Sample records for alkyl ester combustible

  1. Method of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian (Wheat Ridge, CO)

    2010-09-14T23:59:59.000Z

    Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

  2. COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls

    E-Print Network [OSTI]

    Zare, Richard N.

    COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

  3. Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters transportation fuel dedicated to the diesel engine, biodiesel, with an emphasis on ethyl esters because of biodiesel and related components, the main gaps in the field are highlighted to facilitate the convergence

  4. The influence of molecular structure of fatty acid monoalkyl esters on diesel combustion

    SciTech Connect (OSTI)

    Schoenborn, Alessandro; Ladommatos, Nicos [Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE (United Kingdom); Williams, John; Allan, Robert; Rogerson, John [BP Oil UK Limited, Technology Centre, Whitchurch Hill, Pangbourne, Reading, RG8 7QR (United Kingdom)

    2009-07-15T23:59:59.000Z

    The subject of this paper is a series of experiments conducted on a single-cylinder research engine investigating the influence of molecular structure on the combustion behaviour of fatty acid alcohol ester (biodiesel) molecules under diesel engine conditions. The fuels employed in these experiments comprised various samples of pure individual fatty acid alcohol ester molecules of different structure, as well as several mixtures of such molecules. The latter consisted in biodiesel fuels produced by the transesterification of naturally occurring plant oils or animal fat with a monohydric alcohol. It was observed that the molecular structure of the fuel significantly influenced the formation of NO{sub x} and particulate matter and their respective concentration in the exhaust gas. The influence on the formation of NO{sub x} in particular, appeared to be exerted first through the effect which the molecular structure had on the auto-ignition delay occurring after the fuel was injected into the combustion chamber, and second through the flame temperature at which the various molecules burned. The emission of particulates on the other hand showed correlation with the number of double bonds in the fuel molecules for the case of larger accumulation mode particles, and with the boiling point of the fuel samples for the case of the smaller, nucleation mode particles. The effect of ignition delay on the exhaust emissions of these pollutants was isolated by adding the ignition promoting molecule 2-ethylhexyl nitrate to some of the fuel samples in closely specified concentrations, so as to equalise the ignition delay for the relevant fuel samples. The removal of the ignition delay as a main influence on the combustion process enabled the observation of the lesser effects of adiabatic flame temperature. (author)

  5. Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of fatty acid esters experience the typical paraffin-like low temperature oxidation sequence; the alkyl chain length of fatty acid esters has a crucial impact on the ignition...

  6. Experimental and Computational Studies of the Combustion of Classical and Alternative Fuels

    E-Print Network [OSTI]

    Niemann, Ulrich

    Appendix B High Pressure Combustion Facility . . . B.11.1 Motivation for Combustion Research 1.2 DiffusionChapter 5 Critical Conditions of Methyl Ester Combustion 5.1

  7. alkyl esters perspectives: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Open learner models, communication, multiple users. 1 Introduction Open learner models (OLM) are learner models that are accessible Bull, Susan 422 When quadrangles are completely...

  8. acid alkyl esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are better for you than their farm-bred cousins. Farmed Fish; Ronald W. Hardy; Hagerman Fish 373 REVIEW OF PERFORMANCE AND EMISSION ANALYSIS OF B-20 A PROMISING ALTERNATIVE FUEL...

  9. alkyl ester salts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

  10. Asymmetric Alkyl?Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins

    E-Print Network [OSTI]

    Owston, Nathan A.

    A method for asymmetric alkyl?alkyl Suzuki reactions of unactivated secondary alkyl electrophiles, specifically, cross-couplings of racemic acylated halohydrins with alkylborane reagents, has been developed. A range of ...

  11. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    1999-01-01T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinic acid comprising: dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures thereof to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing said alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  12. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, L.

    1999-05-25T23:59:59.000Z

    A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  13. Oscillatory Flame Response in Acoustically Coupled Fuel Droplet Combustion

    E-Print Network [OSTI]

    Sevilla Esparza, Cristhian Israel

    2013-01-01T23:59:59.000Z

    CombustionCombustion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Coupled Droplet Combustion . . . . . . . . . . . . Burning

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Definition Biodiesel is defined as a renewable, biodegradable, mono alkyl ester combustible liquid fuel that is derived from agricultural plant oils or animal fats and...

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    and Renewable Fuel Definitions Biodiesel is defined as a renewable, biodegradable, mono alkyl ester combustible liquid fuel that is derived from vegetable oils or animal fats and...

  16. Sandia National Laboratories: Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TechnologiesCombustion Combustion The Combustion Research Facility (CRF) is an internationally recognized center of excellence for combustion science and technology whose...

  17. A Simple, Accurate Model for Alkyl Adsorption on Late Transition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simple, Accurate Model for Alkyl Adsorption on Late Transition Metals. A Simple, Accurate Model for Alkyl Adsorption on Late Transition Metals. Abstract: A simple model that...

  18. Alkylate

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 OilU.S. Offshore U.S.: ShaleAlaskaDay)

  19. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R. [NETL

    2013-03-05T23:59:59.000Z

    Topics covered in this presentation include: the continued importance of coal; related materials challenges; combining oxy-combustion & A-USC steam; and casting large superalloy turbine components.

  20. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  1. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  2. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  3. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Houston, TX)

    1989-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  4. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  5. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  6. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1994-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  7. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  8. Modeling study of the lowtemperature oxidation of large methyl esters from C11 to C19

    E-Print Network [OSTI]

    Boyer, Edmond

    in biodiesel fuels has been investigated. Models have been developed for these species and then detailed; Biodiesel fuels; Modeling; Oxidation * Corresponding author: Olivier Herbinet Laboratory of Reaction the differences with the combustion of alkanes induced by the ester function. While biodiesel fuels deriving from

  9. Combustion Group Group members

    E-Print Network [OSTI]

    Wang, Wei

    Combustion Group Group members: Thierry Poinsot, Emilien Courtine, Luc Vervisch, Benjamin Farcy § New combustion and energy-conversion concepts #12;Introduction Combustion research thrusts Combustion Dynamics and Flame-Stabilization Research objectives § Obtain fundamental understanding of combustion

  10. An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion

    SciTech Connect (OSTI)

    Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

    2010-02-19T23:59:59.000Z

    Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

  11. NREL: Energy Analysis - Sean Esterly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sean Esterly is a member of the Market and Policy Impact Analysis Group in the Strategic Energy Analysis Center. Analyst On staff since August 2013 Phone number: 303-384-7436...

  12. Combustion & Health

    E-Print Network [OSTI]

    Hamilton, W.

    2012-01-01T23:59:59.000Z

    ) ? Combustion of fossil fuels for ? Electricity ? Industrial processes ? Vehicle propulsion ? Cooking and heat ? Other ? Munitions ? Fireworks ? Light ? Cigarettes, hookahs? FFCOMBUSTION & HEALTH FFCOMBUSTION: THE THREAT ? SCALE (think health... for public health and strategies to reduce GHG ? Reduce CO2 emissions by 50% by 2030 ? Reduction in PM2.5 deaths greatly offset costs in all models FFCOMBUSTION & HEALTH FFCOMBUSTION: PM EXPOSURE ? Combustion is source of most concern ? Health...

