National Library of Energy BETA

Sample records for alumina refining primary

  1. MECS 2006 - Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining MECS 2006 - Petroleum Refining Manufacturing Energy and Carbon Footprint for Petroleum Refining (NAICS 324110) Sector with Total Energy Input, October 2012 (MECS 2006) All available footprints and supporting documents Manufacturing Energy and Carbon Footprint PDF icon Petroleum Refining More Documents & Publications Petroleum Refining (2010 MECS) MECS 2006 - Alumina and Aluminum MECS 2006 - Cement

  2. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... energy that a particular process would require under ideal ... analyses of primary chemical reactions using the ... for Petroleum Refining Processes 1 manufacturing industries. ...

  3. Microporous alumina ceramic membranes

    DOE Patents [OSTI]

    Anderson, Marc A.; Sheng, Guangyao

    1993-01-01

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  4. Microporous alumina ceramic membranes

    DOE Patents [OSTI]

    Anderson, M.A.; Guangyao Sheng.

    1993-05-04

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  5. Rietveld Refinement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    profile Chi-squared value 4.944 Progress so far Inverse Modeling Method 2 Fourier Method Data Model Refined Structure 40 60 80 100 120 140 160 0 1000 2000 3000 4000...

  6. Reuse of activated alumina

    SciTech Connect (OSTI)

    Hobensack, J.E.

    1991-12-31

    Activated alumina is used as a trapping media to remove trace quantities of UF{sub 6} from process vent streams. The current uranium recovery method employs concentrated nitric acid which destroys the alumina pellets and forms a sludge which is a storage and disposal problem. A recently developed technique using a distilled water rinse followed by three dilute acid rinses removes on average 97% of the uranium, and leaves the pellets intact with crush strength and surface area values comparable with new material. Trapping tests confirm the effectiveness of the recycled alumina as UF{sub 6} trapping media.

  7. Refiner Crude Oil Inputs

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Refiner Crude Oil Inputs Refiner Gross Inputs Refiner Operable Capacity ... Download Series History Download Series History Definitions, Sources & Notes Definitions, ...

  8. Alumina Technology Roadmap

    SciTech Connect (OSTI)

    none,

    2002-02-01

    The Alumina Technology Roadmap outlines a comprehensive long-term research and development plan that defines the industry's collective future and establishes a clear pathway forward. It emphasizes twelve high-priority R&D areas deemed most significant in addressing the strategic goals.

  9. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  10. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  11. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining...

    Office of Environmental Management (EM)

    Energy Bandwidth for Petroleum Refining Processes ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes PDF icon bandwidth.pdf More Documents & Publications ITP ...

  12. ITP Petroleum Refining: Profile of the Petroleum Refining Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Profile of the Petroleum Refining Industry in California: California Industries of the Future Program ITP Petroleum Refining: Profile of the Petroleum Refining Industry in ...

  13. Attrition resistant gamma-alumina catalyst support

    DOE Patents [OSTI]

    Singleton, Alan H.; Oukaci, Rachid; Goodwin, James G.

    2006-03-14

    A .gamma.-alumina catalyst support having improved attrition resistance produced by a method comprising the steps of treating a particulate .gamma.-alumina material with an acidic aqueous solution comprising water and nitric acid and then, prior to adding any catalytic material thereto, calcining the treated .gamma.-alumina.

  14. Step 3: Project Refinement

    Energy Savers [EERE]

    3: Project Refinement 2 1 Potential 3 Refinement 4 Implementation 5 Operations & Maintenance 2 Options 3 Refinement 1/28/2016 2 3 FUNDING AND FINANCING OPTIONS Project Ownership Financing structure is highly dependent on size of the project and the capital available for a given project: * Tribe owns the project (cash purchase or debt) * Tribe hosts the project and buys the electricity (power purchase agreement) * Tribe partners with private sector and co-owns the project (uncertainties about

  15. MECS 2006 - Alumina and Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alumina and Aluminum MECS 2006 - Alumina and Aluminum Manufacturing Energy and Carbon Footprint for Alumina and Aluminum Sector (NAICS 3313) with Total Energy Input, October 2012 (MECS 2006) All available footprints and supporting documents Manufacturing Energy and Carbon Footprint PDF icon Alumina and Aluminum More Documents & Publications Alumina and Aluminum (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass

  16. Method for preparing Pb-. beta. ''-alumina ceramic

    DOE Patents [OSTI]

    Hellstrom, E.E.

    1984-08-30

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-..beta..''-alumina ceramic from Na-..beta..''-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-..beta..''-alumina ceramic that is substantially crack-free.

  17. Synthesis of high porosity, monolithic alumina aerogels

    SciTech Connect (OSTI)

    Poco, J F; Satcher, J H; Hrubesh, L W

    2000-09-20

    Many non-silica aerogels are notably weak and fragile in monolithic form. Particularly, few monolithic aerogels with densities less than 50kg/m3 have any significant strength. It is especially difficult to prepare uncracked monoliths of pure alumina aerogels that are robust and moisture stable. In this paper, we discuss the synthesis of strong, stable, monolithic, high porosity (>98% porous) alumina aerogels, using a two-step sol-gel process. The alumina aerogels have a polycrystalline morphology that results in enhanced physical properties. Most of the measured physical properties of the alumina aerogels are superior to those for silica aerogels for equivalent densities.

  18. Alumina forming iron base superalloy

    DOE Patents [OSTI]

    Yamamoto, Yukinori; Muralidharan, Govindarajan; Brady, Michael P.

    2014-08-26

    An austenitic stainless steel alloy, consists essentially of, in weight percent 2.5 to 4 Al; 25 to 35 Ni; 12 to 19 Cr; at least 1, up to 4 total of at least one element selected from the group consisting of Nb and Ta; 0.5 to 3 Ti; less than 0.5 V; 0.1 to 1 of at least on element selected from the group consisting of Zr and Hf; 0.03 to 0.2 C; 0.005 to 0.1 B; and base Fe. The weight percent Fe is greater than the weight percent Ni. The alloy forms an external continuous scale including alumina, and contains coherent precipitates of .gamma.'-Ni.sub.3Al, and a stable essentially single phase FCC austenitic matrix microstructure. The austenitic matrix is essentially delta-ferrite-free and essentially BCC-phase-free.

  19. Parallel tetrahedral mesh refinement with MOAB.

    SciTech Connect (OSTI)

    Thompson, David C.; Pebay, Philippe Pierre

    2008-12-01

    In this report, we present the novel functionality of parallel tetrahedral mesh refinement which we have implemented in MOAB. This report details work done to implement parallel, edge-based, tetrahedral refinement into MOAB. The theoretical basis for this work is contained in [PT04, PT05, TP06] while information on design, performance, and operation specific to MOAB are contained herein. As MOAB is intended mainly for use in pre-processing and simulation (as opposed to the post-processing bent of previous papers), the primary use case is different: rather than refining elements with non-linear basis functions, the goal is to increase the number of degrees of freedom in some region in order to more accurately represent the solution to some system of equations that cannot be solved analytically. Also, MOAB has a unique mesh representation which impacts the algorithm. This introduction contains a brief review of streaming edge-based tetrahedral refinement. The remainder of the report is broken into three sections: design and implementation, performance, and conclusions. Appendix A contains instructions for end users (simulation authors) on how to employ the refiner.

  20. Alumina and Aluminum (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alumina and Aluminum (2010 MECS) Alumina and Aluminum (2010 MECS) Manufacturing Energy and Carbon Footprint for Alumina and Aluminum Sector (NAICS 3313) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint PDF icon Alumina and Aluminum More Documents & Publications MECS 2006 - Alumina and Aluminum Cement (2010 MECS) Glass and Glass Products (2010 MECS) Manufacturing

  1. Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining Petroleum Refining Maintaining the viability of the U.S. petroleum refining industry requires continuous improvement in productivity and energy efficiency. The U.S. refining industry has worked with AMO to provide a range of resources that can provide energy and cost savings for the industry. Analytical Studies & Other Publications Manufacturing Energy and Carbon Footprints provide a mapping of energy use, energy loss, and carbon emissions for selected industry sectors.

  2. CLAMR (Compute Language Adaptive Mesh Refinement)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CLAMR (Compute Language Adaptive Mesh Refinement) CLAMR (Compute Language Adaptive Mesh Refinement) CLAMR (Compute Language Adaptive Mesh Refinement) is being developed as a DOE...

  3. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, Milton; Cook, Glenn M.

    1988-01-01

    Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  4. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1985-05-21

    Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  5. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1988-05-17

    Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

  6. Process for solvent refining of coal using a denitrogenated and dephenolated solvent

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1984-01-01

    A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

  7. Refines Efficiency Improvement

    SciTech Connect (OSTI)

    WRI

    2002-05-15

    Refinery processes that convert heavy oils to lighter distillate fuels require heating for distillation, hydrogen addition or carbon rejection (coking). Efficiency is limited by the formation of insoluble carbon-rich coke deposits. Heat exchangers and other refinery units must be shut down for mechanical coke removal, resulting in a significant loss of output and revenue. When a residuum is heated above the temperature at which pyrolysis occurs (340 C, 650 F), there is typically an induction period before coke formation begins (Magaril and Aksenova 1968, Wiehe 1993). To avoid fouling, refiners often stop heating a residuum before coke formation begins, using arbitrary criteria. In many cases, this heating is stopped sooner than need be, resulting in less than maximum product yield. Western Research Institute (WRI) has developed innovative Coking Index concepts (patent pending) which can be used for process control by refiners to heat residua to the threshold, but not beyond the point at which coke formation begins when petroleum residua materials are heated at pyrolysis temperatures (Schabron et al. 2001). The development of this universal predictor solves a long standing problem in petroleum refining. These Coking Indexes have great potential value in improving the efficiency of distillation processes. The Coking Indexes were found to apply to residua in a universal manner, and the theoretical basis for the indexes has been established (Schabron et al. 2001a, 2001b, 2001c). For the first time, a few simple measurements indicates how close undesired coke formation is on the coke formation induction time line. The Coking Indexes can lead to new process controls that can improve refinery distillation efficiency by several percentage points. Petroleum residua consist of an ordered continuum of solvated polar materials usually referred to as asphaltenes dispersed in a lower polarity solvent phase held together by intermediate polarity materials usually referred to as resins. The Coking Indexes focus on the amount of these intermediate polarity species since coke formation begins when these are depleted. Currently the Coking Indexes are determined by either titration or solubility measurements which must be performed in a laboratory. In the current work, various spectral, microscopic, and thermal techniques possibly leading to on-line analysis were explored for measuring the Coking Indexes.

  8. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes

    Broader source: Energy.gov [DOE]

    This energy bandwidth analysis provides a realistic estimate of the energy that may be saved in petroleum refining processes by quantifying measures of energy consumption.

  9. Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride

    SciTech Connect (OSTI)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01

    The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

  10. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2004-11-02

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  11. ITP Aluminum: Alumina Technology Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alumina Technology Roadmap ITP Aluminum: Alumina Technology Roadmap PDF icon alumina.pdf More Documents & Publications U.S. Energy Requirements for Aluminum Production ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Technology Roadmap

  12. Midcourse Refinements of Financing Strategies

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program Financing Peer Exchange Call: Midcourse Refinements of Financing Strategies, Call Slides and Discussion Summary, March 29, 2012. During this webinar participants discussed how programs have adapted and refined their financing strategies based on initial implementation experience and learning.

  13. Crystal structure refinement with SHELXL

    SciTech Connect (OSTI)

    Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, Georg-August Universitt Gttingen, Tammannstrae 4, Gttingen 37077 (Germany)

    2015-01-01

    New features added to the refinement program SHELXL since 2008 are described and explained. The improvements in the crystal structure refinement program SHELXL have been closely coupled with the development and increasing importance of the CIF (Crystallographic Information Framework) format for validating and archiving crystal structures. An important simplification is that now only one file in CIF format (for convenience, referred to simply as a CIF) containing embedded reflection data and SHELXL instructions is needed for a complete structure archive; the program SHREDCIF can be used to extract the .hkl and .ins files required for further refinement with SHELXL. Recent developments in SHELXL facilitate refinement against neutron diffraction data, the treatment of H atoms, the determination of absolute structure, the input of partial structure factors and the refinement of twinned and disordered structures. SHELXL is available free to academics for the Windows, Linux and Mac OS X operating systems, and is particularly suitable for multiple-core processors.

  14. Method of making nanocrystalline alpha alumina

    DOE Patents [OSTI]

    Siegel, Richard W.; Hahn, Horst; Eastman, Jeffrey A.

    1992-01-01

    Method of making selected phases of nanocrystalline ceramic materials. Various methods of controlling the production of nanocrystalline alpha alumina and titanium oxygen phases are described. Control of the gas atmosphere and use of particular oxidation treatments give rise to the ability to control the particular phases provided in the aluminum/oxygen and titanium/oxygen system.

  15. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    SciTech Connect (OSTI)

    Chuanping Li

    2004-12-19

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the {sup 17}O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles' surfaces in the aqueous suspension. The viscosity of the suspension increases dramatically when the solid volume fraction exceeds 30 vol.%. The overlap of physically adsorbed water layers at this level causes the sharp increase in viscosity. Fructose molecules can weaken the interactions between the particle surfaces and water molecules, as a consequence, they release some bound water layers from the surfaces to the bulk medium. It is believed that fraction of the water that is bound by the solid surface is reduced hence becoming available for flow. The oxygen-17 relaxation time decreased with the increase of particle volume fractions in the suspension. Fructose addition increased the overall water mobility in the suspension. Only part of the alumina particle surfaces was covered with fructose molecules. This adsorption of fructose molecules on the particle surfaces increased the pH of the suspension with a concomitant decrease in {zeta}-potential of the alumina nanoparticles. The interactions between the nanometric alumina particles in water to a large extent can be explained by the DLVO theory. However, the interactions between particles in fructose solutions cannot be well described by the DLVO theory. The interaction forces (magnitude and range) as well as adhesive force and surface tension between nanometric alumina particles were decreased with the fructose concentration.

  16. Electronic structure of superconductivity refined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic structure of superconductivity refined Electronic structure of superconductivity refined A team of physicists propose a new model that expands on a little understood aspect of the electronic structure in high-temperature superconductors. July 10, 2008 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma

  17. Renewable Energy Financial Instruments Guidance Tool (REFINe...

    Open Energy Info (EERE)

    Guidance Tool (REFINe) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Renewable Energy Financial Instruments Guidance Tool (REFINe) Focus Area: Renewable Energy...

  18. Hydrolysis of carbonyl sulfide over alumina

    SciTech Connect (OSTI)

    Polleck, R. E.; Ledley, R. E.; Scott, K. A.

    1985-01-01

    The reaction rate for the hydrolysis of carbonyl sulfide in liquid petroleum hydrocarbons over alumina, such as propylene, is greatly increased by maintaining water in the hydrocarbons in an amount of one mole of water per mole of carbonyl sulfide to an upper limit of about ten moles of water per mole of carbonyl sulfide or about 30% of saturation of the hydrocarbons, whichever upper limit provides the lesser amount of water.

  19. A simple procedure to prepare spherical {alpha}-alumina powders

    SciTech Connect (OSTI)

    Liu Hongyu [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China); Ning Guiling [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Gan Zhihong; Lin Yuan [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)

    2009-04-02

    Spherical {alpha}-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of {alpha}-alumina powders. The precursors crystallized to {gamma}-alumina at 1000 deg. C and converted to {alpha}-alumina at 1150 deg. C without intermediate phases. The particle morphology of precursor was retained after it crystallized to {alpha}-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to {alpha}-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products.

  20. Method for preparing Pb-.beta."-alumina ceramic

    DOE Patents [OSTI]

    Hellstrom, Eric E.

    1986-01-01

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-.beta."-alumina ceramic from Na-.beta."-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-.beta."-alumina ceramic that is substantially crack-free.

  1. Sintering of beta-type alumina bodies using alpha-alumina encapsulation

    DOE Patents [OSTI]

    McEntire, Bryan J.; Virkar, Anil V.

    1981-01-01

    A method of sintering a shaped green, beta-type alumina body comprising: (A) inserting said body into an open chamber prepared by exposing the interior surface of a container consisting essentially of at least about 50 weight percent of alpha-alumina and a remainder of other refractory material to a sodium oxide or sodium oxide producing environment; (B) sealing the chamber; and heating the chamber with the shaped body encapsulated therein to a temperature and for a time necessary to sinter said body to the desired density. The encapsulation chamber prepared as described above is also claimed.

  2. Electrolytic cell for production of aluminum from alumina

    DOE Patents [OSTI]

    Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2005-03-15

    Electrolysis of alumina dissolved in a molten salt electrolyte employing inert anode and cathodes, the anode having a box shape with slots for the cathodes.

  3. Petroleum Refining (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining (2010 MECS) Petroleum Refining (2010 MECS) Manufacturing Energy and Carbon Footprint for Petroleum Refining Sector (NAICS 324110) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint PDF icon Petroleum Refining More Documents & Publications MECS 2006 - Petroleum Refining Cement (2010 MECS) Foundries (2010 MECS) Manufacturing Energy Sankey Diagrams

  4. GRAIN REFINEMENT OF URANIUM BILLETS

    DOE Patents [OSTI]

    Lewis, L.

    1964-02-25

    A method of refining the grain structure of massive uranium billets without resort to forging is described. The method consists in the steps of beta- quenching the billets, annealing the quenched billets in the upper alpha temperature range, and extrusion upset of the billets to an extent sufficient to increase the cross sectional area by at least 5 per cent. (AEC)

  5. Method for refining contaminated iridium

    DOE Patents [OSTI]

    Heshmatpour, B.; Heestand, R.L.

    1982-08-31

    Contaminated iridium is refined by alloying it with an alloying agent selected from the group consisting of manganese and an alloy of manganese and copper, and then dissolving the alloying agent from the formed alloy to provide a purified iridium powder.

  6. Porosity in plasma sprayed alumina coatings

    SciTech Connect (OSTI)

    Ilavsky, J.; Herman, H.; Berndt, C.C.; Goland, A.N.; Long, G.G.; Krueger, S.; Allen, A.J.

    1994-03-01

    Small-angle neutron scattering (SANS) was used to study the porosity of plasma sprayed deposits of alumina in as-sprayed and heat-treated conditions. SANS results were compared with mercury intrusion porosimetry (MIP) and water immersion techniques. Multiple small-angle neutron scattering yields a volume-weighted effective pore radius (R{sub eff}), for pores with sizes between 0.08 and 10{mu}m, the pore volume in this size region, and from the Porod region, the surface area of pores of all sizes.

  7. Process for the recovery of alumina from fly ash

    DOE Patents [OSTI]

    Murtha, Marlyn J.

    1983-08-09

    An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

  8. Combination for electrolytic reduction of alumina

    DOE Patents [OSTI]

    Brown, Craig W.; Brooks, Richard J.; Frizzle, Patrick B.; Juric, Drago D.

    2002-04-30

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises molten electrolyte having the following ingredients: AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound is, a fluoride; oxide, or carbonate. The metal is nickel, iron, copper, cobalt, or molybdenum. The bath is employed in a combination including a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the instant bath during electrolytic reduction of alumina to aluminum improves the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

  9. Aluminum doped zirconia nanopowders: Wet-chemical synthesis and structural analysis by Rietveld refinement

    SciTech Connect (OSTI)

    Srdic, Vladimir V. Rakic, Srdan; Cvejic, Zeljka

    2008-10-02

    Alumina/zirconia nanopowders, with up to 20 mol% Al{sub 2}O{sub 3}, were prepared by wet-chemical synthesis technique, using controlled hydrolysis of alkoxides. The as-synthesized powders are amorphous, have very high specific surface area and the corresponding particle size smaller than 4 nm. Amorphous powders with 0, 10 and 20 mol% Al{sub 2}O{sub 3} crystallize at 460, 692 and 749 deg. C, respectively, as a single-phase tetragonal zirconia, without any traces of alumina phases. Rietvled refinement of X-ray diffraction data, used for the detailed structural analysis of annealed nanopowders, showed that the high-temperature zirconia phase is stabilized due to the formation of ZrO{sub 2}/Al{sub 2}O{sub 3} solid solutions. High solubility of alumina in the tetragonal zirconia (up to 28.6 at% Al{sup 3+}) and stabilization of tetragonal zirconia solid solution up to high temperature (as high as 1150 deg. C) were also confirmed.

  10. Reformulated Gasoline Market Affected Refiners Differently, 1995

    Reports and Publications (EIA)

    1996-01-01

    This article focuses on the costs of producing reformulated gasoline (RFG) as experienced by different types of refiners and on how these refiners fared this past summer, given the prices for RFG at the refinery gate.

  11. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig; Mulholland, James A.; Foster, Edward P.

    1986-01-01

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  12. Optimized alumina coagulants for water treatment

    DOE Patents [OSTI]

    Nyman, May D.; Stewart, Thomas A.

    2012-02-21

    Substitution of a single Ga-atom or single Ge-atom (GaAl.sub.12 and GeAl.sub.12 respectively) into the center of an aluminum Keggin polycation (Al.sub.13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl.sub.12 consistently shows .about.1 order of magnitude increase in pathogen reduction, compared to Al.sub.13. At a concentration of 2 ppm, GaAl.sub.12 performs equivalently to 40 ppm alum, removing .about.90% of the dissolved organic material. The substituted GaAl.sub.12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO.sub.4Al.sub.12(OH).sub.24(H.sub.2O).sub.12].sup.7+.

  13. ITP Petroleum Refining: Energy and Environmental Profile of the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Environmental Profile of the U.S. Petroleum Refining Industry (November 2007) ITP Petroleum Refining: Energy and Environmental Profile of the U.S. Petroleum Refining Industry ...

  14. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOE Patents [OSTI]

    Gaffney, T.R.; Golden, T.C.; Mayorga, S.G.; Brzozowski, J.R.; Taylor, F.W.

    1999-06-29

    A pressure swing adsorption process for absorbing CO[sub 2] from a gaseous mixture containing CO[sub 2] comprises introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100 C and 500 C to adsorb CO[sub 2] to provide a CO[sub 2] laden alumina adsorbent and a CO[sub 2] depleted gaseous mixture and contacting the CO[sub 2] laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO[sub 2] from the CO[sub 2] laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100 C and 600 C, is not degraded by high concentrations of water under process operating conditions. 1 fig.

  15. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOE Patents [OSTI]

    Gaffney, Thomas Richard; Golden, Timothy Christopher; Mayorga, Steven Gerard; Brzozowski, Jeffrey Richard; Taylor, Fred William

    1999-01-01

    A pressure swing adsorption process for absorbing CO.sub.2 from a gaseous mixture containing CO.sub.2 comprising introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100.degree. C. and 500.degree. C. to adsorb CO.sub.2 to provide a CO.sub.2 laden alumina adsorbent and a CO.sub.2 depleted gaseous mixture and contacting the CO.sub.2 laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO.sub.2 from the CO.sub.2 laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100.degree. C. and 600.degree. C., is not degraded by high concentrations of water under process operating conditions.

  16. Cast alumina forming austenitic stainless steels

    DOE Patents [OSTI]

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  17. Improving the accuracy of macromolecular structure refinement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is challenging at low resolution. We compared refinement methods using synchrotron diffraction data of photosystem I at 7.4 resolution, starting from different initial models...

  18. Refiners Increasingly Employing Catalyst Regeneration as Alternative...

    Open Energy Info (EERE)

    million by the end of 2019. Refiners Benefit from Catalyst Regeneration Technology via Price Reductions and Lower Maintenance Costs The catalyst regeneration technology is the...

  19. Midcourse Refinements of Financing Strategies | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 29, 2012. During this webinar participants discussed how programs have adapted and refined their financing strategies based on initial implementation experience and learning. ...

  20. Pneumatic conveying of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R.

    1984-11-06

    A method for pneumatically conveying solvent refined coal to a burner under conditions of dilute phase pneumatic flow so as to prevent saltation of the solvent refined coal in the transport line by maintaining the transport fluid velocity above approximately 95 ft/sec.

  1. North Dakota Refining Capacity Study

    SciTech Connect (OSTI)

    Dennis Hill; Kurt Swenson; Carl Tuura; Jim Simon; Robert Vermette; Gilberto Marcha; Steve Kelly; David Wells; Ed Palmer; Kuo Yu; Tram Nguyen; Juliam Migliavacca

    2011-01-05

    According to a 2008 report issued by the United States Geological Survey, North Dakota and Montana have an estimated 3.0 to 4.3 billion barrels of undiscovered, technically recoverable oil in an area known as the Bakken Formation. With the size and remoteness of the discovery, the question became 'can a business case be made for increasing refining capacity in North Dakota?' And, if so what is the impact to existing players in the region. To answer the question, a study committee comprised of leaders in the region's petroleum industry were brought together to define the scope of the study, hire a consulting firm and oversee the study. The study committee met frequently to provide input on the findings and modify the course of the study, as needed. The study concluded that the Petroleum Area Defense District II (PADD II) has an oversupply of gasoline. With that in mind, a niche market, naphtha, was identified. Naphtha is used as a diluent used for pipelining the bitumen (heavy crude) from Canada to crude markets. The study predicted there will continue to be an increase in the demand for naphtha through 2030. The study estimated the optimal configuration for the refinery at 34,000 barrels per day (BPD) producing 15,000 BPD of naphtha and a 52 percent refinery charge for jet and diesel yield. The financial modeling assumed the sponsor of a refinery would invest its own capital to pay for construction costs. With this assumption, the internal rate of return is 9.2 percent which is not sufficient to attract traditional investment given the risk factor of the project. With that in mind, those interested in pursuing this niche market will need to identify incentives to improve the rate of return.

  2. Plastic deformation and sintering of alumina under high pressure

    SciTech Connect (OSTI)

    Liu, Fangming; Liu, Pingping; Wang, Haikuo; Xu, Chao; Yin, Shuai; Yin, Wenwen; Li, Yong; He, Duanwei

    2013-12-21

    Plastic deformation of alumina (Al{sub 2}O{sub 3}) under high pressure was investigated by observing the shape changes of spherical particles, and the near fully dense transparent bulks were prepared at around 5.5 GPa and 900 °C. Through analyzing the deformation features, densities, and residual micro-strain of the Al{sub 2}O{sub 3} compacts prepared under high pressures and temperatures (2.0–5.5 GPa and 600–1200 °C), the effects of plastic deformation on the sintering behavior of alumina have been demonstrated. Under compression, the microscopic deviatoric stress caused by grain-to-grain contact could initiate the plastic deformation of individual particles, eliminate pores of the polycrystalline samples, and enhance the local atomic diffusion at the grain boundaries, thus produced transparent alumina bulks.

  3. The influence of aluminum grain size on alumina nanoporous structure

    SciTech Connect (OSTI)

    Feil, A. F.; Costa, M. V. da; Amaral, L.; Teixeira, S. R.; Migowski, P.; Dupont, J.; Machado, G.; Peripolli, S. B.

    2010-01-15

    An approach to control the interpore distances and nanopore diameters of 150-nm-thick thin aluminum films is reported here. The Al thin films were grown by sputtering on p-type silicon substrate and anodized with a conventional anodization process in a phosphoric acid solution. It was found that interpore distance and pore diameter are related to the aluminum grain size and can be controlled by annealing. The grain contours limit the sizes of alumina cells. This mechanism is valid for grain sizes supporting only one alumina cell and consequently only one pore.

  4. U.S. Refining Capacity Utilization

    Reports and Publications (EIA)

    1995-01-01

    This article briefly reviews recent trends in domestic refining capacity utilization and examines in detail the differences in reported crude oil distillation capacities and utilization rates among different classes of refineries.

  5. Nanocomposite formed by titanium ion implantation into alumina

    SciTech Connect (OSTI)

    Spirin, R. E.; Salvadori, M. C. Teixeira, F. S.; Sgubin, L. G.; Cattani, M.; Brown, I. G.

    2014-11-14

    Composites of titanium nanoparticles in alumina were formed by ion implantation of titanium into alumina, and the surface electrical conductivity measured in situ as the implantation proceeded, thus generating curves of sheet conductivity as a function of dose. The implanted titanium self-conglomerates into nanoparticles, and the spatial dimensions of the buried nanocomposite layer can thus be estimated from the implantation depth profile. Rutherford backscattering spectrometry was performed to measure the implantation depth profile, and was in good agreement with the calculated profile. Transmission electron microscopy of the titanium-implanted alumina was used for direct visualization of the nanoparticles formed. The measured conductivity of the buried layer is explained by percolation theory. We determine that the saturation dose, φ{sub 0}, the maximum implantation dose for which the nanocomposite material still remains a composite, is φ{sub 0} = 2.2 × 10{sup 16 }cm{sup −2}, and the corresponding saturation conductivity is σ{sub 0} = 480 S/m. The percolation dose φ{sub c}, below which the nanocomposite still has basically the conductivity of the alumina matrix, was found to be φ{sub c} = 0.84 × 10{sup 16 }cm{sup −2}. The experimental results are discussed and compared with a percolation theory model.

  6. Refining Bio-Oil alongside Petroleum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refining Bio-Oil alongside Petroleum Refining Bio-Oil alongside Petroleum April 9, 2013 - 12:00am Addthis W.R. Grace, a leading provider of refining technologies, and Pacific ...

  7. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1995 Annual Averages Motor...

  8. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1997 Annual Averages Motor...

  9. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1997 Annual Averages Motor...

  10. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1995 Annual Averages Motor...

  11. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1996 Annual Averages Motor...

  12. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1996 Annual Averages Motor...

  13. ITP Petroleum Refining: Impacts of Condition Assessment on Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Impacts of Condition Assessment on Energy Use: Selected Applications in Chemicals Processing and Petroleum Refining ITP Petroleum Refining: Impacts of Condition Assessment on ...

  14. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  15. Arbitrary Lagrangian Eulerian Adaptive Mesh Refinement

    Energy Science and Technology Software Center (OSTI)

    2009-09-29

    This is a simulation code involving an ALE (arbitrary Lagrangian-Eulerian) hydrocode with AMR (adaptive mesh refinement) and pluggable physics packages for material strength, heat conduction, radiation diffusion, and laser ray tracing developed a LLNL, UCSD, and Berkeley Lab. The code is an extension of the open source SAMRAI (Structured Adaptive Mesh Refinement Application Interface) code/library. The code can be used in laser facilities such as the National Ignition Facility. The code is alsi being appliedmore » to slurry flow (landslides).« less

  16. Surface modification of zirconia-alumina composite ceramics

    SciTech Connect (OSTI)

    Ghosh, S.K.; Chatterjee, D.K.

    1994-12-31

    Surface modification of tetragonal zirconia and {alpha}-alumina composite was accomplished by diffusion of MgO during sintering at 1500{degrees}C. {alpha}-Al{sub 2}O{sub 3} powder, 2 to 60 wt%, was thoroughly mixed with 5 wt% yttria-alloyed zirconia powder, cold pressed and sintered in contact with fine MgO powder. In the diffusion zone, {alpha}-Al{sub 2}O{sub 3} was transformed to spinel, MgAl{sub 2}O{sub 4}, and transformation of tetragonal zirconia to cubic phase depended primarily on alumina concentration. The modified surface was, therefore, a composite of spinel, tetragonal (t) and/or cubic zirconia as distinguished from the core, comprised of {alpha}-Al{sub 2}O{sub 3} and t-ZrO{sub 2}. Tribological characteristics of the modified outer surface are also reported.

  17. Protective coating for alumina-silicon carbide whisker composites

    DOE Patents [OSTI]

    Tiegs, Terry N.

    1989-01-01

    Ceramic composites formed of an alumina matrix reinforced with silicon carbide whiskers homogenously dispersed therein are provided with a protective coating for preventing fracture strength degradation of the composite by oxidation during exposure to high temperatures in oxygen-containing atmospheres. The coating prevents oxidation of the silicon carbide whiskers within the matrix by sealing off the exterior of the matrix so as to prevent oxygen transport into the interior of the matrix. The coating is formed of mullite or mullite plus silicon oxide and alumina and is formed in place by heating the composite in air to a temperature greater than 1200.degree. C. This coating is less than about 100 microns thick and adequately protects the underlying composite from fracture strength degradation due to oxidation.

  18. Melt processing of Bi--2212 superconductors using alumina

    DOE Patents [OSTI]

    Holesinger, Terry G.

    1999-01-01

    Superconducting articles and a method of forming them, where the superconducting phase of an article is Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.y (Bi-2212). Alumina is combined with Bi-2212 powder or Bi-2212 precursor powder and, in order to form an intimate mixture, the mixture is melted and rapidly cooled to form a glassy solid. The glassy solid is comminuted and the resulting powder is combined with a carrier. An alternative to melting is to form the mixture of nanophase alumina and material having a particle size of less than about 10 microns. The powder, with the carrier, is melt processed to form a superconducting article.

  19. Measurements of prompt radiation induced conductivity of alumina and sapphire.

    SciTech Connect (OSTI)

    Hartman, E. Frederick; Zarick, Thomas Andrew; Sheridan, Timothy J.; Preston, Eric F.

    2011-04-01

    We performed measurements of the prompt radiation induced conductivity in thin samples of Alumina and Sapphire at the Little Mountain Medusa LINAC facility in Ogden, UT. Five mil thick samples were irradiated with pulses of 20 MeV electrons, yielding dose rates of 1E7 to 1E9 rad/s. We applied variable potentials up to 1 kV across the samples and measured the prompt conduction current. Analysis rendered prompt conductivity coefficients between 1E10 and 1E9 mho/m/(rad/s), depending on the dose rate and the pulse width for Alumina and 1E7 to 6E7 mho/m/(rad/s) for Sapphire.

  20. Conduction in alumina with atomic scale copper filaments

    SciTech Connect (OSTI)

    Xu, Xu; Liu, Jie; Anantram, M. P.

    2014-10-28

    The conductance of atomic scale filaments with three and seven Cu atoms in ?-alumina are calculated using ab initio density functional theory. We find that the filament with 3 Cu atoms is sufficient to increase the conductance of 1.3?nm thick alumina film by more than 10{sup 3} times in linear response. As the applied voltage increases, the current quickly saturates and differential resistance becomes negative. Compared to the filament with three Cu atoms, while the conductance of the filament with seven Cu atoms is comparable in linear response, they carry as much as twenty times larger current at large biases. The electron transport is analyzed based on local density of states, and the negative differential resistance in the seven Cu filaments occurs due to their narrow bandwidth.

  1. Proton adsorption onto alumina: extension of multisite complexation (MUSIC) theory

    SciTech Connect (OSTI)

    Nagashima, K.; Blum, F.D.

    1999-09-01

    The adsorption isotherm of protons onto a commercial {gamma}-alumina sample was determined in aqueous nitric acid with sodium nitrate as a background electrolyte. Three discrete regions could be discerned in the log-log plots of the proton isotherm determined at the solution pH 5 to 2. The multisite complexation (MUSIC) model was modified to analyze the simultaneous adsorption of protons onto various kinds of surface species.

  2. ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in California | Department of Energy Energy Efficiency Roadmap for Petroleum Refineries in California ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California PDF icon refining_roadmap.pdf More Documents & Publications ITP Petroleum Refining: Profile of the Petroleum Refining Industry in California: California Industries of the Future Program ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California Bandwidth Study U.S.

  3. Energy Bandwidth for Petroleum Refining Processes

    SciTech Connect (OSTI)

    none,

    2006-10-01

    The petroleum refining energy bandwidth report analyzes the most energy-intensive unit operations used in U.S. refineries: crude oil distillation, fluid catalytic cracking, catalytic hydrotreating, catalytic reforming, and alkylation. The "bandwidth" provides a snapshot of the energy losses that can potentially be recovered through best practices and technology R&D.

  4. Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles

    SciTech Connect (OSTI)

    Lawler, Katherine

    2009-08-05

    The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanosized alumina particle suspensions. The addition of dispersants can change the particle interactions and hence reduce the suspension viscosity. This was demonstrated with saccharides in the aqueous system and with benzoic acid in suspensions with BECy.

  5. Method to produce alumina aerogels having porosities greater than 80 percent

    DOE Patents [OSTI]

    Poco, John F.; Hrubesh, Lawrence W.

    2003-09-16

    A two-step method for producing monolithic alumina aerogels having porosities of greater than 80 percent. Very strong, very low density alumina aerogel monoliths are prepared using the two-step sol-gel process. The method of preparing pure alumina aerogel modifies the prior known sol method by combining the use of substoichiometric water for hydrolysis, the use of acetic acid to control hydrolysis/condensation, and high temperature supercritical drying, all of which contribute to the formation of a polycrystalline aerogel microstructure. This structure provides exceptional mechanical properties of the alumina aerogel, as well as enhanced thermal resistance and high temperature stability.

  6. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  7. Structured Adaptive Mesh Refinement Application Infrastructure

    Energy Science and Technology Software Center (OSTI)

    2010-07-15

    SAMRAI is an object-oriented support library for structured adaptice mesh refinement (SAMR) simulation of computational science problems, modeled by systems of partial differential equations (PDEs). SAMRAI is developed and maintained in the Center for Applied Scientific Computing (CASC) under ASCI ITS and PSE support. SAMRAI is used in a variety of application research efforts at LLNL and in academia. These applications are developed in collaboration with SAMRAI development team members.

  8. Method for thermal processing alumina-enriched spinel single crystals

    DOE Patents [OSTI]

    Jantzen, Carol M.

    1995-01-01

    A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly.

  9. Method for thermal processing alumina-enriched spinel single crystals

    DOE Patents [OSTI]

    Jantzen, C.M.

    1995-05-09

    A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly. 12 figs.

  10. Functionally graded alumina-based thin film systems

    DOE Patents [OSTI]

    Moore, John J.; Zhong, Dalong

    2006-08-29

    The present invention provides coating systems that minimize thermal and residual stresses to create a fatigue- and soldering-resistant coating for aluminum die casting dies. The coating systems include at least three layers. The outer layer is an alumina- or boro-carbide-based outer layer that has superior non-wettability characteristics with molten aluminum coupled with oxidation and wear resistance. A functionally-graded intermediate layer or "interlayer" enhances the erosive wear, toughness, and corrosion resistance of the die. A thin adhesion layer of reactive metal is used between the die substrate and the interlayer to increase adhesion of the coating system to the die surface.

  11. Particle denuded zones in alumina reinforced aluminum matrix composite weldments

    SciTech Connect (OSTI)

    Chidambaram, A.; Bhole, S.D.

    1996-08-01

    The Welding Institute of Canada (WIC), Ontario, has been studying the weldability of different DURALCAN MMC`s. Research on alumina reinforced (20 vol.%) 6061 Al alloy GTA welds showed satisfactory tensile and yield strengths (0.2% Proof Stress) but the welds failed to pass the bend test requirements with fracture taking place in the relatively brittle heat affected zone (HAZ). Further, the welds were characterized by a region which was devoid of reinforcement particles adjacent to the fusion lines. The present study was undertaken to try and explain the formation of this particle denuded zone (PDZ) at the fusion lines.

  12. Silicon carbide whisker-zirconia reinforced mullite and alumina ceramics

    DOE Patents [OSTI]

    Becher, Paul F.; Tiegs, Terry N.

    1987-01-01

    The flexural strength and/or fracture toughness of SiC whisker-reinforced composites utilizing mullite or alumina as the matrix material for the composite are increased by the addition of zirconia in a monoclinic or tetragonal phase to the matrix. The zirconia addition also provides for a lower hot-pressing temperature and increases the flexural strength and/or fracture toughness of the SiC whisker-reinforced composites over SiC whisker-reinforced composites of the similar matrix materials reinforced with similar concentrations of SiC whiskers.

  13. Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conductors | ANSER Center | Argonne-Northwestern National Laboratory Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors Home > Research > ANSER Research Highlights > Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors

  14. Grain Refinement of Permanent Mold Cast Copper Base Alloys

    SciTech Connect (OSTI)

    M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

    2005-04-01

    Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

  15. ITP Petroleum Refining: Impacts of Condition Assessment on Energy Use:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Selected Applications in Chemicals Processing and Petroleum Refining | Department of Energy Impacts of Condition Assessment on Energy Use: Selected Applications in Chemicals Processing and Petroleum Refining ITP Petroleum Refining: Impacts of Condition Assessment on Energy Use: Selected Applications in Chemicals Processing and Petroleum Refining PDF icon condition_assessment.pdf More Documents & Publications Effective Fouling Minimization Increases the Efficiency and Productivity of

  16. Bandwidth Study U.S. Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining Bandwidth Study U.S. Petroleum Refining Bandwidth Study U.S. Petroleum Refining Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas,

  17. ITP Petroleum Refining: Petroleum Technology Vision 2020 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Petroleum Technology Vision 2020 ITP Petroleum Refining: Petroleum Technology Vision 2020 PDF icon techvision.pdf More Documents & Publications Manufacturing Energy and Carbon Footprint References Industrial Technologies Funding Profile by Subprogram ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes

  18. Removal of metals from heavy oils with phosphorus - Alumina catalysts

    SciTech Connect (OSTI)

    Kukes, S.G.; Parrott, S.L.; Gardner, L.E. )

    1987-04-01

    Earlier it was found that various oil-soluble phosphorous compounds were active for vanadium removal from different crude oils. The phosphorous compounds preferentially reacted with low molecular weight vanadium species in the resin fraction and therefore the highest rate of vanadium removal was observed when the asphaltene fraction was partially or completely removed. Phosphorous compounds promoted the rate of vanadium removal during hydroprocessing over alumina in a trickle bed reactor. Some metal phosphates were prepared and tested for demetallization activity. Several mixed metal phosphates, such as Cr-Zr, Ni-Zr, Cu-Zr, V-Co-Zr, Fe-Co-Zr, Ni-Co-Zr, etc., exhibited high activity for both vanadium and nickel removal. These catalysts were found to possess HDM activity and activity maintenance comparable to conventional hydrotreating catalysts available commercially. The vanadium removal selectivity of the mixed metal phosphates was similar to that of the commercial catalyst, but much lower than that observed earlier for oil soluble phosphorous compounds. Since the lack of high vanadium selectivity for the mixed metal phosphates could be due to their transition metal component, they investigated the hydroprocessing of heavy oils over aluminas impregnated with different inorganic phosphorous compounds.

