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Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Method of making alkyl esters  

DOE Patents [OSTI]

Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

Elliott, Brian (Wheat Ridge, CO)

2010-09-14T23:59:59.000Z

2

Experimental Investigations of an IC Engine Operating with Alkyl Esters of Jatropha, Karanja and Castor Seed Oil  

Science Journals Connector (OSTI)

Abstract Diesel engines are efficient systems popularly used to meet electricity and other power requirements for agriculture, industry, transportation and decentralized power generation. Vegetable oils can be successfully used in Compression Ignition (CI) engine either through engine modifications or fuel modifications, later being more feasible option. Fuel modification options include blending of vegetable oils with mineral diesel, transesterification, cracking/pyrolysis, micro-emulsion, and hydrogenation to reduce polymerization and viscosity, transesterification of vegetable oil with a short chain alcohol i.e. methanol or ethanol being most popular. Several non-edible plant oils have been found to be promising crude oils for the production of biodiesel. Methanol is most commonly used in commercial production of biodiesel. Fatty acid alkyl esters (FAAE) produced from higher alcohols is of interest as they may have different fuel properties in comparison to methyl or ethyl esters. In the present investigations, preparation of methanol, ethanol, propanol and butanol were used for formation of alkyl esters of Jatropha, Karanja and Castor. The composition of Jatropha, Karanja and Castor oil were analysed and alcoholysis process for preparing alkyl esters of Jatropha, Karanja and Castor oil with various alcohols was optimised. Alkyl ester-diesel blends were used to test the diesel engine at different load conditions and extensive performance and emissions studies were conducted in single cylinder direct injection compression ignition engines. It is concluded that lower blends of ethyl, propyl and butyl esters of Jatropha and Karanja feedstock have physico-chemical properties similar to methyl esters. However, deviation from the properties became larger for higher blending ratio. Therefore, in order to get engine performance in close range of diesel, the optimum blending ratio of higher alkyl esters need to be even less than methyl esters. Lower blends of higher alkyl esters are expected to give engine characteristics in close proximity to diesel overcoming the limitations of bio-diesel, while retaining the advantages.

Sanjay Bajpai; Lalit Mohan Das

2014-01-01T23:59:59.000Z

3

A Detailed Chemical Kinetic Reaction Mechanism for Oxidation of Four Small Alkyl Esters in Laminar Premixed Flames  

SciTech Connect (OSTI)

A detailed chemical kinetic reaction mechanism has been developed for a group of four small alkyl ester fuels, consisting of methyl formate, methyl acetate, ethyl formate and ethyl acetate. This mechanism is validated by comparisons between computed results and recently measured intermediate species mole fractions in fuel-rich, low pressure, premixed laminar flames. The model development employs a principle of similarity of functional groups in constraining the H atom abstraction and unimolecular decomposition reactions in each of these fuels. As a result, the reaction mechanism and formalism for mechanism development are suitable for extension to larger oxygenated hydrocarbon fuels, together with an improved kinetic understanding of the structure and chemical kinetics of alkyl ester fuels that can be extended to biodiesel fuels. Variations in concentrations of intermediate species levels in these flames are traced to differences in the molecular structure of the fuel molecules.

Westbrook, C K; Pitz, W J; Westmoreland, P R; Dryer, F L; Chaos, M; Osswald, P; Kohse-Hoinghaus, K; Cool, T A; Wang, J; Yang, B; Hansen, N; Kasper, T

2008-02-08T23:59:59.000Z

4

Stereoselective SN2? alkylation reaction sequence of the ?,?-epoxy ?,?-unsaturated ester system via ?,?-chlorohydrin intermediates by the use of a R3Al–CuCN reagent  

Science Journals Connector (OSTI)

A novel stereoselective SN2? alkylation reaction sequence of the ?,?-epoxy ?,?-unsaturated ester system has been developed which involves a regioselective substitution reaction with chloride ions at the ?-position and a subsequent SN2? alkylation reaction of the resulting ?-chloro-?-hydroxy derivatives with a R3Al–CuCN reagent. The new methodology was demonstrated to be applicable to a variety of substrates and to provide various ?-hydroxy-?-alkyl-?,?-unsaturated esters including those bearing a quaternary asymmetric carbon atom at the ?-position in a highly stereoselective manner and high yields.

Fumihiko Yoshimura; Atsushi Matsui; Atsushi Hirai; Keiji Tanino; Masaaki Miyashita

2009-01-01T23:59:59.000Z

5

Heats of Combustion of Fatty Acids and Fatty Acid Esters  

Science Journals Connector (OSTI)

...The military uses JP-8, a kerosene type hydrocarbon, to fuel most of its vehicles and ... , no traditional biodiesel meets the requirements for heat of combustion, freezing point, viscosity and oxidative stabi...

Felicia Levine; Ronald V. Kayea III…

2014-02-01T23:59:59.000Z

6

Alkylate  

U.S. Energy Information Administration (EIA) Indexed Site

Day) Day) Product: Alkylate Aromatics Asphalt & Road Oil Isomers Isobutane Isopentane & Isohexane Isooctane Lubricants Marketable Petroleum Coke Hydrogen Sulfur Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2008 2009 2010 2011 2012 2013 View History U.S. 1,260,985 1,260,923 1,248,514 1,262,443 1,246,875 1,269,361 1982-2013 PAD District 1 110,229 110,229 95,500 108,629 79,429 91,429 1982-2013 Delaware 11,729 11,729 0 11,729 11,729 11,729 1982-2013 Florida 0 0 0 0 0 0 2007-2013 Georgia 0 0 0 0 0 0 2006-2013 Maryland 0 0 0 0 0 0 2007-2013 New Jersey 40,200 40,200 36,200 37,200 37,200 37,200 1982-2013

7

Combustion, performance and emission analysis of diesel engine fuelled with methyl esters of Pongamia oil  

Science Journals Connector (OSTI)

The methyl esters of vegetable oils, known as biodiesel are increasingly becoming popular because of their low environmental impact and potential as a green alternative fuel for diesel engine, and that they would not require significant modification of existing engine hardware. Methyl ester of Pongamia oil (PME) is derived through transesterification process. Experimental investigations have been carried out to examine properties, performance and emissions of different blends (B00, B20, B40, B60, B80 and B100) of PME comparison to diesel. A computer assisted single cylinder constant speed water cooled four stroke direct diesel engine (5 HP), which is commonly used in the agricultural sector for driving the pumps and small electrical generators is selected for the experimental investigation. The performance, emissions and combustion characteristics are analysed. The combustion parameters considered for this analysis are cylinder pressure and rate of heat release. The brake thermal efficiency is slightly reduced and hydrocarbon, carbon monoxide and smoke emissions in the exhaust are reduced when fuelled with methyl esters compared to diesel. But the NOx emissions are high when fuelled with methyl esters compared to diesel. [Received: December 11, 2009; Accepted: March 21, 2010

T. Hari Prasad; K. Hema Chandra Reddy; M. Muralidhara Rao

2010-01-01T23:59:59.000Z

8

The influence of molecular structure of fatty acid monoalkyl esters on diesel combustion  

SciTech Connect (OSTI)

The subject of this paper is a series of experiments conducted on a single-cylinder research engine investigating the influence of molecular structure on the combustion behaviour of fatty acid alcohol ester (biodiesel) molecules under diesel engine conditions. The fuels employed in these experiments comprised various samples of pure individual fatty acid alcohol ester molecules of different structure, as well as several mixtures of such molecules. The latter consisted in biodiesel fuels produced by the transesterification of naturally occurring plant oils or animal fat with a monohydric alcohol. It was observed that the molecular structure of the fuel significantly influenced the formation of NO{sub x} and particulate matter and their respective concentration in the exhaust gas. The influence on the formation of NO{sub x} in particular, appeared to be exerted first through the effect which the molecular structure had on the auto-ignition delay occurring after the fuel was injected into the combustion chamber, and second through the flame temperature at which the various molecules burned. The emission of particulates on the other hand showed correlation with the number of double bonds in the fuel molecules for the case of larger accumulation mode particles, and with the boiling point of the fuel samples for the case of the smaller, nucleation mode particles. The effect of ignition delay on the exhaust emissions of these pollutants was isolated by adding the ignition promoting molecule 2-ethylhexyl nitrate to some of the fuel samples in closely specified concentrations, so as to equalise the ignition delay for the relevant fuel samples. The removal of the ignition delay as a main influence on the combustion process enabled the observation of the lesser effects of adiabatic flame temperature. (author)

Schoenborn, Alessandro; Ladommatos, Nicos [Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE (United Kingdom); Williams, John; Allan, Robert; Rogerson, John [BP Oil UK Limited, Technology Centre, Whitchurch Hill, Pangbourne, Reading, RG8 7QR (United Kingdom)

2009-07-15T23:59:59.000Z

9

Combustion analysis of a direct injection diesel engine when fuelled with sunflower methyl ester and its diesel blends  

Science Journals Connector (OSTI)

Uncertainty in the availability of petroleum-based fuels in the near future and stringent pollution norms have triggered a search for renewable and clean-burning fuels. The use of vegetable oil as an alternative fuel has for long been in the pipeline, but its direct use has been limited because of its higher viscosity. In this work, sunflower oil was taken as feedstock and the feasibility of sunflower oil methyl ester (SFME) as an alternative fuel for diesel engines was investigated. Tests were conducted in a 4.4 kW, single cylinder, naturally aspirated direct injection diesel engine. It was observed that the premixed combustion phase of SFME and its blends were less intense compared with diesel oil. In addition, it was observed that SFME and its blends had slightly lower thermal efficiency and lower tailpipe emissions than diesel oil.

G. Lakshmi Narayana Rao; S. Saravanan; P. Selva Ilavarasi; G. Devasagayam

2009-01-01T23:59:59.000Z

10

The comparative analysis of diesel engine combustion and emission parameters fuelled with palm oil methyl esters and its diesel blends  

Science Journals Connector (OSTI)

In this work, the combustion and emission characteristics of a direct injection compression ignition engine fuelled with diesel-Palm Oil Methyl Ester (POME) blends are investigated. This study shows that the ignition delay decreases with increase in the POME addition. The maximum rate of pressure rise and maximum rate of heat release decreases with increase in POME addition at all loads. As the percentage of POME in the blend increases, the crank angle at which the maximum rate of heat release takes place advances. The brake thermal efficiency decreases with increase in POME addition. The unburned hydrocarbon, carbon monoxide and soot intensity decreases, while nitrogen oxides (NOx) increase with increase in POME addition. [Received: April 4, 2008; Accepted: November 24, 2008

G. Lakshmi Narayana Rao; S. Saravanan; P. Selva Ilavarasi

2009-01-01T23:59:59.000Z

11

Investigation on combustion characteristics of crude rice bran oil methyl ester blend as a heavy duty automotive engine fuel  

Science Journals Connector (OSTI)

In the present work, an attempt was made to test the suitability of crude rice bran oil methyl ester (CRBME) blend as a heavy duty automotive engine fuel. A four stroke, six cylinder direct injection 117.6 kW turbo-charged compression ignition (CI) engine was used for the work. The operation of the engine with CRBME blend showed that the peak pressure increased with lower maximum rate of pressure rise and maximum heat release rate with shorter delay period. Burning rate of the CRBME blend was slower and required a higher crank angle to complete the combustion cycle when compared to diesel. The brake thermal efficiency of the CRBME blend was lower than that of diesel at all speeds except at 2300rpm. As the measured combustion and performance parameters for CRBME blend differs only by a smaller magnitude when compared with diesel, this investigation ensures the suitability of the CRBME blend as fuel for heavy duty automotive engine without any design modifications [Received: August 12, 2010; Accepted: August 29, 2010

S. Saravanan; G. Nagarajan; S. Sampath

2011-01-01T23:59:59.000Z

12

Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a Motored Engine  

Broader source: Energy.gov [DOE]

The alkyl chain of fatty acid esters experience the typical paraffin-like low temperature oxidation sequence; the alkyl chain length of fatty acid esters has a crucial impact on the ignition behavior of fatty acid esters

13

Engine performance and emissions from the combustion of low-temperature Fischerâ??Tropsch synthetic diesel fuel and biodiesel rapeseed methyl ester blends  

Science Journals Connector (OSTI)

The combustion of oxygenated biodiesel (rapeseed methyl ester (RME)) improves the engine-out particulate matter, hydrocarbon and carbon monoxide (CO) emissions, while the low-temperature Fischerâ??Tropsch synthetic paraffinic diesel fuel improves engine-out NOx, CO, hydrocarbon and particulate matter emissions. Blending synthetic diesel (SD) fuel with oxygenated biodiesel could unlock potential performance synergies in the fuel properties (e.g. O2 content in RME and high cetane number of the synthetic fuels) of such blends and benefit engine performance and emissions. The combustion of synthetic diesel fuel/RME blend, named synthetic diesel B50, has shown similar combustion characteristics to diesel fuel, while simultaneous improvements in engine efficiency and smoke-NOx trade-off were achieved by taking advantage of the fuel's properties. The engine thermal efficiency was dependent on the fuel type, and followed the general trend: synthetic diesel > SDB50 > diesel > RME. Therefore, it has been shown that the design of a synthetic fuel with properties similar to the fuel blends presented in this work could improve engine-out NOx, smoke and hydrocarbon emissions and maintain or improve engine performance.

Kampanart Theinnoi; Athanasios Tsolakis; Sathaporn Chuepeng; Andrew P.E. York; Roger F. Cracknell; Richard H. Clark

2009-01-01T23:59:59.000Z

14

Highly Enantioselective sec-Alkyl Sulfatase Activity of Sulfolobus acidocaldarius DSM 639  

Science Journals Connector (OSTI)

Highly Enantioselective sec-Alkyl Sulfatase Activity of Sulfolobus acidocaldarius DSM 639 ... rac-sec-Alkyl sulfate esters 1a?4a were resolved in high enantioselectivities with E-values up to >200 using whole cells of aerobically grown Sulfolobus acidocaldarius DSM 639. ... On the basis of vague hints on the stereospecific and enantioselective hydrolysis of alkyl sulfate esters,3 we recently reported an alkyl sulfatase (termed “RS2”) from Rhodococcus ruber DSM 44541. ...

Sabine R. Wallner; Bettina M. Nestl; Kurt Faber

2004-12-02T23:59:59.000Z

15

Degradable Terpolymers with Alkyl Side Chains Demonstrate Enhanced Gene Delivery Potency and Nanoparticle Stability  

E-Print Network [OSTI]

Degradable, cationic poly(?-amino ester)s (PBAEs) with alkyl side chains are developed for non-viral gene delivery. Nanoparticles formed from these PBAE terpolymers exhibit significantly enhanced DNA transfection potency ...

Eltoukhy, Ahmed A.

16

Combustion and emission characteristics of diesel engine fuelled with methyl esters of pungam oil and rice bran oil  

Science Journals Connector (OSTI)

Biodiesel derived from vegetable oils and animal fats can be used in diesel engines with little or no modifications. In this work, the combustion, performance and emission characteristics of various biodiesel (rice bran oil and pungam oil) and their blends are evaluated in a direct injection diesel engine. Lower ignition delay, higher peak pressure and heat release rate with almost same brake thermal efficiency are obtained for 20% biodiesel blend as compared with diesel fuel. They exhibited lower unburned hydrocarbon, carbon monoxide and soot emissions with a penalty of higher NOx emissions.

G. Lakshmi Narayana Rao; N. Nallusamy; S. Sampath; K. Rajagopal

2008-01-01T23:59:59.000Z

17

A Practical and Highly Stereoselective Umpolung Alternative to the Alkylation of Chiral Enolates  

E-Print Network [OSTI]

-chiral center of high optical purity based on the SN2 displace- ment reaction of alkyl cuprates on chiral allyl, the reaction sometimes leads to self-condensa- tion byproducts. The Lewis acid induced alkylation of silyl enol ethers allows reaction with SN1-prone electrophiles but is of limited use with ester or amide derived O

Spino, Claude

18

Experimental investigations of the performance, emission and combustion characteristics of a biodiesel (ethyl ester of fish oil) fuelled direct-injection diesel engine  

Science Journals Connector (OSTI)

The thirst for fuel is steadily increasing as technology continues to open new areas of exploration. At the same time, the indiscriminate extraction of fossil fuels may also result in pollutant emissions which cause major impacts on ecological systems. In order to overcome the above problems, a suitable biodiesel should be used to replace the diesel fuel. Hence, in this work, feasibility of using biodiesel prepared from fish oil was investigated. Experimental tests were carried out to evaluate the performance, emission and combustion characteristics of a single cylinder, constant speed engine using several blends under variable load conditions. It was found that NOx, HC and CO emission was reduced for blends along with a marginal increase of brake thermal efficiency and smoke. The ignition delay and maximum heat release rate were reduced compared to diesel. Ultimately, fish oil can indeed become the appropriate source for biodiesel with environmental benefits.

G. Sakthivel; G. Nagarajan; M. Ilangkumaran

2013-01-01T23:59:59.000Z

19

Alkylating Properties of Phosphoramide Mustard  

Science Journals Connector (OSTI)

...undergoes alkylation reactions as an intact molecule...rather than a direct SN2 displacement of the chlorine...undergoes alkylation reactions as an intact molecule...ylamine formed in the reaction of phosphoramide mustard...alkylation by direct (SN2) displacement of the...

Michael Colvin; Robert B. Brundrett; Man-Na N. Kan; Ian Jardine; and Catherine Fenselau

1976-03-01T23:59:59.000Z

20

Mild Catalytic methods for Alkyl-Alkyl Bond Formation  

SciTech Connect (OSTI)

Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

David A Vicic

2009-08-10T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Properties and Performance of Levulinate Esters as Diesel Blend Components  

Science Journals Connector (OSTI)

The esters were treated with the cetane-enhancing compound 2-ethyl hexyl nitrate and were tested as blends with diesel fuel in a 2008 model year Cummins ISB engine with the measurement of regulated pollutant emissions over the federal heavy duty diesel transient cycle. ... The various approaches to biomass conversion can be divided into two general types: thermochemical (gasification, pyrolysis, acid hydrolysis, combustion, and liquefaction) and biochemical (fermentation, enzymatic hydrolysis, and anaerobic and aerobic digestion). ...

Earl Christensen; Aaron Williams; Stephen Paul; Steve Burton; Robert L. McCormick

2011-10-05T23:59:59.000Z

22

Advanced Combustion  

SciTech Connect (OSTI)

Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.

Holcomb, Gordon R. [NETL

2013-03-05T23:59:59.000Z

23

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

biodiesel or renewable diesel, renewable gasoline, renewable naphtha, biocrude, biogas, and other renewable, biodegradable, mono alkyl ester combustible fuel derived from...

24

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

and other renewable, biodegradable mono alkyl ester combustible fuel derived from biomass. Waivers to the B2 requirement for state agency vehicles may be granted if the fuel...

25

The Mechanism of Action of Alkylating Agents  

Science Journals Connector (OSTI)

...the Sn2 and Sn1 reactors with their known...alkylating agents on nuclear material and cell...the Sn@ and Sni reactors with their known...alkylating agents on nuclear material and cell...then there was de generation, whereas with x-rays...oegiants, although nuclear granulation similar...

G. P. Warwick

1963-09-01T23:59:59.000Z

26

Combustion Noise  

E-Print Network [OSTI]

stabilize or destabilize the modes of the system, depending on the configuration of the combustor and the form of the coupling [26, 30]. In contrast to combustion instability, in broad-band combustion noise the unsteadiness in the rate of combustion... from th s in a mod on tempera , entropic a de of indir t frequenci r, open que sical theory assical expe s [14] who it by a spa d a transie le gases. A e bubble si idered as a flame was ent was o ng and dif depended udy it wa ion, ? ?,p r t? : (a...

Dowling, Ann P.; Mahmoudi, Yasser

2014-01-01T23:59:59.000Z

27

Combustion Engine  

Broader source: Energy.gov [DOE]

Pictured here is an animation showing the basic mechanics of how an internal combustion engine works. With support from the Energy Department, General Motors researchers developed a new technology ...

28

Modeling study of the lowtemperature oxidation of large methyl esters from C11 to C19  

E-Print Network [OSTI]

in biodiesel fuels has been investigated. Models have been developed for these species and then detailed; Biodiesel fuels; Modeling; Oxidation * Corresponding author: Olivier Herbinet Laboratory of Reaction the differences with the combustion of alkanes induced by the ester function. While biodiesel fuels deriving from

Boyer, Edmond

29

Pulse combustion  

Science Journals Connector (OSTI)

Pulse combustion has been gaining increased interest because of its potential for higher combustion efficiency greater combustion intensity and lower pollutant emissions. Unsteady combustion causes increased mass momentum and heat transfer. As a result reactants mix faster heat release is accelerated and heat transfer is enhanced in unsteady reacting flows. Many of these phenomena were discovered long ago by engineers looking for the cause of often detrimental combustion instabilities. Much more recently some of these enhanced transfer properties have been used to design efficient and compact pulse combustors. Although to date successful commercialization on a large scale has been limited to home heating units (e.g. the Lenox Pulse Furnace) highly efficient pulse spray dryers (Bepex Unison Dryer) pulse calciners and pulse waste incinerators have been designed. Pulsations have also been applied to carbon black fluidized bed gasifiers. Not all these designs will become economically viable. However the development of tunable pulse combustors that can be acoustically matched to the changing resonance frequency of these pulse processes have made many of them more promising. Recent findings that pulsation can enhance burning even in turbulent flows lend further encouragement to the developers of novel pulse combustion devices.

Jechiel I. Jagoda

2000-01-01T23:59:59.000Z

30

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

31

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

32

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

33

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

34

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

35

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

36

Alkylation of organic aromatic compounds  

DOE Patents [OSTI]

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

37

COMBUSTION RESEARCH - FY-1979  

E-Print Network [OSTI]

deposition due to the heat of combustion. The problem wedimensionless heat of combustion, QpYoxoolhw t transferredfraction of specie i heat of combustion per gram of fuel

,

2012-01-01T23:59:59.000Z

38

Chemical Kinetic Models for HCCI and Diesel Combustion  

SciTech Connect (OSTI)

Hydrocarbon fuels for advanced combustion engines consist of complex mixtures of hundreds or even thousands of different components. These components can be grouped into a number of chemically distinct classes, consisting of n-paraffins, branched paraffins, cyclic paraffins, olefins, oxygenates, and aromatics. Biodiesel contains its own unique chemical class called methyl esters. The fractional amounts of these chemical classes are quite different in gasoline, diesel fuel, oil-sand derived fuels and bio-derived fuels, which contributes to the very different combustion characteristics of each of these types of combustion systems. The objectives of this project are: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

Pitz, W J; Westbook, C K; Mehl, M

2008-10-30T23:59:59.000Z

39

Present and Future Alkylation Processes in Refineries  

Science Journals Connector (OSTI)

Present and Future Alkylation Processes in Refineries ... Second, an accident at a Texas refinery released considerable amounts of gaseous HF. ... In addition, following an accident, it is uncertain whether the sprays would still be operable. ...

Lyle F. Albright

2009-01-08T23:59:59.000Z

40

Advanced Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Systems Systems Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to generate electricity, which operate at efficiencies of 35-37 percent. Operation at higher temperatures and pressures can lead to higher efficiencies, resulting in reduced fuel consumption and lower greenhouse gas emissions. Higher efficiency also reduces CO2 production for the same amount of energy produced, thereby facilitating a reduction in greenhouse gas emissions. When combined, oxy-combustion comes with an efficiency hit, so it will actually increase the amount of CO2 to be captured. But without so much N2 in the flue gas, it will be easier and perhaps more efficient to capture, utilize and sequester. NETL's Advanced Combustion Project and members of the NETL-Regional University

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Turbulent combustion  

SciTech Connect (OSTI)

Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

Talbot, L.; Cheng, R.K. [Lawrence Berkeley Laboratory, CA (United States)

1993-12-01T23:59:59.000Z

42

Combustion & Health  

E-Print Network [OSTI]

FFCOMBUSTION & HEALTH Winifred J. Hamilton, PhD, SM Clear Air Through Energy Efficiency (CATEE) Galveston, TX October 9?11, 2012 FFCOMBUSTION & HEALTH FFCOMBUSTION: THE THREAT ? Biggest threat to world ecosystems (and to human health...) ? Combustion of fossil fuels for ? Electricity ? Industrial processes ? Vehicle propulsion ? Cooking and heat ? Other ? Munitions ? Fireworks ? Light ? Cigarettes, hookahs? FFCOMBUSTION & HEALTH FFCOMBUSTION: THE THREAT ? SCALE (think health...

Hamilton, W.

2012-01-01T23:59:59.000Z

43

Low-temperature emission spectra of 9-alkylanthracene esters: Dimer photodecomposition and monomer pair interactions in polymer hosts  

SciTech Connect (OSTI)

Effects due to variation in the alkyl chain length of photodimers of 9-alkylanthracene esters on their photodecomposition efficiencies at 12 K and, by implication, the photoproduct migration as a function of temperature within polymer hosts are investigated. It is shown that dimers with longer alkyl chains have a lower photodecomposition efficiency. The extent of photoproduct migration within the polymer following photodecomposition was also studied as a function of alkyl chain length. This migration and its modulation of the interaction between the separating monomers is shown to affect the emission spectrum. Thus, monomer migration was studied in temperature cycling experiments. It was also found, for the polymer hosts investigated - poly(methyl methacrylate), poly(vinyl chloride), and polystyrene - that these properties are host dependent. This result is probably due to the void space differences that exist among these polymers. 17 refs., 10 figs.

Salt, K.; Scott, G.W. (Univ. of California, Riverside, CA (United States))

1994-10-06T23:59:59.000Z

44

Stretch Efficiency for Combustion Engines: Exploiting New Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes 2012 DOE Hydrogen and Fuel...

45

Light Duty Combustion Research: Advanced Light-Duty Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and...

46

Combustion Control  

E-Print Network [OSTI]

using a liquid fuel. The air and fuel valve designs are vastly different, with different flow characteristics. These factors make the initial adjustment of the system difficult, and proper maintenance of ratio accuracy unlikely. Linked valves... casing of the fuel control regulator with the combustion air piping. The upstream pressure on the burner air orifice is applied to the main diaphragm of the pressure balanced regulator. Assuming sufficient gas pressure at the regulator inlet...

Riccardi, R. C.

1984-01-01T23:59:59.000Z

47

E-Print Network 3.0 - acid alkyl esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitric Acid 34. Sulfuric acid... .5 will not be accepted through this program. Heavy metal, toxic, acidic (without solvents) and basic wastes should... . Mercaptans 4. ......

48

Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol  

DOE Patents [OSTI]

The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

Lin, YuPo J; St. Martin, Edward J

2013-08-13T23:59:59.000Z

49

E-Print Network 3.0 - alkyl esters perspectives Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Centre de mathmatiques Collection: Mathematics 45 Chem 350 Jasperse Ch. 6 Summary of Reaction Types, Ch. 4-6, Test 2 1. Radical Halogenation (Ch. 4) Summary: . Recognition: A....

50

Highly Effective Gene Transfection In Vivo by Alkylated Polyethylenimine  

E-Print Network [OSTI]

We mechanistically explored the effect of increased hydrophobicity of the polycation on the efficacy and specificity of gene delivery in mice. N-Alkylated linear PEIs with varying alkyl chain lengths and extent of substitution ...

Fortune, Jennifer A.

51

Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross-Metathesis  

E-Print Network [OSTI]

n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when (tBuPCP)IrH[subscript 2] was paired ...

Dobereiner, Graham E.

52

Combustion chemistry  

SciTech Connect (OSTI)

This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

1993-12-01T23:59:59.000Z

53

Stretch Efficiency for Combustion Engines: Exploiting New Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

D.C. ace15daw.pdf More Documents & Publications Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion Engines:...

