National Library of Energy BETA

Sample records for aluminum ingot ar

  1. Fatigue-crack propagation in aluminum-lithium alloys processed by power and ingot metallurgy

    SciTech Connect (OSTI)

    Venkateswara Rao, K.T.; Ritchie, R.O. ); Kim, N.J. ); Pizzo, P.P. )

    1990-04-01

    Fatigue-crack propagation behavior in powder-metallurgy (P/M) aluminum-lithium alloys, namely, mechanically-alloyed (MA) Al-4.0Mg-1.5Li-1.1C-0.80{sub 2} (Inco 905-XL) and rapid-solidification-processed (RSP) Al-2.6Li-1.0Cu-0.5Mg-0.5Zr (Allied 644-B) extrusions, has been studied, and results compared with data on an equivalent ingot-metallurgy (I/M) Al-Li alloy, 2090-T81 plate. Fatigue-crack growth resistance of the RSP Al-Li alloy is found to be comparable to the I/M Al-Li alloy; in contrast, crack velocities in MA 905-XL extrusions are nearly three orders of magnitude faster. Growth-rate response in both P/M Al-Li alloys, however, is high anisotropic. Results are interpreted in terms of the microstructural influence of strengthening mechanism, slip mode, grain morphology and texture on the development of crack-tip shielding from crack-path deflection and crack closure. 14 refs., 7 figs., 2 tabs.

  2. A Combined Experimental and Computational Approach for the Design of Mold Topography that Leads to Desired Ingot Surface and Microstructure in Aluminum Casting.

    SciTech Connect (OSTI)

    Dr. Zabaras, N.J.; Samanta, D.; Tan, L.

    2005-10-30

    A design methodology will be developed with which casting mold surface topographies can be tuned to produce required surface features and micro-structural properties of Aluminum ingots. Both static and continuous casting processes will be examined with instrumented molds. Mold surface topographies, which consist of unidirectional and bi-directional groove textures, will be generated using contact and non-contact techniques to elicit a radiator-like effect at the mold-casting interface. The rate of heat extraction, the evolution of near-surface cast microstructure, and shell macro-morphology can be controlled once the proper balance between mold surface area extension and the degree of imperfect wetting at the instant solidification starts is determined. Once this control is achieved, it will be possible to minimize or even eliminate costly post-casting surface milling or scalping which is currently a major barrier to the development of new Aluminum casting processes.

  3. Modeling and Optimization of Direct Chill Casting to Reduce Ingot Cracking

    SciTech Connect (OSTI)

    Das, S.K.; Ningileri, S.; Long, Z.; Saito, K.; Khraisheh, M.; Hassan, M.H.; Kuwana, K.; Han, Q.; Viswanathan, S.; Sabau, A.S.; Clark, J.; Hyrn, J. (ANL)

    2006-08-15

    Approximately 68% of the aluminum produced in the United States is first cast into ingots prior to further processing into sheet, plate, extrusions, or foil. The direct chill (DC) semi-continuous casting process has been the mainstay of the aluminum industry for the production of ingots due largely to its robust nature and relative simplicity. Though the basic process of DC casting is in principle straightforward, the interaction of process parameters with heat extraction, microstructural evolution, and development of solidification stresses is too complex to analyze by intuition or practical experience. One issue in DC casting is the formation of stress cracks [1-15]. In particular, the move toward larger ingot cross-sections, the use of higher casting speeds, and an ever-increasing array of mold technologies have increased industry efficiencies but have made it more difficult to predict the occurrence of stress crack defects. The Aluminum Industry Technology Roadmap [16] has recognized the challenges inherent in the DC casting process and the control of stress cracks and selected the development of 'fundamental information on solidification of alloys to predict microstructure, surface properties, and stresses and strains' as a high-priority research need, and the 'lack of understanding of mechanisms of cracking as a function of alloy' and 'insufficient understanding of the aluminum solidification process', which is 'difficult to model', as technology barriers in aluminum casting processes. The goal of this Aluminum Industry of the Future (IOF) project was to assist the aluminum industry in reducing the incidence of stress cracks from the current level of 5% to 2%. Decreasing stress crack incidence is important for improving product quality and consistency as well as for saving resources and energy, since considerable amounts of cast metal could be saved by eliminating ingot cracking, by reducing the scalping thickness of the ingot before rolling, and by eliminating butt sawing. Full-scale industrial implementation of the results of the proposed research would lead to energy savings in excess of 6 trillion Btu by the year 2020. The research undertaken in this project aimed to achieve this objective by a collaboration of industry, university, and national laboratory personnel through Secat, Inc., a consortium of aluminum companies. During the four-year project, the industrial partners and the research team met in 16 quarterly meetings to discuss research results and research direction. The industrial partners provided guidance, facilities, and experience to the research team. The research team went to two industrial plants to measure temperature distributions in commercial 60,000-lb DC casting ingot production. The project focused on the development of a fundamental understanding of ingot cracking and detailed models of thermal conditions, solidification, microstructural evolution, and stress development during the initial transient in DC castings of the aluminum alloys 3004 and 5182. The microstructure of the DC casting ingots was systematically characterized. Carefully designed experiments were carried out at the national laboratory and university facilities as well as at the industrial locations using the industrial production facilities. The advanced computational capabilities of the national laboratories were used for thermodynamic and kinetic simulations of phase transformation, heat transfer and fluid flow, solidification, and stress-strain evolution during DC casting. The achievements of the project are the following: (1) Identified the nature of crack formation during DC casting; (2) Developed a novel method for determining the mechanical properties of an alloy at the nonequilibrium mushy zone of the alloy; (3) Measured heat transfer coefficients (HTCs) between the solidifying ingot and the cooling water jet; (4) Determined the material constitutive model at high temperatures; and (5) Developed computational capabilities for the simulation of cracking formation in DC casting ingot. The models and the database de

  4. Large grain cavities from pure niobium ingot

    DOE Patents [OSTI]

    Myneni, Ganapati Rao (Yorktown, VA); Kneisel, Peter (Williamsburg, VA); Cameiro, Tadeu (McMurray, PA)

    2012-03-06

    Niobium cavities are fabricated by the drawing and ironing of as cast niobium ingot slices rather than from cold rolled niobium sheet. This method results in the production of niobium cavities having a minimum of grain boundaries at a significantly reduced cost as compared to the production of such structures from cold rolled sheet.

  5. Modeling and Optimization of Direct Chill Casting to Reduce Ingot Cracking

    Office of Scientific and Technical Information (OSTI)

    Aluminum Industry of the Future Managed by UT-Battelle, LLC Final Technical Report Modeling and Optimization of Direct Chill Casting to Reduce Ingot Cracking June 2006 Principal Investigator: Subodh K. Das Secat, Inc. ORNL/TM-2006/56 DOCUMENT AVAILABILITY Reports produced after January 1, 1996, are generally available free via the U.S. Department of Energy (DOE) Information Bridge. Web site http://www.osti.gov/bridge Reports produced before January 1, 1996, may be purchased by members of the

  6. Nitrogen doping study in ingot niobium cavities

    SciTech Connect (OSTI)

    Dhakal, Pashupati; Ciovati, Gianluigi; Kneisel, Peter; Myneni, Ganapati Rao; Makita, Junki

    2015-09-01

    Thermal diffusion of nitrogen in niobium superconducting radio frequency cavities at temperature ~800 C has resulted in the increase in quality factor with a low-field Q-rise extending to Bp > 90 mT. However, the maximum accelerating gradient of these doped cavities often deteriorates below the values achieved by standard treatments prior to doping. Here, we present the results of the measurements on ingot niobium cavities doped with nitrogen at 800 C. The rf measurements were carried out after the successive electropolishing to remove small amount of material from the inner surface layer. The result showed higher breakdown field with lower quality factor as material removal increases.

  7. Authorized limits for Fernald copper ingots

    SciTech Connect (OSTI)

    Frink, N.; Kamboj, S.; Hensley, J.; Chen, S. Y.

    1997-09-01

    This development document contains data and analysis to support the approval of authorized limits for the unrestricted release of 59 t of copper ingots containing residual radioactive material from the U.S. Department of Energy (DOE) Fernald Environmental Management Project (FEMP). The analysis presented in this document comply with the requirements of DOE Order 5400.5, {open_quotes}Radiation Protection of the Public and the Environment,{close_quotes} as well as the requirements of the proposed promulgation of this order as 10 CFR Part 834. The document was developed following the step-by-step process described in the Draft Handbook for Controlling Release for Reuse or Recycle Property Containing Residual Radioactive Material.

  8. Degassing of Aluminum Alloys Using Ultrasonic Vibration

    SciTech Connect (OSTI)

    Meek, T. T.; Han, Q.; Xu, H.

    2006-06-01

    The research was intended to lead to a better fundamental understanding of the effect of ultrasonic energy on the degassing of liquid metals and to develop practical approaches for the ultrasonic degassing of alloys. The goals of the project described here were to evaluate core principles, establish a quantitative basis for the ultrasonic degassing of aluminum alloy melts, and demonstrate the application of ultrsaonic processing during ingot casting and foundry shape casting.

  9. Characterization of Large Grain Nb Ingot Microstructure Using EBSP Mapping and Laue Camera Methods

    SciTech Connect (OSTI)

    Kang Di; Baars, Derek C.; Bieler, Thomas R.; Compton, Chris C.

    2011-03-31

    Large grain/single crystal Nb is currently being examined for fabricating superconducting radiofrequency (SRF) cavities as an alternative to using rolled sheet. Three ingot slices from different suppliers have been characterized and are compared. It is desirable to know the grain orientations of an ingot slice before fabrication. Characterization of an ingot slice has been done using electron backscattered pattern (EBSP) orientation imaging microscopy (OIM), which requires cutting out pieces from the slice, a destructive technique. Use of a Laue camera allows nondestructive characterization of grain orientations. The OIM method was used to examine ingot slices from CBMM and Ningxia, while the Laue method was used to examine a Heraeus ingot slice. The three ingot slices are compared in terms of their crystal orientations and grain boundary misorientations, indicating no obvious commonalities. The Laue method has practical advantages over OIM for evaluating ingot slices during the manufacturing process.

  10. Superconducting DC and RF Properties of Ingot Niobium

    SciTech Connect (OSTI)

    Pashupati Dhakal, Gianluigi Ciovati, Peter Kneisel, Ganapati Rao Myneni

    2011-07-01

    The thermal conductivity, DC magnetization and penetration depth of large-grain niobium hollow cylindrical rods fabricated from ingots, manufactured by CBMM subjected to chemical and heat treatment were measured. The results confirm the influence of chemical and heat-treatment processes on the superconducting properties, with no significant dependence on the impurity concentrations in the original ingots. Furthermore, RF properties, such as the surface resistance and quench field of the niobium rods were measured using a TE{sub 011} cavity. The hollow niobium rod is the center conductor of this cavity, converting it to a coaxial cavity. The quench field is limited by the critical heat flux through the rods' cooling channel.

  11. Method for locating metallic nitride inclusions in metallic alloy ingots

    DOE Patents [OSTI]

    White, Jack C. (Albany, OR); Traut, Davis E. (Corvallis, OR); Oden, Laurance L. (Albany, OR); Schmitt, Roman A. (Corvallis, OR)

    1992-01-01

    A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  12. Analysis of the scheduling problems in ingot handling

    SciTech Connect (OSTI)

    Bullington, S.F.; Moodie, C.L.

    1983-03-01

    The steel production processes from the steelmaking furnaces to the primary rolling mill are considered. A method for sequencing the heats to be refined in the steelmaking furnaces on a particular day is presented. Control procedures for use at the soaking pit area are also analyzed. A heuristic method is developed for sequencing heats to be refined in the steelmaking furnaces. The method is a simple, single-pass, ''look-ahead'' procedure which is based on the information provided by a dynamic ingot heating model. The heuristic considers the estimated future status of facilities, and the relative priority of different types of steel, in addition to optimal track time and soaking time information obtained from the ingot heating model. The optimal track times and soaking times obtained from the heating model are also used in the control of operations at the soaking pit area. The procedures are tested using a digital computer simulation model of a steel production facility. The ''forward-looking'' method is also compared to a ''backward-looking'' heuristic.

  13. Spray Rolling Aluminum Strip

    SciTech Connect (OSTI)

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  14. Dose Rate Calculation of TRU Metal Ingot in Pyroprocessing - 12202

    SciTech Connect (OSTI)

    Lee, Yoon Hee; Lee, Kunjai

    2012-07-01

    Spent fuel management has been a main problem to be solved for continuous utilization of nuclear energy. Spent fuel management policy of Korea is 'Wait and See'. It is focused on Pyro-process and SFR (Sodium-cooled Fast Reactor) for closed-fuel cycle research and development in Korea. For peaceful use of nuclear facilities, the proliferation resistance has to be proved. Proliferation resistance is one of key constraints in the deployment of advanced nuclear energy systems. Non-proliferation and safeguard issues have been strengthening internationally. Barriers to proliferation are that reduces desirability or attractiveness as an explosive and makes it difficult to gain access to the materials, or makes it difficult to misuse facilities and/or technologies for weapons applications. Barriers to proliferation are classified into intrinsic and extrinsic barriers. Intrinsic barrier is inherent quality of reactor materials or the fuel cycle that is built into the reactor design and operation such as material and technical barriers. As one of the intrinsic measures, the radiation from the material is considered significantly. Therefore the radiation of TRU metal ingot from the pyro-process was calculated using ORIGEN and MCNP code. (authors)

  15. AR-CITE

    Energy Science and Technology Software Center (OSTI)

    003796MLTPL00 AR-CITE: Analysis of Search Results for the Clarification and Identification of Technology Emergence

  16. CRADA 2009S001: Investigation of the Supercondcuting RF Properties of Large Grain Ingot Niobium

    SciTech Connect (OSTI)

    Grimm, Terry; Hollister, Jerry L.; Kolka, Ahren; Myneni, Ganapati Rao

    2012-12-18

    This CRADA intended to explore the properties of large grain ingot niobium by fabricating four single cell TESLA shaped accelerating cavities. Once the cavities were fabricated, SRF performance would be measured. Niowave received four discs of large grain ingot niobium from JLAB in February 2009. Niowave cut samples from each disc and tested the RRR. After the RRR was measured with disappointing results, the project lost interest. A no cost extension was signed in July 2009 to allow progress until June 2010, but ultimately no further work was accomplished by either party. No firm conclusions were drawn, as further investigations were not made. Large grain ingot niobium has shown real potential for high accelerating gradient superconducting cavities. However, this particular CRADA did not gather enough data to reach any conclusions in this regard.

  17. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solutions for a Dynamic World PDF icon alumvision.pdf More Documents & Publications ITP Aluminum: Alumina Technology Roadmap U.S. Energy Requirements for Aluminum Production...

  18. Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inert Anode Roadmap (1998) Energy and Environmental Profile of the U.S. Aluminum Industry ... Instrumentation Integrated with Mathematical Modeling for Aluminum Production ...

  19. Proposed sale of radioactively contaminated nickel ingots located at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    1995-10-01

    The U.S. Department of Energy (DOE) proposes to sell 8,500 radioactively contaminated nickel ingots (9.350 short tons), currently in open storage at the Paducah Gaseous Diffusion Plant (PGDP), to Scientific Ecology Group, Inc. (SEG) for decontamination and resale on the international market. SEG would take ownership of the ingots when they are loaded for transport by truck to its facility in Oak Ridge, Tennessee. SEG would receive approximately 200 short tons per month over approximately 48 months (an average of 180 ingots per month). The nickel decontamination process specified in SEG`s technical proposal is considered the best available technology and has been demonstrated in prototype at SEG. The resultant metal for resale would have contamination levels between 0.3 and 20 becquerel per gram (Bq/g). The health hazards associated with release of the decontaminated nickel are minimal. The activity concentration of the end product would be further reduced when the nickel is combined with other metals to make stainless steel. Low-level radioactive waste from the SEG decontamination process, estimated to be approximately 382 m{sup 3} (12,730 ft), would be shipped to a licensed commercial or DOE disposal facility. If the waste were packaged in 0.23 m{sup 3}-(7.5 ft{sup 3}-) capacity drums, approximately 1,500 to 1,900 drums would be transported over the 48-month contract period. Impacts from the construction of decontamination facilities and the selected site are minimal.

  20. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Roadmap for the Automotive Market (May 1999) ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) PDF icon autoroadmap.pdf More Documents ...

  1. Review of ingot niobium as a material for superconducting radiofrequency accelerating cavities

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kneisel, P.; Ciovati, G.; Dhakal, P.; Saito, K.; Singer, W.; Singer, X.; Myneni, G. R.

    2014-12-01

    As a result of collaboration between Jefferson Lab and niobium manufacturer Companhia Brasileira de Metalurgia e Mineração (CBMM), ingot niobium was explored as a possible material for superconducting radiofrequency (SRF) cavity fabrication. The first single cell cavity from large-grain high purity niobium was fabricated and successfully tested at Jefferson Lab in 2004. This work triggered research activities in other SRF laboratories around the world. The large-grain (LG) niobium became not only an interesting alternative material for cavity builders, but also material scientists and surface scientists were eager to participate in the development of this technology. Many single cell cavities mademore » from material of different suppliers have been tested successfully and several multi-cell cavities have shown performances comparable to the best cavities made from standard fine-grain niobium. Several 9-cell cavities fabricated by Research Instruments and tested at DESY exceeded the best performing fine grain cavities with a record accelerating gradient of Eacc=45.6 MV/m. The quality factor of those cavities was also higher than that of fine-grain (FG) cavities processed with the same methods. Such performance levels push the state-of-the art of SRF technology and are of great interest for future accelerators. This contribution reviews the development of ingot niobium technology and highlights some of the differences compared to standard FG material and opportunities for further developments.« less

  2. Review of ingot niobium as a material for superconducting radiofrequency accelerating cavities

    SciTech Connect (OSTI)

    Kneisel, P.; Ciovati, G.; Dhakal, P.; Saito, K.; Singer, W.; Singer, X.; Myneni, G. R.

    2014-12-01

    As a result of collaboration between Jefferson Lab and niobium manufacturer Companhia Brasileira de Metalurgia e Minerao (CBMM), ingot niobium was explored as a possible material for superconducting radiofrequency (SRF) cavity fabrication. The first single cell cavity from large-grain high purity niobium was fabricated and successfully tested at Jefferson Lab in 2004. This work triggered research activities in other SRF laboratories around the world. The large-grain (LG) niobium became not only an interesting alternative material for cavity builders, but also material scientists and surface scientists were eager to participate in the development of this technology. Many single cell cavities made from material of different suppliers have been tested successfully and several multi-cell cavities have shown performances comparable to the best cavities made from standard fine-grain niobium. Several 9-cell cavities fabricated by Research Instruments and tested at DESY exceeded the best performing fine grain cavities with a record accelerating gradient of Eacc=45.6 MV/m. The quality factor of those cavities was also higher than that of fine-grain (FG) cavities processed with the same methods. Such performance levels push the state-of-the art of SRF technology and are of great interest for future accelerators. This contribution reviews the development of ingot niobium technology and highlights some of the differences compared to standard FG material and opportunities for further developments.

  3. ITP Aluminum: Aluminum Industry Technology Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Roadmap ITP Aluminum: Aluminum Industry Technology Roadmap PDF icon al_roadmap.pdf More Documents & Publications ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) Overview of Recycling Technology R&D

  4. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  5. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  6. Nondestructive method for chemically machining crucibles or molds from their enclosed ingots and castings

    DOE Patents [OSTI]

    Stout, Norman D. (Livermore, CA); Newkirk, Herbert W. (Livermore, CA)

    1991-01-01

    An inventive method is described for chemically machining rhenium, rhenium and tungsten alloy, and group 5b and 6b crucibles or molds from included ingots and castings comprised of oxide crystals including YAG and YAG based crystals, garnets, corundum crystals, and ceramic oxides. A mixture of potassium hydroxide and 15 to 90 weight percent of potassium nitrate is prepared and maintained at a temperature above melting and below the lower of 500 degrees centigrade or the temperature of decomposition of the mixture. The enveloping metal container together with its included oxide crystal object is rotated within the heated KOH-KNO.sub.3 mixture, until the container is safely chemically machined away from the included oxide crystal object.

  7. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    World | Department of Energy Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World PDF icon alum_vision.pdf More Documents & Publications ITP Aluminum: Alumina Technology Roadmap U.S. Energy Requirements for Aluminum Production

  8. Agricultural Research Service (ARS) Research Participation Program...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home About USDA ARS About ORISE Current Research Opportunities Site Map Contact ORISE Facebook Twitter Applicants Welcome to the Agricultural Research Service (ARS) Research...

  9. Carbothermic Aluminum Production Using Scrap Aluminum As A Coolant

    DOE Patents [OSTI]

    LaCamera, Alfred F. (Trafford, PA)

    2002-11-05

    A process for producing aluminum metal by carbothermic reduction of alumina ore. Alumina ore is heated in the presence of carbon at an elevated temperature to produce an aluminum metal body contaminated with about 10-30% by wt. aluminum carbide. Aluminum metal or aluminum alloy scrap then is added to bring the temperature to about 900-1000.degree. C. and precipitate out aluminum carbide. The precipitated aluminum carbide is filtered, decanted, or fluxed with salt to form a molten body having reduced aluminum carbide content.

  10. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... It is a technological challenge for designers to balance ... projects will begin in the fall of 1999. Table X-1. ... Aluminum Explosion Prevention The Aluminum ...

  11. On the low carrier lifetime edge zone in multicrystalline silicon ingots

    SciTech Connect (OSTI)

    Jiang, Tingting; Yu, Xuegong; Wang, Lei; Gu, Xin; Yang, Deren, E-mail: mseyang@zju.edu.cn [State Key Laboratory of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

    2014-01-07

    We have demonstrated the cause of low minority carrier lifetime corresponding to the edge zone of casting multicrystalline silicon ingots and its influence on the performance of solar cells. It is found that the concentration of substitutional carbon, interstitial oxygen, and dislocation density have no direct correlation with the low minority carrier lifetime in the edge zone. However, the distribution of interstitial iron exactly coincides with the minority carrier lifetime, indicating that iron contamination is mainly responsible for the lifetime degradation. After phosphorus diffusion gettering process, the low carrier lifetime region became narrower, and the concentration of interstitial iron is reduced by almost one order of magnitude. However, the carrier lifetime in the edge zone cannot be raised to average level. After celling process, the internal quantum efficiency map of the edge zone has a lower response to the long wavelength light, in accordance with the minority carrier lifetime distribution in this region. Therefore, the solar cells based on edge zones exhibit slightly lower efficiency than those conventional ones.

  12. Ar-40/Ar-39 Age Constraints for the Jaramillo Normal Subchron...

    Open Energy Info (EERE)

    oxygen isotope, climate record calibration of the astronomical timescale proposed by Johnson (1982) and Shackleton et al. (1990). Ar-40Ar-39 ages of a normally magnetized...

  13. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1999) | Department of Energy Aluminum Industry Roadmap for the Automotive Market (May 1999) ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) PDF icon autoroadmap.pdf More Documents & Publications Vehicle Technologies Office: US DRIVE Materials Technical Team Roadmap Development of Integrated Die Casting Process for Large Thin-Wall Magnesium Applications Enabling Production of Lightweight Magnesium Parts for Near-Term Automotive Applications ITP Aluminum:

  14. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  15. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  16. Scientists ignite aluminum water mix

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientists ignite aluminum water mix Scientists ignite aluminum water mix Don't worry, that beer can you're holding is not going to spontaneously burst into flames. June 30, 2014 Los Alamos National Laboratory chemist Bryce Tappan ignites a small quantity of aluminum nanoparticle water mixture. In open air, the compound burns like a Fourth of July sparkler. Los Alamos National Laboratory chemist Bryce Tappan ignites a small quantity of aluminum nanoparticle water mixture. In open air, the

  17. Fluxless aluminum brazing

    DOE Patents [OSTI]

    Werner, W.J.

    1974-01-01

    This invention relates to a fluxless brazing alloy for use in forming brazed composites made from members of aluminum and its alloys. The brazing alloy consists of 35-55% Al, 10--20% Si, 25-60% Ge; 65-88% Al, 2-20% Si, 2--18% In; 65--80% Al, 15-- 25% Si, 5- 15% Y. (0fficial Gazette)

  18. Aluminum battery alloys

    DOE Patents [OSTI]

    Thompson, David S. (Richmond, VA); Scott, Darwin H. (Mechanicsville, VA)

    1985-01-01

    Aluminum alloys suitable for use as anode structures in electrochemical cs are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.

  19. SOLDERING OF ALUMINUM BASE METALS

    DOE Patents [OSTI]

    Erickson, G.F.

    1958-02-25

    This patent deals with the soldering of aluminum to metals of different types, such as copper, brass, and iron. This is accomplished by heating the aluminum metal to be soldered to slightly above 30 deg C, rubbing a small amount of metallic gallium into the part of the surface to be soldered, whereby an aluminum--gallium alloy forms on the surface, and then heating the aluminum piece to the melting point of lead--tin soft solder, applying lead--tin soft solder to this alloyed surface, and combining the aluminum with the other metal to which it is to be soldered.

  20. 244-AR Vault Interim Stabilization Project Plan

    SciTech Connect (OSTI)

    LANEY, T.

    2000-03-24

    The 244-AR Vault Facility, constructed between 1966 and 1968, was designed to provide lag storage and treatment for the Plutonium-Uranium Extraction Facility (PUREX) tank farm sludges. Tank farm personnel transferred the waste from the 244-AR Vault Facility to B Plant for recovery of cesium and strontium. B Plant personnel then transferred the treatment residuals back to the tank farms for storage of the sludge and liquids. The last process operations, which transferred waste supporting the cesium/strontium recovery mission, occurred in April 1978. After the final transfer in 1978, the 244-AR facility underwent a cleanout. However, 2,271 L (600 gal) of sludge were left in Tank 004AR from an earlier transfer from Tank 241-AX-104. When the cleanout was completed, the facility was placed in a standby status. The sludge had been transferred to Tank 004AR to support Pacific Northwest National Laboratory [PNNL] vitrification work. Documentation of waste transfers suggests that a portion of the sludge may have been moved from Tank 004AR to Tank 002AR in preparation for transfer back to the AX Tank Farm; however, quantities of the sludge that were moved to Tank 002AR from that transfer must be estimated.

  1. Scientists ignite aluminum water mix

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of a chemical reaction - is a primary function in determining nanoaluminum combustion burn rates. "It's been long understood that nanoscale aluminum particles, 110 nanometers and...

  2. Aluminum processing energy benchmark report

    SciTech Connect (OSTI)

    None, None

    2007-02-01

    Substantial energy efficiency gains have been made in the aluminum industry over the past forty years, resulting in a 58 percent decrease in energy utilization.

  3. ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industry | Department of Energy ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum Industry ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum Industry PDF icon aluminum.pdf More Documents & Publications ITP Aluminum: Technical Working Group on Inert Anode Technologies TTWG Licensing Guide EIS-0333: Draft Environmental Impact Statement

  4. Production of aluminum metal by electrolysis of aluminum sulfide

    DOE Patents [OSTI]

    Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

    1982-04-01

    Metallic aluminum may be produced by the electrolysis of Al/sub 2/S/sub 3/ at 700 to 800/sup 0/C in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

  5. Production of aluminum metal by electrolysis of aluminum sulfide

    DOE Patents [OSTI]

    Minh, Nguyen Q. (Woodridge, IL); Loutfy, Raouf O. (Tucson, AZ); Yao, Neng-Ping (Clarendon Hills, IL)

    1984-01-01

    Production of metallic aluminum by the electrolysis of Al.sub.2 S.sub.3 at 700.degree.-800.degree. C. in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

  6. Mueller Systems ArKion | Open Energy Information

    Open Energy Info (EERE)

    Mueller Systems ArKion Jump to: navigation, search Name: Mueller Systems (ArKion) Place: Middleboro, Massachusetts Zip: MA 02346 Product: Massachusetts-based energy management...

  7. PREPARATION OF URANIUM-ALUMINUM ALLOYS

    DOE Patents [OSTI]

    Moore, R.H.

    1962-09-01

    A process is given for preparing uranium--aluminum alloys from a solution of uranium halide in an about equimolar molten alkali metal halide-- aluminum halide mixture and excess aluminum. The uranium halide is reduced and the uranium is alloyed with the excess aluminum. The alloy and salt are separated from each other. (AEC)

  8. Electrolyte treatment for aluminum reduction

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA); Juric, Drago D. (Bulleen, AU)

    2002-01-01

    A method of treating an electrolyte for use in the electrolytic reduction of alumina to aluminum employing an anode and a cathode, the alumina dissolved in the electrolyte, the treating improving wetting of the cathode with molten aluminum during electrolysis. The method comprises the steps of providing a molten electrolyte comprised of ALF.sub.3 and at least one salt selected from the group consisting of NaF, KF and LiF, and treating the electrolyte by providing therein 0.004 to 0.2 wt. % of a transition metal or transition metal compound for improved wettability of the cathode with molten aluminum during subsequent electrolysis to reduce alumina to aluminum.

  9. Microsoft Word - AR VR rev.1.wpd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EA15PC3041-1-0 August 18, 2003 Rev. 1 Page 1 of 1 Working Copy AR/VR Transmittal Register 1. Page 1 of 2. PR/PO Number: 3. Supplier: 4. Buyer: 5. STR or Cognizant Engineer: 6. Project, System, or Equipment Description: 7. AR/VR No. 8. SOW or Spec. No. 9. Description of Submittal or Special Conditions 10. For Approval/ Record 11. Date Due to WTS or Prior to 12. Date Rec. 13. Date to STR 14. Date from STR 15. Disposition A, C, D 16. Resubmittal Required? 17. Date to Supplier 1. Facility Compliance

  10. APPROVAL/VARIATION REQUEST (AR/VR)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APPROVAL/VARIATION REQUEST (AR/VR) EA15PC3041-2-0 May 30, 2013 Rev. 5 Page 1 of 2 Supplier - enter/complete all applicable blanks and check-boxes (in accordance with attached instructions). 1. APPROVAL REQUEST 2. VARIATION REQUEST - Yes No 3. PO/Subcontract No. 4. AR/VR No. 5. Resubmittal 6. Supplier Company Name 7. Describe request in detail (attach additional documents, if necessary). Reference or list applicable specifications, drawings, document numbers, equipment numbers, etc. If Approval

  11. Aluminum industry applications for OTEC

    SciTech Connect (OSTI)

    Jones, M.S.; Leshaw, D.; Sathyanarayana, K.; Sprouse, A.M.; Thiagarajan, V.

    1980-12-01

    The objective of the program is to study the integration issues which must be resolved to realize the market potential of ocean thermal energy conversion (OTEC) power for the aluminum industry. The study established, as a baseline, an OTEC plant with an electrical output of 100 MWe which would power an aluminum reduction plant. The reduction plant would have a nominal annual output of about 60,000 metric tons of aluminum metal. Three modes of operation were studied, viz: 1. A reduction plant on shore and a floating OTEC power plant moored offshore supplying energy by cable. 2. A reduction plant on shore and a floating OTEC power plant at sea supplying energy by means of an ''energy bridge.'' 3. A floating reduction plant on the same platform as the OTEC power plant. For the floating OTEC/aluminum plantship, three reduction processes were examined. 1. The conventional Hall process with prebaked anodes. 2. The drained cathode Hall cell process. 3. The aluminum chloride reduction process.

  12. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (Auburn, AL); Dispennette, John M. (Auburn, AL)

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  13. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  14. Dissolution and Separation of Aluminum and Aluminosilicates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McFarlane, Joanna; Benker, Dennis; DePaoli, David W.; Felker, Leslie Kevin; Mattus, Catherine H.

    2015-12-19

    The selection of an aluminum alloy for target irradiation affects post-irradiation target dissolution and separations. Recent tests with aluminum alloy 6061 yielded greater than expected precipitation in the dissolver, forming up to 10 wt.% solids of aluminum hydroxides and aluminosilicates. Aluminosilicate dissolution presents challenges in a number of different areas, metals extraction from minerals, flyash treatment, and separations from aluminum alloys. We present experimental work that attempts to maximize dissolution of aluminum metal, along with silicon, magnesium, and copper impurities, through control of temperature, the rate of reagent addition, and incubation time. Aluminum phase transformations have been identified as amore » function of time and temperature, using X-ray diffraction. Solutions have been analyzed using wet chemical methods and X-ray fluorescence. Our data have been compared with published calculations of aluminum phase diagrams. Approaches are given to enhance the dissolution of aluminum and aluminosilicate phases in caustic solution.« less

  15. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

    2004-11-02

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  16. Ultrahigh-Efficiency Aluminum Production Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultrahigh-Efficiency Aluminum Production Cells Saving Energy and Reducing Carbon Emissions with Cell Redesign and Novel Electrolytes This project will develop a multipolar aluminum electrolysis cell technology with an inert anode, a wetted cathode design, a novel low-temperature electrolyte, and advanced sensors and controls. These advancements will save energy, reduce greenhouse gas emissions, cut aluminum production costs, and increase productivity. Introduction Aluminum is an indispensable

  17. A.R.S. 11-801 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 11-801 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-801Legal Abstract County Planning: Definitions...

  18. A.R.S. 41-865 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-865Legal Published NA Year Signed or Took Effect 2015 Legal Citation A.R.S. ...

  19. A.R.S. 11-802 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 11-802 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-802Legal Abstract County Planning: County planning...

  20. A.R.S. 40-281 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 40-281 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-281Legal Abstract Power Plant and Transmission Line...

  1. A.R.S. 40-360 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 40-360 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-360Legal Published NA Year Signed or Took Effect...

  2. A.R.S. 40-282 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 40-282 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 40-282Legal Abstract Power Plant and Transmission Line...

  3. A.R.S. 9-462 | Open Energy Information

    Open Energy Info (EERE)

    A.R.S. 9-462 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 9-462Legal Published NA Year Signed or Took Effect...

  4. Category:Little Rock, AR | Open Energy Information

    Open Energy Info (EERE)

    71 KB SVMediumOffice Little Rock AR Entergy Arkansas Inc.png SVMediumOffice Little ... 68 KB SVMidriseApartment Little Rock AR Entergy Arkansas Inc.png SVMidriseApartment Lit......

  5. ARS 12 - Courts and Civil Proceedings | Open Energy Information

    Open Energy Info (EERE)

    ARS 12 - Courts and Civil Proceedings Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 12 - Courts and Civil ProceedingsLegal...

  6. ITP Aluminum: Alumina Technology Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alumina Technology Roadmap ITP Aluminum: Alumina Technology Roadmap PDF icon alumina.pdf More Documents & Publications U.S. Energy Requirements for Aluminum Production ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Technology Roadmap

  7. Decarbonization process for carbothermically produced aluminum

    DOE Patents [OSTI]

    Bruno, Marshall J.; Carkin, Gerald E.; DeYoung, David H.; Dunlap, Sr., Ronald M.

    2015-06-30

    A method of recovering aluminum is provided. An alloy melt having Al.sub.4C.sub.3 and aluminum is provided. This mixture is cooled and then a sufficient amount of a finely dispersed gas is added to the alloy melt at a temperature of about 700.degree. C. to about 900.degree. C. The aluminum recovered is a decarbonized carbothermically produced aluminum where the step of adding a sufficient amount of the finely dispersed gas effects separation of the aluminum from the Al.sub.4C.sub.3 precipitates by flotation, resulting in two phases with the Al.sub.4C.sub.3 precipitates being the upper layer and the decarbonized aluminum being the lower layer. The aluminum is then recovered from the Al.sub.4C.sub.3 precipitates through decanting.

  8. MEIS1 functions as a potential AR negative regulator

    SciTech Connect (OSTI)

    Cui, Liang; Yang, Yutao; Hang, Xingyi; Cui, Jiajun; Gao, Jiangping

    2014-10-15

    The androgen receptor (AR) plays critical roles in human prostate carcinoma progression and transformation. However, the activation of AR is regulated by co-regulators. MEIS1 protein, the homeodomain transcription factor, exhibited a decreased level in poor-prognosis prostate tumors. In this study, we investigated a potential interaction between MEIS1 and AR. We found that overexpression of MEIS1 inhibited the AR transcriptional activity and reduced the expression of AR target gene. A potential proteinprotein interaction between AR and MEIS1 was identified by the immunoprecipitation and GST pull-down assays. Furthermore, MEIS1 modulated AR cytoplasm/nucleus translocation and the recruitment to androgen response element in prostate specific antigen (PSA) gene promoter sequences. In addition, MEIS1 promoted the recruitment of NCoR and SMRT in the presence of R1881. Finally, MEIS1 inhibited the proliferation and anchor-independent growth of LNCaP cells. Taken together, our data suggests that MEIS1 functions as a novel AR co-repressor. - Highlights: A potential interaction was identified between MEIS1 and AR signaling. Overexpression of MEIS1 reduced the expression of AR target gene. MEIS1 modulated AR cytoplasm/nucleus translocation. MEIS1 inhibited the proliferation and anchor-independent growth of LNCaP cells.

  9. Titanium Matrix Composite Tooling Material for Aluminum Die Castings |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Titanium Matrix Composite Tooling Material for Aluminum Die Castings Titanium Matrix Composite Tooling Material for Aluminum Die Castings Innovative Material Saves Energy and Extends Product Life In Aluminum Die-Casting Components In aluminum die-casting, molten aluminum is forced under high pressure into a die cavity. First a "shot" of molten aluminum is ladled into a shot sleeve and the shot of molten aluminum is forced by a plunger through the shot sleeve

  10. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  11. MECS 2006 - Alumina and Aluminum | Department of Energy

    Office of Environmental Management (EM)

    Alumina and Aluminum MECS 2006 - Alumina and Aluminum Manufacturing Energy and Carbon Footprint for Alumina and Aluminum Sector (NAICS 3313) with Total Energy Input, October 2012 (MECS 2006) All available footprints and supporting documents Manufacturing Energy and Carbon Footprint PDF icon Alumina and Aluminum More Documents & Publications Alumina and Aluminum (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass

  12. PREPARATION OF ACTINIDE-ALUMINUM ALLOYS

    DOE Patents [OSTI]

    Moore, R.H.

    1962-09-01

    BS>A process is given for preparing alloys of aluminum with plutonium, uranium, and/or thorium by chlorinating actinide oxide dissolved in molten alkali metal chloride with hydrochloric acid, chlorine, and/or phosgene, adding aluminum metal, and passing air and/or water vapor through the mass. Actinide metal is formed and alloyed with the aluminum. After cooling to solidification, the alloy is separated from the salt. (AEC)

  13. Aluminum-stabilized NB3SN superconductor

    DOE Patents [OSTI]

    Scanlan, Ronald M. (Livermore, CA)

    1988-01-01

    An aluminum-stabilized Nb.sub.3 Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb.sub.3 Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials.

  14. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W.; Coombs, III, Arthur W.; Yee, Jick H.

    2005-05-03

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  15. Enhanced structural color generation in aluminum metamaterials...

    Office of Scientific and Technical Information (OSTI)

    with a thin polymer layer Citation Details In-Document Search Title: Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer Authors: ...

  16. Regeneration of Aluminum Hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Describes methods and materials required for the formation of alanes. Lowering the free energy of the reaction by making use of "catalyzed aluminum" and formation of ...

  17. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W. (Livermore, CA); Coombs, III, Arthur W. (Patterson, CA); Yee, Jick H. (Livermore, CA)

    2007-12-18

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  18. http://www.ars.usda.gov/research/publications/Publications.htm...

    National Nuclear Security Administration (NNSA)

    - Ed Wagner, Larry Tatarko, John Publications Publications Related National Programs Air Quality (203) Soil Resource Management (202) Page 1 of 2 ARS | Publication request:...

  19. ITP Aluminum: Inert Anodes Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inert Anodes Roadmap ITP Aluminum: Inert Anodes Roadmap PDF icon inertroad.pdf More Documents & Publications U.S. Energy Requirements for Aluminum Production Ultrahigh-Efficiency Aluminum Production Cells

  20. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at Two Aluminum Sheet Production Operations | Department of Energy Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments at Two Aluminum Sheet Production Operations Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments at Two Aluminum Sheet Production Operations This case study describes how Commonwealth Industries (now Aleris Rolled Products) conducted plant-wide energy assessments at its aluminum sheet rolling mills in Lewisport, Kentucky, and

  1. Aluminum low temperature smelting cell metal collection

    DOE Patents [OSTI]

    Beck, Theodore R. (Seattle, WA); Brown, Craig W. (Seattle, WA)

    2002-07-16

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten salt electrolyte in an electrolytic cell having an anodic liner for containing the electrolyte, the liner having an anodic bottom and walls including at least one end wall extending upwardly from the anodic bottom, the anodic liner being substantially inert with respect to the molten electrolyte. A plurality of non-consumable anodes is provided and disposed vertically in the electrolyte. A plurality of cathodes is disposed vertically in the electrolyte in alternating relationship with the anodes. The anodes are electrically connected to the anodic liner. An electric current is passed through the anodic liner to the anodes, through the electrolyte to the cathodes, and aluminum is deposited on said cathodes. Oxygen bubbles are generated at the anodes and the anodic liner, the bubbles stirring the electrolyte. Molten aluminum is collected from the cathodes into a tubular member positioned underneath the cathodes. The tubular member is in liquid communication with each cathode to collect the molten aluminum therefrom while excluding electrolyte. Molten aluminum is delivered through the tubular member to a molten aluminum reservoir located substantially opposite the anodes and cathodes. The molten aluminum is collected from the cathodes and delivered to the reservoir while avoiding contact of the molten aluminum with the anodic bottom.

  2. U.S. Energy Requirements for Aluminum Production | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Requirements for Aluminum Production U.S. Energy Requirements for Aluminum Production Historical Perspective, Theoretical Limits, and Current Practices. PDF icon U.S. Energy Requirements for Aluminum Production (February 2007) More Documents & Publications Ultrahigh-Efficiency Aluminum Production Cells ITP Aluminum: Aluminum Industry Technology Roadmap ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World

  3. Gating of Permanent Molds for ALuminum Casting

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Tom Engle; Qingming Chang

    2004-03-30

    This report summarizes a two-year project, DE-FC07-01ID13983 that concerns the gating of aluminum castings in permanent molds. The main goal of the project is to improve the quality of aluminum castings produced in permanent molds. The approach taken was determine how the vertical type gating systems used for permanent mold castings can be designed to fill the mold cavity with a minimum of damage to the quality of the resulting casting. It is evident that somewhat different systems are preferred for different shapes and sizes of aluminum castings. The main problems caused by improper gating are entrained aluminum oxide films and entrapped gas. The project highlights the characteristic features of gating systems used in permanent mold aluminum foundries and recommends gating procedures designed to avoid common defects. The study also provides direct evidence on the filling pattern and heat flow behavior in permanent mold castings.

  4. Large grain CBMM Nb ingot slices: An ideal test bed for exploring the microstructure-electromagnetic property relationships relevant to SRF

    SciTech Connect (OSTI)

    Sung, Zu -Hawn; Lee, Peter J.; Polyanskii, Anatolii; Balachandran, Shreyas; Chetri, Santosh; Larbalestier, David C.; Wang, Mingmin; Compton, Christopher; Bieler, Thomas R.

    2015-12-04

    High purity (RRR > 200), large grain (> 5-10 cm) niobium ingot slices have been successfully used to fabricate radio frequency (RF) cavities for particle accelerators. In addition, they offer significantly reduced fabrication cost by eliminating processing steps and furthermore they provide the opportunity to study the influence of individual grain boundaries in SRF Nb. Here we summarize our measurements of grain boundary (GB) effects on the superconducting properties of large grain high purity niobium sheet manufactured by CBMM. We show by magneto-optical (MO) imaging that GBs allow premature flux penetration, but only when they are oriented close to the direction of the magnetic field. However, even low angle GBs produced by minor deformations commensurate with half-cell forming produce localized flux penetration. The transport properties of grain boundaries were investigated by direct transport across them and evidence for preferential vortex flow along the GBs of SRF Nb was observed for the first time. Using transmission electron microscopy (TEM) and micro crystallographic analysis with electron backscattered diffraction (EBSD), we were able to quantitatively characterize surface substructures that can lead to localized thermal breakdown of superconductivity. Important to these studies was the development of sample preparation techniques that made the cut-out single, bi-crystal and tri-crystal Nb coupons as representative as possible of the surface properties of cavities manufactured by standard techniques.

  5. Large grain CBMM Nb ingot slices: An ideal test bed for exploring the microstructure-electromagnetic property relationships relevant to SRF

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sung, Zu -Hawn; Lee, Peter J.; Polyanskii, Anatolii; Balachandran, Shreyas; Chetri, Santosh; Larbalestier, David C.; Wang, Mingmin; Compton, Christopher; Bieler, Thomas R.

    2015-12-04

    High purity (RRR > 200), large grain (> 5-10 cm) niobium ingot slices have been successfully used to fabricate radio frequency (RF) cavities for particle accelerators. In addition, they offer significantly reduced fabrication cost by eliminating processing steps and furthermore they provide the opportunity to study the influence of individual grain boundaries in SRF Nb. Here we summarize our measurements of grain boundary (GB) effects on the superconducting properties of large grain high purity niobium sheet manufactured by CBMM. We show by magneto-optical (MO) imaging that GBs allow premature flux penetration, but only when they are oriented close to themore » direction of the magnetic field. However, even low angle GBs produced by minor deformations commensurate with half-cell forming produce localized flux penetration. The transport properties of grain boundaries were investigated by direct transport across them and evidence for preferential vortex flow along the GBs of SRF Nb was observed for the first time. Using transmission electron microscopy (TEM) and micro crystallographic analysis with electron backscattered diffraction (EBSD), we were able to quantitatively characterize surface substructures that can lead to localized thermal breakdown of superconductivity. Important to these studies was the development of sample preparation techniques that made the cut-out single, bi-crystal and tri-crystal Nb coupons as representative as possible of the surface properties of cavities manufactured by standard techniques.« less

  6. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  7. Formulation and method for preparing gels comprising hydrous aluminum oxide

    SciTech Connect (OSTI)

    Collins, Jack L.

    2014-06-17

    Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

  8. A scanning Kelvin probe analysis of aluminum and aluminum alloys

    SciTech Connect (OSTI)

    Hansen, D.C.; Grecsek, G.E.; Roberts, R.O.

    1999-07-01

    A scanning Kelvin probe was used to determine a correlation between work function measurements in air and corrosion potential measurements in solution of pure metals. Test panels of AA2024-T3 treated with various surface preparations and primer/coatings were also analyzed using this technique. Filiform corrosion was observed on a scribed panel that had been exposed to a humid environment, whereas on a non-scribed and non-exposed test panel, holidays in the coating were observed and clearly defined. Work function (wf) analysis yielded more noble values for areas within the scribe mark and more active values were observed for areas adjacent to the scribe mark where delamination of the coating and filiform corrosion was observed. The tips of corrosion filaments were found to be anodic in relation to the body of the filament, with areas of activity extending away from the filaments themselves. Measurements made on an aircraft access panel resulted in the detection of a potential gradient within the repair area. These results indicate that the scanning Kelvin probe is a useful non-destructive technique for the detection of delamination and disbanding of coatings, coating anomalies and corrosion susceptibility of coatings on aluminum aircraft alloys.

  9. Study of constitution diagram aluminum-tantalum

    SciTech Connect (OSTI)

    Glazov, V.M.; Mal'tsev, M.V.; Chistyakov, Y.D.

    1988-10-20

    Alloys of aluminum with tantalum were for the first time obtained by aluminothermic method in 1868 by Moriniak. Later these alloys were studied in the works of Schirmeister (1915) and Brouwer (1938), moreover Brouwer established that tantalum with aluminum forms the chemical compound TaA1, which has tetragonal crystal lattice with parameters a=5.422 angstroms and c=8.536 angstroms (1). However despite the fact that alloys of aluminum with tantalum long ago are obtained already, constitution diagram of this system is not studied until recently. In connection with the application of tantalum as the modifying additive in aluminum alloys an emergency in the construction of this diagram, without the knowledge by which it is not possible to give the correct explanation of the mechanism of the very process of the modification of primary grain. For this purpose was undertaken this work. Russian translations.

  10. Regeneration of aluminum hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy ...

  11. Aqueous recovery of actinides from aluminum alloys

    SciTech Connect (OSTI)

    Gray, J.H.; Chostner, D.F.; Gray, L.W.

