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Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Comparative Investigation of Benzene Steam Reforming over Spinel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

2

Some new progress on the light absorption properties of linear alkyl benzene solvent  

E-Print Network [OSTI]

Linear alkyl benzene (LAB) will be used as the solvent of a liquid scintillator mixture for the JUNO antineutrino experiment in the near future. Its light absorption property should therefore be understood prior to its effective use in the experiment. Attenuation length measurements at a light wavelength of 430 nm have been performed on samples of LAB prepared for the purpose of the JUNO experiment. Inorganic impurities in LAB have also been studied for their possibilities of light absorption in our wavelength of interest. In view of a tentative plan by the JUNO collaboration to utilize neutron capture with hydrogen in the detector, we have also presented in this work, a study on the carbon-hydrogen ratio and the relationship thereof with the attenuation length of the samples.

Guang-You Yu; De-Wen Cao; Ai-Zhong Huang; Lei Yu; Chang-Wei Loh; Wen-Wen Wang; Zhi-Qiang Qian; Hai-Bo Yang; Huang Huang; Zong-Qiang Xu; Xue-Yuan Zhu; Bin Xu; Ming Qi

2015-04-22T23:59:59.000Z

3

Some new progress on the light absorption properties of linear alkyl benzene solvent  

E-Print Network [OSTI]

Linear alkyl benzene (LAB) will be used as the solvent of a liquid scintillator mixture for the JUNO antineutrino experiment in the near future. Its light absorption property should therefore be understood prior to its effective use in the experiment. Attenuation length measurements at a light wavelength of 430 nm have been performed on samples of LAB prepared for the purpose of the JUNO experiment. Inorganic impurities in LAB have also been studied for their possibilities of light absorption in our wavelength of interest. In view of a tentative plan by the JUNO collaboration to utilize neutron capture with hydrogen in the detector, we have also presented in this work, a study on the carbon-hydrogen ratio and the relationship thereof with the attenuation length of the samples.

Yu, Guang-You; Huang, Ai-Zhong; Yu, Lei; Loh, Chang-Wei; Wang, Wen-Wen; Qian, Zhi-Qiang; Yang, Hai-Bo; Huang, Huang; Xu, Zong-Qiang; Zhu, Xue-Yuan; Xu, Bin; Qi, Ming

2015-01-01T23:59:59.000Z

4

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

5

E-Print Network 3.0 - alkyl benzene sulphonates Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S 1 1 Benzaanthracene 56-55-3 S 2A 2 Benzal chloride 98-87-3 S 2A Benzene 71-43-2 ORC 1 1... tar distillate 065996-92-1 S 1 Coal tar pitch volatiles, as benzene solubles...

6

Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts  

SciTech Connect (OSTI)

In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

2013-06-01T23:59:59.000Z

7

ForReview.Confidential-ACS Catalytic Transformation of 1,3,5 -Trimethyl Benzene over USY Zeolite  

E-Print Network [OSTI]

and trimethylbenzenes (TMB) coming from the reforming and pyrolysis of gasoline, into benzene and xylenes via

Al-Khattaf, Sulaiman

8

Fuel Dependence of Benzene Pathways  

SciTech Connect (OSTI)

The relative importance of formation pathways for benzene, an important precursor to soot formation, was determined from the simulation of 22 premixed flames for a wide range of equivalence ratios (1.0 to 3.06), fuels (C{sub 1}-C{sub 12}), and pressures (20 to 760 torr). The maximum benzene concentrations in 15 out of these flames were well reproduced within 30% of the experimental data. Fuel structural properties were found to be critical for benzene production. Cyclohexanes and C{sub 3} and C{sub 4} fuels were found to be among the most productive in benzene formation; and long-chain normal paraffins produce the least amount of benzene. Other properties, such as equivalence ratio and combustion temperatures, were also found to be important in determining the amount of benzene produced in flames. Reaction pathways for benzene formation were examined critically in four premixed flames of structurally different fuels of acetylene, n-decane, butadiene, and cyclohexane. Reactions involving precursors, such as C{sub 3} and C{sub 4} species, were examined. Combination reactions of C{sub 3} species were identified to be the major benzene formation routes with the exception of the cyclohexane flame, in which benzene is formed exclusively from cascading fuel dehydrogenation via cyclohexene and cyclohexadiene intermediates. Acetylene addition makes a minor contribution to benzene formation, except in the butadiene flame where C{sub 4}H{sub 5} radicals are produced directly from the fuel, and in the n-decane flame where C{sub 4}H{sub 5} radicals are produced from large alkyl radical decomposition and H atom abstraction from the resulting large olefins.

Zhang, H; Eddings, E; Sarofim, A; Westbrook, C

2008-07-14T23:59:59.000Z

9

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

10

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

11

DUNCAN PRITCHARD Reforming Reformed Epistemology*  

E-Print Network [OSTI]

DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

Edinburgh, University of

12

alkyl benzene sulfonate: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hb, hemoglobin; MS, mass spectrometry; PBPK, physiologically based pharmacokinetic; SPC, S-phenylcysteine. Andrew B. Lindstrom; Suramya Waidyanatha; Rogelio Tonero-velez;...

13

alkyl benzene sulfonates: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hb, hemoglobin; MS, mass spectrometry; PBPK, physiologically based pharmacokinetic; SPC, S-phenylcysteine. Andrew B. Lindstrom; Suramya Waidyanatha; Rogelio Tonero-velez;...

14

Drinking Water Problems: Benzene  

E-Print Network [OSTI]

Drinking water in Texas sometimes contains potentially harmful chemicals, including benzene. Well owners can learn how to treat their well water to remove these chemicals. 4 pages, 3 images...

Dozier, Monty; Lesikar, Bruce J.

2009-04-16T23:59:59.000Z

15

Method of making alkyl esters  

DOE Patents [OSTI]

Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

Elliott, Brian (Wheat Ridge, CO)

2010-09-14T23:59:59.000Z

16

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

17

Asymmetric Alkyl?Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins  

E-Print Network [OSTI]

A method for asymmetric alkyl?alkyl Suzuki reactions of unactivated secondary alkyl electrophiles, specifically, cross-couplings of racemic acylated halohydrins with alkylborane reagents, has been developed. A range of ...

Owston, Nathan A.

18

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

19

Comparative Investigation of Benzene Steam Reforming over Spinel Supported  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationCleanCommunity Involvement and Making

20

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

Experimental results are presented for the autothermal reforming (ATR) of n-hexane, n-tetradecane, benzene and benzene solutions of naphthalene. The tests were run at atmospheric pressure and at moderately high reactant preheat temperatures in the 800-900 K range. Carbon formation lines were determined for paraffinic and aromatic liquids. Profiles were determined for axial bed temperature and composition. Space velocity efforts were assessed, and the locations and types of carbon were recorded. Significant reactive differences between hydrocarbons were identified. Carbon formation characteristics were hydrocarbon specific. The differing behavior of paraffinic and aromatic fuels with respect to their carbon formation may be important in explaining the narrow range of carbon-free operating conditions found in the ATR of number two fuel oil.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Methods of making alkyl esters  

DOE Patents [OSTI]

A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

Elliott, Brian (Wheat Ridge, CO)

2010-08-03T23:59:59.000Z

22

Alkylate  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYear Jan Feb Mar

23

Steam reforming analyzed  

SciTech Connect (OSTI)

This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

1992-07-01T23:59:59.000Z

24

Benzene Dimer: Dynamic Structure and Thermodynamics Derived from...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Benzene Dimer: Dynamic Structure and Thermodynamics Derived from On-the-Fly ab initio DFT-D Molecular Dynamic Simulations. Benzene Dimer: Dynamic Structure and Thermodynamics...

25

E-Print Network 3.0 - alkyl halide transfer Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alkyl halide, resulting... of the nucleophilic substitution and reduction reactions of iPr-LAB with alkyl halides. Ab initio and density... of alkyl halide by hydride. ......

26

Immigration reform and California agriculture  

E-Print Network [OSTI]

reform and California agriculture Philip Martin Professor,proposals for California agriculture. Immigration reformCenter. 196 CALIFORNIA AGRICULTURE • VOLUME 67 , NUMBER 4

Martin, Philip

2013-01-01T23:59:59.000Z

27

Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded Oxygen Vacancies of TiO2(110). Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded...

28

Enhancement of alkylation catalysts for improved supercritical fluid regeneration  

DOE Patents [OSTI]

A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

2010-12-28T23:59:59.000Z

29

Catalytic reforming methods  

DOE Patents [OSTI]

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

30

Catalytic, Enantioselective Alkylations of N,O-Acetals  

E-Print Network [OSTI]

, 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

Lectka, Thomas

31

NETL - Fuel Reforming Facilities  

ScienceCinema (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2014-06-27T23:59:59.000Z

32

NETL - Fuel Reforming Facilities  

SciTech Connect (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2013-06-12T23:59:59.000Z

33

Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross-Metathesis  

E-Print Network [OSTI]

n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when (tBuPCP)IrH[subscript 2] was paired ...

Dobereiner, Graham E.

34

Natural Gas Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

35

Detection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase-Peroxidase Coupling Reactions  

E-Print Network [OSTI]

bioassay may be suitable for field monitoring of BTEX to identify and track contaminated water and follow in contaminated water because of their accuracy and sensitivity. Although very sensitive, the cost associatedDetection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase

Chen, Wilfred

36

Plasmatron Fuel Reformer Development and Internal Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications...

37

Polyfunctional catalyst for processiing benzene fractions  

SciTech Connect (OSTI)

A by-product of the coke industry is a raw benzene fraction benzene- 1 which may serve as for catalytic processes. The paper reports a study on the influence of the composition and temperatures on the activity and selectivity of NiO-V{sub 2}O{sub 6}-MoO{sub 3}/{gamma}-Al{sub 2}O{sub 3} catalysts and the corresponding binary and tertiary subsystems are studied by a pulse method in model reactions; the hydrodealkylating of toluene and the hydrodesulfurizing of thioprhene. The optimal catalyst composition is established. The new catalyst is compared with industrial catalysts.

G. Byakov; B.D. Zubitskii; B.G. Tryasunov; I.Ya. Petrov [Kuznetsk Basin State Technical University, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

38

Benzene waste NESHAP update and requirements  

SciTech Connect (OSTI)

On January 7, 1993, USEPA promulgated the clarified National Emission Standard for Hazardous Air Pollutants (NESHAP) for Benzene Waste Operations, 40 CFR 61 Subpart FF. This rule limits benzene emissions from petroleum refinery wastewater systems and other waste management units. Since the time of initial promulgation, March 7, 1990, EPA admits that there has been widespread confusion among refiners concerning the key provisions of the rule. This paper provides clarifications of the new final rule and an overview of both the new alternative compliance options and the compliance waiver provisions.

Bennett, C.D. (Ashland Petroleum Co., Russell, KY (United States))

1993-01-01T23:59:59.000Z

39

Add MTBE unit ahead of alkylation  

SciTech Connect (OSTI)

Approximately three years ago, the people at Diamond Shamrock's Sunray, Texas, refinery recognized a growing demand for high octane super premium unleaded gasoline in their regional marketing area. It was apparent that they would need to change their processing scheme to meet this growing demand. After investigating several options, they decided to install an MTBE (methyl tert-butyl ether) unit upstream of their existing sulfuric acid (H/sub 2/SO/sub 4/) aklylation unit. The new unit would process olefin feed before it entered the alkylation unit. The MTBE unit was expected to improve Diamond Shamrock's gasoline pool in two ways. First, the MTBE would be an additional high octane blending stock for the gasoline pool. Second, the MTBE unit would improve the quality of the olefin stream going to the alkylation unit. Diamond Shamrock brought their MTBE unit onstream in December, 1985. The results of the combined operation exceeded expectations, producing alkylate in excess of 98 RON (Research octane number) and MTBE of 118 RON. These components significantly upgraded the refinery's capability to produce a super premium unleaded gasoline.

Masters, K.R.; Prohaska, E.A.

1988-08-01T23:59:59.000Z

40

FOOD REFORM MOVEMENTS Nicolas Larchet  

E-Print Network [OSTI]

FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

Boyer, Edmond

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Reforming the Private Insurance Market  

E-Print Network [OSTI]

SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION he prospects for national health care reform are more promising than at any time since 1994. President Obama and Members of Congress have made health care reform a top priority and legislation

Kammen, Daniel M.

42

Autothermal reforming catalyst and process  

SciTech Connect (OSTI)

High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

1984-09-25T23:59:59.000Z

43

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

44

A Simple, Accurate Model for Alkyl Adsorption on Late Transition...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on Late Transition Metals. A Simple, Accurate Model for Alkyl Adsorption on Late Transition Metals. Abstract: A simple model that predicts the adsorption energy of an...

45

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

46

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

47

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

48

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

49

E-Print Network 3.0 - alkylated silicon111 surfaces Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

13 N-Alkyl-polyethylenimine 2 kDastabilized superparamagnetic iron oxide nanoparticles for MRI cell tracking Summary: N-Alkyl-polyethylenimine 2 kDa-stabilized...

50

E-Print Network 3.0 - alkyl chain bis-quaternary Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by alkyl and alkylthiol chains, while in the archipelago model2 aromatic and naphthenic moieties... , the aromatic rings were linked or bridged through alkyl and...

51

Steam reformer with catalytic combustor  

DOE Patents [OSTI]

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

52

What's right SHIP & Healthcare Reform Forum  

E-Print Network [OSTI]

&Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

Walker, Matthew P.

53

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

54

Novel Reforming Catalysts  

SciTech Connect (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

55

Adsorption of alkyl amides: monolayer structures and mixing behaviour  

E-Print Network [OSTI]

friction in polymer films, particularly in polyethylene and polypropylene. Pure polymers can often be very ‘sticky’ (e.g. as seen in plastic bags). To prevent this tack, alkyl amides, particularly unsaturated amides such as erucamide, are added...

Bhinde, Tej

2011-02-08T23:59:59.000Z

56

Multipath Curved Planar Reformation of the Peripheral  

E-Print Network [OSTI]

Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

57

Optimization of Multiplanar Reformations from Isotropic  

E-Print Network [OSTI]

Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

58

Toward a Reformalization of QSIM Benjamin Shults  

E-Print Network [OSTI]

Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

Kuipers, Benjamin

59

Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods  

SciTech Connect (OSTI)

In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

Vicic, David A.

2014-05-01T23:59:59.000Z

60

Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids  

SciTech Connect (OSTI)

The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

Not Available

1981-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Applications of solar reforming technology  

SciTech Connect (OSTI)

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

62

Before the House Oversight and Government Reform Subcommittee...  

Office of Environmental Management (EM)

Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform...

63

Recover heat from steam reforming  

SciTech Connect (OSTI)

Steam reforming is one of the most important chemical processes--it is used in the manufacture of ammonia, hydrogen, methanol, and many chemicals made from hydrogen and carbon monoxide. Furthermore, many current trends will increase its importance. For example, methanol for addition to gasoline is likely to be produced by steam reforming. Because steam reforming occurs at high temperatures--typically 750 C--900 C--it generates a large amount of waste heat. Clearly, heat recovery is crucial to process economics. A typical 50,000 Nm[sup 3]/h hydrogen plant using natural gas feed has a radiant heat duty of about 50 MW. At a radiant efficiency of 50% and fuel cost of $3/GJ, this means that the reformer fires $9 million worth of fuel per year. Obviously, this amount of fuel justifies a close loot at ways to reduce costs. This article first provides a brief overview of steam reforming. It then outlines the available heat-recovery options and explains how to select the best method.

Fleshman, J.D. (Foster Wheeler USA Corp., Livingston, NJ (United States))

1993-10-01T23:59:59.000Z

64

Alkyl phospholipid antihypertensive agents in method of lowering blood pressure  

DOE Patents [OSTI]

The composition of this invention is 1-O-alkyl-2-acetoyl-sn-glycero-3-phosphocholine, having the ionic structural formula; ##STR1## wherein R is saturated alkyl having 9-21 carbon atoms, or salts or hydrates of the composition. Preferably R has 13-19 carbon atoms and most preferably R has 15 carbon atoms. The composition of this invention is useful for reducing hypertension in warm-blooded animals, including humans, when administered either orally or by injection or innoculation, e.g., intravenous injection. The composition can be prepared from naturally occurring lipids or synthetically from commercially available material.

Snyder, Fred L. (Oak Ridge, TN); Blank, Merle L. (Oak Ridge, TN); Muirhead, Ernest E. (Memphis, TN); Leach, deceased, Byron E. (late of Memphis, TN); Byers, Lawrence W. (Memphis, TN)

1988-01-01T23:59:59.000Z

65

E-Print Network 3.0 - aliphatic alkyl quaternaries Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... with various substrates. This alkylation approach provides a...

66

E-Print Network 3.0 - alkylated aromatics Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... with various substrates. This alkylation approach provides a...

67

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

68

Method of steam reforming methanol to hydrogen  

DOE Patents [OSTI]

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

69

Attrition resistant fluidizable reforming catalyst  

DOE Patents [OSTI]

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

70

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network [OSTI]

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

71

Conversion of hydrocarbons for fuel-cell applications. Part I. Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids. Part II. Steam reforming of n-hexane on pellet and monolithic catalyst beds. Final report  

SciTech Connect (OSTI)

Experimental autothermal reforming (ATR) results obtained in the previous phase of this work with sulfur-free pure hydrocarbon liquids are summarized. Catalyst types and configuration used were the same as in earlier tests with No. 2 fuel oil to facilitate comparisons. Fuel oil has been found to form carbon in ATR at conditions much milder than those predicted by equilibrium. Reactive differences between paraffins and aromatics in ATR, and thus the formation of different carbon precursors, have been shown to be responsible for the observed carbon formation characteristics (fuel-specific). From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation in ATR. Effects of olefin (propylene) addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics (n-tetradecane and benzene) synergistic effects on conversion characteristics were identified. Comparisons of the No. 2 fuel oil data with the experimental results from this work with pure (and mixed) sulfur-free hydrocarbons indicate that the sulfur content of the fuel may be the limiting factor for efficient ATR operation. Steam reforming of hydrocarbons in conventional reformers is heat transfer limited. Steam reforming tasks performed have included performance comparisons between conventional pellet beds and honeycomb monolith catalysts. Metal-supported monoliths offer higher structural stability than ceramic supports, and have a higher thermal conductivity. Data from two metal monoliths of different catalyst (nickel) loading were compared to pellets under the same operating conditions.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-10-01T23:59:59.000Z

72

Plasma-catalyzed fuel reformer  

DOE Patents [OSTI]

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

2013-06-11T23:59:59.000Z

73

New packing in absorption systems for trapping benzene from coke-oven gas  

SciTech Connect (OSTI)

The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

74

Modeling and Optimal Regulation of Erythropoiesis Subject to Benzene Intoxication  

E-Print Network [OSTI]

humans and laboratory animals [11, 16]. Increased incidence of acute myelogenous leukemia in humans obtained in vitro [5, 6]. Since in vitro metabolic parameters are also available for humans, the model could then be extrapolated to humans for risk assessment. Since benzene is a known human leukemogen

75

Lithium-Mediated Benzene Adsorption on Graphene and Graphene Nanoribbons  

E-Print Network [OSTI]

Lithium-Mediated Benzene Adsorption on Graphene and Graphene Nanoribbons Dana Krepel and Oded Hod on lithium adsorption sites at the surface of graphene and nanoribbons thereof are investigated. The effects, bare lithium adsorption turns armchair graphene nanoribbons metallic and their zigzag counterparts half

Hod, Oded

76

Hydrology Days 2014 Thermally Enhanced Attenuation of Substituted Benzenes  

E-Print Network [OSTI]

as a remediation technique for substituted benzenes, anaerobic soil microcosms were constructed using soils from microcosms have produced less biogas than previous petroleum microcosm studies. This suggests at the field site. The device allows for the determination of water quality, temperature, and resistivity

77

Steam reforming utilizing high activity catalyst  

SciTech Connect (OSTI)

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

78

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform  

E-Print Network [OSTI]

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security was their solution effective? 4. What implications for present-day reformers can be drawn from this reform? Lessons learned from each chapter are summarized at the end of each section, and a synthesis of these findings

Lewis, Robert Michael

79

Hydrogen from Biomass by Autothermal Reforming  

Broader source: Energy.gov [DOE]

Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

80

Distributed Bio-Oil Reforming (Presentation)  

SciTech Connect (OSTI)

This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

2007-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Comparative case studies of health reform in England  

E-Print Network [OSTI]

Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

Birmingham, University of

82

Apparatus for production of synthesis gas using convective reforming  

SciTech Connect (OSTI)

This patent describes a system for the steam reforming of hydrocarbons into a hydrogen-rich gas. It comprises a convective reformer device having indirect heat exchange means for partially reforming a feed mixture of hydrocarbons and steam; a steam reforming furnace having a radiant section, reforming tubes in the radiant section, and means for producing radiant heat for the further reforming of the partially reformed effluent; an auto-thermal reformer for fully reforming the effluent; conduit means for passing the partially reformed effluent; conduit means for passing the effluent; and conduit means for passing the fully reformed effluent to supply the heat of reaction for the partial reformation of the hydrocarbon-steam feed mixture.

Karafian, M.; Tsang, I.C.

1991-04-09T23:59:59.000Z

83

Solid oxide fuel cell steam reforming power system  

DOE Patents [OSTI]

The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

2013-03-12T23:59:59.000Z

84

Design, Modeling, and Validation of a Flame Reformer for LNT...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

85

Regulatory and Financial Reform of Federal Research Policy: Recommenda...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

86

Secretary Moniz to Present Project Management Reforms to the...  

Energy Savers [EERE]

Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

87

Diesel Reforming for Fuel Cell Auxiliary Power Units  

SciTech Connect (OSTI)

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

88

Hydrogen generation from plasmatron reformers and use for diesel...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003...

89

E-Print Network 3.0 - alkyl radicals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 2 Radicals and Hydroxy Radical Reactions in Troposphere Summary: : Nitrogen dioxide, 17 valence electrons 7. NO 3 : Nitrate radical 8. R CH 2 1;: alkyl...

90

E-Print Network 3.0 - alkyl hydroperoxide reductase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methyl Esters J. Biet, V. Warth, O. Herbinet* Summary: hydroperoxides methyl esters, acrolein and OH and methyl ester alkyl radicals from unsaturated hydroperoxide... for...

91

E-Print Network 3.0 - alkylating agent consolidation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

92

E-Print Network 3.0 - alkylating agents synthesis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

93

E-Print Network 3.0 - alkylating agents Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

94

E-Print Network 3.0 - alkylating agents evaluacion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

95

Enabling Informed Adaptation of Reformed Instructional Materials  

E-Print Network [OSTI]

Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

Elby, Andy

96

Fuel cell integrated with steam reformer  

DOE Patents [OSTI]

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

97

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network [OSTI]

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

98

Methanol Steam Reformer on a Silicon Wafer  

SciTech Connect (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

99

Computer simulations of benzene in faujasite-type zeolites  

SciTech Connect (OSTI)

The exact nature of the cation-benzene ring interaction is not yet known. In order to remedy this, energy minimization and Monte Carlo methods were used to probe the location and energetics of benzene in sodium zeolite-X and -Y. Sorption energies for the six-ring binding site in each of the zeolite models with the two forcefields (cff91 and cvff) are tabulated as function of Si/Al ratio. Both forcefields predict similar binding sites for each system; however, the final energies are sensitive to form and parameterization of the forcefield. Further work is needed to refine the forcefield for zeolite-sorbate interactions. 5 figs, 21 refs, 2 tabs.

Henson, N.J.; Cheetham, A.K. [California Univ., Santa Barbara, CA (United States). Dept. of Materials; Redondo, A. [Los Alamos National Lab., NM (United States); Levine, S.M.; Newsam, J.M. [Biosym Technologies Inc., San Diego, CA (United States)

1994-03-01T23:59:59.000Z

100

The development of a passive dosimeter for airborne benzene vapors  

E-Print Network [OSTI]

entirely different from that usually employed in gas or vapor collection devices, as there is no need for pumps and airflow control s to provi de fi xed airflows or volumes. This principle, Ficks First Law of Diffusion, states tha t the rate of transfer...+ Ilay 1978 ABSTRACT The Development of a Passive Dosimeter for Airborne Benzene Vapor. ", . (Nay 1978) David Hilliam Hager, B. S. , University of Rochester; Chairman of Advisory Committee: Dr. David F. Ciapo Passive diffusion dosimeters offer...

Hager, David William

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions  

E-Print Network [OSTI]

Part I describes the expansion in scope of a nickel-catalyzed coupling reaction of unactivated alkyl bromides and alkyl boranes to include unactivated alkyl chlorides. The new method is adapted for use outside of a glove ...

Lu, Zhe

2010-01-01T23:59:59.000Z

102

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA  

E-Print Network [OSTI]

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

103

September 25, 2013 AFSCME Continues to Object to Pension Reform;  

E-Print Network [OSTI]

September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

Leistikow, Bruce N.

104

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH  

E-Print Network [OSTI]

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

Royal Holloway, University of London

105

Diesel Reforming for Solid Oxide Fuel Cell Application  

SciTech Connect (OSTI)

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

106

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network [OSTI]

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

107

Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic applications  

E-Print Network [OSTI]

Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic and a fullerene (C60) derivative with long alkyl chains was constructed as a donor­acceptor pair for photovoltaics as attractive candidates for the development of light- energy harvesting and photovoltaic materials because

Nabben, Reinhard

108

for the alkylation reaction. We (23) and others (24) observed similar carbon isotope effects in  

E-Print Network [OSTI]

- ination proceeds to yield the alkylation product and a cationic Ru-hydroxo complex 23. Notably, Ru for the regeneration of the Ru-alkenyl species 22. Extensive hydrogen- deuterium exchange between indene and 2 the catalytic conditions. Our catalytic alkylation method exhibits a broad substrate scope, as well as a high

Jacob, Daniel J.

109

Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation  

E-Print Network [OSTI]

Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system

Zhang, Xumu

110

A Practical and Highly Stereoselective Umpolung Alternative to the Alkylation of Chiral Enolates  

E-Print Network [OSTI]

, acetates, carbonates, and epoxides.9,10 Thus, in principle, the displacement reaction of a chiral allyl reactive electrophiles such as methyl, ethyl, and some primary alkyl iodides and benzyl or allyl halides. s-silyl ketene acetals, and s-alkyl electrophiles are poor electrophiles with this method.7,8 In this paper, we

Spino, Claude

111

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents [OSTI]

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

112

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

113

E-Print Network 3.0 - anaerobic benzene degradation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Topic List Advanced Search Sample search results for: anaerobic benzene degradation Page: << < 1 2 3 4 5 > >> 1 Biodegradation 11: 107116, 2000. 2001 Kluwer Academic...