54

Advanced Combustion | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Advanced Combustion Combustion engines drive a large percentage of our nation's transportation vehicles and power generation and manufacturing facilities. Today's...

55

Method of making a cyanate ester foam  

DOE Patents [OSTI]

A cyanate ester resin mixture with at least one cyanate ester resin, an isocyanate foaming resin, other co-curatives such as polyol or epoxy compounds, a surfactant, and a catalyst/water can react to form a foaming resin that can be cured at a temperature greater than 50.degree. C. to form a cyanate ester foam. The cyanate ester foam can be heated to a temperature greater than 400.degree. C. in a non-oxidative atmosphere to provide a carbonaceous char foam.

Celina, Mathias C.; Giron, Nicholas Henry

2014-08-05T23:59:59.000Z

56

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

57

Chemical Looping Combustion  

Science Journals Connector (OSTI)

Chemical looping combustion (CLC) and looping cycles in general represent an important new ... technologies, which can be deployed for direct combustion as well as be used in gasification...2...stream suitable fo...

Edward John (Ben) Anthony

2012-01-01T23:59:59.000Z

58

Chemistry of Combustion Processes  

Science Journals Connector (OSTI)

The quantitative description and understanding of combustion processes needs extreme computational efforts and has at ... treatment can give a lot of insight into combustion processes, as demonstrated in the foll...

J. Warnatz

2000-01-01T23:59:59.000Z

59

Overview of Biomass Combustion  

Science Journals Connector (OSTI)

The main combustion systems for biomass fuels are presented and the respective requirements ... etc.) in industrial boilers or for co-combustion in power plants. For fuels with high ... moving grate firings are u...

T. Nussbaumer; J. E. Hustad

1997-01-01T23:59:59.000Z

60

Sensitive Analysis of Alkyl Alcohols as Decomposition Products of Alkyl Nitrites in Human Whole Blood and Urine by Headspace Capillary GC with Cryogenic Oven Trapping  

Science Journals Connector (OSTI)

......cryogenic oven trapping. | The abuse of alkyl nitrites is becoming...Sensitivity and Specificity The abuse of alkyl nitrites is becoming...them at common markets or by internet sales. The most popular alkyl...the detection of alkyl nitrite abuse in forensic science practice......

Kanako Watanabe-Suzuki; Robert R. Lemmer; Hideki Nozawa; Osamu Suzuki; Akira Ishii

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Rheology of silicon carbide/vinyl ester nanocomposites  

E-Print Network [OSTI]

New York, 1999. SILICON CARBIDE/VINYL ESTER NANOCOMPOSITESRheology of Silicon Carbide/Vinyl Ester NanocompositesABSTRACT: Silicon carbide (SiC) nanoparticles with no

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

62

Distribution of Pendant Alkyl Groups in the Argonne Premium Coals  

Science Journals Connector (OSTI)

Distribution of Pendant Alkyl Groups in the Argonne Premium Coals ... Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439, and Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 ... The ruthenium(VIII) oxidation reaction has been employed to determine the distribution of alkyl groups that are bonded to aromatic structural elements in lignin and the Argonne Premium Coals. ...

Marcus Obeng; Leon M. Stock

1996-07-18T23:59:59.000Z

63

E-Print Network 3.0 - alkyl amides derivatives Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

allylic alkylation Summary: Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James... been synthesized and employed in the...

64

E-Print Network 3.0 - alkyl chain bending Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interacting alkyl substituents Source: Collection: Chemistry 74 Low absorption liquid crystals for mid-wave infrared applications Summary: (), while keeping the alkyl chain...

65

Synthesis and Opioid Activity of [d-Pro10]Dynorphin A-(1?11) Analogues with N-Terminal Alkyl Substitution  

Science Journals Connector (OSTI)

Tyrosine tert-butyl ester (0.5?1.0 g, Sigma Chemical Co., St. Louis, MO) was dissolved in DMF (2 mL/mmol TyrOtBu), and N,N-diisopropylethylamine (DIEA, 2.5 equiv) was added to the solution dropwise, followed by alkyl bromide (6?7 equiv). ... The tert-butyl group was cleaved as described above and the free acid crystallized from Et2O (142 mg, 20%):? mp 243?244 °C; FAB-MS 222 (M + 1); HPLC tR = 3.6 min (99% purity). ...

Heekyung Choi; Thomas F. Murray; Gary E. DeLander; William K. Schmidt; Jane V. Aldrich

1997-08-15T23:59:59.000Z

66

energy savings by the use of mtbe to replace alkylate in automotive gasolines  

SciTech Connect (OSTI)

This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

1986-07-01T23:59:59.000Z

67

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

68

Synthesis of a new energetic nitrate ester  

SciTech Connect (OSTI)

Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

Chavez, David E [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

69

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

2007-06-05T23:59:59.000Z

70

Low NOx combustion  

SciTech Connect (OSTI)

Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

2008-10-21T23:59:59.000Z

71

Introduction to Biomass Combustion  

Science Journals Connector (OSTI)

Biomass was the major fuel in the world ... hundreds when coal then became dominant. The combustion of solid biofuels as a primary energy...

Jenny M. Jones; Amanda R. Lea-Langton…

2014-01-01T23:59:59.000Z

72

The Combustion of Solid Biomass  

Science Journals Connector (OSTI)

The combustion of solid biomass is covered in this chapter. This covers the general mechanism of combustion, moisture evaporation, devolatilisation, the combustion of the volatiles gases and tars and finally char...

Jenny M. Jones; Amanda R. Lea-Langton…

2014-01-01T23:59:59.000Z

73

Adsorption of alkyl amides: monolayer structures and mixing behaviour  

E-Print Network [OSTI]

adsorbs hydrocarbons from liquid media [42-44]. Groszek [42] provided an explanation for the high affinity of the graphite surface for the hydrocarbons. The zigzag structure of the hydrocarbon fits well into the graphite hexagons (Figure 1... of the composition range. 1.3 Alkyl amides In this section the properties and applications of alkyl amides are explained, and a review of the adsorption of amides on different surfaces such as graphite, polymer surfaces and water is provided. The bulk...

Bhinde, Tej

2011-02-08T23:59:59.000Z

74

Coal Combustion Science  

SciTech Connect (OSTI)

The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

1991-08-01T23:59:59.000Z

75

Fifteenth combustion research conference  

SciTech Connect (OSTI)

The BES research efforts cover chemical reaction theory, experimental dynamics and spectroscopy, thermodynamics of combustion intermediates, chemical kinetics, reaction mechanisms, combustion diagnostics, and fluid dynamics and chemically reacting flows. 98 papers and abstracts are included. Separate abstracts were prepared for the papers.

NONE

1993-06-01T23:59:59.000Z

76

Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods  

SciTech Connect (OSTI)

In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

Vicic, David A.

2014-05-01T23:59:59.000Z

77

Combustion, performance and emission characteristics of a DI CI engine using biodiesel with varied fatty acid composition  

Science Journals Connector (OSTI)

Five Biodiesel produced from different vegetable oils were tested on a diesel engine to study the effect of biodiesel fatty acid composition specifically unsaturated composition on the engine combustion. The results from fuel analysis show that biodiesel (93% unsaturated fatty acid ester composition) with 55% linolenic ester has a higher density of 0.89 kg/mł, lower viscosity of 3.8 cSt, heating value of 39 MJ/kg and cetane number of 49. The engine combustion results exhibits a longer premixed and shorter diffusion burning phase with higher peak pressure of 72 bars and higher cumulative heat release compared to other fatty ester composition. The performance and emission results show that emits more oxides of nitrogen of 16.83 g/kWh and exhibits higher thermal efficiency of 29.76% compared to diesel of 12.83 g/kWh and 28.41% respectively. Biodiesel with 45% saturated ester and 55% unsaturated ester composition shows a NOX neutral fuel with a penalty of 1.75% in thermal efficiency. No significant differences in unburnt hydrocarbon (UBHC), carbon monoxide (CO) and smoke emissions among the biodiesel fuels were noticed except linseed oil methyl ester.

Sukumar Puhan; A. Gopinath; G. Nagarajan

2009-01-01T23:59:59.000Z

78

Sensitive Analysis of Alkyl Alcohols as Decomposition Products of Alkyl Nitrites in Human Whole Blood and Urine by Headspace Capillary GC with Cryogenic Oven Trapping  

Science Journals Connector (OSTI)

......470-1192, Japan The abuse of alkyl nitrites is...oven trapping. | The abuse of alkyl nitrites is...Sensitivity and Specificity The abuse of alkyl nitrites is...abused by inhalation among young people for their aphrodisiac...common markets or by internet sales. The most popular......

Kanako Watanabe-Suzuki; Robert R. Lemmer; Hideki Nozawa; Osamu Suzuki; Akira Ishii

2003-02-01T23:59:59.000Z

79

Coal combustion products (CCPs  

Broader source: Energy.gov (indexed) [DOE]

combustion products (CCPs) combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge. When properly managed, CCPs offer society environmental and economic benefits without harm to public health and safety. Research supported by the U.S. Department of Energy's (DOE) Office of Fossil Energy (FE) has made an important contribution in this regard. Fossil Energy Research Benefits Coal Combustion Products Fossil Energy Research Benefits

80

Thermal ignition combustion system  

SciTech Connect (OSTI)

A thermal ignition combustion system adapted for use with an internal combustion engine is described comprising: (a) means for providing ignition chamber walls defining an ignition chamber, the chamber walls being made of a material having a thermal conductivity greater than 20 W/m/sup 0/C. and a specific heat greater than 480J/kg/sup 0/C., the ignition chamber being in constant communication with the main combustion chamber; (b) means for maintaining the temperature of the chamber walls above a threshold temperature capable of causing ignition of a fuel; and (c) means for conducting fuel to the ignition chamber.

Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

1988-04-19T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Sandia Combustion Research: Technical review  

SciTech Connect (OSTI)

This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

NONE

1995-07-01T23:59:59.000Z

82

Packed Bed Combustion: An Overview  

E-Print Network [OSTI]

;Packed Bed Combustion - University of Ottawa - CICS 2005 fuel fuel feed air products air fuel Retort) products Underfeed Combustion fuel feed air #12;Packed Bed Combustion - University of Ottawa - CICS 2005 required #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Overfeed Bed fuel motion products air

Hallett, William L.H.

83

Comparison of the Antiviral Activities of Alkoxyalkyl and Alkyl Esters of Cidofovir against Human and Murine Cytomegalovirus Replication In Vitro  

Science Journals Connector (OSTI)

...capacity to self-associate with the plasma membrane of the cell. However, the highly...spontaneously into the outer leaflet of the plasma membrane and are subsequently transferred...12). Once in the inner leaflet of the plasma membrane, the highly active CDV analogs...

William B. Wan; James R. Beadle; Caroll Hartline; Earl R. Kern; Stephanie L. Ciesla; Nadejda Valiaeva; Karl Y. Hostetler

2005-02-01T23:59:59.000Z

84

Engine Combustion & Efficiency - FEERC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engine Combustion & Efficiency Engine Combustion & Efficiency ORNL currently and historically supports the U.S. DOE on multi-cylinder and vehicle applications of diesel combustion, lean burn gasoline combustion, and low temperature combustion processes, and performs principal research on efficiency enabling technologies including emission controls, thermal energy recovery, and bio-renewable fuels. Research areas span from fundamental concepts to engine/vehicle integration and demonstration with a particular emphasis on the following areas: Thermodynamics for identifying and characterizing efficiency opportunities for engine-systems as well as the development of non-conventional combustion concepts for reducing fundamental combustion losses. Nonlinear sciences for improving the physical understanding and

85

Definition: Combustion | Open Energy Information  

Open Energy Info (EERE)

Combustion Combustion Jump to: navigation, search Dictionary.png Combustion The process of burning; chemical oxidation accompanied by the generation of light and heat.[1][2] View on Wikipedia Wikipedia Definition "Burning" redirects here. For combustion without external ignition, see spontaneous combustion. For the vehicle engine, see internal combustion engine. For other uses, see Burning (disambiguation) and Combustion (disambiguation). Error creating thumbnail: Unable to create destination directory This article's introduction section may not adequately summarize its contents. To comply with Wikipedia's lead section guidelines, please consider modifying the lead to provide an accessible overview of the article's key points in such a way that it can stand on its own as a

86

Spontaneous Human Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spontaneous Human Combustion Spontaneous Human Combustion Name: S. Phillips. Age: N/A Location: N/A Country: N/A Date: N/A Question: One of our 8th grade students has tried to find information in our library about spontaneous human combustion, but to no avail. Could you tell us where we might locate a simple reference, or provide some in information about this subject for him. Replies: Sorry, but this is definitely "fringe science"...try asking in bookstores. I seem to recall one of those "believe it or not" type of TV shows did an episode on spontaneous human combustion a few years ago in which they reported on some British scientists who investigated this purported phenomenon. Remember that people (back in the Dark Ages, and before) used to believe in "spontaneous generation" of certain plants and animals because they were not aware of the reproduction methods used by those plants and animals.

87

Advanced diesel combustion  

Science Journals Connector (OSTI)

Future emission norms will further reduce the vehicle emissions of diesel engines. To meet the goal of achieving these stringent limits while maintaining attractive attributes of marketability, the combustion ...

Dirk Adolph; Hartwig Busch; Stefan Pischinger; Andreas Kolbeck…

2008-01-01T23:59:59.000Z

88

Advanced Combustion Technologies  

Broader source: Energy.gov [DOE]

The workhorse of America's electric power sector is the coal-fired power plant. Today, coal combustion plants account for more than half of the Nation's electric power generation. Largely because...

89

Catalytic Combustion Processes  

Science Journals Connector (OSTI)

This work presents experimental data on the effect of catalytic additives on the combustion characteristics of ammonium nitrate and perchlorate and the explosives of different classes. Burning rates are determ...

A. P. Glaskova

1991-01-01T23:59:59.000Z

90

Advanced Combustion Technology to Enable High Efficiency Clean...  

Broader source: Energy.gov (indexed) [DOE]

Combustion Technology to Enable High Efficiency Clean Combustion Advanced Combustion Technology to Enable High Efficiency Clean Combustion Summary of advanced combustion research...

91

Coal combustion system  

DOE Patents [OSTI]

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

1988-01-01T23:59:59.000Z

92

Sandia Combustion Research Program  

SciTech Connect (OSTI)

During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

1988-01-01T23:59:59.000Z

93

Combustion Model for Engine Concept Development | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Model for Engine Concept Development Presentation shows how 1-cylinder testing, 3D combustion CFD and 1D gas exchange with an advanced combustion model are used...

94

The infrared and Raman spectra of N-alkyl ethylenimines  

E-Print Network [OSTI]

mother, without wnose sacrifices and help none of this would have been possible. TABLE OF CONTLNTS THE INFPAR D AND P'u~'AN SP" CTPW OF N-ALKYL ETHYLENIYINES Pa8e I. Introduction. . . . , . . . . , II. Experimental. . . , . 3 III ' Discussion... be represented as follows, CH2 R ? ~ &CH 2 where R = CH3-, C2H5-, and (CH3)2CH-. It is assumed here that the alkyl group lies above the plane of the ring as does the N-H hydrogen in ethylenimine. ' ' This assumption has been supported 8 9, 11 in the case...

Ashby, Theodore Leroy

2012-06-07T23:59:59.000Z

95

E-Print Network 3.0 - allylic alkylations added Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

benzyl or allyl halides. s-Alkyl... -chiral center of high optical purity based on the SN2 displace- ment reaction of alkyl cuprates on chiral allyl... A Practical and Highly...

96

E-Print Network 3.0 - asymmetric allylic alkylation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

benzyl or allyl halides. s-Alkyl... -chiral center of high optical purity based on the SN2 displace- ment reaction of alkyl cuprates on chiral allyl... ) Examples of asymmetric...

97

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

98

Combustible structural composites and methods of forming combustible structural composites  

DOE Patents [OSTI]

Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

2013-04-02T23:59:59.000Z

99

Combustible structural composites and methods of forming combustible structural composites  

DOE Patents [OSTI]

Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

Daniels, Michael A. (Idaho Falls, ID); Heaps, Ronald J. (Idaho Falls, ID); Steffler, Eric D (Idaho Falls, ID); Swank, William D. (Idaho Falls, ID)

2011-08-30T23:59:59.000Z

100

Combustion Safety Overview  

Broader source: Energy.gov (indexed) [DOE]

March 1-2, 2012 March 1-2, 2012 Building America Stakeholders Meeting Austin, Texas Combustion Safety in the Codes Larry Brand Gas Technology Institute Acknowledgement to Paul Cabot - American Gas Association 2 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Widely adopted fuel gas codes: * National Fuel Gas Code - ANSI Z223.1/NFPA 54, published by AGA and NFPA (NFGC) * International Fuel Gas Code - published by the International Code Council (IFGC) * Uniform Plumbing Code published by IAPMO (UPC) Safety codes become requirements when adopted by the Authority Having Jurisdiction (governments or fire safety authorities) 3 | Building America Program www.buildingamerica.gov Combustion Safety in the Codes Formal Relationships Between these codes: - The IFGC extracts many safety

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

A MODEL FOR POROUS-MEDIUM COMBUSTION  

Science Journals Connector (OSTI)

......these applied in coal combustion appears in...understanding of the chemistry of combustion...GLASSMAN, Combustion (Academic Press...ESSENHIGH, In Chemistry of Coal Utilization...POROUS-MEDIUM COMBUSTION 177 8. D. A......

J. NORBURY; A. M. STUART

1989-02-01T23:59:59.000Z

102

Microbial degradation of n-alkyl tetrahydrothiophenes found in petroleum  

SciTech Connect (OSTI)

Although n-alkyl-substituted tetrahydrothiophenes are found in nonbiodegraded petroleums, they are not found in petroleums which have undergone biodegradation in their reservoirs. These observations suggested that this group of compounds with alkyl chain lengths from approximately C/sub 10/ to at least C/sub 30/ is biodegradable. Two of these sulfides, 2-n-dodecyltetrahydrothiophene (DTHT) and 2-n-undecyltetrahydrothiophene, were synthesized, and their biodegradabilities were tested by using five gram-positive, n-alkane-degrading bacterial isolates. The alkyl side chains of these compounds were oxidized, and the major intermediates found in 2-n-undecyltetrahydrothiophene- and DTHT-metabolizing cultures were 2-tetrahydrothiophenecarboxylic acid (THTC) and 2-tetrahydrothiopheneacetic acid (THTA), respectively. Four n-alkane-degrading fungi were also shown to degrade DTHT, yielding both THTA and THTC. Quantitation of tetrahydrothiophene ring-containing products in 28-day-old bacterial and fungal cultures suggested that THTC and THTA were metabolized further to unidentified products. In addition, two of the bacterial isolates were shown to degrade a mixture of n-alkyl tetrahydrothiophenes isolated from Bellshill Lake crude oil.

Fedorak, P.M.; Payzant, J.D.; Montgomery, D.S.; Westlake, D.W.S.

1988-05-01T23:59:59.000Z

103

Alkylation of Guanosine and Deoxyguanosine by Phosphoramide Mustard  

Science Journals Connector (OSTI)

...Phosphoramide mustard, an active metabolite of cyclophosphamide...Phosphoramide mustard, an active metabolite of cyclophos...acrolein (1) and an active alkylating agent, phosphoramide...adducts which it forms. MATERIALS AND METHODS Crystalline...field emitter anode and cathode; 8 kV acceler ating...

Jitendra R. Mehta; Michael Przybylski; and David B. Ludlum

1980-11-01T23:59:59.000Z

104

Ester, Alaska: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Ester, Alaska: Energy Resources Ester, Alaska: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 64.8472222°, -148.0144444° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":64.8472222,"lon":-148.0144444,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

105

Vehicle Technologies Office: Combustion Engine Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Engine Combustion Engine Research to someone by E-mail Share Vehicle Technologies Office: Combustion Engine Research on Facebook Tweet about Vehicle Technologies Office: Combustion Engine Research on Twitter Bookmark Vehicle Technologies Office: Combustion Engine Research on Google Bookmark Vehicle Technologies Office: Combustion Engine Research on Delicious Rank Vehicle Technologies Office: Combustion Engine Research on Digg Find More places to share Vehicle Technologies Office: Combustion Engine Research on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Combustion Engine Research

106

Vehicle Technologies Office: Advanced Combustion Engines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Combustion Advanced Combustion Engines to someone by E-mail Share Vehicle Technologies Office: Advanced Combustion Engines on Facebook Tweet about Vehicle Technologies Office: Advanced Combustion Engines on Twitter Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Google Bookmark Vehicle Technologies Office: Advanced Combustion Engines on Delicious Rank Vehicle Technologies Office: Advanced Combustion Engines on Digg Find More places to share Vehicle Technologies Office: Advanced Combustion Engines on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Combustion Engines Emission Control Waste Heat Recovery Fuels & Lubricants Materials Technologies Advanced Combustion Engines

107

Thermal ignition combustion system  

DOE Patents [OSTI]

The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

1988-04-19T23:59:59.000Z

108

Studies in combustion dynamics  

SciTech Connect (OSTI)

The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

109

Thermal ignition combustion system  

SciTech Connect (OSTI)

The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

Kamo, Roy (Columbus, IN); Kakwani, Ramesh M. (Columbus, IN); Valdmanis, Edgars (Columbus, IN); Woods, Melvins E. (Columbus, IN)

1988-01-01T23:59:59.000Z

110

Nanoparticle Emissions from Internal Combustion Engines | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nanoparticle Emissions from Internal Combustion Engines Nanoparticle Emissions from Internal Combustion Engines 2004 Diesel Engine Emissions Reduction (DEER) Conference...

111

Improving alternative fuel utilization: detailed kinetic combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

alternative fuel utilization: detailed kinetic combustion modeling & experimental testing Improving alternative fuel utilization: detailed kinetic combustion modeling &...

112

Mechanism of Hydrocarbon Formation in Combustion Processes  

Science Journals Connector (OSTI)

Emissions from transportation systems that derive their energy directly from combustion processes include products of incomplete combustion, oxides of...

R. A. Matula

1973-01-01T23:59:59.000Z

113

Reversed flow fluidized-bed combustion apparatus  

DOE Patents [OSTI]

The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

Shang, Jer-Yu (Fairfax, VA); Mei, Joseph S. (Morgantown, WV); Wilson, John S. (Morgantown, WV)

1984-01-01T23:59:59.000Z

114

Aviation Combustion Toxicology: An Overview  

Science Journals Connector (OSTI)

......in a radiant heat furnace. Rats...the produced combustion products in...in both the combustion tube and radiant heat systems proved...literature data for CO2, low...acrolein, and heat expo- sures...primary toxic combustion gases and are...structures. The hydrocarbon constituents......

Arvind K. Chaturvedi

2010-01-01T23:59:59.000Z

115

Four Lectures on Turbulent Combustion  

E-Print Network [OSTI]

, combustion in a Diesel engine or in furnaces essentially taakes place under non-premixed conditions. In the Diesel engine a liquid fuel spray is injected into hot compressed air, the fuel evaporates and mixes combustion are in general subdivided into two classes: premixed or non-premixed combustion. For example

Peters, Norbert

116

Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and  

E-Print Network [OSTI]

energy resource that has been consumed by the world's population, exceeding natural gas, coal, nuclear a shift toward alternative sources of energy that are renewable, sustainable, efficient, cost Industries Chimiques de Nancy, Laboratoire Réactions et Génie des Procédés, UMR CNRS 7274, 1 rue Grandville

Paris-Sud XI, Université de

117

Combustion powered linear actuator  

DOE Patents [OSTI]

The present invention provides robotic vehicles having wheeled and hopping mobilities that are capable of traversing (e.g. by hopping over) obstacles that are large in size relative to the robot and, are capable of operation in unpredictable terrain over long range. The present invention further provides combustion powered linear actuators, which can include latching mechanisms to facilitate pressurized fueling of the actuators, as can be used to provide wheeled vehicles with a hopping mobility.

Fischer, Gary J. (Albuquerque, NM)

2007-09-04T23:59:59.000Z

118

US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap  

Broader source: Energy.gov [DOE]

The ACEC focuses on advanced engine and aftertreatment technology for three major combustion strategies: (1) Low-Temperature Combustion, (2) Dilute Gasoline combustion, and (3) Clean Diesel Combustion.

119

Assessment of Combustion and Turbulence Models for the Simulation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Assessment of Combustion and Turbulence Models for the Simulation of Combustion...

120

US DRIVE Advanced Combustion and Emission Control Technical Team...  

Energy Savers [EERE]

for three major combustion strategies: (1) Low-Temperature Combustion, (2) Dilute Gasoline combustion, and (3) Clean Diesel Combustion. acecroadmapjune2013.pdf More Documents...

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abbreviations & Acronyms Abbreviations & Acronyms Reference Shelf Solicitations & Awards Abbreviations & Acronyms The Combustion Technologies Product uses a number of abbreviations and acronyms. This web page gives you a definition of frequently used terms, as follows: 1½-Generation PFBC -- A PFBC plant where the hot (about 1400ºF) PFBC exhaust gases are used as a vitiated air supply for a natural gas combustor supplying high-temperature gas (above 2000ºF) to a combustion turbine expander (synonym for "PFB-NGT"). 1st-Generation PFBC -- Commercial PFBC technology where an unfired low-temperature (below 1650ºF) ruggedized turbine expander expands PFBC exhaust gases (synonym for "PFB-EGT"). 2nd-Generation PFBC (see synonyms: "APFBC," "PFB-CGT") -- Advanced PFBC where a carbonizer (mild gasifier) provides hot (about 1400ºF) coal-derived synthetic fuel gas to a special topping combustor. The carbonizer char is burned in the PFBC, and the PFBC exhaust is used as a hot (about 1400ºF) vitiated air supply for the topping combustor. The syngas and vitiated air are burned in a topping combustor to provide high-temperature gas (above 1700ºF) to a combustion turbine expander.

122

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nebraska Public Power District's Sheldon Station with APFBC Technology Nebraska Public Power District's Sheldon Station with APFBC Technology FBC Repower APFBC AES Greenidge APFBC Dan River FBC, APFBC Four Corners CHIPPS H.F. Lee Products Summary Sheldon Summary APFBC Sheldon GFBCC Sheldon APFBC L.V. Sutton Contents: APFBC Repowering Project Summary Key Features Site Layout Performance Environmental Characteristics Cost Other Combustion Systems Repowering Study Links: A related study is underway that would repower Sheldon Unit 1 and Unit 2 with gasification fluidized-bed combined cycle technology (GFBCC). CLICK HERE to find out more about repowering the Sheldon station with GFBCC instead. APFBC Repowering Project Summary Click on picture to enlarge Advanced circulating pressurized fluidized-bed combustion combined cycle systems (APFBC) are systems with jetting-bed pressurized fluidized-bed (PFB) carbonizer/gasifier and circulating PFBC combustor. The PFB carbonizer and PFBC both operate at elevated pressures (10 to 30 times atmospheric pressure) to provide syngas for operating a gas turbine topping combustor giving high cycle energy efficiency. The remaining char from the PFB carbonizer is burned in the pressurized PFBC. The combustion gas from the PFB also feeds thermal energy to the gas turbine topping combustor. This provides combined cycle plant efficiency on coal by providing the opportunity to generate electricity using both high efficiency gas turbines and steam.

123

Stretch Efficiency for Combustion Engines: Exploiting New Combustion...  

Broader source: Energy.gov (indexed) [DOE]

boost. * H 2 enrichment extends lean limit, improves C p C v ratio, lowers cylinder heat loss, assists cold start, lowers combustion irreversibility. IC Engine Work Reformer...