    1989-01-01

    Early in the 1980's, a joint Rocky Flats/Savannah River program was established to recover actinides from scraps and residues generated during Rocky Flats purification operations. The initial program involved pyrochemical treatment of Molten Salt Extraction (MSE) chloride salts and Electrorefining (ER) anode heel metal to form aluminum alloys suitable for aqueous processing at Savannah River. Recently Rocky Flats has expressed interest in expanding the aluminum alloy program to include treatment of chloride salt residues from a modified Molten Salt Extraction process and from the Electrorefining purification operations. Samples of the current aluminum alloy buttons were prepared at Rocky Flats and sent to Savannah River Laboratory for flowsheet development and characterization of the alloys. A summary of the scrub alloy-anode heel alloy program will be presented along with recent results from aqueous dissolution studies of the new aluminum alloys. 2 figs., 4 tabs.

  12. High-Temperature Aluminum Alloys | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Alloys High-Temperature Aluminum Alloys 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm044_smith_2012_o.pdf More Documents & Publications High-Temperature Aluminum Alloys Vehicle Technologies Office Merit Review 2014: High Temperature Aluminum Alloys (Agreement ID:24034) Project ID:18518 Vehicle Technologies Office Merit Review 2015: Rapidly Solidified High Temperature Aluminum Alloys

  13. Alumina and Aluminum (2010 MECS) | Department of Energy

    Energy Savers [EERE]

    Alumina and Aluminum (2010 MECS) Alumina and Aluminum (2010 MECS) Manufacturing Energy and Carbon Footprint for Alumina and Aluminum Sector (NAICS 3313) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint PDF icon Alumina and Aluminum More Documents & Publications MECS 2006 - Alumina and Aluminum Cement (2010 MECS) Glass and Glass Products

  14. A.R.S. 11-804 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-804Legal Abstract This section authorizes counties to develop and adopt...

  15. A.R.S. 41-841 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-841Legal Abstract Archaeological Discoveries Published NA Year Signed or Took...

  16. A.R.S. 41-842 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-842Legal Abstract Discusses the requirement of prior authorization in order to...

  17. A.R.S. 41-861 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-861Legal Abstract This section discusses agency responsibility for the...

  18. A.R.S. 41-843 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 41-843Legal Abstract Prohibits the unnecessary defacing of an archaeological and...

  19. 49 A.R.S. 201: Definitions | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 201: DefinitionsLegal Abstract This section contains definitions that relate to water...

  20. A.R.S. 11-811 | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 11-811Legal Abstract This section authorizes counties to adopt zoning ordinances....

  1. ARS 41-1092 Uniform Administrative Hearing Procedures | Open...

    Open Energy Info (EERE)

    92 Uniform Administrative Hearing Procedures Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 41-1092 Uniform Administrative...

  2. ARS 41-1072 Licensing Time Frames | Open Energy Information

    Open Energy Info (EERE)

    1-1072 Licensing Time Frames Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS 41-1072 Licensing Time FramesLegal Abstract...

  3. Beta decay of 32Ar for fundamental tests

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    decay of 32 Ar for fundamental tests Chris Wrede University of Washington Argonne-ATLAS user meeting August 8 th , 2009 Outline * 1999 measurement of positron-neutrino correlation...

  4. ARS 40 - Public Utilities and Carriers | Open Energy Information

    Open Energy Info (EERE)

    StatuteStatute: ARS 40 - Public Utilities and CarriersLegal Abstract This title sets forth the statutes for public utilities and carriers in Arizona. Published NA Year Signed...

  5. Combined U-Th/He and 40Ar/39Ar geochronology of post-shield lavas from the Mauna Kea and Kohala volcanoes, Hawaii

    SciTech Connect (OSTI)

    Aciego, S.M.; Jourdan, F.; DePaolo, D.J.; Kennedy, B.M.; Renne, P.R.; Sims, K.W.W.

    2009-10-01

    Late Quaternary, post-shield lavas from the Mauna Kea and Kohala volcanoes on the Big Island of Hawaii have been dated using the {sup 40}Ar/{sup 39}Ar and U-Th/He methods. The objective of the study is to compare the recently demonstrated U-Th/He age method, which uses basaltic olivine phenocrysts, with {sup 40}Ar/{sup 39}Ar ages measured on groundmass from the same samples. As a corollary, the age data also increase the precision of the chronology of volcanism on the Big Island. For the U-Th/He ages, U, Th and He concentrations and isotopes were measured to account for U-series disequilibrium and initial He. Single analyses U-Th/He ages for Hamakua lavas from Mauna Kea are 87 {+-} 40 ka to 119 {+-} 23 ka (2{sigma} uncertainties), which are in general equal to or younger than {sup 40}Ar/{sup 39}Ar ages. Basalt from the Polulu sequence on Kohala gives a U-Th/He age of 354 {+-} 54 ka and a {sup 40}Ar/{sup 39}Ar age of 450 {+-} 40 ka. All of the U-Th/He ages, and all but one spurious {sup 40}Ar/{sup 39}Ar ages conform to the previously proposed stratigraphy and published {sup 14}C and K-Ar ages. The ages also compare favorably to U-Th whole rock-olivine ages calculated from {sup 238}U - {sup 230}Th disequilibria. The U-Th/He and {sup 40}Ar/{sup 39}Ar results agree best where there is a relatively large amount of radiogenic {sup 40}Ar (>10%), and where the {sup 40}Ar/{sup 36}Ar intercept calculated from the Ar isochron diagram is close to the atmospheric value. In two cases, it is not clear why U-Th/He and {sup 40}Ar/{sup 39}Ar ages do not agree within uncertainty. U-Th/He and {sup 40}Ar/{sup 39}Ar results diverge the most on a low-K transitional tholeiitic basalt with abundant olivine. For the most alkalic basalts with negligible olivine phenocrysts, U-Th/He ages were unattainable while {sup 40}Ar/{sup 39}Ar results provide good precision even on ages as low as 19 {+-} 4 ka. Hence, the strengths and weaknesses of the U-Th/He and {sup 40}Ar/{sup 39}Ar methods are complimentary for basalts with ages of order 100-500 ka.

  6. Low Temperature Aluminum Dissolution Of Sludge Waste

    SciTech Connect (OSTI)

    Keefer, M.T.; Hamm, B.A.; Pike, J.A. [Washington Savannah River Company, Aiken, SC (United States)

    2008-07-01

    High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. The sludge is currently being stabilized in the Defense Waste Processing Facility (DWPF) through a vitrification process immobilizing the waste in a borosilicate glass matrix for long-term storage in a federal repository. Without additional treatment, the existing volume of sludge would produce nearly 8000 canisters of vitrified waste. Aluminum compounds, along with other non-radioactive components, represent a significant portion of the sludge mass currently planned for vitrification processing in DWPF. Removing the aluminum from the waste stream reduces the volume of sludge requiring vitrification and improves production rates. Treating the sludge with a concentrated sodium hydroxide (caustic) solution at elevated temperatures (>90 deg. C) to remove aluminum is part of an overall sludge mass reduction effort to reduce the number of vitrified canisters, shorten the life cycle for the HLW system, and reduce the risk associated with the long term storage of radioactive wastes at SRS. A projected reduction of nearly 900 canisters will be achieved by performing aluminum dissolution on six targeted sludge batches; however, a project to develop and install equipment will not be ready for operation until 2013. The associated upgrades necessary to implement a high temperature process in existing facilities are costly and present many technical challenges. Efforts to better understand the characteristics of the sludge mass and dissolution kinetics are warranted to overcome these challenges. Opportunities to further reduce the amount of vitrified waste and increase production rates should also be pursued. Sludge staged in Tank 51 as the next sludge batch for feed to DWPF consisted primarily of radioactive wastes containing a very high aluminum concentration. Based on initial laboratory testing and previous sludge characterization, aluminum in this sludge could be dissolved at low temperature (no more than 65 deg. C) in a concentrated caustic solution. The amount of aluminum predicted to dissolve under these conditions ranged from 25% to 80%. An opportunity existed to remove a significant amount of aluminum prior to vitrification in DWPF and increase the level of understanding of the effects of caustic dissolution of aluminum at lower temperatures. This paper presents the results of a real waste laboratory demonstration and full-scale implementation of a low temperature aluminum dissolution process which should be considered as a viable means to reduce radioactive sludge mass and reduce the amount of waste to be vitrified. (authors)

  7. Underwater vapor phase burning of aluminum particles and on aluminum ignition during steam explosions

    SciTech Connect (OSTI)

    Epstein, M. )

    1991-09-01

    Recently reported experimental studies on aluminum-water steam explosions indicate that there may be a critical metal temperature at which the process changes over from a physical explosion to one which is very violent and involves the rapid liberation of chemical energy. In this report we examine the hypothesis that vapor-phase burning of aluminum is a necessary condition for the occurrence of such ignition-type'' steam explosions. An available two-phase stagnation flow film-boiling model is used to calculate the steam flux to the vaporizing aluminum surface. Combining this calculation with the notion that there is an upper limit to the magnitude of the metal vaporization rate at which the reaction regime must change from vapor phase to surface burning, leads to prediction of the critical metal surface temperature below which vapor phase burning is impossible. The critical temperature is predicted for both the aluminum-water pre-mixture configuration in which coarse drops of aluminum are falling freely through water and for the finely-fragmented aluminum drops in the wake of the pressure shock that triggers'' the explosion. Vapor phase burning is predicted to be possible during the pre-mixture phase but not very likely during the trigger phase of a steam explosion. The implications of these findings in terms of the validity of the hypothesis that ignition may begin with the vapor phase burning of aluminum is discussed. Recently postulated, alternative mechanisms of underwater aluminum ignition are also discussed.

  8. Underwater vapor phase burning of aluminum particles and on aluminum ignition during steam explosions

    SciTech Connect (OSTI)

    Epstein, M.

    1991-09-01

    Recently reported experimental studies on aluminum-water steam explosions indicate that there may be a critical metal temperature at which the process changes over from a physical explosion to one which is very violent and involves the rapid liberation of chemical energy. In this report we examine the hypothesis that vapor-phase burning of aluminum is a necessary condition for the occurrence of such ``ignition-type`` steam explosions. An available two-phase stagnation flow film-boiling model is used to calculate the steam flux to the vaporizing aluminum surface. Combining this calculation with the notion that there is an upper limit to the magnitude of the metal vaporization rate at which the reaction regime must change from vapor phase to surface burning, leads to prediction of the critical metal surface temperature below which vapor phase burning is impossible. The critical temperature is predicted for both the aluminum-water pre-mixture configuration in which coarse drops of aluminum are falling freely through water and for the finely-fragmented aluminum drops in the wake of the pressure shock that ``triggers`` the explosion. Vapor phase burning is predicted to be possible during the pre-mixture phase but not very likely during the trigger phase of a steam explosion. The implications of these findings in terms of the validity of the hypothesis that ignition may begin with the vapor phase burning of aluminum is discussed. Recently postulated, alternative mechanisms of underwater aluminum ignition are also discussed.

  9. Lithium-aluminum-magnesium electrode composition

    DOE Patents [OSTI]

    Melendres, Carlos A.; Siegel, Stanley

    1978-01-01

    A negative electrode composition is presented for use in a secondary, high-temperature electrochemical cell. The cell also includes a molten salt electrolyte of alkali metal halides or alkaline earth metal halides and a positive electrode including a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent and a magnesium-aluminum alloy as a structural matrix. Various binary and ternary intermetallic phases of lithium, magnesium, and aluminum are formed but the electrode composition in both its charged and discharged state remains substantially free of the alpha lithium-aluminum phase and exhibits good structural integrity.

  10. Aluminum phosphate ceramics for waste storage

    SciTech Connect (OSTI)

    Wagh, Arun; Maloney, Martin D

    2014-06-03

    The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

  11. Roll Casting of Aluminum Alloy Clad Strip

    SciTech Connect (OSTI)

    Nakamura, R.; Tsuge, H. [Graduate School of Osaka Institute of Technology (Japan); Haga, T. [Osaka Institute of Technology, 5-16-1 Omiya Asahiku Osaka city 535-8585 (Japan); Watari, H. [Tokyo Institute of Technology, 4259 Nagatsuda Midoriku Yokohama city 226-8502 (Japan); Kumai, S. [Gunma University, 1-5-1 tenjin cho Kiryu city 376-8515 (Japan)

    2011-01-17

    Casting of aluminum alloy three layers of clad strip was tried using the two sets of twin roll casters, and effects of the casting parameters on the cladding conditions were investigated. One twin roll caster was mounted on the other twin roll caster. Base strip was 8079 aluminum alloy and overlay strips were 6022 aluminum alloy. Effects of roll-load of upper and lower casters and melt temperature of the lower caster were investigated. When the roll-load of the upper and lower caster was large enough, the overlay strip could be solidified and be connected. The overlay strip could be connected when the melt of the overlay strip cast by the lower caster was low enough. Sound three layers of clad strip could be cast by proper conditions.

  12. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  13. Aluminum plasmonic metamaterials for structural color printing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Gao, Jie; Stan, Liliana; Rosenmann, Daniel; Czaplewski, David; Yang, Xiaodong

    2015-05-26

    We report a structural color printing platform based on aluminum plasmonic metamaterials supporting near perfect light absorption and narrow-band spectral response tunable across the visible spectrum to realize high-resolution, angle-insensitive color printing with high color purity and saturation. Additionally, the fabricated metamaterials can be protected by a transparent polymer thin layer for ambient use with further improved color performance. The demonstrated structural color printing with aluminum plasmonic metamaterials offers great potential for relevant applications such as security marking and information storage.

  14. Designing aluminum sealing glasses for manufacturability

    SciTech Connect (OSTI)

    Kovacic, L.; Crowder, S.V.; Brow, R.K.; Bencoe, D.N.

    1993-12-31

    Manufacturability issues involved in the development of new sealing glasses include tailoring glass compositions to meet material and component requirements and determining the optimum seal processing parameters. For each of these issues, statistical analysis can be used to shorten the time between concept and product in the development of what is essentially a new manufacturing technology. We use the development of our new family of phosphate-based glasses for aluminum/stainless steel and aluminum/CuBe hermetic sealing, the ALSG family, to illustrate the statistical approach.

  15. Reaction of Aluminum with Water to Produce Hydrogen: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A Study of...

  16. Reaction of Aluminum with Water to Produce Hydrogen - 2010 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the

  17. Method of winning aluminum metal from aluminous ore

    DOE Patents [OSTI]

    Loutfy, Raouf O. (Naperville, IL); Keller, Rudolf (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

    1981-01-01

    Aluminous ore such as bauxite containing alumina is blended with coke or other suitable form of carbon and reacted with sulfur gas at an elevated temperature. For handling, the ore and coke can be extruded into conveniently sized pellets. The reaction with sulfur gas produces molten aluminum sulfide which is separated from residual solid reactants and impurities. The aluminum sulfide is further increased in temperature to cause its decomposition or sublimation, yielding aluminum subsulfide liquid (AlS) and sulfur gas that is recycled. The aluminum monosulfide is then cooled to below its disproportionation temperature to again form molten aluminum sulfide and aluminum metal. A liquid-liquid or liquid-solid separation, depending on the separation temperature, provides product aluminum and aluminum sulfide for recycle to the disproportionation step.

  18. Local residual stress monitoring of aluminum nitride MEMS using...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 42 ENGINEERING aluminum nitride; microelectromechanical systems; Piezoelectric transducers; Raman scattering; stress measurement Word Cloud More Like ...

  19. Composite-Reinforced Aluminum Conductor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Composite-Reinforced Aluminum Conductor Composite-Reinforced Aluminum Conductor New Aluminum Conductor Composite Core Cable Increases Transmission Efficiency and Installs Easily After nearly three years of intensive research and development, Composite Technology Corporation, in association with General Cable, introduced a new conductor type known as ACCC (Aluminum Conductor Composite Core). This new conductor uses a lighter-weight, high-strength carbon and glass fiber core embedded in a

  20. Cathode Connector For Aluminum Low Temperature Smelting Cell

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

    2003-07-16

    Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

  1. Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina

    DOE Patents [OSTI]

    Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

    2004-10-19

    A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

  2. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  3. Chemical vapor deposition of aluminum oxide

    DOE Patents [OSTI]

    Gordon, Roy; Kramer, Keith; Liu, Xinye

    2000-01-01

    An aluminum oxide film is deposited on a heated substrate by CVD from one or more alkylaluminum alkoxide compounds having composition R.sub.n Al.sub.2 (OR').sub.6-n, wherein R and R' are alkyl groups and n is in the range of 1 to 5.

  4. Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiao -Guang; Fang, Youxing; Jiang, Xueguang; Yoshii, Kazuki; Tsuda, Tetsuya; Dai, Sheng

    2015-10-22

    Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl3 as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.

  5. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved aluminum will be stored in Tank 8 and 21,000 kg will be stored in saltcake via evaporation. Up to 77% of the total aluminum planned for SB6 may be removed via aluminum dissolution. Storage of the aluminum-laden supernate in Tank 8 will require routine evaluation of the free hydroxide concentration in order to maintain aluminum in solution. Periodic evaluation will be established on concurrent frequency with corrosion program samples as previously established for aluminum-laden supernate from SB5 that is stored in Tank 11.

  6. Process of electrolysis and fractional crystallization for aluminum purification

    DOE Patents [OSTI]

    Dawless, Robert K. (Monroeville, PA); Bowman, Kenneth A. (Leechburg, PA); Mazgaj, Robert M. (Lower Burrell, PA); Cochran, C. Norman (Oakmont, PA)

    1983-10-25

    A method for purifying aluminum that contains impurities, the method including the step of introducing such aluminum containing impurities to a charging and melting chamber located in an electrolytic cell of the type having a porous diaphragm permeable by the electrolyte of the cell and impermeable to molten aluminum. The method includes further the steps of supplying impure aluminum from the chamber to the anode area of the cell and electrolytically transferring aluminum from the anode area to the cathode through the diaphragm while leaving impurities in the anode area, thereby purifying the aluminum introduced into the chamber. The method includes the further steps of collecting the purified aluminum at the cathode, and lowering the level of impurities concentrated in the anode area by subjecting molten aluminum and impurities in said chamber to a fractional crystallization treatment wherein eutectic-type impurities crystallize and precipitate out of the aluminum. The eutectic impurities that have crystallized are physically removed from the chamber. The aluminum in the chamber is now suited for further purification as provided in the above step of electrolytically transferring aluminum through the diaphragm.

  7. Process of electrolysis and fractional crystallization for aluminum purification

    DOE Patents [OSTI]

    Dawless, R.K.; Bowman, K.A.; Mazgaj, R.M.; Cochran, C.N.

    1983-10-25

    A method is described for purifying aluminum that contains impurities, the method including the step of introducing such aluminum containing impurities to a charging and melting chamber located in an electrolytic cell of the type having a porous diaphragm permeable by the electrolyte of the cell and impermeable to molten aluminum. The method includes further the steps of supplying impure aluminum from the chamber to the anode area of the cell and electrolytically transferring aluminum from the anode area to the cathode through the diaphragm while leaving impurities in the anode area, thereby purifying the aluminum introduced into the chamber. The method includes the further steps of collecting the purified aluminum at the cathode, and lowering the level of impurities concentrated in the anode area by subjecting molten aluminum and impurities in said chamber to a fractional crystallization treatment wherein eutectic-type impurities crystallize and precipitate out of the aluminum. The eutectic impurities that have crystallized are physically removed from the chamber. The aluminum in the chamber is now suited for further purification as provided in the above step of electrolytically transferring aluminum through the diaphragm. 2 figs.

  8. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  9. Issues for conversion coating of aluminum alloys with hydrotalcite

    SciTech Connect (OSTI)

    Drewien, C.A.; Buchheit, R.G.

    1993-12-01

    Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.

  10. sup 40 Ar- sup 39 Ar and K-Ar dating of K-rich rocks from the Roccamonfina volcano, Roman Comagmatic Region, Italy

    SciTech Connect (OSTI)

    Di Brozolo, F.R.; Di Girolamo, P.; Turi, B.; Oddone, M. )

    1988-06-01

    Roccamonfina is the northernmost Volcano of the Campanian area of the K-rich Roman comagmatic Region of Italy. It erupted a huge amount of pyroclastics and lavas belonging to both the Leucite-Basanite and Leucitite Series (LBLS) and the Shoshonite Series (SS), spread over an area of about 300 km{sup 2}. The above series correspond to the High-K Series (HKS) and Low-K Series (LKS) of Appleton (1971), respectively. {sup 40}Ar-{sup 39}Ar and K-Ar dating of samples from both series gave ages ranging from 0.656 to 0.096 Ma for the SS and from 1.03( ) to 0.053 Ma for the LBLS. These results indicate that the products of the two series were outpoured together at least between 0.7 and 0.1 Ma age, i.e. during both the so-called pre-caldera phase and the post-caldera phase of activity. The latest products of the volcanism at Roccamonfina were erupted just before the deposition of the Grey Campanian Ignimbrite, which erupted from vents located about 50 km to the south in the Phlegrean Fields near Naples and has an age of about 33,000 years. Taking into account all the available all the available radiometric data the authors conclude that Roccamonfina was active between 1.5 and 0.05 Ma ago, in excellent agreement with the stratigraphic evidence. In this same time span is concentrated the activity of all the centers of the Roman Region north of Naples.

  11. 41 A.R.S. 1092 et seq.: Uniform Administrative Hearing Procedures...

    Open Energy Info (EERE)

    A.R.S. 1092 et seq.: Uniform Administrative Hearing Procedures Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 41 A.R.S. 1092 et...

  12. Aluminum doped zinc oxide for organic photovoltaics

    SciTech Connect (OSTI)

    Murdoch, G. B.; Hinds, S.; Sargent, E. H.; Tsang, S. W.; Mordoukhovski, L.; Lu, Z. H.

    2009-05-25

    Aluminum doped zinc oxide (AZO) was grown via magnetron sputtering as a low-cost alternative to indium tin oxide (ITO) for organic photovoltaics (OPVs). Postdeposition ozone treatment resulted in devices with lower series resistance, increased open-circuit voltage, and power conversion efficiency double that of devices fabricated on untreated AZO. Furthermore, cells fabricated using ozone treated AZO and standard ITO displayed comparable performance.

  13. Ignition of Aluminum Particles and Clouds

    SciTech Connect (OSTI)

    Kuhl, A L; Boiko, V M

    2010-04-07

    Here we review experimental data and models of the ignition of aluminum (Al) particles and clouds in explosion fields. The review considers: (i) ignition temperatures measured for single Al particles in torch experiments; (ii) thermal explosion models of the ignition of single Al particles; and (iii) the unsteady ignition Al particles clouds in reflected shock environments. These are used to develop an empirical ignition model appropriate for numerical simulations of Al particle combustion in shock dispersed fuel explosions.

  14. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Alane for Hydrogen Storage and Delivery - Accelerating Innovation Webinar Presentation - June 2012 (7,079 KB) <p> Schematic representation of &nbsp;mechanical alloying reaction during ball

  15. Mr. Mark Jackson Aluminum Company of America

    Office of Legacy Management (LM)

    _ of Energy Washington, DC 20565 Mr. Mark Jackson Aluminum Company of America 100 Technical Drive Alcoa Center, Pennsylvania 15069-0001 Dear Mr. Jackson: At,the request of the U.S. Department of Energy and with the consent of your company, Oak Ridge National Laboratory performed a radiological survey of the former ALCOA Research Labo,ratory at 600 Freeport Road in New Kensington, Pennsylvania. Three copies of the radiological survey report are enclosed for your information and use. An additional

  16. NOTES AND COMMENTS REVERE COPPER AR! BRASS DETROIT, MICHIGAN

    Office of Legacy Management (LM)

    * .t-* . * * - -. _ _ ,.. .I AIT. 4 NOTES AND COMMENTS REVERE COPPER AR! BRASS DETROIT, MICHIGAN A preliminary (screening) survey was conducted in several areas of the Revere Copper and Brass Facility, 5851 W. Jefferson Street, Detroit, Michigan. The survey was conducted by the ANL Radiological Survey Group on April 22, 1981. The Survey Group, consisting of W. Smith, R. Mundis, K. Flynn (all of ANI), and E. Jascewsky (DOE-CH) met on site with J. Evans (Safety Engineer), D. Tratt (Asst.

  17. On the dissolution of iridium by aluminum.

    SciTech Connect (OSTI)

    Hewson, John C.

    2009-08-01

    The potential for liquid aluminum to dissolve an iridium solid is examined. Substantial uncertainties exist in material properties, and the available data for the iridium solubility and iridium diffusivity are discussed. The dissolution rate is expressed in terms of the regression velocity of the solid iridium when exposed to the solvent (aluminum). The temperature has the strongest influence in the dissolution rate. This dependence comes primarily from the solubility of iridium in aluminum and secondarily from the temperature dependence of the diffusion coefficient. This dissolution mass flux is geometry dependent and results are provided for simplified geometries at constant temperatures. For situations where there is negligible convective flow, simple time-dependent diffusion solutions are provided. Correlations for mass transfer are also given for natural convection and forced convection. These estimates suggest that dissolution of iridium can be significant for temperatures well below the melting temperature of iridium, but the uncertainties in actual rates are large because of uncertainties in the physical parameters and in the details of the relevant geometries.

  18. High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon lm075_hovanski_2013_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks Vehicle Technologies Office

  19. Five Ways Aluminum Foil Is Advancing Science | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    SLAC National Accelerator Laboratory uses massive quantities of aluminum foil to perform "bake out" of their equipment. In a typical bake out, the equipment is blanketed in foil, wrapped with electrical heat tape, and then covered in foil again. Heat tape is used to heat the metal chamber just enough to loosen any residues that could cause trouble. The aluminum foil helps spread the heat evenly. | Photo of SLAC SLAC National Accelerator Laboratory uses massive quantities of aluminum

  20. Virtual Aluminum Castings An Industrial Application of Integrated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and cost challenges. Nowhere is this more evident than in the development of designs and manufacturing processes for cast aluminum engine blocks and cylinder heads. Increasing...

  1. Microsoft PowerPoint - Aluminum Concentrations in Storm Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    guarantee its technical correctness. Title: Solid and Dissolved Phase Aluminum in Storm Water Runoff on the Pajarito Plateau, Poster, Individual Permit for Storm Water, NPDES...

  2. Aluminum-stabilized Nb/sub 3/Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1984-02-10

    This patent discloses an aluminum-stabilized Nb/sub 3/Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb/sub 3/Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials.

  3. Rechargeable Aluminum Batteries with Conducting Polymers as Positive...

    Office of Scientific and Technical Information (OSTI)

    with Conducting Polymers as Positive Electrodes. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting Polymers as Positive Electrodes. ...

  4. Rechargeable Aluminum Batteries with Conducting Polymers as Active...

    Office of Scientific and Technical Information (OSTI)

    with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode ...

  5. Design of defect spins in piezoelectric aluminum nitride for...

    Office of Scientific and Technical Information (OSTI)

    To date, defect qubits have only been realized in materials ... perturbation theory, we predicted that the negatively charged nitrogen vacancy center in piezoelectric aluminum ...

  6. Aluminum-stabilized Nb[sub 3]Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1988-05-10

    Disclosed are an aluminum-stabilized Nb[sub 3]Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb[sub 3]Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials. 4 figs.

  7. Energy and Environmental Profile of the Aluminum Industry

    SciTech Connect (OSTI)

    Margolis, Nancy

    1997-07-01

    This detailed report (PDF 2.5 MB) benchmarks the energy and environmental characteristics of the key technologies used in the major processes of the aluminum industry.

  8. High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supply chain doesn't exist for high volume joining of automotive aluminum sheet. ... Joining Comparison Evaluate the performance of best in class laser, laserhybrid ...

  9. Joining of parts via magnetic heating of metal aluminum powders

    SciTech Connect (OSTI)

    Baker, Ian

    2013-05-21

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  10. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum wire for high-voltage power transmission with reduced electrical resistance for overhead electrical lines. Description High-voltage electric power transmission...

  11. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum wire for high-voltage power transmission with reduced electrical resistance for overhead electrical lines. High-voltage electric power transmission cables based...

  12. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  13. Enhancement of Aluminum Alloy Forgings Using Rapid Infrared Heating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and industry partners, Queen City Forging Company and Infra Red Heating Technologies LLC, have developed a process for forging aluminum parts using infrared (IR) technology. ...

  14. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, Marian (Flossmoor, IL); Kaun, Thomas D. (New Lenox, IL)

    1984-01-01

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Silicon powder is mixed with powdered electroactive material, such as the lithium-aluminum eutectic, to provide an improved electrode and cell.

  15. Spray-formed tooling and aluminum strip

    SciTech Connect (OSTI)

    McHugh, K.M.

    1995-11-01

    Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. De Laval nozzles offer an alternative method to the more conventional spray nozzle designs. Two applications are described: high-volume production of aluminum alloy strip, and the production of specialized tooling, such as injection molds and dies, for rapid prototyping.

  16. Dusty Plasma in He-Ar Glow Discharge

    SciTech Connect (OSTI)

    Maiorov, S. A.; Ramazanov, T. S.; Dzhumagulova, K. N.; Dosbolayev, M. K.; Jumabekov, A. N.

    2008-09-07

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for He-Ar mixture. It is shown that under the conventional conditions of the experiments with dusty structures in plasma, the choice of light and heavy gases for the mixture suppresses electron heating in electric field and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths and gas pressures.

  17. Electrolytic production of high purity aluminum using inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

    2001-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The inert anodes used in the process preferably comprise a cermet material comprising ceramic oxide phase portions and metal phase portions.

  18. Brazed aluminum, Plate-fin heat exchangers for OTEC

    SciTech Connect (OSTI)

    Foust, H.D.

    1980-12-01

    Brazed aluminum plate-fin heat exchangers have been available for special applications for over thirty years. The performance, compactness, versatility, and low cost of these heat exchangers has been unequaled by other heat exchanger configuration. The application of brazed aluminum has been highly limited because of necessary restrictions for clean non-corrosive atmospheres. Air and gas separation have provided ideal conditions for accepting brazed aluminum and in turn have benefited by the salient features of these plate-fin heat exchangers. In fact, brazed aluminum and cryogenic gas and air separation have become nearly synonymous. Brazed aluminum in its historic form could not be considered for a seawater atmosphere. However, technology presents a new look of significant importance to OTEC in terms of compactness and cost. The significant technological variation made was to include one-piece hollow extensions for the seawater passages. Crevice corrosion sites are thereby entirely eliminated and pitting corrosion attack will be controlled by an integral and sacrificial layer of a zinc-aluminum alloy. This paper on brazed aluminum plate-fin heat exchangers for OTEC will aquaint the reader with the state-of-art and variations suggested to qualify this form of aluminum for seawater use. In order to verify the desirable cost potential for OTEC, Trane teamed with Westinghouse to perform an OTEC system analysis with this heat exchanger. These results are very promising and reported in detail elsewhere.

  19. Electrolytic production of high purity aluminum using ceramic inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA); DiMilia, Robert A. (Baton Rouge, LA); Dynys, Joseph M. (New Kensington, PA); Phelps, Frankie E. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2002-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising ceramic inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The ceramic inert anodes used in the process may comprise oxides containing Fe and Ni, as well as other oxides, metals and/or dopants.

  20. Method of forming aluminum oxynitride material and bodies formed by such methods

    DOE Patents [OSTI]

    Bakas, Michael P. (Ammon, ID) [Ammon, ID; Lillo, Thomas M. (Idaho Falls, ID) [Idaho Falls, ID; Chu, Henry S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16

    Methods of forming aluminum oxynitride (AlON) materials include sintering green bodies comprising aluminum orthophosphate or another sacrificial material therein. Such green bodies may comprise aluminum, oxygen, and nitrogen in addition to the aluminum orthophosphate. For example, the green bodies may include a mixture of aluminum oxide, aluminum nitride, and aluminum orthophosphate or another sacrificial material. Additional methods of forming aluminum oxynitride (AlON) materials include sintering a green body including a sacrificial material therein, using the sacrificial material to form pores in the green body during sintering, and infiltrating the pores formed in the green body with a liquid infiltrant during sintering. Bodies are formed using such methods.

  1. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-07-04

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs.

  2. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, James M. (Lisle, IL); Lepetre, Yves J. (Lauris, FR); Schuller, Ivan K. (Woodridge, IL); Ketterson, John B. (Evanston, IL)

    1989-01-01

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources.

  3. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  4. Process for strengthening aluminum based ceramics and material

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN); Kim, Hyoun-Ee (Seoul, KR)

    2000-01-01

    A process for strengthening aluminum based ceramics is provided. A gaseous atmosphere consisting essentially of silicon monoxide gas is formed by exposing a source of silicon to an atmosphere consisting essentially of hydrogen and a sufficient amount of water vapor. The aluminum based ceramic is exposed to the gaseous silicon monoxide atmosphere for a period of time and at a temperature sufficient to produce a continuous, stable silicon-containing film on the surface of the aluminum based ceramic that increases the strength of the ceramic.

  5. New Process for Grain Refinement of Aluminum. Final Report

    SciTech Connect (OSTI)

    Dr. Joseph A. Megy

    2000-09-22

    A new method of grain refining aluminum involving in-situ formation of boride nuclei in molten aluminum just prior to casting has been developed in the subject DOE program over the last thirty months by a team consisting of JDC, Inc., Alcoa Technical Center, GRAS, Inc., Touchstone Labs, and GKS Engineering Services. The Manufacturing process to make boron trichloride for grain refining is much simpler than preparing conventional grain refiners, with attendant environmental, capital, and energy savings. The manufacture of boride grain refining nuclei using the fy-Gem process avoids clusters, salt and oxide inclusions that cause quality problems in aluminum today.

  6. Cast B2-phase iron-aluminum alloys with improved fluidity

    DOE Patents [OSTI]

    Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

    2002-01-01

    Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

  7. HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP

    SciTech Connect (OSTI)

    KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

    2009-08-19

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the achievements of this program with emphasis on the recent enhancements in Al{sub 2}O{sub 3} loadings in HLW glass and its processing characteristics. Glass formulation development included crucible-scale preparation and characterization of glass samples to assess compliance with all melt processing and product quality requirements, followed by small-scale screening tests to estimate processing rates. These results were used to down-select formulations for subsequent engineering-scale melter testing. Finally, further testing was performed on the DM1200 vitrification system installed at VSL, which is a one-third scale (1.20 m{sup 2}) pilot melter for the WTP HLW melters and which is fitted with a fully prototypical off-gas treatment system. These tests employed glass formulations with high waste loadings and Al{sub 2}O{sub 3} contents of {approx}25 wt%, which represents a near-doubling of the present WTP baseline maximum Al{sub 2}O{sub 3} loading. In addition, these formulations were processed successfully at glass production rates that exceeded the present requirements for WTP HLW vitrification by up to 88%. The higher aluminum loading in the HLW glass has an added benefit in that the aluminum leaching requirements in pretreatment are reduced, thus allowing less sodium addition in pretreatment, which in turn reduces the amount of LAW glass to be produced at the WTP. The impact of the results from this ORP program in reducing the overall cost and schedule for the Hanford waste treatment mission will be discussed.

  8. Gas-tungsten arc welding of aluminum alloys

    DOE Patents [OSTI]

    Frye, L.D.

    1982-03-25

    The present invention is directed to a gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to profice a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surface are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy continguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

  9. Aluminum for bonding Si-Ge alloys to graphite

    DOE Patents [OSTI]

    Eggemann, Robert V.

    1976-01-13

    Improved thermoelectric device and process, comprising the high-temperature, vacuum bonding of a graphite contact and silicon-germanium thermoelectric element by the use of a low void, aluminum, metallurgical shim with low electrical resistance sandwiched therebetween.

  10. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  11. Aluminum Surface Texturing by Means of Laser Interference Metallurgy...

    Office of Scientific and Technical Information (OSTI)

    laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface...

  12. Aluminum electroplating on steel from a fused bromide electrolyte

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek; Toni Y. Gutknecht; Natalie J. Gese; Paula Hahn; Steven M. Frank; Guy L. Frederickson; J. Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBrKBrCsBrAlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBrKBrCsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  13. Method of Preparing Hydrous Hafnium, Cerium, or Aluminum Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cerium, or aluminum oxide microspheres was invented at ORNL. The invention is a type of sol-gel process that solidifies droplets of solution as they enter into a warm environment....

  14. Uv-preionized ArF and KrF excimer lasers

    SciTech Connect (OSTI)

    Cheng, S.; Cailai, Y.; Alrong, Y.C.D.

    1981-11-01

    Experimental investigations of UV-preionized ArF and KrF excimer lasers are reported. The output laser energies of 105 mJ for ArF and 185 mJ for KrF are obtained. Effects of various parameters on the laser characteristics are discussed.

  15. Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficient Melting and Direct Delivery of High Quality Molten Aluminum Complete Scrap-to-Caster System Will Save Energy and Reduce Costs in the Aluminum Industry In aluminum foundries, aluminum is melted in natural gas-fred reverberatory furnaces where heat is transferred to the surface of the molten aluminum by refractory radiation and some convec- tion. These furnaces are characterized by poor thermal effcien- cies ranging from approximately 20%-45%. The Energy Effcient Isothermal Melting (ITM)

  16. Reactions of aluminum with uranium fluorides and oxyfluorides

    SciTech Connect (OSTI)

    Leitnaker, J.M.; Nichols, R.W.; Lankford, B.S.

    1991-12-31

    Every 30 to 40 million operating hours a destructive reaction is observed in one of the {approximately}4000 large compressors that move UF{sub 6} through the gaseous diffusion plants. Despite its infrequency, such a reaction can be costly in terms of equipment and time. Laboratory experiments reveal that the presence of moderate pressures of UF{sub 6} actually cools heated aluminum, although thermodynamic calculations indicate the potential for a 3000-4000{degrees}C temperature rise. Within a narrow and rather low (<100 torr; 1 torr = 133.322 Pa) pressure range, however, the aluminum is seen to react with sufficient heat release to soften an alumina boat. Three things must occur in order for aluminum to react vigorously with either UF{sub 6} or UO{sub 2}F{sub 2}. 1. An initiating source of heat must be provided. In the compressors, this source can be friction, permitted by disruption of the balance of the large rotating part or by creep of the aluminum during a high-temperature treatment. In the absence of this heat source, compressors have operated for 40 years in UF{sub 6} without significant reaction. 2. The film protecting the aluminum must be breached. Melting (of UF{sub 5} at 620 K or aluminum at 930 K) can cause such a breach in laboratory experiments. In contrast, holding Al samples in UF{sub 6} at 870 K for several hours produces only moderate reaction. Rubbing in the cascade can undoubtedly breach the protective film. 3. Reaction products must not build up and smother the reaction. While uranium products tend to dissolve or dissipate in molten aluminum, AIF{sub 3} shows a remarkable tendency to surround and hence protect even molten aluminum. Hence the initial temperature rise must be rapid and sufficient to move reactants into a temperature region in which products are removed from the reaction site.

  17. Aluminum-doped Zinc Oxide Nanoink - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Industrial Technologies Industrial Technologies Building Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Aluminum-doped Zinc Oxide Nanoink Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative

  18. Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode

    Office of Scientific and Technical Information (OSTI)

    Materials. (Conference) | SciTech Connect Conference: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Abstract not provided. Authors: Hudak, Nicholas Publication Date: 2014-04-01 OSTI Identifier: 1143066 Report Number(s): SAND2014-3282C 511744 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Conference Resource Relation:

  19. Rechargeable Aluminum Batteries with Conducting Polymers as Positive

    Office of Scientific and Technical Information (OSTI)

    Electrodes. (Journal Article) | SciTech Connect Journal Article: Rechargeable Aluminum Batteries with Conducting Polymers as Positive Electrodes. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting Polymers as Positive Electrodes. Abstract not provided. Authors: Hudak, Nicholas S. Publication Date: 2013-12-01 OSTI Identifier: 1124475 Report Number(s): SAND2013-10810J 493199 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Journal Article Resource

  20. Rechargeable aluminum batteries with conducting polymers as positive

    Office of Scientific and Technical Information (OSTI)

    electrodes. (Technical Report) | SciTech Connect Technical Report: Rechargeable aluminum batteries with conducting polymers as positive electrodes. Citation Details In-Document Search Title: Rechargeable aluminum batteries with conducting polymers as positive electrodes. This report is a summary of research results from an Early Career LDRD project con-ducted from January 2012 to December 2013 at Sandia National Laboratories. Demonstrated here is the use of conducting polymers as active

  1. Enhanced structural color generation in aluminum metamaterials coated with

    Office of Scientific and Technical Information (OSTI)

    a thin polymer layer (Journal Article) | SciTech Connect Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer Citation Details In-Document Search Title: Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer Authors: Cheng, Fei ; Yang, Xiaodong ; Rosenmann, Daniel ; Stan, Liliana ; Czaplewski, David ; Gao, Jie Publication Date: 2015-09-18 OSTI Identifier: 1221855 Grant/Contract Number: AC02-06CH11357 Type:

  2. Aluminum plasmonic metamaterials for structural color printing (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Aluminum plasmonic metamaterials for structural color printing Citation Details In-Document Search Title: Aluminum plasmonic metamaterials for structural color printing Authors: Cheng, Fei ; Gao, Jie ; Stan, Liliana ; Rosenmann, Daniel ; Czaplewski, David ; Yang, Xiaodong Publication Date: 2015-05-26 OSTI Identifier: 1222274 Grant/Contract Number: AC02-06CH11357 Type: Published Article Journal Name: Optics Express Additional Journal Information: Journal Volume: 23;

  3. Aluminum Bronze Alloys to Improve Furnace Component Life | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Aluminum Bronze Alloys to Improve Furnace Component Life Aluminum Bronze Alloys to Improve Furnace Component Life Improved System Increases Steelmaking Furnace Efficiency, Safety, and Productivity Hoods, roofs, and sidewall systems in basic oxygen furnaces (BOFs) and electric arc furnaces (EAFs) enable effluent gases in excess of 3000°F to be properly captured, cooled, and processed prior to delivery to the environmental control equipment. Traditionally, these carbon steel components

  4. Virtual Aluminum Castings An Industrial Application of Integrated

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Materials Engineering | Energy Frontier Research Centers Virtual Aluminum Castings An Industrial Application of Integrated Computational Materials Engineering Home Author: J. Allison, M. Li, C. Wolverton, X. Su Year: 2006 Abstract: The automotive product design and manufacturing community is continually besieged by Hercule an engineering, timing, and cost challenges. Nowhere is this more evident than in the development of designs and manufacturing processes for cast aluminum

  5. Recovery of aluminum and other metal values from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

  6. Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and

    Office of Scientific and Technical Information (OSTI)

    Invar (Conference) | SciTech Connect Conference: Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and Invar Citation Details In-Document Search Title: Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and Invar Authors: Chen, L ; Swift, D C ; Austin, R A ; Florando, J N ; Hawreliak, J ; Lazicki, A ; Saculla, M D ; Eakins, D ; Bernier, J V ; Kumar, M Publication Date: 2015-09-23 OSTI Identifier: 1239232 Report Number(s): LLNL-PROC-679036 DOE Contract

  7. DOE - Office of Legacy Management -- Kaiser Aluminum Corp - IL 19

    Office of Legacy Management (LM)

    Kaiser Aluminum Corp - IL 19 FUSRAP Considered Sites Site: KAISER ALUMINUM CORP. (IL.19 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Dolton , Illinois IL.19-2 Evaluation Year: 1987 IL.19-2 Site Operations: Performed limited duration work extruding uranium billets into three CP-5 fuel elements, circa 1959. IL.19-2 Site Disposition: Eliminated - Potential for contamination considered remote due to limited scope of activities

  8. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  9. Ars Technica: Finding Smart Ways to Build Smart Things | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Finding Smart Ways to Build Smart Things Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Ars Technica: Finding Smart Ways to Build Smart Things Ars Technica visited GE's Global Research Center in Munich to discover the innovative research being done at the facility. Watch a video of Ars Technica's visit below: You Might

  10. Xe and Ar nanobubbles in Al studied by photoemission spectroscopy (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Xe and Ar nanobubbles in Al studied by photoemission spectroscopy Citation Details In-Document Search Title: Xe and Ar nanobubbles in Al studied by photoemission spectroscopy We have studied xenon and argon bubbles formed in the subsurface region of Al(111) by x-ray photoelectron spectroscopy. As a consequence of the nanometer size of the bubbles, the photohole formed by Xe 3d or Ar 2p photoemission is screened by the Al conduction electrons, which substantially

  11. Boron-doped back-surface fields using an aluminum-alloy process

    SciTech Connect (OSTI)

    Gee, J.M.; Bode, M.D.; Silva, B.L.

    1997-10-01

    Boron-doped back-surface fields (BSF`s) have potentially superior performance compared to aluminum-doped BSF`s due to the higher solid solubility of boron compared to aluminum. However, conventional boron diffusions require a long, high temperature step that is both costly and incompatible with many photovoltaic-grade crystalline-silicon materials. We examined a process that uses a relatively low-temperature aluminum-alloy process to obtain a boron-doped BSF by doping the aluminum with boron. In agreement with theoretical expectations, we found that thicker aluminum layers and higher boron doping levels improved the performance of aluminum-alloyed BSF`s.

  12. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  13. REAL TIME ULTRASONIC ALUMINUM SPOT WELD MONITORING SYSTEM

    SciTech Connect (OSTI)

    Regalado, W. Perez; Chertov, A. M.; Maev, R. Gr. [Institute for Diagnostic Imaging Research, Physics Department, University of Windsor, 292 Essex Hall, 401 Sunset Ave. N9B 3P4 Windsor, Ontario (Canada)

    2010-02-22

    Aluminum alloys pose several properties that make them one of the most popular engineering materials: they have excellent corrosion resistance, and high weight-to-strength ratio. Resistance spot welding of aluminum alloys is widely used today but oxide film and aluminum thermal and electrical properties make spot welding a difficult task. Electrode degradation due to pitting, alloying and mushrooming decreases the weld quality and adjustment of parameters like current and force is required. To realize these adjustments and ensure weld quality, a tool to measure weld quality in real time is required. In this paper, a real time ultrasonic non-destructive evaluation system for aluminum spot welds is presented. The system is able to monitor nugget growth while the spot weld is being made. This is achieved by interpreting the echoes of an ultrasound transducer located in one of the welding electrodes. The transducer receives and transmits an ultrasound signal at different times during the welding cycle. Valuable information of the weld quality is embedded in this signal. The system is able to determine the weld nugget diameter by measuring the delays of the ultrasound signals received during the complete welding cycle. The article presents the system performance on aluminum alloy AA6022.

  14. Hermetic aluminum radio frequency interconnection and method for making

    DOE Patents [OSTI]

    Kilgo, Riley D. (Albuquerque, NM); Kovacic, Larry (Albuquerque, NM); Brow, Richard K. (Rolla, MO)

    2000-01-01

    The present invention provides a light-weight, hermetic coaxial radio-frequency (RF) interconnection having an electrically conductive outer housing made of aluminum or an aluminum alloy, a central electrical conductor made of ferrous or non-ferrous material, and a cylinder of dielectric material comprising a low-melting-temperature, high-thermal-expansion aluminophosphate glass composition for hermetically sealing between the aluminum-alloy outer housing and the ferrous or non-ferrous center conductor. The entire RF interconnection assembly is made permanently hermetic by thermally fusing the center conductor, glass, and housing concurrently by bringing the glass to the melt point by way of exposure to an atmospheric temperature sufficient to melt the glass, less than 540.degree. C., but that does not melt the center conductor or the outer aluminum or aluminum alloy housing. The composition of the glass used is controlled to provide a suitable low dielectric constant so that an appropriate electrical characteristic impedance, for example 50 ohms, can be achieved for an electrical interconnection that performs well at high radio frequencies and also provides an interconnection maintaining a relatively small physical size.

  15. ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum Industry

    Energy Savers [EERE]

    and Environmental Profile of the U.S. Aluminum Industry July 1997 Prepared by , Inc. Columbia, Maryland Prepared for U.S. Department of Energy Office of Industrial Technologies $&.12:/('*0(176 7KLVUHSRUWZDVZULWWHQE\1DQF\0DUJROLVRI(QHUJHWLFV,QFRUSRUDWHGLQ&ROXPELD0DU\ODQG 7KHUHSRUWZDVSUHSDUHGXQGHUWKHJHQHUDOGLUHFWLRQRI/RXLV6RXVD86'HSDUWPHQWRI(QHUJ\

  16. A.R.S. 37-102: State Land Department - Powers and Duties ...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 37-102: State Land Department - Powers and DutiesLegal Abstract This section...

  17. 49 A.R.S. 255 et seq.: Arizona Pollutant Discharge Elimination...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 255 et seq.: Arizona Pollutant Discharge Elimination System ProgramLegal Abstract...

