.J.

1986-05-01T23:59:59.000Z

215

Welcome to Analytical Labs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methods Methods Unique Capabilities Thermal Ion Thermal Ionization Mass Spectrometry The distribution of isotopes within uranium and plutonium materials, are precisely and accurately measured using Thermal Ionization Mass Spectrometers (TIMS). In addition to isotopic abundance measurements, isotope dilution techniques are applied to measure uranium and plutonium concentration on a wide variety of materials processed at the SRS. Rad Nuclear Nuclear Material Dissolution from Destructive Analysis Measurements The Savannah River Site F/H Laboratories perform nuclear material dissolution of Pu/U oxides and metals plus Np oxide to support site productions/remediation projects. Nuclear material dissolutions are performed in glovebox containment via microwaves, hot blocks and hot plates. Resulting solutions are aliquotted for a variety of elemental and compound analyses.

216

Process Analytical Chemistry  

Science Journals Connector (OSTI)

Internet sites for infrared and near-infrared spectrometry are given by Kraemer and Lodder, including on-line instruction and direct communication (D230). ... Special configurations are described for the target analyses of actinides (G67, G68), surface contaminants (G69), and drugs of abuse (G70). ... Young and co-workers describe an iterative method for differentiating between known resonances and uncharacterized baseline contributions in magnetic resonance spectra using wavelet shrinkage and denoising (H187). ...

Jerome Workman, Jr.; David J. Veltkamp; Steve Doherty; Brian B. Anderson; Ken E. Creasy; Mel Koch; James F. Tatera; Alex L. Robinson; Leonard Bond; Lloyd W. Burgess; Gary N. Bokerman; Alan H. Ullman; Gary P. Darsey; Foad Mozayeni; Judith Ann Bamberger; Margaret Stautberg Greenwood

1999-05-01T23:59:59.000Z

217

ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH Al\rD SAFETY DlVlSlON  

Office of Legacy Management (LM)

em IVIL, u-3 em IVIL, u-3 1' 1L, I -' I ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH Al\rD SAFETY DlVlSlON 1956 1. H.# fL22 Industrial Hygiene or Medical Dept. Sample Nor& 3 Date Collected- 5117 by --Route to CES CES r Location IQJKER-PEMJNS Co- Type of Sample-waternalyzed for F Alpha Remarks -&I GG -- u - Beta Samples of water discharged to river during Steam clean- No, Ra ing of equipment. Oil PH Be Th Sample No. Hour Sample Description (RT Please analyze for gm/U/gal. BP-1 P- RO-Kneader BP-2 K- N-Kneader BP-3 Omera Feeder - __-- .___ -- i ___- ------I - 1 I . ----.--- - ------ .-___ _- I I - 3" - 1 ' : i ' Nt! w-d Analytical Chemistry Section: - Date Received 5-21-56 bY %b. Date Reported 5-2 Z-56 by&b. Method of Analysis Fluorimeter

218

An investigation of some of the effects of anhydrous ammonia on the clay minerals montmorillonite and illite  

E-Print Network [OSTI]

with various dominant ions on the exchange complex. 2. The effect of heat in an atmosphere of steam on the (001) spacing of montmorillonite saturated with various ions and treated with anhydrous ammonia. 3. The effect of drying at 110?C. for 24. hours... on the (001) spacing of montmorillonite saturated with various dominant ions and treated with anhydrous ammonia? 4.. The effect of relative humidity and anhydrous ammonia on the (001) spacing of illite with various dominant ions on the exchange complex...

Whiteley, Eli Lamar

2013-10-04T23:59:59.000Z

219

Method for reducing nitrogen oxides in combustion effluents  

DOE Patents [OSTI]

Method for reducing nitrogen oxides (NO.sub.x) in the gas stream from the combustion of fossil fuels is disclosed. In a narrow gas temperature zone, NO.sub.x is converted to nitrogen by reaction with urea or ammonia with negligible remaining ammonia and other reaction pollutants. Specially designed injectors are used to introduce air atomized water droplets containing dissolved urea or ammonia into the gaseous combustion products in a manner that widely disperses the droplets exclusively in the optimum reaction temperature zone. The injector operates in a manner that forms droplet of a size that results in their vaporization exclusively in this optimum NO.sub.x -urea/ammonia reaction temperature zone. Also disclosed is a design of a system to effectively accomplish this injection.

Zauderer, Bert (Merion Station, PA)

2000-01-01T23:59:59.000Z

220

Bearing Analytics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bearing Analytics Bearing Analytics National Clean Energy Business Plan Competition 2013 355 likes Bearing Analytics Purdue University Avoidable bearing failures cost the US industrial economy $50B in damage and downtime every year. Current bearing health monitoring systems do not adequately detect failure until it is too late. Bearing Analytics offers a patent-pending micro-sensor technology that monitors temperature and vibration directly on the bearing cage helping predict performance degradation and impending failure while improving operating, performance, and energy efficiencies. Our technology does all of that with a better accuracy, faster response time, and increased reliability over any other competing solution today. We intend to target the wind turbine industry as our initial target point

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Bearing Analytics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bearing Analytics Bearing Analytics National Clean Energy Business Plan Competition 2013 355 likes Bearing Analytics Purdue University Avoidable bearing failures cost the US industrial economy $50B in damage and downtime every year. Current bearing health monitoring systems do not adequately detect failure until it is too late. Bearing Analytics offers a patent-pending micro-sensor technology that monitors temperature and vibration directly on the bearing cage helping predict performance degradation and impending failure while improving operating, performance, and energy efficiencies. Our technology does all of that with a better accuracy, faster response time, and increased reliability over any other competing solution today. We intend to target the wind turbine industry as our initial target point

222

Bearing Analytics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bearing Analytics Bearing Analytics National Clean Energy Business Plan Competition 2013 355 likes Bearing Analytics Purdue University Avoidable bearing failures cost the US industrial economy $50B in damage and downtime every year. Current bearing health monitoring systems do not adequately detect failure until it is too late. Bearing Analytics offers a patent-pending micro-sensor technology that monitors temperature and vibration directly on the bearing cage helping predict performance degradation and impending failure while improving operating, performance, and energy efficiencies. Our technology does all of that with a better accuracy, faster response time, and increased reliability over any other competing solution today. We intend to target the wind turbine industry as our initial target point

223

Electrospray ion source with reduced analyte electrochemistry  

DOE Patents [OSTI]

An electrospray ion (ESI) source and method capable of ionizing an analyte molecule without oxidizing or reducing the analyte of interest. The ESI source can include an emitter having a liquid conduit, a working electrode having a liquid contacting surface, a spray tip, a secondary working electrode, and a charge storage coating covering partially or fully the liquid contacting surface of the working electrode. The liquid conduit, the working electrode and the secondary working electrode can be in liquid communication. The electrospray ion source can also include a counter electrode proximate to, but separated from, said spray tip. The electrospray ion source can also include a power system for applying a voltage difference between the working electrodes and a counter-electrode. The power system can deliver pulsed voltage changes to the working electrodes during operation of said electrospray ion source to minimize the surface potential of the charge storage coating.

Kertesz, Vilmos; Van Berkel, Gary J

2013-07-30T23:59:59.000Z

224

Analytical Chemistry Laboratory, progress report for FY 1993  

SciTech Connect (OSTI)

The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1993 (October 1992 through September 1993). This annual report is the tenth for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has research programs in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require development or modification of methods and adaption of techniques to obtain useful analytical data. The ACL is administratively within the Chemical Technology Division (CMT), its principal ANL client, but provides technical support for many of the technical divisions and programs at ANL. The ACL has four technical groups--Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis--which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL.

Not Available

1993-12-01T23:59:59.000Z

225

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect (OSTI)

Work completed in this reporting period focused primarily on continuing measurements of the rate of ammonia loss from concrete, and the measurement of ammonia gas in the air above concrete and flowable fill immediately after placement. Concrete slabs were prepared to monitor the loss of ammonia during mixing, the concentration in the airspace above the slabs soon after placement, and the total quantity of ammonia evolved over a longer time period. Variables tested include temperature, ventilation rate, water:cementitious (W:C) ratio, and fly ash source. Short-term data indicate that for concrete placed in areas with poor air ventilation the fly ash NH{sub 3} concentration should not exceed about 90 to 145 mg/kg ash, depending on the water:cement ratio and the fly ash replacement rate, if a concentration of 10 ppm NH{sub 3} in the air is assumed to be the maximum acceptable level. Longer-term experiments showed that the ammonia loss rate is dependent on ammonia source (that is ammoniated ash vs. non-ammoniated ash with ammonia added to the water), and is also dependent on W:C ratio and temperature. Experiments were also conducted to study the loss of ammonia from fresh concrete during mixing. It was found that a high water:cementitious mix lost a greater percentage of ammonia than a low W:C mix, with a medium W:C mix losing an amount intermediate between these two. However, a larger batch size resulted in a smaller percentage of ammonia lost. The data suggest that a significant quantity of ammonia could be lost from Ready Mix concrete during transit, depending on the transit time, batch size, and mix proportions.

Robert F. Rathbone; Thomas L. Robl

2002-04-11T23:59:59.000Z

226

Portable apparatus for separating sample and detecting target analytes  

DOE Patents [OSTI]

Portable devices and methods for determining the presence of a target analyte using a portable device are provided. The portable device is preferably hand-held. A sample is injected to the portable device. A microfluidic separation is performed within the portable device and at least one separated component detected by a detection module within the portable device, in embodiments of the invention. A target analyte is identified, based on the separated component, and the presence of the target analyte is indicated on an output interface of the portable device, in accordance with embodiments of the invention.

Renzi, Ronald F. (Tracy, CA); Wally, Karl (Lafayette, CA); Crocker, Robert W. (Fremont, CA); Stamps, James F. (Livermore, CA); Griffiths; Stewart K. , (Livermore, CA); Fruetel, Julia A. (Livermore, CA); Horn, Brent A. (Roy, UT); Shokair, Isaac R. (Livermore, CA); Yee, Daniel D. (Dublin, CA); VanderNoot, Victoria A. (Pleasanton, CA); Wiedenman, Boyd J. (Aiken, SC); West, Jason A. A. (Pleasanton, CA); Ferko, Scott M. (Livermore, CA)

2008-11-18T23:59:59.000Z

227

Sludge processors have wide choice of solutions for waste ammonia problems  

SciTech Connect (OSTI)

The Ocean Dumping Act of 1988 phased out dumping of sewage sludge into the ocean. To use sewage sludge beneficially, facilities treat and process it using such techniques as digestion, dewatering, composting, thermal drying and chemical stabilization. All of these processes create waste discharges containing high concentrations of nitrogen, mainly in the form of ammonia. When nitrification occurs in receiving waters, ammonia is oxidized to nitrate and can lower dissolved oxygen levels in the water. Excess ammonia also is toxic to fish and other aquatic life. Nitrogen reduction alternatives for sludge dewatering and processing waste discharges include the following: air stripping; steam stripping; breakpoint chlorination; selective ion exchange; reverse osmosis; and chemical precipitation. To remove wastewater nitrogen using biological processes, ammonia and organic nitrogen first are oxidized aerobically (nitrification) to nitrate nitrogen, which then is converted biologically to nitrogen gas (denitrification) under zero or low dissolved oxygen (anoxic) conditions. Because sludge treatment discharges contain valuable quantities of ammonia, they may be considered for reuse as supplemental fertilizer for land application or for reclamation through spraying or injection into soil. Such discharges also may be used in combustion processes.

Chen, Y.S.R.; Samela, D. (Stone and Webster Engineering Corp., Boston, MA (United States). Environmental Technology and Services Div.); Kaylor, F.

1994-09-01T23:59:59.000Z

228

Ultrasonic analyte concentration and application in flow cytometry  

DOE Patents [OSTI]

The present invention includes an apparatus and corresponding method for concentrating analytes within a fluid flowing through a tube using acoustic radiation pressure. The apparatus includes a function generator that outputs a radio frequency electrical signal to a transducer that transforms the radio frequency electric signal to an acoustic signal and couples the acoustic signal to the tube. The acoustic signal is converted within the tube to acoustic pressure that concentrates the analytes within the fluid.

Kaduchak, Gregory; Goddard, Greg; Salzman, Gary; Sinha, Dipen; Martin, John C.; Kwiatkowski, Christopher; Graves, Steven

2014-07-22T23:59:59.000Z

229

Ultrasonic analyte concentration and application in flow cytometry  

DOE Patents [OSTI]

The present invention includes an apparatus and corresponding method for concentrating analytes within a fluid flowing through a tube using acoustic radiation pressure. The apparatus includes a function generator that outputs a radio frequency electrical signal to a transducer that transforms the radio frequency electric signal to an acoustic signal and couples the acoustic signal to the tube. The acoustic signal is converted within the tube to acoustic pressure that concentrates the analytes within the fluid.

Kaduchak, Gregory (Los Alamos, NM); Goddard, Greg (Los Alamos, NM); Salzman, Gary (White Rock, NM); Sinha, Dipen (Los Alamos, NM); Martin, John C. (Los Alamos, NM); Kwiatkowski, Christopher (Los Alamos, NM); Graves, Steven (San Juan Pueblo, NM)

2008-03-11T23:59:59.000Z

230

Triangulating empirical and analytic techniques for improving number entry user interfaces  

Science Journals Connector (OSTI)

Empirical methods and analytic methods have been used independently to analyse and improve number entry system designs. This paper identifies key differences in exploring number entry errors combining laboratory studies and analytic methods and discusses ... Keywords: differential formal analysis, empirical trials, medical devices, number entry

Abigail Cauchi, Patrick Oladimeji, Gerrit Niezen, Harry Thimbleby

2014-06-01T23:59:59.000Z

231

Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part II. Recovery of Ammonia from Sour Waters  

SciTech Connect (OSTI)

Two novel regenerated solvent extraction processes are examined. The first process has the potential to reduce the energy costs inherent in the recovery of low-volatility carboxylic acids from dilute aqueous solutions. The second process has the potential for reducing the energy costs required for separate recovery of ammonia and acid gases (e.g. CO{sub 2} and H{sub 2}S) from industrial sour waters. The recovery of carboxylic acids from dilute aqueous solution can be achieved by extraction with tertiary amines. An approach for regeneration and product recovery from such extracts is to back-extract the carboxylic acid with a water-soluble, volatile tertiary amine, such as trimethylamine. The resulting trimethylammonium carboxylate solution can be concentrated and thermally decomposed, yielding the product acid and the volatile amine for recycle. Experimental work was performed with lactic acid, SUCCiOlC acid, and fumaric acid. Equilibrium data show near-stoichiometric recovery of the carboxylic acids from an organic solution of Alamine 336 into aqueous solutions of trimethylamine. For fumaric and succinic acids, partial evaporation of the aqueous back extract decomposes the carboxylate and yields the acid product in crystalline form. The decomposition of aqueous solutions of trimethylammonium lactates was not carried out to completion, due to the high water solubility of lactic acid and the tendency of the acid to self-associate. The separate recovery of ammonia and acid gases from sour waters can be achieved by combining steam-stripping of the acid gases with simultaneous removal of ammonia by extraction with a liquid cation exchanger. The use of di-2,4,4-trimethylpentyl phosphinic acid as the liquid cation exchanger is explored in this work. Batch extraction experiments were carried out to measure the equilibrium distribution ratio of ammonia between an aqueous buffer solution and an organic solution of the phosphinic acid (0.2N) in Norpar 12. The concentration-based distribution ratios increase from 0.11 to 0.46 as the aqueous phase pH increases from 7.18 to 8.15. Regeneration of the organic extractant solution was carried out by stripping at elevated temperatures to remove the ammonia, with 99% recovery of the ammonia being obtained at 125 C.

Poole, L.J.; King, C.J.

1990-03-01T23:59:59.000Z

232

Use of ammonia to reduce the viscosity of bottoms streams produced in hydroconversion processes  

DOE Patents [OSTI]

Coal, petroleum residuum and similar carbonaceous feed materials are subjected to hydroconversion in the presence of molecular hydrogen to produce a hydroconversion effluent which is then subjected to one or more separation steps to remove lower molecular weight liquids and produce a heavy bottoms stream containing high molecular weight liquids and unconverted carbonaceous material. The viscosity of the bottoms streams produced in the separation step or steps is prevented from increasing rapidly by treating the feed to the separation step or steps with ammonia gas prior to or during the separation step or steps. The viscosity of the heavy bottoms stream produced in the final separation step is also controlled by treating these bottoms with ammonia gas. In a preferred embodiment of the invention, the effluent from the hydroconversion reactor is subjected to an atmospheric distillation followed by a vacuum distillation and the feeds to these distillations are contacted with ammonia during the distillations.

Zaczepinski, Sioma (Houston, TX); Billimoria, Rustom M. (Houston, TX); Tao, Frank (Baytown, TX); Lington, Christopher G. (Houston, TX); Plumlee, Karl W. (Baytown, TX)

1984-01-01T23:59:59.000Z

233

Analytical Dashboards | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Reporting » Analytical Dashboards Reporting » Analytical Dashboards Analytical Dashboards Public Final Occurrence Reports: Searchable information on DOE's Final Occurrence Reports since 2009, available to the public and updated daily. Computerized Accident Incident Reporting System (CAIRS) - Injury and Illness Dashboard: The Injury and Illness Dashboard is a tool that allows users to easily explore DOE occupational safety and health injury and illness information. Its features include: Graphical and tabular depictions of injury and illness information Calendar year and fiscal year incidence rates for DOE and DOE contractor total recordable cases (TRC) of injuries and illnesses and cases involving days away from work or on job transfer or restriction (DART) due to injury or illness Incidence rates of injuries and illnesses by DOE program

234

Ecologic Analytics | Open Energy Information  

Open Energy Info (EERE)

Ecologic Analytics Ecologic Analytics Jump to: navigation, search Name Ecologic Analytics Place Bloomington, Minnesota Zip 55425 Product Minnesota-based meter data management company. Coordinates 42.883574°, -90.926122° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":42.883574,"lon":-90.926122,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

235

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect (OSTI)

The Clean Air Act Amendments of 1990 require large reductions in emissions of NO{sub x} from coal-fired electric utility boilers. This will necessitate the use of ammonia injection, such as in selective catalytic reduction (SCR), in many power plants, resulting in the deposition of ammonia on the fly ash. The presence of ammonia could create a major barrier to fly ash utilization in concrete because of odor concerns. Although there have been limited studies of ammonia emission from concrete, little is known about the quantity of ammonia emitted during mixing and curing, and the kinetics of ammonia release. This is manifested as widely varying opinions within the concrete and ash marketing industry regarding the maximum acceptable levels of ammonia in fly ash. Therefore, practical guidelines for using ammoniated fly ash are needed in advance of the installation of many more SCR systems. The goal of this project was to develop practical guidelines for the handling and utilization of ammoniated fly ash in concrete, in order to prevent a decrease in the use of fly ash for this application. The objective was to determine the amount of ammonia that is released, over the short- and long-term, from concrete that contains ammoniated fly ash. The technical approach in this project was to measure the release of ammonia from mortar and concrete during mixing, placement, and curing. Work initially focused on laboratory mortar experiments to develop fundamental data on ammonia diffusion characteristics. Larger-scale laboratory experiments were then conducted to study the emission of ammonia from concrete containing ammoniated fly ash. The final phase comprised monitoring ammonia emissions from large concrete slabs. The data indicated that, on average, 15% of the initial ammonia was lost from concrete during 40 minutes of mixing, depending on the mix proportions and batch size. Long-term experiments indicated that ammonia diffusion from concrete was relatively slow, with greater than 50% of the initial ammonia content remaining in an 11cm thick concrete slab after 1 month. When placing concrete in an enclosed space, with negligible ventilation, it is recommended that the ammonia concentration in the concrete mix water should not exceed 110 mg NH{sub 3}/L, if the NIOSH exposure limit of 25 ppm in the air is not to be exceeded. If even a modicum of ventilation is present, then the ammonia concentration in the concrete water should be less than 170 mg/L. The maximum level of ammonia in the fly ash can then be calculated using these limits if the concrete mix proportions are known. In general, during the mixing and placement of ammonia-laden concrete, no safety concerns were encountered. The only location where the ammonia concentration attained high levels (i.e. > 25 ppm in the air) was within the concrete mixing drum.

Robert F. Rathbone; Thomas L. Robl

2002-10-30T23:59:59.000Z

236

Analytic Independent Particle Model for Molecules  

Science Journals Connector (OSTI)

Solutions to the Schrdinger equation for an electron in an analytic spheroidal potential are considered. The analysis is carried out in the prolate spheroidal coordinate system resulting in a simple second-order differential equation which is solved numerically by the Cowell-Numerov method. Computations are presented for models of nitrogen and oxygen molecules. The energy levels can be brought into reasonable accord with experimental Rydberg levels by the adjustment of the two parameters of the spheroidal potential. The results of this study represent an interesting tutorial example of a realistic quantum mechanical problem.

J. E. Whalen; A. E. S. Green

1972-01-01T23:59:59.000Z

237

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst surface  

E-Print Network [OSTI]

A quantum chemical study of nitric oxide reduction by ammonia (SCR reaction) on V2O5 catalyst for the selective catalytic reduction (SCR) of nitric oxide by ammonia on (0 1 0) V2O5 surface represented by a V2O9/6-31G** level. The computations indicated that SCR reaction consisted of three main parts

Senkan, Selim M.

238

Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a  

E-Print Network [OSTI]

to the surface properties and the adsorption reactions of titanium dioxide-anatase surface. Lin and Bai [3 reserved. Keywords: TiO2; Anatase; Adsorption; Water; Ammonia; DFT 1. Introduction Titanium oxides are usedAdsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim

Senkan, Selim M.

239

Appendix C Analytical Chemistry Data  

Office of Legacy Management (LM)

Analytical Chemistry Data This page intentionally left blank Contents Section Analytical Data for Deleted Contaminants of Concern ............................................................. C1.O Mol~tezuma Creek Hardness Dat Surface Water Copper Data Summa ................ CI-9 Surface Water Radium-228 Dat Surface Water Radon-222 Data Summary ....................... ....................................... . . . . . . . . . . . C l - I 2 Alluvial Ground Water Aln~noniuu~ as Nitrogen Data Summary ....................... . . . ................................ Cl-15 Alluvial Ground Water Cobalt Data Summary ........... Alluvial Ground Water Copper Data Sumrl Alluvial Ground Water Lead Data Su~nmary ................................. C1-19 Alluvial Ground Water Lead-210 Data Sutl~rnary

240

Analytical Chemistry Laboratory Progress Report for FY 1994  

SciTech Connect (OSTI)

The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1994 (October 1993 through September 1994). This annual report is the eleventh for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has a research program in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. The ACL has four technical groups -- Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis -- which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL. The Chemical Analysis Group uses wet- chemical and instrumental methods for elemental, compositional, and isotopic determinations in solid, liquid, and gaseous samples and provides specialized analytical services. Major instruments in this group include an ion chromatograph (IC), an inductively coupled plasma/atomic emission spectrometer (ICP/AES), spectrophotometers, mass spectrometers (including gas-analysis and thermal-ionization mass spectrometers), emission spectrographs, autotitrators, sulfur and carbon determinators, and a kinetic phosphorescence uranium analyzer.

Green, D.W.; Boparai, A.S.; Bowers, D.L. [and others

1994-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The effect of dietary protein and fiber on in vivo ammonia concentration  

E-Print Network [OSTI]

protein level, ten animals received a basal fiber-free diet, ten received the same diet diluted with 8X cellulose, and ten received the basal diet diluted with BX pectin. Cecal total ammonia (NH + NH ) concentration was highest 4 in the fiber-free high... protein and the cellulose high protein-fed rats. The proximal colon ammonia concentration was greatest in the fiber-free high protein treatment group, and the pectin-fed rats had a significantly greater concentration than the cellulose groups...

Marchant, Linda Jean

1986-01-01T23:59:59.000Z

242

A STUDY OF THE EFFECTS OF POST-COMBUSTION AMMONIA INJECTION ON FLY ASH QUALITY: CHARACTERIZATION OF AMMONIA RELEASE FROM CONCRETE AND MORTARS CONTAINING FLY ASH AS A POZZOLANIC ADMIXTURE  

SciTech Connect (OSTI)

Work completed in this reporting period focused on the measurement of the rate of ammonia loss from mortar and concrete, and the measurement of ammonia gas in the air above the materials immediately after placement. The majority of mortar experiments have been completed, and testing has begun on concrete. The mortar experiments indicate that the rate of ammonia loss is greater in mortars prepared using a higher water content and water:cement (W:C) ratio, although the higher rate is primarily observed within the first 2 days, after which the loss rates are nearly the same. The source of low-calcium (Class F) fly ash exerted a negligible influence on the loss rate. However, mortar prepared using a higher-calcium fly ash evolved ammonia at a slightly slower rate than the Class F ash mortars. The data also indicate that an increase in ventilation increases the ammonia loss rate from mortar, and suggest that a well-ventilated space could substantially increase the loss of ammonia from mortar and, by inference, a concrete slab. Analysis of ammonia concentrations in the air above freshly-placed mortars in an enclosed space indicate that the fly ash ammonia concentration should not exceed 100 mg N/kg ash in confined space applications. For most other applications with some ventilation the maximum acceptable concentration would be approximately 200 mg/kg. Early results from experiments on concrete suggest that, under similar conditions, ammonia diffusion from concrete occurs at a higher rate than in mortar. In addition, increasing the slump of concrete through the use of chemical admixtures has only a minor effect on the ammonia loss rate.