114

Electrical Generation Tax Reform Act (Montana)  

Broader source: Energy.gov [DOE]

This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the Montana electric utility industry that allows...

115

Electricity reform abroad and US investment  

SciTech Connect (OSTI)

This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

NONE

1997-10-01T23:59:59.000Z

116

Device for cooling and humidifying reformate  

DOE Patents [OSTI]

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

2008-04-08T23:59:59.000Z

117

E-Print Network 3.0 - assessing welfare reform Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reventionscience.umn.edu Summary: , poverty, welfare reform, school reform, and health- care reform. An emphasis is given to large... , and dissemination of a variety of programs...

118

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

119

Perspective: The road to reform  

SciTech Connect (OSTI)

The rapid transformation underway in the utility industry provides ample evidence that the reality of the Energy Policy Act of 1992 is sinking in. This law reflected Congress's conclusion that competition in wholesale power generation-at the plant busbar-is a demonstrable reality. It expressed the vision of a fully competitive wholesale generation market, with suppliers linked to markets through a grid that would provide service on a nondiscriminatory basis. But will consumers reap the full benefits of effective competition at the wholesale generation level Or will more disorderly forms of competition emerge, reflecting a hybrid of deregulation and old-fashioned monopoly tactics Along the latter course we run the risk of cost shifts among customer classes, customer defections, diminished utility cooperation, and higher overall costs to society. In short, the vision of a competitive market in wholesale generation will not come about without thoughtful efforts at defining the relevant market, as well as careful attention to the management of a difficult transition away from outmodes mindsets and regulatory models. As a national trade association representing independent power producers (IPPs) and suppliers of goods and services to the competitive wholesale electric generation industry, the Electric Generation Association (EGA) believes that constructive dialogue will yield the best approach to managing this difficult process of transition. In that spirit, the EGA Emerging Operational Issues Committee recently released a while paper, [open quotes]Electrifying Change: Strategies for Structural Reform in the Electric Industry,[close quotes] which forms the basis for this article.

Howe, J.B. (J. Makowski Associates Inc., Boston, MA (United States))

1994-04-01T23:59:59.000Z

120

Hydrogen generation utilizing integrated CO2 removal with steam reforming  

DOE Patents [OSTI]

A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

Duraiswamy, Kandaswamy; Chellappa, Anand S

2013-07-23T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A Multicompartment LiverBased Pharmacokinetic Model for Benzene and Its Metabolites in Mice  

E-Print Network [OSTI]

extrapolated to predict in vivo data for benzene metabolism and dosimetry. 1 Introduction and Problem in a variety of blood and bone marrow disorders in both humans and laboratory animals [9, 18]. IncreasedA Multicompartment Liver­Based Pharmacokinetic Model for Benzene and Its Metabolites in Mice Cammey

122

A Multicompartment Liver-Based Pharmacokinetic Model for Benzene and Its Metabolites in Mice  

E-Print Network [OSTI]

extrapolated to predict in vivo data for benzene metabolism and dosimetry. 1 Introduction and Problem in a variety of blood and bone marrow disorders in both humans and laboratory animals [9, 18]. IncreasedA Multicompartment Liver-Based Pharmacokinetic Model for Benzene and Its Metabolites in Mice Cammey

123

Physiologically Based Pharmacokinetic Modeling of Benzene Metabolism in Mice through Extrapolation  

E-Print Network [OSTI]

metabolic constants for humans can subsequently be extrapolated to predict the dosimetry of benzene and itsPhysiologically Based Pharmacokinetic Modeling of Benzene Metabolism in Mice through Extrapolation parameters are also available for humans. Unknown parameters were estimated by fitting the model to published

124

Modeling benzene plume elongation mechanisms exerted by ethanol using RT3D with a general  

E-Print Network [OSTI]

E10 gasoline (i.e., a blend with 10% vol/vol ethanol/ gasoline) showed that mean benzene plume of E10 gasoline (10% vol/vol ethanol), which compares favorably to field observations. For low benzene Act requirements. The widespread use of ethanol in gasoline has led to an increase in its potential

Alvarez, Pedro J.

125

Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies  

E-Print Network [OSTI]

Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies Rula A. Deeb1 ; Jonathan with Federal Clean Air Act requirements for carbon monoxide and ozone attainment, ethanol is being considered as a replacement for MTBE. The objective of this study is to evaluate the potential impact of ethanol on benzene

Alvarez, Pedro J.

126

Femtosecond Near-Infrared Laser Desorption of Multilayer Benzene on Pt{111}: A Molecular Newton's Cradle?  

E-Print Network [OSTI]

Femtosecond Near-Infrared Laser Desorption of Multilayer Benzene on Pt{111}: A Molecular Newton Recently, the intense near-infrared laser desorption of intact benzene molecules has been reported.1 Three, 1999; In Final Form: February 11, 2000 Velocity distributions resulting from the intense, near-IR laser

Levis, Robert J.

127

Hydrologic and geochemical controls on soluble benzene migration in sedimentary basins  

E-Print Network [OSTI]

, a coupled ground- water flow and heat transfer model computes the hydraulic head, stream function, and temperature in the basin. A coupled mass transport model simulates water washing of benzene from an oil reservoir and its miscible, advective/dispersive transport by groundwater. Benzene mass transfer at the oil­water

Polly, David

128

Low Cost Autothermal Diesel Reforming Catalyst Development  

SciTech Connect (OSTI)

Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

Shihadeh, J.; Liu, D.

2004-01-01T23:59:59.000Z

129

E-Print Network 3.0 - alkylations added insight Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: . In a typical alkylation reaction, a solution of LM (2 L of a 0.5 mM solution in acetonitrile) was added... to achieve efficient reaction....

130

ON-LINE OPTIMIZATION, ENERGY ANALYSIS AND ENVIRONMENTAL IMPACT ASSESSMENT OF SULFURIC ACID CATALYZED ALKYLATION  

E-Print Network [OSTI]

pool, increased amounts of gasoline per volume of crude oil and high heats of combustion. The overall in sulfuric acid consumption potentially could be obtained. 1. Introduction Alkylation process is one

Pike, Ralph W.

131

Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies  

E-Print Network [OSTI]

A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...

Firmansjah, Luke

2007-01-01T23:59:59.000Z

132

Palladium-catalyzed allylic alkylation via decarboxylative and retro-Claisen C-C cleavage methods  

E-Print Network [OSTI]

Presented herein is the development of new methods for Pd-catalyzed allylic alkylation with a central focus on reactions that generate molecular complexity rapidly with little waste byproduct. With this simply stated, yet ...

Grenning, Alexander James

2012-05-31T23:59:59.000Z

133

A Mild, Palladium-Catalyzed Method for the Dehydrohalogenation of Alkyl Bromides: Synthetic and Mechanistic Studies  

E-Print Network [OSTI]

We have exploited a typically undesired elementary step in cross-coupling reactions, ?-hydride elimination, to accomplish palladium-catalyzed dehydrohalogenations of alkyl bromides to form terminal olefins. We have applied ...

Bissember, Alex C.

134

E-Print Network 3.0 - asymmetric intramolecular alkylation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of this alkylation reaction can also be catalyzed by chiral titanate complexes2-4 (e.g., TAD- DOLs2 and chiral... ,2-bis(3,5-dichloro-2-hydroxyben- zenesulfonamido)cyclohexane) for...

135

Electricity reform in Chile : lessons for developing countries  

E-Print Network [OSTI]

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

Pollitt, Michael G.

2004-01-01T23:59:59.000Z

136

The Effect of Welfare Reform on Childbirth, Marriage, and Divorce  

E-Print Network [OSTI]

This dissertation contains two essays on the effect of welfare reform on child- birth, marriage, and divorce. In the first essay, I exploit the cross state variation in welfare reform implementation to identify its effect on birth rates. The results...

Pakdeethai, Pimrak

2010-10-12T23:59:59.000Z

137

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION?  

E-Print Network [OSTI]

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION? David Watts Paulo Atienza to participate. Chile was the pioneer introducing this kind of reforms, through the application of a centralized

Catholic University of Chile (Universidad Católica de Chile)

138

How Did Health Care Reform in Massachusetts Impact Insurance Premiums?  

E-Print Network [OSTI]

It is widely recognized that the 2006 Massachusetts health reforms served as a blueprint for national reform under the 2010 Affordable Care Act (ACA). As such, there is interest in using the Massachusetts experience to ...

Graves, John A.

139

MORE HEALTH CARE REFORM By Victor R. Fuchs  

E-Print Network [OSTI]

MORE HEALTH CARE REFORM By Victor R. Fuchs #12;2 | MORE HEALTH CARE REFORM The Robert Wood Johnson?................................................................................... 8 Government Payment for Health Care -- Causes and Consequences....................................................................................................................................................................................... 16 Health Care Is Different -- That's Why Expenditures Matter

Zalta, Edward N.

140

Pyrochlore catalysts for hydrocarbon fuel reforming  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

2012-08-14T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Thermally integrated staged methanol reformer and method  

DOE Patents [OSTI]

A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

2001-01-01T23:59:59.000Z

142

Electrophilic Metal Alkyl Chemistry in New Ligand Environments  

SciTech Connect (OSTI)

The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

Jordan, Richard F. [University of Chicago] University of Chicago

2013-06-30T23:59:59.000Z

143

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation  

E-Print Network [OSTI]

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation September 2012 1 Ofqual: A Level Reform Consultation Response by the Wellcome Trust September 2012 Key Points National Subject to university. We are therefore pleased to respond to this consultation on reforming A levels. Our comments

Rambaut, Andrew

144

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com  

E-Print Network [OSTI]

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com On March 23, President Obama signed is tracking the myriad other developments of the new health reform law. You can find a wide range of related material, including enacting language, implementing documents, and analysis through the Health Reform

Chapman, Michael S.

145

Preliminary and incomplete A Modest Proposal for International Monetary Reform  

E-Print Network [OSTI]

Preliminary and incomplete A Modest Proposal for International Monetary Reform International Columbia University #12;- 1 - - 1 - #12;- 2 - A Modest Proposal for International Monetary Reform Bruce are fundamental aspects of the present system and that, without reform, they will continue to plague the global

Grishok, Alla

146

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY  

E-Print Network [OSTI]

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY Olivier CARDI Romain RESTOUT December, 2010 REFORMS IN AN OPEN ECONOMY Olivier CARDI Universit´e Panth´eon-Assas ERMES Ecole Polytechnique Romain with traded and non traded goods to in- vestigate the sectoral effects of three tax reforms: i) two revenue

Boyer, Edmond

147

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS?  

E-Print Network [OSTI]

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS? Susie LEE Ingmar SCHUMACHER (in)stability induce financial reforms? Susie Lee1 Ingmar Schumacher2 October 26, 2011 Abstract The article studies whether financial sector (in)stability had an effect on reforms in the fi- nancial sector

Boyer, Edmond

148

the triple aim MEETING THE GOAL OF HEALTH REFORM  

E-Print Network [OSTI]

the triple aim MEETING THE GOAL OF HEALTH REFORM Produced by OHSU Strategic Communications -- emphasizing shared decision-making and coordination between providers -- could influence reform in a big way care. health reform is about getting better health outcomes for our communities, improving access

Chapman, Michael S.

149

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high cases. #12;1 Introduction The naphtha reforming process converts low-octane gasoline blending compo-octane components for use in high-performance gasoline fuels. The reformer also has an important function

Skogestad, Sigurd

150

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

151

Isothermal vapor-liquid equilibria for benzene + cyclohexane + 1-propanol and for three constituent binary systems  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system of benzene + cyclohexane + 1-propanol and its constituent binary systems of benzene + cyclohexane, cyclohexane + 1-propanol, and benzene + 1-propanol at 323.15 and 333.15 K, using the apparatus proposed in a previous study. The experimental binary data were correlated using the NRTL equation. The ternary system was predicted using the binary NRTL parameters. The average absolute percent deviations between the predicted and experimental ternary total pressures are 0.5% at 323.15 K and 0.4% at 333.15 K.

Kurihara, Kiyofumi; Uchiyama, Masanori; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry

1997-01-01T23:59:59.000Z

152

In Njeri Wamukonya, ed., Electricity Reform  

E-Print Network [OSTI]

electricity consumption in industrial countries has caused major air pollution problems. In fact, power plants maintain that governing the electricity industry according to market dynamics, rather than socioIn Njeri Wamukonya, ed., Electricity Reform: Social and Environmental Challenges Roskilde, Denmark

Delaware, University of

153

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

154

Affordable Care Act & Medicaid Reform in Wisconsin  

E-Print Network [OSTI]

Affordable Care Act & Medicaid Reform in Wisconsin Enrollment Trends Chartpack 2013-2014 ACA Open,731 Wisconsinites Living in Poverty Access Health Care Through Medicaid," Press Release, May 19, 2014. http://walker.wi.gov/newsroom/press-release/81731-wisconsinites-living-poverty-access-health-care-through- Medicaid Medicaid & CHIP: April 2014

Sheridan, Jennifer

155

Patent Reform: Aligning Reward and Contribution  

E-Print Network [OSTI]

4 Patent Reform: Aligning Reward and Contribution Carl Shapiro, University of California the current U.S. patent system allows patent holders to capture private rewards that exceed their social with the patent system and discourage in- novation by others. Economic efficiency is promoted if rewards to patent

Sadoulet, Elisabeth

156

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

157

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

158

Hydrogen production from the reaction of solvated electrons with benzene in water-ammonia mixtures  

SciTech Connect (OSTI)

Product analysis data for the reaction of the ammoniated electron with benzene-water mixtures in liquid ammonia show that the dominant product is evolved hydrogen and not 1,4-cyclohexadiene.

Dewald, R.R.; Jones, S.R.; Schwartz, B.S.

1980-11-27T23:59:59.000Z

159

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

interest in subcritical (hot/liquid) water from 298 K to 473subcritical region. Modeling Studies on the Transport of Benzene and H 2 S in CO 2 -Water

Zheng, L.

2011-01-01T23:59:59.000Z

160

Autothermal reforming catalyst having perovskite structure  

DOE Patents [OSTI]

The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

2009-03-24T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Autothermal hydrodesulfurizing reforming method and catalyst  

DOE Patents [OSTI]

A method for reforming a sulfur-containing carbonaceous fuel in which the sulfur-containing carbonaceous fuel is mixed with H.sub.2 O and an oxidant, forming a fuel/H.sub.2 O/oxidant mixture. The fuel H.sub.2 O/oxidant mixture is brought into contact with a catalyst composition comprising a dehydrogenation portion, an oxidation portion and a hydrodesulfurization portion, resulting in formation of a hydrogen-containing gas stream.

Krumpelt, Michael; Kopasz, John P.; Ahmed, Shabbir; Kao, Richard Li-chih; Randhava, Sarabjit Singh

2005-11-22T23:59:59.000Z

162

Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary Structure, and Self-Assembly of Fractalkine  

E-Print Network [OSTI]

Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary-amphiphiles with no spacer (NoSPR), polyethylene glycol (PEG4, PEG8, PEG24), alkyl (C12 and C24), or oligonucleotide (T10 a polyethylene glycol (PEG) or an oligo-T (thymine) spacer is added to the aptamer, especially when attaching

Kokkoli, Efie

163

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls  

E-Print Network [OSTI]

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

Zare, Richard N.

164

Test of electron beam technology on Savannah River Laboratory low-activity aqueous waste for destruction of benzene, benzene derivatives, and bacteria  

SciTech Connect (OSTI)

High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering operations, the effect of irradiation on those populations was also studied. {sup 60}Co and electron beam irradiation were both lethal to the bacteria studied at irradiation levels far lower than were necessary to remove organic contaminants.

Dougal, R.A. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Electrical and Computer Engineering

1993-08-01T23:59:59.000Z

165

Partial oxidation fuel reforming for automotive power systems.  

SciTech Connect (OSTI)

For widespread use of fuel cells to power automobiles in the near future, it is necessary to convert gasoline or other transportation fuels to hydrogen on-board the vehicle. Partial oxidation reforming is particularly suited to this application as it eliminates the need for heat exchange at high temperatures. Such reformers offer rapid start and good dynamic performance. Lowering the temperature of the partial oxidation process, which requires the development of a suitable catalyst, can increase the reforming efficiency. Catalytic partial oxidation (or autothermal) reformers and non-catalytic partial oxidation reformers developed by various organizations are presently undergoing testing and demonstration. This paper summarizes the process chemistries as well as recent test data from several different reformers operating on gasoline, methanol, and other fuels.

Ahmed, S.; Chalk, S.; Krumpelt, M.; Kumar, R.; Milliken, J.

1999-09-07T23:59:59.000Z

166

Distributed Reforming of Renewable Liquids via Water Splitting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

167

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production Systems, Sandy Thomas, H2Gen Integrated Short Contact Time Hydrogen Generator, Wei Wei, GE Global Research Distributed Bio-Oil Reforming, Darlene Steward,...

168

Agenda for the Derived Liquids to Hydrogen Distributed Reforming...  

Broader source: Energy.gov (indexed) [DOE]

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to...

169

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming...

170

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets  

Broader source: Energy.gov [DOE]

Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

171

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contact Time Hydrogen Generator, Ke Liu, GE Global Research Hydrogen from Biomass by Autothermal Reforming, Lanny D. Schmidt, University of Minnesota Low-Cost Hydrogen from Ethanol...

172

Welfare Impacts of Electricity Generation Sector Reform in the Philippines  

E-Print Network [OSTI]

the Government lost and there was an air pollution cost. The paper concludes that the reform with private sector participation increased social welfare....

Toba, Natsuko

2004-06-16T23:59:59.000Z

173

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Broader source: Energy.gov (indexed) [DOE]

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

174

Compatibility of selected ceramics with steam-methane reformer environments  

SciTech Connect (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

175

advance hatchery reform: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

176

Diesel Reformers for On-board Hydrogen Applications  

Broader source: Energy.gov (indexed) [DOE]

After-treatment Catalyst Clean Exhaust Effective Catalyst Regeneration Emission Reduction Electricity for On-road and Idling Loads SOFC APU Efficiency Boost Reformers for...

177

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon  

E-Print Network [OSTI]

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon Countries, Vickerstaff, S & Loretto, W 2012, 'Reforming State Pension provision in `Liberal' Anglo Saxon Countries: Re University Press. Lain, D., Vickerstaff, S. & Loretto, W. 2012, "Reforming State Pension provision

Millar, Andrew J.

178

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type or Print)  

E-Print Network [OSTI]

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type Care Structural Reform: What's Happening in Albany and Washington? Changing the Social Determinants of Health Reform in the Pharmaceutical Industry Sustaining Community Health Workers Comparative

Brown, Lucy L.

179

Aligning modes of organization with technology: Critical transactions in the reform of infrastructures  

E-Print Network [OSTI]

1 Aligning modes of organization with technology: Critical transactions in the reform of their reform. Since infrastructures are characterized by strong technical complementarities, we explore the alignment between organization and technology and should be taken explicitly into account when reforming

Boyer, Edmond

180

Negotiating Education Reform: Teacher Evaluations and Incentives in Chile (1990-2010)  

E-Print Network [OSTI]

Reforms designed to improve the quality of teaching by reforming personnel practices, such as pay for performance arrangements, usually run into opposition from well-organized teacher unions that can either block reform ...

Mizala, Alejandra

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Electricity Sector Reform in Developing Countries: A Survey of Empirical Evidence on Determinants and Performance  

E-Print Network [OSTI]

This paper reviews the empirical evidence on electricity reform in developing countries. We find that country institutions and sector governance play an important role in success and failure of reform; reforms appear to have increased operating...

Jamasb, Tooraj; Mota, Raffaella L; Newbery, David; Pollitt, Michael G.

2004-07-09T23:59:59.000Z

182

Gas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield  

E-Print Network [OSTI]

total AN (gas + aerosol) and ANaer show that on average 21% of ANs are in the condensed phaseGas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield A. W. Rollins samples. These measurements show that ANs are a ubiquitous component of the OA with the ­ONO2 subunit

Cohen, Ronald C.

183

Electronic desorption of alkyl monolayers from silicon by very highly charged ions  

E-Print Network [OSTI]

-assembled alkyl monolayers SAM on Si 111 .13 AFM images of SAMs after exposure to Xe41 and Au63 show craters ions, like Xe41 and Th73 . Atomic force microscope images show craters from single ion impacts be used to modify surfaces at very low impact energies. Impact energies are limited by the image charge

184

Serendipitous alkylation of a Plk1 ligand uncovers a new binding channel  

E-Print Network [OSTI]

We obtained unanticipated synthetic byproducts from alkylation of the ?[superscript 1] nitrogen (N3) of the histidine imidazole ring of the polo-like kinase-1 (Plk1) polo-box domain (PBD)-binding peptide PLHSpT. For the ...

Lim, Dan

185

Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids  

DOE Patents [OSTI]

A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

Miller, P.S.; Ts'o, P.O.P.

1999-06-15T23:59:59.000Z

186

Molecular simulation study of nanoscale friction for alkyl monolayers on Si,,111...  

E-Print Network [OSTI]

. To calculate friction in MD simulations, two Si 111 surfaces coated with the alkyl monolayers were slid against is critical to the design of coatings for microelectromechanical systems. © 2002 American Institute of Physics, such as membranes, gears, motors, pumps and valves.1­3 The integration of miniaturized mechanical components

Zhang, Luzheng

187

Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids  

DOE Patents [OSTI]

A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid and includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional.

Miller, Paul S. (Baltimore, MD); Ts'o, Paul O.P. (Lutherville, MD)

1999-06-15T23:59:59.000Z

188

E-Print Network 3.0 - act contracting reform Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

US Pricing Basics and What to Expect from Healthcare Reform By Jack Mycka... health care reform and pricing 12;3 MME LLC 2010 Applied Pharmacoeconomics and Outcomes...

189

Environmental fiscal reform (EFR) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power Basics (The followingDirectLowDiscussion-4,611,201.00fiscal reform (EFR)

190

Vapor-liquid equilibria for the system benzene-thiophene-methanol  

SciTech Connect (OSTI)

Isothermal vapor pressure data over the whole range of composition were obtained for the system benzene-thiophene-methanol. Data were taken at temperatures of 35, 40, and 45 /sup 0/C by using a static equilibrium cell. The systems benzene-methanol and thiophene-methanol are highly nonideal, while the system benzene-thiophene shows a very small deviation from ideality. The models suggested by Wilson and by Renon and Prausnitz (NRTL) and the modified equation of Abrams and Prausnitz (UNIQUAC) were used in the reduction of data. Physical parameters of these equations obtained from the binary data were used to predict the ternary system. The Wilson equation gives the best fit for the binary as well as the ternary data. Also, this equation gives the best prediction for the ternary system.

Triday, J.O.; Rodriguez, P.

1985-01-01T23:59:59.000Z

191

Economic analysis: impact of CS/R process on benzene market  

SciTech Connect (OSTI)

Contract No. DE-AC01-78ET10159 (formerly ET-78-C-01-3117) between UOP/SDC and the United States Department of Energy (DOE) requires UOP/SDC to provide specific engineering and technical services to the DOE Office of Coal Processing in support of the Coal Gasification Program. This report covers an economic study on the projected price of benzene through the next decade based on the market factors and production costs. The impact of the CS/R process on the benzene market was evaluated. In addition, the cost of gas from the CS/R process was determined as a function of the byproduct credit for benzene.

Spielberger, L.; Klein, J.

1981-05-01T23:59:59.000Z

192

Health Care Reform Challenge: Creating a High Performance Healthcare System  

E-Print Network [OSTI]

Health Care Reform Challenge: Creating a High Performance Healthcare System Tom Simmer, MD Chief;The Challenge of Reform: Accountable Care Organizations (ACO) · ACO's are provider organizations health care delivery Organized Systems of Care Population focus for primary care physicians, hospitals

Finley Jr., Russell L.

193

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high process converts low-octane gasoline blending compo- nents to high-octane components for use in high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

Skogestad, Sigurd

194

BREAKING WITH OR BUILDING ON THE PAST? REFORMING IRISH PUBLIC  

E-Print Network [OSTI]

of the application of new public management styles to Ireland. Particular attention is paid to the public serviceBREAKING WITH OR BUILDING ON THE PAST? REFORMING IRISH PUBLIC ADMINISTRATION: 1958-2008 Niamh? REFORMING IRISH PUBLIC ADMINISTRATION: 1958-2008 Niamh Hardiman and Muiris MacCarthaigh Working Papers

195

ISSN 1745-9648 Electricity Sector Reform in Greece  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Sector Reform in Greece by Ekaterini Iliadou Lawyer - Legal Department of the electricity market reform in Greece which started in 2001 and is still developing slowly. This is related to the persisting dominance of the incumbent company and the specificities of the electricity sector of Greece

Feigon, Brooke

196

Consulting Assistance on Economic Reform II Discussion Papers  

E-Print Network [OSTI]

Consulting Assistance on Economic Reform II Discussion Papers The objectives of the Consulting Assistance on Economic Reform (CAER II) project are to contribute to broad-based and sustainable economic, Bureau for Global Programs, Field Support and Research, Center for Economic Growth and Agricultural

197

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents [OSTI]

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

198

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents [OSTI]

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

199

Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content  

E-Print Network [OSTI]

Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content on the lifespan and maximum length of benzene plumes Diego E. Gomez1 and Pedro 10 March 2009. [1] A numerical model was used to evaluate how the concentration of ethanol

Alvarez, Pedro J.

200

THE JOURNAL OF CHEMICAL PHYSICS 134, 134701 (2011) Binding of hydrogen on benzene, coronene, and graphene from quantum  

E-Print Network [OSTI]

, and graphene from quantum Monte Carlo calculations Jie Ma,1,2,3 Angelos Michaelides,2,3,4 and Dario Alfè3 the binding energy curves of hydrogen on benzene, coronene, and graphene. The DMC results on benzene agree well with MP2, giving an adsorption energy of 40 meV. For physisorbed hydrogen on graphene, DMC

Alfè, Dario

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.