  18. 49 A.R.S. 321 et seq.: Water Quality Appeals | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: 49 A.R.S. 321 et seq.: Water Quality AppealsLegal Abstract This section governs appeals to the...

  19. Experimental study of the beta-delayed proton precursors /sup 33/Ar and /sup 49/Fe

    SciTech Connect (OSTI)

    XU Xiao-ji; GUO Jun-sheng; GUO Ying-xiang; ZHAO Zhi-zheng; LUO Yi-xiao

    1985-01-01

    Beta-delayed proton precursors /sup 33/Ar and /sup 49/Fe have been produced via the (/sup 12/C,3n) reaction in 65-MeV carbon bombardments of /sup 24/Mg and /sup 40/Ca, respectively. The major proton peaks are at 3.28 +- 0.07 MeV for /sup 33/Ar and 1.98 +- 0.04 MeV for /sup 49/Fe. The corresponding cross section for /sup 33/Ar is 0.40 +- 0.08 ..mu..b, and for /sup 49/Fe 0.70 +- 0.14 ..mu..b. The half-life of /sup 33/Ar was determined to be 167 +- 24 ms.

  20. Title 32 CFR 651 Environmental Analysis of Army Actions (AR 200...

    Open Energy Info (EERE)

    of Army Actions (AR 200-2) Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 32 CFR 651...

  1. File:NREL-ar-80m.pdf | Open Energy Information

    Open Energy Info (EERE)

    File Edit with form History File:NREL-ar-80m.pdf Jump to: navigation, search File File history File usage Arkansas Annual Average Wind Speed at 80 Meters Size of this preview: 463...

  2. ARS Title 49-200 Water Quality Control | Open Energy Information

    Open Energy Info (EERE)

    -200 Water Quality Control Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ARS Title 49-200 Water Quality ControlLegal Abstract...

  3. Carbonaceous cathode with enhanced wettability for aluminum production

    DOE Patents [OSTI]

    Keller, Rudolf; Gatty, David G.; Barca, Brian J.

    2003-09-09

    A method of preparing carbonaceous blocks or bodies for use in a cathode in an electrolytic cell for producing aluminum wherein the cell contains an electrolyte and has molten aluminum contacting the cathode, the cathode having improved wettability with molten aluminum. The method comprises the steps of providing a carbonaceous block and a boron oxide containing melt. The carbonaceous block is immersed in the melt and pressure is applied to the melt to impregnate the melt into pores in the block. Thereafter, the carbonaceous block is withdrawn from the melt, the block having boron oxide containing melt intruded into pores therein, the boron oxide capable of reacting with a source of titanium or zirconium or like metal to form titanium or zirconium diboride during heatup or operation of said cell.

  4. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  5. Aluminum and polymeric coatings for protection of uranium

    SciTech Connect (OSTI)

    Colmenares, C.; McCreary, T.; Monaco, S.; Walkup, C.; Gleeson, G.; Kervin, J.; Smith, R.L.; McCaffrey, C.

    1983-12-21

    Ion-plated aluminum films on uranium will not provide adequate protection for 25 years. Magnetron-plated aluminum films on uranium are much better than ion-plated ones. Kel-F 800 films on uranium can provide adequate protection for 25 years. Their use in production must be delayed until the following factors are sorted out: water permeability in Kel-F 800 must be determined between 30 and 60/sup 0/C; the effect of UF/sub 3/, at the Kel-F/metal interface, on the permeability of water must be assessed; and the effect of crystallinity on water permeability must be evaluated. Applying Kel-F films on aluminum ion-plated uranium provides a good interim solution for long term storage.

  6. Al/sub 2/S/sub 3/ preparation and use in electrolysis process for aluminum production

    DOE Patents [OSTI]

    Hsu, C.C.; Loutfy, R.O.; Yao, N.P.

    A continuous process for producing aluminum sulfide and for electrolyzing the aluminum sulfide to form metallic aluminum in which the aluminum sulfide is produced from aluminum oxide and COS or CS/sub 2/ in the presence of a chloride melt which also serves as the electrolysis bath. Circulation between the reactor and electrolysis cell is carried out to maintain the desired concentration of aluminum sulfide in the bath.

  7. Hanford Site's Data Packages in the Administrative Record (AR) and Public Information Repository (PIR)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In 1989, the Department of Energy joined with the Washington State Department of Ecology and the U.S. Environmental Protection Agency in signing the Hanford Federal Facility Agreement and Consent Order more commonly known as the Tri-Party Agreement (TPA). The TPA outlines legally enforceable milestones for Hanford cleanup over the next several decades. The AR is the body of documents and information that is considered or relied upon to arrive at a final decision for remedial action or hazardous waste management. An AR is established for each operable unit (OU); treatment, storage, or disposal unit (TSD); or Expedited Response Action (ERA) group and will contain all documents having information considered in arriving at a Record of Decision or permit. Documents become part of the AR after they have been designated as an AR by the TPA or after EPA, DOE, or other official parties have identified a document or set of documents for inclusion. Furthermore, AR documents are to be kept in a Public Information Repository (PIR).Thousands of data packages that support the AR documents are available to the public in the Hanford PIR.

  8. Low temperature aluminum reduction cell using hollow cathode

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

    2002-08-20

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

  9. Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.

    DOE Patents [OSTI]

    Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR); Bradford, Donald R (Underwood, WA)

    2004-10-05

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

  10. Aluminum Surface Texturing by Means of Laser Interference Metallurgy

    SciTech Connect (OSTI)

    Chen, Jian; Sabau, Adrian S; Jones, Jonaaron F.; Hackett, Alexandra C.; Daniel, Claus; Warren, Charles David

    2015-01-01

    The increasing use of lightweight materials, such as aluminum alloys, in auto body structures requires more effective surface cleaning and texturing techniques to improve the quality of the structural components. The present work introduces a novel surface treatment method using laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface structures. The influences of beam size, laser fluence, wavelength, and pulse number per spot are investigated. High resolution optical profiler images reveal the change of the peak-to-valley height on the laser-treated surface.

  11. Effect of grain orientation on aluminum relocation at incipient melt conditions

    SciTech Connect (OSTI)

    Yilmaz, Nadir; Vigil, Francisco M.; Vigil, Miquela S.; Branam, Robert; Tolendino, Greg; Gill, Walt; Burl Donaldson, A.

    2015-09-01

    Aluminum is commonly used for structural applications in the aerospace industry because of its high strength in relation to its weight. It is necessary to understand the mechanical response of aluminum structures at elevated temperatures such as those experienced in a fire. Additionally, aluminum alloys exhibit many complicated behaviors that require further research and understanding, such as aluminum combustion, oxide skin formation and creep behavior. This paper discusses the effect of grain orientation on aluminum deformation subjected to heating at incipient melt conditions. Experiments were conducted by applying a vertical compressive force to aluminum alloy 7075 block test specimens. Furthermore, compression testing was done on test specimens with the applied load on the long transverse and short transverse orientations. Our results showed that the grain orientation significantly influences aluminums strength and mode of failure.

  12. Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum

    Broader source: Energy.gov [DOE]

    Fact Sheet About Complete Scrap-to-Caster System Will Save Energy and Reduce Costs in the Aluminum Industry

  13. One step process for producing dense aluminum nitride and composites thereof

    DOE Patents [OSTI]

    Holt, J. Birch (San Jose, CA); Kingman, Donald D. (Danville, CA); Bianchini, Gregory M. (Livermore, CA)

    1989-01-01

    A one step combustion process for the synthesis of dense aluminum nitride compositions is disclosed. The process comprises igniting pure aluminum powder in a nitrogen atmosphere at a pressure of about 1000 atmospheres or higher. The process enables the production of aluminum nitride bodies to be formed directly in a mold of any desired shape.

  14. One step process for producing dense aluminum nitride and composites thereof

    DOE Patents [OSTI]

    Holt, J.B.; Kingman, D.D.; Bianchini, G.M.

    1989-10-31

    A one step combustion process for the synthesis of dense aluminum nitride compositions is disclosed. The process comprises igniting pure aluminum powder in a nitrogen atmosphere at a pressure of about 1,000 atmospheres or higher. The process enables the production of aluminum nitride bodies to be formed directly in a mold of any desired shape.

  15. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, Jerry D. (Idaho Falls, ID); Anderson, Philip A. (Pocatello, ID)

    1994-01-01

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed.

  16. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, J.D.; Anderson, P.A.

    1994-11-15

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed. 5 figs.

  17. Theoretical study of Al{sub n}V{sup +} clusters and their interaction with Ar

    SciTech Connect (OSTI)

    Fernndez, Eva Mara; Vega, Andrs; Balbs, Luis Carlos

    2013-12-07

    Recently, it has been experimentally elucidated whether a V impurity in Al{sub n}V{sup +} clusters occupies an external or an internal site by studying their interaction with argon as a function of cluster size [S. M. Lang, P. Claes, S. Neukermans, and E. Janssens, J. Am. Soc. Mass Spectrom. 22, 1508 (2011)]. In the work presented here we studied, by means of density functional theoretic calculations, the structural and electronic properties of Al{sub n}V{sup +} clusters with n = 1421 atoms, as well as the adsorption of a single Ar atom on them. For n < 17 the lowest energy structure of Al{sub n}V{sup +} is related to that of the pure Al {sub n+1}{sup +} cluster with the V atom substituting a surface Al atom. For n ? 17 the V impurity becomes embedded in the cluster, in agreement with the experimental results, and the clusters adopt a fcc-like structure instead of the icosahedral-like skeleton of pure Al {sub n+1}{sup +}. We have studied the binding energy per atom, the second energy difference, and the V and Al atom separation energies, in comparison with those of pure Al {sub n+1}{sup +}. We also studied the adsorption of atomic Ar on endohedral and exohedral V doped clusters. The optimized Ar adsorption geometries are formed with Ar on top of a surface atom (V for n < 17, and Al for n ? 17) without noticeable structural distortion of the host cluster. At the critical size (n = 17) of the exohedral-endohedral transition, the calculated Ar adsorption energy exhibits a drop and the Ar-cluster distance increases drastically, indicating that Ar becomes physisorbed rather than chemisorbed. All these results confirm the assumptions made by the experimentalists when interpreting their measurements.

  18. Improved Irradiation Performance of Uranium-Molybdenum/Aluminum Dispersion Fuel by Silicon Addition in Aluminum

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; A. B. Robinson; D. M. Wachs

    2013-10-01

    Uranium-molybdenum fuel particle dispersion in aluminum is a form of fuel under development for conversion of high-power research and test reactors from highly enriched to low-enriched uranium in the U.S. Global Threat Reduction Initiative program (also known as the Reduced Enrichment for Research and Test Reactors program). Extensive irradiation tests have been conducted to find a solution for problems caused by interaction layer growth and pore formation between U-Mo and Al. Adding a small amount of Si (up to [approximately]5 wt%) in the Al matrix was one of the proposed remedies. The effect of silicon addition in the Al matrix was examined using irradiation test results by comparing side-by-side samples with different Si additions. Interaction layer growth was progressively reduced with increasing Si addition to the matrix Al, up to 4.8 wt%. The Si addition also appeared to delay pore formation and growth between the U-Mo and Al.

  19. Reaction of Aluminum with Water to Produce Hydrogen: A Study of Issues

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. | Department of Energy Reaction of Aluminum with Water to Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Produced in 2008 by DOE and updated in 2010, this report focuses

  20. Simulation of an Ar/NH{sub 3} low pressure magnetized direct current discharge

    SciTech Connect (OSTI)

    Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physiccal Science and Technical College, Dalian University, Dalian 116622 (China)

    2013-01-15

    A two-dimensional fluid model has been used to investigate the properties of plasma in an Ar/NH{sub 3} low pressure magnetized direct current discharge. We compared the simulation results with the theoretical and experimental results of the other gas discharge in which the magnetic field is considered. Results that obtained using this method are in good agreement with literature. The simulation results show that the positive ammonia ion density follows the positive argon ion density. The Ar{sub 2}{sup +} density is slightly higher than the Ar{sup +} density at 100 mTorr. The largest ammonia ion is NH{sub 3}{sup +} ion, followed by NH{sub 2}{sup +}, NH{sub 4}{sup +}, and NH{sup +} ions. The contribution of NH{sup +} ions to the density of the positive ammonia ions is marginal. The influence of pressure on the plasma discharge has been studied by simulation, and the mechanisms have been discussed. The average plasma density increases as pressure increased. The plasma density appears to be more inhomogeneous than that at the lower pressure. The ratio of charge particles changed as pressure increased. The Ar{sup +} density is slightly higher than the Ar{sub 2}{sup +} density as the pressure increased. It makes NH{sub 4}{sup +} ratio increase as pressure increased. It shows that the electron temperature drops with rising pressure by numerical calculation.

  1. Cost-Effective Consolidation of Fine Aluminum Scrap for Increased Remelting Effieciency

    SciTech Connect (OSTI)

    William Van Geertruyden

    2005-09-22

    The main objective of this research was to develop a new re-melting process for fine or light gauge aluminum scrap products that exhibits dramatic improvements in energy efficiency. Light gauge aluminum scrap in the form of chips, turnings, and borings has historically been underutilized in the aluminum recycling process due to its high surface area to volume ratio resulting in low melt recovery. Laboratory scale consolidation experiments were performed using loose aluminum powder as a modeling material as well as shredded aluminum wire scrap. The processing parameters necessary to create consolidated aluminum material were determined. Additionally, re-melting experiments using consolidated and unconsolidated aluminum powder confirmed the hypothesis that metal recovery using consolidated material will significantly improve by as much as 20%. Based on this research, it is estimated that approximately 495 billion Btu/year can be saved by implementation of this technology in one domestic aluminum rolling plant alone. The energy savings are realized by substituting aluminum scrap for primary aluminum, which requires large amounts of energy to produce. While there will be an initial capital investment, companies will benefit from the reduction of dependence on primary aluminum thus saving considerable costs. Additionally, the technology will allow companies to maintain in-house alloy scrap, rather than purchasing from other vendors and eliminate the need to discard the light gauge scrap to landfills.

  2. Dynamics of plasma expansion and shockwave formation in femtosecond laser-ablated aluminum plumes in argon gas at atmospheric pressures

    SciTech Connect (OSTI)

    Miloshevsky, Alexander; Harilal, Sivanandan S.; Miloshevsky, Gennady Hassanein, Ahmed

    2014-04-15

    Plasma expansion with shockwave formation during laser ablation of materials in a background gasses is a complex process. The spatial and temporal evolution of pressure, temperature, density, and velocity fields is needed for its complete understanding. We have studied the expansion of femtosecond (fs) laser-ablated aluminum (Al) plumes in Argon (Ar) gas at 0.5 and 1 atmosphere (atm). The expansion of the plume is investigated experimentally using shadowgraphy and fast-gated imaging. The computational fluid dynamics (CFD) modeling is also carried out. The position of the shock front measured by shadowgraphy and fast-gated imaging is then compared to that obtained from the CFD modeling. The results from the three methods are found to be in good agreement, especially during the initial stage of plasma expansion. The computed time- and space-resolved fields of gas-dynamic parameters have provided valuable insights into the dynamics of plasma expansion and shockwave formation in fs-pulse ablated Al plumes in Ar gas at 0.5 and 1?atm. These results are compared to our previous data on nanosecond (ns) laser ablation of Al [S. S. Harilal et al., Phys. Plasmas 19, 083504 (2012)]. It is observed that both fs and ns plumes acquire a nearly spherical shape at the end of expansion in Ar gas at 1?atm. However, due to significantly lower pulse energy of the fs laser (5 mJ) compared to pulse energy of the ns laser (100 mJ) used in our studies, the values of pressure, temperature, mass density, and velocity are found to be smaller in the fs laser plume, and their time evolution occurs much faster on the same time scale. The oscillatory shock waves clearly visible in the ns plume are not observed in the internal region of the fs plume. These experimental and computational results provide a quantitative understanding of plasma expansion and shockwave formation in fs-pulse and ns-pulse laser ablated Al plumes in an ambient gas at atmospheric pressures.

  3. Ion mass spectrometry investigations of the discharge during reactive high power pulsed and direct current magnetron sputtering of carbon in Ar and Ar/N{sub 2}

    SciTech Connect (OSTI)

    Schmidt, S.; Greczynski, G.; Jensen, J.; Hultman, L.; Czigany, Zs.

    2012-07-01

    Ion mass spectrometry was used to investigate discharges formed during high power impulse magnetron sputtering (HiPIMS) and direct current magnetron sputtering (DCMS) of a graphite target in Ar and Ar/N{sub 2} ambient. Ion energy distribution functions (IEDFs) were recorded in time-averaged and time-resolved mode for Ar{sup +}, C{sup +}, N{sub 2}{sup +}, N{sup +}, and C{sub x}N{sub y}{sup +} ions. An increase of N{sub 2} in the sputter gas (keeping the deposition pressure, pulse width, pulse frequency, and pulse energy constant) results for the HiPIMS discharge in a significant increase in C{sup +}, N{sup +}, and CN{sup +} ion energies. Ar{sup +}, N{sub 2}{sup +}, and C{sub 2}N{sup +} ion energies, in turn, did not considerably vary with the changes in working gas composition. The HiPIMS process showed higher ion energies and fluxes, particularly for C{sup +} ions, compared to DCMS. The time evolution of the plasma species was analyzed for HiPIMS and revealed the sequential arrival of working gas ions, ions ejected from the target, and later during the pulse-on time molecular ions, in particular CN{sup +} and C{sub 2}N{sup +}. The formation of fullerene-like structured CN{sub x} thin films for both modes of magnetron sputtering is explained by ion mass-spectrometry results and demonstrated by transmission electron microscopy as well as diffraction.

  4. Fluorocarbon assisted atomic layer etching of SiO2 and Si using cyclic Ar/C4F8 and Ar/CHF3 plasma

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L.; Joseph, Eric A.; Oehrlein, Gottlieb S.

    2015-11-11

    The need for atomic layer etching (ALE) is steadily increasing as smaller critical dimensions and pitches are required in device patterning. A flux-control based cyclic Ar/C4F8 ALE based on steady-state Ar plasma in conjunction with periodic, precise C4F8 injection and synchronized plasma-based low energy Ar+ ion bombardment has been established for SiO2.1 In this work, the cyclic process is further characterized and extended to ALE of silicon under similar process conditions. The use of CHF3 as a precursor is examined and compared to C4F8. CHF3 is shown to enable selective SiO2/Si etching using a fluorocarbon (FC) film build up. Othermore » critical process parameters investigated are the FC film thickness deposited per cycle, the ion energy, and the etch step length. Etching behavior and mechanisms are studied using in situ real time ellipsometry and X-ray photoelectron spectroscopy. Silicon ALE shows less self-limitation than silicon oxide due to higher physical sputtering rates for the maximum ion energies used in this work, ranged from 20 to 30 eV. The surface chemistry is found to contain fluorinated silicon oxide during the etching of silicon. As a result, plasma parameters during ALE are studied using a Langmuir probe and establish the impact of precursor addition on plasma properties.« less

  5. Radioactive air emissions notice of construction, use of a portable exhauster on 244-AR vault

    SciTech Connect (OSTI)

    Allen, C.P., Fluor Daniel Hanford

    1997-02-11

    This document serves as a notice of construction (NOC), pursuant to the requirements of Washington Administrative Code (WAC) 246-247- 060, and as a request for approval to construct pursuant to 40 Code of Federal Regulations (CFR) 61.96, for the use of a portable exhauster at the 244-AR Vault during transfers or movement of radioactive waste as part of pumping of secondary containment, tank stabilization/pumping, and other activities (i.e., transfer or pumping of radioactive waste using established procedures, entries for maintenance and inspections) within the 244-AR Vault.

  6. Ars Technica: Analyzing the Internet of Things in San Ramon | GE Global

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Analyzing the Internet of Things Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Ars Technica: Analyzing the Internet of Things As a continuation of its Chasing Brilliance series, Ars Technica sent a reporter to GE Global Research in San Ramon to learn about research going on at the software hub. Read more

  7. Developing the model of laser ablation by considering the interplay between emission and expansion of aluminum plasma

    SciTech Connect (OSTI)

    Rezaei, F.; Tavassoli, S. H.

    2013-01-15

    In the present study, the ablation behavior of aluminum target and its plasma radiation in noble ambient gases by a laser pulse with wavelength of 266 nm and pulse duration of 10 ns are numerically studied. A thermal model of laser ablation considering heat conduction, Euler equations, Saha-Eggert equations, Knudsen layer, mass and energy balance relations and optical shielding effects are used for calculation of plasma parameters. Effects of excitation energy on plasma expansion and its emissivity are investigated. Time and spatial-resolved plasma emission including bremsstrahlung, recombination and spectral emission at early delay times after laser irradiation is obtained. Effects of two ambient gases (He and Ar) as well as different gas pressures of 100, 300, 500, and 760 Torr on plasma expansion and its spectrum are studied. Results illustrate that at initial delay times, especially at high noble gas pressures, ionic lines have the maximum intensities, while at later times neutral lines dominate. When the pressure of ambient gas increases, a confinement of the plasma plume is predicted and the intensity of neutral lines decreases. Continuous emission increases with wavelength in both ambient gases. Spatially resolved analysis shows that an intense continuous emission is predicted next to the sample surface decreasing with distance from the latter.

  8. Reduction of Annealing Times for Energy Conservation in Aluminum

    SciTech Connect (OSTI)

    Anthony D. Rollett; Hasso Weiland; Mohammed Alvi; Abhijit Brahme

    2005-08-31

    Carnegie Mellon University was teamed with the Alcoa Technical Center with support from the US Dept. of Energy (Office of Industrial Technology) and the Pennsylvania Technology Investment Authority (PTIA) to make processing of aluminum less costly and more energy efficient. Researchers in the Department of Materials Science and Engineering have investigated how annealing processes in the early stages of aluminum processing affect the structure and properties of the material. Annealing at high temperatures consumes significant amounts of time and energy. By making detailed measurements of the crystallography and morphology of internal structural changes they have generated new information that will provide a scientific basis for shortening processing times and consuming less energy during annealing.

  9. Influence of insulating coating on aluminum wire explosions

    SciTech Connect (OSTI)

    Li, Yang; Wu, Jian; Sheng, Liang; Zhao, Jizhen; Zhang, Mei; Yuan, Yuan; Peng, Bodong; Li, Xingwen

    2014-10-15

    Single wire explosions are widely used in understanding the early stages of z-pinch experiments. This paper presents a serial of experiments conducted on the pulse power generator with ?1?kA peak current and ?10?ns rising time in Xi'an Jiao Tong University. Polyimide coated aluminum wires and uncoated ones were tested under three different voltages to analyze the effect of insulating coating. Experimental results showed that insulating coating can increase the energy deposition 10%?30% in aluminum wires by delaying the voltage collapse and raising the maximum load resistance. The substantial energy deposition resulted in about 20% faster expansion rates for coated wires. Experimental evidence that plasma channel shunts the current from the wire core was observed by streak camera and schlieren graphs. This paper also briefly discussed the influence of nonuniform coating on the morphology of wire expansion.

  10. High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review High Speed Joining of Dissimilar Alloy Aluminum Tailor Welded Blanks YURI HOVANSKI This Presentation does not contain any proprietary, confidential, or otherwise restricted information Project ID #LM075 Pacific Northwest National Laboratory June 18, 2014 Project Overview OEM GM Tier I Supplier TWB Company LLC Material Provider Alcoa 2 2 Start: FY2012 Finish: FY2014 85% complete Capacity to rapidly join Al sheet in dissimilar thicknesses and alloys is not developed. Supply chain

  11. Precursor detonation wave development in ANFO due to aluminum confinement

    SciTech Connect (OSTI)

    Jackson, Scott I; Klyanda, Charles B; Short, Mark

    2010-01-01

    Detonations in explosive mixtures of ammonium-nitrate-fuel-oil (ANFO) confined by aluminum allow for transport of detonation energy ahead of the detonation front due to the aluminum sound speed exceeding the detonation velocity. The net effect of this energy transport on the detonation is unclear. It could enhance the detonation by precompressing the explosive near the wall. Alternatively, it could decrease the explosive performance by crushing porosity required for initiation by shock compression or destroying confinement ahead of the detonation. At present, these phenomena are not well understood. But with slowly detonating, non-ideal high explosive (NIHE) systems becoming increasing prevalent, proper understanding and prediction of the performance of these metal-confined NIHE systems is desirable. Experiments are discussed that measured the effect of this ANFO detonation energy transported upstream of the front by a 76-mm-inner-diameter aluminum confining tube. Detonation velocity, detonation-front shape, and aluminum response are recorded as a function of confiner wall thickness and length. Detonation shape profiles display little curvature near the confining surface, which is attributed to energy transported upstream modifying the flow. Average detonation velocities were seen to increase with increasing confiner thickness, while wavefront curvature decreased due to the stiffer, subsonic confinement. Significant radial sidewall tube motion was observed immediately ahead of the detonation. Axial motion was also detected, which interfered with the front shape measurements in some cases. It was concluded that the confiner was able to transport energy ahead of the detonation and that this transport has a definite effect on the detonation by modifying its characteristic shape.

  12. High Strength, Dissimilar Alloy Aluminum Tailor-Welded Blanks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Merit Review High Strength, Dissimilar Alloy Aluminum Tailor-Welded Blanks YURI HOVANSKI This Presentation does not contain any proprietary, confidential, or otherwise restricted information Project ID #LM099 Pacific Northwest National Laboratory June 12, 2015 Project Overview Automotive OEM GM Tier I Supplier TWB Company LLC Material Provider Alcoa 2 2 Start: FY2015 Finish: FY2017 15% complete Capacity to rapidly join dissimilar alloy Al sheet is not developed for high volume production.

  13. Indirect-Fired Kiln Conserves Scrap Aluminum and Cuts Costs

    Broader source: Energy.gov [DOE]

    This case study examines a succesful process heating technology improvement implemented by Wabash Alloys at its East Syracuse, New York, facility. A demonstration project conducted at this plant by Energy Research Company (ERCo), of Staten Island, New York, involves a new energy-efficient kiln that heats scrap aluminum for reuse. This kiln has enabled Wabash to reduce metal loss and emissions of volatile organic compounds (VOCs) and, in addition, has reduced kiln energy use by more than half.

  14. Adiabatic release measurements in aluminum between 400-1200 GPa. Characterization of aluminum as a shock standard in the multimegabar regime

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knudson, Marcus D.; Desjarlais, Michael P.; Pribram-Jones, Aurora

    2015-06-15

    Aluminum has been used prolifically as an impedance matching standard in the multimegabar regime (1 Mbar = 100 GPa), particularly in nuclear driven, early laser driven, and early magnetically driven flyer plate experiments. The accuracy of these impedance matching measurements depends upon the knowledge of both the Hugoniot and release or reshock response of aluminum. Here, we present the results of several adiabatic release measurements of aluminum from ~400–1200 GPa states along the principal Hugoniot using full density polymethylpentene (commonly known as TPX), and both ~190 and ~110 mg/cc silica aerogel standards. Additionally, these data were analyzed within the frameworkmore » of a simple, analytical model that was motivated by a first-principles molecular dynamics investigation into the release response of aluminum, as well as by a survey of the release response determined from several tabular equations of state for aluminum. Combined, this theoretical and experimental study provides a method to perform impedance matching calculations without the need to appeal to any tabular equation of state for aluminum. Furthermore, as an analytical model, this method allows for propagation of all uncertainty, including the random measurement uncertainties and the systematic uncertainties of the Hugoniot and release response of aluminum. This work establishes aluminum for use as a high-precision standard for impedance matching in the multimegabar regime.« less

  15. Adiabatic release measurements in aluminum between 400-1200 GPa. Characterization of aluminum as a shock standard in the multimegabar regime

    SciTech Connect (OSTI)

    Knudson, Marcus D.; Desjarlais, Michael P.; Pribram-Jones, Aurora

    2015-06-15

    Aluminum has been used prolifically as an impedance matching standard in the multimegabar regime (1 Mbar = 100 GPa), particularly in nuclear driven, early laser driven, and early magnetically driven flyer plate experiments. The accuracy of these impedance matching measurements depends upon the knowledge of both the Hugoniot and release or reshock response of aluminum. Here, we present the results of several adiabatic release measurements of aluminum from ~4001200 GPa states along the principal Hugoniot using full density polymethylpentene (commonly known as TPX), and both ~190 and ~110 mg/cc silica aerogel standards. Additionally, these data were analyzed within the framework of a simple, analytical model that was motivated by a first-principles molecular dynamics investigation into the release response of aluminum, as well as by a survey of the release response determined from several tabular equations of state for aluminum. Combined, this theoretical and experimental study provides a method to perform impedance matching calculations without the need to appeal to any tabular equation of state for aluminum. Furthermore, as an analytical model, this method allows for propagation of all uncertainty, including the random measurement uncertainties and the systematic uncertainties of the Hugoniot and release response of aluminum. This work establishes aluminum for use as a high-precision standard for impedance matching in the multimegabar regime.

  16. Properties of steady discharge in Ar-Kr-F2 gas mixture

    SciTech Connect (OSTI)

    Chengen, Z.

    1981-11-01

    Some properties of Ar-Kr-F/sub 2/ laser gas mixture plasma under steady discharge conditions are computed and discussed. Both the excitation rate of the discharging electrons and the distribution of the discharge energy are discussed. The effects of fluoride gas content and impurity gas content on the discharge property are studied.

  17. CALiPER Application Summary Report 17. LED AR111 and PAR36 Lamps

    SciTech Connect (OSTI)

    none,

    2012-08-01

    Report 17 analyzes the performance of a group of six LED products labeled as AR111 lamps. Results indicate that this product category lags behind other types of directional LED lamps but may perform acceptably in some applications and provide some energy savings.

  18. Heavy ion beam induced charge transfer in Ar-Cs mixtures

    SciTech Connect (OSTI)

    Murnick, D.E.; Gernhauser, R.; Ulrich, A.; Krotz, W.; Wieser, J.

    1993-12-01

    In situ production of target ions in cold, dense matter by heavy ion collisions and subsequent selective charge transfer may provide an effective pumping scheme for heavy ion beam pumped lasers. Charge transfer from cesium atoms to doubly charged argon ions was used for selective population of 4d-levels in Ar II. The argon ions were produced in an argon-cesium gas target by a pulsed beam of 100 MeV {sup 32}S{sup 8+} ions from the Munich Tandem van de Graaff accelerator. The ion beam of 12 {times} 10{sup 6} ions/pulse had a pulse width of 2 ns and a repetition rate of 32 kHz. The argon pressure was typically 250 mbar. The cesium partial pressure was adjusted by heating the gas target, including a cesium reservoir, to temperatures between 250 and 500{degrees}C. Time resolved wavelength spectra showed large intensity increases corresponding to 4d {sup 4}D and 4d {sup 4}F to 4p transitions in Ar II in the ultraviolet wavelength region between 300 and 400 nm. This is interpreted as a resonant charge transfer of outer electrons of cesium to 4d levels in Ar II in Cs{sup 0} + Ar{sup 2+} collisions.

  19. Effect of grain orientation on aluminum relocation at incipient melt conditions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yilmaz, Nadir; Vigil, Francisco M.; Vigil, Miquela S.; Branam, Robert; Tolendino, Greg; Gill, Walt; Burl Donaldson, A.

    2015-09-01

    Aluminum is commonly used for structural applications in the aerospace industry because of its high strength in relation to its weight. It is necessary to understand the mechanical response of aluminum structures at elevated temperatures such as those experienced in a fire. Additionally, aluminum alloys exhibit many complicated behaviors that require further research and understanding, such as aluminum combustion, oxide skin formation and creep behavior. This paper discusses the effect of grain orientation on aluminum deformation subjected to heating at incipient melt conditions. Experiments were conducted by applying a vertical compressive force to aluminum alloy 7075 block test specimens. Furthermore,more » compression testing was done on test specimens with the applied load on the long transverse and short transverse orientations. Our results showed that the grain orientation significantly influences aluminum’s strength and mode of failure.« less

  20. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  1. Impact of Aluminum on Anticipated Corrosion in a Flooded SNF Multi Canister Overpack (MCO)

    SciTech Connect (OSTI)

    DUNCAN, D.R.

    1999-07-06

    Corrosion reactions in a flooded MCO are examined to determine the impact of aluminum corrosion products (from aluminum basket grids and spacers) on bound water estimates and subsequent fuel/environment reactions during storage. The mass and impact of corrosion products were determined to be insignificant, validating the choice of aluminum as an MCO component and confirming expectations that no changes to the Technical Databook or particulate mass or water content are necessary.

  2. DOE - Office of Legacy Management -- Hunter Douglas Aluminum Plant Div of

    Office of Legacy Management (LM)

    Bridgeport Brass Co - CA 11 Hunter Douglas Aluminum Plant Div of Bridgeport Brass Co - CA 11 FUSRAP Considered Sites Site: HUNTER DOUGLAS ALUMINUM PLANT, DIV. OF BRIDGEPORT BRASS CO. (CA.11 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Hunter Douglas Aluminum Corporation CA.11-1 Location: 3016 Kansas Avenue , Riverside , California CA.11-1 Evaluation Year: 1995 CA.11-2 Site Operations: Fabricated uranium metal tubing during the late 1950s.

  3. Investigation of Opportunities for High-Temperature Solar Energy in the Aluminum Industry

    SciTech Connect (OSTI)

    Murray, J.

    2006-05-01

    This report gives the conclusions drawn from a study of the potential application of high-temperature solar process heat for production of aluminum.

  4. Updated Life-Cycle Assessment of Aluminum Production and Semi-fabrication for the GREET Model

    SciTech Connect (OSTI)

    Dai, Qiang; Kelly, Jarod C.; Burnham, Andrew; Elgowainy, Amgad

    2015-09-01

    This report serves as an update for the life-cycle analysis (LCA) of aluminum production based on the most recent data representing the state-of-the-art of the industry in North America. The 2013 Aluminum Association (AA) LCA report on the environmental footprint of semifinished aluminum products in North America provides the basis for the update (The Aluminum Association, 2013). The scope of this study covers primary aluminum production, secondary aluminum production, as well as aluminum semi-fabrication processes including hot rolling, cold rolling, extrusion and shape casting. This report focuses on energy consumptions, material inputs and criteria air pollutant emissions for each process from the cradle-to-gate of aluminum, which starts from bauxite extraction, and ends with manufacturing of semi-fabricated aluminum products. The life-cycle inventory (LCI) tables compiled are to be incorporated into the vehicle cycle model of Argonne National Laboratorys Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model for the release of its 2015 version.

  5. High Methane Storage Capacity in Aluminum Metal-Organic Frameworks (MOFs)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome High Methane Storage Capacity in Aluminum Metal-Organic Frameworks (MOFs)

  6. New Aluminum Alloys for Energy-Efficient Transportation | U.S...

    Office of Science (SC) Website

    New Aluminum Alloys for Energy-Efficient Transportation Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities ...

  7. The Effect of Impurities on the Processing of Aluminum Alloys

    SciTech Connect (OSTI)

    Zi-Kui Liu; Shengjun Zhang; Qingyou Han; Vinod Sikka

    2007-04-23

    For this Aluminum Industry of the Future (IOF) project, the effect of impurities on the processing of aluminum alloys was systematically investigated. The work was carried out as a collaborative effort between the Pennsylvania State University and Oak Ridge National Laboratory. Industrial support was provided by ALCOA and ThermoCalc, Inc. The achievements described below were made. A method that combines first-principles calculation and calculation of phase diagrams (CALPHAD) was used to develop the multicomponent database Al-Ca-K-Li-Mg-Na. This method was extensively used in this project for the development of a thermodynamic database. The first-principles approach provided some thermodynamic property data that are not available in the open literature. These calculated results were used in the thermodynamic modeling as experimental data. Some of the thermodynamic property data are difficult, if not impossible, to measure. The method developed and used in this project allows the estimation of these data for thermodynamic database development. The multicomponent database Al-Ca-K-Li-Mg-Na was developed. Elements such as Ca, Li, Na, and K are impurities that strongly affect the formability and corrosion behavior of aluminum alloys. However, these impurity elements are not included in the commercial aluminum alloy database. The process of thermodynamic modeling began from Al-Na, Ca-Li, Li-Na, K-Na, and Li-K sub-binary systems. Then ternary and higher systems were extrapolated because of the lack of experimental information. Databases for five binary alloy systems and two ternary systems were developed. Along with other existing binary and ternary databases, the full database of the multicomponent Al-Ca-K-Li-Mg-Na system was completed in this project. The methodology in integrating with commercial or other aluminum alloy databases can be developed. The mechanism of sodium-induced high-temperature embrittlement (HTE) of Al-Mg is now understood. Using the thermodynamic database developed in this project, thermodynamic simulations were carried out to investigate the effect of sodium on the HTE of Al-Mg alloys. The simulation results indicated that the liquid miscibility gap resulting from the dissolved sodium in the molten material plays an important role in HTE. A liquid phase forms from the solid face-centered cubic (fcc) phase (most likely at grain boundaries) during cooling, resulting in the occurrence of HTE. Comparison of the thermodynamic simulation results with experimental measurements on the high-temperature ductility of an Al-5Mg-Na alloy shows that HTE occurs in the temperature range at which the liquid phase exists. Based on this fundamental understanding of the HTE mechanism during processing of aluminum alloy, an HTE sensitive zone and a hot-rolling safe zone of the Al-Mg-Na alloys are defined as functions of processing temperature and alloy composition. The tendency of HTE was evaluated based on thermodynamic simulations of the fraction of the intergranular sodium-rich liquid phase. Methods of avoiding HTE during rolling/extrusion of Al-Mg-based alloys were suggested. Energy and environmental benefits from the results of this project could occur through a number of avenues: (1) energy benefits accruing from reduced rejection rates of the aluminum sheet and bar, (2) reduced dross formation during the remelting of the aluminum rejects, and (3) reduced CO2 emission related to the energy savings. The sheet and extruded bar quantities produced in the United States during 2000 were 10,822 and 4,546 million pounds, respectively. It is assumed that 50% of the sheet and 10% of the bar will be affected by implementing the results of this project. With the current process, the rejection rate of sheet and bar is estimated at 5%. Assuming that at least half of the 5% rejection of sheet and bar will be eliminated by using the results of this project and that 4% of the aluminum will be lost through dross (Al2O3) during remelting of the rejects, the full-scale industrial implementation of the project results would lead to energy savings in excess of 6.2 trillion Btu/year and cost savings of $42.7 million by 2020.

  8. FRICTION STIR SPOT WELDING OF 6016 ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Mishra, Rajiv S.; Webb, S.; Freeney, T. A.; Chen, Y. L.; Gayden, X.; Grant, Glenn J.; Herling, Darrell R.

    2007-01-08

    Friction stir spot welding (FSSW) of 6016 aluminum alloy was evaluated with conventional pin tool and new off-center feature tools. The off-center feature tool provides significant control over the joint area. The tool rotation rate was varied between 1000 and 2500 rpm. Maximum failure strength was observed in the tool rotation range of 1200-1500 rpm. The results are interpreted in the context of material flow in the joint and influence of thermal input on microstructural changes. The off-center feature tool concept opens up new possibilities for plunge-type friction stir spot welding.

  9. Fatigue design curves for 6061-T6 aluminum

    SciTech Connect (OSTI)

    Yahr, G.T.

    1993-06-01

    A request has been made to the ASME Boiler and Pressure Vessel Committee that 6061-T6 aluminum be approved for use in the construction of Class 1 welded nuclear vessels so it can be used for the pressure vessel of the Advanced Neutron Source research reactor. Fatigue design curves with and without mean stress effects have been proposed. A knock-down factor of two is applied to the design curve for evaluation of welds. The basis of the curves is explained. The fatigue design curves are compared to fatigue data from base metal and weldments.

  10. High Methane Storage Capacity in Aluminum Metal-Organic Frameworks |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome High Methane Storage Capacity in Aluminum Metal-Organic Frameworks Previous Next List Felipe Gándara, Hiroyasu Furukawa, Seungkyu Lee, and Omar M. Yaghi, J. Am. Chem. Soc., 136, 5271-5274 (2014) DOI: 10.1021/ja501606h Abstract Image Abstract: The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and

  11. Investigation of plasma-dust structures in He-Ar gas mixture

    SciTech Connect (OSTI)

    Maiorov, S. A.; Ramazanov, T. S.; Dzhumagulova, K. N.; Jumabekov, A. N.; Dosbolayev, M. K.

    2008-09-15

    The paper reports on the first experiments with plasma-dust formations in dc gas discharge plasma for a He-Ar mixture. It is shown that the choice of light and heavy gases for the mixture suppresses ion heating in electric field under the conventional conditions of experiments and results in a supersonic jet with high Mach numbers. Distribution functions for drifting ions in the gas mixture are calculated for various mixture concentrations, electric field strengths, and gas pressures.

  12. X-ray diffractometry of lanthanum-nickel-aluminum alloys

    SciTech Connect (OSTI)

    Mosley, W.C.

    1988-08-08

    X-ray diffractometry provides much useful information on LANA alloys that complements data obtained by SEM and Electron Microprobe Analysis. Accurate measurements of the hexagonal lattice parameters of the primary LaNi{sub 5-y}Aly phase reveal the aluminum content (y) and allow the prediction of desorption pressures for the hydrogen isotopes. A study of the broadening of x-ray diffraction lines of the LaNi{sub 5-y}Aly primary phase caused by cyclic absorption and desorption of hydrogen suggests that substitution of aluminum for nickel stabilizes the primary phase with respect to formation of antistructure defects that could cause undesirable trapping of hydrogen isotopes. Correlation of XRD with SEM and EMPA results has helped identify secondary phases, determine their abundances in volume percent, and reveal how they react with hydrogen and the atmosphere. Characterizations of LANA alloys used in process development has provided the bases for development of specifications for alloys to be used in the Replacement Trittium Facility. 28 refs., 4 tabs., 12 figs.

  13. Morphological development and oxidation mechanisms of aluminum nitride whiskers

    SciTech Connect (OSTI)

    Hou Xinmei; Yue Changsheng; Kumar Singh, Ankit; Zhang Mei; Chou Kuochih

    2010-04-15

    Hexagonal aluminum nitride (AlN) whiskers have been synthesized at 1873 K under a flowing nitrogen atmosphere. The synthesized whiskers are long straight filaments with diameters between 1 and 5 {mu}m and length in the cm range. In order to investigate its 'oxidation resistance', a series of experiments have been performed. The oxidation behavior was quite different in the experimental temperature range assigned, which can be attributed to the kinetic factor and the morphological development during oxidation process. It was chemical controlled at lower temperature while both chemical reaction and diffusion controlled at medium temperature. Further accelerating of temperature to 1473 K, AlN whiskers was peeled into smaller parts, which increased the oxidation rate and hence showed powder-like oxidation behavior. Our new kinetic theory has been applied to study the oxidation behavior of AlN whiskers. The comparison of the experimental data with the theoretical ones validates the applicability of the new model. - Hexagonal aluminum nitride (AlN) whiskers have been synthesized at 1873 K under a flowing nitrogen atmosphere. The synthesized whiskers are long straight filaments with diameters between 1 and 5 {mu}m and length in the cm range.

  14. Interfacial charging phenomena of aluminum (hydr)oxides

    SciTech Connect (OSTI)

    Hiemstra, T.; Yong, H.; Van Riemsdijk, W.H.

    1999-08-31

    The interfacial charging of Al(OH){sub 3} (gibbsite and bayerite) and Al{sub 2}O{sub 3} has been studied. For Al(OH){sub 3} it can be shown that the very strong variation in charging behavior for different preparations is related to the relative presence of differently reacting crystal planes. The edge faces of the hexagonal gibbsite crystals are proton reactive over the whole pH range, in contrast to the 001 plane, which is mainly uncharged below pH = 10. On this 001 face only doubly coordinated surface groups are found, in contrast to the edges which also have singly coordinated surface groups. The results are fully in agreement with the predictions of the Multi site complexation (MUSIC) model. The proton adsorption, electrolyte ion adsorption, and shift of the IEP of gibbsite and aluminum oxide have been modeled simultaneously. For gibbsite, the ion pair formation of Na is larger than that of Cl, as is evidenced by modeling the experimentally observed upward shift on the IEP and charge reversal at high electrolyte concentrations. All these experimental results can be satisfactorily modeled with the MUSIC model, including the experimental surface potential of aluminum oxide (ISFET).

  15. Metastable phases in mechanically alloyed aluminum germanium powders

    SciTech Connect (OSTI)

    Yvon, P.J.; Schwarz, R.B.

    1993-03-01

    Aluminum and germanium form a simple eutectic system with no stable intermetallic phase, and limited mutual solubility. We report the formation of a metastable rhombohedral,{gamma}{sub 1} phase by mechanically alloying aluminum and germanium powders. This phase, which appears for compositions between 20 and 50 at. % germanium, has also been observed in rapidly quenched alloys, but there is disagreement as to its composition. By measuring the heat of crystallization as a function of composition, we determined the composition of the {gamma}{sub 1} phase to be Al{sub 70}Ge{sub 30}. We also produced Al{sub 70}Ge{sub 30} by arc melting the pure elements, followed by splat-quenching at a cooling rate in the range of 10{sup 8} K s{sup {minus}1}. This method produced two metastable phases, one of which was found to be the {gamma}{sub 1} phase obtained by mechanical alloying. The other was a monoclinic phase reported earlier in the literature as {gamma}{sub 2}.

  16. Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium

    DOE Patents [OSTI]

    Marks, Tobin J.; Chen, You-Xian

    2000-01-01

    Salts of (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are described. The (polyfluoroaryl)fluoroanions have the formula [ER'R"R'"F].sup..crclbar. wherein E is aluminum, gallium, or indium, wherein F is fluorine, and wherein R', R", and R'" is each a fluorinated phenyl, fluorinated biphenyl, or fluorinated polycyclic group.

  17. Low-Cost Direct Bonded Aluminum (DBA) Substrates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm036_lin_2012_o.pdf More Documents & Publications ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) Low-Cost Direct Bonded Aluminum (DBA) Substrates Vehicle Technologies Office: 2012 Propulsion Materials R&D Annual Progress Report

  18. Low-Cost Direct Bonded Aluminum (DBA) Substrates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm036_lin_2011_p.pdf More Documents & Publications ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) Low-Cost Direct Bonded Aluminum (DBA) Substrates Environmental Effects on Power Electronic Devices

  19. Life-cycle energy savings potential from aluminum-intensive vehicles

    SciTech Connect (OSTI)

    Stodolsky, F.; Vyas, A.; Cuenca, R.; Gaines, L.

    1995-07-01

    The life-cycle energy and fuel-use impacts of US-produced aluminum-intensive passenger cars and passenger trucks are assessed. The energy analysis includes vehicle fuel consumption, material production energy, and recycling energy. A model that stimulates market dynamics was used to project aluminum-intensive vehicle market shares and national energy savings potential for the period between 2005 and 2030. We conclude that there is a net energy savings with the use of aluminum-intensive vehicles. Manufacturing costs must be reduced to achieve significant market penetration of aluminum-intensive vehicles. The petroleum energy saved from improved fuel efficiency offsets the additional energy needed to manufacture aluminum compared to steel. The energy needed to make aluminum can be reduced further if wrought aluminum is recycled back to wrought aluminum. We find that oil use is displaced by additional use of natural gas and nonfossil energy, but use of coal is lower. Many of the results are not necessarily applicable to vehicles built outside of the United States, but others could be used with caution.

  20. Cathode for a hall-heroult type electrolytic cell for producing aluminum

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum from alumina in an electrolytic cell including using a cathode comprised of a base material having low electrical conductivity and wettable with molten aluminum to form a reaction layer having a high electrical conductivity on said base layer and a cathode bar extending from said reaction layer through said base material to conduct electrical current from said reaction layer.

  1. Aluminum-blade development for the Mod-0A 200-kilowatt wind turbine

    SciTech Connect (OSTI)

    Linscott, B.S.; Shaltens, R.K.; Eggers, A.G.

    1981-12-01

    This report documents the operating experience with two aluminum blades used on the DOE/NASA Mod-0A 200-kilowatt wind turbine located at Clayton, New Mexico. Each Mod-0A aluminum blade is 59.9 feet long and weighs 2360 pounds. The aluminum Mod-0A blade design requirements, the selected design, fabrication procedures, and the blade analyses are discussed. A detailed chronology is presented on the operating experience of the Mod-0A aluminum blades used at Clayton, New Mexico. Blade structural damage was experienced. Inspection and damage assessment were required. Structural modifications that were incorporated to the blades successfully extended the useful operating life of the blades. The aluminum blades completed the planned 2 years of operation of the Clayton wind turbine. The blades were removed from service in August 1980 to allow testing of advanced technology wood composite blades.