  13. Chemical Kinetic Models for HCCI and Diesel Combustion

    SciTech Connect (OSTI)

    Pitz, W J; Westbook, C K; Mehl, M

    2008-10-30T23:59:59.000Z

    Hydrocarbon fuels for advanced combustion engines consist of complex mixtures of hundreds or even thousands of different components. These components can be grouped into a number of chemically distinct classes, consisting of n-paraffins, branched paraffins, cyclic paraffins, olefins, oxygenates, and aromatics. Biodiesel contains its own unique chemical class called methyl esters. The fractional amounts of these chemical classes are quite different in gasoline, diesel fuel, oil-sand derived fuels and bio-derived fuels, which contributes to the very different combustion characteristics of each of these types of combustion systems. The objectives of this project are: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

  14. COMBUSTION RESEARCH - FY-1979

    E-Print Network [OSTI]

    ,

    2012-01-01T23:59:59.000Z

    Optical Measurement of Combustion Products by Zeeman Atomicand T. Hadeishi • . . • . • . • • . • Combustion Sources offrom Pulverized Coal Combustion J. Pennucci, R. Greif, F.

  15. Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Combustion To develop a more thorough understanding of combustion, scientists and engineers must be able to analyze the interaction of many different chemical species at...

  16. Combustion Group Group members

    E-Print Network [OSTI]

    Wang, Wei

    Combustion Group Group members: Thierry Poinsot, Emilien Courtine, Luc Vervisch, Benjamin Farcy 2014 #12;Combustion Group Combustion Physics and Modeling Pollutants, Emissions, and Soot Formation Thermoacoustics and Combustion Dynamics Research focus § Examine mechanisms responsible for flame stabilization

  17. Electrochemical method for producing a biodiesel mixture comprising fatty acid alkyl esters and glycerol

    DOE Patents [OSTI]

    Lin, YuPo J; St. Martin, Edward J

    2013-08-13T23:59:59.000Z

    The present invention relates to an integrated method and system for the simultaneous production of biodiesel from free fatty acids (via esterification) and from triglycerides (via transesterification) within the same reaction chamber. More specifically, one preferred embodiment of the invention relates to a method and system for the production of biodiesel using an electrodeionization stack, wherein an ion exchange resin matrix acts as a heterogeneous catalyst for simultaneous esterification and transesterification reactions between a feedstock and a lower alcohol to produce biodiesel, wherein the feedstock contains significant levels of free fatty acid. In addition, because of the use of a heterogeneous catalyst, the glycerol and biodiesel have much lower salt concentrations than raw biodiesel produced by conventional transesterification processes. The present invention makes it much easier to purify glycerol and biodiesel.

  18. Enhancement of alkylation catalysts for improved supercritical fluid regeneration

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID)

    2010-12-28T23:59:59.000Z

    A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

  19. Enhancement of alkylation catalysts for improved supercritical fluid regeneration

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Petkovic, Lucia (Idaho Falls, ID)

    2009-09-22T23:59:59.000Z

    A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

  20. Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded Oxygen Vacancies of TiO2(110). Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded...

  1. Turbulent combustion

    SciTech Connect (OSTI)

    Talbot, L.; Cheng, R.K. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    Turbulent combustion is the dominant process in heat and power generating systems. Its most significant aspect is to enhance the burning rate and volumetric power density. Turbulent mixing, however, also influences the chemical rates and has a direct effect on the formation of pollutants, flame ignition and extinction. Therefore, research and development of modern combustion systems for power generation, waste incineration and material synthesis must rely on a fundamental understanding of the physical effect of turbulence on combustion to develop theoretical models that can be used as design tools. The overall objective of this program is to investigate, primarily experimentally, the interaction and coupling between turbulence and combustion. These processes are complex and are characterized by scalar and velocity fluctuations with time and length scales spanning several orders of magnitude. They are also influenced by the so-called {open_quotes}field{close_quotes} effects associated with the characteristics of the flow and burner geometries. The authors` approach is to gain a fundamental understanding by investigating idealized laboratory flames. Laboratory flames are amenable to detailed interrogation by laser diagnostics and their flow geometries are chosen to simplify numerical modeling and simulations and to facilitate comparison between experiments and theory.

  2. Catalytic, Enantioselective Alkylations of N,O-Acetals

    E-Print Network [OSTI]

    Lectka, Thomas

    , 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

  3. Light Duty Combustion Research: Advanced Light-Duty Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and...

  4. Stretch Efficiency for Combustion Engines: Exploiting New Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes 2013 DOE Hydrogen and Fuel Cells Program and...

  5. Regenerative combustion device

    DOE Patents [OSTI]

    West, Phillip B.

    2004-03-16T23:59:59.000Z

    A regenerative combustion device having a combustion zone, and chemicals contained within the combustion zone, such as water, having a first equilibrium state, and a second combustible state. Means for transforming the chemicals from the first equilibrium state to the second combustible state, such as electrodes, are disposed within the chemicals. An igniter, such as a spark plug or similar device, is disposed within the combustion zone for igniting combustion of the chemicals in the second combustible state. The combustion products are contained within the combustion zone, and the chemicals are selected such that the combustion products naturally chemically revert into the chemicals in the first equilibrium state following combustion. The combustion device may thus be repeatedly reused, requiring only a brief wait after each ignition to allow the regeneration of combustible gasses within the head space.

  6. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R. [NETL

    2013-03-11T23:59:59.000Z

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  7. Simulation of lean premixed turbulent combustion

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    turbulent methane combustion. Proc. Combust. Inst. , 29:in premixed turbulent combustion. Proc. Combust. Inst. ,for zero Mach number combustion. Combust. Sci. Technol. ,

  8. COMBUSTION RESEARCH - FY-1979

    E-Print Network [OSTI]

    ,

    2012-01-01T23:59:59.000Z

    XBL 803-181) product combustion gas mixtures is in samplethrough reaction in the post-combustion gases. The selectiveaddition to the post-combustion gases have been investigated

  9. COMBUSTION RESEARCH - FY-1979

    E-Print Network [OSTI]

    ,

    2012-01-01T23:59:59.000Z

    gases of light fuel oil combustion as a function of severalsystem suitable for the combustion of light oils are underoil, shale, and biomass in these devices poses a dilemma. Much of the scientific understanding of combustion

  10. Add MTBE unit ahead of alkylation

    SciTech Connect (OSTI)

    Masters, K.R.; Prohaska, E.A.

    1988-08-01T23:59:59.000Z

    Approximately three years ago, the people at Diamond Shamrock's Sunray, Texas, refinery recognized a growing demand for high octane super premium unleaded gasoline in their regional marketing area. It was apparent that they would need to change their processing scheme to meet this growing demand. After investigating several options, they decided to install an MTBE (methyl tert-butyl ether) unit upstream of their existing sulfuric acid (H/sub 2/SO/sub 4/) aklylation unit. The new unit would process olefin feed before it entered the alkylation unit. The MTBE unit was expected to improve Diamond Shamrock's gasoline pool in two ways. First, the MTBE would be an additional high octane blending stock for the gasoline pool. Second, the MTBE unit would improve the quality of the olefin stream going to the alkylation unit. Diamond Shamrock brought their MTBE unit onstream in December, 1985. The results of the combined operation exceeded expectations, producing alkylate in excess of 98 RON (Research octane number) and MTBE of 118 RON. These components significantly upgraded the refinery's capability to produce a super premium unleaded gasoline.