2003-05-21T23:59:59.000Z

202

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg

2003-05-01T23:59:59.000Z

203

Kinetics and modeling of mixture effects during complete catalytic oxidation of benzene and methyl tert-butyl ether  

SciTech Connect (OSTI)

The performance of a catalytic incinerator depends on the nature of the compounds being oxidized and cannot be predicted simply by knowing the performance of the incinerator with pure-component model compounds. Considering the importance of mixture effects, an attempt was made to develop a combined model to predict the conversion when benzene and methyl tert-butyl ether (MTBE) are simultaneously oxidized. Complete catalytic oxidation of benzene and MTBE, singly and in mixtures, was investigated over a platinum catalyst. No inhibition effects were seen with benzene, but MTBE conversion was distinctly inhibited by benzene. A Mars-van Krevelen rate model was used to explain the results. Model parameters were obtained from pure-component experiments and then incorporated into a multicomponent model without any adjustment or additional rate parameters. The multicomponent model was able to predict the conversion of benzene and MTBE oxidation in the binary mixture using the pure-component data without adjustable parameters.

Dangi, S.; Abraham, M.A. [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering] [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

204

Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of Alkyl Side  

E-Print Network [OSTI]

Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1Versity, Beijing 100871, China Received October 27, 2006 2-(2H-Tetrazol-5-yl)-1,10-phenanthroline (HL0 ), its alkyl) at the 2H position of the tetrazole ring, and their iron(II) complexes (a for [Fe(L0 )2], na for [Fe(Ln)2

Gao, Song

205

Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions  

DOE Patents [OSTI]

This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

Ginosar, Daniel M. (Idaho Falls, ID); Fox, Robert V. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2000-01-01T23:59:59.000Z

206

Alkylation of mixed olefins with isobutane in a stratco chemical reactor  

SciTech Connect (OSTI)

The 17 reaction model for the sulfuric acid alkylation of isobutane with propylene as proposed by Langley and Pike has been used to simulate the effluent refrigeration reactor. The simulation conditions selected to minimize the formation of light and heavy by-product were determined to be: Temperature: 9 - 10 {degrees}C,- Isobutane/Olefin Ratio: 8 - 10; % Volume of Acid: 50 %. The reactor effluent composition from the simulation program has been used to compare with several sets of published data with reasonable agreement. This model has been extrapolated to simulate the alkylation of isobutane with butylenes and amylenes. The model will be optimized with commercial data. 9 refs., 6 figs., 1 tab.

Vichailak, M. [ABB Lummus Global Inc., Houston, TX (United States); Hopper, J.R.; Yaws, C.L. [Lamar Univ., Beaumont, TX (United States); Pike, R.W. [Louisiana State Univ., Baton Rouge, LA (United States)

1996-12-31T23:59:59.000Z

207

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to the Department for Education's reformed GCSE subject content  

E-Print Network [OSTI]

's reformed GCSE subject content consultation - August 2013 Department for Education: Reformed GCSE subject's reformed GCSE subject content consultation. The proposed changes to science qualifications promote reform and have enclosed a copy for information. 1 ` Direct assessment' is based on the direct assessment

Rambaut, Andrew

208

MOVIE "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color)  

E-Print Network [OSTI]

, transportation, and health care. 8. Investigate how many of the reform proposals were in place twenty years afterMOVIE ­ "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color) SYNOPSIS Following the death of Mayor Harold Washington, residents and reformers of Chicago still hoped for continued reform in Chicago

Illinois at Chicago, University of

209

Physiologically Based Pharmacokinetic (PBPK) Modeling of Benzene in Humans: A Bayesian Approach  

E-Print Network [OSTI]

that are now often used in risk assessment to better extrapolate from experimental animals to humans and from hPhysiologically Based Pharmacokinetic (PBPK) Modeling of Benzene in Humans: A Bayesian Approach for variability among humans, the mathematical model must be integrated into a statistical framework

210

Two-dimensional 1,3,5-Tris(4-carboxyphenyl)benzene self-assembly at  

E-Print Network [OSTI]

Two-dimensional 1,3,5-Tris(4-carboxyphenyl)benzene self-assembly at the 1-phenyloctane and published work see http://pubs.rsc.org/en/journals/journalissues/tc. Two-dimensional (2D) self-assembly storage, selective ion exchange, high den- sity data storage, etc. Molecular self-assembly offers unique

Paris-Sud XI, Université de

211

Structure of hydrophobic hydration of benzene and hexafluorobenzene from first principles  

SciTech Connect (OSTI)

We report on the aqueous hydration of benzene and hexafluorobenzene, as obtained by carrying out extensive (>100 ps) first principles molecular dynamics simulations. Our results show that benzene and hexafluorobenzene do not behave as ordinary hydrophobic solutes, but rather present two distinct regions, one equatorial and the other axial, that exhibit different solvation properties. While in both cases the equatorial regions behave as typical hydrophobic solutes, the solvation properties of the axial regions depend strongly on the nature of the {pi}-water interaction. In particular, {pi}-hydrogen and {pi}-lone pair interactions are found to dominate in benzene and hexafluorobenzene, respectively, which leads to substantially different orientations of water near the two solutes. We present atomic and electronic structure results (in terms of Maximally Localized Wannier Functions) providing a microscopic description of benzene- and hexafluorobenzene-water interfaces, as well as a comparative study of the two solutes. Our results point at the importance of an accurate description of interfacial water in order to characterize hydration properties of apolar molecules, as these are strongly influenced by subtle charge rearrangements and dipole moment redistributions in interfacial regions.

Allesch, M; Schwegler, E; Galli, G

2006-10-23T23:59:59.000Z

212

Evaluation of Partial Oxidation Reformer Emissions  

SciTech Connect (OSTI)

In this study, a gasoline fuel processor and an ethanol fuel processor were operated under conditions simulating both startup and normal operation. Emissions were measured before and after the AGB in order to quantify the effectiveness of the burner catalyst in controlling emissions. The emissions sampling system includes CEM for O2, CO2, CO, NOx, and THC. Also, integrated gas samples are collected in evacuated canisters for hydrocarbon speciation analysis via GC. This analysis yields the concentrations of the hydrocarbon species required for the California NMOG calculation. The PM concentration in the anode burner exhaust was measured through the placement of a filter in the exhaust stream. The emissions from vehicles with fully developed on board reformer systems were estimated.

Unnasch, Stefan; Fable, Scott; Waterland, Larry

2006-01-06T23:59:59.000Z

213

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process is described for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling. 2 figures.

Chen, M.S.; Painter, C.F.; Pastore, S.P.; Roth, G.S.; Winchester, D.C.

1991-10-15T23:59:59.000Z

214

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling.

Chen, Michael S. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary S. (Trexlertown, PA); Winchester, David C. (Allentown, PA)

1991-01-01T23:59:59.000Z

215

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

SciTech Connect (OSTI)

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

216

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

217

The stability of coerced economic reform : the case of IPR  

E-Print Network [OSTI]

Theories in international relations posit, and empirical evidence has verified, that unwilling states can be compelled by another state or by an international institution to enact domestic policy reform. However, these ...

Wilcox, Trudy

2005-01-01T23:59:59.000Z

218

Fuel reforming for scramjet thermal management and combustion optimization  

E-Print Network [OSTI]

Fuel reforming for scramjet thermal management and combustion optimization E. DANIAU* , M. BOUCHEZ in a Scramjet combustion chamber. Another critical point is that mixing and combustion should be sufficiently

Paris-Sud XI, Université de

219

Petroleum Refinery Catalytic Reforming -- Cutting High Energy Costs  

E-Print Network [OSTI]

. It is essential that the operation and maintenance of these furnaces be optimized to minimize production costs. This paper describes the performance testing and evaluation of a set of ten refinery furnaces used to thermally drive several reforming reactors...

Viar, W. L.

1979-01-01T23:59:59.000Z

220

Process Reform, Security and Suitability- December 17, 2008  

Broader source: Energy.gov [DOE]

This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year.

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Before the House Committee on Oversight and Government Reform...  

Broader source: Energy.gov (indexed) [DOE]

Senior Advisor to the Secretary Before the House Committee on Oversight and Government Reform 2-11-15JohnMacWilliams FT HOGR.pdf More Documents & Publications Testimony Before...

222

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...  

Office of Environmental Management (EM)

Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3...

223

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Broader source: Energy.gov (indexed) [DOE]

X , H 2 2:15 pm Break 2:30 pm 3:45 pm X Arlene Anderson, 4:00 pm Adjourn Distributed Bio-Oil Reforming , National Renewable Energy Lab Investigation of Reaction Networks and...

224

Electricity Reform in Argentina: Lessons for Developing Countries  

E-Print Network [OSTI]

Argentina was one of the first countries in the world to implement a comprehensivereform of its electricity sector in the recent period. Among developing countries onlyChile has had a comparably comprehensive and successful reform. This paper traces...

Pollitt, Michael G.

2006-03-14T23:59:59.000Z

225

Faculty perceptions of presidential leadership in urban school reform  

E-Print Network [OSTI]

The study examined urban university faculty members’ perceptions of their presidents’ leadership role in urban school reform. The population for this study consisted of faculty members from five urban research universities. All of the universities...

McClendon, Rodney Prescott

2009-06-02T23:59:59.000Z

226

Argonne National Laboratory Chemical Engineering Division Catalysts for autothermal reforming  

E-Print Network [OSTI]

,110,861) awarded Oct 2000: CRADA w/H2Fuel to commercialize reformer Aug 2001: Began work on perovskite catalysts Feb 2002: CRADA w/Süd-Chemie to optimize catalyst performance Oct 2002: Demonstrated conversion

227

The Dynamics of Reform of India’s Federal System  

E-Print Network [OSTI]

very different set of policies, India has followed China inIssues in Tax Policy and Reform in India, paper presented atWater Disputes in India: Institutions and Policies,” in

Singh, Nirvikar

2007-01-01T23:59:59.000Z

228

Chemical simulation of hydrogen generation in a plasma fuel reformer  

E-Print Network [OSTI]

A model for a plasma fuel reformer or plasmatron has been developed. The model was based in a series of experiments realized at the Plasma Science and Fusion Center with such a plasmatron. The device is set up to produce ...

Margarit Bel, Nuria, 1977-

2004-01-01T23:59:59.000Z

229

Isle of Eigg : land reform, people, and power   

E-Print Network [OSTI]

An historiographical analysis of the present political debates regarding land reform in Scotland provides the point of departure for a case study of the Isle of Eigg and the 1997 purchase of the island by the Isle ofEigg ...

Morgan, Daniel Rhys

2000-07-20T23:59:59.000Z

230

ISSN 1745-9648 Organisation and Reforms of the  

E-Print Network [OSTI]

of liberalisation of the Slovenian electricity market to a large extent resembles what other EU countries were: electricity reform, restructuring, competition, South East Europe, liberalisation #12;2 Acknowledgements

Feigon, Brooke

231

A cross country analysis of electricity market reforms  

E-Print Network [OSTI]

econometric model based on Poisson regression with cross-section data covering 51 US states, 13 Canada states and 51 other countries. The results show that both the background of the chairperson of electricity market regulatory agency when reforms started...

Erdogdu, Erkan

2012-06-19T23:59:59.000Z

232

High Pressure Ethanol Reforming for Distributed Hydrogen Production  

Broader source: Energy.gov [DOE]

Presentation by S. Ahmed and S.H.D. Lee at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

233

On the role of delocalization in benzene: Theoretical and experimental investigation of the effects of strained ring fusion  

SciTech Connect (OSTI)

When an important compound`s discovery dates back as far as 1825, one would imagine that every facet of its chemical and physical properties has been illuminated in the meantime. Benzene, however, has not ceased to challenge the chemist`s notion of structure and bonding since its first isolation by Michael Faraday. This report is divided into the following six chapters: 1. Aromaticity -- Criteria, manifestations, structural limitations; 2. The role of delocalization in benzene; 3. The thermochemical properties of benzocyclobutadienologs; 4. Ab initio study of benzenes fused to four-membered rings; 5. Non-planar polycyclic aromatic hydrocarbons; and 6. Experimental details and input decks. 210 Refs.

Faust, R. [Lawrence Berkeley Lab., CA (United States). Chemical Sciences Div.; [California Univ., Berkeley, CA (United States). Dept. of Chemistry

1993-04-01T23:59:59.000Z

234

Evaluation of reformed methanol as an automotive engine fuel  

E-Print Network [OSTI]

EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December... 1903 Major Subject: Mechanical Engineering EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Approved as to style and content by: Dr. T. R. Lalk (Chairman o f Committee ) Dr. R. R. Davison (Member...

McCall, David M

1983-01-01T23:59:59.000Z

235

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

SciTech Connect (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

236

Effect of alkyl glycerophosphate on the activation of peroxisome proliferator-activated receptor gamma and glucose uptake in C2C12 cells  

SciTech Connect (OSTI)

Highlights: •Alkyl-LPA specifically interacts with PPAR?. •Alkyl-LPA treatments induces lipid accumulation in C2C12 cells. •Alkyl-LPA enhanced glucose uptake in C2C12 cells. •Alkyl-LPA-treated C2C12 cells express increased amounts of GLUT4 mRNA. •Alkyl-LPA is a novel therapeutic agent that can be used for the treatment of obesity and diabetes. -- Abstract: Studies on the effects of lipids on skeletal muscle cells rarely examine the effects of lysophospholipids. Through our recent studies, we identified select forms of phospholipids, such as alkyl-LPA, as ligands for the intracellular receptor peroxisome proliferator-activated receptor gamma (PPAR?). PPAR? is a nuclear hormone receptor implicated in many human diseases, including diabetes and obesity. We previously showed that alkyl-LPA is a specific agonist of PPAR?. However, the mechanism by which the alkyl-LPA–PPAR? axis affects skeletal muscle cells is poorly defined. Our objective in the present study was to determine whether alkyl-LPA and PPAR? activation promotes glucose uptake in skeletal muscle cells. Our findings indicate that PPAR?1 mRNA is more abundant than PPAR?2 mRNA in C2C12 cells. We showed that alkyl-LPA (3 ?M) significantly activated PPAR? and increased intracellular glucose levels in skeletal muscle cells. We also showed that incubation of C2C12 cells with alkyl-LPA led to lipid accumulation in the cells. These findings suggest that alkyl-LPA activates PPAR? and stimulates glucose uptake in the absence of insulin in C2C12 cells. This may contribute to the plasma glucose-lowering effect in the treatment of insulin resistance.

Tsukahara, Tamotsu, E-mail: ttamotsu@shinshu-u.ac.jp [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Haniu, Hisao [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Matsuda, Yoshikazu [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)] [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)

2013-04-12T23:59:59.000Z

237

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

SciTech Connect (OSTI)

In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential p

Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

2010-11-05T23:59:59.000Z

238

Benzene Exposure and Risk of Non-Hodgkin Lymphoma Martyn T. Smith, Rachael M. Jones, and Allan H. Smith  

E-Print Network [OSTI]

Benzene Exposure and Risk of Non-Hodgkin Lymphoma Martyn T. Smith, Rachael M. Jones, and Allan H. Smith Center for Occupational and Environmental Health, School of Public Health, University

California at Berkeley, University of

239

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg; K. M. Shaber

2003-05-01T23:59:59.000Z

240

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

2003-05-21T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Improve syngas production using autothermal reforming  

SciTech Connect (OSTI)

Synthesis gas or syngas, i.e., mixtures of CO and H[sub 2], is a major route from hydrocarbons to many important bulk chemicals ranging from acetic acid to ammonia. Syngas conversion uses hydrocarbon feedstocks, steam, O[sub 2] and CO[sub 2], either separately or in combinations. Autothermal reforming (ATR) is a low-investment process using a simple reactor design. The process is soot-free due to burner design and fixed-bed catalyst. Developed in the late '50s, ATR's main application was for ammonia and methanol syntheses. In ammonia plants, hydrogen production was maximized by operating at high H[sub 2]O/C ratios ranging from 2.5 to 3.5 mole/mole. In methanol units, CO[sub 2] recycle adjusted the syngas composition. ATR is also used to co-produce CO and H[sub 2] as separate streams at H[sub 2]O/C ratios of 1.4 to 2.0 mole/mole. recent developments and optimizations allow cost-effective operation at very low H[sub 2]O/C feed ratios to produce CO-rich syngas. The paper describes the process, including feedstocks and reactor design, the chemical reactions, development and improvements to the process, test results, soot formation, burner design, burner testing, applications, thermodynamic calculations, industrial application, noncatalytic and catalytic partial oxidation, and future uses.

Christensen, T.S.; Primdahl, I.I. (Haldor Topsoe, Copenhagen (Denmark))

1994-03-01T23:59:59.000Z

242

Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities  

SciTech Connect (OSTI)

Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2012-07-01T23:59:59.000Z

243

Determination of a peak benzene exposure to consumers at typical self-service gasoline stations  

E-Print Network [OSTI]

. LITERATURE REVIEW Gasoline is a complex mixture of various volatile hydrocarbons blended with several additives depend1ng on the grade of gasoline desired. The goal in blending gasoline 1s to meet two criteria: l) improve antiknock performance, and 2.... This was due to differences in blending. Those identified hydrocarbons amounted to 98 percent, by weight, of the liquid gasoline sample. Benzene in Liquid Gasoline In 1928, Askey , reported that gasolines in West California 2 might contain as much as 17...

Carapezza, Ted

2012-06-07T23:59:59.000Z

244

Autoignition of toluene and benzene at elevated pressures in a rapid compression machine  

SciTech Connect (OSTI)

Autoignition of toluene and benzene is investigated in a rapid compression machine at conditions relevant to HCCI (homogeneous charge compression ignition) combustion. Experiments are conducted for homogeneous mixtures over a range of equivalence ratios at compressed pressures from 25 to 45 bar and compressed temperatures from 920 to 1100 K. Experiments varying oxygen concentration while keeping the mole fraction of toluene constant reveal a strong influence of oxygen in promoting ignition. Additional experiments varying fuel mole fraction at a fixed equivalence ratio show that ignition delay becomes shorter with increasing fuel concentration. Moreover, autoignition of benzene shows significantly higher activation energy than that of toluene. In addition, the experimental pressure traces for toluene show behavior of heat release significantly different from the results of Davidson et al. [D.F. Davidson, B.M. Gauthier, R.K. Hanson, Proc. Combust. Inst. 30 (2005) 1175-1182]. Predictability of various detailed kinetic mechanisms is also compared. Results demonstrate that the existing mechanisms for toluene and benzene fail to predict the experimental data with respect to ignition delay and heat release. Flux analysis is further conducted to identify the dominant reaction pathways and the reactions responsible for the mismatch of experimental and simulated data. (author)

Mittal, Gaurav; Sung, Chih-Jen [Department of Mechanical and Aerospace Engineering, Case Western Reserve University, Cleveland, OH 44106 (United States)

2007-09-15T23:59:59.000Z

245

Adsorption characteristics of benzene on biosolid adsorbent and commercial activated carbons  

SciTech Connect (OSTI)

This study selected biosolids from a petrochemical wastewater treatment plant as the raw material. The sludge was immersed in 0.5-5 M of zinc chloride (ZnCl{sub 2}) solutions and pyrolyzed at different temperatures and times. Results indicated that the 1-M ZnCl{sub 2}-immersed biosolids pyrolyzed at 500{sup o}C for 30 min could be reused and were optimal biosolid adsorbents for benzene adsorption. Pore volume distribution analysis indicated that the mesopore contributed more than the macropore and micropore in the biosolid adsorbent. The benzene adsorption capacity of the biosolid adsorbent was 65 and 55% of the G206 (granular-activated carbon) and BPL (coal-based activated carbon; Calgon, Carbon Corp.) activated carbons, respectively. Data from the adsorption and desorption cycles indicated that the benzene adsorption capacity of the biosolid adsorbent was insignificantly reduced compared with the first-run capacity of the adsorbent; therefore, the biosolid adsorbent could be reused as a commercial adsorbent, although its production cost is high. 18 refs., 9 figs., 3 tabs.

Hung-Lung Chiang; Kuo-Hsiung Lin; Chih-Yu Chen; Ching-Guan Choa; Ching-Shyung Hwu; Nina Lai [China Medical University, Taichung (Taiwan). Department of Risk Management

2006-05-15T23:59:59.000Z

246

Removal patterns of some alkyl phenyl ketones in a heterogeneous bacterial system  

E-Print Network [OSTI]

never lrave been wri t ten, I can only say thank you. TABLE OF CONTENTS pacCe ABSTRACT ACKNONLEDGEMENTS iLIST OF TABLES LIST OF FIGURES SECTION I Introduction and Literature Review SECTION II Apparatus and Materials Reactor Gas Chromatograph... 2 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3 0 Gas Gas Gas Gas Gas Gas Gas Gas Gas hyl Alkyl Gas Gas Gas Gas Chemical Nomenclature Inorganic i'Jutrients Test A. Reactor Conditions Test A...

Salitros, James Joseph

1969-01-01T23:59:59.000Z

247

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

248

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

249

The use of advanced steam reforming technology for hydrogen production  

SciTech Connect (OSTI)

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturing site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.

Abbishaw, J.B.; Cromarty, B.J. [ICI Katalco, Billingham (United Kingdom)

1996-12-01T23:59:59.000Z

250

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-01-01T23:59:59.000Z

251

Nuclear magnetic resonance (N.M.R.) studies of alkyl formates and of alcohol-water azeotropes  

E-Print Network [OSTI]

from Eq. 2 for 12 Alkyl Formates in Carbon tetrachloride at 37'. Typical N. M. R. Spectrum of a Non-Azeotropic Ethanol- Water Mixture . 16 N. M. R. Spectrum Occasionally Found for Azeotropic Ethanol-Water Mixtures 17 PART I. ALKYL FORMATES... CHAPTER I. INTRODUCTION 1 It has been shown that eq. 1 applies almost exactly to the data for the alkaline hydrolysis of 9 acetate eaters (CH COOR ) in 40% 0 aqueous p - dioxane at 35 . In eq. 1, k is the second-order rate log k = l. 35 + 0. 688 o + 0...

O'Brien, Patrick William

2012-06-07T23:59:59.000Z

252

High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate  

SciTech Connect (OSTI)

Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

None

2009-12-01T23:59:59.000Z

253

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

leg) 8 2004 DEER Conference September 2, 2004 Experimental Setup NOx Trap Engine Reformer Diesel Air Power NOx Trap NOx Trap Engine NOx Trap Diesel Diesel Fuel Reformer Setup...

254

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

255

Bargaining in the Chinese Leviathan: An Examination on the Steel Industry after China's SOE Reform  

E-Print Network [OSTI]

This thesis centers on the competitions between enterprises in the steel industry in China after the SOE (state-owned enterprises) reform, which can be viewed as a case for mass economic reforms within Chinese Leviathan. To examine the effect...

Li, Zichao

2010-06-28T23:59:59.000Z

256

The Lessons of Practice: Domestic Policy Reform as a Way to Address...  

Open Energy Info (EERE)

Practice: Domestic Policy Reform as a Way to Address Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Lessons of Practice: Domestic Policy Reform as a...

257

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

258

A Comparative Study between Co and Rh for Steam Reforming of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

between Co and Rh for Steam Reforming of Ethanol. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Abstract: Rh and Co-based catalyst performance was compared...

259

Voluntary Disclosure and Information Asymmetry: Evidence from the 2005 Securities Offering Reform  

E-Print Network [OSTI]

In 2005, the Securities and Exchange Commission enacted the Securities Offering Reform (Reform), which relaxes “gun-jumping” restrictions, thereby allowing firms to more freely disclose information before equity offerings. ...

SHROFF, NEMIT

260

Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques with an empirical application to Vietnam  

E-Print Network [OSTI]

of Copenhagen and RDRC ABSTRACT Globalization poses special challenges for economies in transition, particularly1 Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques undermine reform and structural adjustments efforts in this important emerging Asian economy. Key words

Kammen, Daniel M.

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

E-Print Network 3.0 - agricultural price reforms Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

T Y J A N U A R Y 1 1 , 2 0 1 0 You Get What You Pay For: The Obama Approach to Health Care Reform 12... fundamental issues in health care reform 12;Coverage is actually quite...

262

From negotiation to auction : Land-Conveyance Reform in China and its institutional and social impacts  

E-Print Network [OSTI]

The land market and the associated land-development-control mechanism in China have been experiencing a series of reforms since the 1990s, of which Land Conveyance Reform (LCR) in 2004 is a very recent and an important ...

Chen, Zhiyu (Zhiyu Jerry)

2007-01-01T23:59:59.000Z

263

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

SciTech Connect (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

264

Steam methane reforming in molten carbonate salt. Final report  

SciTech Connect (OSTI)

This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

Erickson, D.C.

1996-05-01T23:59:59.000Z

265

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

266

High performance internal reforming unit for high temperature fuel cells  

DOE Patents [OSTI]

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

267

Heat exchanger for fuel cell power plant reformer  

DOE Patents [OSTI]

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

268

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS*  

E-Print Network [OSTI]

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS* Zack Cooper, Stephen Gibbons, Simon Jones and Alistair McGuire Recent substantive reforms to the English with fixed prices. This study investigates whether these reforms led to improvements in hospital quality. We

Mateo, Jill M.

269

Even if it's not Bribery: The Case for Campaign Finance Reform  

E-Print Network [OSTI]

Even if it's not Bribery: The Case for Campaign Finance Reform Brendan Daley Erik Snowberg Duke reform alleviates this phenomenon and improves voter welfare at the expense of politicians. Thus, we expect successful politicians to oppose true campaign finance reform. We also show our model

Jensen, Grant J.

270

Copyright reform on the EU level European Network for Copyright in support of  

E-Print Network [OSTI]

Copyright reform on the EU level European Network for Copyright in support of Education and Budapest Business School #12;Copyright reform on the EU level What can science and education expect from a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR

Kuhlen, Rainer

271

BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA  

E-Print Network [OSTI]

107 BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA OR THE SEARCH FOR A "MODERN" of the country. The dominant role of secularist elites paved the way for the "reform of Islam." This process in the organization and reform of official religious institutions. For example, it interfered in the organization

Boyer, Edmond

272

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England  

E-Print Network [OSTI]

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 1 Department for Education: Reform of the National Curriculum in England CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 2

Rambaut, Andrew

273

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network [OSTI]

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

Mallinson, Richard

274

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa  

E-Print Network [OSTI]

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa , N. Baillya , M was designed to be operated in pure methane, without reforming or carrier gas. The fuel cell was built up from-CGO catalytic layer. The operation principle is based on Gradual Internal Reforming. After an initiation in H2

Boyer, Edmond

275

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation -August 2013  

E-Print Network [OSTI]

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation - August 2013 1 Ofqual: GCSE reform consultation Response by the Wellcome Trust August 2013 Key points and indirect practical assessment in its reform proposals. The total contribution of direct and indirect

Rambaut, Andrew

276

August 15, 2013 Bargaining Update 8: UC stresses fair compensation and reasonable pension reform  

E-Print Network [OSTI]

reform UC stressed with the California Nurses Association on Aug. 6-8, 2013 the need to reach a fair's market. UC's pension reform proposal calls for: · Employees hired before July 1, 2013: UC would in substantive negotiations over responsible and necessary pension reform. CNA has not accepted UC's pension

Leistikow, Bruce N.

