National Library of Energy BETA

Sample records for alkyl ester combustible

  1. Method of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian

    2010-09-14

    Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

  2. Methods of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian

    2010-08-03

    A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.

  3. Alkylate

    U.S. Energy Information Administration (EIA) Indexed Site

    Day) Product: Alkylate Aromatics Asphalt & Road Oil Isomers Isobutane Isopentane & Isohexane Isooctane Lubricants Marketable Petroleum Coke Hydrogen Sulfur Period: Annual (as of January 1) Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2011 2012 2013 2014 2015 2016 View History U.S. 1,262,443 1,246,875 1,269,361 1,266,352 1,267,246 1,286,012 1982-2016 PAD District 1 108,629 79,429 91,429 83,429

  4. Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a Motored Engine

    Broader source: Energy.gov [DOE]

    The alkyl chain of fatty acid esters experience the typical paraffin-like low temperature oxidation sequence; the alkyl chain length of fatty acid esters has a crucial impact on the ignition behavior of fatty acid esters

  5. Effects of Turbulence on the Combustion Properties of Partially Premixed Flames of Canola Methyl Ester and Diesel Blends

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhamale, N.; Parthasarathy, R. N.; Gollahalli, S. R.

    2011-01-01

    Canola methyl ester (CME) is a biofuel that is a renewable alternative energy resource and is produced by the transesterification of canola oil. The objective of this study was to document the effects of turbulence on the combustion characteristics of blends of CME and No 2 diesel fuel in a partially-premixed flame environment. The experiments were conducted with mixtures of pre-vaporized fuel and air at an initial equivalence ratio of 7 and three burner exit Reynolds numbers, 2700, 3600, and 4500. Three blends with 25, 50, and 75% volume concentration of CME were studied. The soot volume fraction was highestmore » for the pure diesel flames and did not change significantly with Reynolds number due to the mutually compensating effects of increased carbon input rate and increased air entrainment as the Reynolds number was increased. The global NOx emission index was highest and the CO emission index was the lowest for the pure CME flame, and varied non-monotonically with biofuel content in the blend The mean temperature and the NOx concentration at three-quarter flame height were generally correlated, indicating that the thermal mechanism of NOx formation was dominant in the turbulent biofuel flames also.« less

  6. Carbomethoxyethylation of aryl and alkyl bromides catalyzed by nickel complexes

    SciTech Connect (OSTI)

    Lebedev, S.A.; Lopatina, V.S.; Berestova, S.S.; Petrov, E.S.; Beletskaya, I.P.

    1986-12-10

    The reaction of aryl and alkyl bromides with methyl acrylate in the presence of water, pyridine, and a nickel catalyst results in the formation of saturated conjugate-addition products, viz. methyl esters of aryl- and alkyl-propionic acids.

  7. Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a Motored Engine Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a Motored Engine qThe alkyl chain ...

  8. PREPARATION OF ALKYL PYROPHOSPHATE EXTRACTANTS

    DOE Patents [OSTI]

    Levine, C.A.; Skiens, W.E.; Moore, G.R.

    1960-08-01

    A process for providing superior solvent extractants for metal recovery processes is given wherein the extractant comprises an alkyl pyrophosphoric acid ester dissolved in an organic solvent diluent. Finely divided solid P/sub 2/O/ sub 5/ is slurried in an organic solvent-diluent selected from organic solvents such as kerosene, benzene, chlorobenzene, toluene, etc. An alcohol selected from the higher alcohols having 4 to 17 carbon atoms. e.g.. hexanol-1. heptanol-3, octanol-1. 2.6-dimethyl-heptanol-4, and decanol-1, is rapidly added to the P/sub 2/O/sub 5/ slurry in the amount of about 2 moles of alcohol to 1 mole of P/sub 2/ O/sub 5/. The temperature is maintained below about 110 deg C during the course of the P/sub 2/O/sub 5/-alcohol reaction. An alkyl pyrophosphate extractant compound is formed as a consequence of the reaction process. The alkyl pyrophosphate solvent-diluent extractant phase is useful in solvent extraction metal recovery processes.

  9. Chemistry: Theory - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theory Chemistry: Theory Presentations from 2010 CEFRC First Annual Conference MultireferenceCorrelated WavefunctionCalculations and Reaction Flux Analyses of Methyl Ester Combustion Emily A. Carter, Princeton University Constructing Accurate Combustion Chemistry Models William H. Green, MIT Theoretical Gas Phase Chemical Kinetics Stephen J. Klippenstein, Argonne National Laboratory Theoretical Chemical Kinetics and Combustion Modeling James A. Miller, Argonne National Laboratory Computation of

  10. DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Chemistry/DISI Combustion DISI Combustion admin 2015-10-28T02:44:30+00:00

  11. Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels/Spray Combustion Spray Combustion admin 2015-10-28T02:17:06+00:00

  12. Turbulent Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  13. Combustion Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  14. Mild Catalytic methods for Alkyl-Alkyl Bond Formation

    SciTech Connect (OSTI)

    Vicic, David A

    2009-08-10

    Overview of Research Goals and Accomplishments for the Period 07/01/06 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes

  15. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc

    1999-01-01

    A process of preparing an acid addition salt of delta-aminolevulinic acid comprising: dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures thereof to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing said alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  16. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, L.

    1999-05-25

    A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  17. Combustion Kinetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The chemistry that drives combustion is a highly complicated web of reactions. To describe the combustion of a single fuel compound, say iso-octane, in full chemical detail ...

  18. Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate

    SciTech Connect (OSTI)

    Melánová, Klára; Beneš, Ludvík; Trchová, Miroslava; Svoboda, Jan; Zima, Vítězslav

    2013-06-15

    A set of layered ester and amide derivatives of titanium(IV) carboxymethylphosphonate was prepared by solvothermal treatment of amorphous titanium(IV) carboxymethylphosphonate with corresponding 1-alkanols, 1,ω-alkanediols, 1-aminoalkanes, 1,ω-diaminoalkanes and 1,ω-amino alcohols and characterized by powder X-ray diffraction, IR spectroscopy and thermogravimetric analysis. Whereas alkyl chains with one functional group form bilayers tilted to the layers, 1,ω-diaminoalkanes and most of 1,ω-alkanediols form bridges connecting the adjacent layers. In the case of amino alcohols, the alkyl chains form bilayer and either hydroxyl or amino group is used for bonding. This simple method for the synthesis of ester and amide derivatives does not require preparation of acid chloride derivative as a precursor or pre-intercalation with alkylamines and can be used also for the preparation of ester and amide derivatives of titanium carboxyethylphosphonate and zirconium carboxymethylphosphonate. - Graphical abstract: Ester and amide derivatives of layered titanium carboxymethylphosphonate were prepared by solvothermal treatment of amorphous solid with alkanol or alkylamine. - Highlights: • Ester and amide derivatives of titanium carboxymethylphosphonate. • Solvothermal treatment of amorphous solid with alkanol or alkylamine. • Ester and amide formation confirmed by IR spectroscopy.

  19. Sealed Combustion

    SciTech Connect (OSTI)

    2009-05-12

    This information sheet discusses the benefits of sealed combustion appliance units in order to ensure good indoor air quality.

  20. 2010 1st Annual CEFRC Conference - Combustion Energy Frontier Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center 0 1st Annual CEFRC Conference First Annual Conference, CEFRC Sept 23-24, 2010, Princeton, NJ SESSION CHAIRS: Wade Sisk, Department of Energy Chung K. Law, Combustion Energy Frontier Research Center (CEFRC) Announcements Overview of CEFRC Chemistry: Theory Multi-reference Correlated Wavefunction Calculations and Reaction Flux Analyses of Methyl Ester Combustion Emily A. Carter, Princeton University Computation of Accurate Thermochemical and Rate Parameters for Complex Combustion

  1. Process for removing NO sub x emissions from combustion effluents

    SciTech Connect (OSTI)

    Ham, D.O.; Moniz, G.A.; Gouveia, M.J.

    1992-06-09

    This patent describes a method of removing NO from a stream of combustion products injecting an alkyl amine into the stream to effect reduction of NO to N{sub 2}, wherein the alkyl amine comprises methyl amine, and the process is conducted at a temperature within the range of 350{degrees} C at a molar ratio to amine within the range of about 0.2 to 2.0 without a NO reduction catalyst, the method being capable of at least about a 50% conversion of NO in the combustion products to N{sub 2}.

  2. Ether and ester derivatives of the perborate icosahedron

    DOE Patents [OSTI]

    Hawthorne, M. Frederick; Peymann, Toralf; Maderna, Andreas

    2003-12-16

    New boron icosahedral ethers and esters formed from Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ],; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by reacting the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with an acid anhdride or acid chloride to form the ester or an alkylating agent to form the ether.

  3. Computational Combustion

    SciTech Connect (OSTI)

    Westbrook, C K; Mizobuchi, Y; Poinsot, T J; Smith, P J; Warnatz, J

    2004-08-26

    Progress in the field of computational combustion over the past 50 years is reviewed. Particular attention is given to those classes of models that are common to most system modeling efforts, including fluid dynamics, chemical kinetics, liquid sprays, and turbulent flame models. The developments in combustion modeling are placed into the time-dependent context of the accompanying exponential growth in computer capabilities and Moore's Law. Superimposed on this steady growth, the occasional sudden advances in modeling capabilities are identified and their impacts are discussed. Integration of submodels into system models for spark ignition, diesel and homogeneous charge, compression ignition engines, surface and catalytic combustion, pulse combustion, and detonations are described. Finally, the current state of combustion modeling is illustrated by descriptions of a very large jet lifted 3D turbulent hydrogen flame with direct numerical simulation and 3D large eddy simulations of practical gas burner combustion devices.

  4. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-05

    Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.

  5. Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Duty/Spray Combustion Spray Combustion admin 2015-10-28T02:00:56+00:00 Optically accessible high-temperature, high-pressure spray chamber Optically accessible high-temperature, high-pressure spray chamber Fuel spray injection is expected to be one of the key elements for enabling high-efficiency, low-emission engines of the future. Understanding the details of the spray combustion process is therefore now more important than ever. But investigating engine combustion processes is

  6. Advanced Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to ... development of large-scale Ni-based superalloy castings for power plant applications. ...

  7. Poly(ethyleneoxide) functionalization through alkylation (Patent...

    Office of Scientific and Technical Information (OSTI)

    A new and efficient method of functionalizing high molecular weight polymers through alkylation using a metal amide base is described. This novel procedure can also be used to ...

  8. Theory Of Alkyl Terminated Silicon Quantum Dots

    SciTech Connect (OSTI)

    Reboredo, F; Galli, G

    2004-08-19

    We have carried out a series of ab-initio calculations to investigate changes in the optical properties of Si quantum dots as a function of surface passivation. In particular, we have compared hydrogen passivated dots with those having alkyl groups at the surface. We find that, while on clusters with reconstructed surfaces a complete alkyl passivation is possible, steric repulsion prevents full passivation of Si dots with unreconstructed surfaces. In addition, our calculations show that steric repulsion may have a dominant effect in determining the surface structure, and eventually the stability of alkyl passivated clusters, with results dependent on the length of the carbon chain. Alkyl passivation weakly affects optical gaps of silicon quantum dots, while it substantially decreases ionization potentials and electron affinities and affect their excited state properties. On the basis of our results we propose that alkyl terminated quantum dots may be size selected taking advantage of the change in ionization potential as a function of the cluster size.

  9. Combustion Engine

    Broader source: Energy.gov [DOE]

    Pictured here is an animation showing the basic mechanics of how an internal combustion engine works. With support from the Energy Department, General Motors researchers developed a new technology ...

  10. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  11. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1994-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  12. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  13. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.

    1989-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  14. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  15. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  16. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  17. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  18. Applied combustion

    SciTech Connect (OSTI)

    1993-12-31

    From the title, the reader is led to expect a broad practical treatise on combustion and combustion devices. Remarkably, for a book of modest dimension, the author is able to deliver. The text is organized into 12 Chapters, broadly treating three major areas: combustion fundamentals -- introduction (Ch. 1), thermodynamics (Ch. 2), fluid mechanics (Ch. 7), and kinetics (Ch. 8); fuels -- coal, municipal solid waste, and other solid fuels (Ch. 4), liquid (Ch. 5) and gaseous (Ch. 6) fuels; and combustion devices -- fuel cells (Ch. 3), boilers (Ch. 4), Otto (Ch. 10), diesel (Ch. 11), and Wankel (Ch. 10) engines and gas turbines (Ch. 12). Although each topic could warrant a complete text on its own, the author addresses each of these major themes with reasonable thoroughness. Also, the book is well documented with a bibliography, references, a good index, and many helpful tables and appendices. In short, Applied Combustion does admirably fulfill the author`s goal for a wide engineering science introduction to the general subject of combustion.

  19. An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion

    SciTech Connect (OSTI)

    Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

    2010-02-19

    Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

  20. Biodiesel - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biodiesel Biodiesel Goals Develop accurate multi-scale models and experimental methods for quantitative combustion modeling of methyl esters and biodiesels at current and future engine conditions. Deliverables Obtain new experiment data of elementary reaction rates, ignition delay times, extinction limits, and speciation in broad temperature and pressure ranges. Develop quantum computational schemes for chemically accurate prediction of elementary reaction rates, activation energies, and bond

  1. Biofuels combustion*

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Westbrook, Charles K.

    2013-01-04

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acidsmore » and used primarily to replace or supplement conventional diesel fuels. As a result, research efforts on so-called second- and third-generation biofuels are discussed briefly.« less

  2. Biofuels combustion*

    SciTech Connect (OSTI)

    Westbrook, Charles K.

    2013-01-04

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. As a result, research efforts on so-called second- and third-generation biofuels are discussed briefly.

  3. Solid Catalyst - Alkylation - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Find More Like This Return to Search Solid Catalyst - Alkylation Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary This is a method used to reactivate solid/liquid catalysts used in INL's super critical process to produce alkylates. The method brings the catalyst into contact with the designated fluid that serves as the reactivating agent and has the density to dissolve the impurities. The process reactivates the

  4. DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Automotive/DISI Combustion DISI Combustion admin 2015-10-28T02:06:42+00:00 DISI engine in all-metal configuration with lower oil-collection cylinder installed. DISI engine in all-metal configuration with lower oil-collection cylinder installed. In order to reduce our dependence on petroleum and to reduce CO2emissions, it is important to both supplement traditional gasoline with renewable fuels and to improve the fuel efficiency of automotive engines. Under the Energy Independence and Security

  5. DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels/DISI Combustion DISI Combustion admin 2015-10-28T02:15:13+00:00 In order to reduce our dependence on petroleum and to reduce CO2emissions, it is important to both supplement traditional gasoline with renewable fuels and to improve the fuel efficiency of automotive engines. Under the Energy Independence and Security Act (EISA) of 2007, the volume of renewable fuel required to be blended into transportation fuel will increase from 9 billion gallons in 2008 to 36 billion gallons by 2022. At

  6. Sandia Energy - Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spray Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Fuels Spray Combustion Spray CombustionAshley Otero2015-10-28T02:17:06+00:00 Fuel...

  7. Sandia Energy - DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DISI Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Automotive DISI Combustion DISI CombustionAshley Otero2015-10-28T02:06:42+00:00 DISI...

  8. Sandia Energy - DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DISI Combustion Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry DISI Combustion DISI CombustionAshley Otero2015-10-28T02:44:30+00:00...

  9. Sandia Energy - Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spray Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Automotive Spray Combustion Spray CombustionAshley Otero2015-10-28T02:10:49+00:00...

  10. Sandia Energy - Spray Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spray Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Heavy Duty Spray Combustion Spray CombustionAshley Otero2015-10-28T02:00:56+00:00...

  11. Sandia Energy - DISI Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DISI Combustion Home Transportation Energy Predictive Simulation of Engines Engine Combustion Fuels DISI Combustion DISI CombustionAshley Otero2015-10-28T02:15:13+00:00 In order to...

  12. Chemical Kinetic Models for HCCI and Diesel Combustion

    SciTech Connect (OSTI)

    Pitz, W J; Westbook, C K; Mehl, M

    2008-10-30

    Hydrocarbon fuels for advanced combustion engines consist of complex mixtures of hundreds or even thousands of different components. These components can be grouped into a number of chemically distinct classes, consisting of n-paraffins, branched paraffins, cyclic paraffins, olefins, oxygenates, and aromatics. Biodiesel contains its own unique chemical class called methyl esters. The fractional amounts of these chemical classes are quite different in gasoline, diesel fuel, oil-sand derived fuels and bio-derived fuels, which contributes to the very different combustion characteristics of each of these types of combustion systems. The objectives of this project are: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

  13. Combustion Energy Research Fellows - Combustion Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Energy Research Fellows Combustion Energy Research Fellows Enoch Dames Co-sponsored by Professor William H. Green, MIT, Professor Ronald K. Hanson, Stanford University, ...

  14. Turbulent combustion

    SciTech Connect (OSTI)

    Talbot, L.; Cheng, R.K.

    1993-12-01

    Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

  15. Regenerative combustion device

    DOE Patents [OSTI]

    West, Phillip B.

    2004-03-16

    A regenerative combustion device having a combustion zone, and chemicals contained within the combustion zone, such as water, having a first equilibrium state, and a second combustible state. Means for transforming the chemicals from the first equilibrium state to the second combustible state, such as electrodes, are disposed within the chemicals. An igniter, such as a spark plug or similar device, is disposed within the combustion zone for igniting combustion of the chemicals in the second combustible state. The combustion products are contained within the combustion zone, and the chemicals are selected such that the combustion products naturally chemically revert into the chemicals in the first equilibrium state following combustion. The combustion device may thus be repeatedly reused, requiring only a brief wait after each ignition to allow the regeneration of combustible gasses within the head space.

  16. Turbulent Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  17. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  18. Engine Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engine Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  19. Light Duty Combustion Research: Advanced Light-Duty Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and ...

  20. Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol

    DOE Patents [OSTI]

    Lin, YuPo J; St. Martin, Edward J

    2013-08-13

    The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

  1. Enhancement of alkylation catalysts for improved supercritical fluid regeneration

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia (Idaho Falls, ID)

    2009-09-22

    A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

  2. Enhancement of alkylation catalysts for improved supercritical fluid regeneration

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

    2010-12-28

    A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

  3. Poly(ethyleneoxide) functionalization through alkylation

    DOE Patents [OSTI]

    Sivanandan, Kulandaivelu; Eitouni, Hany Basam; Li, Yan; Pratt, Russell Clayton

    2015-04-21

    A new and efficient method of functionalizing high molecular weight polymers through alkylation using a metal amide base is described. This novel procedure can also be used to synthesize polymer-based macro-initiators containing radical initiating groups at the chain-ends for synthesis of block copolymers.

  4. Advanced Combustion FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Q: What is advanced combustion? A: State-of-the-art, coal-fired boilers use air for the ... Q: What could an advanced combustion power plant look like? A: An oxy-combustion power ...

  5. Pressurized Combustion and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... However, properly designing new pressurized combustion burners and boilers requires accurate data on coal devolatilization and combustion rates under these conditions. Similarly, ...

  6. Combustion Energy Postdoctoral Research Fellowships - Combustion Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frontier Research Center Application Schedule Sample Projects How to Apply Combustion Energy Research Fellows 2016 Combustion Summer School News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » Combustion Energy Postdoctoral Research Fellowships Program Description Two-year positions as Combustion Energy Research Fellows are available for co-sponsored postdoctoral or more senior research associates to perform joint, high-risk/high-payoff

  7. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  8. PROCESS FOR PRODUCING ALKYL ORTHOPHOSPHORIC ACID EXTRACTANTS

    DOE Patents [OSTI]

    Grinstead, R.R.

    1962-01-23

    A process is given for producing superior alkyl orthophosphoric acid extractants for use in solvent extraction methods to recover and purify various metals such as uranium and vanadium. The process comprises slurrying P/sub 2/O/ sub 5/ in a solvent diluent such as kerosene, benzene, isopropyl ether, and the like. An alipbatic alcohol having from nine to seventeen carbon atoms, and w- hcrein ihc OH group is situated inward of the terminal carbon atoms, is added to the slurry while the reaction temperature is mainiained below 60 deg C. The alcohol is added in the mole ratio of about 2 to l, alcohol to P/sub 2/O/sub 5/. A pyrophosphate reaotion product is formed in the slurry-alcohol mixture. Subsequently, the pyrophosphate reaction product is hydrolyzed with dilute mineral acid to produce the desired alkyl orthophosphoric aeid extractant. The extraetant may then be separated and utilized in metal-recovery, solvent- extraction processes. (AEC)

  9. Rotary internal combustion engine

    SciTech Connect (OSTI)

    Le, L.K.

    1990-11-20

    This patent describes an internal combustion engine comprising; a rotary compressor mechanism; a rotary expander mechanism; and combustion chamber means disposed between the compressor mechanism and the expander mechanism, whereby compressed air is delivered to the combustion chamber through the compressor discharge port, and pressurized gas is delivered from the combustion chamber into the expander mechanism through the pressurized gas intake port.

  10. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul chugh; James Hower

    2008-08-31

    This paper discusses the roles and responsibilities of each position within the Combustion Byproducts Recyclcing Consortium.

  11. ALKYL PYROPHOSPHATE METAL SOLVENT EXTRACTANTS AND PROCESS

    DOE Patents [OSTI]

    Long, R.L.

    1958-09-30

    A process is presented for the recovery of uranium from aqueous mineral acidic solutions by solvent extraction. The extractant is a synmmetrical dialkyl pyrophosphate in which the alkyl substituents have a chain length of from 4 to 17 carbon atoms. Mentioned as a preferred extractant is dioctyl pyrophosphate. The uranium is precipitated irom the organic extractant phase with an agent such as HF, fluoride salts. alcohol, or ammonia.

  12. Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Combustion To develop a more thorough understanding of combustion, scientists and engineers must be able to analyze the interaction of many different chemical species at high temperatures and pressures. Making combustion more efficient requires a holistic view of chemical reactions that integrate theoretical and applied chemistry, physics, and advanced computing. Combustion research at Argonne emphasizes studies of the dynamics and rates of gas-phase chemical reactions and the

  13. Combustion 2000

    SciTech Connect (OSTI)

    A. Levasseur; S. Goodstine; J. Ruby; M. Nawaz; C. Senior; F. Robson; S. Lehman; W. Blecher; W. Fugard; A. Rao; A. Sarofim; P. Smith; D. Pershing; E. Eddings; M. Cremer; J. Hurley; G. Weber; M. Jones; M. Collings; D. Hajicek; A. Henderson; P. Klevan; D. Seery; B. Knight; R. Lessard; J. Sangiovanni; A. Dennis; C. Bird; W. Sutton; N. Bornstein; F. Cogswell; C. Randino; S. Gale; Mike Heap

    2001-06-30

    . To achieve these objectives requires a change from complete reliance of coal-fired systems on steam turbines (Rankine cycles) and moving forward to a combined cycle utilizing gas turbines (Brayton cycles) which offer the possibility of significantly greater efficiency. This is because gas turbine cycles operate at temperatures well beyond current steam cycles, allowing the working fluid (air) temperature to more closely approach that of the major energy source, the combustion of coal. In fact, a good figure of merit for a HIPPS design is just how much of the enthalpy from coal combustion is used by the gas turbine. The efficiency of a power cycle varies directly with the temperature of the working fluid and for contemporary gas turbines the optimal turbine inlet temperature is in the range of 2300-2500 F (1260-1371 C). These temperatures are beyond the working range of currently available alloys and are also in the range of the ash fusion temperature of most coals. These two sets of physical properties combine to produce the major engineering challenges for a HIPPS design. The UTRC team developed a design hierarchy to impose more rigor in our approach. Once the size of the plant had been determined by the choice of gas turbine and the matching steam turbine, the design process of the High Temperature Advanced Furnace (HITAF) moved ineluctably to a down-fired, slagging configuration. This design was based on two air heaters: one a high temperature slagging Radiative Air Heater (RAH) and a lower temperature, dry ash Convective Air Heater (CAH). The specific details of the air heaters are arrived at by an iterative sequence in the following order:-Starting from the overall Cycle requirements which set the limits for the combustion and heat transfer analysis-The available enthalpy determined the range of materials, ceramics or alloys, which could tolerate the temperatures-Structural Analysis of the designs proved to be the major limitation-Finally the commercialization

  14. New process schemes, retrofits, fine tune alkylation capabilities

    SciTech Connect (OSTI)

    Rhodes, A.K.

    1994-08-22

    Given alkylate's position as a key bleeding component for reformulated and oxygenated gasolines, process licensors have been working toward improved operation and design of alkylation technologies. An overview of the progress some of these companies have made will give refiners an update on the status of these new schemes. Phillips Petroleum Co. is a major licensor of HF alkylation units. Phillips' latest major process improvement is its so-called split-olefin feed technology (SOFT). By reducing the overall isobutane-to-olefin ratio (I/O) while maintaining a high I/O in the reaction zone, alkylate quality can be maintained and energy usage reduced. Other modifications have improved unit safety and environmental performance. The paper also discusses H[sub 2]SO[sub 4] alkylation processes and the Kellogg/Exxon alkylation process improvements.