  2. Carbothermic reduction and prereduced charge for producing aluminum-silicon alloys

    DOE Patents [OSTI]

    Stevenson, D.T.; Troup, R.L.

    1985-01-01

    Disclosed is a method for the carbothermic reduction of aluminum oxide to form an aluminum alloy including producing silicon carbide by heating a first mix of carbon and silicon oxide in a combustion reactor to an elevated temperature sufficient to produce silicon carbide at an accelerated rate, the heating being provided by an in situ combustion with oxygen gas, and then admixing the silicon carbide with carbon and aluminum oxide to form a second mix and heating the second mix in a second reactor to an elevated metal-forming temperature sufficient to produce aluminum-silicon alloy. The prereduction step includes holding aluminum oxide substantially absent from the combustion reactor. The metal-forming step includes feeding silicon oxide in a preferred ratio with silicon carbide. 1 fig.

  3. Carbothermic reduction and prereduced charge for producing aluminum-silicon alloys

    DOE Patents [OSTI]

    Stevenson, David T. (Washington Township, Armstrong County, PA); Troup, Robert L. (Murrysville, PA)

    1985-01-01

    Disclosed is a method for the carbothermic reduction of aluminum oxide to form an aluminum alloy including producing silicon carbide by heating a first mix of carbon and silicon oxide in a combustion reactor to an elevated temperature sufficient to produce silicon carbide at an accelerated rate, the heating being provided by an in situ combustion with oxygen gas, and then admixing the silicon carbide with carbon and aluminum oxide to form a second mix and heating the second mix in a second reactor to an elevated metal-forming temperature sufficient to produce aluminum-silicon alloy. The prereduction step includes holding aluminum oxide substantially absent from the combustion reactor. The metal-forming step includes feeding silicon oxide in a preferred ratio with silicon carbide.

  4. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR); Ramsey, James A. (The Dalles, OR)

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  5. Final Technical Report Microwave Assisted Electrolyte Cell for Primary Aluminum Production

    SciTech Connect (OSTI)

    Xiaodi Huang; J.Y. Hwang

    2007-04-18

    This research addresses the high priority research need for developing inert anode and wetted cathode technology, as defined in the Aluminum Industry Technology Roadmap and Inert Anode Roadmap, with the performance targets: a) significantly reducing the energy intensity of aluminum production, b) ultimately eliminating anode-related CO2 emissions, and c) reducing aluminum production costs. This research intended to develop a new electrometallurgical extraction technology by introducing microwave irradiation into the current electrolytic cells for primary aluminum production. This technology aimed at accelerating the alumina electrolysis reduction rate and lowering the aluminum production temperature, coupled with the uses of nickel based superalloy inert anode, nickel based superalloy wetted cathode, and modified salt electrolyte. Michigan Technological University, collaborating with Cober Electronic and Century Aluminum, conducted bench-scale research for evaluation of this technology. This research included three sub-topics: a) fluoride microwave absorption; b) microwave assisted electrolytic cell design and fabrication; and c) aluminum electrowinning tests using the microwave assisted electrolytic cell. This research concludes that the typically used fluoride compound for aluminum electrowinning is not a good microwave absorbing material at room temperature. However, it becomes an excellent microwave absorbing material above 550C. The electrowinning tests did not show benefit to introduce microwave irradiation into the electrolytic cell. The experiments revealed that the nickel-based superalloy is not suitable for use as a cathode material; although it wets with molten aluminum, it causes severe reaction with molten aluminum. In the anode experiments, the chosen superalloy did not meet corrosion resistance requirements. A nicked based alloy without iron content could be further investigated.

  6. A.R.S. 37-461: Grants of Rights-of-Way and Site for Public...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: A.R.S. 37-461: Grants of Rights-of-Way and Site for Public UsesLegal Abstract This...

  7. Distinctive plume formation in atmospheric Ar and He plasmas in microwave frequency band and suitability for biomedical applications

    SciTech Connect (OSTI)

    Lee, H. Wk.; Kang, S. K.; Won, I. H.; Kim, H. Y.; Kwon, H. C.; Sim, J. Y.; Lee, J. K.

    2013-12-15

    Distinctive discharge formation in atmospheric Ar and He plasmas was observed in the microwave frequency band using coaxial transmission line resonators. Ar plasmas formed a plasma plume whereas He formed only confined plasmas. As the frequency increased from 0.9 GHz to 2.45 GHz, the Ar plasma exhibited contraction and filamentation, and the He plasmas were constricted. Various powers and gas flow rates were applied to identify the effect of the electric field and gas flow rate on plasma plume formation. The He plasmas were more strongly affected by the electric field than the Ar plasmas. The breakdown and sustain powers yielded opposite results from those for low-frequency plasmas (?kHz). The phenomena could be explained by a change in the dominant ionization process with increasing frequency. Penning ionization and the contribution of secondary electrons in sheath region reduced as the frequency increased, leading to less efficient ionization of He because its ionization and excitation energies are higher than those of Ar. The emission spectra showed an increase in the NO and N{sub 2} second positive band in both the Ar and He plasmas with increasing frequency whereas the hydroxyl radical and atomic O peaks did not increase with increasing frequency but were highest at particular frequencies. Further, the frequency effect of properties such as the plasma impedance, electron density, and device efficiency were presented. The study is expected to be helpful for determining the optimal conditions of plasma systems for biomedical applications.

  8. Structure of stagnated plasma in aluminum wire array Z pinches

    SciTech Connect (OSTI)

    Hall, G. N.; Pikuz, S. A.; Shelkovenko, T. A.; Bland, S. N.; Lebedev, S. V.; Ampleford, D. J.; Palmer, J. B. A.; Bott, S. C.; Rapley, J.; Chittenden, J. P.; Apruzese, J. P.

    2006-08-15

    Experiments with aluminum wire array Z pinches have been carried out on the mega-ampere generator for plasma implosion experiments (MAGPIE) at Imperial College London [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (1996)]. It has been shown that in these arrays, there are two intense sources of radiation during stagnation; Al XII line emission from a precursor-sized object, and both continuum and Al XIII radiation from bright spots of either significantly higher temperature or density randomly distributed around this object so as to produce a hollow emission profile. Spatially resolved spectra produced by spherically bent crystals were recorded, both time-integrated and time-resolved, and were used to show that these two sources of radiation peak at the same time.

  9. Method of manufacturing a niobium-aluminum-germanium superconductive material

    DOE Patents [OSTI]

    Wang, John L. (San Francisco, CA); Pickus, Milton R. (Oakland, CA); Douglas, Kent E. (Redondo Beach, CA)

    1980-01-01

    A method for manufacturing flexible Nb.sub.3 (Al,Ge) multifilamentary superconductive material in which a sintered porous niobium compact is infiltrated with an aluminum-germanium alloy and thereafter deformed and heat treated in a series of steps at different successively higher temperatures preferably below 1000.degree. C. to produce filaments composed of Nb.sub.3 (Al,G3) within the compact. By avoiding temperatures in excess of 1000.degree. C. during the heat treatment, cladding material such as copper can be applied to facilitate a deformation step preceding the heat treatment and can remain in place through the heat treatment to also serve as a temperature stabilizer for supeconductive material produced. Further, these lower heat treatment temperatures favor formation of filaments with reduced grain size and, hence with more grain boundaries which in turn increase the current-carrying capacity of the superconductive material.

  10. Formability Prediction Of Aluminum Sheet In Automotive Applications

    SciTech Connect (OSTI)

    Leppin, Christian; Daniel, Dominique; Shahani, Ravi; Gese, Helmut; Dell, Harry

    2007-05-17

    In the following paper, a full mechanical characterization of the AA6016 T4 aluminum alloy car body sheet DR100 is presented. A comprehensive experimental program was performed to identify and model the orthotopic elasto-plastic deformation behavior of the material and its fracture characteristics including criteria for localized necking, ductile fracture and shear fracture. The commercial software package MF GenYld + CrachFEM in combination with the explicit finite element code Ls-Dyna is used to validate the quality of the material model with experiments, namely, prediction of the FLD, deep drawing with a cross-shaped punch and finally, analysis of a simplified hemming process using a solid discretization of the problem. The focus is on the correct prediction of the limits of the material in such processes.

  11. Laser assisted high entropy alloy coating on aluminum: Microstructural evolution

    SciTech Connect (OSTI)

    Katakam, Shravana; Joshi, Sameehan S.; Mridha, Sanghita; Mukherjee, Sundeep; Dahotre, Narendra B.

    2014-09-14

    High entropy alloy (Al-Fe-Co-Cr-Ni) coatings were synthesized using laser surface engineering on aluminum substrate. Electron diffraction analysis confirmed the formation of solid solution of body centered cubic high entropy alloy phase along with phases with long range periodic structures within the coating. Evolution of such type of microstructure was a result of kinetics associated with laser process, which generates higher temperatures and rapid cooling resulting in retention of high entropy alloy phase followed by reheating and/or annealing in subsequent passes of the laser track giving rise to partial decomposition. The partial decomposition resulted in formation of precipitates having layered morphology with a mixture of high entropy alloy rich phases, compounds, and long range ordered phases.

  12. Energy Assessment Helps Kaiser Aluminum Save Energy and Improve Productivity

    Broader source: Energy.gov [DOE]

    This case study describes how a DOE energy assessment at Kaiser Aluminum's extrusion plant in Sherman, Texas, identified significant potential energy savings in its process heating systems. Employees at the Sherman plant wasted no time moving forward with assessment recommendations. First, they adjusted burner controls on one of the main reverberatory melting furnaces to lower excess oxygen levels. They also made some repairs to the furnaces door sill and jamb to prevent cold air from seeping into it. By implementing these measures the plant achieved annual energy savings of approximately 45,000 MMBtu and improved the furnaces energy intensity by 11.1% between 2006 and 2007. With project costs of approximately $28,000 and energy cost savings of $360,000, the simple payback was under 1 month.

  13. Aluminum Leaching of ''Archived'' Sludge from Tanks 8F, 11H, and 12H

    SciTech Connect (OSTI)

    FONDEUR, FERNANDOF.

    2004-03-12

    Aluminum can promote formation or dissolution of networks in hydroxide solid solutions. When present in large amounts it will act as a network former increasing both the viscosity and the surface tension of melts. This translates into poor free flow properties that affect pour rate of glass production in the Defense Waste Processing Facility (DWPF). To mitigate this situation, DWPF operations limit the amount of aluminum contained in sludge. This study investigated the leaching of aluminum compounds from archived sludge samples. The conclusions found boehmite present as the predominant aluminum compound in sludge from two tanks. We did not identify an aluminum compound in sludge from the third tank. We did not detect any amorphous aluminum hydroxide in the samples. The amount of goethite measured 4.2 percentage weight while hematite measured 3.7 percentage weight in Tank 11H sludge. The recommended recipe for removing gibbsite in sludge proved inefficient for digesting boehmite, removing less than 50 per cent of the compound within 48 hours. The recipe did remove boehmite when the test ran for 10 days (i.e., 7 more days than the recommended baseline leaching period). Additions of fluoride and phosphate to Tank 12H archived sludge did not improve the aluminum leaching efficiency of the baseline recipe.

  14. Characterization of an explosively bonded aluminum proton beam window for the Spallation Neutron Source

    SciTech Connect (OSTI)

    McClintock, David A; Janney, Jim G; Parish, Chad M

    2014-01-01

    An effort is underway at the Spallation Neutron Source (SNS) to change the design of the 1st Generation high-nickel alloy proton beam window (PBW) to one that utilizes aluminum for the window material. One of the key challenges to implementation of an aluminum PBW at the SNS was selection of an appropriate joining method to bond an aluminum window to the stainless steel bulk shielding of the PBW assembly. An explosively formed bond was selected as the most promising joining method for the aluminum PBW design. A testing campaign was conducted to evaluate the strength and efficacy of explosively formed bonds that were produced using two different interlayer materials: niobium and titanium. The characterization methods reported here include tensile testing, thermal-shock leak testing, optical microscopy, and advanced scanning electron microscopy. All tensile specimens examined failed in the aluminum interlayer and measured tensile strengths were all slightly greater than the native properties of the aluminum interlayer, while elongation values were all slightly lower. A leak developed in the test vessel with a niobium interlayer joint after repeated thermal-shock cycles, and was attributed to an extensive crack network that formed in a layer of niobium-rich intermetallics located on the bond interfaces of the niobium interlayer; the test vessel with a titanium interlayer did not develop a leak under the conditions tested. Due to the experience gained from these characterizations, the explosively formed bond with a titanium interlayer was selected for the aluminum PBW design at the SNS.

  15. Ionization of large homogeneous and heterogeneous clusters generated in acetylene-Ar expansions: Cluster ion polymerization

    SciTech Connect (OSTI)

    Kocisek, J.; Lengyel, J.; Farnik, M.

    2013-03-28

    Pure acetylene and mixed Ar-acetylene clusters are formed in supersonic expansions of acetylene/argon mixtures and analysed using reflectron time-of-flight mass spectrometer with variable electron energy ionization source. Acetylene clusters composed of more than a hundred acetylene molecules are generated at the acetylene concentration of Almost-Equal-To 8%, while mixed species are produced at low concentrations ( Almost-Equal-To 0.7%). The electron energy dependence of the mass spectra revealed the ionization process mechanisms in clusters. The ionization above the threshold for acetylene molecule of 11.5 eV results in the main ionic fragment progression (C{sub 2}H{sub 2}){sub n}{sup +}. At the electron energies Greater-Than-Or-Slanted-Equal-To 21.5 eV above the CH+CH{sup +} dissociative ionization limit of acetylene the fragment ions nominally labelled as (C{sub 2}H{sub 2}){sub n}CH{sup +}, n Greater-Than-Or-Slanted-Equal-To 2, are observed. For n Less-Than-Or-Slanted-Equal-To 7 these fragments correspond to covalently bound ionic structures as suggested by the observed strong dehydrogenation [(C{sub 2}H{sub 2}){sub n}-k Multiplication-Sign H]{sup +} and [(C{sub 2}H{sub 2}){sub n}CH -k Multiplication-Sign H]{sup +}. The dehydrogenation is significantly reduced in the mixed clusters where evaporation of Ar instead of hydrogen can stabilize the nascent molecular ion. The C{sub 3}H{sub 3}{sup +} ion was previously assigned to originate from the benzene molecular ion; however, the low appearance energy of Almost-Equal-To 13.7 eV indicates that a less rigid covalently bound structure of C{sub 6}H{sub 6}{sup +} ion must also be formed upon the acetylene cluster electron ionization. The appearance energy of Ar{sub n}(C{sub 2}H{sub 2}){sup +} fragments above Almost-Equal-To 15.1 eV indicates that the argon ionization is the first step in the fragment ion production, and the appearance energy of Ar{sub n{>=}2}(C{sub 2}H{sub 2}){sub m{>=}2}{sup +} at Almost-Equal-To 13.7 eV is discussed in terms of an exciton transfer mechanism.

  16. ALUMINUM READINESS EVALUATION FOR ALUMINUM REMOVAL AND SODIUM HYDROXIDE REGENRATION FROM HANFORD TANK WASTE BY LITHIUM HYDROTALCITE PRECIPITATION

    SciTech Connect (OSTI)

    SAMS TL; MASSIE HL

    2011-01-27

    A Technology Readiness Evaluation (TRE) performed by AREV A Federal Services, LLC (AFS) for Washington River Protection Solutions, LLC (WRPS) shows the lithium hydrotalcite (LiHT) process invented and patented (pending) by AFS has reached an overall Technology Readiness Level (TRL) of 3. The LiHT process removes aluminum and regenerates sodium hydroxide. The evaluation used test results obtained with a 2-L laboratory-scale system to validate the process and its critical technology elements (CTEs) on Hanford tank waste simulants. The testing included detailed definition and evaluation for parameters of interest and validation by comparison to analytical predictions and data quality objectives for critical subsystems. The results of the TRE would support the development of strategies to further mature the design and implementation of the LiHT process as a supplemental pretreatment option for Hanford tank waste.

  17. Fabrication of super-hydrophobic surfaces on aluminum alloy substrates by RF-sputtered polytetrafluoroethylene coatings

    SciTech Connect (OSTI)

    Wang, Yang; Liu, Xiao Wei; Zhang, Hai Feng Zhou, Zhi Ping

    2014-03-15

    In this work, we present a method of fabricating super-hydrophobic surface on aluminum alloy substrate. The etching of aluminum surfaces has been performed using Beck's dislocation etchant for different time to create micrometer-sized irregular steps. An optimised etching time of 50 s is found to be essential before polytetrafluoroethylene (PTFE) coating, to obtain a highest water contact angle of 1652 with a lowest contact angle hysteresis as low as 52. The presence of patterned microstructure as revealed by scanning electron microscopy (SEM) together with the low surface energy ultrathin RF-sputtered PTFE films renders the aluminum alloy surfaces highly super-hydrophobic.

  18. Salt-soda sinter process for recovering aluminum from fly ash

    SciTech Connect (OSTI)

    Mcdowell, W.J.; Seeley, F.G.

    1981-03-03

    A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na2CO3 to a temperature in the range 700*-900* C for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

  19. Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Yang, Xiaodong; Rosenmann, Daniel; Stan, Liliana; Czaplewski, David; Gao, Jie

    2015-09-18

    A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

  20. Comparing Laser Welding Technologies with Friction Stir Welding for Production of Aluminum Tailor-Welded Blanks

    SciTech Connect (OSTI)

    Hovanski, Yuri; Carsley, John; Carlson, Blair; Hartfield-Wunsch, Susan; Pilli, Siva Prasad

    2014-01-15

    A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

  1. Salt-soda sinter process for recovering aluminum from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

  2. Mode transition in CF{sub 4} + Ar inductively coupled plasma

    SciTech Connect (OSTI)

    Liu, Wei; Gao, Fei; Zhao, Shu-Xia; Li, Xue-Chun; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-12-15

    The E to H mode transitions are studied by a hairpin probe and optical emission spectroscopy in inductively coupled CF{sub 4} + Ar plasmas. Electron density, optical emission intensity of Ar, and the voltage and current are measured during the E to H mode transitions. It is found that the electron density and plasma emission intensity increase continuously at low pressure during the E to H mode transition, while they jump up discontinuously at high pressure. Meanwhile, the transition threshold power and ?P (the power interval between E and H mode) increase by increasing the pressure. When the ratio of CF{sub 4} increases, the E to H mode transition happens at higher applied power, and meanwhile, the ?P also significantly increases. Besides, the effects of CF{sub 4} gas ratio on the plasma properties and the circuit electrical properties in both pure E and H modes were also investigated. The electron density and plasma emission intensity both decrease upon increasing the ratio of CF{sub 4} at the two modes, due to the stronger electrons loss scheme. The applied voltages at E and H modes both increase as increasing the CF{sub 4} gas ratio, however the applied current at two modes behave just oppositely with the gas ratio.

  3. Effects of Ar plasma treatment for deposition of ruthenium film by remote plasma atomic layer deposition

    SciTech Connect (OSTI)

    Park, Taeyong; Lee, Jaesang; Park, Jingyu; Jeon, Heeyoung; Jeon, Hyeongtag; Lee, Ki-Hoon; Cho, Byung-Chul; Kim, Moo-Sung; Ahn, Heui-Bok

    2012-01-15

    Ruthenium thin films were deposited on argon plasma-treated SiO{sub 2} and untreated SiO{sub 2} substrates by remote plasma atomic layer deposition using bis(ethylcyclopentadienyl)ruthenium [Ru(EtCp){sub 2}] as a Ru precursor and ammonia plasma as a reactant. The results of in situ Auger electron spectroscopy (AES) analysis indicate that the initial transient region of Ru deposition was decreased by Ar plasma treatment at 400 deg. C, but did not change significantly at 300 deg. C The deposition rate exhibited linearity after continuous film formation and the deposition rates were about 1.7 A/cycle and 0.4 A/cycle at 400 deg. C and 300 deg. C, respectively. Changes of surface energy and polar and dispersive components were measured by the sessile drop test. The quantity of surface amine groups was measured from the surface nitrogen concentration with AES. Furthermore, the Ar plasma-treated SiO{sub 2} contained more amine groups and less hydroxyl groups on the surface than on untreated SiO{sub 2}. Auger spectra exhibited chemical shifts by Ru-O bonding, and larger shifts were observed on untreated substrates due to the strong adhesion of Ru films.

  4. Near- and sub-barrier fusion of {sup 6}He+{sup 40}Ar

    SciTech Connect (OSTI)

    Hinnefeld, J.D.; Kolata, J.J.; Belbot, M.; Lamkin, K.; Zahar, M.; Santi, P.; Kugi, J.

    1993-10-01

    A measurement of the fusion cross section for {sup 6}He + {sup 40}Ar near and below the Coulomb barrier has been performed using a {sup 6}He beam from the UND/Um radioactive beam facility. The {sup 6}He nucleus is thought to have a neutron skin surrounding a {sup 6}He core. If this is the case, then Coulomb polarization of the core relative to the halo might result in neutron flow along a neck, and therefore to a large enhancement of the sub-barrier fusion cross section. {sup 6}He nuclei, of incident energy 10.05 {+-} 0.44 MeV, were directed into a segmented ionization counter (MUSIC) filled with P10 at 40 torr. The {sup 40}Ar in the detector gas served also as the target nuclei. {sup 6}He energies in the 50-cm active length of the detector varied from 7.75 MeV down to 3.05 MeV. Calculations indicate that fusion events should be distinguishable from most non-fusion events on the basis of energy deposition patterns in the ten MUSIC detector segments. For some large-angle scattering events a more elaborate analysis involving detailed Monte Carlo simulation of the various reactions is necessary.

  5. Ablation and cone formation mechanism on CR-39 by ArF laser irradiation

    SciTech Connect (OSTI)

    Shakeri Jooybari, B. E-mail: hafarideh@aut.ac.ir; Afarideh, H. E-mail: hafarideh@aut.ac.ir; Lamehi-Rachti, M.; Ghergherehchi, M.

    2015-03-07

    In this work, chemical properties, surface modification, and micro structures formation on ablated polyallyl di-glycol carbonate (CR-39) polymer by ArF laser irradiation (??=?193?nm) at various fluences and pulse number were investigated. CR-39 samples have been irradiated with an ArF laser (193?nm) at a repetition rate of 1?Hz. Threshold fluence of ablation and effective absorption coefficient of CR-39 were determined. Conical microstructures (Taylor cone) formed on laser-ablated CR-39 exhibit: smooth, Taylor cone shape walls and sharp tips together with interference and well defined fringe-structure with a period of 230?nm, around cone base. Mechanism of cone formation and cone evolution of CR-39 ablated surface were investigated by change of fluences (at a given pulse number) and pulse number (at a given fluence). Cone height, cone base, and region of interface were increased in micrometer steps by increasing the total fluence. Depression on the base of the cone and the circular fringe were simulated. FTIR spectra were measured and energy dispersive x-ray analysis of irradiated and un-irradiated samples was performed.

  6. Solubility and Reaction Rates of Aluminum Solid Phases Under Geothermal Conditions

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.; Anovitz, L.M.

    2000-05-28

    Experimental studies involving equilibrium solubility and dissolution/precipitation rates were initiated on aluminum hydroxide phases prevalent under geothermal reservoir conditions. A large capacity, hydrogen-electrode concentration cell (HECC) was constructed specifically for this purpose.

  7. Aluminum ion parameters for the 2015 PP-on-Al setup in RHIC

    SciTech Connect (OSTI)

    Gardner, C. J.

    2015-10-02

    In this note the nominal parameters for aluminum ions in Booster, AGS, and RHIC are given for the PP-on-Al setup in RHIC. The setup parameters are summarized in Sections 13, 14, 15.

  8. Metal binding in an aluminum based metal-organic framework for carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dioxide capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Metal binding in an aluminum based metal-organic framework for carbon dioxide capture

  9. Iron-niobium-aluminum alloy having high-temperature corrosion resistance

    DOE Patents [OSTI]

    Hsu, Huey S.

    1988-04-14

    An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

  10. Numerical analysis of a mixture of Ar/NH{sub 3} microwave plasma chemical vapor deposition reactor

    SciTech Connect (OSTI)

    Li Zhi [School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); Zhao Zhen [Chemistry Department, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Physical Science and Technical College, Dalian University, Dalian 116622 (China)

    2012-06-01

    A two-dimensional fluid model has been used to investigate the properties of plasma in Ar/NH{sub 3} microwave electron cyclotron resonance discharge at low pressure. The electromagnetic field model solved by the three-dimensional Simpson method is coupled to a fluid plasma model. The finite difference method was employed to discrete the governing equations. 40 species (neutrals, radicals, ions, and electrons) are consisted in the model. In total, 75 electron-neutral, 43 electron-ion, 167 neutral-neutral, 129 ion-neutral, 28 ion-ion, and 90 3-body reactions are used in the model. According to the simulation, the distribution of the densities of the considered plasma species has been showed and the mechanisms of their variations have been discussed. It is found that the main neutrals (Ar*, Ar**, NH{sub 3}{sup *}, NH, H{sub 2}, NH{sub 2}, H, and N{sub 2}) are present at high densities in Ar/NH{sub 3} microwave electron cyclotron resonance discharge when the mixing ratio of Ar/NH{sub 3} is 1:1 at 20 Pa. The density of NH is more than that of NH{sub 2} atom. And NH{sub 3}{sup +} are the most important ammonia ions. But the uniformity of the space distribution of NH{sub 3}{sup +} is lower than the other ammonia ions.

  11. Mapping the ionization state of laser-irradiated Ar gas jets with multiwavelength monochromatic x-ray imaging

    SciTech Connect (OSTI)

    Kugland, N. L.; Niemann, C.; Doeppner, T.; Kemp, A.; Glenzer, S. H.; Schaeffer, D.

    2010-10-15

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx_equal}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultrahigh intensity (10{sup 19} W/cm{sup 2}, 50 TW) Ti:sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {mu}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {mu}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {mu}m along the laser axis.

  12. Mapping the Ionization State of Laser-Irradiated Ar Gas Jets With Multi-Wavelength Monochromatic X-Ray Imaging

    SciTech Connect (OSTI)

    Kugland, N L; Doppner, T; Kemp, A; Schaeffer, D; Glenzer, S H; Niemann, C

    2010-04-08

    Two-dimensional monochromatic images of fast-electron stimulated Ar K{alpha} and He-{alpha} x-ray self-emission have recorded a time-integrated map of the extent of Ar{sup {approx}6+} and Ar{sup 16+} ions, respectively, within a high density (10{sup 20} cm{sup -3} atomic density) Ar plasma. This plasma was produced by irradiating a 2 mm wide clustering Ar gas jet with an ultra-high intensity (10{sup 19} W/cm{sup 2}, 200 fs) Ti:Sapphire laser operating at 800 nm. Spherically bent quartz crystals in the 200 (for K{alpha}) and 201 (for He-{alpha}) planes were used as near-normal incidence reflective x-ray optics. We see that a large (830 {micro}m long) region of plasma emits K{alpha} primarily along the laser axis, while the He-{alpha} emission is confined to smaller hot spot (230 {micro}m long) region that likely corresponds to the focal volume of the f/8 laser beam. X-ray spectra from a Bragg spectrometer operating in the von Hamos geometry, which images in one dimension, indicate that the centroids of the K{alpha} and He-{alpha} emission regions are separated by approximately 330 {micro}m along the laser axis.

  13. Process for the synthesis of nanophase dispersion-strengthened aluminum alloy

    DOE Patents [OSTI]

    Barbour, John C. (Albuquerque, NM); Knapp, James Arthur (Albuquerque, NM); Follstaedt, David Martin (Albuquerque, NM); Myers, Samuel Maxwell (Albuquerque, NM)

    1998-12-15

    A process for fabricating dispersion-strengthened ceramic-metal composites is claimed. The process comprises in-situ interaction and chemical reaction of a metal in gaseous form with a ceramic producer in plasma form. Such composites can be fabricated with macroscopic dimensions. Special emphasis is placed on fabrication of dispersion-strengthened aluminum oxide-aluminum composites, which can exhibit flow stresses more characteristic of high strength steel.

  14. Improving the Cycling Life of Aluminum and Germanium Thin Films for use as

    Office of Scientific and Technical Information (OSTI)

    Anodic Materials in Li-Ion Batteries. (Technical Report) | SciTech Connect Technical Report: Improving the Cycling Life of Aluminum and Germanium Thin Films for use as Anodic Materials in Li-Ion Batteries. Citation Details In-Document Search Title: Improving the Cycling Life of Aluminum and Germanium Thin Films for use as Anodic Materials in Li-Ion Batteries. Abstract not provided. Authors: Hudak, Nicholas ; Huber, Dale L. ; Gulley, Gerald Publication Date: 2014-09-01 OSTI Identifier:

  15. Precipitation and Deposition of Aluminum-Containing Phases in Tank Wastes

    SciTech Connect (OSTI)

    Daniel M. Dabbs; Ilhan A. Aksay

    2005-01-12

    Aluminum-containing phases compose the bulk of solids precipitating during the processing of radioactive tank wastes. Processes designed to minimize the volume of high-level waste through conversion to glassy phases require transporting waste solutions near-saturated with aluminum-containing species from holding tank to processing center. The uncontrolled precipitation within transfer lines results in clogged pipes and lines and fouled ion exchangers, with the potential to shut down processing operations.

  16. Design of defect spins in piezoelectric aluminum nitride for solid-state

    Office of Scientific and Technical Information (OSTI)

    hybrid quantum technologies (Journal Article) | SciTech Connect Design of defect spins in piezoelectric aluminum nitride for solid-state hybrid quantum technologies Citation Details In-Document Search Title: Design of defect spins in piezoelectric aluminum nitride for solid-state hybrid quantum technologies Spin defects in wide-band gap semiconductors are promising systems for the realization of quantum bits, or qubits, in solid-state environments. To date, defect qubits have only been

  17. CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM

    Office of Scientific and Technical Information (OSTI)

    ALLOYS FOR HIGH TEMPERATURE APPLICATION (Conference) | SciTech Connect Conference: CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Citation Details In-Document Search Title: CHARACTERIZATION OF NEAR NET-SHAPE CASTABLE RARE EARTH MODIFIED ALUMINUM ALLOYS FOR HIGH TEMPERATURE APPLICATION Authors: Sims, Zachary C [1] ; Rios, Orlando [1] ; McCall, S. K. [2] ; Ott, Dr. Ryan T. [3] ; Van Buuren, Tony [2] + Show Author Affiliations

  18. Understanding composite explosive energetics: 3, Reactive flow modeling of aluminum reaction kinetics in PETN and TNT

    SciTech Connect (OSTI)

    Tao, W.C.; Tarver, C.M.; Ornellas, D.L.

    1991-12-06

    Using Fabry-Perot interferometry techniques, we have determined that early time rate of energy release from detonating PETN and TNT explosives filled with 5 and 10 wt % of either 5 {mu}m of 18 {mu}m spherical aluminum (Al) particles. From the measured particle velocity data, we are able to infer the reaction rate of aluminum with the detonation products, and calculate the extent of reaction 1--3 {mu}s after the detonation. We observed that a substantional portion of the aluminum metal in all of the PETN and TNE formulations reacted within the timeframe of the one-dimensional experiment. In the PETN formulation filed with 5 wt % of 5 {mu}m aluminum, all of the metal reacted within 1.5 {mu}s, resulting in an increase of 22% in energy compared to pure PETN. A reactive-flow hydrodynamic model based on the Zeldovich-von Neumann-Doring (ZND) description of the reaction zone and subsequent reaction produce expansion (Taylor wave) is used to interpret the reaction rate of the aluminum particles with detonation product gases. The diffusion-controlled reaction mechanism for aluminum and the global kinetic parameters used in the model have been found to be consistent for all the PETN and TNT formulations.

  19. Retention and release of tritium in aluminum clad, Al-Li alloys

    SciTech Connect (OSTI)

    Louthan, M.R. Jr.

    1991-12-31

    Tritium retention in and release from aluminum clad, aluminum-lithium alloys is modeled from experimental and operational data developed during the thirty plus years of tritium production at the Savannah River Site. The model assumes that tritium atoms, formed by the {sup 6}Li(n,{alpha}){sup 3}He reaction, are produced in solid solution in the Al-Li alloy. Because of the low solubility of hydrogen isotopes in aluminum alloys, the irradiated Al-Li rapidly becomes supersaturated in tritium. Newly produced tritium atoms are trapped by lithium atoms to form a lithium tritide. The effective tritium pressure required for trap or tritide stability is the equilibrium decomposition pressure of tritium over a lithium tritide-aluminum mixture. The temperature dependence of tritium release is determined by the permeability of the cladding to tritium and the local equilibrium at the trap sites. This model is used to calculate tritium release from aluminum clad, aluminum-lithium alloys. 9 refs., 3 figs.

  20. Retention and release of tritium in aluminum clad, Al-Li alloys

    SciTech Connect (OSTI)

    Louthan, M.R. Jr.

    1991-01-01

    Tritium retention in and release from aluminum clad, aluminum-lithium alloys is modeled from experimental and operational data developed during the thirty plus years of tritium production at the Savannah River Site. The model assumes that tritium atoms, formed by the {sup 6}Li(n,{alpha}){sup 3}He reaction, are produced in solid solution in the Al-Li alloy. Because of the low solubility of hydrogen isotopes in aluminum alloys, the irradiated Al-Li rapidly becomes supersaturated in tritium. Newly produced tritium atoms are trapped by lithium atoms to form a lithium tritide. The effective tritium pressure required for trap or tritide stability is the equilibrium decomposition pressure of tritium over a lithium tritide-aluminum mixture. The temperature dependence of tritium release is determined by the permeability of the cladding to tritium and the local equilibrium at the trap sites. This model is used to calculate tritium release from aluminum clad, aluminum-lithium alloys. 9 refs., 3 figs.

  1. Direct acid dissolution of aluminum and other metals from fly ash

    SciTech Connect (OSTI)

    Kelmers, A.D.; Egan, B.Z.; Seeley, F.G.; Campbell, G.D.

    1981-01-01

    Fly ash could provide a significant domestic source of alumina and thus supply a large part of the US needs for aluminum and possibly also several other metals. The aluminum and other metals can be solubilized from fly ash by acid dissolution methods. The aluminum may be present in any or all of three solid phases: (1) crystalline; (2) glassy amorphous; and (3) irregular, spongy amorphous. The chemistry of these phases controls the solubilization behavior. The aluminum in high-calcium western ashes is primarily found in the amorphous phases, and much of it can be solubilized by using short-time, ambient-temperature leaching. Little of the aluminum in the low-calcium eastern ashes is solubilized under ambient-temperature conditions, and only a portion can be solubilized even at reflux temperature conditions. Some of the aluminum in these eastern ashes is present as mullite, while some is found in the amorphous material. The fraction contained in mullite is relativey acid insoluble, and only partial solubilization can be achieved even under vigorous acid leach conditions.

  2. Ergonomics Designs of Aluminum Beverage Cans and Bottles

    SciTech Connect (OSTI)

    Han Jing; Itoh, Ryouiti; Shinguryo, Takuro; Yamazaki, Koetsu; Nishiyama, Sadao

    2005-08-05

    This paper introduced the finite element analyses into the ergonomics designs to evaluate the human feelings numerically and objectively. Two design examples in developing aluminum beverage cans and bottles are presented. The first example describes a design of the tab of the can with better finger access. A simulation of finger pulling up the tab of the can has been performed and a pain in the finger has been evaluated by using the maximum value of the contact stress of a finger model. The finger access comparison of three kinds of tab ring shape designs showed that the finger access of the tab that may have a larger contact area with finger is better. The second example describes a design of rib-shape embossed bottles for hot vending. Analyses of tactile sensation of heat have been performed and the amount of heat transmitted from hot bottles to finger was used to present the hot touch feeling. Comparison results showed that the hot touch feeling of rib-shape embossed bottles is better than that of cylindrical bottles, and that the shape of the rib also influenced the hot touch feeling.

  3. Room temperature aluminum antimonide radiation detector and methods thereof

    DOE Patents [OSTI]

    Lordi, Vincenzo; Wu, Kuang Jen J.; Aberg, Daniel; Erhart, Paul; Coombs, III, Arthur W; Sturm, Benjamin W

    2015-03-03

    In one embodiment, a method for producing a high-purity single crystal of aluminum antimonide (AlSb) includes providing a growing environment with which to grow a crystal, growing a single crystal of AlSb in the growing environment which comprises hydrogen (H.sub.2) gas to reduce oxide formation and subsequent incorporation of oxygen impurities in the crystal, and adding a controlled amount of at least one impurity to the growing environment to effectively incorporate at least one dopant into the crystal. In another embodiment, a high energy radiation detector includes a single high-purity crystal of AlSb, a supporting structure for the crystal, and logic for interpreting signals obtained from the crystal which is operable as a radiation detector at a temperature of about 25.degree. C. In one embodiment, a high-purity single crystal of AlSb includes AlSb and at least one dopant selected from a group consisting of selenium (Se), tellurium (Te), and tin (Sn).

  4. Longitudinal study of workers in an aluminum smelter

    SciTech Connect (OSTI)

    Chan-Yeung, M.; Enarson, D.A.; MacLean, L.; Irving, D.

    1989-05-01

    We conducted a 6-y follow-up study that included workers in an aluminum smelter in British Columbia. Of the original cohort, 951 workers left the industry and 985 workers participated in both studies. Comparison of those who left and those who remained showed that those who left were (1) older, (2) had a slightly higher prevalence of respiratory symptoms, and (3) had lower lung function; this was especially true for workers who were 50 + y of age at the time the initial study was conducted. Analyses were conducted only on 586 male workers who did not change their job location or smoking habits between the initial and the follow-up study. Potroom workers in the ''high-exposure'' group had a significant reduction in the prevalence of cough, but experienced an increase in the prevalence of wheeze. There was no significant difference in the annual decline in forced expiratory volume in 1 sec and forced vital capacity between the potroom workers and controls. In general, older workers and smokers had a greater decline in lung function compared to younger workers and nonsmokers. Leukocyte count done during the initial study was found to be an independent predictor of longitudinal decline in lung function. The lack of exposure effect on longitudinal decline in lung function could be due to ''healthy worker'' effect and improvement in the working condition of the smelter.

  5. Process Development for Stamping -Pillar Covers with Aluminum

    SciTech Connect (OSTI)

    Choi, Jung-Pyung; Rohatgi, Aashish; Smith, Mark T.; Lavender, Curt A.

    2015-02-20

    In this work, performed in close collaboration with PACCAR and Magna International, a 6XXX series aluminum alloy was used for the development of A-Pillar cover for the cab of a typical heavy-duty Class-8 truck. The use of Al alloy for the A-pillar cover represents an approximately 40% weight savings over its steel or molded fiberglass composite counterpart. For the selected Al alloy, a small amount of cold work (5% tensile strain), following prior hot-forming, was found to significantly improve the subsequent age-hardening response. The role of solutionizing temperature and rate of cooling on the age-hardening response after paint-bake treatment were investigated. For the temperature range selected in this work, higher solutionizing temperature correlated with greater subsequent age-hardening and vice-versa. However, the age-hardening response was insensitive to the mode of cooling (water quench vs. air cooling). Finally, a two-step forming process was developed where, in the first step, the blank was heated to solutionizing temperature, quenched, and then partially formed at room temperature. For the second step, the pre-form was re-heated and quenched as in the first step, and the forming was completed at room temperature. The resulting A-pillars had sufficient residual ductility to be compatible with hemming and riveting

  6. INTERPRETING ERUPTIVE BEHAVIOR IN NOAA AR 11158 VIA THE REGION'S MAGNETIC ENERGY AND RELATIVE-HELICITY BUDGETS

    SciTech Connect (OSTI)

    Tziotziou, Kostas; Georgoulis, Manolis K.; Liu Yang

    2013-08-01

    In previous works, we introduced a nonlinear force-free method that self-consistently calculates the instantaneous budgets of free magnetic energy and relative magnetic helicity in solar active regions (ARs). Calculation is expedient and practical, using only a single vector magnetogram per computation. We apply this method to a time series of 600 high-cadence vector magnetograms of the eruptive NOAA AR 11158 acquired by the Helioseismic and Magnetic Imager on board the Solar Dynamics Observatory over a five-day observing interval. Besides testing our method extensively, we use it to interpret the dynamical evolution in the AR, including eruptions. We find that the AR builds large budgets of both free magnetic energy and relative magnetic helicity, sufficient to power many more eruptions than the ones it gave within the interval of interest. For each of these major eruptions, we find eruption-related decreases and subsequent free-energy and helicity budgets that are consistent with the observed eruption (flare and coronal mass ejection (CME)) sizes. In addition, we find that (1) evolution in the AR is consistent with the recently proposed (free) energy-(relative) helicity diagram of solar ARs, (2) eruption-related decreases occur before the flare and the projected CME-launch times, suggesting that CME progenitors precede flares, and (3) self terms of free energy and relative helicity most likely originate from respective mutual terms, following a progressive mutual-to-self conversion pattern that most likely stems from magnetic reconnection. This results in the non-ideal formation of increasingly helical pre-eruption structures and instigates further research on the triggering of solar eruptions with magnetic helicity firmly placed in the eruption cadre.

  7. Etching mechanism of niobium in coaxial Ar/Cl2 radio frequency plasma

    SciTech Connect (OSTI)

    Upadhyay, Janardan; Im, Do; Popovic, Svetozar; Valente-Feliciano, Anne -Marie; Phillips, H. Larry; Vuskovic, Leposova

    2015-03-18

    The understanding of the Ar/Cl2 plasma etching mechanism is crucial for the desired modification of inner surface of the three dimensional niobium (Nb) superconductive radio frequency cavities. Uniform mass removal in cylindrical shaped structures is a challenging task because the etch rate varies along the direction of gas flow. The study is performed in the asymmetric coaxial radio-frequency (rf) discharge with two identical Nb rings acting as a part of the outer electrode. The dependence of etch rate uniformity on pressure, rf power, dc bias, Cl2 concentration, diameter of the inner electrode, temperature of the outer cylinder, and position of the samples in the structure is determined. Furthermore, to understand the plasma etching mechanisms, we have studied several factors that have important influence on the etch rate and uniformity, which include the plasma sheath potential, Nb surface temperature, and the gas flow rate.

  8. AR-CITE: Analysis of Search Results for the Clarification and Identification of Technology Emergence

    Energy Science and Technology Software Center (OSTI)

    2012-06-15

    The Analysis of Search Results for the Clarification and Identification of Technology Emergence (AR-CITE) computer code examines a scientometric model that tracks the emergence of an identified technology from initial discovery (via original scientific and conference literature), through critical discoveries (via original scientific, conference literature and patents), transitioning through Technology Readiness Levels (TRLs) and ultimately on to commercial currency of citations, collaboration indicators, and on-line news patterns are identified. The combinations of four distinct andmore »separate searchable on-line networked sources (i.e. scholarly publications and citation, world patents, news archives, and on-line mapping networks) are assembled to become one collective network (a dataset for analysis of relations). This established network becomes the basis from which to quickly analyze the temporal flow of activity (searchable events) for the subject domain to be clarified and identified.« less

  9. MAGNETIC ENERGY PARTITION BETWEEN THE CORONAL MASS EJECTION AND FLARE FROM AR 11283

    SciTech Connect (OSTI)

    Feng, L.; Li, Y. P.; Gan, W. Q.; Wiegelmann, T.; Inhester, B.; Su, Y.; Sun, X. D.

    2013-03-01

    On 2011 September 6, an X-class flare and a halo coronal mass ejection (CME) were observed from Earth erupting from the same active region AR 11283. The magnetic energy partition between them has been investigated. SDO/HMI vector magnetograms were used to obtain the coronal magnetic field using the nonlinear force-free field (NLFFF) extrapolation method. The free magnetic energies before and after the flare were calculated to estimate the released energy available to power the flare and the CME. For the flare energetics, thermal and nonthermal energies were derived using the RHESSI and GOES data. To obtain the radiative output, SDO/EVE data in the 0.1-37 nm waveband were utilized. We have reconstructed the three-dimensional (3D) periphery of the CME from the coronagraph images observed by STEREO-A, B, and SOHO. The mass calculations were then based on a more precise Thomson-scattering geometry. The subsequent estimate of the kinetic and potential energies of the CME took advantage of the more accurate mass, and the height and speed in a 3D frame. The released free magnetic energy resulting from the NLFFF model is about 6.4 Multiplication-Sign 10{sup 31} erg, which has a possible upper limit of 1.8 Multiplication-Sign 10{sup 32} erg. The thermal and nonthermal energies are lower than the radiative output of 2.2 Multiplication-Sign 10{sup 31} erg from SDO/EVE for this event. The total radiation covering the whole solar spectrum is probably a few times larger. The sum of the kinetic and potential energy of the CME could go up to 6.5 Multiplication-Sign 10{sup 31} erg. Therefore, the free energy is able to power the flare and the CME in AR 11283. Within the uncertainty, the flare and the CME may consume a similar amount of free energy.

  10. Simulation study of 3-5 keV x-ray conversion efficiency from Ar K-shell

    Office of Scientific and Technical Information (OSTI)

    vs. Ag L-shell targets on the National Ignition Facility laser (Journal Article) | SciTech Connect Simulation study of 3-5 keV x-ray conversion efficiency from Ar K-shell vs. Ag L-shell targets on the National Ignition Facility laser Citation Details In-Document Search Title: Simulation study of 3-5 keV x-ray conversion efficiency from Ar K-shell vs. Ag L-shell targets on the National Ignition Facility laser Tailored, high-flux, multi-keV x-ray sources are desirable for studying x-ray

  11. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore » (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.« less

  12. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-15

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (<10?pA) using a 40?mm cathode/anode gap, corresponding to field strength of 13.7?MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ?22.5 MV/m with field emission less than 100?pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  13. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  14. Optimization of Squeeze Casting for Aluminum Alloy Parts

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Qingming Chang; Yulong Zhu

    2002-07-30

    This study was initiated with the installation of a new production size UBE 350 Ton VSC Squeeze Casting system in the Metal Casting Laboratory at Case Western University. A Lindberg 75k W electrical melting furnace was installed alongside. The challenge of installation and operation of such industrial-size equipment in an academic environment was met successfully. Subsequently, a Sterling oil die heater and a Visi-Track shot monitoring system were added. A significant number of inserts were designed and fabricated over the span of the project, primarily for squeeze casting different configurations of test bars and plates. A spiral ''ribbon insert'' for evaluation of molten metal fluidity was also fabricated. These inserts were used to generate a broad range of processing conditions and determine their effect on the quality of the squeeze cast parts. This investigation has studied the influence of the various casting variables on the quality of indirect squeeze castings primarily of aluminum alloys. The variables studied include gating design, fill time and fill patter, metal pressure and die temperature variations. The quality of the die casting was assessed by an analysis of both their surface condition and internal soundness. The primary metal tested was an aluminum 356 alloy. In addition to determining the effect of these casting variables on casting quality as measured by a flat plate die of various thickness, a number of test bar inserts with different gating designs have been inserted in the squeeze casting machine. The mechanical properties of these test bars produced under different squeeze casting conditions were measured and reported. The investigation of the resulting properties also included an analysis of the microstructure of the squeeze castings and the effect of the various structural constituents on the resulting properties. The main conclusions from this investigation are as follows: The ingate size and shape are very important since it must remain open until the casting is solidified and pressure is maintained on the solidifying casting. Fanned gates, particularly on the smaller section castings avoid jetting effects at the ingate end. The fan type ingate helps accomplish a rapid fill without high velocities. The molten metal has to fill the cavity before localized solidification occurs. This is best accomplished with a larger ingate to attain rapid filling without excessive velocity or jetting that occurs at high metal velocities. Straight gates are prone to case jetting of the metal stream even a low velocities. Fanned gates allow use of higher fill velocity without excessive jetting. A higher metal pressure provides a more complete fill of the die including improved compensation for solidification shrinkage. With the proper filling pattern, ingates, overflows and die temperature for a given die, very good tensile properties can be attained in squeeze casting. In general, the smaller squeeze castings require higher die temperatures. Computer models using the UES Procast and MagmaSoft finite element software can, after suitable adjustments, predict the flow pattern in the die cavity.

  15. (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2001-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interfere in the ethylene polymerization process, while affecting the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  16. (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2002-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interfere in the ethylene polymerization process, while affecting the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  17. Uranium deposition study on aluminum: results of early tests

    SciTech Connect (OSTI)

    Hughes, M.R.; Nolan, T.A.