  19. Bath for electrolytic reduction of alumina and method therefor

    DOE Patents [OSTI]

    Brown, Craig W.; Brooks, Richard J.; Frizzle, Patrick B.; Juric, Drago D.

    2001-07-10

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

  20. Bath for electrolytic reduction of alumina and method therefor

    DOE Patents [OSTI]

    Brown, Craig W.; Brooks, Richard J.; Frizzle, Patrick B.; Juric, Drago D.

    2002-11-26

    An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode. Removing sulfur from the bath can also minimize cathode deposits. Aluminum formed on the cathode can be removed directly from the cathode.

  1. Genealogy of major U.S. refiners - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    See full Genealogy of Major U.S. Refiners Previous Release Genealogy of Major U.S. Refiners Genealogy of Major U.S. Refiners Release date: September 18, 2013 figre 1. World energy consumption, 1990-2040. The structure of the U.S. petroleum refining industry has changed substantially over the past several years. In the diagram the companies shown on the right side are presently active in U.S. refining. The transactions over the past 25 years that created these companies also are shown. The

  2. Deformable elastic network refinement for low-resolution macromolecular crystallography

    SciTech Connect (OSTI)

    Schrder, Gunnar F.; Levitt, Michael; Brunger, Axel T.

    2014-09-01

    An overview of applications of the deformable elastic network (DEN) refinement method is presented together with recommendations for its optimal usage. Crystals of membrane proteins and protein complexes often diffract to low resolution owing to their intrinsic molecular flexibility, heterogeneity or the mosaic spread of micro-domains. At low resolution, the building and refinement of atomic models is a more challenging task. The deformable elastic network (DEN) refinement method developed previously has been instrumental in the determinion of several structures at low resolution. Here, DEN refinement is reviewed, recommendations for its optimal usage are provided and its limitations are discussed. Representative examples of the application of DEN refinement to challenging cases of refinement at low resolution are presented. These cases include soluble as well as membrane proteins determined at limiting resolutions ranging from 3 to 7 . Potential extensions of the DEN refinement technique and future perspectives for the interpretation of low-resolution crystal structures are also discussed.

  3. Acoustic phonon spectrum and thermal transport in nanoporous alumina arrays

    SciTech Connect (OSTI)

    Kargar, Fariborz; Ramirez, Sylvester; Debnath, Bishwajit; Malekpour, Hoda; Lake, Roger; Balandin, Alexander A.

    2015-10-28

    We report results of a combined investigation of thermal conductivity and acoustic phonon spectra in nanoporous alumina membranes with the pore diameter decreasing from D=180 nm to 25 nm. The samples with the hexagonally arranged pores were selected to have the same porosity Ø ≈13%. The Brillouin-Mandelstam spectroscopy measurements revealed bulk-like phonon spectrum in the samples with D=180-nm pores and spectral features, which were attributed to spatial confinement, in the samples with 25-nm and 40-nm pores. The velocity of the longitudinal acoustic phonons was reduced in the samples with smaller pores. As a result, analysis of the experimental data and calculated phonon dispersion suggests that both phonon-boundary scattering and phonon spatial confinement affect heat conduction in membranes with the feature sizes D<40 nm.

  4. Acoustic phonon spectrum and thermal transport in nanoporous alumina arrays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kargar, Fariborz; Ramirez, Sylvester; Debnath, Bishwajit; Malekpour, Hoda; Lake, Roger; Balandin, Alexander A.

    2015-10-28

    We report results of a combined investigation of thermal conductivity and acoustic phonon spectra in nanoporous alumina membranes with the pore diameter decreasing from D=180 nm to 25 nm. The samples with the hexagonally arranged pores were selected to have the same porosity Ø ≈13%. The Brillouin-Mandelstam spectroscopy measurements revealed bulk-like phonon spectrum in the samples with D=180-nm pores and spectral features, which were attributed to spatial confinement, in the samples with 25-nm and 40-nm pores. The velocity of the longitudinal acoustic phonons was reduced in the samples with smaller pores. As a result, analysis of the experimental data andmore » calculated phonon dispersion suggests that both phonon-boundary scattering and phonon spatial confinement affect heat conduction in membranes with the feature sizes D<40 nm.« less

  5. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  6. Visualization Tools for Adaptive Mesh Refinement Data

    SciTech Connect (OSTI)

    Weber, Gunther H.; Beckner, Vincent E.; Childs, Hank; Ligocki,Terry J.; Miller, Mark C.; Van Straalen, Brian; Bethel, E. Wes

    2007-05-09

    Adaptive Mesh Refinement (AMR) is a highly effective method for simulations that span a large range of spatiotemporal scales, such as astrophysical simulations that must accommodate ranges from interstellar to sub-planetary. Most mainstream visualization tools still lack support for AMR as a first class data type and AMR code teams use custom built applications for AMR visualization. The Department of Energy's (DOE's) Science Discovery through Advanced Computing (SciDAC) Visualization and Analytics Center for Enabling Technologies (VACET) is currently working on extending VisIt, which is an open source visualization tool that accommodates AMR as a first-class data type. These efforts will bridge the gap between general-purpose visualization applications and highly specialized AMR visual analysis applications. Here, we give an overview of the state of the art in AMR visualization research and tools and describe how VisIt currently handles AMR data.

  7. Visualization of Scalar Adaptive Mesh Refinement Data

    SciTech Connect (OSTI)

    VACET; Weber, Gunther; Weber, Gunther H.; Beckner, Vince E.; Childs, Hank; Ligocki, Terry J.; Miller, Mark C.; Van Straalen, Brian; Bethel, E. Wes

    2007-12-06

    Adaptive Mesh Refinement (AMR) is a highly effective computation method for simulations that span a large range of spatiotemporal scales, such as astrophysical simulations, which must accommodate ranges from interstellar to sub-planetary. Most mainstream visualization tools still lack support for AMR grids as a first class data type and AMR code teams use custom built applications for AMR visualization. The Department of Energy's (DOE's) Science Discovery through Advanced Computing (SciDAC) Visualization and Analytics Center for Enabling Technologies (VACET) is currently working on extending VisIt, which is an open source visualization tool that accommodates AMR as a first-class data type. These efforts will bridge the gap between general-purpose visualization applications and highly specialized AMR visual analysis applications. Here, we give an overview of the state of the art in AMR scalar data visualization research.

  8. REFINING PROGRAM HELPS REENERGIZE NEBRASKA UPGRADES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    REFINING PROGRAM HELPS REENERGIZE NEBRASKA UPGRADES REFINING PROGRAM HELPS REENERGIZE NEBRASKA UPGRADES REFINING PROGRAM HELPS REENERGIZE NEBRASKA UPGRADES In a state where energy costs are low and the home performance workforce had not been established, Nebraska's two largest cities-Omaha and Lincoln-took on the challenge of promoting whole home energy upgrades to homeowners, businesses, and nonprofit organizations. Using $10 million in seed funding from the U.S. Department of Energy's (DOE's)

  9. Mechanical Properties of a Graded Alumina-Zirconia Composite Prepared by Centrifugal Slip Casting

    SciTech Connect (OSTI)

    Hara, Yasuyuki; Onda, Tetsuhiko; Hayakawa, Motozo

    2008-02-15

    Compositionally graded composite of alumina-20 vol%zirconia was fabricated by using centrifugal casting incorporated with relatively thin slip. An EPMA analysis exhibited a nearly linear variation of the alumina/zirconia ratio along the centrifugal direction; zirconia tended to accumulate in the bottom section, while alumina in the top section. Such a graded structure exhibited a considerably higher flexural strength when the alumina rich surface was subjected to a tensile stress than compositionally uniform composite of the same average composition. Fracture toughness measurement across the specimen thickness by indentation method revealed that the crack lengths along the vertical and horizontal directions were different. The anisotropy of the fracture toughness was accounted for by the variation of the residual stress across the specimen thicknesss.

  10. Bandwidth Study U.S. Petroleum Refining | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy ...

  11. Developing Refined Products Storage in the Strategic Petroleum...

    Broader source: Energy.gov (indexed) [DOE]

    ... These pipelines supply all or some of the refined products consumed in major population centers such as Nashville, TN; Atlanta, GA; Charlotte, NC; Washington, DC; Philadelphia, PA; ...

  12. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1997 Table 43....

  13. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per Day) - Continued Geographic Area Month Premium All Grades Sales...

  14. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    2000 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per Day) - Continued Geographic Area Month Premium All Grades Sales...

  15. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1996 Table 43....

  16. The Space-Based Telescopes for Actionable Refinement of Ephemeris...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Citation Details In-Document Search Title: The Space-Based Telescopes for ...

  17. Secretary Bodman Tours Refinery and Calls for More Domestic Refining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    called on Congress to simplify the approval process for refiners to expand their refineries, which will help reduce America's imports of foreign oil and the price of energy. ...

  18. EERE Success Story—Refining Bio-Oil alongside Petroleum

    Broader source: Energy.gov [DOE]

    W.R. Grace and Pacific Northwest National Laboratory are working to establish a bio-oil refining process that users existing petroleum refinery infrastructure.

  19. ,"U.S. Reformulated, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...www.eia.govdnavpetpetprirefmg2cnusepm0rdpgalm.htm" ,"Source:","Energy Information ... Reformulated Gasoline Retail Sales by Refiners (Dollars per ...

  20. ,"U.S. Conventional, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...www.eia.govdnavpetpetprirefmg2cnusepm0udpgalm.htm" ,"Source:","Energy Information ... Conventional Gasoline Retail Sales by Refiners (Dollars per ...

  1. The Space-Based Telescopes for Actionable Refinement of Ephemeris...

    Office of Scientific and Technical Information (OSTI)

    Title: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Authors: Simms, L ; De Vries, W ; RIot, V ; Olivier, S ; Pertica, A ; Bauman, B ; ...

  2. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  3. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  4. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  5. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    134 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  6. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    134 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  7. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    220 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  8. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - - W W - - - - - - See footnotes at end of table. 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State 292 Energy...

  9. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  10. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    220 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  11. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  12. ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency Roadmap for Petroleum Refineries in California ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California PDF icon ...

  13. ,"Motor Gasoline Sales to End Users, Total Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales to End Users, Total Refiner Sales Volumes",60,"Monthly","22016","1151983" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefmg...

  14. ,"No. 2 Distillate Sales to End Users Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales to End Users Refiner Sales Volumes",60,"Monthly","22016","1151983" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefot...

  15. Refiners react to changes in the pipeline infrastructure

    SciTech Connect (OSTI)

    Giles, K.A.

    1997-06-01

    Petroleum pipelines have long been a critical component in the distribution of crude and refined products in the U.S. Pipelines are typically the most cost efficient mode of transportation for reasonably consistent flow rates. For obvious reasons, inland refineries and consumers are much more dependent on petroleum pipelines to provide supplies of crude and refined products than refineries and consumers located on the coasts. Significant changes in U.S. distribution patterns for crude and refined products are reshaping the pipeline infrastructure and presenting challenges and opportunities for domestic refiners. These changes are discussed.

  16. New Process for Grain Refinement of Aluminum. Final Report

    SciTech Connect (OSTI)

    Dr. Joseph A. Megy

    2000-09-22

    A new method of grain refining aluminum involving in-situ formation of boride nuclei in molten aluminum just prior to casting has been developed in the subject DOE program over the last thirty months by a team consisting of JDC, Inc., Alcoa Technical Center, GRAS, Inc., Touchstone Labs, and GKS Engineering Services. The Manufacturing process to make boron trichloride for grain refining is much simpler than preparing conventional grain refiners, with attendant environmental, capital, and energy savings. The manufacture of boride grain refining nuclei using the fy-Gem process avoids clusters, salt and oxide inclusions that cause quality problems in aluminum today.

  17. Fluidization Techniques in Producing Refined Uranium from Ore...

    Office of Scientific and Technical Information (OSTI)

    steps of the refining process is described. ... on a pilot scale using equipment which was originally ... Subject: STABLE ISOTOPE SEPARATION; CHEMICAL REACTIONS; ...

  18. ,"U.S. Total Refiner Petroleum Product Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    NUSDPG","EMAEPPRPTGNUSDPG","EMAEPPRLPTGNUSDPG","EMAEPPRHPTGNUSDPG" "Date","U.S. Total Gasoline Retail Sales by Refiners (Dollars per Gallon)","U.S. Aviation Gasoline...

  19. ,"Conventional Gasoline Sales to End Users, Total Refiner Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales to End Users, Total Refiner Sales Volumes",60,"Monthly","22016","1151994" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefmg...

  20. Adaptive h -refinement for reduced-order models: ADAPTIVE h -refinement for reduced-order models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carlberg, Kevin T.

    2014-11-05

    Our work presents a method to adaptively refine reduced-order models a posteriori without requiring additional full-order-model solves. The technique is analogous to mesh-adaptive h-refinement: it enriches the reduced-basis space online by ‘splitting’ a given basis vector into several vectors with disjoint support. The splitting scheme is defined by a tree structure constructed offline via recursive k-means clustering of the state variables using snapshot data. This method identifies the vectors to split online using a dual-weighted-residual approach that aims to reduce error in an output quantity of interest. The resulting method generates a hierarchy of subspaces online without requiring large-scale operationsmore » or full-order-model solves. Furthermore, it enables the reduced-order model to satisfy any prescribed error tolerance regardless of its original fidelity, as a completely refined reduced-order model is mathematically equivalent to the original full-order model. Experiments on a parameterized inviscid Burgers equation highlight the ability of the method to capture phenomena (e.g., moving shocks) not contained in the span of the original reduced basis.« less

  1. Effects of composition on the mechanical response of alumina-filled epoxy.

    SciTech Connect (OSTI)

    Montgomery, Stephen Tedford

    2009-10-01

    The effect of composition on the elastic responses of alumina particle-filled epoxy composites is examined using isotropic elastic response models relating the average stresses and strains in a discretely reinforced composite material consisting of perfectly bonded and uniformly distributed particles in a solid isotropic elastic matrix. Responses for small elastic deformations and large hydrostatic and plane-strain compressions are considered. The response model for small elastic deformations depends on known elastic properties of the matrix and particles, the volume fraction of the particles, and two additional material properties that reflect the composition and microstructure of the composite material. These two material properties, called strain concentration coefficients, are characterized for eleven alumina-filled epoxy composites. It is found that while the strain concentration coefficients depend strongly on the volume fraction of alumina particles, no significant dependence on particle morphology and size is observed for the compositions examined. Additionally, an analysis of the strain concentration coefficients reveals a remarkably simple dependency on the alumina volume fraction. Responses for large hydrostatic and plane-strain compressions are obtained by generalizing the equations developed for small deformation, and letting the alumina volume fraction in the composite increase with compression. The large compression plane-strain response model is shown to predict equilibrium Hugoniot states in alumina-filled epoxy compositions remarkably well.

  2. Report to the Congress on the storage of refined petroleum products and on regional supply interruptions

    SciTech Connect (OSTI)

    Not Available

    1991-06-01

    This report describes petroleum and petroleum products storage and supply disruption. Information is presented under the following topics: Historical Perspective; Current Patterns of Supply and Disposition of Petroleum Products in the Primary Distribution System; PADD I Clean Products Supply/Demand; 1990 Regional Petroleum Reserve Annual Computation; Market Infrastructure and Commercial Practices in the California Motor Gasoline Market, as Related to Potential Refined Petroleum Product Reserve Structures and Sales Procedures; Infrastructure and Commercial Practices in the Northeast Distillate Market, as Related to Potential Refined Petroleum Product Reserve Structures and Sales Procedures; Storage Stability Characteristics of Petroleum Products and Crude Oil; Effect of 1990 Clean Air Act Amendments on Demand for Petroleum Product Storage Capacity; and Environmental Regulations on Tanks.

  3. Refining and End Use Study of Coal Liquids

    SciTech Connect (OSTI)

    1997-10-01

    This report summarizes revisions to the design basis for the linear programing refining model that is being used in the Refining and End Use Study of Coal Liquids. This revision primarily reflects the addition of data for the upgrading of direct coal liquids.

  4. Lightweight alumina refractory aggregate: Phase 3, Full-scale demonstration

    SciTech Connect (OSTI)

    Swansiger, T.G.; Pearson, A.

    1996-07-16

    Technical problems (higher than target fired density, and poor intermediate strength after burnout but before sintering) were addressed and solved; solution involved use of large loading of CP-5 alumina (controlled pore, rehydratable), increased loading of one of the binders, and a steam aging step. Resistance of the lightweight aggregate in a brick formulation to steel slag penetration was assessed in a preliminary test and found to be almost as good as that of T-64. Pelletized process economic feasibility study was updated, based on production levels of 10,000 and 20,000 mt/year, the most up- to-date raw material costs, and the assumption of a retrofit into the Arkansas plant tabular production facility. For the 10,000 mt/y production level, the required selling price of 35% more than the T- 64 selling price exceeds the {le}25% objective. The market survey will determine whether to proceed with the full scale demonstration that will produce at least 54.4 mt (120,000 lb) of the aggregate for incorporation into products, followed by end-user testing and evaluation.

  5. Method for fabricating cermets of alumina-chromium systems

    DOE Patents [OSTI]

    Morgan, Chester S.

    1983-01-01

    Cermet insulators resistant to thermal and mechanical shock are prepared from alumina-chromium systems by providing an Al.sub.2 O.sub.3 material of about 0.5 to 7.0 micron size with a solid-hydrocarbon overcoating by slurring an effective amount of said solid hydrocarbon in a solvent mixture containing said Al.sub.2 O.sub.3 and thereafter evaporating said solvent, contacting said coated Al.sub.2 O.sub.3 with a solution of chromium precursor compound, heating the resulting mixture in a reducing environment to a temperature above the decomposition temperature of said chromium precursor compound but less than the melting temperature of the Al.sub.2 O.sub.3 or chromium for sufficient duration to yield a particulate compound having chromium essentially dispersed throughout the Al.sub.2 O.sub.3, and then densifying said particulate to provide said cermet characterized by a theoretical density in excess of 96% and having 0.1 to 10.0 vol.% elemental chromium metal present therein as a dispersed phase at the boundaries of the Al.sub.2 O.sub.3 material. Cermet components prepared thereby are useful in high temperature equipment, advanced heat engines, and nuclear-related equipment applications where electrical or thermal insulators are required.

  6. Reitveld refinement study of PLZT ceramics

    SciTech Connect (OSTI)

    Kumar, Rakesh; Bavbande, D. V.; Bafna, V. H.; Mohan, D.; Kothiyal, G. P.; Mishra, R.

    2013-02-05

    PLZT ceramics of composition Pb{sub 0.93}La{sub 0.07}(Zr{sub 0.60}Ti{sub 0.40})O{sub 3}, have been milled for 6hrs and 24hrs were prepared by solid state synthesis route. The 6hrs milled and 24hrs milled samples are represented as PLZT-6 and PLZT-24 ceramics respectively. X-ray diffraction (XRD) pattern was recorded at room temperature. The XRD pattern has been analyzed by employing Rietveld refinement method. Phase identification shows that all the peaks observed in PLZT-6 and PLZT-24 ceramics could be indexed to P4mm space group with tetragonal symmetry. The unit cell parameters of 6hrs milled PLZT ceramics are found to be a=b=4.0781(5)A and c=4.0938(7)A and for 24hrs milled PLZT ceramics unit cell parameters are a=b=4.0679(4)A and c=4.1010(5)A . The axial ratio c/a and unit cell volume of PLZT-6 are 1.0038 and 68.09(2)A{sup 3} respectively. In PLZT-24 samples, the axial ratio c/a value is 1.0080 which is little more than that of the 6hr milled PLZT sample whereas the unit cell volume decrease to 67.88 (1) A{sup 3}. An average crystallite size was estimated by using Scherrer's formula. Dielectric properties were obtained by measuring the capacitance and tand loss using Stanford LCR meter.

  7. ATOMIC LAYER DEPOSITION OF TITANIUM OXIDE THIN FILMS ONNANOPOROUS ALUMINA TEMPLATES FOR MEDICAL APPLICATIONS

    SciTech Connect (OSTI)

    Brigmon, R.

    2009-05-05

    Nanostructured materials may play a significant role in controlled release of pharmacologic agents for treatment of cancer. Many nanoporous polymer materials are inadequate for use in drug delivery. Nanoporous alumina provides several advantages over other materials for use in controlled drug delivery and other medical applications. Atomic layer deposition was used to coat all the surfaces of the nanoporous alumina membrane in order to reduce the pore size in a controlled manner. Both the 20 nm and 100 nm titanium oxide-coated nanoporous alumina membranes did not exhibit statistically lower viability compared to the uncoated nanoporous alumina membrane control materials. In addition, 20 nm pore size titanium oxide-coated nanoporous alumina membranes exposed to ultraviolet light demonstrated activity against Escherichia coli and Staphylococcus aureus bacteria. Nanostructured materials prepared using atomic layer deposition may be useful for delivering a pharmacologic agent at a precise rate to a specific location in the body. These materials may serve as the basis for 'smart' drug delivery devices, orthopedic implants, or self-sterilizing medical devices.

  8. Integrated process for the solvent refining of coal

    DOE Patents [OSTI]

    Garg, Diwakar

    1983-01-01

    A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the solid product in a second stage to produce additional liquid product. A fresh inexpensive, throw-away catalyst is utilized in the second stage hydrogenation of the solid product and this catalyst is recovered and recycled for catalyst duty in the solvent refining stage without any activation steps performed on the used catalyst prior to its use in the solvent refining of feed coal.

  9. Refiners Switch to RFG Complex Model

    Reports and Publications (EIA)

    1998-01-01

    On January 1, 1998, domestic and foreign refineries and importers must stop using the "simple" model and begin using the "complex" model to calculate emissions of volatile organic compounds (VOC), toxic air pollutants (TAP), and nitrogen oxides (NOx) from motor gasoline. The primary differences between application of the two models is that some refineries may have to meet stricter standards for the sulfur and olefin content of the reformulated gasoline (RFG) they produce and all refineries will now be held accountable for NOx emissions. Requirements for calculating emissions from conventional gasoline under the anti-dumping rule similarly change for exhaust TAP and NOx. However, the change to the complex model is not expected to result in an increase in the price premium for RFG or constrain supplies.

  10. DOE - Office of Legacy Management -- National Smelting and Refining...

    Office of Legacy Management (LM)

    Also see Documents Related to NATIONAL SMELTING & REFINING CO. OH.20-1 - MED Letter; Zimmerman to Sweeney; Subject: Shipment of Type G-1 Material; October 28, 1943 OH.20-2 - DOE...

  11. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    253.2 2,222.4 W W 206.4 134.3 - 340.7 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  12. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    150.0 2,026.7 W W 234.5 161.7 - 396.3 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  13. The Space-Based Telescopes for Actionable Refinement of Ephemeris

    Office of Scientific and Technical Information (OSTI)

    Pathfinder Mission (Journal Article) | SciTech Connect Journal Article: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Citation Details In-Document Search Title: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Authors: Simms, L ; De Vries, W ; RIot, V ; Olivier, S ; Pertica, A ; Bauman, B ; Phillion, D ; Nikolaev, S Publication Date: 2011-05-19 OSTI Identifier: 1122251 Report Number(s): LLNL-JRNL-485519 DOE Contract

  14. Sol-spray preparation, particulate characteristics, and sintering of alumina powders

    SciTech Connect (OSTI)

    Varma, H.K.; Mani, T.V.; Damodaran, A.D.; Warrier, K.G.K.; Balachandran, U.

    1993-07-01

    Fine alumina powders of spherical morphology and narrow particle-size distribution have been synthesized by a technique that uses precipitation/peptization/spray drying of boehmite sol prepared from aluminum nitrate. The spray-dried powder was further washed with solvents of varying polarities, such as acetone, isopropanol, and tert-butanol. This post-spray-drying treatment changed the powder`s particle-size distribution, morphology, density, and compaction characteristics. Microstructure, dielectric properties, and effect of post-treatment on the boehmite-sol-derived alumina powders in reducing agglomeration are discussed.

  15. Surface preparation for high purity alumina ceramics enabling direct brazing in hydrogen atmospheres

    DOE Patents [OSTI]

    Cadden, Charles H.; Yang, Nancy Yuan Chi; Hosking, Floyd M.

    2001-01-01

    The present invention relates to a method for preparing the surface of a high purity alumina ceramic or sapphire specimen that enables direct brazing in a hydrogen atmosphere using an active braze alloy. The present invention also relates to a method for directly brazing a high purity alumina ceramic or sapphire specimen to a ceramic or metal member using this method of surface preparation, and to articles produced by this brazing method. The presence of silicon, in the form of a SiO.sub.2 -containing surface layer, can more than double the tensile bond strength in alumina ceramic joints brazed in a hydrogen atmosphere using an active Au-16Ni-0.75 Mo-1.75V filler metal. A thin silicon coating applied by PVD processing can, after air firing, produce a semi-continuous coverage of the alumina surface with a SiO.sub.2 film. Room temperature tensile strength was found to be proportional to the fraction of air fired surface covered by silicon-containing films. Similarly, the ratio of substrate fracture versus interface separation was also related to the amount of surface silicon present prior to brazing. This process can replace the need to perform a "moly-manganese" metallization step.

  16. Adsorption of carbonyl sulfide from liquid hydrocarbons with activated alumina and other adsorbents

    SciTech Connect (OSTI)

    Liu, P.K.T. (Alcoa Separations Technology Div., Aluminum Co. of America, Warrendale, PA (US))

    1988-01-01

    Contamination of Liquid hydrocarbon streams with carbonyl sulfide (COS) is not desirable; particularly in propylene. COS may poison the down stream polymerization catalyst. Thus, it is usually required to reduce the COS concentration to an extremely low level, e.g. 1 ppm or less, for polymer grade propylene. Many technologies generally available for sulfur removal, such as scrubbing and distillation are not applicable to the removal of COS from propylene. The former is not suitable for a low level removal. With the boiling point of COS (-50{sup 0}C) very close to that of propylene (-48{sup 0}C) it is difficult to achieve a very efficient separation with distillation. Adsorption technology provides a very energy efficient process in addition to its ability of the low level removal. Adsorbents selected in this study include activated carbon, molecular sieves, zinc oxide and activated alumina. The results show that activated alumina is far superior in both adsorption capacity and rate. An adsorption mechanism with activated alumina is proposed. It is believed that adsorption of COS takes place simultaneously with the hydrolysis of COS on the alumina surface. Adsorption isotherms of COS up to 100 ppm and the effect of moisture content are also addressed in this study.

  17. Silica-alumina trihydrate filled epoxy castings resistant to arced SF.sub.6

    DOE Patents [OSTI]

    Chenoweth, Terrence E.; Yeoman, Frederick A.

    1978-01-01

    A cured, insulating, casting composition, having a coefficient of linear thermal expansion of below about 38 .times. 10.sup.-6 in./in./.degree. C and being resistant to arced sulfur hexafluoride gas, in contact with a metal surface in a sulfur hexafluoride gas environment, is made from hydantoin epoxy resin, anhydride curing agent and a filler combination of fused silica and alumina trihydrate.

  18. Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives

    SciTech Connect (OSTI)

    Lu, XC; Xia, GG; Lemmon, JP; Yang, ZG

    2010-05-01

    The increasing penetration of renewable energy and the trend toward clean, efficient transportation have spurred growing interests in sodium-beta alumina batteries that store electrical energy via sodium ion transport across a beta ''-Al(2)O(3) solid electrolyte at elevated temperatures (typically 300-350 degrees C ). Currently, the negative electrode or anode is metallic sodium in molten state during battery operation; the positive electrode or cathode can be molten sulfur (Na-S battery) or solid transition metal halides plus a liquid phase secondary electrolyte (e.g., ZEBRA battery). Since the groundbreaking works in the sodium-beta alumina batteries a few decades ago, encouraging progress has been achieved in improving battery performance, along with cost reduction. However, there remain issues that hinder broad applications and market penetration of the technologies. To better the Na-beta alumina technologies require further advancement in materials along with component and system design and engineering. This paper offers a comprehensive review on materials of electrodes and electrolytes for the Na-beta alumina batteries and discusses the challenges ahead for further technology improvement. (C) 2009 Published by Elsevier B.V.

  19. Cuprous-chloride-modified nanoporous alumina membranes for ethylene-ethane separation

    SciTech Connect (OSTI)

    Lin, Y.S.; Wang, Y.; Ji, W.; Higgins, R.J.

    1999-06-01

    This paper reports an attempt to synthesize a CuCl-modified {gamma}-alumina membrane for separation of ethylene from ethane. CuCl was effectively coated in the 4 nm pore {gamma}-alumina top layers of disk-shaped and tubular alumina membranes by the reservoir method. Permeation of a single gas and binary mixture of ethylene and ethane was measured to characterize separation properties of the modified membranes. Pure ethylene permeance of the CuCl-modified membrane is 10--40% lower than that predicted from the pure ethane permeance by the Knudsen theory. This result is explained by a model based on the adsorbed layer of ethylene via {pi}-complexation. Such an adsorbed layer hinders the diffusion of ethylene in the nanopores of CuCl-modified {gamma}-alumina. Multiple gas permeation measurements on the CuCl-modified membranes show a separation factor for ethylene over ethane larger than the Knudsen value. This confirms a positive contribution of the surface flow of ethylene to the permeance of ethylene in the multiple gas permeation system. A maximum separation factor for ethylene over ethane of 1.4 is obtained for the CuCl-modified membrane at 60 C.

  20. The structure-directed effect of Al-based metal–organic frameworks on fabrication of alumina by thermal treatment

    SciTech Connect (OSTI)

    Liu, Dandan; Dai, Fangna; Tang, Zhe; Liu, Yunqi; Liu, Chenguang

    2015-05-15

    Highlights: • We use Al-MOFs as precursor in the fabrication process of mesoporous alumina by thermal treatment. • The obtained mesoporous alumina has dual pore system and five-fold aluminum. • The aluminum building units in the precursor show structure-directed effect on the formation of alumina. - Abstract: In this work, the block-shaped Al-based metal–organic frameworks (Al-MOFs) MIL-53 have been synthesized by hydrothermal method. To detect the correlation between the structure of Al-MOFs and the formation of alumina, the ligands are eliminated by thermal treatment. MIL-53 and the calcination products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM), nitrogen adsorption–desorption and solid-state {sup 27}Al nuclear magnetic resonance ({sup 27}Al NMR). It was found that after calcination, the block-shaped Al-MOFs precursor turns into high-crystallinity mesoporous alumina nanosheets, and the thermal treatment product γ-alumina possesses a dual pore system and a large surface area (146 m{sup 2}/g), with five-fold aluminum. During the thermal treatment process, the structure of MIL-53 and its secondary building units have structure-directed effect in the formation of alumina.

  1. Synthesis of High Surface Area Alumina Aerogels without the Use of Alkoxide Precursors

    SciTech Connect (OSTI)

    Baumann, T F; Gash, A E; Chinn, S C; Sawvel, A M; Maxwell, R S; Satcher Jr., J H

    2004-06-25

    Alumina aerogels were prepared through the addition of propylene oxide to aqueous or ethanolic solutions of hydrated aluminum salts, AlCl{sub 3} {center_dot} 6H{sub 2}O or Al(NO{sub 3}){sub 3} {center_dot} 9H{sub 2}O, followed by drying with supercritical CO{sub 2}. This technique affords low-density (60-130 kg/m{sup 3}), high surface area (600-700 m{sup 2}/g) alumina aerogel monoliths without the use of alkoxide precursors. The dried alumina aerogels were characterized using elemental analysis, high-resolution transmission electron microscopy, powder X-ray diffraction, solid state NMR, acoustic measurements and nitrogen adsorption/desorption analysis. Powder X-ray diffraction and TEM analysis indicated that the aerogel prepared from hydrated AlCl{sub 3} in water or ethanol possessed microstructures containing highly reticulated networks of pseudoboehmite fibers, 2-5 nm in diameter and of varying lengths, while the aerogels prepared from hydrated Al(NO{sub 3}){sub 3} in ethanol were amorphous with microstructures comprised of interconnected spherical particles with diameters in the 5-15 nm range. The difference in microstructure resulted in each type of aerogel displaying distinct physical and mechanical properties. In particular, the alumina aerogels with the weblike microstructure were far more mechanically robust than those with the colloidal network, based on acoustic measurements. Both types of alumina aerogels can be transformed to {gamma}-Al{sub 2}O{sub 3} through calcination at 800 C without a significant loss in surface area or monolithicity.

  2. The US petroleum refining industry in the 1980's

    SciTech Connect (OSTI)

    Not Available

    1990-10-11

    As part of the EIA program on petroleum, The US Petroleum Refining Industry in the 1980's, presents a historical analysis of the changes that took place in the US petroleum refining industry during the 1980's. It is intended to be of interest to analysts in the petroleum industry, state and federal government officials, Congress, and the general public. The report consists of six chapters and four appendices. Included is a detailed description of the major events and factors that affected the domestic refining industry during this period. Some of the changes that took place in the 1980's are the result of events that started in the 1970's. The impact of these events on US refinery configuration, operations, economics, and company ownership are examined. 23 figs., 11 tabs.

  3. PROP re-refined oil engine test performance

    SciTech Connect (OSTI)

    Linnard, R.E.

    1980-11-01

    Using conventional, commercially-available nonproprietary (to Phillips) additive treatments, engine test programs have successfully demonstrated Phillips Re-refined Oil Process (PROP) oils' compliance with the performance requirements of MIL-L-46152A and API Services SE/CC. This paper reports on the engine testing experience with PROP refined oils as produced in a full-scale 2 MM GPY PROP plant operating with Buyer-collected used oil feedstocks. Comment is also made on the status of the first two PROP plants, one built for the state of North Carolina and the other for Mohawk Oil Company, Ltd., Vancouver B.C., Canada.

  4. ,"Weekly Refiner Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Net Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Weekly Refiner Net Production",21,"Weekly","5/20/2016","6/4/2010" ,"Release Date:","5/25/2016" ,"Next Release Date:","6/2/2016" ,"Excel File

  5. ITP Petroleum Refining: Technology Roadmap for the Petroleum Industry |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Technology Roadmap for the Petroleum Industry ITP Petroleum Refining: Technology Roadmap for the Petroleum Industry PDF icon petroleumroadmap.pdf More Documents & Publications ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum Industry ITP Aluminum: Technical Working Group on Inert Anode Technologies 2011 Strategic Plan

  6. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.8 W 70.5 78.9 W 76.0 83.6 W 69.2 75.2 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  7. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 68.4 70.8 W W 78.6 W 85.7 81.8 W 69.3 73.8 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  8. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1995 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  9. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1997 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  10. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1995 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  11. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1996 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  12. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices J F M A M J J A S O N D 0 10 20 30 40 50 60 70 1995 Cents per Gallon Excluding Taxes Retail < or 1% Wholesale < or 1% Retail > 1% Wholesale > 1% 7. U.S. Refiner Residual...

  13. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1996 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  14. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1997 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  15. Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts

    DOE Patents [OSTI]

    Singleton, Alan H.; Oukaci, Rachid; Goodwin, James G.

    2001-01-01

    Cobalt catalysts, and processes employing these inventive catalysts, for hydrocarbon synthesis. The inventive catalyst comprises cobalt on an alumina support and is not promoted with any noble or near noble metals. In one aspect of the invention, the alumina support preferably includes a dopant in an amount effective for increasing the activity of the inventive catalyst. The dopant is preferably a titanium dopant. In another aspect of the invention, the cobalt catalyst is preferably reduced in the presence of hydrogen at a water vapor partial pressure effective to increase the activity of the cobalt catalyst for hydrocarbon synthesis. The water vapor partial pressure is preferably in the range of from 0 to about 0.1 atmospheres.

  16. Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Firlar, Emre; ?nar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-05-21

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions.moreWe discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. Our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.less

  17. Experimental investigation of a reticulated porous alumina heat exchanger for high temperature gas heat recovery

    SciTech Connect (OSTI)

    Banerjee, A; Chandran, RB; Davidson, JH

    2015-01-22

    The present study presents an experimental study of a prototype counter-flow heat exchanger designed to recover sensible heat from inert and reactive gases flowing through a high temperature solar reactor for splitting CO2. The tube-in-tube heat exchanger is comprised of two concentric alumina tubes, each filled with reticulated porous alumina with a nominal porosity of 80% and pore density of 5 pores per inch (ppi). The RPC provides high heat transfer surface area per unit volume (917 m(-1)) with low pressure drop. Measurements include the permeability, inertial coefficient, overall heat transfer coefficient, effectiveness and pressure drop. For laminar flow and an inlet gas temperature of 1240 K, the overall heat transfer coefficients are 36-41 W m(-2) K-1. The measured performance is in good agreement with a prior CFD model of the heat exchanger. (C) 2014 Elsevier Ltd. All rights reserved.

  18. Preparation of powders suitable for conversion to useful .beta.-aluminas

    DOE Patents [OSTI]

    Morgan, Peter E. D.

    1982-01-01

    A process for forming a precursor powder which, when suitably pressed and sintered forms highly pure, densified .beta.- or .beta."-alumina, comprising the steps of: (1) forming a suspension (or slurry) of Bayer-derived Al(OH).sub.3 in a water-miscible solvent; (2) adding an aqueous solution of a Mg compound, a Li compound, a Na compound or mixtures thereof to the Bayer-derived Al(OH).sub.3 suspension while agitating the mixture formed thereby, to produce a gel; (3) drying the gel at a temperature above the normal boiling point of water to produce a powder material; (4) lightly ball milling and sieving said powder material; and (5) heating the ball-milled and sieved powder material at a temperature of between 350.degree. to 900.degree. C. to form the .beta.- or .beta."-alumina precursor powder. The precursor powder, thus formed, may be subsequently isopressed at a high pressure and sintered at an elevated temperature to produce .beta.- or .beta."-alumina. BACKGROUND OF THE INVENTION

  19. Hydrogen Selective Thin Palladium-Copper Composite Membranes on Alumina Supports

    SciTech Connect (OSTI)

    Lim, Hankwon; Oyama, S. Ted

    2011-08-15

    Thin and defect-free PdCu composite membranes with high hydrogen permeances and selectivities were prepared by electroless plating of palladium and copper on porous alumina supports with pore sizes of 5 and 100 nm coated with intermediate layers. The intermediate layers on the 100 nm supports were prepared by the deposition of boehmite sols of different particle sizes, and provided a graded, uniform substrate for the formation of defect-free, ultra-thin palladium composite layers. The dependence of hydrogen flux on pressure difference was studied to understand the dominant mechanism of hydrogen transport through a PdCu composite membrane plated on an alumina support with a pore size of 5 nm. The order in hydrogen pressure was 0.98, and indicated that bulk diffusion through the PdCu layer was fast and the overall process was limited by external mass-transfer or a surface process. Scanning electron microscopy (SEM) images of the PdCu composite membrane showed a uniform substrate created after depositing one intermediate layer on top of the alumina support and a dense PdCu composite layer with no visible defects. Cross-sectional views of the membrane showed that the PdCu composite layer had a top layer thickness of 160 nm (0.16 ?m), which is much thinner than previously reported.

  20. The Effect of Excimer Laser Treatment on the Surface Roughness and Fracture Strength of Alumina Substrates

    SciTech Connect (OSTI)

    Smoot, J.E.

    1998-05-13

    The microelectronics industry requires alumina substrates with exceptionally smooth surfaces and few surface defects to allow successful deposition of metallic films for reliable electronic performance. Irradiation by a 248-nm wavelength excimer laser beam (KrF) at a fluence of 125 mJ/mm{sup 2} and at various angles of incidence is shown to significantly reduce the surface roughness of alumina substrates. However, irradiation also creates a fine particulate deposit of alumina that only partially adheres to the substrate and impedes deposition of metal films. Annealing in air between 1350 C and 1450 C was found to remove the particles by sintering. As-received material showed surface roughness average (R{sub a}) mean values of 457 nm, which was reduced to 60 nm (mean) following irradiation and 71 nm (mean) following irradiation and annealing at 1350 C. Irradiation also produced a decrease in the number and severity of surface defects. The flexural strength and Weibull modulus were both increased by laser irradiation and thermal treatment. Flexural strength went from an as-received value of 450 MPa to 560 MPa following irradiation/sintering, measured at 10% probability of failure. The Weibull modulus was increased from the as-received value of about 9, to about 13 following irradiation/sintering. It was concluded that irradiation at an angle of incidence of 60{degree} from perpendicular was most effective in producing a low surface roughness.

  1. REFINING AND END USE STUDY OF COAL LIQUIDS

    SciTech Connect (OSTI)

    Unknown

    2002-01-01

    This document summarizes all of the work conducted as part of the Refining and End Use Study of Coal Liquids. There were several distinct objectives set, as the study developed over time: (1) Demonstration of a Refinery Accepting Coal Liquids; (2) Emissions Screening of Indirect Diesel; (3) Biomass Gasification F-T Modeling; and (4) Updated Gas to Liquids (GTL) Baseline Design/Economic Study.

  2. Parallel Block Structured Adaptive Mesh Refinement on Graphics Processing Units

    SciTech Connect (OSTI)

    Beckingsale, D. A.; Gaudin, W. P.; Hornung, R. D.; Gunney, B. T.; Gamblin, T.; Herdman, J. A.; Jarvis, S. A.