124

Alkyl Amides and Nitriles as Novel Tracers for Biomass Burning  

Science Journals Connector (OSTI)

Ammonia emissions into the atmosphere have been reported for numerous sources, as for example natural decay in soils, sewage treatment plants, livestock waste, and ammonia-based fertilizers (42, 43). ... Anal. of emissions from the burning of dried tropical grasses and agricultural wastes in a small-scale app. ... under the smoldering conditions of residential wood combustion, as compared to the active burning of forest fires and slash burns, incomplete combustion resulted in the preservation of high levels of the natural products. ...

Bernd R. T. Simoneit; A. I. Rushdi; M. R. bin Abas; B. M. Didyk

2002-11-23T23:59:59.000Z

125

Preparation of {alpha},{beta}-unsaturated carboxylic acids and esters  

DOE Patents [OSTI]

Disclosed is a process for the preparation of {alpha},{beta}-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.

1998-09-15T23:59:59.000Z

126

E-Print Network 3.0 - activated ester self-assembled Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ester) Summary: behavior of DNA with the polymer to form self-assembled PHP esterDNA complexes was characterized... 3 and 4). Condensation of Polyanion by...

127

E-Print Network 3.0 - acid esters evaluated Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract... This paper describes an exploratory study on the synthesis of fatty acidpotato starch esters using... : potato starch, fatty acid starch esters, starch laurate, ......

128

Sandia National Laboratories: Diesel Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Diesel Combustion Caterpillar, Sandia CRADA Opens Door to Multiple Research Projects On April 17, 2013, in Capabilities, Computational Modeling & Simulation, CRF, Materials...

129

Improve Your Boiler's Combustion Efficiency  

SciTech Connect (OSTI)

This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

130

Municipal Waste Combustion (New Mexico)  

Broader source: Energy.gov [DOE]

This rule establishes requirements for emissions from, and design and operation of, municipal waste combustion units. "Municipal waste" means all materials and substances discarded from residential...

131

ALS Evidence Confirms Combustion Theory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

are produced, generally, when insufficient oxygen or other factors result in incomplete combustion of organic matter (e.g., in engines and incinerators, when biomass burns in...

132

Numerical Modeling of HCCI Combustion  

Broader source: Energy.gov (indexed) [DOE]

Numerical Modeling of HCCI Combustion Salvador M. Aceves, Daniel L. Flowers, J. Ray Smith, Joel Martinez-Frias, Francisco Espinosa-Loza, Tim Ross, Bruce Buchholz, Nick...

133

E-Print Network 3.0 - alkylating agents synthesis Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

134

E-Print Network 3.0 - alkylating agents Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

135

E-Print Network 3.0 - alkylating agents evaluacion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Product Leinamycin Summary: , the antitumor natural product leina- mycin (LM) (1, 2) is converted to a potent DNA-alkylating agent via... the sequence specificity...

136

Combustion Byproducts Recycling Consortium  

SciTech Connect (OSTI)

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31T23:59:59.000Z

137

Combustion Byproducts Recycling Consortium  

SciTech Connect (OSTI)

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

2008-08-31T23:59:59.000Z

138

Space shuttle based microgravity smoldering combustion experiments  

E-Print Network [OSTI]

zone, and smolder heat of combustion (energy per unit massand Q is the smolder heat of combustion. The mass fluxes ofdata. The smolder heat of combustion is not well determined

Walther, David C; Fernandez-Pello, Carlos; Urban, David L

1999-01-01T23:59:59.000Z

139

Combustion Catalysts in Industry- An Update  

E-Print Network [OSTI]

applications of combustion catalysts for coal are presented. Combustion efficiency and calculations are discussed, followed by an explanation of the theories of combustion catalysis and a review of three case histories....

Merrell, G. A.; Knight, R. S.

140

Self-tuning regulators for combustion oscillations  

Science Journals Connector (OSTI)

...interaction of acoustic waves and combustion processes. An abundant literature...numerical simulations of the combustion processes and coupled fluid dynamics...nonlinear analysis of controlled combustion processes. In Proc. 1999 IEEE Int...

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Combustion-thermoelectric tube  

SciTech Connect (OSTI)

In direct combustion-thermoelectric energy conversion, direct fuel injection and reciprocation of the air flowing in a solid matrix are combined with the solid conduction to allow for obtaining super-adiabatic temperatures at the hot junctions. While the solid conductivity is necessary, the relatively large thermal conductivity of the available high-temperature thermoelectric materials (e.g., Si-Ge alloys) results in a large conduction loss from the hot junctions and deteriorates the performance. Here a combustion-thermoelectric tube is introduced and analyzed. Radially averaged temperatures are used for the fluid and solid phases. A combination of external cooling of the cold junctions, and direct injection of the fuel, has been used to increase the energy conversion efficiency for low thermal conductivity, high-melting temperature thermoelectric materials. The parametric study (geometry, flow, stoichiometry, materials) shows that with the current high figure of merit, high temperature Si{sub 0.7}Ge{sub 0.3} properties, a conversion efficiency of about 11% is achievable. With lower thermal conductivities for these high-temperature materials, efficiencies about 25% appear possible. This places this energy conversion in line with the other high efficiency, direct electric power generation methods.

Park, C.W.; Kaviany, M.

1999-07-01T23:59:59.000Z

142

Ultrarich Filtration Combustion of Ethane  

Science Journals Connector (OSTI)

Ultrarich filtration combustion of ethane is studied in a porous medium composed of alumina spheres with the aim to achieve optimized conversion to hydrogen and syngas. ... Dhamrat, R. S.; Ellzey, J. L.Numerical and experimental study of the conversion of methane to hydrogen in a porous media reactor Combust. ...

Mario Toledo; Khriscia Utria; Alexei V. Saveliev

2014-01-28T23:59:59.000Z

143

A Generalized Pyrolysis Model for Combustible Solids  

E-Print Network [OSTI]

model. ?H c is the heat of combustion, and the ratio ?H c /?may have widely varying heats of combustion (CO vs. gaseous

Lautenberger, Chris

2007-01-01T23:59:59.000Z

144

Optimization of Advanced Diesel Engine Combustion Strategies...  

Broader source: Energy.gov (indexed) [DOE]

Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

145

Advanced Combustion Concepts - Enabling Systems and Solutions...  

Broader source: Energy.gov (indexed) [DOE]

engine * Integration of proposed air path and HCCI combustion control strategies into ECU software * Prototype level 2 updates and proof of combustion concept for vehicle readiness...

146

Advanced Combustion Concepts - Enabling Systems and Solutions...  

Broader source: Energy.gov (indexed) [DOE]

engine installed and vehicle available for application, emission and fuel economy optimization with advanced combustion modes. 4 Advanced combustion control strategy, capable of...

147

Premix charge, compression ignition combustion system optimization...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Premix charge, compression ignition combustion system optimization Premix charge, compression ignition combustion system optimization Presentation given at DEER 2006, August 20-24,...

148

Vehicle Technologies Office: Advanced Combustion Engines | Department...  

Broader source: Energy.gov (indexed) [DOE]

Batteries Fuel Efficiency & Emissions Combustion Engines Fuel Effects on Combustion Idle Reduction Emissions Waste Heat Recovery Lightweighting Parasitic Loss Reduction Lubricants...

149

Sandia Hydrogen Combustion Research | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sandia Hydrogen Combustion Research Sandia Hydrogen Combustion Research Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008...

150

Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...  

Broader source: Energy.gov (indexed) [DOE]

Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary...

151

Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions  

E-Print Network [OSTI]

Part I describes the expansion in scope of a nickel-catalyzed coupling reaction of unactivated alkyl bromides and alkyl boranes to include unactivated alkyl chlorides. The new method is adapted for use outside of a glove ...

Lu, Zhe

2010-01-01T23:59:59.000Z

152

The Role of Comprehensive Detailed Chemical Kinetic Reaction Mechanisms in Combustion Research  

SciTech Connect (OSTI)

Recent developments by the authors in the field of comprehensive detailed chemical kinetic reaction mechanisms for hydrocarbon fuels are reviewed. Examples are given of how these mechanisms provide fundamental chemical insights into a range of combustion applications. Practical combustion consists primarily of chemical heat release from reactions between a fuel and an oxidizer, and computer simulations of practical combustion systems have become an essential tool of combustion research (Westbrook et al., 2005). At the heart of most combustion simulations, the chemical kinetic submodel frequently is the most detailed, complex and computationally costly part of a system model. Historically, the chemical submodel equations are solved using time-implicit numerical algorithms, due to the extreme stiffness of the coupled rate equations, with a computational cost that varies roughly with the cube of the number of chemical species in the model. While early mechanisms (c. 1980) for apparently simple fuels such as methane (Warnatz, 1980) or methanol (Westbrook and Dryer, 1979) included perhaps 25 species, current detailed mechanisms for much larger, more complex fuels such as hexadecane (Fournet et al., 2001; Ristori et al., 2001; Westbrook et al., 2008) or methyl ester methyl decanoate (Herbinet et al., 2008) have as many as 2000 or even 3000 species. Rapid growth in capabilities of modern computers has been an essential feature in this rapid growth in the size and complexity of chemical kinetic reaction mechanisms.

Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

2008-07-16T23:59:59.000Z

153

Characteristics of the performance and emissions of a HSDI diesel engine running with cottonseed oil or its methyl ester and their blends with diesel fuel  

Science Journals Connector (OSTI)

An experimental study has been conducted to evaluate the use of various blends of cottonseed oil or its methyl ester (bio-diesel) with diesel fuel, in blend ratios from 10/90 up to 100/0, in a fully instrumented, four-stroke, High Speed Direct Injection (HSDI), Ricardo/Cussons 'Hydra' diesel engine. The tests were conducted using each of the above fuel blends or neat fuels, with the engine working at a medium and a high load. Volumetric fuel consumption, exhaust smokiness and exhaust-regulated gas emissions such as nitrogen oxides, carbon monoxide and unburnt hydrocarbons were measured. The differences in the performance and exhaust emissions from the baseline operation of the engine, that is, when working with neat diesel fuel, were determined and compared, as well as the differences between cottonseed oil or its methyl ester and their blends. Theoretical aspects of diesel engine combustion were used to aid the correct interpretation of the engine behaviour.

Constantine D. Rakopoulos; Kimon A. Antonopoulos; Dimitrios C. Rakopoulos; Emmanuel C. Kakaras; Efthimios G. Pariotis

2007-01-01T23:59:59.000Z

154

A comparative evaluation of Al 2 O 3 coated low heat rejection diesel engine performance and emission characteristics using fuel as rice bran and pongamia methyl ester  

Science Journals Connector (OSTI)

In this study for the first time a nanoceramic Al 2 O 3 was used as a coatingmaterial in the low heat rejection engine concept. Experiments were conducted on single cylinder four stroke water cooled and direct injection diesel engine. First the engine was tested at different load conditions without coating. Then combustion chamber surfaces (cylinder head cylinder liner valves and piston crown face) were coated with nanoceramic material of Al 2 O 3 using plasma spray method. Comparative evaluation on performance and emission characteristics using fuel as rice bran methyl ester pongamia methyl ester and biodiesel/diesel fuel mixtures was studied in the ceramiccoated and uncoated engines under the same running conditions. An increase in engine power and a decrease in specific fuel consumption as well as significant improvements in exhaust gas emissions (except NOx) and smoke density were observed in the ceramiccoated engines compared with those of the uncoated engine.

M. Mohamed Musthafa; S. P. Sivapirakasam; M. Udayakumar

2010-01-01T23:59:59.000Z

155

Year/PAD District Alkylates Aromatics Road Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Alkylates Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1981 to January 1, 2013 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1981 974 299 765 131 234 276 2,054 NA JAN 1, 1982 984 290 740 162 242 267 1,944 NA JAN 1, 1983 960 237 722 212 241 296 2,298 NA JAN 1, 1984 945 218 800 208 241 407 2,444 NA JAN 1, 1985 917 215 767 219 243 424 2,572 NA JAN 1, 1986 941 276 804 258 246 356 2,357 NA JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

156

Enediolate-Dilithium Amide Mixed Aggregates in the Enantioselective Alkylation of Arylacetic Acids: Structural  

E-Print Network [OSTI]

Despite remarkable progress in the field of catalytic asymmetric synthesis,1 asymmetric alkylations of lithium enolates are pre- dominantly based on covalent chiral auxiliaries even in the simplest functionalizations.2-5 Recently, we developed an alkylation of the dianions of aryl and heteroaryl acetic acids6

Collum, David B.

157

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible pre-atomized fuels, comprising: (A) forming a hydrocarbon-in-water emulsion using an effective amount of a surfactant package comprising at least one water-soluble surfactant, the hydrocarbon-in-water emulsion (1) comprising a hydrocarbon characterized by API gravity of about 20/sup 0/ API or less, viscosity of about 1000 centipoise or greater at 212/sup 0/F., a paraffin content of about 50% by weight or less and, an aromatic content of about 15% by weight or greater, and (2) having a hydrocarbon water ratio from about 60:40 to about 90:10 by volume; and (B) burning the resultant hydrocarbon-in-water emulsion.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III; Bolden, P.L. Jr.

1987-08-04T23:59:59.000Z

158

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible fuels comprising: (A) forming a hydrocarbosol using a surfactant package in a proportion of about 1:100 to about 1:20,000 by weight based on hydrocarbon, (1) the surfactant package comprising (a) at least one water-soluble surfactant, an effective amount of which surfactant promotes emulsification of a hydrocarbon with API gravity of about 20/sup 0//sup o/ API or less; and (b) at least one water-soluble bioemulsifier, being a microboally-derived substance which predominantly resides at hydrocarbon/water interfaces to substantially surround hydrocarbon droplets in hydrocarbon-in-water emulsions; (2) the hydrocarbosol (a) comprising a hydrocarbon characterized by an API gravity of about 20/sup 0//sup o/ API or less; (b) having a hydrocarbon:water ratio of about 70:30 by volume; and (B) burning the resultant hydrocarbosol.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III

1986-10-21T23:59:59.000Z

159

NETL: Combustion Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gas Turbines for APFBC Gas Turbines for APFBC FBC Repower Simple Description Detailed Description APFBC Specs GTs for APFBC Suited for Repowering Existing Power Plants with Advanced Pressurized Fluidized-Bed Combined Cycles APFBC combined cycles have high energy efficiency levels because they use modern, high-temperature, high-efficiency gas turbines as the core of a combined power cycle. This web page discusses a current U.S. Department of Energy project that is evaluating combustion turbines suited for repowering existing steam plants. The natural-gas-fueled version of the Siemens Westinghouse Power Corporation W501F. Modified versions of this gas turbine core are suited for operating in APFBC power plants. Contents: Introduction APFBC Repowering Considerations

160

Synthesis and Decarboxylative Coupling of Sulfonyl Acetic Esters  

E-Print Network [OSTI]

The synthesis and palladium-catalyzed decarboxylative allylation (DCA) of ?-sulfonyl allyl esters is the central focus of this dissertation. Specifically we describe the development of the racemic reaction in which the scope and mechanism...

Weaver, Jimmie Dean

2010-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion  

Broader source: Energy.gov [DOE]

Applied low temperature combustion to the Navistar 6.4L V8 engine with 0.2g NOx/bhp-hr operation attained at the rated 16.5 BMEP

162

Modeling of Combustion Processes in Internal Combustion Engines  

Science Journals Connector (OSTI)

Improving internal combustion engines (ICE) and increasing the quality of operation are linked with the necessity of maximally increasing the degree of compression. For ICE with spark ignition (otto cycle), th...

V. A. Vinokurov; V. A. Kaminskii; V. A. Frost…

2000-11-01T23:59:59.000Z

163

Some recent advances in droplet combustion  

Science Journals Connector (OSTI)

This paper reviews the theoretical and experimental advances in droplet combustion since the 1982 Second International Colloquium on Drops and Bubbles. Specific topics discussed include multicomponent droplet combustion and microexplosion convection droplet combustion the combustion of slurries propellants and hazardous wastes soot formation in droplet burning and several miscellaneous subjects. Areas of further research are suggested.

C. K. Law

1990-01-01T23:59:59.000Z

164

Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels  

SciTech Connect (OSTI)

Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

Naik, C V; Westbrook, C K

2009-04-08T23:59:59.000Z

165

Synthesis, droplet combustion, and sooting characteristics of biodiesel produced from waste vegetable oils  

SciTech Connect (OSTI)

In light of the potential of fatty acid methyl ester (FAME, i.e. biodiesel) as a renewable energy source, an innovative acid catalyzed process was developed for the synthesis of biodiesel from waste vegetable oils. The synthesized biodiesels were analytically characterized for their major components, molar fraction and molecular weight of each component, the average molecular weight, and the heat of combustion. Their droplet combustion characteristics in terms of the burning rate, flame size, and sooting tendency were subsequently determined in a high-temperature, freely-falling droplet apparatus. Results show that the biodiesel droplet has higher burning rate, and that biodiesel in general has a lower propensity to soot because its molecular oxygen content promotes the oxidation of the soot precursors.

Li, T. X.; Zhu, D. L.; Akafuah, N.; Saito, K.; Law, C. K.

2011-01-01T23:59:59.000Z

166

Staged Combustion of Pulverized Coal  

Science Journals Connector (OSTI)

The emissions of nitrogen oxides are much higher with the combustion of fossil fuels containing organic bound nitrogen compounds than with clean fuels like natural gas and light distillate oil. During combusti...

H. Kremer; R. Mechenbier; W. Schulz

1987-01-01T23:59:59.000Z

167

Light Duty Efficient Clean Combustion  

Broader source: Energy.gov (indexed) [DOE]

fuel efficiency over the FTP city drive cycle by 10.5% over today's state-of-the-art diesel engine. Develop & design an advanced combustion system that synergistically meets...

168

20 - Chemical looping combustion (CLC)  

Science Journals Connector (OSTI)

Abstract: Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of the greenhouse gas CO2. The technology involves the use of a metal oxide as an oxygen carrier which transfers oxygen from combustion air to the fuel, and hence a direct contact between air and fuel is avoided. Two inter-connected fluidized beds, i.e. fuel reactor and air reactor, are used in the process. The outlet gas from the fuel reactor consists ideally of CO2 and H2O, and the latter is easily removed by condensation. This chapter presents the basic principles, gives an overview of oxygen-carrier materials and operational experiences, discusses the application to gaseous, liquid and solid fuels, and the use for combustion as well as for hydrogen production.

A. Lyngfelt

2013-01-01T23:59:59.000Z

169

Chemical Kinetics of Combustion Processes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Combustion Processes Hai Wang B. Yang, J. Camacho, S. Lieb, S. Memarzadeh, S.-K. Gao and S. Koumlis University of Southern California 2010 CEFRC Conference Benzene + O( 3 P) ...

170

Plum Combustion | Open Energy Information  

Open Energy Info (EERE)

Plum Combustion Plum Combustion Jump to: navigation, search Name Plum Combustion Place Atlanta, Georgia Product Combustion technology, which reduces NOx-emissions. Coordinates 33.748315°, -84.391109° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":33.748315,"lon":-84.391109,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

171

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

172

Chemistry: Theory - Combustion Energy Frontier Research Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theory Chemistry: Theory Presentations from 2010 CEFRC First Annual Conference MultireferenceCorrelated WavefunctionCalculations and Reaction Flux Analyses of Methyl Ester...

173

Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion  

SciTech Connect (OSTI)

A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

Ho, Min-Da.

1993-05-25T23:59:59.000Z

174

Chemical Looping Combustion Kinetics  

SciTech Connect (OSTI)

One of the most promising methods of capturing CO{sub 2} emitted by coal-fired power plants for subsequent sequestration is chemical looping combustion (CLC). A powdered metal oxide such as NiO transfers oxygen directly to a fuel in a fuel reactor at high temperatures with no air present. Heat, water, and CO{sub 2} are released, and after H{sub 2}O condensation the CO{sub 2} (undiluted by N{sub 2}) is ready for sequestration, whereas the nickel metal is ready for reoxidation in the air reactor. In principle, these processes can be repeated endlessly with the original nickel metal/nickel oxide participating in a loop that admits fuel and rejects ash, heat, and water. Our project accumulated kinetic rate data at high temperatures and elevated pressures for the metal oxide reduction step and for the metal reoxidation step. These data will be used in computational modeling of CLC on the laboratory scale and presumably later on the plant scale. The oxygen carrier on which the research at Utah is focused is CuO/Cu{sub 2}O rather than nickel oxide because the copper system lends itself to use with solid fuels in an alternative to CLC called 'chemical looping with oxygen uncoupling' (CLOU).

Edward Eyring; Gabor Konya

2009-03-31T23:59:59.000Z

175

Particulate emissions from combustion of biomass in conventional combustion (air) and oxy-combustion conditions.  

E-Print Network [OSTI]

??Oxy-fuel combustion is a viable technology for new and existing coal-fired power plants, as it facilitates carbon capture and thereby, can reduce carbon dioxide emissions.… (more)

Ruscio, Amanda

2013-01-01T23:59:59.000Z

176

Advanced High Efficiency Clean Diesel Combustion with Low Cost...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Advanced High Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Clean, in-cylinder combustion...

177

Low-Temperature Automotive Diesel Combustion | Department of...  

Office of Environmental Management (EM)

in Low Temperature Automotive Diesel Combustion Systems Mixture Formation in a Light-Duty Diesel Engine Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments...

178

Oxy-Combustion CO2 Control | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Combustion Oxy-Combustion Chemical Looping Combustion Program Plan Project Portfolio Project Information POSTED January 27, 2015 - Funding Opportunity Announcement DE-FOA-...

179

PARAMETRIC STUDY OF SUBMICRON PARTICULATES FROM PULVERIZED COAL COMBUSTION  

E-Print Network [OSTI]

D. , Trace Element Chemistry of Coal during Combustion andthe Emissions from Coal-Fired Plants. Prog. Energy Combust.Combustion of Pulverized Coal, Lawrence Berkeley Laboratory

Pennucci, J.

2014-01-01T23:59:59.000Z

180

Fuel Effects on Mixing-Controlled Combustion Strategies for High...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency...

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

The Effects of Ethanol/Gasoline Blends on Advanced Combustion Strategies in Internal Combustion Engines.  

E-Print Network [OSTI]

??This dissertation presents the effects of blending ethanol with gasoline on advanced combustion strategies in internal combustion engines. The unique chemical, physical and thermal properties… (more)

Fatouraie, Mohammad

2014-01-01T23:59:59.000Z

182

Jet plume injection and combustion system for internal combustion engines  

DOE Patents [OSTI]

An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

Oppenheim, Antoni K. (Kensington, CA); Maxson, James A. (Berkeley, CA); Hensinger, David M. (Albany, CA)

1993-01-01T23:59:59.000Z

183

Combustion Byproducts Recycling Consortium  

SciTech Connect (OSTI)

The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F-fly ash. Some developed technologies have similar potential in the longer term. (3) Laboratory studies have been completed that indicate that much higher amounts of fly ash could be added in cement-concrete applications under some circumstances. This could significantly increase use of fly ash in cement-concrete applications. (4) A study of the long-term environmental effects of structural fills in a surface mine in Indiana was completed. This study has provided much sought after data for permitting large-volume management options in both beneficial as well as non-beneficial use settings. (5) The impact of CBRC on CCBs utilization trends is difficult to quantify. However it is fair to say that the CBRC program had a significant positive impact on increased utilization of CCBs in every region of the USA. Today, the overall utilization of CCBs is over 43%. (6) CBRC-developed knowledge base led to a large number of other projects completed with support from other sources of funding. (7) CBRC research has also had a large impact on CCBs management across the globe. Information transfer activities and visitors from leading coal producing countries such as South Africa, Australia, England, India, China, Poland, Czech Republic and Japan are truly noteworthy. (8) Overall, the CBRC has been a truly successful, cooperative research program. It has brought together researchers, industry, government, and regulators to deal with a major problem facing the USA and other coal producing countries in the world.

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31T23:59:59.000Z

184

Optimization of combustion bowl geometry for the operation of kapok biodiesel – Diesel blends in a stationary diesel engine  

Science Journals Connector (OSTI)

Abstract The purpose of this research work is to optimize the combustion bowl geometry of a single cylinder stationary diesel engine for the effective operation of KME (kapok methyl ester) – diesel blends. Considering that the reported design modification would render the benefit of adaptation of higher blends of KME, in this study, two different combustion chamber geometries such as TRCC (trapezoidal combustion chamber) and TCC (toroidal combustion chamber) were chosen in addition to the convention design of HCC (hemispherical combustion chamber). In the experimental investigation, suitable blends such as B25 (25% KME + 75% diesel), B50 (50% KME + 50% diesel), B75 (75% KME + 25% diesel) and B100 (100% KME) were tested in a diesel engine with various combustion chamber geometries as mentioned above. Based on the results obtained from this study, TCC was shown to exhibit better performance and emission than TRCC and HCC for all test blends. Further, when compared to diesel, B25 and B50 were found to be the optimum blends with HCC and TCC, respectively, while TRCC seldom evinced better engine characteristics for any of the blends. Categorically, B50 showed a 5.2% increase in BTE (brake thermal efficiency) than diesel with TCC, whereas emissions such as CO (carbon monoxide) and smoke were reduced by 15.7% and 7.8%, respectively, with a comparable NOX (nitrogen oxides) emission with diesel. Similarly, combustion for B50 with TCC was found to be better than diesel, manifesting an increase in maximum heat release rate that that of diesel. Conclusively, from the experimental study, TCC was recognized as an ideal choice of combustion chamber design for the operation of blends up to B50 in a diesel engine.

S. Vedharaj; R. Vallinayagam; W.M. Yang; C.G. Saravanan; P.S. Lee

2015-01-01T23:59:59.000Z

185

Turbulent Combustion in SDF Explosions  

SciTech Connect (OSTI)

A heterogeneous continuum model is proposed to describe the dispersion and combustion of an aluminum particle cloud in an explosion. It combines the gas-dynamic conservation laws for the gas phase with a continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models. It incorporates a combustion model based on the mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the C-4 booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Numerical simulations of the explosion fields from 1.5-g Shock-Dispersed-Fuel (SDF) charge in a 6.6 liter calorimeter were used to validate the combustion model. Then the model was applied to 10-kg Al-SDF explosions in a an unconfined height-of-burst explosion. Computed pressure histories are compared with measured waveforms. Differences are caused by physical-chemical kinetic effects of particle combustion which induce ignition delays in the initial reactive blast wave and quenching of reactions at late times. Current simulations give initial insights into such modeling issues.

Kuhl, A L; Bell, J B; Beckner, V E

2009-11-12T23:59:59.000Z

186

HCCI Combustion: Analysis and Experiments  

SciTech Connect (OSTI)

Homogeneous charge compression ignition (HCCI) is a new combustion technology that may develop as an alternative to diesel engines with high efficiency and low NOx and particulate matter emissions. This paper describes the HCCI research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work. On analysis, we have developed two powerful tools: a single zone model and a multi-zone model. The single zone model has proven very successful in predicting start of combustion and providing reasonable estimates for peak cylinder pressure, indicated efficiency and NOX emissions. This model is being applied to develop detailed engine performance maps and control strategies, and to analyze the problem of engine startability. The multi-zone model is capable of very accurate predictions of the combustion process, including HC and CO emissions. The multi-zone model h as applicability to the optimization of combustion chamber geometry and operating conditions to achieve controlled combustion at high efficiency and low emissions. On experimental work, we have done a thorough evaluation of operating conditions in a 4-cylinder Volkswagen TDI engine. The engine has been operated over a wide range of conditions by adjusting the intake temperature and the fuel flow rate. Satisfactory operation has been obtained over a wide range of operating conditions. Cylinder-to-cylinder variations play an important role in limiting maximum power, and should be controlled to achieve satisfactory performance.