  15. Advanced Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Advanced Combustion Combustion engines drive a large percentage of our nation's transportation vehicles and power generation and manufacturing facilities. Today's...

  16. Method of making a cyanate ester foam

    DOE Patents [OSTI]

    Celina, Mathias C.; Giron, Nicholas Henry

    2014-08-05

    A cyanate ester resin mixture with at least one cyanate ester resin, an isocyanate foaming resin, other co-curatives such as polyol or epoxy compounds, a surfactant, and a catalyst/water can react to form a foaming resin that can be cured at a temperature greater than 50.degree. C. to form a cyanate ester foam. The cyanate ester foam can be heated to a temperature greater than 400.degree. C. in a non-oxidative atmosphere to provide a carbonaceous char foam.

  17. Low-Temperature Diesel Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  18. The photodissociation dynamics of alkyl radicals

    SciTech Connect (OSTI)

    Giegerich, Jens; Fischer, Ingo

    2015-01-28

    The photodisscociation dynamics of the alkyl radicals i-propyl (CH(CH{sub 3}){sub 2}) and t-butyl (C(CH{sub 3}){sub 3}) are investigated by H-atom photofragment imaging. While i-propyl is excited at 250 nm, the photodynamics of t-butyl are explored over a large energy range using excitation wavelengths between 347 nm and 233 nm. The results are compared to those obtained previously for ethyl, CH{sub 3}CH{sub 2}, and to those reported for t-butyl using 248 nm excitation. The translational energy (E{sub T}) distribution of the H-atom photofragments is bimodal and appears rather similar for all three radicals. The low E{sub T} part of the distribution shows an isotropic photofragment angular distribution, while the high E{sub T} part is associated with a considerable anisotropy. Thus, for t-butyl, two H-atom loss channels of roughly equal importance have been identified in addition to the CH{sub 3}-loss channel reported previously. A mechanism for the photodissociation of alkyl radicals is suggested that is based on interactions between Rydberg- and valence states.

  19. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  20. Internal combustion engine

    SciTech Connect (OSTI)

    Perrin, G.; Bergmann, H.

    1984-06-12

    An externally auto-ignited four-stroke internal combustion engine which includes a combustion chamber disposed in an upper surface of a piston such that, in an upper dead-center position of the piston, the combustion chamber receives almost all of the fuel-air mixture. The combustion chamber includes a planar bottom portion and has a cross-sectional shape of a truncated cone expanding in a direction of the cylinder head. The internal combustion engine also includes a recess or depression provided in the cylinder head and disposed eccentrically with respect to a longitudinal center axis of the cylinder. The depression or recess in the cylinder head has the shape of a truncated cone expanding in a direction of the piston, with a spark plug projecting or penetrating into the recess or depression in the cylinder head. In order to enable the achievement of good combustion, increased overall engine performance, and the minimum amount of harmful components in the exhaust gases from the engine when different types of fuel are used, predetermined constructional parameters are selected with respect to the combustion chamber and recess or depression disposed above the combustion chamber as well as the disposition of the combustion chamber with respect to a longitudinal center axis of the cylinder.

  1. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  2. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2008-10-21

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  3. Combustion Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Predictive Simulation of Engines Transportation Energy Consortiums Engine Combustion ... Schematic representation of the experimental set-up. Shown in the figure is the jet-stirre...

  4. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi; Hisashi , Bool, III; Lawrence E.

    2007-06-05

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  5. Supersonic combustion engine and method of combustion initiation and distribution

    SciTech Connect (OSTI)

    Stickler, D.B.; Ballantyne, A.; Kyuman Jeong.

    1993-06-29

    A supersonic combustion ramjet engine having a combustor with a combustion zone intended to channel gas flow at relatively high speed therethrough, the engine comprising: means for substantially continuously supplying fuel into the combustion zone; and means for substantially instantaneously igniting a volume of fuel in the combustion zone for providing a spatially controlled combustion distribution, the igniting means having means for providing a diffuse discharge of energy into the volume, the volume extending across a substantially complete cross-sectional area of the combustion zone, the means for discharging energy being capable of generating free radicals within the volume of reactive fuel in the combustion zone such that fuel in the volume can initiate a controlled relatively rapid combustion of fuel in the combustion zone whereby combustion distribution in relatively high speed gas flows through the combustion zone can be initiated and controlled without dependence upon a flame holder or relatively high local static temperature in the combustion zone.

  6. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  7. Synthesis of a new energetic nitrate ester

    SciTech Connect (OSTI)

    Chavez, David E

    2008-01-01

    Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

  8. 2016 Combustion Summer School - Combustion Energy Frontier Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    To provide the next generation of combustion researchers with a comprehensive knowledge in the technical areas of combustion theory, experiment, computation, fundamentals, and ...

  9. Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Near-Supercritical Fluid Conditions - Energy Innovation Portal Startup America Startup America Find More Like This Return to Search Solid Catalyzed Isoparaffin Alkylation at Supercritical Fluid and Near-Supercritical Fluid Conditions Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL has developed a solid catalyst process for the alkylation reaction of isoparaffins with olefins over solid catalysts. The process includes contacting a mixture of an

  10. Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods

    SciTech Connect (OSTI)

    Vicic, David A.

    2014-05-01

    In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

  11. Fifteenth combustion research conference

    SciTech Connect (OSTI)

    1993-06-01

    The BES research efforts cover chemical reaction theory, experimental dynamics and spectroscopy, thermodynamics of combustion intermediates, chemical kinetics, reaction mechanisms, combustion diagnostics, and fluid dynamics and chemically reacting flows. 98 papers and abstracts are included. Separate abstracts were prepared for the papers.

  12. Particle Ignition and Char Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... reactivity of lignin residues that remain after biomass is processed and on quantifying the residue's ignition delay and char combustion rates during oxy-fuel combustion of coal. ...

  13. Plum Combustion | Open Energy Information

    Open Energy Info (EERE)

    Plum Combustion Place: Atlanta, Georgia Product: Combustion technology, which reduces NOx-emissions. Coordinates: 33.748315, -84.391109 Show Map Loading map......

  14. Optimized Algorithms Boost Combustion Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbulent combustion simulations, which provide input to the design of more fuel-efficient ... simulations, which play an important role in designing more efficient combustion systems. ...

  15. Stratified cross combustion engine

    SciTech Connect (OSTI)

    Rhoads, J.L.

    1981-06-23

    A piston engine is provided in which adjacent cylinder pairs share a common combustion chamber and the pistons are mounted to reciprocate substantially in phase, one of the pistons in each piston pair receiving a rich mixture which is ignited by a sparkplug in that cylinder, with the other cylinder in the cylinder pair being passive in its preferred form, and receiving through a separate intake valve either pure air or a leaner mixture into which the combusted richer mixture pours, insuring that the greatest combustion possible resulting in the greatest percentage of carbon dioxide formation as opposed to carbon monoxide is created.

  16. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines 2012 DOE Hydrogen and Fuel Cells ...

  17. Diacyltransferase Activity and Chain Length Specificity of Mycobacterium tuberculosis PapA5 in the Synthesis of Alkyl β-Diol Lipids

    SciTech Connect (OSTI)

    Touchette, Megan H.; Bommineni, Gopal R.; Delle Bovi, Richard J.; Gadbery, John; Nicora, Carrie D.; Shukla, Anil K.; Kyle, Jennifer E.; Metz, Thomas O.; Martin, Dwight W.; Sampson, Nicole S.; Miller, W. T.; Tonge, Peter J.; Seeliger, Jessica C.

    2015-09-08

    Although classified as Gram-positive bacteria, Corynebacterineae possess an asymmetric outer membrane that imparts structural and thereby physiological similarity to more distantly related Gram-negative bacteria. Like lipopolysaccharide in Gram-negative bacteria, lipids in the outer membrane of Corynebacterineae have been associated with the virulence of pathogenic species such as Mycobacterium tuberculosis (Mtb). For example, Mtb strains that lack long, branched-chain alkyl esters known as dimycocerosates (DIMs) are significantly attenuated in model infections. The resultant interest in the biosynthetic pathway of these unusual virulence factors has led to the elucidation of many of the steps leading to the final esterification of the alkyl beta-diol, phthiocerol, with branched-chain fatty acids know as mycocerosates. PapA5 is an acyltransferase implicated in these final reactions. We here show that PapA5 is indeed the terminal enzyme in DIM biosynthesis by demonstrating its dual esterification activity and chain-length preference using synthetic alkyl beta-diol substrate analogues. Applying these analogues to a series of PapA5 mutants, we also revise a model for the substrate binding within PapA5. Finally, we demonstrate that the Mtb Ser/Thr kinase PknB modifies PapA5 on three Thr residues, including two (T196, T198) located on an unresolved loop. These results clarify the DIM biosynthetic pathway and suggest possible mechanisms by which DIM biosynthesis may be regulated by the post-translational modification of PapA5.

  18. Dry low combustion system with means for eliminating combustion noise

    DOE Patents [OSTI]

    Verdouw, Albert J.; Smith, Duane; McCormick, Keith; Razdan, Mohan K.

    2004-02-17

    A combustion system including a plurality of axially staged tubular premixers to control emissions and minimize combustion noise. The combustion system includes a radial inflow premixer that delivers the combustion mixture across a contoured dome into the combustion chamber. The axially staged premixers having a twist mixing apparatus to rotate the fluid flow and cause improved mixing without causing flow recirculation that could lead to pre-ignition or flashback.

  19. Sandia Combustion Research: Technical review

    SciTech Connect (OSTI)

    1995-07-01

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  20. Internal combustion engine

    SciTech Connect (OSTI)

    Bernauer, O.

    1980-10-07

    An internal combustion engine is described that has walls delimiting the working space or spaces of the internal combustion engine, in which a hydrogen-impervious, encapsulated metal hydride storage device is provided which is in heat-conducting contact with these walls; the interior of the encapsulation is adapted to be selectively connected to a source of hydrogen and/or to a separate further hydrogen storage device.

  1. Combustion and Emissions Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion and Emissions Modeling This email address is being protected from spambots. You need JavaScript enabled to view it. - Computational Fluid Dynamics Project Leader Background Modern transportation engines are designed to use the available fuel resources efficiently and minimize harmful emissions. Optimization of these designs is based on a wealth of practical design, construction and operating experiences, and use of modern testing facilities and sophisticated analyses of the combustion

  2. Sandia Combustion Research Program

    SciTech Connect (OSTI)

    Johnston, S.C.; Palmer, R.E.; Montana, C.A.

    1988-01-01

    During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

  3. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin; Mongia, Hukam C.; Tramm, Peter C.

    1988-01-01

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  4. Preparation and reactivity of macrocyclic rhodium(III) alkyl complexes

    SciTech Connect (OSTI)

    Carraher, Jack M.; Ellern, Arkady; Bakac, Andreja

    2013-09-21

    Macrocyclic rhodium(II) complexes LRh(H2O)(2+) (L = L-1 = cyclam and L-2 = meso-Me-6-cyclam) react with alkyl hydroperoxides RC(CH3)(2)OOH to generate the corresponding rhodium(III) alkyls L(H2O)RhR2+ (R = CH3, C2H5, PhCH2). Methyl and benzyl complexes can also be prepared by bimolecular group transfer from alkyl cobaloximes (dmgH)(2)(H2O) CoR and (dmgBF(2))(2)(H2O) CoR (R = CH3, PhCH2) to LRh(H2O)(2+). The new complexes were characterized by solution NMR and by crystal structure analysis. They exhibit great stability in aqueous solution at room temperature, but undergo efficient Rh-C bond cleavage upon photolysis. (C) 2013 Elsevier B.V. All rights reserved.

  5. Alkyl phospholipid antihypertensive agents in method of lowering blood pressure

    DOE Patents [OSTI]

    Snyder, Fred L.; Blank, Merle L.; Muirhead, Ernest E.; Leach, deceased, Byron E.; Byers, Lawrence W.

    1988-01-01

    The composition of this invention is 1-O-alkyl-2-acetoyl-sn-glycero-3-phosphocholine, having the ionic structural formula; ##STR1## wherein R is saturated alkyl having 9-21 carbon atoms, or salts or hydrates of the composition. Preferably R has 13-19 carbon atoms and most preferably R has 15 carbon atoms. The composition of this invention is useful for reducing hypertension in warm-blooded animals, including humans, when administered either orally or by injection or innoculation, e.g., intravenous injection. The composition can be prepared from naturally occurring lipids or synthetically from commercially available material.

  6. Rotary internal combustion engine

    SciTech Connect (OSTI)

    Murray, J.L.

    1993-07-20

    A multi bank power plant is described comprising at least a first and a second rotary internal combustion engine connectable together in series, each of the engines comprising: a housing; a cam track internally disposed within the housing and adapted to receive a cam follower; an engine block disposed within the housing and rotatable about a central axis; an output shaft extending axially from each the engine block, each output shaft being coaxial with the other; means for coupling the output shafts together so that the output shafts rotate together in the same direction at the same speed; at least one radially arranged cylinder assembly on each block, each cylinder assembly including a cylinder having a longitudinal axis extending generally radially outwardly from the rotational axis of the block, the cylinder including means defining an end wall, a piston member disposed within the cylinder and adapted to reciprocate within the cylinder; a combustion chamber, means permitting periodic introduction of air and fuel into the combustion chamber, means for causing combustion of a compressed mixture of air and fuel within the combustion chamber, means permitting periodic exhaust of products of combustion of air and fuel from the combustion chamber, and means for imparting forces and motions of the piston within the cylinder to and from the cam track, the means comprising a cam follower operatively connected to the piston; wherein the cam track includes at least a first segment and at least a second segment thereof, the first segment having a generally positive slope wherein the segment has a generally increasing radial distance from the rotational axis of the engine block whereby as a piston moves outwardly in a cylinder on a power stroke while the cam follower is in radial register with the cam track segment, the reactive force of the respective cam follower against the cam track segment acts in a direction tending to impart rotation to the engine block.

  7. Vehicle Technologies Office: 2014 Advanced Combustion Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2014 Advanced Combustion Engine Annual Progress Report Vehicle Technologies Office: 2014 Advanced Combustion Engine Annual Progress Report The Advanced Combustion Engine research...

  8. Environmentally conscious coal combustion

    SciTech Connect (OSTI)

    Hickmott, D.D.; Brown, L.F.; Currier, R.P.

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  9. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D; Swank, William D.

    2011-08-30

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  10. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  11. Ionic liquid containing hydroxamate and N-alkyl sulfamate ions

    DOE Patents [OSTI]

    Friesen, Cody A.; Wolfe, Derek; Johnson, Paul Bryan

    2016-03-15

    Embodiments of the invention are related to ionic liquids and more specifically to ionic liquids used in electrochemical metal-air cells in which the ionic liquid includes a cation and an anion selected from hydroxamate and/or N-alkyl sulfamate anions.

  12. Fluidized-bed combustion

    SciTech Connect (OSTI)

    Botros, P E

    1990-04-01

    This report describes the activities of the Morgantown Energy Technology Center's research and development program in fluidized-bed combustion from October 1, 1987, to September 30, 1989. The Department of Energy program involves atmospheric and pressurized systems. Demonstrations of industrial-scale atmospheric systems are being completed, and smaller boilers are being explored. These systems include vortex, multi-solid, spouted, dual-sided, air-cooled, pulsed, and waste-fired fluidized-beds. Combustion of low-rank coal, components, and erosion are being studied. In pressurized combustion, first-generation, combined-cycle power plants are being tested, and second-generation, advanced-cycle systems are being designed and cost evaluated. Research in coal devolatilization, metal wastage, tube corrosion, and fluidization also supports this area. 52 refs., 24 figs., 3 tabs.

  13. Internal combustion rotary engine

    SciTech Connect (OSTI)

    Chen, S.P.

    1993-08-24

    An internal combustion rotary engine is described comprising: an internal combustion chamber wherein a combustible fuel-air mixture is ignited for producing a driving gas flow; a central rotor having an outer surface in which at least one group of curved channels circumferentially-and-axially extending without radially extending through the central rotor; and at least one annular rotor each enclosing the central rotor having an inner surface in which a corresponding number of curved channels circumferentially-and-axially extending without radially extending through the annular rotor; when the curved channels in the central rotor communicate with the curved channels in the annular rotor, the driving gas flow circumferentially-and-axially passing between the outer surface of the central rotor and the inner surface of the annular rotor for rotating the central rotor and the annular rotor in opposite directions.

  14. Internal combustion engine

    DOE Patents [OSTI]

    Baker, Quentin A.; Mecredy, Henry E.; O'Neal, Glenn B.

    1991-01-01

    An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

  15. Advanced Combustion Technology to Enable High Efficiency Clean Combustion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Technology to Enable High Efficiency Clean Combustion Advanced Combustion Technology to Enable High Efficiency Clean Combustion Summary of advanced combustion research at Cummins to explore strategies for fuel economy improvements (PCCI and HECC) and redced engine-out NOx emissions. deer08_stanton.pdf (1.23 MB) More Documents & Publications Integration of Diesel Engine Technology to Meet US EPA 2010 Emissions with Improved Thermal Efficiency Development of Enabling

  16. Studies in combustion dynamics

    SciTech Connect (OSTI)

    Koszykowski, M.L.

    1993-12-01

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  17. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  18. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, Roy; Kakwani, Ramesh M.; Valdmanis, Edgars; Woods, Melvins E.

    1988-01-01

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

  19. Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    focuses on the combustion of fossil and alternative fuels to produce heat and power. The research team is led by 15 of the nation's leading combustion scientists from seven...

  20. Optimized Algorithms Boost Combustion Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimized Algorithms Boost Combustion Research Optimized Algorithms Boost Combustion Research Methane Flame Simulations Run 6x Faster on NERSC's Hopper Supercomputer November 25, 2014 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Turbulent combustion simulations, which provide input to the design of more fuel-efficient combustion systems, have gotten their own efficiency boost, thanks to researchers from the Computational Research Division (CRD) at Lawrence Berkeley National

  1. Improve Your Boiler's Combustion Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE)

    This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system.

  2. Optimization of Advanced Diesel Engine Combustion Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies Computational Fluid Dynamics ...

  3. Transonic Combustion ’ - Injection Strategy Development for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transonic Combustion - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Transonic Combustion - Injection Strategy ...

  4. Plasmatron Fuel Reformer Development and Internal Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications ...

  5. Combustion Air Zone (CAZ) Best Practices

    Broader source: Energy.gov [DOE]

    This webinar covered combustion safety testing, several tests, national standards, and implementing combustion safety testing in programs.

  6. Coal combustion research

    SciTech Connect (OSTI)

    Daw, C.S.

    1996-06-01

    This section describes research and development related to coal combustion being performed for the Fossil Energy Program under the direction of the Morgantown Energy Technology Center. The key activity involves the application of chaos theory for the diagnosis and control of fossil energy processes.

  7. Pressurized Combustion and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressurized Combustion and Gasification - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management

  8. Coal Combustion Products

    Office of Energy Efficiency and Renewable Energy (EERE)

    Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge.

  9. Reversed flow fluidized-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu; Mei, Joseph S.; Wilson, John S.

    1984-01-01

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  10. Low emission internal combustion engine

    DOE Patents [OSTI]

    Karaba, Albert M.

    1979-01-01

    A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

  11. Method for reactivating solid catalysts used in alkylation reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2003-06-17

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  12. Coal combustion products (CCPs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge. When properly managed, CCPs offer society environmental and economic benefits without harm to public health and safety. Research supported by the U.S. Department of Energy's (DOE) Office of Fossil Energy (FE) has made an

  13. APBF Effects on Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FT001 - APBF Effects on Combustion (advanced petroleum based fuels, DOE project # 18546) Bruce G. Bunting, Jim Szybist, Scott Sluder, John Storey, Sam Lewis, Robert Wagner, Jun Qu, Robert Crawford 2010 DOE Hydrogen Program and Vehicle Technologies Annual Merit Review and Peer Evaluation Meeting, June 7-10, 2010 This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE management team: Kevin Stork, Drew Ronneberg, Dennis Smith, Steve Przesmitzki 2

  14. Applied Turbulent Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbulent Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  15. Combustion powered linear actuator

    DOE Patents [OSTI]

    Fischer, Gary J.

    2007-09-04

    The present invention provides robotic vehicles having wheeled and hopping mobilities that are capable of traversing (e.g. by hopping over) obstacles that are large in size relative to the robot and, are capable of operation in unpredictable terrain over long range. The present invention further provides combustion powered linear actuators, which can include latching mechanisms to facilitate pressurized fueling of the actuators, as can be used to provide wheeled vehicles with a hopping mobility.

  16. Combustion air preheating

    SciTech Connect (OSTI)

    Wells, T.A.; Petterson, W.C.

    1986-10-14

    This patent describes a process for steam cracking hydrocarbons to cracked gases in a tubular furnace heated by burning a mixture of fuel and combustion air and subsequently quenching the cracked gases. Waste heat is recovered in the form of high pressure steam and the combustion air is preheated prior to introduction into the furnace. The improvement described here comprises: (a) superheating the high pressure steam and expanding at least a portion of the superheated high pressure steam through a first turbine to produce shaft work and superheated medium pressure steam at a temperature between 260/sup 0/ and 465/sup 0/ C.; (b) expanding at least a portion of the superheated medium pressure steam through a second turbine to produce shaft work and low pressure steam at a temperature between 120/sup 0/ and 325/sup 0/ C.; and (c) preheating the combustion air by indirect heat exchange with at least a portion of the superheated medium pressure stream and at least a portion of the low pressure steam.

  17. Internal combustion engine using premixed combustion of stratified charges

    DOE Patents [OSTI]

    Marriott, Craig D.; Reitz, Rolf D. (Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  18. Internal combustion engine with rotary combustion chamber

    SciTech Connect (OSTI)

    Hansen, C.N.; Cross, P.C.

    1986-09-23

    This patent describes an internal combustion engine comprising: a block having at least one cylindrical wall surrounding a piston chamber, piston means located in the piston chamber means operable to reciprocate the piston means in the chamber, head means mounted on the block covering the chamber. The head means has an air and fuel intake passage, and exhaust gas passage, a rotary valve assembly operatively associated with the head means for controlling the flow of air and fuel into the rotary valve assembly and piston chamber and the flow of exhaust gas from rotary valve assembly and the piston chamber. The means has a housing with a bore open to the piston chamber accommodating the rotary valve assembly, the valve assembly comprising a cylindrical sleeve located in the bore, the sleeve having an inner surface, an ignition hole, and intake and exhaust ports aligned with the intake passage and exhaust gas passage, spark generating means mounted on the housing operable to generate a spark. The rotatable valving means is located within the sleeve for controlling the flow of air and fuel into the rotary valve assembly and piston chamber and the flow of exhaust gases out of the rotary valve assembly and piston chamber.

  19. Microbial production of wax esters from highly branched alkanes

    DOE Patents [OSTI]

    Bogan, William W.; Sullivan, Wendy R.; Paterek, James R.

    2005-02-01

    A microbial culture and method for producing wax esters using highly branched alkanes. In accordance with one embodiment, the highly branched alkane is squalane.

  20. Preparation of Propylene Glycol Fatty Acid Ester or Other Glycol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and more specifically uses methyl esters of vegetable oils that are referred to as "biodiesel" fuels. One particularly useful biodiesel is soybean oil biodiesel (methyl soyate)...

  1. Vehiculos de combustible flexible: brindando opciones en combustible...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    actualizada para convertidores de combustible alternativo de la EPA en su sitio web, www.epa.govotaq certdearmfrcisd0602.pdf. El E85 afecta el desempeo del...

  2. Advanced Combustion Technology to Enable High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology to Enable High Efficiency Clean Combustion Advanced Combustion Technology to Enable High Efficiency Clean Combustion Summary of advanced combustion research at Cummins ...

  3. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Applied low temperature combustion to the Navistar ...

  4. Fuel Effects on Mixing-Controlled Combustion Strategies for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion ...

  5. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In

  6. Tire gassification and combustion system

    SciTech Connect (OSTI)

    Nance, D.; Towne, G.A.

    1992-04-07

    This patent describes a system for disposing of a material such as vehicle tires and similar substantially organic matter and generating useful heat therefrom. It comprises gasification means for holding an amount of the material to be disposed while the material is allowed to partially combust and for containing combustible gas produced thereby, the gasification means comprising a substantially air tight gasification chamber having at least one access way for inserting the material therein; inlet means for receiving a controlled amount of oxygen containing gas into the gasification means, the inlet means comprising a tuyere disposed in the air tight gasification chamber and a blower connected to the tuyere; removal means for removing the combustible gas from the gasification means, the removal means comprising a gas outlet located above the tuyere in the gasification chamber such that substantially amounts of the combustible gases produced by the partially combusted material exits through the gas outlet; primary combustion means for receiving and mixing the combustible gas removed from the gasification means with an oxygen containing gas and burning the combustible gas; and means for directing the combustion products to a heat utilizing device.