    2014-11-17

    Block-structured adaptive mesh refinement is a technique that can be used when solving partial differential equations to reduce the number of zones necessary to achieve the required accuracy in areas of interest. These areas (shock fronts, material interfaces, etc.) are recursively covered with finer mesh patches that are grouped into a hierarchy of refinement levels. Despite the potential for large savings in computational requirements and memory usage without a corresponding reduction in accuracy, AMR adds overhead in managing the mesh hierarchy, adding complex communication and data movement requirements to a simulation. In this paper, we describe the design and implementation of a native GPU-based AMR library, including: the classes used to manage data on a mesh patch, the routines used for transferring data between GPUs on different nodes, and the data-parallel operators developed to coarsen and refine mesh data. We validate the performance and accuracy of our implementation using three test problems and two architectures: an eight-node cluster, and over four thousand nodes of Oak Ridge National Laboratory’s Titan supercomputer. Our GPU-based AMR hydrodynamics code performs up to 4.87× faster than the CPU-based implementation, and has been scaled to over four thousand GPUs using a combination of MPI and CUDA.

  3. Mesh refinement for uncertainty quantification through model reduction

    SciTech Connect (OSTI)

    Li, Jing Stinis, Panos

    2015-01-01

    We present a novel way of deciding when and where to refine a mesh in probability space in order to facilitate uncertainty quantification in the presence of discontinuities in random space. A discontinuity in random space makes the application of generalized polynomial chaos expansion techniques prohibitively expensive. The reason is that for discontinuous problems, the expansion converges very slowly. An alternative to using higher terms in the expansion is to divide the random space in smaller elements where a lower degree polynomial is adequate to describe the randomness. In general, the partition of the random space is a dynamic process since some areas of the random space, particularly around the discontinuity, need more refinement than others as time evolves. In the current work we propose a way to decide when and where to refine the random space mesh based on the use of a reduced model. The idea is that a good reduced model can monitor accurately, within a random space element, the cascade of activity to higher degree terms in the chaos expansion. In turn, this facilitates the efficient allocation of computational sources to the areas of random space where they are more needed. For the Kraichnan–Orszag system, the prototypical system to study discontinuities in random space, we present theoretical results which show why the proposed method is sound and numerical results which corroborate the theory.

  4. RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company, Inc.Commonwealth of Puerto Rico RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company, Inc....

  5. Petroleum Refining Sector (NAICS 324110) Energy and GHG Combustion Emissions Profile, November 2012

    Energy Savers [EERE]

    69 2.4 PETROLEUM REFINING SECTOR (NAICS 324110) 2.4.1. Overview of the Petroleum Refining Manufacturing Sector Petroleum refining is a complex industry that generates a diverse slate of fuel products and petrochemicals, from gasoline to asphalt. Refining requires a range of processing steps, including distillation, cracking, reforming, and treating. Most of these processes are highly reliant on process heating and steam energy. Petroleum refineries are an essential part of the U.S. economy.

  6. Cogeneration handbook for the petroleum refining industry. [Contains glossary

    SciTech Connect (OSTI)

    Fassbender, L.L.; Garrett-Price, B.A.; Moore, N.L.; Fassbender, A.G.; Eakin, D.E.; Gorges, H.A.

    1984-03-01

    The decision of whether to cogenerate involves several considerations, including technical, economic, environmental, legal, and regulatory issues. Each of these issues is addressed separately in this handbook. In addition, a chapter is included on preparing a three-phase work statement, which is needed to guide the design of a cogeneration system. In addition, an annotated bibliography and a glossary of terminology are provided. Appendix A provides an energy-use profile of the petroleum refining industry. Appendices B through O provide specific information that will be called out in subsequent chapters.

  7. Changing Trends in the Refining Industry (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    There have been some major changes in the U.S. refining industry recently, prompted in part by a significant decline in the quality of imported crude oil and by increasing restrictions on the quality of finished products. As a result, high-quality crudes, such as the West Texas Intermediate (WTI) crude that serves as a benchmark for oil futures on the New York Mercantile Exchange (NYMEX), have been trading at record premiums to the OPEC (Organization of the Petroleum Exporting Countries) Basket price.

  8. Manufacturing Energy and Carbon Footprint - Sector: Alumina and Aluminum (NAICS 3313), January 2014 (MECS 2010)

    Energy Savers [EERE]

    Alumina and Aluminum (NAICS 3313) Process Energy Electricity and Steam Generation Losses Process Losses 3 Nonprocess Losses 456 105 Steam Distribution Losses 3 7 Nonprocess Energy 99 Electricity Generation Steam Generation 456 5 Prepared for the U.S. Department of Energy, Advanced Manufacturing Office by Energetics Incorporated 16 198 116 Generation and Transmission Losses Generation and Transmission Losses 2 234 214 207 13 220 351 7 10 0.4 20.3 20.8 4.2 24.0 1.3 26 5.3 26.1 0.4 Fuel Total

  9. Numerical simulation of alumina spraying in argon-helium plasma jet

    SciTech Connect (OSTI)

    Chang, C.H.

    1992-01-01

    A new numerical model is described for simulating thermal plasmas containing entrained particles, with emphasis on plasma spraying applications. The plasma is represented as a continuum multicomponent chemically reacting ideal gas, while the particles are tracked as discrete Lagrangian entities coupled to the plasma. Computational results are presented from a transient simulation of alumina spraying in a turbulent argon-helium plasma jet in air environment, including torch geometry, substrate, and multiple species with chemical reactions. Particle-plasma interactions including turbulent dispersion have been modeled in a fully self-consistent manner. Interactions between the plasma and the torch and substrate walls are modeled using wall functions. (15 refs.)

  10. Numerical simulation of alumina spraying in argon-helium plasma jet

    SciTech Connect (OSTI)

    Chang, C.H.

    1992-08-01

    A new numerical model is described for simulating thermal plasmas containing entrained particles, with emphasis on plasma spraying applications. The plasma is represented as a continuum multicomponent chemically reacting ideal gas, while the particles are tracked as discrete Lagrangian entities coupled to the plasma. Computational results are presented from a transient simulation of alumina spraying in a turbulent argon-helium plasma jet in air environment, including torch geometry, substrate, and multiple species with chemical reactions. Particle-plasma interactions including turbulent dispersion have been modeled in a fully self-consistent manner. Interactions between the plasma and the torch and substrate walls are modeled using wall functions. (15 refs.)

  11. Single-crystal structure refinement of four compounds in the Y{sub 1{minus}{ital x}}Pr{sub {ital x}}Ba{sub 2}Cu{sub 3{minus}{ital y}}Al{sub {ital y}}O{sub 7{minus}{delta}} system

    SciTech Connect (OSTI)

    Meden, A.; Holzinger-Schweiger, E.; Leising, G.; Pejovnik, S.; Golic, L.

    1996-12-01

    X-ray single crystal diffraction data were used for structural refinement of the title compounds with different {ital x} (0.15, 0.27, 0.49 and 0.89). Crystals were grown in alumina crucibles using self-flux method. Aluminum, which originates from the crucibles, substitutes only Cu(1), and thus induces tetragonal symmetry which was observed in all four crystals. The main structural effect of praseodymium is an increased separation of superconducting layers. Substituent concentrations ({ital x} and {ital y} in the formula) have been refined and compared with the values obtained by EDX (energy dispersive x-ray analysis) in an electron microscope. It was indicated that the refined values of Y:Pr ratio and the oxygen content are more reliable than those obtained by EDX while the refinement is less sensitive for Cu(1):Al ratio and this value is more uncertain. This is in accordance with the result of wet chemical analysis. {copyright} {ital 1996 Materials Research Society.}

  12. Primary enzyme quantitation

    DOE Patents [OSTI]

    Saunders, G.C.

    1982-03-04

    The disclosure relates to the quantitation of a primary enzyme concentration by utilizing a substrate for the primary enzyme labeled with a second enzyme which is an indicator enzyme. Enzyme catalysis of the substrate occurs and results in release of the indicator enzyme in an amount directly proportional to the amount of primary enzyme present. By quantifying the free indicator enzyme one determines the amount of primary enzyme present.

  13. Hydrodesulfurization of dibenzothiophene catalyzed by alumina-supported ruthenium carbonyl complexes in a pressurized flow system

    SciTech Connect (OSTI)

    NONE

    1994-11-01

    Ruthenium sulfide has been found to be most active for hydrodesulfurization (HDS) of thiophenes as well as hydrogenation and hydrodenitrogenation among transition metal sulfides. When ruthenium sulfide is supported on alumina, silica, or zeolite with high surface area, highly dispersed ruthenium sulfide formed on the supports would increase the catalytic activity per a ruthenium atom. Several researchers have already reported HDS using supported ruthenium sulfides. In these works [Ru(NH{sub 3}){sub 6}]{sup +}, Ru{sub 3}(CO){sub 12}, RuCl{sub 3}, and Ru(III) acetate supported on alumina, zeoliate, carbon, etc., were used as catalyst precursors in HDS of thiophene, benzothiophene, or dibenzothiophene. Although these HDS reactions were performed under an atmospheric pressure, the activity of the catalysts derived from supported ruthenium in a pressurized flow system have not yet been understood. In the present study, HDS of DBT catalyzed by ruthenium catalysts is investigated in a pressurized flow reactor. 17 refs., 2 figs., 2 tabs.

  14. Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Firlar, Emre; Çınar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-05-21

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions.more » We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. As a result, our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.« less

  15. Method for preparing configured silicon carbide whisker-reinforced alumina ceramic articles

    DOE Patents [OSTI]

    Tiegs, Terry N.

    1987-01-01

    A ceramic article of alumina reinforced with silicon carbide whiskers suitable for the fabrication into articles of complex geometry are provided by pressureless sintering and hot isostatic pressing steps. In accordance with the method of the invention a mixture of 5 to 10 vol. % silicon carbide whiskers 0.5 to 5 wt. % of a sintering aid such as yttria and the balance alumina powders is ball-milled and pressureless sintered in the desired configuration in the desired configuration an inert atmosphere at a temperature of about 1800.degree. C. to provide a self-supporting configured composite of a density of at least about 94% theoretical density. The composite is then hot isostatically pressed at a temperature and pressure adequate to provide configured articles of at least about 98% of theoretical density which is sufficient to provide the article with sufficient strength and fracture toughness for use in most structural applications such as gas turbine blades, cylinders, and other components of advanced heat engines.

  16. Characterization of the alumina-zirconia ceramic system by ultrasonic velocity measurements

    SciTech Connect (OSTI)

    Carreon, Hector; Ruiz, Alberto; Medina, Ariosto; Barrera, Gerardo; Zarate, Juan

    2009-08-15

    In this work an alumina-zirconia ceramic composites have been prepared with {alpha}-Al{sub 2}O{sub 3} contents from 10 to 95 wt.%. The alumina-zirconia ceramic system was characterized by means of precise ultrasonic velocity measurements. In order to find out the factors affecting the variation in wave velocity, the ceramic composite have been examined by X-ray diffraction (XRD) and (SEM) scanning electron microscopy. It was found that the ultrasonic velocity measurements changed considerably with respect to the ceramic composite composition. In particular, we studied the behavior of the physical material property hardness, an important parameter of the ceramic composite mechanical properties, with respect to the variation in the longitudinal and shear wave velocities. Shear wave velocities exhibited a stronger interaction with microstructural and sub-structural features as compared to that of longitudinal waves. In particular, this phenomena was observed for the highest {alpha}-Al{sub 2}O{sub 3} content composite. Interestingly, an excellent correlation between ultrasonic velocity measurements and ceramic composite hardness was observed.

  17. A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)

    SciTech Connect (OSTI)

    Anil Virkar

    2008-03-31

    This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

  18. ENZO: AN ADAPTIVE MESH REFINEMENT CODE FOR ASTROPHYSICS

    SciTech Connect (OSTI)

    Bryan, Greg L.; Turk, Matthew J.; Norman, Michael L.; Bordner, James; Xu, Hao; Kritsuk, Alexei G.; O'Shea, Brian W.; Smith, Britton; Abel, Tom; Wang, Peng; Skillman, Samuel W.; Wise, John H.; Reynolds, Daniel R.; Collins, David C.; Harkness, Robert P.; Kim, Ji-hoon; Kuhlen, Michael; Goldbaum, Nathan; Hummels, Cameron; Collaboration: Enzo Collaboration; and others

    2014-04-01

    This paper describes the open-source code Enzo, which uses block-structured adaptive mesh refinement to provide high spatial and temporal resolution for modeling astrophysical fluid flows. The code is Cartesian, can be run in one, two, and three dimensions, and supports a wide variety of physics including hydrodynamics, ideal and non-ideal magnetohydrodynamics, N-body dynamics (and, more broadly, self-gravity of fluids and particles), primordial gas chemistry, optically thin radiative cooling of primordial and metal-enriched plasmas (as well as some optically-thick cooling models), radiation transport, cosmological expansion, and models for star formation and feedback in a cosmological context. In addition to explaining the algorithms implemented, we present solutions for a wide range of test problems, demonstrate the code's parallel performance, and discuss the Enzo collaboration's code development methodology.

  19. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  20. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  1. A comparative assessment of resource efficiency in petroleum refining

    SciTech Connect (OSTI)

    Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad; Cai, Hao; Wang, Michael; DiVita, Vincent B.

    2015-03-25

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study were incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.

  2. A comparative assessment of resource efficiency in petroleum refining

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad; Cai, Hao; Wang, Michael; DiVita, Vincent B.

    2015-03-25

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study weremore » incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.« less

  3. A Comparative Assessment of Resource Efficiency in Petroleum Refining

    SciTech Connect (OSTI)

    Han, Jeongwoo; Forman, G; Elgowainy, Amgad; Cai, Hao; Wang, Michael; Divita, V

    2015-10-01

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study were incorporated in Argonne National Laboratory's GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio. (c) 2015 Argonne National Laboratory. Published by Elsevier Ltd.

  4. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations: TROPICAL CHANNEL REFINEMENT IN MPAS-A

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martini, Matus N.; Gustafson, William I.; O'Brien, Travis A.; Ma, Po-Lun

    2015-09-01

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configurationmore » using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. The relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier studies that only refined portion of the tropics.« less

  5. Influence of Alloy and Solidification Parameters on Grain Refinement in Aluminum Weld Metal due to Inoculation

    SciTech Connect (OSTI)

    Schempp, Philipp [BAM, Germany; Tang, Z. [BIAS, Germany; Cross, Carl E. [Los Alamos National Laboratory; Seefeld, T. [BIAS, Germany; Pittner, A. [BAM, Germany; Rethmeier, M. [BAM, Germany

    2012-06-28

    The goals are: (1) Establish how much Ti/B grain refiner is need to completely refine aluminum weld metal for different alloys and different welding conditions; (2) Characterize how alloy composition and solidification parameters affect weld metal grain refinement; and (3) Apply relevant theory to understand observed behavior. Conclusions are: (1) additions of Ti/B grain refiner to weld metal in Alloys 1050, 5083, and 6082 resulted in significant grain refinement; (2) grain refinement was more effective in GTAW than LBW, resulting in finer grains at lower Ti content - reason is limited time available for equiaxed grain growth in LBW (inability to occlude columnar grain growth); (3) welding travel speed did not markedly affect grain size within GTAW and LBW clusters; and (4) application of Hunt CET analysis showed experimental G to be on the order of the critical G{sub CET}; G{sub CET} was consistently higher for GTAW than for LBW.

  6. Impact of Environmental Compliance Costs on U.S. Refining Profitability 1995-2001

    Reports and Publications (EIA)

    2003-01-01

    This report assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations during the 1995 to 2001 period. This study is a follow-up to the October 1997 publication entitled The Impact of Environmental Compliance Costs on U.S. Refining Profitability, that focused on the financial impacts of U.S. refining pollution abatement investment requirements in the 1988 to1995 period.

  7. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  8. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  9. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    retail outlets, e.g., sales to agricultural customers, commercial sales, and industrial sales. Source: Energy Information Administration Form EIA-782A, "Refiners'Gas...

  10. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  11. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  12. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 401 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  13. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  14. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  15. ,"Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Sales to End Users Refiner Sales Volumes",60,"Monthly","22016","1151983" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefot...

  16. ,"U.S. Sales to End Users, Total Refiner Motor Gasoline Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Gasoline Volumes",1,"Monthly","22016","1151983" ,"Data 2","by Grade",3,"Monthly","22016","1151983" ,"Data 3","by Formulation",3,"Monthly","22016","1151994" ...

  17. ,"U.S. Sales for Resale, Total Refiner Motor Gasoline Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Gasoline Volumes",1,"Monthly","22016","1151983" ,"Data 2","by Grade",3,"Monthly","22016","1151983" ,"Data 3","by Formulation",3,"Monthly","22016","1151994" ...

  18. Development and characterization of joining techniques for dispersion-strengthened alumina

    SciTech Connect (OSTI)

    Lugscheider, E.; Broich, U.; Buerger, W.

    1997-09-01

    The suitability of active brazing technology for joining TiC-strengthened alumina (ATC) to itself and to stainless steel is evaluated. The main emphasis is put on the investigation of the microstructural and mechanical properties of the active brazed joints. Furthermore, the electrical properties are investigated by determining the specific electrical resistance of active brazed Al{sub 2}O{sub 3}/TiC joints. For fabrication of the joints two process technologies are applied: vacuum furnace brazing and induction brazing under shielding gas. Four-point bend tests revealed that some of the vacuum-brazed ATC joints reach bending strengths comparable to those of bulk ATC. The induction brazing process is shown to be applicable when ATC has to be joined to metals, as in stainless steel for example. However, mechanically tough ATC-steel joints can only be fabricated when using very ductile filler metals, which are able to compensate thermally induced stresses by plastic deformation.

  19. Sealing 304L to lithia-alumina-silica (LAS) glass-ceramics

    SciTech Connect (OSTI)

    Moddeman, W.E.; Pence, R.E.; Massey, R.T.; Cassidy, R.T.; Kramer, D.P.

    1989-12-31

    The formation of a crack-free between 300 series stainless steel and a glass-ceramic is difficult owing to the high coefficients of thermal expansion of the stainless steels. Lithia-alumina-silica (LAS) glass-ceramics were successfully developed and sealed to 304L stainless steel. These crack-free seals were fabricated by two techniques: by adjusting the parent glass composition (reducing the Al{sub 2}O{sub 3} content), or by adjusting the sealing/crystallization cycle. All seals were hermetic, with leak rates < 10{sup -8} cc/sec STP helium. CTE and alloy yield strengths are given which show the feasibility of using these materials to make feedthroughs, pyrotechnic components, etc. Metallography, SEM, and wavelength dispersive spectroscopy show the quality and integrity of the glass-ceramic/stainless steel interface. These data are compared to those on the Inconel 718/LAS-glass seal system.

  20. Oxidation Reaction Induced Structural Changes in Sub-Nanometer Platinum Supported on Alumina

    SciTech Connect (OSTI)

    DeBusk, Melanie Moses; Allard, Jr, Lawrence Frederick; Blom, Douglas Allen; Narula, Chaitanya Kumar

    2015-06-26

    Platinum supported on alumina is an essential component of emission treatment catalysts used in transportation. Theoretical, experimental, and mechanistic aspects of platinum particles supported on a variety of supports have been extensively studied; however, available experimental information on the behavior of single vs. sub-nanometer platinum is extremely limited. To bridge the knowledge gap between single supported platinum and well-formed supported platinum nanoparticles, we have carried out synthesis, characterization, and CO and NO oxidation studies of sub-nanometer platinum supported on ?, ?, and ?-Al2O3 and monitored changes in structure upon exposure to CO and NO oxidation conditions. We find that sub-nanometer Pt is highly effective for CO oxidation due to high platinum dispersion but is not very efficient as NO oxidation catalyst. Furthermore, sub-nanometer platinum agglomerates rapidly under CO or NO oxidation conditions to form nanoparticles.

  1. Stress state and nature of failure of detonation coatings based on alumina

    SciTech Connect (OSTI)

    Anisimov, M.I.; Galeev, I.M.; Gol`dfain, V.N.

    1995-03-01

    Detonation coatings based on alumina are used on an increasing scale in industry for increasing the corrosion and wear resistance of materials. The physicomechanical and service characteristics of coatings are determined by the stress state . In this work, investigations were carried out into the distribution of residual phase stresses in the layer and the nature of failure of coatings in combined deformation with the substrate at T = 600{degrees}C. Coatings of electrocorundum powder of 24A grade with a grain size of M40 were deposited on a substrate of KhN78 alloy. In certain cases, an intermediate layer of PN85Yu15 powder was deposited on the substrate prior to spraying. Spraying was carried out in ADK Prometei equipment using an oxygen-acetylene mixture. The thickness of the coatings was 0.4-0.5 mm.

  2. Thermally conductive alumina/organic composites for photovoltaic concentrator cell isolation

    SciTech Connect (OSTI)

    Beavis, L.C.; Panitz, J.K.G.; Sharp, D.J.

    1988-01-01

    Electrophoretically deposited styrene-acrylate films were studied. These yield marginally useful thermal conductivities of 0.1--0.2 watts/meter-Kelvin, but have useful dielectric strengths over 2500 volts for 40 micrometer thick coatings. Thin, 25 micrometer, coatings of anodically grown Al/sub 2/O/sub 3/ films were also investigated. These films have thermal conductivities of approximately 6--8 watts/meter-Kelvin. Although these Al/sub 2/O/sub 3/ films have greater thermal conductivity than the polymer films, they exhibit porosity which typically limits their dielectric strength to less than 1000 volts. In the current study we have determined that styrene-acrylate can be electrophoretically deposited in porous anodic aluminum oxide films to form an alumina-organic composite with improved electrical breakdown strengths as well as higher thermal conductivity than styrene-acrylate films. 7 refs., 2 tabs.

  3. Oxidation Reaction Induced Structural Changes in Sub-Nanometer Platinum Supported on Alumina

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    DeBusk, Melanie Moses; Allard, Jr, Lawrence Frederick; Blom, Douglas Allen; Narula, Chaitanya Kumar

    2015-01-01

    Platinum supported on alumina is an essential component of emission treatment catalysts used in transportation. Theoretical, experimental, and mechanistic aspects of platinum particles supported on a variety of supports have been extensively studied; however, available experimental information on the behavior of single vs. sub-nanometer platinum is extremely limited. To bridge the knowledge gap between single supported platinum and well-formed supported platinum nanoparticles, we have carried out synthesis, characterization, and CO and NO oxidation studies of sub-nanometer platinum supported on α, θ, and γ-Al2O3 and monitored changes in structure upon exposure to CO and NO oxidation conditions. We find that sub-nanometermore » Pt is highly effective for CO oxidation due to high platinum dispersion but is not very efficient as NO oxidation catalyst. Furthermore, sub-nanometer platinum agglomerates rapidly under CO or NO oxidation conditions to form nanoparticles.« less

  4. Highly fluorescent silver nanoclusters in alumina-silica composite optical fiber

    SciTech Connect (OSTI)

    Halder, A.; Chattopadhyay, R.; Majumder, S.; Paul, M. C.; Das, S.; Bhadra, S. K.; Bysakh, S.; Unnikrishnan, M.

    2015-01-05

    An efficient visible fluorescent optical fiber embedded with silver nanoclusters (Ag-NCs) having size ∼1 nm, uniformly distributed in alumina-silica composite core glass, is reported. Fibers are fabricated in a repetitive controlled way through modified chemical vapour deposition process associated with solution doping technique. Fibers are drawn from the transparent preforms by conventional fiber drawing process. Structural characteristics of the doped fibers are studied using transmission electron microscopy and electron probe micro analysis. The oxidation state of Ag within Ag-NCs is investigated by X-ray photo electron spectroscopy. The observed significant fluorescence of the metal clusters in fabricated fibers is correlated with electronic model. The experimentally observed size dependent absorption of the metal clusters in fabricated fibers is explained with the help of reported results calculated by ab-initio density functional theory. These optical fibers may open up an opportunity of realizing tunable wavelength fiber laser without the help of rare earth elements.

  5. Structure, Stoichiometry and Stability in Magnetoplumbite and {beta}-Alumina Structured Type Ceramics. Final Report

    SciTech Connect (OSTI)

    Cormack, A. N.

    2004-03-01

    Work has been completed on the atomistic simulation of hexa-aluminate ceramics with the magnetoplumbite and beta-alumina type structures. In this report, three aspects of the work are highlighted. One is the simulation of surface structures. The second concerns details of the interstitially mechanisms observed in molecular dynamics simulations. The novel result here is the observation that the lattice ion always leaves its Beevers-Ross site before the aBR interstitial begins to move towards the lattice site. It is also found that, as expected, the interstitial mechanism is the most common mechanism in the heavily disordered nonstoichiometric structure, as well as in the stoichiometric material. Finally, the disposition of trivalent europium in the phosphor material BAM has been elucidated.

  6. Advances in Patch-Based Adaptive Mesh Refinement Scalability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gunney, Brian T.N.; Anderson, Robert W.

    2015-12-18

    Patch-based structured adaptive mesh refinement (SAMR) is widely used for high-resolution simu- lations. Combined with modern supercomputers, it could provide simulations of unprecedented size and resolution. A persistent challenge for this com- bination has been managing dynamically adaptive meshes on more and more MPI tasks. The dis- tributed mesh management scheme in SAMRAI has made some progress SAMR scalability, but early al- gorithms still had trouble scaling past the regime of 105 MPI tasks. This work provides two critical SAMR regridding algorithms, which are integrated into that scheme to ensure efficiency of the whole. The clustering algorithm is an extensionmore » of the tile- clustering approach, making it more flexible and efficient in both clustering and parallelism. The partitioner is a new algorithm designed to prevent the network congestion experienced by its prede- cessor. We evaluated performance using weak- and strong-scaling benchmarks designed to be difficult for dynamic adaptivity. Results show good scaling on up to 1.5M cores and 2M MPI tasks. Detailed timing diagnostics suggest scaling would continue well past that.« less

  7. Advances in Patch-Based Adaptive Mesh Refinement Scalability

    SciTech Connect (OSTI)

    Gunney, Brian T.N.; Anderson, Robert W.

    2015-12-18

    Patch-based structured adaptive mesh refinement (SAMR) is widely used for high-resolution simu- lations. Combined with modern supercomputers, it could provide simulations of unprecedented size and resolution. A persistent challenge for this com- bination has been managing dynamically adaptive meshes on more and more MPI tasks. The dis- tributed mesh management scheme in SAMRAI has made some progress SAMR scalability, but early al- gorithms still had trouble scaling past the regime of 105 MPI tasks. This work provides two critical SAMR regridding algorithms, which are integrated into that scheme to ensure efficiency of the whole. The clustering algorithm is an extension of the tile- clustering approach, making it more flexible and efficient in both clustering and parallelism. The partitioner is a new algorithm designed to prevent the network congestion experienced by its prede- cessor. We evaluated performance using weak- and strong-scaling benchmarks designed to be difficult for dynamic adaptivity. Results show good scaling on up to 1.5M cores and 2M MPI tasks. Detailed timing diagnostics suggest scaling would continue well past that.

  8. Environmental regulations and changes in petroleum refining operations

    SciTech Connect (OSTI)

    Lidderdale, T.C.M.

    1996-03-01

    The U.S. petroleum industry has responded to four major new federal rules on motor gasoline product quality in the last 6 years: Phase 1 Summer Volatility (Rvp) Regulation, June 1989; Phase 2 Summer Volatility (Rvp) regulation, May 1992; oxygenated Gasoline, November 1992; and reformulated Gasoline Phase I Simple Model, December 1994. These regulations have generated significant changes in domestic refinery operations, affecting marginal production costs and market prices, refinery yields, and the seasonality of production. Some changes have been dramatic. The price of motor gasoline has increased by as much as 60 {cents}/gal due to regulations. Refinery yields of motor gasoline (refinery output of motor gasoline as a fraction of refinery inputs or total refinery output), which historically peaked in the early summer to meet high summer driving demand, now are highest during the winter months. These changes in domestic refining operations are identified and related to the vapor pressure, oxygenated and reformulated gasoline (RFG) product quality regulations. This analysis uses linear regression equations from the Energy Information Administration`s (EIA) Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the EIA`s Short-Term Energy Outlook.

  9. Aspects of Western Refining, Inc.'s Proposed Acquisition of Giant Industries, Inc.

    Reports and Publications (EIA)

    2006-01-01

    Presentation of company-level, non-proprietary data and relevant aggregate data for U.S. refinery capacity and gasoline marketing of Western Refining and Giant Industries to inform discussions of Western Refining Inc.'s proposed acquisition of Giant Industries Inc. for a total of $1.5 billion, which was announced August 28, 2006.

  10. RAM: a Relativistic Adaptive Mesh Refinement Hydrodynamics Code

    SciTech Connect (OSTI)

    Zhang, Wei-Qun; MacFadyen, Andrew I.; /Princeton, Inst. Advanced Study

    2005-06-06

    The authors have developed a new computer code, RAM, to solve the conservative equations of special relativistic hydrodynamics (SRHD) using adaptive mesh refinement (AMR) on parallel computers. They have implemented a characteristic-wise, finite difference, weighted essentially non-oscillatory (WENO) scheme using the full characteristic decomposition of the SRHD equations to achieve fifth-order accuracy in space. For time integration they use the method of lines with a third-order total variation diminishing (TVD) Runge-Kutta scheme. They have also implemented fourth and fifth order Runge-Kutta time integration schemes for comparison. The implementation of AMR and parallelization is based on the FLASH code. RAM is modular and includes the capability to easily swap hydrodynamics solvers, reconstruction methods and physics modules. In addition to WENO they have implemented a finite volume module with the piecewise parabolic method (PPM) for reconstruction and the modified Marquina approximate Riemann solver to work with TVD Runge-Kutta time integration. They examine the difficulty of accurately simulating shear flows in numerical relativistic hydrodynamics codes. They show that under-resolved simulations of simple test problems with transverse velocity components produce incorrect results and demonstrate the ability of RAM to correctly solve these problems. RAM has been tested in one, two and three dimensions and in Cartesian, cylindrical and spherical coordinates. they have demonstrated fifth-order accuracy for WENO in one and two dimensions and performed detailed comparison with other schemes for which they show significantly lower convergence rates. Extensive testing is presented demonstrating the ability of RAM to address challenging open questions in relativistic astrophysics.

  11. On the physical and chemical details of alumina atomic layer deposition: A combined experimental and numerical approach

    SciTech Connect (OSTI)

    Pan, Dongqing; Ma, Lulu; Xie, Yuanyuan; Yuan, Chris; Jen, Tien Chien

    2015-03-15

    Alumina thin film is typically studied as a model atomic layer deposition (ALD) process due to its high dielectric constant, high thermal stability, and good adhesion on various wafer surfaces. Despite extensive applications of alumina ALD in microelectronics industries, details on the physical and chemical processes are not yet well understood. ALD experiments are not able to shed adequate light on the detailed information regarding the transient ALD process. Most of current numerical approaches lack detailed surface reaction mechanisms, and their results are not well correlated with experimental observations. In this paper, the authors present a combined experimental and numerical study on the details of flow and surface reactions in alumina ALD using trimethylaluminum and water as precursors. Results obtained from experiments and simulations are compared and correlated. By experiments, growth rate on five samples under different deposition conditions is characterized. The deposition rate from numerical simulation agrees well with the experimental results. Details of precursor distributions in a full cycle of ALD are studied numerically to bridge between experimental observations and simulations. The 3D transient numerical model adopts surface reaction kinetics and mechanisms based on atomic-level studies to investigate the surface deposition process. Surface deposition is shown as a strictly self-limited process in our numerical studies. ALD is a complex strong-coupled fluid, thermal and chemical process, which is not only heavily dependent on the chemical kinetics and surface conditions but also on the flow and material distributions.

  12. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore; Cross, Carl E.

    2012-06-28

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  13. Method for fabricating cermets of alumina-chromium systems. [Patent application

    DOE Patents [OSTI]

    Morgan, C.S.

    1981-10-05

    Cermet insulators resistant to thermal and mechanical shock are prepared from alumina-chromium systems in the following way: by providing an Al/sub 2/O/sub 3/ material of about 0.5 to 7.0 micron size with a solid-hydrocarbon overcoating by slurrying an effective amount of said solid hydrocarbon in a solvent mixture containing said Al/sub 2/O/sub 3/ and thereafter evaporating said solvent, contacting said coated Al/sub 2/O/sub 3/ with a solution of chromium precursor compound, heating the resulting mixture in a reducing environment to a temperature above the decomposition temperature of said chromium precursor compound but less than the melting temperature of the Al/sub 2/O/sub 3/ or chromium for sufficient duration to yield a particulate compound having chromium essentially dispersed throughout the Al/sub 2/O/sub 3/, and then densifying said particulate to provide said cermet characterized by a theoretical density in excess of 96% and having 0.1 to 10.0 vol. % elemental chromium metal present therein as a dispersed phase at the boundaries of the Al/sub 2/O/sub 3/ material. Cermet components prepared thereby are useful in high temperature equipment, advanced heat engines, and nuclear-related equipment applications where electrical or thermal insulators are required.

  14. Freeze-cast alumina pore networks: Effects of freezing conditions and dispersion medium

    SciTech Connect (OSTI)

    Miller, S. M.; Xiao, X.; Faber, K. T.

    2015-11-01

    Alumina ceramics were freeze-cast from water- and camphene-based slurries under varying freezing conditions and examined using X-ray computed tomography (XCT). Pore network characteristics, i.e., porosity, pore size, geometric surface area, and tortuosity, were measured from XCT reconstructions and the data were used to develop a model to predict feature size from processing conditions. Classical solidification theory was used to examine relationships between pore size, temperature gradients, and freezing front velocity. Freezing front velocity was subsequently predicted from casting conditions via the two-phase Stefan problem. Resulting models for water-based samples agreed with solidification-based theories predicting lamellar spacing of binary eutectic alloys, and models for camphene-based samples concurred with those for dendritic growth. Relationships between freezing conditions and geometric surface area were also modeled by considering the inverse relationship between pore size and surface area. Tortuosity was determined to be dependent primarily on the type of dispersion medium. (C) 2015 Elsevier Ltd. All rights reserved.

  15. Precipitation kinetics during aging of an alumina-forming austenitic stainless steel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Trotter, Geneva; Hu, Bin; Sun, Annie Y.; Harder, Reed; Miller, Michael K.; Baker, Ian; Yao, Lan

    2016-04-28

    The microstructural evolution of DAFA26, an alumina-forming austenitic (AFA) stainless steel, was investigated during aging. The effect of aging at 750 °C and 800 °C on the growth of spherical γ’-Ni3(Al, Ti) particles present in the as-processed state was studied extensively using X-ray diffraction, microhardness testing, scanning electron microscopy, transmission electron microscopy, and atom probe tomography. The γ’ particles had a cube-on-cube orientation relationship with the matrix (i.e. ((010)(010)m//(010)(010)p, [100][100]m//[100][100]p)). The coarsening kinetics of γ’-Ni3Al particles were in agreement with the Lifshitz, Slyozof-Wagner theory. Coarse Laves phase particles were also present in the as-processed state, and during the aging processmore » both smaller Laves phase precipitates and B2-NiAl precipitates formed on both the grain boundaries and in the matrix. As a result, the γ’ precipitates were determined to have the most impact on the room temperature hardness.« less

  16. Rheology and microstructure of concentrated zirconia-alumina suspensions for gelcasting composites

    SciTech Connect (OSTI)

    Bleier, A.; Omatete, O.O.

    1992-12-31

    The relations among colloidal stability, suspension rheology, and solids loading are elucidated for zirconia-alumina mixtures containing 20 volt ZrO{sub 2}, based on solids. The lower colloidal stability of ZrO{sub 2} limits the rheological properties of this system. If the zeta potential of ZrO{sub 2} is less than 49 mV, high degrees of pseudoplasticity, high yield stress, high viscosity, and long relaxation times characterize the binary suspensions. These effects occur, despite the fact that ZrO{sub 2} is the minor ceramic constituent. If the zeta potential of ZrO{sub 2} is maintained above 49 mV, suspensions with high solids loading (55 vol%) can be prepared which behave as Newtonian fluids over the 0-to-200 s-1 shear rate range and as an elastic solid at higher rates. As the solids loading of a highly stable binary suspension is increased, the rheological properties change. They evolve from those of a near Newtonian-like fluid with nearly independent particles (40 vol%) to those of a pseudoplastic fluid with a weakly interacting particle network (50 vol%) to those of an elastic-like solid composed of crowded, strongly repulsive particles (55 vol%). Low-shear conditions for suspension-transport and mold-filling operations that ensure a homogeneous arrangement of ZrO{sub 2} and Al{sub 2}O{sub 3} particles in a gelcast ceramic seem promising.

  17. Optical performance and durability of solar reflectors protected by an alumina coating

    SciTech Connect (OSTI)

    Kennedy, C.E.; Smilgys, R.V.; Kirkpatrick, D.A.; Ross, J.S.

    1996-07-01

    Solar thermal electric power systems use large solar reflectors to concentrate sunlight to generate electricity. The economic viability of these systems depends on developing a durable, low-cost reflector. The goals for such a reflector are specular reflectance above 90% for at least 10 years under outdoor service conditions and a large-volume manufacturing cost of less than $10.8/m{sup 2} ($1.00/ft{sup 2}). Currently, the best candidate materials for solar reflectors are silver-coated, low-iron glass and silvered polymer films. Polymer reflectors are lighter in weight, offer greater system design flexibility, and have the potential for lower cost than glass reflectors. A promising low-cost reflector consists of a silvered polymer protected by an optically transparent alumina coating. The coating is deposited by an ion-beam-assisted physical vapor deposition (IBAD) technique. Samples of this reflector have maintained high optical performance in accelerated testing at the National Renewable Energy Laboratory for more than 3000 hours. Solar reflectors produced using this technique may represent an opportunity to bring solar power generation to reality.

  18. Recovery Act - Refinement of Cross Flow Turbine Airfoils

    SciTech Connect (OSTI)

    McEntee, Jarlath

    2013-08-30

    Ocean Renewable Power Company, LLC (ORPC) is a global leader in hydrokinetic technology and project development. ORPC develops hydrokinetic power systems and eco-conscious projects that harness the power of oceans and rivers to create clean, predictable renewable energy. ORPC’s technology consists of a family of modular hydrokinetic power systems: the TidGen® Power System, for use at shallow to medium-depth tidal sites; the RivGen™ Power System, for use at river and estuary sites; and the OCGen® Power System, presently under development, for use at deep tidal and offshore ocean current sites. These power systems convert kinetic energy in moving water into clean, renewable, grid-compatible electric power. The core technology component for all ORPC power systems is its patented turbine generator unit (TGU). The TGU uses proprietary advanced design cross flow (ADCF) turbines to drive an underwater permanent magnet generator mounted at the TGU’s center. It is a gearless, direct-drive system that has the potential for high reliability, requires no lubricants and releases no toxins that could contaminate the surrounding water. The hydrokinetic industry shows tremendous promise as a means of helping reduce the U.S.’s use of fossil fuels and dependence on foreign oil. To exploit this market opportunity, cross-flow hydrokinetic devices need to advance beyond the pre-commercial state and more systematic data about the structure and function of cross-flow hydrokinetic devices is required. This DOE STTR project, “Recovery Act - Refinement of Cross Flow Turbine Airfoils,” refined the cross-flow turbine design process to improve efficiency and performance and developed turbine manufacturing processes appropriate for volume production. The project proposed (1) to overcome the lack of data by extensively studying the properties of cross flow turbines, a particularly competitive design approach for extracting hydrokinetic energy and (2) to help ORPC mature its pre-commercial hydrokinetic technology into a commercially viable product over a three-year period by means of a design-for-manufacture process to be applied to the turbines which would result in a detail turbine design suitable for volume manufacture. In Phase I of the Project, ORPC systematically investigated performance of cross flow turbines by varying design parameters including solidity, foil profile, number of foils and foil toe angle using scale models of ORPC’s turbine design in a tow tank at the University of Maine (UMaine). Data collected provided information on interactions between design variables and helped ORPC improve turbine efficiency from 21% to greater than 35%. Analytical models were developed to better understand the physical phenomena at play in cross-flow turbines. In Phase II of the Project, ORPC expanded on data collected in Phase I to continue improving turbine efficiency, with a goal to optimally approach the Betz limit of 59.3%. Further tow tank testing and development of the analytical models and techniques was completed at UMaine and led to a deeper understanding of the flow phenomena involved. In addition, ORPC evaluated various designs, materials and manufacturing methods for full-scale turbine foils, and identified those most conducive to volume manufacture. Selected components of the turbine were structurally tested in a laboratory environment at UMaine. Performance and structural testing of the full scale turbine design was conducted as part of the field testing. The work funded by this project enabled the development of design tools for the rapid and efficient development of high performance cross-flow hydrokinetic turbine foils. The analytical tools are accurate and properly capture the underlying physical flow phenomena present in hydrokinetic cross-flow turbines. The ability to efficiently examine the design space provides substantial economic benefit to ORPC in that it allows for rapid design iteration at a low computational cost. The design-for-manufacture work enabled the delivery of a turbine design suitable for manufacture in intermediate to large quantity, lowering the unit cost of turbines and the levelized cost of electricity from ORPC hydrokinetic turbine. ORPC fielded the turbine design in a full scale application – the Cobscook Bay Tidal Energy Project which began operation off the coast of Eastport, Maine in September 2012. This is the first commercial, grid-connected tidal energy project in North America and the only ocean energy project not involving a dam which delivers power to a utility grid anywhere in the Americas. ORPC received a Federal Energy Regulatory Commission pilot project license to install and operate this project in February 2012. Construction of the TidGen® Power System began in March 2012, and the system was grid-connected on September 13, 2012. A 20-year commercial power purchase agreement to sell the power generated by the project was completed with Bangor Hydro Electric Company and is the first and only power purchase agreement for tidal energy. This is the first project in the U.S. to receive Renewable Energy Certificates for tidal energy production. The STTR project is a benefit to the public through its creation of jobs. ORPC’s recent deployment of the TidGen™ Power System is part of their larger project, the Maine Tidal Energy Project. According to ORPC’s report to the Maine Public Utilities Commission and the 20-year power purchase agreement, the Maine Tidal Energy Project will create and/or retain at least 80 direct full-time equivalent jobs in Maine during the development, construction and installation phase (2011 through 2016). In addition, the Maine Tidal Energy Project will create and/or retain at least 12 direct full-time equivalent jobs in Maine during the operating and maintenance phase (2016 through 2020). The STTR project has facilitated new and expanded services in manufacturing, fabrication and assembly, including major business growth for the composite technologies sector; creation of deepwater deployment, maintenance and retrieval services; and the expansion and formation of technical support services such as site assessment and design services, geotechnical services, underwater transmission services, and environmental monitoring services. The Maine Tidal Energy Project’s impact on workforce will enable other ocean energy projects – be they offshore wind, wave or additional tidal opportunities – to succeed in Maine. ORPC received a 2013 Tibbetts Award by the U.S. Small Business Administration.