277

Inequality and the Politics of Social Policy Implementation: Gender, Age and Chile's 2004 Health Reforms  

E-Print Network [OSTI]

Reforms CHRISTINA EWIG and GASTO´ N A. PALMUCCI * University of Wisconsin-Madison, USA Summary implementation. We examine the 2004 Chilean health reforms that sought to regulate private insurers, and measure their effects on gender and age inequality. We find that reforms intended to decrease these inequalities largely

Wisconsin at Madison, University of

278

Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1  

E-Print Network [OSTI]

1 Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1 Mark Guzdial1, Matthew educational reform efforts, but there are many challenges to face before achieving that vision. Two attempting to use this tool to leverage a particular kind of educational reform goal: Achieving integration

Guzdial, Mark

279

SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR  

E-Print Network [OSTI]

process of a solar reformer of dry methane reforming was proposed to operate in a temperature range of 600SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR Khalid Al-Ali 1 including lower melting point, thermal and chemical stability, acting simultaneously as heat transport

Paris-Sud XI, Université de

280

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC  

E-Print Network [OSTI]

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC Hugh Rudnick for a second stage of reform, establishing highly flexible mechanisms of decentralised exchanges, and achieving about the validity of this new paradigm for second stage reforms. They question themselves

Catholic University of Chile (Universidad Católica de Chile)

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Method for improving catalyst function in auto-thermal and partial oxidation reformer-based processors  

DOE Patents [OSTI]

The invention provides a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H.D.; Ahluwalia, Rajesh K.

2014-08-26T23:59:59.000Z

282

2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting  

E-Print Network [OSTI]

Biogas reformation Shift reactorShift reactor Selective oxidation of COSelective oxidation of CO Fuel cellFuel cell2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts Hua Song Lingzhi Zhang Umit S

283

Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State Universities  

E-Print Network [OSTI]

situation: health care and retirement. First, Medicaid expenditures, already a substantial share of state1 Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State errors, are those of the authors alone. I.The Urgent Need for Reform Public pension reform is a national

Illinois at Chicago, University of

284

PHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011  

E-Print Network [OSTI]

and describe two state-based reforms underway in Wisconsin's health care industry. Topics/Readings The Big Patient Protection and Affordable Care Act Current State-Level Trends and Health Reforms The SyllabusPHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011 Course Overview

Sheridan, Jennifer

285

Health Care Reform: What School Mental Health Professionals Need to Know  

E-Print Network [OSTI]

Health Care Reform: What School Mental Health Professionals Need to Know On March 23, 2010, President Obama signed comprehensive health care reform, the Patient Protection and Affordable Care Act (ACA), into law (P.L. 111-148). This major reform to health care certainly has had and will continue to have

Weber, David J.

286

The effect of reformate gas enrichment on extinction limits and NOX formation  

E-Print Network [OSTI]

premixed combustion. When the reformate gas is added, the formation of NO is reduced in a near advantage of the reformate gas enriched lean premixed combustion is that it greatly reduces the formation combustion; Fuel enrichment; NOX; Extinction limit; Reformate gas 1. Introduction Lean premixed combustion

Gülder, �mer L.

287

Carbon?Oxygen Bond Forming Mechanisms in Rhenium Oxo-Alkyl Complexes  

SciTech Connect (OSTI)

Three C?X bond formation mechanisms observed in the oxidation of (HBpz{sub 3})ReO(R)(OTf) [HBpz{sub 3} = hydrotris(1-pyrazolyl)borate; R = Me, Et, and iPr; OTf = OSO{sub 2}CF{sub 3}] by dimethyl sulfoxide (DMSO) were investigated using quantum mechanics (M06//B3LYP DFT) combined with solvation (using the PBF Poisson?Boltzmann polarizable continuum solvent model). For R = Et we find the alkyl group is activated through ?-hydrogen abstraction by external base OTf{sup ?} with a free energy barrier of only 12.0 kcal/mol, leading to formation of acetaldehyde. Alternatively, ethyl migration across the M?O bond (leading to the formation of acetaldehyde and ethanol) poses a free energy barrier of 22.1 kcal/mol, and the previously proposed ?-hydrogen transfer to oxo (a 2+2 forbidden reaction) poses a barrier of 44.9 kcal/mol. The rate-determining step to formation of the final product acetaldehyde is an oxygen atom transfer from DMSO to the ethylidene, with a free energy barrier of 15.3 kcal/mol. When R = iPr, the alkyl 1,2-migration pathway becomes the more favorable pathway (both kinetically and thermodynamically), with a free energy barrier (?G{sup ?} = 11.8 kcal/mol) lower than ?-hydrogen abstraction by OTf{sup ?} (?G{sup ?} = 13.5 kcal/mol). This suggests the feasibility of utilizing this type of migration to functionalize M?R to M?OR. We also considered the nucleophilic attack of water and ammonia on the Re-ethylidene ?-carbon as a means of recovering two-electron-oxidized products from an alkane oxidation. Nucleophilic attack (with internal deprotonation of the nucleophile) is exothermic. However, the subsequent protonolysis of the Re?alkyl bond (to liberate an alcohol or amine) poses a barrier of 37.0 or 42.4 kcal/mol, respectively. Where comparisons are possible, calculated free energies agree very well with experimental measurements.

Cheng, Mu-Jeng; Nielsen, Robert J; Ahlquist, Marten; Goddard, William A

2010-01-01T23:59:59.000Z

288

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect (OSTI)

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

289

Mobility of Supercooled liquid Toluene, Ethylbenzene, and Benzene near their Glass Transition Temperatures Investigated using Inert Gas Permeation  

SciTech Connect (OSTI)

We investigate the mobility of supercooled liquid toluene, ethylbenzene, and benzene near their respective glass transition temperatures (Tg). The permeation rate of Ar, Kr, and Xe through the supercooled liquid created when initially amorphous overlayers heated above their glass transition temperature is used to determine the diffusivity. Amorphous benzene crystallizes at temperatures well below its Tg and as a result the inert gas underlayer remains trapped until the onset of benzene desorption. In contrast, for toluene and ethylbenzene the onset of inert gas permeation is observed at temperatues near Tg. The inert gas desorption peak temperature as a function of the heating rate and overlayer thickness is used to quantify the diffusivity of supercooled liquid toluene and ethylbenzene from 115 K to 135 K. In this temperature range, diffusivities are found to vary across five orders of magnitude (~10-14 to 10-9 cm2/s). These data are compared to viscosity measurements and used to determine the low temperature fractional Stokes-Einstein exponent. Efforts to determine the diffusivity of a mixture of benzene and ethylbenzene are detailed, and the effect of mixing these materials on benzene crystallization is explored using infrared spectroscopy.

May, Robert A.; Smith, R. Scott; Kay, Bruce D.

2013-11-21T23:59:59.000Z

290

Acute toxicity of toluene, hexane, xylene, and benzene to the rotifers Brachionus calyciflorus and Brachionus plicatilis  

SciTech Connect (OSTI)

A large number of studies on the biological effects of oil pollution in the aquatic environment deal with the effects of whole crude or refined oils or their water-soluble fractions. However, low boiling, aromatic hydrocarbons, which are probably the most toxic constituents of oil, have until now not been examined in sufficient detail. Toluene, benzene and xylene, constitute a major component of various oils. They may be readily lost by weathering but are toxic in waters that are relatively stagnant and are chronically polluted. Korn et al. have stated that toluene is more toxic than many other hydrocarbons such as benzene, though the latter are more water-soluble. Report of the effects of exposure to organic solvents like hexane or toluene are still limited although organic solvents are a well-known group of neurointoxicants. Various benzene derivates continue to be used as chemical intermediates, solvents, pesticides, so on, in spite of incomplete knowledge of their chronic toxicity. The majority of toxicity studies about the effects of pollution on aquatic organisms under controlled conditions have used either fish or the cladoceran Daphnia magna and there are few studies reported using rotifers. The effects of herbicides on population variables of laboratory rotifer cultures have been investigated. Rotifers are one of the main sources of zooplankton production and they have an important ecological significance in the aquatic environment. The present work was designed to investigate the effect of short-term exposure to some petroleum derivates which might be expected to occur immediately under an oil-slick, on freshwater and brackish environment rotifers. 18 refs., 1 tab.

Ferrando, M.D.; Andreu-Moliner, E. (Univ. of Valencia (Spain))

1992-08-01T23:59:59.000Z

291

Reactions of the CN Radical with Benzene and Toluene: Product Detection and Low-Temperature Kinetics  

SciTech Connect (OSTI)

Low temperature rate coefficients are measured for the CN + benzene and CN + toluene reactions using the pulsed Laval nozzle expansion technique coupled with laser-induced fluorescence detection. The CN + benzene reaction rate coefficient at 105, 165 and 295 K is found to be relatively constant over this temperature range, 3.9 - 4.9 x 10-10 cm3 molecule-1 s-1. These rapid kinetics, along with the observed negligible temperature dependence, are consistent with a barrierless reaction entrance channel and reaction efficiencies approaching unity. The CN + toluene reaction is measured to have a slower rate coefficient of 1.3 x 10-10 cm3 molecule-1 s-1 at 105 K. At room temperature, non-exponential decay profiles are observed for this reaction that may suggest significant back-dissociation of intermediate complexes. In separate experiments, the products of these reactions are probed at room temperature using synchrotron VUV photoionization mass spectrometry. For CN + benzene, cyanobenzene (C6H5CN) is the only product recorded with no detectable evidence for a C6H5 + HCN product channel. In the case of CN + toluene, cyanotoluene (NCC6H4CH3) constitutes the only detected product. It is not possible to differentiate among the ortho, meta and para isomers of cyanotoluene because of their similar ionization energies and the ~;; 40 meV photon energy resolution of the experiment. There is no significant detection of benzyl radicals (C6H5CH2) that would suggest a H-abstraction or a HCN elimination channel is prominent at these conditions. As both reactions are measured to be rapid at 105 K, appearing to have barrierless entrance channels, it follows that they will proceed efficiently at the temperatures of Saturn?s moon Titan (~;;100 K) and are also likely to proceed at the temperature of interstellar clouds (10-20 K).

Trevitt, Adam J.; Goulay, Fabien; Taatjes, Craig A.; Osborn, David L.; Leone, Stephen R.

2009-12-23T23:59:59.000Z

292

The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol  

SciTech Connect (OSTI)

The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

1990-02-01T23:59:59.000Z

293

Alkyl nitrate (C1-C3) depth profiles in the tropical Pacific Ocean E. E. Dahl,1,2  

E-Print Network [OSTI]

and distribution of tropo- spheric ozone. Atmospheric alkyl nitrates are normally associated with polluted air free radical processes initiated by radioactive decay or cosmic rays, enzymatically mediated reactions expedition in the equatorial Pacific, an equatorial maximum in atmospheric ethyl and isopropyl nitrate

Saltzman, Eric

294

J. CHEM. SOC. DALTON TRANS. 1984 2789 12-Bis(dimethy1phosphino)ethane (dmpe) Alkyl Compounds of  

E-Print Network [OSTI]

gives the dialkyldichloro-complex ZrMe,Cl,(dmpe),, whereas interaction with excess LiMe gives the tetraMe,, prepared by alkylation of TiCI, with methyl-lithium at -70 "C.' Unfortunately, this complex decomposes above -70 OC,' and thus little is known concerning its properties. The zirconium analogue ZrMe, is even

Girolami, Gregory S.

295

Aggregation of hexylammonium propionate in DMSO-benzene and DMSO-D?O solvent systems  

E-Print Network [OSTI]

Fig. 18. Aggregation number plots for HAP in 75@a DpO/25$ DMSO-de ~ 72 3. 0 CHg (CH p ) 4CH pNH 3 2. 00 1. 00 ~ 0. 00 I A U 0 i 3. 00 + CHp (CHg) 4CHpNH3 0 0 2. 00 1. 00 0. 0 1. 00 1. 20 1. 40 1. 60 1. 80 2. 00 2 + log tS] 73 Fig... The relationships between a micelle forming surfactant, hexylammonium propionate (1), and the overlapping mixed solvent systems of benzene/dimethyl- sulfoxide/water have been investigated using 'H nuclear magnetic resonance techniques. The changes in t' he...

Constein, Vernon George

1974-01-01T23:59:59.000Z

296

energy savings by the use of mtbe to replace alkylate in automotive gasolines  

SciTech Connect (OSTI)

This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

1986-07-01T23:59:59.000Z

297

Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide  

E-Print Network [OSTI]

The largest non-cyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of its straight-chain structural isomer. This detection suggests that branched carbon-chain molecules may be generally abundant in the ISM. Our astrochemical model indicates that both isomers are produced within or upon dust grain ice mantles through the addition of molecular radicals, albeit via differing reaction pathways. The production of iso-propyl cyanide appears to require the addition of a functional group to a non-terminal carbon in the chain. Its detection therefore bodes well for the presence in the ISM of amino acids, for which such side-chain structure is a key characteristic.

Belloche, Arnaud; Müller, Holger S P; Menten, Karl M

2014-01-01T23:59:59.000Z

298

ISSN 1745-9648 The Impact of Electricity Market Reform  

E-Print Network [OSTI]

ISSN 1745-9648 The Impact of Electricity Market Reform on Consumers by Catherine Waddams Price ESRC, University of East Anglia CCP Working Paper 08-7 Abstract: We examine the effect of current electricity, where household expenditure surveys and electricity tariffs are available, we analyse the effects

Feigon, Brooke

299

French public management reform: an evaluation Gilles Jeannot, Danile Guillemot  

E-Print Network [OSTI]

shared opposition in principle to certain New Public Management precepts (especially benchmarking1 French public management reform: an evaluation Gilles Jeannot, Danièle Guillemot International journal of public sector management, vol 26, n° 4, 2013, p. 283-297 Comparative research depicts France

Paris-Sud XI, Université de

300

Argonne Electrochemical Technology Program Sulfur removal from reformate  

E-Print Network [OSTI]

Argonne Electrochemical Technology Program Sulfur removal from reformate Xiaoping Wang, Theodore Krause, and Romesh Kumar Chemical Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure Technologies 2003 Merit Review Berkeley, CA May 19-22, 2003 #12;Argonne Electrochemical Technology

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301

Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming  

E-Print Network [OSTI]

-gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

Kuncharam, Bhanu Vardhan

2013-11-26T23:59:59.000Z

302

DFMA Cost Estimates of Fuel-Cell/Reformer Systems  

E-Print Network [OSTI]

Page 1 DFMA Cost Estimates of Fuel-Cell/Reformer Systems at Low/Medium/High Production Rates Brian system · Direct hydrogen fuel cell system (with 5kpsi H2 storage) 2. Determine costs for system ·Fuel cell stacks ·Air supply and humidification ·Thermal management ·Water management ·Fuel Supply

303

Steam Reforming of Low-Level Mixed Waste  

SciTech Connect (OSTI)

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

304

ISSN 1745-9648 Electricity Reform in Serbia  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Reform in Serbia by Sandra Jednak Faculty of Organizational Sciences in Serbia have been started, and certain results were achieved. But, the electric power infrastructure decided whether the Serbian Electric Power Industry will be privatised, and if it is privatised which

Feigon, Brooke

305

ISSN 1745-9648 Electricity Reform in Romania  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Reform in Romania by Oana Diaconu Department of Economics and Management-11 Abstract: Romania is a net exporter of electricity to the SE Europe region. Its performance of this role for international transmission. Romania has committed itself to an electricity restructuring plan that includes

Feigon, Brooke

306

The Clean Development Mechanism and Power Sector Reforms in Developing  

E-Print Network [OSTI]

regions include stimulating private sector financing, increasing operational and managerial efficiencies and lowering electricity tariffs #12;The CDM and renewable energy · Power sector reforms could potentially require higher investments for electricity generation than conventional fuel projects · Can also offer

307

ISSN 1745-9648 Potential Impact of Electricity Reforms on  

E-Print Network [OSTI]

reforming her energy sector in line with EU Energy Acquis since 2001. Introducing a cost reflective tariff Bagdadioglu Department of Public Finance, Hacettepe University & Alparslan Basaran Department of Public for price changes, and consumption information from the 2003 Turkish Household Expenditure Survey. Turkey

Feigon, Brooke

308

Integrated autothermal reactor concepts for oxidative coupling and reforming of  

E-Print Network [OSTI]

#12;Integrated autothermal reactor concepts for oxidative coupling and reforming of methane #12-90-365-2985-3, DOI 10.3990/1.9789036529853 #12;INTEGRATED AUTOTHERMAL REACTOR CONCEPTS FOR OXIDATIVE COUPLING . . . . . . . . . . . . . . . . . . . . 31 2.5 Dual function catalyst particle . . . . . . . . . . . . . . . . . . . . . . 34 2.6 Autothermal

Twente, Universiteit

309

The Role of Informatics in Health Care Reform  

E-Print Network [OSTI]

The Role of Informatics in Health Care Reform Yueyi I. Liu, MD, PhD, Daniel L. Rubin, MD, MS Improving health care quality while simultaneously reducing cost has become a high priority of health care (such as radiation dose tracking) and quality initiatives. Key Words: Informatics; health care. ª

Rubin, Daniel L.

310

Healthcare Reform in Texas: How the Affordable Care Act (ACA)  

E-Print Network [OSTI]

Healthcare Reform in Texas: How the Affordable Care Act (ACA) Will Impact Small Employer Health requirements, the function of health insurance exchanges and the future of employer-sponsored health insurance Shield of Texas Katrina Daniel Associate Commissioner, Life, Accident and Health Section Regulatory

O'Toole, Alice J.

311

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network [OSTI]

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

Collins, Gary S.

312

First Generation Indian External Sector Reforms in Context  

E-Print Network [OSTI]

India's first generation external sector reforms are a fascinating case study of emergence from a post-Independence socialist-style economy to the world’s largest free market democracy. Part I of this article reviews the Indian license Raj system...

Bhala, Raj

2013-01-01T23:59:59.000Z

313

Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production  

SciTech Connect (OSTI)

Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

2006-04-19T23:59:59.000Z

314

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to the NHS Future Forum inquiry into the NHS reforms  

E-Print Network [OSTI]

into the NHS reforms October 2011 1 NHS Future Forum: Inquiry into the NHS reforms Response by the Wellcome focus primarily on the impact of the reforms on health research and innovation, which run throughout the Future Forum's four themes. 3. The reforms of the NHS and public health systems must bring about

Rambaut, Andrew

315

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to Department for Education: Reforming Key Stage 4 qualifications  

E-Print Network [OSTI]

: Reforming Key Stage 4 qualifications December 2012 Department for Education: Reforming Key Stage 4 science skills. 2. We are pleased to have the opportunity to respond to the consultation on reforms to Key consultations on the reform to curriculum and assessment at various stages of schooling. There is an opportunity

Rambaut, Andrew

316

Negative Valve Overlap Reforming Chemistry in Low-Oxygen Environments  

SciTech Connect (OSTI)

Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed. The other experimental facility, located at Sandia National Laboratories, uses a dump valve to capture the exhaust from a single NVO event for analysis. Results from the two experiments are in excellent trend-wise agreement and indicate that the reforming process under low-O2 conditions produces substantial concentrations of H2, CO, methane, and other short-chain hydrocarbon species. The concentration of these species is found to be strongly dependent on fuel injection timing and injected fuel type, with weaker dependencies on NVO duration and initial temperature, indicating that NVO reforming is kinetically slow. Further, NVO reforming does not require a large energy input from the engine, meaning that it is not thermodynamically expensive. The implications of these results on HCCI and other forms of combustion are discussed in detail.

Szybist, James P [ORNL] [ORNL; Steeper, Richard R. [Sandia National Laboratories (SNL)] [Sandia National Laboratories (SNL); Splitter, Derek A [ORNL] [ORNL; Kalaskar, Vickey B [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

2014-01-01T23:59:59.000Z

317

Exposure to methyl tert-butyl ether, benzene, and total hydrocarbons at the Singapore-Malaysia causeway immigration checkpoint  

SciTech Connect (OSTI)

The primary aim of this study was to determine the extent and levels of exposure to volatile organic compounds (VOCs) from automobile emissions in a group of immigration officers at a busy cross-border checkpoint. A majority (80%) of the workers monitored were exposed to benzene at levels between 0.01 and 0.5 ppm, with only 1.2% exceeding the current Occupational Safety and Health Administration occupational exposure limit of 1 ppm. The geometric mean (GM) concentrations of 8-hr time-weighted average exposure were 0.03 ppm, 0.9 ppm, and 2.46 ppm for methyl-tert-butyl ether (MTBE), benzene, and total hydrocarbons (THC), respectively. The highest time-weighted average concentrations measured were 1.05 ppm for MTBE, 2.01 ppm for benzene, and 34 ppm for THC. It was found that motorbikes emitted a more significant amount of pollutants compared with motor cars. On average, officers at the motorcycle booths were exposed to four to five times higher levels of VOCs (GMs of 0.07 ppm, 0.23 ppm, and 4.7 ppm for MTBE, benzene, and THC) than their counterparts at the motor car booths (GMs of 0.01 ppm, 0.05 ppm, and 1.5 ppm). The airborne concentrations of all three pollutants correlated with the flow of vehicle traffic. Close correlations were also noted for the concentrations in ambient air for the three pollutants measured. Benzene and MTBE had a correlation coefficient of 0.97. The overall findings showed that the concentrations of various VOCs were closely related to the traffic density, suggesting that they were from a common source, such as exhaust emissions from the vehicles. The results also indicated that although benzene, MTBE, and THC are known to be volatile, a significant amount could still be detected in the ambient environment, thus contributing to our exposure to these compounds. 4 refs., 6 figs.

Tan, C.; Ong, H.Y.; Kok, P.W. [and others

1996-12-31T23:59:59.000Z

318

HH22 Reformer, Fuel Cell Power Plant,Reformer, Fuel Cell Power Plant, & Vehicle Refueling System& Vehicle Refueling System  

E-Print Network [OSTI]

sufficient hydrogen demand develops. #12;4 Relevant DOE Program Objectives Reduce dependence on foreign oil Promote use of diverse, domestic energy resources ­ Natural gas reformation Develop and demonstrate on test fill tank, CNG/H2 ICE vehicles and H2 Fuel Cell vehicles. Fuel dispensing integrated with City

319

Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships.  

SciTech Connect (OSTI)

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration.

Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

2001-12-04T23:59:59.000Z

320

Exposure Evaluation for Benzene, Lead and Noise in Vehicle and Equipment Repair Shops  

SciTech Connect (OSTI)

An exposure assessment was performed at the equipment and vehicle maintenance repair shops operating at the U. S. Department of Energy Hanford site, in Richland, Washington. The maintenance shops repair and maintain vehicles and equipment used in support of the Hanford cleanup mission. There are three general mechanic shops and one auto body repair shop. The mechanics work on heavy equipment used in construction, cranes, commercial motor vehicles, passenger-type vehicles in addition to air compressors, generators, and farm equipment. Services include part fabrication, installation of equipment, repair and maintenance work in the engine compartment, and tire and brake services. Work performed at the auto body shop includes painting and surface preparation which involves applying body filler and sanding. 8-hour time-weighted-average samples were collected for benzene and noise exposure and task-based samples were collected for lead dust work activities involving painted metal surfaces. Benzene samples were obtained using 3M™ 3520 sampling badges and were analyzed for additional volatile organic compounds. These compounds were selected based on material safety data sheet information for the aerosol products used by the mechanics for each day of sampling. The compounds included acetone, ethyl ether, toluene, xylene, VM&P naphtha, methyl ethyl ketone, and trichloroethylene. Laboratory data for benzene, VM&P naphtha, methyl ethyl ketone and trichloroethylene were all below the reporting detection limit. Airborne concentrations for acetone, ethyl ether, toluene and xylene were all less than 10% of their occupational exposure limit. The task-based samples obtained for lead dusts were submitted for a metal scan analysis to identify other metals that might be present. Laboratory results for lead dusts were all below the reporting detection limit and airborne concentration for the other metals observed in the samples were less than 10% of the occupational exposure limit. Noise dosimetry sampling was performed on a random basis and was representative of the different work activities within the four shops. Twenty three percent of the noise samples exceeded the occupational exposure limit of 85 decibels for an 8-hour time-weightedaverage. Work activities where noise levels were higher included use of impact wrenches and grinding wheels.

Sweeney, Lynn C.

2013-04-10T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Detailed Hydration Maps of Benzene and Cyclohexane Reveal Distinct Water Structures Tanya M. Raschke* and Michael Levitt  

E-Print Network [OSTI]

of water to exclude apolar groups play a key role in the stabilization of protein native states,1Detailed Hydration Maps of Benzene and Cyclohexane Reveal Distinct Water Structures Tanya M of a single solute in water. Detailed, spatially resolved, three-dimensional maps of the density of the water

Raschke, Tanya M.

322

Comparing the effects of various fuel alcohols on the natural attenuation of Benzene Plumes using a general substrate interaction model  

E-Print Network [OSTI]

and Environmental Engineering, Rice University, MS-317, 6100 Main St., Houston, TX 77005, USA a r t i c l e i n f o a b s t r a c t Article history: Received 30 October 2009 Received in revised form 26 January 2010 generalizations about the level of impact of specific fuel alcohols on benzene plume dynamics. © 2010 Elsevier B

Alvarez, Pedro J.

323

Diffusion and Catalytic Cracking of 1,3,5 Tri-iso-propyl-benzene in FCC Catalysts  

E-Print Network [OSTI]

1 Diffusion and Catalytic Cracking of 1,3,5 Tri-iso- propyl-benzene in FCC Catalysts S.Al-Khattaf1 describes catalytic cracking experiments developed in a novel CREC Riser Simulator using 1,3,5-Tri-iso

Al-Khattaf, Sulaiman

324

Fuel cell system with combustor-heated reformer  

DOE Patents [OSTI]

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

325

Voting Systems and Election Reform: What Do Election Officials Think?  

E-Print Network [OSTI]

and systems, local election officials face different constraints and institutional arrangements depending on their state. The Election Reform Information Project?s research found a diverse set of ?power-sharing arrangements ranging from elections run... obscure but powerful group of administrators: election board officials at the state and local level. Second, Florida highlighted the role that existing voting technology plays in shaping the number of votes counted and, in particular, problems...