  7. Light Duty Efficient, Clean Combustion

    SciTech Connect (OSTI)

    Stanton, Donald W.

    2011-06-03

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy’s Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of our objectives were met with fuel efficiency improvement targets exceeded.

  8. Improve Your Boiler's Combustion Efficiency

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  9. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

  10. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  11. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, clean coal combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered allowable under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  12. 33rd International Symposium on Combustion Hottel Lecture Applications of Quantitative Laser Sensors to Kinetics, Propulsion and Practical Combustion Systems Ronald K. Hanson Department of Mechanical Engineering Stanford University, Stanford CA, 94305

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Combustion Science Stanford University Contribution R. K. Hanson and D. F. Davidson Department of Mechanical Engineering Stanford University 1 * Butanol Studies * Ignition Delay Times * Species Time-Histories * Reaction Rate Constants * Methyl Ester Studies * Ignition Delay Times Long-Term Objectives * Generate high-quality fundamental kinetics database using shock tube/laser absorption methods Leading to: * Improved detailed mechanisms for next-generation fuels First Targets: * Isomers of

  13. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P.; Matthews, Francis T.

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  14. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Mo, Weijian; Muylle, Michel Serge Marie; Mandema, Remco Hugo; Nair, Vijay

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  15. Preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters

    DOE Patents [OSTI]

    Gogate, Makarand Ratnakar; Spivey, James Jerry; Zoeller, Joseph Robert

    1998-01-01

    Disclosed is a process for the preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

  16. Preparation of {alpha},{beta}-unsaturated carboxylic acids and esters

    DOE Patents [OSTI]

    Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.

    1998-09-15

    Disclosed is a process for the preparation of {alpha},{beta}-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

  17. Path planning during combustion mode switch

    DOE Patents [OSTI]

    Jiang, Li; Ravi, Nikhil

    2015-12-29

    Systems and methods are provided for transitioning between a first combustion mode and a second combustion mode in an internal combustion engine. A current operating point of the engine is identified and a target operating point for the internal combustion engine in the second combustion mode is also determined. A predefined optimized transition operating point is selected from memory. While operating in the first combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion engine to approach the selected optimized transition operating point. When the engine is operating at the selected optimized transition operating point, the combustion mode is switched from the first combustion mode to the second combustion mode. While operating in the second combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion to approach the target operating point.

  18. Rotary reciprical combustion engines

    SciTech Connect (OSTI)

    Blount, D.H.

    1992-10-20

    This patent describes a rotary-reciprocal combustion engine having a cycle which includes the four strokes of intake, compression, expansion and exhaustion, the engine. It comprises: a housing formed with a peripheral wall with side walls, a rotor in the housing, the inner surface of the peripheral inner wall being cylindrical; a shaft; mounted in the center of the housing, passing through the rotor's hub and extending through the side walls of the housing, the hub having means to allow the rotor to reciprocate on the shaft while the shaft is rotating with the rotor; a reciprocal and rotary guide having means to guide the rotary and reciprocal motions of the rotor while keeping the rotor's piston in continuous sealing contact with the cylinder chamber walls and varying the volume of the cylinder chambers enabling a compression of a gaseous mixture to take place after aspirating a gaseous mixture; an ignition system having means for igniting compressed gaseous mixture and expansion of the cylinder chambers due to pressure of the combustion products.

  19. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-06-14

    Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.

  20. Method for in situ combustion

    DOE Patents [OSTI]

    Pasini, III, Joseph; Shuck, Lowell Z.; Overbey, Jr., William K.

    1977-01-01

    This invention relates to an improved in situ combustion method for the recovery of hydrocarbons from subterranean earth formations containing carbonaceous material. The method is practiced by penetrating the subterranean earth formation with a borehole projecting into the coal bed along a horizontal plane and extending along a plane disposed perpendicular to the plane of maximum permeability. The subterranean earth formation is also penetrated with a plurality of spaced-apart vertical boreholes disposed along a plane spaced from and generally parallel to that of the horizontal borehole. Fractures are then induced at each of the vertical boreholes which project from the vertical boreholes along the plane of maximum permeability and intersect the horizontal borehole. The combustion is initiated at the horizontal borehole and the products of combustion and fluids displaced from the earth formation by the combustion are removed from the subterranean earth formation via the vertical boreholes. Each of the vertical boreholes are, in turn, provided with suitable flow controls for regulating the flow of fluid from the combustion zone and the earth formation so as to control the configuration and rate of propagation of the combustion zone. The fractures provide a positive communication with the combustion zone so as to facilitate the removal of the products resulting from the combustion of the carbonaceous material.

  1. Development of Advanced Combustion Technologies for Increased...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Technologies for Increased Thermal Efficiency Development of Advanced Combustion Technologies for Increased Thermal Efficiency Investigation of fuel effects on ...

  2. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency ... system to manage multi-modemulti-fuel combustion events and achieve an up to 30 percent ...

  3. Hydrogen engine and combustion control process

    DOE Patents [OSTI]

    Swain, Michael R.; Swain, Matthew N.

    1997-01-01

    Hydrogen engine with controlled combustion comprises suction means connected to the crankcase reducing or precluding flow of lubricating oil or associated gases into the combustion chamber.

  4. Process Heater for Stoichiometric Combustion Control | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heater for Stoichiometric Combustion Control Process Heater for Stoichiometric Combustion Control An Enhanced, CO-Based, Low Excess Air Control System Saves Energy While Reducing ...

  5. Thermodynamic Advantages of Low Temperature Combustion Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use ...

  6. Optimization of Advanced Diesel Engine Combustion Strategies...

    Broader source: Energy.gov (indexed) [DOE]

    Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies Use of Low Cetane Fuel to Enable Low Temperature ...

  7. Building America Technology Solutions Case Study: Combustion...

    Energy Savers [EERE]

    Combustion Safety Simplified Test Protocol Building America Technology Solutions Case Study: Combustion Safety Simplified Test Protocol Two U.S. Department of Energy Building ...

  8. AVTA: Hydrogen Internal Combustion Engine Vehicle Specifications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Internal Combustion Engine Vehicle Specifications and Test Procedures AVTA: Hydrogen Internal Combustion Engine Vehicle Specifications and Test Procedures HICEV Technical ...

  9. Biomass Combustion Systems Inc | Open Energy Information

    Open Energy Info (EERE)

    Biomass Combustion Systems Inc Retrieved from "http:en.openei.orgwindex.php?titleBiomassCombustionSystemsInc&oldid768602" Feedback Contact needs updating Image...

  10. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency Light Duty Vehicles Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for ...

  11. advanced combustion engines | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Combustion Engines Improving the efficiency of internal combustion engines is one of the most promising and cost-effective near- to mid-term approaches to increasing...

  12. Events - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CEFRC, Sept 23-24, 2010, Princeton, NJ Enoch Dames, " Soot Formation in Fuel Combustion - The Role of Aromatic Diradicals" Stephen J. Klippenstein, " Combustion at High...

  13. Rotary internal combustion engine

    SciTech Connect (OSTI)

    Murray, J.L.; Mosca, J.O.

    1992-02-25

    This patent describes a rotary internal combustion engine. It includes a housing; a cam track internally disposed within the housing and adapted to receive a cam follower; an engine block disposed within the housing, the engine block being relatively rotatable within the housing about a central axis; means connectable to an external drive member for translating the relative rotation of the engine block with respect to the housing into useful work; at least one radially arranged cylinder assembly on the block, each cylinder assembly including a cylinder having a longitudinal axis extending generally radially outwardly from the rotational axis of the block, the cylinder including means defining an end wall, a piston member disposed within the cylinder and adapted to reciprocate within the cylinder; the piston, cylinder and cylinder end wall together.

  14. The Role of Comprehensive Detailed Chemical Kinetic Reaction Mechanisms in Combustion Research

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

    2008-07-16

    Recent developments by the authors in the field of comprehensive detailed chemical kinetic reaction mechanisms for hydrocarbon fuels are reviewed. Examples are given of how these mechanisms provide fundamental chemical insights into a range of combustion applications. Practical combustion consists primarily of chemical heat release from reactions between a fuel and an oxidizer, and computer simulations of practical combustion systems have become an essential tool of combustion research (Westbrook et al., 2005). At the heart of most combustion simulations, the chemical kinetic submodel frequently is the most detailed, complex and computationally costly part of a system model. Historically, the chemical submodel equations are solved using time-implicit numerical algorithms, due to the extreme stiffness of the coupled rate equations, with a computational cost that varies roughly with the cube of the number of chemical species in the model. While early mechanisms (c. 1980) for apparently simple fuels such as methane (Warnatz, 1980) or methanol (Westbrook and Dryer, 1979) included perhaps 25 species, current detailed mechanisms for much larger, more complex fuels such as hexadecane (Fournet et al., 2001; Ristori et al., 2001; Westbrook et al., 2008) or methyl ester methyl decanoate (Herbinet et al., 2008) have as many as 2000 or even 3000 species. Rapid growth in capabilities of modern computers has been an essential feature in this rapid growth in the size and complexity of chemical kinetic reaction mechanisms.

  15. High Efficiency, Clean Combustion

    SciTech Connect (OSTI)

    Donald Stanton

    2010-03-31

    Energy use in trucks has been increasing at a faster rate than that of automobiles within the U.S. transportation sector. According to the Energy Information Administration (EIA) Annual Energy Outlook (AEO), a 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected between 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow between 2009 and 2050 while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. economy. An essential part of a stable and vibrant U.S. economy is a productive U.S. trucking industry. Studies have shown that the U.S. gross domestic product (GDP) is strongly correlated to freight transport. Over 90% of all U.S. freight tonnage is transported by diesel power and over 75% is transported by trucks. Given the vital role that the trucking industry plays in the economy, improving the efficiency of the transportation of goods was a central focus of the Cummins High Efficient Clean Combustion (HECC) program. In a commercial vehicle, the diesel engine remains the largest source of fuel efficiency loss, but remains the greatest opportunity for fuel efficiency improvements. In addition to reducing oil consumption and the dependency on foreign oil, this project will mitigate the impact on the environment by meeting US EPA 2010 emissions regulations. Innovation is a key element in sustaining a U.S. trucking industry that is competitive in global markets. Unlike passenger vehicles, the trucking industry cannot simply downsize the vehicle and still transport the freight with improved efficiency. The truck manufacturing and supporting industries are faced with numerous

  16. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    Broader source: Energy.gov [DOE]

    Applied low temperature combustion to the Navistar 6.4L V8 engine with 0.2g NOx/bhp-hr operation attained at the rated 16.5 BMEP

  17. Combustible structural composites and methods of forming combustible...

    Office of Scientific and Technical Information (OSTI)

    The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the ...

  18. Combustion-gas recirculation system

    DOE Patents [OSTI]

    Baldwin, Darryl Dean

    2007-10-09

    A combustion-gas recirculation system has a mixing chamber with a mixing-chamber inlet and a mixing-chamber outlet. The combustion-gas recirculation system may further include a duct connected to the mixing-chamber inlet. Additionally, the combustion-gas recirculation system may include an open inlet channel with a solid outer wall. The open inlet channel may extend into the mixing chamber such that an end of the open inlet channel is disposed between the mixing-chamber inlet and the mixing-chamber outlet. Furthermore, air within the open inlet channel may be at a pressure near or below atmospheric pressure.

  19. International combustion engines; Applied thermosciences

    SciTech Connect (OSTI)

    Ferguson, C.R.

    1985-01-01

    Focusing on thermodynamic analysis - from the requisite first law to more sophisticated applications - and engine design, this book is an introduction to internal combustion engines and their mechanics. It covers the many types of internal combustion engines, including spark ignition, compression ignition, and stratified charge engines, and examines processes, keeping equations of state simple by assuming constant specific heats. Equations are limited to heat engines and later applied to combustion engines. Topics include realistic equations of state, stroichiometry, predictions of chemical equilibrium, engine performance criteria, and friction, which is discussed in terms of the hydrodynamic theory of lubrication and experimental methods such as dimensional analysis.

  20. Combustion Analysis Software Package for Internal Combustion Engines -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Industrial Technologies Industrial Technologies Energy Analysis Energy Analysis Find More Like This Return to Search Combustion Analysis Software Package for Internal Combustion Engines Colorado State University Contact CSU About This Technology Technology Marketing Summary Researchers at the Colorado State University Engines and Energy Conversion Laboratory have developed a complete software package for use with National

  1. APBF Effects on Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    APBF Effects on Combustion APBF Effects on Combustion 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ft001_bunting_2010_o.pdf (1.06 MB) More Documents & Publications Fuel and Lubricant Effects APBF Effects on Combustion Non-Petroleum Based Fuel Effects on Advanced Combustion

  2. Putting combustion optimization to work

    SciTech Connect (OSTI)

    Spring, N.

    2009-05-15

    New plants and plants that are retrofitting can benefit from combustion optimization. Boiler tuning and optimization can complement each other. The continuous emissions monitoring system CEMS, and tunable diode laser absorption spectroscopy TDLAS can be used for optimisation. NeuCO's CombustionOpt neural network software can determine optimal fuel and air set points. Babcock and Wilcox Power Generation Group Inc's Flame Doctor can be used in conjunction with other systems to diagnose and correct coal-fired burner performance. The four units of the Colstrip power plant in Colstrips, Montana were recently fitted with combustion optimization systems based on advanced model predictive multi variable controls (MPCs), ABB's Predict & Control tool. Unit 4 of Tampa Electric's Big Bend plant in Florida is fitted with Emerson's SmartProcess fuzzy neural model based combustion optimisation system. 1 photo.

  3. Loop-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu; Mei, Joseph S.; Slagle, Frank D.; Notestein, John E.

    1984-01-01

    The present invention is directed to a combustion apparatus in the configuration of a oblong annulus defining a closed loop. Particulate coal together with a sulfur sorbent such as sulfur or dolomite is introduced into the closed loop, ignited, and propelled at a high rate of speed around the loop. Flue gas is withdrawn from a location in the closed loop in close proximity to an area in the loop where centrifugal force imposed upon the larger particulate material maintains these particulates at a location spaced from the flue gas outlet. Only flue gas and smaller particulates resulting from the combustion and innerparticle grinding are discharged from the combustor. This structural arrangement provides increased combustion efficiency due to the essentially complete combustion of the coal particulates as well as increased sulfur absorption due to the innerparticle grinding of the sorbent which provides greater particle surface area.

  4. Combustion modeling in waste tanks

    SciTech Connect (OSTI)

    Mueller, C.; Unal, C.; Travis, J.R. |

    1997-08-01

    This paper has two objectives. The first one is to repeat previous simulations of release and combustion of flammable gases in tank SY-101 at the Hanford reservation with the recently developed code GASFLOW-II. The GASFLOW-II results are compared with the results obtained with the HMS/TRAC code and show good agreement, especially for non-combustion cases. For combustion GASFLOW-II predicts a steeper pressure rise than HMS/TRAC. The second objective is to describe a so-called induction parameter model which was developed and implemented into GASFLOW-II and reassess previous calculations of Bureau of Mines experiments for hydrogen-air combustion. The pressure time history improves compared with the one-step model, and the time rate of pressure change is much closer to the experimental data.

  5. Engine combustion and flow diagnostics

    SciTech Connect (OSTI)

    1995-12-31

    This informative publication discusses the application of diagnostic techniques to internal combustion engines. The papers included fall into three broad categories: flow diagnostics, combustion diagnostics, and fuel spray diagnostics. Contents include: controlling combustion in a spark ignition engine by quantitative fuel distribution; a model for converting SI engine flame arrival signals into flame contours; in-cylinder diesel flame imaging compared with numerical computations; ignition and early soot formation in a DI diesel engine using multiple 2-D imaging diagnostics; investigation of diesel sprays using diffraction-based droplet sizing; fuel distribution effects on the combustion of a direct-injection stratified-charge engine; and 2-D measurements of the liquid phase temperature in fuel sprays.

  6. Rotary-reciprocal combustion engines

    SciTech Connect (OSTI)

    Blount, D.H.

    1992-10-06

    This patent describes an internal combustion engine of the rotary-reciprocal type. It comprises a housing formed with a peripheral wall; a rotor; and a shaft for the rotor.

  7. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    during these next phases of combustion. Research conducted by: D.S.N. Parker and R.I. Kaiser (University of Hawaii at Manoa ), T.P. Troy and M. Ahmed (Lawrence Berkeley National...

  8. Combustion Science for Cleaner Fuels

    SciTech Connect (OSTI)

    Ahmed, Musahid

    2014-10-17

    Musahid Ahmed discusses how he and his team use the Advanced Light Source (ALS) to study combustion chemistry at our '8 Big Ideas' Science at the Theater event on October 8th, 2014, in Oakland, California.

  9. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  10. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-03-15

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  11. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

    2015-04-07

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  12. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In addition, the results could have implications for the burgeoning field of

  13. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In addition, the results could have implications for the burgeoning field of

  14. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In addition, the results could have implications for the burgeoning field of

  15. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In addition, the results could have implications for the burgeoning field of

  16. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and other carbon-based compounds. It's a discovery that could help combustion chemists make more efficient, less polluting fuels and help materials scientists fine-tune their carbon nanotubes and graphene sheets for faster, smaller electronics. In addition, the results could have implications for the burgeoning field of

  17. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.; Beltran, Leslie V.; Kunz, Linda A.; Pals, Tessa M.; Quinn, Jordan R; Behrends, Jr., Raymond T.; Bernhardt, Randal J.

    2016-07-05

    Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.

  18. Reducing mode circulating fluid bed combustion

    DOE Patents [OSTI]

    Lin, Yung-Yi; Sadhukhan, Pasupati; Fraley, Lowell D.; Hsiao, Keh-Hsien

    1986-01-01

    A method for combustion of sulfur-containing fuel in a circulating fluid bed combustion system wherein the fuel is burned in a primary combustion zone under reducing conditions and sulfur captured as alkaline sulfide. The reducing gas formed is oxidized to combustion gas which is then separated from solids containing alkaline sulfide. The separated solids are then oxidized and recycled to the primary combustion zone.

  19. Oxy-Combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxy-Combustion oxy-combustion.jpg The combustion of fossil fuels in nearly pure oxygen-known as oxy-combustion-is a promising technology for capturing carbon dioxide (CO2) from fossil fuel power plants, and reducing greenhouse gas emissions. However, the cost, energy consumption, and operational challenges of oxygen separation are significant challenges that NETL researchers are helping to tackle. In an oxy-combustion process, a pure or enriched oxygen (O2) stream is used instead of air for

  20. Partially Premixed Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Partially Premixed Combustion Partially Premixed Combustion Published materials on partial premixed combustion (PPC) combined with Volvo's own combustion research provides understanding of how to proceed for future work that enables PPC to reach the market deer11_andersson.pdf (560.85 KB) More Documents & Publications Combustion Model for Engine Concept Development Path to High Efficiency Gasoline Engine Effects of Biomass Fuels on Engine & System Out Emissions for Short Term Endurance

  1. Industrial Facility Combustion Energy Use

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    McMillan, Colin

    2016-08-01

    Facility-level industrial combustion energy use is calculated from greenhouse gas emissions data reported by large emitters (>25,000 metric tons CO2e per year) under the U.S. EPA's Greenhouse Gas Reporting Program (GHGRP, https://www.epa.gov/ghgreporting). The calculation applies EPA default emissions factors to reported fuel use by fuel type. Additional facility information is included with calculated combustion energy values, such as industry type (six-digit NAICS code), location (lat, long, zip code, county, and state), combustion unit type, and combustion unit name. Further identification of combustion energy use is provided by calculating energy end use (e.g., conventional boiler use, co-generation/CHP use, process heating, other facility support) by manufacturing NAICS code. Manufacturing facilities are matched by their NAICS code and reported fuel type with the proportion of combustion fuel energy for each end use category identified in the 2010 Energy Information Administration Manufacturing Energy Consumption Survey (MECS, http://www.eia.gov/consumption/manufacturing/data/2010/). MECS data are adjusted to account for data that were withheld or whose end use was unspecified following the procedure described in Fox, Don B., Daniel Sutter, and Jefferson W. Tester. 2011. The Thermal Spectrum of Low-Temperature Energy Use in the United States, NY: Cornell Energy Institute.

  2. Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion

    SciTech Connect (OSTI)

    Ho, Min-Da.

    1993-05-25

    A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

  3. Jet plume injection and combustion system for internal combustion engines

    DOE Patents [OSTI]

    Oppenheim, A.K.; Maxson, J.A.; Hensinger, D.M.

    1993-12-21

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure. 24 figures.

  4. Jet plume injection and combustion system for internal combustion engines

    DOE Patents [OSTI]

    Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

    1993-01-01

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

  5. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F

  6. Rape oil methyl ester (RME) and used cooking oil methyl ester (UOME) as alternative fuels

    SciTech Connect (OSTI)

    Hohl, G.H.

    1995-12-31

    The author presents a review about the fleet tests carried out by the Austrian Armed Forces concerning the practical application of a vegetable oil, i.e Rape Oil Methyl Ester (RME) and Used Cooking Oil Methyl Ester (UOME) as alternative fuels for vehicles under military conditions, and reviews other research results carried out in Austria. As a result of over-production in Western European agriculture, the increase in crop yields has led to tremendous surpluses. Alternative agricultural products have been sought. One alternative can be seen in biological fuel production for tractors, whereby the farmer is able to produce his own fuel supply as was the case when he previously provided self-made feed for his horses. For the market introduction different activities were necessary. A considerable number of institutes and organizations including the Austrian Armed Forces have investigated, tested and developed these alternative fuels. The increasing disposal problems of used cooking oil have initiated considerations for its use. The recycling of this otherwise waste product, and its preparation for use as an alternative fuel to diesel oil, seems to be most promising.

  7. Advanced High Efficiency Clean Diesel Combustion with Low Cost...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Advanced High Efficiency Clean Diesel Combustion with Low Cost for Hybrid Engines Clean, in-cylinder combustion ...

  8. Multicylinder Diesel Engine for Low Temperature Combustion Operation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Low Temperature Combustion Operation Multicylinder Diesel Engine for Low Temperature Combustion Operation Fuel injection strategies to extend low temperature combustion ...

  9. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Broader source: Energy.gov (indexed) [DOE]

    Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion Impact of Variable Valve Timing on Low Temperature Combustion Multicylinder Diesel Engine Design for ...

  10. H2 Internal Combustion Engine Research Towards 45% efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling

  11. Modeling of HCCI and PCCI Combustion Processes | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI and PCCI Combustion Processes Modeling of HCCI and PCCI Combustion Processes 2005 ... More Documents & Publications Numerical Modeling of HCCI Combustion High Fidelity Modeling ...

  12. Combustor nozzle for a fuel-flexible combustion system (Patent...

    Office of Scientific and Technical Information (OSTI)

    The combustor nozzle includes a first fuel system configured to introduce a syngas fuel into a combustion chamber to enable lean premixed combustion within the combustion chamber ...

  13. Low-Temperature Combustion Demonstrator for High-Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for High-Efficiency Clean Combustion Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  14. Turbulent Combustion in SDF Explosions

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E

    2009-11-12

    A heterogeneous continuum model is proposed to describe the dispersion and combustion of an aluminum particle cloud in an explosion. It combines the gas-dynamic conservation laws for the gas phase with a continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models. It incorporates a combustion model based on the mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the C-4 booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Numerical simulations of the explosion fields from 1.5-g Shock-Dispersed-Fuel (SDF) charge in a 6.6 liter calorimeter were used to validate the combustion model. Then the model was applied to 10-kg Al-SDF explosions in a an unconfined height-of-burst explosion. Computed pressure histories are compared with measured waveforms. Differences are caused by physical-chemical kinetic effects of particle combustion which induce ignition delays in the initial reactive blast wave and quenching of reactions at late times. Current simulations give initial insights into such modeling issues.

  15. Compositions of alkyl 4-[o-(substituted amino)phenyl]-3-thioallophanates and methods of use

    DOE Patents [OSTI]

    Adams, Charles De Witt

    1977-03-01

    Various alkyl 4-[o-(substituted amino)phenyl]-3-thioallophanates are useful as fungicides and mite ovicides. An exemplary specie is methyl 4-(o-butyramidophenyl)-3-thioallophanate.

  16. PROCESS OF RECOVERING ZIRCONIUM VALUES FROM HAFNIUM VALUES BY SOLVENT EXTRACTION WITH AN ALKYL PHOSPHATE

    DOE Patents [OSTI]

    Peppard, D.F.