    1984-06-19

    Laboratory experiments to quantify uranium compound deposition on Aluminum 3003 test coupons have been initiated. These experiments consist of exposing the coupons to normal assay UF/sub 6/ (0.7% /sup 235/U) in nickel reaction vessels under various conditions of UF/sub 6/ pressure, temperature, and time. To-date, runs from 5 minutes to 2000 hr have been completed at a UF/sub 6/ pressure of 100 torr and at a temperature of 60/sup 0/C. Longer exposure times are in progress. Initial results indicated that a surface film of uranium, primarily as uranyl fluoride (UO/sub 2/F/sub 2/), is deposited very soon after exposure to UF/sub 6/. In a five minute UF/sub 6/ exposure at a temperature of 60/sup 0/C, an average of 2.9 ..mu..g U/cm/sup 2/ was deposited; after 24 hr the deposit typically increased to 5.0 ..mu..g/cm/sup 2/ and then increased to 10.4 ..mu..g/cm/sup 2/ after 2000 hr. This amount of deposit (at 2000 hr exposure) would contribute roughly 10 to 20% to the total 186 keV gamma signal obtained from a GCEP product header pipe being operated at UF/sub 6/ pressures of 2 to 5 torr. The amount of isotopic exchange which would occur in the deposit in the event that HEU and LEU productions were alternated is considered. It is felt that isotopic exchange would not occur to any significant amount within the fixed deposit during relatively short HEU production periods since the HEU would be present primarily as adsorbed UF/sub 6/ molecules on the surface of the deposit. The adsorbed HEU molecules would be removed by evacuation and diluted by LEU production. Major increases in the deposit count would be observed if a leak occurred or moisture was introduced into the system while HEU was being produced.

  18. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al{sub 6}

    SciTech Connect (OSTI)

    Coon, S.R.; Calaway, W.F.; Pellin, M.J.; Curlee, G.A.; White, J.M.

    1992-12-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al{sub 6} were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E{sup {minus}3} to E{sup {minus}4.5}. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  19. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al[sub 6

    SciTech Connect (OSTI)

    Coon, S.R.; Calaway, W.F.; Pellin, M.J. ); Curlee, G.A. . Dept. of Physics); White, J.M. . Dept. of Chemistry and Biochemistry)

    1992-01-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al[sub 6] were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E[sup [minus]3] to E[sup [minus]4.5]. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  20. Method for removing magnesium from aluminum-magnesium alloys with engineered scavenger compound

    SciTech Connect (OSTI)

    Riley, W.D.; Jong, B.W.

    1994-12-31

    The invention relates to a method for removal and production of high purity magnesium from aluminum-magnesium alloys using an engineered scanvenger compound. In particular, the invention relates to a method for removal and production of high purity magnesium from aluminum-magnesium alloys using the engineered scanvenger compound (ESC) lithium titanate (Li2O3TiO2). The removal of magnesium from the aluminum-magnesium alloys is performed at about 600-750 C in a molten salt bath of KCl or KCl-MgCl2 using lithium titanate (Li2O3TiO2) as the engineered scavenger compound (ESC). Electrode deposition of magnesium from the loaded ESC onto a stainless steel electrode is accomplished in a second step, and provides a clean magnesium electrode deposit for recycling. The second step also prepares the ESC for reuse.

  1. Exploring Mbar shock conditions and isochorically heated aluminum at the MEC end station of the LCLS

    SciTech Connect (OSTI)

    Fletcher, L. B.; Lee, H. J.; SLAC, aff; Barbrel, B.; Gauthier, M.; Galtier, E.; Nagler, B.; Doppner, T.; LePape, S.; Ma, T.; Pak, A.; Turnbull, D.; White, T.; Gregori, G.; Wei, M.; Falcone, R. W.; Heimann, P.; Zastrau, U.; Hastings, J. B.; Glenzer, S. H.

    2015-02-05

    Recent experiments performed at the Matter in Extreme Conditions end station (MEC) of the Linac Coherent Light Source (LCLS) have demonstrated the first spectrally resolved measurements of plasmons from isochorically heated aluminum. The experiments have been performed using a seeded 8-keV x-ray laser beam as a pump and probe to both volumetrically heat and scatter x-rays from aluminum. Collective x-ray Thomson scattering spectra show a well-resolved plasmon feature that is down-shifted in energy by 19 eV. In addition, Mbar shock pressures from laser-compressed aluminum foils using Velocity Interferometer System for Any Reflector (VISAR) have been measured. The combination of experiments fully demonstrates the possibility to perform warm dense matter studies at the LCLS with unprecedented accuracy and precision.

  2. Spectroscopy diagnostic of dual-frequency capacitively coupled CHF{sub 3}/Ar plasma

    SciTech Connect (OSTI)

    Liu, Wen-Yao; Du, Yong-Quan [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); Liu, Yong-Xin; Liu, Jia; Zhao, Tian-Liang; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Xu, Yong; Li, Xiao-Song; Zhu, Ai-Min [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China) [Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-11-15

    A combined spectroscopic method of absorption, actinometry, and relative optical emission intensity is employed to determine the absolute CF{sub 2} density, the relative F and H densities, H atom excitation temperature and the electron density in dual-frequency (60/2 MHz) capacitively coupled CHF{sub 3}/Ar plasmas. The effects of different control parameters, such as high-frequency (HF) power, low-frequency (LF) power, gas pressure, gap length and content of CHF{sub 3}, on the concentration of radical CF{sub 2}, F, and H and excitation temperature are discussed, respectively. It is found that the concentration of CF{sub 2} is strongly dependent on the HF power, operating pressure and the proportion of CHF{sub 3} in feed gas, while it is almost independent of the LF power and the gap length. A higher concentration ratio of F to CF{sub 2} could be obtained in dual-frequency discharge case. Finally, the generation and decay mechanisms of CF{sub 2} and F were also discussed.

  3. Ordered InP nanostructures fabricated by Ar{sup +}-ion irradiation

    SciTech Connect (OSTI)

    Mohanta, S.K.; Soni, R.K.; Tripathy, S.; Chua, S.J.

    2006-01-23

    In this letter, we report fabrication of ordered InP nanostructures using 50 keV Ar{sup +}-ion irradiation at normal incidence. The structural and optical properties of these nanodots as a function of ion dose have been investigated. Scanning electron microscopy investigations reveal that the average sizes of the InP nanodots vary from 50 nm to 90 nm as the ion dose increases from 1x10{sup 17} to 1x10{sup 18} cm{sup -2}. Furthermore, an increase in ion dose results in a wider dot size distribution. Apart from the bulk InP band-edge photoluminescence (PL), the surface nanostructuring leads to the observation of an additional PL band at 1.98 eV. Such a blueshifted PL peak could arise due to a combined effect of carrier confinement in the surface nanodots and radiative recombination associated with surface states. The room-temperature micro-Raman investigation of InP nanodots reveals optical phonon softening due to phonon confinement in the surface nanodots.

  4. Structural modifications in InP nanostructures prepared by Ar{sup +}-ion irradiation

    SciTech Connect (OSTI)

    Mohanta, S. K.; Soni, R. K.; Gosvami, N. N.; Vajpeyi, A. P.; Tripathy, S.

    2007-10-01

    The evolution of nanopatterned InP surfaces by low-energy Ar{sup +}-ion irradiation and their dependence on incidence angle were investigated by field emission scanning electron microscopy, atomic force microscopy, and Raman scattering. Ordered surface nanodots of high aspect ratio were created. At large ion incidence angle the dot density decreases and the size varies in the range of 65-130 nm with height of around 25-30 nm. Rapid thermal annealing of the patterned surface shows cluster formation at annealing temperatures of 400 deg. C and above, with some micro-cracks at ion incidence angle of 45 deg. C . With increasing ion incidence angle, the optical phonon Raman modes display systematic downward shift and large asymmetric broadening associated with increased contribution of disorder activated LO and TO modes from the patterned surface. The lowering of phonon frequencies, induced by the phonon wave function confinement, signifies the presence of embedded nanocrystallites in the large sized nanodot patterned surface. The surface damage recovery is achieved by rapid thermal annealing of the samples as reflected in the increased optical phonon frequencies and reduced line shape broadening with annealing temperature. For large ion incident angle, the strain relaxation in the irradiated surface region leads to micro-crack formation in the patterned surface and further hardening of the phonon frequencies.

  5. SUCCESSIVE SOLAR FLARES AND CORONAL MASS EJECTIONS ON 2005 SEPTEMBER 13 FROM NOAA AR 10808

    SciTech Connect (OSTI)

    Liu Chang; Wang Haimin; Lee, Jeongwoo; Karlicky, Marian; Choudhary, Debi Prasad; Deng Na E-mail: haimin@flare.njit.ed E-mail: karlicky@asu.cas.c E-mail: na.deng@csun.ed

    2009-09-20

    We present a multiwavelength study of the 2005 September 13 eruption from NOAA AR 10808 that produced total four flares and two fast coronal mass ejections (CMEs) within {approx}1.5 hr. Our primary attention is paid to the fact that these eruptions occurred in close succession in time, and that all of them were located along an S-shaped magnetic polarity inversion line (PIL) of the active region. In our analysis, (1) the disturbance created by the first flare propagated southward along the PIL to cause a major filament eruption that led to the first CME and the associated second flare underneath. (2) The first CME partially removed the overlying magnetic fields over the northern delta spot to allow the third flare and the second CME. (3) The ribbon separation during the fourth flare would indicate reclosing of the overlying field lines opened by the second CME. It is thus concluded that these series of flares and CMEs are interrelated to each other via magnetic reconnections between the expanding magnetic structure and the nearby magnetic fields. These results complement previous works made on this event with the suggested causal relationship among the successive eruptions.

  6. Hyperveolcity impacts on aluminum from 6 to 11 km/s for hydrocode benchmarking.

    SciTech Connect (OSTI)

    Saul, W. Venner; Reinhart, William Dodd; Thornhill, Tom Finley, III; Lawrence, Raymond Jeffery Jr.; Chhabildas, Lalit Chandra; Bessette, Gregory Carl; Kipp, Marlin E.

    2003-04-01

    A systematic computational and experimental study is presented on impact generated debris resulting from record-high impact speeds recently achieved on the Sandia three-stage light-gas gun. In these experiments, a target plate of aluminum is impacted by a titanium-alloy flyer plate at speeds ranging from 6.5 to 11 km/s, producing pressures from 1 Mb to over 2.3 Mb, and temperatures as high as 15000 K (>1 eV). The aluminum plate is totally melted at stresses above 1.6 Mb. Upon release, the thermodynamic release isentropes will interact with the vapor dome. The amount of vapor generated in the debris cloud will depend on many factors such as the thickness of the aluminum plate, super-cooling, vaporization kinetics, the distance, and therefore time, over which the impact-generated debris is allowed to expand. To characterize the debris cloud, the velocity history produced by stagnation of the aluminum expansion products against a witness plate is measured using velocity interferometry. X-ray measurements of the debris cloud are also recorded prior to stagnation against an aluminum witness plate. Both radiographs and witness-plate velocity measurements suggest that the vaporization process is both time-dependent and heterogeneous when the material is released from shocked states around 230 GPa. Experiments suggest that the threshold for vaporization kinetics in aluminum should become significant when expanded from shocked states over 230 GPa. Numerical simulations are conducted to compare the measured x-ray radiographs of the debris cloud and the time-resolved experimental interferometer record with calculational results using the 3-D hydrodynamic wavecode, CTH. Results of these experiments and calculations are discussed in this paper.

  7. Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Effect Cost-Effective Mass Reduction | Department of Energy Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_powell.pdf More Documents & Publications

  8. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan; Bridges, Craig A.; Paranthaman, Mariappan Parans; Dai, Sheng; Brown, Gilbert M.

    2015-10-07

    A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.

  9. Shock-ramp loading of tin and aluminum. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Shock-ramp loading of tin and aluminum. Citation Details In-Document Search Title: Shock-ramp loading of tin and aluminum. Abstract not provided. Authors: Seagle, Christopher T Publication Date: 2013-07-01 OSTI Identifier: 1115231 Report Number(s): SAND2013-5377C 478690 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: SCCM/AIRAPT held July 8-12, 2013 in Seattle, WA.; Related Information: Proposed for presentation at the SCCM/AIRAPT held July 8-12, 2013

  10. Inductively coupled plasmareactive ion etching of c- and a-plane AlGaN over the entire Al composition range: Effect of BCl{sub 3} pretreatment in Cl{sub 2}/Ar plasma chemistry

    SciTech Connect (OSTI)

    Shah, Amit P.; Laskar, Masihhur R.; Azizur Rahman, A.; Gokhale, Maheshwar R.; Bhattacharya, Arnab

    2013-11-15

    Inductively coupled plasma (ICP)reactive ion etching (RIE) patterning is a standard processing step for UV and optical photonic devices based on III-nitride materials. There is little research on ICP-RIE of high Al-content AlGaN alloys and for nonpolar nitride orientations. The authors present a comprehensive study of the ICP-RIE of c- and a-plane AlGaN in Cl{sub 2}/Ar plasma over the entire Al composition range. The authors find that the etch rate decreases in general with increasing Al content, with different behavior for c- and a-plane AlGaN. They also study the effect of BCl{sub 3} deoxidizing plasma pretreatment. An ICP deoxidizing BCl{sub 3} plasma with the addition of argon is more efficient in removal of surface oxides from Al{sub x}Ga{sub 1?x}N than RIE alone. These experiments show that Al{sub x}Ga{sub 1?x}N etching is affected by the higher binding energy of AlN and the higher affinity of oxygen to aluminum compared to gallium, with oxides on a-plane AlGaN more difficult to etch as compared to oxides on c-plane AlGaN, specifically for high Al composition materials. The authors achieve reasonably high etch rate (?350 nm/min) for high Al-content materials with a smooth surface morphology at a low DC bias of ??45 VDC.

  11. THE KINEMATICS AND PLASMA PROPERTIES OF A SOLAR SURGE TRIGGERED BY CHROMOSPHERIC ACTIVITY IN AR11271

    SciTech Connect (OSTI)

    Kayshap, P.; Srivastava, Abhishek K. [Aryabhatta Research Institute of Observational Sciences (ARIES), Manora Peak, Nainital 263 129 (India)] [Aryabhatta Research Institute of Observational Sciences (ARIES), Manora Peak, Nainital 263 129 (India); Murawski, K., E-mail: kmur@kft.umcs.lublin.pl [Group of Astrophysics, UMCS, ul. Radziszewskiego 10, 20-031 Lublin (Poland)

    2013-01-20

    We observe a solar surge in NOAA AR11271 using the Solar Dynamics Observatory (SDO) Atmospheric Imaging Assembly 304 A image data on 2011 August 25. The surge rises vertically from its origin up to a height of Almost-Equal-To 65 Mm with a terminal velocity of Almost-Equal-To 100 km s{sup -1}, and thereafter falls and fades gradually. The total lifetime of the surge was Almost-Equal-To 20 minutes. We also measure the temperature and density distribution of the observed surge during its maximum rise and find an average temperature and a density of 2.0 MK and 4.1 Multiplication-Sign 10{sup 9} cm{sup -3}, respectively. The temperature map shows the expansion and mixing of cool plasma lagging behind the hot coronal plasma along the surge. Because SDO/HMI temporal image data do not show any detectable evidence of significant photospheric magnetic field cancellation for the formation of the observed surge, we infer that it is probably driven by magnetic-reconnection-generated thermal energy in the lower chromosphere. The radiance (and thus the mass density) oscillations near the base of the surge are also evident, which may be the most likely signature of its formation by a reconnection-generated pulse. In support of the present observational baseline of the triggering of the surge due to chromospheric heating, we devise a numerical model with conceivable implementation of the VAL-C atmosphere and a thermal pulse as an initial trigger. We find that the pulse steepens into a slow shock at higher altitudes which triggers plasma perturbations exhibiting the observed features of the surge, e.g., terminal velocity, height, width, lifetime, and heated fine structures near its base.

  12. Proceedings of the Seventh Annual Conference on Fossil Energy Materials. Fossil Energy AR and TD Materials Program

    SciTech Connect (OSTI)

    Cole, N.C.; Judkins, R.R.

    1993-07-01

    Objective of the AR&TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The 37 papers are arranged into 3 sessions: ceramics, new alloys/intermetallics, and new alloys/advanced austenitics. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  13. Rotational and angular distributions of NO products from NO-Rg(Rg = He, Ne, Ar) complex photodissociation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Heather L. Holmes-Ross; Hall, Gregory E.; Valenti, Rebecca J.; Yu, Hua -Gen; Lawrance, Warren D.

    2016-01-29

    In this study, we present the results of an investigation into the rotational and angular distributions of the NO A~ state fragment following photodissociation of the NO-He, NO-Ne and NO-Ar van der Waals complexed excited via the A~ ← X~ transition. For each complex the dissociation is probed for several values of Ea, the available energy above the dissociation threshold.

  14. MANAGEMENT OF RESEARCH AND TEST REACTOR ALUMINUM SPENT NUCLEAR FUEL - A TECHNOLOGY ASSESSMENT

    SciTech Connect (OSTI)

    Vinson, D.

    2010-07-11

    The Department of Energy's Environmental Management (DOE-EM) Program is responsible for the receipt and storage of aluminum research reactor spent nuclear fuel or used fuel until ultimate disposition. Aluminum research reactor used fuel is currently being stored or is anticipated to be returned to the U.S. and stored at DOE-EM storage facilities at the Savannah River Site and the Idaho Nuclear Technology and Engineering Center. This paper assesses the technologies and the options for safe transportation/receipt and interim storage of aluminum research reactor spent fuel and reviews the comprehensive strategy for its management. The U.S. Department of Energy uses the Appendix A, Spent Nuclear Fuel Acceptance Criteria, to identify the physical, chemical, and isotopic characteristics of spent nuclear fuel to be returned to the United States under the Foreign Research Reactor Spent Nuclear Fuel Acceptance Program. The fuel is further evaluated for acceptance through assessments of the fuel at the foreign sites that include corrosion damage and handleability. Transport involves use of commercial shipping casks with defined leakage rates that can provide containment of the fuel, some of which are breached. Options for safe storage include wet storage and dry storage. Both options must fully address potential degradation of the aluminum during the storage period. This paper focuses on the various options for safe transport and storage with respect to technology maturity and application.

  15. SPERT Destructive Test - I on Aluminum, Highly Enriched Plate Type Core

    ScienceCinema (OSTI)

    None

    2014-05-07

    SPERT - Special Power Excursion Reactor Tests Destructive Test number 1 On Aluminum, Highly Enriched Plate Type Core. A test studying the behavior of the reactor under destructive conditions on a light water moderated pool-type reactor with a plate-type core.

  16. Silicon Solar Cells with Front Hetero-Contact and Aluminum Alloy Back Junction: Preprint

    SciTech Connect (OSTI)

    Yuan, H.-C.; Page, M. R.; Iwaniczko, E.; Xu, Y.; Roybal, L.; Wang, Q.; Branz, H. M.; Meier, D. L.

    2008-05-01

    We prototype an alternative n-type monocrystalline silicon (c-Si) solar cell structure that utilizes an n/i-type hydrogenated amorphous silicon (a-Si:H) front hetero-contact and a back p-n junction formed by alloying aluminum (Al) with the n-type Si wafer.

  17. SPERT Destructive Test - I on Aluminum, Highly Enriched Plate Type Core

    SciTech Connect (OSTI)

    2011-04-05

    SPERT - Special Power Excursion Reactor Tests Destructive Test number 1 On Aluminum, Highly Enriched Plate Type Core. A test studying the behavior of the reactor under destructive conditions on a light water moderated pool-type reactor with a plate-type core.

  18. Development of an electronic device quality aluminum antimonide (AlSb) semiconductor for solar cell applications

    DOE Patents [OSTI]

    Sherohman, John W; Yee, Jick Hong; Combs, III, Arthur W

    2014-11-11

    Electronic device quality Aluminum Antimonide (AlSb)-based single crystals produced by controlled atmospheric annealing are utilized in various configurations for solar cell applications. Like that of a GaAs-based solar cell devices, the AlSb-based solar cell devices as disclosed herein provides direct conversion of solar energy to electrical power.

  19. Mechanical Properties of Aluminum Matrix Composite Reinforced by Carbothermally Reduced of Fly Ash

    SciTech Connect (OSTI)

    Jamasri; Wildan, M. W.; Sulardjaka; Kusnanto

    2011-01-17

    The addition of fly ash into aluminum as reinforcement can potentially reduce the production cost and density of aluminum. However, mechanical properties of aluminum matrix composite reinforced by fly ash (MMC ALFA) have some limitations due to the characteristic of fly ash. In this study, a carbothermal reduction process of fly ash and activated carbon powder with particle size <32 {mu}m was performed prior to produce MMC ALFA.The process was carried out in a furnace at 1300 deg. C in vacuum condition under argon flow. Synthesis product was analyzed by XRD with Cu-K{sub {alpha}} radiation. From XRD analysis, it shows that the synthesis process can produce SiC powder. The synthesis product was subsequently used as reinforcement particle. Aluminum powder was mixed with 5, 10 and 15% of the synthesized powder, and then uni-axially compacted at pressure of 300 MPa. The compacted product was sintered for 2 hours in argon atmosphere at temperature variation of 550 and 600 deg. C. Flexural strength, hardness and density of MMC ALFA's product were respectively evaluated using a four point bending test method based on ASTM C1161 standard, Brinell hardness scale and Archimedes method. The result of this study shows that the increase of weight of reinforcement can significantly increase the hardness and flexural strength of MMCs. The highest hardness and flexural strength of the MMC product are 300 kg/mm{sup 2} and 107.5 MPa, respectively.

  20. Ionic Current Mapping Techniques and Applications to Aluminum-Copper Corrosion

    SciTech Connect (OSTI)

    Isaacs, H. S.; Jeffcoate, C. S.; Missert, N. A.; Barbour, J. C.

    1999-10-17

    Measurements have been made of the aluminum/metal galvanic couple. A wide range of geometries were investigated varying the areas of anodic and cathodic surfaces and employing specially designed galvanic cells with crevices. In situ ionic current density mapping was used to monitor galvanic corrosion and currents flowing between separated metals was measured.

  1. Reduced temperature aluminum production in an electrolytic cell having an inert anode

    DOE Patents [OSTI]

    Dawless, Robert K. (Monroeville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA); Kozarek, Robert L. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2000-01-01

    Aluminum is produced by electrolytic reduction of alumina in a cell having a cathode, an inert anode and a molten salt bath containing metal fluorides and alumina. The inert anode preferably contains copper, silver and oxides of iron and nickel. Reducing the molten salt bath temperature to about 900-950.degree. C. lowers corrosion on the inert anode constituents.

  2. Effect of 200 keV Ar{sup +} implantation on optical and electrical properties of polyethyleneterepthalate (PET)

    SciTech Connect (OSTI)

    Kumar, Rajiv Goyal, Meetika Sharma, Ambika; Aggarwal, Sanjeev; Sharma, Annu; Kanjilal, D.

    2015-05-15

    In the present paper we have discussed the effect of 200 keV Ar{sup +} ions on the electrical and optical properties of PET samples. PET samples were implanted with 200 keV Ar{sup +} ions to various doses ranging from 110{sup 15} to 110{sup 17} Ar{sup +} cm{sup 2}. The changes in the electrical and optical properties of pristine and implanted PET specimens have been studied by using Keithley electrometer and UV-Visible absorption spectroscopy. The electrical conductivity has found to be increased with increasing ion dose. The optical studies have revealed the drastic alterations in optical band gap from 3.63 eV to 1.48 eV and also increase in number of carbon atoms per cluster from 215 to 537. Further, the change in the electrical conductivity and optical band gap has also been correlated with the formation of conductive islands in the implanted layers of PET.

  3. Fish scale deformation analysis using scanning electron microscope: New potential biomarker in aquatic environmental monitoring of aluminum and iron contamination

    SciTech Connect (OSTI)

    Hidayati, Dewi; Sulaiman, Norela; Othman, Shuhaimi; Ismail, B. S.

    2013-11-27

    Fish scale has the potential to be a rapid biomarker due to its structure and high possibility to come into contact with any pollutant in the aquatic environment. The scale structure consists of osteoblastic cells and other bone materials such as collagen where it is possible to form a molecular complex with heavy metals such as aluminum and iron. Hence, aluminum and iron in water could possibly destroy the scale material and marked as a scale deformation that quantitatively could be analyzed by comparing it to the normal scale structure. Water sampling and fish cage experiment were performed between June and July 2011 in Porong river which represented the water body that has high aluminum and iron contamination. The filtered water samples were preserved and extracted using the acid-mixture procedure prior to measurement of the aluminum and iron concentrations using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), while samples for total suspended solid (TSS) analysis were kept at 4 C in cool-boxes. The scales were cleaned with sterile water, then dehydrated in 30, 50, 70, and 90% ethanol and dried on filter papers. They were then mounted on an aluminum stub and coated with gold in a sputter coater prior to Scanning Electron Microscope (SEM) observation. According to the SEM analysis, it was found that there were several deformations on the scale samples taken from sites that have high concentrations of aluminum and iron i.e. the increasing number of pits, deformation and decreasing number of spherules and ridges while the control scale exhibited the normal features. However, the site with higher TSS and pH indicated lower aluminum effect. A moderate correlation was found between the number of pits with aluminum (r=0.43) and iron (r=0.41) concentrations. Fish scale deformation using SEM analysis can potentially be a rapid biomarker in aquatic monitoring of aluminum and iron contamination. However, the measurement must be accompanied by pH and TSS observations.

  4. An international land-biosphere model benchmarking activity for the IPCC Fifth Assessment Report (AR5)

    SciTech Connect (OSTI)

    Hoffman, Forrest M [ORNL; Randerson, James T [ORNL; Thornton, Peter E [ORNL; Bonan, Gordon [National Center for Atmospheric Research (NCAR); Erickson III, David J [ORNL; Fung, Inez [University of California, Berkeley

    2009-12-01

    The need to capture important climate feedbacks in general circulation models (GCMs) has resulted in efforts to include atmospheric chemistry and land and ocean biogeochemistry into the next generation of production climate models, called Earth System Models (ESMs). While many terrestrial and ocean carbon models have been coupled to GCMs, recent work has shown that such models can yield a wide range of results (Friedlingstein et al., 2006). This work suggests that a more rigorous set of global offline and partially coupled experiments, along with detailed analyses of processes and comparisons with measurements, are needed. The Carbon-Land Model Intercomparison Project (C-LAMP) was designed to meet this need by providing a simulation protocol and model performance metrics based upon comparisons against best-available satellite- and ground-based measurements (Hoffman et al., 2007). Recently, a similar effort in Europe, called the International Land Model Benchmark (ILAMB) Project, was begun to assess the performance of European land surface models. These two projects will now serve as prototypes for a proposed international land-biosphere model benchmarking activity for those models participating in the IPCC Fifth Assessment Report (AR5). Initially used for model validation for terrestrial biogeochemistry models in the NCAR Community Land Model (CLM), C-LAMP incorporates a simulation protocol for both offline and partially coupled simulations using a prescribed historical trajectory of atmospheric CO2 concentrations. Models are confronted with data through comparisons against AmeriFlux site measurements, MODIS satellite observations, NOAA Globalview flask records, TRANSCOM inversions, and Free Air CO2 Enrichment (FACE) site measurements. Both sets of experiments have been performed using two different terrestrial biogeochemistry modules coupled to the CLM version 3 in the Community Climate System Model version 3 (CCSM3): the CASA model of Fung, et al., and the carbon-nitrogen (CN) model of Thornton. Comparisons of the CLM3 offline results against observational datasets have been performed and are described in Randerson et al. (2009). CLM version 4 has been evaluated using C-LAMP, showing improvement in many of the metrics. Efforts are now underway to initiate a Nitrogen-Land Model Intercomparison Project (N-LAMP) to better constrain the effects of the nitrogen cycle in biosphere models. Presented will be new results from C-LAMP for CLM4, initial N-LAMP developments, and the proposed land-biosphere model benchmarking activity.

  5. Revision of Army regulation (AR) 200-2, environmental effects of Army actions, and the application of total quality mangement (TQM) principles

    SciTech Connect (OSTI)

    Merkel, H,K.; Robitaille, P.

    1995-12-01

    AR 200-2 is the Army`s implementing regulation to the National Environmental Policy Act (NEPA) and DoD`s NEPA Directive DoDD 6050.1. AR 200-2 was last revised in the late 1980s and since then the scope of Army NEPA compliance activities have significantly increased, and NEPA practice and case law are continually changing. The purpose of revising AR 200-2 is to provide Army personel with clear and Concise guidance on how to meet their NEPA compliance requirements. The revision process included reviewing the current AR 200-2 to identify areas and topics needing clarification or modification; conferring with Army NEPA personnel to obtain views on NEPA compliance practices and procedures; conducting a review and analysis of significant, recent developments in NEPA case law; reviewing other federal NEPA implementing regulations to identify useful, transferrable concepts; preparing a {open_quotes}strawman{close_quotes} version of AR 200-2 to use as a starting point in the revision process; coordinating and consolidating input from the AR 200-2 Revisions Steering Committee; and responding to review comments. A draft version of AR 200-2 has been completed and informal Army-wide comments have been addressed. Some of the issues that the AR 200-2 Revisions Steering Committee considered during the revision effort included expanding the list of categorical exclusions, determining the appropriate length for the public comment period for environmental assessments prior to approval of the finding of no significant impact, determining the appropriate level of analysis for Army actions abroad, and determining whether Comprehensive Environmental Response Compensation Liability Act (CERCLA) or Resource Conservation and Recovery Act (RCRA) actions should be addressed under NEPA. Total Quality Management (TQM) principles were applied during the revision process. GroupSystems{trademark} software was used as a vehicle to enhance total group participation from managers to practitioners.

  6. Fluorocarbon assisted atomic layer etching of SiO2 and Si using cyclic Ar/C4F8 and Ar/CHF3 plasma

    SciTech Connect (OSTI)

    Metzler, Dominik; Li, Chen; Engelmann, Sebastian; Bruce, Robert L.; Joseph, Eric A.; Oehrlein, Gottlieb S.

    2015-11-11

    The need for atomic layer etching (ALE) is steadily increasing as smaller critical dimensions and pitches are required in device patterning. A flux-control based cyclic Ar/C4F8 ALE based on steady-state Ar plasma in conjunction with periodic, precise C4F8 injection and synchronized plasma-based low energy Ar+ ion bombardment has been established for SiO2.1 In this work, the cyclic process is further characterized and extended to ALE of silicon under similar process conditions. The use of CHF3 as a precursor is examined and compared to C4F8. CHF3 is shown to enable selective SiO2/Si etching using a fluorocarbon (FC) film build up. Other critical process parameters investigated are the FC film thickness deposited per cycle, the ion energy, and the etch step length. Etching behavior and mechanisms are studied using in situ real time ellipsometry and X-ray photoelectron spectroscopy. Silicon ALE shows less self-limitation than silicon oxide due to higher physical sputtering rates for the maximum ion energies used in this work, ranged from 20 to 30 eV. The surface chemistry is found to contain fluorinated silicon oxide during the etching of silicon. As a result, plasma parameters during ALE are studied using a Langmuir probe and establish the impact of precursor addition on plasma properties.

  7. sup 40 Ar/ sup 39 laser-probe dating by step heating and spot fusion of phengites from the Dora Maira nappe of the western Alps, Italy

    SciTech Connect (OSTI)

    Scaillet, S.; Feraud, G. ); Lagabrielle, Y. ); Ballevre, M.; Ruffet, G. )

    1990-08-01

    {sup 40}Ar/{sup 39}Ar laser-probe dating of phengitic micas has been carried out by step-heating and spot-fusion procedures. These micas represent successive deformation stages in the structural evolution of the internal Dora Maira nappe, western Alps. Single phengites from a gneiss affected by a single ductile strain under retrogressive conditions (sample 99.1) display complete isotopic resetting with nearly homogeneous intracrystalline Ar distribution and yield plateau ages of about 40 Ma. Small clusters of phengites from an earlier foliation were selected from a polydeformed mica schist (sample PTX3). They show a partial isotopic resetting in response to overprinting during the retrogressive deformation stage with a concentric age zoning from 68 Ma on the rim to 87 Ma in the core one cleavage plane. This zonation is fully consistent with the laser-derived discordant age spectrum, which ranges from 40 to 90 Ma from low to high temperatures. According to the deformation history of both samples, these preliminary data suggest a deformation control on Ar migration during recrystallization processes, and they are consistent with the timing of the collisional evolution previously reported for southern Dora Maira units. This study shows that the {sup 40}Ar/{sup 39}Ar continuous laser-probe dating technique produces data accurate enough to discriminate several tectonometamorphic episodes recorded in single hand samples.

  8. Modeling of plasma chemistry in an atmospheric pressure Ar/NH{sub 3} cylindrical dielectric barrier discharge described using the one-dimensional fluid model

    SciTech Connect (OSTI)

    Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physical Science and Technical College, Dalian University, Dalian 116622 (China)

    2013-01-15

    The keynote of our research is to study the gas phase chemistry in an atmospheric pressure Ar/NH{sub 3} cylindrical dielectric barrier discharge, which is very important to produce the iron-nitride magnetic fluid. For this purpose, a home-made one dimensional fluid model with the Scharfetter-Gummel method has been developed. The equations solved are the particle balances, assuming a drift-diffusion approximation for the fluxes, and the electron energy equation. The self-consistent electric field is obtained by the simultaneous solution of Poisson's equation. The simulations were carried out for the different ammonia concentrations (2%, 3.5%, and 7%), at a voltage of 1 kV, and a driving frequency of 20 kHz. It concluded that the major ion products of Ar are Ar{sup +} and Ar{sub 2}{sup +}. Ar{sup +} is the most important positive ions, followed by Ar{sub 2}{sup +}. It is shown that the NH{sup +} density is smaller than that of the other ammonia ions. The density of NH{sub 4}{sup +} is more than that of the other ammonia ions when the ammonia concentration increased. The diffuse mode can be established after the discharge was ignited, and the mode changes to filamentary mode with an increase in ammonia concentration.

  9. Silicon etch using SF{sub 6}/C{sub 4}F{sub 8}/Ar gas mixtures

    SciTech Connect (OSTI)

    Bates, Robert L.; Stephan Thamban, P. L.; Goeckner, Matthew J.; Overzet, Lawrence J.

    2014-07-01

    While plasmas using mixtures of SF{sub 6}, C{sub 4}F{sub 8}, and Ar are widely used in deep silicon etching, very few studies have linked the discharge parameters to etching results. The authors form such linkages in this report. The authors measured the optical emission intensities of lines from Ar, F, S, SF{sub x}, CF{sub 2}, C{sub 2}, C{sub 3}, and CS as a function of the percentage C{sub 4}F{sub 8} in the gas flow, the total gas flow rate, and the bias power. In addition, the ion current density and electron temperature were measured using a floating Langmuir probe. For comparison, trenches were etched of various widths and the trench profiles (etch depth, undercut) were measured. The addition of C{sub 4}F{sub 8} to an SF{sub 6}/Ar plasma acts to reduce the availability of F as well as increase the deposition of passivation film. Sulfur combines with carbon in the plasma efficiently to create a large optical emission of CS and suppress optical emissions from C{sub 2} and C{sub 3}. At low fractional flows of C{sub 4}F{sub 8}, the etch process appears to be controlled by the ion flux more so than by the F density. At large C{sub 4}F{sub 8} fractional flows, the etch process appears to be controlled more by the F density than by the ion flux or deposition rate of passivation film. CF{sub 2} and C{sub 2} do not appear to cause deposition from the plasma, but CS and other carbon containing molecules as well as ions do.

  10. Influence of Fe-doped Graphite Electrode Characteristics on Ar-H2 Carbon Arc Plasma and SWCNT Formation

    SciTech Connect (OSTI)

    Huczko, A.; Lange, H.; Bystrzejewski, M.; Ando, Y.; Zhao, X.; Inoue, S.

    2005-09-27

    Two Fe-doped (ca. 1 at.%) homogeneous graphite electrodes (different graphite microcrystals, degree of graphitization and, thereby, electrical conductivities) electrodes were used in the process of production of single-walled carbon nanotubes in Ar-H2 arc plasma under pressure 26 kPa. The C2 content (namely carbon vapor pressure) and temperature distributions in the arc plasma were determined using optical emission spectroscopy. The mechanism of CNT formation based on carbon dimers as the building blocks seems to be at least questionable.

  11. {sup 39}Ar Detection at the 10{sup -16} Isotopic Abundance Level with Atom Trap Trace Analysis

    SciTech Connect (OSTI)

    Jiang, W.; Williams, W.; Bailey, K.; O'Connor, T. P.; Mueller, P.; Davis, A. M.; Hu, S.-M.; Sun, Y. R.; Lu, Z.-T.; Purtschert, R.; Sturchio, N. C.

    2011-03-11

    Atom trap trace analysis, a laser-based atom counting method, has been applied to analyze atmospheric {sup 39}Ar (half-life=269 yr), a cosmogenic isotope with an isotopic abundance of 8x10{sup -16}. In addition to the superior selectivity demonstrated in this work, the counting rate and efficiency of atom trap trace analysis have been improved by 2 orders of magnitude over prior results. The significant applications of this new analytical capability lie in radioisotope dating of ice and water samples and in the development of dark matter detectors.

  12. Response function of the magnetic spectrometer PRISMA for the multinucleon transfer reaction {sup 40}Ar+{sup 208}Pb

    SciTech Connect (OSTI)

    Mijatovic, T.; Szilner, S.; Corradi, L.; Courtin, S.; Farnea, E.; Fioretto, E.; Gadea, A.; Goasduff, A.; Haas, F.; Jelavic-Malenica, D.; Lunardi, S.; Mengoni, D.; Montagnoli, G.; Montanari, D.; Pollarolo, G.; Recchia, F.; Sahin, E.; Scarlassara, F.; Soic, N.; Stefanini, A. M.; and others

    2012-10-20

    Multinucleon transfer reaction {sup 40}Ar+{sup 208}Pb has been investigated with the PRISMA-CLARA experimental setup in LNL, INFN, Italy. The experimental differential cross sections have been obtained for different transfer channels by measuring more than {Delta}{theta}{sub lab} = 20 Degree-Sign covered by three angular settings of PRISMA. Results have been compared with the semiclassical calculation GRAZING. Since the understanding of the reaction mechanism depends strongly on the determination of absolute cross section, effect of transport of ions through PRISMA has been studied via a Monte Carlo simulation code.

  13. Iron-aluminum alloys having high room-temperature and method for making same

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); McKamey, Claudette G. (Knoxville, TN)

    1993-01-01

    Iron-aluminum alloys having selectable room-temperature ductilities of greater than 20%, high resistance to oxidation and sulfidation, resistant pitting and corrosion in aqueous solutions, and possessing relatively high yield and ultimate tensile strengths are described. These alloys comprise 8 to 9.5% aluminum, up to 7% chromium, up to 4% molybdenum, up to 0.05% carbon, up to 0.5% of a carbide former such as zirconium, up to 0.1 yttrium, and the balance iron. These alloys in wrought form are annealed at a selected temperature in the range of 700.degree. C. to about 1100.degree. C. for providing the alloys with selected room-temperature ductilities in the range of 20 to about 29%.

  14. Cu--Ni--Fe anode for use in aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.; Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2006-07-18

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900.degree. C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable Cu--Ni--Fe anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.

  15. CHARACTERIZATION OF TANK 11H AND TANK 51H POST ALUMINUM DISSOLUTION PROCESS SAMPLES

    SciTech Connect (OSTI)

    Hay, M; Daniel McCabe, D

    2008-05-16

    A dip sample of the liquid phase from Tank 11H and a 3-L slurry sample from Tank 51H were obtained and sent to Savannah River National Laboratory for characterization. These samples provide data to verify the amount of aluminum dissolved from the sludge as a result of the low temperature aluminum dissolution process conducted in Tank 51H. The characterization results for the as-received Tank 11H and Tank 51H supernate samples and the total dried solids of the Tank 51H sludge slurry sample appear quite good with respect to the precision of the sample replicates and minimal contamination present in the blank. The two supernate samples show similar concentrations for the major components as expected.

  16. Method for processing aluminum spent potliner in a graphite electrode ARC furnace

    DOE Patents [OSTI]

    O'Connor, William K. (Lebanon, OR); Turner, Paul C. (Independence, OR); Addison, Gerald W. (St. Stephen, SC)

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

  17. Method for processing aluminum spent potliner in a graphite electrode arc furnace

    DOE Patents [OSTI]

    O'Connor, William K.; Turner, Paul C.; Addison, G.W. (AJT Enterprises, Inc.)

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spend aluminum pot liner is crushed, iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine, and CO.

  18. Colloidal infrared reflective and transparent conductive aluminum-doped zinc oxide nanocrystals

    DOE Patents [OSTI]

    Buonsanti, Raffaella; Milliron, Delia J

    2015-02-24

    The present invention provides a method of preparing aluminum-doped zinc oxide (AZO) nanocrystals. In an exemplary embodiment, the method includes (1) injecting a precursor mixture of a zinc precursor, an aluminum precursor, an amine, and a fatty acid in a solution of a vicinal diol in a non-coordinating solvent, thereby resulting in a reaction mixture, (2) precipitating the nanocrystals from the reaction mixture, thereby resulting in a final precipitate, and (3) dissolving the final precipitate in an apolar solvent. The present invention also provides a dispersion. In an exemplary embodiment, the dispersion includes (1) nanocrystals that are well separated from each other, where the nanocrystals are coated with surfactants and (2) an apolar solvent where the nanocrystals are suspended in the apolar solvent. The present invention also provides a film. In an exemplary embodiment, the film includes (1) a substrate and (2) nanocrystals that are evenly distributed on the substrate.

  19. Iron-aluminum alloys having high room-temperature and method for making same

    DOE Patents [OSTI]

    Sikka, V.K.; McKamey, C.G.

    1993-08-24

    A wrought and annealed iron-aluminum alloy is described consisting essentially of 8 to 9.5% aluminum, an effective amount of chromium sufficient to promote resistance to aqueous corrosion of the alloy, and an alloying constituent selected from the group of elements consisting of an effective amount of molybdenum sufficient to promote solution hardening of the alloy and resistance of the alloy to pitting when exposed to solutions containing chloride, up to about 0.05% carbon with up to about 0.5% of a carbide former which combines with the carbon to form carbides for controlling grain growth at elevated temperatures, and mixtures thereof, and the balance iron, wherein said alloy has a single disordered [alpha] phase crystal structure, is substantially non-susceptible to hydrogen embrittlement, and has a room-temperature ductility of greater than 20%.

  20. Boron-carbide-aluminum and boron-carbide-reactive metal cermets

    DOE Patents [OSTI]

    Halverson, Danny C. (Manteca, CA); Pyzik, Aleksander J. (Seattle, WA); Aksay, Ilhan A. (Seattle, WA)

    1986-01-01

    Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

  1. Target designs for Accelerator Production of Tritium (APT) utilizing lithium-aluminum

    SciTech Connect (OSTI)

    Todosow, M.; Van Tuyle, G.J.

    1996-03-01

    A number of accelerator-driven spallation neutron-source target/blanket systems have been developed for production of tritium under the APT Program. The two systems described in this paper employ a proton linear accelerator, and a target which contains a heavy-metal(s) for the production of neutrons via spallation, and solid lithium-aluminum for the production of tritium via neutron capture. lie lithium-aluminum technology is based on that employed at Savannah River for tritium production since the 1950`s. In the APT concept tritium is produced without the presence of fissionable materials; therefore, no high-level waste is produced, and the ES&H concerns are significantly reduced compared to reactor systems.

  2. Energy conservation in the primary aluminum and chlor-alkali industries

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The primary aluminum and chlor-alkali industries together use nearly 13% of the electrical energy consumed by US industry. As part of its mission to promote energy conservation in basic US industries, the DOE surveys the present technological status of the major electrochemical industries and evaluates promising technological innovations that may lead to reduced energy requirements. This study provides technical and economic analyses in support of a government program of research and development in advanced electrolytic technology. This program is intended to supplement the development efforts directed toward energy savings by private industry. Sections II and III of this report cover aluminum and chlorine production processes only, since these two industries represent over 90% of the electrical energy requirements of all electrolytic industries in the United States. Section IV examines barriers to accelerated research and development by the electrolytic industries, and makes suggestions for government actions to overcome these barriers.

  3. Refining of solid ferrous scrap intermingled with copper by using molten aluminum

    SciTech Connect (OSTI)

    Iwase, M.

    1996-12-31

    A new approach for the removal of copper from solid ferrous scrap has been proposed by the present authors. With this process, solid ferrous scrap intermingled with pure copper is brought into contact with molten aluminum, which dissolved copper preferentially, and is recovered as {l_brace}Al + Cu{r_brace} alloys. After a duration of 30 minutes at temperatures between 963 K and 1,223 K, steel scrap is removed from the bath, resulting in being free of copper contamination.

  4. Quench-age method for the fabrication of niobium-aluminum superconductors

    DOE Patents [OSTI]

    Pickus, Milton R. (Oakland, CA); Ciardella, Robert L. (Cardiff, CA)

    1978-01-01

    A flexible Nb.sub.3 Al superconducting wire is fabricated from a niobium-aluminum composite wire by heating to form a solid solution which is retained at room temperature as a metastable solid solution by quenching. The metastable solid solution is then transformed to the stable superconducting A-15 phase by low temperature aging. The transformation induced by aging can be controlled to yield either a multifilamentary or a solid A-15 core surrounded by ductile niobium.

  5. THE APPARENT SOLUBILITY OF ALUMINUM(III) IN HANFORD HIGH-LEVEL WASTE TANKS

    SciTech Connect (OSTI)

    REYNOLDS JG

    2012-06-20

    The solubility of aluminum in Hanford nuclear waste impacts on the process ability of the waste by a number of proposed treatment options. For many years, Hanford staff has anecdotally noted that aluminum appears to be considerably more soluble in Hanford waste than the simpler electrolyte solutions used as analogues. There has been minimal scientific study to confirm these anecdotal observations, however. The present study determines the apparent solubility product for gibbsite in 50 tank samples. The ratio of hydroxide to aluminum in the liquid phase for the samples is calculated and plotted as a function of total sodium molarity. Total sodium molarity is used as a surrogate for ionic strength, because the relative ratios of mono, di and trivalent anions are not available for all of the samples. These results were compared to the simple NaOH-NaAl(OH{sub 4})H{sub 2}O system, and the NaOH-NaAl(OH{sub 4})NaCl-H{sub 2}O system data retrieved from the literature. The results show that gibbsite is apparently more soluble in the samples than in the simple systems whenever the sodium molarity is greater than two. This apparent enhanced solubility cannot be explained solely by differences in ionic strength. The change in solubility with ionic strength in simple systems is small compared to the difference between aluminum solubility in Hanford waste and the simple systems. The reason for the apparent enhanced solubility is unknown, but could include. kinetic or thermodynamic factors that are not present in the simple electrolyte systems. Any kinetic explanation would have to explain why the samples are always supersaturated whenever the sodium molarity is above two. Real waste characterization data should not be used to validate thermodynamic solubility models until it can be confirmed that the apparent enhanced gibbsite solubility is a thermodynamic effect and not a kinetic effect.

  6. Maintaining molten salt electrolyte concentration in aluminum-producing electrolytic cell

    DOE Patents [OSTI]

    Barnett, Robert J.; Mezner, Michael B.; Bradford, Donald R

    2005-01-04

    A method of maintaining molten salt concentration in a low temperature electrolytic cell used for production of aluminum from alumina dissolved in a molten salt electrolyte contained in a cell free of frozen crust wherein volatile material is vented from the cell and contacted and captured on alumina being added to the cell. The captured volatile material is returned with alumina to cell to maintain the concentration of the molten salt.