  19. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  20. Impact of Environmental Compliance Costs on U.S. Refining Profitability

    Reports and Publications (EIA)

    1997-01-01

    Assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations. The analysis draws heavily on financial and operating data from the Energy Information Administration's Financial Reporting System (FRS).

  1. FIA-15-0002- In the Matter of Alon Refining Krotz Springs, Inc.

    Broader source: Energy.gov [DOE]

    This Decision concerns an Appeal that Alon Refining Krotz Springs, Inc. (Alon) filed in response to a determination that was issued to it by the Department of Energy’s (DOE) Office of Information...

  2. Energy and Environmental Profile of the U.S. Petroleum Refining Industry

    SciTech Connect (OSTI)

    Pellegrino, Joan; Brueske, Sabine; Carole, Tracy; Andres, Howard

    2007-11-01

    This 2007 report provides an overview of the U.S. petroleum refining industry, including new data on market trends and energy and material consumption, as well as information on environmental performance.

  3. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    NA 26.6 See footnotes at end of table. 14 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type...

  4. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    NA 27.4 See footnotes at end of table. 14 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type...

  5. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  6. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.3 3.4 7.9 3.3 W 11.3 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  7. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    88.4 87.8 80.1 70.0 NA 72.6 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  8. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 4.4 12.9 NA 17.3 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  9. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.8 92.5 84.0 72.5 W 80.7 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  10. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    87.4 86.9 78.3 68.5 W 70.8 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  11. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.4 92.1 83.7 74.1 W 80.9 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  12. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    98.0 98.0 86.6 75.0 - 80.1 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  13. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    94.0 93.9 83.2 73.8 - 79.3 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  14. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.6 3.7 7.9 3.1 W 11.0 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  16. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    0.1 18.7 See footnotes at end of table. 18 Energy Information Administration Petroleum Marketing Annual 1995 Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade...

  17. Fact #676: May 23, 2011 U.S. Refiners Produce about 19 Gallons...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A standard U.S. barrel contains 42 gallons of crude oil which yields about 44 gallons of ... and 10 gallons of diesel fuel are produced from a barrel of crudeoil by U.S. refiners. ...

  18. Reductions in Northeast Refining Activity: Potential Implications for Petroleum Product Markets

    Reports and Publications (EIA)

    2011-01-01

    This report is the Energy Information Administration's (EIA) initial effort to provide information and analysis on the potential impacts on petroleum product markets from reductions in Northeast petroleum refining activity.

  19. The Space-based Telescopes for Actionable Refinement of Ephemeris (STARE)

    Office of Scientific and Technical Information (OSTI)

    mission (Conference) | SciTech Connect Space-based Telescopes for Actionable Refinement of Ephemeris (STARE) mission Citation Details In-Document Search Title: The Space-based Telescopes for Actionable Refinement of Ephemeris (STARE) mission Authors: Riot, V ; Devries, W ; Bauman, B ; Simms, L ; Carter, D ; Phillion, D ; Olivier, S Publication Date: 2013-05-28 OSTI Identifier: 1092503 Report Number(s): LLNL-CONF-637976 DOE Contract Number: W-7405-ENG-48 Resource Type: Conference Resource

  20. Gulf Canada donor refined bitumen heavy oil upgrading process

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-09-01

    The method is a moderate-pressure, noncatalytic alternative which has been shown to be applicable to a wide range of bitumens and heavy oils. It offers the potential of efficiency and reliability at a low capitalized investment and operating cost. The raw distillates are separated from the bitumen or heavy oil and the vacuum residuum is blended with an efficient hydrogen donor stream containing a high proportion of substituted tetralins, and is thermally cracking in the liquid phase. The exhausted donor is recovered from the middle distillate reactor product, reactivated by fixed bed hydrogenation before being recycled to the reactor. The process can be self-sufficient in donor and is independent of the metal content of the feed. The products are blanded with the raw distillates and further hydrogenated to high quality petroleum products. While the primary hydrogen consumption is low, the reconstituted naphtha, distillate and gas oil fractions require less hydrogen than the coker liquids to achieve acceptable refinery feed quality. 1 figure, 9 tables.

  1. Manufacture of Alumina-Forming Austenitic Steel Alloys by Conventional Casting and Hot-Working Methods

    SciTech Connect (OSTI)

    Brady, M.P.; Yamamoto, Y.; Magee, J.H.

    2009-03-10

    Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation Program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 301b heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(l-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions. AFA alloy properties to date have been obtained from small laboratory scale arc-castings made at ORNL. The goal of the ORNL-CarTech CRADA was to establish the viability for producing plate, sheet and foil of the AFA alloys by conventional casting and hot working approaches as a first step towards scale up and commercialization of the AFA alloys. The AFA alloy produced under this effort will then be evaluated in related CRADAs with two gas turbine engine manufacturers for gas turbine recuperator applications.

  2. An adaptive grid refinement strategy for the simulation of negative streamers

    SciTech Connect (OSTI)

    Montijn, C. . E-mail: carolynne.montijn@cwi.nl; Hundsdorfer, W. . E-mail: willem.hundsdorfer@cwi.nl; Ebert, U. . E-mail: ute.ebert@cwi.nl

    2006-12-10

    The evolution of negative streamers during electric breakdown of a non-attaching gas can be described by a two-fluid model for electrons and positive ions. It consists of continuity equations for the charged particles including drift, diffusion and reaction in the local electric field, coupled to the Poisson equation for the electric potential. The model generates field enhancement and steep propagating ionization fronts at the tip of growing ionized filaments. An adaptive grid refinement method for the simulation of these structures is presented. It uses finite volume spatial discretizations and explicit time stepping, which allows the decoupling of the grids for the continuity equations from those for the Poisson equation. Standard refinement methods in which the refinement criterion is based on local error monitors fail due to the pulled character of the streamer front that propagates into a linearly unstable state. We present a refinement method which deals with all these features. Tests on one-dimensional streamer fronts as well as on three-dimensional streamers with cylindrical symmetry (hence effectively 2D for numerical purposes) are carried out successfully. Results on fine grids are presented, they show that such an adaptive grid method is needed to capture the streamer characteristics well. This refinement strategy enables us to adequately compute negative streamers in pure gases in the parameter regime where a physical instability appears: branching streamers.

  3. Table 5.22 Refiner Sales Prices and Refiner Margins for Selected Petroleum Products, 1995-2011 (Dollars per Gallon, Excluding Taxes)

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Refiner Sales Prices and Refiner Margins for Selected Petroleum Products, 1995-2011 (Dollars 1 per Gallon, Excluding Taxes) Product 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 Sales Prices to Resellers: 2 Aviation Gasoline 0.975 1.055 1.065 0.912 1.007 1.330 1.256 1.146 1.288 1.627 2.076 2.490 2.758 3.342 2.480 2.874 3.739 Motor Gasoline .626 .713 .700 .526 .645 .963 .886 .828 1.002 1.288 1.670 1.969 2.182 2.586 1.767 2.165 2.867 Unleaded Regular .593

  4. Adaptive h -refinement for reduced-order models: ADAPTIVE h -refinement for reduced-order models

    SciTech Connect (OSTI)

    Carlberg, Kevin T.

    2014-11-05

    Our work presents a method to adaptively refine reduced-order models a posteriori without requiring additional full-order-model solves. The technique is analogous to mesh-adaptive h-refinement: it enriches the reduced-basis space online by splitting a given basis vector into several vectors with disjoint support. The splitting scheme is defined by a tree structure constructed offline via recursive k-means clustering of the state variables using snapshot data. This method identifies the vectors to split online using a dual-weighted-residual approach that aims to reduce error in an output quantity of interest. The resulting method generates a hierarchy of subspaces online without requiring large-scale operations or full-order-model solves. Furthermore, it enables the reduced-order model to satisfy any prescribed error tolerance regardless of its original fidelity, as a completely refined reduced-order model is mathematically equivalent to the original full-order model. Experiments on a parameterized inviscid Burgers equation highlight the ability of the method to capture phenomena (e.g., moving shocks) not contained in the span of the original reduced basis.

  5. Density dependence of the room temperature thermal conductivity of atomic layer deposition-grown amorphous alumina (Al{sub 2}O{sub 3})

    SciTech Connect (OSTI)

    Gorham, Caroline S.; Gaskins, John T.; Hopkins, Patrick E.; Parsons, Gregory N.; Losego, Mark D.

    2014-06-23

    We report on the thermal conductivity of atomic layer deposition-grown amorphous alumina thin films as a function of atomic density. Using time domain thermoreflectance, we measure the thermal conductivity of the thin alumina films at room temperature. The thermal conductivities vary ?35% for a nearly 15% change in atomic density and are substrate independent. No density dependence of the longitudinal sound speeds is observed with picosecond acoustics. The density dependence of the thermal conductivity agrees well with a minimum limit to thermal conductivity model that is modified with a differential effective-medium approximation.

  6. Deformation Behavior of Sub-micron and Micron Sized Alumina Particles in Compression.

    SciTech Connect (OSTI)

    Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay; Mook, William; Boyce, Brad; Kotula, Paul G.; McKenzie, Bonnie B.; Bufford, Daniel Charles; Hall, Aaron Christopher.

    2014-09-01

    The ability to integrate ceramics with other materials has been limited due to high temperature (>800degC) ceramic processing. Recently, researchers demonstrated a novel process , aerosol deposition (AD), to fabricate ceramic films at room temperature (RT). In this process, sub - micro n sized ceramic particles are accelerated by pressurized gas, impacted on the substrate, plastically deformed, and form a dense film under vacuum. This AD process eliminates high temperature processing thereby enabling new coatings and device integration, in which ceramics can be deposited on metals, plastics, and glass. However, k nowledge in fundamental mechanisms for ceramic particle s to deform and form a dense ceramic film is still needed and is essential in advancing this novel RT technology. In this wo rk, a combination of experimentation and atomistic simulation was used to determine the deformation behavior of sub - micron sized ceramic particle s ; this is the first fundamental step needed to explain coating formation in the AD process . High purity, singl e crystal, alpha alumina particles with nominal size s of 0.3 um and 3.0 um were examined. Particle characterization, using transmission electron microscopy (TEM ), showed that the 0.3 u m particles were relatively defect - free single crystals whereas 3.0 u m p articles were highly defective single crystals or particles contained low angle grain boundaries. Sub - micron sized Al 2 O 3 particles exhibited ductile failure in compression. In situ compression experiments showed 0.3um particles deformed plastically, fractured, and became polycrystalline. Moreover, dislocation activit y was observed within the se particles during compression . These sub - micron sized Al 2 O 3 particles exhibited large accum ulated strain (2 - 3 times those of micron - sized particles) before first fracture. I n agreement with the findings from experimentation , a tomistic simulation s of nano - Al 2 O 3 particles showed dislocation slip and significant plastic deformation during compressi on . On the other hand, the micron sized Al 2 O 3 particles exhibited brittle f racture in compression. In situ compression experiments showed 3um Al 2 O 3 particles fractured into pieces without observable plastic deformation in compression. Particle deformation behaviors will be used to inform Al 2 O 3 coating deposition parameters and particle - particle bonding in the consolidated Al 2 O 3 coatings.

  7. Free kick instead of cross-validation in maximum-likelihood refinement of macromolecular crystal structures

    SciTech Connect (OSTI)

    Pranikar, Jure [Institute Joef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); University of Primorska, (Slovenia); Turk, Duan, E-mail: dusan.turk@ijs.si [Institute Joef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); Center of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, (Slovenia)

    2014-12-01

    The maximum-likelihood free-kick target, which calculates model error estimates from the work set and a randomly displaced model, proved superior in the accuracy and consistency of refinement of crystal structures compared with the maximum-likelihood cross-validation target, which calculates error estimates from the test set and the unperturbed model. The refinement of a molecular model is a computational procedure by which the atomic model is fitted to the diffraction data. The commonly used target in the refinement of macromolecular structures is the maximum-likelihood (ML) function, which relies on the assessment of model errors. The current ML functions rely on cross-validation. They utilize phase-error estimates that are calculated from a small fraction of diffraction data, called the test set, that are not used to fit the model. An approach has been developed that uses the work set to calculate the phase-error estimates in the ML refinement from simulating the model errors via the random displacement of atomic coordinates. It is called ML free-kick refinement as it uses the ML formulation of the target function and is based on the idea of freeing the model from the model bias imposed by the chemical energy restraints used in refinement. This approach for the calculation of error estimates is superior to the cross-validation approach: it reduces the phase error and increases the accuracy of molecular models, is more robust, provides clearer maps and may use a smaller portion of data for the test set for the calculation of R{sub free} or may leave it out completely.

  8. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  9. Room temperature deformation mechanisms of alumina particles observed from in situ micro-compression and atomistic simulations.

    SciTech Connect (OSTI)

    Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay D.; Mook, William M.; Bufford, Daniel Charles; Boyce, Brad L.; Hattar, Khalid Mikhiel; Kotula, Paul G.; Hall, Aaron Christopher

    2015-09-22

    Aerosol deposition (AD) is a solid-state deposition technology that has been developed to fabricate ceramic coatings nominally at room temperature. Sub-micron ceramic particles accelerated by pressurized gas impact, deform, and consolidate on substrates under vacuum. Ceramic particle consolidation in AD coatings is highly dependent on particle deformation and bonding; these behaviors are not well understood. In this work, atomistic simulations and in situ micro-compressions in the scanning electron microscope, and the transmission electron microscope (TEM) were utilized to investigate fundamental mechanisms responsible for plastic deformation/fracture of particles under applied compression. Results showed that highly defective micron-sized alumina particles, initially containing numerous dislocations or a grain boundary, exhibited no observable shape change before fracture/fragmentation. Simulations and experimental results indicated that particles containing a grain boundary only accommodate low strain energy per unit volume before crack nucleation and propagation. In contrast, nearly defect-free, sub-micron, single crystal alumina particles exhibited plastic deformation and fracture without fragmentation. Dislocation nucleation/motion, significant plastic deformation, and shape change were observed. Simulation and TEM in situ micro-compression results indicated that nearly defect-free particles accommodate high strain energy per unit volume associated with dislocation plasticity before fracture. As a result, the identified deformation mechanisms provide insight into feedstock design for AD.

  10. Room temperature deformation mechanisms of alumina particles observed from in situ micro-compression and atomistic simulations.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay D.; Mook, William M.; Bufford, Daniel Charles; Boyce, Brad L.; Hattar, Khalid Mikhiel; Kotula, Paul G.; Hall, Aaron Christopher

    2015-09-22

    Aerosol deposition (AD) is a solid-state deposition technology that has been developed to fabricate ceramic coatings nominally at room temperature. Sub-micron ceramic particles accelerated by pressurized gas impact, deform, and consolidate on substrates under vacuum. Ceramic particle consolidation in AD coatings is highly dependent on particle deformation and bonding; these behaviors are not well understood. In this work, atomistic simulations and in situ micro-compressions in the scanning electron microscope, and the transmission electron microscope (TEM) were utilized to investigate fundamental mechanisms responsible for plastic deformation/fracture of particles under applied compression. Results showed that highly defective micron-sized alumina particles, initially containingmore » numerous dislocations or a grain boundary, exhibited no observable shape change before fracture/fragmentation. Simulations and experimental results indicated that particles containing a grain boundary only accommodate low strain energy per unit volume before crack nucleation and propagation. In contrast, nearly defect-free, sub-micron, single crystal alumina particles exhibited plastic deformation and fracture without fragmentation. Dislocation nucleation/motion, significant plastic deformation, and shape change were observed. Simulation and TEM in situ micro-compression results indicated that nearly defect-free particles accommodate high strain energy per unit volume associated with dislocation plasticity before fracture. As a result, the identified deformation mechanisms provide insight into feedstock design for AD.« less

  11. Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

    SciTech Connect (OSTI)

    Firlar, Emre; ?nar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-05-21

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions. We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. As a result, our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.

  12. Interpolation Methods and the Accuracy of Lattice-Boltzmann Mesh Refinement

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Interpolation Methods and the Accuracy of Lattice-Boltzmann Mesh Refinement Citation Details In-Document Search Title: Interpolation Methods and the Accuracy of Lattice-Boltzmann Mesh Refinement Authors: Guzik, S M ; Weisgraber, T H ; Colella, P ; Alder, B J Publication Date: 2012-10-18 OSTI Identifier: 1226215 Report Number(s): LLNL-JRNL-594615 DOE Contract Number: AC52-07NA27344 Resource Type: Journal Article Resource Relation: Journal

  13. New Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants New Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants January 31, 2012 - 2:09pm Addthis The Electric Power Research Institute (EPRI), the U.S. Department of Energy (DOE), and the U.S. Nuclear Regulatory Commission (NRC) released a new seismic study today that will help U.S. nuclear facilities in the central and eastern United States reassess seismic hazards. The Central and Eastern United

  14. Implications of Increasing Light Tight Oil Production for U.S. Refining

    U.S. Energy Information Administration (EIA) Indexed Site

    Implications of Increasing Light Tight Oil Production for U.S. Refining May 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Implications of Increasing Light Oil Production on the U.S. Refining System i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are

  15. Austenite grain refinement during load-biased thermal cycling of a

    Office of Scientific and Technical Information (OSTI)

    Ni49.9Ti50.1 shape memory alloy (Journal Article) | DOE PAGES Austenite grain refinement during load-biased thermal cycling of a Ni49.9Ti50.1 shape memory alloy This content will become publicly available on June 30, 2017 « Prev Next » Title: Austenite grain refinement during load-biased thermal cycling of a Ni49.9Ti50.1 shape memory alloy Authors: Bowers, M. L. ; Gao, Y. ; Yang, L. ; Gaydosh, D. J. ; De Graef, M. ; Noebe, R. D. ; Wang, Y. ; Mills, M. J. Publication Date: 2015-06-01 OSTI

  16. ,"U.S. Aviation Gasoline Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Aviation Gasoline Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Aviation Gasoline Refiner Sales Volumes",2,"Monthly","2/2016","1/15/1983" ,"Release Date:","5/2/2016" ,"Next Release Date:","6/1/2016" ,"Excel File

  17. ,"U.S. Residual Fuel Oil Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Residual Fuel Oil Refiner Sales Volumes",2,"Monthly","2/2016","1/15/1983" ,"Release Date:","5/2/2016" ,"Next Release Date:","6/1/2016" ,"Excel File

  18. ,"Aviation Gasoline Sales to End Users Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Aviation Gasoline Sales to End Users Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Aviation Gasoline Sales to End Users Refiner Sales Volumes",60,"Monthly","2/2016","1/15/1983" ,"Release Date:","5/2/2016" ,"Next Release

  19. Initial chemical and biological characterization of hydrotreated solvent refined coal (SRC-II) liquids: a status report

    SciTech Connect (OSTI)

    Weimer, W.C.; Wilson, B.W.; Pelroy, R.A.; Craun, J.C.

    1980-07-01

    This report presents the results of both chemical and biomedical research performed on a solvent refined coal (SRC-II) research material (distillate blend) which was produced by the pilot plant facility at Fort Lewis, Washington. Samples of this distillate blend were subjected to research-scale hydrotreatment by Universal Oil Products, Inc., prior to chemical and biological analysis at PNL. The samples are considered to be, in general, generically representative of raw or hydrotreated materials which might be produced by demonstration or commercial-scale facilities. The above described feedstock and hydrotreated materials were analyzed for chemical composition both prior to and after chemical fractionation. The fractionation procedure used was an acid-base-neutral solvent extraction. The fractions produced, as well as the unfractionated materials, were subjected to microbial mutagenesis testing (Ames assay) and to further chemical analysis. The principal components of the unmodified distillate blend are two and three ringed aromatic and heteroatomic species together with high concentrations of phenolic and polynuclear aromatic components relative to typical levels found in petroleum crudes. The Ames assay mutagenic response for the unfractionated material, as well as the fractions produced by the solvent separation, was reduced considerably in the hydrotreated materials compared to that of the feedstock. Total mutagenic response for the hydrotreated products was approximately 1% of that in the untreated feedstock. The concentrations of two important genetically active compound classes, the polynuclear aromatic hydrocarbons and the primary aromatic amines, were considerably reduced in both of the hydrotreated products compared to the feedstock.

  20. Studies on design of a process for organo-refining of coal to obtain super clean coal

    SciTech Connect (OSTI)

    Sharma, C.S.; Sharma, D.K.

    1999-08-01

    Organo-refining of coal results in refining the coal to obtain super clean coal and residual coal. Super clean coal may be used to obtain value added chemicals, products, and cleaner fuels from coal. In the present work, studies on the design of a semicontinuous process for organo-refining of one ton of coal have been made. The results are reported. This is only a cursory attempt for the design, and further studies may be required for designing this process for use in the development of a scaled-up process of organo-refining of coal.

  1. Table 3b. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual" "Projected Price in Nominal Dollars" " (nominal dollars per barrel)" ,1993,1994,1995,1996,1997,1998,1999,2000,2001,2002,2003,2004,2005,2006,2007,2008,2009,2010,2011,2012,2013 "AEO

  2. Tools for macromolecular model building and refinement into electron cryo-microscopy reconstructions

    SciTech Connect (OSTI)

    Brown, Alan; Long, Fei; Nicholls, Robert A.; Toots, Jaan; Emsley, Paul; Murshudov, Garib, E-mail: garib@mrc-lmb.cam.ac.uk [MRC Laboratory of Molecular Biology, Francis Crick Avenue, Cambridge CB2 0QH (United Kingdom)

    2015-01-01

    A description is given of new tools to facilitate model building and refinement into electron cryo-microscopy reconstructions. The recent rapid development of single-particle electron cryo-microscopy (cryo-EM) now allows structures to be solved by this method at resolutions close to 3 . Here, a number of tools to facilitate the interpretation of EM reconstructions with stereochemically reasonable all-atom models are described. The BALBES database has been repurposed as a tool for identifying protein folds from density maps. Modifications to Coot, including new Jiggle Fit and morphing tools and improved handling of nucleic acids, enhance its functionality for interpreting EM maps. REFMAC has been modified for optimal fitting of atomic models into EM maps. As external structural information can enhance the reliability of the derived atomic models, stabilize refinement and reduce overfitting, ProSMART has been extended to generate interatomic distance restraints from nucleic acid reference structures, and a new tool, LIBG, has been developed to generate nucleic acid base-pair and parallel-plane restraints. Furthermore, restraint generation has been integrated with visualization and editing in Coot, and these restraints have been applied to both real-space refinement in Coot and reciprocal-space refinement in REFMAC.

  3. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.6 92.3 78.2 101.8 83.6 87.5 74.7 See footnotes at end of table. A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District, and State, 1984-Present 452 Energy Information...

  4. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    61.5 67.3 89.8 89.5 82.2 69.4 71.1 74.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  5. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    35.2 213.6 9.5 9.8 12.9 16.6 NA 29.5 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  6. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 5.6 0.5 0.5 0.5 0.4 - 0.9 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  7. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.2 68.5 90.1 89.6 82.4 70.9 NA 75.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  8. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    33.9 215.8 9.7 10.0 12.1 16.3 0.0 28.4 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  9. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - 4.9 0.4 0.4 0.3 0.4 - 0.7 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  10. Environmental Regulations and Changes in Petroleum Refining Operations (Released in the STEO June 1998)

    Reports and Publications (EIA)

    1998-01-01

    Changes in domestic refining operations are identified and related to the summer Reid vapor pressure (RVP) restrictions and oxygenate blending requirements. This analysis uses published Energy Information Administration survey data and linear regression equations from the Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the Short-Term Energy Outlook.

  11. Towards solution and refinement of organic crystal structures by fitting to the atomic pair distribution function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prill, Dragica; Juhas, Pavol; Billinge, Simon J. L.; Schmidt, Martin U.

    2016-01-01

    In this study, a method towards the solution and refinement of organic crystal structures by fitting to the atomic pair distribution function (PDF) is developed. Approximate lattice parameters and molecular geometry must be given as input. The molecule is generally treated as a rigid body. The positions and orientations of the molecules inside the unit cell are optimized starting from random values. The PDF is obtained from carefully measured X-ray powder diffraction data. The method resembles `real-space' methods for structure solution from powder data, but works with PDF data instead of the diffraction pattern itself. As such it may bemore » used in situations where the organic compounds are not long-range-ordered, are poorly crystalline, or nanocrystalline. The procedure was applied to solve and refine the crystal structures of quinacridone (β phase), naphthalene and allopurinol. In the case of allopurinol it was even possible to successfully solve and refine the structure in P1 with four independent molecules. As an example of a flexible molecule, the crystal structure of paracetamol was refined using restraints for bond lengths, bond angles and selected torsion angles. In all cases, the resulting structures are in excellent agreement with structures from single-crystal data.« less

  12. EIS-0069: Solvent Refined Coal-II Demonstration Project, Fort Martin, Monongalia County, West Virginia

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to assess the potential environmental, economic and social impacts associated with the construction and short-term operation of a 6,000-tons-per-stream-day-capacity facility that will demonstrate the technical operability, economic viability, and environmental acceptability of the solvent refined coal process at Fort Martin, West Virginia.

  13. Towards solution and refinement of organic crystal structures by fitting to the atomic pair distribution function

    SciTech Connect (OSTI)

    Prill, Dragica; Juhas, Pavol; Billinge, Simon J. L.; Schmidt, Martin U.

    2016-01-01

    In this study, a method towards the solution and refinement of organic crystal structures by fitting to the atomic pair distribution function (PDF) is developed. Approximate lattice parameters and molecular geometry must be given as input. The molecule is generally treated as a rigid body. The positions and orientations of the molecules inside the unit cell are optimized starting from random values. The PDF is obtained from carefully measured X-ray powder diffraction data. The method resembles `real-space' methods for structure solution from powder data, but works with PDF data instead of the diffraction pattern itself. As such it may be used in situations where the organic compounds are not long-range-ordered, are poorly crystalline, or nanocrystalline. The procedure was applied to solve and refine the crystal structures of quinacridone (β phase), naphthalene and allopurinol. In the case of allopurinol it was even possible to successfully solve and refine the structure in P1 with four independent molecules. As an example of a flexible molecule, the crystal structure of paracetamol was refined using restraints for bond lengths, bond angles and selected torsion angles. In all cases, the resulting structures are in excellent agreement with structures from single-crystal data.

  14. Obtaining aluminas from the thermal decomposition of their different precursors: An {sup 27}Al MAS NMR and X-ray powder diffraction studies

    SciTech Connect (OSTI)

    Chagas, L.H.; De Carvalho, G.S.G.; San Gil, R.A.S.; Chiaro, S.S.X.; Leito, A.A.; Diniz, R.

    2014-01-01

    Graphical abstract: - Highlights: We synthesized three precursors of alumina from different methods. The calcination of the precursors generated several alumina polymorphs. XRD and NMR were used for structural investigation of the polymorphs. The synthesis route determines the structural and textural properties of the solids. - Abstract: A commercial sample of Boehmite was used as precursor of alumina polymorphs. For comparison, three other precursors were synthesized from different methods. Particularly, the use of excess of urea promoted a very crystalline form of basic aluminum carbonate. The characteristics of the four precursors were investigated by thermal, vibrational and X-ray powder diffraction (XRD) analysis. Additionally, the nuclear magnetic resonance, with magic angle spinning ({sup 27}Al MAS NMR), was used to verify the coordination of aluminum cations. Each precursor was calcined at various temperatures generating alumina polymorphs, which were structurally analyzed by XRD and {sup 27}Al MAS NMR. Due to interest in catalysis supports, special attention was given to the ?-Al{sub 2}O{sub 3} phase, which in addition to structural investigation was subjected to textural analysis. The results showed that, from different synthesis procedures and common route of calcination, one can obtain materials with the same composition but with different structural and textural properties, which in turn can significantly influence the performance of a supported catalyst.

  15. Formation of calcium aluminates in the lime sinter process. [Extraction of alumina from fly ash

    SciTech Connect (OSTI)

    Chou, K.S.

    1980-03-01

    A study of the formation of several calcium aluminates from pure components in the lime sinter process was undertaken to determine the kinetics of formation and subsequent leaching using a dilute sodium carbonate solution. The composition CaO 61.98%, SiO/sub 2/ 26.67%, and Al/sub 2/O/sub 3/ 11.53% was used. Isothermal sintering runs of 0.2 to 10.0 h were carried out at 1200, 1250, 1300, and 1350/sup 0/C. When the sintering temperature was below the eutectic temperature (1335/sup 0/C), the ternary mixture behaved like two binary systems, i.e. CaO-Al/sub 2/O/sub 3/ and CaO-SiO/sub 2/. Only one compound, 3CaO.SiO/sub 2/, was formed between CaO and SiO/sub 2/. With lower sintering temperature and shorter sintering time, the ..beta..-phase was dominant. However, when both temperature and time increased, more and more of the ..beta..-C/sub 2/S was transformed into the ..gamma..-phase. Several different aluminates were formed during the sintering of CaO and Al/sub 2/O/sub 3/. The compounds CaO.Al/sub 2/O/sub 3/ and 3CaO.Al/sub 2/O/sub 3/ were observed at all tested sintering temperatures, while the 5CaO.3Al/sub 2/O/sub 3/ phase was found only at 1200/sup 0/C and 12CaO.7Al/sub 2/O/sub 3/ at 1250/sup 0/C or higher. The first compound formed between CaO and Al/sub 2/O/sub 3/ was probably 12CaO.7Al/sub 2/O/sub 3/, but the amount did not increase immediately with time. The first dominant compound between CaO and Al/sub 2/O/sub 3/ was CaO.3Al/sub 2/O/sub 3/. When the calcium ion diffused through the product layer of CaO.Al/sub 2/O/sub 3/, 3CaO.Al/sub 2/O/sub 3/ was formed. If unreacted Al/sub 2/O/sub 3/ were present after the formation of CaO.Al/sub 2/O/sub 3/, CaO.2Al/sub 2/O/sub 3/ would form. Subsequent leaching of the sinters showed that the extractable alumina in the products increased with both sintering temperature and time, reaching a max of about 90%. These extraction data corresponded very well to the quantities of aluminates in the sinters. 59 figures, 13 tables.

  16. Exploiting structure similarity in refinement: automated NCS and target-structure restraints in BUSTER

    SciTech Connect (OSTI)

    Smart, Oliver S. Womack, Thomas O.; Flensburg, Claus; Keller, Peter; Paciorek, Włodek; Sharff, Andrew; Vonrhein, Clemens; Bricogne, Gérard

    2012-04-01

    Local structural similarity restraints (LSSR) provide a novel method for exploiting NCS or structural similarity to an external target structure. Two examples are given where BUSTER re-refinement of PDB entries with LSSR produces marked improvements, enabling further structural features to be modelled. Maximum-likelihood X-ray macromolecular structure refinement in BUSTER has been extended with restraints facilitating the exploitation of structural similarity. The similarity can be between two or more chains within the structure being refined, thus favouring NCS, or to a distinct ‘target’ structure that remains fixed during refinement. The local structural similarity restraints (LSSR) approach considers all distances less than 5.5 Å between pairs of atoms in the chain to be restrained. For each, the difference from the distance between the corresponding atoms in the related chain is found. LSSR applies a restraint penalty on each difference. A functional form that reaches a plateau for large differences is used to avoid the restraints distorting parts of the structure that are not similar. Because LSSR are local, there is no need to separate out domains. Some restraint pruning is still necessary, but this has been automated. LSSR have been available to academic users of BUSTER since 2009 with the easy-to-use -autoncs and @@target target.pdb options. The use of LSSR is illustrated in the re-refinement of PDB entries http://scripts.iucr.org/cgi-bin/cr.cgi?rm, where -target enables the correct ligand-binding structure to be found, and http://scripts.iucr.org/cgi-bin/cr.cgi?rm, where -autoncs contributes to the location of an additional copy of the cyclic peptide ligand.

  17. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, John P.; Granite, Evan J.; Rupp, Erik C.; Stanko, Dennis C.; Howard, Bret; Pennline, Henry W.

    2011-05-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur, and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide, but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur, resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  18. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Rupp, E.C.; Stanko, D.C.; Howard, B.; Pennline, H.W.

    2011-01-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur. and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide. but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur. resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  19. Development of value-added products from alumina industry mineral wastes using low-temperature-setting phosphate ceramics

    SciTech Connect (OSTI)

    Wagh, A.S.; Jeong, Seung-Young; Singh, D.

    1996-01-01

    A room-temperature process for stabilizing mineral waste streams has been developed, based on acid-base reaction between MgO and H3PO4 or acid phosphate solution. The resulting waste form sets into a hard ceramic in a few hours. In this way, various alumina industry wastes, such as red mud and treated potliner waste, can be solidified into ceramics which can be used as structural materials in waste management and construction industry. Red mud ceramics made by this process were low-porosity materials ({approx}2 vol%) with a compression strength equal to portland cement concrete (4944 psi). Bonding mechanism appears to be result of reactions of boehmite, goethite, and bayerite with the acid solution, and also encapsulation of red mud particles in Mg phosphate matrix. Possible applications include liners for ponds and thickned tailings disposal, dikes for waste ponds, and grouts. Compatability problems arising at the interface of the liner and the waste are avoided.

  20. The effects of air pollution regulations on the US refining industry. Task 3

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    Numerous air pollution regulations affecting petroleum refineries recently have been promulgated, have been proposed, or are under consideration at the federal, state, and local level. As shown in Figure ES-1, all of these environmental regulations are intended to take effect over the relatively short time period from 1989 through 1995. In the aggregate these regulatory activities have significant implications for the US refining industry and the Nation, including: Major investment requirements; changes in industry profitability; potential closure of some refineries; and potential changes in crude oil or product import dependence. At issue is whether the cumulative effect of these regulations could so adversely affect the US refining industry that US national security would be affected. In addition to the regulations outlined in Figure ES-1, President Bush recently presented a major new plan to improve the nation`s air quality. The aspects of the President`s plan that could strongly affect US refineries are summarized below.

  1. NREL Refines Method to Convert Lignin to Nylon Precursor - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL NREL Refines Method to Convert Lignin to Nylon Precursor Recent Findings Published in Energy & Environmental Science February 26, 2015 A new study from the Energy Department's National Renewable Energy Laboratory (NREL) demonstrates the conversion of lignin-derived compounds to adipic acid, an important industrial dicarboxylic acid produced for its use as a precursor to nylon, plasticizers, lubricants, polyesters, and other popular products and chemicals. The demonstration is an

  2. Implications of Increasing Light Tight Oil Production for U.S. Refining -

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Implications of Increasing Light Tight Oil Production for U.S. Refining Release date: May 5, 2015 Revised: May 12, 2015 (revision) 1. Background and Analytical Framework Background Recent and projected increases in U.S. crude production have sparked discussion about the implications of current limitations on crude oil exports for prices, including both world and domestic crude oil and petroleum product prices, and for the level of domestic crude production

  3. Application of a catalyst deactivation model for hydrotreating solvent refined coal feedstocks

    SciTech Connect (OSTI)

    Nalitham, R.V.

    1983-10-01

    A simple kinetic model, including a first-order catalyst deactivation rate, is applied to upgrading of coal-derived feedstocks prepared from two solvent refined coal fractions. A catalyst deactivation mechanism is proposed which involves the adsorption and surface reaction of coke precursors on catalytic active sites. The effect of feedstock composition, temperature and pressure on kinetic parameters, and in particular the catalyst deactivation rate, is determined.

  4. Fewer Steps to Higher Octane Gasoline in Petroleum Refining | U.S. DOE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Science (SC) Fewer Steps to Higher Octane Gasoline in Petroleum Refining Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 07.01.13 Fewer

  5. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for stepmore » structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.« less

  6. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    SciTech Connect (OSTI)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for step structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.

  7. Steam system opportunity assessment for the pulp and paper, chemical manufacturing, and petroleum refining industries: Main report

    SciTech Connect (OSTI)

    None, None

    2002-10-01

    This report assesses steam generation and use in the pulp and paper, chemical, and petroleum refining industries, and estimates the potential for energy savings from implementation of steam system performance and efficiency improvements.

  8. Fact #676: May 23, 2011 U.S. Refiners Produce about 19 Gallons of Gasoline from a Barrel of Oil

    Broader source: Energy.gov [DOE]

    A standard U.S. barrel contains 42 gallons of crude oil which yields about 44 gallons of petroleum products. The additional 2 gallons of petroleum products come from refiner gains which result in...

  9. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations

    SciTech Connect (OSTI)

    Martini, Matus N.; Gustafson, Jr., William I.; O'Brien, Travis A.; Ma, Po -Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configuration using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. Furthermore, the relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier studies that only refined portion of the tropics.

  10. Evaluation of Tropical Channel Refinement using MPAS-A Aquaplanet Simulations

    SciTech Connect (OSTI)

    Martini, Matus; Gustafson, William I.; O'Brien, Travis A.; Ma, Po-Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configuration using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. The relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier studies that only refined portion of the tropics.

  11. Direct Reduction of Waste through Refining of DOE Metal Assets - 13632

    SciTech Connect (OSTI)

    Hargett, Michael C.; Terekhov, Dimitri; Khozan, Kamran M.

    2013-07-01

    CVMR{sup R} presents a technology for refining nickel from the enrichment barrier materials of the DOE that is proven through 100 years of use by the metals industry. CVMR{sup R} applies modern controls, instrumentation for process and monitoring of the system, and innovative production methods to produce a wide spectrum of products that generate new technology applications and improvements to our society and economy. CVMR{sup R} will receive barrier materials as a secure operation and size reduce the metal to a shred that is fed to a carbonylation reactor where nickel is reacted with carbon monoxide and generate nickel carbonyl. The carbonyl will be filtered and decomposed with heat to form a variety of products that include high value nano powders, coated substrates, net shapes and pure nickel. The residue from the reactor will retain radionuclides from enrichment activities. The carbon monoxide will only react and extract nickel under the operating conditions to leave volumetric contamination in the unreacted residue. A demonstration plant was designed and built by CVMR{sup R} and operated by BWXT, to demonstrate the systems capabilities to DOE in 2006. A pilot plant operation precedes the detailed design of the nickel refinery and provides essential data for design, safe work practices, waste characterizations and system kinetics and confirms the project feasibility. CVMR{sup R} produces nickel products that are cleaner than the nickel in U.S. commerce and used by industry today. The CVMR{sup R} process and systems for nickel refining is well suited for DOE materials and will provide value through environmental stewardship, recovery of high value assets, and support of the DOE environmental remediation programs as the refined nickel generates additional long term benefits to local communities. (authors)

  12. Manufacturing Energy and Carbon Footprint - Sector: Petroleum Refining (NAICS 324110), January 2014 (MECS 2010)

    Energy Savers [EERE]

    Petroleum Refining (NAICS 324110) Process Energy Electricity and Steam Generation Losses Process Losses 234 Nonprocess Losses 3,542 689 Steam Distribution Losses 150 22 Nonprocess Energy 2,873 Electricity Generation Steam Generation 3,542 150 Prepared for the U.S. Department of Energy, Advanced Manufacturing Office by Energetics Incorporated 59 2,734 153 Generation and Transmission Losses Generation and Transmission Losses 58 308 2,793 2,285 891 3,176 461 208 657 13.2 26.7 40.0 139.2 176.3 3.2

  13. Table 3a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual" "Projected Price in Constant Dollars" " (constant dollars per barrel in ""dollar year"" specific to each AEO)" ,"AEO $ Year",1993,1994,1995,1996,1997,1998,1999,2000,2001,2002,2003,2004,2005,2006,2007,2008,2009,2010,2011,2012,2013 "AEO 1994",1992,16.69,16.42999,16.9899,17.66,18.28,19.0599,19.89,20.72,21.65,22.61,23.51,24.29,24.9,25.6,26.3,27,27.64,28.16

  14. Quantitative phase analysis of Mg:ZrO{sub 2} nanoparticles by Rietveld refinement method

    SciTech Connect (OSTI)

    Balaji, V. Senthilkumaran, S. Thangadurai, P.

    2014-04-24

    To quantify the structural phases of nanocrystalline ZrO{sub 2} doped with Mg ions of varying concentrations (3, 5, 10, 15 and 20%) and annealed at different temperatures. Magnesia doped zirconia was prepared by chemical co-precipitation method and annealed up to 1000°C. The monoclinic and tetragonal phases present in Mg:ZrO{sub 2} were quantified using Rietveld refinement analysis of the X-ray diffraction data and compared with the Direct method based on peak intensity calculations. Tetragonal phase was dominant in the 600°C annealed Mg:ZrO{sub 2} for all Mg concentrations.