  11. Advanced Combustion and Fuels

    Broader source: Energy.gov (indexed) [DOE]

    and predictive tools for fuel property effects on combustion and engine efficiency optimization (Fuels & Lubricants Technologies) * Lack of modeling capability for combustion and...

  12. Sandia Hydrogen Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Combustion Research Sandia Hydrogen Combustion Research Sebastian A. Kaiser (PI) Sandia National Laboratories Christopher M. White University of New Hampshire Sponsor: DoE...

  13. Adsorption of alkyl amides: monolayer structures and mixing behaviour

    E-Print Network [OSTI]

    Bhinde, Tej

    2011-02-08T23:59:59.000Z

    Adsorption of alkyl amides: monolayer structures and mixing behaviour Tej Bhinde Jesus College University of Cambridge October 2010 This dissertation is submitted for the degree of Doctor of Philosophy i   Preface... gratitude to my family for their love, support and encouragement. iii Adsorption of alkyl amides: monolaye r structures and mixing behaviour Tej Bhinde Abstract In this work monolayers of alkyl amides adsorbed on a graphite surface have been...

  14. Method of making a cyanate ester foam

    DOE Patents [OSTI]

    Celina, Mathias C.; Giron, Nicholas Henry

    2014-08-05T23:59:59.000Z

    A cyanate ester resin mixture with at least one cyanate ester resin, an isocyanate foaming resin, other co-curatives such as polyol or epoxy compounds, a surfactant, and a catalyst/water can react to form a foaming resin that can be cured at a temperature greater than 50.degree. C. to form a cyanate ester foam. The cyanate ester foam can be heated to a temperature greater than 400.degree. C. in a non-oxidative atmosphere to provide a carbonaceous char foam.

  15. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  16. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul chugh; James Hower

    2008-08-31T23:59:59.000Z

    This paper discusses the roles and responsibilities of each position within the Combustion Byproducts Recyclcing Consortium.

  17. Alkyl Chlorides as Hydrogen Bond Acceptors

    SciTech Connect (OSTI)

    Nadas, Janos I [ORNL; Vukovic, Sinisa [ORNL; Hay, Benjamin [ORNL

    2012-01-01T23:59:59.000Z

    To gain an understanding of the role of an alkyl chloride as a hydrogen bond acceptor, geometries and interaction energies were calculated at the MP2/aug-cc-pVDZ level of theory for complexes between ethyl chloride and representative hydrogen donor groups. The results establish that these donors, which include hydrogen cyanide, methanol, nitrobenzene, pyrrole, acetamide, and N-methylurea, form X-H {hor_ellipsis} Cl hydrogen bonds (X = C, N, O) of weak to moderate strength, with {Delta}E values ranging from -2.8 to -5.3 kcal/mol.

  18. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  19. Stretch Efficiency for Combustion Engines: Exploiting New Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Washington D.C. ace15daw.pdf More Documents & Publications Stretch Efficiency for Combustion Engines: Exploiting New Combustion Regimes Stretch Efficiency for Combustion...

  20. Light Duty Combustion Research: Advanced Light-Duty Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    duty Diesel Combustion Research Advanced Light-Duty Combustion Experiments Paul Miles Sandia National Laboratories Light-Duty Combustion Modeling Rolf Reitz University of Wisconsin...

  1. Transport Properties for Combustion Modeling

    E-Print Network [OSTI]

    Brown, N.J.

    2010-01-01T23:59:59.000Z

    a critical role in combustion processes just as chemicalparameters are essential for combustion modeling; molecularwith Application to Combustion. Transport Theor Stat 2003;

  2. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  3. Advanced Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Advanced Combustion Combustion engines drive a large percentage of our nation's transportation vehicles and power generation and manufacturing facilities. Today's...

  4. Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides, Including Secondary Alkyl Chlorides, with

    E-Print Network [OSTI]

    Fu, Gregory C.

    Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides February 27, 2006; E-mail: gcf@mit.edu Early work in the area of palladium- and nickel-catalyzed cross of unactivated secondary alkyl halides is based on nickel/bathophenanthroline.4 This method can be applied

  5. Solution Combustion Synthesis Impregnated Layer Combustion Synthesis is a Novel

    E-Print Network [OSTI]

    Mukasyan, Alexander

    Solution Combustion Synthesis Impregnated Layer Combustion Synthesis is a Novel Methodology Engineering University of Notre Dame University of Notre Dame #12;Outline: Overview of combustion synthesis Reaction system Combustion front analaysis Theoretical model results Conclusions Acknowledgements #12

  6. Combustion 2000

    SciTech Connect (OSTI)

    None

    2000-06-30T23:59:59.000Z

    This report presents work carried out under contract DE-AC22-95PC95144 ''Combustion 2000 - Phase II.'' The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: {lg_bullet} thermal efficiency (HHV) {ge} 47% {lg_bullet} NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) {lg_bullet} coal providing {ge} 65% of heat input {lg_bullet} all solid wastes benign {lg_bullet} cost of electricity {le} 90% of present plants Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. Phase II, had as its initial objective the development of a complete design base for the construction and operation of a HIPPS prototype plant to be constructed in Phase III. As part of a descoping initiative, the Phase III program has been eliminated and work related to the commercial plant design has been ended. The rescoped program retained a program of engineering research and development focusing on high temperature heat exchangers, e.g. HITAF development (Task 2); a rescoped Task 6 that is pertinent to Vision 21 objectives and focuses on advanced cycle analysis and optimization, integration of gas turbines into complex cycles, and repowering designs; and preparation of the Phase II Technical Report (Task 8). This rescoped program deleted all subsystem testing (Tasks 3, 4, and 5) and the development of a site specific engineering design and test plan for the HIPPS prototype plant (Task 7). Work reported herein is from: {lg_bullet} Task 2.2.4 Pilot Scale Testing {lg_bullet} Task 2.2.5.2 Laboratory and Bench Scale Activities

  7. Combustion 2000

    SciTech Connect (OSTI)

    A. Levasseur; S. Goodstine; J. Ruby; M. Nawaz; C. Senior; F. Robson; S. Lehman; W. Blecher; W. Fugard; A. Rao; A. Sarofim; P. Smith; D. Pershing; E. Eddings; M. Cremer; J. Hurley; G. Weber; M. Jones; M. Collings; D. Hajicek; A. Henderson; P. Klevan; D. Seery; B. Knight; R. Lessard; J. Sangiovanni; A. Dennis; C. Bird; W. Sutton; N. Bornstein; F. Cogswell; C. Randino; S. Gale; Mike Heap