Robert F. Rathbone; Thomas L. Robl

2001-10-11T23:59:59.000Z

243

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network [OSTI]

energy conversion (OTEC) systems, where plant ships could then bring the ammonia to shore as an energy carrier (

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

244

Online Marketing Analytics Spring 2009  

E-Print Network [OSTI]

- 1 - Online Marketing Analytics Syllabus Spring 2009 #12;- 2 - Course Description: The practice of marketing is changing. Due to increasing desktop computing power and companies amassing massive amounts of data, marketing decisions made by companies are becoming more and more data based. This holds in many

Jank, Wolfgang

245

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania  

E-Print Network [OSTI]

International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

Kentucky, University of

246

Analytical Modeling At Coso Geothermal Area (1980) | Open Energy  

Open Energy Info (EERE)

Modeling At Coso Geothermal Area (1980) Modeling At Coso Geothermal Area (1980) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Analytical Modeling At Coso Geothermal Area (1980) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Analytical Modeling Activity Date 1980 Usefulness not indicated DOE-funding Unknown Exploration Basis 1) Characterize a magma source. 2) To conduct reservoir modeling of a steam reservoir. Notes 1) Closed-form analytical solutions for the conduction heat transfer from various idealized magma geometries (dikes, sills, and spheres) are obtained using either the Schwarz-Christoffel transformation theorem (dikes and sills) or the 'method of images' with superposition (spheres). Comparison of these analytically determined heat flux distributions with

247

Analytical Plan for Roman Glasses  

SciTech Connect (OSTI)

Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent experiment that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

2011-01-01T23:59:59.000Z

248

Metal-nonmetal transition in metal-ammonia solutions  

Science Journals Connector (OSTI)

In this paper we present a coherent physical picture of the metal-nonmetal transition in metal-ammonia solutions in the intermediate concentration range. We propose that in Li-NH3 and Na-NH3 solutions the metallic propagation regime is separated from a nonmetallic regime by a microscopically inhomogeneous regime in which the concentration fluctuates locally about either of two well-defined values M0 and M1, M0>M1, the local concentration remaining near M0 or M1 over radii approximately equal to the Debye short correlation length b for concentration fluctuations. Provided that the concentration-fluctuation decay length is much smaller than b, we can define a percolation problem in which a volume fraction C of the material is occupied by metallic regions of concentration M0, the remainder containing the low concentration M1 of dissociated electron-cation complexes. M0 and M1 constitute the upper and the lower bounds of the inhomogeneous regime, respectively, while C exhibits a linear dependence on M. This physical picture is borne out by concentration-fluctuation determinations based on chemical-potential measurements in Li and Na solutions and by small-angle x-ray and neutron scattering in Li solutions. Assuming that the phase-coherence length of the conduction electrons is shorter than b and having demonstrated that tunneling corrections are negligible, we can define local electronic structure and transport properties. The limits of the inhomogeneous regime were determined from a combination of concentration-fluctuation measurements, electrical conductivity, Hall effect, and paramagnetic susceptibility data to be M0=9 mole percent metal (MPM) and M1=2(13) MPM, which yield the C scale, C=[M-2(13)]6(23), for both Li-NH3 at 223K and for Na-NH3 at 240K. We have also established the consistency of our picture with the available magnetic data for Na solutions. An analysis of the electronic and the thermal transport properties was carried out in terms of an effective-medium theory, modified to account for scattering from the boundaries of the metallic clusters. For low values of the conductivity ratio (? 10-3) between the nonmetallic and the metallic regions the modified effective-medium theory is valid for C>0.4. In an attempt to mimic the features of continuous percolation, we have carried out numerical simulations of the conductivity in a simple cubic lattice incorporating correlation between metallic bonds. An excellent fit of the experimental conductivity data for Li and Na with the results of the numerical simulations has been obtained over a three order of magnitude variation of the conductivity throughout the entire inhomogeneous regime. A small systematic negative deviation of the conductivity from the predictions of the effective-medium theory for C>0.4 can be properly accounted for in terms of boundary scattering corrections resulting in b?15 for Li at 223K and b?32 for Na at 240K. The overall agreement of the experimental Hall effect, Hall mobility, thermalconductivity, and thermoelectric-power data with the effective-medium theory is good. The proposed inhomogeneous regime in Li and Na solutions resembles a macroscopic mixed phase at a concentration inside a coexistence curve but with mixing on a microscopic scale. The concentration fluctuations in the inhomogeneous state have nothing to do with critical fluctuations; nevertheless, this state seems to be closely associated with the occurrence of a phase separation.

Joshua Jortner and Morrel H. Cohen

1976-02-15T23:59:59.000Z

249

Midinfrared interferometry on spectral lines: III. Ammonia and Silane around IRC +10216 and VY CMa  

E-Print Network [OSTI]

J. D. Monnier 1 , W. C. Danchi 2 , D. S. Hale, P. G. Tuthill 3 , C. H. Townes Space Sciences beyond both the dust formation and gas acceleration zones. Specifically, ammonia was found to form before silane in a region of decaying gas turbulence ( ? ¸ 20 R ? ), while the silane is produced in a region

Monnier, John D.

250

Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs  

E-Print Network [OSTI]

Competition for Ammonia Influences the Structure of Chemotrophic Communities in Geothermal Springs of organisms capable of ni- trogen fixation in geothermal communities. These observations help to explain-to-alkaline geothermal springs. All life requires fixed sources of nitrogen (N), and its availabil- ity often limits

Ahmad, Sajjad

251

MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE  

E-Print Network [OSTI]

- izers, emission from soils, biomass burning, and domestic animal waste (Bouwman et al., 1997MEASUREMENT AND MODELLING OF AMMONIA EMISSIONS AT WASTE TREATMENT LAGOON-ATMOSPHERIC INTERFACE animals ( 32 Tg N -1yr-1). Waste storage and treatment lagoons are used to treat the excreta of hogs

Aneja, Viney P.

252

Rapid Ammonia Gas Transport Accounts for Futile Transmembrane Cycling under NH3/NH4  

E-Print Network [OSTI]

Rapid Ammonia Gas Transport Accounts for Futile Transmembrane Cycling under NH3/NH4 + Toxicity) seedlings is predominately of the gaseous NH3 species, rather than the NH4 + ion. Influx of 13 NH3/13 NH4 + , which exceeded 200 mmol g­1 h­1 , was not commensurate with membrane depolarization or increases in root

Britto, Dev T.

253

Solar absorption aqua-ammonia absorption system simulation base on climate of Malaysia  

Science Journals Connector (OSTI)

Solar energy is one of the most well known green sources of energy. This research presents a feasibility study of evacuated solar thermal collector by aqua-ammonia ejector absorption systems as a small scale air conditioning unit. The modeling has been ... Keywords: ejector, evacuated tubes, solar assisted absorption system

Poorya Ooshaksaraei; Sohif Mat; M. Yahya; Ahmad Mahir Razali; Azami Zaharim; K. Sopian

2010-01-01T23:59:59.000Z

254

Complete Genome Sequence of the Marine, Chemolithoautotrophic, Ammonia-Oxidizing Bacterium Nitrosococcus oceani ATCC 19707  

Science Journals Connector (OSTI)

...hypothetical genes; pale green, structural RNAs...electron acceptors (green). The two inner circles...their involvement in energy metabolism (ATP, pmf...Springer Science and Business Media, Inc., New York...oxidation of ammonia as an energy source in bacteria in...

Martin G. Klotz; Daniel J. Arp; Patrick S. G. Chain; Amal F. El-Sheikh; Loren J. Hauser; Norman G. Hommes; Frank W. Larimer; Stephanie A. Malfatti; Jeanette M. Norton; Amisha T. Poret-Peterson; Lisa M. Vergez; Bess B. Ward

2006-09-01T23:59:59.000Z

255

mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the  

E-Print Network [OSTI]

mARUS37, 207--213 (1979) Ammonia Photolysisand the Greenhouse Effect in the Primordial Atmosphere mixing ratio of am- monia of 10-5 or greater would provide a sufficient greenhouse effect to keep of longwave radiation NH3 could pro- duce a substantial "greenhouse effect" and maintain a surface temperature

Atreya, Sushil

256

Sky coverage of orbital detectors. Analytical approach  

E-Print Network [OSTI]

Orbital detectors without pointing capability have to keep their field of view axis laying on their orbital plane, to observe the largest sky fraction. A general approach to estimate the exposure of each sky element for such detectors is a valuable tool in the R&D phase of a project, when the detector characteristics are still to be fixed. An analytical method to estimate the sky exposure is developed, which makes only few very reasonable approximations. The formulae obtained with this method are used to compute the histogram of the sky exposure of a hypothetical gamma-ray detector installed on the ISS. The C++ code used in this example is freely available on the http://cern.ch/casadei/software.html web page.

Diego Casadei

2005-11-23T23:59:59.000Z

257

Analyte detection using an active assay  

DOE Patents [OSTI]

Analytes using an active assay may be detected by introducing an analyte solution containing a plurality of analytes to a lacquered membrane. The lacquered membrane may be a membrane having at least one surface treated with a layer of polymers. The lacquered membrane may be semi-permeable to nonanalytes. The layer of polymers may include cross-linked polymers. A plurality of probe molecules may be arrayed and immobilized on the lacquered membrane. An external force may be applied to the analyte solution to move the analytes towards the lacquered membrane. Movement may cause some or all of the analytes to bind to the lacquered membrane. In cases where probe molecules are presented, some or all of the analytes may bind to probe molecules. The direction of the external force may be reversed to remove unbound or weakly bound analytes. Bound analytes may be detected using known detection types.

Morozov, Victor (Manassas, VA); Bailey, Charles L. (Cross Junction, VA); Evanskey, Melissa R. (Potomac Falls, VA)

2010-11-02T23:59:59.000Z

258

Energy Analytics | Open Energy Information  

Open Energy Info (EERE)

Energy Analytics Energy Analytics Place Brewster, New York Product New York-based energy management and curtailment company. Coordinates 48.099675°, -119.78091° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":48.099675,"lon":-119.78091,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

259

Complete genome sequence of Nitrosomonas sp. Is79, an ammonia oxidizing bacterium adapted to low ammonium concentrations  

SciTech Connect (OSTI)

Nitrosomonas sp. Is79 is a chemolithoautotrophic ammonia-oxidizing bacterium that belongs to the family Nitrosomonadaceae within the phylum Proteobacteria. Ammonia oxidation is the first step of nitrification, an important process in the global nitrogen cycle ultimately resulting in the production of nitrate. Nitrosomonas sp. Is79 is an ammonia oxidizer of high interest because it is adapted to low ammonium and can be found in freshwater environments around the world. The 3,783,444-bp chromosome with a total of 3,553 protein coding genes and 44 RNA genes was sequenced by the DOE-Joint Genome Institute Program CSP 2006.

Bollmann, Annette [Miami University, Oxford, OH; Sedlacek, Christopher J [Miami University, Oxford, OH; Laanbroek, Hendrikus J [Netherlands Institute of Ecology (NIOO-KNAW); Suwa, Yuichi [Chuo University, Tokyo, Japan; Stein, Lisa Y [University of California, Riverside; Klotz, Martin G [University of Louisville, Louisville; Arp, D J [Oregon State University; Sayavedra-Soto, LA [Oregon State University; Lu, Megan [Los Alamos National Laboratory (LANL); Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Han, James [U.S. Department of Energy, Joint Genome Institute; Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Pennacchio, Len [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Huntemann, Marcel [U.S. Department of Energy, Joint Genome Institute; Deshpande, Shweta [U.S. Department of Energy, Joint Genome Institute; Han, Cliff [Los Alamos National Laboratory (LANL); Chen, Amy [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Mavromatis, K [U.S. Department of Energy, Joint Genome Institute; Markowitz, Victor [U.S. Department of Energy, Joint Genome Institute; Szeto, Ernest [U.S. Department of Energy, Joint Genome Institute; Ivanova, N [U.S. Department of Energy, Joint Genome Institute; Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Pagani, Ioanna [U.S. Department of Energy, Joint Genome Institute; Pati, Amrita [U.S. Department of Energy, Joint Genome Institute; Peters, Lin [U.S. Department of Energy, Joint Genome Institute; Ovchinnikova, Galina [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL)

2013-01-01T23:59:59.000Z

260

Solar fuels and chemicals system design study (ammonia/nitric acid production process). Volume 2. Conceptual design. Final report  

SciTech Connect (OSTI)

As part of the Solar Central Receiver Fuels and Chemicals Program, Foster Wheeler Solar Development Corporation (FWSDC), under contract to Sandia National Laboratories-Livermore (SNLL), developed a conceptual design of a facility to produce ammonia and nitric acid using solar energy as the principal external source of process heat. In the selected process, ammonia is produced in an endothermic reaction within a steam methane (natural gas) reformer. The heat of reaction is provided by molten carbonate salt heated by both a solar central receiver and an exothermic ammonia-fired heater. After absorption by water, the product of the latter reaction is nitric acid.

Not Available

1986-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT.  

Office of Legacy Management (LM)

NATIONAL LEAD COMPANY OF OHIO NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET 1. H. NO. INDUSTRIAL HYGIENE AND RADIATION DEPT. ANALYTICAL CHEMISTRY SECT10 AMPLE NOS.: - ROUTE TO1 7 c, U NO:, Oil Bo Cl Beta METHOD OC ANALYSIS: Ro r/fae*3 r4tSAAQ. 5 PH DYI Th TSS COVNTINO DATA1 -BKGD .31=/cr, b EO w% SAMPLE I HOUR SAMPLE DESCRIPTION NO. DlSTRlBUTlON OF COPIES 1 Analytical Loboratory (RECORD COPI) 2 lndurtrlal Hygiene CI, Radlatlon Dept. 2 Water freatmnt Plant (Fw Wehr Samples Only) NLD-n&s-736 IREV.10/1v/60~ NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET INDUSTRIAL HYGIENE AND RADIATION DEPT. ANALYTICAL CHEMISTRY SECT10 BATE RILCEIVPDI InYr I OUNTINC DATA1 IKGD - 14x1, GE0

262

Ocean thermal plantships for production of ammonia as the hydrogen carrier.  

SciTech Connect (OSTI)

Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solar energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.

Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.; Energy Systems; Johns Hopkins Univ.; Arctic Energies, Ltd.

2009-12-02T23:59:59.000Z

263

Multipass optical device and process for gas and analyte determination  

DOE Patents [OSTI]

A torus multipass optical device and method are described that provide for trace level determination of gases and gas-phase analytes. The torus device includes an optical cavity defined by at least one ring mirror. The mirror delivers optical power in at least a radial and axial direction and propagates light in a multipass optical path of a predefined path length.

Bernacki, Bruce E. (Kennewick, WA)

2011-01-25T23:59:59.000Z

264

Jorg Waldvogel, ETH Zurich 1 Computing Integrals of Analytic Functions  

E-Print Network [OSTI]

J¨org Waldvogel, ETH Z¨urich 1 Computing Integrals of Analytic Functions: A Universal Algorithm with Exponential Convergence J¨org Waldvogel, ETH Z¨urich Applied Mathematics ETH Z¨urich New Methods for Quadrature Third Scopes Meeting Z¨urich, December 9, 2006 #12;J¨org Waldvogel, ETH Z¨urich 2 The Problem

Waldvogel, Jörg

265

Digital Control Computers In Analytical Chemistry  

Science Journals Connector (OSTI)

Digital Control Computers In Analytical Chemistry ... Time-Sharing Minicomputer Data Acquisition-Processing System ... Automation of organic elemental analysis ...

Jack W. Frazer

1968-07-01T23:59:59.000Z

266

Global distributions, time series and error characterization of atmospheric ammonia (NH[subscript 3]) from IASI satellite observations  

E-Print Network [OSTI]

Ammonia (NH[subscript 3]) emissions in the atmosphere have increased substantially over the past decades, largely because of intensive livestock production and use of fertilizers. As a short-lived species, NH[subscript 3] ...

Van Damme, M.

267

Oxygen sorption and thermal regeneration of sorption centers on catalysts of ammonia synthesis in helium and hydrogen flow  

Science Journals Connector (OSTI)

The interaction of oxygen with catalysts for ammonia synthesis in helium and hydrogen flow has been studied. Various catalysts sorb from 7 to 12 oxygen layers. 2 to 4 layers can be removed by thermal activatio...

A. V. Krylova; V. V. Morozov; S. S. Lachinov

268

Some remarks on the radius of spatial analyticity for the Euler equations  

E-Print Network [OSTI]

We consider the Euler equations on $\\mathbb{T}^d$ with analytic data and prove lower bounds for the radius of spatial analyticity $\\epsilon(t)$ of the solution using a new method based on inductive estimates in standard Sobolev spaces. Our results are consistent with similar previous results proved by Kukavica and Vicol, but give a more precise dependence of $\\epsilon(t)$ on the radius of analyticity of the initial datum.

Marco Cappiello; Fabio Nicola

2014-04-24T23:59:59.000Z

269

Analytical description for field-line wandering in strong magnetic turbulence  

Science Journals Connector (OSTI)

We investigate analytically the random walk of magnetic field lines. In previous analytical treatments of field line wandering or random walk, it was assumed that the turbulent magnetic field is much weaker than the mean field. In the present paper, we develop an improved analytical method to describe the stochastic properties of turbulent magnetic fields. This approach is an extension of the standard theory of field line wandering and can be applied to weak as well as to strong magnetic turbulence.

A. Shalchi; J. A. le Roux; G. M. Webb; G. P. Zank

2009-12-31T23:59:59.000Z

270

Estimation of ammonia volatilization from surface-applied urea as indicated by bermudagrass N-use efficiency  

E-Print Network [OSTI]

ESTIMATION OF AMMONIA VOLATILIZATION FROM SURFACE-APPLIED UREA AS INDICATED BY BERMUDAGRASS N-USE EFFICIENCY A Thesis by JOHN MATTHEW DRWAL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1986 Major Subject: Soil Science ESTIMATION OF AMMONIA VOLATILIZATION FROM SURFACE-APPLIED UREA AS INDICATED BY BERMUDAGRASS N-USE EFFICIENCY A Thesis by JOHN MATTHEW DRWAL Approved as to style and content by...

Drwal, John Matthew

2012-06-07T23:59:59.000Z

271

Process for treating ammonia and nitrite containing waters to prevent nitric oxide emissions therefrom  

SciTech Connect (OSTI)

This patent describes a process for controlling the emission of nitrogen dioxide from, and the amount of one or more organisms, selected from the group consisting of fungi, algae and bacteria, growing in a system for handling a flow of condensate of steam, the condensate containing ammonia, ammonia precursors, or a mixture thereof. It comprises contacting the condensate in a substantially continuous manner with an amount of an oxidizing biocide which substantially prevents the emission of nitrogen dioxide from the condensate handling system but which does not substantially inhibit the growth of the organisms in the condensate handling system; and periodically contacting the condensate with an amount of a second biocide which substantially reduces the amount of the organisms.

Gallup, D.L.; Featherstone, J.L.

1991-07-16T23:59:59.000Z

272

Excimer laser photochemistry of silane-ammonia mixtures at 193 nm  

SciTech Connect (OSTI)

The ArF excimer laser induced photochemistry of silane-ammonia mixtures has been studied with molecular beam sampling mass spectrometry. The observed products include disilane, trisilane, and all possible aminosilanes, SiH{sub x}(NH{sub 2}){sub 4-x}, x = 0-3. These products are formed under steady-state photolysis conditions and under single-laser-pulse conditions. A mechanism for the formation of these species is proposed and quantitatively evaluated.

Beach, D.B.; Jasinski, J.M. (Thomas J. Watson Research Center, Yorktown Heights, NY (USA))

1990-04-05T23:59:59.000Z

273

Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies  

E-Print Network [OSTI]

biomass into available and /or soluble sugars and organic acids (i. e. uronic acid esters etc. ). The chemical linkages between hemicellulose and lignin may be affected by ammoniation pre-treatment. The significance of this fact is that heavily cross... by Turner et al (1995) demonstrated a significant increase in the available energy and crude protein of NH3 treated maize. Ammoniation of rice straw (Pradhan et al, 1997) bound residual ammonia to fiber and yielded an increase in the level of crude...

Williams, James Jason

1999-01-01T23:59:59.000Z

274

Toxicity of ammonia to larvae of the freshwater shrimp, Macrobrachium rosenbergii  

E-Print Network [OSTI]

to larval and juvenile shrimps (Armstrong et al. , 1976; Wickins, 1976) and to fish (Russo et al. , 1974", Smith and Williams, 1974", Smith and Russo' 1975; Crawford and Allen, 1977; Thurston et al. , 1978; Wedemeyer and Yasutake, 1978) and can.... Although the toxicity of ammonia to freshwater shrimp larvae has been reported by Armstrong et al. (1978), other aspects require further investigation before a reliable estimate of safe concentrations can be esta'blished. This study, which examines...

Llobrera, Jose Alvarez

1979-01-01T23:59:59.000Z

275

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia  

DOE Patents [OSTI]

Noxious nitrogen oxides in a waste gas stream such as the stack gas from a fossil-fuel-fired power generation plant or other industrial plant off-gas stream is catalytically reduced to elemental nitrogen and/or innocuous nitrogen oxides employing ammonia as reductant in the presence of a zeolite catalyst in the hydrogen or sodium form having pore openings of about 3 to 10 A.

Pence, Dallas T. (Idaho Falls, ID); Thomas, Thomas R. (Idaho Falls, ID)

1980-01-01T23:59:59.000Z

276

Retail refrigeration systems -- The use of ammonia and two-level secondary refrigeration  

SciTech Connect (OSTI)

The concept of a secondary refrigeration system for high-temperature use as investigated in 1991, and a design for a full high-temperature system was completed the following year. In late 1992, a supermarket chain commissioned a study of the feasibility of turning the design into a practical application and assisted the project in 1993 by commissioning a test facility for single-temperature secondary refrigeration at one of the company`s factory sites. Results and conclusions from this trial work pointed toward the need for a total secondary refrigeration system, including a low-temperature system for frozen food display cases, and the possibility of utilizing environmentally friendly ammonia as the primary refrigerant. Therefore, in late 1993/early 1994, a low-temperature system was developed and commissioned at the test facility. Full collaboration between the supermarket company and the contractor resulted in the funding of practical trial work and feasibility studies for both secondary refrigeration and a fully detailed proposal for the use of ammonia in a public retail environment. In May 1995, the first UK ammonia and two-level secondary refrigeration system began operation in a supermarket in Horsham, Sussex England.

Thomas, A.S. [Westward Refrigeration, Gloucester (United Kingdom)

1998-10-01T23:59:59.000Z

277

INVESTIGATION OF AMMONIA ADSORPTION ON FLY ASH DUE TO INSTALLATION OF SELECTIVE CATALYTIC REDUCTION SYSTEMS  

SciTech Connect (OSTI)

This report summarizes an investigation of the potential impacts associated with the utilization of selective catalytic reduction (SCR) systems at coal-fired power plants. The study was sponsored by the U.S. Department of Energy Emission Control By-Products Consortium, Dominion Generation, the University of Kentucky Center for Applied Energy Research and GAI Consultants, Inc. SCR systems are effective in reducing nitrogen oxides (NOx) emissions as required by the Clean Air Act (CAA) Amendments. However, there may be potential consequences associated with ammonia contamination of stack emissions and combustion by-products from these systems. Costs for air quality, landfill and pond environmental compliance may increase significantly and the marketability of ash may be seriously reduced, which, in turn, may also lead to increased disposal costs. The potential impacts to air, surface water, groundwater, ash disposal, ash utilization, health and safety, and environmental compliance can not be easily quantified based on the information presently available. The investigation included: (1) a review of information and data available from published and unpublished sources; (2) baseline ash characterization testing of ash samples produced from several central Appalachian high-volatile bituminous coals from plants that do not currently employ SCR systems in order to characterize the ash prior to ammonia exposure; (3) an investigation of ammonia release from fly ash, including leaching and thermal studies; and (4) an evaluation of the potential impacts on plant equipment, air quality, water quality, ash disposal operations, and ash marketing.

G.F. Brendel; J.E. Bonetti; R.F. Rathbone; R.N. Frey Jr.

2000-11-01T23:59:59.000Z

278

Flue gas cleaning with ammonia reduces SO{sub 2} emission  

SciTech Connect (OSTI)

This paper describes the technical and commercial development and basis for application in North America for wet flue gas desulfurization (FGD) of the AMASOX{reg_sign} (i.e. Ammonia Absorbs Sulfur Oxides) Process of Krupp Uhde (Germany) employing ammonia reagent. This process technology has been emerging slowly and stepwise over a twenty-year period in reaching the present stage of commercial applicability. The discussion herein considers the need for accommodating to and advantageously addressing the increasing number of applications with high and ultra-high flue-gas concentrations of SO{sub 2} at the boiler outlet accompanied by significant levels of other pollutants. Key measures in accomplishing this include use of important process innovations. This, as well, calls for the effective use, when applicable, of wet electrostatic precipitator mist-elimination means to gain low/minimum-opacity stack plume trailoff in wet scrubber use together with reduction of air toxics to low concentrations. With cost-effectiveness in electric utility service, detailed herein, superior to FGD processes commonly used to date in high-sulfur service, utilization of this technology is expanding. Important, potentially trend-setting types of powerplant applications of ammonia FGD are reviewed to identify foreseen market sectors and procurement trends that will at the same time serve to substantially broaden lowest-cost coal utilization.

Emish, G.J. [Krupp Wilputte Corp., Bridgeville, PA (United States); Schulte, W. [Krupp Uhde GmbH, Dortmund (Germany); Ellison, W. [Ellison Consultants, Monrovia, MD (United States)

1997-12-31T23:59:59.000Z

279

Stress-corrosion cracking of steels in ammonia with consideration given to OTEC design: a survey  

SciTech Connect (OSTI)

Carbon steel, alloy steel, and high-strength, quenched and tempered steel, when under applied or residual stress and especially when cold formed and/or welded without subsequent thermal stress relief, are subject to failure by stress-corrosion cracking (SCC) in air-contaminated dry ammonia. Water as well as hydrazine when present in small amounts have been shown to be effective inhibitors in an all steel system. Galvanic corrosion between dissimilar metals and/or accelerated failure by SCC of stressed steel as a result of galvanic coupling may be of concern. Where water has proven effective as an inhibitor of SCC in an all steel system, it may not be adequate in a mixed metal system. With aluminum tubes, the tube sheet will either have to be solid aluminum, aluminum clad steel or some nonconductive coating will be necessary to effectively remove the cathodic alloy from the galvanic circuit. Research is required to determine the severity of the coupling effect between dissimilar alloys in ammonia under OTEC conditions; especially the possibility of accelerated SCC failures of stressed steel where the presence of an inhibitor in the ammonia may not be sufficient to override the galvanic coupling effect.

Teel, R.B.

1980-03-01T23:59:59.000Z

280

NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL...  

Office of Legacy Management (LM)

HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET NLO NO. DISTRIBUTION OF COPIES 1 Analytical Loboratory (RECORD COPY) 2 Industrial Hygiene & Radiation Dept. 3...