  15. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-03-15

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  16. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

    2015-04-07

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  17. ,"U.S. Refiner Acquisition Cost of Crude Oil"

    U.S. Energy Information Administration (EIA) Indexed Site

    Acquisition Cost of Crude Oil" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Refiner Acquisition Cost of Crude Oil",3,"Monthly","3/2016","1/15/1974" ,"Release Date:","5/2/2016" ,"Next Release Date:","6/1/2016" ,"Excel File

  18. Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

    SciTech Connect (OSTI)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  19. European refiners must seek creative processes to justify heavy-ends projects

    SciTech Connect (OSTI)

    Hunt, P.

    1996-12-09

    There are strong reasons for wanting to upgrade the bottom of the crude oil barrel. But European refiners will not find it easy to get approval and funding for major capital investment projects. In most cases, investment justification will have to be creative and may need to rely on factors traditionally considered to be outside the conventional refinery fence. Examples of such creative upgrading schemes are those employed in four gasification projects planned for refineries in Italy. It is clear that the major obstacles to heavy residue processing are not technical, but economic. A review of these obstacles will set the stage for European investment in bottom-of-the-barrel processing.

  20. Application of non-porous alumina based ceramics as structural material for devices handling tritium at elevated temperatures

    SciTech Connect (OSTI)

    Yukhimchuk, A.A.; Maksimkin, I.P.; Baluev, V.V.; Boitsov, I.E.; Vertey, A.V.; Malkov, I.L.; Musyaev, R.K.; Popov, V.V.; Sitdikov, D.T.; Khapov, A.S.; Grishechkin, S.K.; Kiselev, V.G.

    2015-03-15

    The article presents results of comparative tests for the determination of deuterium fluxes permeating through walls of austenitic stainless steel AISI304 (DIN 1.4301) chamber and Al{sub 2}O{sub 3} based ceramic F99.7 chamber. Both chambers represent a piece of φ(ext)=26*φ(int)=22*117 mm{sup 3} tube with spherical bottom ending. It is shown that at 773 K and deuterium pressure of 1200 mbar the permeated deuterium flux through the stainless steel chamber constituted 8*10{sup -5} cm{sup 3}/s, while the flux through ceramic one it did not exceed the sensitivity of the measurement method threshold, namely about 1.5*10{sup -7} cm{sup 3}/s. The ceramic chamber turned out to survive more than 10{sup 3} cycles of heating up to 773 K with no damages. It did not lose its tightness up to 10 bar of internal deuterium pressure. The authors also present test results of a prototype bed for reversible tritium storage. The bed's case was made of alumina based ceramic F99.7, titanium being used as tritide making metal and high frequency induction used for heating the tritide metal. (authors)

  1. Manufacture of Alumina-Forming Austenitic Stainless Steel Alloys by Conventional Casting and Hot-Working Methods

    SciTech Connect (OSTI)

    Brady, M.P.; Yamamoto, Y.; Magee, J.H. (Carpenter Technol. Corp.)

    2009-03-23

    Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 30lb heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(1-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions.

  2. CRADA NFE-08-01456 Evaluation of Alumina-Forming Austenitic Stainless Steel Alloys in Industrial Gas Turbines

    SciTech Connect (OSTI)

    Brady, Michael P; Pint, Bruce A; Unocic, Kinga A; Yamamoto, Yukinori; Kumar, Deepak; Lipschutz, Mark D.

    2011-09-01

    Oak Ridge National Laboratory (ORNL) and Solar Turbines Incorporated (Solar) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation Program to explore the feasibility for use of developmental ORNL alumina-forming austenitic (AFA) stainless steels as a material of construction for industrial gas turbine recuperator components. ORNL manufactured lab scale foil of three different AFA alloy compositions and delivered them to Solar for creep properties evaluation. One AFA composition was selected for a commercial trial foil batch. Both lab scale and the commercial trial scale foils were evaluated for oxidation and creep behavior. The AFA foil exhibited a promising combination of properties and is of interest for future scale up activities for turbine recuperators. Some issues were identified in the processing parameters used for the first trial commercial batch. This understanding will be used to guide process optimization of future AFA foil material production.

  3. The effects of cold work on the microstructure and mechanical properties of intermetallic strengthened alumina-forming austenitic stainless steels

    SciTech Connect (OSTI)

    Hu, Bin; Baker, Ian; Miller, Michael K.; Yao, Lan; Chen, Si; Cai, Z.; Trotter, G.

    2015-06-12

    In order to achieve energy conversion efficiencies of >50 pct for steam turbines/boilers in power generation systems, materials are required that are both strong and corrosion-resistant at >973 K (700 °C), and economically viable. Austenitic steels strengthened with Laves phase, NiAl and Ni3Al precipitates, and alloyed with aluminum to improve oxidation resistance, are potential candidate materials for these applications. The microstructure and microchemistry of recently developed alumina-forming austenitic stainless steels have been characterized by scanning electron microscopy, transmission electron microscopy, and synchrotron X-ray diffraction. Different thermo-mechanical treatments were performed on these steels to improve their mechanical performance. These reduced the grain size significantly to the nanoscale (~100 nm) and the room temperature yield strength to above 1000 MPa. Lastly, a solutionizing anneal at 1473 K (1200 °C) was found to be effective for uniformly redistributing the Laves phase precipitates that form upon casting.

  4. The effects of cold work on the microstructure and mechanical properties of intermetallic strengthened alumina-forming austenitic stainless steels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Bin; Baker, Ian; Miller, Michael K.; Yao, Lan; Chen, Si; Cai, Z.; Trotter, G.

    2015-06-12

    In order to achieve energy conversion efficiencies of >50 pct for steam turbines/boilers in power generation systems, materials are required that are both strong and corrosion-resistant at >973 K (700 °C), and economically viable. Austenitic steels strengthened with Laves phase, NiAl and Ni3Al precipitates, and alloyed with aluminum to improve oxidation resistance, are potential candidate materials for these applications. The microstructure and microchemistry of recently developed alumina-forming austenitic stainless steels have been characterized by scanning electron microscopy, transmission electron microscopy, and synchrotron X-ray diffraction. Different thermo-mechanical treatments were performed on these steels to improve their mechanical performance. These reduced themore » grain size significantly to the nanoscale (~100 nm) and the room temperature yield strength to above 1000 MPa. Lastly, a solutionizing anneal at 1473 K (1200 °C) was found to be effective for uniformly redistributing the Laves phase precipitates that form upon casting.« less

  5. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of β"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  6. Conformation-dependent backbone geometry restraints set a new standard for protein crystallographic refinement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moriarty, Nigel W.; Tronrud, Dale E.; Adams, Paul D.; Karplus, P. Andrew

    2014-06-17

    Ideal values of bond angles and lengths used as external restraints are crucial for the successful refinement of protein crystal structures at all but the highest of resolutions. The restraints in common usage today have been designed based on the assumption that each type of bond or angle has a single ideal value independent of context. However, recent work has shown that the ideal values are, in fact, sensitive to local conformation, and as a first step toward using such information to build more accurate models, ultra-high resolution protein crystal structures have been used to derive a conformation-dependent library (CDL)more » of restraints for the protein backbone (Berkholz et al. 2009. Structure. 17, 1316). Here, we report the introduction of this CDL into the Phenix package and the results of test refinements of thousands of structures across a wide range of resolutions. These tests show that use of the conformation dependent library yields models that have substantially better agreement with ideal main-chain bond angles and lengths and, on average, a slightly enhanced fit to the X-ray data. No disadvantages of using the backbone CDL are apparent. In Phenix usage of the CDL can be selected by simply specifying the cdl=True option. This successful implementation paves the way for further aspects of the context-dependence of ideal geometry to be characterized and applied to improve experimental and predictive modelling accuracy.« less

  7. Conformation-dependent backbone geometry restraints set a new standard for protein crystallographic refinement

    SciTech Connect (OSTI)

    Moriarty, Nigel W.; Tronrud, Dale E.; Adams, Paul D.; Karplus, P. Andrew

    2014-06-17

    Ideal values of bond angles and lengths used as external restraints are crucial for the successful refinement of protein crystal structures at all but the highest of resolutions. The restraints in common usage today have been designed based on the assumption that each type of bond or angle has a single ideal value independent of context. However, recent work has shown that the ideal values are, in fact, sensitive to local conformation, and as a first step toward using such information to build more accurate models, ultra-high resolution protein crystal structures have been used to derive a conformation-dependent library (CDL) of restraints for the protein backbone (Berkholz et al. 2009. Structure. 17, 1316). Here, we report the introduction of this CDL into the Phenix package and the results of test refinements of thousands of structures across a wide range of resolutions. These tests show that use of the conformation dependent library yields models that have substantially better agreement with ideal main-chain bond angles and lengths and, on average, a slightly enhanced fit to the X-ray data. No disadvantages of using the backbone CDL are apparent. In Phenix usage of the CDL can be selected by simply specifying the cdl=True option. This successful implementation paves the way for further aspects of the context-dependence of ideal geometry to be characterized and applied to improve experimental and predictive modelling accuracy.

  8. US imports. Part II. Refined product market shares, then and now

    SciTech Connect (OSTI)

    Not Available

    1987-07-08

    Unlike imports of crude oil to the US, which were up 45.7% between 1977 and 1986, imports of petroleum products have fallen by about 8.6% during the same period. The crude oil price crash of 1986 deepened US dependency on imports of crude, from 21.4% in 1977 to 25.4% in 1986, but reduced the dependency in the case of total refined products from 11.32% in 1977 to 11.13% in 1986. Comparing the first four months of 1987 with 1986, US dependency on imported petroleum products is down 2.73 percentage points; import dependency on OPEC petroleum products is down 4.60 percentage points; dependency on Arab OPEC countries product imports is down 1.88 percentage points; and for Eastern Hemisphere exporters, that dependency has fallen 2.17 percentage points. This issue also contains: (1) ED refining netback data from the US Gulf and West coasts, Rotterdam, and Singapore for early July 1987; and (2) ED fuel price/tax series for countries of the Western Hemisphere, July 1987 edition. 4 figures, 5 tables.

  9. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  10. Primary & Secondary Navigation Menus (help/navigation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power Services Site Navigation Aids Primary & Secondary Navigation Menus The primary navigation menus are located in the black horizontal navigation bars at the top and bottom of...

  11. Primary Energy Ventures | Open Energy Information

    Open Energy Info (EERE)

    Energy Ventures Jump to: navigation, search Name: Primary Energy Ventures Place: Oak Brook, Illinois Zip: 60523 Product: Primary Energy Ventures is a privately held developer,...

  12. Lead-free primary explosives

    DOE Patents [OSTI]

    Huynh, My Hang V.

    2010-06-22

    Lead-free primary explosives of the formula (cat).sub.Y[M.sup.II(T).sub.X(H.sub.2O).sub.6-X].sub.Z, where T is 5-nitrotetrazolate, and syntheses thereof are described. Substantially stoichiometric equivalents of the reactants lead to high yields of pure compositions thereby avoiding dangerous purification steps.

  13. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martini, Matus N.; Gustafson, Jr., William I.; O'Brien, Travis A.; Ma, Po -Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configurationmore » using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. Furthermore, the relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier studies that only refined portion of the tropics.« less

  14. Table 3a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual Projected Price in Constant Dollars (constant dollars per barrel in "dollar year" specific to each AEO) AEO $ Year 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 AEO 1994 1992 16.69 16.43 16.99 17.66 18.28 19.06 19.89 20.72 21.65 22.61 23.51 24.29 24.90 25.60 26.30 27.00 27.64 28.16 AEO 1995 1993 14.90 16.41 16.90 17.45 18.00 18.53 19.13 19.65 20.16 20.63

  15. Table 3b. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    b. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual Projected Price in Nominal Dollars (nominal dollars per barrel) 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 AEO 1994 17.06 17.21 18.24 19.43 20.64 22.12 23.76 25.52 27.51 29.67 31.86 34.00 36.05 38.36 40.78 43.29 45.88 48.37 AEO 1995 15.24 17.27 18.23 19.26 20.39 21.59 22.97 24.33 25.79 27.27 28.82 30.38 32.14 33.89 35.85 37.97 40.28 AEO 1996 17.16 17.74 18.59

  16. Early F-type stars - refined classification, confrontation with Stromgren photometry, and the effects of rotation

    SciTech Connect (OSTI)

    Gray, R.O.; Garrison, R.F.

    1989-02-01

    The classification for early F-type stars in the MK spectral classification system presented by Gray and Garrison (1987) is refined. The effect of rotation on spectral classification and ubvy-beta photometry of early F-type stars is examined. It is found that the classical luminosity criterion, the 4417 A/4481 A ratio gives inconsistent results. It is shown that most of the stars in the Delta Delphini class of metallic-line stars are either normal or are indistinguishable from proto-Am stars. It is suggested that the designation Delta Delphini should be dropped. The classifications are compared with Stromgren photometry. The effects of rotation on the delta-c sub 1 index in the early-F field dwarfs is demonstrated. 55 references.

  17. On the Computation of Integral Curves in Adaptive Mesh Refinement Vector Fields

    SciTech Connect (OSTI)

    Deines, Eduard; Weber, Gunther H.; Garth, Christoph; Van Straalen, Brian; Borovikov, Sergey; Martin, Daniel F.; Joy, Kenneth I.

    2011-06-27

    Integral curves, such as streamlines, streaklines, pathlines, and timelines, are an essential tool in the analysis of vector field structures, offering straightforward and intuitive interpretation of visualization results. While such curves have a long-standing tradition in vector field visualization, their application to Adaptive Mesh Refinement (AMR) simulation results poses unique problems. AMR is a highly effective discretization method for a variety of physical simulation problems and has recently been applied to the study of vector fields in flow and magnetohydrodynamic applications. The cell-centered nature of AMR data and discontinuities in the vector field representation arising from AMR level boundaries complicate the application of numerical integration methods to compute integral curves. In this paper, we propose a novel approach to alleviate these problems and show its application to streamline visualization in an AMR model of the magnetic field of the solar system as well as to a simulation of two incompressible viscous vortex rings merging.

  18. Effects of gas injection condition on mixing efficiency in the ladle refining process

    SciTech Connect (OSTI)

    Pan, S.M.; Chiang, J.D.; Hwang, W.S.

    1997-02-01

    The aim of this research was to investigate the effects of injection condition on the mixing efficiency of the gas injection treatment of the ladle refining process in steelmaking. A water modeling approach was employed. A NaCl solution was injected into the vessel and the electric conductivity value of the water solution was measured to represent the concentration of the additive. The results of this investigation reveal that up to a certain level, mixing efficiency is improved as the gas flow rate increases. Off-center injection is better than centerline injection. However, the injection lance should not be too close to the wall. Also, mixing efficiency is improved when the submerged depth of the immersion lance increases. The immersion hood has a optimal size as far as mixing efficiency is concerned. A larger or smaller hood would reduce its efficiency. The submerged depth of the immersion hood should be kept to a minimum to improve mixing efficiency.

  19. A node-centered local refinement algorithm for poisson's equation in complex geometries

    SciTech Connect (OSTI)

    McCorquodale, Peter; Colella, Phillip; Grote, David P.; Vay, Jean-Luc

    2004-05-04

    This paper presents a method for solving Poisson's equation with Dirichlet boundary conditions on an irregular bounded three-dimensional region. The method uses a nodal-point discretization and adaptive mesh refinement (AMR) on Cartesian grids, and the AMR multigrid solver of Almgren. The discrete Laplacian operator at internal boundaries comes from either linear or quadratic (Shortley-Weller) extrapolation, and the two methods are compared. It is shown that either way, solution error is second order in the mesh spacing. Error in the gradient of the solution is first order with linear extrapolation, but second order with Shortley-Weller. Examples are given with comparison with the exact solution. The method is also applied to a heavy-ion fusion accelerator problem, showing the advantage of adaptivity.

  20. Methods of refining natural oils, and methods of producing fuel compositions

    DOE Patents [OSTI]

    Firth, Bruce E.; Kirk, Sharon E.

    2015-10-27

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  1. Methods of refining natural oils and methods of producing fuel compositions

    DOE Patents [OSTI]

    Firth, Bruce E; Kirk, Sharon E; Gavaskar, Vasudeo S

    2015-11-04

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  2. 3D Adaptive Mesh Refinement Simulations of Pellet Injection in Tokamaks

    SciTech Connect (OSTI)

    R. Samtaney; S.C. Jardin; P. Colella; D.F. Martin

    2003-10-20

    We present results of Adaptive Mesh Refinement (AMR) simulations of the pellet injection process, a proven method of refueling tokamaks. AMR is a computationally efficient way to provide the resolution required to simulate realistic pellet sizes relative to device dimensions. The mathematical model comprises of single-fluid MHD equations with source terms in the continuity equation along with a pellet ablation rate model. The numerical method developed is an explicit unsplit upwinding treatment of the 8-wave formulation, coupled with a MAC projection method to enforce the solenoidal property of the magnetic field. The Chombo framework is used for AMR. The role of the E x B drift in mass redistribution during inside and outside pellet injections is emphasized.

  3. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  4. A technical and economic assessment of petroleum, heavy oil, shale oil and coal liquid refining

    SciTech Connect (OSTI)

    Sikonia, J.G.; Shah, B.R.; Ulowetz, M.A.

    1983-11-01

    Decreasing availability of conventional crude oil will result in the utilization of alternative raw materials for the production of transportation fuels. Based on currently available processes and as a result of detailed pilot plant studies, the differences in the technical and economic aspects of refining alternative feedstocks of heavy oil, coal liquids and shale oil have indicated that heavy, hydrogen-deficient materials require more complex and costly upgrading techniques. Compared to the base case of Arabian Light crude oil, the Mexican Maya heavy oil is worth about $4.35/B less, the coal liquid about $2.38/B less and the shale oil about $5.98/B less. All of these alternative fuels can be upgraded into high quality transportation fuels.

  5. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-12-20

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

  6. Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

  7. Development of a performance-based industrial energy efficiency indicator for corn refining plants.

    SciTech Connect (OSTI)

    Boyd, G. A.; Decision and Information Sciences; USEPA

    2006-07-31

    Organizations that implement strategic energy management programs have the potential to achieve sustained energy savings if the programs are carried out properly. A key opportunity for achieving energy savings that plant managers can take is to determine an appropriate level of energy performance by comparing their plant's performance with that of similar plants in the same industry. Manufacturing facilities can set energy efficiency targets by using performance-based indicators. The U.S. Environmental Protection Agency (EPA), through its ENERGY STAR{reg_sign} program, has been developing plant energy performance indicators (EPIs) to encourage a variety of U.S. industries to use energy more efficiently. This report describes work with the corn refining industry to provide a plant-level indicator of energy efficiency for facilities that produce a variety of products--including corn starch, corn oil, animal feed, corn sweeteners, and ethanol--for the paper, food, beverage, and other industries in the United States. Consideration is given to the role that performance-based indicators play in motivating change; the steps needed to develop indicators, including interacting with an industry to secure adequate data for an indicator; and the actual application and use of an indicator when complete. How indicators are employed in the EPA's efforts to encourage industries to voluntarily improve their use of energy is discussed as well. The report describes the data and statistical methods used to construct the EPI for corn refining plants. Individual equations are presented, as are the instructions for using them in an associated Excel spreadsheet.

  8. An enriched finite element model with q-refinement for radiative boundary layers in glass cooling

    SciTech Connect (OSTI)

    Mohamed, M. Shadi; Seaid, Mohammed; Trevelyan, Jon; Laghrouche, Omar

    2014-02-01

    Radiative cooling in glass manufacturing is simulated using the partition of unity finite element method. The governing equations consist of a semi-linear transient heat equation for the temperature field and a stationary simplified P{sub 1} approximation for the radiation in non-grey semitransparent media. To integrate the coupled equations in time we consider a linearly implicit scheme in the finite element framework. A class of hyperbolic enrichment functions is proposed to resolve boundary layers near the enclosure walls. Using an industrial electromagnetic spectrum, the proposed method shows an immense reduction in the number of degrees of freedom required to achieve a certain accuracy compared to the conventional h-version finite element method. Furthermore the method shows a stable behaviour in treating the boundary layers which is shown by studying the solution close to the domain boundaries. The time integration choice is essential to implement a q-refinement procedure introduced in the current study. The enrichment is refined with respect to the steepness of the solution gradient near the domain boundary in the first few time steps and is shown to lead to a further significant reduction on top of what is already achieved with the enrichment. The performance of the proposed method is analysed for glass annealing in two enclosures where the simplified P{sub 1} approximation solution with the partition of unity method, the conventional finite element method and the finite difference method are compared to each other and to the full radiative heat transfer as well as the canonical Rosseland model.

  9. Ceramic Technology Project database: September 1990 summary report. [SiC, SiN, whisker-reinforced SiN, ZrO-toughened aluminas, zirconias, joints

    SciTech Connect (OSTI)

    Keyes, B.L.P.

    1992-06-01

    Data generated within the Ceramic Technology Project (CTP) represent a valuable resource for both research and industry. The CTP database was created to provide easy access to this information in electronic and hardcopy forms by using a computerized database and by issuing periodic hardcopy reports on the database contents. This report is the sixth in a series of semiannual database summaries and covers recent additions to the database, including joined brazed specimen test data. It covers 1 SiC, 34 SiN, 10 whisker-reinforced SiN, 2 zirconia-toughened aluminas, 8 zirconias, and 34 joints.

  10. Method and system for the combination of non-thermal plasma and metal/metal oxide doped .gamma.-alumina catalysts for diesel engine exhaust aftertreatment system

    DOE Patents [OSTI]

    Aardahl, Christopher L.; Balmer-Miller, Mari Lou; Chanda, Ashok; Habeger, Craig F.; Koshkarian, Kent A.; Park, Paul W.

    2006-07-25

    The present disclosure pertains to a system and method for treatment of oxygen rich exhaust and more specifically to a method and system that combines non-thermal plasma with a metal doped .gamma.-alumina catalyst. Current catalyst systems for the treatment of oxygen rich exhaust are capable of achieving only approximately 7 to 12% NO.sub.x reduction as a passive system and only 25 40% reduction when a supplemental hydrocarbon reductant is injected into the exhaust stream. It has been found that treatment of an oxygen rich exhaust initially with a non-thermal plasma and followed by subsequent treatment with a metal doped .gamma.-alumina prepared by the sol gel method is capable of increasing the NO.sub.x reduction to a level of approximately 90% in the absence of SO.sub.2 and 80% in the presence of 20 ppm of SO.sub.2. Especially useful metals have been found to be indium, gallium, and tin.

  11. Local timespace mesh refinement for simulation of elastic wave propagation in multi-scale media

    SciTech Connect (OSTI)

    Kostin, Victor; Lisitsa, Vadim; Reshetova, Galina; Tcheverda, Vladimir

    2015-01-15

    This paper presents an original approach to local timespace grid refinement for the numerical simulation of wave propagation in models with localized clusters of micro-heterogeneities. The main features of the algorithm are the application of temporal and spatial refinement on two different surfaces; the use of the embedded-stencil technique for the refinement of grid step with respect to time; the use of the Fast Fourier Transform (FFT)-based interpolation to couple variables for spatial mesh refinement. The latter makes it possible to perform filtration of high spatial frequencies, which provides stability in the proposed finite-difference schemes. In the present work, the technique is implemented for the finite-difference simulation of seismic wave propagation and the interaction of such waves with fluid-filled fractures and cavities of carbonate reservoirs. However, this approach is easy to adapt and/or combine with other numerical techniques, such as finite elements, discontinuous Galerkin method, or finite volumes used for approximation of various types of linear and nonlinear hyperbolic equations.

  12. Table 5.21 Crude Oil Refiner Acquisition Costs, 1968-2011 (Dollars per Barrel)

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Crude Oil Refiner Acquisition Costs, 1968-2011 (Dollars per Barrel) Year Domestic Imported Composite Nominal 1 Real 2 Nominal 1 Real 2 Nominal 1 Real 2 1968E 3.21 14.57 [R] 2.90 13.16 [R] 3.17 14.39 [R] 1969E 3.37 14.58 [R] 2.80 12.11 [R] 3.29 14.23 [R] 1970E 3.46 14.22 [R] 2.96 12.16 [R] 3.40 13.97 [R] 1971E 3.68 14.40 [R] 3.17 12.41 [R] 3.60 14.09 [R] 1972E 3.67 13.77 [R] 3.22 12.08 [R] 3.58 13.43 [R] 1973E 4.17 14.82 [R] 4.08 14.50 [R] 4.15 14.75 [R] 1974 7.18 23.40 [R] 12.52 40.80 [R] 9.07

  13. Dimensional reduction as a tool for mesh refinement and trackingsingularities of PDEs

    SciTech Connect (OSTI)

    Stinis, Panagiotis

    2007-06-10

    We present a collection of algorithms which utilizedimensional reduction to perform mesh refinement and study possiblysingular solutions of time-dependent partial differential equations. Thealgorithms are inspired by constructions used in statistical mechanics toevaluate the properties of a system near a critical point. The firstalgorithm allows the accurate determination of the time of occurrence ofa possible singularity. The second algorithm is an adaptive meshrefinement scheme which can be used to approach efficiently the possiblesingularity. Finally, the third algorithm uses the second algorithm untilthe available resolution is exhausted (as we approach the possiblesingularity) and then switches to a dimensionally reduced model which,when accurate, can follow faithfully the solution beyond the time ofoccurrence of the purported singularity. An accurate dimensionallyreduced model should dissipate energy at the right rate. We construct twovariants of each algorithm. The first variant assumes that we have actualknowledge of the reduced model. The second variant assumes that we knowthe form of the reduced model, i.e., the terms appearing in the reducedmodel, but not necessarily their coefficients. In this case, we alsoprovide a way of determining the coefficients. We present numericalresults for the Burgers equation with zero and nonzero viscosity toillustrate the use of the algorithms.

  14. Synthesis and Rietveld refinement of the small-pore zeolite SSZ-16

    SciTech Connect (OSTI)

    Lobo, R.F.; Zones, S.I.; Medrud, R.C.

    1996-10-01

    Recent research efforts invested in the synthesis of new high-silica zeolites have yielded several novel materials with medium ({approximately}5.6 {Angstrom}) and large ({approximately}7.2 {Angstrom}) pores. Examples include new zeolites with intersecting 10 and 12 member rings-i.e., pores bounded by 10 and 12 tetrahedral (T) atoms respectively-like SSZ-26, NU-87, SSZ-37, SSZ-25, MCM-22, CIT-1 (CON), and the aluminophosphate-based DAF-1 (DFO). However, except for the zeolites SSZ-28 (DDR) and SSZ-13 (CHA), no new high-silica zeolites with small pores have been reported. High-silica small-pore zeolites could be potentially useful for several catalytic reactions including the synthesis of dimethylamine, the reduction of NO{sub x} from combustion gases and the dewaxing of fuels for octane upgrading. The authors present here the synthesis and structural characterization using Rietveld refinement of synchrotron X-ray powder diffraction data of the zeolite SSZ-16. 27 refs., 3 figs., 2 tabs.

  15. A Predictive Model of Fragmentation using Adaptive Mesh Refinement and a Hierarchical Material Model

    SciTech Connect (OSTI)

    Koniges, A E; Masters, N D; Fisher, A C; Anderson, R W; Eder, D C; Benson, D; Kaiser, T B; Gunney, B T; Wang, P; Maddox, B R; Hansen, J F; Kalantar, D H; Dixit, P; Jarmakani, H; Meyers, M A

    2009-03-03

    Fragmentation is a fundamental material process that naturally spans spatial scales from microscopic to macroscopic. We developed a mathematical framework using an innovative combination of hierarchical material modeling (HMM) and adaptive mesh refinement (AMR) to connect the continuum to microstructural regimes. This framework has been implemented in a new multi-physics, multi-scale, 3D simulation code, NIF ALE-AMR. New multi-material volume fraction and interface reconstruction algorithms were developed for this new code, which is leading the world effort in hydrodynamic simulations that combine AMR with ALE (Arbitrary Lagrangian-Eulerian) techniques. The interface reconstruction algorithm is also used to produce fragments following material failure. In general, the material strength and failure models have history vector components that must be advected along with other properties of the mesh during remap stage of the ALE hydrodynamics. The fragmentation models are validated against an electromagnetically driven expanding ring experiment and dedicated laser-based fragmentation experiments conducted at the Jupiter Laser Facility. As part of the exit plan, the NIF ALE-AMR code was applied to a number of fragmentation problems of interest to the National Ignition Facility (NIF). One example shows the added benefit of multi-material ALE-AMR that relaxes the requirement that material boundaries must be along mesh boundaries.

  16. Chemical coal cleaning process and costs refinement for coal-water slurry manufacture

    SciTech Connect (OSTI)

    Bhasin, A.K.; Berggren, M.H.; Ronzio, N.J.; Smit, F.J.

    1985-12-31

    This report describes the results of process and cost refinement studies for the manufacture of ultra-clean coal-slurry fuel for direct-fired gas turbines. The work was performed as an extension to an earlier contract in which AMAX R and D supplied METC with two lots of highly beneficiated coal slurry fuel for use in the Heat Engines program. A conceptual design study and cost estimate supplied to METC at that time indicated that a combined physical and chemical cleaning process could produce ultra-clean fuel at a competitive price. Laboratory and pilot plant studies performed for the contract extension further defined the process conditions and operating and capital costs to prepare coals containing from 0.2 to 1.0% ash as slurry fuels. A base-case fuel containing coal cleaned to 0.5% ash in a 1000 cp slurry containing 55% coal was $4.16 per million Btu when produced in quantities required to fuel a 500 MW gas-turbine generating station. Coal slurry fuel production costs as low as $3.66 per million Btu were projected for coals cleaned to 1.0% ash. 12 refs., 23 figs., 63 tabs.

  17. Solvent Refined Coal (SRC) process. Quarterly technical progress report, April 1979-June 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project for the period March 25, 1979, through June 24, 1979. SRC-I turnaround activities at the Fort Lewis Pilot Plant and several other problems delayed successful startup until April 11. Slurry was injected to the Lummus Deashing Unit for the first time April 12. After approximately eight days, slurry feed was diverted because of indications that solids were accumulating in the settler vessel. The Fort Lewis Pilot Plant was shut down from April 28 to May 12, 1979, while the Lummus Unit settler vessel was hydroblasted. Cleaning of the settler vessel was complete May 10. Modifications to the unit were nearly complete at the end of the reporting period. Slurry feed to the Lummus Unit was reestablished June 15. To date, continuous production of specification product at design rates has not been achieved. One material balance run, MBR 79-1, was completed using Kentucky No. 9/14 coal at proposed design conditions for the SRC-I Demonstration Plant. Process Development Unit P-99 was on-stream for all of the second quarter of 1979, with the exception of a two-week scheduled turn-around. Six different run conditions were tested feeding Pittsburgh Seam coal from the Powhatan No. 5 Mine.

  18. Refined rotational period, pole solution, and shape model for (3200) Phaethon

    SciTech Connect (OSTI)

    Ansdell, Megan; Meech, Karen J.; Kaluna, Heather; Hainaut, Olivier; Buie, Marc W.; Bauer, James; Dundon, Luke

    2014-09-20

    (3200) Phaethon exhibits both comet- and asteroid-like properties, suggesting it could be a rare transitional object such as a dormant comet or previously volatile-rich asteroid. This justifies detailed study of (3200) Phaethon's physical properties as a better understanding of asteroid-comet transition objects can provide insight into minor body evolution. We therefore acquired time series photometry of (3200) Phaethon over 15 nights from 1994 to 2013, primarily using the Tektronix 2048 2048 pixel CCD on the University of Hawaii 2.2 m telescope. We utilized light curve inversion to (1) refine (3200) Phaethon's rotational period to P = 3.6032 0.0008 hr; (2) estimate a rotational pole orientation of ? = +85 13 and ? = 20 10; and (3) derive a shape model. We also used our extensive light curve data set to estimate the slope parameter of (3200) Phaethon's phase curve as G ? 0.06, consistent with C-type asteroids. We discuss how this highly oblique pole orientation with a negative ecliptic latitude supports previous evidence for (3200) Phaethon's origin in the inner main asteroid belt as well as the potential for deeply buried volatiles fueling impulsive yet rare cometary outbursts.

  19. Biocide usage in cooling towers in the electric power and petroleum refining industries

    SciTech Connect (OSTI)

    Veil, J.; Rice, J.K.; Raivel, M.E.S.

    1997-11-01

    Cooling towers users frequently apply biocides to the circulating cooling water to control growth of microorganisms, algae, and macroorganisms. Because of the toxic properties of biocides, there is a potential for the regulatory controls on their use and discharge to become increasingly more stringent. This report examines the types of biocides used in cooling towers by companies in the electric power and petroleum refining industries, and the experiences those companies have had in dealing with agencies that regulate cooling tower blowdown discharges. Results from a sample of 67 electric power plants indicate that the use of oxidizing biocides (particularly chlorine) is favored. Quaternary ammonia salts (quats), a type of nonoxidizing biocide, are also used in many power plant cooling towers. The experience of dealing with regulators to obtain approval to discharge biocides differs significantly between the two industries. In the electric power industry, discharges of any new biocide typically must be approved in writing by the regulatory agency. The approval process for refineries is less formal. In most cases, the refinery must notify the regulatory agency that it is planning to use a new biocide, but the refinery does not need to get written approval before using it. The conclusion of the report is that few of the surveyed facilities are having any difficulty in using and discharging the biocides they want to use.

  20. Decontamination of metals by melt refinings/slagging: An annotated bibliography

    SciTech Connect (OSTI)

    Mizia, R.E.; Worcester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.

    1993-07-01

    As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult, the problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste storage problems, Westinghouse Idaho Nuclear Company (WINCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technology for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small scale melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of large scale melting demonstrations (100--500 lbs) to be conducted at selected facilities. The program will support recycling and decontaminating stainless steel RSM for use in waste canisters for Idaho Waste Immobilization Facility densified high level waste. This report is the result of the literature search conducted to establish a basis for experimental melt/slag program development.

  1. Refinement, Validation and Application of Cloud-Radiation Parameterization in a GCM

    SciTech Connect (OSTI)

    Dr. Graeme L. Stephens

    2009-04-30

    The research performed under this award was conducted along 3 related fronts: (1) Refinement and assessment of parameterizations of sub-grid scale radiative transport in GCMs. (2) Diagnostic studies that use ARM observations of clouds and convection in an effort to understand the effects of moist convection on its environment, including how convection influences clouds and radiation. This aspect focuses on developing and testing methodologies designed to use ARM data more effectively for use in atmospheric models, both at the cloud resolving model scale and the global climate model scale. (3) Use (1) and (2) in combination with both models and observations of varying complexity to study key radiation feedback Our work toward these objectives thus involved three corresponding efforts. First, novel diagnostic techniques were developed and applied to ARM observations to understand and characterize the effects of moist convection on the dynamical and thermodynamical environment in which it occurs. Second, an in house GCM radiative transfer algorithm (BUGSrad) was employed along with an optimal estimation cloud retrieval algorithm to evaluate the ability to reproduce cloudy-sky radiative flux observations. Assessments using a range of GCMs with various moist convective parameterizations to evaluate the fidelity with which the parameterizations reproduce key observable features of the environment were also started in the final year of this award. The third study area involved the study of cloud radiation feedbacks and we examined these in both cloud resolving and global climate models.

  2. OPEC and lower oil prices: Impacts on production capacity, export refining, domestic demand and trade balances

    SciTech Connect (OSTI)

    Fesharaki, F.; Fridley, D.; Isaak, D.; Totto, L.; Wilson, T.

    1988-12-01

    The East-West Center has received a research grant from the US Department of Energy's Office of Policy, Planning, and Analysis to study the impact of lower oil prices on OPEC production capacity, on export refineries, and petroleum trade. The project was later extended to include balance-of-payments scenarios and impacts on OPEC domestic demand. As the study progressed, a number of preliminary presentations were made at the US Department of Energy in order to receive feedback from DOE officials and to refine the focus of our analysis. During one of the presentations on June 4, 1987, the then Director of Division of Oil and Gas, John Stanley-Miller, advised us to focus our work on the Persian Gulf countries, since these countries were of special interest to the United States Government. Since then, our team has visited Iran, the United Arab Emirates, and Saudi Arabia and obtained detailed information from other countries. The political turmoil in the Gulf, the Iran/Iraq war, and the active US military presence have all worked to delay the final submission of our report. Even in countries where the United States has close ties, access to information has been difficult. In most countries, even mundane information on petroleum issues are treated as national secrets. As a result of these difficulties, we requested a one-year no cost extension to the grant and submitted an Interim Report in May 1988. As part of our grant extension request, we proposed to undertake additional tasks which appear in this report. 20 figs., 21 tabs.

  3. Petropower energia project under way in Chile promises refiner better economics at lower cost

    SciTech Connect (OSTI)

    1996-12-31

    Construction of the Republic of Chile`s first public/private industrial partnership project is well under way. Ground was broken for the $232-million Petropower Energia Limitada project early this year, shortly after the final contract between the parties - Foster Wheeler Power Systems, Inc. (FWPS); Petrox S.A. Refineria de Petroleo and Empresa Nacional del Petroleo (ENAP) - was signed. The Petropower project, located adjacent to Petrox`s 84,000-b/d refinery in Talcahuano, represents the first project ever to combine petroleum coking technology with cogeneration technology in a single project financing. Petropower is 85% owned by FWPS, 7.5% by ENAP, the Chilean national oil company and parent of Petrox S.A. When completed in mid-1998, the Petropower project will enable Petrox to refine heavier crudes and enhance the refinery`s flexibility and economics. The project will consist of a delayed coking facility (a 12,000-b/d delayed coking unit and a 7,000-b/d hydrotreating plant) and a 67-MW (59 MW net) cogeneration plant. The coke produced will fuel a Foster Wheeler proprietary-design circulating fluidized-bed (CFB) boiler which will generate all the high-pressure steam and electric power needs of the Petrox refinery. This unit will be the first circulating fluidized-bed boiler to be built in Latin America. The cogeneration facility, using limestone as a reagent and equipped with a baghouse, will control SO{sub x} emissions from combustion of the green coke fuel and easily meet all Chilean environmental standards. Moreover, by constructing the cogeneration facility, Petrox will not have to proceed with capital improvements to existing facilities to ensure a reliable source of steam and electricity, resulting in substantial savings for Petrox. The cogeneration plant provides a permanent {open_quotes}disposal{close_quotes} for all coke produced by the delayed coker, thereby solving any future problems of unwanted or excess coke.

  4. Temperature dependent dielectric function in the near-infrared to vacuum-ultraviolet ultraviolet spectral range of alumina and yttria stabilized zirconia thin films

    SciTech Connect (OSTI)

    Schmidt-Grund, R. Lhmann, T.; Bntgen, T.; Franke, H.; Lorenz, M.; Grundmann, M.; Opper, D.

    2013-12-14

    The dielectric function of nano-/polycrystalline alumina and yttria stabilised zirconia thin films has been investigated in a wide spectral range from 1.0?eV to 7.5?eV and temperatures between 10?K and room temperature. In the near band-edge spectral range, we found a broad distribution of optical transitions within the band gap, the so-called Urbach absorption tail which is typical for amorphous or polycrystalline materials due to the lack of long range order in the crystal structure. The coupling properties of the electronic system to the optical phonon bath and thermal lattice vibrations strongly depend on the ratio of the spectral extent of these disorder states to the main phonon energy, which we correlate with the different crystalline structure of our samples. The films have been grown at room temperature and 650?C by pulsed laser deposition.

  5. On the Use of ARM Data in the Validation and Refinement of a GCM Radiation Parameterization Scheme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Use of ARM Data in the Validation and Refinement of a GCM Radiation Parameterization Scheme G. L. Stephens, R. T. Austin, P. M. Gabriel, and N. B. Wood Colorado State University Department of Atmospheric Science Fort Collins, Colorado Introduction Data provided under the Atmospheric Radiation Measurement (ARM) Program of the U.S. Department of Energy have been analyzed with the goal of evaluating a radiation parameterization scheme currently used in both cloud resolving models and general

  6. Study of deactivation and regeneration of catalysts used in the LC-fining of solvent refined coal

    SciTech Connect (OSTI)

    Curtis, C.W. (Auburn Univ., AL); Guin, J.A.; Nalitham, R.; mohsin, A.; Tarrer, A.R.; Potts, J.D.; Hastings, K.E.

    1981-03-29

    Batch experiments as well as results from LC-Fining catalytic upgrading of coal extracts indicate deactivation of the Shell 324 Ni/Mo catalyst in the presence of solvent refined coal (SRC). At increased levels of SRC loading, deactivation increases. The chief cause of catalyst deactivation appears to be coking. The Shell 324 catalyst can be substantially regenerated after the upgrading reaction by medium temperature ashing followed by presulfiding.