  7. Experimental investigations of electron density and ion energy distributions in dual-frequency capacitively coupled plasmas for Ar/CF{sub 4} and Ar/O{sub 2}/CF{sub 4} discharges

    SciTech Connect (OSTI)

    Liu, Jia; Liu, Yong-Xin; Gao, Fei; Wang, You-Nian, E-mail: ynwang@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Bi, Zhen-Hua [School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600 (China)

    2014-01-07

    The electron density and ion energy distribution (IED) are investigated in low-pressure dual-frequency capacitively coupled Ar/CF{sub 4} (90%/10%) and Ar/O{sub 2}/CF{sub 4} (80%/10%/10%) plasmas. The relations between controllable parameters, such as high-frequency (HF) power, low-frequency (LF) power and gas pressure, and plasma parameters, such as electron density and IEDs, are studied in detail by utilizing a floating hairpin probe and an energy resolved quadrupole mass spectrometer, respectively. In our experiment, the electron density is mainly determined by the HF power and slightly influenced by the LF power. With increasing gas pressure, the electron density first goes up rapidly to a maximum value and then decreases at various HF and LF powers. The HF power also plays a considerable role in affecting the IEDs under certain conditions and the ion energy independently controlled by the LF source is discussed here. For clarity, some numerical results obtained from a two-dimensional fluid model are presented.

  8. Time-dependent quantum wave packet study of the Ar+H{sub 2}{sup +}{yields}ArH{sup +}+H reaction on a new ab initio potential energy surface for the ground electronic state (1{sup 2}A Prime )

    SciTech Connect (OSTI)

    Hu Mei; Liu Xinguo; Tan Ruishan; Li Hongzheng; Xu Wenwu

    2013-05-07

    A new global potential energy surface for the ground electronic state (1{sup 2}A Prime ) of the Ar+H{sub 2}{sup +}{yields}ArH{sup +}+H reaction has been constructed by multi-reference configuration interaction method with Davidson correction and a basis set of aug-cc-pVQZ. Using 6080 ab initio single-point energies of all the regions for the dynamics, a many-body expansion function form has been used to fit these points. The quantum reactive scattering dynamics calculations taking into account the Coriolis coupling (CC) were carried out on the new potential energy surface over a range of collision energies (0.03-1.0 eV). The reaction probabilities and integral cross sections for the title reaction were calculated. The significance of including the CC quantum scattering calculation has been revealed by the comparison between the CC and the centrifugal sudden approximation calculation. The calculated cross section is in agreement with the experimental result at collision energy 1.0 eV.

  9. An investigation of aluminum titanate-spinel composites behavior in radiation

    SciTech Connect (OSTI)

    Cevikbas, G.; Tugrul, A. B.; Boyraz, T.; Buyuk, B.; Onen, U.

    2015-03-30

    In the present work, the radiation attenuation properties of Aluminum titanate (Al{sub 2}TiO{sub 5})-Spinel (MgAl{sub 2}O{sub 4}) ceramics composites were investigated. Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics composites which have different Al{sub 2}TiO{sub 5} percentages (0%, 5% and 10%) were produced and performed against gamma sources. Cs-137 and Co-60 were used as gamma radiation sources. Transmission technique was used in the experiments. The linear and mass attenuation coefficients of the samples were carried out for gamma radiation sources. The experimental results were compared with the theoretical mass attenuation coefficients which were calculated by using XCOM computer code. Increasing Al{sub 2}TiO{sub 5} percentage in the Aluminum titanate/ Spinel ceramics composites causes the higher linear and mass attenuation coefficients of the composites against Cs-137 and Co-60 gamma radioisotopes. Therefore Also theoretical mass attenuation coefficients are compatible with the experimental results. In conclusion, increasing the Aluminum titanate ratio in the Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics composites increases the gamma shielding property of the Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics for nuclear shielding applications.

  10. Chloride-free processing of aluminum scrap to recover by-product materials

    SciTech Connect (OSTI)

    Riley, W.D.; Jong, B.W.

    1995-12-31

    The US Bureau of Mines has developed technology to recover by-product materials from aluminum scrap using engineered scavenger compounds (ESC). ESCs are structural oxides with a channel or tunnel structure that allows them to hold ions of a specific sizes and charges. The scavenging reaction is easily reversible allowing the ESC to be recharged for continued use and the ion is recovered as an electrodeposit. Key features of this novel technology are: (a) ESC systems are designed to have a high degree of selectivity for a desired ionic species. (b) The recovered material requires little or no additional reprocessing prior to reuse. Two current uses for the ESC technology that are described in this paper are the removal and recycle of lithium (Li) from lithium aluminum (Li-Al) alloys; and, using ESCs as a replacement for the conventional demaging (magnesium removal) technology used by the secondary casting industry. Research indicates that the ESC technology proposed for both these applications has either distinct economic and/or environmental advantages over previously employed methods of recovering metal values from aluminum scrap.

  11. A hot-cracking mitigation technique for welding high-strength aluminum alloy

    SciTech Connect (OSTI)

    Yang, Y.P.; Dong, P.; Zhang, J.; Tian, X.

    2000-01-01

    A hot-cracking mitigation technique for gas tungsten arc welding (GTAW) of high-strength aluminum alloy 2024 is presented. The proposed welding technique incorporates a trailing heat sink (an intense cooling source) with respect to the welding torch. The development of the mitigation technique was based on both detailed welding process simulation using advanced finite element techniques and systematic laboratory experiments. The finite element methods were used to investigate the detailed thermomechanical behavior of the weld metal that undergoes the brittle temperature range (BTR) during welding. As expected, a tensile deformation zone within the material BTR region was identified behind the weld pool under conventional GTA welding process conventional GTA welding process conditions for the aluminum alloy studied. To mitigate hot cracking, the tensile zone behind the weld pool must be eliminated or reduce to a satisfactory level if the weld metal hot ductility cannot be further improved. With detailed computational modeling, it was found that by the introduction of a trailing heat sink at some distance behind the welding arc, the tensile strain rate with respect to temperature in the zone encompassing the BTR region can be significantly reduced. A series of parametric studies were also conducted to derive optimal process parameters for the trailing heat sink. The experimental results confirmed the effectiveness of the trailing heat sink technique. With a proper implementation of the trailing heat sink method, hot cracking can be completely eliminated in welding aluminum alloy 2024 (AA 2024).

  12. Radioactive air emissions notice of construction use of a portable exhauster at 244-AR vault. Revision 2

    SciTech Connect (OSTI)

    Carrell, D.J.

    1997-12-17

    This document serves as a notice of construction (NOC), pursuant to the requirements of Washington Administrative Code (WAC) 246-247-060, and as a request for approval to construct, pursuant to 40 Code of Federal Regulations (CFR) 61.96, a portable exhauster at the 244-AR Vault. The exhauster would be used during air jetting of accumulated liquids from the cell sumps into the tanks and to make transfers among the tanks within the vault when needed. The 244-AR Vault is considered to be a double-contained receiver tank (OCRT) based on its functional characteristics, although it is not listed as one of the five designated DCRTs in the 200 Area Tank Farm systems. Process operations at the vault have been inactive since 1978 and the vault`s two stacks have not operated since 1993. Since cessation of vault operations an extremely large amount of rain water and snow melt have accumulated in the cell sumps. The water level in the sumps is substantially above their respective operating levels and there is concern for leakage to the environment through containment failure due to corrosion from backed-up sump liquid. Active ventilation is required to provide contamination control during air jetting operations within the vault. It has been determined that it would not be cost effective to repair the existing exhaust systems to an operational condition; thus, a portable exhauster will be used to support the intermittent operations.

  13. Proceedings of the sixth annual conference on fossil energy materials. Fossil Energy AR and TD Mateials Program

    SciTech Connect (OSTI)

    Cole, N.C.; Judkins, R.R.

    1992-07-01

    The Sixth Annual Conference on Fossil Energy Materials was held in Oak Ridge, Tennessee, on May 12--14, 1992. The meeting was sponsored by the US Department of Energy`s Office of Fossil Energy through the Advanced Research and Technology Development (AR&TD) Materials Program, and ASM International. The objective of the AR&TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The management of the Program has been decentralized to the DOE Field Office, Oak Ridge with Oak Ridge National Laboratory (ORNL) as the technical support contractor. The research is performed by staff members at ORNL and by a substantial number of researchers at other national laboratories, universities, and in private industry. The work is divided into the following categories: (1) ceramics, (2) development and corrosion resistance of iron aluminide, advanced austenitic and chromium-niobium alloys, and (3) technology assessment and technology transfer. This conference is held each year to review the work on all of the projects of the Program. The agenda for the meeting is given in Appendix A, and a list of attendees is presented in Appendix B. ASM International cosponsored the conference, for which we are especially grateful.

  14. Preliminary study of the electrolysis of aluminum sulfide in molten salts

    SciTech Connect (OSTI)

    Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

    1983-02-01

    A preliminary laboratory-scale study of the electrolysis of aluminum sulfide in molten salts investigated the (1) solubility of Al/sub 2/S/sub 3/ in molten salts, (2) electrochemical behavior of Al/sub 2/S/sub 3/, and (3) electrolysis of Al/sub 2/S/sub 3/ with the determination of current efficiency as a function of current density. The solubility measurements show that MgCl/sub 2/-NaCl-KCl eutectic electrolyte at 1023 K can dissolve up to 3.3 mol % sulfide. The molar ratio of sulfur to aluminum in the eutectic is about one, which suggests that some sulfur remains undissolved, probably in the form of MgS. The experimental data and thermodynamic calculations suggest that Al/sub 2/S/sub 3/ dissolves in the eutectic to form AlS/sup +/ species in solution. Addition of AlCl/sub 3/ to the eutectic enhances the solubility of Al/sub 2/S/sub 3/; the solubility increases with increasing AlCl/sub 3/ concentration. The electrode reaction mechanism for the electrolysis of Al/sub 2/S/sub 3/ was elucidated by using linear sweep voltammetry. The cathodic reduction of aluminum-ion-containing species to aluminum proceeds by a reversible, diffusion-controlled, three-electron reaction. The anodic reaction involves the two-electron discharge of sulfide-ion-containing species, followed by the fast dimerization of sulfur atoms to S/sub 2/. Electrolysis experiments show that Al/sub 2/S/sub 3/ dissolved in molten MgCl/sub 2/-NaCl-KCl eutectic or in eutectic containing AlCl/sub 3/ can be electrolyzed to produce aluminum and sulfur. In the eutectic at 1023 K, the electrolysis can be conducted up to about 300 mA/cm/sup 2/ for the saturation solubility of Al/sub 2/S/sub 3/. Although these preliminary results are promising, additional studies are needed to elucidate many critical operating parameters before the technical potential of the electrolysis can be accurately assessed. 20 figures, 18 tables.

  15. Metallic Reinforcement of Direct Squeeze Die Casting Aluminum Alloys for Improved Strength and Fracture Resistance

    SciTech Connect (OSTI)

    D. Schwam: J.F. Wallace: Y. Zhu: J.W. Ki

    2004-10-01

    The utilization of aluminum die casting as enclosures where internal equipment is rotating inside of the casting and could fracture requires a strong housing to restrain the fractured parts. A typical example would be a supercharger. In case of a failure, unless adequately contained, fractured parts could injure people operating the equipment. A number of potential reinforcement materials were investigated. The initial work was conducted in sand molds to create experimental conditions that promote prolonged contact of the reinforcing material with molten aluminum. Bonding of Aluminum bronze, Cast iron, and Ni-resist inserts with various electroplated coatings and surface treatments were analyzed. Also toughening of A354 aluminum cast alloy by steel and stainless steel wire mesh with various conditions was analyzed. A practical approach to reinforcement of die cast aluminum components is to use a reinforcing steel preform. Such performs can be fabricated from steel wire mesh or perforated metal sheet by stamping or deep drawing. A hemispherical, dome shaped casting was selected in this investigation. A deep drawing die was used to fabricate the reinforcing performs. The tendency of aluminum cast enclosures to fracture could be significantly reduced by installing a wire mesh of austenitic stainless steel or a punched austenitic stainless steel sheet within the casting. The use of reinforcements made of austenitic stainless steel wire mesh or punched austenitic stainless steel sheet provided marked improvement in reducing the fragmentation of the casting. The best strengthening was obtained with austenitic stainless steel wire and with a punched stainless steel sheet without annealing this material. Somewhat lower results were obtained with the annealed punched stainless steel sheet. When the annealed 1020 steel wire mesh was used, the results were only slightly improved because of the lower mechanical properties of this unalloyed steel. The lowest results were obtained with unreinforced 356 aluminum casting. Good strength can be obtained with a sound die casting without any defects produced by squeeze casting. The use of higher pressure to produce the squeeze casting has been shown to increase the strength of a hemispherical dome casting. This dome shape casting has been produced both with and without reinforcement and tested to determine its pressure resistance under internal pressure of water. Only a slight improvement in strength could be determined because of water leaks at the seal between hemispherical dome and its flat supporting side. However, when the ability of the casting was tested under the compressive force of a plunger, the strengthening effect of wire mesh or sheet was evident. Higher loads to failure were obtained because of the reinforcement of the stainless steel wire and punched sheet. Rather than a sudden failure occurring, the reinforcement of the stainless steel wire or the punched hard stainless steel sheet held the material together and prevented any loss of the fractured casting to the surroundings. Unalloyed steel did not have the required strength or mechanical properties to increase the properties of the casting.

  16. REPORT ON QUALITATIVE VALIDATION EXPERIMENTS USING LITHIUM-ALUMINUM LAYERED DOUBLE-HYDROXIDES FOR THE REDUCTION OF ALUMINUM FROM THE WASTE TREATMENT PLANT FEEDSTOCK

    SciTech Connect (OSTI)

    HUBER HJ; DUNCAN JB; COOKE GA

    2010-05-11

    A process for removing aluminum from tank waste simulants by adding lithium and precipitating Li-Al-dihydroxide (Lithiumhydrotalcite, [LiAl{sub 2}(OH){sub 6}]{sup +}X{sup -}) has been verified. The tests involved a double-shell tank (DST) simulant and a single-shell tank (SST) simulant. In the case of the DST simulant, the product was the anticipated Li-hydrotalcite. For the SST simulant, the product formed was primarily Li-phosphate. However, adding excess Li to the solution did result in the formation of traces of Li-hydrotalcite. The Li-hydrotalcite from the DST supernate was an easily filterable solid. After four water washes the filter cake was a fluffy white material made of < 100 {micro}m particles made of smaller spheres. These spheres are agglomerates of {approx} 5 {micro}m diameter platelets with < 1 {micro}m thickness. Chemical and mineralogical analyses of the filtrate, filter cake, and wash waters indicate a removal of 90+ wt% of the dissolved Al for the DST simulant. For the SST simulant, the main competing reaction to the formation of lithium hydrotalcite appears to be the formation of lithium phosphate. In case of the DST simulant, phosphorus co-precipitated with the hydrotalcite. This would imply the added benefit of the removal of phosphorus along with aluminum in the pre-treatment part of the waste treatment and immobilization plant (WTP). For this endeavor to be successful, a serious effort toward process parameter optimization is necessary. Among the major issues to be addressed are the dependency of the reaction yield on the solution chemistry, as well as residence times, temperatures, and an understanding of particle growth.

  17. Fourier-transform microwave spectroscopy and determination of the three dimensional potential energy surface for ArCS

    SciTech Connect (OSTI)

    Niida, Chisato; Nakajima, Masakazu; Endo, Yasuki; Sumiyoshi, Yoshihiro; Ohshima, Yasuhiro; Kohguchi, Hiroshi

    2014-03-14

    Pure rotational transitions of the ArCS van der Waals complex have been observed by Fourier Transform Microwave (FTMW) and FTMW-millimeter wave double resonance spectroscopy. Rotational transitions of v{sub s} = 0, 1, and 2 were able to be observed for normal CS, together with those of C{sup 34}S in v{sub s} = 0, where v{sub s} stands for the quantum number of the CS stretching vibration. The observed transition frequencies were analyzed by a free rotor model Hamiltonian, where rovibrational energies were calculated as dynamical motions of the three nuclei on a three-dimensional potential energy surface, expressed by analytical functions with 57 parameters. Initial values for the potential parameters were obtained by high-level ab initio calculations. Fifteen parameters were adjusted among the 57 parameters to reproduce all the observed transition frequencies with the standard deviation of the fit to be 0.028 MHz.

  18. (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2001-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interefere in the ethylene polymerization process, while affecting the the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  19. SLUDGE HEEL REMOVAL BY ALUMINUM DISSOLUTION AT SAVANNAH RIVER SITE 12390

    SciTech Connect (OSTI)

    Keefer, M.

    2012-01-12

    High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. Operations are underway to remove and disposition the waste, clean the tanks and fill with grout for permanent closure. Heel removal is the intermediate phase of the waste retrieval and tank cleaning process at SRS, which is intended to reduce the volume of waste prior to treatment with oxalic acid. The goal of heel removal is to reduce the residual amount of radioactive sludge wastes to less than 37,900 liters (10,000 gallons) of wet solids. Reducing the quantity of residual waste solids in the tank prior to acid cleaning reduces the amount of acid required and reduces the amount of excess acid that could impact ongoing waste management processes. Mechanical heel removal campaigns in Tank 12 have relied solely on the use of mixing pumps that have not been effective at reducing the volume of remaining solids. The remaining waste in Tank 12 is known to have a high aluminum concentration. Aluminum dissolution by caustic leaching was identified as a treatment step to reduce the volume of remaining solids and prepare the tank for acid cleaning. Dissolution was performed in Tank 12 over a two month period in July and August, 2011. Sample results indicated that 16,440 kg of aluminum oxide (boehmite) had been dissolved representing 60% of the starting inventory. The evolution resulted in reducing the sludge solids volume by 22,300 liters (5900 gallons), preparing the tank for chemical cleaning with oxalic acid.

  20. Steel and Aluminum Energy Conservation and Technology Competitiveness Act of 1988. Fiscal year 1993 annual report

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Steel and Aluminum Energy Conservation and Technology Competitiveness Act of 1988 (Act), commonly referred to as the Metals Initiative, was signed into law on November 17, 1988 (Public Law 100-680). The Act, 15 U.S.C. 5101 et seq., has tile following purposes: (1) to {open_quotes}increase the energy efficiency and enhance the competitiveness of American steel, aluminum, and copper industries{close_quotes}; and (2) to continue the research and development efforts begun under the Department of Energy (DOE) program known as the Steel Initiative. Section 8 of tile Act requires the Secretary of Energy to prepare an annual report to Congress describing the activities carried out under the Act during each fiscal year. 15 U.S.C. 5107 In addition, with respect to reports on fiscal years 1993, 1995, and 1997, Section 8 requires a complete summary of activities under the management plan and research plan from inception with an analysis of extent of their success in accomplishing the purposes of the Act. Id. The Metals Initiative is currently supporting six steel industry research and development projects: (1) Superplastic Steel Processing with Lawrence Livermore National Laboratory; (2) Direct Steelmaking with the American Iron and Steel Institute; (3) Electrochemical Dezincing of Steel Scrap with Argonne National Laboratory and Metal Recovery Industries (U.S.), Inc.; (4) Rapid Analysis of Molten Metals Using Laser Produced Plasmas with Lehigh University; (5) Direct Strip Casting using a single wheel caster with Armco, Inc.; and (6) Advanced Process Control, also with the American Iron and Steel Institute. At the close of the fiscal year, a seventh project, Waste Oxide Recycling with the American Iron and Steel Institute, was selected for inclusion in the Direct Steelmaking project. There are three projects with the aluminum industry. The first, Wettable Cathodes for Alumina Reduction Cells with the Reynolds Metals Company, continues from the prior periods.

  1. Life Cycle Energy and Environmental Assessment of Aluminum-Intensive Vehicle Design

    SciTech Connect (OSTI)

    Das, Sujit

    2014-01-01

    Advanced lightweight materials are increasingly being incorporated into new vehicle designs by automakers to enhance performance and assist in complying with increasing requirements of corporate average fuel economy standards. To assess the primary energy and carbon dioxide equivalent (CO2e) implications of vehicle designs utilizing these materials, this study examines the potential life cycle impacts of two lightweight material alternative vehicle designs, i.e., steel and aluminum of a typical passenger vehicle operated today in North America. LCA for three common alternative lightweight vehicle designs are evaluated: current production ( Baseline ), an advanced high strength steel and aluminum design ( LWSV ), and an aluminum-intensive design (AIV). This study focuses on body-in-white and closures since these are the largest automotive systems by weight accounting for approximately 40% of total curb weight of a typical passenger vehicle. Secondary mass savings resulting from body lightweighting are considered for the vehicles engine, driveline and suspension. A cradle-to-cradle life cycle assessment (LCA) was conducted for these three vehicle material alternatives. LCA methodology for this study included material production, mill semi-fabrication, vehicle use phase operation, and end-of-life recycling. This study followed international standards ISO 14040:2006 [1] and ISO 14044:2006 [2], consistent with the automotive LCA guidance document currently being developed [3]. Vehicle use phase mass reduction was found to account for over 90% of total vehicle life cycle energy and CO2e emissions. The AIV design achieved mass reduction of 25% (versus baseline) resulting in reductions in total life cycle primary energy consumption by 20% and CO2e emissions by 17%. Overall, the AIV design showed the best breakeven vehicle mileage from both primary energy consumption and climate change perspectives.

  2. Precipitation and Deposition of Aluminum-Containing Phases in Tank Wastes

    SciTech Connect (OSTI)

    Dabbs, Daniel M.; Aksay, I.A.

    2005-12-01

    In the first phase of our study, we focused on the use of simple organics to raise the solubility of aluminum oxyhydroxides in high alkaline aqueous solvents. In a limited survey of common organic acids, we determined that citric acid had the highest potential to achieve our goal. However, our subsequent investigation revealed that the citric acid appeared to play two roles in the solutions: first, raising the concentration of aluminum in highly alkaline solutions by breaking up or inhibiting ''seed'' polycations and thereby delaying the nucleation and growth of particles; and second, stabilizing nanometer-sized particles in suspension when nucleation did occur. The results of this work were recently published in Langmuir: D.M. Dabbs, U. Ramachandran, S. Lu, J. Liu, L.-Q. Wang, I.A. Aksay, ''Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid'' Langmuir, 21, 11690-11695 (2005). The second phase of our work involved the solvation of silicon, again in solutions of high alkalinity. Citric acid, due to its unfavorable pKa values, was not expected to be useful with silicon-containing solutions. Here, the use of polyols was determined to be effective in maintaining silicon-containing particles under high pH conditions but at smaller size with respect to standard suspensions of silicon-containing particles. There were a number of difficulties working with highly alkaline silicon-containing solutions, particularly in solutions at or near the saturation limit. Small deviations in pH resulted in particle formation or dissolution in the absence of the organic agents. One of the more significant observations was that the polyols appeared to stabilize small particles of silicon oxyhydroxides across a wider range of pH, albeit this was difficult to quantify due to the instability of the solutions.

  3. Mathematical simulation of the amplification of 1790-nm laser radiation in a nuclear-excited He Ar plasma containing nanoclusters of uranium compounds

    SciTech Connect (OSTI)

    Kosarev, V A; Kuznetsova, E E

    2014-02-28

    The possibility of applying dusty active media in nuclearpumped lasers has been considered. The amplification of 1790-nm radiation in a nuclear-excited dusty He Ar plasma is studied by mathematical simulation. The influence of nanoclusters on the component composition of the medium and the kinetics of the processes occurring in it is analysed using a specially developed kinetic model, including 72 components and more than 400 reactions. An analysis of the results indicates that amplification can in principle be implemented in an active laser He Ar medium containing 10-nm nanoclusters of metallic uranium and uranium dioxide. (lasers)

  4. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  5. Measurement of quasiparticle transport in aluminum films using tungsten transition-edge sensors

    SciTech Connect (OSTI)

    Yen, J. J. Shank, B.; Cabrera, B.; Moffatt, R.; Redl, P.; Young, B. A.; Tortorici, E. C.; Brink, P. L.; Cherry, M.; Tomada, A.; Kreikebaum, J. M.

    2014-10-20

    We report on experimental studies of phonon sensors which utilize quasiparticle diffusion in thin aluminum films connected to tungsten transition-edge-sensors (TESs) operated at 35 mK. We show that basic TES physics and a simple physical model of the overlap region between the W and Al films in our devices enables us to accurately reproduce the experimentally observed pulse shapes from x-rays absorbed in the Al films. We further estimate quasiparticle loss in Al films using a simple diffusion equation approach. These studies allow the design of phonon sensors with improved performance.

  6. Manganese-Aluminum-Based Magnets: Nanocrystalline t-MnAI Permanent Magnets

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: Dartmouth is developing specialized alloys with magnetic properties superior to the rare earths used in todays best magnets. EVs and renewable power generators typically use rare earths to turn the axles in their electric motors due to the magnetic strength of these minerals. However, rare earths are difficult and expensive to refine. Dartmouth will swap rare earths for a manganese-aluminum alloy that could demonstrate better performance and cost significantly less. The ultimate goal of this project is to develop an easily scalable process that enables the widespread use of low-cost and abundant materials for the magnets used in EVs and renewable power generators.

  7. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore; Cross, Carl E.

    2012-06-28

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  8. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Ramsey, Philip B. (Livermore, CA); Juntz, Robert S. (Hayward, CA)

    1995-01-01

    An improved method for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite's high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding.

  9. Non-consumable anode and lining for aluminum electrolytic reduction cell

    DOE Patents [OSTI]

    Beck, Theodore R. (Seattle, WA); Brooks, Richard J. (Seattle, WA)

    1994-01-01

    An oxidation resistant, non-consumable anode, for use in the electrolytic reduction of alumina to aluminum, has a composition comprising copper, nickel and iron. The anode is part of an electrolytic reduction cell comprising a vessel having an interior lined with metal which has the same composition as the anode. The electrolyte is preferably composed of a eutectic of AlF.sub.3 and either (a) NaF or (b) primarily NaF with some of the NaF replaced by an equivalent molar amount of KF or KF and LiF.

  10. DOE - Office of Legacy Management -- Aluminum Co of America - NJ 24

    Office of Legacy Management (LM)

    NJ 24 FUSRAP Considered Sites Site: Aluminum Co of America (NJ.24 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: ALCOA (Garwood Plant) NJ.24-1 Location: Garwood , New Jersey NJ.24-1 Evaluation Year: Circa 1987 NJ.24-5 Site Operations: Constructed and altered die-casting dies and conducted die casting operation on uranium slugs. NJ.24-1 NJ.24-3 NJ.24-4 Site Disposition: Eliminated - Potential for residual contamination considered remote due to limited

  11. DOE - Office of Legacy Management -- Aluminum Co of America - PA 23

    Office of Legacy Management (LM)

    PA 23 FUSRAP Considered Sites Site: Aluminum Company of America (ALCOA) ( PA.23 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: ALCOA Research Laboratory ALCOA New Kensington Works PA.23-3 PA.23-4 Location: 600 Freeport Road and Pine and Ninth Streets , New Kensington , Pennsylvania PA.23-1 PA.23-4 Evaluation Year: Circa 1993 PA.23-1 Site Operations: Research/Development and Production activities in support of the MED uranium slug canning and

  12. Manufacturing Energy and Carbon Footprint - Sector: Alumina and Aluminum (NAICS 3313), January 2014 (MECS 2010)

    Office of Environmental Management (EM)

    Alumina and Aluminum (NAICS 3313) Process Energy Electricity and Steam Generation Losses Process Losses 3 Nonprocess Losses 456 105 Steam Distribution Losses 3 7 Nonprocess Energy 99 Electricity Generation Steam Generation 456 5 Prepared for the U.S. Department of Energy, Advanced Manufacturing Office by Energetics Incorporated 16 198 116 Generation and Transmission Losses Generation and Transmission Losses 2 234 214 207 13 220 351 7 10 0.4 20.3 20.8 4.2 24.0 1.3 26 5.3 26.1 0.4 Fuel Total

  13. Numerical Simulation and Experimental Characterization of a Binary Aluminum Alloy Spray - Application to the Spray Rolling Process

    SciTech Connect (OSTI)

    S. B. Johnson; J.-P. Delplanque; Y. Lin; Y. Zhou; E. J. Lavernia; K. M. McHugh

    2005-02-01

    A stochastic, droplet-resolved model has been developed to describe the behavior of a binary aluminum alloy spray during the spray-rolling process. In this process, a molten aluminum alloy is atomized and the resulting spray is depostied on the rolls of a twin-roll caster to produce aluminum strip. The one-way coupled spray model allows the prediction of spray characteristics such as enthalph and solid fraction, and their distribution between the nozzle and the depostion surface. This paper outlines the model development and compares the predicted spray dynamics to PDI measurements performed in a controlled configuration. Predicted and measured droplet velocity and size distributions are presented for two points along the spray centerline along with predicted spray averaged specific enthalph and solid fraction curves.

  14. Aluminum Stabilized NbTi Conductor Test Coil Design, Fabrication, and Test Results

    SciTech Connect (OSTI)

    Andreev, N.; Chlachidze, G.; Evbota, D.; Kashikhin, V.S.; Lamm, M.; Makarov, A.; Tartaglia, M.; Nakamoto, T.; Ogitsu, T.; Tanaka, K.; Yamamoto, A.; /KEK, Tsukuba

    2011-09-01

    A new generation of precision muon conversion experiments is planned at both Fermilab and KEK. These experiments will depend upon a complex set of solenoid magnets for the production, momentum selection and transport of a muon beam to a stopping target, and for tracking detector momentum analysis of candidate conversion electrons from the target. Baseline designs for the production and detector solenoids use NbTi cable that is heavily stabilized by an extruded high RRR aluminum jacket. A U.S.-Japan research collaboration has begun whose goal is to advance the development of optimized Al-NbTi conductors, gain experience with the technology of winding coils from this material, and test the conductor performance as modest length samples become available. For this purpose, a 'conductor test' solenoid with three coils was designed and built at Fermilab. A sample of the RIKEN Al-NbTi conductor from KEK was wound into a 'test' coil; this was sandwiched between two 'field' coils wound from doubled SSC cable, to increase the peak field on the RIKEN test coil. All three solenoid coils were epoxy impregnated, and utilized aluminum outer bandage rings to apply preload to the coils when cold. The design and fabrication details, and results of the magnet quench performance tests are presented and discussed.

  15. Simulation of Turbulent Combustion Fields of Shock-Dispersed Aluminum Using the AMR Code

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E; Khasainov, B

    2006-11-02

    We present a Model for simulating experiments of combustion in Shock-Dispersed-Fuel (SDF) explosions. The SDF charge consisted of a 0.5-g spherical PETN booster, surrounded by 1-g of fuel powder (flake Aluminum). Detonation of the booster charge creates a high-temperature, high-pressure source (PETN detonation products gases) that both disperses the fuel and heats it. Combustion ensues when the fuel mixes with air. The gas phase is governed by the gas-dynamic conservation laws, while the particle phase obeys the continuum mechanics laws for heterogeneous media. The two phases exchange mass, momentum and energy according to inter-phase interaction terms. The kinetics model used an empirical particle burn relation. The thermodynamic model considers the air, fuel and booster products to be of frozen composition, while the Al combustion products are assumed to be in equilibrium. The thermodynamic states were calculated by the Cheetah code; resulting state points were fit with analytic functions suitable for numerical simulations. Numerical simulations of combustion of an Aluminum SDF charge in a 6.4-liter chamber were performed. Computed pressure histories agree with measurements.

  16. Combustion of Shock-Dispersed Flake Aluminum - High-Speed Visualization

    SciTech Connect (OSTI)

    Neuwald, P; Reichenbach, H; Kuhl, A

    2006-06-19

    Charges of 0.5 g PETN were used to disperse 1 g of flake aluminum in a rectangular test chamber of 4 liter inner volume and inner dimensions of approximately 10 cm x 10 cm x 40 cm. The subsequent combustion of the flake aluminum with the ambient air in the chamber gave rise to a highly luminous flame. The evolution of the luminous region was studied by means of high-speed cinematography. The high-speed camera is responsive to a broad spectral range in the visible and near infra-red. For a number of tests this response range was narrowed down by means of a band-pass filter with a center wavelength of 488 nm and a half-width of 23 nm. The corresponding images were expected to have a stronger temperature dependence than images obtained without the filter, thus providing better capability to highlight hot-spots. Emission in the range of the pass-band of the filter can be due to continuous thermal radiation from hot Al and Al{sub 2}O{sub 3} particles or to molecular band emission from gaseous AlO. A time-resolving spectrometer was improvised to inspect this topic. The results suggest that AlO emission occurs, but that the continuous spectrum is the dominating effect in our experiments.

  17. X-ray diffractometry of lanthanum-nickel-aluminum alloys. Part 1

    SciTech Connect (OSTI)

    Mosley, W.C.

    1988-08-08

    X-ray diffractometry provides much useful information on LANA alloys that complements data obtained by SEM and Electron Microprobe Analysis. Accurate measurements of the hexagonal lattice parameters of the primary LaNi{sub 5-y}Aly phase reveal the aluminum content (y) and allow the prediction of desorption pressures for the hydrogen isotopes. A study of the broadening of x-ray diffraction lines of the LaNi{sub 5-y}Aly primary phase caused by cyclic absorption and desorption of hydrogen suggests that substitution of aluminum for nickel stabilizes the primary phase with respect to formation of antistructure defects that could cause undesirable trapping of hydrogen isotopes. Correlation of XRD with SEM and EMPA results has helped identify secondary phases, determine their abundances in volume percent, and reveal how they react with hydrogen and the atmosphere. Characterizations of LANA alloys used in process development has provided the bases for development of specifications for alloys to be used in the Replacement Trittium Facility. 28 refs., 4 tabs., 12 figs.

  18. Optical fiducial timing system for X-ray streak cameras with aluminum coated optical fiber ends

    DOE Patents [OSTI]

    Nilson, David G. (Oakland, CA); Campbell, E. Michael (Pleasanton, CA); MacGowan, Brian J. (Livermore, CA); Medecki, Hector (Livermore, CA)

    1988-01-01

    An optical fiducial timing system is provided for use with interdependent groups of X-ray streak cameras (18). The aluminum coated (80) ends of optical fibers (78) are positioned with the photocathodes (20, 60, 70) of the X-ray streak cameras (18). The other ends of the optical fibers (78) are placed together in a bundled array (90). A fiducial optical signal (96), that is comprised of 2.omega. or 1.omega. laser light, after introduction to the bundled array (90), travels to the aluminum coated (82) optical fiber ends and ejects quantities of electrons (84) that are recorded on the data recording media (52) of the X-ray streak cameras (18). Since both 2.omega. and 1.omega. laser light can travel long distances in optical fiber with only a slight attenuation, the initial arial power density of the fiducial optical signal (96) is well below the damage threshold of the fused silica or other material that comprises the optical fibers (78, 90). Thus the fiducial timing system can be repeatably used over long durations of time.

  19. Joining aluminum to titanium alloy by friction stir lap welding with cutting pin

    SciTech Connect (OSTI)

    Wei, Yanni [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China) [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China); Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Li, Jinglong, E-mail: lijinglg@nwpu.edu.cn [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)] [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Xiong, Jiangtao [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China) [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China); Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Huang, Fu; Zhang, Fusheng; Raza, Syed Hamid [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)] [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)

    2012-09-15

    Aluminum 1060 and titanium alloy Ti-6Al-4V plates were lap joined by friction stir welding. A cutting pin of rotary burr made of tungsten carbide was employed. The microstructures of the joining interface were observed by scanning electron microscopy. Joint strength was evaluated by a tensile shear test. During the welding process, the surface layer of the titanium plate was cut off by the pin, and intensively mixed with aluminum situated on the titanium plate. The microstructures analysis showed that a visible swirl-like mixed region existed at the interface. In this region, the Al metal, Ti metal and the mixed layer of them were all presented. The ultimate tensile shear strength of joint reached 100% of 1060Al that underwent thermal cycle provided by the shoulder. - Highlights: Black-Right-Pointing-Pointer FSW with cutting pin was successfully employed to form Al/Ti lap joint. Black-Right-Pointing-Pointer Swirl-like structures formed due to mechanical mixing were found at the interface. Black-Right-Pointing-Pointer High-strength joints fractured at Al suffered thermal cycle were produced.

  20. Iron and aluminum interaction with amyloid-beta peptides associated with Alzheimers disease

    SciTech Connect (OSTI)

    Drochioiu, Gabi; Ion, Laura; Murariu, Manuela; Habasescu, Laura

    2014-10-06

    An elevation in the concentration of heavy metal ions in Alzheimers disease (AD) brain has been demonstrated in many studies. A? precipitation and toxicity in AD brains seem to be caused by abnormal interactions with neocortical metal ions, especially iron, copper, zinc, and aluminum [13]. There is increasing evidence that iron and aluminum ions are involved in the mechanisms that underlie the neurodegenerative diseases [4,5]. However, evidence was brought to demonstrate that some A? fragments, at physiological pH, are not able to form binary complexes with Fe(III) ions of sufficient stability to compete with metal hydroxide precipitation [6]. On the contrary, multiple metal ions are known to interact with A? peptides [7]. Consequently, we investigated here the interaction of Fe(II/III) and Al(III) ions with some amyloid-? peptides and fragments that results in peptide aggregation and fibrillation [8,9]. Infrared spectroscopy, atomic force microscopy, scanning electron microscopy, electrophoresis and mass spectrometry demonstrated conformational changes of peptides in the presence of such metals.

  1. Computer-assisted Rheo-forging Processing of A356 Aluminum Alloys

    SciTech Connect (OSTI)

    Kim, H. H. [Department of Mechanical and Precision Engineering, Pusan National University, Busan 609-735 (Korea, Republic of); Kang, C. G. [School of Mechanical Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2010-06-15

    Die casting process has been used widely for complex automotive products such as the knuckle, arm and etc. Generally, a part fabricated by casting has limited strength due to manufacturing defects by origin such as the dendrite structure and segregation. As an attempt to offer a solution to these problems, forging has been used as an alternative process. However, the forging process provides limited formability for complex shape products. Rheo-forging of metal offers not only superior mechanical strength but also requires significantly lower machine loads than solid forming processes. In order to produce semi-solid materials of the desired microstructure, a stirring process is applied during solidification of A356 aluminum molten state. This paper presents the results of an A356 aluminum alloy sample, which were obtained by experiment and by simulation using DEFORM 3D V6.1. Samples of metal parts were subsequently fabricated by using hydraulic press machinery. In order to compare the influence of loading method, two types of samples were fabricated: (1) samples fabricated under direct loading die sets (2) those fabricated under indirect loading die sets. The formability and defects, which were predicted by FEM simulation, were similar to those of samples used in practice.

  2. Study of integration issues to realize the market potential of OTEC energy in the aluminum industry. Final report

    SciTech Connect (OSTI)

    Jones, Jr., M. S.; Thiagarajan, V.; Sathyanarayana, K.; Markel, A. L.; Snyder, III, J. E.; Sprouse, A. M.; Leshaw, D.

    1980-09-01

    The various integration issues are studied which must be considered to realize the market potential for the use of OTEC by the aluminum industry. The chloride reduction process has been identified as an attractive candidate for use with OTEC systems, and drained-cathode Hall cells and two alternative chloride reduction processes are considered. OTEC power system and plantships for the different processes are described. Aluminum industry characteristics important for OTEC considerations are given, including economic models and case history analyses. Appended are supporting cost estimates and energy bridge concepts for getting OTEC energy to shore. (LEW)

  3. ASSESSMENT OF THE STATE OF PRECIPITATION IN ALUMINUM CASTING A356.2 ALLOY USING NONDESTRUCTIVE MICROSTRUCTURE ELECTRONIC PROPERTY MEASUREMENTS

    SciTech Connect (OSTI)

    Kiattisaksri, P.; Gibbs, P. J.; Koenig, K.; Pfeif, E. A.; Mishra, B.; Olson, D. L. [Colorado School of Mines, Golden, Colorado (United States); Lasseigne, A. N. [Generation 2 Materials Technology LLC, Firestone, Colorado (United States); Mendez, P. F. [University of Alberta, Edmonton, Alberta (Canada)

    2010-02-22

    Application of nondestructive electronic property measurements to assess the strengthening of Mg{sub 2}Si precipitates in aluminum A356.2 casting has been demonstrated. The results indicated the evolution of precipitation phase through over aging with increased cooling time or thickness of the cast part. The classical optimum precipitation behavior has been characterized and verified with thermal analysis, thermoelectric power, low frequency impedance, and micro hardness measurements. A proposed practice to use nondestructive electronic property measurement tools to assess aluminum casting for acceptable mechanical properties after mold shake out is presented.

  4. Role of stoichiometric ratio of components during the formation of oxide and hydroxide layers on aluminum in oxoanion solutions

    SciTech Connect (OSTI)

    Mikhailovskii, Y.N.; Derdzenishvili, G.A.

    1986-07-01

    This paper investigates the corrosion-electrochemical behavior of aluminum in chloride-fluoride solutions containing oxoanions of the oxidizing type (CrO/sup 2 -//sub 4/, MnO/sup -//sub 4/, MoO/sup 2 -//sub 4/, VO/sup 3 -//sub 4/, WO/sup 2 -//sub 4/). It is shown that, depending on the ratio of the concentrations of the oxoanions and hydroxonium ions, the oxidizing agent may activate or inhibit the corrosion process on the metal. The conditions of formation of surface phases is studied, which can impart good protective properties (conversion coatings), on aluminum during its self-solution.

  5. Influence of pH on electrochemical and corrosion behavior of aluminum in media containing oxo anions of the oxidizing type

    SciTech Connect (OSTI)

    Mikhailovskii, Y.N.; Berdzenishvili, G.A.

    1986-07-01

    This paper investigates the influence of CrO/sub 4//sup 2 -/, MnO/sub 4//sup -/, VO/sub 4//sup 3 -/, MoO/sub 4//sup 2 -/, and WO/sub 4//sup 2 -/ on the potential and corrosion rate of aluminum in chloride-fluoride solutions with pH from 2 to 12. In neutral solutions on aluminum there is formed a mixed oxide-hydroxide layer with excess hydroxides which inhibits the corrosion of aluminum. Vanadates, molybdates, and tungstates in neutral solutions also formed mixed oxide-hydroxide layers with excess OH/sup -/ on the surface of the aluminum. This paper clearly displays the general laws of variation of the corrosion-electrochemical properties of aluminum in relation to pH in the presence of oxoanions of the oxidizing type.

  6. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

    SciTech Connect (OSTI)

    Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

    2010-10-01

    Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOEs 2010 and 2015 targets for system wt%.

  7. Theoretical investigation of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe)

    SciTech Connect (OSTI)

    Gao, Kunqi; Sheng, Li

    2015-04-14

    The equilibrium geometries, harmonic frequencies, and dissociation energies of HNgNH{sub 3}{sup +} ions (Ng = He, Ne, Ar, Kr, and Xe) were investigated using the following method: Becke-3-parameter-Lee-Yang-Parr (B3LYP), Boese-Matrin for Kinetics (BMK), second-order Mller-Plesset perturbation theory (MP2), and coupled-cluster with single and double excitations as well as perturbative inclusion of triples (CCSD(T)). The results indicate that HHeNH{sub 3}{sup +}, HArNH{sub 3}{sup +}, HKrNH{sub 3}{sup +}, and HXeNH{sub 3}{sup +} ions are metastable species that are protected from decomposition by high energy barriers, whereas the HNeNH{sub 3}{sup +} ion is unstable because of its relatively small energy barrier for decomposition. The bonding nature of noble-gas atoms in HNgNH{sub 3}{sup +} was also analyzed using the atoms in molecules approach, natural energy decomposition analysis, and natural bond orbital analysis.

  8. Pechiney Rolled Products: Plant-Wide Energy Assessment Identifies Opportunities to Optimize Aluminum Casting and Rolled Operations

    SciTech Connect (OSTI)

    2004-07-01

    A Pechiney Rolled Products plant focused on various aluminum casting processes during a PWA. The assessment revealed potential annual savings of 460,000 MMBtu in natural gas, 9.6 million kWh in electricity, 69 million pounds in CO2, and $2.5 million.

  9. Evaluation of cast carbon steel and aluminum for rack insert in MCO Mark 1A fuel basket

    SciTech Connect (OSTI)

    Graves, C.E., Fluor Daniel Hanford

    1997-03-21

    This document evaluates the effects ofusing a cast carbon steel or aluminum instead of 3O4L stainless steel in the construction ofthe fuel rack insert for the Spent Nuclear Fuel MCO Mark IA fuel baskets. The corrosion, structural, and cost effects are examined.

  10. Technology maturation project on optimization of sheet metal forming of aluminum for use in transportation systems: Final project report

    SciTech Connect (OSTI)

    Johnson, K.I.; Smith, M.T.; Lavender, C.A.; Khalell, M.A.

    1994-10-01

    Using aluminum instead of steel in transportation systems could dramatically reduce the weight of vehicles--an effective way of decreasing energy consumption and emissions. The current cost of SMF aluminum alloys (about $4 per pound) and the relatively long forming times of current materials are serious drawbacks to the widespread use of SMF in industry. The interdependence of materials testing and model development is critical to optimizing SMF since the current process is conducted in a heated, pressurized die where direct measurement of critical SMF parameters is extremely difficult. Numerical models provide a means of tracking the forming process, allowing the applied gas pressure to be adjusted to maintain the optimum SMF behavior throughout the forming process. Thus, models can help produce the optimum SMF component in the least amount of time. The Pacific Northwest Laboratory is integrating SMF model development with research in improved aluminum alloys for SMF. The objectives of this research are: develop and characterize competitively priced aluminum alloys for SMF applications in industry; improve numerical models to accurately predict the optimum forming cycle for reduced forming time and improved quality; verify alloy performance and model accuracy with forming tests conducted in PNL`s Superplastic Forming User Facility. The activities performed in this technology maturation project represent a critical first step in achieving these objectives through cooperative research among industry, PNL, and universities.

  11. Nondestructive detection of an undesirable metallic phase, T.sub.1, during processing of aluminum-lithium alloys

    DOE Patents [OSTI]

    Buck, Otto (Ames, IA); Bracci, David J. (Maryland Heights, MO); Jiles, David C. (Ames, IA); Brasche, Lisa J. H. (Nevada, IA); Shield, Jeffrey E. (Ames, IA); Chumbley, Leonard S. (Ames, IA)

    1990-08-07

    A method is disclosed for detecting the T.sub.1 phase in aluminum-lithium alloys through simultaneous measurement of conductivity and hardness. In employing eddy current to measure conductivity, when the eddy current decreases with aging of the alloy, while the hardness of the material continues to increase, the presence of the T.sub.1 phase may be detected.

  12. ALUMINUM REMOVAL FROM HANFORD WASTE BY LITHIUM HYDROTALCITE PRECIPITATION - LABORATORY SCALE VALIDATION ON WASTE SIMULANTS TEST REPORT

    SciTech Connect (OSTI)

    SAMS T; HAGERTY K

    2011-01-27

    To reduce the additional sodium hydroxide and ease processing of aluminum bearing sludge, the lithium hydrotalcite (LiHT) process has been invented by AREV A and demonstrated on a laboratory scale to remove alumina and regenerate/recycle sodium hydroxide prior to processing in the WTP. The method uses lithium hydroxide (LiOH) to precipitate sodium aluminate (NaAI(OH){sub 4}) as lithium hydrotalcite (Li{sub 2}CO{sub 3}.4Al(OH){sub 3}.3H{sub 2}O) while generating sodium hydroxide (NaOH). In addition, phosphate substitutes in the reaction to a high degree, also as a filterable solid. The sodium hydroxide enriched leachate is depleted in aluminum and phosphate, and is recycled to double-shell tanks (DSTs) to leach aluminum bearing sludges. This method eliminates importing sodium hydroxide to leach alumina sludge and eliminates a large fraction of the total sludge mass to be treated by the WTP. Plugging of process equipment is reduced by removal of both aluminum and phosphate in the tank wastes. Laboratory tests were conducted to verify the efficacy of the process and confirm the results of previous tests. These tests used both single-shell tank (SST) and DST simulants.

  13. Atomic layer deposition of aluminum sulfide thin films using trimethylaluminum and hydrogen sulfide

    SciTech Connect (OSTI)

    Sinha, Soumyadeep; Sarkar, Shaibal K.; Mahuli, Neha

    2015-01-15

    Sequential exposures of trimethylaluminum and hydrogen sulfide are used to deposit aluminum sulfide thin films by atomic layer deposition (ALD) in the temperature ranging from 100 to 200?C. Growth rate of 1.3 per ALD cycle is achieved by in-situ quartz crystal microbalance measurements. It is found that the growth rate per ALD cycle is highly dependent on the purging time between the two precursors. Increased purge time results in higher growth rate. Surface limited chemistry during each ALD half cycle is studied by in-situ Fourier transformed infrared vibration spectroscopy. Time of flight secondary ion-mass spectroscopy measurement is used to confirm elemental composition of the deposited films.

  14. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, D.M.; Ramsey, P.B.; Juntz, R.S.

    1995-07-04

    An improved method is disclosed for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite`s high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding. 11 figs.