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Application of the Analytic Network Process to facility layout selection  

Science Journals Connector (OSTI)

Abstract This paper applies the Analytic Network Process (ANP) method to the selection of the best facility layout plan based on multiple dependent and independent criteria. This is the first time that this method is used in such a context. An ANP model is built taking into account the interdependencies between criteria that are found based on experts opinions and fundamental equations. A network structure is built that shows all elements and clusters and their interactions that can be used to find the most effective layout. Limit priorities are computed which identify the most important factors in the selection process. A case study is conducted in a wood factory which represents a real demonstration of the developed model. A comparison is conducted between ANP and Analytic Hierarchy Process (AHP) which shows the differences between the two methods. Finally, sensitivity analysis shows the robustness of the model.

Tarek Al-Hawari; Ahmad Mumani; Amer Momani

2014-01-01T23:59:59.000Z

282

Two-reagent reactions of iron clusters with ammonia and deuterium: Saturated compositions and the kinetics of reactions of deuterium with ammoniated clusters  

SciTech Connect (OSTI)

Studies of two-reagent reactions of iron clusters with ammonia and deuterium are described. The compositions of clusters saturated with both ammonia and deuterium have been determined, and indicate that the ammonia binds nondissociatively to iron clusters and to different sites than the deuterium. Rate constants for the reaction of the first deuterium molecule with ammoniated clusters have been measured. In general, low ammonia coverage (one to three molecules) has either little effect on cluster reactivity, or in the case of unreactive bare clusters, increases reactivity dramatically. Clusters saturated with ammonia show general reactivity decreases, although again the least reactive bare clusters show dramatic increases in reactivity when covered with ammonia molecules. Interesting cluster activation and deactivation effects are seen. Possible mechanisms for these reactions are discussed.

Hoffman W.F. III; Parks, E.K.; Riley, S.J.

1989-02-01T23:59:59.000Z

283

A rapid analytical pyrolysis method - Alfalfa (Medicago sativa)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Increase in 4-coumaryl alcohol (H) units during lignification in Increase in 4-coumaryl alcohol (H) units during lignification in alfalfa (Medicago sativa) alters extractability and molecular weight of lignin Angela Ziebell 1,2 , Kristen Gracom ,1,2 , Rui Katahira 1 , Fang Chen 3,4 , Yunqiao Pu 5,6 , Art Ragauskas 5,6 , Richard A. Dixon 3,4 and Mark Davis 1,2 1-National Bioenergy Center, National Renewable Energy Laboratory, Golden, CO 80401-3393; 2-Bioenergy Science Center, National Renewable Energy Laboratory, 1617 Golden, CO 80401-3393; 3-Samuel Roberts Noble Foundation, Ardmore, OK 73401; 4-Bioenergy Science Center, Ardmore, OK 73401; 5-Institute of Paper Science and Technology at Georgia Tech., Atlanta, GA 30318; 6-Bioenergy Science Center, Georgia Tech., Atlanta, GA 30318 Running head: Increase in coumaryl alcohol units alters lignin molecular weight

284

MARTIN, D. F. 1972. Marine chemistry, v. 1. Analytical methods.  

Science Journals Connector (OSTI)

for the obvious care with which they have been selected and for the annotations which ... manuals (Amer. Public Health Ass. 1971; Environ. Prot. Agency 1971).

1999-12-27T23:59:59.000Z

285

Analytical Methods for Implementing Industrial Load Management Programs  

E-Print Network [OSTI]

Many utilities have completed long-term planning studies and have shown that a load management program is cost effective. They are now actively implementing large-scale, system-wide programs such as demand subscription, interruptable rates, and time...

Hassig, N.; Chan, M.; Carlson, R.

1982-01-01T23:59:59.000Z

286

Anglophone Historicism: From Modernist Method to Post-analytic Philosophy  

E-Print Network [OSTI]

Bevir / Journal of the Philosophy of History 3 (2009) 211Journal of the Philosophy of History 3 (2009) 211224of the Society for the Philosophy of History at the American

Bevir, Mark

2009-01-01T23:59:59.000Z

287

SASSI Analytical Methods Compared with SHAKE Free-Field Results  

Office of Environmental Management (EM)

presents a methodology for validating SASSI for use with a particular site profile, foundation size, and embedment depth. Two case studies are presented: 1) a deep soil site at...

288

Putting synchrotron radiation to work for technology: Analytic methods  

SciTech Connect (OSTI)

This report contains viewgraphs on: Advanced Light Source; Ultra-ESCA: Advanced Capabilities of XPS with High-Brightness Synchrotron Radiation; High-Resolution (20 nm) XPS and XANES with the ALS; Photoelectron Spectroscopy in Industry: Current Capabilities, Needs, and Possible Roles for the ALS; Materials Analysis by Photoemission: Is This Practical at ALS?; Applications of Long-Wavelength X-Ray Fluorescence Spectrometry and X-Ray Powder Diffractometry.

Not Available

1992-02-01T23:59:59.000Z

289

Putting synchrotron radiation to work for technology: Analytic methods  

SciTech Connect (OSTI)

This report contains viewgraphs on: Advanced Light Source; Ultra-ESCA: Advanced Capabilities of XPS with High-Brightness Synchrotron Radiation; High-Resolution (20 nm) XPS and XANES with the ALS; Photoelectron Spectroscopy in Industry: Current Capabilities, Needs, and Possible Roles for the ALS; Materials Analysis by Photoemission: Is This Practical at ALS ; Applications of Long-Wavelength X-Ray Fluorescence Spectrometry and X-Ray Powder Diffractometry.

Not Available

1992-02-01T23:59:59.000Z

290

COMPARISON OF ANALYTICAL METHODS FOR CHARACTERIZATION OF THE THERMOCHROMIC  

E-Print Network [OSTI]

, electrochromic materials, and sensors.1 Another interesting property of many conjugated polymers utilized for the characterization of the electrochromic properties of conjugated polymers.7 Investigation

Euler, William B.

291

Validation of Analytic Methods for Biomarkers Used in Drug Development  

Science Journals Connector (OSTI)

...this reflects the lengthy process of assay development and validation...agency was not slowing the process of marker development unduly...Information on current FDA review processes can be found at http...additional barriers to biomarker commercialization were identified (Table 2...

Cindy H. Chau; Olivier Rixe; Howard McLeod; and William D. Figg

2008-10-01T23:59:59.000Z

292

Structural reliability of brittle materials - an analytical method  

E-Print Network [OSTI]

) (IIember) J r'-*rr 1967 (IR&nth) (Year) 111 A?as T p AcT Thc ir&creasin?use of britt. le, maLcrials i)a sero- spa' . appl. i c?tions a'nd a laclc of adequate prescr&t 3c&aoieledge ?s to t:heir behavior ha crentecl a serious pro'blam. Clas&ica3...

Shields, Charles Burch

1967-01-01T23:59:59.000Z

293

Early test facilities and analytic methods for radiation shielding: Proceedings  

SciTech Connect (OSTI)

This report represents a compilation of eight papers presented at the 1992 American Nuclear Society/European Nuclear Society International Meeting. The meeting is of special significance since it commemorates the fiftieth anniversary of the first controlled nuclear chain reaction. The papers contained in this report were presented in a special session organized by the Radiation Protection and Shielding Division in keeping with the historical theme of the meeting. The paper titles are good indicators of their content and are: (1) The origin of radiation shielding research: The Oak Ridge experience, (2) Shielding research at the hanford site, (3) Aircraft shielding experiments at General Dynamics Fort Worth, 1950-1962, (4) Where have the neutrons gone , a history of the tower shielding facility, (5) History and evolution of buildup factors, (6) Early shielding research at Bettis atomic power laboratory, (7) UK reactor shielding: then and now, (8) A very personal view of the development of radiation shielding theory.

Ingersoll, D.T. (comp.) (Oak Ridge National Lab., TN (United States)); Ingersoll, J.K. (comp.) (Tec-Com, Knoxville, TN (United States))

1992-11-01T23:59:59.000Z

294

OIL AND GREASE: A PROPOSED ANALYTICAL METHOD FOR  

E-Print Network [OSTI]

(vol) PE, filter and apply suction until reasonably dry. Air dry and store in a jar. Filter paper and jars (Virtis Model 23 and 200-ml blender jars), rotating evaporator with 250-ml flask, film to seal without vacuum. Apply vacuum, rinse brief- ly, and press down along edge of mat to ensure a good seal

295

D-1 2003 SITE ENVIRONMENTAL REPORT Instrumentation and Analytical Methods  

E-Print Network [OSTI]

) traceable standards: americium-241 for alpha, and strontium-90 for beta. Spiked duplicates are performed-traceable standards: americium-241 for alpha and strontium-90 for beta. Tritium Analysis - Water Matrix - EPA 906

Homes, Christopher C.

296

Widget:AnalyticsSummary | Open Energy Information  

Open Energy Info (EERE)

AnalyticsSummary AnalyticsSummary Jump to: navigation, search Google Analytics widget that returns an HTML summary of site-wide analytics. Use any arbitrary number of days; for instance, 30-31 days will say "a month", 7 days will say "a week", 1 day will say "a day", 365 days will say "a year", and all other day rates will say "n days". How to call it: {{#Widget:AnalyticsSummary|days=30}} Example Output Loading... Statistics summary for the last 1 7 30 365 days Retrieved from "http://en.openei.org/w/index.php?title=Widget:AnalyticsSummary&oldid=535712" Category: Widgets What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

297

Analytical Processing Over XML and XLink  

Science Journals Connector (OSTI)

Current commercial and academic OLAP tools do not process XML data that contains XLink. Aiming at overcoming this issue, this paper proposes an analytical system composed by LMDQL, an analytical query language. Also, the XLDM metamodel is given to model ... Keywords: Link-Based and Multidimensional Query Language LMDQL, On-Line Analytical Processing OLAP, XLPath, XLink-Based Multidimensional Metamodel XLDM, XML Linking Language XLink, eXtensible Markup Language XML

Paulo Caetano da Silva; Valria Cesrio Times; Ricardo Rodrigues Ciferri; Cristina Dutra de Aguiar Ciferri

2012-01-01T23:59:59.000Z

298

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network [OSTI]

or hydro-powered water electrolysis. Ammonia as a HydrogenV for conventional water electrolysis (Cooper and Botte,electricity required for water electrolysis under standard

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

299

Data Analytics and Visualization at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a yet large intersection in terms of their functions. Visualization Analytics Visit Matlab Paraview Mathematica Python AVS R Python tools - Numpy, Scipy, iPython, matplotlib...

300

Strategies for Choosing Analytics and Visualization Software...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in mind that their functions may be interchangeable. Visualization Analytics Visit Matlab Python tools: Numpy, Scipy, iPython, matplotlib Paraview Mathematica Perl IDL Python...

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Determination of Extractives in Biomass: Laboratory Analytical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Extractives in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NRELTP-510-42619...

302

Nanotechnology for Molecular Recognition of Biological Analytes.  

E-Print Network [OSTI]

??Nanotechnology is a term used to describe nanometer scaled systems. This thesis presents various nanomaterials and systems for the investigation of biologically relevant analytes in (more)

Triulzi, Robert C.

2009-01-01T23:59:59.000Z

303

Development of Analytical Methodology for Neurochemical Investigations  

E-Print Network [OSTI]

David J. Fischer Department of Pharmaceutical Chemistry University of Kansas Neurochemical Applications of Microchip Electrophoresis The development of sensitive and selective analytical tools has facilitated the investigation ...

Fischer, David John

2010-01-25T23:59:59.000Z

304

Contained radiological analytical chemistry module  

DOE Patents [OSTI]

A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

Barney, David M. (Scotia, NY)

1989-01-01T23:59:59.000Z

305

Contained radiological analytical chemistry module  

DOE Patents [OSTI]

A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

Barney, David M. (Scotia, NY)

1990-01-01T23:59:59.000Z

306

Method of Determining the Extent to which a Nickel Structure has been Attached by a Fluorine-Containing Gas  

DOE Patents [OSTI]

The method of determining the extent to which a nickel structure has been attacked by a halogen containing gas to which it has been exposed which comprises preparing a quantity of water substantially free from dissolved oxygen, passing ammonia gas through a cuprammonium solution to produce ammonia substantially free from oxygen, dissolving said oxygen-free ammonia in said water to produce a saturated aqueous ammonia solution free from uncombined oxygen, treating at least a portion of said nickel structure of predetermined weight with said solution to dissolve nickel compounds from the surface of said structure without dissolving an appreciable amount of said nickel and analyzing the resulting solution to determine the quantity of said nickel compounds that was associated with said said portion of said structure to determine the proportion of combined nickel in said nickel structure.

Brusie, James P.

2004-07-13T23:59:59.000Z

307

Comparison of Numerical and Analytical Solutions of Heat Equation in R1n  

E-Print Network [OSTI]

Example Analytical Calculation of Heat Equation in 1-D 4 4 2-D Matrix Methods for Numerical Approximations Bibliography 11 8 Appendices 11 8.1 Graphs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 8.2 Matlab Code

Marzuola, Jeremy

308

An Analytical Model for Determining the Thermal Conductivity of Closed-Cell Foam Insulation  

Science Journals Connector (OSTI)

The purpose of this paper is to present analytical methods and some preliminary test results for determining the thermal conductivity and net heat flow in closed-cell foam materials used as cryogenic insulation. ...

M. B. Hammond Jr.

1995-01-01T23:59:59.000Z

309

ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlDN  

Office of Legacy Management (LM)

ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlDN I -. . Industrial Hygiene or Medical Dept. 1956 I. H.# 984 Sample Nos. l2 Date Collected- o/2g by&- Route to J" Location SSi4.X CUiTn! CXJitP. Type of Sample&-dust Analyzed for F Alpha x Remarks P~UXC~JGIi.' ON. 14lCI11~ U Beta - IIoll0Wi.n~ slucs - NO, Ra Oil PH Be Th Sample No. 7573p Hour Sample Description 1355 CZ Orxxator sets slul: into place, closes shield over machine S starts &ill. oil coolant flows through hollow drill ____ 3 is rebounded back through an openiq covers 1 cor.lp N9 8775 Analytical Chemistry Section: Date Received 7-2-66 by hb Date Reported 74X& bY IIR Method of Analysis Alpha sdntillation cam 2 % ' CJly Counting Data: BKGD .27 c/min GE0 4o% /min 1 I c- d/ill/M 3

310

Reaction of iron clusters with ammonia. I. Compositions of the ammoniated products and their implications for cluster structure  

SciTech Connect (OSTI)

Studies are described of the chemisorption of ammonia on isolated neutral iron clusters Fe/sub n/ for 2less than or equal tonless than or equal to165. Clusters are generated by laser vaporization in a continuous-flow-tube reactor, and reaction products are detected by laser-ionization time-of-flight mass spectrometry. Ammonia is found to chemisorb nondissociatively on cluster surfaces on the 1 ms time scale of these experiments. Measurements of ammonia uptake provide information on adsorption kinetics and on the number and nature of the binding sites. The ammonia binding energy is found to decrease with increasing cluster coverage. For chemically saturated clusters, the ratio of adsorbed NH/sub 3/ molecules to surface iron atoms is found to decrease with increasing cluster size, going from >1/3 for small clusters to <1/3 for n>100. Ammonia chemisorption is accompanied by a large decrease in cluster ionization potentials, as much as 2 eV for saturated clusters. At sufficiently high exposure the beginning of the formation of a second, physisorbed layer of molecules is seen. Detailed measurements of product composition under different exposure conditions give evidence for numerous changes in cluster structure throughout the growth sequence from small to large clusters. Often these structural changes involve particularly stable reaction products. Evidence for the existence of metastable structures is presented. Several possibilities for cluster structure are suggested.

Parks, E.K.; Nieman, G.C.; Pobo, L.G.; Riley, S.J.

1988-05-15T23:59:59.000Z

311

Small capacity absorption systems for cooling and power with a scroll expander and ammonia based working fluids  

Science Journals Connector (OSTI)

Abstract Up to now, the use of ammonia/water absorption cycles has been mainly limited to the production of refrigeration or air conditioning but due to the relatively high generator pressure some authors have proposed the integration in parallel of an expander to produce cooling and power simultaneously. This feature could provide many benefits in the future such as the use of solar thermal energy to partially cover the heating, cooling and electricity demand of a building. In the other hand the life cycle cost of the absorption system is improved because of the increase in the number of running hours in periods in which there is no demand for cooling but the demand for electrical power is still important. This paper shows a new combined absorption system using a scroll expander and three different working fluids using ammonia as refrigerant: ammonia/water, ammonia/lithium nitrate and ammonia/sodium thiocyanate. The scroll expander performance maps were obtained experimentally and modeled to predict the power production, rotational speed and exhaust temperature of the expander and included in the complete absorption cycle model build using Engineering Equation Solver (EES) Software. This system produces different amounts of cooling and power at the desired power/cooling ratio to cover varying demand profiles.

Luis Carlos Mendoza; Dereje S. Ayou; Joaqun Navarro-Esbr; Joan Carles Bruno; Alberto Coronas

2014-01-01T23:59:59.000Z

312

Fast In Situ Airborne Measurement of Ammonia Using a Mid-Infrared Off-Axis ICOS Spectrometer  

SciTech Connect (OSTI)

A new ammonia (NH3) spectrometer was developed based on off-axis integrated cavity output spectroscopy. Its feasibility was demonstrated in airborne test flights in the troposphere on board of the Department of Energy (DOE) Gulfstream-1 (G-1) aircraft. This ammonia gas analyzer consists of an optical cell, a quantum-cascade laser, gas sampling system, electronics for control and data acquisition, and data-analysis software. The NH3 mixing ratio is determined from high-resolution NH3 absorption line shapes by tuning the laser wavelength over the sR(3,K) transition of the fundamental vibration band near 9.67 ?m. Excellent linearity is obtained in a wide range (0- 101 ppb) during calibration. The instrument is capable of collecting data at 2 Hz. Two research flights were conducted over Sunnyside, Washington. In the first test flight, the ammonia gas sensor was used to identify signatures of feedstock from local dairy farms with high vertical spatial resolution under low wind and stable atmospheric conditions. In the second flight, the NH3 spectrometer showed high sensitivity in capturing feedstock emission signals under windy and less stable conditions. Our results demonstrate that this new ammonia spectrometer is airborne feasible and that it has the capability to provide fast in situ observations of ammonia to advance our understanding of atmospheric compositions and aerosol formation.

Leen, Brian; Yu, Xiao-Ying; Gupta, Manish; Baer, Douglas S.; Hubbe, John M.; Kluzek, Celine D.; Tomlinson, Jason M.; Hubbell, Michael R.

2013-09-17T23:59:59.000Z

313

ANALYTICAL DATA SHEET hlul ANALYTICAL DEPT. - HEALTH ANI SAFETY...  

Office of Legacy Management (LM)

NLO. H&S. 736 (2.2.56) t)li , ' (i, g * ' a (:I L I- j w 9908 Analyriccll Chemistry Section: Date Received-?7"56 Date Repcrted- 8a7-56 Method of Analysis. A@1 by Iab...

314

Analytical Alias Resolution Mehmet Hadi Gunes and Kamil Sarac  

E-Print Network [OSTI]

that · includes artificial links/nodes · misses existing links/nodes Alias Resolution: Problem IPA2 IPA3 IPA4 IPA5IPA6 IPA1 #12;Analytical Alias Resolution 5/13 Address Based Method (Mercator and iffinder) [J.Pansiot98] · Send probe packets to different IP addresses (i.e. IPA and IPB) · If replies from have the same

Gunes, Mehmet Hadi

315

Analysis of vibrational structure and Jahn?Teller effects in the electron spectrum of ammonia  

Science Journals Connector (OSTI)

The electron spectra of the 2 A 1 ? 1 A 1 and the 2 E? 1 A 1 transitions of ammonia have been measured with sufficient resolution to observe considerable fine structure. The first transition 2 A 1 ? 1 A 1 contains two vibrational progressions which are assigned to the ?2 bending mode. The second transition 2 E? 1 A 1 consists of two overlapping electron bands due to Jahn?Teller splitting of the 2 E state. The vibronic structure accompanying this transition has been partially resolved and compared to the results of model calculations.

J. W. Rabalais; L. Karlsson; L. O. Werme; T. Bergmark; K. Siegbahn

1973-01-01T23:59:59.000Z

316

Selective reduction of nitric oxide with ammonia over vanadia on pillared titanium phosphate  

E-Print Network [OSTI]

in the catalyst. Shikada et al. (1981) compared AlzOz, SiOz, and SiO, ? TiOz (equimolar) supports for VzOs using a simulated flue gas containing 100 ppni SOz. The silica- titanium dioxide supported catalyst showed the highest NO conversions followed by those...SELECTIVE REDUCTION OF NITRIC OXIDE YVITH AMMONIA OVER VANADIA ON PILLARED TITANIUM PHOSPHATE A Thesis LAWRENCE JOSEPH CZARNECKI Submitted to the Graduate College of Texas AkM University in partial fulfillment of the requirement for the degree...

Czarnecki, Lawrence Joseph

1988-01-01T23:59:59.000Z

317

Modeling of selective catalytic reduction (SCR) of nitric oxide with ammonia using four modern catalysts  

E-Print Network [OSTI]

and Ammonia and Oxygen Exponents for V Catalyst........................ 36 Table 6.20 Experimental Data at 150 o C for V-Ti Based PILC Catalyst [28].................................. 40 Table 6.21 Experimental Data at 200 o C for V-Ti Based PILC Catalyst... [28].................................. 40 Table 6.22 Experimental Data at 250 o C for V-Ti Based PILC Catalyst [28].................................. 40 Table 6.23 Experimental Data at 300 o C for V-Ti Based PILC Catalyst [28...

Sharma, Giriraj

2005-11-01T23:59:59.000Z

318

An investigation of the effect of ammonia and amines on the recovery of oil  

E-Print Network [OSTI]

AE INVESTIGATION OF THE EFFECT OF AMMONIA A?D ANIEES OE THE RECOVERT OF OIL A Thesis EF~ %0 JAMES MP RICHARDSON Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE ~J1 8 Na)or Subject: Petroleum En carin AE IEVESTIGATIOE OF TEE EFFECT OF AMMOBIA AED AMIEES OE TRE RECOVERY OF OIL JAMES M, RICRARDSOE Approve& as to sty1e aad eoateat by". Cha1rsan o CeeeeAt e Read of Departaeat J~18...

Richardson, James Malone

2012-06-07T23:59:59.000Z

319

Robust Accurate Non-Invasive Analyte Monitor  

DOE Patents [OSTI]

An improved method and apparatus for determining noninvasively and in vivo one or more unknown values of a known characteristic, particularly the concentration of an analyte in human tissue. The method includes: (1) irradiating the tissue with infrared energy (400 nm-2400 nm) having at least several wavelengths in a given range of wavelengths so that there is differential absorption of at least some of the wavelengths by the tissue as a function of the wavelengths and the known characteristic, the differential absorption causeing intensity variations of the wavelengths incident from the tissue; (2) providing a first path through the tissue; (3) optimizing the first path for a first sub-region of the range of wavelengths to maximize the differential absorption by at least some of the wavelengths in the first sub-region; (4) providing a second path through the tissue; and (5) optimizing the second path for a second sub-region of the range, to maximize the differential absorption by at least some of the wavelengths in the second sub-region. In the preferred embodiment a third path through the tissue is provided for, which path is optimized for a third sub-region of the range. With this arrangement, spectral variations which are the result of tissue differences (e.g., melanin and temperature) can be reduced. At least one of the paths represents a partial transmission path through the tissue. This partial transmission path may pass through the nail of a finger once and, preferably, twice. Also included are apparatus for: (1) reducing the arterial pulsations within the tissue; and (2) maximizing the blood content i the tissue.

Robinson, Mark R. (1603 Solano NE., Albuquerque, NM 87110)

1998-11-03T23:59:59.000Z

320

Study of the effects of interleakage of ammonia and seawater on corrosion and scaling of candidate materials for OTEC heat exchngers. Final report  

SciTech Connect (OSTI)

Assessment has been made on the effect of small concentrations of ammonia in seawater and varying concentrations of seawater in anhydrous ammonia upon corrosion and scaling of candidate OTEC heat exchanger materials - A1-5052, Alclad 3003, copper alloys 706, 715 and 722, AL-6X stainless steel and CP titanium. Results are presented. AL-6X stainless steel and CP titanium showed exceptional corrosion resistance to all test environments. Alclad alloy 3003 showed satisfactory performance in seawater and seawater plus ammonia environments. Only minimal pitting was observed and this was limited to the sacrificial cladding in seawater plus ammonia only. Cladding alloy 7072 showed unacceptable corrosion resistance in anhydrous ammonia containing low seawater concentrations. Al-5052 tubes showed unsatisfactory corrosion behavior in the presence of seawater flow with ammonia interleakage. Copper alloys considered showed unacceptable corrosion resistance in all seawater environments containing ammonia. Low pressure differentials between seawater and anhydrous ammonia in the tube testing unit resulted in scaling and moderately efficient plug seal formation at the artificial leak sites of the tubes. It is recommended that Alclad 3003, CP titanium and AL-6X stainless steel tubes be assessed for suitability in the presence of probable OTEC cleaning systems.

Grimes, W D; Schrieber, C F; Manning, J A

1980-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Investigation of ammonia equipment configurations for supermarket refrigeration applications (for microcomputers). Software  

SciTech Connect (OSTI)

This product gives results of a project to quantify the advantages and disadvantages of using ammonia with a secondary brine refrigerant compared to R-22 in supermarket refrigeration applications. Project objectives were achieved by numerical experiments using simulations. Mechanistic models of refrigeration system components were used, based on fundamental principles, accepted heat transfer/pressure drop correlations, and available manufacturers` data. Available thermodynamic and transport property data correlations for ammonia and R-22 were used in the models. The parameters of these models were varied to determine their effect on system performance and locate optimum values. A modular approach was used in which each component was separately modeled, allowing simple changes in system configurations. The combined component models resulted in a large set of coupled nonlinear algebraic equations for the quasi-steady systems that did not involve brine storage. The system involved differential and algebraic equations. These equations were solved using the general-purpose simulation programs EES and TRNSYS. EES is a robust nonlinear equation-solving program with built-in thermophysical property data. TRNSYS is a sequential modular simulation program that uses schemes to solve coupled algebraic and differential equations.