    2001-06-30T23:59:59.000Z

    This report is a presentation of work carried out on Phase II of the HIPPS program under DOE contract DE-AC22-95PC95144 from June 1995 to March 2001. The objective of this report is to emphasize the results and achievements of the program and not to archive every detail of the past six years of effort. These details are already available in the twenty-two quarterly reports previously submitted to DOE and in the final report from Phase I. The report is divided into three major foci, indicative of the three operational groupings of the program as it evolved, was restructured, or overtaken by events. In each of these areas, the results exceeded DOE goals and expectations. HIPPS Systems and Cycles (including thermodynamic cycles, power cycle alternatives, baseline plant costs and new opportunities) HITAF Components and Designs (including design of heat exchangers, materials, ash management and combustor design) Testing Program for Radiative and Convective Air Heaters (including the design and construction of the test furnace and the results of the tests) There are several topics that were part of the original program but whose importance was diminished when the contract was significantly modified. The elimination of the subsystem testing and the Phase III demonstration lessened the relevance of subtasks related to these efforts. For example, the cross flow mixing study, the CFD modeling of the convective air heater and the power island analysis are important to a commercial plant design but not to the R&D product contained in this report. These topics are of course, discussed in the quarterly reports under this contract. The DOE goal for the High Performance Power Plant System ( HIPPS ) is high thermodynamic efficiency and significantly reduced emissions. Specifically, the goal is a 300 MWe plant with > 47% (HHV) overall efficiency and {le} 0.1 NSPS emissions. This plant must fire at least 65% coal with the balance being made up by a premium fuel such as natural gas. To achieve these objectives requires a change from complete reliance of coal-fired systems on steam turbines (Rankine cycles) and moving forward to a combined cycle utilizing gas turbines (Brayton cycles) which offer the possibility of significantly greater efficiency. This is because gas turbine cycles operate at temperatures well beyond current steam cycles, allowing the working fluid (air) temperature to more closely approach that of the major energy source, the combustion of coal. In fact, a good figure of merit for a HIPPS design is just how much of the enthalpy from coal combustion is used by the gas turbine. The efficiency of a power cycle varies directly with the temperature of the working fluid and for contemporary gas turbines the optimal turbine inlet temperature is in the range of 2300-2500 F (1260-1371 C). These temperatures are beyond the working range of currently available alloys and are also in the range of the ash fusion temperature of most coals. These two sets of physical properties combine to produce the major engineering challenges for a HIPPS design. The UTRC team developed a design hierarchy to impose more rigor in our approach. Once the size of the plant had been determined by the choice of gas turbine and the matching steam turbine, the design process of the High Temperature Advanced Furnace (HITAF) moved ineluctably to a down-fired, slagging configuration. This design was based on two air heaters: one a high temperature slagging Radiative Air Heater (RAH) and a lower temperature, dry ash Convective Air Heater (CAH). The specific details of the air heaters are arrived at by an iterative sequence in the following order:-Starting from the overall Cycle requirements which set the limits for the combustion and heat transfer analysis-The available enthalpy determined the range of materials, ceramics or alloys, which could tolerate the temperatures-Structural Analysis of the designs proved to be the major limitation-Finally the commercialization issues of fabrication and reliability, availability and maintenance. The program that has s

  8. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17T23:59:59.000Z

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  9. Rotary internal combustion engine

    SciTech Connect (OSTI)

    Crittenden, W.

    1987-01-27T23:59:59.000Z

    This patent describes an improved rotary internal combustion engine comprising: (a) a combustion chamber which is generally circular in cross-section and which has a ring-like peripheral wall; (b) a driven shaft member journaled for rotation and disposed to pass eccentrically through the combustion chamber; (c) a compression chamber which is generally circular in cross-section positioned with a ring-like wall is adjacent to and spatially offset with the combustion chamber such that the driven shaft passes centrally therethrough; and (d) a circular combustion rotor fixed concentrically to the shaft member for rotation eccentrically within the combustion chamber. The combustion rotor is positioned such that the space between the periphery of the rotor and the periphery of the combustion chamber results in a crescent shape.

  10. Maintain Combustion Systems

    E-Print Network [OSTI]

    Fletcher, R. J.

    1979-01-01T23:59:59.000Z

    Energy is consumed, and wasted, in liberal amounts in the combustion processes which supply heat energy to boilers and process heaters. Close attention to combustion systems can be extremely beneficial: Optimum air to fuel ratios, i.e., maintaining...

  11. Production of methyl tert-alkyl ethers

    SciTech Connect (OSTI)

    Trofimov, V.A.

    1995-01-01T23:59:59.000Z

    The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

  12. Consider Compressed Combustion

    E-Print Network [OSTI]

    Crowther, R. H.

    1982-01-01T23:59:59.000Z

    sharing systems employing gas turbines. Incentives for compressed combustion have been explored and are presented in this discussion....

  13. Turbulent Combustion Luc Vervisch

    E-Print Network [OSTI]

    Kern, Michel

    ;19 "Perfect" combustion modes: Fuel + Oxidizer () Products Engines, gas turbines... Laboratory experiment1 Turbulent Combustion Modeling Luc Vervisch INSA de Rouen, IUF, CORIA-CNRS Quelques problèmes rencontrés en chimie numérique : Hydrologie - Combustion - Atmosphère 16 décembre, INRIA Rocquencourt #12

  14. Saponification rates of esters in aqueous dioxane

    E-Print Network [OSTI]

    Christian, John Donald

    1952-01-01T23:59:59.000Z

    trimethylacetate Ethyl n-'valerate Ethyl isovalerate Ethyl me thylethyla c e tate Ethyl trimethylacetate k in liter/Cmoles min.) 25? 35? 45? 4.56 9.21 13.6 1.73 3.35 5.56 1.10 2.01 3.50 0.469 0.970 1.51 2.27 4.05 6.65 0.793 1.36 2.18 0.360 0.635 0.............................. .......... 9 Methyl and Ethyl Esters of n-Valeric Acid . . . . 9 Methyl and Ethyl Esters of Isovaleric Acid . . . 10 Methyl and Ethyl Esters of Methylethylacetic A c i d ...................................... 11 Methyl and Ethyl Esters...

  15. Cross-coupling reactions of unactivated alkyl halides

    E-Print Network [OSTI]

    Zhou, Jianrong (Jianrong Steve)

    2005-01-01T23:59:59.000Z

    My graduate research at MIT has been focused on the development of palladium- or nickel-catalyzed cross-coupling reactions using unactivated alkyl electrophiles (e.g., halides and sulfonates). Although aryl and alkenyl ...

  16. Solvation studies on anion radicals of alkyl nitrobenzene derivatives in acetonitrile-alkyl alcohol solvent mixtures at 25 p0 sC

    E-Print Network [OSTI]

    Chu, William Wen-Chen

    1970-01-01T23:59:59.000Z

    SOLVATION STUDIES OM ANION RADICALS QF ALKYL NITROBENZENE DERIVATIVES IN ACETONITRILE- ALKYL ALCOHOL SOLVENT MIXTURES AT PS C A Thesis by WILLIAM WEN CHEN CHU Submitted to the Graduate College of Texas ASM University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1970 Ma)or Sub)oct: Chemistry SOLVATION STUDIES ON ANION RADICALS OF ALKYL NITROBENZENE DERIVATIVES IN ACETONITRILE- ALKYL ALCOHOL SOLVENT MIXTURES AT 25'C A Thesis NILLIAM HEN-CHEN CHU Approved...

  17. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi, Hisashi (Putnam Valley, NY); Bool, III, Lawrence E. (Aurora, NY)

    2008-10-21T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  18. Low NOx combustion

    SciTech Connect (OSTI)

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05T23:59:59.000Z

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  19. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    Ashlines: To promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing.

  20. Sandia National Laboratories: Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion New Polarized-Depolarized Measurement Capability Extends Use of RamanRayleigh Methods to More Flame Types On April 23, 2014, in Capabilities, CRF, Energy, Facilities,...