  7. Techno-Economic Analysis of the Deacetylation and Disk Refining Process. Characterizing the Effect of Refining Energy and Enzyme Usage on Minimum Sugar Selling Price and Minimum Ethanol Selling Price

    SciTech Connect (OSTI)

    Chen, Xiaowen; Shekiro, Joseph; Pschorn, Thomas; Sabourin, Marc; Tucker, Melvin P.; Tao, Ling

    2015-10-29

    A novel, highly efficient deacetylation and disk refining (DDR) process to liberate fermentable sugars from biomass was recently developed at the National Renewable Energy Laboratory (NREL). The DDR process consists of a mild, dilute alkaline deacetylation step followed by low-energy-consumption disk refining. The DDR corn stover substrates achieved high process sugar conversion yields, at low to modest enzyme loadings, and also produced high sugar concentration syrups at high initial insoluble solid loadings. The sugar syrups derived from corn stover are highly fermentable due to low concentrations of fermentation inhibitors. The objective of this work is to evaluate the economic feasibility of the DDR process through a techno-economic analysis (TEA). A large array of experiments designed using a response surface methodology was carried out to investigate the two major cost-driven operational parameters of the novel DDR process: refining energy and enzyme loadings. The boundary conditions for refining energy (128–468 kWh/ODMT), cellulase (Novozyme’s CTec3) loading (11.6–28.4 mg total protein/g of cellulose), and hemicellulase (Novozyme’s HTec3) loading (0–5 mg total protein/g of cellulose) were chosen to cover the most commercially practical operating conditions. The sugar and ethanol yields were modeled with good adequacy, showing a positive linear correlation between those yields and refining energy and enzyme loadings. The ethanol yields ranged from 77 to 89 gallons/ODMT of corn stover. The minimum sugar selling price (MSSP) ranged from $0.191 to $0.212 per lb of 50 % concentrated monomeric sugars, while the minimum ethanol selling price (MESP) ranged from $2.24 to $2.54 per gallon of ethanol. The DDR process concept is evaluated for economic feasibility through TEA. The MSSP and MESP of the DDR process falls within a range similar to that found with the deacetylation/dilute acid pretreatment process modeled in NREL’s 2011 design report. The DDR process is a much simpler process that requires less capital and maintenance costs when compared to conventional chemical pretreatments with pressure vessels. As a result, we feel the DDR process should be considered as an option for future biorefineries with great potential to be more cost-effective.

  8. Techno-Economic Analysis of the Deacetylation and Disk Refining Process. Characterizing the Effect of Refining Energy and Enzyme Usage on Minimum Sugar Selling Price and Minimum Ethanol Selling Price

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Xiaowen; Shekiro, Joseph; Pschorn, Thomas; Sabourin, Marc; Tucker, Melvin P.; Tao, Ling

    2015-10-29

    A novel, highly efficient deacetylation and disk refining (DDR) process to liberate fermentable sugars from biomass was recently developed at the National Renewable Energy Laboratory (NREL). The DDR process consists of a mild, dilute alkaline deacetylation step followed by low-energy-consumption disk refining. The DDR corn stover substrates achieved high process sugar conversion yields, at low to modest enzyme loadings, and also produced high sugar concentration syrups at high initial insoluble solid loadings. The sugar syrups derived from corn stover are highly fermentable due to low concentrations of fermentation inhibitors. The objective of this work is to evaluate the economic feasibilitymore » of the DDR process through a techno-economic analysis (TEA). A large array of experiments designed using a response surface methodology was carried out to investigate the two major cost-driven operational parameters of the novel DDR process: refining energy and enzyme loadings. The boundary conditions for refining energy (128–468 kWh/ODMT), cellulase (Novozyme’s CTec3) loading (11.6–28.4 mg total protein/g of cellulose), and hemicellulase (Novozyme’s HTec3) loading (0–5 mg total protein/g of cellulose) were chosen to cover the most commercially practical operating conditions. The sugar and ethanol yields were modeled with good adequacy, showing a positive linear correlation between those yields and refining energy and enzyme loadings. The ethanol yields ranged from 77 to 89 gallons/ODMT of corn stover. The minimum sugar selling price (MSSP) ranged from $0.191 to $0.212 per lb of 50 % concentrated monomeric sugars, while the minimum ethanol selling price (MESP) ranged from $2.24 to $2.54 per gallon of ethanol. The DDR process concept is evaluated for economic feasibility through TEA. The MSSP and MESP of the DDR process falls within a range similar to that found with the deacetylation/dilute acid pretreatment process modeled in NREL’s 2011 design report. The DDR process is a much simpler process that requires less capital and maintenance costs when compared to conventional chemical pretreatments with pressure vessels. As a result, we feel the DDR process should be considered as an option for future biorefineries with great potential to be more cost-effective.« less

  9. Projections of the impact of expansion of domestic heavy oil production on the U.S. refining industry from 1990 to 2010. Topical report

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Strycker, A.R.; Guariguata, G.; Salmen, F.G.

    1994-12-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil (10{degrees} to 20{degrees} API gravity) production. This report provides a compendium of the United States refining industry and analyzes the industry by Petroleum Administration for Defense District (PADD) and by ten smaller refining areas. The refining capacity, oil source and oil quality are analyzed, and projections are made for the U.S. refining industry for the years 1990 to 2010. The study used publicly available data as background. A linear program model of the U.S. refining industry was constructed and validated using 1990 U.S. refinery performance. Projections of domestic oil production (decline) and import of crude oil (increases) were balanced to meet anticipated demand to establish a base case for years 1990 through 2010. The impact of additional domestic heavy oil production, (300 MB/D to 900 MB/D, originating in select areas of the U.S.) on the U.S. refining complex was evaluated. This heavy oil could reduce the import rate and the balance of payments by displacing some imported, principally Mid-east, medium crude. The construction cost for refining units to accommodate this additional domestic heavy oil production in both the low and high volume scenarios is about 7 billion dollars for bottoms conversion capacity (delayed coking) with about 50% of the cost attributed to compliance with the Clean Air Act Amendment of 1990.

  10. Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making

    DOE Patents [OSTI]

    McCallum, R. William; Branagan, Daniel J.

    1996-01-23

    A method of making a permanent magnet wherein 1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and 2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties.

  11. Carbide/nitride grain refined rare earth-iron-boron permanent magnet and method of making

    DOE Patents [OSTI]

    McCallum, R.W.; Branagan, D.J.

    1996-01-23

    A method of making a permanent magnet is disclosed wherein (1) a melt is formed having a base alloy composition comprising RE, Fe and/or Co, and B (where RE is one or more rare earth elements) and (2) TR (where TR is a transition metal selected from at least one of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and Al) and at least one of C and N are provided in the base alloy composition melt in substantially stoichiometric amounts to form a thermodynamically stable compound (e.g. TR carbide, nitride or carbonitride). The melt is rapidly solidified in a manner to form particulates having a substantially amorphous (metallic glass) structure and a dispersion of primary TRC, TRN and/or TRC/N precipitates. The amorphous particulates are heated above the crystallization temperature of the base alloy composition to nucleate and grow a hard magnetic phase to an optimum grain size and to form secondary TRC, TRN and/or TRC/N precipitates dispersed at grain boundaries. The crystallized particulates are consolidated at an elevated temperature to form a shape. During elevated temperature consolidation, the primary and secondary precipitates act to pin the grain boundaries and minimize deleterious grain growth that is harmful to magnetic properties. 33 figs.

  12. Trends in Commercial Buildings--Total Primary Energy Detail

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Consumption and Graph Total Primary Energy Consumption Graph Detail and Data Table 1979 to 1992 primary consumption trend with 95% confidence ranges 1979 to 1992 primary...

  13. Study on Evaluation of Project Management Data for Decommissioning of Uranium Refining and Conversion Plant - 12234

    SciTech Connect (OSTI)

    Usui, Hideo; Izumo, Sari; Tachibana, Mitsuo; Shibahara, Yuji; Morimoto, Yasuyuki; Tokuyasu, Takashi; Takahashi, Nobuo; Tanaka, Yoshio; Sugitsue, Noritake

    2012-07-01

    Some of nuclear facilities that would no longer be required have been decommissioned in JAEA (Japan Atomic Energy Agency). A lot of nuclear facilities have to be decommissioned in JAEA in near future. To implement decommissioning of nuclear facilities, it was important to make a rational decommissioning plan. Therefore, project management data evaluation system for dismantling activities (PRODIA code) has been developed, and will be useful for making a detailed decommissioning plan for an object facility. Dismantling of dry conversion facility in the uranium refining and conversion plant (URCP) at Ningyo-toge began in 2008. During dismantling activities, project management data such as manpower and amount of waste generation have been collected. Such collected project management data has been evaluated and used to establish a calculation formula to calculate manpower for dismantling equipment of chemical process and calculate manpower for using a green house (GH) which was a temporary structure for preventing the spread of contaminants during dismantling. In the calculation formula to calculate project management data related to dismantling of equipment, the relation of dismantling manpower to each piece of equipment was evaluated. Furthermore, the relation of dismantling manpower to each chemical process was evaluated. The results showed promise for evaluating dismantling manpower with respect to each chemical process. In the calculation formula to calculate project management data related to use of the GH, relations of GH installation manpower and removal manpower to GH footprint were evaluated. Furthermore, the calculation formula for secondary waste generation was established. In this study, project management data related to dismantling of equipment and use of the GH were evaluated and analyzed. The project management data, manpower for dismantling of equipment, manpower for installation and removal of GH, and secondary waste generation from GH were considered. Establishment of the calculation formula for dismantling of each kind of equipment makes it possible to evaluate manpower for dismantling the whole facility. However, it is not easy to prepare calculation formula for all kinds of equipment that exist in the facility. Therefore, a simpler evaluation method was considered to calculate manpower based on facility characteristics. The results showed promise for evaluating dismantling manpower with respect to each chemical process. For dismantling of contaminated equipment, a GH has been used for protection of the spread of contamination. The use of a GH increases manpower for installation and removal of GH etc. Moreover, structural materials of the GH such as plastic sheets, adhesive tape become a burnable secondary waste. To create an effective dismantling plan, it is necessary to carefully consider use of a GH preliminarily. Thus, an evaluation method of project management data such as manpower and secondary waste generation was considered. The results showed promise for evaluating project management data of GH by using established calculation formula. (authors)

  14. Development of Adaptive Model Refinement (AMoR) for Multiphysics and Multifidelity Problems

    SciTech Connect (OSTI)

    Turinsky, Paul

    2015-02-09

    This project investigated the development and utilization of Adaptive Model Refinement (AMoR) for nuclear systems simulation applications. AMoR refers to utilization of several models of physical phenomena which differ in prediction fidelity. If the highest fidelity model is judged to always provide or exceeded the desired fidelity, than if one can determine the difference in a Quantity of Interest (QoI) between the highest fidelity model and lower fidelity models, one could utilize the fidelity model that would just provide the magnitude of the QoI desired. Assuming lower fidelity models require less computational resources, in this manner computational efficiency can be realized provided the QoI value can be accurately and efficiently evaluated. This work utilized Generalized Perturbation Theory (GPT) to evaluate the QoI, by convoluting the GPT solution with the residual of the highest fidelity model determined using the solution from lower fidelity models. Specifically, a reactor core neutronics problem and thermal-hydraulics problem were studied to develop and utilize AMoR. The highest fidelity neutronics model was based upon the 3D space-time, two-group, nodal diffusion equations as solved in the NESTLE computer code. Added to the NESTLE code was the ability to determine the time-dependent GPT neutron flux. The lower fidelity neutronics model was based upon the point kinetics equations along with utilization of a prolongation operator to determine the 3D space-time, two-group flux. The highest fidelity thermal-hydraulics model was based upon the space-time equations governing fluid flow in a closed channel around a heat generating fuel rod. The Homogenous Equilibrium Mixture (HEM) model was used for the fluid and Finite Difference Method was applied to both the coolant and fuel pin energy conservation equations. The lower fidelity thermal-hydraulic model was based upon the same equations as used for the highest fidelity model but now with coarse spatial meshing, corrected somewhat by employing effective fuel heat conduction values. The effectiveness of switching between the highest fidelity model and lower fidelity model as a function of time was assessed using the neutronics problem. Based upon work completed to date, one concludes that the time switching is effective in annealing out differences between the highest and lower fidelity solutions. The effectiveness of using a lower fidelity GPT solution, along with a prolongation operator, to estimate the QoI was also assessed. The utilization of a lower fidelity GPT solution was done in an attempt to avoid the high computational burden associated with solving for the highest fidelity GPT solution. Based upon work completed to date, one concludes that the lower fidelity adjoint solution is not sufficiently accurate with regard to estimating the QoI; however, a formulation has been revealed that may provide a path for addressing this shortcoming.

  15. COLLABORATIVE RESEARCH: CONTINUOUS DYNAMIC GRID ADAPTATION IN A GLOBAL ATMOSPHERIC MODEL: APPLICATION AND REFINEMENT

    SciTech Connect (OSTI)

    Gutowski, William J.; Prusa, Joseph M.; Smolarkiewicz, Piotr K.

    2012-05-08

    This project had goals of advancing the performance capabilities of the numerical general circulation model EULAG and using it to produce a fully operational atmospheric global climate model (AGCM) that can employ either static or dynamic grid stretching for targeted phenomena. The resulting AGCM combined EULAG's advanced dynamics core with the "physics" of the NCAR Community Atmospheric Model (CAM). Effort discussed below shows how we improved model performance and tested both EULAG and the coupled CAM-EULAG in several ways to demonstrate the grid stretching and ability to simulate very well a wide range of scales, that is, multi-scale capability. We leveraged our effort through interaction with an international EULAG community that has collectively developed new features and applications of EULAG, which we exploited for our own work summarized here. Overall, the work contributed to over 40 peer-reviewed publications and over 70 conference/workshop/seminar presentations, many of them invited. 3a. EULAG Advances EULAG is a non-hydrostatic, parallel computational model for all-scale geophysical flows. EULAG's name derives from its two computational options: EULerian (flux form) or semi-LAGrangian (advective form). The model combines nonoscillatory forward-in-time (NFT) numerical algorithms with a robust elliptic Krylov solver. A signature feature of EULAG is that it is formulated in generalized time-dependent curvilinear coordinates. In particular, this enables grid adaptivity. In total, these features give EULAG novel advantages over many existing dynamical cores. For EULAG itself, numerical advances included refining boundary conditions and filters for optimizing model performance in polar regions. We also added flexibility to the model's underlying formulation, allowing it to work with the pseudo-compressible equation set of Durran in addition to EULAG's standard anelastic formulation. Work in collaboration with others also extended the demonstrated range of validity of soundproof models, showing that they are more broadly applicable than some had previously thought. Substantial testing of EULAG included application and extension of the Jablonowski-Williamson baroclinic wave test - an archetype of planetary weather - and further analysis of multi-scale interactions arising from collapse of temperature fronts in both the baroclinic wave test and simulations of the Held-Suarez idealized climate. These analyses revealed properties of atmospheric gravity waves not seen in previous work and further demonstrated the ability of EULAG to simulate realistic behavior over several orders of magnitude of length scales. Additional collaborative work enhanced capability for modeling atmospheric flows with adaptive moving meshes and demonstrated the ability of EULAG to move into petascale computing. 3b. CAM-EULAG Advances We have developed CAM-EULAG in collaboration with former project postdoc, now University of Cape Town Assistant Professor, Babatunde Abiodun. Initial study documented good model performance in aqua-planet simulations. In particular, we showed that the grid adaptivity (stretching) implemented in CAM-EULAG allows higher resolution in selected regions without causing anomalous behavior such as spurious wave reflection. We then used the stretched-grid version to analyze simulated extreme precipitation events in West Africa, comparing the precipitation and event environment with observed behavior. The model simulates fairly well the spatial scale and the interannual and intraseasonal variability of the extreme events, although its extreme precipitation intensity is weaker than observed. In addition, both observations and the simulations show possible forcing of extreme events by African easterly waves. 3c. Other Contributions Through our collaborations, we have made contributions to a wide range of outcomes. For research focused on terrestrial behavior, these have included (1) upwind schemes for gas dynamics, (2) a nonlinear perspective on the dynamics of the Madden-Julian Oscillation, (3) numerical realism of thermal co

  16. Final Technical Report Microwave Assisted Electrolyte Cell for Primary Aluminum Production

    SciTech Connect (OSTI)

    Xiaodi Huang; J.Y. Hwang

    2007-04-18

    This research addresses the high priority research need for developing inert anode and wetted cathode technology, as defined in the Aluminum Industry Technology Roadmap and Inert Anode Roadmap, with the performance targets: a) significantly reducing the energy intensity of aluminum production, b) ultimately eliminating anode-related CO2 emissions, and c) reducing aluminum production costs. This research intended to develop a new electrometallurgical extraction technology by introducing microwave irradiation into the current electrolytic cells for primary aluminum production. This technology aimed at accelerating the alumina electrolysis reduction rate and lowering the aluminum production temperature, coupled with the uses of nickel based superalloy inert anode, nickel based superalloy wetted cathode, and modified salt electrolyte. Michigan Technological University, collaborating with Cober Electronic and Century Aluminum, conducted bench-scale research for evaluation of this technology. This research included three sub-topics: a) fluoride microwave absorption; b) microwave assisted electrolytic cell design and fabrication; and c) aluminum electrowinning tests using the microwave assisted electrolytic cell. This research concludes that the typically used fluoride compound for aluminum electrowinning is not a good microwave absorbing material at room temperature. However, it becomes an excellent microwave absorbing material above 550C. The electrowinning tests did not show benefit to introduce microwave irradiation into the electrolytic cell. The experiments revealed that the nickel-based superalloy is not suitable for use as a cathode material; although it wets with molten aluminum, it causes severe reaction with molten aluminum. In the anode experiments, the chosen superalloy did not meet corrosion resistance requirements. A nicked based alloy without iron content could be further investigated.

  17. A Freestream-Preserving High-Order Finite-Volume Method for Mapped Grids with Adaptive-Mesh Refinement

    SciTech Connect (OSTI)

    Guzik, S; McCorquodale, P; Colella, P

    2011-12-16

    A fourth-order accurate finite-volume method is presented for solving time-dependent hyperbolic systems of conservation laws on mapped grids that are adaptively refined in space and time. Novel considerations for formulating the semi-discrete system of equations in computational space combined with detailed mechanisms for accommodating the adapting grids ensure that conservation is maintained and that the divergence of a constant vector field is always zero (freestream-preservation property). Advancement in time is achieved with a fourth-order Runge-Kutta method.

  18. Table A1. Total First Use (formerly Primary Consumption) of...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... W "," W "," W "," W "," W ",0,220,0,16 2911,"Petroleum Refining (h)",249,1824," W "," W ",17," W "," W ",0,220,0,13.8 30,"Rubber and Miscellaneous Plastics ...

  19. Laser damage by ns and sub-ps pulses on hafnia/silica anti-reflection coatings on fused silica double-sided polished using zirconia or ceria and washed with or without an alumina wash step.

    SciTech Connect (OSTI)

    Bellum, John Curtis; Rambo, Patrick K.; Schwarz, Jens; Kletecka, Damon; Atherton, Briggs W.; Kimmel, Mark W.; Smith, Ian Craig; Smith, Douglas; Hobbs, Zachary

    2010-10-01

    Sandia's Large Optics Coating Operation has extensive results of laser induced damage threshold (LIDT) testing of its anti-reflection (AR) and high reflection coatings on substrates pitch polished using ceria and washed in a process that includes an alumina wash step. The purpose of the alumina wash step is to remove residual polishing compound to minimize its role in laser damage. These LIDT tests are for multi longitudinal mode, ns class pulses at 1064 nm and 532 nm (NIF-MEL protocol) and mode locked, sub-ps class pulses at 1054 nm (Sandia measurements), and show reasonably high and adequate laser damage resistance for coatings in the beam trains of Sandia's Z-Backlighter terawatt and petawatt lasers. An AR coating in addition to coatings of our previous reports confirms this with LIDTs of 33.0 J/cm{sup 2} for 3.5 ns pulses and 1.8 J/cm{sup 2} for 350 fs pulses. In this paper, we investigate both ceria and zirconia in doublesided polishing (common for large flat Z-Backlighter laser optics) as they affect LIDTs of an AR coating on fused silica substrates washed with or without the alumina wash step. For these AR coated, double-sided polished surfaces, ceria polishing in general affords better resistance to laser damage than zirconia polishing and laser damage is less likely with the alumina wash step than without it. This is supported by specific results of laser damage tests with 3.5 ns, multi longitudinal mode, single shot pulses at 1064 nm and 532 nm, with 7.0 ns, single and multi longitudinal mode, single and multi shot pulses at 532 nm, and with 350 fs, mode-locked, single shot pulses at 1054 nm.

  20. Initial activity of reduced chromia/alumina catalyst in n-butane dehydrogenation monitored by on-line FT-IR gas analysis

    SciTech Connect (OSTI)

    Hakuli, A.; Kytoekivi, A.; Suntola, T.

    1996-06-01

    The initial activity of chromia/alumina catalyst (13 wt% Cr) in n-butane dehydrogenation was studied in a flow reactor at 853 K. The initial activity was determined by on-line FT-IR gas analysis, which enabled sampling of the gaseous product mixture at a time resolution of seconds. The catalysts were processed in repeated cycles of oxidation, reduction, and dehydrogenation using n-butane, methane, hydrogen, or carbon monoxide as reducing agents. With n-butane, methane, and hydrogen and dehydrogenation activity was associated with Cr{sup 3+} species apparently formed in the reduction of high-valence Cr species. The catalyst reduced with carbon monoxide at 853 K showed poor initial selectivity for butenes and, relative to the other catalysts. Simultaneous data relating the initial activity, coke content, and some of the physicochemical properties of the catalyst indicated that the surfaces of all catalysts were modified to some extent by the successive reaction cycles. 33 refs., 7 figs., 2 tabs.

  1. Research and Development of a New Silica-Alumina Based Cementitious Material Largely Using Coal Refuse for Mine Backfill, Mine Sealing and Waste Disposal Stabilization

    SciTech Connect (OSTI)

    Henghu Sun; Yuan Yao

    2012-06-29

    Coal refuse and coal combustion byproducts as industrial solid waste stockpiles have become great threats to the environment. To activate coal refuse is one practical solution to recycle this huge amount of solid waste as substitute for Ordinary Portland Cement (OPC). The central goal of this project is to investigate and develop a new silica-alumina based cementitious material largely using coal refuse as a constituent that will be ideal for durable construction, mine backfill, mine sealing and waste disposal stabilization applications. This new material is an environment-friendly alternative to Ordinary Portland Cement. The main constituents of the new material are coal refuse and other coal wastes including coal sludge and coal combustion products (CCPs). Compared with conventional cement production, successful development of this new technology could potentially save energy and reduce greenhouse gas emissions, recycle vast amount of coal wastes, and significantly reduce production cost. A systematic research has been conducted to seek for an optimal solution for enhancing pozzolanic reactivity of the relatively inert solid waste-coal refuse in order to improve the utilization efficiency and economic benefit as a construction and building material.

  2. The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies

    SciTech Connect (OSTI)

    Kim, C.

    1992-04-01

    Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO[sub x], the addition of Pt increased the selectivity of hydrogenation over isomerization.

  3. The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies

    SciTech Connect (OSTI)

    Kim, C.

    1992-04-01

    Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO{sub x}, the addition of Pt increased the selectivity of hydrogenation over isomerization.

  4. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-12-01

    An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.

  5. A revised partiality model and post-refinement algorithm for X-ray free-electron laser data

    SciTech Connect (OSTI)

    Ginn, Helen Mary; Brewster, Aaron S.; Hattne, Johan; Evans, Gwyndaf; Wagner, Armin; Grimes, Jonathan M.; Sauter, Nicholas K.; Sutton, Geoff; Stuart, David Ian

    2015-05-23

    An updated partiality model and post-refinement algorithm for XFEL snapshot diffraction data is presented and confirmed by observing anomalous density for S atoms at an X-ray wavelength of 1.3 . Research towards using X-ray free-electron laser (XFEL) data to solve structures using experimental phasing methods such as sulfur single-wavelength anomalous dispersion (SAD) has been hampered by shortcomings in the diffraction models for X-ray diffraction from FELs. Owing to errors in the orientation matrix and overly simple partiality models, researchers have required large numbers of images to converge to reliable estimates for the structure-factor amplitudes, which may not be feasible for all biological systems. Here, data for cytoplasmic polyhedrosis virus type 17 (CPV17) collected at 1.3 wavelength at the Linac Coherent Light Source (LCLS) are revisited. A previously published definition of a partiality model for reflections illuminated by self-amplified spontaneous emission (SASE) pulses is built upon, which defines a fraction between 0 and 1 based on the intersection of a reflection with a spread of Ewald spheres modelled by a super-Gaussian wavelength distribution in the X-ray beam. A method of post-refinement to refine the parameters of this model is suggested. This has generated a merged data set with an overall discrepancy (by calculating the R{sub split} value) of 3.15% to 1.46 resolution from a 7225-image data set. The atomic numbers of C, N and O atoms in the structure are distinguishable in the electron-density map. There are 13 S atoms within the 237 residues of CPV17, excluding the initial disordered methionine. These only possess 0.42 anomalous scattering electrons each at 1.3 wavelength, but the 12 that have single predominant positions are easily detectable in the anomalous difference Fourier map. It is hoped that these improvements will lead towards XFEL experimental phase determination and structure determination by sulfur SAD and will generally increase the utility of the method for difficult cases.

  6. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    SciTech Connect (OSTI)

    Compere, A L; Griffith, William {Bill} L

    2009-04-01

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  7. Enhancing adaptive sparse grid approximations and improving refinement strategies using adjoint-based a posteriori error estimates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jakeman, J. D.; Wildey, T.

    2015-01-01

    In this paper we present an algorithm for adaptive sparse grid approximations of quantities of interest computed from discretized partial differential equations. We use adjoint-based a posteriori error estimates of the interpolation error in the sparse grid to enhance the sparse grid approximation and to drive adaptivity. We show that utilizing these error estimates provides significantly more accurate functional values for random samples of the sparse grid approximation. We also demonstrate that alternative refinement strategies based upon a posteriori error estimates can lead to further increases in accuracy in the approximation over traditional hierarchical surplus based strategies. Throughout this papermore » we also provide and test a framework for balancing the physical discretization error with the stochastic interpolation error of the enhanced sparse grid approximation.« less

  8. Enhancing adaptive sparse grid approximations and improving refinement strategies using adjoint-based a posteriori error estimates

    SciTech Connect (OSTI)

    Jakeman, J.D. Wildey, T.

    2015-01-01

    In this paper we present an algorithm for adaptive sparse grid approximations of quantities of interest computed from discretized partial differential equations. We use adjoint-based a posteriori error estimates of the physical discretization error and the interpolation error in the sparse grid to enhance the sparse grid approximation and to drive adaptivity of the sparse grid. Utilizing these error estimates provides significantly more accurate functional values for random samples of the sparse grid approximation. We also demonstrate that alternative refinement strategies based upon a posteriori error estimates can lead to further increases in accuracy in the approximation over traditional hierarchical surplus based strategies. Throughout this paper we also provide and test a framework for balancing the physical discretization error with the stochastic interpolation error of the enhanced sparse grid approximation.

  9. A revised partiality model and post-refinement algorithm for X-ray free-electron laser data

    SciTech Connect (OSTI)

    Ginn, Helen Mary; Brewster, Aaron S.; Hattne, Johan; Evans, Gwyndaf; Wagner, Armin; Grimes, Jonathan M.; Sauter, Nicholas K.; Sutton, Geoff; Stuart, David Ian

    2015-05-23

    Research towards using X-ray free-electron laser (XFEL) data to solve structures using experimental phasing methods such as sulfur single-wavelength anomalous dispersion (SAD) has been hampered by shortcomings in the diffraction models for X-ray diffraction from FELs. Owing to errors in the orientation matrix and overly simple partiality models, researchers have required large numbers of images to converge to reliable estimates for the structure-factor amplitudes, which may not be feasible for all biological systems. Here, data for cytoplasmic polyhedrosis virus type 17 (CPV17) collected at 1.3 wavelength at the Linac Coherent Light Source (LCLS) are revisited. A previously published definition of a partiality model for reflections illuminated by self-amplified spontaneous emission (SASE) pulses is built upon, which defines a fraction between 0 and 1 based on the intersection of a reflection with a spread of Ewald spheres modelled by a super-Gaussian wavelength distribution in the X-ray beam. A method of post-refinement to refine the parameters of this model is suggested. This has generated a merged data set with an overall discrepancy (by calculating theRsplitvalue) of 3.15% to 1.46 resolution from a 7225-image data set. The atomic numbers of C, N and O atoms in the structure are distinguishable in the electron-density map. There are 13 S atoms within the 237 residues of CPV17, excluding the initial disordered methionine. These only possess 0.42 anomalous scattering electrons each at 1.3 wavelength, but the 12 that have single predominant positions are easily detectable in the anomalous difference Fourier map. It is hoped that these improvements will lead towards XFEL experimental phase determination and structure determination by sulfur SAD and will generally increase the utility of the method for difficult cases.

  10. Equal Channel Angular Pressing (ECAP) and Its Application to Grain Refinement of Al-Zn-Mg-Cu Alloy

    SciTech Connect (OSTI)

    Tekeli, Sueleyman; Gueral, Ahmet

    2011-12-10

    Microstructure of a metal can be considerably changed by severe plastic deformation techniques such as high pressure torsion, extrusion and equal-channel angular pressing (ECAP). Among these methods, ECAP is particularly attractive because it has a potential for introducing significant grain refinement and homogeneous microstructure into bulk materials. Typically, it reduces the grain size to the submicrometer level or even nanometer range and thus produces materials that are capable of exhibiting unusual mechanical properties. In the present study, a test unites for equal channel angular pressing was constructed and this system was used for Al-Zn-Mg-Cu alloy. After the optimization tests, it was seen that the most effective lubricant for the dies was MoS{sub 2}, the pressing pressure was around 25-35 ton and the pressing speed was 2 mm/s. By using these parameters, the Al-Zn-Mg-Cu alloy was successfully ECAPed up to 14 passes at 200 deg. C using route C. After ECAP tests, the specimens were characterized by transmission electron microscope (TEM), hardness and macrostructural investigations. It was seen that the plastic deformation in the ECAPed specimens occurred from edge to the centre like whirlpool. In addition, the deformation intensity increased with increasing pass number. The grain size of the specimens effectively also decreased with increasing pass number. That is, while the grain size of unECAPed specimen was 10 {mu}m, this value decreased to 300 nm after 14 passes. At the beginning, while there was a banding tendency in the grains toward deformation direction, homogeneous and equiaxed grains were formed with increasing pass number. This grain refinement was as a result of an interaction between shear strain and thermal recovery during ECAP processing. Hardness measurements showed that the hardness values increased up to 4 passes, decreased effectively at 6th pass, again increased at 8th pass and after this pass, the hardness again decreased due to dynamic recrystallization.

  11. Refinement of the Kansas City Plant site conceptual model with respect to dense non-aqueous phase liquids (DNAPL)

    SciTech Connect (OSTI)

    Korte, N.E.; Hall, S.C.; Baker, J.L.

    1995-10-01

    This document presents a refinement of the site conceptual model with respect to dense non-aqueous phase liquid (DNAPL) at the US Department of Energy Kansas City Plant (KCP). This refinement was prompted by a review of the literature and the results of a limited study that was conducted to evaluate whether pools of DNAPL were present in contaminated locations at the KCP. The field study relied on the micropurge method of sample collection. This method has been demonstrated as a successful approach for obtaining discrete samples within a limited aquifer zone. Samples were collected at five locations across 5-ft well screens located at the base of the alluvial aquifer at the KCP. The hypothesis was that if pools of DNAPL were present, the dissolved concentration would increase with depth. Four wells with highly contaminated groundwater were selected for the test. Three of the wells were located in areas where DNAPL was suspected, and one where no DNAPL was believed to be present. The results demonstrated no discernible pattern with depth for the four wells tested. A review of the data in light of the available technical literature suggests that the fine-grained nature of the aquifer materials precludes the formation of pools. Instead, DNAPL is trapped as discontinuous ganglia that are probably widespread throughout the aquifer. The discontinuous nature of the DNAPL distribution prevents the collection of groundwater samples with concentrations approaching saturation. Furthermore, the results indicate that attempts to remediate the aquifer with conventional approaches will not result in restoration to pristine conditions because the tortuous groundwater flow paths will inhibit the efficiency of fluid-flow-based treatments.

  12. A revised partiality model and post-refinement algorithm for X-ray free-electron laser data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ginn, Helen Mary; Brewster, Aaron S.; Hattne, Johan; Evans, Gwyndaf; Wagner, Armin; Grimes, Jonathan M.; Sauter, Nicholas K.; Sutton, Geoff; Stuart, David Ian

    2015-05-23

    Research towards using X-ray free-electron laser (XFEL) data to solve structures using experimental phasing methods such as sulfur single-wavelength anomalous dispersion (SAD) has been hampered by shortcomings in the diffraction models for X-ray diffraction from FELs. Owing to errors in the orientation matrix and overly simple partiality models, researchers have required large numbers of images to converge to reliable estimates for the structure-factor amplitudes, which may not be feasible for all biological systems. Here, data for cytoplasmic polyhedrosis virus type 17 (CPV17) collected at 1.3 Å wavelength at the Linac Coherent Light Source (LCLS) are revisited. A previously published definitionmore » of a partiality model for reflections illuminated by self-amplified spontaneous emission (SASE) pulses is built upon, which defines a fraction between 0 and 1 based on the intersection of a reflection with a spread of Ewald spheres modelled by a super-Gaussian wavelength distribution in the X-ray beam. A method of post-refinement to refine the parameters of this model is suggested. This has generated a merged data set with an overall discrepancy (by calculating theRsplitvalue) of 3.15% to 1.46 Å resolution from a 7225-image data set. The atomic numbers of C, N and O atoms in the structure are distinguishable in the electron-density map. There are 13 S atoms within the 237 residues of CPV17, excluding the initial disordered methionine. These only possess 0.42 anomalous scattering electrons each at 1.3 Å wavelength, but the 12 that have single predominant positions are easily detectable in the anomalous difference Fourier map. It is hoped that these improvements will lead towards XFEL experimental phase determination and structure determination by sulfur SAD and will generally increase the utility of the method for difficult cases.« less

  13. Working with SRNL - Our Facilities- Primary Standards Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Primary Standards Laboratory Working with SRNL Our Facilities - Primary Standards Laboratory The Primary Standards Laboratory at SRNL provides calibration services compliant to the requirements of the American national standard for calibration laboratories.

  14. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  15. Primary Characteristics of Loan Loss Reserve Funds | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Primary Characteristics of Loan Loss Reserve Funds Primary Characteristics of Loan Loss ... Typical residential energy efficiency loans, for example, are in the range of 5,000 to ...

  16. Organosilicon-Based Electrolytes for Long-Life Lithium Primary...

    Office of Scientific and Technical Information (OSTI)

    Long-Life Lithium Primary Batteries Citation Details In-Document Search Title: Organosilicon-Based Electrolytes for Long-Life Lithium Primary Batteries This report describes ...

  17. Primary Science of Energy Student Guide (42 Activities) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Student Guide (42 Activities) Primary Science of Energy Student Guide (42 Activities) Information about Primary Science of Energy, 42 student activities on energy basics for grades...

  18. Preoperational test report, primary ventilation system

    SciTech Connect (OSTI)

    Clifton, F.T.

    1997-11-04

    This represents a preoperational test report for Primary Ventilation Systems, Project W-030. Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks. The system provides vapor space filtered venting of tanks AY101, AY102, AZ101, AZ102. The tests verify correct system operation and correct indications displayed by the central Monitor and Control System.

  19. Surface Protonation at the Rutile (110) Interface: Explicit Incorporation of Solvation Structure within the Refined MUSIC Model Framework

    SciTech Connect (OSTI)

    Machesky, Michael L.; Predota, M.; Wesolowski, David J

    2008-11-01

    The detailed solvation structure at the (110) surface of rutile ({alpha}-TiO{sub 2}) in contact with bulk liquid water has been obtained primarily from experimentally verified classical molecular dynamics (CMD) simulations of the ab initio-optimized surface in contact with SPC/E water. The results are used to explicitly quantify H-bonding interactions, which are then used within the refined MUSIC model framework to predict surface oxygen protonation constants. Quantum mechanical molecular dynamics (QMD) simulations in the presence of freely dissociable water molecules produced H-bond distributions around deprotonated surface oxygens very similar to those obtained by CMD with nondissociable SPC/E water, thereby confirming that the less computationally intensive CMD simulations provide accurate H-bond information. Utilizing this H-bond information within the refined MUSIC model, along with manually adjusted Ti-O surface bond lengths that are nonetheless within 0.05 {angstrom} of those obtained from static density functional theory (DFT) calculations and measured in X-ray reflectivity experiments (as well as bulk crystal values), give surface protonation constants that result in a calculated zero net proton charge pH value (pHznpc) at 25 C that agrees quantitatively with the experimentally determined value (5.4 {+-} 0.2) for a specific rutile powder dominated by the (110) crystal face. Moreover, the predicted pH{sub znpc} values agree to within 0.1 pH unit with those measured at all temperatures between 10 and 250 C. A slightly smaller manual adjustment of the DFT-derived Ti-O surface bond lengths was sufficient to bring the predicted pH{sub znpc} value of the rutile (110) surface at 25 C into quantitative agreement with the experimental value (4.8 {+-} 0.3) obtained from a polished and annealed rutile (110) single crystal surface in contact with dilute sodium nitrate solutions using second harmonic generation (SHG) intensity measurements as a function of ionic strength. Additionally, the H-bond interactions between protolyzable surface oxygen groups and water were found to be stronger than those between bulk water molecules at all temperatures investigated in our CMD simulations (25, 150 and 250 C). Comparison with the protonation scheme previously determined for the (110) surface of isostructural cassiterite ({alpha}-SnO{sub 2}) reveals that the greater extent of H-bonding on the latter surface, and in particular between water and the terminal hydroxyl group (Sn-OH) results in the predicted protonation constant for that group being lower than for the bridged oxygen (Sn-O-Sn), while the reverse is true for the rutile (110) surface. These results demonstrate the importance of H-bond structure in dictating surface protonation behavior, and that explicit use of this solvation structure within the refined MUSIC model framework results in predicted surface protonation constants that are also consistent with a variety of other experimental and computational data.

  20. Securing Financial Incentives for Energy Efficiency Projects...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Aluminum Leader for 125 Years F Upstream Bauxite mining Alumina refining Aluminum ... market for commercial EE retrofits (Urban Land Institute) * Large Untapped Annual ...

  1. Primary coal crushers grow to meet demand

    SciTech Connect (OSTI)

    Fiscor, S.

    2009-09-15

    Mine operators look for more throughput with less fines generation in primary crushers (defined here as single role crushers and two stage crushers). The article gives advice on crusher selection and application. Some factors dictating selection include the desired product size, capacity, Hard Grove grindability index, percentage of rock to be freed and hardness of that rock. The hardness of coal probably has greatest impact on product fineness. 2 refs., 1 fig., 1 tab.

  2. Solvent Refined Coal (SRC) process: trace elements. Volume III. Pilot plant development work. Part 6. Fate of trace elements in the SRC process. [Ph. D. Thesis

    SciTech Connect (OSTI)

    Weiss, C.S.

    1980-09-01

    A study of the forms of trace elements occurring in Solvent Refined Coal has been performed by chemical separation of the Solvent Refined Coal based on differences in the functionality and molecular weight of the organic matrix. Analysis of the fractions separated for various trace elements has revealed associations of certain elements with other elements as well as with certain fractions. The analysis of Solvent Refined Coal I by these methods provided data on the distribution of Ti, V, Ca, S, Al, Mn, As, Se, Cr, Fe, Ni, Zn, Sc, and Ga in the fractions generated. Because of the low trace element content of Solvent Refined Coal II only As, Se, and Cr could be detected in the silica fractions. Based on the distributions three different groups of elements have been based on the association of elements with each other and with certain fractions. The first group is composed of As, Se, and Cr associated with silica fractions of relatively low functionality; these elements have a high percent solubility in the starting Solvent Refined Coal II oil. The second group composed of Ti, V, and to a lesser extent a second form of Cr, is associated with fractions that have a high concentration of phenolic material and is probably present as phenoxide complexes. The third group composed of Fe, Ca, K, Al, and Mg is associated with the most functional fractions and is possibly present as humic acid type complexes or as submicron size particulates. The integration of chromatographic methods with trace element analysis of the fractions generated is capable of discerning the presence of different forms of the elements. The methods used are applicable to other important geologically occurring organic matter.

  3. A top-down assessment of energy, water and land use in uranium mining, milling, and refining

    SciTech Connect (OSTI)

    E. Schneider; B. Carlsen; E. Tavrides; C. van der Hoeven; U. Phathanapirom

    2013-11-01

    Land, water and energy use are key measures of the sustainability of uranium production into the future. As the most attractive, accessible deposits are mined out, future discoveries may prove to be significantly, perhaps unsustainably, more intensive consumers of environmental resources. A number of previous attempts have been made to provide empirical relationships connecting these environmental impact metrics to process variables such as stripping ratio and ore grade. These earlier attempts were often constrained by a lack of real world data and perform poorly when compared against data from modern operations. This paper conditions new empirical models of energy, water and land use in uranium mining, milling, and refining on contemporary data reported by operating mines. It shows that, at present, direct energy use from uranium production represents less than 1% of the electrical energy produced by the once-through fuel cycle. Projections of future energy intensity from uranium production are also possible by coupling the empirical models with estimates of uranium crustal abundance, characteristics of new discoveries, and demand. The projections show that even for the most pessimistic of scenarios considered, by 2100, the direct energy use from uranium production represents less than 3% of the electrical energy produced by the contemporary once-through fuel cycle.