NONE

1995-02-01T23:59:59.000Z

322

Ammonia Generation over TWC for Passive SCR NOX Control for Lean Gasoline Engines  

SciTech Connect (OSTI)

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at =0.96 for nearly all conditions studied. At the =0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than =0.96 did not provide more NH3 yield and led to higher HC and CO emissions. Results of the reductant conversion and consumption processes were used to calculate a representative fuel consumption of the engine operating with an ideal passive SCR system. The results show a 1-7% fuel economy benefit at various steady-state engine speed and load points relative to a stoichiometric engine operation.

Prikhodko, Vitaly Y [ORNL] [ORNL; Parks, II, James E [ORNL; Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

323

Reactions of cobalt clusters with water and ammonia: Implications for cluster structure  

SciTech Connect (OSTI)

Reactions of cobalt clusters in the 6 to 150 atom size range with water and ammonia are used to probe cluster geometrical structure. Clusters saturated with ammonia are found in several isomeric forms in much of this size region, including a structure based on icosahedral packing for clusters having 50 to 120 atoms. The variations with cluster size of the binding energy for a single water molecule provide evidence for icosahedral structure of the bare cobalt clusters in the same size range seen for the ammoniated clusters. However, both probes suggest that in many cases the bare clusters also have multiple isomers. The evidence for icosahedral structure in the bare and ammoniated clusters disappears above [similar to]120 atoms and is clearly not seen at the third icosahedral shell closing at 147 atoms. Comparison with earlier studies of hydrogenated cobalt clusters and with bare and hydrogenated nickel clusters is made. Reasons for the failure to form the closed-shell 147 atom icosahedral cluster are discussed.

Parks, E.K.; Klots, T.D.; Winter, B.J.; Riley, S.J. (Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States))

1993-10-15T23:59:59.000Z

324

Laser separation of nitrogen isotopes by the IR+UV dissociation of ammonia molecules  

SciTech Connect (OSTI)

The separation of nitrogen isotopes is studied upon successive single-photon IR excitation and UV dissociation of ammonia molecules. The excitation selectivity was provided by tuning a CO{sub 2} laser to resonance with {sup 14}NH{sub 3} molecules [the 9R(30) laser line] or with {sup 15}NH{sub 3} molecules [the 9R(10) laser line]. Isotopic mixtures containing 4.8% and 0.37% (natural content) of the {sup 15}NH isotope were investigated. The dependences of the selectivity and the dissociation yield for each isotopic component on the buffer gas pressure (N{sub 2}, O{sub 2}, Ar) and the ammonia pressure were obtained. In the limit of low NH{sub 3} pressures (0.5-2 Torr), the dissociation selectivity {alpha}(15/14) for {sup 15}N was 17. The selectivity mechanism of the IR+UV dissociation is discussed and the outlook is considered for the development of the nitrogen isotope separation process based on this approach. (laser isotope separation)

Apatin, V M; Klimin, S A; Laptev, V B; Lokhman, V N; Ogurok, D D; Pigul'skii, S V; Ryabov, E A [Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow region (Russian Federation)

2008-08-31T23:59:59.000Z

325

Theoretical study on a novel ammoniawater cogeneration system with adjustable cooling to power ratios  

Science Journals Connector (OSTI)

Abstract A novel ammoniawater cogeneration system with adjustable cooling to power ratios is proposed and investigated. In the combined system, a modified Kalina subcycle and an ammonia absorption cooling subcycle are interconnected by mixers, splitters, absorbers and heat exchangers. The proposed system can adjust its cooling to power ratios from the separate mode without splitting/mixing processes in the two subcycles to the combined operation modes which can produce different ratios of cooling and power. Simulation analysis is conducted to investigate the effects of operation parameter on system performance. The results indicate that the combined system efficiency can reach the maximum values of 37.79% as SR1 (split ratio 1) is equal to 1. Compared with the separate system, the combined efficiency and COP values of the proposed system can increase by 6.6% and 100% with the same heat input, respectively. In addition, the cooling to power ratios of the proposed system can be adjusted in the range of 1.83.6 under the given operating conditions.

Zeting Yu; Jitian Han; Hai Liu; Hongxia Zhao

2014-01-01T23:59:59.000Z

326

Licenses Available in Analytical Instrumentation | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytical Instrumentation Analytical Instrumentation SHARE Analytical Instrumentation 199700361 Neutron Detection Using an Embedded Sol-Gel Neutron Absorber 199700370 Bioluminescent Bioreporter Integrated Circuits 199900683 Microscale Ion Trap Mass Spectrometer 200101009 Automated Sampling for Microarray Readout Using Electrospray Mass Spectrometry 200201069 Planar Flow-By Electrode Capacitive Electrospray Ion Source 200201145 Fluorescent Nanoparticles for Radiation Detection 200301290 Pulse Thermal Processing of Functional Materials Using a Directed Plasma Arc 200401367 Composite Solid-State Scintillators for Neutron Detection 200501505 Resistive-Glass Drift Tube for Use as a Controlled Kinetic Energy Ion Source 200601675 Functionalized Gold Nanoparticles for Rapid,

327

Thermodynamic modelling of three-stage combined cycle power systems utilising ammonia-water mixture as a working fluid in bottoming cycle  

Science Journals Connector (OSTI)

In this study, two three-stage combined power cycles with ammonia-water mixture in bottoming cycle are introduced; one with variable ammonia fraction and the other with constant ammonia fraction. Energy and exergy analyses are carried out and optimal parameters of the proposed cycles are compared with the conventional power cycles. The second law efficiency of three-stage cycles with variable and constant ammonia fraction are 4.71% and 5.15% higher than steam-gas combined power cycle, respectively. Exergy flow diagram for each cycle is presented and exergy destruction of all components is investigated. Results quantitatively highlight the thermodynamic advantages of the proposed cycles in comparison with the conventional cycles. Three-stage cycle with constant ammonia fraction has the best performance in comparison with the others.

Amin Momeni; Hossein Shokouhmand

2014-01-01T23:59:59.000Z

328

Nonperturbative Coherent Population Trapping: An Analytic Model  

Science Journals Connector (OSTI)

Coherent population trapping is shown to occur in a driven symmetric double-well potential in the strong-field regime. The system parameters have been chosen to reproduce the 0-?3+ transition of the inversion mode of the ammonia molecule. For a molecule initially prepared in its lower doublet we find that, under certain circumstances, the 3+ level remains unpopulated, and this occurs in spite of the fact that the laser field is resonant with the 0-?3+ transition and intense enough so as to strongly mix the 0+ and 0- ground states. This counterintuitive result constitutes a coherent population trapping phenomenon of nonperturbative origin which cannot be accounted for with the usual models.

V. Delgado and J. M. Gomez Llorente

2002-01-23T23:59:59.000Z

329

Deep Sludge Gas Release Event Analytical Evaluation  

SciTech Connect (OSTI)

Long Abstract. Full Text. The purpose of the Deep Sludge Gas Release Event Analytical Evaluation (DSGRE-AE) is to evaluate the postulated hypothesis that a hydrogen GRE may occur in Hanford tanks containing waste sludges at levels greater than previously experienced. There is a need to understand gas retention and release hazards in sludge beds which are 200 -300 inches deep. These sludge beds are deeper than historical Hanford sludge waste beds, and are created when waste is retrieved from older single-shell tanks (SST) and transferred to newer double-shell tanks (DST).Retrieval of waste from SSTs reduces the risk to the environment from leakage or potential leakage of waste into the ground from these tanks. However, the possibility of an energetic event (flammable gas accident) in the retrieval receiver DST is worse than slow leakage. Lines of inquiry, therefore, are (1) can sludge waste be stored safely in deep beds; (2) can gas release events (GRE) be prevented by periodically degassing the sludge (e.g., mixer pump); or (3) does the retrieval strategy need to be altered to limit sludge bed height by retrieving into additional DSTs? The scope of this effort is to provide expert advice on whether or not to move forward with the generation of deep beds of sludge through retrieval of C-Farm tanks. Evaluation of possible mitigation methods (e.g., using mixer pumps to release gas, retrieving into an additional DST) are being evaluated by a second team and are not discussed in this report. While available data and engineering judgment indicate that increased gas retention (retained gas fraction) in DST sludge at depths resulting from the completion of SST 241-C Tank Farm retrievals is not expected and, even if gas releases were to occur, they would be small and local, a positive USQ was declared (Occurrence Report EM-RP--WRPS-TANKFARM-2012-0014, "Potential Exists for a Large Spontaneous Gas Release Event in Deep Settled Waste Sludge"). The purpose of this technical report is to (1) present and discuss current understandings of gas retention and release mechanisms for deep sludge in U.S. Department of Energy (DOE) complex waste storage tanks; and (2) to identify viable methods/criteria for demonstrating safety relative to deep sludge gas release events (DSGRE) in the near term to support the Hanford C-Farm retrieval mission. A secondary purpose is to identify viable methods/criteria for demonstrating safety relative to DSGREs in the longer term to support the mission to retrieve waste from the Hanford Tank Farms and deliver it to the Waste Treatment and Immobilization Plant (WTP). The potential DSGRE issue resulted in the declaration of a positive Unreviewed Safety Question (USQ). C-Farm retrievals are currently proceeding under a Justification for Continued Operation (JCO) that only allows tanks 241-AN-101 and 241-AN-106 sludge levels of 192 inches and 195 inches, respectively. C-Farm retrievals need deeper sludge levels (approximately 310 inches in 241-AN-101 and approximately 250 inches in 241-AN-106). This effort is to provide analytical data and justification to continue retrievals in a safe and efficient manner.

Sams, Terry L.

2013-08-15T23:59:59.000Z

330

Visualization and Analytics Software at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytics Analytics Visualization and Analytics AVS/Express AVS/Express includes functionality for data visualization and analysis, image processing and data display. It uses a graphical application development environment. Read More » VisIt - 3D Scientific Visualization VisIt is a point-and-click 3D scientific visualization application that supports most common visualization techniques (e.g., isocontouring and volume rendering) on structured and unstructured grids. Due to its distributed and parallel architecture, VisIt is able to handle very large datasets interactively. In addition, VisIt is extensible, allowing users to add data loaders or additional analysis tools to VisIt. The NERSC Analytics Group has developed extensions to VisIt to support NERSC user applications,

331

Software and Analytical Tools | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Information Resources » Software and Analytical Tools Information Resources » Software and Analytical Tools Software and Analytical Tools October 8, 2013 - 2:12pm Addthis Software and analytical tools are available to help Federal agencies implement energy- and water-efficiency projects. Building Energy Software Tools Directory: This U.S. Department of Energy's Building Technology Office website lists more than 400 software tools for evaluating energy efficiency in facilities. Building Life Cycle Cost (BLCC) Programs: The following National Institute of Standards and Technology programs help compute and analyze capital investments in buildings: BLCC5 Program: Analyze capital investments in buildings. Energy Escalation Rate Calculator: Compute an average annual escalation rate. Distributed Generation Energy Technology Capital Costs: This National

332

Analytical number-projected BCS nuclear model  

Science Journals Connector (OSTI)

Transforming both the overlap energy kernel and overlap functionals into polynomial forms, the well-known integral of the number-projected BCS theory is performed analytically. We then obtain the projected ground state BCS energy in the closed form.

Mauro Kyotoku

1988-05-01T23:59:59.000Z

333

Sensor for detecting and differentiating chemical analytes  

DOE Patents [OSTI]

A sensor for detecting and differentiating chemical analytes includes a microscale body having a first end and a second end and a surface between the ends for adsorbing a chemical analyte. The surface includes at least one conductive heating track for heating the chemical analyte and also a conductive response track, which is electrically isolated from the heating track, for producing a thermal response signal from the chemical analyte. The heating track is electrically connected with a voltage source and the response track is electrically connected with a signal recorder. The microscale body is restrained at the first end and the second end and is substantially isolated from its surroundings therebetween, thus having a bridge configuration.

Yi, Dechang (Metuchen, NJ); Senesac, Lawrence R. (Knoxville, TN); Thundat, Thomas G. (Knoxville, TN)

2011-07-05T23:59:59.000Z

334

An Analytical Model for Tropical Relative Humidity  

Science Journals Connector (OSTI)

An analytical model is derived for tropical relative humidity using only the ClausiusClapeyron relation, hydrostatic balance, and a bulk-plume water budget. This theory is constructed for radiativeconvective equilibrium and compared against a ...

David M. Romps

2014-10-01T23:59:59.000Z

335

Process Analytical Technology in biopharmaceutical manufacturing  

E-Print Network [OSTI]

Process Analytical Technology (PAT) became a well-defined concept within the pharmaceutical industry as a result of a major initiative by the FDA called "Pharmaceutical cGMPs for the 21st Century: A Risk-Based Approach." ...

Cosby, Samuel T. (Samuel Thomas)

2013-01-01T23:59:59.000Z

336

Google Analytics | OpenEI Community  

Open Energy Info (EERE)

2012 - 13:58 OpenEI dashboard Google Analytics mediawiki OpenEI statistics wiki OpenEI web traffic from Bangalore, India Did you know that in the last month, 621 people in...

337

Analytical study of thermonuclear reaction probability integrals  

Science Journals Connector (OSTI)

An analytic study of the reaction probability integralscorresponding to the various forms of the slowly varyingcross-section factor S(E) is attempted. Exact expressions forreaction probability integrals are expre...

M.Aslam Chaudhry; H.J. Haubold; A.M. Mathai

2000-09-01T23:59:59.000Z

338

Analytic Power LLC | Open Energy Information  

Open Energy Info (EERE)

Analytic Power LLC Analytic Power LLC Jump to: navigation, search Name Analytic Power LLC Place Woburn, Massachusetts Zip 01801 Sector Hydrogen Product Fuel cell developer Website http://www.analytic-power.com/ Coordinates 42.4884618°, -71.1329685° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":42.4884618,"lon":-71.1329685,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

339

Transfer Operators for Coupled Analytic Maps  

E-Print Network [OSTI]

We consider analytic coupled map lattices over $\\Z^d$ with exponentially decaying interaction. We introduce Banach spaces for the infinite-dimensional system that include measures with analytic, exponentially bounded finite dimensional marginals. Using residue calculus and `cluster expansion'-like techniques we define transfer operators on these Banach spaces. For these we get a unique probability measure that exhibits exponential decay of correlations.

Torsten Fischer; Hans Henrik Rugh

1997-11-18T23:59:59.000Z

340

Building up the elliptic flow: analytical insights  

E-Print Network [OSTI]

In this paper, we present a fully analytical description of the early-stage formation of elliptic flow in relativistic viscous hydrodynamics. We first construct an elliptic deformation of Gubser flow which is a boost invariant solution of the Navier-Stokes equation with a nontrivial transverse profile. We then analytically calculate the momentum anisotropy of the flow as a function of time and discuss the connection with the empirical formula by Bhalerao {\\it et al.} regarding the viscosity dependence of elliptic flow.

Yoshitaka Hatta; Bo-Wen Xiao

2014-05-08T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Developing Guidelines for Assessing Visual Analytics Environments  

SciTech Connect (OSTI)

Visual analytic systems can be evaluated from a user perspective with quantitative metrics (i.e., time to complete the analysis or the accuracy of the solution found). However, qualitative measures are also useful in a user assessment. These include such measures as the utility of the interactive visualizations in the analysis process and the user's assessment of the efficiency of the analytic process. Quantitative measures can be found if data sets with embedded ground truth are used for analysis. Qualitative measures are more elusive. In this paper we report on an experiment with professional analysts who ranked five of submissions to the VAST 2009 Challenge and provided the rationale for their rankings. Their comments were used in conjunction with a meta-analysis of the 2009 VAST Challenge reviews to produce a set of guidelines for visual analytic systems. As visual analytic software is expected to eventually help in all aspects of analysis, we expect to see future systems provide more help with generating the final report. Hence, researchers also need to have an understanding of what makes a good analytic product. Therefore we asked the analysts to rank the situational assessments of four grand challenge entries and to provide comments on those assessments. We used these comments to produce guidelines for researchers to use in evaluating their analytic reports.

Scholtz, Jean

2011-09-22T23:59:59.000Z

342

S urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia and steam  

E-Print Network [OSTI]

-based activated carbon fibers (ACF) to optimize the oxidative retention of up to 5000 ppmv of SO2 in moist air suitable for the recovery of sulfuric acid at room temperature than granular activated carbon becauseS urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia

Paris-Sud XI, Université de

343

Analytic Evolution of Singular Distribution Amplitudes in QCD  

SciTech Connect (OSTI)

We describe a method of analytic evolution of distribution amplitudes (DA) that have singularities, such as non-zero values at the end-points of the support region, jumps at some points inside the support region and cusps. We illustrate the method by applying it to the evolution of a flat (constant) DA, anti-symmetric at DA and then use it for evolution of the two-photon generalized distribution amplitude. Our approach has advantages over the standard method of expansion in Gegenbauer polynomials, which requires infinite number of terms in order to accurately reproduce functions in the vicinity of singular points, and over a straightforward iteration of an initial distribution with evolution kernel. The latter produces logarithmically divergent terms at each iteration, while in our method the logarithmic singularities are summed from the start, which immediately produces a continuous curve, with only one or two iterations needed afterwards in order to get rather precise results.

Radyushkin, Anatoly V. [Old Dominion University, Norfolk, VA (United States); Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Tandogan Kunkel, Asli [Old Dominion University, Norfolk, VA (United States); Thomas Jefferson National Accelerator Facility, Newport News, VA (United States)

2014-03-01T23:59:59.000Z

344

Characterization of Chemically Vapor Deposited Silicon Nitride Films from Disilane and Ammonia  

Science Journals Connector (OSTI)

Amorphous silicon nitride films a:SiNx were prepared by low pressure chemical vapor deposition (LPCVD) from disilane ( Si2H6) and ammonia ( NH3). Most of the depositions were performed at 600 C with various NH3/Si2H6 gas ratios ranging from 4 to 50. Different deposits with composition (x= N/Si) ranging from silicon-rich to stoichiometric silicon nitride were characterized by means of infrared spectroscopy (FTIR), ellipsometry, electron energy loss spectroscopy (EELS), and their structure analysed by transmission electron microscopy (TEM). Transmission infrared measurements showed low hydrogen content (x= N/Si) and density of the films were correlated with their refractive index and discussed.

Redhouane Henda; Larbi Laanab; Emmanuel Scheid; Robert Fourmeaux

1995-01-01T23:59:59.000Z

345

Thermal Stability and Hydrogen Release Kinetics of Ammonia Borane Under Vehicle Storage Conditions  

SciTech Connect (OSTI)

Ammonia borane (AB) is a promising chemical hydrogen storage material for H2 powered fuel-cell vehicles (FCVs) owing to its considerable hydrogen density and stability under typical ambient conditions. U.S. Department of Energy (DOE) Technical Targets for on-board hydrogen storage systems in 2015 provide a requirement for operating temperatures in full-sun exposure as high as 60C (50C by 2010) [1]. The purpose of this work is to investigate the thermal stability of solid AB during storage on-board a FCV at 40 to 60C. Calorimeter measurements and calculation models are used to estimate AB thermal stability and H2 release kinetics under isothermal, adiabatic, and cooled storage conditions as a function of storage time, temperature, and AB purity.

Rassat, Scot D.; Smith, R. Scott; Aardahl, Christopher L.; Autrey, Thomas; Chin, Arthur A.; Magee, Joseph W.; VanSciver, Gary R.; Lipiecki, Frank J.

2006-09-01T23:59:59.000Z

346

Calculations on spin-paired species in metal-ammonia solutions  

SciTech Connect (OSTI)

In this paper we show that the spin-paired species in ammonia is consistent with a cluster of two single-electron ammoniated cavity species held together by a cation, also probably solvated. With the electronic part of the wave functions for the ammoniated electron as determined by Newton, the ground-state electronic configuration is a singlet and the singlet-triplet separation is calculated to be about 0.1 eV. The spectrum of the individual cavity species is only shifted by a few hundredths of an electronvolt based on perturbation calculations. These data are consistent with the experimental values recently found by Schindewolf and Werner, who have other data which support the particular species studied in this paper.

Kestner, N.R.; Rao, B.K.; Finley, C.W.

1983-04-14T23:59:59.000Z

347

Evaluation of a solar intermittent refrigeration system for ice production operating with ammonia/lithium nitrate  

SciTech Connect (OSTI)

A novel solar intermittent refrigeration system for ice production developed in the Centro de Investigacion en Energia of the Universidad Nacional Autonoma de Mexico is presented. The system operates with the ammonia/lithium nitrate mixture. The system developed has a nominal capacity of 8 kg of ice/day. It consists of a cylindrical parabolic collector acting as generator-absorber. Evaporator temperatures as low as -11 C were obtained for several hours with solar coefficients of performance up to 0.08. It was found that the coefficient of performance increases with the increment of solar radiation and the solution concentration. A dependency of the coefficient of performance was not founded against the cooling water temperature. Also it was found that the maximum operating pressure increases meanwhile the generation temperature decreases with an increase of the solution concentration. (author)

Rivera, W.; Moreno-Quintanar, G.; Best, R. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, A.P. 34, 62580 Temixco, Mor. (Mexico); Rivera, C.O.; Martinez, F. [Facultad de Ingenieria Campus Coatzacoalcos, Universidad Veracruzana, Av. Universidad Km 7.5, 96530 Coatzacoalcos, Ver. (Mexico)

2011-01-15T23:59:59.000Z

348

Evaluation of Aqua-Ammonia Chiller Technologies and Field Site Installation  

SciTech Connect (OSTI)

The Naval Facilities Engineering Service Center (NFESC) has sponsored Oak Ridge National Laboratory (ORNL) to review, select, and evaluate advanced, gas-fired, 5-ton, aqua-ammonia, chiller technologies. The selection criteria was that units have COP values of 0.67 or better at Air-conditioning and Refrigeration Institute (ARI) 95 F outdoor rating conditions, an active refrigerant flow control, and a variable-speed condenser fan. These features are expected to allow these units to operate at higher ambient temperatures (up to the maximum operating temperature of 110 F) with minimal degradation in performance. ORNL evaluated three potential manufacturers of advanced, gas-fired, 5-ton, aqua-ammonia chillers-Robur, Ambian, and Cooling Technologies. Unfortunately, Robur did not meet the COP requirements and Cooling Technologies could not deliver a unit to be tested at the U.S. Department of Energy (DOE)-ORNL environmental chamber testing facility for thermally activated heat pumps. This eliminated these two technologies from further consideration, leaving only the Ambian chillers for evaluation. Two Ambian chillers were evaluated at the DOE-ORNL test facility. Overall these chillers operated well over a wide range of ambient conditions with minimal degradation in performance due to several control strategies used such as a variable speed condenser fan, a modulating burner, and active refrigerant flow control. These Ambian pre-commercial units were selected for installation and field testing at three federal facilities. NFESC worked with ORNL to assist with the site selection for installation and evaluation of these chillers. Two sites (ORNL and Naval Surface Warfare Center [NSWC] Corona) had a single chiller unit installed; and at one site (Naval Amphibious Base [NAB] Little Creek), two 5-ton chillers linked together were installed to provide 10 tons of cooling. A chiller link controller developed under this project was evaluated in the field test at Little Creek.

Zaltash, Abdolreza [ORNL

2007-09-01T23:59:59.000Z

349

Consistency of FMEA used in the validation of analytical procedures  

Science Journals Connector (OSTI)

In order to explore the consistency of the outcome of a Failure Mode and Effects Analysis (FMEA) in the validation of analytical procedures, an FMEA was carried out by two different teams. The two teams applied two separate \\{FMEAs\\} to a High Performance Liquid ChromatographyDiode Array DetectionMass Spectrometry (HPLCDADMS) analytical procedure used in the quality control of medicines. Each team was free to define their own ranking scales for the probability of severity (S), occurrence (O), and detection (D) of failure modes. We calculated Risk Priority Numbers (RPNs) and we identified the failure modes above the 90th percentile of RPN values as failure modes needing urgent corrective action; failure modes falling between the 75th and 90th percentile of RPN values were identified as failure modes needing necessary corrective action, respectively. Team 1 and Team 2 identified five and six failure modes needing urgent corrective action respectively, with two being commonly identified. Of the failure modes needing necessary corrective actions, about a third were commonly identified by both teams. These results show inconsistency in the outcome of the FMEA. To improve consistency, we recommend that FMEA is always carried out under the supervision of an experienced FMEA-facilitator and that the FMEA team has at least two members with competence in the analytical method to be validated. However, the \\{FMEAs\\} of both teams contained valuable information that was not identified by the other team, indicating that this inconsistency is not always a drawback.

M.T. Oldenhof; J.F. van Leeuwen; M.J. Nauta; D. de Kaste; Y.M.C.F. Odekerken-Rombouts; M.J. Vredenbregt; M. Weda; D.M. Barends

2011-01-01T23:59:59.000Z

350

Risk analysis by FMEA as an element of analytical validation  

Science Journals Connector (OSTI)

We subjected a Near-Infrared (NIR) analytical procedure used for screening drugs on authenticity to a Failure Mode and Effects Analysis (FMEA), including technical risks as well as risks related to human failure. An FMEA team broke down the NIR analytical method into process steps and identified possible failure modes for each step. Each failure mode was ranked on estimated frequency of occurrence (O), probability that the failure would remain undetected later in the process (D) and severity (S), each on a scale of 110. Human errors turned out to be the most common cause of failure modes. Failure risks were calculated by Risk Priority Numbers (RPNs)=OנDנS. Failure modes with the highest RPN scores were subjected to corrective actions and the FMEA was repeated, showing reductions in RPN scores and resulting in improvement indices up to 5.0. We recommend risk analysis as an addition to the usual analytical validation, as the FMEA enabled us to detect previously unidentified risks.