Salvador M. Aceves; Daniel L. Flowers; Joel Martinez-Frias; J. Ray Smith; Robert Dibble; Michael Au; James Girard

2001-05-14T23:59:59.000Z

187

Palladium-catalyzed allylic alkylation via decarboxylative and retro-Claisen C-C cleavage methods  

E-Print Network [OSTI]

Presented herein is the development of new methods for Pd-catalyzed allylic alkylation with a central focus on reactions that generate molecular complexity rapidly with little waste byproduct. With this simply stated, yet ...

Grenning, Alexander James

2012-05-31T23:59:59.000Z

188

E-Print Network 3.0 - alkylation response protein Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: -DNA methyltransferases such as Ada and Ogt in E. coli and MGMT (or AGT) in humans. These proteins directly remove alkyl... purified proteins have been reported only for...

189

E-Print Network 3.0 - alkylating agent monobromobimane Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Naphthoate and Central Amide in Sequence-Dependent Summary: . In these assays, a 100-fold excess of agents was used in order to provide measurable alkylation yields in single......

190

1208 Organometallics1988,7,1208-1213 Copper(I) Alkyls. Synthesis and Characterization of Tertiary  

E-Print Network [OSTI]

-Champaign, Urbana, Illinois 61801 Received December 28. 1986 Alkylation of copper(I1)acetate reflections and 62 variables. Introduction Lithium dialkylcuprates, LiCuR2,are used extensively in organic

Girolami, Gregory S.

191

E-Print Network 3.0 - alkyl methyl ketones Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

l S e m e s t e r 1 9 9 7 Summary: . These acetylides are nucleophilic enough to undergo SN2 reactions with alkyl halides. There are two steps involved... : (a) formation of the...

192

Major research topics in combustion  

SciTech Connect (OSTI)

The Institute for Computer Applications in Science and Engineering (ICASE) and NASA Langley Research Center (LaRC) hosted a workshop on October 2--4, 1989 to discuss some combustion problems of technological interest to LaRC and to foster interaction with the academic community in these research areas. The topics chosen for this purpose were flame structure, flame holding/extinction, chemical kinetics, turbulence-kinetics interaction, transition to detonation, and reacting free shear layers. This document contains the papers and edited versions of general discussions on these topics. The lead paper set the stage for the meeting by discussing the status and issues of supersonic combustion relevant to the scramjet engine. Experts were then called upon to review the current knowledge in the aforementioned areas, to focus on how this knowledge can be extended and applied to high-speed combustion, and to suggest future directions of research in these areas.

Hussaini, M.Y.; Kumar, A.; Voigt, R.G. (eds.)

1992-01-01T23:59:59.000Z

193

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Natural Ores as Oxygen Carriers in Chemical Looping Combustion ... Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. ...

Hanjing Tian; Ranjani Siriwardane; Thomas Simonyi; James Poston

2013-01-02T23:59:59.000Z

194

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

1983-09-21T23:59:59.000Z

195

Combustion heater for oil shale  

DOE Patents [OSTI]

A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

1985-01-01T23:59:59.000Z

196

Chemical kinetics and combustion modeling  

SciTech Connect (OSTI)

The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

197

Combustion synthesis method and products  

DOE Patents [OSTI]

Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

Holt, J.B.; Kelly, M.

1993-03-30T23:59:59.000Z

198

Combustion synthesis method and products  

DOE Patents [OSTI]

Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

Holt, J. Birch (San Jose, CA); Kelly, Michael (West Alexandria, OH)

1993-01-01T23:59:59.000Z

199

Engine Combustion Network Experimental Data  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Maintained by the Engine Combustion Department of Sandia National Laboratories, data currently available on the website includes reacting and non-reacting sprays in a constant-volume chamber at conditions typical of diesel combustion. The data are useful for model development and validation because of the well-defined boundary conditions and the wide range of conditions employed. A search utility displays data based on experimental conditions such as ambient temperature, ambient density, injection pressure, nozzle size, fuel, etc. Experiment-related visualizations are also available. The search utility for experimental data is located at http://public.ca.sandia.gov/ecn/cvdata/frameset.html (Specialized Interface)

200

Transonic Combustion Inc | Open Energy Information  

Open Energy Info (EERE)

Transonic Combustion Inc Transonic Combustion Inc Jump to: navigation, search Name Transonic Combustion, Inc. Place Camarillo, California Zip CA 93012 Sector Efficiency, Renewable Energy Product Transonic Combustion, Inc. is a US based research & development company focused on developing ultra-high efficiency automotive engines that run on gasoline and bio-renewable flex fuels. References Transonic Combustion, Inc.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Transonic Combustion, Inc. is a company located in Camarillo, California . References ↑ "Transonic Combustion, Inc." Retrieved from "http://en.openei.org/w/index.php?title=Transonic_Combustion_Inc&oldid=352376

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Biomass Combustion: Carbon Capture and Storage  

Science Journals Connector (OSTI)

This chapter deals with the capture and storage of carbon dioxide produced by the combustion of biomass. Since biomass combustion is potentially carbon neutral, this technique could provide a method of reducing t...

Jenny M. Jones; Amanda R. Lea-Langton…

2014-01-01T23:59:59.000Z

202

Coal Characterization in Relation to Coal Combustion  

Science Journals Connector (OSTI)

Most coals are used worldwide for combustion today. Generally all kinds of coals are applicable for combustion. The major methods of burning are fixed bed firing, fluidized bed firing and suspension firing. Th...

Harald Jüntgen

1987-01-01T23:59:59.000Z

203

Practical Use of Coal Combustion Research  

Science Journals Connector (OSTI)

Laboratory measurements of coal rapid pyrolysis char yield and char reactivity, together with a simple model of pulverized coal combustion, have been used to predict coal combustion efficiency in utility boile...

P. T. Roberts; C. Morley

1987-01-01T23:59:59.000Z

204

Emissions and Heat Transfer in Combustion Systems  

Science Journals Connector (OSTI)

A variety of combustion systems that employ turbulent diffusion combustion have been major sources of air pollutants such as NOx, particulates and hydrocarbons in spite of their high thermal efficiency compare...

Y. Daisho

1993-01-01T23:59:59.000Z

205

Simulation of lean premixed turbulent combustion  

E-Print Network [OSTI]

combustion systems that can burn fuels such as hydrogen or syngas.syngas, which is obtained from coal gasi?cation. E?ective utilization of these fuels requires combustion

2008-01-01T23:59:59.000Z

206

Combustion of Solid Biomass: Classification of Fuels  

Science Journals Connector (OSTI)

The combustion of solid biomass and the classification of these fuels are considered. Firstly the different methods of combustion appliances and plants are outlined from a ... view. The forms and types of solid biomass

Jenny M. Jones; Amanda R. Lea-Langton…

2014-01-01T23:59:59.000Z

207

Volatile Organic Compounds — Emissions from Biomass Combustion  

Science Journals Connector (OSTI)

The emissions of Volatile Organic Compounds (VOC) from biomass combustion have been investigated. VOC contribute both to ... 0.5–10 MW. A variety of biomass fuel types and combustion equipment was covered. The su...

Lennart Gustavsson; Mats-Lennart Karlsson

1993-01-01T23:59:59.000Z

208

E-Print Network 3.0 - acid mono-2-ethylhexyl ester Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B. Magnetic properties a b s t r a c t FeVinyl ester... surfactant or coupling agent. Vinyl ester monomer serves as a coupling agent with one side covalently bound Source: Guo,...

209

E-Print Network 3.0 - acid dimethyl ester Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Properties of Higher Fatty Esters of Corn Starch Summary: fatty esters (C8C18) of potato starch and corn amylose using fatty acid chlorides and pyridine... exploratory...

210

Fuel Modification t Facilitate Future Combustion Regimes? | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Modification t Facilitate Future Combustion Regimes? Fuel Modification t Facilitate Future Combustion Regimes? 2005 Diesel Engine Emissions Reduction (DEER) Conference...

211

Electrophilic Metal Alkyl Chemistry in New Ligand Environments  

SciTech Connect (OSTI)

The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

Jordan, Richard F. [University of Chicago] University of Chicago

2013-06-30T23:59:59.000Z

212

Modeling of HCCI and PCCI Combustion Processes  

Broader source: Energy.gov (indexed) [DOE]

combustion timing control - Startup - Fuel air ratio measurement and control - Low Power Density - Hydrocarbon and CO emissions Approach: Fundamental and...

213

Oxy-combustion Boiler Material Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxy-combustion Boiler Material Oxy-combustion Boiler Material Development Background In an oxy-combustion system, combustion air (79 percent nitrogen, 21 percent oxygen) is replaced by oxygen and recycled flue gas (carbon dioxide [CO 2 ] and water), eliminating nitrogen in the flue gas stream. When applied to an existing boiler, the flue gas recirculation rate is adjusted to enable the boiler to maintain its original air-fired heat absorption performance, eliminating the need to derate the boiler

214

E-Print Network 3.0 - acid esters inhibit Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surfaces Summary: for catalysis or inhibition however. Recent studies with agrochemicals possessing carboxylic acid ester... . Keywords: Naptalam; amide hydrolysis; metal...

215

Polymer combustion: effects of flame emissivity  

Science Journals Connector (OSTI)

...gas phase. Polymer combustion chemistry is modelled...investigating polymer combustion it has proven advantageous...properties and treat the heat flux from the ignition...luminous flames from hydrocarbon fuels, it is common...A (1999) Polymer combustion: effects of flame emissivity...

1999-01-01T23:59:59.000Z

216

Fundamental Study of Single Biomass Particle Combustion  

E-Print Network [OSTI]

Fundamental Study of Single Biomass Particle Combustion Maryam Momeni #12;Fundamental Study of Single Biomass Particle Combustion Maryam Momeni Dissertation submitted to the Faculty of Engineering Fundamental Study of Single Biomass Particle Combustion This thesis is a comprehensive study of single biomass

Berning, Torsten

217

Evaluation of RME (rapeseed methyl ester) and mineral diesel fuels behaviour in quiescent vessel and EURO 5 engine  

Science Journals Connector (OSTI)

Abstract Alternative diesel fuels for internal combustion engines have grown significantly in interest in the last decade. This is due to the potential benefits in pollutant emissions and particulate matter reduction. Nevertheless at possible increase in nitrogen oxide (NOx), and almost certainly increase of fuel consumption have been observed. In this paper, mineral diesel and RME (rapeseed methyl ester) fuels have been characterized in a non-evaporative spray chamber and in an optically-accessible single-cylinder engine using a Common Rail injector (8 holes, 148° cone opening angle and 480 cc/30s@10 MPa flow number) to measure the spatial fuel distribution, the temporal evolution and the vaporization–combustion processes. The injection process and mixture formation have been investigated at the Urban Driving Cycle ECE R15: 1500 rpm at 0.2 MPa of break mean effective pressure. Characteristic parameters of the spray like penetration length and liquid fuel distribution have been analysed and they have been correlated with the exhaust gaseous and particulate matter emissions. In the spray-analysis in non-evaporative conditions, short events (pilot) are mostly affected by asymmetries in the fuel distributions with noticeable standard deviations at low injected quantities. In the engine tests, the jets reached immediately the stabilization. A comparative analysis on the liquid phase of the spray, in non-evaporative and evaporative conditions, has permitted to investigate better the mixture formation. Its effect on pollutant emissions has been analysed for both fuels.

Luigi Allocca; Ezio Mancaruso; Alessandro Montanaro; Luigi Sequino; Bianca Maria Vaglieco

2014-01-01T23:59:59.000Z

218

Cross-Couplings of Unactivated Secondary Alkyl Halides: Room-Temperature Nickel-Catalyzed Negishi Reactions of Alkyl Bromides and Iodides  

E-Print Network [OSTI]

-carbon bonds.1 To date, most studies of these processes have focused on forming Csp2-Csp2 (particularly biaryl-coupling catalysts for generating Csp3-Csp3 bonds.2 The availability of general methods for building the latter set to constructing Csp3-Csp3 bonds via metal- catalyzed cross-couplings of alkyl electrophiles with alkylmetals

Fu, Gregory C.

219

Method of combustion for dual fuel engine  

DOE Patents [OSTI]

Apparatus and a method of introducing a primary fuel, which may be a coal water slurry, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure. 19 figures.

Hsu, B.D.; Confer, G.L.; Zujing Shen; Hapeman, M.J.; Flynn, P.L.

1993-12-21T23:59:59.000Z

220

Method of combustion for dual fuel engine  

DOE Patents [OSTI]

Apparatus and a method of introducing a primary fuel, which may be a coal water slutty, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure.

Hsu, Bertrand D. (Erie, PA); Confer, Gregory L. (Erie, PA); Shen, Zujing (Erie, PA); Hapeman, Martin J. (Edinboro, PA); Flynn, Paul L. (Fairview, PA)

1993-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Modeling of Laser-Induced Metal Combustion  

SciTech Connect (OSTI)

Experiments involving the interaction of a high-power laser beam with metal targets demonstrate that combustion plays an important role. This process depends on reactions within an oxide layer, together with oxygenation and removal of this layer by the wind. We present an analytical model of laser-induced combustion. The model predicts the threshold for initiation of combustion, the growth of the combustion layer with time, and the threshold for self-supported combustion. Solutions are compared with detailed numerical modeling as benchmarked by laboratory experiments.

Boley, C D; Rubenchik, A M

2008-02-20T23:59:59.000Z

222

Measurement and simulation of swirling coal combustion  

Science Journals Connector (OSTI)

Particle image velocimetry (PIV), thermocouples and flue gas analyzer are used to study swirling coal combustion and NO formation under different secondary-air ratios. Eulerian–Lagrangian large-eddy simulation (LES) using the Smagorinsky–Lilly sub-grid scale stress model, presumed-PDF fast chemistry and eddy-break-up (EBU) gas combustion models, particle devolatilization and particle combustion models, are simultaneously used to simulate swirling coal combustion. Statistical LES results are validated by measurement results. Instantaneous LES results show that the coherent structures for swirling coal combustion are stronger than those for swirling gas combustion. Particles are shown to concentrate along the periphery of the coherent structures. Combustion flame is located in the high vorticity and high particle concentration zones. Measurement shows that secondary-air ratios have little effect on final NO formation at the exit of the combustor.

Liyuan Hu; Lixing Zhou; Yonghao Luo; Caisong Xu

2013-01-01T23:59:59.000Z

223

Combustion synthesis continuous flow reactor  

DOE Patents [OSTI]

The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

Maupin, Gary D. (Richland, WA); Chick, Lawrence A. (West Richland, WA); Kurosky, Randal P. (Maple Valley, WA)

1998-01-01T23:59:59.000Z

224

Homogeneous catalysts in hypersonic combustion  

SciTech Connect (OSTI)

Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

1989-01-01T23:59:59.000Z

225

Dose-dependent cytotoxic and mutagenic effects of antineoplastic alkylating agents on human lymphoblastoid cells  

SciTech Connect (OSTI)

The alkylating agents in clinical use as antineoplastics are strongly implicated as human carcinogens on the basis of animal studies and human epidemiologic studies. However, there is little quantitative information on the extent to which exposure to these drugs is mutagenic for normal (non-malignant) cells and the extent to which such mutagenicity correlates with cytotoxicity of these agents. Human lymphoblastoid cells (WIL2-NS) were exposed to graded doses of eight antineoplastic alkylating agents. Dose-dependent decreases in survival were used to calculate IC{sub 50}s for each of the drugs tested. The mutagenicity of these agents is correlated strongly with cytotoxicity. These results quantitate the dose-dependent cytotoxic and mutagenic effects of these bifunctional alkylating agents on human cells. All are cytotoxic and mutagenic, although their mutagenic efficiency varies.

Sanderson, B.J.S.; Johnson, K.J.; Henner, W.D. (Oregon Health Sciences Univ., Portland (United States))

1991-01-01T23:59:59.000Z

226

Phosphate ester inhibitors solve naphthenic acid corrosion problems  

SciTech Connect (OSTI)

Crude oils containing naphthenic acids can cause a variety of corrosion problems in any of several process areas. But because of the complexity of naphthenic acid corrosion, no routine technique is available for predicting corrosion from this source. Certain high-temperature corrosion inhibitors with a general phosphate ester structure have shown good mitigation of naphthenic acid corrosion in commercial applications. A description of two such cases will help refiners know what to look for to prevent similar occurrences in their plants.

Babaian-Kibala, E. (Nalco Chemical Co., Sugar Land, TX (United States))

1994-02-28T23:59:59.000Z

227

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels  

Science Journals Connector (OSTI)

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels ... Results derived from soybean oil, jatropha oil, and tung oil show that certain biofuel fractions met JP-8 specifications and Navy distillate specifications. ... Therefore, tung-oil-derived CH biofuel will have added value as a blend stock for existing FT jet fuels and emerging biofuels such as those produced from the UOP/ENI EcofiningTM process to meet fuel specifications by increasing density and aromatic content. ...

Lixiong Li; Edward Coppola; Jeffrey Rine; Jonathan L. Miller; Devin Walker

2010-01-13T23:59:59.000Z

228

Adsorption studies of phthalic acid esters in aqueous solutions  

E-Print Network [OSTI]

they are produced in large quantities and are frequently found in environmental samples. Montmorillonite, kaolinite, Ca-montmorillonite, calcite, and a sediment sample were used as representative marine particulates. Both phthalic acid esters were adsorbed onto... and desorbed from the solid adsorbents and the glass test tubes used in the adsorption experiments . A study of the kinetics of phthal ate adsorption showed that equilibrium was attained after 12 hours. At equilibrium, the amount of phthalate bound to a...

Sullivan, Kevin Francis

2012-06-07T23:59:59.000Z

229

Syntheses of 11 F-labeled carboxylic esters within a  

E-Print Network [OSTI]

and with reduced infusion rate. Radioactive methyl ester 4b was obtained from the reaction of 1 (10 mM) with 2b in 56% decay-corrected radiochemical yield (RCY) at an infusion rate of 10 mL min21 , and when the infusion rate was reduced to 1 mL min21 , the RCY increased to 88%. The synthesis of the non

Shen, Jun

230

Sorption of Phthalate Esters and PCBs in a Marine Ecosystem  

E-Print Network [OSTI]

Sorption of Phthalate Esters and PCBs in a Marine Ecosystem C H E R Y L E . M A C K I N T O S H to particulate matter in aquatic environments. Sorption plays a key role in controlling the long-term fate of the sorption of many commercial DPEs do not exist. To characterize the sorptive nature of DPEs in a real

Gobas, Frank

231

Characteristics of biomass in flameless combustion: A review  

Science Journals Connector (OSTI)

Abstract The demands of energy and pollutant emissions reduction have motivated the combustion researchers to work on combustion improvement. Flameless combustion or high temperature air combustion has many features such as flame stability, low pollutant emission and uniform profiles of temperature compared to the other modes of combustion. Combustion of solid fuels likes biomass and wastes in flameless combustion conditions has not been investigated as comprehensive as combustion of gaseous fuels. The aim of using biomass in combustion is to reduce the pollutant emissions and to decrease the rate of fossil fuel consumption. In this review, combustion characteristics of biomass in flameless combustion are explained. The paper summarizes the research on the mass loss, ignition time, and \\{NOx\\} emissions during biomass flameless combustion. These summaries show that biomass under flameless combustion gives low pollutant emissions, low mass loss and it decreases the ignition time.

A.A.A. Abuelnuor; M.A. Wahid; Seyed Ehsan Hosseini; A. Saat; Khalid M. Saqr; Hani H. Sait; M. Osman

2014-01-01T23:59:59.000Z

232

Sandia Combustion Research Program: Annual report, 1986  

SciTech Connect (OSTI)

This report presents research results of the past year, divided thematically into some ten categories. Publications and presentations arising from this work are included in the appendix. Our highlighted accomplishment of the year is the announcement of the discovery and demonstration of the RAPRENOx process. This new mechanism for the elimination of nitrogen oxides from essentially all kinds of combustion exhausts shows promise for commercialization, and may eventually make a significant contribution to our nation's ability to control smog and acid rain. The sections of this volume describe the facility's laser and computer system, laser diagnostics of flames, combustion chemistry, reacting flows, liquid and solid propellant combustion, mathematical models of combustion, high-temperature material interfaces, studies of engine/furnace combustion, coal combustion, and the means of encouraging technology transfer. 182 refs., 170 figs., 12 tabs.

Not Available

1986-01-01T23:59:59.000Z

233

Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary Structure, and Self-Assembly of Fractalkine  

E-Print Network [OSTI]

Effect of Polyethylene Glycol, Alkyl, and Oligonucleotide Spacers on the Binding, Secondary-amphiphiles with no spacer (NoSPR), polyethylene glycol (PEG4, PEG8, PEG24), alkyl (C12 and C24), or oligonucleotide (T10 a polyethylene glycol (PEG) or an oligo-T (thymine) spacer is added to the aptamer, especially when attaching

Kokkoli, Efie

234

NETL: IEP – Post-Combustion CO2 Emissions Control - Oxy-Combustion Boiler  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxy-Combustion Boiler Material Development Oxy-Combustion Boiler Material Development Project No.: DE-NT0005262 CLICK ON IMAGE TO ENLARGE Foster Wheeler Oxy-combustion CFD Graphic The objectives of this Foster Wheeler Corporation-managed program are to assess the corrosion characteristics of oxy-combustion relative to air-fired combustion; identify the corrosion mechanisms involved; and determine the effects of oxy-combustion on conventional boiler tube materials, conventional protective coatings, and alternative materials and coatings when operating with high to low sulfur coals. The program involves the prediction of oxy-combustion gas compositions by computational fluid dynamic calculations, exposure of coupons of boiler materials and coverings coated with coal ash deposit to simulated oxy-combustion gases in electric

235

A fundamental study of biomass oxy-fuel combustion and co-combustion.  

E-Print Network [OSTI]

??While oxy-fuel combustion research is developing and large scale projects are proceeding, little information is available on oxy-biomass combustion and cocombustion with coal. To address… (more)

Farrow, Timipere Salome

2013-01-01T23:59:59.000Z

236

Estimating heat of combustion for waste materials  

SciTech Connect (OSTI)

Describes a method of estimating the heat of combustion of hydrocarbon waste (containing S,N,Q,C1) in various physical forms (vapor, liquid, solid, or mixtures) when the composition of the waste stream is known or can be estimated. Presents an equation for predicting the heat of combustion of hydrocarbons containing some sulfur. Shows how the method is convenient for estimating the heat of combustion of a waste profile as shown in a sample calculation.

Chang, Y.C.

1982-11-01T23:59:59.000Z

237

Supersonic combustion studies using a multivariate quadrature based method for combustion modeling  

E-Print Network [OSTI]

of predictive models for supersonic combustion is a critical step in design and development of scramjet engines

Raman, Venkat

238

Researchers create successful predictions of combustion reaction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemical reactions that take place during the combustion process, said Sandia's Ahren Jasper, the study's lead author. As they determine and understand the speeds and outcomes of...

239

combustion index | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in electricity cost. Advanced Combustion Research Overview Experience with steam boilers has provided information on existing boiler alloys, but limited data is available at...

240

Optimization of Advanced Diesel Engine Combustion Strategies  

Broader source: Energy.gov (indexed) [DOE]

B, extending combustion duration Location B with dummy plug installed Location A with optics installed fiber to FTIR common rail injector common rail fuel spray Location B with...

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Chemical Kinetic Models for Advanced Engine Combustion  

Broader source: Energy.gov (indexed) [DOE]

barriers to increased engine efficiency and decreased emissions by allowing optimization of fuels with advanced engine combustion 6 LLNL-PRES-652979 2014 DOE Merit Review...

242

Oxygen-Enriched Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING...

243

Vehicle Technologies Office: Advanced Combustion Strategies ...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

element of LTC - is achieved by controlling the timing of the autoignition and rate of heat release. This process works to eliminate excessive combustion rates that can cause...

244

Advanced Combustion Concepts - Enabling Systems and Solutions...  

Broader source: Energy.gov (indexed) [DOE]

Fuel efficiency as key market driver Stringent emission requirements System cost of advanced combustion Targets 30% fuel efficiency improvement SULEV emissions...

245

Laser in situ monitoring of combustion processes  

Science Journals Connector (OSTI)

Several examples of laser in situ monitoring of combustion processes are presented. Using a frequency modulated 13CO2 waveguide laser, in situ concentrations of...

Arnold, A; Becker, H; Hemberger, R; Hentschel, W; Ketterle, W; Kollner, M; Meienburg, W; Monkhouse, P; Neckel, H; Schafer, M; Schindler, K P; Sick, V; Suntz, R; Wolfrum, J

1990-01-01T23:59:59.000Z

246

Supersonic Jet Sampling for Combustion Diagnostics  

Science Journals Connector (OSTI)

The purpose of this note is to describe a novel application of supersonic molecular beam spectrometry to the study of combustion processes in piston engines. In this technique,...

Whitten, W B

1986-01-01T23:59:59.000Z

247

Advanced Control Methodology for Biomass Combustion.  

E-Print Network [OSTI]

??This thesis presents a feasibility study for a low cost sensor-based combustion control system using a predictive chemical kinetic model that captures efficiencies and pollution… (more)

Bjornsson, Stefan

2014-01-01T23:59:59.000Z

248

Partially Premixed Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

that enables PPC to reach the market deer11andersson.pdf More Documents & Publications Combustion Model for Engine Concept Development Path to High Efficiency Gasoline Engine...

249

Research Teams - Combustion Energy Frontier Research Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research Teams Research Teams Associates Greg Smith, Senior Research Chemist, SRI International Jeffrey A. Sutton, Assistant Professor, Ohio State Univeristy Combustion Energy...

250

Chemistry and Transport - Combustion Energy Frontier Research...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry and Transport Chemistry and Transport The overall goal of the flame chemistry working group is to obtain fundamental combustion and emission properties of low and high...

251

Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...  

Broader source: Energy.gov (indexed) [DOE]

Combustion, and Emission Modeling Using KH-ACT Primary Breakup Model & Detailed Chemistry Sibendu Som, Douglas E. Longman Engine and Emissions Group (Energy Systems Division)...

252

Chemistry: Mechanism and Experiment - Combustion Energy Frontier...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry: Mechanism and Experiment Chemistry: Mechanism and Experiment The Mechanism and Experiment DWG uses an array of advanced experimental apparatus to probe the combustion...

253

A determination of the heats of combustion of the five-carbon fatty acids and their methyl and ethyl esters  

E-Print Network [OSTI]

'srr Ins~ Ce?c ~c Dl? 30? Tbe bstwLs sodAL 1Need wss ohtwixlsd frccc ths Q?S? Wool? Bar? of ghsnclalPds? Tbs hest ef ~tdocc wss giwRl se g6?QQ shs? kja/g? cocos (weighed in wceccs) er QLg eaL/g? essa (in @sees)? 3 oslorie? 0?wg$840 sbs, +? 'ei ~ r...LLd bs ~aied fer tbs fi~carhc?L aCCLds?ad the baste of vaoorisat4os of tbs ether Lsaee4e ac@de ae4hsated a4 their ~g, xdn4s The bs?te of vsyorhwQ. oe o' ths sands a4 2~ C? wars estiaated ly a?S~ 4R? k", ~? ~4lcsi55, ccsd '~ ~ . -? AIL' %7? Q? ~ +sad...