  1. acidmethyl ester concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Properties and Phase Behavior of 12-tert-Butyl Ester Dendrimer Harmon, Julie P. 62 Modelling Study of the Low-Temperature Oxidation of Large Methyl Esters J. Biet, V. Warth, O....

  2. COMBUSTION SOURCES OF NITROGEN COMPOUNDS

    E-Print Network [OSTI]

    Brown, Nancy J.

    2011-01-01T23:59:59.000Z

    Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

  3. ON THE PURPORTED FISCHER-TROPSCH ALKYLATION OF BENZENE: THE REACTION OF BENZENE WITH ALUMINUM TRICHLORIDE REVISITED

    E-Print Network [OSTI]

    Benner, Linda S.

    2014-01-01T23:59:59.000Z

    ON THE PURPORTED FISCHER-TROPSCH ALKYLATION OF BENZENE: THEOn the Purported Fischer-Tropsch Alkylation of Benzene: TheAbstract The purported Fischer-Tropsch alkylation of benzene

  4. Sandia National Laboratories: combustion simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    combustion simulation Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy,...

  5. Sandia National Laboratories: advanced combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    combustion Sandia and General Motors: Advancing Clean Combustion Engines with Predictive Simulation Tools On February 14, 2013, in CRF, Energy, Partnership, Transportation Energy...

  6. Sandia National Laboratories: Engine Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy, Facilities, News,...

  7. Optimized Algorithms Boost Combustion Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimized Algorithms Boost Combustion Research Optimized Algorithms Boost Combustion Research Methane Flame Simulations Run 6x Faster on NERSC's Hopper Supercomputer November 25,...

  8. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process...

  9. Fifteenth combustion research conference

    SciTech Connect (OSTI)

    NONE

    1993-06-01T23:59:59.000Z

    The BES research efforts cover chemical reaction theory, experimental dynamics and spectroscopy, thermodynamics of combustion intermediates, chemical kinetics, reaction mechanisms, combustion diagnostics, and fluid dynamics and chemically reacting flows. 98 papers and abstracts are included. Separate abstracts were prepared for the papers.

  10. ester Thurow says "what sounds sensible (export

    E-Print Network [OSTI]

    ester Thurow says "what sounds sensible (export more) when heard sepa- rately in each country becomes nonsense when aggregated around the world. No one can have more net exports unless someone else a strong relationship between exports and farm prosperity in the United States. From the early 1900s

  11. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  12. Alkyl phospholipid antihypertensive agents in method of lowering blood pressure

    DOE Patents [OSTI]

    Snyder, Fred L. (Oak Ridge, TN); Blank, Merle L. (Oak Ridge, TN); Muirhead, Ernest E. (Memphis, TN); Leach, deceased, Byron E. (late of Memphis, TN); Byers, Lawrence W. (Memphis, TN)

    1988-01-01T23:59:59.000Z

    The composition of this invention is 1-O-alkyl-2-acetoyl-sn-glycero-3-phosphocholine, having the ionic structural formula; ##STR1## wherein R is saturated alkyl having 9-21 carbon atoms, or salts or hydrates of the composition. Preferably R has 13-19 carbon atoms and most preferably R has 15 carbon atoms. The composition of this invention is useful for reducing hypertension in warm-blooded animals, including humans, when administered either orally or by injection or innoculation, e.g., intravenous injection. The composition can be prepared from naturally occurring lipids or synthetically from commercially available material.

  13. Theoretical studies on hydrogen ignition and droplet combustion

    E-Print Network [OSTI]

    Del Álamo, Gonzalo

    2006-01-01T23:59:59.000Z

    1.2 Droplet Combustion . . . . . . . . . . . . .Combustion . . . . . . . . . . . . . . . . . . . . . . . . . .Lewis, B. and von Elbe, G. Combustion, Flames and Explosions

  14. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines 2012 DOE Hydrogen and Fuel Cells...

  15. Computation of azimuthal combustion instabilities in an helicopter combustion chamber

    E-Print Network [OSTI]

    Nicoud, Franck

    Computation of azimuthal combustion instabilities in an helicopter combustion chamber C. Sensiau to compute azimuthal combustion instabilities is presented. It requires a thermoacoustic model using a n - formulation for the coupling between acoutics and combustion. The parameters n and are computed from a LES

  16. Dry low combustion system with means for eliminating combustion noise

    DOE Patents [OSTI]

    Verdouw, Albert J.; Smith, Duane; McCormick, Keith; Razdan, Mohan K.

    2004-02-17T23:59:59.000Z

    A combustion system including a plurality of axially staged tubular premixers to control emissions and minimize combustion noise. The combustion system includes a radial inflow premixer that delivers the combustion mixture across a contoured dome into the combustion chamber. The axially staged premixers having a twist mixing apparatus to rotate the fluid flow and cause improved mixing without causing flow recirculation that could lead to pre-ignition or flashback.

  17. Sandia Combustion Research: Technical review

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  18. Four Lectures on Turbulent Combustion

    E-Print Network [OSTI]

    Peters, Norbert

    Four Lectures on Turbulent Combustion N. Peters Institut f¨ur Technische Mechanik RWTH Aachen Turbulent Combustion: Introduction and Overview 1 1.1 Moment Methods in Modeling Turbulence with Combustion and Velocity Scales . . . . . . . . . . . 11 1.4 Regimes in Premixed Turbulent Combustion

  19. Sequence specific alkylation of DNA by hairpin pyrroleimidazole polyamide conjugates

    E-Print Network [OSTI]

    Stoltz, Brian M.

    Sequence specific alkylation of DNA by hairpin pyrrole­imidazole polyamide conjugates Nicholas R predetermined sequences in the minor groove of DNA with affinities and specificities comparable to those of DNA for covalent reaction at specific DNA sequences and thereby inhibit DNA­protein interactions. Site

  20. Project Sponsors: UCI Combustion

    E-Print Network [OSTI]

    Mease, Kenneth D.

    of a Commercial Microturbine Generator". 8th U. S. National Combustion Meeting. · R. Hack and V. McDonell. (2008 Microturbine Generator." Journal of Eng. Gas Turb. & Power 130 (1). OVERVIEW Fluid dynamics and chemical

  1. Maintain Combustion Systems 

    E-Print Network [OSTI]

    Fletcher, R. J.

    1979-01-01T23:59:59.000Z

    the lowest excess air possible, for example, can produce big savings. Maintaining combustion equipment - from fuel preparation equipment through burners and controls in optimum operating condition also can save large amounts of energy, and keep a plant...

  2. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01T23:59:59.000Z

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  3. Sandia Combustion Research Program

    SciTech Connect (OSTI)

    Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

    1988-01-01T23:59:59.000Z

    During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

  4. COMBUSTION-GENERATED INDOOR AIR POLLUTION

    E-Print Network [OSTI]

    Hollowell, C.D.

    2011-01-01T23:59:59.000Z

    Pollutants from Indoor Combustion Sources: I. Field Measure-Characteristics in Two Stage Combustion, paper presented atInternational) on Combustion, August, 1974, Tokyo, Japan. 8

  5. Vehicle Technologies Office: 2014 Advanced Combustion Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Annual Progress Report Vehicle Technologies Office: 2014 Advanced Combustion Engine Annual Progress Report The Advanced Combustion Engine research and...