J.F. van Leeuwen; M.J. Nauta; D. de Kaste; Y.M.C.F. Odekerken-Rombouts; M.T. Oldenhof; M.J. Vredenbregt; D.M. Barends

2009-01-01T23:59:59.000Z

351

Evans Analytical Group EAG | Open Energy Information  

Open Energy Info (EERE)

Analytical Group EAG Analytical Group EAG Jump to: navigation, search Name Evans Analytical Group (EAG) Place Sunnyvale, California Zip 94086 Sector Solar Product California-based firm involved in materials characterization. The company provides testing and performance measurements for solar PV energy systems. Coordinates 32.780338°, -96.547405° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":32.780338,"lon":-96.547405,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

352

Semi-analytical solutions of contaminant transport equation with nonlinear sorption in 1D  

E-Print Network [OSTI]

Semi-analytical solutions of contaminant transport equation with nonlinear sorption in 1D Peter of one-dimensional contaminant transport problem with nonlinear sorption is described. This method transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir

Frolkovic, Peter

353

An analytically solvable eigenvalue problem for the linear elasticity equations.  

SciTech Connect (OSTI)

Analytic solutions are useful for code verification. Structural vibration codes approximate solutions to the eigenvalue problem for the linear elasticity equations (Navier's equations). Unfortunately the verification method of 'manufactured solutions' does not apply to vibration problems. Verification books (for example [2]) tabulate a few of the lowest modes, but are not useful for computations of large numbers of modes. A closed form solution is presented here for all the eigenvalues and eigenfunctions for a cuboid solid with isotropic material properties. The boundary conditions correspond physically to a greased wall.

Day, David Minot; Romero, Louis Anthony

2004-07-01T23:59:59.000Z

354

Semantic Interaction for Visual Analytics: Toward Coupling Cognition and Computation  

SciTech Connect (OSTI)

The dissertation discussed in this article [1] was written in the midst of an era of digitization. The world is becoming increasingly instrumented with sensors, monitoring, and other methods for generating data describing social, physical, and natural phenomena. Thus, data exist with the potential of being analyzed to uncover, or discover, the phenomena from which it was created. However, as the analytic models leveraged to analyze these data continue to increase in complexity and computational capability, how can visualizations and user interaction methodologies adapt and evolve to continue to foster discovery and sensemaking?

Endert, Alexander

2014-07-01T23:59:59.000Z

355

ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

, . - - ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1 DE89 009559 W. D. Shults Analytical Chemistry Division Oak Ridge National Laboratory* Oak Ridge, Tennessee 37831-6129 ABSTRACT Over the past forty years, analytical scientists within the DOE complex have had a tremendous impact on the field of analytical chemistry. This paper suggests six "high impact" research/development areas that either originated within or wcce brought to maturity within the DOE laboratories. "High impact" means they lead to new subdisciplines or to new ways of doing business. DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their

356

Analytical quality control services of the International Atomic Energy Agency  

Science Journals Connector (OSTI)

The International Atomic Energy Agency provides quality control services to analytical laboratories. These services...

O. Suschny

1986-01-01T23:59:59.000Z

357

Analytical Techniques for Characterizing Enzymatic Biofuel Cells  

Science Journals Connector (OSTI)

Analytical Techniques for Characterizing Enzymatic Biofuel Cells ... Most enzymic biofuel cells contain bioanodes with single enzymes to partially oxidize biofuels. ... The citric acid cycle is one of the main metabolic pathways living cells utilize to completely oxidize biofuels to carbon dioxide and water. ...

Michael J. Moehlenbrock; Robert L. Arechederra; Kyle H. Sjholm; Shelley D. Minteer

2009-11-04T23:59:59.000Z

358

Analytic Hierarchy March 26th, 2013  

E-Print Network [OSTI]

Analytic Hierarchy March 26th, 2013 Nick Knaus and Pye Pye Zaw #12;Importance or the decision maker returns to Step 3 #12;Figure Of Merit (FOM) ODefinition: A metric by which to as Measures of Effectiveness or Measures of Performance by DOD #12;Figure of Merit (FOM) OA good

Rhoads, James

359

ENERGY, POWER AND ENVIRONMENT (Environmental Analytical Chemistry)  

E-Print Network [OSTI]

ENERGY, POWER AND ENVIRONMENT (Environmental Analytical Chemistry) CHEM 6284/CHEM 4803 Fall 2014 3 a major impact on environment. As the global population grows, so does the demand for energy. Strictly cannot be made without understanding the science and engineering behind them. Since the discovery of laws

Sherrill, David

360

An analytical review of DSPIN-13  

E-Print Network [OSTI]

A short analytical review of XV Workshop on High Energy Spin Physics (DSPIN-13) is given. All materials of the workshop, including all presented talks, list of participants and the pdf-file of Proceedings are available on the site http://theor.jinr.ru/~spin/2013/.

A. V. Efremov; J. Soffer

2014-04-13T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Analytical Study of Thermonuclear Reaction Probability Integrals  

E-Print Network [OSTI]

An analytic study of the reaction probability integrals corresponding to the various forms of the slowly varying cross-section factor $S(E)$ is attempted. Exact expressions for reaction probability integrals are expressed in terms of the extended gamma functions.

M. A. Chaudhry; H. J. Haubold; A. M. Mathai

2000-01-16T23:59:59.000Z

362

MODIFIED KREIN FORMULA AND ANALYTIC PERTURBATION PROCEDURE  

E-Print Network [OSTI]

mathematical problem concerning perturbation of embedded eigen- values. For practical needs consisting of a single compact quantum well and few semi-infinite wires attached to it. In the theoretical-body scattering problem. In this paper we suggest a semi-analytic perturbation procedure which permits

363

Biofuels from Bacteria, Electricity, and CO2: Biofuels from CO2 Using Ammonia or Iron-Oxidizing Bacteria in Reverse Microbial Fuel Cells  

SciTech Connect (OSTI)

Electrofuels Project: Electrofuels Project: Columbia University is using carbon dioxide (CO2) from ambient air, ammoniaan abundant and affordable chemical, and a bacteria called N. europaea to produce liquid fuel. The Columbia University team is feeding the ammonia and CO2 into an engineered tank where the bacteria live. The bacteria capture the energy from ammonia and then use that energy to convert CO2 into a liquid fuel. When the bacteria use up all the ammonia, renewable electricity can regenerate it and pump it back into the systemcreating a continuous fuel-creation cycle. In addition, Columbia University is also working with the bacteria A. ferrooxidans to capture and use energy from ferrous iron to produce liquid fuels from CO2.

None

2010-07-01T23:59:59.000Z

364

Study of the action of ammonia on phosphorus trifluoride. Density study of the two components system propylene-etylene in the liquid state.  

E-Print Network [OSTI]

??Part I: Ammonia can react with phosphorus trifluoride only at low temperature, (-78c.), to produce ammonium fluoride and phosphotriamide, P (NH2)3. This last compound is (more)

Brais, Roger.

1942-01-01T23:59:59.000Z

365

Ammonia-Borane and Related N-B-H Compounds and Materials: Safety Aspects, Properties, and Applications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ammonia-Borane and Related N-B-H Compounds and Materials: Ammonia-Borane and Related N-B-H Compounds and Materials: Safety Aspects, Properties and Applications (A survey completed as part of a project for the DOE Chemical Hydrogen Storage Center of Excellence, Contract # DE-FC36-05GO15060) Clinton F. Lane Department of Chemistry and Biochemistry Northern Arizona University PO Box 5698 Flagstaff, AZ 86011-5698 Phone: 928-523-6296 e-mail: clint.lane@nau.edu Outline 1. Introduction 2. Safety Aspects 3. Synthesis 4. Physical Properties 5. Theoretical Studies 6. Chemical Properties 7. Synthetic Applications 8. Industrial Applications 9. Conclusions 10. References 1. Introduction Amine-borane complexes have great potential for use as a key component in hydrogen storage fuels due to their stability and the high gravimetric content of hydrogen in these

366

Development of a 5 kW Cooling Capacity Ammonia-water Absorption Chiller for Solar Cooling Applications  

Science Journals Connector (OSTI)

The development of a small capacity absorption chiller and the numerical and experimental results are presented in this paper. The prototype is a thermally driven ammonia-water absorption chiller of 5kW cooling capacity for solar cooling applications. The chiller was developed in an industrial perspective with a goal of overall compactness and using commercially available components. In order to characterize various component technologies and different optimization components, the prototype is monitored with temperature, pressure and mass flow rate accurate sensors. The resulting chiller, characterized by a reduced load in ammonia-water solution and the use of brazed plate heat exchanger, has shown good performance during the preliminary tests. A comparison with the expected numerical results is given.

Franois Boudhenn; Hlne Demasles; Jol Wyttenbach; Xavier Jobard; David Chze; Philippe Papillon

2012-01-01T23:59:59.000Z

367

Integration of an Ammonia-water Absorption Refrigeration System with a Marine Diesel Engine: A Thermodynamic Study  

Science Journals Connector (OSTI)

This paper examines through a thermodynamic analysis the feasibility of using waste heat from marine Diesel engines to drive an ammonia-water absorption refrigeration system. An energy balance of a diesel engine shows that sufficient waste heat is provided. The results illustrate that higher performance of the system is obtained at high generator and evaporator temperatures and also at low condenser and absorber temperatures.

Ahmed Ouadha; Youcef El-Gotni

2013-01-01T23:59:59.000Z

368

Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARP) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution  

E-Print Network [OSTI]

Refinery Waste Heat Ammonia Absorption Refrigeration Plant (WHAARp?) Recovers LPG's and Gasoline, Saves Energy, and Reduces Air Pollution Benjamin Brant Sabine Brueske Donald Erickson Riyaz Papar Planetec Planetec Energy Concepts Company Energy... in Denver, Colorado. The Waste Heat Ammo nia Absorption Refrigeration Plant (WHAARP?) is based on a patented process and cycle design developed by Energy Concepts Co. (ECC) to cost effectively re cover 73,000 barrels a year of salable LPGs and gasoline...

Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

369

Evaluation of autotrophic growth of ammonia-oxidizers associated with granular activated carbon used for drinking water purification byDNA-stable isotope probing  

Science Journals Connector (OSTI)

Abstract Nitrification is an important biological function of granular activated carbon (GAC) used in advanced drinking water purification processes. Newly discovered ammonia-oxidizing archaea (AOA) have challenged the traditional understanding of ammonia oxidation, which considered ammonia-oxidizing bacteria (AOB) as the sole ammonia-oxidizers. Previous studies demonstrated the predominance of AOA on GAC, but the contributions of AOA and AOB to ammonia oxidation remain unclear. In the present study, DNA-stable isotope probing (DNA-SIP) was used to investigate the autotrophic growth of AOA and AOB associated with GAC at two different ammonium concentrations (0.14mgN/L and 1.4mgN/L). GAC samples collected from three full-scale drinking water purification plants in Tokyo, Japan, had different abundance of AOA and AOB. These samples were fed continuously with ammonium and 13C-bicarbonate for 14 days. The DNA-SIP analysis demonstrated that only AOA assimilated 13C-bicarbonate at low ammonium concentration, whereas AOA and AOB exhibited autotrophic growth at high ammonium concentration. This indicates that a lower ammonium concentration is preferable for AOA growth. Since AOA could not grow without ammonium, their autotrophic growth was coupled with ammonia oxidation. Overall, our results point towards an important role of AOA in nitrification in GAC filters treating low concentration of ammonium.

Jia Niu; Ikuro Kasuga; Futoshi Kurisu; Hiroaki Furumai; Takaaki Shigeeda

2013-01-01T23:59:59.000Z

370

Decontamination of an Analytical Laboratory Hot Cell Facility  

SciTech Connect (OSTI)

An Analytical Laboratory Hot Cell Facility at Argonne National Laboratory-West (ANL-W) had been in service for nearly thirty years. In order to comply with current DOE regulations governing such facilities and meet programmatic requirements, a major refurbishment effort was mandated. Due to the high levels of radiation and contamination within the cells, a decontamination effort was necessary to provide an environment that permitted workers to enter the cells to perform refurbishment activities without receiving high doses of radiation and to minimize the potential for the spread of contamination. State-of-the-art decontamination methods, as well as time-proven methods were utilized to minimize personnel exposure as well as maximize results.

Michelbacher, J.A.; Henslee, S.P.; Rosenberg, K.E.; Coleman, R.M.

1995-11-01T23:59:59.000Z

371

Hanford Environmental Analytical Methods (methods of of March 1990). Volume 1  

SciTech Connect (OSTI)

Techniques in use at the Hanford Reservation as of March, 1990 for the analysis of liquids and radioactive effluents are described. Limitations and applications of the techniques are included.

Goheen, S.C.; McCulloch, M.; Daniel, J.L.

1993-05-01T23:59:59.000Z

372

E-Print Network 3.0 - analytical methods methods Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Marine Benthic Ecology and Evolution, Collection: Biology and Medicine ; Environmental Sciences and Ecology 12 Multicriteria analysis problems Multicriteria analysis problem may...

373

Growth of Fe3N films via chemical vapor deposition of iron acetylacetonate and anhydrous ammonia  

Science Journals Connector (OSTI)

Polycrystalline Fe3N films have been grown via chemical vapor deposition (CVD) on 50-?m thick polycrystalline Ti substrates using iron acetylacetonate (IAA) and anhydrous ammonia (NH3) in a cold-wall vertical pancake-style reactor. X-ray diffraction data indicated that single phase Fe3N was present in films deposited at and above 600C; below this temperature no deposition occurred. The composition of the Fe3N films did not vary with changes in the deposition temperature, the NH3 flow rate or the deposition rate at a constant deposition pressure of 100 Torr. The surface macrostructure of the as-deposited films was independent of the deposition temperature and was very similar to that of the uncoated Ti substrate. The microstructure of the films was porous with a thickness variation of ?1 ?m across the surface of the films. Larger grains were produced at 600 and 800C, while smaller and more uniform grains were produced at 700C. Energy dispersive X-ray data indicated that films deposited at and above 600C contained low levels of both carbon and oxygen.

S.L. Roberson; D. Finello; A.D. Banks; R.F. Davis

1998-01-01T23:59:59.000Z

374

Production of silica aerogel microparticles loaded with ammonia borane by batch and semicontinuous supercritical drying techniques  

Science Journals Connector (OSTI)

Abstract Silica aerogel microparticles were prepared by supercritical drying and used as support for hydrogen-storing ammonia borane (AB). The formation of aerogel microparticles was done using two different processes: batch supercritical fluid extraction and a semicontinuous drying process. Silica aerogel microparticles with a surface area ranging from 400 to 800m2/g, a volume of pores of 1cm3/g, and a mean particle diameter ranging from 12 to 27?m were produced using the two drying techniques. The particle size distribution (PSD) of the microparticles was influenced by shear rate, amount of catalyst, hydrophilichydrophobic solvent ratio and hydrophobic surface modification. In particular, irregular aerogel particles were obtained from hydrophilic gels, while regular, spherical particles with smooth surfaces were obtained from hydrophobic gels. AB was loaded into silica aerogel microparticles in concentrations ranging from 1% till 5% wt. Hydrogen release kinetics from the hydride-loaded aerogel was analyzed with a volumetric cell at 80C. By stabilization of AB into the silica aerogel microparticles, an improvement of the release rate of hydrogen from AB was observed.

Miriam Rueda; Luis Miguel Sanz-Moral; Antonio Nieto-Mrquez; Pablo Longone; Facundo Mattea; ngel Martn

2014-01-01T23:59:59.000Z

375

Kinetics Study of Solid Ammonia Borane Hydrogen Release Modeling and Experimental Validation for Chemical Hydrogen Storage  

SciTech Connect (OSTI)

Ammonia borane (AB), NH3BH3, is a promising material for chemical hydrogen storage with 19.6 wt% gravimetric hydrogen capacity of which 16.2 wt% hydrogen can be utilized below 200C. We have investigated the kinetics of hydrogen release from AB and from an AB-methyl cellulose (AB/MC) composite at temperatures of 160-300C using both experiments and modeling. The purpose of our study was to show safe hydrogen release without thermal runaway effects and to validate system model kinetics. AB/MC released hydrogen at ~20C lower than neat AB and at a rate that is two times faster. Based on the experimental results, the kinetics equations were revised to better represent the growth and nucleation process during decomposition of AB. We explored two different reactor concepts; Auger and fixed bed. The current Auger reactor concept turned out to not be appropriate, however, we demonstrated safe self-propagation of the hydrogen release reaction of solid AB/MC in a fixed bed reactor.

Choi, Yong-Joon; Ronnebro, Ewa; Rassat, Scot D.; Karkamkar, Abhijeet J.; Maupin, Gary D.; Holladay, Jamelyn D.; Simmons, Kevin L.; Brooks, Kriston P.

2014-02-24T23:59:59.000Z

376

PLEAEERUSH ANALYTICAL DA-~-A SHEET  

Office of Legacy Management (LM)

' ' PLEAEERUSH ANALYTICAL DA-~-A SHEET ' ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlON 1956 Industrial Hygiene or Medical Dept. 1. H.#~~Sample Nos. 3 --Date Collected~~by-CESS-.Route to CBS LocationTITANIUM Type of Sample airnalyzed for F Alpham Remarks NIAGARA pALI+S* N.Y. U Beta Bldg. 103 - furnace room - -NO, Ra Oil PH Be Th Sample No. Hour Sample Description I I I--- R ) T 1 Q I I I 7392 1100 GA Induction furnace area duri-nn ----l----- mDeriod;.02; 151 .3 while furnace was charged with UOT_- and carbon, and under heat. 7393 / GA Continuation of 7392 I I 7394 GA Continuation of 7393 -I- ----J -___-_-- - ___(_-- I- -~----~ -- ~- __ __ ___ -----.A ri --- - ----_' ---p. ----- __- -. -~-- -~ - 1 - .- -__ -___ -_--__ -___-- I -__-- -- --' II--T---

377

Constrained analytical interrelations in neutrino mixing  

E-Print Network [OSTI]

Hermitian squared mass matrices of charged leptons and light neutrinos in the flavor basis are studied under general additive lowest order perturbations away from the tribimaximal (TBM) limit in which a weak basis with mass diagonal charged leptons is chosen. Simple analytical expressions are found for the three measurable TBM-deviants in terms of perturbation parameters appearing in the neutrino and charged lepton eigenstates in the flavor basis. Taking unnatural cancellations to be absent and charged lepton perturbation parameters to be small, constrained analytical and testable interrelations are derived among neutrino masses, mixing angles and the amount of CP-violation, posing the challenge of verification to forthcoming experiments at the intensity frontier.

Brahmachari, Biswajoy

2014-01-01T23:59:59.000Z

378

Constrained analytical interrelations in neutrino mixing  

E-Print Network [OSTI]

Hermitian squared mass matrices of charged leptons and light neutrinos in the flavor basis are studied under general additive lowest order perturbations away from the tribimaximal (TBM) limit in which a weak basis with mass diagonal charged leptons is chosen. Simple analytical expressions are found for the three measurable TBM-deviants in terms of perturbation parameters appearing in the neutrino and charged lepton eigenstates in the flavor basis. Taking unnatural cancellations to be absent and charged lepton perturbation parameters to be small, constrained analytical and testable interrelations are derived among neutrino masses, mixing angles and the amount of CP-violation, posing the challenge of verification to forthcoming experiments at the intensity frontier.

Biswajoy Brahmachari; Probir Roy

2014-03-09T23:59:59.000Z

379

Analytic solutions of topologically disjoint systems  

E-Print Network [OSTI]

We describe a procedure to solve an up to $2N$ problem where the particles are separated topologically in $N$ groups with at most two particles in each. Arbitrary interactions are allowed between the (two) particles within one group. All other interactions are approximated by harmonic oscillator potentials. The problem is first reduced to an analytically solvable $N$-body problem and $N$ independent two-body problems. We calculate analytically spectra, wave functions, and normal modes for both the inverse square and delta-function two-body interactions. In particular, we calculate separation energies between two strings of particles. We find that the string separation energy increases with $N$ and interaction strength.

J. R. Armstrong; A. G. Volosniev; D. V. Fedorov; A. S. Jensen; N. T. Zinner

2015-01-29T23:59:59.000Z

380

Analytical model for Stirling cycle machine design  

E-Print Network [OSTI]

In order to study further the promising free piston Stirling engine architecture, there is a need of an analytical thermodynamic model which could be used in a dynamical analysis for preliminary design. To aim at more realistic values, the models have to take into account the heat losses and irreversibilities on the engine. An analytical model which encompasses the critical flaws of the regenerator and furthermore the heat exchangers effectivenesses has been developed. This model has been validated using the whole range of the experimental data available from the General Motor GPU-3 Stirling engine prototype. The effects of the technological and operating parameters on Stirling engine performance have been investigated. In addition to the regenerator influence, the effect of the cooler effectiveness is underlined.

Formosa, Fabien; 10.1016/j.enconman.2010.02.010

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

BN Bonded BN fiber article and method of manufacture  

DOE Patents [OSTI]

A boron nitride bonded boron nitride fiber article and the method for its manufacture which comprises forming a shaped article with a composition comprising a bonding compound selected from boron oxide and boric acid and a structural fiber selected from the group consisting of boron oxide, boron nitride and partially nitrided boron oxide fibers, heating the composition in an anhydrous gas to a temperature above the melting point of the compound and nitriding the resulting article in ammonia gas.

Hamilton, Robert S. (Youngstown, NY)

1981-08-18T23:59:59.000Z

382

Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts  

SciTech Connect (OSTI)

Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1999-09-10T23:59:59.000Z

383

Visual Analytics and Storytelling through Video  

SciTech Connect (OSTI)

This paper supplements a video clip submitted to the Video Track of IEEE Symposium on Information Visualization 2005. The original video submission applies a two-way storytelling approach to demonstrate the visual analytics capabilities of a new visualization technique. The paper presents our video production philosophy, describes the plot of the video, explains the rationale behind the plot, and finally, shares our production experiences with our readers.

Wong, Pak C.; Perrine, Kenneth A.; Mackey, Patrick S.; Foote, Harlan P.; Thomas, Jim

2005-10-31T23:59:59.000Z

384

Human performance modeling for system of systems analytics.  

SciTech Connect (OSTI)

A Laboratory-Directed Research and Development project was initiated in 2005 to investigate Human Performance Modeling in a System of Systems analytic environment. SAND2006-6569 and SAND2006-7911 document interim results from this effort; this report documents the final results. The problem is difficult because of the number of humans involved in a System of Systems environment and the generally poorly defined nature of the tasks that each human must perform. A two-pronged strategy was followed: one prong was to develop human models using a probability-based method similar to that first developed for relatively well-understood probability based performance modeling; another prong was to investigate more state-of-art human cognition models. The probability-based modeling resulted in a comprehensive addition of human-modeling capability to the existing SoSAT computer program. The cognitive modeling resulted in an increased understanding of what is necessary to incorporate cognition-based models to a System of Systems analytic environment.

Dixon, Kevin R.; Lawton, Craig R.; Basilico, Justin Derrick; Longsine, Dennis E. (INTERA, Inc., Austin, TX); Forsythe, James Chris; Gauthier, John Henry; Le, Hai D.

2008-10-01T23:59:59.000Z

385

Predicting Student Success using Analytics in Course Learning Management Systems  

SciTech Connect (OSTI)

Educational data analytics is an emerging discipline, concerned with developing methods for exploring the unique types of data that come from the educational context. For example, predicting college student performance is crucial for both the student and educational institutions. It can support timely intervention to prevent students from failing a course, increasing efficacy of advising functions, and improving course completion rate. In this paper, we present the efforts carried out at Oak Ridge National Laboratory (ORNL) toward conducting predictive analytics to academic data collected from 2009 through 2013 and available in one of the most commonly used learning management systems, called Moodle. First, we have identified the data features useful for predicting student outcomes such as students scores in homework assignments, quizzes, exams, in addition to their activities in discussion forums and their total GPA at the same term they enrolled in the course. Then, Logistic Regression and Neural Network predictive models are used to identify students as early as possible that are in danger of failing the course they are currently enrolled in. These models compute the likelihood of any given student failing (or passing) the current course. Numerical results are presented to evaluate and compare the performance of the developed models and their predictive accuracy.

Olama, Mohammed M [ORNL] [ORNL; Thakur, Gautam [ORNL] [ORNL; McNair, Wade [ORNL] [ORNL; Sukumar, Sreenivas R [ORNL] [ORNL

2014-01-01T23:59:59.000Z

386

Model and Analytic Processes for Export License Assessments  

SciTech Connect (OSTI)

This paper represents the Department of Energy Office of Nonproliferation Research and Development (NA-22) Simulations, Algorithms and Modeling (SAM) Program's first effort to identify and frame analytical methods and tools to aid export control professionals in effectively predicting proliferation intent; a complex, multi-step and multi-agency process. The report focuses on analytical modeling methodologies that alone, or combined, may improve the proliferation export control license approval process. It is a follow-up to an earlier paper describing information sources and environments related to international nuclear technology transfer. This report describes the decision criteria used to evaluate modeling techniques and tools to determine which approaches will be investigated during the final 2 years of the project. The report also details the motivation for why new modeling techniques and tools are needed. The analytical modeling methodologies will enable analysts to evaluate the information environment for relevance to detecting proliferation intent, with specific focus on assessing risks associated with transferring dual-use technologies. Dual-use technologies can be used in both weapons and commercial enterprises. A decision-framework was developed to evaluate which of the different analytical modeling methodologies would be most appropriate conditional on the uniqueness of the approach, data availability, laboratory capabilities, relevance to NA-22 and Office of Arms Control and Nonproliferation (NA-24) research needs and the impact if successful. Modeling methodologies were divided into whether they could help micro-level assessments (e.g., help improve individual license assessments) or macro-level assessment. Macro-level assessment focuses on suppliers, technology, consumers, economies, and proliferation context. Macro-level assessment technologies scored higher in the area of uniqueness because less work has been done at the macro level. An approach to developing testable hypotheses for the macro-level assessment methodologies is provided. The outcome of this works suggests that we should develop a Bayes Net for micro-level analysis and continue to focus on Bayes Net, System Dynamics and Economic Input/Output models for assessing macro-level problems. Simultaneously, we need to develop metrics for assessing intent in export control, including the risks and consequences associated with all aspects of export control.

Thompson, Sandra E.; Whitney, Paul D.; Weimar, Mark R.; Wood, Thomas W.; Daly, Don S.; Brothers, Alan J.; Sanfilippo, Antonio P.; Cook, Diane; Holder, Larry

2011-09-29T23:59:59.000Z

387

An Interactive Visual Analytics Framework for Multi-Field Data...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interactive Visual Analytics Framework for Multi-Field Data in a Geo-Spatial Context. An Interactive Visual Analytics Framework for Multi-Field Data in a Geo-Spatial Context....