Gilby, Ralph F

2012-06-07T23:59:59.000Z

254

Investigation of the effects of renewable diesel fuels on engine performance, combustion, and emissions  

Science Journals Connector (OSTI)

Abstract A study was undertaken to investigate renewable fuels in a compression-ignition internal combustion engine. The focus of this study was the effect of newly developed renewable fuels on engine performance, combustion, and emissions. Eight fuels were investigated, and they include diesel, jet fuel, a traditional biodiesel (fatty acid methyl ester: FAME), and five next generation biofuels. These five fuels were derived using a two-step process: hydrolysis of the oil into fatty acids (if necessary) and then a thermo-catalytic process to remove the oxygen via a decarboxylation reaction. The fuels included a fed batch deoxygenation of canola derived fatty acids (DCFA), a fed batch deoxygenation of canola derived fatty acids with varying amounts of H2 used during the deoxygenation process (DCFAH), a continuous deoxygenation of canola derived fatty acids (CDCFA), fed batch deoxygenation of lauric acid (DLA), and a third reaction to isomerize the products of the deoxygenated canola derived fatty acid alkanes (IPCF). Diesel, jet fuel, and biodiesel (FAME) have been used as benchmarks for comparing with the newer renewable fuels. The results of the experiments show slightly lower mechanical efficiency but better brake specific fuel consumption for the new renewable fuels. Results from combustion show shorter ignition delays for most of the renewable (deoxygenated) fuels with the exception of fed batch deoxygenation of lauric acid. Combustion results also show lower peak in-cylinder pressures, reduced rate of increase in cylinder pressure, and lower heat release rates for the renewable fuels. Emission results show an increase in hydrocarbon emissions for renewable deoxygenated fuels, but a general decrease in all other emissions including NOx, greenhouse gases, and soot. Results also demonstrate that isomers of the alkanes resulting from the deoxygenation of the canola derived fatty acids could be a potential replacement to conventional fossil diesel and biodiesel based on the experiments in this work.

Dolanimi Ogunkoya; William L. Roberts; Tiegang Fang; Nirajan Thapaliya

2015-01-01T23:59:59.000Z

255

Theoretical studies of combustion dynamics  

SciTech Connect (OSTI)

The basic objectives of this research program are to develop and apply theoretical techniques to fundamental dynamical processes of importance in gas-phase combustion. There are two major areas currently supported by this grant. One is reactive scattering of diatom-diatom systems, and the other is the dynamics of complex formation and decay based on L{sup 2} methods. In all of these studies, the authors focus on systems that are of interest experimentally, and for which potential energy surfaces based, at least in part, on ab initio calculations are available.

Bowman, J.M. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

256

Circulating fluidised-bed combustion  

SciTech Connect (OSTI)

Steam generators with circulating fluidized-bed combustion systems (CFBC) are characterized by a high degree of environmental comparability and a wide acceptance for FBC boiler plants involving a wide fuel spectrum which ranges from dried brown coal to high-ash coal and low-volatile bituminous coal as well as wood waste and bark. These plants incorporate a variety of CFBC systems. The choice in favor of different system options was not motivated by the inherent fuel properties but has evolved from the progressive advancement in power station FBC technology. The article elucidates several FBC system variants.

Rettemeier, W.; von der Kammer, G. (Steinmueller (L.u.C.) GmbH, Gummersbach (Germany, F.R.))

1990-01-01T23:59:59.000Z

257

Chemical looping combustion of coal in interconnected fluidized beds  

Science Journals Connector (OSTI)

Chemical looping combustion is the indirect combustion by use of oxygen carrier. It can...2...capture in power generating processes. In this paper, chemical looping combustion of coal in interconnected fluidized ...

LaiHong Shen; Min Zheng; Jun Xiao; Hui Zhang…

2007-04-01T23:59:59.000Z

258

Fuel reforming for scramjet thermal management and combustion optimization  

E-Print Network [OSTI]

Fuel reforming for scramjet thermal management and combustion optimization E. DANIAU* , M. BOUCHEZ in a Scramjet combustion chamber. Another critical point is that mixing and combustion should be sufficiently

Paris-Sud XI, Université de

259

Gas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield  

E-Print Network [OSTI]

total AN (gas + aerosol) and ANaer show that on average 21% of ANs are in the condensed phaseGas/particle partitioning of total alkyl nitrates observed with TD-LIF in Bakersfield A. W. Rollins samples. These measurements show that ANs are a ubiquitous component of the OA with the ­ONO2 subunit

Cohen, Ronald C.

260

Serendipitous alkylation of a Plk1 ligand uncovers a new binding channel  

E-Print Network [OSTI]

We obtained unanticipated synthetic byproducts from alkylation of the ?[superscript 1] nitrogen (N3) of the histidine imidazole ring of the polo-like kinase-1 (Plk1) polo-box domain (PBD)-binding peptide PLHSpT. For the ...

Lim, Dan

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids  

DOE Patents [OSTI]

A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

Miller, P.S.; Ts'o, P.O.P.

1999-06-15T23:59:59.000Z

262

Whitesides et al. f Reaction ctfAlkyl Halides with Magnesiunt Mechanismof Formationof GrignardReagents.  

E-Print Network [OSTI]

carbanionsand carbonium ionsare not intermediates,and tliat the transition-itut. structuredoesnot resemblean SN2.rnagncsiumatom at the mctal surface(or possibly in solution) rrrrghtdisplacehelidefrotncarbonin an SN2-likc rcuctionor inrcrlWhitesides et al. f Reaction ctfAlkyl Halides with Magnesiunt Mechanismof Formationof Grignard

Prentiss, Mara

263

Esters of propane-1,3-diboric and propane-1,3-dithioboric acids  

Science Journals Connector (OSTI)

The polymer formed by hydroborating boron-trialkyl reacts with methyl borate, giving the tetramethyl ester of propane-1,3-diboric acid.

B. M. Mikhailov; V. F. Pozdnev

1962-10-01T23:59:59.000Z

264

E-Print Network 3.0 - acid diethyl ester Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University Collection: Chemistry 98 RAFT Polymerization of a Novel Activated Ester Monomer and Conversion to a Terpyridine-Containing Homopolymer Summary: -succinimide...

265

E-Print Network 3.0 - antiproliferative cephalotaxus esters Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

JP, Perchellet EM. Phorbol ester tumor promoters and multistage skin carcinogenesis. ISI Atlas... . Perchellet EM, Gali HU, Gao XM, Perchellet JP. Ability of the nonphorbol...

266

E-Print Network 3.0 - activated ester terminated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Developmental Biology, University of Michigan Collection: Biology and Medicine 39 Synthesis of Higher Fatty Acid Starch Esters using Vinyl Laurate and Stearate as Reactants...

267

Internal combustion engine intake valve  

SciTech Connect (OSTI)

In a inlet valve for use in an internal combustion engine in which the valve has a stem and a head, the head having, when seated, a first side positioned within a combustion chamber of an engine block and a second, opposite, side attached to the stem, the second side including that piston of the head forming the seat with the engine block when the valve is in a seated position, and first side including that portion of the head from the seat toward the chamber when the valve is in the seated position, and the engine including means for moving the valve from the closed position to an open position to allow a fuel mixture to enter the chamber, the improvement in the valve comprising: an extension ridge from the first side, positioned in alignment with the periphery of the valve head, the ridge forming with the seat a single, continuous, smooth outer surface along the periphery thereof for reducing the coefficient of drag of the fuel entering the chamber around the valve head when the valve is in the open position.

Mosler, W.B.

1988-10-25T23:59:59.000Z

268

Method and system for controlled combustion engines  

DOE Patents [OSTI]

A system for controlling combustion in internal combustion engines of both the Diesel or Otto type, which relies on establishing fluid dynamic conditions and structures wherein fuel and air are entrained, mixed and caused to be ignited in the interior of a multiplicity of eddies, and where these structures are caused to sequentially fill the headspace of the cylinders.

Oppenheim, A. K. (Berkeley, CA)

1990-01-01T23:59:59.000Z

269

The Cool Flame Combustion of Ethanol  

Science Journals Connector (OSTI)

...research-article The Cool Flame Combustion of Ethanol J. Brown C. F. H. Tipper The kinetics...products of the cool flame combustion of ethanol between about 280 and 330 C have been...much less for a 1 : 2 than for a 1 : 1 ethanol/oxygen mixture at constant T and varied...

1969-01-01T23:59:59.000Z

270

Numerical modelling of MILD combustion for coal  

Science Journals Connector (OSTI)

Emissions of nitrogen oxides from coal combustion are a major environmental problem because they have been shown to contribute to the formation of acid rain and photochemical smog. Moderate and Intensive Low oxygen Dilution (MILD) combustion is a promising technology for decreasing pollutant emissions and improving combustion efficiency. A combination of air preheating and fuel dilution with combustion products of low oxygen concentration are the main features of this technique. In the MILD combustion mode, preheated air and fuel are gradually mixed with large amounts of recirculated exhaust gas. The objective of the present work is to investigate the capability of present fuel NO mechanisms for pulverised coal combustion to predict the observed nitrogen oxide levels in MILD combustion mode. For this purpose, knowledge of the fate of coal nitrogen during the combustion process is vital. The interaction between turbulence and chemistry is modelled by an advanced Eddy Dissipation Concept (EDC). The NOx model is used to predict NO profiles that are compared to measurements obtained from semi-industrial scale experiments.

Ju Pyo Kim; U. Schnell; G. Scheffknecht; A.C. Benim

2007-01-01T23:59:59.000Z

271

Redeeming features of in situ combustion  

SciTech Connect (OSTI)

In situ combustion remains the most tantalizing enhanced oil recovery method. It has been tested extensively - in over 150 field tests - in both heavy and light oil reservoirs. What we have learned from this experience is that in situ combustion works under most conditions, but the nature of the problems is such that it is seldom profitable. Also, looking at many previous in situ combustion tests, steam injection, and even waterflooding, would have been a better choice. Yet in situ combustion has unique features not found in any other EOR method. These must be weighed against its shortcomings to evaluate a potential application. This paper discusses the redeeming features of in situ combustion, in particular the reservoir conditions under which in situ combustion may be superior to other EOR methods are outlined. All variations of in situ combustion - forward, reverse, wet, dry - as well as combinations with other EOR methods are considered. The conclusions is that in situ combustion still has a place, and its future application would depend on research on certain crucial aspects of the process.

Farouq Ali, S.M. [Univ. of Alberta, Edmonton (Canada)

1995-02-01T23:59:59.000Z

272

NETL- High-Pressure Combustion Research Facility  

SciTech Connect (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2013-07-08T23:59:59.000Z

273

Generating Resources Combined Cycle Combustion Turbine  

E-Print Network [OSTI]

turbine (s) Heat recovery steam generator (s) - HRSG with or without duct firing Natural gas supply11/17/2014 1 Generating Resources Combined Cycle Combustion Turbine Utility Scale Solar PV Steven doing recently around two key supply-side resource technologies 1. Combined Cycle Combustion Turbine

274

Coal slurry combustion and technology. Volume 2  

SciTech Connect (OSTI)

Volume II contains papers presented at the following sessions of the Coal Slurry Combustion and Technology Symposium: (1) bench-scale testing; (2) pilot testing; (3) combustion; and (4) rheology and characterization. Thirty-three papers have been processed for inclusion in the Energy Data Base. (ATT)

Not Available

1983-01-01T23:59:59.000Z

275

NETL- High-Pressure Combustion Research Facility  

ScienceCinema (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2014-06-26T23:59:59.000Z

276

Pulse Combustion Characteristics of Various Gaseous Fuels  

Science Journals Connector (OSTI)

Pulse combustion performance of fuels with low and high heating values is also compared. ... Selected gaseous fuels such as low molecular weight hydrocarbons, high molecular weight hydrocarbons, biofuels, and mixed fuels are tested for pulse combustion, and their operational properties are presented and compared. ... Heat transfer data for several exptl. ...

Wu Zhonghua; Arun S. Mujumdar

2008-02-06T23:59:59.000Z

277

Combustion Modeling for Diesel Engine Control Design  

E-Print Network [OSTI]

Combustion Modeling for Diesel Engine Control Design Von der Fakult¨at f¨ur Maschinenwesen der Combustion Modeling for Diesel Engine Control Design WICHTIG: D 82 überprüfen !!! #12;Bibliographic research stays at General Motors R&D in Warren, MI, USA, possible. Furthermore, I would like thank Tom

Peters, Norbert

278

Boiler Combustion Control and Monitoring System  

Broader source: Energy.gov [DOE]

Efficiency of existing boilers can be improved in three ways; replacement with new boilers, replacement of the burner, or installation of a combustion control system. While installation of a new boiler or replacement of the burner can lead to the greatest efficiency gains, the higher costs associated with these measures typically leads to longer payback periods than combustion control systems.

279

Collaborative Combustion Research with BES | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Research with BES Collaborative Combustion Research with BES 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

280

Overview of Sonex Combustion Systems (SCS) for DI Engines | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Sonex Combustion Systems (SCS) for DI Engines Overview of Sonex Combustion Systems (SCS) for DI Engines The SCS system has undergone computational and experimental verification and...

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Sandia National Laboratories: Low--Temperature Combustion Enables...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ECFacilitiesCRFLow--Temperature Combustion Enables Cleaner, More Efficient Engines Low--Temperature Combustion Enables Cleaner, More Efficient Engines Assessing the Economic...

282

Evaluation of High Efficiency Clean Combustion (HECC) Strategies...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion (HECC) Strategies for Meeting Future Emissions Regulations in Light-Duty Engines Evaluation of High Efficiency Clean Combustion (HECC) Strategies for Meeting Future...

283

2008 DOE Annual Merit Review Advanced Combustion Engines and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advanced Combustion Engines and Fuels R&DTechnology Integration Plenary Session Overview 2008 DOE Annual Merit Review Advanced Combustion Engines and Fuels R&DTechnology...

284

High-Efficiency Clean Combustion Design for Compression Ignition...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Efficiency Clean Combustion Design for Compression Ignition Engines High-Efficiency Clean Combustion Design for Compression Ignition Engines Presentation given at DEER 2006,...

285

Complete Fuel Combustion for Diesel Engines Resulting in Greatly...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Complete Fuel Combustion for Diesel Engines Resulting in Greatly Reduced Emissions and Improved Fuel Efficiency Complete Fuel Combustion for Diesel Engines Resulting in Greatly...

286

Syngas Enhanced High Efficiency Low Temperature Combustion for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

287

Non-Petroleum-Based Fuel Effects on Advanced Combustion | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Non-Petroleum-Based Fuel Effects on Advanced Combustion Non-Petroleum-Based Fuel Effects on Advanced Combustion 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit...

288

Catalyst for Improving the Combustion Efficiency of Petroleum...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines Catalyst for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines 2005 Diesel...

289

World's Largest Post-Combustion Carbon Capture Project Begins...  

Broader source: Energy.gov (indexed) [DOE]

World's Largest Post-Combustion Carbon Capture Project Begins Construction World's Largest Post-Combustion Carbon Capture Project Begins Construction July 15, 2014 - 9:55am Addthis...

290

The Role of Advanced Combustion in Improving Thermal Efficiency  

Broader source: Energy.gov [DOE]

Combustion plays an important role in enabling high thermal efficiencies. Technologies that deliver short combustion duration and low soot emissions are needed.

291

Low-Temperature Diesel Combustion Cross-Cut Research | Department...  

Broader source: Energy.gov (indexed) [DOE]

Low-Temperature Diesel Combustion A Conceptual Model for Partially PremixedLow-Temperature Diesel Combustion Based onIn-Cylinder Laser Diagnostics and Chemical Kinetics Modeling...

292

Enabling High Efficiency Clean Combustion with Micro-Variable...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of variable orifice fuel injector are described that will extend the operation maps of early PCCI combustion and enable dual-mode combustion over full operating maps....

293

Low-Temperature Diesel Combustion Cross-Cut Research | Department...  

Broader source: Energy.gov (indexed) [DOE]

Low-Temperature Diesel Combustion Cross-Cut Research Low-Temperature Diesel Combustion Cross-Cut Research 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review...

294

Development of Fuel-Flexible Combustion Systems Utilizing Opportunity...  

Office of Environmental Management (EM)

Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines - Fact Sheet, May 2014 Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in...

295

Oscillatory Flame Response in Acoustically Coupled Fuel Droplet Combustion  

E-Print Network [OSTI]

and volumetric heats of combustion in biofuels render themVaporization [kJ/kg] Heat of Combustion [kJ/kg] †Estimated

Sevilla Esparza, Cristhian Israel

2013-01-01T23:59:59.000Z

296

2014 Annual Merit Review Results Report - Advanced Combustion...  

Energy Savers [EERE]

Advanced Combustion Engine Technologies 2014 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research...

297

Advanced Combustion Technology to Enable High Efficiency Clean...  

Broader source: Energy.gov (indexed) [DOE]

Combustion System + Air Handling Air Handling + Sensors + Calibration Low P, High Flow Rate EGR + VVA - Simulated Robustness Advanced Combustion Concepts - Simulated 0.0...

298

2.61 Internal Combustion Engines, Spring 2004  

E-Print Network [OSTI]

Fundamentals of how the design and operation of internal combustion engines affect their performance, operation, fuel requirements, and environmental impact. Study of fluid flow, thermodynamics, combustion, heat transfer ...

Heywood, John B.

299

Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines  

Broader source: Energy.gov [DOE]

Document:  ace012_flowers_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Dan FlowersPresenting Organization: Lawrence Livermore National Laboratory (LLNL...

300

Haraldrud Municipal Solid Waste Combustion Plant in Oslo.  

E-Print Network [OSTI]

??This thesis has studied Haraldrud MSW combustion process. Haraldrud is a realcombustion plant burning waste for citizens of Oslo. A thoroughly description ofthe combustion process… (more)

Gudim, Simen Johan

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Combustion Turbine CHP System for Food Processing Industry -...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Turbine CHP System for Food Processing Industry - Presentation by Frito-Lay North America, June 2011 Combustion Turbine CHP System for Food Processing Industry -...

302

Oxygen-Enriched Combustion for Military Diesel Engine Generators...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak...

303

Modeling Combustion Control for High Power Diesel Mode Switching...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Control for High Power Diesel Mode Switching Modeling Combustion Control for High Power Diesel Mode Switching Poster presentation given at the 16th Directions in...

304

High Efficiency Clean Combustion for Heavy-Duty Engine  

Broader source: Energy.gov [DOE]

Explore advancements in engine combustion systems using high-efficiency clean combustion (HECC) techniques to minimize engine-out emissions while optimizing fuel economy.

305

Low Temperature Combustion and Diesel Emission Reduction Research...  

Broader source: Energy.gov (indexed) [DOE]

Low Temperature Combustion and Diesel Emission Reduction Research Low Temperature Combustion and Diesel Emission Reduction Research Presentation given at DEER 2006, August 20-24,...

306

Dilute Clean Diesel Combustion Achieves Low Emissions and High...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High...

307

Unregulated Emissions from High-Efficiency Clean Combustion Modes...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Poster presentation at...

308

Low-Temperature Automotive Diesel Combustion | Department of...  

Energy Savers [EERE]

Diesel Combustion Low-Temperature Automotive Diesel Combustion 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

309

State Grid Biomass Fuel and Combustion Technology Laboratory...  

Open Energy Info (EERE)

Combustion Technology Laboratory Jump to: navigation, search Name: State Grid Biomass Fuel and Combustion Technology Laboratory Place: Beijing Municipality, China Sector: Biomass...

310

Fuel Effects on Ignition and Their Impact on Advanced Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ignition and Their Impact on Advanced Combustion Engines Fuel Effects on Ignition and Their Impact on Advanced Combustion Engines Presentation given at DEER 2006, August 20-24,...

311

Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines...  

Broader source: Energy.gov (indexed) [DOE]

Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Combustion Exhaust Gas Heat to Power Using Thermoelectric Engines Discusses a novel TEG which utilizes a...

312

Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel...  

Broader source: Energy.gov (indexed) [DOE]

Assisted Diesel Combustion in a Common Rail Turbodiesel Engine P-3 Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine P-3 Gregory Lilik, Jos Martn...

313

Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Assisted Diesel Combustion in a Common Rail Turbodiesel Engine Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine This study measured the effects of hydrogen...

314

Heavy-Duty Low Temperature Combustion Development Activities...  

Broader source: Energy.gov (indexed) [DOE]

soot emissions - Cylinder pressure and rise rate limits - Low load combustion stabilityignition Robust combustion control - Cylinder-to-cylinder variability - Ambient...

315

2011 2nd Annual CEFRC Conference - Combustion Energy Frontier...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemistry and diagnostics (HansenYang) Chemical kinetics and transport of combustion processes (Wang) H2O number density measurements in an RCM and plasma combustion using...

316

Modeling of High Efficiency Clean Combustion Engines | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

merit08flowers.pdf More Documents & Publications Modeling of HCCI and PCCI Combustion Processes Numerical Modeling of HCCI Combustion Improving alternative fuel utilization:...

317

Modeling of HCCI and PCCI Combustion Processes | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

HCCI and PCCI Combustion Processes Modeling of HCCI and PCCI Combustion Processes 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters...

318

Factors Affecting HCCI Combustion Phasing for Fuels with Single...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004...

319

CFD Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry  

Broader source: Energy.gov [DOE]

A method is presented that allows for efficient conditional moment closure combustion simulations through the use of a progress variable based parameterization of the combustion chemistry.

320

CFD Combustion Modeling with Conditional Moment Closure using...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry CFD Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry A method is...

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Accurate Predictions of Fuel Effects on Combustion and Emissions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using...

322

Numerical Modeling of PCCI Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Modeling of HCCI and PCCI Combustion Processes Numerical Modeling of HCCI Combustion Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines...

323

Fuel Effects on Advanced Combustion Engines | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research Greenpower Trap Mufflerl System Low-Temperature Diesel Combustion...

324

High Efficiency Clean Combustion Engine Designs for Gasoline...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines High Efficiency Clean Combustion Engine Designs for Gasoline and Diesel Engines 2009 DOE Hydrogen...

325

Light-Duty Diesel Combustion | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Light-Duty Diesel Combustion Light-Duty Diesel Combustion 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting...

326

Light Duty Efficient Clean Combustion | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Light Duty Efficient Clean Combustion Light Duty Efficient Clean Combustion 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

327

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

328

Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle  

DOE Patents [OSTI]

A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

2013-12-17T23:59:59.000Z

329
330

Oxy-coal Combustion Studies  

SciTech Connect (OSTI)

The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?˘ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?˘ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?˘ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?˘ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?˘ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?˘ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

2012-01-01T23:59:59.000Z

331

Argonne TTRDC - Engines - Combustion Visualization - emissions,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Visualization Combustion Visualization Exploring Combustion Using Advanced Imaging Techniques In the photo, the GM diesel test cell is shown with vehicle exhaust aftertreatment hardware (diesel particulate filtration and diesel oxidation catalyst) along with other advanced technology-such as a variable geometry turbocharger, cooled exhaust gas recirculation and a common-rail fuel injection system. Fig. 1. The GM diesel test cell is shown with vehicle exhaust aftertreatment hardware (diesel particulate filtration and diesel oxidation catalyst) along with other advanced technology-such as a variable geometry turbocharger, cooled exhaust gas recirculation and a common-rail fuel injection system. Two-dimensional image of hydrogen combustion OH chemiluminescence. Fig. 2. Two-dimensional image of hydrogen combustion OH chemiluminescence.

332

Fine Particle Emissions from Combustion Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fine Particle Emissions from Combustion Systems Fine Particle Emissions from Combustion Systems Speaker(s): Allen Robinson Date: November 11, 2005 - 12:00pm Location: 90-3122 Combustion systems such as motor vehicles and power plants are major sources of fine particulate matter. This talk describes some of the changes in fine particle emissions that occur as exhaust from combustion systems mix with background air. This mixing cools and dilutes the exhaust which influences gas-particle partitioning of semi-volatile species, the aerosol size distribution, and the fine particle mass. Dilution sampling is used to characterize fine particle emissions from combustion systems because it simulates the rapid cooling and dilution that occur as exhaust mixes with the atmosphere. Results from dilution sampler

333

Advanced Combustion Technologies | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Science & Innovation » Clean Coal » Advanced Combustion Science & Innovation » Clean Coal » Advanced Combustion Technologies Advanced Combustion Technologies Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant emissions in advanced power cycles using gas turbines. Photo courtesy of NETL Multimedia. Joe Yip, a researcher at FE's National Energy Technology Laboratory, uses laser-based Rayleigh light scattering to measure flame density and speed over a flat flame burner. Oxyfuel combustion, using oxygen in place of air with diluents such as steam or carbon dioxide, can reduce pollutant

334

Development of a Sustainable Catalytic Ester Amidation Process  

Science Journals Connector (OSTI)

Development of a Sustainable Catalytic Ester Amidation Process ... In this paper, and as part of our ongoing interests in the advancement and uptake of green synthesis in a discovery chemistry setting,(17-19) we report our efforts to develop a significantly more sustainable process and demonstrate its applicability to the synthesis of a range of lead-like substrates. ... Overall, consideration of the isolated yields obtained with this new and sustainable coupling protocol indicates that the current method is an extremely viable alternative compared to the previously developed approach. ...

Nicola Caldwell; Craig Jamieson; Iain Simpson; Allan J. B. Watson

2013-07-30T23:59:59.000Z

335

Axial cylinder internal combustion engine  

SciTech Connect (OSTI)

This patent describes improvement in a barrel type internal combustion engine including an engine block having axial-positioned cylinders with reciprocating pistons arranged in a circular pattern: a drive shaft concentrically positioned within the cylinder block having an offset portion extending outside the cylinder block; a wobble spider rotatably journaled to the offset portion; connecting rods for each cylinder connecting each piston to the wobble spider. The improvement comprising: a first sleeve bearing means supporting the drive shaft in the engine block in a cantilevered manner for radial loads; a second sleeve bearing means rotatably supporting the wobble spider on the offset portion of the drive shaft for radial loads; a first roller bearing means positioned between the offset portion of the drive shaft and the wobble spider carrying thrust loadings only; a second roller bearing means carrying thrust loads only reacting to the first roller bearing located on the opposite end of the driveshaft between the shaft and the engine block.

Gonzalez, C.

1992-03-10T23:59:59.000Z

336

Advances in pulverized coal combustion  

SciTech Connect (OSTI)

A combustion system has been developed to operate cost effectively in the difficult regulatory and economic climate of the 1980's. The system is designed to reduce auxiliary fuel oil comsumption by at least 30% while meeting all relevant emissions limits. This is achieved with the fewest components consistent with practical reliable design criteria. The Controlled Flow Split/Flame low NO/sub x/ burner, MBF pulverizer and Two-Stage ignition system are integrated into a mutually supporting system which is applicable to both new steam generators and, on a retrofit basis, to existing units. In the future, a pulverized coal ignition system will be available to eliminate fuel oil use within the boiler.

Vatsky, J.

1981-01-01T23:59:59.000Z

337

Vehicle Technologies Office: Advanced Combustion Engines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Combustion Engines Combustion Engines Improving the efficiency of internal combustion engines is one of the most promising and cost-effective near- to mid-term approaches to increasing highway vehicles' fuel economy. The Vehicle Technologies Office's research and development activities address critical barriers to commercializing higher efficiency, very low emissions advanced internal combustion engines for passenger and commercial vehicles. This technology has great potential to reduce U.S. petroleum consumption, resulting in greater economic, environmental, and energy security. Already offering outstanding drivability and reliability to over 230 million passenger vehicles, internal combustion engines have the potential to become substantially more efficient. Initial results from laboratory engine tests indicate that passenger vehicle fuel economy can be improved by more than up to 50 percent, and some vehicle simulation models estimate potential improvements of up to 75 percent. Advanced combustion engines can utilize renewable fuels, and when combined with hybrid electric powertrains could have even further reductions in fuel consumption. As the EIA reference case forecasts that by 2035, more than 99 percent of light- and heavy-duty vehicles sold will still have internal combustion engines, the potential fuel savings is tremendous.