  6. The Combustion Institute 5001 Baum Boulevard

    E-Print Network [OSTI]

    Tennessee, University of

    as applied to fuel cells and fuel processing, and combustion control including artificial neural networks. Fundamentals of micro-combustors, mesoscale combustion modeling and diagnostics, catalytic combustion

  7. Low-Temperature Automotive Diesel Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Automotive Diesel Combustion Light-Duty Combustion Experiments Paul Miles Sandia National Laboratories Light-Duty Combustion Modeling Rolf Reitz University of Wisconsin June 8,...

  8. Internal combustion engine system

    SciTech Connect (OSTI)

    Nam, C.W.

    1987-01-27T23:59:59.000Z

    This patent describes an internal combustion engine system comprising: an engine body including a main combustion engine for transmitting the power generated by explosion pressure to a pumping piston and a power transmission apparatus for transmitting to a power crank shaft power that is increased by the ratio of the cross-sectional area of a combustion chamber piston to a power piston. The stroke distance of the combustion chamber piston is equal to that of the power piston; a swash plate-type stirling engine coupled to an exhaust gas outlet of the main combustion engine to be driven by exhaust heat therefrom; a one-stage screw-type compressor coupled by a driving shaft to the swash plate-type stirling engine, thereby generating a great amount of compressed air; a turbo-charger mounted adjacent to a gas outlet of the stirling engine to force a supply of fresh air into the combustion chamber of the main combustion engine; a booster being mounted between a compressed air source and the power transmission apparatus to amplify the air pressure derived from the compressed air source and then provide the amplified air pressure to the power transmission apparatus by operation of a cam in accordance with the rotation of the first crankshaft; compressed air sources being mounted between the compressor and the booster for storing a great amount of compressed air from the compressor; and an accumulator in communication with the power transmission apparatus through a fluid oil pipe, thereby maintaining constant control of the oil pressure in the power transmission apparatus.

  9. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A. (Idaho Falls, ID); Heaps, Ronald J. (Idaho Falls, ID); Steffler, Eric D (Idaho Falls, ID); Swank, William D. (Idaho Falls, ID)

    2011-08-30T23:59:59.000Z

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  10. Combustible structural composites and methods of forming combustible structural composites

    DOE Patents [OSTI]

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02T23:59:59.000Z

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  11. arrhizus ethyl esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1. Introduction Biodiesel, consisting of the methyl or ethyl ester of fatty acids with biodiesel. To the extent that these deal with biodiesel from virgin vegetable fatty acids,...

  12. Microbial production of wax esters from highly branched alkanes

    DOE Patents [OSTI]

    Bogan, William W.; Sullivan, Wendy R.; Paterek, James R.

    2005-02-01T23:59:59.000Z

    A microbial culture and method for producing wax esters using highly branched alkanes. In accordance with one embodiment, the highly branched alkane is squalane.

  13. Method for reactivating solid catalysts used in alkylation reactions

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Thompson, David N.; Coates, Kyle; Zalewski, David J.; Fox, Robert V.

    2003-06-17T23:59:59.000Z

    A method for reactivating a solid alkylation catalyst is provided which can be performed within a reactor that contains the alkylation catalyst or outside the reactor. Effective catalyst reactivation is achieved whether the catalyst is completely deactivated or partially deactivated. A fluid reactivating agent is employed to dissolve catalyst fouling agents and also to react with such agents and carry away the reaction products. The deactivated catalyst is contacted with the fluid reactivating agent under pressure and temperature conditions such that the fluid reactivating agent is dense enough to effectively dissolve the fouling agents and any reaction products of the fouling agents and the reactivating agent. Useful pressures and temperatures for reactivation include near-critical, critical, and supercritical pressures and temperatures for the reactivating agent. The fluid reactivating agent can include, for example, a branched paraffin containing at least one tertiary carbon atom, or a compound that can be isomerized to a molecule containing at least one tertiary carbon atom.

  14. Fluidized-bed combustion

    SciTech Connect (OSTI)

    Botros, P E

    1990-04-01T23:59:59.000Z

    This report describes the activities of the Morgantown Energy Technology Center's research and development program in fluidized-bed combustion from October 1, 1987, to September 30, 1989. The Department of Energy program involves atmospheric and pressurized systems. Demonstrations of industrial-scale atmospheric systems are being completed, and smaller boilers are being explored. These systems include vortex, multi-solid, spouted, dual-sided, air-cooled, pulsed, and waste-fired fluidized-beds. Combustion of low-rank coal, components, and erosion are being studied. In pressurized combustion, first-generation, combined-cycle power plants are being tested, and second-generation, advanced-cycle systems are being designed and cost evaluated. Research in coal devolatilization, metal wastage, tube corrosion, and fluidization also supports this area. 52 refs., 24 figs., 3 tabs.

  15. Internal combustion engine

    DOE Patents [OSTI]

    Baker, Quentin A. (P.O. Box 6477, San Antonio, TX 78209); Mecredy, Henry E. (1630-C W. 6th, Austin, TX 78703); O'Neal, Glenn B. (6503 Wagner Way, San Antonio, TX 78256)

    1991-01-01T23:59:59.000Z

    An improved engine is provided that more efficiently consumes difficult fuels such as coal slurries or powdered coal. The engine includes a precombustion chamber having a portion thereof formed by an ignition plug. The precombustion chamber is arranged so that when the piston is proximate the head, the precombustion chamber is sealed from the main cylinder or the main combustion chamber and when the piston is remote from the head, the precombustion chamber and main combustion chamber are in communication. The time for burning of fuel in the precombustion chamber can be regulated by the distance required to move the piston from the top dead center position to the position wherein the precombustion chamber and main combustion chamber are in communication.

  16. Development of Advanced Combustion Technologies for Increased...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Technologies for Increased Thermal Efficiency Development of Advanced Combustion Technologies for Increased Thermal Efficiency Investigation of fuel effects on...

  17. Stretch Efficiency - Thermodynamic Analysis of New Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037) Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037)...

  18. Transonic Combustion ? - Injection Strategy Development for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transonic Combustion - Injection Strategy Development for Supercritical Gasoline Injection-Ignition in a Light Duty Engine Transonic Combustion - Injection Strategy...

  19. Enhancing Transportation Energy Security through Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Energy Security through Advanced Combustion and Fuels Technologies Enhancing Transportation Energy Security through Advanced Combustion and Fuels Technologies 2005...

  20. Improving alternative fuel utilization: detailed kinetic combustion...

    Energy Savers [EERE]

    Improving alternative fuel utilization: detailed kinetic combustion modeling & experimental testing Improving alternative fuel utilization: detailed kinetic combustion modeling &...

  1. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19T23:59:59.000Z

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  2. Studies in combustion dynamics

    SciTech Connect (OSTI)

    Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  3. A Continuous Homologation of Esters: An Efficient Telescoped Reduction–Olefination Sequence

    E-Print Network [OSTI]

    Webb, Damien

    A continuous protocol for the two-carbon homologation of esters to ?,?-unsaturated esters is described. This multireactor homologation telescopes an ester reduction, phosphonate deprotonation, and Horner–Wadsworth–Emmons ...