  15. New Method to Characterize Degradation of First Surface Aluminum Reflectors: Preprint

    SciTech Connect (OSTI)

    Sutter, F.; Heller, P.; Meyen, S.; Pitz-Paal, R.; Kennedy, C.; Fernandez-Garcia, A.; Schmucker, M.

    2010-10-01

    This paper reports the development of a new optical instrument capable of characterizing the aging process of enhanced first surface aluminum reflectors for concentrating solar power (CSP) application. Samples were exposed outdoors at different sites and in accelerated exposure tests. All samples exposed outdoors showed localized corrosion spots. Degradation originated from points of damage in the protective coating, but propagated underneath the protective coating. The degraded samples were analyzed with a microscope and with a newly designed space-resolved specular reflectometer (SR)2 that is capable of optically detecting and characterizing the corrosion spots. The device measures the specular reflectance at three acceptance angles and the wavelengths with spatial resolution using a digital camera's CMOS sensor. It can be used to measure the corrosion growth rate during outdoor and accelerated exposure tests. These results will allow a correlation between the degraded mirror surface and its specular reflectance.

  16. Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process

    DOE Patents [OSTI]

    Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

    1998-01-01

    The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

  17. The total hemispheric emissivity of painted aluminum honeycomb at cryogenic temperatures

    SciTech Connect (OSTI)

    Tuttle, J.; Canavan, E.; DiPirro, M.; Li, X.; Knollenberg, P.

    2014-01-29

    NASA uses high-emissivity surfaces on deep-space radiators and thermal radiation absorbers in test chambers. Aluminum honeycomb core material, when coated with a high-emissivity paint, provides a lightweight, mechanically robust, and relatively inexpensive black surface that retains its high emissivity down to low temperatures. At temperatures below about 100 Kelvin, this material performs much better than the paint itself. We measured the total hemispheric emissivity of various painted honeycomb configurations using an adaptation of an innovative technique developed for characterizing thin black coatings. These measurements were performed from room temperature down to 30 Kelvin. We describe the measurement technique and compare the results with predictions from a detailed thermal model of each honeycomb configuration.

  18. Method For Creating Corrosion Resistant Surface On An Aluminum Copper Alloy

    DOE Patents [OSTI]

    Mansfeld, Florian B. (Playa del Rey, CA); Wang, You (Jingshou, CN); Lin, Simon H. (San Dimas, CA)

    1997-06-03

    A method for treating the surface of aluminum alloys hang a relatively high copper content is provided which includes the steps of removing substantially all of the copper from the surface, contacting the surface with a first solution containing cerium, electrically charging the surface while contacting the surface in an aqueous molybdate solution, and contacting the surface with a second solution containing cerium. The copper is substantially removed from the surface in the first step either by (i) contacting the surface with an acidic chromate solution or by (ii) contacting the surface with an acidic nitrate solution while subjecting the surface to an electric potential. The corrosion-resistant surface resulting from the invention is excellent, consistent and uniform throughout the surface. Surfaces treated by the invention may often be certified for use in salt-water services.

  19. An evaluation of the Johnson-Cook model to simulate puncture of 7075 aluminum plates.

    SciTech Connect (OSTI)

    Corona, Edmundo; Orient, George Edgar

    2014-02-01

    The objective of this project was to evaluate the use of the Johnson-Cook strength and failure models in an adiabatic finite element model to simulate the puncture of 7075- T651 aluminum plates that were studied as part of an ASC L2 milestone by Corona et al (2012). The Johnson-Cook model parameters were determined from material test data. The results show a marked improvement, in particular in the calculated threshold velocity between no puncture and puncture, over those obtained in 2012. The threshold velocity calculated using a baseline model is just 4% higher than the mean value determined from experiment, in contrast to 60% in the 2012 predictions. Sensitivity studies showed that the threshold velocity predictions were improved by calibrating the relations between the equivalent plastic strain at failure and stress triaxiality, strain rate and temperature, as well as by the inclusion of adiabatic heating.

  20. Controlled Release from Core-Shell Nanoporous Silica Particles for Corrosion Inhibition of Aluminum Alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Xingmao; Jiang, Ying-Bing; Liu, Nanguo; Xu, Huifang; Rathod, Shailendra; Shah, Pratik; Brinker, C. Jeffrey

    2011-01-01

    Ceriumore » m (Ce) corrosion inhibitors were encapsulated into hexagonally ordered nanoporous silica particles via single-step aerosol-assisted self-assembly. The core/shell structured particles are effective for corrosion inhibition of aluminum alloy AA2024-T3. Numerical simulation proved that the core-shell nanostructure delays the release process. The effective diffusion coefficient elucidated from release data for monodisperse particles in water was 1.0 × 10 − 14  m 2 s for Ce 3+ compared to 2.5 × 10 − 13  m 2 s for NaCl. The pore size, pore surface chemistry, and the inhibitor solubility are crucial factors for the application. Microporous hydrophobic particles encapsulating a less soluble corrosion inhibitor are desirable for long-term corrosion inhibition.« less

  1. Recovery and recycling of aluminum, copper, and precious metals from dismantled weapon components

    SciTech Connect (OSTI)

    Lutz, J.D.; Wheelis, W.T.; Gundiler, I.H.

    1995-02-01

    Sandia National Laboratories (SNL) is tasked to support the Department of Energy in the dismantlement and disposal of SNL designed weapon components. These components are sealed in a potting compound, and contain heavy metals, explosive, radioactive, and toxic materials in discrete sub-components. SNL developed and demonstrated a process to identify and remove the hazardous sub-components utilizing real-time radiography and abrasive water-jet cutting. The remaining components were then crushed, granulated, screened, and separated into an aluminum and a precious-and-base-metals fraction using air-tables. Plastics were further cleaned for disposal as non-hazardous waste. The New Mexico Bureau of Mines & Mineral Resources assisted SNL in investigation of size-reduction and separation technologies and in the development of a conceptual design for a mechanical separation system.

  2. Recovery and recycling of aluminum, copper, and precious metals from dismantled weapon components

    SciTech Connect (OSTI)

    Gundiler, I.H.; Lutz, J.D.; Wheelis, W.T.

    1994-03-03

    Sandia National Laboratories (SNL) is tasked to support The Department of Energy in the dismantlement and disposal of SNL designed weapon components. These components are sealed in a potting compound, and contain heavy metals, explosive, radioactive, and toxic materials. SNL developed a process to identify and remove the hazardous sub-components utilizing real-time radiography and abrasive water-jet cutting. The components were then crushed, granulated, screened, and separated into an aluminum and a precious-and-base-metals fraction using air-tables. Plastics were further cleaned for disposal as non-hazardous waste. New Mexico Bureau of Mines and Mineral Resources assisted SNL in investigation of size-reduction and separation technologies.

  3. Horn-coupled, commercially-fabricated aluminum lumped-element kinetic inductance detectors for millimeter wavelengths

    SciTech Connect (OSTI)

    McCarrick, H. Flanigan, D.; Jones, G.; Johnson, B. R.; Araujo, D.; Limon, M.; Luu, V.; Miller, A.; Ade, P.; Doyle, S.; Tucker, C.; Bradford, K.; Che, G.; Cantor, R.; Day, P.; Leduc, H.; Mauskopf, P.; Mroczkowski, T.; Zmuidzinas, J.

    2014-12-15

    We discuss the design, fabrication, and testing of prototype horn-coupled, lumped-element kinetic inductance detectors (LEKIDs) designed for cosmic microwave background studies. The LEKIDs are made from a thin aluminum film deposited on a silicon wafer and patterned using standard photolithographic techniques at STAR Cryoelectronics, a commercial device foundry. We fabricated 20-element arrays, optimized for a spectral band centered on 150 GHz, to test the sensitivity and yield of the devices as well as the multiplexing scheme. We characterized the detectors in two configurations. First, the detectors were tested in a dark environment with the horn apertures covered, and second, the horn apertures were pointed towards a beam-filling cryogenic blackbody load. These tests show that the multiplexing scheme is robust and scalable, the yield across multiple LEKID arrays is 91%, and the measured noise-equivalent temperatures for a 4 K optical load are in the range 266 ?K?(s)

  4. Influence of Alloy and Solidification Parameters on Grain Refinement in Aluminum Weld Metal due to Inoculation

    SciTech Connect (OSTI)

    Schempp, Philipp [BAM, Germany; Tang, Z. [BIAS, Germany; Cross, Carl E. [Los Alamos National Laboratory; Seefeld, T. [BIAS, Germany; Pittner, A. [BAM, Germany; Rethmeier, M. [BAM, Germany

    2012-06-28

    The goals are: (1) Establish how much Ti/B grain refiner is need to completely refine aluminum weld metal for different alloys and different welding conditions; (2) Characterize how alloy composition and solidification parameters affect weld metal grain refinement; and (3) Apply relevant theory to understand observed behavior. Conclusions are: (1) additions of Ti/B grain refiner to weld metal in Alloys 1050, 5083, and 6082 resulted in significant grain refinement; (2) grain refinement was more effective in GTAW than LBW, resulting in finer grains at lower Ti content - reason is limited time available for equiaxed grain growth in LBW (inability to occlude columnar grain growth); (3) welding travel speed did not markedly affect grain size within GTAW and LBW clusters; and (4) application of Hunt CET analysis showed experimental G to be on the order of the critical G{sub CET}; G{sub CET} was consistently higher for GTAW than for LBW.

  5. Local residual stress monitoring of aluminum nitride MEMS using UV micro-Raman spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Sukwon; Griffin, Benjamin A.

    2016-01-06

    Localized stress variation in aluminum nitride (AlN) sputtered on patterned metallization has been monitored through the use of UV micro-Raman spectroscopy. This technique utilizing 325 nm laser excitation allows detection of the AlN E2(high) phonon mode in the presence of metal electrodes beneath the AlN layer with a high spatial resolution of less than 400 nm. The AlN film stress shifted 400 MPa from regions where AlN was deposited over a bottom metal electrode versus silicon dioxide. Thus, across wafer stress variations were also investigated showing that wafer level stress metrology, for example using wafer curvature measurements, introduces large uncertaintiesmore » for predicting the impact of AlN residual stress on the device performance.« less

  6. Thermal Management in Friction-Stir Welding of Precipitation-Hardening Aluminum Alloys

    SciTech Connect (OSTI)

    Upadhyay, Piyush; Reynolds, Anthony

    2015-05-25

    Process design and implementation in FSW is mostly dependent on empirical information gathered through experience. Basic science of friction stir welding and processing can only be complete when fundamental interrelationships between process control parameters and response variables and resulting weld microstructure and properties are established to a reasonable extent. It is known that primary process control parameters like tool rotation and translation rate and forge axis force have complicated and interactive relationships to the process response variables such as peak temperature, time at temperature etc. Of primary influence to the other process response parameters are temperature and its gradient at the deformation and heat affected zones. Through review of pertinent works in the literature and some experimental results from boundary condition work performed in precipitation hardening aluminum alloys this paper will partially elucidate the nature and effects of temperature transients caused by variation of thermal boundaries in Friction Stir Welding.

  7. Ab initio study of formation, migration and binding properties of helium-vacancy clusters in aluminum

    SciTech Connect (OSTI)

    Yang, Li; Zu, Xiaotao T.; Gao, Fei

    2008-08-01

    Ab initio calculations based on density functional theory have been performed to study the dissolution and migration of helium, and the stability of small helium-vacancy clusters HenVm (n, m=0 to 4) in aluminum. The results indicate that the octahedral configuration is more stable than the tetrahedral. Interstitial helium atoms are predicted to have attractive interactions and jump between two octahedral sites via an intermediate tetrahedral site with low migration energy of 0.10 eV. The binding energies of an interstitial He atom and an isolated vacancy to a HenVm cluster are also obtained from the calculated formation energies of the clusters. We find that the divacancy and tri--vacancy clusters are not stable, but He atoms can increase the stability of vacancy clusters. The interactions of He atoms with a vacancy are found to be in good agreement with the experimental results.

  8. A MODERN INTERPRETATION OF THE BARNEY DIAGRAM FOR ALUMINUM SOLUBILITY IN TANK WASTE

    SciTech Connect (OSTI)

    REYNOLDS JG; REYNOLDS DA

    2009-12-16

    Experimental and modeling studies of aluminum solubility in Hanford tank waste have been developed and refined for many years in efforts to resolve new issues or develop waste treatment flowsheets. The earliest of these studies was conducted by G. Scott Barney, who performed solubility studies in highly concentrated electrolyte solutions to support evaporator campaign flowsheets in the 1970's. The 'Barney Diagram', a term still widely used at Hanford today, suggested gibbsite ({gamma}-Al(OH){sub 3}) was much more soluble in tank waste than in simple sodium hydroxide solutions. These results, which were highly surprising at the time, continue to be applied to new situations where aluminum solubility in tank waste is of interest. Here, we review the history and provide a modern explanation for the large gibbsite solubility observed by Barney, an explanation based on basic research that has been performed and published in the last 30 years. This explanation has both thermodynamic and kinetic aspects. Thermodynamically, saturated salt solutions stabilize soluble aluminate species that are minor components in simple sodium hydroxide solutions. These species are the aluminate dimer and the sodium-aluminate ion-pair. Ion-pairs must be present in the Barney simulants because calculations showed that there was insufficient space between the highly concentrated ions for a water molecule. Thus, most of the ions in the simulants have to be ion-paired. Kinetics likely played a role as well. The simulants were incubated for four to seven days, and more recent data indicate that this was unlikely sufficient time to achieve equilibrium from supersaturation. These results allow us to evaluate applications of the Barney results to current and future tank waste issues or flowsheets.

  9. Non Invasive estimation of aluminum concentration in Hall-Heroult reduction cells

    SciTech Connect (OSTI)

    David Bell

    2004-03-01

    The present best practice for the preparation of primary aluminum is by electrolysis of alumina in the traditional Hall-Heroult reduction cell. The process conditions in the electrolyte of this cell required for the reduction to proceed are sufficiently harsh to have precluded the implementation of in situ sensing of the electrolyte composition, specifically the concentration of the ionized alumina. This report reveals the theoretical basis for a non-invasive method for estimation of the ionized alumina concentration which does not require the use of any sensor in direct contact with the cell electrolyte. The proposed method can in principle be applied with equal efficacy to the so-called drained cathode cell designs and to cells having any anode composition, because only knowledge of the electrolyte conduction behavior is required a priori. For an operating cell, the proposed method requires only readily available electrical measurements and the facilities to process the acquired signals. The proposed method rests on the ability to identify certain characteristics of the transients in the reduction cell terminal voltages caused by the quasiperiodic introduction of alumina. It will be shown that these voltage transients manifest measurable properties, in a statistical sense, that should permit estimation of the ionized alumina concentration with a delay of one alumina feed cycle. The next logical step following the present work, consistent with the Aluminum Technology Roadmap [1], is to experimentally verify the predictions made here; no doubt practical refinements to the proposed approach will evolve during the course of experimentation. Successful verification of the proposed estimation method will permit the design of reduction cell control algorithms based directly on the mass balance of alumina in the electrolyte. This report assumes that the reader understands certain basic concepts important to the operation of electrolytic cells, and the Hall-Heroult cell in particular. References [2,3] provide such concepts in a manner accessible to the technically educated reader; reference [6] is a more thorough treatment.

  10. Thermal oxidation of polycrystalline and single crystalline aluminum nitride wafers (Prop 2003-054)

    SciTech Connect (OSTI)

    Speakman, Scott A; Gu, Z; Edgar, J H; Blom, Douglas Allen; Perrin, J; Chaudhuri, J

    2006-10-01

    Two types of aluminum nitride (AlN) samples were oxidized in flowing oxygen between 900 C and 1150 C for up to 6 h - highly (0001) textured polycrystalline AlN wafers and low defect density AlN single crystals. The N-face consistently oxidized at a faster rate than the Al-face. At 900 C and 1000 C after 6 h, the oxide was 15% thicker on the N-face than on the Al-face of polycrystalline AlN. At 1100 C and 1150 C, the oxide was only 5% thicker on the N-face, as the rate-limiting step changed from kinetically-controlled to diffusion-controlled with the oxide thickness. A linear parabolic model was established for the thermal oxidation of polycrystalline AlN on both the Al- and N-face. Transmission electron microscopy (TEM) confirmed the formation of a thicker crystalline oxide film on the N-face than on the Al-face, and established the crystallographic relationship between the oxide film and substrate. The oxidation of high-quality AlN single crystals resulted in a more uniform colored oxide layer compared to polycrystalline AlN. The aluminum oxide layer was crystalline with a rough AlN/oxide interface. The orientation relationship between AlN and Al{sub 2}O{sub 3} was (0001) AlN//(10{bar 1}0) Al{sub 2}O{sub 3} and (1{bar 1}00) AlN//(01{bar 1}2) Al{sub 2}O{sub 3}.

  11. Hot Rolling Scrap Reduction through Edge Cracking and Surface Defects Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Rolling Scrap Reduction through Edge Cracking and Surface Defects Control Improving Energy Efficiency in Hot Rolling by Increasing Recovery Rates Hot rolling of large ingots is the predominant process for producing plate, sheet, and foil aluminum products. Hot rolling has typical recovery rates of 82%, because 18% of the original material is lost as planned end cuts and scalping, or as incidental (unplanned) scrap. Hot rolled scrap is then typically re-melted to either form fresh ingot

  12. AR03-04

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    andia National Laboratories began in 1945 on Sandia Base in Albuquerque, New Mexico, as Z Division, part of what's now Los Alamos National Laboratory. Both labs were born out of America's atomic bomb development effort-the Manhattan project. Sandia came into being as an ordnance design, testing, and assembly facility, and was located on Sandia Base to be close to an airfield and work closely with the military. In 1949, President Harry Truman wrote a letter to the American Telephone and Telegraph

  13. FY06 AR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    f i c e o f F o s s i l E n e r g y N a t i o n a l E n e r g y T e c h n o l o g y L a b o r a t o r y ACCOMPLISHMENTS NETL Accomplishments FY 2006 2 NETL Accomplishments FY 2006 3 MESSAGE FROM THE DIRECTOR For 200 years, America's energy demands have grown at a remarkable rate. As we have moved from an agricultural society, through industrial expansion, and into the current technological era, our society's transformation has depended on reliable, affordable energy supplies. Energy reliance is

  14. STUDY OF THE RECURRING DIMMING REGION DETECTED AT AR 11305 USING THE CORONAL DIMMING TRACKER (CoDiT)

    SciTech Connect (OSTI)

    Krista, Larisza D.; Reinard, Alysha

    2013-01-10

    We present a new approach to coronal dimming detection using the COronal DImming Tracker tool (CODIT), which was found to be successful in locating and tracking multiple dimming regions. This tool, an extension of a previously developed coronal hole tracking software, allows us to study the properties and the spatial evolution of dimming regions at high temporal and spatial cadence from the time of their appearance to their disappearance. We use Solar Dynamics Observatory/Atmospheric Imaging Assembly 193 A wavelength observations and Helioseismic and Magnetic Imager magnetograms to study dimmings. As a demonstration of the detection technique we analyzed six recurrences of a dimming observed near AR 11305 between 2011 September 29 and October 2. The dimming repeatedly appeared and formed in a similar way, first expanding then shrinking and occasionally stabilizing in the same location until the next eruption. The dimming areas were studied in conjunction with the corresponding flare magnitudes and coronal mass ejection (CME) masses. These properties were found to follow a similar trend during the observation period, which is consistent with the idea that the magnitude of the eruption and the CME mass affect the relative sizes of the consecutive dimmings. We also present a hypothesis to explain the evolution of the recurrent single dimming through interchange reconnection. This process would accommodate the relocation of quasi-open magnetic field lines and hence allow the CME flux rope footpoint (the dimming) to expand into quiet-Sun regions. By relating the properties of dimmings, flares, and CMEs we improve our understanding of the magnetic field reconfiguration caused by reconnection.

  15. Parametric study of atmospheric pressure microwave-induced Ar/O{sub 2} plasmas and the ambient air effect on the plasma

    SciTech Connect (OSTI)

    Moon, Se Youn; Choe, W.

    2006-10-15

    A torch type microwave-induced afterglow plasma was produced at atmospheric pressure using an open-ended fused silica concentric double tube assisted by Ar and O{sub 2} supply gases. The plasma emerged from the end of the discharge tube and was exposed to ambient air. A parametric study of the plasma characteristics was performed by measuring the temperature, density, and plasma volume as the operational parameters such as microwave power, gas flow rate, and its composition were varied. The excitation temperature (T{sub exc}) obtained from the Ar I emission spectrum ranged from 3010 to 4350 K and the rotational temperature (T{sub rot}) measured from the OH and O{sub 2} diatomic molecular spectra ranged from 2250 to 3550 K. The electron density (n{sub e}) from the H{sub {beta}} Stark broadening width at the plasma core was in the range of 6.6 to 7.6x10{sup 14} cm{sup -3}. The two-dimensional distribution of T{sub exc} and T{sub rot} was also obtained. Experiments while varying the Ar and O{sub 2} gas flow rate and the O{sub 2}/Ar ratio showed that n{sub e} was reduced but T{sub exc} was increased as the O{sub 2} flow rate was increased. Using an additional dielectric tube for shielding the plasma from the ambient air demonstrated a significantly enlarged plasma length and lower T{sub rot} due to the nitrogen entrainment, as compared to the unshielded case.

  16. Publications of the Oak Ridge National Laboratory Fossil Energy Program and the AR and TD Materials Program, April 1, 1995--March 31, 1997

    SciTech Connect (OSTI)

    Carlson, P.T.

    1997-07-01

    The Oak Ridge National Laboratory (ORNL) Fossil Energy Program, organized in FY 1974 as the Coal Technology Program, involves research and development activities that cover a wide range of fossil energy technologies. The principal focus of the Laboratory`s fossil energy activities relates to coal, with current emphasis on materials research and development; environmental, health, and safety research; and the bioprocessing of coal to produce liquid or gaseous fuels. This bibliography covers the period of April 1, 1995, through March 31, 1997, and is a supplement to the earlier bibliographies in this series. The publications listed in this document have been limited to topical reports, open literature publications, full-length papers in published proceedings of conferences, and books and book articles. A major activity of the Fossil Energy Program is the Advanced Research and Technology Development (AR and TD) Materials Program. The objective of the AR and TD Materials Program is to conduct research and development on materials for fossil energy applications, with a focus on the longer-term needs for materials with general applicability to the various fossil fuel technologies. Beginning with this report, publications of the AR and TD Materials Program, previously compiled in separate reports, and publications from non-materials activities of the Fossil Energy Program will be combined in a single report.

  17. Absolute CF{sub 2} density and gas temperature measurements by absorption spectroscopy in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas

    SciTech Connect (OSTI)

    Liu, Wen-Yao; Xu, Yong Peng, Fei; Gong, Fa-Ping; Li, Xiao-Song; Zhu, Ai-Min; Liu, Yong-Xin; Wang, You-Nian

    2014-10-15

    Broadband ultraviolet absorption spectroscopy has been used to determine the CF{sub 2} radical density in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas, using the CF{sub 2} A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system of absorption spectrum. The rotational temperature of ground state CF{sub 2} and excited state CF was also estimated by using A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system and B{sup 2}??X{sup 2}? system, respectively. The translational gas temperature was deduced from the Doppler width of the Ar{sup *}({sup 3}P{sub 2}) and Ar{sup *}({sup 3}P{sub 0}) metastable atoms absorption line by using the tunable diode laser absorption spectroscopy. The rotational temperatures of the excited state CF are about 100?K higher than those of ground state CF{sub 2}, and about 200?K higher than the translational gas temperatures. The dependences of the radical CF{sub 2} density, electron density, electron temperature, rotational temperature, and gas temperature on the high frequency power and pressure have been analyzed. Furthermore, the production and loss mechanisms of CF{sub 2} radical and the gas heating mechanisms have also been discussed.

  18. NEUTRALIZATIONS OF HIGH ALUMINUM LOW URANIUM USED NUCLEAR FUEL SOLUTIONS CONTAINING GADOLINIUM AS A NEUTRON POISON

    SciTech Connect (OSTI)

    Taylor-Pashow, K.

    2011-06-08

    H-Canyon will begin dissolving High Aluminum - Low Uranium (High Al/Low U) Used Nuclear Fuel (UNF) following approval by DOE which is anticipated in CY2011. High Al/Low U is an aluminum/enriched uranium UNF with small quantities of uranium relative to aluminum. The maximum enrichment level expected is 93% {sup 235}U. The High Al/Low U UNF will be dissolved in H-Canyon in a nitric acid/mercury/gadolinium solution. The resulting solution will be neutralized and transferred to Tank 39H in the Tank Farm. To confirm that the solution generated could be poisoned with Gd, neutralized, and discarded to the Savannah River Site (SRS) high level waste (HLW) system without undue nuclear safety concerns the caustic precipitation of simulant solutions was examined. Experiments were performed with three simulant solutions representative of the H-Canyon estimated concentrations in the final solutions after dissolution. The maximum U, Gd, and Al concentration were selected for testing from the range of solution compositions provided. Simulants were prepared in three different nitric acid concentrations, ranging from 0.5 to 1.5 M. The simulant solutions were neutralized to four different endpoints: (1) just before a solid phase was formed (pH 3.5-4), (2) the point where a solid phase was obtained, (3) 0.8 M free hydroxide, and (4) 1.2 M free hydroxide, using 50 wt % sodium hydroxide (NaOH). The settling behavior of the neutralized solutions was found to be slower compared to previous studies, with settling continuing over a one week period. Due to the high concentration of Al in these solutions, precipitation of solids was observed immediately upon addition of NaOH. Precipitation continued as additional NaOH was added, reaching a point where the mixture becomes almost completely solid due to the large amount of precipitate. As additional NaOH was added, some of the precipitate began to redissolve, and the solutions neutralized to the final two endpoints mixed easily and had expected densities of typical neutralized waste. Based on particle size and scanning electron microscopy analyses, the neutralized solids were found to be homogeneous and less than 20 microns in size. The majority of solids were less than 4 microns in size. Compared to previous studies, a larger percentage of the Gd was found to precipitate in the partially neutralized solutions (at pH 3.5-4). In addition the Gd:U mass ratio was found to be at least 1.0 in all of the solids obtained after partial or full neutralization. The hydrogen to U (H:U) molar ratios for two accident scenarios were also determined. The first was for transient neutralization and agitator failure. Experimentally this scenario was determined by measuring the H:U ratio of the settled solids. The minimum H:U molar ratio for solids from fully neutralized solutions was 388:1. The second accident scenario is for the solids drying out in an unagitiated pump box. Experimentally, this scenario was determined by measuring the H:U molar ratio in centrifuged solids. The minimum H:U atom ratios for centrifuged precipitated solids was 250:1. It was determined previously that a 30:1 H:Pu atom ratio was sufficient for a 1:1 Gd:Pu mass ratio. Assuming a 1:1 equivalence with {sup 239}Pu, the results of these experiments show Gd is a viable poison for neutralizing U/Gd solutions with the tested compositions.

  19. The PIKfyveArPIKfyveSac3 triad in human breast cancer: Functional link between elevated Sac3 phosphatase and enhanced proliferation of triple negative cell lines

    SciTech Connect (OSTI)

    Ikonomov, Ognian C. Filios, Catherine Sbrissa, Diego Chen, Xuequn Shisheva, Assia

    2013-10-18

    Highlights: We assess PAS complex proteins and phosphoinositide levels in breast cancer cells. Sac3 and ArPIKfyve are markedly elevated in triple-negative breast cancer cells. Sac3 silencing inhibits proliferation in triple-negative breast cancer cell lines. Phosphoinositide profiles are altered in breast cancer cells. This is the first evidence linking high Sac3 with breast cancer cell proliferation. -- Abstract: The phosphoinositide 5-kinase PIKfyve and 5-phosphatase Sac3 are scaffolded by ArPIKfyve in the PIKfyveArPIKfyveSac3 (PAS) regulatory complex to trigger a unique loop of PtdIns3PPtdIns(3,5)P{sub 2} synthesis and turnover. Whereas the metabolizing enzymes of the other 3-phosphoinositides have already been implicated in breast cancer, the role of the PAS proteins and the PtdIns3PPtdIns(3,5)P{sub 2} conversion is unknown. To begin elucidating their roles, in this study we monitored the endogenous levels of the PAS complex proteins in cell lines derived from hormone-receptor positive (MCF7 and T47D) or triple-negative breast cancers (TNBC) (BT20, BT549 and MDA-MB-231) as well as in MCF10A cells derived from non-tumorigenic mastectomy. We report profound upregulation of Sac3 and ArPIKfyve in the triple negative vs. hormone-sensitive breast cancer or non-tumorigenic cells, with BT cell lines showing the highest levels. siRNA-mediated knockdown of Sac3, but not that of PIKfyve, significantly inhibited proliferation of BT20 and BT549 cells. In these cells, knockdown of ArPIKfyve had only a minor effect, consistent with a primary role for Sac3 in TNBC cell proliferation. Intriguingly, steady-state levels of PtdIns(3,5)P{sub 2} in BT20 and T47D cells were similar despite the 6-fold difference in Sac3 levels between these cell lines. However, steady-state levels of PtdIns3P and PtdIns5P, both regulated by the PAS complex, were significantly reduced in BT20 vs. T47D or MCF10A cell lines, consistent with elevated Sac3 affecting directly or indirectly the homeostasis of these lipids in TNBC. Together, our results uncover an unexpected role for Sac3 phosphatase in TNBC cell proliferation. Database analyses, discussed herein, reinforce the involvement of Sac3 in breast cancer pathogenesis.

  20. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Development of Elevated Temperature Aluminum Metal Matrix Composite (MMC) Alloy and Its Processing Technology

    SciTech Connect (OSTI)

    Weiss, David C.; Gegal, Gerald A.

    2014-04-15

    The objective of this project was to provide a production capable cast aluminum metal matrix composite (MMC) alloy with an operating temperature capability of 250-300°C. Important industrial sectors as well as the military now seek lightweight aluminum alloy castings that can operate in temperature ranges of 250-300°C. Current needs in this temperature range are being satisfied by the use of titanium alloy castings. These have the desired strength properties but the end components are heavier and significantly more costly. Also, the energy requirements for production of titanium alloy castings are significantly higher than those required for production of aluminum alloys and aluminum alloy castings.

  1. CONTAINMENT ANALYSIS METHODOLOGY FOR TRANSPORT OF BREACHED CLAD ALUMINUM SPENT FUEL

    SciTech Connect (OSTI)

    Vinson, D.

    2010-07-11

    Aluminum-clad, aluminum-based spent nuclear fuel (Al-SNF) from foreign and domestic research reactors (FRR/DRR) is being shipped to the Savannah River Site and placed in interim storage in a water basin. To enter the United States, a cask with loaded fuel must be certified to comply with the requirements in the Title 10 of the U.S. Code of Federal Regulations, Part 71. The requirements include demonstration of containment of the cask with its contents under normal and accident conditions. Many Al-SNF assemblies have suffered corrosion degradation in storage in poor quality water, and many of the fuel assemblies are 'failed' or have through-clad damage. A methodology was developed to evaluate containment of Al-SNF even with severe cladding breaches for transport in standard casks. The containment analysis methodology for Al-SNF is in accordance with the methodology provided in ANSI N14.5 and adopted by the U. S. Nuclear Regulatory Commission in NUREG/CR-6487 to meet the requirements of 10CFR71. The technical bases for the inputs and assumptions are specific to the attributes and characteristics of Al-SNF received from basin and dry storage systems and its subsequent performance under normal and postulated accident shipping conditions. The results of the calculations for a specific case of a cask loaded with breached fuel show that the fuel can be transported in standard shipping casks and maintained within the allowable release rates under normal and accident conditions. A sensitivity analysis has been conducted to evaluate the effects of modifying assumptions and to assess options for fuel at conditions that are not bounded by the present analysis. These options would include one or more of the following: reduce the fuel loading; increase fuel cooling time; reduce the degree of conservatism in the bounding assumptions; or measure the actual leak rate of the cask system. That is, containment analysis for alternative inputs at fuel-specific conditions and at cask-loading-specific conditions could be performed to demonstrate that release is within the allowable leak rates of the cask.

  2. Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells

    SciTech Connect (OSTI)

    R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

    2001-11-05

    During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

  3. Boron-carbide-aluminum and boron-carbide-reactive metal cermets. [B/sub 4/C-Al

    DOE Patents [OSTI]

    Halverson, D.C.; Pyzik, A.J.; Aksay, I.A.

    1985-05-06

    Hard, tough, lighweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidated step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modules of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi..sqrt..in. These composites and methods can be used to form a variety of structural elements.

  4. Methods of forming aluminum oxynitride-comprising bodies, including methods of forming a sheet of transparent armor

    DOE Patents [OSTI]

    Chu, Henry Shiu-Hung [Idaho Falls, ID; Lillo, Thomas Martin [Idaho Falls, ID

    2008-12-02

    The invention includes methods of forming an aluminum oxynitride-comprising body. For example, a mixture is formed which comprises A:B:C in a respective molar ratio in the range of 9:3.6-6.2:0.1-1.1, where "A" is Al.sub.2O.sub.3, "B" is AlN, and "C" is a total of one or more of B.sub.2O.sub.3, SiO.sub.2, Si--Al--O--N, and TiO.sub.2. The mixture is sintered at a temperature of at least 1,600.degree. C. at a pressure of no greater than 500 psia effective to form an aluminum oxynitride-comprising body which is at least internally transparent and has at least 99% maximum theoretical density.

  5. Recovery of aluminum oxide by the Ames lime-soda sinter process: scale-up using a rotary kiln

    SciTech Connect (OSTI)

    Murtha, M.J.; Burnet, G.; Harnby, N.

    1985-01-01

    The Ames Lime-Soda Sinter Process provides a means for recovering aluminum oxide from power plant fly ash while producing a residue that can be used in the manufacture of sulfate resistant (Type V) portland cement. The process has been fully researched and its feasibility is now being demonstrated through pilot plant scale investigation. This paper reports results of the pelletized feed preparation by agglomeration in a rotary pan granulator, continuous feed sintering in an electrically heated rotary kiln, and product recovery from the clinker by aqueous extraction, desilication of the filtrate, and precipitation of a hydrated aluminum oxide. Results from earlier bench-scale research have been found to apply consistently to the pilot plant scale work.

  6. New ionic liquids based on complexation of dipropylsulfide and AlCl3 for electrochodeposition of aluminum

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, Youxing; Jiang, Xueguang; Dai, Sheng; Sun, Xiao-Guang

    2015-01-01

    A new kind of ionic liquid based on complexation of dipropyl sulfide (DPS) and AlCl3 has been prepared. The equivalent concentration of AlCl3 in the ionic liquid is as high as 2.3 M. More importantly, it is highly fluidic and exhibits an ambient ionic conductivity of 1.25 x 10-4 S cm-1. This new ionic liquid can be successfully used as an electrolyte for electrodeposition of aluminum.

  7. Two step novel hydrogen system using additives to enhance hydrogen release from the hydrolysis of alane and activated aluminum

    DOE Patents [OSTI]

    Zidan, Ragaiy; Teprovich, Joseph A.; Motyka, Theodore

    2015-12-01

    A system for the generation of hydrogen for use in portable power systems is set forth utilizing a two-step process that involves the thermal decomposition of AlH.sub.3 (10 wt % H.sub.2) followed by the hydrolysis of the activated aluminum (Al*) byproduct to release additional H.sub.2. Additionally, a process in which water is added directly without prior history to the AlH.sub.3:PA composite is also disclosed.

  8. Oxidation Behavior of In-Flight Molten Aluminum Droplets in the Twin-Wire Electric Arc Thermal Spray Process

    SciTech Connect (OSTI)

    Donna Post Guillen; Brian G. Williams

    2005-05-01

    This paper examines the in-flight oxidation of molten aluminum sprayed in air using the twin-wire electric arc (TWEA) thermal spray process. The oxidation reaction of aluminum in air is highly exothermic and is represented by a heat generation term in the energy balance. Aerodynamic shear at the droplet surface enhances the amount of in-flight oxidation by: (1) promoting entrainment and mixing of the surface oxides within the droplet, and (2) causing a continuous heat generation effect that increases droplet temperature over that of a droplet without internal circulation. This continual source of heat input keeps the droplets in a liquid state during flight. A linear rate law based on the Mott-Cabrera theory was used to estimate the growth of the surface oxide layer formed during droplet flight. The calculated oxide volume fraction of an average droplet at impact agrees well with the experimentally determined oxide content for a typical TWEA-sprayed aluminum coating, which ranges from 3.3 to 12.7%. An explanation is provided for the elevated, nearly constant surface temperature (~ 2000 oC) of the droplets during flight to the substrate and shows that the majority of oxide content in the coating is produced during flight, rather than after deposition.

  9. Aluminum forms in stream sediment: Relation to bedrock geology and water chemistry

    SciTech Connect (OSTI)

    Turner, R.R.; Bogle, M.A.; Zeiler, M.A.; Mulholland, P.J.; Elwood, J.W.; Cook, R.B.

    1987-01-01

    Longitudinal gradients in sediment and water chemistry were characterized in a high elevation stream in the southern Appalachian Mountains, USA, to elucidate the geochemical behavior of aluminum across gradients in pH (4.5 to 6.5) and elevation (1120 to 1895 m). Observed gradients are driven in part by the presence of pyritic bedrock, which occurs at higher elevations and yields acidity when exposed to oxidation by landslide activity. Exchangeable Al in sediment (estimated using potassium chloride) varied in response to monomeric Al in streamwater and thus decreased downstream. Organic Al in sediment (estimated using sodium pyrophosphate) did not vary in proportion to the organic carbon content of sediment. Amorphous Al in sediment (estimated as the difference between oxalate- and pyrophosphate-extractable Al) and Al extractable with acidified streamwater (pH 4.5) was lowest at the more acidic sites. These results suggest that increases in soluble Al in downstream reaches during episodic pH depressions could be due in part to the release of adsorbed and/or precipitated Al in sediment.

  10. Structural and optical properties of DC reactive magnetron sputtered zinc aluminum oxide thin films

    SciTech Connect (OSTI)

    Kumar, B. Rajesh; Rao, T. Subba

    2014-10-15

    Highly transparent conductive Zinc Aluminum Oxide (ZAO) thin films have been deposited on glass substrates using DC reactive magnetron sputtering method. The thin films were deposited at 200 C and post-deposition annealing from 15 to 90 min. XRD patterns of ZAO films exhibit only (0 0 2) diffraction peak, indicating that they have c-axis preferred orientation perpendicular to the substrate. Scanning electron microscopy (SEM) is used to study the surface morphology of the films. The grain size obtained from SEM images of ZAO thin films are found to be in the range of 20 - 26 nm. The minimum resistivity of 1.74 10{sup ?4} ? cm and an average transmittance of 92% are obtained for the thin film post annealed for 30 min. The optical band gap of ZAO thin films increased from 3.49 to 3.60 eV with the increase of annealing time due to Burstein-Moss effect. The optical constants refractive index (n) and extinction coefficient (k) were also determined from the optical transmission spectra.

  11. Electrolytic conditioning of a magnesium aluminum chloride complex for reversible magnesium deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barile, Christopher J.; Barile, Elizabeth C.; Zavadil, Kevin R.; Nuzzo, Ralph G.; Gewirth, Andrew A.

    2014-12-04

    We describe in this report the electrochemistry of Mg deposition and dissolution from the magnesium aluminum chloride complex (MACC). The results define the requirements for reversible Mg deposition and definitively establish that voltammetric cycling of the electrolyte significantly alters its composition and performance. Elemental analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (SEM-EDS) results demonstrate that irreversible Mg and Al deposits form during early cycles. Electrospray ionization-mass spectrometry (ESI-MS) data show that inhibitory oligomers develop in THF-based solutions. These oligomers form via the well-established mechanism of a cationic ring-opening polymerization of THF during the initial synthesis of the MACC andmore » under resting conditions. In contrast, MACC solutions in 1,2-dimethoxyethane (DME), an acyclic solvent, do not evolve as dramatically at open circuit potential. Furthermore, we propose a mechanism describing how the conditioning process of the MACC in THF improves its performance by both tuning the Mg:Al stoichiometry and eliminating oligomers.« less

  12. Residual stress and plastic anisotropy in indented 2024-T351 aluminum disks

    SciTech Connect (OSTI)

    Clausen, Bjorn; Prime, Michael B; Saurabh, Kabra; Brown, Donald W; Pagliaro, Pierluigi; Backlund, Peter; Shaw, Sanjiv; Criss, Everett

    2009-01-01

    Recent studies have proven that generating a well defined residual stress state using the indented disk approach is an excellent way to validate experimental and modeling techniques for measuring and predicting residual stresses. The previous studies dealt with indented stainless steel disks, and included experimental determination of residual stresses using the Contour Method and neutron diffraction measurements. The measured residual stress states showed good agreement between the techniques, and a Finite Element Model predicted residual stress state based upon material properties determined form standard tension and compression/tension tests was also in good agreement with the measurements. In the present work, disks of 2024-T351 Aluminum were investigated. As before, the residual stress profile was measured using neutron diffraction and the Contour Method and Finite Element Modeling was employed to predict the residual stress profile. Analysis and comparison of the three techniques were complicated by the fact that the experimental data shows evidence of plastic anisotropy and strong Bauschinger effect within the indented disks.

  13. Electrolytic conditioning of a magnesium aluminum chloride complex for reversible magnesium deposition

    SciTech Connect (OSTI)

    Barile, Christopher J.; Barile, Elizabeth C.; Zavadil, Kevin R.; Nuzzo, Ralph G.; Gewirth, Andrew A.

    2014-12-04

    We describe in this report the electrochemistry of Mg deposition and dissolution from the magnesium aluminum chloride complex (MACC). The results define the requirements for reversible Mg deposition and definitively establish that voltammetric cycling of the electrolyte significantly alters its composition and performance. Elemental analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (SEM-EDS) results demonstrate that irreversible Mg and Al deposits form during early cycles. Electrospray ionization-mass spectrometry (ESI-MS) data show that inhibitory oligomers develop in THF-based solutions. These oligomers form via the well-established mechanism of a cationic ring-opening polymerization of THF during the initial synthesis of the MACC and under resting conditions. In contrast, MACC solutions in 1,2-dimethoxyethane (DME), an acyclic solvent, do not evolve as dramatically at open circuit potential. Furthermore, we propose a mechanism describing how the conditioning process of the MACC in THF improves its performance by both tuning the Mg:Al stoichiometry and eliminating oligomers.

  14. Microstructure characterization of the stir zone of submerged friction stir processed aluminum alloy 2219

    SciTech Connect (OSTI)

    Feng, Xiuli, E-mail: feng.97@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Liu, Huijie, E-mail: liuhj@hit.edu.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Lippold, John C., E-mail: lippold.1@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States)

    2013-08-15

    Aluminum alloy 2219-T6 was friction stir processed using a novel submerged processing technique to facilitate cooling. Processing was conducted at a constant tool traverse speed of 200 mm/min and spindle rotation speeds in the range from 600 to 800 rpm. The microstructural characteristics of the base metal and processed zone, including grain structure and precipitation behavior, were studied using optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Microhardness maps were constructed on polished cross sections of as-processed samples. The effect of tool rotation speed on the microstructure and hardness of the stir zone was investigated. The average grain size of the stir zone was much smaller than that of the base metal, but the hardness was also lower due to the formation of equilibrium ? precipitates from the base metal ?? precipitates. Stir zone hardness was found to decrease with increasing rotation speed (heat input). The effect of processing conditions on strength (hardness) was rationalized based on the competition between grain refinement strengthening and softening due to precipitate overaging. - Highlights: SZ grain size (? 1 ?m) is reduced by over one order of magnitude relative to the BM. Hardness in the SZ is lower than that of the precipitation strengthened BM. Metastable ?? in the base metal transforms to equilibrium ? in the stir zone. Softening in the SZ results from a decrease of precipitation strengthening.

  15. Stress-dependent recovery of point defects in deformed aluminum: An acoustic-damping study

    SciTech Connect (OSTI)

    Ogi, H.; Tsujimoto, A.; Hirao, M.; Ledbetter, H.

    1999-10-26

    The stress dependence of point-defect diffusion to dislocations in a 99.99% polycrystalline aluminum was studied using shear-wave attenuation and phase velocity. By holding the stress after deformation, attenuation and velocity approach their nonstressed values. The holding stress was varied between 0 and 12 MPa, after applying a 15 MPa compressive stress. Time-independent attenuation and stress-induced velocity change were introduced into the Granato-Hikata-Luecke theory, which first established the change of attenuation and velocity caused by the point-defect diffusion to dislocations. Good agreement was found between measurements and the modified theory. The stress dependence of the recovery rate was interpreted as a reduction of the migration energy of point defects diffusing to dislocations, and the activation volume was calculated for uniaxial stress. Electromagnetic acoustic resonance (EMAR) was used for the measurements. Being noncontact and highly sensitive, EMAR permitted detailed measurement of the attenuation and velocity evolutions during the unloading-holding stress sequence.

  16. Development of Cost-Effective Low-Permeability Ceramic and Refractory Components for Aluminum Melting and Casting

    SciTech Connect (OSTI)

    Dale E. Brown (Pyrotek); Puja B. Kadolkar (ORNL)

    2005-12-15

    The primary goal of this project was to develop and validate new classes of cost-effective low-permeability ceramic and refractory components for handling molten aluminum in both melting and casting environments. Three approaches were employed with partial to full success to achieve this goal: (1) Develop materials and methods for sealing surface porosity in thermal-shock-resistant ceramic refractories; (2) Develop new ceramic coatings for extreme service in molten aluminum operations, with particular emphasis on coatings based on highly stable oxide phases; and (3) Develop new monolithic refractories designed for lower-permeability applications using controlled porosity gradients and particle size distributions. The results of the research work and the field tests performed utilizing these three approaches are listed below: (1) It was demonstrated that high-density IR heating could be a tool for altering and sealing the surface porosity of fused silica. However, the process was not very cost-effective. (2) A low-cost glaze composition having a coefficient of thermal expansion (CTE) similar to that of a DFS tube was identified and was successfully tested for its integrity and adherence to DFS. Although the glaze acted as a barrier between the molten aluminum and the DFS, persistent porosity and crazing within the glaze affected its performance during the reactivity tests, thus acting as an obstacle in scaling up production of this glaze. (3) Pyrotek's XL glaze showed great success in improving the life of the DFS tubes. Pyrotek has reported an increasing market demand for the XL-coated DFS tubes, which exhibit useful lifetimes three times better than those of uncoated tubes. (4) A computer model to optimize particle size distribution for reduced permeability was developed and successfully applied to casting formulations. Silica riser tubes produced using these new formulations have been tested in a commercial aluminum casting facility and have been reported to increase the life of the DFS tubes by 700%. (5) If all the DFS riser tubes used in LPD casting of aluminum automotive components are replaced with the better, longer-lasting castable riser tubes, the potential national energy savings is estimated to be 206 billion Btu/year.

  17. New XDM-corrected potential energy surfaces for ArNO(X{sup 2}?): A comparison with CCSD(T) calculations and experiments

    SciTech Connect (OSTI)

    Warehime, Michael; Johnson, Erin R.; K?os, Jacek

    2015-01-14

    We report new potential energy surfaces for the ground state ArNO(X{sup 2}?) van der Waals system calculated using the unrestricted Hartree-Fock (UHF) method with the addition of the Becke-Roussel correlation functional and exchange-hole dipole moment dispersion correction (XDM). We compare UHFBR-XDM surfaces and those previously reported by Alexander from coupled cluster CCSD(T) calculations [J. Chem. Phys. 111, 7426 (1999)]. The bound states of ArNO have been investigated with these new UHFBR-XDM surfaces, including relative energy-level spacing, adiabatic bender states and wave functions, and spectroscopic data. These results have been found to be in good agreement with calculations based on the CCSD(T) PESs. These new PESs are used to investigate the inelastic scattering of NO(X) by Ar. Full close-coupling integral cross sections at collision energies of 442 cm{sup ?1}, 1774 cm{sup ?1} and differential cross sections at collision energy of 530 cm{sup ?1} were determined for transitions out of the lowest NO(X) rotational level (j = ? = 1/2,f). These cross sections are in good agreement with those calculated with CCSD(T) and accordingly in good agreement with the most recent initial and final state resolved experimental data. The UHFBR-XDM scheme yields high-quality potential surfaces with computational cost comparable to the Hartree-Fock method and our results may serve as a benchmark for application of this scheme to collisions between larger molecules.