338

Low NOx combustion system for heavy oil  

SciTech Connect (OSTI)

As a result of the increasing demand for white oil as one of countermeasures for pollution control and as a fuel for motor vehicle, coupled with the increasing import of heavy crude oil, heavy oils such as asphalt and distillation residue have become surplus in Japan. It is difficult by the conventional low NOx technology to control the NOx emission from the industrial small and medium capacity boilers, which use heavy oil as their fuels. The authors have been developing and improving NOx control technologies for boilers such as low NOx burners, two-stage combustion methods and so on. They have developed a new combustion system for heavy oil, which generates less NOx and soot than conventional systems, by applying the knowledge, obtained in the course of their development of Coal Partial Combustor (CPC). The conventional low NOx combustion method for oil firing boilers has been developed based on decreasing the flame temperature and delaying the combustion reaction. In the system, however, the heavy oil shall be combusted in the intense reducing atmosphere at the high flame temperature between 1,500 C and 1,600 C, and then the combustions gas shall be cooled and oxidized by two-stage combustion air. With this system, NOx emission can be suppressed below 100ppm (converted as O{sub 2}=4%).

Kurata, Chikatoshi; Sasaki, Hideki

1999-07-01T23:59:59.000Z

339

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

340

Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: Effects of Alkyl Side  

E-Print Network [OSTI]

Spin Crossover in a Series of Iron(II) Complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1Versity, Beijing 100871, China Received October 27, 2006 2-(2H-Tetrazol-5-yl)-1,10-phenanthroline (HL0 ), its alkyl) at the 2H position of the tetrazole ring, and their iron(II) complexes (a for [Fe(L0 )2], na for [Fe(Ln)2

Gao, Song

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Gas turbine alternative fuels combustion characteristics  

SciTech Connect (OSTI)

An experimental investigation was conducted to obtain combustion performance and exhaust pollutant concentrations for specific synthetic hydrocarbon fuels. Baseline comparison fuels used were gasoline and diesel fuel number two. Testing was done over a range of fuel to air mass ratios, total mass flow rates, and input combustion air temperatures in a flame-tube-type gas turbine combustor. Test results were obtained in terms of released heat and combustion gas emission values. The results were comparable to those obtained with the base fuels with variations being obtained with changing operating conditions. The release of carbon particles during the tests was minimal. 22 refs., 12 figs., 2 tabs.

Rollbuhler, R.J.

1989-02-01T23:59:59.000Z

342

In Situ NMR Spectroscopy of Combustion  

Science Journals Connector (OSTI)

In situ nuclear magnetic resonance spectroscopy (NMR) of high-temperature reactions is of potential value for the investigation of catalytic combustion and other high-temperature applications of catalysts such as partial oxidation of hydrocarbons and steam reforming. ... Two-dimensional (2D) studies of gas exchange within different heat zones of the combustion process provide valuable insights into the gas-phase dynamics. ... This may be the case at the high combustion temperatures, but neither experimental nor theoretical xenon chemical shift data is available in current literature for temperatures above 1000 K. ...

Satyanarayana Anala; Galina E. Pavlovskaya; Prakash Pichumani; Todd J. Dieken; Michael D. Olsen; Thomas Meersmann

2003-10-07T23:59:59.000Z

343

Combustion in cracks of PBX 9501  

SciTech Connect (OSTI)

Recent experiments involving the combustion of PBX 9501 explosive under confined conditions reveal the importance of crack and flaws in reaction violence. Experiments on room temperature confined disks of pristine and thermally damaged PBX 9501 reveal that crack ignition depends on hot gases entering existing or pressure induced cracks rather than on energy release at the crack tip. PBX 9501 slot combustion experiments show that the reaction propagation rate in the slot does not depend on the external pressure. We have observed 1500 d s in long slots of highly-confined PBX 9501. We present experiments that examine the combustion of mechanically and thermally damaged samples of PBX 9501.

Berghout, H. L. (Henry L.); Son, S. F. (Steven F.); Bolme, C. A. (Cynthia A.); Hill, L. G. (Larry G.); Asay, B. W. (Blaine W.); Dickson, P. M. (Peter M.); Henson, B. F. (Bryan F.); Smilowitz, L. B. (Laura B.)

2002-01-01T23:59:59.000Z

344

Diesel knock noise from combustion phenomenon to perceived signals  

E-Print Network [OSTI]

Diesel knock noise from combustion phenomenon to perceived signals O. Sauvagea , A. Lauracb , M for reducing Diesel knock are modifications of engine parameters used for controlling combustion processes-acoustic properties, throught its noticeable combustion noise (also called "Diesel knock"). Combustion noise generated

Paris-Sud XI, Université de

345

Thermodynamic Analysis of Alternative Approaches to Chemical Looping Combustion  

Science Journals Connector (OSTI)

Thermodynamic Analysis of Alternative Approaches to Chemical Looping Combustion ... Because H2 and syngas have similar combustion irreversibilities, when reforming is done optimally (with TR close to 650 K), iso-octane can be combusted with the same efficiency as that of preheated, isothermal H2 combustion. ... A loop of chem. ...

V. Kalyana Chakravarthy; C. Stuart Daw; Josh A. Pihl

2011-01-19T23:59:59.000Z

346

US National Technical Meeting of the Combustion Institute  

E-Print Network [OSTI]

potential to enhance combustion performance in gas turbines and scramjet engines. Extensive efforts have

Ju, Yiguang

347

Robust Feedback Control of Combustion Instability with Modeling Uncertainty  

E-Print Network [OSTI]

to mod- ulate combustion processes in propulsion sys- tems has recently received extensive attention [1

Ray, Asok

348

Emission formation during wood log combustion in fireplaces â?? part I: volatile combustion stage  

Science Journals Connector (OSTI)

A CFD-based tool for the analysis of combustion and emissions in batch-fired wood log combustion is introduced. It consists of submodels for drying and pyrolysis of a wood log, for combustion of volatilised fuel and char, for radiative heat transfer, and for NO formation implemented in a commercial CFD-programme (Fluent) for turbulent flows. Comparing model predictions to experimental data in a test oven shows the applicability of the different submodels and combination of them.

M. Huttunen; J. Saastamoinen; P. Kilpinen; L. Kjaldman; H. Oravainen; S. Bostrom

2006-01-01T23:59:59.000Z

349

Field Validation of Polyethylene Passive Air Samplers for Parent and Alkylated PAHs in Alexandria, Egypt  

Science Journals Connector (OSTI)

Field Validation of Polyethylene Passive Air Samplers for Parent and Alkylated PAHs in Alexandria, Egypt ... In Alexandria for example, eight monitoring stations were established for monitoring the atmospheric quality since the establishment of the Egyptian environmental Law (Law No. 4, 1994). ... Environmental Characterization of Alexandria, Egypt; Egyptian Environmental Affairs Agency: Cairo, 2007; www.eeaa.gov.eg/English/reports/GovProfiles/final/Alex%20Des.pdf. ...

Mohammed A. Khairy; Rainer Lohmann

2012-03-07T23:59:59.000Z

350

Summary of Substitution and Elimination Reactions of Alkyl Halides Polar protic solvent  

E-Print Network [OSTI]

will come from E2 and/or SN2, or there will be no reaction, depending upon the structure of the alkyl halide­X E2, SN2, E1/SN1 First, you need to know which products to expect from each mechanism. Second, you: 1) 1° halides will give SN2 unless the halide is hindered on the backside by branching

Walba, David

351

Biomass Combustion Systems Inc | Open Energy Information  

Open Energy Info (EERE)

Combustion Systems Inc Combustion Systems Inc Jump to: navigation, search Name Biomass Combustion Systems Inc Address 67 Millbrook St Place Worcester, Massachusetts Zip 01606 Sector Biomass Product Combustion systems for wood fuel Website http://www.biomasscombustion.c Coordinates 42.290195°, -71.799627° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":42.290195,"lon":-71.799627,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

352

Chemical Looping for Combustion and Hydrogen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ChemiCal looping for Combustion and ChemiCal looping for Combustion and hydrogen produCtion Objective The objective of this project is to determine the benefits of chemical looping technology used with coal to reduce CO 2 emissions. Background Chemical looping is a new method to convert coal or gasified coal to energy. In chemical looping, there is no direct contact between air and fuel. The chemical looping process utilizes oxygen from metal oxide oxygen carrier for fuel combustion, or for making hydrogen by "reducing" water. In combustion applications, the products of chemical looping are CO 2 and H 2 O. Thus, once the steam is condensed, a relatively pure stream of CO 2 is produced ready for sequestration. The production of a sequestration ready CO 2 stream does not require any additional separation units

353

Coal fuel slurry for internal combustion engines  

Science Journals Connector (OSTI)

A technoeconomic study of the production of coal-water fuel slurry for internal combustion engines and thermal power plants was performed. Based on the accumulated experimental data, it was found that, in the ...

N. I. Red’kina; G. S. Khodakov; E. G. Gorlov

2013-09-01T23:59:59.000Z

354

The Role of Volatiles in Coal Combustion  

Science Journals Connector (OSTI)

Our knowledge of the role of volatiles in coal combustion ranges at this time from the self-evident to the ambiguous. The clearest point on which all agree is that pyrolysis will occur during the total coal co...

Robert H. Essenhigh; Eric M. Suuberg

1987-01-01T23:59:59.000Z

355

Oil shale retorting and combustion system  

DOE Patents [OSTI]

The present invention is directed to the extraction of energy values from l shale containing considerable concentrations of calcium carbonate in an efficient manner. The volatiles are separated from the oil shale in a retorting zone of a fluidized bed where the temperature and the concentration of oxygen are maintained at sufficiently low levels so that the volatiles are extracted from the oil shale with minimal combustion of the volatiles and with minimal calcination of the calcium carbonate. These gaseous volatiles and the calcium carbonate flow from the retorting zone into a freeboard combustion zone where the volatiles are burned in the presence of excess air. In this zone the calcination of the calcium carbonate occurs but at the expense of less BTU's than would be required by the calcination reaction in the event both the retorting and combustion steps took place simultaneously. The heat values in the products of combustion are satisfactorily recovered in a suitable heat exchange system.

Pitrolo, Augustine A. (Fairmont, WV); Mei, Joseph S. (Morgantown, WV); Shang, Jerry Y. (Fairfax, VA)

1983-01-01T23:59:59.000Z

356

Coal Combustion By-Products (Maryland)  

Broader source: Energy.gov [DOE]

The Department of the Environment is responsible for regulating fugitive air emissions from the transportation of coal combustion by-products and the permissible beneficial uses of these by...

357

Control of NOx by combustion process modifications  

E-Print Network [OSTI]

A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

Ber?, J. M.

1981-01-01T23:59:59.000Z

358

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

359

Virtual Design of Stirling Engine Combustion Chamber  

Science Journals Connector (OSTI)

The paper deals with the designing of a combustion chamber of the Stirling engine using the CFD approach. Virtual prototypes enabled ... . The presented results help to increase the Stirling engine efficiency tog...

Z. Kaplan; P. Novotný; V. Píšt?k

2010-01-01T23:59:59.000Z

360

Vortex driven flame dynamics and combustion instability  

E-Print Network [OSTI]

Combustion instability in premixed combustors mostly arises due to the coupling between heat release rate dynamics and system acoustics. It is crucial to understand the instability mechanisms to design reliable, high ...

Altay, Hurrem Murat

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

State of Industrial Fluidized Bed Combustion  

E-Print Network [OSTI]

A new combustion technique has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal limits. Low quality fuels can be burned directly...

Mesko, J. E.

1982-01-01T23:59:59.000Z

362

Coal Combustion Products Extension Program  

SciTech Connect (OSTI)

This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to 40% by 2010, the CCP Extension Program be expanded at OSU, with support from state and federal agencies, utilities, trade groups, and the university, to focus on the following four specific areas of promise: (a) Expanding use in proven areas (such as use of fly ash in concrete); (b) Removing or reducing regulatory and perceptual barriers to use (by working in collaboration with regulatory agencies); (c) Developing new or under-used large-volume market applications (such as structural fills); and (d) Placing greater emphasis on FGD byproducts utilization.

Tarunjit S. Butalia; William E. Wolfe

2006-01-11T23:59:59.000Z

363

Fundamental Studies in Syngas Premixed Combustion Dynamics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Studies Studies in Syngas Premixed Combustion Dynamics Ahmed F. Ghoniem, Anuradha M. Annaswamy, Raymond L. Speth, H. Murat Altay Massachusetts Institute of Technology SCIES Project 05-01-SR121 Project Awarded (08/01/2005, 36 Month Duration) Needs & Objectives Gas Turbine Needs Flexibility to operate with variable syngas compositions Ensure stable operation over a wide range of conditions Reduce emissions of CO and NO x Project Objectives Study experimentally lean premixed syngas combustion

364

Oxy-combustion: Oxygen Transport Membrane Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion: Oxygen Transport combustion: Oxygen Transport Membrane Development Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

365

Building America Expert Meeting: Combustion Safety  

SciTech Connect (OSTI)

This is a meeting overview of 'The Best Approach to Combustion Safety in a Direct Vent World', held June 28, 2012, in San Antonio, Texas. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

Brand, L.

2013-03-01T23:59:59.000Z

366

33rd International Symposium on Combustion Hottel Lecture Application...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Delay Times * Species Time-Histories * Reaction Rate Constants * Methyl Ester Studies * Ignition Delay Times Long-Term Objectives * Generate high-quality fundamental kinetics...

367

Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters  

SciTech Connect (OSTI)

Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packing—in the solid-state—to be scrutinized in detail.

Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

2014-11-13T23:59:59.000Z

368

Rapid Deployment of Rich Catalytic Combustion  

SciTech Connect (OSTI)

The overall objective of this research under the Turbines Program is the deployment of fuel flexible rich catalytic combustion technology into high-pressure ratio industrial gas turbines. The resulting combustion systems will provide fuel flexibility for gas turbines to burn coal derived synthesis gas or natural gas and achieve NO{sub x} emissions of 2 ppmvd or less (at 15 percent O{sub 2}), cost effectively. This advance will signify a major step towards environmentally friendly electric power generation and coal-based energy independence for the United States. Under Phase 1 of the Program, Pratt & Whitney (P&W) performed a system integration study of rich catalytic combustion in a small high-pressure ratio industrial gas turbine with a silo combustion system that is easily scalable to a larger multi-chamber gas turbine system. An implementation plan for this technology also was studied. The principal achievement of the Phase 1 effort was the sizing of the catalytic module in a manner which allowed a single reactor (rather than multiple reactors) to be used by the combustion system, a conclusion regarding the amount of air that should be allocated to the reaction zone to achieve low emissions, definition of a combustion staging strategy to achieve low emissions, and mechanical integration of a Ceramic Matrix Composite (CMC) combustor liner with the catalytic module.

Richard S. Tuthill

2004-06-10T23:59:59.000Z

369

Effect of Oxyfuel Combustion on Superheater Corrosion  

SciTech Connect (OSTI)

Combustion of coal in an oxygen environment (as opposed to air) will facilitate the sequestering of carbon dioxide by minimizing the amount of nitrogen in the exit gas stream. The presence of higher levels of certain gases associated with oxyfuel combustion (eg, CO2, SO2, and H2O) may impact the corrosion of waterwalls, superheaters, headers, reheaters, and other boiler components. Research is being conducted on bare and ash-embedded boiler tube materials in simulated oxyfuel- combustion and air-combustion environments at a superheater temperature of 675°C. Alloys were exposed at temperature to two different gaseous environments. Preliminary results show: (1) an increase in corrosion rate of bare K02707, K11547, K21590, K91560, K92460, S30409, S34700, and N06617 exposed to the oxyfuel combustion environment when compared to the air combustion environment; (2) an increase in corrosion rate of alloys K21590, K92460, S34700, and N06617, when embedded in ash in comparison to bare exposure; and (3) no effect of gaseous environment on alloy corrosion rate when embedded in ash.

Covino, B.S., Jr.; Matthes, S.A.; Bullard, S.J.

2008-03-16T23:59:59.000Z

370

Combustion kinetics and reaction pathways  

SciTech Connect (OSTI)

This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

Klemm, R.B.; Sutherland, J.W. [Brookhaven National Laboratory, Upton, NY (United States)

1993-12-01T23:59:59.000Z

371

A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS  

SciTech Connect (OSTI)

I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

Huggins, John Mitchell

1980-06-01T23:59:59.000Z

372

Reducible Oxide Based Oxygen Carriers for Chemical Looping Combustion and Partial Oxidation of Methane.  

E-Print Network [OSTI]

??Chemical looping combustion (CLC) is a novel combustion technology that offers a highly efficient route towards clean combustion of fuel with inherent CO2 capture. In… (more)

Bhavsar, Saurabh

2014-01-01T23:59:59.000Z

373

An In-Cylinder Imaging Survey of Low-Temperature, High-Efficiency Combustion Strategies  

Broader source: Energy.gov [DOE]

High speed imaging of in-cylinder spray and combustion luminosity of low temperature combustion strategies are contrasted to conventional gasoline and diesel engine combustion

374

Advanced High Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines  

Broader source: Energy.gov [DOE]

Clean, in-cylinder combustion can be enabled by a micro-variable circular orifice, dual mode PCCI, dew film combustion, and a novel combustion chamber design

375

Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory  

E-Print Network [OSTI]

emissions during biomass combustion: Controlling factors andfrom smoldering combustion of biomass measured by open-pathduring the open combustion of biomass in the laboratory

McMeeking, Gavin R.

2009-01-01T23:59:59.000Z

376

Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

377

Combustion Synthesis of Silicon Carbide 389 Combustion Synthesis of Silicon Carbide  

E-Print Network [OSTI]

Combustion Synthesis of Silicon Carbide 389 X Combustion Synthesis of Silicon Carbide Alexander S velocity and 17 #12;Properties and Applications of Silicon Carbide390 reaction rate throughout the mixture by graphite during SHS of carbides. Local reaction initiation is typically accomplished by hot tungsten wire

Mukasyan, Alexander

378

Utilization of Combustion?Driven Oscillations  

Science Journals Connector (OSTI)

The possible applications of combustion?driven oscillations fall into two categories. The first category includes applications that are related to the combustion process itself such as those concerned with the possibility of alterlog space heat?release rate combustion efficiency heat transfer to surfaces and agglomeration of solid or liquid products of combustion. A consideration of available experimental and theoreticalinformation indicates that none of these applications are too promising when compared with alternative methods of performing the same functions. The second category includes applications that use pulsatory phenomena to do a particular iob. Examples are the application of valveless pulse jets to (a) the propulsion of drones (b) helicopter blade?tip propulsion (c) cutting of Arctic ice and (d) inducing pressure rises in through?flow combustion systems. For one reason or another most of these ideas have been dropped. However the use of the pulsating?combustion process to supply both the air at a high flow velocity to a combustor and the products of combustion at a high velocity to a heat exchanger thereby making possible a compact self?contained unit appears to have great promise. One such unit of residential boiler size is already available. Although this unit is valved as was the V?1 conversion to a valveless unit appears possible. The development of industrial?sized units appears equally feasible. Apparently the development of such units is contingent upon (a) adequate understanding of how to design effective aerodynamic valves and (b) the collaboration of an inventor experimentalist analyst and financier on a specific program.

Abbott A. Putnam

1963-01-01T23:59:59.000Z

379

NETL: IEP – Post-Combustion CO2 Emissions Control - Oxy-Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Oxy-Combustion CO2 Emissions Control IEP - Oxy-Combustion CO2 Emissions Control Oxy-Combustion Technology Development for Industrial-Scale Boiler Applications Project No.: DE-NT0005290 Alstom oxy-combustion test facility Alstom oxy-combustion test facility. Alstom will develop an oxyfuel firing system design specifically for retrofit to tangential-fired (T-fired) boilers and provide information to address the technical gaps for commercial boiler design. Several oxyfuel system design concepts, such as internal flue gas recirculation and various oxygen injection schemes, will be evaluated for cost-effectiveness in satisfying furnace design conditions in a T-fired boiler. The evaluation will use an array of tools, including Alstom's proprietary models and design codes, along with 3-D computational fluid dynamics modeling. A

380

Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FEMP Technology FEMP Technology Brief: Boiler Combustion Control and Monitoring System to someone by E-mail Share Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion Control and Monitoring System on Facebook Tweet about Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion Control and Monitoring System on Twitter Bookmark Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion Control and Monitoring System on Google Bookmark Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion Control and Monitoring System on Delicious Rank Federal Energy Management Program: FEMP Technology Brief: Boiler Combustion Control and Monitoring System on Digg Find More places to share Federal Energy Management Program: FEMP

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Flamelet model for pulverized coal combustion  

Science Journals Connector (OSTI)

Abstract A new flamelet model applicable to the simulation of pulverized coal combustion has been developed. First, a modeling approach that considers the coupling with both devolatilization and char combustion was adopted. We changed the fuel composition of the flamelet equation relative to the states of devolatilization and char combustion. In order to determine the fuel composition coming through the char combustion, all the gasified char was assumed to be converted into CO by the oxidation reaction. The validity of the developed flamelet model was examined in a simple two-dimensional pulverized coal jet field ignited by burnt co-flows. The accuracy of the model was evaluated by comparing its instantaneous distributions of temperature, CO2 mass fraction, and OH mass fraction with those of a detailed chemistry model. Good agreement was obtained in terms of the overall features of turbulent structures and combustion state, although the flamelet model showed slightly quicker ignition due to the transitional state in the ignition process being insufficiently reproducible.

Junya Watanabe; Kenji Yamamoto

2014-01-01T23:59:59.000Z

382

Reaction and diffusion in turbulent combustion  

SciTech Connect (OSTI)

The motivation for this project is the need to obtain a better quantitative understanding of the technologically-important phenomenon of turbulent combustion. In nearly all applications in which fuel is burned-for example, fossil-fuel power plants, furnaces, gas-turbines and internal-combustion engines-the combustion takes place in a turbulent flow. Designers continually demand more quantitative information about this phenomenon-in the form of turbulent combustion models-so that they can design equipment with increased efficiency and decreased environmental impact. For some time the PI has been developing a class of turbulent combustion models known as PDF methods. These methods have the important virtue that both convection and reaction can be treated without turbulence-modelling assumptions. However, a mixing model is required to account for the effects of molecular diffusion. Currently, the available mixing models are known to have some significant defects. The major motivation of the project is to seek a better understanding of molecular diffusion in turbulent reactive flows, and hence to develop a better mixing model.

Pope, S.B. [Mechanical and Aerospace Engineering, Ithaca, NY (United States)

1993-12-01T23:59:59.000Z

383

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

384

Descargue Datos de Ahorro de Combustible  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Descargue Datos de Ahorro de Combustible Descargue Datos de Ahorro de Combustible Los datos de ahorro de combustible son el resultado de las pruebas realizadas en el Laboratorio de Emisiones de Combustible y VehĂ­culos de la Agencia Nacional de ProtecciĂłn del Medio Ambiente en Ann Arbor, Michigan y por fabricantes de automĂłviles, con la supervisiĂłn de la EPA. Archivo Descargable de Ahorro de Combustible Archivo* de la GuĂ­a de Ahorremos Gasolina Archivo 2014 No Disponible Archivo 2013 de la GuĂ­a de Ahorremos Gasolina 2013 ĂŤcono de Adobe Acrobat Archivo 2012 de la GuĂ­a de Ahorremos Gasolina 2012 ĂŤcono de Adobe Acrobat Archivo 2011 de la GuĂ­a de Ahorremos Gasolina 2011 ĂŤcono de Adobe Acrobat Archivo 2010 de la GuĂ­a de Ahorremos Gasolina 2010 ĂŤcono de Adobe Acrobat Archivo 2009 de la GuĂ­a de Ahorremos Gasolina 2009 ĂŤcono de Adobe Acrobat

385

E-Print Network 3.0 - acid isopropyl ester Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5087-5090,1988 0040-403988 3.00 + .oO Printed in Great Britain Pergamon Press plc Summary: into their corresponding esters using Jones' (acidic), and permanganate or...

386

A Csp3–Csp3 Bond Forming Reductive Condensation of ?-Keto Esters and Enolizable Carbon Pronucleophiles  

Science Journals Connector (OSTI)

The preparation of densely functionalized unsymmetrical 1,4-dicarbonyl structural motifs by a phosphorus(III)-mediated reductive condensation of ?-keto esters and enolizable carbon pronucleophiles is described. The reaction, which is initiated by Kukhtin–...

Wei Zhao; Darla M. Fink; Carolyn A. Labutta; Alexander T. Radosevich

2013-06-05T23:59:59.000Z

387

Emulsion polymerization of ethylene-vinyl acetate-branched vinyl ester using a pressure reactor system.  

E-Print Network [OSTI]

??A new pressure reactor system was designed to synthesize a novel branched ester-ethylene-vinyl acetate (BEEVA) emulsion polymer. The reactor system was capable of handling pressure… (more)

Tan, Chee Boon

2008-01-01T23:59:59.000Z

388

E-Print Network 3.0 - acid allyl ester Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbons of High Summary: to this problem. This is the case of the copper-mediated SN2 substitu- tion of chiral allylic esters of defined... Ratios of Cuprate Addition on...

389

E-Print Network 3.0 - acid 2-benzothiazolylthiomethyl ester Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: acid 2-benzothiazolylthiomethyl ester Page: << < 1 2 3 4 5 > >> 1 GTQ, Chemistry 212, Dr. Glaser, FS96 --1 --GTQ on Lactones. (30 points, reaction chem., mechanistic...

390

E-Print Network 3.0 - acetoacetic acid esters Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sample search results for: acetoacetic acid esters Page: << < 1 2 3 4 5 > >> 1 GTQ, Chemistry 212, Dr. Glaser, FS96 --1 --GTQ on Michael Reactions. (20 points, synthesis,...

391

Synthesis of Esters from Cage-Like Unsaturated Hydrocarbons, Carboxylic Acid Anhydrides, and Water  

Science Journals Connector (OSTI)

A convenient method for the preparation of esters was developed on the basis of reaction of cage-like polycyclic olefins with carboxylic acid anhydrides and water. Mixed anhydrides were found to give rise to t...

M. K. Mamedov; E. K. Nabieva; R. A. Rasulova

392

Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities  

SciTech Connect (OSTI)

Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2012-07-01T23:59:59.000Z

393

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-10-01T23:59:59.000Z

394

Understanding the thermodynamic inefficiencies in combustion processes  

Science Journals Connector (OSTI)

Abstract The thermodynamic inefficiencies associated with any energy conversion process are expressed by the exergy destruction and the exergy losses associated with the process. Combustion processes exhibit very high thermodynamic inefficiencies caused by chemical reaction, heat transfer, friction, and mixing. In this paper, we discuss how to estimate the thermodynamic inefficiencies resulting from each one of these sources. The thermodynamic evaluation can be conducted with the aid of either a conventional exergetic analysis or an advanced one. The latter allows estimation of the potential for improvement of the process being considered and demonstrates the interactions among the components of the system in which combustion takes place. The paper discusses how advanced exergy-based evaluations can be used to reduce the thermodynamic inefficiencies, costs, and environmental impacts associated with energy conversion systems including combustion processes.

George Tsatsaronis; Tatiana Morosuk; Daniela Koch; Max Sorgenfrei

2013-01-01T23:59:59.000Z

395

Premixed Combustion of Hydrogen Augmented Natural Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Premixed Combustion of Hydrogen Premixed Combustion of Hydrogen Augmented Natural Gas * Lean premixed combustion * Effective for emission reduction with natural gas * High hydrogen flame speed requires care in premixer design for SGH fuels * UC Irvine study quantifies effectiveness of hydrogen augmentation strategy * Lean stability limit improves linearly with hydrogen augmentation * Emissions reduction can be achieved * Two OEM's and the California Energy Commission have used the results to help guide them on adapting to hydrogen fuel UC Irvine Scott Samuelsen / Vince McDonell Project 98-01-SR062 1200 1300 1400 1500 1600 1700 1800 1900 0 10 20 30 40 50 60 Hydrogen Volume in Main Fuel (%) Adiabatic Flame Temperature (K) P0(3/4) High Stability High Stability Low emission Low emission operational zone operational zone

396

Study of the potential valorization of metal contaminated Salix via phytoextraction by combustion  

E-Print Network [OSTI]

, different energy-recovery- techniques (incineration, combustion, gasification, pyrolysis, anaerobic

Paris-Sud XI, Université de

397

http://www.genie.uottawa.ca/~hallett/hallett.htm Combustion Research  

E-Print Network [OSTI]

Engineering Main themes: - solid fuel combustion/packed beds - liquid droplet combustion - biofuels (biomass, Mechanical Engineering #12;Liquid Droplet Combustion W. Hallett, Mechanical Engineering Recent Work - biomasshttp://www.genie.uottawa.ca/~hallett/hallett.htm Combustion Research W. Hallett, Mechanical

Hallett, William L.H.