  4. Reversed flow fluidized-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Mei, Joseph S. (Morgantown, WV); Wilson, John S. (Morgantown, WV)

    1984-01-01T23:59:59.000Z

    The present invention is directed to a fluidized-bed combustion apparatus provided with a U-shaped combustion zone. A cyclone is disposed in the combustion zone for recycling solid particulate material. The combustion zone configuration and the recycling feature provide relatively long residence times and low freeboard heights to maximize combustion of combustible material, reduce nitrogen oxides, and enhance sulfur oxide reduction.

  5. Packed Bed Combustion: An Overview

    E-Print Network [OSTI]

    Hallett, William L.H.

    Packed Bed Combustion: An Overview William Hallett Dept. of Mechanical Engineering Université d'Ottawa - University of Ottawa #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Introduction air fuel feedproducts xbed grate Packed Bed Combustion: fairly large particles of solid fuel on a grate, air supplied

  6. Combustion Models in Finance

    E-Print Network [OSTI]

    C. Tannous; A. Fessant

    2001-01-07T23:59:59.000Z

    Combustion reaction kinetics models are used for the description of a special class of bursty Financial Time Series. The small number of parameters they depend upon enable financial analysts to predict the time as well as the magnitude of the jump of the value of the portfolio. Several Financial Time Series are analysed within this framework and applications are given.

  7. Combustion of black liquor

    SciTech Connect (OSTI)

    Mullen, W.T.

    1989-08-15T23:59:59.000Z

    This patent describes an improvement in the combustion of black liquor in an existing Tomlison recovery boiler unit in which black liquor is sprayed into a furnace in which it is successively dried, pyrolyzed and converted to a bed of solid carbonaceous residue, using a primary air stream and a secondary air stream and the residue is subsequently converted to a smelt. The improvement comprises: the addition of between an effective amount up to 5% oxygen by volume to the primary air stream directed at the bed of solid carbonaceous residue, the amount of oxygen added being sufficient to increase the adiabatic flame temperature, the combustion rate of the solid carbonaceous material, the rate of pyrolysis, the temperature in the lower portion of the furnace, the the drying rate of black liquor droplets, and to decrease the temperature of the gases entering the heat transfer surfaces in the upper portion of the furnace and the rate of deposit formation on the surfaces and wherein the amount of black liquor combusted is increased as compared with the amount combusted in the same furnace operated without the addition of oxygen to the primary air.

  8. Combined Cycle Combustion Turbines

    E-Print Network [OSTI]

    Combined Cycle Combustion Turbines Steven Simmons February 27 2014 1 #12;CCCT Today's Discussion 1 Meeting Pricing of 4 advanced units using information from Gas Turbine World Other cost estimates from E E3 EIA Gas Turbine World California Energy Commission Date 2010 Oct 2012, Dec 2013 Apr 2013 2013 Apr

  9. Fragments, Combustion and Earthquakes

    E-Print Network [OSTI]

    Oscar Sotolongo-Costa; Antonio Posadas

    2005-03-16T23:59:59.000Z

    This paper is devoted to show the advantages of introducing a geometric viewpoint and a non extensive formulation in the description of apparently unrelated phenomena: combustion and earthquakes. Here, it is shown how the introduction of a fragmentation analysis based on that formulation leads to find a common point for description of these phenomena

  10. Preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters

    DOE Patents [OSTI]

    Gogate, Makarand Ratnakar (Durham, NC); Spivey, James Jerry (Cary, NC); Zoeller, Joseph Robert (Kingsport, TN)

    1998-01-01T23:59:59.000Z

    Disclosed is a process for the preparation of .alpha.,.beta.-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

  11. Preparation of {alpha},{beta}-unsaturated carboxylic acids and esters

    DOE Patents [OSTI]

    Gogate, M.R.; Spivey, J.J.; Zoeller, J.R.

    1998-09-15T23:59:59.000Z

    Disclosed is a process for the preparation of {alpha},{beta}-unsaturated carboxylic acids and esters thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic acid, ester or anhydride in the presence of a catalyst comprising an oxide of niobium.

  12. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-01T23:59:59.000Z

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  13. Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions

    E-Print Network [OSTI]

    Lu, Zhe

    2010-01-01T23:59:59.000Z

    Part I describes the expansion in scope of a nickel-catalyzed coupling reaction of unactivated alkyl bromides and alkyl boranes to include unactivated alkyl chlorides. The new method is adapted for use outside of a glove ...

  14. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Energy Savers [EERE]

    Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Presentation from the U.S....

  15. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Applied low temperature combustion to the Navistar...

  16. Low-Temperature Combustion Demonstrator for High-Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion 2010 DOE Vehicle...

  17. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion 2009 DOE Hydrogen Program...

  18. Fuel Effects on Mixing-Controlled Combustion Strategies for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion...

  19. Assessment of Combustion and Turbulence Models for the Simulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Turbulence Models for the Simulation of Combustion Processes in a DI Diesel Engine Assessment of Combustion and Turbulence Models for the Simulation of Combustion...

  20. Advanced Combustion Technology to Enable High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology to Enable High Efficiency Clean Combustion Advanced Combustion Technology to Enable High Efficiency Clean Combustion Summary of advanced combustion research at Cummins...

  1. COMBUSTION RESEARCH PROGRAM. CHAPTER FROM ENERGY & ENVIRONMENT ANNUAL REPORT 1977

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    of Combustion in Internal Combustion Engines," Paper 750890,clean burning internal combustion engines. Another importantthat occur in an internal combustion engine. Our goal is the

  2. Internal combustion engine using premixed combustion of stratified charges

    DOE Patents [OSTI]

    Marriott, Craig D. (Rochester Hills, MI); Reitz, Rolf D. (Madison, WI

    2003-12-30T23:59:59.000Z

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  3. The Diesel Combustion Collaboratory: Combustion Researchers Collaborating over the Internet

    SciTech Connect (OSTI)

    C. M. Pancerella; L. A. Rahn; C. Yang

    2000-02-01T23:59:59.000Z

    The Diesel Combustion Collaborator (DCC) is a pilot project to develop and deploy collaborative technologies to combustion researchers distributed throughout the DOE national laboratories, academia, and industry. The result is a problem-solving environment for combustion research. Researchers collaborate over the Internet using DCC tools, which include: a distributed execution management system for running combustion models on widely distributed computers, including supercomputers; web-accessible data archiving capabilities for sharing graphical experimental or modeling data; electronic notebooks and shared workspaces for facilitating collaboration; visualization of combustion data; and video-conferencing and data-conferencing among researchers at remote sites. Security is a key aspect of the collaborative tools. In many cases, the authors have integrated these tools to allow data, including large combustion data sets, to flow seamlessly, for example, from modeling tools to data archives. In this paper the authors describe the work of a larger collaborative effort to design, implement and deploy the DCC.

  4. Combustion powered linear actuator

    DOE Patents [OSTI]

    Fischer, Gary J. (Albuquerque, NM)

    2007-09-04T23:59:59.000Z

    The present invention provides robotic vehicles having wheeled and hopping mobilities that are capable of traversing (e.g. by hopping over) obstacles that are large in size relative to the robot and, are capable of operation in unpredictable terrain over long range. The present invention further provides combustion powered linear actuators, which can include latching mechanisms to facilitate pressurized fueling of the actuators, as can be used to provide wheeled vehicles with a hopping mobility.