  4. Structure of 2 molar NaOH in aqueous solution from neutron diffraction and empirical potential structure refinement

    SciTech Connect (OSTI)

    McLain, Sylvia E.; Imberti, Silvia; Soper, Alan K.; Botti, Alberto; Bruni, Fabio; Ricci, Maria Antonietta

    2006-09-01

    Neutron diffraction with isotopic substitution has been used to investigate aqueous solutions of 2M NaOH in the liquid state. The data were modeled using empirical potential structure refinement which allows for the extraction of the ion-water and water-water correlations. The data show that the ion-water radial distribution functions are in accordance with those found by previous studies on NaOH solutions and follow a trend which is dependent on the concentration of the solute. In particular, the shape of the hydroxide hydration shell is found to be concentration independent, but the number of water molecules occupying this shell increases with dilution. Additionally, the water-water correlations show that there is still a measurable effect on water structure with the addition of ions at this concentration, as the second shell in the water oxygen radial distribution function is compressed relative to the first shell. The data are also used to discuss the recent claims that the published radial distribution functions of water are unreliable, showing that data taken at different neutron sources, with different diffraction geometry and systematic errors lead to the same structural information when analyzed via a realistic modeling regime.

  5. A procedure for the estimation of the numerical uncertainty of CFD calculations based on grid refinement studies

    SciTech Connect (OSTI)

    Ea, L.; Hoekstra, M.

    2014-04-01

    This paper offers a procedure for the estimation of the numerical uncertainty of any integral or local flow quantity as a result of a fluid flow computation; the procedure requires solutions on systematically refined grids. The error is estimated with power series expansions as a function of the typical cell size. These expansions, of which four types are used, are fitted to the data in the least-squares sense. The selection of the best error estimate is based on the standard deviation of the fits. The error estimate is converted into an uncertainty with a safety factor that depends on the observed order of grid convergence and on the standard deviation of the fit. For well-behaved data sets, i.e. monotonic convergence with the expected observed order of grid convergence and no scatter in the data, the method reduces to the well known Grid Convergence Index. Examples of application of the procedure are included. - Highlights: Estimation of the numerical uncertainty of any integral or local flow quantity. Least squares fits to power series expansions to handle noisy data. Excellent results obtained for manufactured solutions. Consistent results obtained for practical CFD calculations. Reduces to the well known Grid Convergence Index for well-behaved data sets.

  6. Weekly Refiner Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil 4,773 4,712 4,906 4,794 4,746 4,673 2010-2016 15 ppm Sulfur and Under 4,472 4,446 4,590 4,494 4,434 4,400 2010-2016 > 15 ppm to 500 ppm Sulfur 132 106 181 121 ...

  7. Method for mercury refinement

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-04-09

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  8. Apparatus for mercury refinement

    DOE Patents [OSTI]

    Grossman, Mark W.; Speer, Richard; George, William A.

    1991-01-01

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  9. Method for mercury refinement

    DOE Patents [OSTI]

    Grossman, Mark W.; Speer, Richard; George, William A.

    1991-01-01

    The effluent from mercury collected during the photochemical separation of the .sup.196 Hg isotope is often contaminated with particulate mercurous chloride, Hg.sub.2 Cl.sub.2. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg.sub.2 Cl.sub.2 contaminant. The present invention is particularly directed to such filtering.

  10. Apparatus for mercury refinement

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.; George, W.A.

    1991-07-16

    The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

  11. Refining climate models

    SciTech Connect (OSTI)

    Warren, Jeff; Iversen, Colleen; Brooks, Jonathan; Ricciuto, Daniel

    2012-10-31

    Using dogwood trees, Oak Ridge National Laboratory researchers are gaining a better understanding of the role photosynthesis and respiration play in the atmospheric carbon dioxide cycle. Their findings will aid computer modelers in improving the accuracy of climate simulations.

  12. Refining climate models

    ScienceCinema (OSTI)

    Warren, Jeff; Iversen, Colleen; Brooks, Jonathan; Ricciuto, Daniel

    2014-06-26

    Using dogwood trees, Oak Ridge National Laboratory researchers are gaining a better understanding of the role photosynthesis and respiration play in the atmospheric carbon dioxide cycle. Their findings will aid computer modelers in improving the accuracy of climate simulations.

  13. Autonomous Demand Response for Primary Frequency Regulation

    SciTech Connect (OSTI)

    Donnelly, Matt; Trudnowski, Daniel J.; Mattix, S.; Dagle, Jeffery E.

    2012-02-28

    The research documented within this report examines the use of autonomous demand response to provide primary frequency response in an interconnected power grid. The work builds on previous studies in several key areas: it uses a large realistic model (i.e., the interconnection of the western United States and Canada); it establishes a set of metrics that can be used to assess the effectiveness of autonomous demand response; and it independently adjusts various parameters associated with using autonomous demand response to assess effectiveness and to examine possible threats or vulnerabilities associated with the technology.

  14. Refinement of Modeling Techniques for the Structural Evaluation of Hanford Single-Shell Nuclear Waste Storage Tanks

    SciTech Connect (OSTI)

    Karri, Naveen K.; Rinker, Michael W.; Johnson, Kenneth I.; Bapanapalli, Satish K.

    2012-03-01

    Abstract: A total of 149 tanks out of 177 at the Hanford Site (in Washington State, USA) belong to the first generation of underground nuclear waste storage tanks known as single shell tanks (SSTs). These tanks were constructed between 1943 and 1964 and are well beyond their design life. All the SSTs had been removed from active service by November 1980 and have been later interim stabilized by removing the pumpable liquids. The remaining waste in the tanks is in the form of salt cake and sludge awaiting r permanent disposal.. The evaluation of the structural integrity of these tanks is of utmost importance not only for the continued safe storage of the waste until waste retrieval and closure, but also to assure safe retrieval and closure operations. This article discusses the structural analysis approach, modeling challenges and issues encountered during the ongoing analysis of record (AOR) for evaluating the structural integrity of the SSTs. There are several geometrical and material nonlinearities and uncertainties to be dealt with while performing the modern finite element analysis of these tanks. Several studies were conducted to refine the models in order to minimize modeling artifacts introduced by soil arching, boundary effects, concrete cracking, and concrete-soil interface behavior. The analysis takes into account the temperature history of the tanks and allowable mechanical operating loads of these tanks for proper estimation of creep strains and thermal degradation of material properties. The loads imposed in the AOR models also include anticipated loads that these tanks may see during waste retrieval and closure. Due to uncertainty in a number of inputs to the models, sensitivity studies were conducted to address questions related to the boundary conditions to realistically or conservatively represent the influence of surrounding tanks in a tank farm, the influence of backfill excavation slope, the extent of backfill and the total extent of undisturbed soil surrounding the backfill. The article also discusses the criteria and design standards used for evaluating the structural integrity of these underground concrete tanks. Because of the non-availability of complete data on the thermal and operating history for many of the individual tanks, some of the data was assumed or interpolated. However, the models developed for the analysis of record represent the bounding scenarios and include the worst and extreme loading cases that the tanks were subjected to or anticipated. The modeling refinement techniques followed in the AOR resulted in conservative estimates for force and moment demands at various sections in the concrete tanks. The SSTs are classified into 4 types as per their configuration and capacity. This article discusses the modeling aspects related to two types of SSTs that have been analyzed until now. The TOLA results combined with seismic demands from seismic analysis for the analysis of record indicate that the tanks analyzed are structurally stable as per the evaluation criteria established. These results are presented in a separate article. The modeling techniques, methodology and evaluation criteria developed for evaluating the structural integrity of SSTs at Hanford are in general applicable to any similar tanks or underground concrete storage structures.

  15. Refinement of Modeling Techniques for the Structural Evaluation of Hanford Single-Shell Nuclear Waste Storage Tanks

    SciTech Connect (OSTI)

    Karri, Naveen K.; Rinker, Michael W.; Johnson, Kenneth I.; Bapanapalli, Satish K.

    2012-11-10

    ABSTRACT Several tanks at the Hanford Site (in Washington State, USA) belong to the first generation of underground nuclear waste storage tanks known as single shell tanks (SSTs). These tanks were constructed between 1943 and 1964 and are well beyond their design life. This article discusses the structural analysis approach and modeling challenges encountered during the ongoing analysis of record (AOR) for evaluating the structural integrity of the SSTs. There are several geometrical and material nonlinearities and uncertainties to be dealt with while performing the modern finite element analysis of these tanks. The analysis takes into account the temperature history of the tanks and allowable mechanical operating loads of these tanks for proper estimation of creep strains and thermal degradation of material properties. The loads prescribed in the AOR models also include anticipated loads that these tanks may see during waste retrieval and closure. Due to uncertainty in a number of inputs to the models, sensitivity studies were conducted to address questions related to the boundary conditions to realistically or conservatively represent the influence of surrounding tanks in a tank farm, the influence of backfill excavation slope, the extent of backfill and the total extent of undisturbed soil surrounding the backfill. Because of the limited availability of data on the thermal and operating history for many of the individual tanks, some of the data was assumed or interpolated. However, the models developed for the analysis of record represent the bounding scenarios and include the loading conditions that the tanks were subjected to or anticipated. The modeling refinement techniques followed in the AOR resulted in conservative estimates for force and moment demands at various sections in the concrete tanks. This article discusses the modeling aspects related to Type-II and Type-III SSTs. The modeling techniques, methodology and evaluation criteria developed for evaluating the structural integrity of SSTs at Hanford are in general applicable to any similar tanks or underground concrete storage structures.

  16. Chemical coal cleaning process and costs refinement for coal-water slurry manufacture. Semi-annual progress report

    SciTech Connect (OSTI)

    Bhasin, A.K.; Berggren, M.H.; Smit, F.J.; Ames, L.B.; Ronzio, N.J.

    1985-03-01

    The Department of Energy, through the Morgantown Energy Technology Center (METC), has initiated a program to determine the feasibility and potential applications for direct firing of coal and coal-derived fuels in heat engines, specifically gas turbines and diesel engines. AMAX Extractive Research and Development, Inc. supplied METC with two lots of highly beneficiated coal slurry fuel for use in the Heat Engines programs. One of the lots was of ultra-clean coal-water slurry fuel (UCCSF) for which a two-stage caustic and acid leaching procedure was developed to chemically clean the coal. As a part of the contract, AMAX R and D developed a conceptual design and preliminary cost estimate for a commercial-scale process for UCCSF manufacture. The contract was extended to include the following objectives: define chemical cleaning and slurry preparation process conditions and costs more precisely; investigate methods to reduce the product cost; and determine the relationship, in dollars per million Btu, between product cost and fuel quality. Laboratory investigations have been carried out to define the chemical cleaning process conditions required to generate fuels containing from 0.17 to 1.0% ash. Capital and operating cost refinements are to be performed on the basis of the preferred process operating conditions identified during the laboratory investigations. Several such areas for cost reductions have been identified. Caustic strengths from 2 to 7% NaOH are currently anticipated while 25% NaOH was used as the basis for the preliminary cost estimate. In addition, leaching times for each of the process steps have been reduced to half or less of the times used for the preliminary cost estimate. Improvement of fuel quality has been achieved by use of a proprietary hot-water leaching step to reduce the residual alkali content to less than 250 ppM (Na/sub 2/O plus K/sub 2/O) on a dry coal basis. 2 refs., 3 figs., 24 tabs.

  17. Evaluation of heavy oil upgrading/refining process designs for HRI Dynacracking and UOP Aurabon Process. Final report

    SciTech Connect (OSTI)

    Davis, H.; Adams, D.G.; Fox, J.V.

    1984-04-01

    The process designs examined consist of two non-commercialized heavy oil upgrading processes; namely, the Hydrocarbon Research, Inc. (HRI) Dynacracking Process and the UOP Process Division (UOP) Aurabon Process. The latter process design includes, besides the Aurabon Process, an integrated hydrotreating section which does have commercial stature. The Dynacracking Process designs cover six cases involving three heavy crude feedstocks. The Aurabon Complex designs are based on four cases, two for each of two heavy crude feedstocks. The engineering support services involved engineering review and assessment of data, drawings, reports and other information generated by the two process designers. Background information, the review and assessment methodology employed for evaluating the process designs, and a detailed discussion of the process design data generated by both process contractors are presented in this report. Significant findings for both processes may be summarized as follows: (1) The process designs were executed using sound engineering principles and practices; (2) Both processes may be deemed to perform in accordance with their process design; (3) a wide variety of heavy oil charge stocks can be upgraded by either process to products generally suitable for further refinery processing; (4) no insurmountable operating or environmental problems are anticipated; (5) the estimated capital investments and operating utility requirements are indicative of the increased cost to process contaminated heavy crudes; (6) the cost differential between the higher quantity lighter crudes and the poorer quality heavy crudes must be sufficient to justify these higher expenditures; and (7) both processes merit consideration by refiners contemplating contaminated heavy oil upgrading. 53 references, 40 tables.

  18. A recombination outside the BB deletion refines the location of the X-linked retinitis pigmentosa locus RP3

    SciTech Connect (OSTI)

    Fujita, R.; Bingham, E.; Forsythe, P.; McHenry, C.

    1996-07-01

    Genetic loci for X-linked retinitis pigmentosa (XLRP) have been mapped between Xp11.22 and Xp22.13 (RP2, RP3, RP6, and RP15). The RP3 gene, which is responsible for the predominant form of XLRP in most Caucasian populations, has been localized to Xp21.1 by linkage analysis and the map positions of chromosomal deletions associated with the disease. Previous linkage studies have suggested that RP3 is flanked by the markers DXS1110 (distal) and OTC (proximal). Patient BB was though to have RP because of a lesion at the RP3 locus, in addition to chronic granulomatous disease, Duchenne muscular dystrophy (DMD), mild mental retardation, and the McLeod phenotype. This patient carried a deletion extending {approximately}3 Mb from DMD in Xp21.3 to Xp21.1, with the proximal breakpoint located {approximately}40 kb centromeric to DXS1110. The RP3 gene, therefore, is believed to reside between DXS1110 and the proximal breakpoint of the BB deletion. In order to refine the location of RP3 and to ascertain patients with RP3, we have been analyzing several XLRP families for linkage to Xp markers. Linkage analysis in an American family of 27 individuals demonstrates segregation of XLRP with markers in Xp21.1, consistent with the RP3 subtype. One affected male shows a recombination event proximal to DXS1110. Additional markers within the DXS1110-OTC interval show that the crossover is between two novel polymorphic markers, DXS8349 and M6, both of which are present in BB DNA and lie centromeric to the proximal breakpoint. This recombination places the XLRP mutation in this family outside the BB deletion and redefines the location of RP3. 22 refs., 3 figs., 2 tabs.

  19. Decontamination of metals by melt refining/slagging. An annotated bibliography: Update on stainless steel and steel

    SciTech Connect (OSTI)

    Worchester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.; Mizia, R.E.

    1995-01-01

    The following presentation is an update to a previous annotation, i.e., WINCO-1138. The literature search and annotated review covers all metals used in the nuclear industries but the emphasis of this update is directed toward work performed on mild steels. As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult, the problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste problems, Lockheed Idaho Technologies Co (LITCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technology for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small wide melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of large scale melting demonstrations (100--2,000 lbs) to be conducted at selected facilities. The program will support recycling and decontaminating stainless steel RSM for use in waste canisters for Idaho Waste Immobilization Facility densified high level waste and Pit 9/RWMC boxes. This report is the result of the literature search conducted to establish a basis for experimental melt/slag program development. The program plan will be jointly developed by Montana Tech and LITCO.

  20. Alumina-based ceramic composite

    DOE Patents [OSTI]

    Alexander, K.B.; Tiegs, T.N.; Becher, P.F.; Waters, S.B.

    1996-07-23

    An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite. 5 figs.

  1. Alumina-based ceramic composite

    DOE Patents [OSTI]

    Alexander, Kathleen B.; Tiegs, Terry N.; Becher, Paul F.; Waters, Shirley B.

    1996-01-01

    An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite.

  2. Ion source with improved primary arc collimation

    DOE Patents [OSTI]

    Dagenhart, William K.

    1985-01-01

    An improved negative ion source is provided in which a self-biasing, molybdenum collimator is used to define the primary electron stream arc discharge from a filament operated at a negative potential. The collimator is located between the anode and the filament. It is electrically connected to the anode by means of an appropriate size resistor such that the collimator is biased at essentially the filament voltage during operation. Initially, the full arc voltage appears across the filament to collimator until the arc discharge strikes. Then the collimator biases itself to essentially filament potential due to current flow through the resistor thus defining the primary electron stream without intercepting any appreciable arc power. The collimator aperture is slightly smaller than the anode aperture to shield the anode from the arc power, thereby preventing the exposure of the anode to the full arc power which, in the past, has caused overheating and erosion of the anode collimator during extended time pulsed-beam operation of the source. With the self-biasing collimator of this invention, the ion source may be operated from short pulse periods to steady-state without destroying the anode.

  3. Ion source with improved primary arc collimation

    DOE Patents [OSTI]

    Dagenhart, W.K.

    1983-12-16

    An improved negative ion source is provided in which a self-biasing, molybdenum collimator is used to define the primary electron stream arc discharge from a filament operated at a negative potential. The collimator is located between the anode and the filament. It is electrically connected to the anode by means of an appropriate size resistor such that the collimator is biased at essentially the filament voltage during operation. Initially, the full arc voltage appears across the filament to collimator until the arc discharge strikes. Then the collimator biases itself to essentially filament potential due to current flow through the resistor thus defining the primary electron stream without intercepting any appreciable arc power. The collimator aperture is slightly smaller than the anode aperture to shield the anode from the arc power which, in the past, has caused overheating and erosion of the anode collimator during extended time pulsed-beam operation of the source. With the self-biasing collimator of this invention, the ion source may be operated from short pulse periods to steady-state without destroying the anode.

  4. Table A3. Total First Use (formerly Primary Consumption) of...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... and Ductile Iron Foundries",2,0," * "," * "," * ",31," W "," W ",29.3 3331," Primary Copper"," * ",0,0,0," W ",0,0," W ",1.1 3334," Primary Aluminum",40,0,0,0," W ",8," W "," W ...

  5. Non Invasive estimation of aluminum concentration in Hall-Heroult reduction cells

    SciTech Connect (OSTI)

    David Bell

    2004-03-01

    The present best practice for the preparation of primary aluminum is by electrolysis of alumina in the traditional Hall-Heroult reduction cell. The process conditions in the electrolyte of this cell required for the reduction to proceed are sufficiently harsh to have precluded the implementation of in situ sensing of the electrolyte composition, specifically the concentration of the ionized alumina. This report reveals the theoretical basis for a non-invasive method for estimation of the ionized alumina concentration which does not require the use of any sensor in direct contact with the cell electrolyte. The proposed method can in principle be applied with equal efficacy to the so-called drained cathode cell designs and to cells having any anode composition, because only knowledge of the electrolyte conduction behavior is required a priori. For an operating cell, the proposed method requires only readily available electrical measurements and the facilities to process the acquired signals. The proposed method rests on the ability to identify certain characteristics of the transients in the reduction cell terminal voltages caused by the quasiperiodic introduction of alumina. It will be shown that these voltage transients manifest measurable properties, in a statistical sense, that should permit estimation of the ionized alumina concentration with a delay of one alumina feed cycle. The next logical step following the present work, consistent with the Aluminum Technology Roadmap [1], is to experimentally verify the predictions made here; no doubt practical refinements to the proposed approach will evolve during the course of experimentation. Successful verification of the proposed estimation method will permit the design of reduction cell control algorithms based directly on the mass balance of alumina in the electrolyte. This report assumes that the reader understands certain basic concepts important to the operation of electrolytic cells, and the Hall-Heroult cell in particular. References [2,3] provide such concepts in a manner accessible to the technically educated reader; reference [6] is a more thorough treatment.

  6. Simultaneous use of solution NMR and X-ray data in REFMAC5 for joint refinement/detection of structural differences

    SciTech Connect (OSTI)

    Rinaldelli, Mauro; Ravera, Enrico; Calderone, Vito; Parigi, Giacomo; Murshudov, Garib N.; Luchinat, Claudio

    2014-04-01

    Paramagnetic NMR data (pseudocontact shifts and self-orientation residual dipolar couplings) and diamagnetic residual dipolar couplings can now be used in the program REFMAC5 from CCP4 as structural restraints together with X-ray crystallographic data. These NMR restraints can reveal differences between solid state and solution conformations of molecules or, in their absence, can be used together with X-ray crystallographic data for structural refinement. The program REFMAC5 from CCP4 was modified to allow the simultaneous use of X-ray crystallographic data and paramagnetic NMR data (pseudocontact shifts and self-orientation residual dipolar couplings) and/or diamagnetic residual dipolar couplings. Incorporation of these long-range NMR restraints in REFMAC5 can reveal differences between solid-state and solution conformations of molecules or, in their absence, can be used together with X-ray crystallographic data for structural refinement. Since NMR and X-ray data are complementary, when a single structure is consistent with both sets of data and still maintains reasonably ideal geometries, the reliability of the derived atomic model is expected to increase. The program was tested on five different proteins: the catalytic domain of matrix metalloproteinase 1, GB3, ubiquitin, free calmodulin and calmodulin complexed with a peptide. In some cases the joint refinement produced a single model consistent with both sets of observations, while in other cases it indicated, outside the experimental uncertainty, the presence of different protein conformations in solution and in the solid state.

  7. Secondary emission electron gun using external primaries

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni (Shoreham, NY); Ben-Zvi, Ilan (Setauket, NY)

    2009-10-13

    An electron gun for generating an electron beam is provided, which includes a secondary emitter. The secondary emitter includes a non-contaminating negative-electron-affinity (NEA) material and emitting surface. The gun includes an accelerating region which accelerates the secondaries from the emitting surface. The secondaries are emitted in response to a primary beam generated external to the accelerating region. The accelerating region may include a superconducting radio frequency (RF) cavity, and the gun may be operated in a continuous wave (CW) mode. The secondary emitter includes hydrogenated diamond. A uniform electrically conductive layer is superposed on the emitter to replenish the extracted current, preventing charging of the emitter. An encapsulated secondary emission enhanced cathode device, useful in a superconducting RF cavity, includes a housing for maintaining vacuum, a cathode, e.g., a photocathode, and the non-contaminating NEA secondary emitter with the uniform electrically conductive layer superposed thereon.

  8. Secondary emission electron gun using external primaries

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni (Shoreham, NY); Ben-Zvi, Ilan (Setauket, NY); Kewisch, Jorg (Wading River, NY); Chang, Xiangyun (Middle Island, NY)

    2007-06-05

    An electron gun for generating an electron beam is provided, which includes a secondary emitter. The secondary emitter includes a non-contaminating negative-electron-affinity (NEA) material and emitting surface. The gun includes an accelerating region which accelerates the secondaries from the emitting surface. The secondaries are emitted in response to a primary beam generated external to the accelerating region. The accelerating region may include a superconducting radio frequency (RF) cavity, and the gun may be operated in a continuous wave (CW) mode. The secondary emitter includes hydrogenated diamond. A uniform electrically conductive layer is superposed on the emitter to replenish the extracted current, preventing charging of the emitter. An encapsulated secondary emission enhanced cathode device, useful in a superconducting RF cavity, includes a housing for maintaining vacuum, a cathode, e.g., a photocathode, and the non-contaminating NEA secondary emitter with the uniform electrically conductive layer superposed thereon.

  9. Combustor with two stage primary fuel assembly

    DOE Patents [OSTI]

    Sharifi, Mehran; Zolyomi, Wendel; Whidden, Graydon Lane

    2000-01-01

    A combustor for a gas turbine having first and second passages for pre-mixing primary fuel and air supplied to a primary combustion zone. The flow of fuel to the first and second pre-mixing passages is separately regulated using a single annular fuel distribution ring having first and second row of fuel discharge ports. The interior portion of the fuel distribution ring is divided by a baffle into first and second fuel distribution manifolds and is located upstream of the inlets to the two pre-mixing passages. The annular fuel distribution ring is supplied with fuel by an annular fuel supply manifold, the interior portion of which is divided by a baffle into first and second fuel supply manifolds. A first flow of fuel is regulated by a first control valve and directed to the first fuel supply manifold, from which the fuel is distributed to first fuel supply tubes that direct it to the first fuel distribution manifold. From the first fuel distribution manifold, the first flow of fuel is distributed to the first row of fuel discharge ports, which direct it into the first pre-mixing passage. A second flow of fuel is regulated by a second control valve and directed to the second fuel supply manifold, from which the fuel is distributed to second fuel supply tubes that direct it to the second fuel distribution manifold. From the second fuel distribution manifold, the second flow of fuel is distributed to the second row of fuel discharge ports, which direct it into the second pre-mixing passage.

  10. Refinement of Modeling Techniques for the Structural Evaluation of Hanford Single-Shell Nuclear Waste Storage Tanks - 12288

    SciTech Connect (OSTI)

    Karri, Naveen K.; Rinker, Michael W.; Johnson, Kenneth I.; Bapanapalli, Satish K.

    2012-07-01

    The single-shell tanks at the Hanford Site (in Washington State, USA) were constructed between 1943 and 1964 and are well beyond their estimated 25 year design life. This article discusses the structural analysis approach and modeling challenges encountered during the ongoing analysis of record for evaluating the structural integrity of the single-shell tanks. There are several geometrical and material nonlinearities and uncertainties to be dealt with while performing the modern finite element analysis of these tanks. The analysis takes into account the temperature history of the tanks and allowable mechanical operating loads for proper estimation of creep strains and thermal degradation of material properties. The loads prescribed in the analysis of record models also include anticipated loads that may occur during waste retrieval and closure. Due to uncertainty in a number of modeling details, sensitivity studies were conducted to address questions related to boundary conditions that realistically or conservatively represent the influence of surrounding tanks in a tank farm, the influence of backfill excavation slope, the extent of backfill and the total extent of undisturbed soil surrounding the backfill. Because of the limited availability of data on the thermal and operating history for many of the individual tanks, some of the data was assumed or interpolated. However, the models developed for the analysis of record represent the bounding scenarios and include the loading conditions that the tanks were subjected to or anticipated. The modeling refinement techniques followed in the analysis of record resulted in conservative estimates for force and moment demands at various sections in the concrete tanks. This article discusses the modeling aspects related to Type-II and Type-III single-shell tanks. The modeling techniques, methodology and evaluation criteria developed for evaluating the structural integrity of single-shell tanks at Hanford are in general applicable to other similar tanks or underground concrete storage structures. This article presented the details of the finite element models and analysis approach followed during the ongoing effort to establish structural integrity of single shell tanks at the Hanford site. The details of the material constitutive models applicable to the underground Hanford concrete tanks that capture the thermal and creep induce degradation are also presented. The thermal profiles were developed based on the available tank temperature data for the Type II and Type III single-shell tanks, and they were chosen to yield conservative demands under the thermal and operating loads analysis of these tanks. Sensitivity studies were conducted to address two issues regarding the soils modeled around the single-shell tanks. The results indicate that excluding the boundary separating the backfill soil from the undisturbed soil will result in conservative demands (plots 14b and 14c green lines for circumferential Demand/Capacity ratios). The radial extent study indicated that the soil model extending to 240 ft gave more conservative results than the model with 62 ft of soil (plots 17a and 17c magenta lines for hoop Demand/Capacity ratios). Based on these results, a 240 ft far-field soil boundary with backfill throughout the lateral extent was recommended and used for the finite element models used in the Type-II and Type-III analyses of record. The modeling effort and sensitivity studies discussed in this article helped in developing bounding models for the structural integrity evaluation of single shell tanks at the Hanford site. (authors)

  11. Chromosome abnormalities in primary ovarian cancer

    SciTech Connect (OSTI)

    Yonescu, R.; Currie, J.; Griffin, C.A.

    1994-09-01

    Chromosome abnormalities that are specific and recurrent may occur in regions of the genome that are involved in the conversion of normal cells to those with tumorigenic potential. Ovarian cancer is the primary cause of death among patients with gynecological malignancies. We have performed cytogenetic analysis of 16 ovarian tumors from women age 28-82. Three tumors of low malignant potential and three granulosa cell tumors had normal karyotypes. To look for the presence of trisomy 12, which has been suggested to be a common aberration in this group of tumors, interphase fluorescence in situ hybridization was performed on direct preparations from three of these tumors using a probe for alpha satellite sequences of chromosome 12. In the 3 preparations, 92-98 percent of the cells contained two copies of chromosome 12, indicating that trisomy 12 is not a universal finding in low grade ovarian tumors. Endometrioid carcinoma of the ovary is histologically indistinguishable from endometial carcinoma of the uterus. We studied 10 endometrioid tumors to determine the degree of genetic similarity between these two carcinomas. Six out of ten endometrioid tumors showed a near-triploid modal number, and one presented with a tetraploid modal number. Eight of the ten contained structural chromosome abnormalities, of which the most frequent were 1p- (5 tumors), 19q+ (3 tumors), 6q- or ins(6) (4 tumors), 3q- or 3q+ (4 tumors). These cytogenetic results resemble those reported for papillary ovarian tumors and differ from those of endometrial carcinoma of the uterus. We conclude that despite the histologic similarities between the endometrioid and endometrial carcinomas, the genetic abnormalities in the genesis of these tumors differ significantly.

  12. Dependence of Achievable Plan Quality on Treatment Technique and Planning Goal Refinement: A Head-and-Neck Intensity Modulated Radiation Therapy Application

    SciTech Connect (OSTI)

    Qi, X. Sharon Ruan, Dan; Lee, Steve P.; Pham, Andrew; Kupelian, Patrick; Low, Daniel A.; Steinberg, Michael; Demarco, John

    2015-03-15

    Purpose: To develop a practical workflow for retrospectively analyzing target and normal tissue dose–volume endpoints for various intensity modulated radiation therapy (IMRT) delivery techniques; to develop technique-specific planning goals to improve plan consistency and quality when feasible. Methods and Materials: A total of 165 consecutive head-and-neck patients from our patient registry were selected and retrospectively analyzed. All IMRT plans were generated using the same dose–volume guidelines for TomoTherapy (Tomo, Accuray), TrueBeam (TB, Varian) using fixed-field IMRT (TB-IMRT) or RAPIDARC (TB-RAPIDARC), or Siemens Oncor (Siemens-IMRT, Siemens). A MATLAB-based dose–volume extraction and analysis tool was developed to export dosimetric endpoints for each patient. With a fair stratification of patient cohort, the variation of achieved dosimetric endpoints was analyzed among different treatment techniques. Upon identification of statistically significant variations, technique-specific planning goals were derived from dynamically accumulated institutional data. Results: Retrospective analysis showed that although all techniques yielded comparable target coverage, the doses to the critical structures differed. The maximum cord doses were 34.1 ± 2.6, 42.7 ± 2.1, 43.3 ± 2.0, and 45.1 ± 1.6 Gy for Tomo, TB-IMRT, TB-RAPIDARC, and Siemens-IMRT plans, respectively. Analyses of variance showed significant differences for the maximum cord doses but no significant differences for other selected structures among the investigated IMRT delivery techniques. Subsequently, a refined technique-specific dose–volume guideline for maximum cord dose was derived at a confidence level of 95%. The dosimetric plans that failed the refined technique-specific planning goals were reoptimized according to the refined constraints. We observed better cord sparing with minimal variations for the target coverage and other organ at risk sparing for the Tomo cases, and higher parotid doses for C-arm linear accelerator–based IMRT and RAPIDARC plans. Conclusion: Patient registry–based processes allowed easy and systematic dosimetric assessment of treatment plan quality and consistency. Our analysis revealed the dependence of certain dosimetric endpoints on the treatment techniques. Technique-specific refinement of planning goals may lead to improvement in plan consistency and plan quality.

  13. Fast computational methods for predicting protein structure from primary

    Office of Scientific and Technical Information (OSTI)

    amino acid sequence (Patent) | DOEPatents Data Explorer Search Results Fast computational methods for predicting protein structure from primary amino acid sequence Title: Fast computational methods for predicting protein structure from primary amino acid sequence The present invention provides a method utilizing primary amino acid sequence of a protein, energy minimization, molecular dynamics and protein vibrational modes to predict three-dimensional structure of a protein. The present

  14. Fast computational methods for predicting protein structure from primary

    Office of Scientific and Technical Information (OSTI)

    amino acid sequence (Patent) | DOEPatents Fast computational methods for predicting protein structure from primary amino acid sequence Title: Fast computational methods for predicting protein structure from primary amino acid sequence The present invention provides a method utilizing primary amino acid sequence of a protein, energy minimization, molecular dynamics and protein vibrational modes to predict three-dimensional structure of a protein. The present invention also determines possible

  15. Feeding Arteries of Primary Tongue Cancers on Intra-arterial...

    Office of Scientific and Technical Information (OSTI)

    on Intra-arterial Infusion Chemotherapy Citation Details In-Document Search Title: Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy PurposeTo ...

  16. Light Absorption of Primary Organic Aerosol Paper Named ACS Editors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absorption of Primary Organic Aerosol Paper Named ACS Editors' Choice For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights...

  17. Texas Large Construction Site Notice for Primary Operators |...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Reference: Texas Large Construction Site Notice for Primary Operators Published Texas Commission on Environmental...

  18. "Table 2. Real Average Annual Coal Transportation Costs, By Primary...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Annual Coal Transportation Costs, By Primary Transport Mode and Supply Region" "(2013 dollars per ton)" "Coal Supply Region",2008,2009,2010,2011,2012,2013 "Railroad"...

  19. Estimation of net primary productivity using a process-based...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Estimation of net primary productivity using a process-based model in Gansu Province, Northwest China Citation Details In-Document Search Title: Estimation of net ...

  20. Primary Science of Energy Teacher and Student Guides (42 Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Teacher and Student Guides (42 Activities) Primary Science of Energy Teacher and Student Guides (42 Activities) Below is information about the student activitylesson plan from...

  1. Lithium Ethylene Dicarbonate Identified as the Primary Product...

    Office of Scientific and Technical Information (OSTI)

    Lithium Ethylene Dicarbonate Identified as the Primary Product ofChemical and Electrochemical Reduction of EC in EC:EMC1.2M LiPF6Electrolyte Citation Details In-Document Search ...

  2. Is Primary Prostate Cancer Treatment Influenced by Likelihood of

    Office of Scientific and Technical Information (OSTI)

    Extraprostatic Disease? A Surveillance, Epidemiology and End Results Patterns of Care Study (Journal Article) | SciTech Connect Is Primary Prostate Cancer Treatment Influenced by Likelihood of Extraprostatic Disease? A Surveillance, Epidemiology and End Results Patterns of Care Study Citation Details In-Document Search Title: Is Primary Prostate Cancer Treatment Influenced by Likelihood of Extraprostatic Disease? A Surveillance, Epidemiology and End Results Patterns of Care Study Purpose: To

  3. S. 42: A Bill to amend the Internal Revenue Code of 1986 to impose a fee on the importation of crude oil and refined petroleum products. Introduced in the Senate of the United States, One Hundredth First Congress, First Session, January 25, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    S. 42 is a bill to amend the Internal Revenue Code of 1986 to impose a fee on the importation of crude oil and refined petroleum products.

  4. PETRO-SAFE '91 conference papers: Volume 3 (Drilling and production environment and safety), Volume 4 (Transportation and storage environment and safety) and Volume 5 (Processing and refining environment and safety)

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This conference provided a forum for the oil, gas, and petrochemical industries to discuss state of the art knowledge in those fields. The following topics were addressed: drilling and production environment and safety; transportation and storage environment and safety; and processing and refining environment and safety. Separate papers are processed for inclusion in the appropriate data bases.

  5. Fracture mechanics evaluation for at typical PWR primary coolant pipe

    SciTech Connect (OSTI)

    Tanaka, T.; Shimizu, S.; Ogata, Y.

    1997-04-01

    For the primary coolant piping of PWRs in Japan, cast duplex stainless steel which is excellent in terms of strength, corrosion resistance, and weldability has conventionally been used. The cast duplex stainless steel contains the ferrite phase in the austenite matrix and thermal aging after long term service is known to change its material characteristics. It is considered appropriate to apply the methodology of elastic plastic fracture mechanics for an evaluation of the integrity of the primary coolant piping after thermal aging. Therefore we evaluated the integrity of the primary coolant piping for an initial PWR plant in Japan by means of elastic plastic fracture mechanics. The evaluation results show that the crack will not grow into an unstable fracture and the integrity of the piping will be secured, even when such through wall crack length is assumed to equal the fatigue crack growth length for a service period of up to 60 years.

  6. Design study of primary ion provider for RHIC-EBIS

    SciTech Connect (OSTI)

    Kondo, K.; Kanesue, T.; Tamura, J.; Okamura, M.

    2009-09-20

    Brookhaven National Laboratory (BNL) has developed the new pre-injector system, Electron Beam Ion Source (EBIS) for Relativistic Heavy Ion Collider (RHIC) and NASA Space Radiation Laboratory (NSRL). Design of primary ion provider is an essential problem since it is required to supply beams with different ion species to multiple users simultaneously. The laser ion source with a defocused laser can provide a low charge state and low emittance ion beam, and is a candidate for the primary ion source for RHIC-EBIS. We show a suitable design with appropriate drift length and solenoid, which helps to keep sufficient total charge number with longer pulse length. The whole design of primary ion source, as well as optics arrangement, solid targets configuration and heating about target, is presented.

  7. Safety and performance enhancement circuit for primary explosive detonators

    DOE Patents [OSTI]

    Davis, Ronald W.

    2006-04-04

    A safety and performance enhancement arrangement for primary explosive detonators. This arrangement involves a circuit containing an energy storage capacitor and preset self-trigger to protect the primary explosive detonator from electrostatic discharge (ESD). The circuit does not discharge into the detonator until a sufficient level of charge is acquired on the capacitor. The circuit parameters are designed so that normal ESD environments cannot charge the protection circuit to a level to achieve discharge. When functioned, the performance of the detonator is also improved because of the close coupling of the stored energy.

  8. Primary Cilium-Dependent and -Independent Hedgehog Signaling Inhibits

    Office of Scientific and Technical Information (OSTI)

    p16INK4A (Journal Article) | SciTech Connect Journal Article: Primary Cilium-Dependent and -Independent Hedgehog Signaling Inhibits p16INK4A Citation Details In-Document Search Title: Primary Cilium-Dependent and -Independent Hedgehog Signaling Inhibits p16INK4A Authors: Bishop, Cleo L. ; Bergin, Ann-Marie H. ; Fessart, Delphine ; Borgdorff, Viola ; Hatzimasoura, Elizabeth ; Garbe, James C. ; Stampfer, Martha R. ; Koh, Jim ; Beach, David H. Publication Date: 2010-11-01 OSTI Identifier:

  9. Refinement of the experimental dynamic structure factor for liquid para-hydrogen and ortho-deuterium using semi-classical quantum simulation

    SciTech Connect (OSTI)

    Smith, Kyle K. G. Rossky, Peter J.; Poulsen, Jens Aage; Cunsolo, A.

    2014-01-21

    The dynamic structure factor of liquid para-hydrogen and ortho-deuterium in corresponding thermodynamic states (T = 20.0?K, n = 21.24?nm{sup ?3}) and (T = 23.0?K, n = 24.61?nm{sup ?3}), respectively, has been computed by both the Feynman-Kleinert linearized path-integral (FK-LPI) and Ring-Polymer Molecular Dynamics (RPMD) methods and compared with Inelastic X Ray Scattering spectra. The combined use of computational and experimental methods enabled us to reduce experimental uncertainties in the determination of the true sample spectrum. Furthermore, the refined experimental spectrum of para-hydrogen and ortho-deuterium is consistently reproduced by both FK-LPI and RPMD results at momentum transfers lower than 12.8?nm{sup ?1}. At larger momentum transfers the FK-LPI results agree with experiment much better for ortho-deuterium than for para-hydrogen. More specifically we found that for k ? 20.0 nm{sup ?1} para-hydrogen provides a test case for improved approximations to quantum dynamics.

  10. Synthesis, structure refinement at 296 K and physico-chemical characterizations of KMnHP{sub 3}O{sub 10}

    SciTech Connect (OSTI)

    Mechergui, J.; Belam, W.

    2008-12-01

    Potassium manganese(III) monohydrogentriphosphate KMnHP{sub 3}O{sub 10} was synthesized by flux method and characterized by single-crystal X-ray diffraction, crystallizes in the monoclinic system with centric space group C2/c. The parameters of the unit cell are a = 12.104(1), b = 8.287(1). c = 9.150(1) A, {beta} = 110.97(1) deg. and Z = 4. The structure was solved at 296 K using 893 independent reflections and refined until R(F) = 0.022; wR(F{sup 2}) = 0.045. The atomic arrangement of the title compound consists of MnO{sub 6} octahedra linked by hydrogentriphosphate anions to form a three-dimensional framework containing tunnels parallel to the c-axis where the K{sup +} cations are inserted. The structure of KMnHP{sub 3}O{sub 10} contains a single Mn site which is surrounded by typical Jahn-Teller [2 + 2 + 2] distorted octahedron. The title material has been also characterized by different physico-chemical techniques: powder X-ray diffraction, IR, NMR and CI spectroscopies and DTA-TGA-DSC thermal analysis.

  11. NIF Functional Requirements and Primary Criteria Rev. 1.8 September...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: NIF Functional Requirements and Primary Criteria Rev. 1.8 September 2006 Citation Details In-Document Search Title: NIF Functional Requirements and Primary ...

  12. Crack stability analysis of low alloy steel primary coolant pipe

    SciTech Connect (OSTI)

    Tanaka, T.; Kameyama, M.; Urabe, Y.