    1960-02-01

    A process of separating hafnium nitrate from zirconium nitrate contained in a nitric acid solution by selectively. extracting the zirconium nitrate with a water-immiscible alkyl phosphate is reported.

  17. Method and apparatus for detecting combustion instability in continuous combustion systems

    DOE Patents [OSTI]

    Benson, Kelly J.; Thornton, Jimmy D.; Richards, George A.; Straub, Douglas L.

    2006-08-29

    An apparatus and method to sense the onset of combustion stability is presented. An electrode is positioned in a turbine combustion chamber such that the electrode is exposed to gases in the combustion chamber. A control module applies a voltage potential to the electrode and detects a combustion ionization signal and determines if there is an oscillation in the combustion ionization signal indicative of the occurrence of combustion stability or the onset of combustion instability. A second electrode held in a coplanar but spaced apart manner by an insulating member from the electrode provides a combustion ionization signal to the control module when the first electrode fails. The control module broadcasts a notice if the parameters indicate the combustion process is at the onset of combustion instability or broadcasts an alarm signal if the parameters indicate the combustion process is unstable.

  18. Asymmetric Intramolecular Alkylation of Chiral Aromatic Imines via Catalytic C-H Bond Activation

    SciTech Connect (OSTI)

    Watzke, Anja; Wilson, Rebecca; O'Malley, Steven; Bergman, Robert; Ellman, Jonathan

    2007-04-16

    The asymmetric intramolecular alkylation of chiral aromatic aldimines, in which differentially substituted alkenes are tethered meta to the imine, was investigated. High enantioselectivities were obtained for imines prepared from aminoindane derivatives, which function as directing groups for the rhodium-catalyzed C-H bond activation. Initial demonstration of catalytic asymmetric intramolecular alkylation also was achieved by employing a sterically hindered achiral imine substrate and catalytic amounts of a chiral amine.

  19. Stratified charge internal combustion engine

    SciTech Connect (OSTI)

    Skopil, A.O.

    1991-01-01

    This patent describes an internal combustion engine. It comprises: a main cylinder, a main piston within the main cylinder, and means for delivering a combustible charge into the main cylinder; a smaller idle cylinder, and idle piston within the idle cylinder, and means for delivering a combustible charge into the idle cylinder; an ignition passageway leading from the idle cylinder to the main cylinder; and an ignition device within the ignition passageway operable to ignite a compressed charge discharged by the idle cylinder into the ignition passageway. The passageway being positioned to discharge the ignited compressed charge from the idle cylinder into the main cylinder to ignite the compressed charge within the main cylinder.

  20. Steam boosted internal combustion engine

    SciTech Connect (OSTI)

    Green, M.A.

    1987-01-20

    A device is described to supplement the power produced by burning fuel in an internal combustion engine with steam, the device comprising: a means for producing a constant flow of water past a boiler means; a means for allowing the water to flow in the direction of the boiler; a boiler means external to the internal combustion engine to convert the water into superheated steam; a means for controlling the pressure of the water such that the water pressure is greater than the pressure of the steam produced by the boiler; and a means for injection of the superheated steam directly into a cylinder of the internal combustion engine, a means for producing a constant flow of water at a pressure greater than the pressure of the superheated steam, wherein the constant flow means at greater pressure comprises a chamber with a gaseous component, with the gaseous component being of constant volume and exerting constant pressure upon water within the chamber.

  1. Effects of alkyl polyglycoside (APG) on composting of agricultural wastes

    SciTech Connect (OSTI)

    Zhang Fabao; Gu Wenjie; Xu Peizhi; Tang Shuanhu; Xie Kaizhi; Huang Xu; Huang Qiaoyi

    2011-06-15

    Composting is the biological degradation and transformation of organic materials under controlled conditions to promote aerobic decomposition. To find effective ways to accelerate composting and improve compost quality, numerous methods including additive addition, inoculation of microorganisms, and the use of biosurfactants have been explored. Studies have shown that biosurfactant addition provides more favorable conditions for microorganism growth, thereby accelerating the composting process. However, biosurfactants have limited applications because they are expensive and their use in composting and microbial fertilizers is prohibited. Meanwhile, alkyl polyglycoside (APG) is considered a 'green' surfactant. This study aims to determine whether APG addition into a compost reaction vessel during 28-day composting can enhance the organic matter degradation and composting process of dairy manure. Samples were periodically taken from different reactor depths at 0, 3, 5, 7, 14, 21, and 28 days. pH levels, electrical conductivity (EC), ammonium and nitrate nitrogen, seed germination indices, and microbial population were determined. Organic matter and total nitrogen were also measured. Compared with the untreated control, the sample with APG exhibited slightly increased microbial populations, such as bacteria, fungi, and actinomycetes. APG addition increased temperatures without substantially affecting compost pH and EC throughout the process. After 28 days, APG addition increased nitrate nitrogen concentrations, promoted matter degradation, and increased seed germination indices. The results of this study suggest that the addition of APG provides more favorable conditions for microorganism growth, slightly enhancing organic matter decomposition and accelerating the composting process, improving the compost quality to a certain extent.

  2. Combustion instability modeling and analysis

    SciTech Connect (OSTI)

    Santoro, R.J.; Yang, V.; Santavicca, D.A.; Sheppard, E.J.

    1995-12-31

    It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

  3. Combustion synthesis method and products

    DOE Patents [OSTI]

    Holt, J.B.; Kelly, M.

    1993-03-30

    Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

  4. Combustion synthesis method and products

    DOE Patents [OSTI]

    Holt, J. Birch; Kelly, Michael

    1993-01-01

    Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

  5. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, Richard G.; Walton, Otis R.; Lewis, Arthur E.; Braun, Robert L.

    1985-01-01

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

  6. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

    1983-09-21

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

  7. Engine Combustion Network Experimental Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maintained by the Engine Combustion Department of Sandia National Laboratories, data currently available on the website includes reacting and non-reacting sprays in a constant-volume chamber at conditions typical of diesel combustion. The data are useful for model development and validation because of the well-defined boundary conditions and the wide range of conditions employed. A search utility displays data based on experimental conditions such as ambient temperature, ambient density, injection pressure, nozzle size, fuel, etc. Experiment-related visualizations are also available. (Specialized Interface)

  8. Engine Combustion Network Experimental Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maintained by the Engine Combustion Department of Sandia National Laboratories, data currently available on the website includes reacting and non-reacting sprays in a constant-volume chamber at conditions typical of diesel combustion. The data are useful for model development and validation because of the well-defined boundary conditions and the wide range of conditions employed. A search utility displays data based on experimental conditions such as ambient temperature, ambient density, injection pressure, nozzle size, fuel, etc. Experiment-related visualizations are also available. The search utility for experimental data is located at http://public.ca.sandia.gov/ecn/cvdata/frameset.html (Specialized Interface)

  9. Chemical kinetics and combustion modeling

    SciTech Connect (OSTI)

    Miller, J.A.

    1993-12-01

    The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

  10. Improved Solvers for Advanced Engine Combustion Simulation

    Broader source: Energy.gov [DOE]

    Document:  ace076_mcnenly_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Matthew McNenlyPresenting Organization: Lawrence Livermore National Laboratory ...

  11. Pre-Combustion Carbon Capture Research

    Broader source: Energy.gov [DOE]

    Pre-combustion capture refers to removing CO2 from fossil fuels before combustion is completed. For example, in gasification processes a feedstock (such as coal) is partially oxidized in steam and...

  12. Method for storing radioactive combustible waste

    DOE Patents [OSTI]

    Godbee, H.W.; Lovelace, R.C.

    1973-10-01

    A method is described for preventing pressure buildup in sealed containers which contain radioactively contaminated combustible waste material by adding an oxide getter material to the container so as to chemically bind sorbed water and combustion product gases. (Official Gazette)

  13. Open cycle, internal combustion Stirling engine

    SciTech Connect (OSTI)

    Thring, R.H.

    1991-09-24

    This patent describes an internal- combustion fluid engine. It comprises means, including a hot piston, for defining a combustion chamber; means for causing combustion within the combustion chamber; means, including a cold piston, for defining a compression chamber for pressurizing a fluid; inlet control means for controlling flow of the fluid into the compression chamber; cooling means for maintaining lower temperature in the compression chamber than in the combustion chamber; means, comprising linkage between the hot piston and the cold piston, for varying the volume of the compression chamber in relation to the volume of the combustion chamber in a manner characteristic of a conventional Stirling engine; a manifold connected in fluid communication between the combustion chamber and the compression chamber for enabling flow of the fluid from the compression chamber to the compression chamber; transfer control means for controlling the flow of the fluid from the compression chamber to the combustion chamber.

  14. Heavy Duty Low-Temperature & Diesel Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Security Lab Foundations Bioscience Computing & Info Sciences Geoscience Engineering ... diesel engines will likely require unconventional engine combustion and operating ...

  15. Oxygen-Enriched Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion Oxygen-Enriched Combustion This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING TIP SHEET #3 Oxygen-Enriched Combustion (September 2005) (249.42 KB) More Documents & Publications Save Energy Now in Your Process Heating Systems Waste Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions Performance: A

  16. Preheated Combustion Air | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preheated Combustion Air Preheated Combustion Air This tip sheet describes how to improve process heating efficiency by preheating combustion air for burners. PROCESS HEATING TIP SHEET #1 Preheated Combustion Air (November 2007) (232.65 KB) More Documents & Publications Waste Heat Reduction and Recovery for Improving Furnace Efficiency, Productivity and Emissions Performance: A BestPractices Process Heating Technical Brief Install Waste Heat Recovery Systems for Fuel-Fired Furnaces Load

  17. Premix charge, compression ignition combustion system optimization |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Premix charge, compression ignition combustion system optimization Premix charge, compression ignition combustion system optimization Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_gustafson.pdf (1.47 MB) More Documents & Publications Advanced Combustion Technology to Enable High Efficiency Clean Combustion Heavy-Duty HCCI Development

  18. Effects of Advanced Combustion Technologies on Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics ...

  19. Building America Case Study: Combustion Safety Simplified Test...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Safety Simplified Test Protocol Chicago, Illinois, and Minneapolis, Minnesota PROJECT INFORMATION Project Name: Combustion Safety Simplified Test Protocol Location: ...

  20. Reduced No.sub.x combustion method

    DOE Patents [OSTI]

    Delano, Mark A.

    1991-01-01

    A combustion method enabling reduced NO.sub.x formation wherein fuel and oxidant are separately injected into a combustion zone in a defined velocity relation, combustion gases are aspirated into the oxidant stream prior to intermixture with the fuel, and the fuel is maintained free from contact with oxygen until the intermixture.

  1. Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

    DOE Patents [OSTI]

    Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

    2008-10-07

    This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

  2. Combustor nozzle for a fuel-flexible combustion system

    DOE Patents [OSTI]

    Haynes, Joel Meier; Mosbacher, David Matthew; Janssen, Jonathan Sebastian; Iyer, Venkatraman Ananthakrishnan

    2011-03-22

    A combustor nozzle is provided. The combustor nozzle includes a first fuel system configured to introduce a syngas fuel into a combustion chamber to enable lean premixed combustion within the combustion chamber and a second fuel system configured to introduce the syngas fuel, or a hydrocarbon fuel, or diluents, or combinations thereof into the combustion chamber to enable diffusion combustion within the combustion chamber.

  3. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace001_musculus_2011_o.pdf (1.84 MB) More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

  4. Combustive management of oil spills

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris.

  5. ESTER, Enel integrated System for TEsts on stoRage (Smart Grid...

    Open Energy Info (EERE)

    ESTER, Enel integrated System for TEsts on stoRage (Smart Grid Project) Jump to: navigation, search Project Name ESTER, Enel integrated System for TEsts on stoRage Country Italy...

  6. Rheinische Bio Ester GmbH Co KG | Open Energy Information

    Open Energy Info (EERE)

    Rheinische Bio Ester GmbH Co KG Jump to: navigation, search Name: Rheinische Bio Ester GmbH & Co.KG Place: Neuss, North Rhine-Westphalia, Germany Zip: 41460 Product: Rheinische Bio...

  7. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, B.D.; Confer, G.L.; Zujing Shen; Hapeman, M.J.; Flynn, P.L.

    1993-12-21

    Apparatus and a method of introducing a primary fuel, which may be a coal water slurry, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure. 19 figures.

  8. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, Bertrand D.; Confer, Gregory L.; Shen, Zujing; Hapeman, Martin J.; Flynn, Paul L.

    1993-12-21

    Apparatus and a method of introducing a primary fuel, which may be a coal water slutty, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure.

  9. Light Duty Efficient, Clean Combustion

    SciTech Connect (OSTI)

    Donald Stanton

    2010-12-31

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy's Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of the following objectives were met with fuel efficiency improvement targets exceeded: (1) Improve light duty vehicle (5000 lb. test weight) fuel efficiency by 10.5% over today's state-of-the-art diesel engine on the FTP city drive cycle; (2) Develop and design an advanced combustion system plus aftertreatment system that synergistically meets Tier 2 Bin 5 NOx and PM emissions standards while demonstrating the efficiency improvements; (3) Maintain power density comparable to that of current conventional engines for the applicable vehicle class; and (4) Evaluate different fuel components and ensure combustion system compatibility with commercially available biofuels. Key accomplishments include: (1) A 25% improvement in fuel efficiency was achieved with the advanced LDECC engine equipped with a novel SCR aftertreatment system compared to the 10.5% target; (2) An 11% improvement in fuel efficiency was achieved with the advanced LDECC engine and no NOx aftertreamtent system; (3) Tier 2 Bin 5 and SFTP II emissions regulations were met with the advanced LDECC engine equipped with a novel SCR aftertreatment system; (4) Tier 2 Bin 5 emissions regulations were met with the advanced LDECC engine and no NOx aftertreatment, but SFTP II emissions regulations were not met for the US06 test cycle - Additional technical barriers exist for the no NOx

  10. Combustion diagnostic for active engine feedback control

    DOE Patents [OSTI]

    Green, Jr., Johney Boyd; Daw, Charles Stuart; Wagner, Robert Milton

    2007-10-02

    This invention detects the crank angle location where combustion switches from premixed to diffusion, referred to as the transition index, and uses that location to define integration limits that measure the portions of heat released during the combustion process that occur during the premixed and diffusion phases. Those integrated premixed and diffusion values are used to develop a metric referred to as the combustion index. The combustion index is defined as the integrated diffusion contribution divided by the integrated premixed contribution. As the EGR rate is increased enough to enter the low temperature combustion regime, PM emissions decrease because more of the combustion process is occurring over the premixed portion of the heat release rate profile and the diffusion portion has been significantly reduced. This information is used to detect when the engine is or is not operating in a low temperature combustion mode and provides that feedback to an engine control algorithm.

  11. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Ojeda, William de

    2010-07-31

    The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally

  12. Combustion synthesis continuous flow reactor

    DOE Patents [OSTI]

    Maupin, Gary D.; Chick, Lawrence A.; Kurosky, Randal P.

    1998-01-01

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

  13. Internal combustion engine fuel feed

    SciTech Connect (OSTI)

    Cochard, P.; Guicherd, C.

    1980-02-19

    In a method and apparatus for controlling the fuel feed to a stratified-charge internal combustion engine, from idle up to the position corresponding with the maximum flow of air, the overall richness (Rg) of the combustible mixture is reduced by acting simultaneously upon the flow of fuel feeding the main chamber and upon the flow of fuel injected into the auxiliary chamber. For higher loads the maximum flow of air is kept constant and rg is increased by continuing to act upon both fuel flows. By keeping the richness of the mixture in the auxiliary chamber substantially constant, it is possible to obtain the best compromise between the performance of the engine and the emission of pollutant gases.

  14. Combustion synthesis continuous flow reactor

    DOE Patents [OSTI]

    Maupin, G.D.; Chick, L.A.; Kurosky, R.P.

    1998-01-06

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor. 10 figs.

  15. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    Wendt, J.; Eddings, E.; Lighty, J.; Ring, T.; Smith, P.; Thornock, J.; Y Jia, W. Morris; Pedel, J.; Rezeai, D.; Wang, L.; Zhang, J.; Kelly, K.

    2012-01-06

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol.

  16. Particle Ignition and Char Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ignition and Char Combustion - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  17. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  18. ABB Combustion Engineering nuclear technology

    SciTech Connect (OSTI)

    Matzie, R.A.

    1994-12-31

    The activities of ABB Combustion Engineering in the design and construction of nuclear systems and components are briefly reviewed. ABB Construction Engineering continues to improve the design and design process for nuclear generating stations. Potential improvements are evaluated to meet new requirements both of the public and the regulator, so that the designs meet the highest standards worldwide. Advancements necessary to meet market needs and to ensure the highest level of performance in the future will be made.

  19. Homogeneous catalysts in hypersonic combustion

    SciTech Connect (OSTI)

    Harradine, D.M.; Lyman, J.L.; Oldenborg, R.C.; Pack, R.T.; Schott, G.L.

    1989-01-01

    Density and residence time both become unfavorably small for efficient combustion of hydrogen fuel in ramjet propulsion in air at high altitude and hypersonic speed. Raising the density and increasing the transit time of the air through the engine necessitates stronger contraction of the air flow area. This enhances the kinetic and thermodynamic tendency of H/sub 2/O to form completely, accompanied only by N/sub 2/ and any excess H/sub 2/(or O/sub 2/). The by-products to be avoided are the energetically expensive fragment species H and/or O atoms and OH radicals, and residual (2H/sub 2/ plus O/sub 2/). However, excessive area contraction raises air temperature and consequent combustion-product temperature by adiabatic compression. This counteracts and ultimately overwhelms the thermodynamic benefit by which higher density favors the triatomic product, H/sub 2/O, over its monatomic and diatomic alternatives. For static pressures in the neighborhood of 1 atm, static temperature must be kept or brought below ca. 2400 K for acceptable stability of H/sub 2/O. Another measure, whose requisite chemistry we address here, is to extract propulsive work from the combustion products early in the expansion. The objective is to lower the static temperature of the combustion stream enough for H/sub 2/O to become adequately stable before the exhaust flow is massively expanded and its composition ''frozen.'' We proceed to address this mechanism and its kinetics, and then examine prospects for enhancing its rate by homogeneous catalysts. 9 refs.

  20. Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Post-Doctoral Position in Direct Numerical Simulations of Low-Dimensional Reacting Flows The Combustion EFRC seeks outstanding applicants for the position of post-doctoral research associate to perform research at the University of Southern California and the Sandia National Laboratories on multi-dimensional simulations of a number of experimental configurations. The development of detailed kinetic models describing the pyrolysis and oxidation of fuels depends heavily on experimental data that

  1. Oil shale combustion/retorting

    SciTech Connect (OSTI)

    Not Available

    1983-05-01

    The Morgantown Energy Technology Center (METC) conducted a number of feasibility studies on the combustion and retorting of five oil shales: Celina (Tennessee), Colorado, Israeli, Moroccan, and Sunbury (Kentucky). These studies generated technical data primarily on (1) the effects of retorting conditions, (2) the combustion characteristics applicable to developing an optimum process design technology, and (3) establishing a data base applicable to oil shales worldwide. During the research program, METC applied the versatile fluidized-bed process to combustion and retorting of various low-grade oil shales. Based on METC's research findings and other published information, fluidized-bed processes were found to offer highly attractive methods to maximize the heat recovery and yield of quality oil from oil shale. The principal reasons are the fluidized-bed's capacity for (1) high in-bed heat transfer rates, (2) large solid throughput, and (3) selectivity in aromatic-hydrocarbon formation. The METC research program showed that shale-oil yields were affected by the process parameters of retorting temperature, residence time, shale particle size, fluidization gas velocity, and gas composition. (Preferred values of yields, of course, may differ among major oil shales.) 12 references, 15 figures, 8 tables.

  2. Is combustion of plastics desirable?

    SciTech Connect (OSTI)

    Piasecki, B.; Rainey, D.; Fletcher, K.

    1998-07-01

    Managing waste will always entail some tradeoffs. All of the three options--recycling, landfilling and combustion--have some disadvantages. Even landfilling, which produces no emissions, fails to take advantage of the energy value inherent in plastic. Waste combustion, on the other hand, recovers the energy in plastic materials and reduces the volume of disposed solid waste by up to 90% of its initial preburn volumes. However, this management option generates emissions and produces an ash residue that must be managed. As demonstrated by recent test burns, improvements in combustion and air-pollution-control technology have dramatically reduced the health risks from emissions and ash. Recent studies have shown that plastics--in quantities even higher than those normally found in municipal solid waste--do not adversely affect levels of emissions or the quality of ash from waste-to-energy facilities. In addition, waste-to-energy facilities may be a relatively economical source of fuel, and may be a more economic solution to waste management than the other available options. A waste-to-energy plant generally produces electricity that is sold to the electric utilities for approximately six cents per kilowatt-hour, a rate that is competitive with those offered by nuclear power plants and power plants that generate energy by burning fossil fuels.

  3. US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Advanced Combustion and Emission Control Technical Team Roadmap US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap The ACEC focuses on advanced engine and aftertreatment technology for three major combustion strategies: (1) Low-Temperature Combustion, (2) Dilute Gasoline combustion, and (3) Clean Diesel Combustion. acec_roadmap_june2013.pdf (1.29 MB) More Documents & Publications Overview of the Advanced Combustion Engine R&D Overview of DOE

  4. Impact of Variable Valve Timing on Low Temperature Combustion | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Variable Valve Timing on Low Temperature Combustion Impact of Variable Valve Timing on Low Temperature Combustion Documents effects of variable valve actuation in implementing low temperature combustion in production engine platform. deer10_de_ojeda.pdf (1.64 MB) More Documents & Publications Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Multicylinder Diesel Engine for

  5. Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

    DOE Patents [OSTI]

    Roberts, Jr., Charles E.; Chadwell, Christopher J.

    2004-09-21

    The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

  6. Suppression of alkylating agent induced cell transformation and gastric ulceration by low-dose alkylating agent pretreatment

    SciTech Connect (OSTI)

    Onodera, Akira; Department of Pharmaceutical Sciences, Kobegakuin University, 1-1-3 Minatojima, Chuo-ku, Kobe 650-8586 ; Kawai, Yuichi; Kashimura, Asako; Ogita, Fumiya; Tsutsumi, Yasuo; Itoh, Norio

    2013-06-14

    Highlights: Low-dose MNNG pretreatment suppresses high-dose MNNG induced in vitro transformation. Gastric ulcers induced by high-dose MNNG decreased after low-dose MNNG pretreatment. Efficacy of low-dose MNNG related to resistance of mutation and oxidative stress. -- Abstract: Exposure to mild stress by chemicals and radiation causes DNA damage and leads to acquired stress resistance. Although the linear no-threshold (LNT) model of safety assessment assumes risk from any dose, evidence from radiological research demonstrates a conflicting hormetic phenomenon known as the hormesis effect. However, the mechanisms underlying radiation hormesis have not yet been clarified, and little is known about the effects of low doses of chemical carcinogens. We analyzed the efficacy of pretreatment with low doses of the alkylating agent N-methyl-N?-nitro-N-nitrosoguanidine (MNNG) on the subsequent induction of cell transformation and gastric ulceration by high-dose MNNG. We used an in vitro Balb/3T3 A31-1-1 cell transformation test and monitored the formation of gastric ulcers in 5-week-old male ICR mice that were administered MNNG in drinking water. The treatment concentrations of MNNG were determined by the cell survival rate and past reports. For low-dose in vitro and in vivo experiments, MNNG was used at 0.028 ?M, and 2.8 ?g/mL, respectively. The frequency of cell transformation induced by 10 ?m MNNG was decreased by low-dose MNNG pretreatment to levels similar to that of spontaneous transformation. In addition, reactive oxygen species (ROS) and mutation frequencies induced by 10 ?m MNNG were decreased by low-dose MNNG pretreatment. Importantly, low-dose MNNG pretreatment had no effect on cell proliferation. In vivo studies showed that the number of gastric ulcers induced by 1 mg/mL MNNG decreased after low-dose MNNG pretreatment. These data indicate that low-dose pretreatment with carcinogens may play a beneficial role in the prevention of chemical toxicity under

  7. A survey of plant practices and experience in HF alkylation units

    SciTech Connect (OSTI)

    Dobis, J.D.; Clarida, D.R.; Richert, J.P.

    1994-12-31

    The T-8-20 Task Group conducted a survey of plant practices and of the performance of materials of construction in HF alkylation units. A primary goal of the survey was to expand the limited body of information on alternative alloy performance in HF alkylation units and to better define the susceptibility of steel to hydrogen induced cracking. Survey results indicate that although the incidence of cracking is reported to be low, hydrogen blistering is commonly found in pressure vessels. Few applications of alternative alloys were reported, but several areas of vulnerability or high corrosion rates are identified. Common design and maintenance practices are reviewed.