Gray, Jennifer; Gray, Marshall; Hodges, Joshua; Jewell, Jeff; Larson, Marcia; Mitchell, Ryan; Murello, Erin; Murello, Steve; Reeves, Alice; Siddique, Julie

2005-01-01T23:59:59.000Z

326

National Development and Reform Commission | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3Informationof EnergyNapaInformationand Reform Commission

327

Nonresonant hyper?Raman and hyper?Rayleigh scattering in benzene and pyridine  

E-Print Network [OSTI]

is discussed in Sec. III, and results and discussion are presented in Sec. IV, The HRS spectra of benzene and pyr- a) ACS-PRF Summer Research Fellow. Current address: Carroll College, Waukesha, WI 53186. b) Author to whom correspondence should be addressed...I(c)lI(a) + GG'rG'JrJI rIG (OJIi,GO -OJ\\)(OJJJ,GO -OJ\\ +OJs ) + GG'rG'JrJI rIG h a lI(b)lI(a)lI(c) ] (OJIi,GO + OJs )(OJJj,GO - OJ\\ + OJs ) (glQa li) vii) (l10) } X , €b - €b, where f..Lg'J = (G I (OIf..La IJ(O», etc. (7) The A term is the Condon...

Neddersen, John P.; Mounter, Sarah A.; Bostick, James M.; Johnson, Carey K.

1989-01-01T23:59:59.000Z

328

Steam reforming of low-level mixed waste. Final report  

SciTech Connect (OSTI)

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

329

Thermodynamic evaluation of hydrogen production via bioethanol steam reforming  

SciTech Connect (OSTI)

In this article, a thermodynamic analysis for bioethanol steam reforming for hydrogen production is presented. Bioethanol is a newly proposed renewable energy carrier mainly produced from biomass fermentation. Reforming of bioethanol provides a promising method for hydrogen production from renewable resources. Steam reforming of ethanol (SRE) takes place under the action of a metal catalyst capable of breaking C-C bonds into smaller molecules. A large domain for the water/bioethanol molar ratio as well as the temperature and average pressure has been used in the present work. The interval of investigated temperature was 100-800°C, the pressure was in the range of 1-10 bar and the molar ratio was between 3-25. The variations of gaseous species concentration e.g. H{sub 2}, CO, CO{sub 2}, CH{sub 4} were analyzed. The concentrations of the main products (H{sub 2} and CO) at lower temperature are smaller than the ones at higher temperature due to by-products formation (methane, carbon dioxide, acetylene etc.). The concentration of H2 obtained in the process using high molar ratio (>20) is higher than the one at small molar ratio (near stoichiometric). When the pressure is increased the hydrogen concentration decreases. The results were compared with literature data for validation purposes.

Tasnadi-Asztalos, Zsolt; Cormos, Ana-Maria; Imre-Lucaci, Árpád; Cormos, C?lin C. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)] [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

330

Remediation of overlapping benzene/MTBE and MTBE-only plumes: A case study  

SciTech Connect (OSTI)

Two overlapping dissolved hydrocarbon plumes were identified in the shallow water-bearing zone at a commercial vehicle service and fueling facility. Plume 1 originated from a pre-1993 gasoline product line/dispenser leak. This plume contained a relatively common mix of benzene, toluene, ethylbenzene, xylenes (BTEX), and methyl tert-butyl ether (MTBE); benzene and MTBE were identified as the Plume 1 contaminants of concern based on their detection at approximately 200 {mu}g/l each, which exceeded regulatory guidance. Plume 2, which was detected in the tank cavity during UST removal, resulted from gasoline line leaks/underground storage tank overfills. Although the majority of impacted soils in both the dispenser and tank cavity areas were removed during UST excavation, rainfall during impacted soil removal mobilized the MTBE contained in the soils to groundwater. As a result, Plume 2 contained approximately 900 {mu}g/l MTBE while BTEX compounds were non-detect. Although the impacted zone sustained an approximate yield of only 0.3 gallon per minute, Pennsylvania regulations dictate that this zone must be treated as an aquifer. The failure of remediating gasoline plumes using pump-and-treat has been predominantly due to BTEX`s tendency to adsorb onto soil, creating a residual-phase product layer which acts as a continuing source of dissolved-phase BTEX. Based on this experience, most groundwater and remediation professionals reject pump-and-treat as a viable remedial option, except in situations where controlling groundwater movement is the predominant goal.

Carpenter, P.L. [TolTest, Inc., Pittsburgh, PA (United States); Vinch, C.A. [Ryder Transportation Services, Lawrenceville, NJ (United States)

1997-12-31T23:59:59.000Z

331

Changes in the peripheral blood transcriptome associated with occupational benzene exposure identified by cross-comparison on two microarray platforms  

SciTech Connect (OSTI)

Benzene is an established cause of leukemia and a possible cause of lymphoma in humans but the molecular pathways underlying this remain largely undetermined. This study sought to determine if the use of two different microarray platforms could identify robust global gene expression and pathway changes associated with occupational benzene exposure in the peripheral blood mononuclear cell (PBMC) gene expression of a population of shoe-factory workers with well-characterized occupational exposures to benzene. Microarray data was analyzed by a robust t-test using a Quantile Transformation (QT) approach. Differential expression of 2692 genes using the Affymetrix platform and 1828 genes using the Illumina platform was found. While the overall concordance in genes identified as significantly associated with benzene exposure between the two platforms was 26% (475 genes), the most significant genes identified by either array were more likely to be ranked as significant by the other platform (Illumina = 64%, Affymetrix = 58%). Expression ratios were similar among the concordant genes (mean difference in expression ratio = 0.04, standard deviation = 0.17). Four genes (CXCL16, ZNF331, JUN and PF4), which we previously identified by microarray and confirmed by real-time PCR, were identified by both platforms in the current study and were among the top 100 genes. Gene Ontology analysis showed over representation of genes involved in apoptosis among the concordant genes while Ingenuity{reg_sign} Pathway Analysis (IPA) identified pathways related to lipid metabolism. Using a two-platform approach allows for robust changes in the PBMC transcriptome of benzene-exposed individuals to be identified.

McHale, Cliona M.; Zhang, Luoping; Lan, Qing; Li, Guilan; Hubbard, Alan E.; Forrest, Matthew S.; Vermeulen, Roel; Chen, Jinsong; Shen, Min; Rappaport, Stephen M.; Yin, Songnian; Smith, Martyn T.; Rothman, Nathaniel

2009-03-01T23:59:59.000Z

332

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

333

Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents  

DOE Patents [OSTI]

Preparation and use of tetra-C-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents. Tetra-C-alkyl derivatives of cobalt dicarbollide, Co(C{sub 2}R{sub 2}B{sub 9}H{sub 9}){sub 2}{sup {minus}}(CoB{sub 2}R{sub 4}{sup {minus}}; R=CH{sub 3} and C{sub 6}H{sub 13}) are demonstrated to be significant cesium and strontium extractants from acidic and alkaline solutions into non-toxic organic solvent systems. Extractions using mesitylene and diethylbenzene are compared to those with nitrobenzene as the organic phase. CoB{sub 2}-hexyl{sub 4}{sup {minus}} in diethylbenzene shows improved selectivity (10{sup 4}) for Cs over Na in acidic solution. In dilute alkaline solution, CoB{sub 2}-hexyl{sub 4}{sup {minus}} extracts Cs less efficiently, but more effectively removes Sr from higher base concentrations. A general synthesis of tetra-C-alkyl cobalt dicarbollides is described. 6 figs.

Miller, R.L.; Pinkerton, A.B.; Abney, K.D.; Kinkead, S.A.

1997-02-11T23:59:59.000Z

334

Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents  

DOE Patents [OSTI]

Preparation and use of tetra-C-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents. Tetra-C-alkyl derivatives of cobalt dicarbollide, Co(C.sub.2 R.sub.2 B.sub.9 H.sub.9).sub.2.sup.- (CoB.sub.2 R.sub.4.sup.- ; R=CH.sub.3 and C.sub.6 H.sub.13) are demonstrated to be significant cesium and strontium extractants from acidic and alkaline solutions into non-toxic organic solvent systems. Extractions using mesitylene and diethylbenzene are compared to those with nitrobenzene as the organic phase. CoB.sub.2 -hexyl.sub.4.sup.- in diethylbenzene shows improved selectivity (10.sup.4) for Cs over Na in acidic solution. In dilute alkaline solution, CoB.sub.2 -hexyl.sub.4.sup.- extracts Cs less efficiently, but more effectively removes Sr from higher base concentrations. A general synthesis of tetra-C-alkyl cobalt dicarbollides is described.

Miller, Rebecca L. (Los Alamos, NM); Pinkerton, Anthony B. (Santa Fe, NM); Abney, Kent D. (Los Alamos, NM); Kinkead, Scott A. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

335

Extraction of carbonate complexes of trivalent transplutonium elements with alkyl pyrocatechols  

SciTech Connect (OSTI)

Extraction of trivalent americium curium, californium, and europium with a technical mixture of mono-and didecyl pyrocatechols (TAP) in different diluents from carbonate solutions is studied. The influence of various factors (pH, K/sub 2/CO/sub 3/, TAP and metal concentration, phase contact time) on the degree of extraction and separation of the elements is clarified. It is shown that the elements concerned are extracted quantitatively by TAP solution in toluene and cyclohexane in the K/sub 2/CO/sub 3/ concentration range 0.25-1.5 M. A difference is noted in the coefficients of americium and curium distribution when they are extracted with TAP from 0.25 M K/sub 2/CO/sub 3/ solution. The separation coefficients of this pair rise with the pH of the carbonate solution. The separation coefficients of this pair rise with the pH of the carbonate solution. The separation can be improved at the stage of reextraction of the elements with a mixture of K/sub 2/CO/sub 3/ and DTPA or EDTA from alkyl pyrocatechol because the americium and curium reextraction rate constants differ widely. The composition of the compounds in the organic phase based on 4-(..cap alpha..,..cap alpha..-dioctylethyl)pyrocatechol (DOP) is studied by /sup 13/C NMR spectroscopy.

Karalova, Z.K.; Bukina, T.I.; Myasoedov, B.F.; Fedorov, L.A.; Sokolovskii, S.A.

1987-01-01T23:59:59.000Z

336

A review of "Reformation and Religious Identity in Cambridge, 1590-1644" by David Hoyle  

E-Print Network [OSTI]

a deeply anti-Roman ?prevailing consensus? (69) among Reformed Protestant theologians of various stripes from the 1590s through the 1610s, centered around concerns such as predestination, election, assurance, and perseverance. Theologians... with and part of the pre-Reformation Catholic past? As Hoyle himself suggests (5), much of the material he covers will be familiar to scholars of the period. His treatment of a late Elizabethan church that was fundamentally Reformed Protestant in its...

Gregory, Brad S.

2008-01-01T23:59:59.000Z

337

Working Group Meeting Presentation Guidance at a Glance Distributed Reforming of Biomass Pyrolysis Oils  

E-Print Network [OSTI]

(75%) Char (13%) Gas (12%) Catalytic Auto-thermal Reforming of Bio-Oil at 650oC: 0.71 CH1.98O0.76 + 0 Case (Ethanol Case) Bio-oil Storage Tank $106,040 Reformer $803,000 Shift Reactor, PSA, BOP $1 Oils DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting November 6

338

E-Print Network 3.0 - autothermal steam reforming Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(ITM) Reactor - Air Products and Chemicals, Inc. Autothermal Reforming (ATR) - Praxair Inc. 12... sequestration. 2005 2010 2013 2015 12;Barriers to Hydrogen Production...

339

E-Print Network 3.0 - autothermal reformer catalyst Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(ITM) Reactor - Air Products and Chemicals, Inc. Autothermal Reforming (ATR) - Praxair Inc. 12... 95% of the hydrogen used to supplement refinery and chemical industry...

340

E-Print Network 3.0 - autothermal reformer processes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(ITM) Reactor - Air Products and Chemicals, Inc. Autothermal Reforming (ATR) - Praxair Inc. 12... Hydrogen Coordination Meeting Arthur Hartstein Program Manager Natural...

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming  

Broader source: Energy.gov [DOE]

Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

342

Corporate governance reform in a developing country : the case of Bangladesh   

E-Print Network [OSTI]

Bangladesh reformed its corporate governance by adopting Bangladesh Corporate Governance Guidelines-2006 (the BCGG-2006 hereafter) due to pressures from international financial institutions (IFIs). However, there is huge ...

Sobhan, Md. Abdus

2014-07-02T23:59:59.000Z

343

Regulatory Reform in the Wake of the Financial Crisis of 2007—2008  

E-Print Network [OSTI]

Purpose – The purpose of this paper is to analyse regulatory reform in the wake of the financial crisis of 2007-2008.

Lo, Andrew W.

344

Giannini Foundation of Agricultural Economics New Horizons for Rural Reform in China  

E-Print Network [OSTI]

11 Giannini Foundation of Agricultural Economics New Horizons for Rural Reform in China: Resources Population Rice Fruit #12;12 Giannini Foundation of Agricultural Economics dominate domestic production

Kammen, Daniel M.

345

Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.  

SciTech Connect (OSTI)

Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

1999-06-07T23:59:59.000Z

346

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents [OSTI]

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier. 10 figs.

Dederer, J.T.; Hager, C.A.

1998-03-31T23:59:59.000Z

347

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents [OSTI]

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier.

Dederer, Jeffrey T. (Valencia, PA); Hager, Charles A. (Mars, PA)

1998-01-01T23:59:59.000Z

348

E-Print Network 3.0 - agrarian reform process Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Peace Agreement... and adopt entrenched positions in support of their interests. In Nepal, land reform is a constant source... groups. One of the main sources of conflict is...

349

E-Print Network 3.0 - actinide reformer concept Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OF PEANUT Summary: gasification -Storable inter. reforming: ethanol methanol methane Pyrolysis oil + + Figure 1. Overall concept... ENGINEERING SCALE UP OF RENEWABLE HYDROGEN...

350

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network [OSTI]

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has… (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

351

E-Print Network 3.0 - abortion law reform Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Hagen Collection: Computer Technologies and Information Sciences 30 Health Care Reform Law Challenged in Courts President Barack Obama on March 23, 2010, signed into...

352

At the Nexus of Social Policy and Capital Markets: Pension Reform and Enterprise Governance in Germany  

E-Print Network [OSTI]

Company Pension Schemes in Germany,” Monthly Report, March.2001. “Pension Reform in Germany,” draft chapter in R. Kentof Stakeholderism in Germany,”forthcoming, Industrielle

Ziegler, J. Nicholas

2008-01-01T23:59:59.000Z

353

E-Print Network 3.0 - arc plasma-catalyst reformer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: by reforming their political institutions. States such as Indonesia, Thailand, the Philippines, Taiwan and East... systems and other key democratic...

354

The Ambiguous Transition: Building State Capacity and Expanding Popular Participation in Venezuela's Agrarian Reform  

E-Print Network [OSTI]

El Universal, Caracas, Venezuela. Bengelsdorf, Carollee.Crisis and Reform in Venezuela. ” Journal of Interamerican2):27-61. Datamonitor. (2004). “Venezuela Country Profile. ”

Page, Tiffany Linton

2011-01-01T23:59:59.000Z

355

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Use of a Diesel Fuel Processor for Rapid...

356

Mayors, Markets and Municipal Reform: The Politics of Water Delivery in Mexico  

E-Print Network [OSTI]

Bank and Policy Reform in Mexico and Argentina. ” Latinand policies, such as Pinochet’s Chile, Menem’s Argentina, and

Herrera, Veronica Maria Sol

2011-01-01T23:59:59.000Z

357

Autothermal and partial oxidation reformer-based fuel processor, method for improving catalyst function in autothermal and partial oxidation reformer-based processors  

DOE Patents [OSTI]

The invention provides a fuel processor comprising a linear flow structure having an upstream portion and a downstream portion; a first catalyst supported at the upstream portion; and a second catalyst supported at the downstream portion, wherein the first catalyst is in fluid communication with the second catalyst. Also provided is a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H. D.; Ahluwalia, Rajesh K.

2013-01-08T23:59:59.000Z

358

High School Principals' Perceptions of Their Effectiveness in Leading District Initiated High School Reform: An Analysis of High School Principals Previously Engaged in High School Reform in an Urban Texas School District  

E-Print Network [OSTI]

school reform. However, to date, research has not provided examples of a successful relationship between campus principals as a collective group and the district (central office) leadership team attempting to implement district-wide high school reform...

Rios, Carlos

2012-07-16T23:59:59.000Z

359

A study of land reform and its impact in the Greater Letaba Local Municipality of the Mopani District in the Limpopo Province.  

E-Print Network [OSTI]

??Since the dawn of democracy in South Africa, numerous land reform projects have been approved by the Minister of Rural Development and Land Reform. This… (more)

Malahlela, Tebogo.

2015-01-01T23:59:59.000Z

360

Columbia River Hatchery Reform System-Wide Report.  

SciTech Connect (OSTI)

The US Congress funded the Puget Sound and Coastal Washington Hatchery Reform Project via annual appropriations to the US Fish and Wildlife Service (USFWS) beginning in fiscal year 2000. Congress established the project because it recognized that while hatcheries have a necessary role to play in meeting harvest and conservation goals for Pacific Northwest salmonids, the hatchery system was in need of comprehensive reform. Most hatcheries were producing fish for harvest primarily to mitigate for past habitat loss (rather than for conservation of at-risk populations) and were not taking into account the effects of their programs on naturally spawning populations. With numerous species listed as threatened or endangered under the Endangered Species Act (ESA), conservation of salmon in the Puget Sound area was a high priority. Genetic resources in the region were at risk and many hatchery programs as currently operated were contributing to those risks. Central to the project was the creation of a nine-member independent scientific review panel called the Hatchery Scientific Review Group (HSRG). The HSRG was charged by Congress with reviewing all state, tribal and federal hatchery programs in Puget Sound and Coastal Washington as part of a comprehensive hatchery reform effort to: conserve indigenous salmonid genetic resources; assist with the recovery of naturally spawning salmonid populations; provide sustainable fisheries; and improve the quality and cost-effectiveness of hatchery programs. The HSRG worked closely with the state, tribal and federal managers of the hatchery system, with facilitation provided by the non-profit organization Long Live the Kings and the law firm Gordon, Thomas, Honeywell, to successfully complete reviews of over 200 hatchery programs at more than 100 hatcheries across western Washington. That phase of the project culminated in 2004 with the publication of reports containing the HSRG's principles for hatchery reform and recommendations for Puget Sound/Coastal Washington hatchery programs, followed by the development in 2005 of a suite of analytical tools to support application of the principles (all reports and tools are available at www.hatcheryreform.us). In 2005, Congress directed the National Oceanic and Atmospheric Administration-Fisheries (NOAA Fisheries) to replicate the Puget Sound and Coastal Washington Hatchery Reform Project in the Columbia River Basin. The HSRG was expanded to 14 members to include individuals with specific knowledge about the Columbia River salmon and steelhead populations. This second phase was initially envisioned as a one-year review, with emphasis on the Lower Columbia River hatchery programs. It became clear however, that the Columbia River Basin needed to be viewed as an inter-connected ecosystem in order for the review to be useful. The project scope was subsequently expanded to include the entire Basin, with funding for a second year provided by the Bonneville Power Administration (BPA) under the auspices of the Northwest Power and Conservation Council's (NPCC) Fish and Wildlife Program. The objective of the HSRG's Columbia River Basin review was to change the focus of the Columbia River hatchery system. In the past, these hatchery programs have been aimed at supplying adequate numbers of fish for harvest as mitigation primarily for hydropower development in the Basin. A new, ecosystem-based approach is founded on the idea that harvest goals are sustainable only if they are compatible with conservation goals. The challenge before the HSRG was to determine whether or not conservation and harvest goals could be met by fishery managers and, if so, how. The HSRG determined that in order to address these twin goals, both hatchery and harvest reforms are necessary. The HSRG approach represents an important change of direction in managing hatcheries in the region. It provides a clear demonstration that current hatchery programs can indeed be redirected to better meet both conservation and harvest goals. For each Columbia River Basin Environmentally Significant Unit

Warren, Dan [Hatchery Scientific Review Group

2009-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Coal anion structure and chemistry of coal alkylation. Final report, March 1, 1979-February 29, 1980  

SciTech Connect (OSTI)

In accord with Task 1, some ether cleavage reactions were carried out in two different media - potassium/naphthalene/tetrahydrofuran and potassium/ ammonia - so that the merits and demerits of the two methods could be compared. Preliminary results suggest that both systems yield the same products, and that the ammonia medium is more convenient to work with, because of the absence of by-products such as reduced naphthalenes and tetralin. Dialkyl ethers were found to be least reactive compounds while the benzyl and phenyl ethers were found to be most reactive, as would be expected. The reductive alkylation of coal was carried out in ammonia at 25/sup 0/C. The tetrahydrofuran solubility of the reaction product was surprisingly low. We have obtained additional /sup 13/C)/sup 1/H) nmr data for tetrahydrofuran-soluble butylated coal and some model compounds; obtained additional Styragel(R) chromatography data of tetrahydrofuran-soluble coal labelled with 98%-enriched butyl-1,1-d/sub 2/ iodide; and obtained /sup 2/D nmr spectra of all the deuterium-labelled, tetrahydrofuran-soluble coal products. In accord with Task 4, we have undertaken a review of the information now available concerning the nature of Illinois No. 6 coal. Also, the effects of organic additives on the exchange reactions between tetralin-d/sub 12/ and diphenyl-methane and on the thermal cleavage reactions of several model compounds in tetralin were investigated to probe the relationship between structure and reactivity. The exchange reaction can be accelerated by coal, asphaltene-preasphaltene fractions derived from coal, compounds with labile bonds, or compounds which can be reduced readily. The pyridine-insoluble coal product, acids, and bases are inactive toward the exchange reaction.

Stock, L.M.

1980-01-01T23:59:59.000Z

362

Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192  

SciTech Connect (OSTI)

The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

Czernik, S.

2010-07-01T23:59:59.000Z

363

Sodium dodecyl benzene sulfonate-assisted synthesis through a hydrothermal reaction  

SciTech Connect (OSTI)

Graphical abstract: Reaction of a SeCl{sub 4} aqueous solution with a NiCl{sub 2}·6H{sub 2}O aqueous solution in presence of sodium dodecyl benzene sulfonate (SDBS) as capping agent and hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant, produces nanosized nickel selenide through a hydrothermal method. The effect of temperature, reaction time and amounts of reductant on the morphology, particle sizes of NiSe nanostructures has been investigated. Highlights: ? NiSe nanostructures were synthesized by hydrothermal method. ? A novel Se source was used to synthesize NiSe. ? SDBS as capping agent plays a crucial role on the morphology of products. ? A mixture of Ni{sub 3}Se{sub 2} and NiSe was prepared in the presence of 2 ml hydrazine. ? A pure phase of NiSe was prepared in the presence of 4 or 6 ml hydrazine. -- Abstract: The effects of the anionic surfactant on the morphology, size and crystallization of NiSe precipitated from NiCl{sub 2}·6H{sub 2}O and SeCl{sub 4} in presence of hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant were investigated. The products have been successfully synthesized in presence of sodium dodecyl benzene sulfonate (SDBS) as surfactant via an improved hydrothermal route. A variety of synthesis parameters, such as reaction time and temperature, capping agent and amount of reducing agent have a significant effect on the particle size, phase purity and morphology of the obtained products. The sample size became bigger with decreasing reaction temperature and increasing reaction time. In the presence of 2 ml hydrazine, the samples were found to be the mixture of Ni{sub 3}Se{sub 2} and NiSe. With increasing the reaction time and amount of hydrazine a pure phase of hexagonal NiSe was obtained. X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM) images indicate phase, particle size and morphology of the products. Chemical composition and purity of the products were characterized by X-ray energy dispersive spectroscopy (EDS). Photoluminescence (PL) was used to study the optical properties of NiSe samples.

Sobhani, Azam [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of); Salavati-Niasari, Masoud, E-mail: salavati@kashanu.ac.ir [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of) [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of); Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of)

2012-08-15T23:59:59.000Z

364

Land reform, regional planning and socioeconomic development in Brazil  

E-Print Network [OSTI]

baseline study of PCT settings 96 4.1 Introduction 96 4.2 Access to land under the Land Bill Programme 99 4.3 Agriculture and livestock production on PCT settlements 111 4.4 The standard of living of PCT beneficiaries 119 4.5 The surveyed sites vis... of governance for plan-led land reform 145 Figure 5.3: An illustrative diagram for the regional planning cycle 180 10 ABBREVIATIONS CONTAG National Confederation of Agricultural Workers FUNDEB Basic Education Fund HDI...

Souza, Saulo

2011-01-11T23:59:59.000Z

365

SMALL SCALE FUEL CELL AND REFORMER SYSTEMS FOR REMOTE POWER  

SciTech Connect (OSTI)

New developments in fuel cell technologies offer the promise of clean, reliable affordable power, resulting in reduced environmental impacts and reduced dependence on foreign oil. These developments are of particular interest to the people of Alaska, where many residents live in remote villages, with no roads or electrical grids and a very high cost of energy, where small residential power systems could replace diesel generators. Fuel cells require hydrogen for efficient electrical production, however. Hydrogen purchased through conventional compressed gas suppliers is very expensive and not a viable option for use in remote villages, so hydrogen production is a critical piece of making fuel cells work in these areas. While some have proposed generating hydrogen from renewable resources such as wind, this does not appear to be an economically viable alternative at this time. Hydrogen can also be produced from hydrocarbon feed stocks, in a process known as reforming. This program is interested in testing and evaluating currently available reformers using transportable fuels: methanol, propane, gasoline, and diesel fuels. Of these, diesel fuels are of most interest, since the existing energy infrastructure of rural Alaska is based primarily on diesel fuels, but this is also the most difficult fuel to reform, due to the propensity for coke formation, due to both the high vaporization temperature and to the high sulfur content in these fuels. There are several competing fuel cell technologies being developed in industry today. Prior work at UAF focused on the use of PEM fuel cells and diesel reformers, with significant barriers identified to their use for power in remote areas, including stack lifetime, system efficiency, and cost. Solid Oxide Fuel Cells have demonstrated better stack lifetime and efficiency in demonstrations elsewhere (though cost still remains an issue), and procuring a system for testing was pursued. The primary function of UAF in the fuel cell industry is in the role of third party independent testing. In order for tests to be conducted, hardware must be purchased and delivered. The fuel cell industry is still in a pre-commercial state, however. Commercial products are defined as having a fixed set of specifications, fixed price, fixed delivery date, and a warrantee. Negotiations with fuel cell companies over these issues are often complex, and the results of these discussions often reveal much about the state of development of the technology. This work includes some of the results of these procurement experiments. Fuel cells may one day replace heat engines as the source of electrical power in remote areas. However, the results of this program to date indicate that currently available hardware is not developed sufficiently for these environments, and that significant time and resources will need to be committed for this to occur.