    1997-04-01

    At present, cast duplex stainless steel has been used for the primary coolant piping of PWRs in Japan and joints of dissimilar material have been applied for welding to reactor vessels and steam generators. For the primary coolant piping of the next APWR plants, application of low alloy steel that results in designing main loops with the same material is being studied. It means that there is no need to weld low alloy steel with stainless steel and that makes it possible to reduce the welding length. Attenuation of Ultra Sonic Wave Intensity is lower for low alloy steel than for stainless steel and they have advantageous inspection characteristics. In addition to that, the thermal expansion rate is smaller for low alloy steel than for stainless steel. In consideration of the above features of low alloy steel, the overall reliability of primary coolant piping is expected to be improved. Therefore, for the evaluation of crack stability of low alloy steel piping to be applied for primary loops, elastic-plastic future mechanics analysis was performed by means of a three-dimensioned FEM. The evaluation results for the low alloy steel pipings show that cracks will not grow into unstable fractures under maximum design load conditions, even when such a circumferential crack is assumed to be 6 times the size of the wall thickness.

  13. Table 9. Net electricity trade index and primary electricity...

    U.S. Energy Information Administration (EIA) Indexed Site

    2,2003,2004,2005,2006,2007,2008,2009,2010,,"Primary " ,,,2011,"Source" ,"Least CO2 per capita" ," New York",0.94,1,0.95,0.92,0.87,0.93,1.01,0.99,0.99,0.95,0.93,1,"Natural...

  14. Carbon Emissions: Petroleum Refining Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Contact: Stephanie Battles Stephanie.Battles@eia.doe.gov (Phone: (202) 586-7237) FAX: 202-586-0018 Contact Us URL: http:www.eia.govemeuefficiencycarbonemissionspetroleum...

  15. Electronic structure of superconductivity refined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    667-7000 LOS ALAMOS, New Mexico, July 10, 2008- A team of physicists, including Neil Harrison and Charles Mielke from Los Alamos National Laboratory, propose a new model that...

  16. Cleaning Cesium Radionuclides from BN-350 Primary Sodium

    SciTech Connect (OSTI)

    Romanenko, O.G.; Allen, K.J.; Wachs, D.M.; Planchon, H.P.; Wells, P.B.; Michelbacher, J.A.; Nazarenko, P.; Dumchev, I.; Maev, V.; Zemtzev, B.; Tikhomirov, L.; Yakovlev, V.; Synkov, A

    2005-04-15

    This paper reports the successful design and operation of a system to remove highly radioactive cesium from the sodium coolant of the BN-350 reactor in Aktau, Kazakhstan. As an international effort between the United States and the Republic of Kazakhstan, a cesium-trapping system was jointly designed, fabricated, installed, and successfully operated. The results are significant for a number of reasons, including (a) a significant reduction of radioactivity levels of the BN-350 coolant and reactor surfaces, thereby reducing exposure to workers during shutdown operations; (b) demonstration of scientific ideas; and (c) the engineering application of effective cesium trap deployment for commercial-sized liquid-metal reactors. About 255 300 GBq (6900 Ci) of cesium was trapped, and the {sup 137}Cs specific activity in BN-350 primary sodium was decreased from 296 MBq/kg (8000 {mu}Ci/kg) to 0.37 MBq/kg (10 {mu}Ci/kg) by using seven cesium traps containing reticulated vitreous carbon (RVC) as the cesium adsorbent. Cesium trapping was accomplished by pumping sodium from the primary circuit, passing it through a block of RVC within each trap, and returning the cleaned sodium to the primary circuit. Both to predict and to analyze the behavior of the cesium traps in the BN-350 reactor primary circuit, a model was developed that satisfactorily describes the observed results of the cesium trapping. By using this model, thermodynamic parameters, such as the heat of adsorption of cesium atoms on RVC and on internal piping surfaces of the BN-350 reactor primary circuit, -22.7 and -5.0 kJ/mole, respectively, were extracted from the experimental data.

  17. Parametric and kinetic studies on deactivation and regeneration of hydrotreating catalysts in solvent refined coal upgrading process and an evaluation of the liquid vaporization effects on hydrotreater performance

    SciTech Connect (OSTI)

    Nalitham, R.V.

    1983-01-01

    Catalysts used in hydrotreating the solvent refined coal were rapidly deactivated during the initial stages of processing. The major cause of deactivation appears to be the deposition of carbonaceous material on the catalyst. A simulated aging technique involving a series of reactions on the same batch of catalyst and a model compound activity test were developed and used to study the effects of process conditions, feedstock characteristics, catalyst properties, and catalyst pretreatment on initial catalyst deactivation. The variables shown to increase the rate of deactivation are: increased catalyst loading, high reaction temperature, low hydrogen pressure, unsulfiding the catalyst, and high concentrations of preasphaltenes and insoluble organic matter in the feedstock. The loss in catalyst surface area during the aging process was substantial, being as high as 95%. A simple kinetic model, including a first-order catalyst deactivation rate, was applied to upgrading of two-coal derived feedstocks. A catalyst deactivation mechanism was proposed which involves the adsorption and surface reaction of coke precursors on catalytic active sites. Catalyst regeneration of aged catalysts from the LC-Finer and the ITSL process has been accomplished through oxidative treatment followed by presulfiding. A parametric study has been performed to identify the optimum regeneration conditions. The degree of regeneration appears to be dependent on the feed material and reaction history of the catalyst. Liquid vaporization affects the hydrotreater performance significantly. The hydrotreater is simulated to study the effects of the solvent volatility, hydrogen flow rate, feed concentration, temperature, and pressure. A gradientless reactor system was designed, built, and used to verify the key result ofthe simulation study.

  18. HANFORD DST THERMAL & SEISMIC PROJECT ANSYS BENCHMARK ANALYSIS OF SEISMIC INDUCED FLUID STRUCTURE INTERACTION IN A HANFORD DOUBLE SHELL PRIMARY TANK

    SciTech Connect (OSTI)

    MACKEY, T.C.

    2006-03-14

    M&D Professional Services, Inc. (M&D) is under subcontract to Pacific Northwest National Laboratories (PNNL) to perform seismic analysis of the Hanford Site Double-Shell Tanks (DSTs) in support of a project entitled ''Double-Shell Tank (DSV Integrity Project-DST Thermal and Seismic Analyses)''. The overall scope of the project is to complete an up-to-date comprehensive analysis of record of the DST System at Hanford in support of Tri-Party Agreement Milestone M-48-14. The work described herein was performed in support of the seismic analysis of the DSTs. The thermal and operating loads analysis of the DSTs is documented in Rinker et al. (2004). The overall seismic analysis of the DSTs is being performed with the general-purpose finite element code ANSYS. The overall model used for the seismic analysis of the DSTs includes the DST structure, the contained waste, and the surrounding soil. The seismic analysis of the DSTs must address the fluid-structure interaction behavior and sloshing response of the primary tank and contained liquid. ANSYS has demonstrated capabilities for structural analysis, but the capabilities and limitations of ANSYS to perform fluid-structure interaction are less well understood. The purpose of this study is to demonstrate the capabilities and investigate the limitations of ANSYS for performing a fluid-structure interaction analysis of the primary tank and contained waste. To this end, the ANSYS solutions are benchmarked against theoretical solutions appearing in BNL 1995, when such theoretical solutions exist. When theoretical solutions were not available, comparisons were made to theoretical solutions of similar problems and to the results from Dytran simulations. The capabilities and limitations of the finite element code Dytran for performing a fluid-structure interaction analysis of the primary tank and contained waste were explored in a parallel investigation (Abatt 2006). In conjunction with the results of the global ANSYS analysis reported in Carpenter et al. (2006), the results of the two investigations will be compared to help determine if a more refined sub-model of the primary tank is necessary to capture the important fluid-structure interaction effects in the tank and if so, how to best utilize a refined sub-model of the primary tank. Both rigid tank and flexible tank configurations were analyzed with ANSYS. The response parameters of interest are total hydrodynamic reaction forces, impulsive and convective mode frequencies, waste pressures, and slosh heights. To a limited extent: tank stresses are also reported. The results of this study demonstrate that the ANSYS model has the capability to adequately predict global responses such as frequencies and overall reaction forces. Thus, the model is suitable for predicting the global response of the tank and contained waste. On the other hand, while the ANSYS model is capable of adequately predicting waste pressures and primary tank stresses in a large portion of the waste tank, the model does not accurately capture the convective behavior of the waste near the free surface, nor did the model give accurate predictions of slosh heights. Based on the ability of the ANSYS benchmark model to accurately predict frequencies and global reaction forces and on the results presented in Abatt, et al. (2006), the global ANSYS model described in Carpenter et al. (2006) is sufficient for the seismic evaluation of all tank components except for local areas of the primary tank. Due to the limitations of the ANSYS model in predicting the convective response of the waste, the evaluation of primary tank stresses near the waste free surface should be supplemented by results from an ANSYS sub-model of the primary tank that incorporates pressures from theoretical solutions or from Dytran solutions. However, the primary tank is expected to have low demand to capacity ratios in the upper wall. Moreover, due to the less than desired mesh resolution in the primary tank knuckle of the global ANSYS model, the evaluation of the primary tank stresses in the lo

  19. EBR-II Primary Tank Wash-Water Alternatives Evaluation

    SciTech Connect (OSTI)

    Demmer, R. L.; Heintzelman, J. B.; Merservey, R. H.; Squires, L. N.

    2008-05-01

    The EBR-II reactor at Idaho National Laboratory was a liquid sodium metal cooled reactor that operated for 30 years. It was shut down in 1994; the fuel was removed by 1996; and the bulk of sodium metal coolant was removed from the reactor by 2001. Approximately 1100 kg of residual sodium remained in the primary system after draining the bulk sodium. To stabilize the remaining sodium, both the primary and secondary systems were treated with a purge of moist carbon dioxide. Most of the residual sodium reacted with the carbon dioxide and water vapor to form a passivation layer of primarily sodium bicarbonate. The passivation treatment was stopped in 2005 and the primary system is maintained under a blanket of dry carbon dioxide. Approximately 670 kg of sodium metal remains in the primary system in locations that were inaccessible to passivation treatment or in pools of sodium that were too deep for complete penetration of the passivation treatment. The EBR-II reactor was permitted by the Idaho Department of Environmental Quality (DEQ) in 2002 under a RCRA permit that requires removal of all remaining sodium in the primary and secondary systems by 2022. The proposed baseline closure method would remove the large components from the primary tank, fill the primary system with water, react the remaining sodium with the water and dissolve the reaction products in the wash water. This method would generate a minimum of 100,000 gallons of caustic, liquid, low level radioactive, hazardous waste water that must be disposed of in a permitted facility. On February 19-20, 2008, a workshop was held in Idaho Falls, Idaho, to look at alternatives that could meet the RCRA permit clean closure requirements and minimize the quantity of hazardous waste generated by the cleanup process. The workshop convened a panel of national and international sodium cleanup specialists, subject matter experts from the INL, and the EBR-II Wash Water Project team that organized the workshop. The workshop was conducted by a trained facilitator using Value Engineering techniques to elicit the most technically sound solutions from the workshop participants. The path forward includes developing the OBA into a well engineered solution for achieving RCRA clean closure of the EBR-II Primary Reactor Tank system. Several high level tasks are also part of the path forward such as reassigning responsibility of the cleanup project to a dedicated project team that is funded by the DOE Office of Environmental Management, and making it a priority so that adequate funding is available to complete the project. Based on the experience of the sodium cleanup specialists, negotiations with the DEQ will be necessary to determine a risk-based de minimus quantity for acceptable amount of sodium that can be left in the reactor systems after cleanup has been completed.

  20. Mechanical Design of the HER Synchrotron Light Monitor Primary Mirror

    SciTech Connect (OSTI)

    Daly, Edward F.; Fisher, Alan S.; Kurita, Nadine R.; Langton, J.; /SLAC

    2011-09-14

    This paper describes the mechanical design of the primary mirror that images the visible portion of the synchrotron radiation (SR) extracted from the High Energy Ring (HER) of the PEP-II B-Factory. During off-axis operation, the water-cooled GlidCop mirror is subjected to a heat flux in excess of 2000 W/cm2. When on-axis imaging occurs, the heat flux due to scattered SR, resistive wall losses and Higher-Order-Mode (HOM) heating is estimated at 1 W/cm2. The imaging surface is plated with Electroless Nickel to improve its optical characteristics. The design requirements for the primary mirror are listed and discussed. Calculated mechanical distortions and stresses experienced by the mirror during on-axis and off-axis operation will be presented.

  1. DETECTION OF THE COMPRESSED PRIMARY STELLAR WIND IN {eta} CARINAE

    SciTech Connect (OSTI)

    Teodoro, M.; Madura, T. I.; Gull, T. R.; Corcoran, M. F.; Hamaguchi, K.

    2013-08-10

    A series of three Hubble Space Telescope/Space Telescope Imaging Spectrograph spectroscopic mappings, spaced approximately one year apart, reveal three partial arcs in [Fe II] and [Ni II] emissions moving outward from {eta} Carinae. We identify these arcs with the shell-like structures, seen in the three-dimensional hydrodynamical simulations, formed by compression of the primary wind by the secondary wind during periastron passages.

  2. Comparing the Primary Electron Transfer Process in Organic Photovoltaic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterojunctions with Photosynthetic Reaction Centers | MIT-Harvard Center for Excitonics Comparing the Primary Electron Transfer Process in Organic Photovoltaic Heterojunctions with Photosynthetic Reaction Centers October 4, 2011 at 3pm/36-428 Garry Rumbles National Renewable Energy Laboratory (NREL), Univeristy of Colorado, Boulder rumbles002 Abstract: This presentation will focus on some of the fundamental science associated with the rapidly emerging field of organic photovoltaics (OPV).

  3. IMPROVED CORROSION RESISTANCE OF ALUMINA REFRACTORIES

    SciTech Connect (OSTI)

    John P. Hurley; Patty L. Kleven

    2001-09-30

    The initial objective of this project was to do a literature search to define the problems of refractory selection in the metals and glass industries. The problems fall into three categories: Economic--What do the major problems cost the industries financially? Operational--How do the major problems affect production efficiency and impact the environment? and Scientific--What are the chemical and physical mechanisms that cause the problems to occur? This report presents a summary of these problems. It was used to determine the areas in which the EERC can provide the most assistance through bench-scale and laboratory testing. The final objective of this project was to design and build a bench-scale high-temperature controlled atmosphere dynamic corrosion application furnace (CADCAF). The furnace will be used to evaluate refractory test samples in the presence of flowing corrodents for extended periods, to temperatures of 1600 C under controlled atmospheres. Corrodents will include molten slag, steel, and glass. This test should prove useful for the glass and steel industries when faced with the decision of choosing the best refractory for flowing corrodent conditions.

  4. Gelcasting Alumina Cores for Investment Casting

    SciTech Connect (OSTI)

    Janney, M A; Klug, F J

    2001-01-01

    General Electric currently uses silica investment casting cores for making superalloy turbine blades. The silica core technology does not provide the degree of dimensional control needed for advanced turbine system manufacture. The sum of the various process variables in silica core manufacturing produces cores that have more variability than is allowed for in advanced, power-generation gas turbine airfoils.

  5. Optimized Alumina Coagulants for Water Purification - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    purification. By inserting a single gallium atom in the center of an aluminum oxide cluster, the stability and efficacy of the reagent is greatly improved. This stability also...

  6. Subclonal diversification of primary breast cancer revealed by multiregion sequencing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yates, Lucy R.; Gerstung, Moritz; Knappskog, Stian; Desmedt, Christine; Gundem, Gunes; Van Loo, Peter; Aas, Turid; Alexandrov, Ludmil B.; Larsimont, Denis; Davies, Helen; et al

    2015-06-22

    Sequencing cancer genomes may enable tailoring of therapeutics to the underlying biological abnormalities driving a particular patient's tumor. However, sequencing-based strategies rely heavily on representative sampling of tumors. To understand the subclonal structure of primary breast cancer, we applied whole-genome and targeted sequencing to multiple samples from each of 50 patients' tumors (303 samples in total). The extent of subclonal diversification varied among cases and followed spatial patterns. No strict temporal order was evident, with point mutations and rearrangements affecting the most common breast cancer genes, including PIK3CA, TP53, PTEN, BRCA2 and MYC, occurring early in some tumors and latemore » in others. In 13 out of 50 cancers, potentially targetable mutations were subclonal. Landmarks of disease progression, such as resistance to chemotherapy and the acquisition of invasive or metastatic potential, arose within detectable subclones of antecedent lesions. These findings highlight the importance of including analyses of subclonal structure and tumor evolution in clinical trials of primary breast cancer.« less

  7. Radiation effects in the stainless steel primary coolant supply adapter

    SciTech Connect (OSTI)

    Farrell, K.

    1995-09-01

    The primary coolant supply adapter (PCSA) is a flanged, cylindrical collar of 316NG stainless steel that is part of the primary pressure boundary of the Advanced Neutron Source. The radiation fluxes on the PCSA are dominated by thermal neutrons. During its intended 40-year service life, the PCSA will receive a thermal neutron fluence of 1.8 {times} 10{sup 26} m{sup {minus}2} in its upper sections at a temperature of <1OO{degree}C. The PCSA will suffer radiation damage, caused primarily by the interaction of thermal neutrons with the 14% nickel in the steel, which will generate helium by the sequential reactions {sup 58}Ni (n,y){sup 59}Ni (n,{alpha}){sup 56}Fe and will concurrently produce significant atomic displacements per atom (dpa) from the {sup 59}Ni (n,{alpha}){sup 56}Fe recoils. It is estimated that the helium concentration and total atomic displacements in the upper parts of the PCSA will be about 430 atomic parts per million and 1 dpa, respectively. From newly compiled trend curves of tensile properties and fracture toughness data versus atomic displacements for 316 steel, it is deduced that the irradiated PCSA will retain at least 20% uniform tensile elongation and a fracture toughness of more than 200 Mpa{radical}m, which are judged adequate to resist brittle failure. Tberefore, employment of a neutron shield around the PCSA is unnecessary.

  8. Primary side stress corrosion cracking and remedial measures

    SciTech Connect (OSTI)

    Theus, G.J.

    1986-01-01

    Primary side stress corrosion cracking (SCC) of Alloy 600 stream generator tubing in some recirculating pressurized water reactor steam generators has usually occurred in two locations: at the roll transition and expansion locations within the tube-sheets and at the apex and tangent areas of the tight radius U bends. Occasionally, other highly stressed areas have also suffered primary side SCC: at support plate tube intersections where secondary side denting has occurred and at the steam generator tube transition areas of explosively installed mini-sleeves. Laboratory data and operating performances of Alloy 600 tubing indicate that the factors affecting the susceptibility to this type of SSC, in decreasing order of importance, are high stresses, material microstructures, and operating temperatures. Remedial measures to correct these problems in newer plants include changing design and fabrication procedures, thus avoiding highly stressed areas of tubing, and changing tube manufacturing heat treating requirements, thus improving the microstructures. Alternate tube materials, such as Alloy 800, Monel 400, or austenitic stainless steels, have not suffered this type of failure.

  9. Subclonal diversification of primary breast cancer revealed by multiregion sequencing

    SciTech Connect (OSTI)

    Yates, Lucy R.; Gerstung, Moritz; Knappskog, Stian; Desmedt, Christine; Gundem, Gunes; Van Loo, Peter; Aas, Turid; Alexandrov, Ludmil B.; Larsimont, Denis; Davies, Helen; Li, Yilong; Ju, Young Seok; Ramakrishna, Manasa; Haugland, Hans Kristian; Lilleng, Peer Kaare; Nik-Zainal, Serena; McLaren, Stuart; Butler, Adam; Martin, Sancha; Glodzik, Dominic; Menzies, Andrew; Raine, Keiran; Hinton, Jonathan; Jones, David; Mudie, Laura J.; Jiang, Bing; Vincent, Delphine; Greene-Colozzi, April; Adnet, Pierre -Yves; Fatima, Aquila; Maetens, Marion; Ignatiadis, Michail; Stratton, Michael R.; Sotiriou, Christos; Richardson, Andrea L.; Lønning, Per Eystein; Wedge, David C.; Campbell, Peter J.

    2015-06-22

    Sequencing cancer genomes may enable tailoring of therapeutics to the underlying biological abnormalities driving a particular patient's tumor. However, sequencing-based strategies rely heavily on representative sampling of tumors. To understand the subclonal structure of primary breast cancer, we applied whole-genome and targeted sequencing to multiple samples from each of 50 patients' tumors (303 samples in total). The extent of subclonal diversification varied among cases and followed spatial patterns. No strict temporal order was evident, with point mutations and rearrangements affecting the most common breast cancer genes, including PIK3CA, TP53, PTEN, BRCA2 and MYC, occurring early in some tumors and late in others. In 13 out of 50 cancers, potentially targetable mutations were subclonal. Landmarks of disease progression, such as resistance to chemotherapy and the acquisition of invasive or metastatic potential, arose within detectable subclones of antecedent lesions. These findings highlight the importance of including analyses of subclonal structure and tumor evolution in clinical trials of primary breast cancer.

  10. Fact #864: March 16, 2015 Imports of Primary Energy have Declined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: March 16, 2015 Imports of Primary Energy have Declined Sharply Since the Peak Reached in 2007 Fact 864: March 16, 2015 Imports of Primary Energy have Declined Sharply Since the ...

  11. Fact #864: March 16, 2015 Imports of Primary Energy have Declined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact 864: March 16, 2015 Imports of Primary Energy have Declined Sharply Since the Peak Reached in 2007 Excel file and dataset for Imports of Primary Energy have Declined Sharply ...

  12. Primary Water Stress Corrosion Crack Morphology and Nondestructive Evaluation Reliability

    SciTech Connect (OSTI)

    Doctor, Steven R.; Schuster, George J.; Anderson, Michael T.

    2004-12-01

    A research program on primary stress corrosion crack (PWSCC) is being conducted by Pacific Northwest National Laboratory (PNNL). In this program, the material degradation problem in Alloys 600, 182, and 82 is being investigated with objectives that include compling a knowledge base on all cracking in nickel based materials at all degradation sites in nuclear power plants, assessing NDE methods using mockups to quantify the detection, sizing, and using mockups to quantify the detection sizing and characterization of tight cracks, and determining the role of welding processes in degradation. In this paper, the resuts of the initial literature searchs are presented. The relevant data on crack properties such as shape and orientation are presented and their impace on nondestructive evaluation (NDE) reliability is discussed.

  13. BRCA1 mutations in primary breast and ovarian carcinomas

    SciTech Connect (OSTI)

    Futreal, P.A.; Cochran, C.; Bennett, L.M.; Haugen-Strano, A.; Terry, L.; Barrett, J.C.; Wiseman, R.; Liu, Q.; Shattuck-Eidens, D.; Harshman, K.

    1994-10-07

    Loss of heterozygosity data from familial tumors suggested that BRCA1, a gene that confers susceptibility to ovarian and early-onset breast cancer, encodes a tumor suppressor. The BRCA1 region is also subject to allelic loss in sporadic breast and ovarian cancers, an indication that BRCA1 mutations may occur somatically in these tumors. The BRCA1 coding region was examined for mutations in primary breast and ovarian tumors that show allele loss at the BRCA1 locus. Mutations were detected in 3 of 32 breast and 1 of 12 ovarian carcinomas; all four mutations were germline alterations and occurred in early-onset cancers. These results suggest that mutation of BRCA1 may not be critical in the development of the majority of breast and ovarian cancers that arise in the absence of a mutant germline allele.

  14. Mechanistic Selection and Growth of Twinned Bicrystalline Primary Si in Near Eutectic Al-Si Alloys

    SciTech Connect (OSTI)

    Choonho Jung

    2006-12-12

    Morphological evolution and selection of angular primary silicon is investigated in near-eutectic Al-Si alloys. Angular silicon arrays are grown directionally in a Bridgman furnace at velocities in the regime of 10{sup -3} m/sec and with a temperature gradient of 7.5 x 10{sup 3} K/m. Under these conditions, the primary Si phase grows as an array of twinned bicrystalline dendrites, where the twinning gives rise to a characteristic 8-pointed star-shaped primary morphology. While this primary Si remains largely faceted at the growth front, a complex structure of coherent symmetric twin boundaries enables various adjustment mechanisms which operate to optimize the characteristic spacings within the primary array. In the work presented here, this primary silicon growth morphology is examined in detail. In particular, this thesis describes the investigation of: (1) morphological selection of the twinned bicrystalline primary starshape morphology; (2) primary array behavior, including the lateral propagation of the starshape grains and the associated evolution of a strong <100> texture; (3) the detailed structure of the 8-pointed star-shaped primary morphology, including the twin boundary configuration within the central core; (4) the mechanisms of lateral propagation and spacing adjustment during array evolution; and (5) the thermosolutal conditions (i.e. operating state) at the primary growth front, including composition and phase fraction in the vicinity of the primary tip.

  15. Batteries called primary source of lead, cadmium in municipal waste

    SciTech Connect (OSTI)

    Not Available

    1989-04-01

    The US Environmental Protection Agency reports that lead-acid batteries, such as those used in automobiles, and rechargeable nickel-cadmium batteries used in consumer electronics equipment, are the primary sources of lead and cadmium in municipal trash and garbage. A report prepared for EPA analyzed existing data from 1970 to 1986 and made projections to the year 2000. Lead-acid batteries continue to constitute a major source of lead in garbage even though 80 percent of them are now recycled. As a result, EPA is calling for additional recycling of batteries. This study is an important step in implementing EPA's strategy for helping states and cities achieve the national goal of recycling and reducing 25 percent of all municipal garbage by 1992. The findings on batteries are the result of a study conducted for EPA because of concern over the levels of lead and cadmium found n ash (residue) from municipal waste incinerators. Lead and cadmium are two metals of particular concern in the solid waste stream. The metals can contaminate soil and groundwater when landfilled. They also may be found in some incinerator emissions.

  16. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  17. Nonbreast Second Malignancies After Treatment of Primary Breast Cancer

    SciTech Connect (OSTI)

    Yadav, Budhi S. Sharma, Suresh C.; Patel, Firuza D.; Ghoshal, Sushmita; Kapoor, Rakesh; Kumar, Rajinder

    2009-04-01

    Purpose: To determine the incidence and risk factors for nonbreast second malignancies (NBSMs) in women after treatment for primary breast cancer. Methods and Materials: Between January 1985 and December 1995, a total of 1,084 breast cancer patients were analyzed for NBSMs. Detailed analysis was carried out for age, family history, disease stage, radiation therapy, chemotherapy, hormone therapy, other clinical/pathologic characteristics, and site of NBSMs. The Cox proportional hazard regression model was used to estimate the relative risk of NBSMs. Results: Median follow-up was 12 years. In total, 33 cases of NBSMs were noted in 29 patients. The overall incidence of NBSM was 3%, and the median time for NBSMs was 7 years. The most common NBSMs were gynecologic (22 patients), gastrointestinal (4 patients), head and neck (3 patients), hematologic (2 patients), lung (1 patient), and thyroid (1 patient). The NBSMs rate at 12 years was 2.4% for both mastectomy and radiation therapy groups. In the subset of patients less than 45 years of age at the time of treatment, the NBSMs rate was 0.7% as compared with 4.6% in patients more than 45 years of age (p = 0.001). Statistically significant higher incidences of endometrial and ovarian cancer were seen in patients with hormonal therapy (5.2%) as compared with patients without hormonal therapy (1.8%, p = 0.002). Women with a family history of breast cancer had a higher incidence (6%) of endometrial and ovarian malignancy compared with women without such a history (2.1%, p = 0.003). Chemotherapy did not affect the risk of second malignancy. Conclusion: The most common NBSMs in this study were gynecologic. Family history of breast cancer was a high risk factor for NBSMs. No risk of NBSMs with radiotherapy was observed.

  18. Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion

    Office of Scientific and Technical Information (OSTI)

    Chemotherapy (Journal Article) | SciTech Connect Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy Citation Details In-Document Search Title: Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy PurposeTo evaluate the frequency and the predictive factor of each feeding artery on intra-arterial infusion chemotherapy (IAIC) in primary tongue cancer.Materials and MethodsWe retrospectively evaluated 20 patients who received IAIC for

  19. Fact #863 March 9, 2015 Crude Oil Accounts for the Majority of Primary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Imports while Exports are Mostly Petroleum Products - Dataset | Department of Energy Fact #863 March 9, 2015 Crude Oil Accounts for the Majority of Primary Energy Imports while Exports are Mostly Petroleum Products - Dataset Fact #863 March 9, 2015 Crude Oil Accounts for the Majority of Primary Energy Imports while Exports are Mostly Petroleum Products - Dataset Excel file and dataset for Crude Oil Accounts for the Majority of Primary Energy Imports while Exports are Mostly Petroleum

  20. Organosilicon-Based Electrolytes for Long-Life Lithium Primary Batteries

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Organosilicon-Based Electrolytes for Long-Life Lithium Primary Batteries Citation Details In-Document Search Title: Organosilicon-Based Electrolytes for Long-Life Lithium Primary Batteries This report describes advances in electrolytes for lithium primary battery systems. Electrolytes were synthesized that utilize organosilane materials that include anion binding agent functionality. Numerous materials were synthesized and tested in lithium carbon

  1. Table 1.3 Primary Energy Consumption Estimates by Source, 1949...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Primary Energy Consumption Estimates by Source, 1949-2011 (Quadrillion Btu) Year Fossil Fuels Nuclear Electric Power Renewable Energy 1 Electricity Net Imports 3 Total Coal Coal ...

  2. NIF Functional Requirements and Primary Criteria Rev. 1.8 September...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: NIF Functional Requirements and Primary ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  3. Rietveld refinement and ionic conductivity of Ca{sub 8.4}Bi{sub 1.6}(PO{sub 4}){sub 6}O{sub 1.8}

    SciTech Connect (OSTI)

    Tmar Trabelsi, I.; Madani, A.; Mercier, A.M.; Toumi, M.

    2013-01-15

    The structure of Ca{sub 8.4}Bi{sub 1.6}(PO{sub 4}){sub 6}O{sub 1.8}, isostructural with Fluoroapatite, was determined by X-ray powder diffraction methods. The results of Rietveld refinement revealed that the formula of this compound is [Ca{sub 4}]{sup 4f}[Ca{sub 4.4}Bi{sub 1.6}]{sup 6h}(PO{sub 4}){sub 6}[O{sub 1.8}]{sup 2a}, space group P63/m (a=9.468 (3) A, c=6.957 (3) A). A total substitution of Bi{sup 3+} ions in the (6h) sites was related particularly to the high polarizability of the Bi{sup 3+} ion compared to Ca{sup 2+}. The observed frequencies in the Raman and infrared spectra were explained and discussed on the basis of unit-cell group analyses and in comparison with Fluoroapatite and other oxyapatites. The ionic conductivity over a wide range of temperature was investigated according to the complex impedance method. The highest overall conductivity values were found at {sigma}{sub 700 Degree-Sign C} =5.03 Multiplication-Sign 10{sup -7} S cm{sup -1} and E{sub a}=0.50 eV. - Graphical abstract: The final Rietveld refinement plot of the Ca{sub 8.4}Bi{sub 1.6} (PO{sub 4}){sub 6}O{sub 1.8}. Highlights: Black-Right-Pointing-Pointer The Rietveld refinement revealed that the formula of this compound is Ca{sub 8.4}Bi{sub 1.6}(PO{sub 4}){sub 6}O{sub 1.8}. Black-Right-Pointing-Pointer Vibrational spectroscopy supports the high symmetry P63/m space group for this apatite. Black-Right-Pointing-Pointer This apatite contained channels where oxygen ions were located in 2a sites. Black-Right-Pointing-Pointer The possibility of anionic conduction along these channels was considered.

  4. Rietveld refinement and dielectric studies of Bi{sub 0.8}Ba{sub 0.2}Fe{sub 0.95}V{sub 0.05}O{sub 3} ceramic

    SciTech Connect (OSTI)

    Priyanka, Agarwal, A. Ahlawat, N. Sanghi, S. Rani, S.

    2014-04-24

    Polycrystalline Bi{sub 0.8}Ba{sub 0.2}Fe{sub 0.95}V{sub 0.05}O{sub 3} ceramic has been prepared by the conventional solid state reaction technique. The Rietveld refinement of x-ray powder diffraction revealed that the sample has a rhombohedral crystal structure (space group R3c) with average particle size of 29 nm. The values of dielectric constant (ε′) and dielectric loss (tan δ) increases with increasing temperature at different frequencies which may be the result of increase in the number of charge carriers and their mobilities due to the thermal activation. The Jonscher’s universal power law used to analyze the ac conductivity. In the measured temperature range, the values of frequency exponent ‘s’ are less than one and shows a continous decrease which is attributed to the short range translational hopping assisted by large polaron hopping mechanisms.

  5. Solvent Refined Coal (SRC) process: trace elements. Research and development report No. 53, interim report No. 31, August 1976-July 1977. Volume III. Pilot plant development work. Part 6. [Fate of 36 trace elements

    SciTech Connect (OSTI)

    1980-03-01

    Results are presented on a study of the distribution and fate of 34 trace elements in the Solvent Refined Coal Process at the pilot plant located at Fort Lewis, Washington, and operated by The Pittsburg and Midway Coal Mining Co. under contract with the US Department of Energy. Neutron activation analysis was used to determine Ti, V, Ca, Mg, Al, Cl, Mn, As, Sb, Se, Hg, Br, Co, Ni, Cr, Fe, Na, Rb, Cs, K, Sc, Tb, Eu, Sm, Ce, La, Sr, Ba, Th, Hf, Ta, Ga, Zr, and Cu in feed coals, process solvent, Solvent Refined Coal (SRC), mineral residues, wet filter cake, by-product solvents, process and effluent waters and by-product sulfur. The sample points were chosen such that the major process streams were adequately described and that the major input and output materials were included. Atomic absorption spectrophotometry was used to measure the toxic elements Pb, Cd, Be in plant-derived solvents, effluent water and Hamer Marsh water. Specific methods were developed for analysis of a wide range of material compositions. The neutron activation analysis procedures were divided into short and long irradiation procedures for elements with short half lives (less than 3 hours) and intermediate to long half lives ( 8 hours to 5.2 years). Data are presented for a third equilibrium set of samples from the SRC-I process and compared to two similar sets analyzed previously. A material balance (or budget) was calculated for each element from the concentration data and the yields of each process fraction. Data are also presented on a study of carbon monoxide addition to the hydrogen stream and its effect on trace elements, and trace element data on a study of thirty-six plant effluent water samples taken during an SRC-I production run.

  6. Table A1. Total Primary Consumption of Energy for All Purposes...

    U.S. Energy Information Administration (EIA) Indexed Site

    ...,144,28,106,"W","W",1,11.3 3331," Primary Copper",21,1246,"W","W",15,3,"W","W","*",1 ...50,0,14,2,18,1,74,"*",16.6 3331," Primary Copper","*","W",0,"W","*","*",0,"*","*",1.1 ...

  7. H. R. 4662: a bill to amend the Internal Revenue Code of 1954 to impose a fee on the importation of crude oil and refined petroleum products. Introduced in the House of Representatives, Ninety-Ninth Congress, Second Session, April 22, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    A bill to amend the Internal Revenue Code of 1954 to impose a fee on the importation of crude oil and refined petroleum products was introduced and referred to the House Ways and Means Committee. The fee would apply to the first sale of crude or refined petroleum products following importation into the US and the first use. It exempts certain exports, but requires proof of eligibility for exemption. Sections of the bill outline procedures for determining prices and adjustments, the registration of affected parties, and penalties for non-compliance.

  8. S. 65: A Bill to amend the Internal Revenue Code of 1986 to impose a fee on the importation of crude oil and refined petroleum products. Introduced in the Senate of the United States, One Hundred Third Congress, First Session, January 21, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    S. 65 may be cited as the [open quotes]Domestic Petroleum Security Act of 1993.[close quotes] This Bill proposes a fee on imported crude oil or refined petroleum products. In general, Subtitle E of the Internal Revenue Code of 1986 is to be amended by adding at the end thereof the following new chapter: [open quotes]Chapter 55--Imported Crude Oil of Refined Petroleum Products.[close quotes] Section 5891 will be Imposition of Tax; Section 5892, Definitions; Section 5893, Registration; and Section 5894, Procedures, Returns, and Penalties.

  9. H. R. 838: A Bill to amend the Internal Revenue Code of 1986 to impose a fee on the importation of crude oil or refined petroleum products. Introduced in the House of Representatives, One Hundred Third Congress, First Session, February 4, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    H.R. 838 may be cited as the [open quotes]Energy Security Tax Act.[close quotes] The purpose of this Bill is to impose a fee on imported crude oil or refined petroleum products. In general, Subtitle E of the Internal Revenue Code of 1986 is to be amended by adding at the end thereof the following new chapter: [open quotes]Chapter 55--Imported Crude Oil, Refined Petroleum Products, and Petrochemical Feedstocks or Derivatives.[close quotes] Section 5886 will be concerned with Imposition of Tax; Section 5887 with Definitions; Section 5888 with Procedures, Returns, and Penalties; and Section 5890 with Adjustment for inflation.

  10. Electronic structure of the primary electron donor of Blastochloris viridis heterodimer mutants : high field EPR study.

    SciTech Connect (OSTI)

    Ponomarenko, N. S.; Poluektov, O. G.; Bylina, E. J.; Norris, J. R.; Chemical Sciences and Engineering Division; Univ. of Chicago

    2010-09-01

    High-field electron paramagnetic resonance (HF EPR) has been employed to investigate the primary electron donor electronic structure of Blastochloris viridis heterodimer mutant reaction centers (RCs). In these mutants the amino acid substitution His(M200)Leu or His(L173)Leu eliminates a ligand to the primary electron donor, resulting in the loss of a magnesium in one of the constituent bacteriochlorophylls (BChl). Thus, the native BChl/BChl homodimer primary donor is converted into a BChl/bacteriopheophytin (BPhe) heterodimer. The heterodimer primary donor radical in chemically oxidized RCs exhibits a broadened EPR line indicating a highly asymmetric distribution of the unpaired electron over both dimer constituents. Observed triplet state EPR signals confirm localization of the excitation on the BChl half of the heterodimer primary donor. Theoretical simulation of the triplet EPR lineshapes clearly shows that, in the case of mutants, triplet states are formed by an intersystem crossing mechanism in contrast to the radical pair mechanism in wild type RCs. Photooxidation of the mutant RCs results in formation of a BPhe anion radical within the heterodimer pair. The accumulation of an intradimer BPhe anion is caused by the substantial loss of interaction between constituents of the heterodimer primary donor along with an increase in the reduction potential of the heterodimer primary donor D/D{sup +} couple. This allows oxidation of the cytochrome even at cryogenic temperatures and reduction of each constituent of the heterodimer primary donor individually. Despite a low yield of primary donor radicals, the enhancement of the semiquinone-iron pair EPR signals in these mutants indicates the presence of kinetically viable electron donors.

  11. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, Robert H. (Bethany, CT); Brown, Stephen H. (East Haven, CT)

    1989-01-01

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  12. Fact #864: March 16, 2015 Imports of Primary Energy have Declined Sharply

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Since the Peak Reached in 2007 | Department of Energy 864: March 16, 2015 Imports of Primary Energy have Declined Sharply Since the Peak Reached in 2007 Fact #864: March 16, 2015 Imports of Primary Energy have Declined Sharply Since the Peak Reached in 2007 Excel file and dataset for Imports of Primary Energy have Declined Sharply Since the Peak Reached in 2007 File fotw#864_web.xlsx More Documents & Publications Fact #915: March 7, 2016 Average Historical Annual Gasoline Pump Price,

  13. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, R.H.; Brown, S.H.

    1989-10-17

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  14. S. 2886: a bill to amend the Internal Revenue Code of 1954 to impose a fee on the importation of crude oil or refined petroleum products. Introduced in the Senate of the United States, Ninety-Ninth Congress, Second Session, September 27, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    This bill amends Subtitle E of the Internal Revenue Code of 1954 to impose a fee on the importation of crude oil or refined petroleum products. The bill inserts Chapter 54, which defines the rate of tax, procedures for its payment and for registration, and imposes penalties for non-compliance.

  15. S. 254: A Bill to amend the Internal Revenue Code of 1986 to impose a fee on the importation of crude oil or refined petroleum products. Introduced in the Senate of the United States, One Hundred Third Congress, First Session, January 28, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This is the text of a bill to impose import taxes on crude oil and refined petroleum products, petrochemical feedstock or petrochemical derivatives. Taxes will be paid by the first person who sells the product within the U.S. and by the person who uses the product.

  16. Qualitative assessment of the ignition of highly flammable fuels by primary explosives

    SciTech Connect (OSTI)

    Elischer, P.P.; De Yong, L.

    1983-06-01

    An assessment of the ignition of fuel/air mixtures and of fabrics soaked with different fuels (ethanol, n-hexane and diethyl ether) by primary explosives has been carried out.

  17. EIA Energy Efficiency-Table 2a. First Use for All Purposes (Primary...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    a Page Last Modified: May 2010 Table 2a. Consumption of Energy (Primary 1 Energy) for All Purposes (First Use) for Selected Industries, 1998, 2002, and 2006 (Trillion Btu) MECS...

  18. EIA Energy Efficiency-Table 2b. Primary Fuel Consumption for...

    Gasoline and Diesel Fuel Update (EIA)

    b Page Last Modified: May 2010 Table 2b. End Uses of Fuel Consumption (Primary 1 Energy) for Selected Industries, 1998, 2002, and 2006 (Trillion Btu) MECS Survey Years NAICS...

  19. Photochemical dimerization and functionalization of alkanes, ethers, primary alcohols and silanes

    DOE Patents [OSTI]

    Crabtree, Robert H. (Bethany, CT); Brown, Stephen H. (East Haven, CT)

    1988-01-01

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary alcohols and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  20. Photochemical dimerization and functionalization of alkanes, ethers, primary alcohols and silanes

    DOE Patents [OSTI]

    Crabtree, R.H.; Brown, S.H.

    1988-02-16

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary alcohols and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.