  8. Sandia Combustion Research Program: Annual report, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    This report presents research results of the past year, divided thematically into some ten categories. Publications and presentations arising from this work are included in the appendix. Our highlighted accomplishment of the year is the announcement of the discovery and demonstration of the RAPRENOx process. This new mechanism for the elimination of nitrogen oxides from essentially all kinds of combustion exhausts shows promise for commercialization, and may eventually make a significant contribution to our nation's ability to control smog and acid rain. The sections of this volume describe the facility's laser and computer system, laser diagnostics of flames, combustion chemistry, reacting flows, liquid and solid propellant combustion, mathematical models of combustion, high-temperature material interfaces, studies of engine/furnace combustion, coal combustion, and the means of encouraging technology transfer. 182 refs., 170 figs., 12 tabs.

  9. Industrial Combustion Vision: A Vision by and for the Industrial Combustion Community

    SciTech Connect (OSTI)

    none,

    1998-05-01

    The Industrial Combustion Vision is the result of a collaborative effort by manufacturers and users of burners, boilers, furnaces, and other process heating equipment. The vision sets bold targets for tomorrow's combustion systems.

  10. Constant Volume During Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Constant Volume During Combustion Constant Volume During Combustion This presentation covers constant volume during combustion and discusses how it can alter the kinematics of piston to crankshaft travel. deer08_joniec.pdf (88.76 KB) More Documents & Publications Utilizing the Rapid Ignition Region of HCCI to Attain > 60% BTE 50% thermo-mechanical efficiency utilizing a free-piston engine in Hybrid vehicles DOE-HDBK-1018/1-93

  11. NREL: Transportation Research - Fuel Combustion Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Laboratory NREL's Fuel Combustion Laboratory focuses on characterizing fuels at the molecular level. This information can then be used to understand and predict a fuel's effect on engine performance and emissions. By understanding the effects of fuel chemistry on ignition, as well as the potential emissions impacts, we can develop fuels that enable more efficient engine designs, using both today's technology and future advanced combustion concepts. This lab supports the Renewable

  12. Chemical Looping Combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Looping Combustion chemical-looping-combustion.jpg An economical option for using our abundant, domestic coal resources while eliminating CO2 emissions may sound like science fiction, but NETL researchers are working to bring this technology of the future into the present. Chemical looping is the solution. This cost-effective indirect combustion technology has CO2 capture "built in," effectively eradicating greenhouse gas emissions from coal. Although still a few years away

  13. 2010 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2010 Session Course Descriptions Lecturers Lecture Notes 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2010 Session 2010 Session The 2010 session, held from June 27 to July 3, offered the following two courses: (1) Combustion Theory, delivered by Professor Norbert Peters of RWTH-Aachen, Germany, and (2) Combustion Chemistry, jointly delivered by Dr. Charles K.

  14. 2011 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Descriptions Lecturers Lecture Notes FAQs 2010 Session 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2011 Session 2011 Session The 2011 session, held from June 26 to July 1, offered the following three courses: (1) Combustion Theory, delivered by Professor Moshe Matalon of the University of Illinois at Urbana-Champaign, (2) Combustion Chemistry, delivered by

  15. 2012 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Descriptions Lecturers Lecture Notes 2011 Session 2010 Session 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2012 Session 2012 Session The 2012 session, held from June 24 to June 29, offered the following courses: Combustion Theory, delivered by Professor Heinz Pitsch of the RWTH Aachen University; Combustion Chemistry, delivered by Professor Hai Wang of the

  16. 2013 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Descriptions Lecture Notes Lecture Videos 2012 Session 2011 Session 2010 Session 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2013 Session 2013 Session The 2013 session, held from June 23 to June 28, offered the following courses: Combustion Theory, delivered by Professor Moshe Matalon of the University of Illinois at Urbana-Champaign; Combustion Chemistry,

  17. Combustion with reduced carbon in the ash

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2005-12-27

    Combustion of coal in which oxygen is injected into the coal as it emerges from burner produces ash having reduced amounts of carbon.

  18. Predicting Pressure-Dependent Combustion Chemical Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Chemical Reactions HomeCapabilities, Computational Modeling & Simulation, CRF, Energy, ... in combus-tion and atmospheric chemistry that is expected to benefit auto and ...

  19. Engine Valve Actuation For Combustion Enhancement

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Rutland, Christopher J.; Jhavar, Rahul

    2004-05-18

    A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-stroke combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

  20. Engine valve actuation for combustion enhancement

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Rutland, Christopher J.; Jhavar, Rahul

    2008-03-04

    A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-strokes combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

  1. Vehicle Technologies Office: 2015 Advanced Combustion Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technologies under development. Research focuses on addressing critical barriers to commercializing higher efficiency, very low emissions advanced internal combustion engines for ...

  2. Vehicle Technologies Office: 2014 Advanced Combustion Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technologies under development. Research focuses on addressing critical barriers to commercializing higher efficiency, very low emissions advanced internal combustion engines for ...

  3. Stochastic (w*) Convergence for Turbulent Combustion | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stochastic (w*) Convergence for Turbulent Combustion PI Name: James Glimm PI Email: ... chemistry for LES, and (2) stochastic (w*) convergence based on probability ...

  4. Engine Combustion Network (ECN): Global sensitivity analysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 Date Published June 2015 Keywords diesel, Engine Combustion Network, global sensitivity ... The uncertainty in the fuel temperature was found to have a profound influence on the ...

  5. Cummins Executives Visit Combustion Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EnergyWater History Water Monitoring & Treatment Technology Decision Models for ... Sandia's transportation Energy Center) low-temperature gasoline combustion (LTGC) engine ...

  6. understanding the low-temperature combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-temperature combustion chemistry - Sandia Energy Energy Search Icon Sandia Home ... EnergyWater History Water Monitoring & Treatment Technology Decision Models for ...

  7. Advancing Internal Combustion Engine Simulations using Sensitivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advancing Internal Combustion Engine Simulations using Sensitivity Analysis PI Name: Sibendu Som PI Email: ssom@anl.gov Institution: Argonne National Laboratory Allocation Program:...

  8. Boiler Combustion Control and Monitoring System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... What Were the Benefits? boilercombustionchart.jpg The boiler combustion control and monitoring system was installed on a 25 MMBtuhr steam boiler located at the Watervliet ...

  9. Application Schedule - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application Schedule Application Schedule Applications for the Combustion Energy Research Fellows program are considered on a rolling basis. Applicant selection occurs three times...

  10. Past Sessions - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home 2015 Combustion Summer School Past Sessions Past Sessions 2015 Session 2014 Session 2013 Session...

  11. Pyrolysis reactor and fluidized bed combustion chamber

    DOE Patents [OSTI]

    Green, Norman W.

    1981-01-06

    A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

  12. Oxy-Combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... to supply O2, atmospheric-pressure combustion for fuel conversion in a conventional supercritical pulverized-coal boiler; substantial flue gas recycle; conventional pollution ...

  13. Major Lectures & Conference Papers - Combustion Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beijing, China, (2010). "Formation of Nascent Soot and Other Condensed-Phase Materials in Flames," by Hai Wang, 33rd International Symposium on Combustion, Beijing, China, ...

  14. Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

    SciTech Connect (OSTI)

    Strzelec, Andrea

    2009-12-01

    The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

  15. Rotary reciprocating internal combustion engine

    SciTech Connect (OSTI)

    Ogren, W.

    1992-06-23

    This patent describes a rotary reciprocating internal combustion engine. It comprises a housing which comprises a cylindrical head with two end and frame plates mounted on both ends of the head enclose the head, the head including a pair of fuel into ports and a pair of exhaust ports, a pair of ring gears; a rotor axially aligned in the cylindrical head and comprising a set of four radially extending cylinders and pistons reciprocable in the cylinders; a power take off shaft fixed to the crank support plates and axially aligned with the rotor; oiling means for oiling the rotary engine; and a set of eight crank gears.

  16. Theoretical studies of combustion dynamics

    SciTech Connect (OSTI)

    Bowman, J.M.

    1993-12-01

    The basic objectives of this research program are to develop and apply theoretical techniques to fundamental dynamical processes of importance in gas-phase combustion. There are two major areas currently supported by this grant. One is reactive scattering of diatom-diatom systems, and the other is the dynamics of complex formation and decay based on L{sup 2} methods. In all of these studies, the authors focus on systems that are of interest experimentally, and for which potential energy surfaces based, at least in part, on ab initio calculations are available.

  17. Chemical Kinetics of Combustion Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Combustion Processes Hai Wang B. Yang, J. Camacho, S. Lieb, S. Memarzadeh, S.-K. Gao and S. Koumlis University of Southern California 2010 CEFRC Conference Benzene + O( 3 P) → Products * Overall rate coefficient extensively studied, but the products and branching ratios not well known. * Theoretical challenges in dealing with spin-state crossing. Figure 1. Branching ratios observed as a function of temperature at 4 Torr for (a) m/z=94/93 and m/z=66/65 by magnetic sector mass spectrometer

  18. Optical investigation of the combustion behaviour inside the engine operating in HCCI mode and using alternative diesel fuel

    SciTech Connect (OSTI)

    Mancaruso, E.; Vaglieco, B.M.

    2010-04-15

    In order to understand the effect of both the new homogeneous charge compression ignition (HCCI) combustion process and the use of biofuel, optical measurements were carried out into a transparent CR diesel engine. Rape seed methyl ester was used and tests with several injection pressures were performed. OH and HCO radical were detected and their evolutions were analyzed during the whole combustion. Moreover, soot concentration was measured by means the two colour pyrometry method. The reduction of particulate emission with biodiesel as compared to the diesel fuel was noted. Moreover, this effect resulted higher increasing the injection pressure. In the case of RME the oxidation of soot depends mainly from O{sub 2} content of fuel and OH is responsible of the NO formation in the chamber as it was observed for NO{sub x} exhaust emission. Moreover, it was investigated the evolution of HCO and CO into the cylinder. HCO was detected at the start of combustion. During the combustion, HCO oxidizes due to the increasing temperature and it produces CO. Both fuels have similar trend, the highest concentrations are detected for low injection pressure. This effect is more evident for the RME fuel. (author)

  19. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, P.S.; Ts'o, P.O.P.

    1999-06-15

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

  20. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, Paul S.; Ts'o, Paul O.P.

    1999-06-15

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid and includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional.

  1. Vehicle Technologies Office: 2011 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion R&D Annual Progress Report Vehicle Technologies Office: 2011 Advanced Combustion R&D Annual Progress Report Annual report on the work of the the Advanced Combustion ...

  2. Vehicle Technologies Office: 2009 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Advanced Combustion R&D Annual Progress Report Vehicle Technologies Office: 2009 Advanced Combustion R&D Annual Progress Report The Advanced Combustion Engine R&D subprogram ...

  3. Vehicle Technologies Office: 2012 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion R&D Annual Progress Report Vehicle Technologies Office: 2012 Advanced Combustion R&D Annual Progress Report Annual report on the work of the the Advanced Combustion ...

  4. Development of Advanced Combustion Technologies for Increased Thermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency | Department of Energy Advanced Combustion Technologies for Increased Thermal Efficiency Development of Advanced Combustion Technologies for Increased Thermal Efficiency Investigation of fuel effects on low-temperature combustion, particularly HCCI / PCCI combustion deer09_gehrke.pdf (669.71 KB) More Documents & Publications The Role of Advanced Combustion in Improving Thermal Efficiency Heavy-Duty Low Temperature Combustion Development Activities at Caterpillar Diesel HCCI

  5. Assessment of Combustion and Turbulence Models for the Simulation of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Processes in a DI Diesel Engine | Department of Energy Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Assessment of Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Various applied combustion and turbulence models were investigated along with chemical kinetic mechanisms simulating a biodiesel-fueled engine deer09_ren.pdf (497.22 KB) More Documents & Publications Low Temperature

  6. Method and system for controlled combustion engines

    DOE Patents [OSTI]

    Oppenheim, A. K.

    1990-01-01

    A system for controlling combustion in internal combustion engines of both the Diesel or Otto type, which relies on establishing fluid dynamic conditions and structures wherein fuel and air are entrained, mixed and caused to be ignited in the interior of a multiplicity of eddies, and where these structures are caused to sequentially fill the headspace of the cylinders.

  7. NETL- High-Pressure Combustion Research Facility

    ScienceCinema (OSTI)

    None

    2014-06-26

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  8. Injector tip for an internal combustion engine

    DOE Patents [OSTI]

    Shyu, Tsu Pin; Ye, Wen

    2003-05-20

    This invention relates to a the tip structure of a fuel injector as used in a internal combustion engine. Internal combustion engines using Homogeneous Charge Compression Ignition (HCCI) technology require a tip structure that directs fuel spray in a downward direction. This requirement necessitates a tip design that is capable of withstanding mechanical stresses associated with the design.

  9. NETL- High-Pressure Combustion Research Facility

    SciTech Connect (OSTI)

    2013-07-08

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  10. Sandia combustion research program: Annual report, 1987

    SciTech Connect (OSTI)

    Palmer, R.E.; Sanders, B.R.; Ivanetich, C.A.

    1988-01-01

    More than a decade ago, in response to a national energy crisis, Sandia proposed to the US Department of Energy a new, ambitious program in combustion research. Our strategy was to apply the rapidly increasing capabilities in lasers and computers to combustion science and technology. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''User Facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative--involving US universities, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions of several research projects which have been stimulated by Working Groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship Program has been instrumental in the success of some of the joint efforts. The remainder of this report presents research results of calendar year 1987, separated thematically into nine categories. Refereed journal articles appearing in print during 1987, along with selected other publications, are included at the end of Section 10. In addition to our ''traditional'' research--chemistry, reacting flow, diagnostics, engine combustion, and coal combustion--you will note continued progress in somewhat recent themes: pulse combustion, high temperature materials, and energetic materials, for example. Moreover, we have just started a small, new effort to understand combustion-related issues in the management of toxic and hazardous materials.

  11. Coal slurry combustion and technology. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    Volume II contains papers presented at the following sessions of the Coal Slurry Combustion and Technology Symposium: (1) bench-scale testing; (2) pilot testing; (3) combustion; and (4) rheology and characterization. Thirty-three papers have been processed for inclusion in the Energy Data Base. (ATT)

  12. Improve Your Boiler's Combustion Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency This tip sheet outlines how to improve boiler combustion efficiency as part of an optimized steam system. STEAM TIP SHEET 4 Improve...

  13. Improve Your Boiler's Combustion Efficiency, Energy Tips: STEAM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improve Your Boiler's Combustion Efficiency Combustion Efficiency Operating your boiler with an optimum amount of excess air will minimize heat loss up the stack and improve ...

  14. Aceite vegetal puro como combustible diesel? (Straight Vegetable...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    sobre combustibles alternativos y vehculos de combustibles alternativos. El sitio web de la Oficina de Eficiencia Energtica y de Energa Renovable del DOE, www.eere....

  15. Fuel Modification t Facilitate Future Combustion Regimes? | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modification t Facilitate Future Combustion Regimes? Fuel Modification t Facilitate Future ... Merit Review 2015: RCM Studies to Enable Gasoline-Relevant Low Temperature Combustion

  16. Adaptive Control to Improve Low Temperature Diesel Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control to Improve Low Temperature Diesel Engine Combustion Adaptive Control to Improve Low Temperature Diesel Engine Combustion Presentation given at DEER 2006, August 20-24, ...

  17. Enabling High Efficiency Clean Combustion with Micro-Variable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel Injector and Adaptive PCCI Enabling High Efficiency Clean Combustion with Micro-Variable Circular-Orifice (MVCO) ...

  18. 2008 Annual Merit Review Results Summary - 7. Combustion Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7. Combustion Research 2008 Annual Merit Review Results Summary - 7. Combustion Research DOE Vehicle Technologies Annual Merit Review 2008meritreview7.pdf (1.84 MB) More ...

  19. 2012 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review Results Report - Advanced Combustion Engine Technologies 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE ...

  20. 2014 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2014 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research ...

  1. Particulate Produced from Advanced Combustion Operation in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produced from Advanced Combustion Operation in a Compression Ignition Engine Particulate Produced from Advanced Combustion Operation in a Compression Ignition Engine Determine ...

  2. 2013 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2013 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research ...

  3. Enabling Low Temperature Combustion Through Thermo-Chemical Recuperati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Through Thermo-Chemical Recuperation Enabling Low Temperature Combustion Through Thermo-Chemical Recuperation Poster presentation from the 2007 Diesel ...

  4. Heavy-Duty Low Temperature Combustion Development Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Development Activities at Caterpillar Heavy-Duty Low Temperature Combustion Development Activities at Caterpillar Presentation given at the 2007 Diesel ...

  5. Dilute Clean Diesel Combustion Achieves Low Emissions and High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High ...

  6. 3-D Combustion Simulation Strategy Status, Future Potential,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D Combustion Simulation Strategy Status, Future Potential, and Application Issues 3-D Combustion Simulation Strategy Status, Future Potential, and Application Issues 2004 Diesel ...

  7. Exploring Advanced Combustion Regimes for Efficiency and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploring Advanced Combustion Regimes for Efficiency and Emissions Exploring Advanced Combustion Regimes for Efficiency and Emissions 2003 DEER Conference Presentation: Oak Ridge ...

  8. Systems and methods of storing combustion waste products (Patent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Systems and methods of storing combustion waste products Citation Details In-Document Search Title: Systems and methods of storing combustion waste products In one aspect, ...

  9. Demonstrating Optimum HCCI Combustion with Advanced Control Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimum HCCI Combustion with Advanced Control Technology Demonstrating Optimum HCCI Combustion with Advanced Control Technology Presentation given at the 2007 Diesel ...

  10. Syngas Enhanced High Efficiency Low Temperature Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant ...

  11. Cylinder Head Gasket with Integrated Combustion Pressure Sensors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cylinder Head Gasket with Integrated Combustion Pressure Sensors Cylinder Head Gasket with Integrated Combustion Pressure Sensors Poster presented at the 16th Directions in ...

  12. 2011 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2011 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research ...

  13. Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel Engines Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel Engines 2005 Diesel Engine Emissions ...

  14. Combustion, Efficiency, and Fuel Effects in a Spark-Assisted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine 2004 Diesel ...

  15. Code Gaps and Future Research Needs of Combustion Safety: Building...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Code Gaps and Future Research Needs of Combustion Safety: Building America Expert Meeting Update Code Gaps and Future Research Needs of Combustion Safety: Building America Expert ...

  16. CFD Combustion Modeling with Conditional Moment Closure using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry CFD Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry A method is ...

  17. Large Eddy Simulation (LES) Applied to Advanced Engine Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    Large Eddy Simulation (LES) Applied to Advanced Engine Combustion Research Large Eddy Simulation (LES) Applied to Low-Temperature and Diesel Engine Combustion Research Vehicle ...

  18. Modeling Combustion Control for High Power Diesel Mode Switching...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Control for High Power Diesel Mode Switching Modeling Combustion Control for High Power Diesel Mode Switching Poster presentation given at the 16th Directions in ...

  19. Computational Fluid Dynamics Modeling of Diesel Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions 2005 Diesel Engine ...

  20. Sandia Energy - Low--Temperature Combustion Enables Cleaner,...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-temperature diesel combustion," in Progress in Energy and Combustion Science hope to communicate the details of how LTC works to the broader engine research community....

  1. Increased Engine Efficiency via Advancements in Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Efficiency via Advancements in Engine Combustion Systems Increased Engine Efficiency via Advancements in Engine Combustion Systems Presentation given at the 16th Directions...

  2. Material Testing of Coated Alloys in a Syngas Combustion Environment...

    Office of Scientific and Technical Information (OSTI)

    Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - Activity ... Title: Material Testing of Coated Alloys in a Syngas Combustion Environment Year 6 - ...

  3. Optimization of Direct-Injection H2 Combustion Engine Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions H2 Internal Combustion Engine Research Towards 45% ...

  4. Combustion Turbine CHP System for Food Processing Industry -...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Turbine CHP System for Food Processing Industry - Presentation by Frito-Lay North America, June 2011 Combustion Turbine CHP System for Food Processing Industry - ...

  5. State Grid Biomass Fuel and Combustion Technology Laboratory...

    Open Energy Info (EERE)

    Biomass Fuel and Combustion Technology Laboratory Jump to: navigation, search Name: State Grid Biomass Fuel and Combustion Technology Laboratory Place: Beijing Municipality, China...

  6. Princeton-CEFRC Summer Program on Combustion: 2013 Session |...

    Office of Science (SC) Website

    on Combustion: 2013 Session Print Text Size: A A A Subscribe FeedbackShare Page June 23 - June 28, 2013 :: The Combustion Energy Frontier Research Center at Princeton...

  7. A University Consortium on High Pressure, Lean Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure, Lean Combustion for Efficient and Clean IC Engines (UM - lead, MIT, UCB) A University Consortium on High Pressure, Lean Combustion for Efficient and Clean IC Engines ...

  8. High Efficiency Combustion and Controls | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Controls High Efficiency Combustion and Controls 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010...

  9. CRADA with Cummins on Characterization and Reduction of Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cummins on Characterization and Reduction of Combustion Variations CRADA with Cummins on Characterization and Reduction of Combustion Variations 2012 DOE Hydrogen and Fuel Cells ...

  10. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity...

    Energy Savers [EERE]

    Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines - Fact Sheet, May 2014 Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in ...

  11. Recuperative Reforming (RR) for H2 Enhanced Combustion | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recuperative Reforming (RR) for H2 Enhanced Combustion Recuperative Reforming (RR) for H2 Enhanced Combustion 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations ...

  12. US DRIVE Advanced Combustion and Emission Control Technical Team...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion and Emission Control Technical Team Roadmap US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap The ACEC focuses on advanced engine and ...

  13. General Motors Clean Combustion Engines Advanced with Predictive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Motors Clean Combustion Engines Advanced with Predictive Simulation Tools Sandia National ... batteries and hydrogen storage; clean advanced combustion; and future generation ...

  14. Advanced Combustion Systems - Systems Analysis | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Guidance for NETL's Oxy-combustion R&D Program: Chemical Looping Combustion Reference Plant Designs and Sensitivity Studies An emerging, coal-fired power plant technology, chemical ...

  15. Computationally Efficient Modeling of High-Efficiency Clean Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines Computationally Efficient Modeling of High-Efficiency Clean Combustion ...

  16. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  17. Fluidized-bed combustion fuel

    SciTech Connect (OSTI)

    Rich, J.W. Jr.

    1990-10-09

    This patent describes a process for producing from a solid carbonaceous refuse a high ash fuel for use in a circulating fluidized-bed combustion chamber. It comprises separating from the refuse a carbonaceous portion having an ash content in a selected range percent by weight; separating the carbonaceous portion into first and second fractions, the first fraction being at or above a selected size; crushing the first fraction; and combining the crushed first fraction with the second fraction. Also described is a process wherein the selected ash content range is between about 30 percent and about 50 percent, by weight. Also described is a process wherein the selected size is above about 1/4 inch.

  18. Real-time combustion controller

    DOE Patents [OSTI]

    Lindner, Jeffrey S.; Shepard, W. Steve; Etheridge, John A.; Jang, Ping-Rey; Gresham, Lawrence L.

    1997-01-01

    A method and system of regulating the air to fuel ratio supplied to a burner to maximize the combustion efficiency. Optical means are provided in close proximity to the burner for directing a beam of radiation from hot gases produced by the burner to a plurality of detectors. Detectors are provided for sensing the concentration of, inter alia, CO, CO.sub.2, and H.sub.2 O. The differences between the ratios of CO to CO.sub.2 and H.sub.2 O to CO are compared with a known control curve based on those ratios for air to fuel ratios ranging from 0.85 to 1.30. The fuel flow is adjusted until the difference between the ratios of CO to CO.sub.2 and H.sub.2 O to CO fall on a desired set point on the control curve.

  19. Real-time combustion controller

    DOE Patents [OSTI]

    Lindner, J.S.; Shepard, W.S.; Etheridge, J.A.; Jang, P.R.; Gresham, L.L.

    1997-02-04

    A method and system are disclosed for regulating the air to fuel ratio supplied to a burner to maximize the combustion efficiency. Optical means are provided in close proximity to the burner for directing a beam of radiation from hot gases produced by the burner to a plurality of detectors. Detectors are provided for sensing the concentration of, inter alia, CO, CO{sub 2}, and H{sub 2}O. The differences between the ratios of CO to CO{sub 2} and H{sub 2}O to CO are compared with a known control curve based on those ratios for air to fuel ratios ranging from 0.85 to 1.30. The fuel flow is adjusted until the difference between the ratios of CO to CO{sub 2} and H{sub 2}O to CO fall on a desired set point on the control curve. 20 figs.

  20. Assembly for directing combustion gas

    DOE Patents [OSTI]

    Charron, Richard C.; Little, David A.; Snyder, Gary D.