398

ADSORPTION/DESORPTION STUDIES ON SOLID ACID ALKYLATION CATALYSTS USING A TAPERED ELEMENT OSCILLATING MICROBALANCE (TEOM)  

E-Print Network [OSTI]

for the first time the adsorption/desorption characteristics of alkylation reactants and products on these zeolites and some mesoporous materials. Equilibrium adsorption isotherms were obtained on these catalysts using n-butane, isobutane, and propane....2.1. Zeolites 72 4.2.2. Mesoporous Materials 78 4.2.3. Chemicals 79 vi 4.3. Equilibrium Adsorption Isotherms of n-Butane, Isobutane, and Propane on b- zeolite and USY-zeolite 79 4.4. Equilibrium Adsorption Isotherms of CO2 on b-zeolite and USY-zeolite 89 4...

Gong, Kening

2008-10-23T23:59:59.000Z

399

Hydrothermal combustion of biofuels in supercritical water  

SciTech Connect (OSTI)

Supercritical water oxidation (SCWO) has long been recognized as a safe, clean and energy efficient method for destroying a wide range of organic materials and hazardous wastes. As SCWO systems operate at elevated pressure, all effluent streams are fully contained allowing efficient recovery of thermal energy using compact heat exchangers. Water vapor produced by the combustion efficiency, especially for fuels with increasing moisture content such as biomass. This paper compares the performance of a simple Rankine vapor power cycle which derives it`s heat input from (1) a hydrothermal combustion system, and (2) a conventionally-fired steam boiler. The study is based on a hypothetical cellulose-based organic fuel with a higher heating value of 7,000 BT/1bm (dry). For a constant organic feedrate of 100 tons/day (bone dry) mixed in 20:80 fuel/water ratio with water, the calculated net electric power output from the 31.93%. Whereas, for an organic feedrate of 100 tons/day (bone dry) with zero of 5,382 kW, at an overall thermal efficiency of 31.48%. The hydrothermal combustion power cycle is unaffected by free moisture in the fuel, and thereby uniquely well-suited for use in biomass power generation applications. The hydrothermal combustion process is exceptionally clean burning, and allows full control over carbon dioxide and SOx emissions. NOx levels are inherently ultra-low due to lower combustion temperatures. Hydrothermal combustion technology is ready for pilot-scale engineering development and demonstration.

McGuinness, T.G. [Summit Research Corporation, Sante Fe, NM (United States); Marentis, R. [Summit Research Corporation, Allentown, PA (United States)

1994-12-31T23:59:59.000Z

400

Argonne TTRDC - Engines - Home - combustion, compression ignition,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

* Combustion Visualization * Combustion Visualization * Compression-Ignition * Emissions Control * Fuel Injection and Sprays * Idling * Multi-Dimensional Modeling * Particulate Matter * Spark Ignition Green Racing GREET Hybrid Electric Vehicles Hydrogen & Fuel Cells Materials Modeling, Simulation & Software Plug-In Hybrid Electric Vehicles PSAT Smart Grid Student Competitions Technology Analysis Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Engines Omnivorous engine tested by Thomas Wallner Thomas Wallner tests the omnivorous engine, a type of spark-ignition engine. Argonne's engine research is contributing to advances in technology that will impact the use of conventional and alternative fuels and the design of advanced technology vehicles. Compression Ignition

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Building America Expert Meeting: Combustion Safety  

Broader source: Energy.gov (indexed) [DOE]

Meeting: Combustion Safety Meeting: Combustion Safety L. Brand Partnership for Advanced Residential Retrofit March 2013 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, subcontractors, or affiliated partners makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply

402

Building America Expert Meeting: Combustion Safety  

Broader source: Energy.gov [DOE]

This expert meeting, The Best Approach to Combustion Safety in a Direct Vent World, was conducted by the Partnership for Advanced Residential Retrofit team on June 28, 2012, in San Antonio, TX. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

403

Kinetic data base for combustion modeling  

SciTech Connect (OSTI)

The aim of this work is to develop a set of evaluated rate constants for use in the simulation of hydrocarbon combustion. The approach has been to begin with the small molecules and then introduce larger species with the various structural elements that can be found in all hydrocarbon fuels and decomposition products. Currently, the data base contains most of the species present in combustion systems with up to four carbon atoms. Thus, practically all the structural grouping found in aliphatic compounds have now been captured. The direction of future work is the addition of aromatic compounds to the data base.

Tsang, W.; Herron, J.T. [National Institute of Standards and Technology, Gaithersburg, MD (United States)

1993-12-01T23:59:59.000Z

404

Resonance ionization detection of combustion radicals  

SciTech Connect (OSTI)

Fundamental research on the combustion of halogenated organic compounds with emphasis on reaction pathways leading to the formation of chlorinated aromatic compounds and the development of continuous emission monitoring methods will assist in DOE efforts in the management and disposal of hazardous chemical wastes. Selective laser ionization techniques are used in this laboratory for the measurement of concentration profiles of radical intermediates in the combustion of chlorinated hydrocarbon flames. A new ultrasensitive detection technique, made possible with the advent of tunable VUV laser sources, enables the selective near-threshold photoionization of all radical intermediates in premixed hydrocarbon and chlorinated hydrocarbon flames.

Cool, T.A. [Cornell Univ., Ithaca, NY (United States)

1993-12-01T23:59:59.000Z

405

Past experiences with automotive external combustion engines  

SciTech Connect (OSTI)

GMR (General Motors Research Laboratories, now GM R and D Center) has a history of improving the internal combustion engine, especially as it relates to automotive use. During the quarter century from 1950--75, considerable effort was devoted to evaluating alternative powerplants based on thermodynamic cycles different from those on which the established spark-ignition and diesel engines are founded. Two of these, the steam engine and the Stirling engine, incorporated external combustion. Research on those two alternatives is reviewed. Both were judged to fall short of current needs for commercial success as prime movers for conventional automotive vehicles.

Amann, C.A.

1999-07-01T23:59:59.000Z

406

Evaluating the fluidized bed combustion options  

SciTech Connect (OSTI)

The proceedings from a conference on fluidized bed combustion are now available. The book discusses the immediate availability of atmospheric fluidized bed combustion technology as a practical, environmentally sound option for burning all grades of coal, wood, wood wastes, and biomass. The economics and technical fundamentals of atmospheric FBC are explained for the benefit of owners and managers of industrial boilers, boiler operators, architects/engineers, boiler manufacturers, and fuel suppliers. More than 15 FBC experts have contributed their expertise and experiences to the book.

Sheahan, R.T. (ed.)

1984-01-01T23:59:59.000Z

407

1 - Combustion processes of textile fibres  

Science Journals Connector (OSTI)

Abstract: This chapter reviews the current knowledge of the processes involved in the combustion behaviour of textiles and approaches to their flame retardant protection. Synthetic fibre-forming polymers, both thermoplastic and high temperature resistant, as well as naturally occurring fibre types are discussed. The combustion process is described with reference to the thermal stability, degradation and oxidative degradation of various individual polymer types. The significance of textile structure is considered with respect to the textile flammability. The mechanisms of the different flame retardant systems applied to various textiles are discussed as well as the more recent application of nano-composites. Finally, a prediction of potential future developments is presented.

D. Price; A.R. Horrocks

2013-01-01T23:59:59.000Z

408

Non-Petroleum Based Fuel Effects on Advanced Combustion (Agreement...  

Broader source: Energy.gov (indexed) [DOE]

Non-Petroleum Based Fuel Effects on Advanced Combustion (Agreement 13425) Non-Petroleum Based Fuel Effects on Advanced Combustion (Agreement 13425) Presentation from the U.S. DOE...

409

Conditions of realization of superwet in-situ combustion  

SciTech Connect (OSTI)

In in-situ combustion adding water to the air considerably improves the characteristics of the process: the combustible fuel concentration is reduced, the steam plateau ahead of the combustion front increases, less oxidizer is required to displace the oil, and the thermal wave has a higher propagation velocity. In wet combustion the temperature in the combustion zone reaches approx. 500/sup 0/C. In superwet combustion it depends on the reservoir pressure and may be 200-300/sup 0/C. It is not known in advance whether the heat of combustion will suffice to sustain the thermal wave, and if it does suffice, what will be the maximum values of the water-air ratio for the process. This paper attempts to construct a mathematical model of the superwet combustion process.

Bokserman, A.A.; Stepanov, V.P.

1985-07-01T23:59:59.000Z

410

A new type of self-organization in combustion  

Science Journals Connector (OSTI)

... a solid-phase gasless combustion3 which proceeds with the formation of a melt or a flameless gas3'4. ... gas3'4. Flameless combustion has recently been described for several tetrazole compounds5.

A. I. Lesnikovich; V. V. Sviridov; G. V. Printsev; O. A. Ivashkevich; P. N. Gaponik

1986-10-23T23:59:59.000Z

411

Large-Eddy Simulation of Swirling Pulverized-Coal Combustion  

Science Journals Connector (OSTI)

A Eulerian-Lagrangian large-eddy simulation (LES) with a Smagorinsky-Lilly sub-grid scale stress model, presumed-PDF fast chemistry and EBU gas combustion models, particle devolatilization and particle combustion

L. Y. Hu; L. X. Zhou; Y. H. Luo; C. S. Xu

2013-01-01T23:59:59.000Z

412

Carbonation of Fly Ash in Oxy-fuel CFB Combustion  

Science Journals Connector (OSTI)

Oxy-fuel combustion of fossil fuel is one of the most promising methods to produce a stream of concentrated CO2 ready for sequestration. Oxy-fuel FBC (fluidized bed combustion) can use limestone as a sorbent for

Chunbo Wang; Lufei Jia; Yewen Tan…

2007-01-01T23:59:59.000Z

413

A Comparison of Combustion and Emissions of Diesel Fuels and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated...

414

Advanced Combustion Systems Project Information | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FC26-07NT43088 Recovery Act: Oxy-combustion: Oxygen Transport Membrane Development Praxair, Inc. Completed Projects FE0009686 High Efficiency Molten-Bed Oxy-Coal Combustion...

415

COMBUSTION RESEARCH PROGRAM. CHAPTER FROM ENERGY & ENVIRONMENT ANNUAL REPORT 1977  

E-Print Network [OSTI]

The pulverized coal has significant ash content, about 6%.of Ash and Trace Metals from Pulverized Coal Combustion P.of Ash and Trace Metals from Pulverized Coal Combustion P.

Authors, Various

2011-01-01T23:59:59.000Z

416

MILD combustion for hydrogen and syngas at elevated pressures  

Science Journals Connector (OSTI)

As gas recirculation constitutes a fundamental condition for the realization of MILD combustion, it is necessary to determine gas recirculation ratio before designing MILD combustor. MILD combustion model with ga...

Mingming Huang; Zhedian Zhang; Weiwei Shao; Yan Xiong…

2014-02-01T23:59:59.000Z

417

Combustion of Low-Calorific Waste Biomass Syngas  

Science Journals Connector (OSTI)

The industrial combustion chamber designed for burning low-calorific syngas from gasification of waste biomass is presented. ... chips and turkey feathers the non-premixed turbulent combustion in the chamber is s...

Kamil Kwiatkowski; Marek Dudy?ski; Konrad Bajer

2013-12-01T23:59:59.000Z

418

The role played by self-inhibition in combustion processes  

Science Journals Connector (OSTI)

The absence of correlations between the heat of combustion of substances and substance combustion characteristics is shown to be caused by the special features of competition between reaction chain branching a...

V. V. Azatyan; I. A. Bolod’yan; Yu. N. Shebeko…

2006-04-01T23:59:59.000Z

419

Thermogravimetric analysis of co-combustion of biomass and biochar  

Science Journals Connector (OSTI)

The co-combustion of biomass and biochar was investigated by thermogravimetric analysis....R M...) for different blends were used to evaluate co-combustion features. As the biomass content increas...

Qiguo Yi; Fangjie Qi; Gong Cheng…

2013-06-01T23:59:59.000Z

420

The Inorganic Chemistry of Biomass Combustion: Problems and Solutions  

Science Journals Connector (OSTI)

High temperature molten products of the combustion of biomass present special problems related to fouling and ... performed calculations of the total inorganic chemistry of biomass combustion using a free energy ...

M. Blander

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Light-Duty Advanced Diesel Combustion Research | Department of...  

Broader source: Energy.gov (indexed) [DOE]

Light-Duty Advanced Diesel Combustion Research Light-Duty Advanced Diesel Combustion Research Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008...

422

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels  

Science Journals Connector (OSTI)

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels ... A loop of chem. ... Energy Combust. ...

Yueying Fan; Ranjani Siriwardane

2014-02-21T23:59:59.000Z

423

E-Print Network 3.0 - advanced wall-fired combustion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass and Animal Waste Combustion Energy Engine Emission Fuel Cells... Gasification Internal Combustion Engine Performance Pollutants Formation (NOx, Hg) and...

424

Using Parametrized Finite Combustion Stage Models to Characterize Combustion in Diesel Engines  

Science Journals Connector (OSTI)

Characterizing combustion in diesel engines is not only necessary when researching the instantaneous combustion phenomena but also when investigating the change of the combustion process under variable engine operating conditions. ... This project partly is financially supported by the Fundamental Research Funds for the Central Universities, Harbin Engineering University, China, HEUCF120307, and the International Science and Technology Cooperation Program of China. ... Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy (2011), 225 (3), 309-318 CODEN: PMAEET; ISSN:0957-6509. ...

Yu Ding; Douwe Stapersma; Hugo Grimmelius

2012-10-29T23:59:59.000Z

425

Oxygen-Enriched Combustion for Military Diesel Engine Generators  

Broader source: Energy.gov [DOE]

Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

426

Trash or treasure? Putting coal combustion waste to work  

SciTech Connect (OSTI)

The use of coal combustion wastes from power plants in construction materials, leaching and the impact of regulations are discussed.

Tenenbaum, D.J.

2009-11-15T23:59:59.000Z

427

Traveling-Wave Thermoacoustic Engines With Internal Combustion  

DOE Patents [OSTI]

Thermoacoustic devices are disclosed wherein, for some embodiments, a combustion zone provides heat to a regenerator using a mean flow of compressible fluid. In other embodiments, burning of a combustible mixture within the combustion zone is pulsed in phase with the acoustic pressure oscillations to increase acoustic power output. In an example embodiment, the combustion zone and the regenerator are thermally insulated from other components within the thermoacoustic device.

Weiland, Nathan Thomas (Blacksburg, VA); Zinn, Ben T. (Atlanta, GA); Swift, Gregory William (Sante Fe, NM)

2004-05-11T23:59:59.000Z

428

Advanced Combustion Modeling with STAR-CD using Transient Flemelet...  

Broader source: Energy.gov (indexed) [DOE]

occurs - Spray modeling is required * Autoignition, combustion, pollutant formation chemistry - Kinetic modeling required for various fuels - Soot, NOx models required *...

429

Simulation of High Efficiency Clean Combustion Engines and Detailed...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

ongoing work exploring fuel chemistry, analysis of and improving simulation methodologies for high efficiency clean combustion regimes, and computational performance...

430

Impact of Extreme Injection Pressure and EGR on the Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Analyse of the Injection System * Simulation * Hydraulic Characterisation * Optical Spray Diagnostics Engine Investigations * Experimental Results * Optical Combustion...

431

Combustion Air Preheat Should Be More Than Simply Recycling Energy  

E-Print Network [OSTI]

Combustion air preheat can and should result in fuel savings far in excess of the energy added to the combustion air. In a typical installation of air preheat on a fired tubular reactor, the addition of 2.5 million BTU/hr to the combustion air...

Grantom, R. L.

1980-01-01T23:59:59.000Z

432

ME 374C Combustion Engine Processes ABET EC2000 syllabus  

E-Print Network [OSTI]

combustion engines, fuels, carburetion, combustion, exhaust emissions, knock, fuel injection, and factors engine, although diesels and 2-strokes are also discussed. Topics Covered (# of classes per topic): 1 of an Engineering System 4. Introduction to Engine Modeling 5. Fuels 6. Combustion and Knock 7. 4-stroke SI Engines

Ben-Yakar, Adela

433

Fast computation of multi-scale combustion systems  

Science Journals Connector (OSTI)

...consider a detailed combustion mechanism for air...The mean specific heat (under constant...being the specific heat of species i (mass...with a detailed combustion mechanism, where...between retrieved data and detailed solution...combustion mechanism for hydrocarbons. Moreover, on...

2011-01-01T23:59:59.000Z

434

Paper # A02 Topic: Laminar Flames US Combustion Meeting  

E-Print Network [OSTI]

been focused on synthetic fuel gas (syngas) combustion. Syngas is derived from coal throughPaper # A02 Topic: Laminar Flames 1 5th US Combustion Meeting Organized by the Western States Section of the Combustion Institute and Hosted by the University of California at San Diego March 25

Seitzman, Jerry M.

435

NOTE / NOTE Variability in organic matter lost by combustion in  

E-Print Network [OSTI]

) to the atmosphere through combustion of biomass. An estimated 1470 ± 59 km2 of peatland burns annually in boreal libère du carbone (C) directement dans l'atmosphère par la combustion de biomasse. AnnuellementNOTE / NOTE Variability in organic matter lost by combustion in a boreal bog during the 2001

Benscoter, Brian W.

436

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-01-01T23:59:59.000Z

437

Alkyl Surface Treatments of Planar Zinc Oxide in Hybrid Organic/Inorganic Solar Cells  

SciTech Connect (OSTI)

Hybrid organic/inorganic solar cells have not lived up to their potential because of poor interface properties. Interfacial molecular layers provide a way of adjusting these devices to improve their performance. We have studied a prototypical system involving poly(3-hexylthiophene) (P3HT) on planar zinc oxide (ZnO) films that have been modified with two types of molecules having identical 18-carbon alkyl chain termination and different surface attachments: octadecanethiol (ODT) and octadecyltriethoxysilane (OTES). We examined the functionalized surfaces using water contact angle measurements, Kelvin probe measurements, infrared absorbance spectroscopy, and atomic force microscopy. These have shown that OTES forms disordered incomplete monolayers, while ODT is prone to develop multilayered islands. Both treatments enhance polymer ordering. However, inverted solar cell devices fabricated with these treated interfaces performed very differently. ODT improves the short circuit current (J{sub SC}), open circuit voltage (V{sub OC}), and power conversion efficiency ({eta}), while these parameters all decrease in devices constructed from OTES-treated ZnO. The differences in V{sub OC} are related to modifications of the surface dipole associated with deposition of the two types of alkyl molecules, while changes in J{sub SC} are attributed to a balance between charge transfer blocking caused by the saturated hydrocarbon and the improved hole mobility in the polymer.

Allen, C. G.; Baker, D. J.; Brenner, T. M.; Weigand, C. C.; Albin, J. M.; Steirer, K. X.; Olson, D. C.; Ladam, C.; Ginley, D. S.; Collins, R. T.; Furtak, T. E.

2012-04-26T23:59:59.000Z

438

Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside  

Science Journals Connector (OSTI)

Weathered crude oil contaminated soils (COCSs), which are much more difficult to remediate than those freshly contaminated, are widespread especially at the sites of oil fields and industries. Surfactant enhanced ex situ soil washing could be used to remediate COCSs, but surfactant toxicity becomes one of the major concerns. In this study, a class of green surfactants, alkyl polyglucosides (APGs), were tested in washing the field weathered COCS with relatively high oil concentration (123 mg g?1 dry soil) from Jilin Oilfield, Northeastern China. APG1214, characterized with longer alkyl chain, was more effective than APG0810 in crude oil removal. Adding inorganic sodium salts into APG1214 solution further improved the crude oil removal efficiency (CORE). Washing parameters (temperature, washing time, agitation speed and solution/soil ratio) were investigated and further optimized integratedly with an orthogonal design. At the optimum conditions, the CORE reached 97%. GC/MS analysis showed that the proportion of small n-alkanes (C16–C23) in residual crude oil gradually increased, which was helpful to interpret the oil removal mechanism. Moreover, eminent effect on removal of large n-alkanes was achieved from the synergy between APG1214 and inorganic salts, which was opposite to the effect when they were added separately. This study demonstrated a promising way to remediate COCS with ecologically compatible surfactant and provided guidelines for its practical application.

Mei Han; Guodong Ji; Jinren Ni

2009-01-01T23:59:59.000Z

439

Combustion Model for a CFB Boiler with Consideration of Post-Combustion in the Cyclone  

Science Journals Connector (OSTI)

Severe post combustion in the cyclone of CFB boilers could destroy heat absorbing balance among ... rarely considered in the design phase of a CFB boiler. Based on our previous experiment results ... added into a...

S. H. Li; H. R. Yang; H. Zhang; Y. X. Wu…

2010-01-01T23:59:59.000Z

440

Control of Combustion Processes in an Internal Combustion Engine by Low-Temperature Plasma  

Science Journals Connector (OSTI)

A new method of operation of internal combustion engines enhances power and reduces fuel consumption and exhaust toxicity. Low-temperature plasma control combines working processes of thermal engines and steam machines into a single process.

E. A. Olenev

2002-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Control of Combustion Processes in an Internal Combustion Engine by Low-Temperature Plasma  

Science Journals Connector (OSTI)

A new method of operation of internal combustion engines enhances power and reduces fuel consumption and exhaust toxicity. Low-temperature plasma control combines working processes of thermal engines and steam...

E. A. Olenev

2002-07-01T23:59:59.000Z

442

Assessment of Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine  

Broader source: Energy.gov [DOE]

Various applied combustion and turbulence models were investigated along with chemical kinetic mechanisms simulating a biodiesel-fueled engine

443

Nuclear magnetic resonance (N.M.R.) studies of alkyl formates and of alcohol-water azeotropes  

E-Print Network [OSTI]

from Eq. 2 for 12 Alkyl Formates in Carbon tetrachloride at 37'. Typical N. M. R. Spectrum of a Non-Azeotropic Ethanol- Water Mixture . 16 N. M. R. Spectrum Occasionally Found for Azeotropic Ethanol-Water Mixtures 17 PART I. ALKYL FORMATES... CHAPTER I. INTRODUCTION 1 It has been shown that eq. 1 applies almost exactly to the data for the alkaline hydrolysis of 9 acetate eaters (CH COOR ) in 40% 0 aqueous p - dioxane at 35 . In eq. 1, k is the second-order rate log k = l. 35 + 0. 688 o + 0...

O'Brien, Patrick William

2012-06-07T23:59:59.000Z

444

High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate  

SciTech Connect (OSTI)

Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

None

2009-12-01T23:59:59.000Z

445

Some Experimental Studies of Oscillatory Combustion  

Science Journals Connector (OSTI)

Measurements of the perturbations in pressure as recorded by flush?mounted transducers during the combustion of mixtures of air and natural gas in a cooled copper tube at atmospheric pressure are reported for a range of mixture ratios. Also presented are the residual quantities of the oxides of nitrogen as well as the principal components of the products of reaction. The results indicate two stable modes of oscillation. One was found predominantly at mixture ratios above stoichiometric. There was a region near stoichiometric where both modes existed. The quantities of the residual oxides of nitrogen were from 10–30 times as large during oscillatory combustion as during relatively steady combustion. In addition measurements in a smaller cooled copper combustor at pressures up to 50 lb/sq in. absolute are recorded. Again two stable modes of oscillation were encountered and the double amplitude of the oscillation for the mode near stoichiometric was nearly five times as great as that away from stoichiometric. The influence of mixture ratio and rates of flow was explored. The quantities of the oxides of nitrogen were determined after quenching the products of reaction at rates of approximately 5° per ?sec. Again the presence of oscillatory combustion appeared to exert a pronounced influence on the presence of oxides of nitrogen. In the case of the high?pressure combustor the premixed fuel and oxidant were introduced through a supersonic converging?diverging nozzle to avoid coupling between the feed system and the combustor.

B. H. Sage

1963-01-01T23:59:59.000Z

446

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

447

Starting apparatus for internal combustion engines  

DOE Patents [OSTI]

This report is a patent description for a system to start an internal combustion engine. Remote starting and starting by hearing impaired persons are addressed. The system monitors the amount of current being drawn by the starter motor to determine when the engine is started. When the engine is started the system automatically deactivates the starter motor. Five figures are included.

Dyches, G.M.; Dudar, A.M.

1995-01-01T23:59:59.000Z

448

A MODEL FOR POROUS-MEDIUM COMBUSTION  

Science Journals Connector (OSTI)

......usually taken from experiments; Vo is determined by the inlet gas velocity under consideration, and for the typical combustion processes where Vo is parallel to the z-axis in which we are interested it is natural to choose V3o~0-1 to 1-Oms......

J. NORBURY; A. M. STUART

1989-02-01T23:59:59.000Z

449

Sandia National Laboratories Combustion Research Facility  

E-Print Network [OSTI]

Hydrogen & Combustion Technologies Department Livermore, CA DOE Hydrogen, Fuel Cells, and Infrastructure collector, compressor, high-P storage, pump, FC stack (efficiency vs power) · Developing: ICE gen-set, wind Borns, Scott Jones, Paul Pickard ­ Economic modeling of H2 unit cost · Production: reforming

450

Oxy-Combustion Boiler Material Development  

SciTech Connect (OSTI)

Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

2012-01-31T23:59:59.000Z

451

Oxy-Combustion Boiler Material Development  

SciTech Connect (OSTI)

Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year) data. The test program details and data are presented herein.

Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

2012-01-31T23:59:59.000Z

452

Combustion toxics: Available data and additional needs  

SciTech Connect (OSTI)

With the continuing expansion of air pollution regulations there is an increasing awareness of the potential need to assess the emissions and impact of trace compounds from combustion sources in refineries and chemical plants. It has been found that these trace compounds may be emitted as the result of incomplete fuel combustion, formation of new compounds during combustion, or the presence of inorganics (e.g., metals) in the fuel. Emission factors based on field data from these sources have recently been published by both the US Environmental Protection Agency (EPA) and the American Petroleum Institute (API). The emission factors indicate that a large number of trace compounds may be emitted from combustion sources including volatiles, semi-volatiles, PAHs, metals, and dioxins/furans. Some of these trace compounds have been classified as hazardous or toxic. A review of the EPA and API published data sets indicates that, while there is some overlap, many gaps exist in specific source and emission types. Where gaps exist, there is a lack of confirmation for the reported emission factor. Comparison of the EPA and API emission factors for gas and fuel oil fired boilers, however, indicates reasonable agreement for several metals and some PAHs where the data overlap. EPA, however, has sampled for many more metals than API and several EPA factors for PAHs are significantly higher than reported by API. Additionally tests may be warranted where there is insufficient overlap. Much additional work needs to be done to provide reliable factors which can be used to estimate trace toxic emissions from combustion. Many gaps and inconsistencies exist in the emission factors database and changes to existing factors are expected as the database is expanded.

Siegell, J.H.