388

NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL...  

Office of Legacy Management (LM)

J &' fi -35-24 saps RUSH NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET ULO-n&s-736 (REV. 8u591 -----" . . . , -.-.-- ....

389

The rigid analytical regulator and K_2 of Drinfeld modular curves.  

E-Print Network [OSTI]

We evaluate a rigid analytical analogue of the Beilinson-Bloch-Deligne regulator on certain explicit elements in the K_2 of Drinfeld modular curves, constructed from analogues of modular units, and relate its value to special values of L-series using the Rankin-Selberg method.

Ambrus Pal

390

validation_vs66_fe_and_analytical_dry.eps  

E-Print Network [OSTI]

Page 1. 0. 50. 100. 150. 2. Frequency (Hz). 800. 1000. 1200. 1400. Phase velocity (m/s). Numerical. Analytical.

santos

391

Photovoltaic Degradation Rates -- An Analytical Review  

SciTech Connect (OSTI)

As photovoltaic penetration of the power grid increases, accurate predictions of return on investment require accurate prediction of decreased power output over time. Degradation rates must be known in order to predict power delivery. This article reviews degradation rates of flat-plate terrestrial modules and systems reported in published literature from field testing throughout the last 40 years. Nearly 2000 degradation rates, measured on individual modules or entire systems, have been assembled from the literature, showing a median value of 0.5%/year. The review consists of three parts: a brief historical outline, an analytical summary of degradation rates, and a detailed bibliography partitioned by technology.

Jordan, D. C.; Kurtz, S. R.

2012-06-01T23:59:59.000Z

392

Logical and Analytic Truths That Are Not Edward N. Zalta  

E-Print Network [OSTI]

are consequences of the tradi- tional conception of logical truth, analytic truth, and necessity: (1Logical and Analytic Truths That Are Not Necessary Edward N. Zalta Center for the Study of Language and Information Stanford University The notions of logical truth, analytic truth, and necessary truth

Zalta, Edward N.

393

PLJ3ASE RUSH ANALYTICAL DATA SHEET  

Office of Legacy Management (LM)

+-L3-+. I +-L3-+. I PLJ3ASE RUSH -- ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HULTH AND SAFETY DIVISIDN 1956 lnd&rial Hyglono or Mediul Dept. I. H.# 929 Sample Nor-ato Colloctod-6/14byARouto to- ' a Location @kUEN WWH CO- 1~ : Jypo Alphau Rama& NUWOOD. WI0 "' of Samplo_nirduslf__Analyzed for F U Beta Stamping wrahor8.fm jqtip6 of U heated in 900° P salt No Ro 5 bath. ' :,.a r ' .. ? ' ). ;..- *fhv 11 $- n _... .I < Oil 3 PH kmph No. . . , r, . Hour *- SImplr Description Be Th jR(T(Q 6375 1144 GA Pre66 area durinn stamina of 14 I a .16 I I I wa8her8. I I I 1 fl&ed off very rapidly. One waahcr mug& fir I + 1.: $. (! ., I I I~NJA~WICAL UBORATORY MPAII' IMENT (RCCOaD COW) 3.MEDICAL DEPARTMENT Z.INDUSTRIAL HYGIENE DEPARTMENT 4-DIRECTOR OF WEALTH b

394

ANALYTICAL STAR FORMATION RATE FROM GRAVOTURBULENT FRAGMENTATION  

SciTech Connect (OSTI)

We present an analytical determination of the star formation rate (SFR) in molecular clouds, based on a time-dependent extension of our analytical theory of the stellar initial mass function. The theory yields SFRs in good agreement with observations, suggesting that turbulence is the dominant, initial process responsible for star formation. In contrast to previous SFR theories, the present one does not invoke an ad hoc density threshold for star formation; instead, the SFR continuously increases with gas density, naturally yielding two different characteristic regimes, thus two different slopes in the SFR versus gas density relationship, in agreement with observational determinations. Besides the complete SFR derivation, we also provide a simplified expression, which reproduces the complete calculations reasonably well and can easily be used for quick determinations of SFRs in cloud environments. A key property at the heart of both our complete and simplified theory is that the SFR involves a density-dependent dynamical time, characteristic of each collapsing (prestellar) overdense region in the cloud, instead of one single mean or critical freefall timescale. Unfortunately, the SFR also depends on some ill-determined parameters, such as the core-to-star mass conversion efficiency and the crossing timescale. Although we provide estimates for these parameters, their uncertainty hampers a precise quantitative determination of the SFR, within less than a factor of a few.

Hennebelle, Patrick [Laboratoire de Radioastronomie, UMR CNRS 8112, Ecole Normale Superieure et Observatoire de Paris, 24 rue Lhomond, 75231 Paris Cedex 05 (France); Chabrier, Gilles [Ecole Normale Superieure de Lyon, CRAL, UMR CNRS 5574, 69364 Lyon Cedex 07 (France)

2011-12-20T23:59:59.000Z

395

Visual Analytics for Power Grid Contingency Analysis  

SciTech Connect (OSTI)

Contingency analysis is the process of employing different measures to model scenarios, analyze them, and then derive the best response to remove the threats. This application paper focuses on a class of contingency analysis problems found in the power grid management system. A power grid is a geographically distributed interconnected transmission network that transmits and delivers electricity from generators to end users. The power grid contingency analysis problem is increasingly important because of both the growing size of the underlying raw data that need to be analyzed and the urgency to deliver working solutions in an aggressive timeframe. Failure to do so may bring significant financial, economic, and security impacts to all parties involved and the society at large. The paper presents a scalable visual analytics pipeline that transforms about 100 million contingency scenarios to a manageable size and form for grid operators to examine different scenarios and come up with preventive or mitigation strategies to address the problems in a predictive and timely manner. Great attention is given to the computational scalability, information scalability, visual scalability, and display scalability issues surrounding the data analytics pipeline. Most of the large-scale computation requirements of our work are conducted on a Cray XMT multi-threaded parallel computer. The paper demonstrates a number of examples using western North American power grid models and data.

Wong, Pak C.; Huang, Zhenyu; Chen, Yousu; Mackey, Patrick S.; Jin, Shuangshuang

2014-01-20T23:59:59.000Z

396

Immunoassay, biosensors and other nonchromatographic methods  

E-Print Network [OSTI]

. Gee and Bruce D. Hammock pp. 623­679 in Handbook of Residue Analytical Methods for Agrochemicals (ISBN for Agrochemicals. C 2003 John Wiley & Sons Ltd. #12;624 Recent advances in analytical technology, immunoassay the potential for ELISA for agrochemicals and environmental pollutants. Since then, the use of immunoassay

Hammock, Bruce D.

397

An Approximate Analytical Algorithm for Evaluating the Distances in a Dark Energy Dominated Universe  

E-Print Network [OSTI]

The most recent cosmological observations indicate that the present universe is flat and vacuum dominated. In such a universe, the distance measurements are always difficult and involve numerical computations. In this paper, it is shown that the most fundamental distance measurement of cosmology, the luminosity distance, for such a universe can be obtained in an approximate analytical way with very small errors of less than 0.02% up to %z = 5$ for any value of vacuum energy. The analytical calculation is shown to be exceedingly efficient, as compared to the traditional numerical methods.

T. Wickramasinghe

2007-12-05T23:59:59.000Z

398

Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB),  

Broader source: Energy.gov (indexed) [DOE]

Immobilization Plant (WTP) Analytical Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Full Document and Summary Versions are available for download Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Summary - WTP Analytical Lab, BOF and LAW Waste Vitrification Facilities More Documents & Publications Waste Treatment and Immobilation Plant HLW Waste Vitrification Facility Waste Treatment and Immobilation Plant Pretreatment Facility Compilation of TRA Summaries

399

Analytical evaluation of the lattice Green function for the face centered cubic lattice  

E-Print Network [OSTI]

An efficient calculation method is proposed for the face centered cubic (FCC) lattice Green function. The method is based on binomial expansion theorems, which is provide us establish analytical formulae through simple basic integrals. The resulting series present better convergence rates. Several acceleration techniques are combined to further improve the efficiency. The obtained results for the lattice Green function are in good agreement with the known numerical calculation results.

B. A. Mamedov

2012-05-07T23:59:59.000Z

400

Ammonia-Borane under High Pressure - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 4 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Jiuhua Chen (Primary Contact), Shah Najiba, Yongzhou Sun, Jennifer Girard, Vadym Drozd Center for the Study of Matters at Extreme Conditions Department of Mechanical and Materials Engineering Florida International University 11200 SW 8 th Street Miami, FL 33199 Phone: (305) 348-3140 Email: chenj@fiu.edu DOE Program Officer: Dr. Lane Wilson Phone: (301) 903-5877 Email: Lane.Wilson@science.doe.gov Subcontractor: Wendy Mao, Stanford University Objectives Understand pressure influence on the structure, phase * stability, dehydrogenation of ammonia borane and its

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401

OCIO Technology Summit: Data Analytics | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OCIO Technology Summit: Data Analytics OCIO Technology Summit: Data Analytics OCIO Technology Summit: Data Analytics May 13, 2013 - 1:51pm Addthis OCIO Technology Summit: Data Analytics The Energy Department's Office of the Chief Information Officer hosted a Data Analytics Technology Summit to showcase how the agency is using data analytics to make better data-driven decisions, provide value, and ultimately create mission impact. Data scientists and practitioners from Lawrence Livermore National Laboratory are using data analytics to secure information, and as a result have real-time detection capabilities for cyber attacks and intrusions giving the Department the ability to protect its data. Our partners at the Energy Information Administration demonstrated the Electricity Data Browser influence on creating the visualization of data,

402

An Analytical Study Of A 2-Layer Transient Thermal Conduction Problem As  

Open Energy Info (EERE)

Analytical Study Of A 2-Layer Transient Thermal Conduction Problem As Analytical Study Of A 2-Layer Transient Thermal Conduction Problem As Applied To Soil-Temperature Surveys Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Analytical Study Of A 2-Layer Transient Thermal Conduction Problem As Applied To Soil-Temperature Surveys Details Activities (0) Areas (0) Regions (0) Abstract: The soil temperature survey is an inexpensive exploration method in groundwater and geothermal resource investigations. In its simplest form, temperatures measured in shallow holes are analyzed to deduce variations in material properties. Typical interpretation schemes are based on simple, one-layer solutions to the Fourier conduction equation using the annual solar cycle as a surface heat source. We present a solution to the

403

Aptamer- and nucleic acid enzyme-based systems for simultaneous detection of multiple analytes  

DOE Patents [OSTI]

The present invention provides aptamer- and nucleic acid enzyme-based systems for simultaneously determining the presence and optionally the concentration of multiple analytes in a sample. Methods of utilizing the system and kits that include the sensor components are also provided. The system includes a first reactive polynucleotide that reacts to a first analyte; a second reactive polynucleotide that reacts to a second analyte; a third polynucleotide; a fourth polynucleotide; a first particle, coupled to the third polynucleotide; a second particle, coupled to the fourth polynucleotide; and at least one quencher, for quenching emissions of the first and second quantum dots, coupled to the first and second reactive polynucleotides. The first particle includes a quantum dot having a first emission wavelength. The second particle includes a second quantum dot having a second emission wavelength different from the first emission wavelength. The third polynucleotide and the fourth polynucleotide are different.

Lu, Yi (Champaign, IL); Liu, Juewen (Albuquerque, NM)

2011-11-15T23:59:59.000Z

404

Analytical Improvements in PV Degradation Rate Determination  

SciTech Connect (OSTI)

As photovoltaic (PV) penetration of the power grid increases, it becomes vital to know how decreased power output may affect cost over time. In order to predict power delivery, the decline or degradation rates must be determined accurately. For non-spectrally corrected data several complete seasonal cycles (typically 3-5 years) are required to obtain reasonably accurate degradation rates. In a rapidly evolving industry such a time span is often unacceptable and the need exists to determine degradation rates accurately in a shorter period of time. Occurrence of outliers and data shifts are two examples of analytical problems leading to greater uncertainty and therefore to longer observation times. In this paper we compare three methodologies of data analysis for robustness in the presence of outliers, data shifts and shorter measurement time periods.

Jordan, D. C.; Kurtz, S. R.

2011-02-01T23:59:59.000Z

405

Laser ablation in analytical chemistry - A review  

SciTech Connect (OSTI)

Laser ablation is becoming a dominant technology for direct solid sampling in analytical chemistry. Laser ablation refers to the process in which an intense burst of energy delivered by a short laser pulse is used to sample (remove a portion of) a material. The advantages of laser ablation chemical analysis include direct characterization of solids, no chemical procedures for dissolution, reduced risk of contamination or sample loss, analysis of very small samples not separable for solution analysis, and determination of spatial distributions of elemental composition. This review describes recent research to understand and utilize laser ablation for direct solid sampling, with emphasis on sample introduction to an inductively coupled plasma (ICP). Current research related to contemporary experimental systems, calibration and optimization, and fractionation is discussed, with a summary of applications in several areas.

Russo, Richard E.; Mao, Xianglei; Liu, Haichen; Gonzalez, Jhanis; Mao, Samuel S.

2001-10-10T23:59:59.000Z

406

Astrophysical bow shocks: An analytical solution for the hypersonic blunt body problem in the intergalactic medium  

E-Print Network [OSTI]

Aims: Bow shock waves are a common feature of groups and clusters of galaxies since they are generated as a result of supersonic motion of galaxies through the intergalactic medium. The goal of this work is to present an analytical solution technique for such astrophysical hypersonic blunt body problems. Methods: A method, developed by Schneider (1968, JFM, 31, 397) in the context of aeronautics, allows calculation of the galaxy's shape as long as the shape of the bow shock wave is known (so-called inverse method). In contrast to other analytical models, the solution is valid in the whole flow region (from the stagnation point up to the bow shock wings) and in particular takes into account velocity gradients along the streamlines. We compare our analytical results with two-dimensional hydrodynamical simulations carried out with an extended version of the VH-1 hydrocode which is based on the piecewise parabolic method with a Lagrangian remap. Results: It is shown that the applied method accurately predicts the...

Schulreich, Michael Mathias

2011-01-01T23:59:59.000Z

407

Multi-attribute evaluation and selection of sites for agricultural product warehouses based on an Analytic Hierarchy Process  

Science Journals Connector (OSTI)

Site selection for companies is a complex and unstructured problem that must be analyzed carefully and properly, since a localization error could drive to bankrupt. This problem has been discussed widely and effectively using multi-attribute methods ... Keywords: Analytic Hierarchy Process, Multi-criteria and Multi-attribute methods in agribusiness, Site selection attributes, Site selection problem

J. L. Garca; A. Alvarado; J. Blanco; E. Jimnez; A. A. Maldonado; G. Corts

2014-01-01T23:59:59.000Z

408

EA-0970: Environmental Safety and Health Analytical Laboratory Project No.  

Broader source: Energy.gov (indexed) [DOE]

70: Environmental Safety and Health Analytical Laboratory 70: Environmental Safety and Health Analytical Laboratory Project No. 94-AA-01 Pantex Plant, Amarillo, Texas EA-0970: Environmental Safety and Health Analytical Laboratory Project No. 94-AA-01 Pantex Plant, Amarillo, Texas SUMMARY This EA evaluates the environmental impacts of the proposal to construct and operate an Environmental Safety and Health Analytical Laboratory and subsequent demolition of the existing Analytical Chemistry Laboratory building at the U.S. Department of Energy's Pantex Plant near Amarillo, Texas. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD July 6, 1995 EA-0970: Finding of No Significant Impact Environmental Safety and Health Analytical Laboratory Project No. 94-AA-01 Pantex Plant Amarillo, TX

409

Analytic energy gradients for constrained DFT-configuration interaction  

SciTech Connect (OSTI)

The constrained density functional theory-configuration interaction (CDFT-CI) method has previously been used to calculate ground-state energies and barrier heights, and to describe electronic excited states, in particular conical intersections. However, the method has been limited to evaluating the electronic energy at just a single nuclear configuration, with the gradient of the energy being available only via finite difference. In this paper, we present analytic gradients of the CDFT-CI energy with respect to nuclear coordinates, which gives the potential for accurate geometry optimization and molecular dynamics on both the ground and excited electronic states, a realm which is currently quite challenging for electronic structure theory. We report the performance of CDFT-CI geometry optimization for representative reaction transition states as well as molecules in an excited state. The overall accuracy of CDFT-CI for computing barrier heights is essentially unchanged whether the energies are evaluated at geometries obtained from quadratic configuration-interaction singles and doubles (QCISD) or CDFT-CI, indicating that CDFT-CI produces very good reaction transition states. These results open up tantalizing possibilities for future work on excited states.

Kaduk, Benjamin; Tsuchimochi, Takashi; Van Voorhis, Troy, E-mail: tvan@mit.edu [Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States)

2014-05-14T23:59:59.000Z

410

Mathematica and Fortran programs for various analytic QCD couplings  

E-Print Network [OSTI]

We outline here the motivation for the existence of analytic QCD models, i.e., QCD frameworks in which the running coupling $A(Q^2)$ has no Landau singularities. The analytic (holomorphic) coupling $A(Q^2)$ is the analog of the underlying pQCD coupling $a(Q^2) \\equiv \\alpha_s(Q^2)/\\pi$, and any such $A(Q^2)$ defines an analytic QCD model. We present the general construction procedure for the couplings $A_{\

Cesar Ayala; Gorazd Cvetic

2014-11-06T23:59:59.000Z

411

Mathematica and Fortran programs for various analytic QCD couplings  

E-Print Network [OSTI]

We outline here the motivation for the existence of analytic QCD models, i.e., QCD frameworks in which the running coupling $A(Q^2)$ has no Landau singularities. The analytic (holomorphic) coupling $A(Q^2)$ is the analog of the underlying pQCD coupling $a(Q^2) \\equiv \\alpha_s(Q^2)/\\pi$, and any such $A(Q^2)$ defines an analytic QCD model. We present the general construction procedure for the couplings $A_{\

Ayala, Cesar

2014-01-01T23:59:59.000Z

412

PRELIMINARY SURVEY OF WINCHESTER ENGINEERING AND ANALYTICAL CENTER  

Office of Legacy Management (LM)

WINCHESTER ENGINEERING AND ANALYTICAL CENTER WINCHESTER ENGINEERING AND ANALYTICAL CENTER Winchester, Massachusetts Work performed by the Health and Safety Research Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830 March 1980 . .- _ 2. / f OAK RIDGE NATIONAL LABORATORY operated by UNION CARBIDE CORPOdATIOt'i for the DEPARTMENT OF ENERGY as part of the Formerly Utilized Sites-- Remedial Action PL;ogram .-__ - - .--..--_ ~. _.. -. THE FORMER WINCHESTER ENGINEERING AND ANALYTICAL CENTER Winchester, Massachusetts At the request of the Department of Energy (DOE, then ERDA), a preliminary survey was performed at the former Winchester Engineering and Analytical Center, Winchester, Massachusetts (see Fig. 1), on January 25, 1977, to assess the radiological status of this facility

413

The Development of the Functional Analytic Psychotherapy Intimacy Scale  

Science Journals Connector (OSTI)

Functional analytic psychotherapy (FAP) is a contextual behavior therapy that targets idiographic behaviors relevant to interpersonal functioning. FAP often targets issues with intimacy, defined as behavior ex...

Rachel C. Leonard; Lindsey E. Knott; Eric B. Lee; Sonia Singh

2014-12-01T23:59:59.000Z

414

Determination of Ash in Biomass: Laboratory Analytical Procedure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ash in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, B. Hames, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NREL...

415

Analytical Modeling At Lightning Dock Geothermal Area (Brook...  

Open Energy Info (EERE)

Modeling At Lightning Dock Geothermal Area (Brook, Et Al., 1978) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Analytical Modeling At Lightning...

416

Analytical Modeling At Valles Caldera - Redondo Geothermal Area...  

Open Energy Info (EERE)

Analytical Modeling At Valles Caldera - Redondo Geothermal Area (White, 1986) Exploration Activity Details Location Valles Caldera - Redondo Geothermal Area Exploration Technique...

417

Detection of Low Volatility Organic Analytes on Soils Using Infrared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Low Volatility Organic Analytes on Soils Using Infrared Reflection Spectroscopy. Abstract: Previous work on detection of low-volatility liquid organic (and...

418

EVALUATION OF AEROSOL EMISSIONS DOWNSTREAM OF AN AMMONIA-BASED SO2 SCRUBBER  

SciTech Connect (OSTI)

Depending on the size and type of boiler, the 1990 Clean Air Act Amendments required specific reductions in SO{sub 2} emissions from coal-fired electric utilities. To meet these requirements, SO{sub 2} reduction strategies have included installing scrubbing technology, switching to a more expensive low-sulfur coal, or purchasing SO{sub 2} allowances. It is expected that over the next 10 years there will be an increase in the price of low-sulfur coals, but that higher-sulfur coal costs will remain the same. Technologies must be strongly considered that allow the use of high-sulfur fuels while at the same time meeting current and future SO{sub 2} emission limits. One such technology is the ammonia based flue gas desulfurization (FGD) (NH{sub 3}-based FGD) system manufactured by Marsulex Environmental Technologies (MET). The MET scrubber is a patented NH{sub 3}-based FGD process that efficiently converts SO{sub 2} (>95%) into a fertilizer product, ammonium sulfate ([NH{sub 4}]{sub 2}SO{sub 4}). A point of concern for the MET technology, as well as other FGD systems, is the emission of sulfuric acid/SO{sub 3} aerosols that could result in increased opacity at the stack. This is a direct result of firing high-sulfur fuels that naturally generate more SO{sub 3} than do low-sulfur coals. SO{sub 3} is formed during the coal combustion process. SO{sub 3} is converted to gaseous H{sub 2}SO{sub 4} by homogeneous condensation, leading to a submicron acid fume that is very difficult to capture in a dry electrostatic precipitator (ESP). The condensed acid can also combine with the fly ash in the duct and scale the duct wall, potentially resulting in corrosion of both metallic and nonmetallic surfaces. Therefore, SO{sub 3} in flue gas can have a significant impact on the performance of coal-fired utility boilers, air heaters, and ESPs. In addition to corrosion problems, excess SO{sub 3} emissions can result in plume opacity problems. Thus the Energy & Environmental Research Center (EERC) was contracted by MET and the U.S. Department of Energy (DOE) to evaluate the potential of a wet ESP for reducing SO{sub 3} emissions. The work consisted of pilot-scale tests using the EERC's slagging furnace system (SFS) to determine the effectiveness of a wet ESP to control SO{sub 3}/H{sub 2}SO{sub 4} aerosol emissions in conjunction with a dry ESP and MET's NH{sub 3}-based FGD. Because these compounds are in the form of fine particles, it is speculated that a relatively small, highly efficient wet ESP following the MET scrubber would remove these fine aerosol particles. The performance target for the wet ESP was a particulate mass collection efficiency of >90%; this level of performance would likely ensure a stack opacity of <10%.

Dennis L. Laudal

2002-04-01T23:59:59.000Z

419

Guided Text Search Using Adaptive Visual Analytics  

SciTech Connect (OSTI)

This research demonstrates the promise of augmenting interactive visualizations with semi- supervised machine learning techniques to improve the discovery of significant associations and insights in the search and analysis of textual information. More specifically, we have developed a system called Gryffin that hosts a unique collection of techniques that facilitate individualized investigative search pertaining to an ever-changing set of analytical questions over an indexed collection of open-source documents related to critical national infrastructure. The Gryffin client hosts dynamic displays of the search results via focus+context record listings, temporal timelines, term-frequency views, and multiple coordinate views. Furthermore, as the analyst interacts with the display, the interactions are recorded and used to label the search records. These labeled records are then used to drive semi-supervised machine learning algorithms that re-rank the unlabeled search records such that potentially relevant records are moved to the top of the record listing. Gryffin is described in the context of the daily tasks encountered at the US Department of Homeland Security s Fusion Center, with whom we are collaborating in its development. The resulting system is capable of addressing the analysts information overload that can be directly attributed to the deluge of information that must be addressed in the search and investigative analysis of textual information.

Steed, Chad A [ORNL; Symons, Christopher T [ORNL; Senter, James K [ORNL; DeNap, Frank A [ORNL

2012-10-01T23:59:59.000Z

420

Simple analytic model for astrophysical S factors  

SciTech Connect (OSTI)

We propose a physically transparent analytic model of astrophysical S factors as a function of a center-of-mass energy E of colliding nuclei (below and above the Coulomb barrier) for nonresonant fusion reactions. For any given reaction, the S(E) model contains four parameters [two of which approximate the barrier potential, U(r)]. They are easily interpolated along many reactions involving isotopes of the same elements; they give accurate practical expressions for S(E) with only several input parameters for many reactions. The model reproduces the suppression of S(E) at low energies (of astrophysical importance) due to the shape of the low-r wing of U(r). The model can be used to reconstruct U(r) from computed or measured S(E). For illustration, we parametrize our recent calculations of S(E) (using the Sao Paulo potential and the barrier penetration formalism) for 946 reactions involving stable and unstable isotopes of C, O, Ne, and Mg (with nine parameters for all reactions involving many isotopes of the same elements, e.g., C+O). In addition, we analyze astrophysically important {sup 12}C+{sup 12}C reaction, compare theoretical models with experimental data, and discuss the problem of interpolating reliably known S(E) values to low energies (E < or approx. 2-3 MeV).

Yakovlev, D. G.; Beard, M.; Gasques, L. R.; Wiescher, M. [Ioffe Physical Technical Institute, Poliekhnicheskaya 26, 194021 St. Petersburg (Russian Federation); Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Laboratorio Pelletron, Instituto de Fisica da Universidade de Sao Paulo, 05315-970, Sao Paulo, SP (Brazil); Department of Physics and The Joint Institute for Nuclear Astrophysics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

2010-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Data Intensive Architecture for Scalable Cyber Analytics  

SciTech Connect (OSTI)

Cyber analysts are tasked with the identification and mitigation of network exploits and threats. These compromises are difficult to identify due to the characteristics of cyber communication, the volume of traffic, and the duration of possible attack. In this paper, we describe a prototype implementation designed to provide cyber analysts an environment where they can interactively explore a months worth of cyber security data. This prototype utilized On-Line Analytical Processing (OLAP) techniques to present a data cube to the analysts. The cube provides a summary of the data, allowing trends to be easily identified as well as the ability to easily pull up the original records comprising an event of interest. The cube was built using SQL Server Analysis Services (SSAS), with the interface to the cube provided by Tableau. This software infrastructure was supported by a novel hardware architecture comprising a Netezza TwinFin for the underlying data warehouse and a cube server with a FusionIO drive hosting the data cube. We evaluated this environment on a months worth of artificial, but realistic, data using multiple queries provided by our cyber analysts. As our results indicate, OLAP technology has progressed to the point where it is in a unique position to provide novel insights to cyber analysts, as long as it is supported by an appropriate data intensive architecture.