Dennis Witmer

2003-12-01T23:59:59.000Z

366

Distributed Bio-Oil Reforming | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: TopEnergy DOEDealingVehicle BatteryofDisabilityDistributed Bio-Oil Reforming

367

HealtH reform and oHsu how we'll change  

E-Print Network [OSTI]

HealtH reform and oHsu how we'll change Health reform will touch all of oHsu's missions. the coming changes are about more than public policy and health insurance. We will see transformation in how care is delivered, how health professionals are trained and how we decide what health care to buy. oHsu's missions

Chapman, Michael S.

368

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT  

E-Print Network [OSTI]

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

369

Report of the Ad Hoc Committee on Washington Natural Resource Agency Reform  

E-Print Network [OSTI]

Report of the Ad Hoc Committee on Washington Natural Resource Agency Reform February 16, 2010 recommended formation of an ad hoc committee to evaluate opportunities for SFR and others in College. As a result, the Washington Natural Resource Agency Reform ad hoc Committee was established and given

Borenstein, Elhanan

370

Development of a comprehensive reporting system for a school reform organization: The Accelerated Schools Project  

E-Print Network [OSTI]

on the evaluation procedures of whole-school reform organizations. Because the ultimate goal is to improve school performance, it should also be a goal of each whole-school reform organization to design a comprehensive data collection system to evaluate each school...

Stephens, Jennifer Anne

2006-04-12T23:59:59.000Z

371

Electricity Markets: Should the Rest of the World Adopt the UK Reforms?  

E-Print Network [OSTI]

PWP-069 Electricity Markets: Should the Rest of the World Adopt the UK Reforms? Catherine D;1 Electricity Markets: Should the Rest of the World Adopt the UK Reforms?1 By Catherine D. Wolfram2 Britain was one of the first countries to liberalize its electricity industry when it restructured and privatized

California at Berkeley. University of

372

PHS 650 Summer 2012 Page 1 State-Level Health System and Coverage Reform  

E-Print Network [OSTI]

and Affordable Care Act Current State-Level Trends and Health Reforms The Syllabus includes a variety of readingPHS 650 Summer 2012 Page 1 State-Level Health System and Coverage Reform Course Overview and Syllabus Description: Overview of the state initiatives in health care coverage, access, and costs, trends

Sheridan, Jennifer

373

Inaugural Lecture The Politics of Belief and U.S. Health Care Reform  

E-Print Network [OSTI]

1 Inaugural Lecture The Politics of Belief and U.S. Health Care Reform Joseph White Ph.D John G will not pretend to fully explain the politics of health care reform in the U.S.. I could make many other caveats is to give you some interesting ideas that you might use in thinking about American government. Health care

Oxford, University of

374

Agenda Setting And The Role Of Leadership In National Health Care Reform During The Early 1990s  

E-Print Network [OSTI]

Health care reform was the dominant issue on the political agenda during the early 1990s. Few issues

Kang, Michael S,

2006-01-05T23:59:59.000Z

375

A review of "Godly Reformers and their Opponents in Early Modern England: Religion in Norwich." by Matthew Reynolds  

E-Print Network [OSTI]

relatively uncontested Reformation, Norwich became Protestant ?in a process that was far from quiet? (35). The religious divisions the Reformation created remained rife, providing Laudian reforms with a measure of lay support within the city, which in turn... part of James? reign. Religious division was widespread, evident amongst the higher clergy attached to the Cathedral, where relations were defined by a split between those who stood against further reform and evangelical Protestants. In civic politics...

Baker, Geoff

2006-01-01T23:59:59.000Z

376

GOVERNMENT VERSUS GOVERNANCE AS A FRAMEWORK Government versus Governance as a Framework to analyze Mexico's Energy Reform  

E-Print Network [OSTI]

branch, the oil company PEMEX' union, other critics of the reform among a part of the left party Partido

Texas at Austin, University of

377

Activity and structure of perovskites as diesel reforming catalysts for solid oxide fuel cells.  

SciTech Connect (OSTI)

Recent progress in developing perovskite materials as more cost-effective catalysts in autothermal reforming (ATR) of diesel fuel to hydrogen-rich reformate for solid oxide fuel cell (SOFC) application is reported. Perovskite-type metal oxides with B sites partially exchanged by ruthenium were prepared and evaluated under ATR reaction conditions. The hydrogen yield, reforming efficiency, and CO{sub x} selectivity of these catalysts were investigated using diesel surrogate fuel with 50 ppm sulfur. The catalyst performances have approached or exceeded a benchmark, high-cost rhodium-based material. In parallel with the reactivity study, we also investigated the physical properties of B-site doped perovskites and their impact on the reforming performance using various characterization techniques such as BET, X-ray powder diffraction, temperature programmable reduction, scanning electron microscopy, and synchrotron X-ray absorption spectroscopy. We found that ruthenium is highly dispersed into perovskite lattice and its redox behavior is directly associated with reforming activity.

Liu, D.-J.; Krumpelt, M.; Chemical Engineering

2005-01-01T23:59:59.000Z

378

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2006-04-01T23:59:59.000Z

379

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken with so little public debate or  

E-Print Network [OSTI]

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken reform is unique neither in terms of its controversial substance nor in its lack of meaningful democratic processes. In the past, major immigration reform has typically been the result of parliamentary deliberation

Handy, Todd C.

380

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network [OSTI]

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect (OSTI)

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

382

Exposure to methyl tert-butyl ether and benzene among service station attendants and operators  

SciTech Connect (OSTI)

Concerns for atmospheric pollution from auto exhaust have led to the blending of {open_quotes}oxygenates{close_quotes} with motor fuels. The most common oxygenate, methyl tert-butyl ether (MTBE) is currently required within several metropolitan areas (Denver and Phoenix) in the range of 12% of the motor fuel. Amendments to the Clean Air Act may expand this requirement to as many as 44 other areas of the United States in the near future. In consideration of the magnitude of potential uncontrolled exposures from its extensive use and a related concern involving the potential influence of MTBE blending on exposures to other constituents of gasoline (particularly benzene), an evaluation of exposures among service station attendants and operators was undertaken at the request, and in cooperation with, the American Petroleum Institute during the latter part of 1990. For application of the survey results to a broad audience, three categories or types of service stations were identified with regard to MTBE use and exposure potential: (a) service stations that do not use MTBE or use it only as an octane enhancer, (b) service stations with seasonal requirements to use 12-15% MTBE (the Denver, Colorado, and Phoenix, Arizona, metropolitan areas), and (c) service stations equipped with stage II (active) vapor recovery systems (several coastal areas, most notably Southern California). 4 refs., 4 tabs.

Hartle, R. [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States)

1993-12-01T23:59:59.000Z

383

Modified Ni-Cu catalysts for ethanol steam reforming  

SciTech Connect (OSTI)

Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

Dan, M.; Mihet, M.; Almasan, V.; Borodi, G. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania); Katona, G.; Muresan, L. [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania)] [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania); Lazar, M. D., E-mail: diana.lazar@itim-cj.ro [65-103 Donath Street (Romania)

2013-11-13T23:59:59.000Z

384

Fiftieth CCR reformer goes on stream in Germany  

SciTech Connect (OSTI)

The fiftieth continuous catalytic reformer built since this technology was introduced by UOP Process Division in 1971 has gone on stream in West Germany. The 21,300-b/sd unit is in Deutsche Shell AG's Godorf refinery. It is the sixth such unit put in service by Shell International. Others are in refineries at Harburg, West Germany; Shellhaven, England; Palau Bokum, Singapore; Pernis, Netherlands; and Geelong, Australia. CCR units operate at much higher severity than older reforming units. Severity is a function of higher octane, lower pressure, and feedstock. The operating severity or catalyst deactivation rate may be 20 times that of high pressure, low octane units. Continuous catalyst regeneration is then the key for maintaining long-term operations at steady state conditions. To facilitate continuous catalyst regeneration, the three reactors are stacked. This design permits the catalyst to move in essentially plug flow through the reactors at a rate determined by the rate of catalyst withdrawal to the regeneration section.

Not Available

1985-03-18T23:59:59.000Z

385

[98e]-Catalytic reforming of gasoline and diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a fuel processor for converting liquid hydrocarbon fuels to a hydrogen-rich product suitable for a polymer electrolyte fuel cell stack. The processor uses an autothermal reformer to convert the feed to a mixture of hydrogen, carbon dioxide, carbon monoxide and water with trace quantities of other components. The carbon monoxide in the product gas is then converted to carbon dioxide in water-gas shift and preferential oxidation reactors. Fuels that have been tested include standard and low-sulfur gasoline and diesel fuel, and Fischer-Tropsch fuels. Iso-octane and n-hexadecane were also examined as surrogates for gasoline and diesel, respectively. Complete conversion of gasoline was achieved at 750 C in a microreactor over a novel catalyst developed at Argonne. Diesel fuel was completely converted at 850 C over this same catalyst. Product streams contained greater than 60% hydrogen on a dry, nitrogen-free basis with iso-octane, gasoline, and n-hexadecane. For a diesel fuel, product streams contained >50% hydrogen on a dry, nitrogen-free basis. The catalyst activity did not significantly decrease over >16 hours operation with the diesel fuel feed. Coke formation was not observed. The carbon monoxide fraction of the product gas could be reduced to as low as 1% on a dry, nitrogen-free basis when the water-gas shift reactors were used in tandem with the reformer.

Pereira, C.; Wilkenhoener, R.; Ahmed, S.; Krumpelt, M.

2000-02-29T23:59:59.000Z

386

Hydrocarbon reforming for hydrogen fuel cells: a study of carbon formation on autothermal reforming catalysts. Final report  

SciTech Connect (OSTI)

The mechanism of carbon formation on nickel autothermal steam reforming catalysts has been studied by temperature-programming, thermogravimetric and electron microscopic techniques. Temperature-programmed surface reaction (TPSR) studies of carbon deposited on nickel reforming catalysts by the decomposition of C/sub 2/H/sub 4/ and C/sub 2/H/sub 2/ exhibit seven forms of carbon that are distinguished by their characteristic reactivity with H/sub 2/ and 3.0-vol % H/sub 2/O/He. The relative population of the different carbon states depends primarily on the temperature during deposition. C/sub 2/H/sub 2/ exposure populates the same carbon states as C/sub 2/H/sub 4/ exposure but at approximately 100/sup 0/K lower deposition temperature. Similar carbon states were found on all nickel catalysts studies including Ni/..gamma..-Al/sub 2/O/sub 3/ and Ni/MgO-Al/sub 2/O/sub 3/ leading to the conclusion that the support has little effect on carbon deposit formation and reactivity. The reactivity of the carbon states is not altered by exposure to steam in C/sub 2/H/sub 4/-H/sub 2/O mixtures, but the amount of carbon deposited decreases to zero as H/sub 2/O/C increases past a critical ratio.

McCarty, J.G.; Sheridan, D.M.; Wise, H.; Wood, B.J.

1981-12-01T23:59:59.000Z

387

Synthesis and chemistry of cationic d{sup 0} metal alkyl complexes. Progress report, July 1988--May 1991  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-12-31T23:59:59.000Z

388

Benchmark Theoretical Study of the ?–? Binding Energy in the Benzene Dimer  

SciTech Connect (OSTI)

We establish a new estimate for the interaction energy between two benzene molecules in the parallel displaced (PD) conformation by systematically converging (i) the intra- and intermolecular geometry at the minimum geometry, (ii) the expansion of the orbital basis set and (iii) the level of electron correlation. The calculations were performed at the second order Møller - Plesset perturbation (MP2) and the Coupled Cluster including Singles, Doubles and a perturbative estimate of Triples replacements [CCSD(T)] levels of electronic structure theory. At both levels of theory, by including results corrected for Basis Set Superposition Error (BSSE), we have estimated the Complete Basis Set (CBS) limit by employing the family of Dunning’s correlation consistent polarized valence basis sets. The largest MP2 calculation was performed with the cc-pV6Z basis set (2,772 basis functions), whereas the largest CCSD(T) calculation with the cc-pV5Z basis set (1,752 basis functions). The cluster geometries were optimized with basis sets up to quadruple-? quality, observing that both its intra- and inter-molecular parts have practically converged with the triple-? quality sets. The use of converged geometries was found to play an important role for obtaining accurate estimates for the CBS limits. Our results demonstrate that the binding energies with the families of the plain (cc-pVnZ) and augmented (aug-cc-pVnZ) sets converge [to within < 0.01 kcal/mol for MP2 and < 0.15 kcal/mol for CCSD(T)] to the same CBS limit. In addition, the average of the uncorrected and BSSEcorrected binding energies was found to converge to the same CBS limit must faster than either of the two constituents (uncorrected or BSSE-corrected binding energies). Due to the fact that the family of augmented basis sets (especially for the larger sets) causes serious linear dependency problems, the plain basis sets (for which no linear dependencies were found) are deemed as a more efficient and straightforward path for obtaining an accurate CBS limit. We considered extrapolations of the uncorrected (?𝐸) and BSSE-corrected (?𝐸!") binding energies, their average value (?𝐸!"#) as well as the average of the latter over the plain and augmented sets (?𝐸!"#) with the cardinal number of the basis set n. Our best estimate of the CCSD(T)/CBS limit for the ?-? interaction energy in the PD benzene dimer is De = 2.65 ± 0.02 kcal/mol. The best CCSD(T)/cc-pV5Z calculated value is 2.62 kcal/mol, just 0.03 kcal/mol away from the CBS limit. For comparison, the MP2/CBS limit estimate is 5.00 ± 0.01 kcal/mol, demonstrating a 90% overbinding with respect to CCSD(T). The Spin-Component-Scaled (SCS) MP2 variant was found to closely reproduce the CCSD(T) results for each basis set, while Scaled-Opposite-Spin (SOS) yielded results that are too low when compared to CCSD(T).

Miliordos, Evangelos; Apra, Edoardo; Xantheas, Sotiris S.

2014-09-04T23:59:59.000Z

389

How fuel composition affects on-board reforming for fuel cell vehicles.  

SciTech Connect (OSTI)

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h{sup -1} ) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

Kopasz, J. P.; Miller, L. E.; Applegate, D. V.; Chemical Engineering

2003-01-01T23:59:59.000Z

390

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

391

Five Kilowatt Solid Oxide Fuel Cell/Diesel Reformer  

SciTech Connect (OSTI)

Reducing fossil fuel consumption both for energy security and for reduction in global greenhouse emissions has been a major goal of energy research in the US for many years. Fuel cells have been proposed as a technology that can address both these issues--as devices that convert the energy of a fuel directly into electrical energy, they offer low emissions and high efficiencies. These advantages are of particular interest to remote power users, where grid connected power is unavailable, and most electrical power comes from diesel electric generators. Diesel fuel is the fuel of choice because it can be easily transported and stored in quantities large enough to supply energy for small communities for extended periods of time. This projected aimed to demonstrate the operation of a solid oxide fuel cell on diesel fuel, and to measure the resulting efficiency. Results from this project have been somewhat encouraging, with a laboratory breadboard integration of a small scale diesel reformer and a Solid Oxide Fuel Cell demonstrated in the first 18 months of the project. This initial demonstration was conducted at INEEL in the spring of 2005 using a small scale diesel reformer provided by SOFCo and a fuel cell provided by Acumentrics. However, attempts to integrate and automate the available technology have not proved successful as yet. This is due both to the lack of movement on the fuel processing side as well as the rather poor stack lifetimes exhibited by the fuel cells. Commercial product is still unavailable, and precommercial devices are both extremely expensive and require extensive field support.

Dennis Witmer; Thomas Johnson

2008-12-31T23:59:59.000Z

392

Impact of the revised OSHA exposure standard on evaluation and control of benzene and other volatile organic chemicals in the liquid petroleum pipeline industry  

SciTech Connect (OSTI)

The primary purpose of this study was to determine the benzene exposure potential of workers in the liquid petroleum pipeline industry and to assess the impact of compliance with the revised standard on this industry. In addition, exposure to ethylene dibromide (EDB), and ethylene dichloride (EDC), which have toxicological profiles similar to that of benzene and are routinely found in this industry, were evaluated and appropriate control protocols were recommended. Exposure potential to benzene in excess of the 0.5 ppm (8-hour TWA) OSHA action level was shown to be limited to three free product handling operations, and that this increased exposure potential was dependent on the length of time necessary to perform the operations. The incidence and magnitude of benzene overexposure was not severe and control could be accomplished with engineering methods, along with work practice controls and personal protective equipment. Through application of a risk assessment model it was shown that 14 excess leukemia deaths per one thousand workers could be expected in the employee population that routinely performs those operation having maximum benzene exposure potential. This compares to less than on excess leukemia death per one thousand workers in the total work population. The evaluation of EDB and EDC indicated that exposure potential to EDB was of greatest concern. Even though exposure could be limited through application of standard industrial hygiene methods, any control protocol short of total elimination of EDB from the product stream may be not sufficient to reduce exposure to accepted levels.

Mercer, D.O.

1989-01-01T23:59:59.000Z

393

Ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface  

SciTech Connect (OSTI)

The interaction of potassium with carbon monoxide and benezene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. The authors find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface. 36 references, 11 figures.

Kudo, M.; Garfunkel, E.L.; Somorjai, G.A.

1985-07-18T23:59:59.000Z

394

The wholesale market for electricity in England and Wales : recent developments and future reforms  

E-Print Network [OSTI]

The England and Wales wholesale electricity market is about to undergo major reform (NETA). I describe and analyse the proposed arrangements, contrasting them with those currently in operation. I argue that while NETA will ...

Sweeting, Andrew

2000-01-01T23:59:59.000Z

395

E-Print Network 3.0 - auto thermal reforming Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

psig H2 PSA Natural Gas Syngas CMP HX CMP HX Thermal... ACR is more cost effective 12;Praxair BP 7 Reformer Design 150 kW thermal NG unit 0 10 20 30 40 50... GE Autothermal...

396

American Institute of Aeronautics and Astronautics Measurements for fuel reforming for scramjet thermal management and  

E-Print Network [OSTI]

American Institute of Aeronautics and Astronautics 1 Measurements for fuel reforming for scramjet to be achieved with dual-mode-Ramjet (Ramjet under Mach 6 and Scramjet beyond) because of its high specific

Paris-Sud XI, Université de

397

American Institute of Aeronautics and Astronautics Measurements for fuel reforming for scramjet thermal management and  

E-Print Network [OSTI]

American Institute of Aeronautics and Astronautics 1 Measurements for fuel reforming for scramjet, since even composite materials can't withstand the large heat load found in a Scramjet combustion

Paris-Sud XI, Université de

398

Deregulating and regulatory reform in the U.S. electric power sector  

E-Print Network [OSTI]

This paper discusses the evolution of wholesale and retail competition in the U.S electricity sector and associated industry restructuring and regulatory reforms. It begins with a discussion of the industry structure and ...

Joskow, Paul L.

2000-01-01T23:59:59.000Z

399

An Act to Reform Land Use Planning in the Unorganized Territory (Maine)  

Broader source: Energy.gov [DOE]

An Act to Reform Land Use Planning in the Unorganized Territory alters the makeup and responsibilities of Maine's Land Use Regulation Commission (LURC). It took effect on August 29, 2012 and...

400

The impact of Basel II reforms : a contraction in SME lending  

E-Print Network [OSTI]

The implementation of Basel II reforms has been designed to protect the international financial system from major bank collapses through the enforcement of minimum capital adequacy ratios. This new set of rules has raised ...

Charpentier, Apolline

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A time for reform: the woman suffrage campaign in rural Texas, 1914-1919  

E-Print Network [OSTI]

, and Ferguson's own tabloid Ferguson Forum, rural voters found themselves constantly bombarded by messages about how they should view questions of reform in their state. The organizational culture that sustained suffrage organizations in urban Texas failed to do...

Motl, Kevin Conrad

2009-06-02T23:59:59.000Z

402

Periodicities in societal systems behaviors: relationships of economies, generations, and technologies to reforms in medical education  

E-Print Network [OSTI]

, Marchetti). In seeking to discover how medical education responds to such societal changes, this research analyzes past educational reforms in the context of concurrent social environments. By discovering temporal connections between cyclical behaviors...

Kinra, Reva Elaine

2013-02-22T23:59:59.000Z

403

The Li'an ("Docketing") Process: Barriers to Initiating Lawsuits in China and Possible Reforms  

E-Print Network [OSTI]

Supreme People's Court ("SPC") found it necessary to pro-note 10, at 88-9. The 1999 SPC Five Year Reform Program ("On May 29, 1997, the SPC issued the Li'an ("Docketing") Work

Cheuk, Andrea

2008-01-01T23:59:59.000Z

404

Kill Fewer, Kill Carefully: An Analysis of the 2006 to 2007 Death Penalty Reforms in China  

E-Print Network [OSTI]

Supreme People's Court ("SPC") review of every death sen-view of each sentence by the SPC. These reforms are the mostdoubts about whether the SPC would effectively implement

Minas, Stephen

2009-01-01T23:59:59.000Z

405

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network [OSTI]

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

406

Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry  

E-Print Network [OSTI]

for on- board hydrogen production for fuel-cell poweredSteam-Reforming Hydrogen production Reactors, M.S. Thesis,at the UC Davis Hydrogen Production and Utilization

Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

2006-01-01T23:59:59.000Z

407

Effects of operating conditions, compression ratio, and gasoline reformate on SI engine knock limits  

E-Print Network [OSTI]

A set of experiments was performed to investigate the effects of air-fuel ratio, inlet boost pressure, hydrogen rich fuel reformate, and compression ratio on engine knock behavior. For each condition the effect of spark ...

Gerty, Michael D

2005-01-01T23:59:59.000Z

408

The risk of reform : privatisation and liberalisation in the Brazilian electric power industry  

E-Print Network [OSTI]

In 1996, when Brazil was well-underway to privatising and liberalising its electric power industry, few would have predicted that within five years the reforms would be a shambles. Like its neighbors Argentina and Chile, ...

Tankha, Sunil, Ph. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

409

Healthcare reform in the United States and China: pharmaceutical market implications  

E-Print Network [OSTI]

. This article analyzes the implications of health system reforms in the United States and China for national pharmaceutical markets. It follows a historical institutionalist approach that identifies path dependency in the design and operation of national health...

Daemmrich, Arthur; Mohanty, Ansuman

2014-07-14T23:59:59.000Z

410

Fuel cell generator with fuel electrodes that control on-cell fuel reformation  

DOE Patents [OSTI]

A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA); Zhang, Gong (Murrysville, PA)

2011-10-25T23:59:59.000Z

411

The Resurgence of Land Reform Policy and Agrarian Movements in Indonesia  

E-Print Network [OSTI]

157 He invoked Amartya Sen’s notion of development asby access reform à la Amartya Sen” 166 (Winoto 2006:81, bolddengan reformasi akses ala Amartya Sen. to mention the NARP

Rachman, Noer Fauzi

2011-01-01T23:59:59.000Z

412

Organizational sense making : responsibilities to the MCAS reform in the Massachusetts public schools  

E-Print Network [OSTI]

Educational reform has become a central concern of public policy debates at both the state and federal level. The policy trend both nationally and locally is towards uniform standards in education, with testing as the ...

Goldman, Janice J., 1953-

2005-01-01T23:59:59.000Z

413

The rules of ruling : charter reform in Los Angeles, 1850-2008  

E-Print Network [OSTI]

and officers face the charter as a constant constraint. If centralized purchasingand Purchasing Agent. The Mayor would appoint these officerspurchasing, campaign finance reform, strengthen the recall to cover appointed officials and create staggered elections for officers.

Ingram, James Warren

2008-01-01T23:59:59.000Z

414

Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming  

SciTech Connect (OSTI)

In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

Gunther Dieckmann

2006-06-30T23:59:59.000Z

415

Admonition and the academy : installation, video, and performance art in Reform Era China  

E-Print Network [OSTI]

China's Reform Era (1978-present) has seen the reinvigoration of academic, and artistic practice, and a rapprochement between the Chinese Communist Party and the intellectual elite. At its beginnings in the early- to ...

Oen, Karin Grace

2012-01-01T23:59:59.000Z

416

The Forgotten Children: African American Children and Child Welfare Reform in St. Louis, 1890-1930  

E-Print Network [OSTI]

Abstract Forgotten Children examines the influence of racial ideology on the trajectory of child welfare reform in late nineteenth century and early twentieth century St. Louis. The modern American child welfare system emerged in this time period...

Thirlkel, Thomas E.

2010-05-07T23:59:59.000Z

417

Building the Reformed Kirk: the cultural use of ecclesiastical buildings in Scotland, 1560–1645   

E-Print Network [OSTI]

This thesis examines the built environment and culture of Scotland between 1560 and 1645 by analysing church buildings erected during the period. The mid-sixteenth century ecclesiastical Reformation and mid-seventeenth-century ...

Chernoff, Graham Thomas

2013-07-05T23:59:59.000Z

418

Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Background Paper  

Broader source: Energy.gov [DOE]

Paper by Arlene Anderson and Tracy Carole presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group, with a focus on key drivers, purpose, and scope.

419

OXIDATION OF FUELS IN THE COOL FLAME REGIME FOR COMBUSTION AND REFORMING FOR FUEL CELLS.  

SciTech Connect (OSTI)

THE REVIEW INTEGRATES RECENT INVESTIGATIONS ON AUTO OXIDATION OF FUEL OILS AND THEIR REFORMING INTO HYDROGEN RICH GAS THAT COULD SERVE AS A FEED FOR FUEL CELLS AND COMBUSTION SYSTEMS.

NAIDJA,A.; KRISHNA,C.R.; BUTCHER,T.; MAHAJAN,D.

2002-08-01T23:59:59.000Z

420

Evaluating the Evidence on Electricity Reform: Lessons for the South East Europe (SEE) Market  

E-Print Network [OSTI]

at evaluating the impact of any given step (e.g. privatisation or the introduction of incentive regulation etc.) problematic. These observations immediately give rise to the suggestion that it is not clear that a proper evaluation of the impact of electricity... .g. with a single reform variable) or to distinguish all the elements of reform carefully (e.g. incentive regulation). Clearly the ability of the model to deliver efficient investment, especially in generation, has not been established by econometrics...

Pollitt, Michael G.

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Reforming Small Power Systems under Political Volatility: The Case of Nepal  

E-Print Network [OSTI]

electricity systems in Nepal and other South Asian countries are inefficient and suffer from institutionalized corruption and persistent rent seeking behaviour together with poor economic governance of the power sector (Smith, 2004). 3. Major Reforms... electricity reforms initiatives was mooted after the creation of NEA by merging the Electricity Department, Electricity Boards and Nepal Electricity Corporation in 1985 in accordance with the provisions of NEA Act of 1984 (Thakur, 2002). The establishment...