2000-03-31T23:59:59.000Z

453

2009 Advanced Combustion Engine R&D Annual Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

COMBUSTION COMBUSTION ENGINE RESEARCH AND DEVELOPMENT annual progress report 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 Approved by Gurpreet Singh Team Leader, Advanced Combustion Engine R&D Office of Vehicle Technologies FY 2009 Progress rePort For AdvAnced combustion engine reseArcH And deveLoPment Energy Efficiency and Renewable Energy Office of Vehicle Technologies December 2009 U.S. Department of Energy 1000 Independence Avenue, S.W. Washington, D.C. 20585-0121 ii Advanced Combustion Engine Technologies FY 2009 Annual Progress Report

454

FEMP Technology Brief: Boiler Combustion Control and Monitoring System |  

Broader source: Energy.gov (indexed) [DOE]

Boiler Combustion Control and Monitoring Boiler Combustion Control and Monitoring System FEMP Technology Brief: Boiler Combustion Control and Monitoring System October 7, 2013 - 9:12am Addthis This composite photo shows technicians observing operation at the monitoring station and making subsequent fine adjustments on combustion system controls Technical staff are making boiler adjustments with the control and monitoring system. Photo courtesy of the Department of Defense's Environmental Security Technology Certification Program. Technology Description A novel combustion control system, along with gas sensors, sets the opening of fuel and air inlets based on flue-gas concentrations. Continuous feedback from measurements of oxygen, carbon monoxide, and nitrogen oxide concentrations enable the control system

455

Direct Functionalization of Arenes by Primary Alcohol Sulfonate Esters Catalyzed by Gold(III)  

E-Print Network [OSTI]

operating here. For electron-rich arenes, a gold(III)- mediated reaction, which seems to go through an SN2 in mediating reactions involving alkynes. In contrast, gold-catalyzed arene functionalization has been less also discovered a gold-catalyzed alkylation of arenes by epoxides.2b We report here a unique reaction

He, Chuan

456

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

457

Metathesis of tobacco fatty acid methyl esters: Generation of industrially important platform chemicals  

Science Journals Connector (OSTI)

Abstract Self-methathesis of vegetable oil based unsaturated fatty acids provide a renewable and convenient route for the preparation of a number of platform chemicals useful for the production of polymers, biolubricants and other industrial products. The present study is focused on the use of the unsaturated non-edible oil methyl esters of tobacco (Nicotiana tabacum 82.2%) self- metathesis. Metathesis was carried out reacting equimolar quantities of fatty acid methyl esters (6.8 mm) with Grubbs second generation catalyst (0.3 mm) at 40–45 °C for 36 h. The metathesized products were characterized using GC and GC–MS analysis. Self-metathesis of the tobacco methyl esters resulted in the formation of hydrocarbons, of which 9-octadecene (24%) and a cyclodecacyclododecene (19%) were found to be major. In addition 9-octadecenoic acid methyl ester (17%) and 9,12-octadecadienoic acid methyl esters (11%) were also observed. The study also discusses the molecules involved in the formation of the above intermediates which are useful for the preparation of a number of industrial products.

Yelchuri Vyshnavi; Rachapudi B.N. Prasad; Mallampalli S.L. Karuna

2013-01-01T23:59:59.000Z

458

Carbon?Oxygen Bond Forming Mechanisms in Rhenium Oxo-Alkyl Complexes  

SciTech Connect (OSTI)

Three C?X bond formation mechanisms observed in the oxidation of (HBpz{sub 3})ReO(R)(OTf) [HBpz{sub 3} = hydrotris(1-pyrazolyl)borate; R = Me, Et, and iPr; OTf = OSO{sub 2}CF{sub 3}] by dimethyl sulfoxide (DMSO) were investigated using quantum mechanics (M06//B3LYP DFT) combined with solvation (using the PBF Poisson?Boltzmann polarizable continuum solvent model). For R = Et we find the alkyl group is activated through ?-hydrogen abstraction by external base OTf{sup ?} with a free energy barrier of only 12.0 kcal/mol, leading to formation of acetaldehyde. Alternatively, ethyl migration across the M?O bond (leading to the formation of acetaldehyde and ethanol) poses a free energy barrier of 22.1 kcal/mol, and the previously proposed ?-hydrogen transfer to oxo (a 2+2 forbidden reaction) poses a barrier of 44.9 kcal/mol. The rate-determining step to formation of the final product acetaldehyde is an oxygen atom transfer from DMSO to the ethylidene, with a free energy barrier of 15.3 kcal/mol. When R = iPr, the alkyl 1,2-migration pathway becomes the more favorable pathway (both kinetically and thermodynamically), with a free energy barrier (?G{sup ?} = 11.8 kcal/mol) lower than ?-hydrogen abstraction by OTf{sup ?} (?G{sup ?} = 13.5 kcal/mol). This suggests the feasibility of utilizing this type of migration to functionalize M?R to M?OR. We also considered the nucleophilic attack of water and ammonia on the Re-ethylidene ?-carbon as a means of recovering two-electron-oxidized products from an alkane oxidation. Nucleophilic attack (with internal deprotonation of the nucleophile) is exothermic. However, the subsequent protonolysis of the Re?alkyl bond (to liberate an alcohol or amine) poses a barrier of 37.0 or 42.4 kcal/mol, respectively. Where comparisons are possible, calculated free energies agree very well with experimental measurements.

Cheng, Mu-Jeng; Nielsen, Robert J; Ahlquist, Marten; Goddard, William A

2010-01-01T23:59:59.000Z

459

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid B. L. Smiley and G. L. Richmond*  

E-Print Network [OSTI]

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid Interface B. L chain ordering in phosphatidylcholines (PCs) adsorbed from aqueous solution to a carbon tetrachloride-dimensional phases are discussed. Introduction Surfactant monolayers adsorbed at oil-water interfaces in biological

Richmond, Geraldine L.

460

Alkyl nitrate (C1-C3) depth profiles in the tropical Pacific Ocean E. E. Dahl,1,2  

E-Print Network [OSTI]

and distribution of tropo- spheric ozone. Atmospheric alkyl nitrates are normally associated with polluted air free radical processes initiated by radioactive decay or cosmic rays, enzymatically mediated reactions expedition in the equatorial Pacific, an equatorial maximum in atmospheric ethyl and isopropyl nitrate

Saltzman, Eric

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension  

Science Journals Connector (OSTI)

The reductive alkylation of thioamides by Grignard reagents in the presence of Ti(OiPr)4 is the subject of a study involving 20 different substrates. The influence of various parameters has been evaluated, showing notably that the yields of this ...

Fabien Hermant; Ewelina Urba?ska; Sarah Seizilles de Mazancourt; Thomas Maubert; Emmanuel Nicolas; Yvan Six

2014-07-28T23:59:59.000Z

462

The Absorption Spectra of Ethylene, Deutero-Ethylene and Some Alkyl-Substituted Ethylenes in the Vacuum Ultra-Violet  

Science Journals Connector (OSTI)

1 February 1940 research-article The Absorption Spectra of Ethylene, Deutero-Ethylene and Some Alkyl-Substituted Ethylenes in the Vacuum Ultra-Violet W. C. Price W. T. Tutte The Royal Society is collaborating with JSTOR to digitize...

1940-01-01T23:59:59.000Z

463

Reactions of r-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the  

E-Print Network [OSTI]

Reactions of r-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms (SN2) and base-induced elimination (E2). As the extent of substitution in the neutral reactants through a traditional SN2 transition state, followed by an elimination step in the SN2 product ion

Lineberger, W. Carl

464

Chapter 8 - Coal Combustion Residue Disposal Options  

Science Journals Connector (OSTI)

Abstract Coal combustion residues (CCRs) are presently regulated as solid waste (Subtitle D) under the Resource Conservation Recovery Act. Such classification promotes beneficial use by end-users i.e. mitigating excessive liability. According to the US Environmental Protection agency (USEPA), about 131 million tons of coal combustion residuals—including 71 million tons of fly ash, 20 million tons of bottom ash and boiler slag, and 40 million tons of flue gas desulfurization (FGD) material—were generated in the US in 2007. Of this, approximately 36% was disposed of in landfills, 21% was disposed of in surface impoundments, 38% was beneficially reused, and 5% was used as minefill. Stringent regulation, as Subtitle C (hazardous waste), would impose a perceived liability upon end-users; greatly reducing beneficial use opportunities. Mandatory use of synthetic liners—would not have prevented dike wall failure and fails to consider inherent engineering characteristics of CCRs.

Richard W. Goodwin

2014-01-01T23:59:59.000Z

465

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

466

Critical reaction rates in hypersonic combustion chemistry  

SciTech Connect (OSTI)

High Mach number flight requires that the scramjet propulsion system operate at a relatively low static inlet pressure and a high inlet temperature. These two constraints can lead to extremely high temperatures in the combustor, yielding high densities of radical species and correspondingly poor chemical combustion efficiency. As the temperature drops in the nozzle expansion, recombination of these excess radicals can produce more product species, higher heat yield, and potentially more thrust. The extent to which the chemical efficiency can be enhanced in the nozzle expansion depends directly on the rate of the radical recombination reactions. A comprehensive assessment of the important chemical processes and an experimental validation of the critical rate parameters is therefore required if accurate predictions of scramjet performance are to be obtained. This report covers the identification of critical reactions, and the critical reaction rates in hypersonic combustion chemistry. 4 refs., 2 figs.

Oldenborg, R.C.; Harradine, D.M.; Loge, G.W.; Lyman, J.L.; Schott, G.L.; Winn, K.R.

1989-01-01T23:59:59.000Z

467

Diesel Engine Combustion of Biomass Pyrolysis Oils  

Science Journals Connector (OSTI)

Biomass pyrolysis oils are manufactured through a moderate-temperature process (?500 °C) in which the biomass feedstock is subjected to rapid heating in the absence of air, where it vaporizes, cracks, and is condensed after a short residence time (?500 ms) into a dark brown liquid composed of a complex mixture of oxygenated hydrocarbons whose heating value is approximately half that of No. 2 diesel fuel. ... The combustion air inlet temperature can be preheated up to 130 °C through the use of an in-line electric heater, which allows engine operation with fuels that have long ignition delay, without relying on any ignition additives. ... Their data showed that in addition to reducing the peak heat release magnitude, slower chemical kinetics resulted in reduced rate of instantaneous heat release (the slope of the instantaneous heat release curve) in the early combustion phase, resulting in delayed peak heat release timing relative to SOC. ...

Alan Shihadeh; Simone Hochgreb

2000-02-15T23:59:59.000Z

468

Fluidized bed combustion picks up steam  

SciTech Connect (OSTI)

Industrial interest in fluidized-bed combustion (FBC) continues, although the technology has been slow to enter the marketplace. Two FBC pilot plants funded by DOE and one commercial size project are in operation. FBC designs and commercial warranties are already available from the boiler industry, but 1981 was the first year to see significant numbers of privately-funded orders, now numbering 38 out of 50 boilers. Manufacturers are working on a universal boiler able to accept any fuel, but potential users are wary of new technology without a long-term demonstration of reliability and economics. There is interest in second generation designs, a new shallow-bed design suitable for retrofitting, and circulating bed types that decouple the combustion system from the heat removal system. (DCK)

Lawn, J.

1982-02-01T23:59:59.000Z

469

ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) |  

Open Energy Info (EERE)

ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) Jump to: navigation, search Project Name ESTER, Enel integrated System for TEsts on stoRage Country Italy Headquarters Location Livorno, Italy Coordinates 43.551876°, 10.308011° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":43.551876,"lon":10.308011,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

470

Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications  

SciTech Connect (OSTI)

This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States)

1996-12-31T23:59:59.000Z

471

Experimental investigations on diesel engine fuelled with methyl esters of cotton seed oil  

Science Journals Connector (OSTI)

In this investigation, cotton seed methyl ester (CSME) was prepared by transesterification using potassium hydroxide (KOH) as catalyst. The engine performance was analysed with different blends of biodiesel and was compared with neat diesel. It was concluded that the lower blends of biodiesel are closer to diesel as far as thermal efficiency is concerned. In the lower blends, the brakes specific fuel consumption is also comparatively reduced. The smoke density also increases for the blends of methyl ester of cotton seed oil diesel compared to neat diesel operation. The oxides of nitrogen (NOx) emission level are decreased with the blends of methyl ester of cotton seed oil compared to neat diesel. The results proved that the use of biodiesel (produced from cotton seed oil) in compression ignition engine is a viable alternative to diesel.

M. Saravanan; A. Anbarasu; M. Loganathan

2013-01-01T23:59:59.000Z

472

Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production  

SciTech Connect (OSTI)

Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

2006-04-19T23:59:59.000Z

473

Advanced Combustion R&D Selections  

Broader source: Energy.gov [DOE]

In 2013, the Department of Energy made several project selections under the Fossil Energy Advanced Combustion R&D program. Through these four selections, nearly $37 million, $26 million from the Energy Department and $11 million in cost-share from industry, universities, and other research institutions, are being committed over four years to address CO2 compliance required by the proposed regulations to reduce CO2 emissions.

474

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

475

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

476

Marine propulsion device internal combustion engine  

SciTech Connect (OSTI)

This patent describes an internal combustion engine. It comprises an engine block including a surface, means including the engine block surface for defining a substantially sealed chamber, and pressure relief means including a movable valve member for venting the chamber when the pressure in the chamber exceeds a predetermined value, the chamber containing one of the following: a flywheel, means for generating an electrical current, a finned heat exchanger, and means for starting the engine.

Anderson, P.A.; Bernau, W.A.; Breckenfeld, P.W.; Broughton, G.L.

1992-01-07T23:59:59.000Z

477

Fluid Bed Combustion Applied to Industrial Waste  

E-Print Network [OSTI]

of its relatively recent application to coal fired steam production, fluid beds have been uti lized in industry for over 60 years. Beginning in Germany in the twenties for coal gasification, the technology was applied to catalytic cracking of heavy... system cost), use of minimum excess air required, and maintaining the min"imum reactor temperature neces sary to sustain combustion. For superautogenous fuels, where incineration. only is desired, minimum capital cost is achieved by using direct bed...

Mullen, J. F.; Sneyd, R. J.

478

Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles  

SciTech Connect (OSTI)

The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanos

Lawler, Katherine

2009-08-05T23:59:59.000Z

479

Real-Time Combustion Controls and Diagnostics Sensors (CCADS)  

SciTech Connect (OSTI)

The present invention is directed to an apparatus for the monitoring of the combustion process within a combustion system. The apparatus comprises; a combustion system, a means for supplying fuel and an oxidizer, a device for igniting the fuel and oxidizer in order to initiate combustion, and a sensor for determining the current conducted by the combustion process. The combustion system comprises a fuel nozzle and an outer shell attached to the combustion nozzle. The outer shell defines a combustion chamber. Preferably the nozzle is a lean premix fuel nozzle (LPN). Fuel and an oxidizer are provided to the fuel nozzle at separate rates. The fuel and oxidizer are ignited. A sensor positioned within the combustion system comprising at least two electrodes in spaced-apart relationship from one another. At least a portion of the combustion process or flame is between the first and second electrodes. A voltage is applied between the first and second electrodes and the magnitude of resulting current between the first and second electrodes is determined.

Thornton, J.D.; Richard, G.A.; Dodrill, K.A.; Nutter, R.S. Jr; Straub, D.

2005-05-03T23:59:59.000Z

480

Coal combustion science. Quarterly progress report, April 1993--June 1993  

SciTech Connect (OSTI)

This document is a quarterly status report of the Coal Combustion Science Project that is being conducted at the Combustion Research Facility, Sandia National Laboratories. The information reported is for Apr-Jun 1993. The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the PETC Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. The objective of the kinetics and mechanisms of pulverized coal char combustion task is to characterize the combustion behavior of selected US coals under conditions relevant to industrial pulverized coal-fired furnaces. Work is being done in four areas: kinetics of heterogeneous fuel particle populations; char combustion kinetics at high carbon conversion; the role of particle structure and the char formation process in combustion and; unification of the Sandia char combustion data base. This data base on the high temperature reactivities of chars from strategic US coals will permit identification of important fuel-specific trends and development of predictive capabilities for advanced coal combustion systems. The objective of the fate of inorganic material during coal combustion task is the establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of inorganic material during coal combustion as a function of coal type, particle size and temperature, the initial forms and distribution of inorganic species in the unreacted coal, and the local gas temperature and composition. In addition, optical diagnostic capabilities are being developed for in situ, real-time detection of inorganic vapor species and surface species during ash deposition. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

Hardesty, D.R. [ed.

1994-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "alkyl ester combustible" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Electronic governor for an internal combustion engine  

SciTech Connect (OSTI)

An electronic governor for an internal combustion engine provided with a fuel injection pump for supplying fuel to the engine and having a control rack for adjusting fuel injection amount is described comprising, means providing a designated speed signal Vno indicative of the desired rotational speed No of the internal combustion engine, a speed detector detecting the rotational speed N of the internal combustion engine and producing the speed detection signal Vn indicative of the rotational speed N, a rack position detector detecting the position of the rack and producing a rack position detection signal VL indicative of the position of the rack, a speed deviation operation circuit responsive to the speed detection signal Vn for producing a constant speed control signal Vnd for effecting control to maintain the deviation of the actual rotational speed N from the designated rotational speed No within a permissible range, a rack position deviation operation circuit for producing a maximum rack position control signal VLd for effecting control to maintain the deviation of the rack position, a control mode selector and means responsive to the output of the control mode selector for controlling the rack to cause the deviation of the actual rotational speed N from the designated rotational speed No or the rack position from the maximum rack position to be within a certain range.

Nanjyo, H.; Suzuki, H.

1987-11-24T23:59:59.000Z

482

In situ combustion field experiences in Venezuela  

SciTech Connect (OSTI)

A literature review of four in situ combustion projects: in Miga, Tia Juana, Melones and Morichal fields in Venezuela was made, and a summary of these projects is presented. Reservoir description and project performance data were analyzed. The behavior of the four in situ combustion field tests can be summarized as follows: The problems most often encountered were corrosion and high temperature producing wells. The direction in which the burning front moved was guided essentially by reservoir characteristics. The produced oil was upgraded by about 4{degrees} API, and viscosity was substantially reduced. For Mirochal and Miga fields, the analyses of available information from the combustion projects indicated that the process has been successful in the affected region. Conclusions from this review indicate that the two most frequent problems encountered were operational problems in producing wells and the direction of the burning front. The heterogeneous nature of the sands probably resulted in the burning front moving in a preferential direction, hence reducing areal sweep efficiency.

Villalba, M.; Estrada, M.; Bolivar, J. [INTEVEP, Caracas (Venezuela)

1995-02-01T23:59:59.000Z

483

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

484

Optimization of extraction of high-ester pectin from passion fruit peel (Passiflora edulis flavicarpa) with citric acid by using  

E-Print Network [OSTI]

Optimization of extraction of high-ester pectin from passion fruit peel (Passiflora edulis for extraction of high-ester yellow passion fruit pectin. Ă? 2007 Elsevier Ltd. All rights reserved. Keywords: Pectin extraction; Passion fruit peel; Degree of esterification; Response surface methodology; Central

Ferreira, Márcia M. C.

485

A comparative study of Al2O3 coated LHR engine characteristic using rice bran and mahua methyl ester as a fuel  

Science Journals Connector (OSTI)

In this study, for the first time, a nano material of Al2O3 was used as ceramic layer in low heat rejection engine concepts. The coating was carried out by plasma spray method on the combustion chamber surfaces (cylinder head, cylinder liner, valves and crown surfaces) of the DI diesel engine. A comparative evaluation of Al2O3 coated engine was carried out between two types of biodiesel (methyl ester of rice bran and mahua oil) and diesel. Experiments were conducted on single cylinder, four strokes, water cooled and direct injection diesel engine. The test run was also repeated for uncoated engine and compared. The results indicated that, an increase in engine power (6.3-11.4%) and decrease in specific fuel consumption (0.8-10.9%), as well as significant improvements in exhaust gas emissions (except NOx) and smoke opacity (19.6-28.9%) were observed in Al2O3 coated engine compared with that of the uncoated engine.

M. Mohamed Musthafa; S.P. Sivapirakasam; M. Udayakumar

2012-01-01T23:59:59.000Z

486

Hybrid Combustion-Gasification Chemical Looping  

SciTech Connect (OSTI)

For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2} separation, and also syngas production from coal with the calcium sulfide (CaS)/calcium sulfate (CaSO{sub 4}) loop utilizing the PDU facility. The results of Phase I were reported in Reference 1, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase I Report' The objective for Phase II was to develop the carbonate loop--lime (CaO)/calcium carbonate (CaCO{sub 3}) loop, integrate it with the gasification loop from Phase I, and ultimately demonstrate the feasibility of hydrogen production from the combined loops. The results of this program were reported in Reference 3, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase II Report'. The objective of Phase III is to operate the pilot plant to obtain enough engineering information to design a prototype of the commercial Chemical Looping concept. The activities include modifications to the Phase II Chemical Looping PDU, solids transportation studies, control and instrumentation studies and additional cold flow modeling. The deliverable is a report making recommendations for preliminary design guidelines for the prototype plant, results from the pilot plant testing and an update of the commercial plant economic estimates.

Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

2009-01-07T23:59:59.000Z

487

Pre-Combustion Carbon Capture Research | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-Combustion Carbon Capture Research Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and oxygen/air under high temperature and pressure to form synthesis gas. This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller amounts of other gaseous components, such as methane. The syngas can then undergo the water-gas shift reaction to convert CO and water (H2O) to H2 and CO2, producing a H2 and CO2-rich gas mixture. The concentration of CO2 in this mixture can range from 15-50%. The CO2 can then be captured and separated, transported, and ultimately sequestered, and the H2-rich fuel combusted.

488

CO2 Emissions from Fuel Combustion | Open Energy Information  

Open Energy Info (EERE)

CO2 Emissions from Fuel Combustion CO2 Emissions from Fuel Combustion Jump to: navigation, search Tool Summary Name: CO2 Emissions from Fuel Combustion Agency/Company /Organization: International Energy Agency Sector: Energy Topics: Baseline projection, GHG inventory Resource Type: Dataset, Publications Website: www.iea.org/co2highlights/co2highlights.pdf CO2 Emissions from Fuel Combustion Screenshot References: CO2 Emissions from Fuel Combustion[1] Overview "This annual publication contains: estimates of CO2 emissions by country from 1971 to 2008 selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh CO2 emissions from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References ↑ "CO2 Emissions from Fuel Combustion"

489

NREL: Vehicles and Fuels Research - Fuel Combustion Lab  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Combustion Lab Fuel Combustion Lab NREL's Fuel Combustion Laboratory focuses on characterizing fuels at the molecular level. This information can then be used to understand and predict the fuel's effect on engine performance and emissions. By understanding the effects of fuel chemistry on ignition we can develop fuels that enable more efficient engine designs, using both today's technology and future advanced combustion concepts. This lab supports the distributed Renewable Fuels and Lubricants (ReFUEL) Laboratory, and the Biofuels activity. Photo of assembled IQT. Ignition Quality Tester The central piece of equipment in the Fuel Combustion Laboratory is the Ignition Quality Tester (IQT(tm)). The IQT(tm) is a constant volume combustion vessel that is used to study ignition properties of liquid

490

Theoretical Adiabatic Temperature and Chemical Composition of Sodium Combustion Flame  

SciTech Connect (OSTI)

Sodium fire safety analysis requires fundamental combustion properties, e.g., heat of combustion, flame temperature, and composition. We developed the GENESYS code for a theoretical investigation of sodium combustion flame.Our principle conclusions on sodium combustion under atmospheric air conditions are (a) the maximum theoretical flame temperature is 1950 K, and it is not affected by the presence of moisture; the uppermost limiting factor is the chemical instability of the condensed sodium-oxide products under high temperature; (b) the main combustion product is liquid Na{sub 2}O in dry air condition and liquid Na{sub 2}O with gaseous NaOH in moist air; and (c) the chemical equilibrium prediction of the residual gaseous reactants in the flame is indispensable for sodium combustion modeling.

Okano, Yasushi; Yamaguchi, Akira [O-arai Engineering Center (Japan)

2003-12-15T23:59:59.000Z

491

Method of controlling cyclic variation in engine combustion  

DOE Patents [OSTI]

Cyclic variation in combustion of a lean burning engine is reduced by detecting an engine combustion event output such as torsional acceleration in a cylinder (i) at a combustion event (k), using the detected acceleration to predict a target acceleration for the cylinder at the next combustion event (k+1), modifying the target output by a correction term that is inversely proportional to the average phase of the combustion event output of cylinder (i) and calculating a control output such as fuel pulse width or spark timing necessary to achieve the target acceleration for cylinder (i) at combustion event (k+1) based on anti-correlation with the detected acceleration and spill-over effects from fueling. 27 figs.

Davis, L.I. Jr.; Daw, C.S.; Feldkamp, L.A.; Hoard, J.W.; Yuan, F.; Connolly, F.T.

1999-07-13T23:59:59.000Z

492

FY 2008 Progress Report for Advanced Combustion Engine Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

COMBUSTION COMBUSTION ENGINE TECHNOLOGIES annual progress report 2008 V e h i c l e T e c h n o l o g i e s P r o g r a m U.S. Department of Energy 1000 Independence Avenue, S.W. Washington, D.C. 20585-0121 FY 2008 Progress rePort For AdvAnced combustion engine technologies Energy Efficiency

493

Mercury Release and Speciation in Chemical Looping Combustion of Coal  

Science Journals Connector (OSTI)

Mercury Release and Speciation in Chemical Looping Combustion of Coal ... In the in situ Gasification Chemical Looping Combustion of coal (iG-CLC), the fuel is gasified in situ in the fuel reactor and gasification products are converted to CO2 and H2O by reaction with the oxygen carrier. ... This work is the first study on mercury release in Chemical Looping Combustion of coal. ...

T. Mendiara; M. T. Izquierdo; A. Abad; P. Gayán; F. García-Labiano; L. F. de Diego; J. Adánez

2014-03-06T23:59:59.000Z

494

Emissions Characterization from Advanced Combustion & Alternative Fuels -  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Emissions Characterization from Advanced Combustion & Emissions Characterization from Advanced Combustion & Alternative Fuels Exhaust emissions from engines operating in advanced combustion modes such as PCCI (Premixed Charge Compression Ignition) and HCCI (Homogeneous Charge Compression Ignition) are analyzed with an array of analytical tools. Furthermore, emissions from a variety of alternative fuels and mixtures thereof with conventional gasoline and diesel fuels are also measured. In addition to measuring the criteria pollutants nitrogen oxides (NOx), carbon monoxide (CO), hydrocarbons (HCs) are also measured and categorized based on chemistry. These chemical details of the emissions provide important information for optimizing combustion processes to maximize fuel efficiency while minimizing emissions

495

Computationally Efficient Modeling of High-Efficiency Clean Combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Peer Evaluation ace012aceves2011o.pdf More Documents & Publications Simulation of High Efficiency Clean Combustion Engines and Detailed Chemical Kinetic Mechanisms Development...

496

Fuel Effects on Ignition and Their Impact on Advanced Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Ignition and Their Impact on Advanced Combustion Engines Joshua D. Taylor - National Renewable Energy Laboratory Stuart Neill, Hailin Li - National Research Council Canada...

497

A University Consortium on Low Temperature Combustion (LTC) for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines A University Consortium on High Pressure, Lean Combustion for Efficient and Clean IC...

498

Fuels Performance: Navigating the Intersection of Fuels and Combustion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemistry, ignition kinetics, combustion, and emissions, with innovative approaches to engines and fuels that meet drivers' expectations, while minimizing petroleum use and GHGs....

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OLCF Researcher to Work with Clean Combustion Center at Saudi...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with Engine Knock Research Researchers at the King Abdullah University of Science and Technology Clean Combustion Research Center and ORNL are using supercomputer simulations...

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New Argonne initiative to examine the details of the combustion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

New Argonne initiative to examine the details of the combustion process By Jared Sagoff * July 15, 2014 Tweet EmailPrint ARGONNE, Ill. - Every science experiment and every...