    2016-04-12

    An arrangement is provided for delivering gases from a plurality of combustors of a can-annular gas turbine combustion engine to a first row of turbine blades including a first row of turbine blades. The arrangement includes a gas path cylinder, a cone and an integrated exit piece (IEP) for each combustor. Each IEP comprises an inlet chamber for receiving a gas flow from a respective combustor, and includes a connection segment. The IEPs are connected together to define an annular chamber extending circumferentially and concentric to an engine longitudinal axis, for delivering the gas flow to the first row of blades. A radiused joint extends radially inward from a radially outer side of the inlet chamber to an outer boundary of the annular chamber, and a flared fillet extends radially inward from a radially inner side of the inlet chamber to an inner boundary of the annular chamber.

  1. Multiple vane rotary internal combustion engine

    SciTech Connect (OSTI)

    Pangman, E.L.

    1994-01-11

    A three-piece housing enclosing a cavity has rotatably mounted therein a rotor having a plurality of slots, each slot supporting a vane. Each vane has a retention end guided in its revolution around the rotor by an internal, non-circular vane retention track. Two adjacent vanes define opposite sides of a combustion chamber, while the housing and the portion of the rotor between the adjacent vanes form the remaining surfaces of the combustion chamber. Each combustion chamber is rotated past an intake port, a diagonal plasma bleed-over groove, and an exhaust port to accomplish the phases of a combustion cycle. Fuel ignition is provided to more than one combustion chamber at a time by expanding gases passing through a plasma bleed-over groove and being formed into a vortex that ignites and churns the charge in a succeeding combustion chamber. Exhaust gases remaining after primary evacuation are removed by a secondary evacuation system utilizing a venturi creating negative pressure which evacuates the combustion chamber. Lubrication is circulated through the engine without the use of a lubricant pump. The centrifugal force of the rotating rotor causes the lubricant therein to be pressurized thereby drawing additional lubricant into the closed system and forcing lubricant within the engine to be circulated. 9 figs.

  2. Misfire tolerant combustion-powered actuation

    DOE Patents [OSTI]

    Spletzer, Barry L.; Fischer, Gary J.; Marron, Lisa C.; Kuehl, Michael A.

    2001-01-01

    The present invention provides a combustion-powered actuator that is suitable for intermittent actuation, that is suitable for use with atmospheric pressure carburetion, and that requires little electrical energy input. The present invention uses energy from expansion of pressurized fuel to effectively purge a combustion chamber, and to achieve atmospheric pressure carburetion. Each purge-fill-power cycle can be independent, allowing the actuator to readily tolerate misfires. The present invention is suitable for use with linear and rotary operation combustion chambers, and is suitable for use in a wide variety of applications.

  3. Annual Report: Advanced Combustion (30 September 2012)

    SciTech Connect (OSTI)

    Hawk, Jeffrey; Richards, George

    2012-09-30

    The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

  4. Post combustion trials at Dofasco's KOBM furnace

    SciTech Connect (OSTI)

    Farrand, B.L.; Wood, J.E.; Goetz, F.J.

    1992-01-01

    Post combustion trials were conducted at Dofasco's 300 tonne KOBM furnace as part of the AISI Direct Steelmaking Program. The purpose of the project work was to measure the post combustion ratio (PCR) and heat transfer efficiency (HTE) of the post combustion reaction in a full size steelmaking vessel. A method of calculating PCR and HTE using off gas analysis and gas temperature was developed. The PCR and HTE were determined under normal operating conditions. Trials assessed the effect of lance height, vessel volume, foaming slag and pellet additions on PCR and HTE.

  5. Internal combustion engine injection superheated steam

    SciTech Connect (OSTI)

    Mahoney, F.G.

    1991-01-22

    This patent describes a method for introducing water vapor to the combustion chambers of an internal combustion engine. It comprises: introducing a metered amount of liquid water into a heat exchanger; contacting the heat exchanger directly with hot exhaust gases emanating from the exhaust manifold; maintaining the water in the heat exchanger for a period sufficient to vaporize the water into steam and superheat same; reducing pressure and increasing temperature to create superheated steam; introducing the superheated steam into the air supply proximate to the air induction system, upstream of any carburetion, of the internal combustion engine.

  6. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Kong, Peter C.

    2000-01-01

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  7. Internal combustion engine utilizing stratified charge combustion process

    SciTech Connect (OSTI)

    Artman, N.G.

    1991-07-16

    This patent describes an internal combustion engine in which a piston is reciprocal alternately toward and from the upper end of a cylinder within a variable volume space adjacent to such end, a cylinder head having a face in closing relation with such cylinder end and containing a precombustion chamber with a sidewall having an inner periphery constructed about an axis extending upwardly from the cylinder and the periphery having an open lower end in two-way communication through the face with the variable volume space, the lower open end being smaller in diameter than the diameter of the cylinder, the upper end of the chamber having an air inlet passage closable by a valve, the chamber being operable when the valve is open and attendant to movement of the piston downwardly from the upper cylinder end to receive from the inlet passage a main inlet air stream and conduct the same downwardly therein and discharge the same through the open end downwardly therein and discharge the same through the open end downwardly into the variable volume space.

  8. Workshop on the Increased Use of Ethanol and Alkylates in Automotive Fuels in California

    SciTech Connect (OSTI)

    Rice, D W

    2001-05-04

    The goals of the Workshop are to: (1) Review the existing state of knowledge on (a) physicochemical properties, multi-media transport and fate, exposure mechanisms and (b) release scenarios associated with the production, distribution, and use of ethanol and alkylates in gasoline; (2) Identify key regulatory, environmental, and resource management issues and knowledge gaps associated with anticipated changes in gasoline formulation in California; and (3) Develop a roadmap for addressing issues/knowledge gaps.

  9. H2 Internal Combustion Engine Research Towards 45% efficiency and

    Broader source: Energy.gov (indexed) [DOE]

    Tier2-Bin5 emissions | Department of Energy ace_09_wallner.pdf (2.11 MB) More Documents & Publications Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling

  10. Numerical Modeling of PCCI Combustion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PCCI Combustion Numerical Modeling of PCCI Combustion 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Lawrence Livermore National Laboratory/University of Michigan 2004_deer_flowers.pdf (252.97 KB) More Documents & Publications Modeling of HCCI and PCCI Combustion Processes Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines Numerical Modeling of HCCI Combustion

  11. Pulse combustion: an assessment of opportunities for increased efficiency

    SciTech Connect (OSTI)

    Brenchley, D.L.; Bomelburg, H.J.

    1984-12-01

    The results of a literature review on pulse combustion are discussed. Current, near-future, and potential opportunities for pulse combustion applications are summarized, and the barriers to developing and using pulse combustion technology are discussed, along with research and development needs. Also provided are the proceedings of a pulse combustion workshop held in May, 1984 in Seattle, Washington. (LEW)

  12. Transesterification process to manufacture ethyl ester of rape oil

    SciTech Connect (OSTI)

    Korus, R.A.; Hoffman, D.S.; Bam, N.; Peterson, C.L.; Drown, D.C.

    1993-12-31

    A process for the production of the ethyl ester of winter rape [EEWR] for use as a biodiesel fuel has been studied. The essential part of the process is the transesterification of rape oil with ethanol, in the presence of a catalyst, to yield the ethyl ester of rape oil as a product and glycerin as a by-product. Experiments have been performed to determine the optimum conditions for the preparation of EEWR. The process variables were: (1) temperature, (2) catalyst, (3) rate of agitation, (4) water content of the alcohol used, and (5) the amount of excess alcohol used. The optimum conditions were: (1) room temperature, (2) 0.5% sodium methoxide or 1% potassium hydroxide catalyst by weight of rapeseed oil, (3) extremely vigorous agitation with some splashing during the initial phase of the reaction and agitation was not necessary after the reaction mixture became homogeneous, (4) absolute ethanol was necessary for high conversion, and (5) 50% excess ethanol with NaOCH{sub 3} or 100% excess with KOH gave a maximum conversion. Viscosity, cloud point and pour point of the EEWR were measured. A preliminary break-even cost for the commercial production of EEWR was found to be $0.55/liter [$2.08/US gallon].

  13. Pseudo-hydroxide extraction in the separation of sodium hydroxide from aqueous solutions using alkyl phenols

    SciTech Connect (OSTI)

    Kang, Hyun Ah; Moyer, Bruce A

    2006-01-01

    Pseudo-hydroxide extraction of sodium hydroxide from aqueous solution using four alkyl phenols of nearly identical molecular weight in 1-octanol at 25 degrees C was examined to understand the effect of alkyl substituents. The order of extraction strength among the four alkyl phenols tested was 4-tert-octylphenol. 3,5-di-tertbutylphenol. 2,4-di-tert-butylphenol. 2,6-di-tert-butyl-4-methylphenol. A good correlation with phenol pK(a) was observed, indicating that extraction strength is determined by phenol acidity, as modified by steric effects in proximity to the phenol - OH group. The effective partition ratios (P-eff) of two phenols from 1 M NaOH solution were determined, showing that the phenols remain predominantly in the 1-octanol phase even when converted to their sodium salts. However, the hydrophobicity of the tested phenols may not be sufficient for process purposes. The equilibrium constants for the governing extraction equilibria were determined by modeling the data using the program SXLSQI, supporting the cation-exchange extraction mechanism. The proposed mechanism consists of two simple sets of equilibria for a. Ion-pair extraction to give Na+OH- ion pairs and corresponding free ions in 1-octanol the phase and b. Cation exchange by monomeric phenol molecules (HAs) to form monomeric organic-phase Na(+)A(-) ion pairs and corresponding free organic-phase ions.

  14. Coal Combustion Products Extension Program

    SciTech Connect (OSTI)

    Tarunjit S. Butalia; William E. Wolfe

    2006-01-11

    This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to 40% by 2010, the CCP Extension Program be

  15. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc

    2003-06-24

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  16. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_01_musculus.pdf (2.77 MB) More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel

  17. Oil shale retorting and combustion system

    DOE Patents [OSTI]

    Pitrolo, Augustine A.; Mei, Joseph S.; Shang, Jerry Y.

    1983-01-01

    The present invention is directed to the extraction of energy values from l shale containing considerable concentrations of calcium carbonate in an efficient manner. The volatiles are separated from the oil shale in a retorting zone of a fluidized bed where the temperature and the concentration of oxygen are maintained at sufficiently low levels so that the volatiles are extracted from the oil shale with minimal combustion of the volatiles and with minimal calcination of the calcium carbonate. These gaseous volatiles and the calcium carbonate flow from the retorting zone into a freeboard combustion zone where the volatiles are burned in the presence of excess air. In this zone the calcination of the calcium carbonate occurs but at the expense of less BTU's than would be required by the calcination reaction in the event both the retorting and combustion steps took place simultaneously. The heat values in the products of combustion are satisfactorily recovered in a suitable heat exchange system.

  18. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M.; Splitter, Derek A.; Kokjohn, Sage L.

    2015-07-14

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choosing the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  19. Two phase exhaust for internal combustion engine

    DOE Patents [OSTI]

    Vuk, Carl T.

    2011-11-29

    An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

  20. Flex-flame burner and combustion method

    DOE Patents [OSTI]

    Soupos, Vasilios; Zelepouga, Serguei; Rue, David M.; Abbasi, Hamid A.

    2010-08-24

    A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

  1. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2013-12-31

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  2. Preheated Combustion Air; Industrial Technologies Program (ITP...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fuel-fired industrial heating processes, one of the most potent ways to improve efficiency and productivity is to preheat the combustion air going to the burners. The source of ...

  3. Fuel injector nozzle for internal combustion engine

    SciTech Connect (OSTI)

    Klomp, E.D.; Peters, B.D.

    1990-06-12

    This patent describes a fuel injection nozzle for a combustion chamber of an internal combustion engine. It comprises: a nozzle body with at least one fuel flow opening therethrough for feed fuel to the chamber, a resilient diaphragm normally sealing the opening and having orifice means therein for further atomizing and directing the pulses into the chamber, fastening means for fixing the diaphragm to the body so that diaphragm can deflect by a predetermined amount under low engine load operating conditions so that a wide angle cone of atomized fuel is injected into and generally at one end of the combustion chamber for the stratified charge thereof and deflect by an amount greater than the first amount of deflection under high engine load operating conditions. A narrow spray cone of atomized fuel is injected in a deeper pattern into and throughout the combustion chamber for optimizing the charge thereof and fuel burns under the low and high load engine operating conditions.

  4. Media - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    School Posted Jan 07, 2015by Lilian Tsang The 2015 Princeton-CEFRC Summer School on Combustion is now accepting applications for the June 21 - 26 session. Apply online at http:...

  5. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  6. Transonic Combustion Inc | Open Energy Information

    Open Energy Info (EERE)

    focused on developing ultra-high efficiency automotive engines that run on gasoline and bio-renewable flex fuels. References: Transonic Combustion, Inc.1 This article is a stub....

  7. Energy-Efficient Glass Melting: Submerged Combustion

    SciTech Connect (OSTI)

    2004-01-01

    Oxy-gas-fired submerged combustion melter offers simpler, improved performance. For the last 100 years, the domestic glass industry has used the same basic equipment for melting glass on an industrial scale.

  8. Advanced Combustion Technologies | Department of Energy

    Office of Environmental Management (EM)

    Photo courtesy of NETL Multimedia. The workhorse of America's electric power sector is the coal-fired power plant. Today, coal combustion plants account for more than half of the ...

  9. Internal combustion engine and method for control

    SciTech Connect (OSTI)

    Brennan, Daniel G

    2013-05-21

    In one exemplary embodiment of the invention an internal combustion engine includes a piston disposed in a cylinder, a valve configured to control flow of air into the cylinder and an actuator coupled to the valve to control a position of the valve. The internal combustion engine also includes a controller coupled to the actuator, wherein the controller is configured to close the valve when an uncontrolled condition for the internal engine is determined.

  10. Building America Expert Meeting: Combustion Safety

    SciTech Connect (OSTI)

    Brand, L.

    2013-03-01

    This is a meeting overview of 'The Best Approach to Combustion Safety in a Direct Vent World', held June 28, 2012, in San Antonio, Texas. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

  11. Building America Expert Meeting. Combustion Safety

    SciTech Connect (OSTI)

    Brand, Larry

    2013-03-01

    This is an overview of "The Best Approach to Combustion Safety in a Direct Vent World," held June 28, 2012, in San Antonio, TX. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

  12. Sample Projects - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sample Projects Sample Projects These are only a few of the many possible research directions for Combustion Energy Research Fellows. For a more complete view on possible CEFRC postdoctoral research projects and collaborations please contact the Center Principal Investigators individually. Advanced Combustion Simulations with Dr. Jacqueline H. Chen and Prof. D. Haworth DNS/LES simulations with Prof. Stephen B. Pope and Dr. Jacqueline H. Chen. Simulations of experimental flames with Prof. Fokion

  13. Publication sites productive uses of combustion ash

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publication Sites Productive Uses of Combustion Ash For more information contact: e:mail: Public Affairs Golden, Colo., Jan. 23, 1997 -- A new technology brief published by the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) describes how ash use can reduce the cost of waste management and not harm the environment. Communities in the United States typically dump municipal solid waste combustion ash in landfills. The new technology brief describes recent studies where ash

  14. 2014 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Description Lecturers Lecture Notes Lecture Videos 2013 Session 2012 Session 2011 Session 2010 Session 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2014 Session 2014 Session The 2014 session, held from June 22 to June 27, offered the following courses: Combustion Theory and Applications in CFD, delivered by Professor Heinz Pitsch of RWTH Aachen University;

  15. 2015 Session - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Description Lecture Notes Lecture Videos Lecturers 2014 Session 2013 Session 2012 Session 2011 Session 2010 Session 2016 FAQ Lecture Videos News, Events & Publications Contact CEFRC CEFRC In Pictures CEFRC Intranet (Members Only) Home » 2016 Combustion Summer School » Past Sessions » 2015 Session 2015 Session The 2015 session, held from June 21 to June 26, offered the following courses: Dynamics of Combustion Waves: From Flames to Detonations, delivered by Professor Paul Clavin of

  16. Combustion Model for Engine Concept Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Model for Engine Concept Development Combustion Model for Engine Concept Development Presentation shows how 1-cylinder testing, 3D combustion CFD and 1D gas exchange with an advanced combustion model are used together for fast, reliable predictions deer12_andersson.pdf (1.12 MB) More Documents & Publications Partially Premixed Combustion Flex Fuel Optimized SI and HCCI Engine High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control

  17. chemical-looping-combustion | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Looping Combustion Chemical Looping Combustion Advantages: Oxygen is created in-situ... Oxygen production requirement is eliminated ...reduces energy demand and system costs. Uses conventional construction materials and techniques ...decreases capital cost. The combustion of fossil fuels in nearly pure oxygen, rather than air, presents an opportunity to simplify carbon dioxide (CO2) capture in power plant applications. Oxy-combustion power generation provides oxygen to the combustion

  18. Progress of the Engine Combustion Network | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the Engine Combustion Network Progress of the Engine Combustion Network ECN seeks to accelerate development of clean high-efficiency engines. deer09_pickett.pdf (1.91 MB) More Documents & Publications Spray Combustion Cross-Cut Engine Research Vehicle Technologies Office Merit Review 2015: Spray Combustion Cross-Cut Engine Research Vehicle Technologies Office Merit Review 2016: Spray Combustion Cross-Cut Engine Research

  19. Vehicle Technologies Office: Advanced Combustion Engines | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Fuel Efficiency & Emissions » Vehicle Technologies Office: Advanced Combustion Engines Vehicle Technologies Office: Advanced Combustion Engines Researchers take laser-based velocity measurements at the Sandia National Laboratory's Combustion Research Facility. Researchers take laser-based velocity measurements at the Sandia National Laboratory's Combustion Research Facility. Improving the efficiency of internal combustion engines is one of the most promising and cost-effective

  20. Vehicle Technologies Office: Advanced Combustion Strategies | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Vehicle Technologies Office: Advanced Combustion Strategies Vehicle Technologies Office: Advanced Combustion Strategies On the left is real-time video of conventional diesel combustion. The fuel injector sprays 8 jets of liquid fuel into the combustion chamber. Compression-heating ignites the fuel, creating a flame. Soot forms in jets, which glow red, orange, and yellow. High temperature combustion has high efficiency, but also produces high emissions of nitrogen oxides. On the right

  1. Multicylinder Diesel Engine for Low Temperature Combustion Operation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy for Low Temperature Combustion Operation Multicylinder Diesel Engine for Low Temperature Combustion Operation Fuel injection strategies to extend low temperature combustion temperatures to yield low NOx at higher loads and better efficiency over the speed-load range deer08_deojeda.pdf (1.22 MB) More Documents & Publications Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Multicylinder Diesel Engine Design for HCCI Operation Impact of

  2. Carburetor for internal combustion engines

    DOE Patents [OSTI]

    Csonka, John J.; Csonka, Albert B.

    1978-01-01

    A carburetor for internal combustion engines having a housing including a generally discoidal wall and a hub extending axially from the central portion thereof, an air valve having a relatively flat radially extending surface directed toward and concentric with said discoidal wall and with a central conoidal portion having its apex directed toward the interior of said hub portion. The housing wall and the radially extending surface of the valve define an air passage converging radially inwardly to form an annular valving construction and thence diverge into the interior of said hub. The hub includes an annular fuel passage terminating at its upper end in a circumferential series of micro-passages for directing liquid fuel uniformly distributed into said air passage substantially at said valving constriction at right angles to the direction of air flow. The air valve is adjustable axially toward and away from the discoidal wall of the carburetor housing to regulate the volume of air drawn into the engine with which said carburetor is associated. Fuel is delivered under pressure to the fuel metering valve and from there through said micro-passages and controlled cams simultaneously regulate the axial adjustment of said air valve and the rate of delivery of fuel through said micro-passages according to a predetermined ratio pattern. A third jointly controlled cam simultaneously regulates the ignition timing in accordance with various air and fuel supply settings. The air valve, fuel supply and ignition timing settings are all independent of the existing degree of engine vacuum.

  3. Rotary valve internal combustion engine

    SciTech Connect (OSTI)

    Bunk, P.H.

    1989-03-28

    A rotary valve internal combustion engine is described, comprising: an engine block; at least one cylinder in the engine block; at least one cylinder having a top end; cylinder head means located adjacent the top end of at least one cylinder, the cylinder head means having a cylindrically shaped cavity therein, the cylindrically shaped cavity being oriented in perpendicular relation to at least one cylinder; a piston sealingly mounted in at least one cylinder for reciprocable movement therein, the reciprocable movement including an intake stroke and an exhaust stroke; engine shaft means rotatably mounted to the engine block; means within the engine block for converting the reciprocable movement of the piston into rotary motion of the engine shaft means; a cylinder port located at the top end of at least one cylinder; a rotary valve rotatably mounted in the cylindrically shaped cavity; means connected with the engine shaft means for rotating the rotary valve in a predetermined synchronization with the reciprocable movement of the piston; aspiration means in the rotary valve for selectively aspirating at least one cylinder during the intake an exhaust strokes; and a spark plug removably mounted within the rotary valve and rotatable therewith.

  4. Combustion kinetics and reaction pathways

    SciTech Connect (OSTI)

    Klemm, R.B.; Sutherland, J.W.

    1993-12-01

    This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

  5. Dust Combustion Safety Issues for Fusion Applications

    SciTech Connect (OSTI)

    L. C. Cadwallader

    2003-05-01

    This report summarizes the results of a safety research task to identify the safety issues and phenomenology of metallic dust fires and explosions that are postulated for fusion experiments. There are a variety of metal dusts that are created by plasma erosion and disruptions within the plasma chamber, as well as normal industrial dusts generated in the more conventional equipment in the balance of plant. For fusion, in-vessel dusts are generally mixtures of several elements; that is, the constituent elements in alloys and the variety of elements used for in-vessel materials. For example, in-vessel dust could be composed of beryllium from a first wall coating, tungsten from a divertor plate, copper from a plasma heating antenna or diagnostic, and perhaps some iron and chromium from the steel vessel wall or titanium and vanadium from the vessel wall. Each of these elements has its own unique combustion characteristics, and mixtures of elements must be evaluated for the mixtures combustion properties. Issues of particle size, dust temperature, and presence of other combustible materials (i.e., deuterium and tritium) also affect combustion in air. Combustion in other gases has also been investigated to determine if there are safety concerns with inert atmospheres, such as nitrogen. Several coolants have also been reviewed to determine if coolant breach into the plasma chamber would enhance the combustion threat; for example, in-vessel steam from a water coolant breach will react with metal dust. The results of this review are presented here.

  6. Internal combustion engine utilizing stratified charge combustion process

    SciTech Connect (OSTI)

    Artman, N.G.

    1988-11-15

    This patent describes an internal combustion engine having a main air inlet passage communicating at an end thereof through the face of an cylinder head with an alternately expandable and contractable variable volume space in an end of a cylinder closed by such head, there being within the cylinder head a precombustion chamber forming a section of such passage and interposed between the space and an upstream portion of the passage, the chamber having a principal axis extending between opposite ends thereof and of which ends one is an air inlet and having a valve seat through which the chamber is communicative with the upstream passage portion and of which ends the other is an open end through which the passage has two-way communication with the space and is disposed to discharge air from the chamber into the space axially of the cylinder, the combination of air deflecting means in the chamber and operable during expansion of the space to modulate the flow of intake air passing through the chamber into the space into the form of a stream composed of a core portion flowing axially of the cylinder into the space and of a tubular portion encircling the core portion and flowing helically thereabout, fuel delivery means operable during a fuel injection period commencing during expansion of the space and subsequent to entry of a leading portion of the air stream into the space to inject evaporative fuel into the passage and into a trailing portion of the air stream therein at a rate to mix and form therewith an air-fuel mixture lean in fuel richness than flows within and at least partially through the chamber en route to the space during the expansion thereof. The fuel delivery means being operable to increase the volume of the trailing air stream portion mixed with fuel by advancing the starting time of the fuel injection period to increase the length of such period measured in units of space expansion.

  7. Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

    2014-11-13

    Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packingin the solid-stateto be scrutinized in detail.

  8. Gasdynamic enhancement of nonpremixed combustion

    SciTech Connect (OSTI)

    Marble, F.E.