Olsen, Bryan K.; Johnson, John R.; Critchlow, Terence J.

2011-12-19T23:59:59.000Z

422

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents [OSTI]

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

423

J. Phys.: Condens. Matter 11 (1999) 833845. Printed in the UK PII: S0953-8984(99)96581-5 Structural and magnetic properties of ammonia-nitrided  

E-Print Network [OSTI]

J. Phys.: Condens. Matter 11 (1999) 833­845. Printed in the UK PII: S0953-8984(99)96581-5 Structural and magnetic properties of ammonia-nitrided Y2Fe17 N X Shen, J I Budnick, W A Hines, Y D Zhang, D of Connecticut, Storrs, CT 06269, USA Department of Physics, College of the Holy Cross, Worcester, MA 01610, USA

Yang, De-Ping

424

Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts  

E-Print Network [OSTI]

The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow reactor was investigated...

Oh, Hyuk Jin

2004-09-30T23:59:59.000Z

425

Terahertz Vibration?Rotation?Tunneling Spectroscopy of the Ammonia Dimer. II. A?E States of an Out-of-Plane Vibration and an In-Plane Vibration  

Science Journals Connector (OSTI)

Terahertz Vibration?Rotation?Tunneling Spectroscopy of the Ammonia Dimer. ... In order to proceed toward the ultimate goal of determining an accurate intermolecular potential surface like what has been done for the water dimer, it is necessary to thoroughly characterize the intermolecular vibrations. ... The ab initio harmonic vibrational frequencies are known to be often too high for the weakly bound systems. ...

Wei Lin; Jia-xiang Han; Lynelle K. Takahashi; Jennifer G. Loeser; Richard J. Saykally

2007-09-07T23:59:59.000Z

426

Forecasting hotspots using predictive visual analytics approach  

SciTech Connect (OSTI)

A method for forecasting hotspots is provided. The method may include the steps of receiving input data at an input of the computational device, generating a temporal prediction based on the input data, generating a geospatial prediction based on the input data, and generating output data based on the time series and geospatial predictions. The output data may be configured to display at least one user interface at an output of the computational device.

Maciejewski, Ross; Hafen, Ryan; Rudolph, Stephen; Cleveland, William; Ebert, David

2014-12-30T23:59:59.000Z

427

Managing Complex Network Operation with Predictive Analytics  

SciTech Connect (OSTI)

Complex networks play an important role in modern societies. Their failures, such as power grid blackouts, would lead to significant disruption of peoples life, industry and commercial activities, and result in massive economic losses. Operation of these complex networks is an extremely challenging task due to their complex structures, wide geographical coverage, complex data/information technology systems, and highly dynamic and nonlinear behaviors. None of the complex network operation is fully automated; human-in-the-loop operation is critical. Given the complexity involved, there may be thousands of possible topological configurations at any given time. During an emergency, it is not uncommon for human operators to examine thousands of possible configurations in near real-time to choose the best option and operate the network effectively. In todays practice, network operation is largely based on experience with very limited real-time decision support, resulting in inadequate management of complex predictions and inability to anticipate, recognize, and respond to situations caused by human errors, natural disasters, and cyber attacks. A systematic approach is needed to manage the complex operation paradigms and choose the best option in a near-real-time manner. This paper applies predictive analytics techniques to establish a decision support system for complex network operation management and help operators to predict potential network failures and adapt the network to adverse situations. The resultant decision support system enables continuous monitoring of network performance and turns large amounts of data into actionable information. Examples with actual power grid data are presented to demonstrate the capability of this proposed decision support system.

Huang, Zhenyu; Wong, Pak C.; Mackey, Patrick S.; Chen, Yousu; Ma, Jian; Schneider, Kevin P.; Greitzer, Frank L.

2008-03-26T23:59:59.000Z

428

AUTOMATIC SYNTHESIS OF OPERATIONAL AMPLIFIERS BASED ON ANALYTIC CIRCUIT  

E-Print Network [OSTI]

a practical intermediate approach to automating op amp synthesis. It is based on analytic circuit models simulation to verify that indeed all the design specifications are met. This whole process has been automatedAUTOMATIC SYNTHESIS OF OPERATIONAL AMPLIFIERS BASED ON ANALYTIC CIRCUIT MODELS Han Young Koh, Carlo

O'Brien, James F.

429

Pharos: enable physical analytics through visible light based indoor localization  

Science Journals Connector (OSTI)

Indoor physical analytics calls for high-accuracy localization that existing indoor (e.g., WiFi-based) localization systems may not offer. By exploiting the ever increasingly wider adoption of LED lighting, in this paper, we study the problem of using ... Keywords: LED, indoor localization, mobile, optical channel model, physical analytics, visible light

Pan Hu; Liqun Li; Chunyi Peng; Guobin Shen; Feng Zhao

2013-11-01T23:59:59.000Z

430

Analytic Functions in Smirnov Classes Ep Real Boundary Values  

E-Print Network [OSTI]

Analytic Functions in Smirnov Classes Ep with Real Boundary Values L. De Castro and D. Khavinson. [1] Ch. 10.) Definition 1. An analytic function f(z) in G is said to belong to the class Ep (G) for p known that for p 1 functions in Ep -classes can be represented as Cauchy integrals of their boundary

Khavinson, Dmitry

431

Flexible MapReduce Workflows for Cloud Data Analytics  

Science Journals Connector (OSTI)

Data analytics applications handle large data sets subject to multiple processing phases, some of which can execute in parallel on clusters, grids or clouds. Such applications can benefit from using MapReduce model, only requiring the end-user to define ... Keywords: Cloud, Data Analytics Applications, MapReduce, Text Mining, Workflow

Carlos Goncalves, Luis Assuncao, Jose C. Cunha

2013-10-01T23:59:59.000Z

432

Resource allocation contracts for open analytic runtime models  

Science Journals Connector (OSTI)

Open Analytic Runtime (OAR) Models embed analysis algorithms into runtime architectural models, thus integrating the model and its analytic interpretations. Such an integration is critical for Cyber-Physical Systems (CPS) when model parts are independently ... Keywords: aadl, assumption management, cyber-physical systems, design by contract, resource allocation

Min-Young Nam; Dionisio de Niz; Lutz Wrage; Lui Sha

2011-10-01T23:59:59.000Z

433

Cost and Performance Baseline for Fossil Energy Plants Volume 2: Coal to Synthetic Natural Gas and Ammonia  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cost and Performance Cost and Performance Baseline for Fossil Energy Plants Volume 2: Coal to Synthetic Natural Gas and Ammonia July 5, 2011 DOE/NETL- 2010/1402 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or

434

Properties of nitrogen doped silicon films deposited by low pressure chemical vapour deposition from disilane and ammonia  

Science Journals Connector (OSTI)

Nitrogen doped silicon films have been deposited by low pressure chemical vapour deposition from disilane Si2H6 and ammonia NH3. Deposition kinetics is investigated, pointing out the influences of the deposition temperature, the total pressure and the gas flow rates. According to the Bruggeman theory, variations of the NH3/Si2H6 gaseous ratio allow for a wide range of the SiNx stoichiometry as well as a good control of the film nitrogen doping. The different behaviours of the nitrogen atom in silicon films are discussed and an overview of the nitrogen doped silicon physical properties (optical, mechanical and electrical) is proposed for the development of boron-doped polysilicon gates.

P Temple-Boyer; L Jalabert; E Couderc; E Scheid; P Fadel; B Rousset

2002-01-01T23:59:59.000Z

435

Emission computed tomography of /sup 18/F-fluorodeoxyglucose and /sup 13/N-ammonia in stroke and epilepsy  

SciTech Connect (OSTI)

The ECAT Positron Tomograph was used to scan normal control subjects, stroke patients at various times during recovery, and patients with partial epilepsy during EEG monitoring. /sup 18/F-fluorodeoxyglucose (/sup 18/FDG) and /sup 13/N-Ammonia (/sup 13/NH/sub 3/) were used as indicators of abnormalities in local cerebral glucose utilization (LCMR/sub glc/) and relative perfusion, respectively. Hypometabolism, due to deactivation or minimal damage, was demonstrated with the /sup 18/FDG scan in deep structures and broad zones of cerebral cortex which appeared normal on x-ray CT (XCT) and /sup 99m/Tc pertechnetate scans. In patients with partial epilepsy, who had unilateral or focal electrical abnormalities, interictal /sup 18/FDG scan patterns clearly showed localized regions of decreased (20 to 50%) LCMR/sub glc/, which correlated anatomically with the eventual EEG localization.

Kuhl, D.E.; Phelps, M.E.; Engel, J. Jr.

1980-01-01T23:59:59.000Z

436

Dominance-based rough set approach and analytic network process for assessing urban transformation scenarios  

Science Journals Connector (OSTI)

The paper shows the contribution that two different multiple criteria decision aiding (MCDA) methods could provide in the field of strategic decisions and urban and territorial planning. In particular, the analytic network process and the dominance-based rough set approach have been considered and discussed in the work with reference to their role in supporting such decision-making processes, trying to compare the different contributions given by the two approaches in this specific domain of application.

Francesca Abastante; Marta Bottero; Salvatore Greco; Isabella M. Lami

2013-01-01T23:59:59.000Z

437

Analytical and numerical calculations of spectral and optical characteristics of spheroidal quantum dots  

SciTech Connect (OSTI)

In the effective mass approximation for electronic (hole) states of a spheroidal quantum dot with and without external fields the perturbation theory schemes are constructed in the framework of the Kantorovich and adiabatic methods. The eigenvalues and eigenfunctions of the problem, obtained in both analytical and numerical forms, were applied for the analysis of spectral and optical characteristics of spheroidal quantum dots in homogeneous electric fields.

Gusev, A. A., E-mail: gooseff@jinr.ru; Hai, L. L.; Vinitsky, S. I.; Chuluunbaatar, O. [Joint Institute for Nuclear Research (Russian Federation)] [Joint Institute for Nuclear Research (Russian Federation); Derbov, V. L.; Klombotskaya, A. S. [Saratov State University (Russian Federation)] [Saratov State University (Russian Federation); Dvoyan, K. G.; Sarkisyan, H. A. [Russian-Armenian (Slavonic) University (Armenia)] [Russian-Armenian (Slavonic) University (Armenia)

2013-08-15T23:59:59.000Z

438

E-Print Network 3.0 - ammonia dimethylamine trimethylamine Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 A NOTE ON THE ESTIMATION OF TRIMETHYLAMINE IN FISH MUSCLE Summary: . An improved method to analyze trimethylamine in fish and the...

439

DOE National Analytical Management Program Draws Global Interest |  

Broader source: Energy.gov (indexed) [DOE]

National Analytical Management Program Draws Global Interest National Analytical Management Program Draws Global Interest DOE National Analytical Management Program Draws Global Interest February 27, 2013 - 12:00pm Addthis Hnin Khaing focuses on her work at WIPP Laboratories near Carlsbad, New Mexico Hnin Khaing focuses on her work at WIPP Laboratories near Carlsbad, New Mexico Corey White works at WIPP Laboratories near Carlsbad, New Mexico Corey White works at WIPP Laboratories near Carlsbad, New Mexico Hnin Khaing focuses on her work at WIPP Laboratories near Carlsbad, New Mexico Corey White works at WIPP Laboratories near Carlsbad, New Mexico CARLSBAD, N.M. - The National Analytical Management Program (NAMP), which coordinates analytical services and capabilities throughout DOE, has garnered global interest. "NAMP is addressing a vital need to attain the most effective use of

440

Argonne Chemical Sciences & Engineering - Facilities - Analytical Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Analytical Chemistry Laboratory Analytical Chemistry Laboratory sullivan ACL manager Vivian Sullivan places a plate for alpha spectrometry into the Alpha Analyst instrument. naik Seema Naik prepares an inorganic sample for analysis on the ICP-Optical Emission Spectrometer. lopykinski Susan Lopykinski prepares a sample for mercury analysis on the cold vapor Atomic Absorption instrument. ICP-Mass Spectrometer Analytical Chemist Yifen Tsai prepares a sample for analysis on the high-resolution ICP-Mass Spectrometer. The Analytical Chemistry Laboratory (ACL) provides a broad range of analytical chemistry support services to the scientific and engineering programs at Argonne National Laboratory and specialized analysis for government, academic, and industrial organizations, including other national laboratories and QA/QC programs and audits.

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Test set of gaseous analytes at Hanford tank farms  

SciTech Connect (OSTI)

DOE has stored toxic and radioactive waste materials in large underground tanks. When the vapors in the tank headspaces vent to the open atmosphere a potentially dangerous situation can occur for personnel in the area. An open-path atmospheric pollution monitor is being developed to monitor the open air space above these tanks. In developing this infrared spectra monitor as a safety alert instrument, it is important to know what hazardous gases, called the Analytes of Concern, are most likely to be found in dangerous concentrations. The monitor must consider other gases which could interfere with measurements of the Analytes of Concern. The total list of gases called the Test Set Analytes form the basis for testing the pollution monitor. Prior measurements in 54 tank headspaces have detected 102 toxic air pollutants (TAPs) and over 1000 other analytes. The hazardous Analytes are ranked herein by a Hazardous Atmosphere Rating which combines their measured concentration, their density relative to air, and the concentration at which they become dangerous. The top 20 toxic air pollutants, as ranked by the Hazardous Atmosphere Rating, and the top 20 other analytes, in terms of measured concentrations, are analyzed for possible inclusion in the Test Set Analytes. Of these 40 gases, 20 are selected. To these 20 gases are added the 6 omnipresent atmospheric gases with the highest concentrations, since their spectra could interfere with measurements of the other spectra. The 26 Test Set Analytes are divided into a Primary Set and a Secondary Set. The Primary Set, gases which must be detectable by the monitor, includes the 6 atmospheric gases and the 6 hazardous gases which have been measured at dangerous concentrations. The Secondary Set gases need not be monitored at this time. The infrared spectra indicates that the pollution monitor will detect all 26 Test Set Analytes by thermal emission and will detect 15 Test Set Analytes by laser absorption.

NONE

1997-01-01T23:59:59.000Z

442

Qualitative and analytical results of the bifurcation thresholds to halo orbits  

E-Print Network [OSTI]

We study the dynamics in the neighborhood of the collinear Lagrangian points in the spatial, circular, restricted three--body problem. We consider the case in which one of the primaries is a radiating body and the other is oblate (although the latter is a minor effect). Beside having an intrinsic mathematical interest, this model is particularly suited for the description of a mission of a spacecraft (e.g., a solar sail) to an asteroid. The aim of our study is to investigate the occurrence of bifurcations to halo orbits, which take place as the energy level is varied. The estimate of the bifurcation thresholds is performed by analytical and numerical methods: we find a remarkable agreement between the two approaches. As a side result, we also evaluate the influence of the different parameters, most notably the solar radiation pressure coefficient, on the dynamical behavior of the model. To perform the analytical and numerical computations, we start by implementing a center manifold reduction. Next, we estimate the bifurcation values using qualitative techniques (e.g. Poincar\\'e surfaces, frequency analysis, FLIs). Concerning the analytical approach, following \\cite{CPS} we implement a resonant normal form, we transform to suitable action-angle variables and we introduce a detuning parameter measuring the displacement from the synchronous resonance. The bifurcation thresholds are then determined as series expansions in the detuning. Three concrete examples are considered and we find in all cases a very good agreement between the analytical and numerical results.

Sara Bucciarelli; Marta Ceccaroni; Alessandra Celletti; Giuseppe Pucacco

2015-02-01T23:59:59.000Z

443

Qualitative and analytical results of the bifurcanion thresholds to halo orbits  

E-Print Network [OSTI]

We study the dynamics in the neighborhood of the collinear Lagrangian points in the spatial, circular, restricted three--body problem. We consider the case in which one of the primaries is a radiating body and the other is oblate (although the latter is a minor effect). Beside having an intrinsic mathematical interest, this model is particularly suited for the description of a mission of a spacecraft (e.g., a solar sail) to an asteroid. The aim of our study is to investigate the occurrence of bifurcations to halo orbits, which take place as the energy level is varied. The estimate of the bifurcation thresholds is performed by analytical and numerical methods: we find a remarkable agreement between the two approaches. As a side result, we also evaluate the influence of the different parameters, most notably the solar radiation pressure coefficient, on the dynamical behavior of the model. To perform the analytical and numerical computations, we start by implementing a center manifold reduction. Next, we estimate the bifurcation values using qualitative techniques (e.g. Poincar\\'e surfaces, frequency analysis, FLIs). Concerning the analytical approach, following \\cite{CPS} we implement a resonant normal form, we transform to suitable action-angle variables and we introduce a detuning parameter measuring the displacement from the synchronous resonance. The bifurcation thresholds are then determined as series expansions in the detuning. Three concrete examples are considered and we find in all cases a very good agreement between the analytical and numerical results.

Sara Bucciarelli; Marta Ceccaroni; Alessandra Celletti; Giuseppe Pucacco

2015-01-23T23:59:59.000Z

444

Analytical invariant manifolds near unstable points and the structure of chaos  

E-Print Network [OSTI]

It is known that the asymptotic invariant manifolds around an unstable periodic orbit in conservative systems can be represented by convergent series (Cherry 1926, Moser 1956, 1958, Giorgilli 2001). The unstable and stable manifolds intersect at an infinity of homoclinic points, generating a complicated homoclinic tangle. In the case of simple mappings it was found (Da Silva Ritter et al. 1987) that the domain of convergence of the formal series extends to infinity along the invariant manifolds. This allows in practice to study the homoclinic tangle using only series. However in the case of Hamiltonian systems, or mappings with a finite analyticity domain,the convergence of the series along the asymptotic manifolds is also finite. Here, we provide numerical indications that the convergence does not reach any homoclinic points. We discuss in detail the convergence problem in various cases and we find the degree of approximation of the analytical invariant manifolds to the real (numerical) manifolds as i) the order of truncation of the series increases, and ii) we use higher numerical precision in computing the coefficients of the series. Then we introduce a new method of series composition, by using action-angle variables, that allows the calculation of the asymptotic manifolds up to an a arbitrarily large extent. This is the first case of an analytic development that allows the computation of the invariant manifolds and their intersections in a Hamiltonian system for an extent long enough to allow the study of homoclinic chaos by analytical means.

C. Efthymiopoulos; G. Contopoulos; M. Katsanikas

2014-04-30T23:59:59.000Z

445

274 CEREAL CHEMISTRY ANALYTICAL TECHNIQUES AND INSTRUMENTATION  

E-Print Network [OSTI]

as a Method to Detect Reduced Corn Wet-Milling Quality KENT D. RAUSCH,1 STEVEN R. ECKHOFF,2 and MARVIN R corn is separated into frac- tions rich in starch, protein, fiber, and oil. Wet milling of corn has corn has been dried under conditions that result in poor wet-milling or dry-milling characteristics

446

Studies of Analytic Evolution of Two-Photon Generalized Distribution Amplitude in QCD  

SciTech Connect (OSTI)

We extend our method of analytic ERBL evolution for the case of distribution amplitudes that have jumps at some points x = {zeta}{sub I} inside the support region 0 < x < 1. As an application of the method, we use it for evolution of the two-photon generalized distribution amplitude. Our approach has advantages over the standard method of expansion in Gegenbauer polynomials, which requires infinite number of terms in order to accuretly reproduce functions in the vicinity of singular points, and over the method of straightforward iteration of initial distribution with evolution kernel which produces logarithmically divergent terms at each iteration. In our method, the logarithmic singularities are summed from the start, which immediately produces a continuous curve, with only one or two iterations needed afterwards in order to get precise results.

Tandogan Kunkel, Asli [Old Dominion Univ., Norfolk, VA and JLAB, Newport News, VA (United States); Radyushkin, Anatoly V. [Old Dominion Univ., Norfolk, VA and JLAB, Newport News, VA (United States)

2014-01-01T23:59:59.000Z

447

QuEChERS Multiresidue Method Validation and Mass Spectrometric Assessment for the Novel Anthranilic Diamide Insecticides Chlorantraniliprole and Cyantraniliprole  

Science Journals Connector (OSTI)

Timo Schwarz , Timothy A. Snow , Christopher J. Santee #, Christopher C. Mulligan #, Thomas Class , Michael P. Wadsley ?, and Sergio C. Nanita *? ... Briefly, acceptable analytical methods are expected to provide average percent recoveries, (analyte found/analyte added) 100, between 70 and 110% for the individual analytes in each matrix tested, with relative standard deviation (RSD) no greater than 20%. ... classes, which demonstrate the general applicability of the method for multiclass anal. ...

Timo Schwarz; Timothy A. Snow; Christopher J. Santee; Christopher C. Mulligan; Thomas Class; Michael P. Wadsley; Sergio C. Nanita

2010-12-31T23:59:59.000Z

448

Progress In Electromagnetics Research M, Vol. 35, 173182, 2014 Three-Dimensional Analytical Model for an Axial-Field  

E-Print Network [OSTI]

--In this paper, we propose an analytical method for modeling a permanent magnets axial field magnetic coupling. Shaft Rout Magnets Soft-Iron yoke h h Rin e To load From motor Magnetic coupling Figure 1. Structure equipped with axially magnetized permanent magnets (PMs). The PMs are glued on an iron yoke to form a north

Paris-Sud XI, Université de

449

A meta-analytic review of the weapon focus effect  

Science Journals Connector (OSTI)

This meta-analytic review examined 19 tests of the weapon focus effectthe hypothesis that the presence of a weapon during commission of a crime will negatively ... the perpetrator. A significant overall differen...

Nancy Mehrkens Steblay

1992-08-01T23:59:59.000Z

450

Hanford analytical sample projections FY 1998--FY 2002  

SciTech Connect (OSTI)

Analytical Services projections are compiled for the Hanford site based on inputs from the major programs for the years 1998 through 2002. Projections are categorized by radiation level, protocol, sample matrix and program. Analyses requirements are also presented. This document summarizes the Hanford sample projections for fiscal years 1998 to 2002. Sample projections are based on inputs submitted to Analytical Services covering Environmental Restoration, Tank Waste Remediation Systems (TWRS), Solid Waste, Liquid Effluents, Spent Nuclear Fuels, Transition Projects, Site Monitoring, Industrial Hygiene, Analytical Services and miscellaneous Hanford support activities. In addition, details on laboratory scale technology (development) work, Sample Management, and Data Management activities are included. This information will be used by Hanford Analytical Services (HAS) and the Sample Management Working Group (SMWG) to assure that laboratories and resources are available and effectively utilized to meet these documented needs.

Joyce, S.M.

1998-02-12T23:59:59.000Z

451

Incorporating Information Literacy Skills into Analytical Chemistry: An Evolutionary Step  

Science Journals Connector (OSTI)

We have developed Data Analysis and Information Technology assignments for our analytical chemistry course. These assignments require that students demonstrate how to: locate and effectively use Internet-based science resources; create and manage ...

Mary M. Walczak; Paul T. Jackson

2007-08-01T23:59:59.000Z

452

An Analytic Model for Colluding Processes Stephen M. Watt  

E-Print Network [OSTI]

An Analytic Model for Colluding Processes Stephen M. Watt University of Western Ontario London, Canada www.csd.uwo.ca/watt Abstract--We develop a quantitative framework in order to understand how

Watt, Stephen M.

453

Crystal ball planning for analytics implementation in Singapore  

E-Print Network [OSTI]

Amgen is building a new drug substance manufacturing site in Singapore (ASM). This project identified and mitigated the risks associated with implementing analytical technologies to facilitate the design and implementation ...

Fang, Cong, Ph.D. California State University, Los Angeles

2014-01-01T23:59:59.000Z

454

Analytic model of solar power plant with a Stirling engine  

Science Journals Connector (OSTI)

An analytic model is proposed of a solar power plant (SPP) with a Stirling engine that is based on the isothermal model of the Stirling engine (SE) working process and is improved...

I. A. Tursunbaev

2007-03-01T23:59:59.000Z

455

Analytic behavior of the QED polarizability function at finite temperature  

E-Print Network [OSTI]

We revisit the analytical properties of the static quasi-photon polarizability function for an electron gas at finite temperature, in connection with the existence of Friedel oscillations in the potential created by an impurity. In contrast with the zero temperature case, where the polarizability is an analytical function, except for the two branch cuts which are responsible for Friedel oscillations, at finite temperature the corresponding function is not analytical, in spite of becoming continuous everywhere on the complex plane. This effect produces, as a result, the survival of the oscillatory behavior of the potential. We calculate the potential at large distances, and relate the calculation to the non-analytical properties of the polarizability.

A. Bernal; A. Perez

2011-01-20T23:59:59.000Z

456

Analytical study of a control algorithm based on emotional processing  

E-Print Network [OSTI]

Dennis L. O?Neal December 2005 Major Subject: Mechanical Engineering iii ABSTRACT Analytical Study of a Control Algorithm Based on Emotional Processing. (December 2005) Manik Chandra, B. Tech., Indian Institute of Technology Kanpur...

Chandra, Manik

2007-04-25T23:59:59.000Z

457

Light trapping limits in plasmonic solar cells: an analytical investigation  

E-Print Network [OSTI]

We analytically investigate the light trapping performance in plasmonic solar cells with Si/metallic structures. We consider absorption enhancements for surface plasmon polaritons (SPPs) at planar Si/metal interfaces and ...

Sheng, Xing

458

A fundamental study on analyte adsorption onto metallophthalocyanines  

E-Print Network [OSTI]

E FePc=analyte TEA TMA TMP UHV US-PP VASP vs. V ?E ZPE ZPEsuccessfully maintaining a UHV environment. Additionally, Ifilm in ultra high vacuum (UHV). 11 The experimental results

Tran, Ngoc L.