Nepal, Rabindra; Jamasb, Tooraj

422

Steam Reforming on Transition-metal Carbides from Density-functional Theory  

SciTech Connect (OSTI)

A screening study of the steam reforming reaction on clean and oxygen covered early transition-metal carbides surfaces is performed by means of density-functional theory calculations. It is found that carbides provide a wide spectrum of reactivities, from too reactive via suitable to too inert. Several molybdenum-based systems are identified as possible steam reforming catalysts. The findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2012-05-11T23:59:59.000Z

423

Alkylating agent methyl methanesulfonate (MMS) induces a wave of global protein hyperacetylation: Implications in cancer cell death  

SciTech Connect (OSTI)

Protein acetylation modification has been implicated in many cellular processes but the direct evidence for the involvement of protein acetylation in signal transduction is very limited. In the present study, we found that an alkylating agent methyl methanesulfonate (MMS) induces a robust and reversible hyperacetylation of both cytoplasmic and nuclear proteins during the early phase of the cellular response to MMS. Notably, the acetylation level upon MMS treatment was strongly correlated with the susceptibility of cancer cells, and the enhancement of MMS-induced acetylation by histone deacetylase (HDAC) inhibitors was shown to increase the cellular susceptibility. These results suggest protein acetylation is important for the cell death signal transduction pathway and indicate that the use of HDAC inhibitors for the treatment of cancer is relevant.

Lee, Min-Young [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Kim, Myoung-Ae [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Kim, Hyun-Ju [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Bae, Yoe-Sik [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Park, Joo-In [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Kwak, Jong-Young [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of); Chung, Jay H. [Laboratory of Biochemical Genetics, NHLBI, NIH, 10 Center Drive, Bethesda, MD 20892 (United States); Yun, Jeanho [Department of Biochemistry, College of Medicine, Dong-A University, 3-1, Dongdaeshin-Dong, Seo-Gu, Busan 602-714, South Korea (Korea, Republic of)]. E-mail: yunj@dau.ac.kr

2007-08-24T23:59:59.000Z

424

Surface structure of coadsorbed benzene and carbon monoxide on the rhodium(111) single crystal analyzed with low-energy electron diffraction intensities  

SciTech Connect (OSTI)

The first structural analysis of a molecular coadsorbate system is presented. Mutual reordering and site shifting are found to occur for benzene and CO coadsorbed in a (/sub 13//sup 31/) lattice on Rh(111). This low-energy electron diffraction (LEED) intensity analysis yields the first confirmed hollow-site adsorption of CO on a single-crystal metal surface, with a C-O bond length expanded by 0.06 +/- 0.05 A from the gas phase. The flat-lying benzene is found centered over hcp-type hollow sites with a strong Kekule-type distortion: C-C bond lengths alternate between 1.33 +/- 0.15 A (hydrogen positions were not determined). This suggests the possibility of a 1,3,5-cyclohexatriene species being formed. The Rh-C bond length is 2.35 +/- 0.05 A for benzene and 2.16 +/- 0.04 A for CO.

Van Hove, M.A.; Lin, R.F.; Somorjai, G.A.

1986-05-14T23:59:59.000Z

425

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

Paul A. Erickson

2005-09-30T23:59:59.000Z

426

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR BENCH-SCALE REFORMER TREATABILITY STUDIES  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required. The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.

BANNING DL

2011-02-11T23:59:59.000Z

427

Electrochemical investigations of product deposition and dissolution of the reduced forms of alkyl viologens on glassy carbon  

SciTech Connect (OSTI)

The reductions of several alkyl viologens in aqueous solutions at a glassy carbon working electrode were investigated. All of the viologens studied exist as colorless dication salts (V[sup 2+]) which are easily reduced to the violet cation radical (V[sup +.]) by a one electron process. The dications can be reduced directly to the yellow-brown, quinoidal neutral species (V[sup 0]) by a two electron process, or to neutral via the cation radical by two successive one electron transfers. In the absence of sodium n-alkyl sulfates, all but one displayed reversible, diffusion-controlled electron transfers for the V[sup 2+]/V[sup +.] couple. With addition of sodium decyl, undecyl and dodecyl sulfates at concentrations below their critical micelle concentrations (cmc), the cation radical product of methyl and ethyl viologen deposits on the electrode surface. The addition of these surfactants at concentrations below their cmc's precipitated the dicationic species of butyl, benzyl, and heptyl viologens. All redox forms of the viologens are solubilized by the onset of micelles. Double potential step chronocoulometry showed the deposition mechanism to be governed by solubility product equilibria. Open-circuit rotating ring-disk electrode (OC-RRDE) voltammetric experiments revealed that two forms of deposit exist. Above the cmc, little or no deposition of neutral forms occurs as V[sup 0] is solubilized in the hydrocarbon interior of the micelles. Cyclic voltammetric investigations revealed that there are also two forms of deposit for neutral viologens. For heptyl viologen, there may be more than two forms of both the V[sup +.] and V[sup 0] deposits. Deposition of the neutral form is governed by nucleation and subsequent growth. From RRDE voltammetry lower limits of solubility of neutral viologens were estimated. OC-RRDE voltammetric experiments showed that dissolution occurred by extremely fast conproportionation reaction which caused the process to be mass-transfer controlled.

Engelman, E.E.

1993-01-01T23:59:59.000Z

428

Facile preparation of sphere-like copper ferrite nanostructures and their enhanced visible-light-induced photocatalytic conversion of benzene  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Spinel CuFe{sub 2}O{sub 4} nanospheres were successfully synthesized via a facile method. • CuFe{sub 2}O{sub 4} nanospheres showed high photocatalytic activity toward benzene. • Ethyl acetate, carboxylic acid and aldehyde were the intermediate products. - Abstract: Spinel copper ferrite nanospheres with diameters of about 116 nm were synthesized in high yield via a facile solvothermal route. The prepared nanospheres had cubic spinel structure and exhibited good size uniformity and regularity. The band-gap energy of CuFe{sub 2}O{sub 4} nanospheres was calculated to be about 1.69 eV, indicating their potential visible-light-induced photocatalytic activity. The dramatically enhanced photocatalytic activity of the CuFe{sub 2}O{sub 4} nanospheres was evaluated via the photocatalytic conversion of benzene under Xe lamp irradiation. By using the in situ FTIR technique, ethyl acetate, carboxylic acid and aldehyde could be regarded as the intermediate products, and CO{sub 2} was produced as the final product during the reaction process. This study provided new insight into the design and preparation of functional nanomaterials with sphere structure in high yield, and the as-grown architectures demonstrated an excellent ability to remove organic pollutants in the atmosphere.

Shen, Yu, E-mail: shenyuqing0322@gmail.com [School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028 (China); Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Wu, Yanbo; Xu, Hongfeng; Fu, Jie [School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028 (China); Li, Xinyong; Zhao, Qidong; Hou, Yang [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China)

2013-10-15T23:59:59.000Z

429

Methods of reforming hydrocarbon fuels using hexaaluminate catalysts  

DOE Patents [OSTI]

A metal substituted hexaaluminate catalyst for reforming hydrocarbon fuels to synthesis gas of the general formula AB.sub.yAl.sub.12-yO.sub.19-.delta., A being selected from alkali metals, alkaline earth metals and lanthanide metals or mixtures thereof. A dopant or surface modifier selected from a transitions metal, a spinel of an oxygen-ion conductor is incorporated. The dopant may be Ca, Cs, K, La, Sr, Ba, Li, Mg, Ce, Co, Fe, Ir, Rh, Ni, Ru, Cu, Pe, Os, Pd, Cr, Mn, W, Re, Sn, Gd, V, Ti, Ag, Au, and mixtures thereof. The oxygen-ion conductor may be a perovskite selected from M'RhO.sub.3, M'PtO.sub.3, M'PdO.sub.3, M'IrO.sub.3, M'RuO.sub.3 wherein M'=Mg, Sr, Ba, La, Ca; a spinel selected from MRh.sub.2O.sub.4, MPt.sub.2O.sub.4, MPd.sub.2O.sub.4, MIr.sub.2O.sub.4, MRu.sub.2O.sub.4 wherein M=Mg, Sr, Ba, La, Ca and mixtures thereof; a florite is selected from M''O.sub.2.

Gardner, Todd H. (Morgantown, WV); Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV)

2012-03-27T23:59:59.000Z

430

Steam reforming of low-level mixed waste  

SciTech Connect (OSTI)

The U.S. department of Energy (DOE) is responsible for the treatment and disposal of an inventory of approximately 160,000 tons of Low-Level Mixed Waste (LLMW). Most of this LLMW is stored in drums, barrels and steel boxes at 20 different sites throughout the DOE complex. The basic objective of low-level mixed waste treatment systems is to completely destroy the hazardous constituents and to simultaneously isolate and capture the radionuclides in a superior final waste form such as glass. The DOE is sponsoring the development of advanced technologies that meet this objective while achieving maximum volume reduction, low-life cycle costs and maximum operational safety. ThermoChem, Inc. is in the final stages of development of a steam-reforming system capable of treating a wide variety of DOE low-level mixed waste that meets these objectives. The design, construction, and testing of a nominal 1 ton/day Process Development Unit is described.

Voelker, G.E.; Steedman, W.G. [Thermochem, Inc., Columbia, MD (United States); Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

1996-12-31T23:59:59.000Z

431

FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL  

SciTech Connect (OSTI)

Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

Williams, M

2008-05-09T23:59:59.000Z

432

A novel technique for on-line coke gasification during propane steam reforming using forced CO2 cycling.  

E-Print Network [OSTI]

??Steam reforming is an important source of synthesis gas production that is used by major petrochemical processes such as ammonia, methanol and the Fisher-Tropsch process.… (more)

Alenazey, Feraih Sheradh

2011-01-01T23:59:59.000Z

433

Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products  

SciTech Connect (OSTI)

A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

2011-11-17T23:59:59.000Z

434

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided by Fundamental Atomistics Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a novel hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, Sn/Ni alloy as a potential carbon tolerant reforming catalyst. Sn/Ni alloy was synthesized and tested in steam reforming of methane, propane, and isooctane. We demonstrated that the alloy catalyst is carbon-tolerant under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by a few characteristics: (a) Knowledge-based, bottom-up approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) The focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2006-08-31T23:59:59.000Z

435

New Insights into Reaction Mechanisms of Ethanol Steam Reforming on Co-ZrO2  

SciTech Connect (OSTI)

The reaction pathway of ethanol steam reforming on Co-ZrO2 has been identified and the active sites associated with each step are proposed. Ethanol is converted to acetaldehyde and then to acetone, followed by acetone steam reforming. More than 90% carbon was found to follow this reaction pathway. N2-Sorption, X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR), in situ X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy, as well as theoretical Density Functional Theory (DFT) calculations have been employed to identify the structure and functionality of the catalysts, which was further used to correlate their performance in ESR. It was found that metallic cobalt is mainly responsible for the acetone steam reforming reactions; while, CoO and basic sites on the support play a key role in converting ethanol to acetone via dehydrogenation and condensation/ketonization reaction pathways. The current work provides fundamental understanding of the ethanol steam reforming reaction mechanisms on Co-ZrO2 catalysts and sheds light on the rational design of selective and durable ethanol steam reforming catalysts.

Sun, Junming; Karim, Ayman M.; Mei, Donghai; Engelhard, Mark H.; Bao, Xinhe; Wang, Yong

2015-01-01T23:59:59.000Z

436

Development of Sulfur and Carbon Tolerant Reforming Alloy Catalysts Aided Fundamental Atomistic Insights  

SciTech Connect (OSTI)

Current hydrocarbon reforming catalysts suffer from rapid carbon and sulfur poisoning. Even though there is a tremendous incentive to develop more efficient catalysts, these materials are currently formulated using inefficient trial and error experimental approaches. We have utilized a hybrid experimental/theoretical approach, combining quantum Density Functional Theory (DFT) calculations and various state-of-the-art experimental tools, to formulate carbon tolerant reforming catalysts. We have employed DFT calculations to develop molecular insights into the elementary chemical transformations that lead to carbon poisoning of Ni catalysts. Based on the obtained molecular insights, we have identified, using DFT quantum calculation, various Ni alloy catalysts as potential carbon tolerant reforming catalysts. The alloy catalysts were synthesized and tested in steam reforming and partial oxidation of methane, propane, and isooctane. We demonstrated that the alloy catalysts are much more carbon-tolerant than monometallic Ni catalysts under nearly stoichiometric steam-to-carbon ratios. Under these conditions, monometallic Ni is rapidly poisoned by sp2 carbon deposits. The research approach is distinguished by two characteristics: (a) knowledge-based, bottomup approach, compared to the traditional trial and error approach, allows for a more efficient and systematic discovery of improved catalysts. (b) the focus is on exploring alloy materials which have been largely unexplored as potential reforming catalysts.

Suljo Linic

2008-12-31T23:59:59.000Z

437

An Innovative Injection and Mixing System for Diesel Fuel Reforming  

SciTech Connect (OSTI)

This project focused on fuel stream preparation improvements prior to injection into a solid oxide fuel cell reformer. Each milestone and the results from each milestone are discussed in detail in this report. The first two milestones were the creation of a coking formation test rig and various testing performed on this rig. Initial tests indicated that three anti-carbon coatings showed improvement over an uncoated (bare metal) baseline. However, in follow-up 70 hour tests of the down selected coatings, Scanning Electron Microscope (SEM) analysis revealed that no carbon was generated on the test specimens. These follow-up tests were intended to enable a down selection to a single best anti-carbon coating. Without the formation of carbon it was impossible to draw conclusions as to which anti-carbon coating showed the best performance. The final 70 hour tests did show that AMCX AMC26 demonstrated the lowest discoloration of the metal out of the three down selected anti-carbon coatings. This discoloration did not relate to carbon but could be a useful result when carbon growth rate is not the only concern. Unplanned variations in the series of tests must be considered and may have altered the results. Reliable conclusions could only be drawn from consistent, repeatable testing beyond the allotted time and funding for this project. Milestones 3 and 4 focused on the creation of a preheating pressure atomizer and mixing chamber. A design of experiment test helped identify a configuration of the preheating injector, Build 1, which showed a very uniform fuel spray flow field. This injector was improved upon by the creation of a Build 2 injector. Build 2 of the preheating injector demonstrated promising SMD results with only 22psi fuel pressure and 0.7 in H2O of Air. It was apparent from testing and CFD that this Build 2 has flow field recirculation zones. These recirculation zones may suggest that this Build 2 atomizer and mixer would require steam injection to reduce the auto ignition potential. It is also important to note that to achieve uniform mixing within a short distance, some recirculation is necessary. Milestone 5 generated CFD and FEA results that could be used to optimize the preheating injector. CFD results confirmed the recirculation zones seen in test data and confirmed that the flow field would not change when attached to a reformer. The FEA predicted fuel wetted wall temperatures which led to several suggested improvements that could possibly improve nozzle efficiency. Milestone 6 (originally an optional task) took a different approach than the preheating pressure atomizer. It focused on creation and optimization of a piezoelectric injector which could perform at extremely low fuel pressures. The piezoelectric atomizer showed acceptable SMD results with fuel pressure less than 1.0 psig and air pressure less than 1.0 in H2O. These SMD values were enhanced when a few components were changed, and it is expected would improve further still at elevated air temperatures. It was demonstrated that the piezoelectric injector could accomplish the desired task. The addition of phase tracking and a burst mode to the frequency controller increased the usability of the piezoelectric injector. This injector is ready to move on to the next phase of development. Engine Components has met the required program milestones of this project. Some of the Milestones were adjusted to allow Milestone 6 to be completed in parallel with the other Milestones. Because of this, Task 3.10 and 3.13 were made optional instead of Milestone 6. Engine Components was extremely grateful for the support that was provided by NETL in support of this work.

Spencer Pack

2007-12-31T23:59:59.000Z

438

FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION  

SciTech Connect (OSTI)

The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

Jantzen, C

2006-09-13T23:59:59.000Z

439

Durability Testing of Fluidized Bed Steam Reforming Products  

SciTech Connect (OSTI)

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

2005-07-01T23:59:59.000Z

440

Liquid-liquid equilibria for the ternary systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene  

SciTech Connect (OSTI)

Sulfolane is widely used as a solvent for the extraction of aromatic hydrocarbons. Ternary phase equilibrium data are essential for the proper understanding of the solvent extraction process. Liquid-liquid equilibrium data for the systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene were determined at 298.15, 308.15, and 318.15 K. Tie line data were satisfactorily correlated by the Othmer and Tobias method. The experimental data were compared with the values calculated by the UNIQUAC and NRTL models. Good quantitative agreement was obtained with these models. However, the calculated values based on the NRTL model were found to be better than those based on the UNIQUAC model.

Lee, S.; Kim, H. [Seoul National Univ. (Korea, Republic of). Dept. of Chemical Engineering

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Process and apparatus for the production of hydrogen by steam reforming of hydrocarbon  

DOE Patents [OSTI]

In the steam reforming of hydrocarbon, particularly methane, under elevated temperature and pressure to produce hydrogen, a feed of steam and hydrocarbon is fed into a first reaction volume containing essentially only reforming catalyst to partially reform the feed. The balance of the feed and the reaction products of carbon dioxide and hydrogen are then fed into a second reaction volume containing a mixture of catalyst and adsorbent which removes the carbon dioxide from the reaction zone as it is formed. The process is conducted in a cycle which includes these reactions followed by countercurrent depressurization and purge of the adsorbent to regenerate it and repressurization of the reaction volumes preparatory to repeating the reaction-sorption phase of the cycle.

Sircar, Shivaji (Wescosville, PA); Hufton, Jeffrey Raymond (Fogelsville, PA); Nataraj, Shankar (Allentown, PA)

2000-01-01T23:59:59.000Z

442

Steam reforming on transition-metal carbides from density-functional theory  

E-Print Network [OSTI]

A screening study of the steam reforming reaction (CH_4 + H_2O -> CO + 3H_2) on early transition-metal carbides (TMC's) is performed by means of density-functional theory calculations. The set of considered surfaces includes the alpha-Mo_2C(100) surfaces, the low-index (111) and (100) surfaces of TiC, VC, and delta-MoC, and the oxygenated alpha-Mo_2C(100) and TMC(111) surfaces. It is found that carbides provide a wide spectrum of reactivities towards the steam reforming reaction, from too reactive via suitable to too inert. The reactivity is discussed in terms of the electronic structure of the clean surfaces. Two surfaces, the delta-MoC(100) and the oxygen passivated alpha-Mo_2C(100) surfaces, are identified as promising steam reforming catalysts. These findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2009-01-01T23:59:59.000Z

443

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST  

SciTech Connect (OSTI)

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

BANNING DL

2010-08-03T23:59:59.000Z

444

Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast  

E-Print Network [OSTI]

of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

Leu, Tzong-Shyng "Jeremy"

445

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration  

E-Print Network [OSTI]

Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air PEM fuel cell systems fuelled by steam reformed methanol. Various fuel cell system solutions exist, they mainly differ depending on the desired fuel used. High temperature PEM (HTPEM) fuel cells offer

Berning, Torsten

446

Theoretical study of Diesel fuel reforming by a non-thermal arc discharge A. Lebouvier1,2  

E-Print Network [OSTI]

Theoretical study of Diesel fuel reforming by a non-thermal arc discharge A. Lebouvier1,2 , G anti-pollution norm namely for Diesel powered vehicles. NOx (NO, NO2,...) are very irritant pollutants- nologies purge is the use of non-thermal plasma. Plasma reforming of diesel fuel and exhaust gas mix- ture

Paris-Sud XI, Université de

447

The Olympus Scandal and Corporate Governance Reform: Can Japan Find a Middle Ground between the Board Monitoring Model and Management Model  

E-Print Network [OSTI]

OLYMPUS SCANDAL AND CORPORATE GOVERNANCE REFORM: CAN JAPANScandal and Corporate Governance Issues A. Background of theunder Japan's Corporate Governance System ..

Aronson, Bruce E.

2012-01-01T23:59:59.000Z

448

Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Kick-Off Meeting Proceedings Hilton Garden Inn-BWI,Baltimore, MD October 24, 2006  

Broader source: Energy.gov [DOE]

Proceedings from the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

449

Demonstration of Energy Efficient Steam Reforming in Microchannels for Automotive Fuel Processing  

SciTech Connect (OSTI)

A compact, energy efficient microchannel steam reforming system has been demonstrated. The unit generates sufficient reformate to provide H2 to a 10 kWe PEM fuel cell (when coupled with a water-gas shift and CO cleanup reactors). The overall volume of the reactor is 4.9 liters while that of the supporting network of heat exchangers is 1.7 liters . Use of a microchannel configuration in the steam reforming reactor produces rapid heat and mass transport which enables fast kinetics for the highly endothermic reaction. Heat is provided to the reactor by a combustion gas flowing in interleaved microchannels in cross flow with the reaction channels. A network of microchannel heat exchangers allows recovery of heat in the reformate product and combustion exhaust streams for use in vaporizing water and fuel, preheating reactants to reactor temperature and preheating combustion air. The microchannel architecture enables very compact and highly effective heat exchangers to be constructed. As a result of the heat exchange network, the system exhaust temperatures are typically ~50?C for the combustion gas and ~130?C for the reformate product while the reactor is operated at 750?C. While reforming isooctane at a rate sufficient to supply a 13.7 kWe fuel cell the system achieved 98.6% conversion with an estimated overall system efficiency after integration with WGS and PEM fuel cell of 44% (electrical output / LHV fuel). The efficiency estimate assumes integration with a WGS reactor (90% conversion CO to CO2 with 100% selectivity) and a PEM fuel cell (64% power conversion effectiveness with 85% H2 utilization for an overall 54% efficiency) and does not include parasitic losses for compression of combustion air. Acknowledgement The work described here was funded by the U.S. Department of Energy, Office of Transportation Technology as part of the OTT Fuel Cells Program.

Whyatt, Greg A.; TeGrotenhuis, Ward E.; Geeting, John GH; Davis, James M.; Wegeng, Robert S.; Pederson, Larry R.

2002-01-01T23:59:59.000Z

450

Quantifying the Sigma and Pi interactions between U(V) f orbitals and halide, alkyl, alkoxide, amide and ketimide ligands  

SciTech Connect (OSTI)

f Orbital bonding in actinide and lanthanide complexes is critical to their behavior in a variety of areas from separations to magnetic properties. Octahedral f1 hexahalide complexes have been extensively used to study f orbital bonding due to their simple electronic structure and extensive spectroscopic characterization. The recent expansion of this family to include alkyl, alkoxide, amide, and ketimide ligands presents the opportunity to extend this study to a wider variety of ligands. To better understand f orbital bonding in these complexes, the existing molecular orbital (MO) model was refined to include the effect of covalency on spin orbit coupling in addition to its effect on orbital angular momentum (orbital reduction). The new MO model as well as the existing MO model and the crystal field (CF) model were applied to the octahedral f1 complexes to determine the covalency and strengths of the ? and ? bonds formed by the f orbitals. When covalency is significant, MO models more precisely determined the strengths of the bonds derived from the f orbitals; however, when covalency was small, the CF model was better than either MO model. The covalency determined using the new MO model is in better agreement with both experiment and theory than that predicted by the existing MO model. The results emphasize the role played by the orbital energy in determining the strength and covalency of bonds formed by the f orbitals.

University of California, Berkeley; Lukens, Wayne W.; Edelstein, Norman M.; Magnani, Nicola; Hayton, Trevor W.; Fortier, Skye; Seaman, Lani A.

2013-06-20T23:59:59.000Z

451

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-04-01T23:59:59.000Z

452

Testing of a Catalytic Partial Oxidation Diesel Reformer with a Solid Oxide Fuel Cell System  

SciTech Connect (OSTI)

Rural Alaska currently uses diesel generator sets to produce much of its power. The high energy content of diesel (i.e. ~140,000 BTU per gallon) makes it the fuel of choice because this reduces the volume of fuel that must be transported, stored, and consumed in generating the power. There is an existing investment in infrastructure for the distribution and use of diesel fuel. Problems do exist, however, in that diesel generators are not very efficient in their use of diesel, maintenance levels can be rather high as systems age, and the environmental issues related to present diesel generators are of concern. The Arctic Energy Technology Development Laboratory at the University of Alaska -- Fairbanks is sponsoring a project to address the issues mentioned above. The project takes two successful systems, a diesel reformer and a tubular solid oxide fuel cell unit, and jointly tests those systems with the objective of producing a for-purpose diesel fueled solid oxide fuel cell system that can be deployed in rural Alaska. The reformer will convert the diesel to a mixture of carbon monoxide and hydrogen that can be used as a fuel by the fuel cell. The high temperature nature of the solid oxide fuel cell (SOFC is capable of using this mixture to generate electricity and provide usable heat with higher efficiency and lower emissions. The high temperature nature of the SOFC is more compatible with the arctic climate than are low temperature technologies such as the proton exchange membrane fuel cells. This paper will look at the interaction of a SOFC system that is designed to internally reform methane and a catalytic partial oxidation (CPOX) diesel reformer. The diesel reformer produces a reformate that is approximately 140 BTU per scf (after removal of much of the reformate water) as compared to a methane based reformate that is over twice that value in BTU content. The project also considers the effect of altitude since the test location will be at 4800 feet with the consequential drop in oxygen content and necessary increases in flow rates.

Lyman Frost; Bob Carrington; Rodger McKain; Dennis Witmer

2005-03-01T23:59:59.000Z

453

A review of "John Donne: The Reforming Soul" by John Stubbs  

E-Print Network [OSTI]

REVIEWS 1 John Stubbs. John Donne: The Reformed Soul. New York: W. W. Norton, 2007. 576 pp. $35.00. Review by SEAN MCDOWELL, SEATTLE UNIVERSITY. In John Donne scholarship, the nonfiction book one is most likely to find not just in libraries... but also in chain bookstores across the English-speaking world is John Donne: The Reformed Soul, the new full-length biography of Donne?s life by English scholar John Stubbs. Published first in the U. K. in 2006 and subsequently by W. W. Norton in 2007...