    1994-12-31

    To promote efficient performance of very high speed air-breathing propulsion systems, the combustor Mach number must be of the order of six for a flight Mach number of 18. Because of this high gas speed through the combustor, mixing rates of hydrogen fuel with air must be very rapid in order to allow a combustor of reasonable length. It is proposed to enhance the rate of mixing and combustion of hydrogen and air, and thereby reduce combustor length, through the introduction of streamwise vorticity generated by the interaction of a weak oblique shock wave with the density gradient between air and a cylindrical jet of hydrogen. Because of the high Mach number flow in the combustor, the oblique shock traverses the jet at a small angle with respect to the free stream direction, and the principle of slender body theory allows one conceptually to replace the three-dimensional steady flow with a two-dimensional unsteady flow. As a consequence, two-dimensional time-dependent computational studies and an extensive experimental shock tube investigation were employed to assess mixing rates for the steady flow in the combustor. The results indicated that under realistic conditions, adequate mixing could be accomplished within 1 ms, a rate that was technologically interesting. Encouraged by these experiments, a ``practical`` injector, utilizing shock-enhanced mixing, was designed for a combustor having a free stream Mach number of 6.0. A detailed aerodynamic and mixing investigation was carried out in the Mach 6 High Reynolds Number Tunnel at the NASA-Langley Research Center. The results confirmed both the details and the overall effectiveness of the shock-enhanced mixing concept.

  9. Comparison between a propane-air combustion front and a helium-air simulated combustion front

    SciTech Connect (OSTI)

    Barraclough, S.

    1983-12-01

    Turbulent combustion experiments were performed in a right cylindrical combustion bomb using a premixed propane-air gaseous fuel. The initial conditions inside the combustion chamber were three psig and room temperature. Prior to spark firing, the turbulence intensity inside the combustion chamber was measured and could be varied over a ten fold range. The effect of initial turbulence intensity on turbulent flame propagation was investigated. Two regimes of turbulent combustion were identified, which is in agreement with a previous investigator's results. One of them, a ''transition regime'' occurs when the turbulence intensity is approximately twice the laminar flame speed. Within the transition regime, the turbulent burning speed is linearly proportional to initial turbulence intensity and independent of laminar flame speed and turbulence length scale. A high pressure helium front was injected into the combustion chamber to simulate the combustion front. Since the helium front is isothermal, hot-wire anemometry can be used to quantify the change in turbulence intensity ahead of the propagating front. The helium front was found to have different characteristics than the combustion front.

  10. Pulsating catalytic combustion of gaseous fuels

    SciTech Connect (OSTI)

    Gal-Ed, R.

    1988-01-01

    This study investigated the feasibility of operating catalytic combustors under pulsating conditions and the circumstances under which acoustic pulsations increase the combustion efficiencies and output of catalytic combustors. An experimental catalytic combustor was developed, and a theoretical model of acoustic motions in non-isothermal, low match number, duct flow was used to predict the acoustic behavior of the combustor. The effects of pulsations were determined by comparing temperature and species concentration data measured during operation with pulsations at different frequencies and pressure amplitudes to similar data measured during non-pulsating combustion. Experiments conducted with lean mixtures of methane or propane with air revealed that acoustic pulsations affected the temperature distribution along the combustor at flow Reynolds numbers less than 17,500. Excitation of pulsations during methane combustion caused shifts in the location of the combustion, and sometimes the onset of extinction of gas phase reactions. This occurred when several catalyst segments were located in the combustion section between an upstream pressure node and a downstream velocity node, defined here as an in phase location. Propane mixtures were used to investigate possible improvements in combustor's performance. Burning propane mixtures on a single catalyst segment at an in phase location showed that the excitation of acoustic pulsations increased the combustion efficiency by 10 to 50%. The changes in the operation of catalytic combustors caused by acoustic waves are explained by acoustic streaming. When the catalyst surfaces are at an in phase location, rotational flows caused by acoustic streaming enhance the reactants and products diffusion rate to and from the catalyst surfaces, respectively, improving combustion efficiency.

  11. Parameters of a supersonic combustion chamber with organization of combustion at the flame front

    SciTech Connect (OSTI)

    Solokhin, E.L.; Mironenko, V.A.; Ivanov, V.I.

    1985-10-25

    In some engineering problems, it is necessary to burn fuel in the combustion chamber with supersonic flow. As a rule, the scheme of organization of the process in such a chamber presupposes a separate accompanying feed of fuel and oxidant in which combustion of fuel takes place in a diffusion flame front. In this article we give theoretical results of investigation of a supersonic combustion chamber in which combustion of the fuel mixture takes place in a oblique flame front stabilized by an external source (analogous to the subsonic combustion chambers of ramjets). The possibility of the existence of such an oblique flame front in a supersonic flow of fuel mixture was previously proved experimentally.

  12. Assessment of Literature Related to Combustion Appliance Venting Systems

    SciTech Connect (OSTI)

    Rapp, V. H.; Less, B. D.; Singer, B. C.; Stratton, J. C.; Wray, C. P.

    2015-02-01

    In many residential building retrofit programs, air tightening to increase energy efficiency is often constrained by safety concerns with naturally vented combustion appliances. Tighter residential buildings more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spill combustion exhaust into the living space. Several measures, such as installation guidelines, vent sizing codes, and combustion safety diagnostics, are in place with the intent to prevent backdrafting and combustion spillage, but the diagnostics conflict and the risk mitigation objective is inconsistent. This literature review summarizes the metrics and diagnostics used to assess combustion safety, documents their technical basis, and investigates their risk mitigations. It compiles information from the following: codes for combustion appliance venting and installation; standards and guidelines for combustion safety diagnostics; research evaluating combustion safety diagnostics; research investigating wind effects on building depressurization and venting; and software for simulating vent system performance.

  13. Hydrocarbon Fouling of SCR during PCCI combustion

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Lewis Sr, Samuel Arthur; Parks, II, James E

    2012-01-01

    The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust. The Fe-zeolite NOX conversion efficiency was significantly degraded, especially at low temperatures (<250 C), after the catalyst was exposed to the raw engine exhaust. The degradation of the Fe-zeolite performance was similar for both combustion modes. The Cu-zeolite showed better tolerance to HC fouling at low temperatures compared to the Fe-zeolite but PCCI exhaust had a more significant impact than the exhaust from conventional combustion on the NOX conversion efficiency. Furthermore, chemical analysis of the hydrocarbons trapped on the SCR cores was conducted to better determine chemistry specific effects.

  14. Reaction and diffusion in turbulent combustion

    SciTech Connect (OSTI)

    Pope, S.B.

    1993-12-01

    The motivation for this project is the need to obtain a better quantitative understanding of the technologically-important phenomenon of turbulent combustion. In nearly all applications in which fuel is burned-for example, fossil-fuel power plants, furnaces, gas-turbines and internal-combustion engines-the combustion takes place in a turbulent flow. Designers continually demand more quantitative information about this phenomenon-in the form of turbulent combustion models-so that they can design equipment with increased efficiency and decreased environmental impact. For some time the PI has been developing a class of turbulent combustion models known as PDF methods. These methods have the important virtue that both convection and reaction can be treated without turbulence-modelling assumptions. However, a mixing model is required to account for the effects of molecular diffusion. Currently, the available mixing models are known to have some significant defects. The major motivation of the project is to seek a better understanding of molecular diffusion in turbulent reactive flows, and hence to develop a better mixing model.

  15. Combustion Safety Simplified Test Protocol Field Study

    SciTech Connect (OSTI)

    Brand, L; Cautley, D.; Bohac, D.; Francisco, P.; Shen, L.; Gloss, S.

    2015-11-05

    "9Combustions safety is an important step in the process of upgrading homes for energy efficiency. There are several approaches used by field practitioners, but researchers have indicated that the test procedures in use are complex to implement and provide too many false positives. Field failures often mean that the house is not upgraded until after remediation or not at all, if not include in the program. In this report the PARR and NorthernSTAR DOE Building America Teams provide a simplified test procedure that is easier to implement and should produce fewer false positives. A survey of state weatherization agencies on combustion safety issues, details of a field data collection instrumentation package, summary of data collected over seven months, data analysis and results are included. The project provides several key results. State weatherization agencies do not generally track combustion safety failures, the data from those that do suggest that there is little actual evidence that combustion safety failures due to spillage from non-dryer exhaust are common and that only a very small number of homes are subject to the failures. The project team collected field data on 11 houses in 2015. Of these homes, two houses that demonstrated prolonged and excessive spillage were also the only two with venting systems out of compliance with the National Fuel Gas Code. The remaining homes experienced spillage that only occasionally extended beyond the first minute of operation. Combustion zone depressurization, outdoor temperature, and operation of individual fans all provide statistically significant predictors of spillage.

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-04-01

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

  17. Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities

    SciTech Connect (OSTI)

    Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K.

    2012-07-01

    Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

  18. A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

    SciTech Connect (OSTI)

    Dai, Sheng; Sun, Xiao-Guang

    2015-01-01

    A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

  19. A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wan, Shun; Jiang, Xueguang; Guo, Bingkun; Dai, Sheng; Goodenough, John B.; Sun, Xiao-Guang

    2015-04-27

    A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

  20. Fuel Interchangeability Considerations for Gas Turbine Combustion

    SciTech Connect (OSTI)

    Ferguson, D.H.

    2007-10-01

    In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

  1. Quantum combustion chamber for the digital engine

    SciTech Connect (OSTI)

    Evers, L.W.; Baasch, V.

    1985-01-01

    For increasing fuel economy and reducing hydrocarbon emissions, a two-stoke-cycle, loop-scavenged single cylinder engine was modified by replacing the head with a head having three subchambers and incorporating a distributing pump fuel injection system. The fuel injection system allowed one subchamber to be operated at a time. The quantum combustion system demonstrated both lower fuel consumption and lower hydrocarbon emissions than a conventional homogeneous charge engine. The experimental evidence also indicates that the combustion essentially occurred in the one chamber into which fuel was injected. Establishing stratified charge combustion by mechanically separating the regions of air from the regions of air/fuel mixtures by means of subchambers is feasible.

  2. Combustion chamber for a gas turbine

    SciTech Connect (OSTI)

    Holzapfel, I.

    1982-09-21

    A combustion chamber for a gas turbine, in particular for motor vehicles, with an atomizer nozzle for the fuel fed to a prechamber, in which the inlet cross section for the primary air is changed by the longitudinal movement of a deflection member extending through the inlet opening of the combustion chamber. The deflection member serves as a flame holder for the stabilization of the combustion in the primary air zone while the air-atomizing nozzle is constructed ring-shaped and is provided with swirl slots in such a manner that the mixture of the fuel and of the atomizing air enters as an annular jet the primary air inlet channel, impinges approximately perpendicularly onto the primary air flow, penetrates the same and uniformly mixes with the same on its way to the inlet into the primary zone. The quantity of the primary air to be supplied is thereby automatically adjustable.

  3. Combustion chamber, especially for gas turbines

    SciTech Connect (OSTI)

    Meyer, F.

    1980-04-29

    A combustion chamber is disclosed that has an end-wall at the inlet side and an axial inlet opening, which is adjoined by an essentially cylindrical wall section provided with secondary air inlet openings; the end-wall thereby adjoins the inlet opening approximately hemispherically shaped with a sphere diameter which is larger than the diameter of the cylindrical wall section while the adjoining combustion chamber portion is again reduced to the adjacent cylindrical wall section by way of a combustion chamber wall substantially continuing the sphere shape; the fuel injection device is provided upstream of the inlet opening which injects fuel into the inlet opening, itself covered off by a deflection means.

  4. Starting procedure for internal combustion vessels

    DOE Patents [OSTI]

    Harris, Harry A.

    1978-09-26

    A vertical vessel, having a low bed of broken material, having included combustible material, is initially ignited by a plurality of ignitors spaced over the surface of the bed, by adding fresh, broken material onto the bed to buildup the bed to its operating depth and then passing a combustible mixture of gas upwardly through the material, at a rate to prevent back-firing of the gas, while air and recycled gas is passed through the bed to thereby heat the material and commence the desired laterally uniform combustion in the bed. The procedure permits precise control of the air and gaseous fuel mixtures and material rates, and permits the use of the process equipment designed for continuous operation of the vessel.

  5. Technical Report: Rayleigh Scattering Combustion Diagnostic

    SciTech Connect (OSTI)

    Adams, Wyatt; Hecht, Ethan

    2015-07-29

    A laser Rayleigh scattering (LRS) temperature diagnostic was developed over 8 weeks with the goal of studying oxy-combustion of pulverized coal char in high temperature reaction environments with high concentrations of carbon dioxide. Algorithms were developed to analyze data collected from the optical diagnostic system and convert the information to temperature measurements. When completed, the diagnostic will allow for the kinetic gasification rates of the oxy-combustion reaction to be obtained, which was previously not possible since the high concentrations of high temperature CO2 consumed thermocouples that were used to measure flame temperatures inside the flow reactor where the combustion and gasification reactions occur. These kinetic rates are important for studying oxycombustion processes suitable for application as sustainable energy solutions.

  6. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  7. Spectroscopy, Kinetics, and Dynamics of Combustion Radicals

    SciTech Connect (OSTI)

    Nesbitt, David J.

    2013-08-06

    Spectroscopy, kinetics and dynamics of jet cooled hydrocarbon transients relevant to the DOE combustion mission have been explored, exploiting i) high resolution IR lasers, ii) slit discharge sources for formation of jet cooled radicals, and iii) high sensitivity detection with direct laser absorption methods and near the quantum shot noise limit. What makes this combination powerful is that such transients can be made under high concentrations and pressures characteristic of actual combustion conditions, and yet with the resulting species rapidly cooled (T ≈10-15K) in the slit supersonic expansion. Combined with the power of IR laser absorption methods, this provides novel access to spectral detection and study of many critical combustion species.

  8. Control system for supercharged internal combustion engine

    SciTech Connect (OSTI)

    Kawamura, H.

    1988-05-24

    A control system for controlling an internal combustion engine is described having a supercharge including a rotatable shaft and an exhaust turbine driven by exhaust gas. The control system comprising: a rotary electric machine mounted on the rotatable shaft of the supercharger for imposing a load on the exhaust turbine of the supercharger; setting means for setting an engine brake mode of the internal combustion engine; and operating means for operating the rotary electric machine when the engine brake mode is set by the setting means.

  9. Resonance ionization detection of combustion radicals

    SciTech Connect (OSTI)

    Cool, T.A.

    1993-12-01

    Fundamental research on the combustion of halogenated organic compounds with emphasis on reaction pathways leading to the formation of chlorinated aromatic compounds and the development of continuous emission monitoring methods will assist in DOE efforts in the management and disposal of hazardous chemical wastes. Selective laser ionization techniques are used in this laboratory for the measurement of concentration profiles of radical intermediates in the combustion of chlorinated hydrocarbon flames. A new ultrasensitive detection technique, made possible with the advent of tunable VUV laser sources, enables the selective near-threshold photoionization of all radical intermediates in premixed hydrocarbon and chlorinated hydrocarbon flames.

  10. Kinetic data base for combustion modeling

    SciTech Connect (OSTI)

    Tsang, W.; Herron, J.T.

    1993-12-01

    The aim of this work is to develop a set of evaluated rate constants for use in the simulation of hydrocarbon combustion. The approach has been to begin with the small molecules and then introduce larger species with the various structural elements that can be found in all hydrocarbon fuels and decomposition products. Currently, the data base contains most of the species present in combustion systems with up to four carbon atoms. Thus, practically all the structural grouping found in aliphatic compounds have now been captured. The direction of future work is the addition of aromatic compounds to the data base.

  11. Past experiences with automotive external combustion engines

    SciTech Connect (OSTI)

    Amann, C.A.

    1999-07-01

    GMR (General Motors Research Laboratories, now GM R and D Center) has a history of improving the internal combustion engine, especially as it relates to automotive use. During the quarter century from 1950--75, considerable effort was devoted to evaluating alternative powerplants based on thermodynamic cycles different from those on which the established spark-ignition and diesel engines are founded. Two of these, the steam engine and the Stirling engine, incorporated external combustion. Research on those two alternatives is reviewed. Both were judged to fall short of current needs for commercial success as prime movers for conventional automotive vehicles.

  12. Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines

    Broader source: Energy.gov [DOE]

    Document:  ace012_flowers_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Dan FlowersPresenting Organization: Lawrence Livermore National Laboratory (LLNL...

  13. A Comparison of Combustion and Emissions of Diesel Fuels and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated ...

  14. Combustion and Emissions Performance of Dual-Fuel Gasoline and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Emissions Performance of Dual-Fuel Gasoline and Diesel HECC on a Multi-Cylinder Light Duty Diesel Engine Combustion and Emissions Performance of Dual-Fuel Gasoline ...

  15. Vehicle Technologies Office: 2013 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion R&D Annual Progress Report Vehicle Technologies Office: 2013 Advanced Combustion R&D Annual Progress Report This report describes the progress made on the research and ...

  16. Investigation of Fuel Quality Impact on the Combustion and Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Quality Impact on the Combustion and Exhaust Emissions of a Turbo-Charged SI Engine Operated on Low BTU Gases Investigation of Fuel Quality Impact on the Combustion and ...

  17. Vehicle Technologies Office: 2010 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 Advanced Combustion R&D Annual Progress Report Vehicle Technologies Office: 2010 Advanced Combustion R&D Annual Progress Report 2010advcombustionengine.pdf (16.62 MB) More ...

  18. Vehicle Technologies Office: 2008 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion R&D Annual Progress Report Vehicle Technologies Office: 2008 Advanced Combustion R&D Annual Progress Report 2008advcombustionengine.pdf (13.18 MB) More Documents & ...

  19. Use of Low Cetane Fuel to Enable Low Temperature Combustion

    Broader source: Energy.gov [DOE]

    Document:  ace011_ciatti_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Steve CiattiPresenting Organization: Argonne National Laboratory (ANL...

  20. Vehicle Technologies Office: 2011 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11 Advanced Combustion R&D Annual Progress Report Vehicle Technologies Office: 2011 Advanced Combustion R&D Annual Progress Report Annual report on the work of the the Advanced...

  1. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  2. Idling Emissions Reduction Technology with Low Temperature Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion of DI Biodiesel and PFI n-Butanol Idling Emissions Reduction Technology with Low Temperature Combustion of DI Biodiesel and PFI n-Butanol Results from an ...

  3. Development of High-Efficiency Clean Combustion Engines Designs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Clean Combustion Engines Designs for SI and CI Engines Development of High-Efficiency Clean Combustion Engines Designs for SI and CI Engines 2010 DOE Vehicle...

  4. Making a Difference: Heavy-Duty Combustion Engine Research Saved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Combustion Engine Research Saved Billions Making a Difference: Heavy-Duty Combustion Engine Research Saved Billions December 29, 2015 - 12:22pm Addthis Sandia researcher ...

  5. Helical Poly(5-alkyl-2,3-thiophene)s: Controlled Synthesis and Structure Characterization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Hong-Hai; Ma, Chuanxu; Bonnesen, Peter V.; Zhu, Jiahua; Sumpter, Bobby G.; Carrillo, Jan-Michael Y.; Yin, Panchao; Wang, Yangyang; Li, An-Ping; Hong, Kunlun

    2016-07-12

    Whereas Poly(3-alkyl-2,5-thiophene)s (P3AT), with many potential applications, have been extensively investigated, their ortho-connected isomers, poly(5-alkyl-2,3-thiophene)s (P5AT), have never been reported because of the difficulty in their syntheses. We herein present the first synthesis of regioregular P5AT via controlled Suzuki cross-coupling polymerization with PEPPSI-IPr as catalyst, affording the polymers with tunable molecular weight, narrow polydispersity (PDI) and well-defined functional end groups at the gram scale. The helical geometry of P5AT was studied by a combination of NMR, small angle x-ray scattering (SAXS) and scanning tunneling microscopy (STM). Particularly, the single polymer chain of poly(5- 2 butyl-2,3-thiophene) (P5BT) on highly oriented pyrolyticmore » graphite (HOPG) substrates with either M or P helical conformation was directly observed by STM. The comparison of UV-vis absorption between poly(5-hexyl-2,3-thiophene) (P5HT) (λ = 345 nm) and poly(3-hexyl-2,5- thiophene) (P3HT) (λ = 450 nm) indicated that the degree of conjugation of the backbone in P5HT is less than in P3HT, which may be a consequence of the helical geometry of the former compared to the more planar geometry of the latter. Moreover, we found that P5HT can emit green fluorescence under UV (λ = 360 nm) irradiation« less

  6. Building America Expert Meeting: Combustion Safety | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Safety Building America Expert Meeting: Combustion Safety This expert meeting, The Best Approach to Combustion Safety in a Direct Vent World, was conducted by the Partnership for Advanced Residential Retrofit team on June 28, 2012, in San Antonio, TX. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety

  7. Building America Technology Solutions Case Study: Combustion Safety

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simplified Test Protocol | Department of Energy Combustion Safety Simplified Test Protocol Building America Technology Solutions Case Study: Combustion Safety Simplified Test Protocol Two U.S. Department of Energy Building America teams-Partnership for Advanced Residential Retrofit and NorthernSTAR Building America Partnership -developed a simplified test procedure (STP) to address combustion safety to implement than current tests and should produce fewer false positives. Combustion Safety

  8. Traveling-Wave Thermoacoustic Engines With Internal Combustion

    DOE Patents [OSTI]

    Weiland, Nathan Thomas; Zinn, Ben T.; Swift, Gregory William

    2004-05-11

    Thermoacoustic devices are disclosed wherein, for some embodiments, a combustion zone provides heat to a regenerator using a mean flow of compressible fluid. In other embodiments, burning of a combustible mixture within the combustion zone is pulsed in phase with the acoustic pressure oscillations to increase acoustic power output. In an example embodiment, the combustion zone and the regenerator are thermally insulated from other components within the thermoacoustic device.

  9. Simulation of High Efficiency Clean Combustion Engines and Detailed...

    Broader source: Energy.gov (indexed) [DOE]

    ongoing work exploring fuel chemistry, analysis of and improving simulation methodologies for high efficiency clean combustion regimes, and computational performance ...

  10. Staged combustion with piston engine and turbine engine supercharger

    DOE Patents [OSTI]

    Fischer, Larry E.; Anderson, Brian L.; O'Brien, Kevin C.

    2011-11-01

    A combustion engine method and system provides increased fuel efficiency and reduces polluting exhaust emissions by burning fuel in a two-stage combustion system. Fuel is combusted in a piston engine in a first stage producing piston engine exhaust gases. Fuel contained in the piston engine exhaust gases is combusted in a second stage turbine engine. Turbine engine exhaust gases are used to supercharge the piston engine.

  11. Staged combustion with piston engine and turbine engine supercharger

    DOE Patents [OSTI]

    Fischer, Larry E.; Anderson, Brian L.; O'Brien, Kevin C.

    2006-05-09

    A combustion engine method and system provides increased fuel efficiency and reduces polluting exhaust emissions by burning fuel in a two-stage combustion system. Fuel is combusted in a piston engine in a first stage producing piston engine exhaust gases. Fuel contained in the piston engine exhaust gases is combusted in a second stage turbine engine. Turbine engine exhaust gases are used to supercharge the piston engine.

  12. 3-D Combustion Simulation Strategy Status, Future Potential, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application Issues | Department of Energy D Combustion Simulation Strategy Status, Future Potential, and Application Issues 3-D Combustion Simulation Strategy Status, Future Potential, and Application Issues 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: DaimlerChrylser 2004_deer_steiner.pdf (2.16 MB) More Documents & Publications Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine Applications Advancement in Fuel Spray and Combustion

  13. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  14. Supportive studies in fluidized-bed combustion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    CHALCOGENIDES; CHEMICAL REACTIONS; COMBUSTION; COMBUSTORS; ENERGY SOURCES; FOSSIL FUELS; FUELS; FUNCTIONAL MODELS; GASEOUS WASTES; NITROGEN COMPOUNDS; OXIDATION; OXIDES; ...