2008-01-01T23:59:59.000Z

459

ONE FACULTY POSITIONS IN ANALYTICAL, FORENSIC CHEMISTRY OR TOXICOLOGY  

E-Print Network [OSTI]

ONE FACULTY POSITIONS IN ANALYTICAL, FORENSIC CHEMISTRY OR TOXICOLOGY The Department of Chemistry, we seek one outstanding individual to join our recently established Forensic Technology Institute and our FEPAC- accredited Forensics Chemistry Program. A primary focus on forensics research should

Linsley, Braddock K.

460

Analytical calculation of detailed model parameters of cast resin dry-type transformers  

Science Journals Connector (OSTI)

Non-flammable characteristic of cast resin dry-type transformers make them suitable for different kind of usages. This paper presents an analytical method of how to obtain parameters of detailed model of these transformers. The calculated parameters are compared and verified with the corresponding FEM results and if it was necessary, correction factors are introduced for modification of the analytical solutions. Transient voltages under full and chopped test impulses are calculated using the obtained detailed model. In order to validate the model, a setup was constructed for testing on high-voltage winding of cast resin dry-type transformer. The simulation results were compared with the experimental data measured from FRA and impulse tests.

M. Eslamian; B. Vahidi; S.H. Hosseinian

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

ANALYTIC EXPRESSIONS FOR THE LIGHT-SCATTERING CROSS SECTION  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ANALYTIC ANALYTIC EXPRESSIONS FOR THE LIGHT-SCATTERING CROSS SECTION AND ÅNGSTRÖM EXPONENT OF AN AEROSOL Ernie R. Lewis Brookhaven National Laboratory, Upton, NY 11933 elewis@bnl.gov BACKGROUND For an aerosol consisting of spherical particles with size distribution of number concentration dN(r)/dr and real index of refraction m (thus no absorption), the light-scattering coefficient σ sp

462

Quality assurance management plan (QAPP) special analytical support (SAS)  

SciTech Connect (OSTI)

It is the policy of Special Analytical Support (SAS) that the analytical aspects of all environmental data generated and processed in the laboratory, subject to the Environmental Protection Agency (EPA), U.S. Department of Energy or other project specific requirements, be of known and acceptable quality. It is the intention of this QAPP to establish and assure that an effective quality controlled management system is maintained in order to meet the quality requirements of the intended use(s) of the data.

LOCKREM, L.L.

1999-05-20T23:59:59.000Z

463

Sorption of carboxylic acid from carboxylic salt solutions at pHs close to or above the pK[sub a] of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH[sub a] into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. The acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carboxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia. 8 figs.

King, C.J.; Tung, L.A.

1992-07-21T23:59:59.000Z

464

Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.

King, C. Judson (Kensington, CA); Tung, Lisa A. (El Cerrito, CA)

1992-01-01T23:59:59.000Z

465

Understanding ammonia selective catalytic reduction kinetics over Cu-SSZ-13 from motion of the Cu ions  

SciTech Connect (OSTI)

Cu-SSZ-13 catalysts with three Si/Al ratios, at 6, 12 and 35, are synthesized with solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation, and standard ammonia selective catalytic reduction (NH3-SCR) reactions. By varying Si/Al ratios and Cu loadings, it is possible to synthesize catalysts with one dominant type of isolated Cu2+ ion species. Prior to full dehydration of the zeolite catalyst, hydrated Cu2+ ions are found to be very mobile as judged from EPR. NO oxidation is catalyzed by O-bridged Cu-dimer species that form at relatively high Cu loadings and in the presence of O2. For NH3 oxidation and standard SCR reactions, transient Cu-dimers even form at much lower Cu loadings; and these are proposed to be the active sites for reaction temperatures ? 350 C. These dimer species can be viewed as in equilibrium with monomeric Cu ion complexes. Between ~250 and 350 C, these moieties become less stable causing SCR reaction rates to decrease. At temperatures above 350 C and at low Cu loadings, Cu-dimers completely dissociate to regenerate isolated Cu2+ monomers that then locate at ion-exchange sites of the zeolite lattice. At low Cu loadings, these Cu species are the high-temperature active SCR catalytic centers. At high Cu loadings, on the other hand, both Cu-dimers and monomers are highly active in the high temperature kinetic regime, yet Cu-dimers are less selective in SCR. Brnsted acidity is also very important for SCR reactivity in the high-temperature regime. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOEs Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

Gao, Feng; Walter, Eric D.; Kollar, Marton; Wang, Yilin; Szanyi, Janos; Peden, Charles HF

2014-11-01T23:59:59.000Z

466

Synthesis of Multipole Acoustic Logging Measurements Using the Generalized Reflection/Transmission Matrices Method  

E-Print Network [OSTI]

Synthesis of Multipole Acoustic Logging Measurements Using the Generalized Reflection analytical method that has been used in multipole waveform synthesis for radially multilayered formations

Torres-Verdín, Carlos

467

11.220 Quantitative Reasoning and Statistical Method for Planning I, Spring 2006  

E-Print Network [OSTI]

This course develops logical, empirically based arguments using statistical techniques and analytic methods. It covers elementary statistics, probability, and other types of quantitative reasoning useful for description, ...

Zegras, P. Christopher

468

Visual Analytics for Law Enforcement: Deploying a Service-Oriented Analytic Framework for Web-based Visualization  

SciTech Connect (OSTI)

This paper presents key components of the Law Enforcement Information Framework (LEIF) that provides communications, situational awareness, and visual analytics tools in a service-oriented architecture supporting web-based desktop and handheld device users. LEIF simplifies interfaces and visualizations of well-established visual analytical techniques to improve usability. Advanced analytics capability is maintained by enhancing the underlying processing to support the new interface. LEIF development is driven by real-world user feedback gathered through deployments at three operational law enforcement organizations in the US. LEIF incorporates a robust information ingest pipeline supporting a wide variety of information formats. LEIF also insulates interface and analytical components from information sources making it easier to adapt the framework for many different data repositories.

Dowson, Scott T.; Bruce, Joseph R.; Best, Daniel M.; Riensche, Roderick M.; Franklin, Lyndsey; Pike, William A.

2009-04-14T23:59:59.000Z

469

Analytical investigation of collector optimum tilt angle at low latitude  

Science Journals Connector (OSTI)

An analytical investigation on the optimum tilt angle for solar collectors at low latitude a case study of Universiti Teknologi PETRONAS (UTP) 4.39N and 100.98E Malaysia is presented in this work. The study employed Hay Davies Klucher and Reindl (HDKR) anisotropic sky model to evaluate the available hourly solar radiation on inclined surface using the location metrological data. The tilt angles considered were 0 to 30 in step of 3 with the inclusion of the location latitude angle. The study employed the ratio of global solar radiation on tilted surface to the global solar radiation on horizontal surface in the decision of the optimum tilt. The system equations were converted to MATLAB codes to solve for the optimum tilt angles. The results show that the optimum tilt varies monthly but gave zero degree for south facing collector for the months of April to August; thus the investigation also considered north facing orientation for the months of April to September. The optimum annual tilt angle for the location using the tilt to horizontal radiation ratio was found to be equal to the location latitude angle. Using the conventional average of the monthly optimum tilt angles the annual optimum tilt angle was found to be 9.75 for south facing collector. Considering seasonal optimum tilt angle for the location using the tilt to horizontal radiation ratio 18 facing south was found to be the optimum tilt angle for rainy season (September to March) and 15 facing north for dry season (April to August). Employing the average of monthly optimum tilt method the seasonal optimum tilt angle was found to be 17 for rainy season and 12 facing north dry season. The effect of dust on the collector was considered with reference to literature and the annual tilt angle of 15 facing south was recommended for the location in the case of large solar collector that cannot be monthly or seasonally adjusted.

Ogboo Chikere Aja; Hussain H. Al-Kayiem; Zainal Ambri Abdul Karim

2013-01-01T23:59:59.000Z

470

SYSTEMS MODELING OF AMMONIA BORANE BEAD REACTOR FOR OFF-BOARD REGENERABLE HYDROGEN STORAGE IN PEM FUEL CELL APPLICATIONS  

SciTech Connect (OSTI)

Out of the materials available for chemical hydrogen storage in PEM fuel cell applications, ammonia borane (AB, NH3BH3) has a high hydrogen storage capacity (upto 19.6% by weight for the release of three hydrogen molecules). Therefore, AB was chosen in our chemical hydride simulation studies. A model for the AB bead reactor system was developed to study the system performance and determine the energy, mass and volume requirements for off-board regenerable hydrogen storage. The system includes hot and cold augers, ballast tank and reactor, product tank, H2 burner and a radiator. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure in the reactor system. Control signals to various components are governed by a control system which is modeled as an independent subsystem. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. Preliminary system simulation results for a start-up case and for a transient drive cycle indicate accurate trends in the reactor system dynamics.

Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; King, Dale A.; Herling, Darrell R.

2010-06-01T23:59:59.000Z

471

Recovery and removal of ammonianitrogen and phosphate from swine wastewater by internal recycling of struvite chlorination product  

Science Journals Connector (OSTI)

Abstract The recovery of the total orthophosphate (PT) and removal of the total ammonianitrogen (TAN) from swine wastewater were investigated through a combined technology of using bittern as the magnesium source in struvite precipitation along with internal recycling of the chlorination product of the recovered struvite. Results revealed that the PT recovery efficiency and the struvite purity was mainly depended on the wastewater pH and the Mg:PT molar ratio. Co-precipitations of Mg3(PO4)2, MgKPO4, Ca3(PO4)2, and Mg(OH)2 (pH>9) were confirmed to be responsible for the decrease in the purity of struvite. The decomposition of recovered struvite by sodium hypochlorite (NaClO) was feasible. The TAN concentration of the swine wastewater was decreased to 63mg/L by internal recycling of the chlorination decomposition product for seven cycles. An economic evaluation showed that 37% of the treatment cost of the proposed process could be saved as compared with struvite precipitation using pure chemicals.

Haiming Huang; Jiang Yang; Ding Li

2014-01-01T23:59:59.000Z

472

E-Print Network 3.0 - analytical tem comparisons Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Radiation Laboratory (UltRa) Collection: Engineering 15 Analytical Formulae of Quantum-Mechanical Electron Density in Inversion Layer in Planar MOSFETs Summary: Analytical...

473

E-Print Network 3.0 - analytical scanning electron Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electron Microscope Philips CM20 Analytical Scanning... during formation of the carbide particles. 12;Philips CM20 Analytical Scanning Transmission Electron... at SCSAM ...

474

E-Print Network 3.0 - analytical case study Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The New Path to Value How the smartest organizations are embedding analytics to transform insights into action Summary: 12;Analytics: The New Path to Value How the smartest...

475

E-Print Network 3.0 - analytical techniques applied Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The New Path to Value How the smartest organizations are embedding analytics to transform insights into action Summary: reporting Data visualization 6 In 24 months Analytic...

476

E-Print Network 3.0 - analytical techniques needed Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The New Path to Value How the smartest organizations are embedding analytics to transform insights into action Summary: reporting Data visualization 6 In 24 months Analytic...

477

E-Print Network 3.0 - analytical model comparison Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Slope Summary: -Depleted SONFET is presented. The analytical model is validated by comparison to the Medici simulation results... Vertical Silicon-on-Nothing FET: Analytical...

478

A rigid analytical regulator for the K_2 of Mumford curves.  

E-Print Network [OSTI]

We construct a rigid analytical regulator for the K_2 of Mumford curves, a non-archimedean analogue of the complex analytical Beilinson-Bloch-Deligne regulator.

Ambrus Pal

479

E-Print Network 3.0 - activation analysis--an analytical Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(SOP), water sampling plans, Summary: procedures, and NOAA's Analytical Quality Assurance Project Plan (QAPP). Samples were sent to certified... accredited analytical...

480

Data and Analytics to Inform Energy Retrofit of High Performance Buildings  

SciTech Connect (OSTI)

Buildings consume more than one-third of the world?s primary energy. Reducing energy use in buildings with energy efficient technologies is feasible and also driven by energy policies such as energy benchmarking, disclosure, rating, and labeling in both the developed and developing countries. Current energy retrofits focus on the existing building stocks, especially older buildings, but the growing number of new high performance buildings built around the world raises a question that how these buildings perform and whether there are retrofit opportunities to further reduce their energy use. This is a new and unique problem for the building industry. Traditional energy audit or analysis methods are inadequate to look deep into the energy use of the high performance buildings. This study aims to tackle this problem with a new holistic approach powered by building performance data and analytics. First, three types of measured data are introduced, including the time series energy use, building systems operating conditions, and indoor and outdoor environmental parameters. An energy data model based on the ISO Standard 12655 is used to represent the energy use in buildings in a three-level hierarchy. Secondly, a suite of analytics were proposed to analyze energy use and to identify retrofit measures for high performance buildings. The data-driven analytics are based on monitored data at short time intervals, and cover three levels of analysis ? energy profiling, benchmarking and diagnostics. Thirdly, the analytics were applied to a high performance building in California to analyze its energy use and identify retrofit opportunities, including: (1) analyzing patterns of major energy end-use categories at various time scales, (2) benchmarking the whole building total energy use as well as major end-uses against its peers, (3) benchmarking the power usage effectiveness for the data center, which is the largest electricity consumer in this building, and (4) diagnosing HVAC equipment using detailed time-series operating data. Finally, a few energy efficiency measures were identified for retrofit, and their energy savings were estimated to be 20percent of the whole-building electricity consumption. Based on the analyses, the building manager took a few steps to improve the operation of fans, chillers, and data centers, which will lead to actual energy savings. This study demonstrated that there are energy retrofit opportunities for high performance buildings and detailed measured building performance data and analytics can help identify and estimate energy savings and to inform the decision making during the retrofit process. Challenges of data collection and analytics were also discussed to shape best practice of retrofitting high performance buildings.

Hong , Tianzhen; Yang, Le; Hill, David; Feng , Wei

2014-01-25T23:59:59.000Z

Note: This page contains sample records for the topic "analytical method ammonia" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Field measurements of ammonia volatilization from surface applications of nitrogen fertilizers to a calcareous soil  

E-Print Network [OSTI]

hydrolysis study . . . . . . . . . . . , . . . . . . 71 Table 14 Effect of added soil water and added urease on loss of NH3 from Solution 32 applied at a rate of 224 kg N/ha in the field Page 72 15 Effect of method of application and added urease... on loss of NH from Solution 32 applied at a r2te of 112 kg N/ha in the field . . . . . . . . . . 74 16 Some physical and chemical characteris- tics of Houston Black clay . . . . . . . . 89 LIST OF FIGURES Figure Page A schematic of the apparatus used...

Hargrove, W. L

2012-06-07T23:59:59.000Z

482

Analytical-Numerical Modeling Of Komatiite Lava Emplacement And Thermal  

Open Energy Info (EERE)

Analytical-Numerical Modeling Of Komatiite Lava Emplacement And Thermal Analytical-Numerical Modeling Of Komatiite Lava Emplacement And Thermal Erosion At Perseverance, Western Australia Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Analytical-Numerical Modeling Of Komatiite Lava Emplacement And Thermal Erosion At Perseverance, Western Australia Details Activities (0) Areas (0) Regions (0) Abstract: We have applied a thermal-fluid dynamic-geochemical model to investigate the emplacement and erosional potential of Archean komatiite flows at Perseverance, Western Australia. Perseverance has been proposed as a site of large-scale thermal erosion by large-volume komatiite eruption(s), resulting in a 100-150-m-deep lava channel containing one of the world's largest komatiite-hosted Fe-Ni-Cu-(PGE) sulfide deposits. Using

483

Analytic description of dipole-bound anion photodetachment  

SciTech Connect (OSTI)

An analytical model for a dipole-bound anion (DBA) is proposed based on the exactly solvable three-dimensional Schroedinger equation for the excess electron bound by dipole potential of the parent neutral molecule (NM) in the Born-Oppenheimer approximation. The model gives reasonable analytical approximation for the dependence of the DBA binding energy on the NM dipole moment previously found numerically by many authors. The cross section of one-photon photodetachment of DBA is calculated in explicit analytical form. In the limit of high photon frequency, {omega}, the calculated cross-section displays {approx}{omega}{sup -2} behavior, which agrees perfectly with the experimental data [Bailey et al., J. Chem. Phys 104, 6976 (1996)]. At the threshold, the cross section demonstrates Gailitis-Damburg oscillations. Numerical dependence is provided for the maximal value of the cross section as a function of the NM dipole moment and the binding energy of the excess electron.

Chernov, V. E.; Dolgikh, A. V.; Zon, B. A. [Voronezh State University, 1 University Sq., Voronezh, 394006 (Russian Federation)

2005-11-15T23:59:59.000Z

484

Risk analysis of analytical validations by probabilistic modification of FMEA  

Science Journals Connector (OSTI)

Risk analysis is a valuable addition to validation of an analytical chemistry process, enabling not only detecting technical risks, but also risks related to human failures. Failure Mode and Effect Analysis (FMEA) can be applied, using a categorical risk scoring of the occurrence, detection and severity of failure modes, and calculating the Risk Priority Number (RPN) to select failure modes for correction. We propose a probabilistic modification of FMEA, replacing the categorical scoring of occurrence and detection by their estimated relative frequency and maintaining the categorical scoring of severity. In an example, the results of traditional FMEA of a Near Infrared (NIR) analytical procedure used for the screening of suspected counterfeited tablets are re-interpretated by this probabilistic modification of FMEA. Using this probabilistic modification of FMEA, the frequency of occurrence of undetected failure mode(s) can be estimated quantitatively, for each individual failure mode, for a set of failure modes, and the full analytical procedure.

D.M. Barends; M.T. Oldenhof; M.J. Vredenbregt; M.J. Nauta

2012-01-01T23:59:59.000Z

485

Analytical investigation of the dynamics behaviors of quantum cascade laser  

Science Journals Connector (OSTI)

Abstract In this paper, we investigate analytically and numerically the transient dynamics of the mid-infrared quantum cascade laser operating in a single mode. The approach is based on using adiabatic elimination in the rate equations model. Analytical solutions are derived for steady-state and time-dependent number of electrons in the various levels, population inversion and number of photons in the cavity. In addition, the equation that allows for the determination of time for steady-state establishment is derived within the premises of our analytical model in the most general case. The results are compared with numerical calculations. The dependence of the buildup time on current injection is also examined and compared with our other existing model.

A. Hamadou

2015-01-01T23:59:59.000Z

486

A Physically Based Analytical Model to Predict Quantized Eigen Energies and Wave Functions Incorporating Penetration Effect  

E-Print Network [OSTI]

We propose a physically based analytical compact model to calculate Eigen energies and Wave functions which incorporates penetration effect. The model is applicable for a quantum well structure that frequently appears in modern nano-scale devices. This model is equally applicable for both silicon and III-V devices. Unlike other models already available in the literature, our model can accurately predict all the eigen energies without the inclusion of any fitting parameters. The validity of our model has been checked with numerical simulations and the results show significantly better agreement compared to the available methods.

Nadim Chowdhury; Imtiaz Ahmed; Zubair Al Azim; Md. Hasibul Alam; Iftikhar Ahmad Niaz; Quazi D. M. Khosru

2014-04-14T23:59:59.000Z

487

Comparison of analytical models for zonal flow generation in ion-temperature-gradient mode turbulence  

SciTech Connect (OSTI)

During the past years the understanding of the multi scale interaction problems have increased significantly. However, at present there exists a flora of different analytical models for investigating multi scale interactions and hardly any specific comparisons have been performed among these models. In this work two different models for the generation of zonal flows from ion-temperature-gradient (ITG) background turbulence are discussed and compared. The methods used are the coherent mode coupling model and the wave kinetic equation model (WKE). It is shown that the two models give qualitatively the same results even though the assumption on the spectral difference is used in the (WKE) approach.

Anderson, J.; Miki, K.; Uzawa, K.; Li, J.; Kishimoto, Y. [Dept. Fundamental Energy Science, School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto, 611-0011 (Japan)

2006-11-30T23:59:59.000Z

488

Analytically expressed constraint on two Majorana phases in neutrinoless double beta decay  

E-Print Network [OSTI]

We assume that neutrinoless double beta decay is caused by the exchange of three light Majorana neutrinos. Under this assumption, we obtain, by the method of perturbation, the equation representing the isocontour of effective Majorana mass which is the function of two CP-violating Majorana phases. The equation representing the isocontour (constraint equation between two Majorana phases) is expressed analytically by six parameters: two lepton mixing angles, two kinds of neutrino mass squared differences, lightest neutrino mass scale, and the effective Majorana mass. We discuss how the constraint equation between two Majorana phases changes when the lightest neutrino mass scale is varied.

Maedan, Shinji

2014-01-01T23:59:59.000Z

489

Expanding the Frontiers of Visual Analytics and Visualization  

SciTech Connect (OSTI)

Expanding the Frontiers of Visual Analytics and Visualization contains international contributions by leading researchers from within the field. Dedicated to the memory of Jim Thomas, the book begins with the dynamics of evolving a vision based on some of the principles that Jim and colleagues established and in which Jims leadership was evident. This is followed by chapters in the areas of visual analytics, visualization, interaction, modelling, architecture, and virtual reality, before concluding with the key area of technology transfer to industry.

Dill, John; Earnshaw, Rae; Kasik, David; Vince, John; Wong, Pak C.

2012-05-31T23:59:59.000Z

490

A comparison of an analytical and two electric analogy methods of hydraulic flow analysis  

E-Print Network [OSTI]

~ +0. 00085 ~ *0. 0006 ~ ~0. 0005 OS0. 0004 ~ +0 ~ 00015 PIPE DIAMETER, D& IN INCHES FIGVRE 2 ~ RATIO ~ / D FOR VARIOOS TRIPES OF PIPES Employing the continuity equation for steady incompressible flow, the following relationship is found, Q=AV... ~ +0. 00085 ~ *0. 0006 ~ ~0. 0005 OS0. 0004 ~ +0 ~ 00015 PIPE DIAMETER, D& IN INCHES FIGVRE 2 ~ RATIO ~ / D FOR VARIOOS TRIPES OF PIPES Employing the continuity equation for steady incompressible flow, the following relationship is found, Q=AV...

Hoffman, Joe Douglas

2012-06-07T23:59:59.000Z

491

Improvement of the assimilable organic carbon (AOC) analytical method for reclaimed water  

Science Journals Connector (OSTI)

Microbial growth is an issue of concern that may cause hygienic and aesthetic problems during the transportation and usage of reclaimed water. Assimilable organic carbon (AOC) is an important parameter which dete...

Xin Zhao; Hongying Hu; Shuming Liu

2013-08-01T23:59:59.000Z

492

E-Print Network 3.0 - analytical methods biodiesel Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solar Center Collection: Renewable Energy ; Energy Storage, Conversion and Utilization 94 Bioenergy and Sustainable Development? Summary: reserved 1543-5938071121-013120.00 Key...

493

A New Analytical Method to Quantify Residual Fluid Cleanup in Hydraulic Fractures  

E-Print Network [OSTI]

A number of factors contribute to reduce the production benefits from hydraulic fracturing, including inefficient fluid design, poor proppant selection and or, the inability of fracture fluid to degrade and flow back after treatment. Undegraded...

Zarrin, Tahira

2014-04-17T23:59:59.000Z

494

Analytical methods for establishing least cost search patterns for fault isolation in testing procedures  

E-Print Network [OSTI]

YL and sho!n in 1 i gurc 2. A!sly?is of th ~ configuration shows that each n )ramcter ti!at . . uppoz t: Y can be tested inde . pndently or '. t can t&e . est d in coml& nation, ", as follows: (1) Individually by measuring x), x2, x3, nd x, , v... of the twc will be selected, however, a limit can be established on the maximum number of useful test n-1 patterns at 2 -1, and for the example case, 7. 15 DFCIHIOI'1 CR1TFRIA Intuitively, it woui d be expected to test an itesi . or failure that has a...

Howie, Thomas Fisher

2012-06-07T23:59:59.000Z

495

Hydrogen Fuel Quality- Focus: Analytical Methods Development & Hydrogen Fuel Quality Results  

Broader source: Energy.gov [DOE]

2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

496

Analytical Method for Determination of Trace Organics in Gas Samples Collected by Canister  

Science Journals Connector (OSTI)

......usage of the 5 mL of water causes a great deal...analysis of highly water soluble compounds...dioxane. Liquid nitrogen (b.p. -196 C...their polarity or solubility in water. Therefore, with...reasonably good except the gases, which have overly......

J.P. Hsu; Greg Miller; Victor Moran; III

1991-02-01T23:59:59.000Z

497

E-Print Network 3.0 - analytical chromatography methods Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

inductively coupled plasma-mass spectrometry (IC-ICP-MS), liquid ... Source: Missouri-Rolla, University of - Laboratory for Information Technology Evaluation Collection:...

498

E-Print Network 3.0 - analytical methods subtask Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

overlapped with the ... Source: Naval Postgraduate School, Center for Information Systems Security Studies and Research Collection: Computer Technologies and Information Sciences 3...

499

New Analytical Methods Reveal the Pattern of Seismic Activity in Western Washington  

Science Journals Connector (OSTI)

...Explosion-Generated Seismic Waves". 7. I. N. Gupta, "Resonant Oscillations of the Overburden Exeited by Seismic Waves". 8. P. L...galvanometer. The slat is illuminated 11 times a second by a Xenon flash lamp. Light pulses passing through the code piste are...

Frank Neumann

500

An analytical method for simultaneously assessing biological and physical barriers of the rat intestinal mucosa  

E-Print Network [OSTI]

. Arrows indicate the product-ion that was selected in each case for subsequent quantitative (MRM) analyses. Predicted fragment-structure for atenololwas rationalized based on exact mass measurements (145.0653; C10H9O, 4.5 ppm) whereas predicted... fragment-structure for verpamil and norverapamil were obtained from the literature (9,10). H+ NH NC CH3CH3 CH3 O O CH3 CH3 O O CH3 m/z 165 H+ CH3 N NC CH3CH3 CH3 O O CH3 CH3 O O CH3 m/z 165 A B C m/z 145 m/z 165 m/z 165O + O NH CH3 CH3 NH2 O OH H+ PLASMA...

Mudra, D. R.; Borchardt, Ronald T.

2006-10-25T23:59:59.000Z