McDowell, Sean

2008-01-01T23:59:59.000Z

454

The BFA Intercollegiate Athletics Committee (IAC) has completed its review and discussion of the Coalition on Intercollegiate Athletics (COIA) report, entitled "Framing the Future: Reforming  

E-Print Network [OSTI]

of the Coalition on Intercollegiate Athletics (COIA) report, entitled "Framing the Future: Reforming-by-campus basis -- for reforming intercollegiate athletics. The University of Colorado has been deeply involved are now models for many of the reforms that COIA recommends; and is, therefore, already a recognized

Bradley, Elizabeth

455

University Council Reform 2012-13 For some years, while appreciating the opportunity to return to campus annually for the University Council  

E-Print Network [OSTI]

University Council Reform 2012-13 Context: For some years, while appreciating the opportunity its own composition and size providing impetus to consider reform further. Following the University to look anew at the possible reform of Council in light of the changes to the Charter and a Board

Graham, Nick

456

Eric Gobe, "Deceptive Liberal Reforms: Institutional Adjustments and the Dynamics of Authoritarianism in Tunisia (19972005)", in Kienle Eberhard (ed.), Democracy Building & Democracy Erosion. Political  

E-Print Network [OSTI]

1 Eric Gobe, "Deceptive Liberal Reforms: Institutional Adjustments and the Dynamics Reforms: Institutional Adjustments and the Dynamics of Authoritarianism in Tunisia (1997­2005) Eric Gobe of political forces. In Ben Ali's Tunisia, the institutional reforms introduced in the 1990s

Boyer, Edmond

457

*sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer for a HTPEM fuel cell system  

E-Print Network [OSTI]

of the fuel water/methanol mixture is done by electrical heaters, but could be integrated with the burner side reformed hydro- carbon as fuel for fuel cells can redu- ce fuel storage volume considerably. The PBI of evaporated water and methanol is presented and steam-reformed to a hydrogen rich gas. The steam reforming

Andreasen, Søren Juhl

458

Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report  

SciTech Connect (OSTI)

Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

NONE

1996-11-01T23:59:59.000Z

459

Disclosures due to Health Care Reform Changes Disclosure of Grandfather Status  

E-Print Network [OSTI]

Disclosures due to Health Care Reform Changes Disclosure of Grandfather Status UCSD Medical Center of the Affordable Care Act that apply to other plans. Grandfathered health plans must comply with certain other believes this health plan coverage is a "grandfathered health plan" under the Patient Protection

Gleeson, Joseph G.

460

Reforming Household Energy Markets: Some Welfare Effects in the United Catherine Waddams Price  

E-Print Network [OSTI]

final energy prices (though those of monopoly inputs such as transmission and distribution remainReforming Household Energy Markets: Some Welfare Effects in the United Kingdom by Catherine Waddams Price Centre for Competition and Regulation and School of Management University of East Anglia, UK

Feigon, Brooke

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Studies of mechanisms and kinetics of methane and ethane steam reforming on nickel catalysts  

SciTech Connect (OSTI)

Methane and ethane adsorption/desorption and reaction on steam-reforming catalysts, Ni(INCO), Ni/ZrO{sub 2}, and Ni/CaAl{sub 2}O{sub 4}, were studied by temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and thermogravimetric (TGA) techniques. The data show that only a fraction of the methane adsorbed (determined by TPSR with H{sub 2}) on nickel catalysts is desorbed during TPD experiments. The results of TPD indicate supports and promoters affect the adsorption of methane and ethane, and transformation of adsorbed carbon species. Several carbon types formed during methane and ethane adsorptions including {alpha}, {beta}, {gamma}, vermicular (v), and graphitic (c) carbon can be identified by TPSR. These data indicate that the distribution of these carbon forms is also strongly a function of adsorption temperature and catalyst. The results show that there are significant quantities of CH{sub 4}, CO, and CO{sub 2} desorbed during TPSR reaction of H{sub 2}O with preadsorbed CH{sub 4}, CD{sub 4} and C{sub 2}H{sub 6}. The agreement between previously reported steady-state and the unsteady-state steam reforming reforming rates of this study indicates that the steam-reforming kinetic data can be quantitatively measured by TPSR experiments.

Hsieh, H.Y.

1988-01-01T23:59:59.000Z

462

Anaerobic digestion for methane generation and ammonia reforming for hydrogen production  

E-Print Network [OSTI]

,000,000 digesters, 2000 [14]), among other places [15,16]. These digesters operate to generate biogas, comprisingAnaerobic digestion for methane generation and ammonia reforming for hydrogen production Accepted 24 May 2013 Available online Keywords: Anaerobic digestion Ammonia Bioenergy Bioammonia Hydrogen

463

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL  

E-Print Network [OSTI]

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL University Denmark ABSTRACT Solid oxide fuel cell (SOFC) is a promising technology for decentralized power be theoretically improved through integration in power cycles; the low emissions; and the pos- sibility of using

Berning, Torsten

464

EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY  

E-Print Network [OSTI]

1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto combustion engine. The potential benefits of using H2 in spark ignition (SI) engines may be listed as follows

Paris-Sud XI, Université de

465

Project Information Form Project Title Program for Vehicle Regulatory Reform: Assessing Life Cycle-Based  

E-Print Network [OSTI]

,931.44 Total Project Cost $98,931.44 Agency ID or Contract Number DTRT13-G-UTC29 Start and End Dates November 1Project Information Form Project Title Program for Vehicle Regulatory Reform: Assessing Life Cycle, 2014 ­ October 31, 2015 Brief Description of Research Project Current greenhouse gas emissions

California at Davis, University of

466

Food Price Subsidies and Nutrition: Evidence from State Reforms to India's Public Distribution System1  

E-Print Network [OSTI]

Food Price Subsidies and Nutrition: Evidence from State Reforms to India's Public Distribution, the Economic Research Service, and the University of Sussex. All remaining errors are attributable Research Service or the U.S. Department of Agriculture. 2 University of California - Berkeley, Law School

Bandyopadhyay, Antar

467

FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE  

SciTech Connect (OSTI)

This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

HEWITT WM

2011-04-08T23:59:59.000Z

468

ECOLOGICAL TAX REFORM: Estimated Environmental and Employment Effects in British Columbia  

E-Print Network [OSTI]

of the Requirements for the Degree of Master of Resource Management in the School of Resource Environmental Managementi ECOLOGICAL TAX REFORM: Estimated Environmental and Employment Effects in British Columbia by Amy in British Columbia. To do this, I simulated ecological taxes on water consumption, solid waste and carbon

469

Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming  

SciTech Connect (OSTI)

A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences. LCA is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes.

Spath, P. L.; Mann, M. K.

2000-09-28T23:59:59.000Z

470

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-09-30T23:59:59.000Z

471

Indian agricultural development in the context of economic reforms. Causes of change and issues for  

E-Print Network [OSTI]

are an important component of the agricultural policy. The agricultural policy of India supports the application the influence of reforms in the 1990s regarding the agricultural development in India. Many studies have sector rather than on the agricultural sector. After India gained independence, the government

Richner, Heinz

472

The energy sector in Sri Lanka is currently a hotbed of activity and change. A reform  

E-Print Network [OSTI]

the new reformed electricity struc- ture, private sector power developers will attempt to recover is underway in the power sector, and the debt-ridden state-owned electricity utility - the Ceylon Electricity of the electricity sector in this small island country in South Asia. The country's current installed power capacity

Kammen, Daniel M.

473

Potential Impacts of Mexico's Energy Reform on Texas' Transportation System 1 Testimony of Jolanda Prozzi  

E-Print Network [OSTI]

the monopoly of the oil company Petróleos Mexicanos (Pemex) and encourage foreign investment in Mexico's energy, the tax burden on Pemex, and Mexico's petroleum fund. The reform to the Mexican constitution releases the government's control over Pemex and attracts private investment in the energy industry. The government

474

Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate  

E-Print Network [OSTI]

Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate Samuel September 2014 Available online xxx Keywords: High temperature PEM Fuel cell Methanol Impedance spectroscopy]. The report forecasts even more success for fuel cells in the near future. Proton exchange membrane (PEM) fuel

Kær, Søren Knudsen

475

Modeling and simulation of a reformate supplied PEM fuel cell stack, application to fault detection  

E-Print Network [OSTI]

Modeling and simulation of a reformate supplied PEM fuel cell stack, application to fault detection exchange membrane (PEM) fuel cells are the main type of fuel cell developed for ground vehicle applications tool for thermal characteristic and fault detection of a PEM fuel cell stack. The fuel cell stack model

Paris-Sud XI, Université de

476

Application of the Kellogg reforming exchanger system to large scale methanol plants  

SciTech Connect (OSTI)

In a majority of existing methanol production facilities, synthesis gas is furnished typically by a tubular fired steam reformer which uses natural gas as a feedstock. When one considers all synthesis gas produced from both ammonia and methanol plants, well over 80% is produced in a conventional reforming furnace. Steam reforming in a conventional sense, however, requires a considerable investment in both capital equipment and on-going maintenance and further, the use of such a unit operation will require heat recovery in the form of steam which forces the hand of the designer with respect to machinery driver selection. The authors have investigated alternatives to the coinventional approach with a view towards developing a process for methanol production that would be hopefully less expensive to construct, easier to operate and more reliable over the course of long term operation. In this paper, the authors present an alternative methanol plant process based on Kellogg`s proprietary reforming exchanger system (KRES). The flowsheet presented herein is for a 1500 MTPD facility that will produce US Federal Grade AA + methanol and will be compared on an economic basis to a conventional plant with respect to investment requirements and expected energy efficiency.

Joshi, G.; Schneider, R.V. III [M.W. Kellogg Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

477

Impacts of Selected Provisions of the "Agriculture Reform, Food and Jobs  

E-Print Network [OSTI]

May 2012 Impacts of Selected Provisions of the "Agriculture Reform, Food and Agricultural Policy Research Institute (FAPRI) at the University of Missouri (MU), 101 Park DeVille Drive, Suite E; Columbia, MO 65203. FAPRI­MU is part of the College of Agriculture, Food and Natural Resources

Noble, James S.

478

Novel Catalytic Fuel Reforming Using Micro-Technology with Advanced Separations Technology  

E-Print Network [OSTI]

when renewable resources power fuel cells. When compared to compressed hydrogen, reformed hydrocarbon sulfur-tolerant catalysts and hydrogen membrane technology to create a portable-sized hydrogen generator purification for electrical generation by a PEM fuel cell. This report presents the results of work

479

National Poverty Center Working Paper Series Welfare Reform, Saving, and Vehicle Ownership  

E-Print Network [OSTI]

National Poverty Center Working Paper Series #05-07 May 2005 Welfare Reform, Saving, and Vehicle at the National Poverty Center Working Paper Series index at: http of the author(s) and do not necessarily reflect the view of the National Poverty Center or any sponsoring agency

Shyy, Wei

480

Economic Growth, Poverty and Inequality: Indian Experience of Reforms and Development  

E-Print Network [OSTI]

Economic Growth, Poverty and Inequality: Indian Experience of Reforms and Development Panchanan Das economy since the 1970s has affected the incidence of poverty at the regional level and income suggest that the faster economic growth causes higher incidence of poverty and inequality. Income

Krivobokova, Tatyana

Note: This page contains sample records for the topic "alkylate reformate benzene" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

HEALTH CARE REFORM AND ITS EFFECT ON STUDENT HEALTH PLANS INTRODUCTION  

E-Print Network [OSTI]

TOPIC: HEALTH CARE REFORM AND ITS EFFECT ON STUDENT HEALTH PLANS INTRODUCTION: The Patient the initial impact of the Act on college and university- sponsored employee health care plans [1]. This Note-sponsored student health plans ("SHPs"). After the Affordable Care Act was enacted, many within the higher education

Martinez, Tony R.

482

Steam reforming as a method to treat Hanford underground storage tank (UST) wastes  

SciTech Connect (OSTI)

This report summarizes a Sandia program that included partnerships with Lawrence Livermore National Laboratory and Synthetica Technologies, Inc. to design and test a steam reforming system for treating Hanford underground storage tank (UST) wastes. The benefits of steam reforming the wastes include the resolution of tank safety issues and improved radionuclide separations. Steam reforming destroys organic materials by first gasifying, then reacting them with high temperature steam. Tests indicate that up to 99% of the organics could be removed from the UST wastes by steam exposure. In addition, it was shown that nitrates in the wastes could be destroyed by steam exposure if they were first distributed as a thin layer on a surface. High purity alumina and nickel alloys were shown to be good candidates for materials to be used in the severe environment associated with steam reforming the highly alkaline, high nitrate content wastes. Work was performed on designing, building, and demonstrating components of a 0.5 gallon per minute (gpm) system suitable for radioactive waste treatment. Scale-up of the unit to 20 gpm was also considered and is feasible. Finally, process demonstrations conducted on non-radioactive waste surrogates were carried out, including a successful demonstration of the technology at the 0.1 gpm scale.

Miller, J.E.; Kuehne, P.B. [eds.] [and others

1995-07-01T23:59:59.000Z

483

Experimental and Numerical Observations of Hydrate Reformation during Depressurization in a Core-Scale Reactor  

SciTech Connect (OSTI)

Gas hydrate has been predicted to reform around a wellbore during depressurization-based gas production from gas hydrate-bearing reservoirs. This process has an adverse effect on gas production rates and it requires time and sometimes special measures to resume gas flow to producing wells. Due to lack of applicable field data, laboratory scale experiments remain a valuable source of information to study hydrate reformation. In this work, we report laboratory experiments and complementary numerical simulations executed to investigate the hydrate reformation phenomenon. Gas production from a pressure vessel filled with hydrate-bearing sand was induced by depressurization with and without heat flux through the boundaries. Hydrate decomposition was monitored with a medical X-ray CT scanner and pressure and temperature measurements. CT images of the hydrate-bearing sample were processed to provide 3-dimensional data of heterogeneous porosity and phase saturations suitable for numerical simulations. In the experiments, gas hydrate reformation was observed only in the case of no-heat supply from surroundings, a finding consistent with numerical simulation. By allowing gas production on either side of the core, numerical simulations showed that initial hydrate distribution patterns affect gas distribution and flow inside the sample. This is a direct consequence of the heterogeneous pore network resulting in varying hydraulic properties of the hydrate-bearing sediment.

Seol, Yongkoo; Myshakin, Evgeniy

2011-01-01T23:59:59.000Z

484

Mixed Ionic/Electronic Conducting Ceramic Membranes for Oxygen-Assisted CO2 Reforming  

E-Print Network [OSTI]

Incorporating a SrFeCo0.5Ox (SFC) membrane into a CO2 reforming reactor doubles methane conversion with a powder Pt/ZrO2 catalyst. The deactivation of both Pt/ZrO2 and a Pt/CeZrO2 catalyst is also retarded substantially. Catalyst performance...

Slade, David

2010-03-29T23:59:59.000Z

485

A New Look at Patent Reform: Comparison to other suggested approaches  

E-Print Network [OSTI]

A New Look at Patent Reform: Comparison to other suggested approaches Lee A. Hollaar Professor (The latest version of the paper can be found at http://digital-law-online.info/papers/lah/mini-patent while not substantially helping patents. "Gold-plated patents" In their paper "What to Do about Bad

Hollaar, Lee A.

486

High Efficiency Solar-based Catalytic Structure for CO{sub 2} Reforming  

SciTech Connect (OSTI)

Throughout this project, we developed and optimized various photocatalyst structures for CO{sub 2} reforming into hydrocarbon fuels and various commodity chemical products. We also built several closed-loop and continuous fixed-bed photocatalytic reactor system prototypes for a larger-scale demonstration of CO{sub 2} reforming into hydrocarbons, mainly methane and formic acid. The results achieved have indicated that with each type of reactor and structure, high reforming yields can be obtained by refining the structural and operational conditions of the reactor, as well as by using various sacrificial agents (hole scavengers). We have also demonstrated, for the first time, that an aqueous solution containing acid whey (a common bio waste) is a highly effective hole scavenger for a solar-based photocatalytic reactor system and can help reform CO{sub 2} into several products at once. The optimization tasks performed throughout the project have resulted in efficiency increase in our conventional reactors from an initial 0.02% to about 0.25%, which is 10X higher than our original project goal. When acid whey was used as a sacrificial agent, the achieved energy efficiency for formic acid alone was ~0.4%, which is 16X that of our original project goal and higher than anything ever reported for a solar-based photocatalytic reactor. Therefore, by carefully selecting sacrificial agents, it should be possible to reach energy efficiency in the range of the photosynthetic efficiency of typical crop and biofuel plants (1-3%).

Menkara, Hisham

2013-09-30T23:59:59.000Z

487

The Effect of Reformate on PEM Fuel Cell Performance Mahesh Murthy  

E-Print Network [OSTI]

Exchanged Membrane (PEM) fuel cells in a "hydrogen-challenged" economy, hydrogen can be produced contains about 35 - 40 % hydrogen [1]. The effects of reformate fuel on the performance of PEM fuel cells in hydrogen for a laboratory polymer electrolyte membrane fuel cell [3, 4]. In these earlier studies

Van Zee, John W.

488

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network [OSTI]

,2 operated by fuel cells. Unfortunately, the lack of infrastructure, such as a network of hydrogen refueling of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiencyPerformance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel

Azad, Abdul-Majeed

489

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation  

E-Print Network [OSTI]

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

Fayer, Michael D.

490

Unintended Consequences of Regulatory Takings Reform on the SDCP and Arizona Water Management  

E-Print Network [OSTI]

a property owners to just compensation if the value of a person's property is reduced by the enactmentUnintended Consequences of Regulatory Takings Reform on the SDCP and Arizona Water Management Fellowship Program #12;Introduction: Regulatory laws are often passed with the best intentions

Fay, Noah

491

Structural Reforms and Agricultural Export Performance D. Susanto, C. P. Rosson, and R. Costa  

E-Print Network [OSTI]

;INTRODUCTION Structural reforms: policy measures that reduce or remove impediments to the efficient allocation and accelerated in 1990. Trade liberalization policies have been widely adopted in most (developing) countries government intervention. Countries like India, Indonesia, Brazil, Argentina, among others have reduced

492

Operation of a solid oxide fuel cell on biodiesel with a partial oxidation reformer  

SciTech Connect (OSTI)

The National Energy Technology Laboratory’s Office of Research & Development (NETL/ORD) has successfully demonstrated the operation of a solid oxide fuel cell (SOFC) using reformed biodiesel. The biodiesel for the project was produced and characterized by West Virginia State University (WVSU). This project had two main aspects: 1) demonstrate a catalyst formulation on monolith for biodiesel fuel reforming; and 2) establish SOFC stack test stand capabilities. Both aspects have been completed successfully. For the first aspect, in–house patented catalyst specifications were developed, fabricated and tested. Parametric reforming studies of biofuels provided data on fuel composition, catalyst degradation, syngas composition, and operating parameters required for successful reforming and integration with the SOFC test stand. For the second aspect, a stack test fixture (STF) for standardized testing, developed by Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) for the Solid Energy Conversion Alliance (SECA) Program, was engineered and constructed at NETL. To facilitate the demonstration of the STF, NETL employed H.C. Starck Ceramics GmbH & Co. (Germany) anode supported solid oxide cells. In addition, anode supported cells, SS441 end plates, and cell frames were transferred from PNNL to NETL. The stack assembly and conditioning procedures, including stack welding and sealing, contact paste application, binder burn-out, seal-setting, hot standby, and other stack assembly and conditioning methods were transferred to NETL. In the future, fuel cell stacks provided by SECA or other developers could be tested at the STF to validate SOFC performance on various fuels. The STF operated on hydrogen for over 1000 hrs before switching over to reformed biodiesel for 100 hrs of operation. Combining these first two aspects led to demonstrating the biodiesel syngas in the STF. A reformer was built and used to convert 0.5 ml/min of biodiesel into mostly hydrogen and carbon monoxide (syngas.) The syngas was fed to the STF and fuel cell stack. The results presented in this experimental report document one of the first times a SOFC has been operated on syngas from reformed biodiesel.

Siefert, N, Shekhawat, D.; Gemmen, R.; Berry, D.

2010-01-01T23:59:59.000Z

493

A density functional theory study of magneto-electric Jones birefringence of noble gases, furan homologues, and mono-substituted benzenes  

SciTech Connect (OSTI)

We report on the results of a systematic ab initio study of the Jones birefringence of noble gases, of furan homologues, and of monosubstituted benzenes, in the gas phase, with the aim of analyzing the behavior and the trends within a list of systems of varying size and complexity, and of identifying candidates for a combined experimental/theoretical study of the effect. We resort here to analytic linear and nonlinear response functions in the framework of time-dependent density functional theory. A correlation is made between the observable (the Jones constant) and the atomic radius for noble gases, or the permanent electric dipole and a structure/chemical reactivity descriptor as the para Hammett constant for substituted benzenes.

Fahleson, Tobias; Norman, Patrick, E-mail: panor@ifm.liu.se [Department of Physics, Chemistry and Biology, Linköping University, SE-581 83 Linköping (Sweden); Coriani, Sonia, E-mail: coriani@units.it [Dipartimento di Scienze Chimiche e Farmaceutiche, Università degli Studi di Trieste, I-34127 Trieste (Italy); Rizzo, Antonio, E-mail: rizzo@ipcf.cnr.it [CNR - Consiglio Nazionale delle Ricerche, Istituto per i Processi Chimico Fisici (IPCF-CNR), UOS di Pisa, I-56124 Pisa (Italy); Rikken, Geert L. J. A., E-mail: geert.rikken@lncmi.cnrs.fr [Laboratoire National des Champs Magnétiques Intenses, UPR3228, CNRS/INSA/UJF/UPS, Toulouse and Grenoble (France)

2013-11-21T23:59:59.000Z

494

Interaction and dynamics of (alkylamide + electrolyte) deep eutectics: Dependence on alkyl chain-length, temperature, and anion identity  

SciTech Connect (OSTI)

Here we investigate the solute-medium interaction and solute-centered dynamics in (RCONH{sub 2} + LiX) deep eutectics (DEs) via carrying out time-resolved fluorescence measurements and all-atom molecular dynamics simulations at various temperatures. Alkylamides (RCONH{sub 2}) considered are acetamide (CH{sub 3}CONH{sub 2}), propionamide (CH{sub 3}CH{sub 2}CONH{sub 2}), and butyramide (CH{sub 3}CH{sub 2}CH{sub 2}CONH{sub 2}); the electrolytes (LiX) are lithium perchlorate (LiClO{sub 4}), lithium bromide (LiBr), and lithium nitrate (LiNO{sub 3}). Differential scanning calorimetric measurements reveal glass transition temperatures (T{sub g}) of these DEs are ?195 K and show a very weak dependence on alkyl chain-length and electrolyte identity. Time-resolved and steady state fluorescence measurements with these DEs have been carried out at six-to-nine different temperatures that are ?100–150 K above their individual T{sub g}s. Four different solute probes providing a good spread of fluorescence lifetimes have been employed in steady state measurements, revealing strong excitation wavelength dependence of probe fluorescence emission peak frequencies. Extent of this dependence, which shows sensitivity to anion identity, has been found to increase with increase of amide chain-length and decrease of probe lifetime. Time-resolved measurements reveal strong fractional power dependence of average rates for solute solvation and rotation with fraction power being relatively smaller (stronger viscosity decoupling) for DEs containing longer amide and larger (weaker decoupling) for DEs containing perchlorate anion. Representative all-atom molecular dynamics simulations of (CH{sub 3}CONH{sub 2} + LiX) DEs at different temperatures reveal strongly stretched exponential relaxation of wavevector dependent acetamide self dynamic structure factor with time constants dependent both on ion identity and temperature, providing justification for explaining the fluorescence results in terms of temporal heterogeneity and amide clustering in these multi-component melts.

Guchhait, Biswajit; Das, Suman; Daschakraborty, Snehasis; Biswas, Ranjit, E-mail: ranjit@bose.res.in [Department of Chemical, Biological and Macromolecular Sciences, S. N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India)] [Department of Chemical, Biological and Macromolecular Sciences, S. N. Bose National Centre for Basic Sciences, Block-JD, Sector-III, Salt Lake, Kolkata 700098 (India)

2014-03-14T23:59:59.000Z

495

Investigation of Reaction Networks and Active Sites In Bio-Ethanol Steam Reforming Over Co-Based Catalysts  

Broader source: Energy.gov [DOE]

Paper by Umit S. Ozkan, Hua Song, and Lingzhi Zhang (Ohio State University) on the fundamental understanding of reaction networks, active sites of deactivation mechanisms of potential bio-ethanol steam reforming catalysts.

496

Any health care reform must allow continuation of robust Medicaid Buy-In programs for working people with disabilities  

E-Print Network [OSTI]

National health care reform must meet the unique health care needs of people with disabilities. However, obtaining health care coverage for a person with disabilities can be challenging in an employer-based health insurance environment. The final...

Otto, B.; Salley, S.; Hall, Jean P.; Himmelstein, J.

2009-10-20T23:59:59.000Z

497

Running an enlarged euro-zone – reforming the European Central Bank: Efficiency, legitimacy and national economic interest   

E-Print Network [OSTI]

This article analyses the December 2002 reform of decision making in the European Central Bank’s (ECB) Governing Council in terms of national economy size reflected in the bargaining power of the ECB Governing Council ...

Howarth, D.

498

Policy Experimentation and the Search for Institutional Change: The Politics of Red-Green Reform in Germany  

E-Print Network [OSTI]

the first four years of Germany first Red-Green coalition.OF RED-GREEN REFORM IN GERMANY June 2006 J. Nicholas Zieglercoalition government in Germany between Social Democrats and

Ziegler, J. Nicholas; Leslie, John C.

2006-01-01T23:59:59.000Z

499

Proceedings of the IEEE, vol. 97, no. 4, pp. 708-19, April 2009. Sharing Spectrum through Spectrum Policy Reform  

E-Print Network [OSTI]

Spectrum Policy Reform and Cognitive Radio1 Jon M. Peha Carnegie Mellon University Abstract Traditionally inefficient use of spectrum. Cognitive radio along with software radio, spectrum sensors, mesh networks sharing, spectrum policy, cognitive radio, band manager, unlicensed, etiquette, opportunistic access

Peha, Jon M.

500

A review of "Reformed Theology and Visual Culture: the Protestant Imagination from Calvin to Edwards." by William A. Dyrness  

E-Print Network [OSTI]

REVIEWS 1 William A. Dyrness. Reformed Theology and Visual Culture: the Protestant Imagination from Calvin to Edwards. Cambridge: Cambridge University Press, 2004. xv + 339 pp. + 43 illus. $85.00. Review by GRAHAM PARRY, UNIVERSITY OF YORK... remarks Dyrness confesses to a certain sense of deprivation in his settings of worship, and even suggests that Reformed Protestants generally have a diminished response to the visual arts and to the beauty of the world around them. Taking as a starting...

Graham Parry

2005-01-01T23:59:59.000Z