  15. Fuels for Advanced Combustion Engines (FACE) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Advanced Combustion Engines (FACE) Fuels for Advanced Combustion Engines (FACE) Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). deer07_taylor.pdf (415.77 KB) More Documents & Publications Fuels For Advanced Combustion Engines (FACE) Fuels for Advanced Combustion Engines Fuels for Advanced

  16. Oxygen-Enriched Combustion for Military Diesel Engine Generators |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion deer09_yelvington.pdf (196.85 KB) More Documents & Publications Development Methodology for Power-Dense Military Diesel Engine Oxygen-Enriched Combustion Emission Control Strategy for Downsized Light-Duty Diese

  17. Vehicle Technologies Office: Materials for High-Efficiency Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy High-Efficiency Combustion Engines Vehicle Technologies Office: Materials for High-Efficiency Combustion Engines The Vehicle Technologies Office (VTO) is supporting work to improve the efficiency of advanced internal combustion engines for automotive, light trucks, and heavy-truck applications by 25% to 50%. However, many of these combustion strategies require high operating temperatures and pressures that exceed current materials' abilities to reliably operate

  18. 2008 Annual Merit Review Results Summary - 7. Combustion Research |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 7. Combustion Research 2008 Annual Merit Review Results Summary - 7. Combustion Research DOE Vehicle Technologies Annual Merit Review 2008_merit_review_7.pdf (1.84 MB) More Documents & Publications 2008 Annual Merit Review Results Summary - 8. High Efficiency Clean Combustion and Enabling Technologies 2008 Annual Merit Review Results Summary - 9. Emission Control and Aftertreatment 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies

  19. 2012 Annual Merit Review Results Report - Advanced Combustion Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy 2 Annual Merit Review Results Report - Advanced Combustion Engine Technologies 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research activities 2012_amr_04.pdf (8.69 MB) More Documents & Publications 2011 Annual Merit Review Results Report - Advanced Combustion Engine Technologies DOE Vehicle Technologies Program 2009 Merit Review Report - Advanced Combustion 2010 DOE EERE

  20. Biodiesel's Enabling Characteristics in Attaining Low Temperature Diesel Combustion

    Broader source: Energy.gov [DOE]

    Discusses reasons and physical significance of cool-flame behavior of biodiesel on improving low temperature diesel combustion

  1. 2008 Annual Merit Review Results Summary - 7. Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7-1 7. Combustion Research Introduction The U.S. Department of Energy's Advanced Combustion Engine research addresses critical technical barriers to the commercialization of more efficient advanced internal combustion engines in light-, medium-, and heavy-duty vehicles. Specific goals are to improve, by 2012, the efficiency of internal combustion engines for (1) light-duty applications from 30% to 45% and (2) for heavy-duty applications from 40% to 55% - while meeting cost, durability, and

  2. 2011 Annual Merit Review Results Report - Advanced Combustion Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Advanced Combustion Engine Technologies 2011 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research activities 2011_amr_04.pdf (12.57 MB) More Documents & Publications 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Advanced Combustion Engine R&D and Fuels Technology Merit Review 2010 DOE EERE Vehicle Technologies Program Merit Review -

  3. 2014 Annual Merit Review Results Report - Advanced Combustion Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies | Department of Energy Advanced Combustion Engine Technologies 2014 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research activities 2014_amr_04.pdf (7.88 MB) More Documents & Publications 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies 2013 Annual Merit Review Results Report - Advanced Combustion Engine Technologies 2010 DOE EERE Vehicle Technologies Program Merit

  4. The Role of Advanced Combustion in Improving Thermal Efficiency |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy of Advanced Combustion in Improving Thermal Efficiency The Role of Advanced Combustion in Improving Thermal Efficiency Combustion plays an important role in enabling high thermal efficiencies. Technologies that deliver short combustion duration and low soot emissions are needed. deer08_gehrke.pdf (1.39 MB) More Documents & Publications Development of Enabling Technologies for High Efficiency, Low Emissions Homogeneous Charge Compression Ignition (HCCI) Engines

  5. CFD Combustion Modeling with Conditional Moment Closure using Tabulated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry | Department of Energy Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry CFD Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry A method is presented that allows for efficient conditional moment closure combustion simulations through the use of a progress variable based parameterization of the combustion chemistry. p-15_borg.pdf (228.78 KB) More Documents & Publications Advanced CFD Models for High Efficiency Compression

  6. Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Assisted Diesel Combustion in a Common Rail Turbodiesel Engine Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine This study measured the effects of hydrogen substitution on engine performance and reducing NOx emissions in a diesel engine deer09_boehman.pdf (150.76 KB) More Documents & Publications Particulate Produced from Advanced Combustion Operation in a Compression Ignition Engine Advanced Diesel Combustion with Low Hydrocarbon and Carbon

  7. Trash or treasure? Putting coal combustion waste to work

    SciTech Connect (OSTI)

    Tenenbaum, D.J.

    2009-11-15

    The use of coal combustion wastes from power plants in construction materials, leaching and the impact of regulations are discussed.

  8. Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ

    Office of Scientific and Technical Information (OSTI)

    Transesterification: Laboratory Analytical Procedure (LAP) (Technical Report) | SciTech Connect Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) Citation Details In-Document Search Title: Determination of Total Lipids as Fatty Acid Methyl Esters (FAME) by in situ Transesterification: Laboratory Analytical Procedure (LAP) This procedure is based on a whole biomass transesterification of lipids to fatty acid

  9. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  10. Multi-stage combustion using nitrogen-enriched air

    DOE Patents [OSTI]

    Fischer, Larry E.; Anderson, Brian L.

    2004-09-14

    Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and lifetime cycles of materials in contact with combustion products and to reduce pollutants while maintaining relatively high combustion and thermal cycle efficiencies. The first stage of combustion operates fuel rich where most of the heat of combustion is released by burning it with nitrogen-enriched air. Part of the energy in the combustion gases is used to perform work or to provide heat. The cooled combustion gases are reheated by additional stages of combustion until the last stage is at or near stoichiometric conditions. Additional energy is extracted from each stage to result in relatively high thermal cycle efficiency. The air is enriched with nitrogen using air separation technologies such as diffusion, permeable membrane, absorption, and cryogenics. The combustion method is applicable to many types of combustion equipment, including: boilers, burners, turbines, internal combustion engines, and many types of fuel including hydrogen and carbon-based fuels including methane and coal.

  11. Internal combustion engine with an exhaust gas turbocharger

    SciTech Connect (OSTI)

    Hiereth, H.; Withalm, G.

    1981-06-09

    An internal combustion engine with an exhaust-gas turbocharger, particularly a mixture-compressing internal combustion engine, is disclosed in which a bleeder valve is provided which during the operation of the internal combustion engine in the partial load range conducts the exhaust gases in bypassing relationship to the turbine of the exhaust gas turbocharger.

  12. Optimization of Advanced Diesel Engine Combustion Strategies | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace020_reitz_2011_o.pdf (786.77 KB) More Documents & Publications Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies Use of Low Cetane Fuel to Enable Low Temperature Combustion

  13. Spray Combustion Cross-Cut Engine Research | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace005_pickett_2011_o.pdf (2.06 MB) More Documents & Publications Low-Temperature Diesel Combustion Cross-Cut Research Spray Combustion Cross-Cut Engine Research Progress of the Engine Combustion Network

  14. E-Alerts: Combustion, engines, and propellants (reciprocation and rotating combustion engines). E-mail newsletter

    SciTech Connect (OSTI)

    1999-04-01

    Design, performance, and testing of reciprocating and rotating engines of various configurations for all types of propulsion. Includes internal and external combustion engines; engine exhaust systems; engine air systems components; engine structures; stirling and diesel engines.

  15. Internal combustion engine with sustained power stroke

    SciTech Connect (OSTI)

    McNair, R.J.

    1980-09-09

    A four stroke cycle internal combustion engine is presented having a sustained power stroke which results from a delayed mixing of a stratified charge. Use of delayed mixing of an overall stoichiometric air-fuel mixture results in formation of a low amount of the oxides of nitrogen. Delayed mixing of the stratified charge is achieved by placement of at least one Helmholtz resonator cavity in the head or closed end of each combustion chamber. The Helmholtz resonator cavity communicates with the top end of the main combustion chamber via a narrow slot. On the intake stroke of each engine cylinder, the main chamber is filled with a slightly fuel rich gaseous charge while the companion Helmholtz resonator cavity is filled with air. During the compression stroke some of the rich air-fuel mixture is forced into the resonator cavity via the communicating slot. At or near tdc, the air-fuel mixture in the main chamber is ignited. As the flame front progresses across the chamber a rapid increase in pressure serves not only to power the piston, but also to initiate a resonant reaction in the Helmholtz resonator cavity which results in a transfer of the unburned gases therein into the main combustion chamber. This both sustains the power stroke and at the same time lowers the peak flame temperature in the main chamber.

  16. Experience in preparing fuel for combustion

    SciTech Connect (OSTI)

    Rude, J.

    1995-09-01

    The key phase seems to be that wood is the ORIGINAL FUEL. Certainly as man discovered fire, it was the most obvious as well as abundantly available fuel and it burned very well because man was smart enough to select the dry wood once he understood the basics of combustion. As the needs started to go beyond the most elementary, designs for burning ideal fuels were pretty well perfected, however, the burning of less ideal fuels still remain a challenge. To provide plant steam requirements by burning waste that must be disposed of anyway can reduce operating cost considerably. For most of us involved in producing steam, the experience we have with fuels such as bark, wood waste, sludge, and miscellaneous forms of solid combustible waste material, are a result of burning these fuels in an existing boiler supposedly designed for wood waste or possibly a combination of wood and other fuels such as coal, oil, or gas. For a supplier of fuel preparation systems, the typical application involves the sizing, cleaning, and drying of wood waste, and sludge from a pulp and/or paper mill. Other forms of combustible waste are dealt with occasionally and after proper preparation fired in the combustion system for the purpose of generating hot gas and/or steam for the plant process.

  17. Starting apparatus for internal combustion engines

    DOE Patents [OSTI]

    Dyches, G.M.; Dudar, A.M.

    1995-01-01

    This report is a patent description for a system to start an internal combustion engine. Remote starting and starting by hearing impaired persons are addressed. The system monitors the amount of current being drawn by the starter motor to determine when the engine is started. When the engine is started the system automatically deactivates the starter motor. Five figures are included.

  18. Parallel Performance of a Combustion Chemistry Simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Skinner, Gregg; Eigenmann, Rudolf

    1995-01-01

    We used a description of a combustion simulation's mathematical and computational methods to develop a version for parallel execution. The result was a reasonable performance improvement on small numbers of processors. We applied several important programming techniques, which we describe, in optimizing the application. This work has implications for programming languages, compiler design, and software engineering.

  19. Contact CEFRC - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact CEFRC Contact CEFRC Combustion Energy Frontier Research Center Princeton University Engineering Quadrangle Suite D-334 Olden Street Princeton, NJ 08544-5263 Phone: 609.258.4083 Fax: 609.258.6233 Email: asaha@princeton.edu © 2016 The Trustees of Princeton University Last update: February 17, 2016

  20. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2002-08-01

    This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

  1. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect (OSTI)

    2005-09-01

    This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

  2. NOx Emission Reduction by Oscillating Combustion

    SciTech Connect (OSTI)

    John C. Wagner

    2004-03-31

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  3. NOx Emission Reduction by Oscillating combustion

    SciTech Connect (OSTI)

    Institute of Gas Technology

    2004-01-30

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  4. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Gagliano, Michael; Seltzer, Andrew; Agarwal, Hans; Robertson, Archie; Wang, Lun

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO2 level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to two year

  5. Oxy-Combustion Boiler Material Development

    SciTech Connect (OSTI)

    Michael Gagliano; Andrew Seltzer; Hans Agarwal; Archie Robertson; Lun Wang

    2012-01-31

    Under U.S. Department of Energy Cooperative Agreement No. DE-NT0005262 Foster Wheeler North America Corp conducted a laboratory test program to determine the effect of oxy-combustion on boiler tube corrosion. In this program, CFD modeling was used to predict the gas compositions that will exist throughout and along the walls of air-fired and oxy-fired boilers operating with low to high sulfur coals. Test coupons of boiler tube materials were coated with deposits representative of those coals and exposed to the CFD predicted flue gases for up to 1000 hours. The tests were conducted in electric tube furnaces using oxy-combustion and air-fired flue gases synthesized from pressurized cylinders. Following exposure, the test coupons were evaluated to determine the total metal wastage experienced under air and oxy-combustions conditions and materials recommendations were made. Similar to air-fired operation, oxy-combustion corrosion rates were found to vary with the boiler material, test temperature, deposit composition, and gas composition. Despite this, comparison of air-fired and oxy-fired corrosion rates showed that oxy-firing rates were, for the most part, similar to, if not lower than those of air-firing; this finding applied to the seven furnace waterwall materials (wrought and weld overlay) and the ten superheater/reheater materials (wrought and weld overlay) that were tested. The results of the laboratory oxy-combustion tests, which are based on a maximum bulk flue gas SO{sub 2} level of 3200 ppmv (wet) / 4050 ppmv (dry), suggest that, from a corrosion standpoint, the materials used in conventional subcritical and supercritical, air-fired boilers should also be suitable for oxy-combustion retrofits. Although the laboratory test results are encouraging, they are only the first step of a material evaluation process and it is recommended that follow-on corrosion tests be conducted in coal-fired boilers operating under oxy-combustion to provide longer term (one to

  6. Combustion Energy Frontier Research Center Post-Doctoral Position in Advanced Combustion Simulations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Frontier Research Center (CEFRC) seeks outstanding applicants for the position of post-doctoral research associate to perform research at Cornell University and Sandia National Laboratories on advanced simulations of turbulent combustion. This position is as a Combustion Energy Research Fellow, as described at http://pcl.princeton.edu/efrc/fellow_Flyer.html . The project involves two simulation methodologies: direct numerical simulation (DNS); and large-eddy simulation (LES) using the

  7. Combustive management of oil spills. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris.

  8. A combustion model for IC engine combustion simulations with multi-component fuels

    SciTech Connect (OSTI)

    Ra, Youngchul; Reitz, Rolf D.

    2011-01-15

    Reduced chemical kinetic mechanisms for the oxidation of representative surrogate components of a typical multi-component automotive fuel have been developed and applied to model internal combustion engines. Starting from an existing reduced mechanism for primary reference fuel (PRF) oxidation, further improvement was made by including additional reactions and by optimizing reaction rate constants of selected reactions. Using a similar approach to that used to develop the reduced PRF mechanism, reduced mechanisms for the oxidation of n-tetradecane, toluene, cyclohexane, dimethyl ether (DME), ethanol, and methyl butanoate (MB) were built and combined with the PRF mechanism to form a multi-surrogate fuel chemistry (MultiChem) mechanism. The final version of the MultiChem mechanism consists of 113 species and 487 reactions. Validation of the present MultiChem mechanism was performed with ignition delay time measurements from shock tube tests and predictions by comprehensive mechanisms available in the literature. A combustion model was developed to simulate engine combustion with multi-component fuels using the present MultiChem mechanism, and the model was applied to simulate HCCI and DI engine combustion. The results show that the present multi-component combustion model gives reliable performance for combustion predictions, as well as computational efficiency improvements through the use of reduced mechanism for multi-dimensional CFD simulations. (author)

  9. Variable compression ratio device for internal combustion engine

    DOE Patents [OSTI]

    Maloney, Ronald P.; Faletti, James J.

    2004-03-23

    An internal combustion engine, particularly suitable for use in a work machine, is provided with a combustion cylinder, a cylinder head at an end of the combustion cylinder and a primary piston reciprocally disposed within the combustion cylinder. The cylinder head includes a secondary cylinder and a secondary piston reciprocally disposed within the secondary cylinder. An actuator is coupled with the secondary piston for controlling the position of the secondary piston dependent upon the position of the primary piston. A communication port establishes fluid flow communication between the combustion cylinder and the secondary cylinder.

  10. Systems and methods of storing combustion waste products

    DOE Patents [OSTI]

    Chen, Shen-En; Wang, Peng; Miao, Xiexing; Feng, Qiyan; Zhu, Qianlin

    2016-04-12

    In one aspect, methods of storing one or more combustion waste products are described herein. Combustion waste products stored by a method described herein can include solid combustion waste products such as coal ash and/or gaseous combustion products such as carbon dioxide. In some embodiments, a method of storing carbon dioxide comprises providing a carbon dioxide storage medium comprising porous concrete having a macroporous and microporous pore structure and flowing carbon dioxide captured from a combustion flue gas source into the pore structure of the porous concrete.

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this

  12. Effect of air distribution on solid fuel bed combustion

    SciTech Connect (OSTI)

    Kuo, J.T.; Hsu, W.S.; Yo, T.C.

    1996-09-01

    One important aspect of refuse mass-burn combination control is the manipulation of combustion air. Proper air manipulation is key to the achievement of good combustion efficiency and reduction of pollutant emissions. Experiments, using a small fix-grate laboratory furnace with cylindrical combustion chamber, were performed to investigate the influence of undergrate/sidewall air distribution on the combustion of beds of wood cubes. Wood cubes were used as a convenient laboratory surrogate of solid refuse. Specifically, for different bed configurations (e.g. bed height, bed voidage and bed fuel size, etc.), burning rates and combustion temperatures at different bed locations were measured under various air supply and distribution conditions. One of the significant results of the experimental investigation is that combustion, with air injected from side walls and no undergrate air, provide the most efficient combustion. On the other hand, combustion with undergrate air achieves higher combustion rates but with higher CO emissions. A simple one-dimensional model was constructed to derive correlations of combustion rate as functions of flue gas temperature and oxygen concentration. Despite the fact that the model is one dimensional and many detailed chemical and physical processes of combustion are not considered, comparisons of the model predictions and the experimental results indicate that the model is appropriate for quantitative evaluation of bed burning rates.

  13. Combustion chamber and thermal vapor stream producing apparatus and method

    DOE Patents [OSTI]

    Sperry, John S.; Krajicek, Richard W.; Cradeur, Robert R.

    1978-01-01

    A new and improved method and apparatus for burning a hydrocarbon fuel for producing a high pressure thermal vapor stream comprising steam and combustion gases for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, wherein a high pressure combustion chamber having multiple refractory lined combustion zones of varying diameters is provided for burning a hydrocarbon fuel and pressurized air in predetermined ratios injected into the chamber for producing hot combustion gases essentially free of oxidizing components and solid carbonaceous particles. The combustion zones are formed by zones of increasing diameters up a final zone of decreasing diameter to provide expansion zones which cause turbulence through controlled thorough mixing of the air and fuel to facilitate complete combustion. The high pressure air and fuel is injected into the first of the multiple zones where ignition occurs with a portion of the air injected at or near the point of ignition to further provide turbulence and more complete combustion.

  14. Alkyl group substitution by oxime-bound palladium(II) (the Shaw reaction): Alkly group selectivity and deuterium isotope effects

    SciTech Connect (OSTI)

    Wells, A.P.; Kitching, W.

    1992-08-01

    This report provides information regarding the selectivity of alkyl groups and the nature of the transition state for C-H palladation by oxime-bound palladium(II) (the Shaw reaction). The kinetic deuterium isotope effects are also presented. 21 refs.

  15. Alkyl-bis(imidazolium) salts: a new amphiphile platform that forms thermotropic and non-aqueous lyotropic bicontinuous cubic phases

    SciTech Connect (OSTI)

    Robertson, LA; Schenkel, MR; Wiesenauer, BR; Gin, DL

    2013-01-01

    New ionic amphiphiles with a hexyl-bridged bis(imidazolium) headgroup; Br-, BF4-, or Tf2N- anions; and a long n-alkyl tail can form thermotropic bicontinuous cubic liquid crystal phases in neat form and/or lyotropic bicontinuous cubic phases with several non-aqueous solvents or water.

  16. Vapor pressures of 1,3-dialkylimidazolium bis(trifluoromethylsulfonyl)imide ionic liquids with long alkyl chains

    SciTech Connect (OSTI)

    Rocha, Marisa A. A. E-mail: marisa.alexandra.rocha@gmail.com; Coutinho, João A. P.; Santos, Luís M. N. B. F. E-mail: marisa.alexandra.rocha@gmail.com

    2014-10-07

    This work presents the vapor pressure at several temperatures for the 1,3-dialkylimidazolium bis(trifluoromethylsulfonyl)imide series, [C{sub N/2}C{sub N/2}im][NTf{sub 2}] (N = 14, 16, 18, and 20), measured by a Knudsen effusion method combined with a quartz crystal microbalance. The thermodynamic properties of vaporization of the ionic liquids under study are analysed together with the results obtained previously for the shorter alkyl chain length [C{sub N/2}C{sub N/2}im][NTf{sub 2}] (N = 2, 4, 6, 8, 10, and 12), in order to evaluate the effect of the alkyl side chains of the cation and to get additional insights concerning the nanostructuration of ionic liquids. The symmetry effect is explored, based on the comparison with the asymmetric imidazolium based ionic liquids, [C{sub N-1}C{sub 1}im][NTf{sub 2}]. A trend shift on the thermodynamic properties of vaporization along the alkyl side chains of the extended symmetric ionic liquids, around [C{sub 6}C{sub 6}im][NTf{sub 2}], was detected. An intensification of the odd-even effect was observed starting from [C{sub 6}C{sub 6}im][NTf{sub 2}], with higher enthalpies and entropies of vaporization for the odd numbered ionic liquids, [C{sub 7}C{sub 7}im][NTf{sub 2}] and [C{sub 9}C{sub 9}im][NTf{sub 2}]. Similar, but less pronounced, odd-even effect was found for the symmetric ionic liquids with lower alkyl side chains length, [C{sub N/2}C{sub N/2}im][NTf{sub 2}] (with N = 4, 6, 8, 10, and 12). This effect is related with the predominant orientation of the terminal methyl group of the alkyl chain to the imidazolium ring and their influence in the cation-anion interaction. The same Critical Alkyl length at the hexyl, (C{sub 6}C{sub 1}and C{sub 6}C{sub 6}) was found for both asymmetric and symmetric series indicating that the nanostructuration of the ionic liquids is related with alkyl chain length.

  17. Raman Scattering Sensor for Control of the Acid Alkylation Process in Gasoline Production

    SciTech Connect (OSTI)

    Uibel, Rory, H.; Smith, Lee M.; Benner, Robert, E.

    2006-04-19

    Gasoline refineries utilize a process called acid alkylation to increase the octane rating of blended gasoline, and this is the single most expensive process in the refinery. For process efficiency and safety reasons, the sulfuric acid can only be used while it is in the concentration range of 98 to 86 %. The conventional technique to monitor the acid concentration is time consuming and is typically conducted only a few times per day. This results in running higher acid concentrations than they would like to ensure that the process proceeds uninterrupted. Maintaining an excessively high acid concentration costs the refineries millions of dollars each year. Using SBIR funding, Process Instruments Inc. has developed an inline sensor for real time monitoring of acid concentrations in gasoline refinery alkylation units. Real time data was then collected over time from the instrument and its responses were matched up with the laboratory analysis. A model was then developed to correlate the laboratory acid values to the Raman signal that is transmitted back to the instrument from the process stream. The instrument was then used to demonstrate that it could create real-time predictions of the acid concentrations. The results from this test showed that the instrument could accurately predict the acid concentrations to within ~0.15% acid strength, and this level of prediction proved to be similar or better then the laboratory analysis. By utilizing a sensor for process monitoring the most economic acid concentrations can be maintained. A single smaller refinery (50,000 barrels/day) estimates that they should save over $120,000/year, with larger refineries saving considerably more.

  18. Internal combustion engine with integral intercooler

    SciTech Connect (OSTI)

    Poore, B.B.; Beitel, H.V.; Weinert, S.

    1990-11-06

    This patent describes a liquid-cooled internal combustion engine. It comprises: a cylinder block; a cylinder head attached to the block and having formed therein a combustion air inlet, a coolant supply passage, a coolant return passage and an air supply passage for receiving turbocharged air; an intercooler having a coolant inlet and a coolant outlet; a first conduit communicating the intercooler coolant inlet with the coolant supply passage; a second conduit communicating the intercooler coolant outlet with the coolant return passage; a cover attachable to the cylinder head, the cover completely enclosing the intercooler and the first and second conduits; and the cover, the cylinder head and the intercooler being arranged so that turbocharged air flows from the air supply passage to the air inlet via the intercooler.

  19. Findings of Hydrogen Internal Combustion Engine Durability

    SciTech Connect (OSTI)

    Garrett Beauregard

    2010-12-31

    Hydrogen Internal Combustion Engine (HICE) technology takes advantage of existing knowledge of combustion engines to provide a means to power passenger vehicle with hydrogen, perhaps as an interim measure while fuel cell technology continues to mature. This project seeks to provide data to determine the reliability of these engines. Data were collected from an engine operated on a dynamometer for 1000 hours of continuous use. Data were also collected from a fleet of eight (8) full-size pickup trucks powered with hydrogen-fueled engines. In this particular application, the data show that HICE technology provided reliable service during the operating period of the project. Analyses of engine components showed little sign of wear or stress except for cylinder head valves and seats. Material analysis showed signs of hydrogen embrittlement in intake valves.

  20. Methods and systems for combustion dynamics reduction

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Varatharajan, Balachandar; Srinivasan, Shiva; Lynch, John Joseph; Yilmaz, Ertan; Kim, Kwanwoo; Lacy, Benjamin; Crothers, Sarah; Singh, Kapil Kumar

    2009-08-25

    Methods and systems for combustion dynamics reduction are provided. A combustion chamber may include a first premixer and a second premixer. Each premixer may include at least one fuel injector, at least one air inlet duct, and at least one vane pack for at least partially mixing the air from the air inlet duct or ducts and fuel from the fuel injector or injectors. Each vane pack may include a plurality of fuel orifices through which at least a portion of the fuel and at least a portion of the air may pass. The vane pack or packs of the first premixer may be positioned at a first axial position and the vane pack or packs of the second premixer may be positioned at a second axial position axially staggered with respect to the first axial position.