  18. Experimental and theoretical study of the ion-ion mutual neutralization reactions Ar{sup +}+SF{sub n}{sup -} (n=6, 5, and 4)

    SciTech Connect (OSTI)

    Bopp, Joseph C.; Miller, Thomas M.; Viggiano, Albert A.; Troe, Juergen

    2008-08-21

    The ion-ion mutual neutralization reactions Ar{sup +}+SF{sub n}{sup -}{yields}Ar+SF{sub n} (n=6, 5, and 4) have been studied in a flowing afterglow-Langmuir probe (FALP) apparatus at 300 K and 1 Torr of He buffer gas. Electron concentrations and product ion fractions were measured, and neutralization rate constants of 4.0x10{sup -8}, 3.8x10{sup -8}, and 4x10{sup -8} cm{sup 3} s{sup -1} for SF{sub 6}{sup -}, SF{sub 5}{sup -}, and SF{sub 4}{sup -}, respectively, were derived, with uncertainties of {+-}25% ({+-}35% for SF{sub 4}{sup -}). During the neutralization process, excited neutrals are generated that are able to dissociate to neutral fragments. In the case of SF{sub 6}, the formation of SF{sub 5} and SF{sub 4}, and similarly in the case of SF{sub 5}, the formation of SF{sub 4} and SF{sub 3} were observed and quantified. The mechanism of primary and secondary reaction was analyzed in detail, and rate constants for the dissociative electron attachments e{sup -}+SF{sub 5}{yields}F{sup -}+SF{sub 4} (k=3x10{sup -9} cm{sup 3} s{sup -1},{+-}40%) and e{sup -}+SF{sub 3}{yields}F{sup -}+SF{sub 2} (k=2x10{sup -8} cm{sup 3} s{sup -1},+400%,-75%) were also derived. The experimental ion-ion neutralization rate constants were found to be in good agreement with estimates from an optimum two-state double-passage Landau-Zener model. It was also found that energy partitioning in the neutralization is related to the extent of electronic excitation of Ar generated by the electron transfer processes.

  19. Modeling of inductively coupled plasma SF{sub 6}/O{sub 2}/Ar plasma discharge: Effect of O{sub 2} on the plasma kinetic properties

    SciTech Connect (OSTI)

    Pateau, Amand; Rhallabi, Ahmed Fernandez, Marie-Claude; Boufnichel, Mohamed; Roqueta, Fabrice

    2014-03-15

    A global model has been developed for low-pressure, inductively coupled plasma (ICP) SF{sub 6}/O{sub 2}/Ar mixtures. This model is based on a set of mass balance equations for all the considered species, coupled with the discharge power balance equation and the charge neutrality condition. The present study is an extension of the kinetic global model previously developed for SF{sub 6}/Ar ICP plasma discharges [Lallement et al., Plasma Sources Sci. Technol. 18, 025001 (2009)]. It is focused on the study of the impact of the O{sub 2} addition to the SF{sub 6}/Ar gas mixture on the plasma kinetic properties. The simulation results show that the electron density increases with the %O{sub 2}, which is due to the decrease of the plasma electronegativity, while the electron temperature is almost constant in our pressure range. The density evolutions of atomic fluorine and oxygen versus %O{sub 2} have been analyzed. Those atomic radicals play an important role in the silicon etching process. The atomic fluorine density increases from 0 up to 40% O{sub 2} where it reaches a maximum. This is due to the enhancement of the SF{sub 6} dissociation processes and the production of fluorine through the reactions between SF{sub x} and O. This trend is experimentally confirmed. On the other hand, the simulation results show that O(3p) is the preponderant atomic oxygen. Its density increases with %O{sub 2} until reaching a maximum at almost 40% O{sub 2}. Over this value, its diminution with O{sub 2}% can be justified by the high increase in the loss frequency of O(3p) by electronic impact in comparison to its production frequency by electronic impact with O{sub 2}.

  20. Evaluation of Aluminum-Boron Carbide Neutron Absorbing Materials for Interim Storage of Used Nuclear Fuel

    SciTech Connect (OSTI)

    Wang, Lumin; Wierschke, Jonathan Brett

    2015-04-08

    The objective of this work was to understand the corrosion behavior of Boral® and Bortec® neutron absorbers over long-term deployment in a used nuclear fuel dry cask storage environment. Corrosion effects were accelerated by flowing humidified argon through an autoclave at temperatures up to 570°C. Test results show little corrosion of the aluminum matrix but that boron is leaching out of the samples. Initial tests performed at 400 and 570°C were hampered by reduced flow caused by the rapid build-up of solid deposits in the outlet lines. Analysis of the deposits by XRD shows that the deposits are comprised of boron trioxide and sassolite (H3BO3). The collection of boron- containing compounds in the outlet lines indicated that boron was being released from the samples. Observation of the exposed samples using SEM and optical microscopy show the growth of new phases in the samples. These phases were most prominent in Bortec® samples exposed at 570°C. Samples of Boral® exposed at 570°C showed minimal new phase formation but showed nearly the complete loss of boron carbide particles. Boron carbide loss was also significant in Boral samples at 400°C. However, at 400°C phases similar to those found in Bortec® were observed. The rapid loss of the boron carbide particles in the Boral® is suspected to inhibit the formation of the new secondary phases. However, Material samples in an actual dry cask environment would be exposed to temperatures closer to 300°C and less water than the lowest test. The results from this study conclude that at the temperature and humidity levels present in a dry cask environment, corrosion and boron leaching will have no effect on the performance of Boral® and Bortec® to maintain criticality control.

  1. Orientation effects on the measurement and analysis of critical CTOA in an aluminum alloy sheet

    SciTech Connect (OSTI)

    Sutton, M.A.; Dawicke, D.S.; Newman, J.C. Jr.

    1995-12-31

    Fracture tests were conducted on 76.2 mm wide, 2.3 mm thick middle crack tension (M(T)) specimens machined from 2024-T3 aluminum sheet. The specimens were tested in the T-L orientation and comparisons were made to similar tests conducted in the L-T orientation. Measurement of critical crack tip opening angle (CTOA), applied stress, and crack front shape were made as a function of crack extension. A two-dimensional, elastic-plastic finite element analysis was used to simulate the fracture behavior for both orientations. The results indicate that the T-L orientation had a 10% lower stress at fracture than similar tests conducted in the L-T orientation. Correspondingly, the critical CTOA in the T-L tests reached a constant value of 4.7{degree} after 2--3 mm of crack extension and the L-T tests reached a value of 6{degree}. The fracture surface of the T-L specimens were observed to remain flat, while those of the L-T specimens transitioned to a 45{degree} slant fracture after about 2--3 mm of crack extension. The tunneling behavior of the two orientations also differed; the T-L specimens reached a deeply tunneled stabilized crack front shape, while the L-T specimens were observed to have only a small amount of tunneling once the crack began to grow on the 45{degree} slant. The two-dimensional, elastic-plastic finite element analysis was able to simulate the fracture behavior for both the T-L and L-T orientations.

  2. Precipitation of aluminum nitride in a high strength maraging steel with low nitrogen content

    SciTech Connect (OSTI)

    Jeanmaire, G.; Dehmas, M.; Redjamia, A.; Puech, S.; Fribourg, G.

    2014-12-15

    In the present work, aluminum nitride (AlN) precipitation was investigated in a X23NiCoCrMoAl13-6-3 maraging steel with low nitrogen content (wt.% N = 5.5 ppm). A reliable and robust automatic method by scanning electron microscopy observations coupled with energy dispersive X-ray spectroscopy was developed for the quantification of AlN precipitates. The first stage was to identify the solvus temperature and to develop a heat treatment able to dissolve the AlN precipitates. The experimental determination of equilibrium conditions and solvus temperature show good agreement with ThermoCalc simulation. Then, from this AlN-free state, the cooling rate, isothermal holding time and temperature were the subject of an intensive investigation in the austenite region of this maraging steel. In spite of the high temperatures used during heat treatments, the growth kinetic of the largest AlN precipitates (> 1 ?m) is slow. The cooling rate has a major effect on the size and the number density of AlN due to a higher driving force for nucleation at low temperatures. At last, quenching prior to isothermal annealing at high temperatures leads to fine and dense AlN precipitation, resulting from the martensite to austenite transformation. Experimental results will be discussed and compared with kinetic data obtained with the mobility database MobFe2 implemented in Dictra software. - Highlights: Slow dissolution kinetic of AlN precipitates due to both their large size and small chemical driving force Significant effects of cooling rate prior isothermal heat treatment, holding time and temperature on AlN precipitation Size of AlN precipitates can be reduced by quenching prior isothermal holding. Fine precipitation of AlN related to the ? ? ? transformation.

  3. An improved three-dimensional two-temperature model for multi-pulse femtosecond laser ablation of aluminum

    SciTech Connect (OSTI)

    Zhang, Jinping; Chen, Yuping Hu, Mengning; Chen, Xianfeng

    2015-02-14

    In this paper, an improved three-dimensional two-temperature model for multi-pulse femtosecond laser ablation of aluminum was proposed and proved in our experiment. Aiming to achieve hole-drilling with a high ratio of depth/entrance diameter in vacuum, this model can predict the depth and radius of the drilled holes precisely when employing different laser parameters. Additionally, for multi-pulse laser ablation, we found that the laser fluence and number of pulses are the dominant parameters and the multi-pulse ablation threshold is much lower than the single-pulse one, which will help to obtain high-quality holes.

  4. Controlled growth and multi-photon luminescence of hexagonal arrays of Au nanoparticles on anodic aluminum oxide templates

    SciTech Connect (OSTI)

    Li Jianbo; Yu Ying; Peng Xiaoniu; Yang Zhongjian; Zhou Li; Zhou Zhangkai

    2012-06-15

    Au nanoparticles were deposited onto anodic aluminum oxide (AAO) templates by using a rotating sputtering technique. Interestingly, hexagonal arrays of Au nanoparticles were obtained at an appropriate rotating rate and deposition time. Strong three-photon luminescence was observed from the hexagonally arrayed Au nanoparticles, which is attributed to the strong enhancements of local electromagnetic fields at both excitation and emission wavelengths. Our findings provide a new method to prepare Au nanoparticle arrays with large field enhancements and could have prospective applications in plasmonic nanodevices, such as surface-enhanced Raman scattering substrates, and biosensors.

  5. New ionic liquids based on complexation of dipropylsulfide and AlCl3 for electrochodeposition of aluminum

    SciTech Connect (OSTI)

    Fang, Youxing; Jiang, Xueguang; Dai, Sheng; Sun, Xiao-Guang

    2015-01-01

    A new kind of ionic liquid based on complexation of dipropyl sulfide (DPS) and AlCl3 has been prepared. The equivalent concentration of AlCl3 in the ionic liquid is as high as 2.3 M. More importantly, it is highly fluidic and exhibits an ambient ionic conductivity of 1.25 x 10-4 S cm-1. This new ionic liquid can be successfully used as an electrolyte for electrodeposition of aluminum.

  6. Atomic layer deposited lithium aluminum oxide: (In)dependency of film properties from pulsing sequence

    SciTech Connect (OSTI)

    Miikkulainen, Ville Nilsen, Ola; Fjellvg, Helmer; Li, Han; King, Sean W.; Laitinen, Mikko; Sajavaara, Timo

    2015-01-01

    Atomic layer deposition (ALD) holds markedly high potential of becoming the enabling method for achieving the three-dimensional all-solid-state thin-film lithium ion battery (LiB). One of the most crucial components in such a battery is the electrolyte that needs to hold both low electronic conductivity and at least fair lithium ion conductivity being at the same time pinhole free. To obtain these desired properties in an electrolyte film, one necessarily has to have a good control over the elemental composition of the deposited material. The present study reports on the properties of ALD lithium aluminum oxide (Li{sub x}Al{sub y}O{sub z}) thin films. In addition to LiB electrolyte applications, Li{sub x}Al{sub y}O{sub z} is also a candidate low dielectric constant (low-k) etch stop and diffusion barrier material in nanoelectronics applications. The Li{sub x}Al{sub y}O{sub z} films were deposited employing trimethylaluminum-O{sub 3} and lithium tert-butoxide-H{sub 2}O for Al{sub 2}O{sub 3} and Li{sub 2}O/LiOH, respectively. The composition was aimed to be controlled by varying the pulsing ratio of those two binary oxide ALD cycles. The films were characterized by several methods for composition, crystallinity and phase, electrical properties, hardness, porosity, and chemical environment. Regardless of the applied pulsing ratio of Al{sub 2}O{sub 3} and Li{sub 2}O/LiOH, all the studied ALD Li{sub x}Al{sub y}O{sub z} films of 200 and 400 nm in thickness were polycrystalline in the orthorhombic ?-LiAlO{sub 2} phase and also very similar to each other with respect to composition and other studied properties. The results are discussed in the context of both fundamental ALD chemistry and applicability of the films as thin-film LiB electrolytes and low-k etch stop and diffusion barriers.

  7. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION FINAL REPORT 08R1360-1

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT W; PEGG IL; JOSEPH I; BARDAKCI T; GAN H; GONG W; CHAUDHURI M

    2010-01-04

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in wasteloading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  8. Direct comparative study on the energy level alignments in unoccupied/occupied states of organic semiconductor/electrode interface by constructing in-situ photoemission spectroscopy and Ar gas cluster ion beam sputtering integrated analysis system

    SciTech Connect (OSTI)

    Yun, Dong-Jin Chung, JaeGwan; Kim, Yongsu; Park, Sung-Hoon; Kim, Seong-Heon; Heo, Sung

    2014-10-21

    Through the installation of electron gun and photon detector, an in-situ photoemission and damage-free sputtering integrated analysis system is completely constructed. Therefore, this system enables to accurately characterize the energy level alignments including unoccupied/occupied molecular orbital (LUMO/HOMO) levels at interface region of organic semiconductor/electrode according to depth position. Based on Ultraviolet Photoemission Spectroscopy (UPS), Inverse Photoemission Spectroscopy (IPES), and reflective electron energy loss spectroscopy, the occupied/unoccupied state of in-situ deposited Tris[4-(carbazol-9-yl)phenyl]amine (TCTA) organic semiconductors on Au (E{sub LUMO}: 2.51?eV and E{sub HOMO}: 1.35?eV) and Ti (E{sub LUMO}: 2.19?eV and E{sub HOMO}: 1.69?eV) electrodes are investigated, and the variation of energy level alignments according to work function of electrode (Au: 4.81?eV and Ti: 4.19?eV) is clearly verified. Subsequently, under the same analysis condition, the unoccupied/occupied states at bulk region of TCTA/Au structures are characterized using different Ar gas cluster ion beam (Ar GCIB) and Ar ion sputtering processes, respectively. While the Ar ion sputtering process critically distorts both occupied and unoccupied states in UPS/IPES spectra, the Ar GCIB sputtering process does not give rise to damage on them. Therefore, we clearly confirm that the in-situ photoemission spectroscopy in combination with Ar GCIB sputtering allows of investigating accurate energy level alignments at bulk/interface region as well as surface region of organic semiconductor/electrode structure.

  9. Acetylene from the co-pyrolysis of biomass and waste tires or coal in the H{sub 2}/Ar plasma

    SciTech Connect (OSTI)

    Bao, W.; Cao, Q.; Lv, Y.; Chang, L.

    2008-07-01

    Acetylene from carbon-containing materials via plasma pyrolysis is not only simple but also environmentally friendly. In this article, the acetylene produced from co-pyrolyzing biomass with waste tire or coal under the conditions of H{sub 2}/Ar DC arc plasma jet was investigated. The experimental results showed that the co-pyrolysis of mixture with biomass and waste tire or coal can improve largely the acetylene relative volume fraction (RVF) in gaseous products and the corresponding yield of acetylene. The change trends for the acetylene yield of plasma pyrolysis from mixture with raw sample properties were the same as relevant RVF. But the yield change trend with feeding rate is different from its RVF. The effects of the feeding rate of raw materials and the electric current of plasmatron on acetylene formation are also discussed.

  10. Glow-to-arc transition events in H{sub 2}-Ar direct current pulsed plasma: Automated measurement of current and voltage

    SciTech Connect (OSTI)

    Mendes, Luciano A.; Rodrigues, Jhonatam C.; Mafra, Marcio

    2012-01-15

    The glow-to-arc transition phenomena (arcing) observed in plasma reactors used in materials processing was studied through the arcs characteristic current and voltage waveforms. In order to capture these arcs signals, a LABVIEW based automated instrumentation system (ARCVIEW) was developed, including the integration of an oscilloscope equipped with proper current and voltage probes. The system also allows capturing the process parameters at the arc occurrence moments, which were used to map the arcs events conditions. Experiments in H{sub 2}-Ar DC pulsed plasma returned signals data from 215 arcs events, which were analyzed through software routines. According to the results, an anti-arcing system should react in the time order of few microseconds to prevent most of the damage caused by the undesired arcing phenomena.

  11. Understanding composite explosive energetics: 4. Reactive flow modeling of aluminum reaction kinetics in PETN and TNT using normalized product equation of state

    SciTech Connect (OSTI)

    Tao, W.C.; Tarver, C.M.; Kury, J.W.; Lee, C.G.; Ornellas, D.L.

    1993-07-01

    Using Fabry-Perot interferometry techniques, we have determined the early time rate of energy release from detonating PETN and TNT explosives filled with 5 to 20 wt % of either 5 {mu}m or 18 {mu}m spherical aluminum with the detonation products, and calculate the extent of reaction at 1--3 {mu}s after the detonation. All of the metal in PETN formulations filled with 5 wt % and 10 wt % of either 5 {mu}m or 18 {mu}m aluminum reacted within 1.5 {mu}s, resulting in an increase of 18--22% in energy compared to pure PETN. For TNT formulations, between 5 to 10 wt % aluminum reacts completely with the same timeframe. A reactive flow hydrodynamic code model based on the Zeldovich-von Neumann-Doring (ZND) description of the reaction zone and subsequent reaction product expansion (Taylor wave) is used to address the reaction rate of the aluminum particles with detonation product gases. The detonation product JWL equation of state is derived from that of pure PETN using a parametric normalization methodology.

  12. Optical properties of chromium and neodymium in zirconium-barium-lanthanum-aluminum fluoride glass. Final report, October 1987-September 1988

    SciTech Connect (OSTI)

    Hanson, F.E.; Caspers, H.H.

    1993-08-01

    The optical properties are reported of chromium and neodymium doped in zirconium-barium-lanthanum-aluminum fluoride glass (ZBLA). The fluorescence of Cr(3+) and of co-doped Cr(3+), Nd(3+) glasses is investigated. Fluorescence decay rates of Cr(3+) and Nd(3+) are measured at various temperatures, and the excitation transfer efficiency between Cr(3+) and Nd(3+) is determined. The absorption spectrum of Nd(3+):ZBLA is characterized in terms of the Judd-Ofelt model of crystal field-induced electric-dipole transitions. The three phenomenological intensity parameters for Nd(3+) in ZBLA glass Omega sub 2,4,6, are compared to those obtained for Nd(3+) in Y3Al5Ol2, Gd3S2Al3Ol2, and LHG-8 glass.

  13. DETERMINATION OF IN-VITRO LUNG SOLUBILITY AND INTAKE-TO-DOSE CONVERSION FACTOR FOR TRITIATED LANTHANUM NICKEL ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Farfan, E.; Labone, T.; Staack, G.; Cheng, Y.; Zhou, Y.; Varallo, T.

    2011-11-11

    A sample of tritiated lanthanum nickel aluminum alloy (LaNi4.25Al0.75 or LANA.75) similar to that used at the Savannah River Site Tritium Facilities was analyzed to estimate the particle size distribution of this metal tritide powder and the rate, at which this material dissolves in the human respiratory tract after it is inhaled. This information is used to calculate the committed effective dose received by a worker after inhaling the material. These doses, which were calculated using the same methodology given in the DOE Tritium Handbook, are presented as inhalation intake-to-dose conversion factors (DCF). The DCF for this metal tritide is less than the DCF for tritiated water and radiation worker bioassay programs designed for tritiated water are adequate to monitor for intakes of this material.

  14. Method using selected carbons to react with Al2O and Al vapors in the carbothermic production of aluminum

    DOE Patents [OSTI]

    Fruehan, Richard J.; Li, Yun; Carkin, Gerald

    2005-02-01

    In a method for recovering Al from an off-gas (3,4) produced during carbothermic reduction of aluminum utilizing at least one smelter (1,2), the off-gas (3,4) is directed to an enclosed reactor (5) which is fed a supply of wood charcoal (7) having a porosity of from about 50 vol. % to 85 vol. % and an average pore diameter of from about 0.05 .mu.m to about 2.00 .mu.m, where the wood charcoal (7) contacts the off-gas (3,4) to produce at least Al.sub.4 C.sub.3 (6), which is passed back to the smelter (1,2).

  15. A density functional tight binding/force field approach to the interaction of molecules with rare gas clusters: Application to (C{sub 6}H{sub 6}){sup +/0}Ar{sub n} clusters

    SciTech Connect (OSTI)

    Iftner, Christophe; Simon, Aude; Korchagina, Kseniia; Rapacioli, Mathias; Spiegelman, Fernand

    2014-01-21

    We propose in the present paper a SCC-DFTB/FF (Self-Consistent-Charge Density Functional based Tight Binding/Force-Field) scheme adapted to the investigation of molecules trapped in rare gas environments. With respect to usual FF descriptions, the model involves the interaction of quantum electrons in a molecule with rare gas atoms in an anisotropic scheme. It includes polarization and dispersion contributions and can be used for both neutral and charged species. Parameters for this model are determined for hydrocarbon-argon complexes and the model is validated for small hydrocarbons. With the future aim of studying polycyclic aromatic hydrocarbons in Ar matrices, extensive benchmark calculations are performed on (C{sub 6}H{sub 6}){sup +/0}Ar{sub n} clusters against DFT and CCSD(T) calculations for the smaller sizes, and more generally against other experimental and theoretical data. Results on the structures and energetics (isomer ordering and energy separation, cohesion energy per Ar atom) are presented in detail for n = 18, 13, 20, 27, and 30, for both neutrals and cations. We confirm that the clustering of Ar atoms leads to a monotonous decrease of the ionization potential of benzene for n ? 20, in line with previous experimental and FF data.

  16. Study of metallic powder behavior in very low pressure plasma spraying (VLPPS) Application to the manufacturing of titaniumaluminum coatings

    SciTech Connect (OSTI)

    Vautherin, B.; Planche, M.-P.; Montavon, G.; Lapostolle, F.; Quet, A.; Bianchi, L.

    2015-08-28

    In this study, metallic materials made of aluminum and titanium were manufactured implementing very low pressure plasma spraying (VLPPS). Aluminum was selected at first as a demonstrative material due to its rather low vaporization enthalpy (i.e., 381.9 kJmol?). Developments were then carried out with titanium which exhibits a higher vaporization enthalpy (i.e., 563.6 kJmol?). Optical emission spectroscopy (OES) was implemented to analyze the behavior of each solid precursor (metallic powders) when it is injected into the plasma jet under very low pressure (i.e., in the 150 Pa range). Besides, aluminum, titanium and titaniumaluminum coatings were deposited in the same conditions implementing a stick-cathode plasma torch operated at 50 kW, maximum power. Coating phase compositions were identified by X-Ray Diffraction (XRD). Coating elementary compositions were quantified by Glow Discharge Optical Emission Spectroscopy (GDOES) and Energy Dispersive Spectroscopy (EDS) analyses. The coating structures were observed by Scanning Electron Microscopy (SEM). The coating void content was determined by Ultra-Small Angle X-ray Scattering (USAXS). The coatings exhibit a two-scale structure corresponding to condensed vapors (smaller scale) and solidified areas (larger scale). Titaniumaluminum sprayed coatings, with various Ti/Al atomic ratios, are constituted of three phases: metastable ?-Ti, Al and metastable ??-Ti?Al. This latter is formed at elevated temperature in the plasma flow, before being condensed. Its rather small fraction, impeded by the rather small amount of vaporized Ti, does not allow modifying however the coating hardness.

  17. High-nitrogen-metal complexes as burning-rate modifiers for the aluminum-water propellant system

    SciTech Connect (OSTI)

    Tappan, Bryce C; Mason, Benjamin A

    2009-01-01

    The reactions of electropositive metals, such as aluminum, with water have long been utilized in explosive and propellant formulations, but until recently this has mostly been limited to the water formed as a product gas from the decomposition of another energetic system . Recently, however, with the increased availability of nano-particulate materials, the direct reaction of nano-aluminum (nAl) with water as an oxidizer has been investigated as a propellant system due to high reaction temperatures and the production of hydrogen as the primary gaseous species. This system could be useful for intra-planetary travel where non-terrestrial water is harvested for the oxidizer. Here we present the study of nAl, mixed at a stoichiometric ratio with water ({Phi} = 1) with the highly water soluble metal complexes of bis(tetrazolato)amine (BTA) added at 5, 15,30 and 50 wt% in the case of FeBTA and 5 and 15 wt% in the case of NiBTA and CoBTA. The basic structure of the BTA complexes is shown below where M = Fe, Ni or Co, and x = 3 for Fe and Co and x = 2 for Ni. The particle size of nAl studied was primarily 38 nm with various studies with the particle size of 80 nm. The FeBT A at a loading of 15 wt% gave the highest burning rate enhancement (4.6x at {approx}6.8 MPa), while retaining a low pressure exponent (0.21 compared to 0.24 for nA/H{sub 2}O). At 15 wt% the Ni and Co increased the burning rate, but also increased the pressure exponents. The burning rate of the FeBTA modified material with 80 nm Al decreased as the weight percent of FeBTA was increased, which also tracked decrease in the calculated specific impulse of the mixtures.

  18. Ductile Tearing of Thin Aluminum Plates Under Blast Loading. Predictions with Fully Coupled Models and Biaxial Material Response Characterization

    SciTech Connect (OSTI)

    Corona, Edmundo; Gullerud, Arne S.; Haulenbeek, Kimberly K.; Reu, Phillip L.

    2015-06-01

    The work presented in this report concerns the response and failure of thin 2024- T3 aluminum alloy circular plates to a blast load produced by the detonation of a nearby spherical charge. The plates were fully clamped around the circumference and the explosive charge was located centrally with respect to the plate. The principal objective was to conduct a numerical model validation study by comparing the results of predictions to experimental measurements of plate deformation and failure for charges with masses in the vicinity of the threshold between no tearing and tearing of the plates. Stereo digital image correlation data was acquired for all tests to measure the deflection and strains in the plates. The size of the virtual strain gage in the measurements, however, was relatively large, so the strain measurements have to be interpreted accordingly as lower bounds of the actual strains in the plate and of the severity of the strain gradients. A fully coupled interaction model between the blast and the deflection of the structure was considered. The results of the validation exercise indicated that the model predicted the deflection of the plates reasonably accurately as well as the distribution of strain on the plate. The estimation of the threshold charge based on a critical value of equivalent plastic strain measured in a bulge test, however, was not accurate. This in spite of efforts to determine the failure strain of the aluminum sheet under biaxial stress conditions. Further work is needed to be able to predict plate tearing with some degree of confidence. Given the current technology, at least one test under the actual blast conditions where the plate tears is needed to calibrate the value of equivalent plastic strain when failure occurs in the numerical model. Once that has been determined, the question of the explosive mass value at the threshold could be addressed with more confidence.

  19. Mechanism and computational model for Lyman-{alpha}-radiation generation by high-intensity-laser four-wave mixing in Kr-Ar gas

    SciTech Connect (OSTI)

    Louchev, Oleg A.; Saito, Norihito; Wada, Satoshi; Bakule, Pavel; Yokoyama, Koji; Ishida, Katsuhiko; Iwasaki, Masahiko

    2011-09-15

    We present a theoretical model combined with a computational study of a laser four-wave mixing process under optical discharge in which the non-steady-state four-wave amplitude equations are integrated with the kinetic equations of initial optical discharge and electron avalanche ionization in Kr-Ar gas. The model is validated by earlier experimental data showing strong inhibition of the generation of pulsed, tunable Lyman-{alpha} (Ly-{alpha}) radiation when using sum-difference frequency mixing of 212.6 nm and tunable infrared radiation (820-850 nm). The rigorous computational approach to the problem reveals the possibility and mechanism of strong auto-oscillations in sum-difference resonant Ly-{alpha} generation due to the combined effect of (i) 212.6-nm (2+1)-photon ionization producing initial electrons, followed by (ii) the electron avalanche dominated by 843-nm radiation, and (iii) the final breakdown of the phase matching condition. The model shows that the final efficiency of Ly-{alpha} radiation generation can achieve a value of {approx}5x10{sup -4} which is restricted by the total combined absorption of the fundamental and generated radiation.

  20. Energy levels, oscillator strengths and transition probabilities for Si-like P II, S III, Cl IV, Ar V and K VI

    SciTech Connect (OSTI)

    Abou El-Maaref, A.; Uosif, M.A.M.; Allam, S.H.; El-Sherbini, Th.M.

    2012-07-15

    Fine-structure calculations of energy levels, oscillator strengths, and transition probabilities for transitions among the terms belonging to 3s{sup 2}3p{sup 2}, 3s3p{sup 3}, 3s{sup 2}3p3d, 3s{sup 2}3p4s, 3s{sup 2}3p4p, 3s{sup 2}3p4d, 3s{sup 2}3p5s and 3s{sup 2}3p5p configurations of silicon-like ions P II, S III, Cl IV, Ar V and K VI have been calculated using configuration-interaction version 3 (CIV3). We compared our data with the available experimental data and other theoretical calculations. Most of our calculations of energy levels and oscillator strengths (in length form) show good agreement with both experimental and theoretical data. Lifetimes of the excited levels are also given.

  1. Reduction of Carbon Footprint and Energy Efficiency Improvement in Aluminum Production by Use of Novel Wireless Instrumentation Integrated with Mathematical Modeling

    SciTech Connect (OSTI)

    James W. Evans

    2012-04-11

    The work addressed the greenhouse gas emission and electrical energy consumption of the aluminum industry. The objective was to provide a means for reducing both through the application of wireless instrumentation, coupled to mathematical modeling. Worldwide the aluminum industry consumes more electrical energy than all activities in many major countries (e.g. the UK) and emits more greenhouse gasses (e.g. than France). Most of these excesses are in the 'primary production' of aluminum; that is the conversion of aluminum oxide to metal in large electrolytic cells operating at hundreds of thousands of amps. An industry-specific GHG emission has been the focus of the work. The electrolytic cells periodically, but at irregular intervals, experience an upset condition known as an 'anode effect'. During such anode effects the cells emit fluorinated hydrocarbons (PFCs, which have a high global warming potential) at a rate far greater than in normal operation. Therefore curbing anode effects will reduce GHG emissions. Prior work had indicated that the distribution of electrical current within the cell experiences significant shifts in the minutes before an anode effect. The thrust of the present work was to develop technology that could detect and report this early warning of an anode effect so that the control computer could minimize GHG emissions. A system was developed to achieve this goal and, in collaboration with Alcoa, was tested on two cells at an Alcoa plant in Malaga, Washington. The project has also pointed to the possibility of additional improvements that could result from the work. Notable among these is an improvement in efficiency that could result in an increase in cell output at little extra operating cost. Prospects for commercialization have emerged in the form of purchase orders for further installations. The work has demonstrated that a system for monitoring the current of individual anodes in an aluminum cell is practical. Furthermore the system has been installed twice on a smelter in the US without exposing workers to hazards usually associated with running signal wires in aluminum plants. The results display the early warning of an anode effect that potentially can be used to minimize such anode effects with their excessive GHG emissions. They also point to a possible, but substantial, economic benefit that could result in improved current efficiency by anode adjustment based on individual anode current measurements.

  2. DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING GLASS FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL; JOSEPH I

    2009-12-30

    This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP contract requirements. The WTP's overall mission will require the immobilization oftank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in waste-loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  3. Energy Assessment Helps Kaiser Aluminum Save Energy and Improve Productivity; DOE Software Adopted as Standard for Analyzing Plant Process Heating Systems Company-Wide; Industrial Technologies Program (ITP) Save Energy Now (SEN) Case Study

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kaiser Aluminum plant in Sherman, Texas, improved its annual furnace energy intensity by 11.1% after imple- menting recommendations from the Save Energy Now assessment. Energy Assessment Helps Kaiser Aluminum Save Energy and Improve Productivity DOE Software Adopted as Standard for Analyzing Plant Process Heating Systems Company-Wide Industrial Technologies Program Case Study Key Findings * Opportunities for energy efficiency do not require large capital expenditures to achieve significant

  4. DEGRADATION OF SM2ZR2O7 THERMAL BARRIER COATING CAUSED BY CALCIUM-MAGNESIUM-ALUMINUM-SILICON OXIDE (CMAS) DEPOSITION

    SciTech Connect (OSTI)

    Wang, Honglong; Sheng, Zhizhi; Tarwater, Emily; Zhang, Xingxing; Dasgupta, Sudip; Fergus, Jeffrey

    2015-03-16

    Rare earth zirconates are promising materials for use as thermal barrier coatings in gas turbine engines. Among the lanthanide zirconate materials, Sm2Zr2O7 with the pyrochlore structure has lower thermal conductivity and better corrosion resistance against calcium-magnesium-aluminum-silicon oxide (CMAS). In this work, after reaction with CMAS, the pyrochlore structure transforms to the cubic fluorite structure and Ca2Sm8(SiO4)6O2 forms in elongated grain.

  5. ALUMINUM REMOVAL AND SODIUM HYDROXIDE REGENERATION FROM HANFORD TANK WASTE BY LITHIUM HYDROTALCITE PRECIPITATION SUMMARY OF PRIOR LAB-SCALE TESTING

    SciTech Connect (OSTI)

    SAMS TL; GUILLOT S

    2011-01-27

    Scoping laboratory scale tests were performed at the Chemical Engineering Department of the Georgia Institute of Technology (Georgia Tech), and the Hanford 222-S Laboratory, involving double-shell tank (DST) and single-shell tank (SST) Hanford waste simulants. These tests established the viability of the Lithium Hydrotalcite precipitation process as a solution to remove aluminum and recycle sodium hydroxide from the Hanford tank waste, and set the basis of a validation test campaign to demonstrate a Technology Readiness Level of 3.

  6. Corrosion of aluminum clad spent nuclear fuel in the 70 ton cask during transfer from L area to H-canyon

    SciTech Connect (OSTI)

    Mickalonis, J. I.

    2015-08-01

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33% was found after 1 year in the cask with a maximum temperature of 263 °C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 °C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  7. Corrosion of aluminum clad spent nuclear fuel in the 70 ton cask during transfer from L area to H-canyon

    SciTech Connect (OSTI)

    Mickalonis, J. I.

    2015-08-31

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33 % was found after 1 year in the cask with a maximum temperature of 263 °C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 °C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  8. CORROSION OF ALUMINUM CLAD SPENT NUCLEAR FUEL IN THE 70 TON CASK DURING TRANSFER FROM L AREA TO H-CANYON

    SciTech Connect (OSTI)

    Mickalonis, J.

    2014-06-01

    Aluminum-clad spent nuclear fuel will be transported for processing in the 70-ton nuclear fuel element cask from L Basin to H-canyon. During transport these fuels would be expected to experience high temperature aqueous corrosion from the residual L Basin water that will be present in the cask. Cladding corrosion losses during transport were calculated for material test reactor (MTR) and high flux isotope reactors (HFIR) fuels using literature and site information on aqueous corrosion at a range of time/temperature conditions. Calculations of the cladding corrosion loss were based on Arrhenius relationships developed for aluminum alloys typical of cladding material with the primary assumption that an adherent passive film does not form to retard the initial corrosion rate. For MTR fuels a cladding thickness loss of 33 % was found after 1 year in the cask with a maximum temperature of 260 {degrees}C. HFIR fuels showed a thickness loss of only 6% after 1 year at a maximum temperature of 180 {degrees}C. These losses are not expected to impact the overall confinement function of the aluminum cladding.

  9. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    1999-05-25

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  10. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (San Diego, CA); Dispennette, John M. (Oceanside, CA); Blank, Edward (San Diego, CA); Kolb, Alan C. (Rancho Santa Fe, CA)

    1999-01-19

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  11. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.; Blank, E.; Kolb, A.C.

    1999-01-19

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH{sub 3}CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  12. Comprehensive study and design of scaled metal/high-k/Ge gate stacks with ultrathin aluminum oxide interlayers

    SciTech Connect (OSTI)

    Asahara, Ryohei; Hideshima, Iori; Oka, Hiroshi; Minoura, Yuya; Hosoi, Takuji Shimura, Takayoshi; Watanabe, Heiji; Ogawa, Shingo; Yoshigoe, Akitaka; Teraoka, Yuden

    2015-06-08

    Advanced metal/high-k/Ge gate stacks with a sub-nm equivalent oxide thickness (EOT) and improved interface properties were demonstrated by controlling interface reactions using ultrathin aluminum oxide (AlO{sub x}) interlayers. A step-by-step in situ procedure by deposition of AlO{sub x} and hafnium oxide (HfO{sub x}) layers on Ge and subsequent plasma oxidation was conducted to fabricate Pt/HfO{sub 2}/AlO{sub x}/GeO{sub x}/Ge stacked structures. Comprehensive study by means of physical and electrical characterizations revealed distinct impacts of AlO{sub x} interlayers, plasma oxidation, and metal electrodes serving as capping layers on EOT scaling, improved interface quality, and thermal stability of the stacks. Aggressive EOT scaling down to 0.56 nm and very low interface state density of 2.4 × 10{sup 11 }cm{sup −2}eV{sup −1} with a sub-nm EOT and sufficient thermal stability were achieved by systematic process optimization.

  13. Effect of tool pin features on process response variables during friction stir welding of dissimilar aluminum alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rabby, Reza; Tang, Wei; Reynolds, A. P.

    2015-07-01

    In this article, the effect of pin features and orientation/placement of the materials on advancing side were investigated for friction stir welding (FSW) of dissimilar aluminum alloys AA2050 and AA6061. Pins for FSW were produced with a 2.12 mm pitch thread having three flats/flutes. Three sets of rotational speed/welding speed were used to perform a series of welds in a butt joint arrangement. The results show that, joint quality, process response variables and welding temperature are highly affected by pin features and material orientation in FSW. Defect free joints with effective material transportation in the weld nugget zone were obtainedmore » when welding was performed with AA2050 on the advancing side. The tool also encounters less in-plane reaction force for welding with 2050 on the advancing side. Pin with thread+3 flats produces quality welds at low rotational and travel speed regardless of the location of alloys on advancing or retreating side.« less

  14. Criteria for calculating the efficiency of deep-pleated HEPA filters with aluminum separators during and after design basis accidents

    SciTech Connect (OSTI)

    Bergman, W.; First, M.W.; Anderson, W.L.; Gilbert, H.; Jacox, J.W.

    1995-02-01

    The authors have reviewed the literature on the performance of high efficiency particulate air (HEPA) filters under normal and abnormal conditions to establish criteria for calculating the efficiency of HEPA filters in a DOE nonreactor nuclear facility during and after a Design Basis Accident (DBA). This study is only applicable to the standard deep-pleated HEPA filter with aluminum separators as specified in ASME N509. The literature review included the performance of new filters and parameters that may cause deterioration in the filter performance such as filter age, radiation, corrosive chemicals, seismic and rough handling, high temperature, moisture, particle clogging, high air flow and pressure pulses. The deterioration of the filter efficiency depends on the exposure parameters; in severe exposure conditions the filter will be structurally damaged and have a residual efficiency of 0%. Despite the many studies on HEPA filter performance under adverse conditions, there are large gaps and limitations in the data that introduce significant error in the estimates of HEPA filter efficiencies under DBA conditions. Because of this limitation, conservative values of filter efficiency were chosen when there was insufficient data.

  15. Study of hot tearing of A206 aluminum alloy using Instrumented Constrained T-shaped Casting method

    SciTech Connect (OSTI)

    Esfahani, M.R. Nasr [Department of Materials Engineering, Isfahan University of Technology, 84156-83111, Isfahan (Iran, Islamic Republic of); Niroumand, B., E-mail: behzn@cc.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, 84156-83111, Isfahan (Iran, Islamic Republic of)

    2010-03-15

    The hot tearing susceptibility of A206 aluminum alloy was investigated using Instrumented Constrained T-shaped Casting method and the effect of the casting temperature on hot tearing was studied. The Instrumented Constrained T-shaped Casting apparatus enabled real-time measurements of the contraction load developed in the casting and the temperature variations during solidification as a function of time. Critical temperatures and points during solidification of the castings were extracted from these data. The contraction load developed at the coalescence point of the castings was identified as a comparative criterion for predicting the hot tearing susceptibility of the alloys which could be utilized even when no visual tearing had occurred. The results showed that hot tearing susceptibility increased with the casting temperature. This was associated with reduced cooling rate, increased solute segregation and more localized hot spot formation at the T-junction area. Increase in the casting temperature also increased the grain size which may in turn have affected the initiation of the hot tears. The visual observations were further validated with radiographic tests.

  16. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. J.; Dispennette, J. M.; Blank, E.; Kolb, A. C.

    1999-05-25

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH[sub 3]CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  17. Final Report - Melt Rate Enhancement for High Aluminum HLW Glass Formulation, VSL-08R1360-1, Rev. 0, dated 12/19/08

    SciTech Connect (OSTI)

    Kruger, Albert A.; Pegg, I. L.; Chaudhuri, M.; Gong, W.; Gan, H.; Matlack, K. S.; Bardakci, T.; Kot, W.

    2013-11-13

    The principal objective of the work reported here was to develop and identify HLW glass compositions that maximize waste processing rates for the aluminum limted waste composition specified by ORP while maintaining high waste loadings and acceptable glass properties. This was accomplished through a combination of crucible-scale tests, confirmation tests on the DM100 melter system, and demonstration at pilot scale (DM1200). The DM100-BL unit was selected for these tests since it was used previously with the HLW waste streams evaluated in this study, was used for tests on HLW glass compositions to support subsequent tests on the HLW Pilot Melter, conduct tests to determine the effect of various glass properties (viscosity and conductivity) and oxide concentrations on glass production rates with HLW feed streams, and to assess the volatility of cesium and technetium during the vitrification of an HLW AZ-102 composition. The same melter was selected for the present tests in order to maintain comparisons between the previously collected data. These tests provide information on melter processing characteristics and off-gas data, including formation of secondary phases and partitioning. Once DM100 tests were completed, one of the compositions was selected for further testing on the DM1200; the DM1200 system has been used for processing a variety of simulated Hanford waste streams. Tests on the larger melter provide processing data at one third of the scale of the actual WTP HLW melter and, therefore, provide a more accurate and reliable assessment of production rates and potential processing issues. The work focused on maximizing waste processing rates for high aluminum HLW compositions. In view of the diversity of forms of aluminum in the Hanford tanks, tests were also conducted on the DM100 to determine the effect of changes in the form of aluminum on feed properties and production rate. In addition, the work evaluated the effect on production rate of modest increases in melter operating temperature. Glass composition development was based on one of the HLW waste compositions specified by ORP that has a high concentration of aluminum. Small-scale tests were used to provide an initial screening of various glass formulations with respect to melt rates; more definitive screening was provided by the subsequent DM100 tests. Glass properties evaluated included: viscosity, electrical conductivity, crystallinity, gross glass phase separation and the 7- day Product Consistency Test (ASTM-1285). Glass property limits were based upon the reference properties for the WTP HLW melter. However, the WTP crystallinity limit (< 1 vol% at 950oC) was relaxed slightly as a waste loading constraint for the crucible melts.

  18. Monte Carlo electron-photon transport using GPUs as an accelerator: Results for a water-aluminum-water phantom

    SciTech Connect (OSTI)

    Su, L.; Du, X.; Liu, T.; Xu, X. G.

    2013-07-01

    An electron-photon coupled Monte Carlo code ARCHER - Accelerated Radiation-transport Computations in Heterogeneous Environments - is being developed at Rensselaer Polytechnic Institute as a software test bed for emerging heterogeneous high performance computers that utilize accelerators such as GPUs. In this paper, the preliminary results of code development and testing are presented. The electron transport in media was modeled using the class-II condensed history method. The electron energy considered ranges from a few hundred keV to 30 MeV. Moller scattering and bremsstrahlung processes above a preset energy were explicitly modeled. Energy loss below that threshold was accounted for using the Continuously Slowing Down Approximation (CSDA). Photon transport was dealt with using the delta tracking method. Photoelectric effect, Compton scattering and pair production were modeled. Voxelised geometry was supported. A serial ARHCHER-CPU was first written in C++. The code was then ported to the GPU platform using CUDA C. The hardware involved a desktop PC with an Intel Xeon X5660 CPU and six NVIDIA Tesla M2090 GPUs. ARHCHER was tested for a case of 20 MeV electron beam incident perpendicularly on a water-aluminum-water phantom. The depth and lateral dose profiles were found to agree with results obtained from well tested MC codes. Using six GPU cards, 6x10{sup 6} histories of electrons were simulated within 2 seconds. In comparison, the same case running the EGSnrc and MCNPX codes required 1645 seconds and 9213 seconds, respectively, on a CPU with a single core used. (authors)

  19. Fabrication and microstructure of cerium doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics by solid-state reaction method

    SciTech Connect (OSTI)

    Li, Junlang; Xu, Jian; Shi, Ying; Qi, Hongfang; Xie, Jianjun; Lei, Fang

    2014-07-01

    Highlights: We fabricate Ce doped lutetium aluminum garnet ceramics by solid-state method. The raw materials include Lu{sub 2}O{sub 3} nanopowders synthesized by co-precipitation method. The density of the transparent ceramics reach 99.7% of the theoretical value. The optical transmittance of the bulk ceramic at 550 nm was 57.48%. Some scattering centers decrease the optical characteristic of the ceramic. - Abstract: Polycrystalline Ce{sup 3+} doped lutetium aluminum garnet (Ce:LuAG) transparent ceramics fabricated by one step solid-state reaction method using synthetic nano-sized Lu{sub 2}O{sub 3}, commercial ?-Al{sub 2}O{sub 3} and CeO{sub 2} powders were investigated in this paper. The green compacts shaped by the mixed powders were successfully densified into Ce:LuAG transparent ceramics after vacuum sintering at 1750 C for 10 h. The in-line optical transmittance of the Ce:LuAG ceramic made by home-made Lu{sub 2}O{sub 3} powders could reach 57.48% at 550 nm, which was higher than that of the ceramic made by commercial Lu{sub 2}O{sub 3} powders (22.96%). The microstructure observation showed that light scattering centers caused by micro-pores, aluminum segregation and refraction index inhomogeneities induced the decrease of optical transparency of the Ce:LuAG ceramics, which should be removed and optimized in the future work.

  20. Response to high-energy photons of PTW31014 PinPoint ion chamber with a central aluminum electrode

    SciTech Connect (OSTI)

    Agostinelli, S.; Garelli, S.; Piergentili, M.; Foppiano, F.

    2008-07-15

    Since its introduction the PinPoint (PTW-Freiburg) micro-ionization chamber has been proposed for relative dosimetry (output factors, depth dose curves, and beam profiles) as well as for determination of absolute dose of small high-energy photon beams. This paper investigates the dosimetric performance of a new design (type 31014) of the PinPoint ion chamber with a central aluminum electrode. The study included characterization of inherent and radiation-induced leakage, ion collection efficiency and polarity effect, relative response of the chamber, measurement of beam profiles, and depth dose curves. The 6 and 15 MV photon beams of a Varian 2100 C/D were considered. At the nominal operating voltage of 400 V the PinPoint type 31014 chamber was found to present a strong field size dependence of the polarity correction factor and an excess of the collected charge, which can lead to an underestimation of the collection efficiency if determined with the conventional ''two-voltage'' method. In comparison to the original PinPoint design (type 31006) the authors found for type 31014 chamber no overresponse to large-area fields if polarity correction is applied. If no correction is taken into consideration, the authors found the chamber's output to be inaccurate for large-area fields (0.5% accuracy limited up to the 12x12 and 20x20 cm{sup 2} field for the 6 and 15 MV beams, respectively), which is a direct consequence of the stem and polarity effects due to the chamber's very small sensitive volume (0.015 cc) and cable irradiation. Beam profiles and depth dose curves measured with type 31014 PinPoint chamber for small and medium size fields were compared to data measured with a 0.125 cc ion chamber and with high-resolution Kodak EDR2 films. Analysis of the penumbra (80%-20% distance) showed that the spatial resolution of type 31014 PinPoint ion chamber approaches (penumbra broadening {<=}0.6 mm) EDR2 film results.