  5. IR-laser initiated combustion -- A step toward complete combustion

    SciTech Connect (OSTI)

    Laghai, A.; Nabavi, S.H.; Servati, H.B.; Syed, F.

    1996-09-01T23:59:59.000Z

    The new global environmental regulations for reducing the engine emissions from both moving and stationary sources, as well as improvement in fuel economy are the major motifs to obtain a perfect combustion process and exhaust aftertreatment methods. Infrared (IR)-Laser initiated combustion provides a very high initial temperature, which produces propagation of a turbulent thermopressure pulse that results in a fast burning and improved combustion. The role of IR is to maximize the heat generation efficiency.

  6. Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation

    E-Print Network [OSTI]

    Zhang, Xumu

    Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system

  7. A Practical and Highly Stereoselective Umpolung Alternative to the Alkylation of Chiral Enolates

    E-Print Network [OSTI]

    Spino, Claude

    , acetates, carbonates, and epoxides.9,10 Thus, in principle, the displacement reaction of a chiral allyl reactive electrophiles such as methyl, ethyl, and some primary alkyl iodides and benzyl or allyl halides. s-silyl ketene acetals, and s-alkyl electrophiles are poor electrophiles with this method.7,8 In this paper, we

  8. Cleavage of Carbon-Carbon Bonds in Alkyl Cyanides Using Nickel(0)

    E-Print Network [OSTI]

    Jones, William D.

    Cleavage of Carbon-Carbon Bonds in Alkyl Cyanides Using Nickel(0) Juventino J. Garci´a,*, Alma Are of alkyl cyanides afforded nickel(0) compounds of the type [(dippe)Ni(2 -RCN)], where R ) Me, Et, Pr, i Pr cyanides using [(dippe)NiH]2, leading to the formation of an 2- nitrile complex of nickel(0), which

  9. Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic applications

    E-Print Network [OSTI]

    Nabben, Reinhard

    Assembly of carbon nanotubes and alkylated fullerenes: nanocarbon hybrid towards photovoltaic and a fullerene (C60) derivative with long alkyl chains was constructed as a donor­acceptor pair for photovoltaics as attractive candidates for the development of light- energy harvesting and photovoltaic materials because

  10. Sequence Specificity of DNA Alkylation by the Antitumor Natural Product Leinamycin

    E-Print Network [OSTI]

    Gates, Kent. S.

    Sequence Specificity of DNA Alkylation by the Antitumor Natural Product Leinamycin Hong Zang. The sequence specificity for DNA alkylation by this structurally novel compound has not previously been at the 5-G in 5-GG and 5-GT sequences. The sequence preferences for activated leinamycin are significantly

  11. Sandia National Laboratories: combustion science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    science Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy, Facilities, News, News...

  12. Sandia National Laboratories: combustion intermediates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intermediates Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy, Facilities,...

  13. Sandia National Laboratories: combustion modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modeling Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy, Facilities, News,...

  14. Light Duty Efficient Clean Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficient Clean Combustion February 27, 2008 Tim Frazier Research & Technology 2008 Semi-Mega Merit Review Agenda Project Goals and Objectives Project Partners Technical...

  15. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

  16. Enabling High Efficiency Clean Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Clean Combustion 2008 Semi-Mega Merit Review Donald Stanton Research & Technology February 26 th , 2008 This presentation does not contain any proprietary or...

  17. Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Position in Direct Numerical Simulations of Low-Dimensional Reacting Flows The Combustion EFRC seeks outstanding applicants for the position of post-doctoral research...

  18. Improve Your Boiler's Combustion Efficiency

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on boiler combustion efficiency provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  19. Numerical Modeling of HCCI Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Numerical Modeling of HCCI Combustion Salvador M. Aceves, Daniel L. Flowers, J. Ray Smith, Joel Martinez-Frias, Francisco Espinosa-Loza, Tim Ross, Bruce Buchholz, Nick...

  20. Sandia National Laboratories: combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  1. COMBUSTION SOURCES OF NITROGEN COMPOUNDS

    E-Print Network [OSTI]

    Brown, Nancy J.

    2011-01-01T23:59:59.000Z

    however, in combustion processes using crude oil, coal andcombustion processes increases with nitrogen content of the fuel, TABLE 1 Typical Nitrogen Content of Fuels Reference Fuel Crude Oil

  2. Sandia National Laboratories: Diesel Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diesel Combustion Caterpillar, Sandia CRADA Opens Door to Multiple Research Projects On April 17, 2013, in Capabilities, Computational Modeling & Simulation, CRF, Materials...

  3. Fuels for Advanced Combustion Engines

    Broader source: Energy.gov (indexed) [DOE]

    Fuels for Advanced Combustion Engines Bradley T. Zigler National Renewable Energy Laboratory 15 May 2012 Project ID FT002 This presentation does not contain any proprietary,...

  4. acid methyl esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  5. acid ester homologs: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  6. acid methyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 (> 170 o C). Each fraction was analyzed composition of fatty acid ethyl esters using gas chromatography (GC). The result showed that the yield medium chain fatty acid ethyl...

  7. Diagnostics for the Combustion Science Workbench

    E-Print Network [OSTI]

    Grcar, J.F.; Day, M.S.; Bell, J.B.

    2007-01-01T23:59:59.000Z

    2005) 10006–10011. 5 th US Combustion Meeting – Paper # D09and D. A. Gousis. Combustion and Flame, 117 (1999) 685–4] I. Glassman. Combustion. Academic Press, third edition,

  8. COMBUSTION-GENERATED INDOOR AIR POLLUTION

    E-Print Network [OSTI]

    Hollowell, C.D.

    2010-01-01T23:59:59.000Z

    x A Emission Characteristics in Two Stage Combustion. PaperInternational) on Combustion, Tokyo (August, 1974). Chang,fll , J I ___F J "J LBL-S9lS COMBUSTION-GENERATED INDOOR AIR

  9. Preparation and recovery of methacrylic acid and its esters

    SciTech Connect (OSTI)

    Frank, P.J.; Hite, J.R.

    1986-07-15T23:59:59.000Z

    This patent describes a process for the vapor phase catalytic oxydehydrogenation of isobutyric acid or its esters to form methacrylic acid or its esters wherein the gaseous product is condensed and purified. The improvement described here consists of adding to the gaseous product at or about the point of its condensation from 1 to 6000 ppm of a surfactant material selected from the group consisting of an anionic a cationic and non-ionic surfactant.

  10. The Role of Comprehensive Detailed Chemical Kinetic Reaction Mechanisms in Combustion Research

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

    2008-07-16T23:59:59.000Z

    Recent developments by the authors in the field of comprehensive detailed chemical kinetic reaction mechanisms for hydrocarbon fuels are reviewed. Examples are given of how these mechanisms provide fundamental chemical insights into a range of combustion applications. Practical combustion consists primarily of chemical heat release from reactions between a fuel and an oxidizer, and computer simulations of practical combustion systems have become an essential tool of combustion research (Westbrook et al., 2005). At the heart of most combustion simulations, the chemical kinetic submodel frequently is the most detailed, complex and computationally costly part of a system model. Historically, the chemical submodel equations are solved using time-implicit numerical algorithms, due to the extreme stiffness of the coupled rate equations, with a computational cost that varies roughly with the cube of the number of chemical species in the model. While early mechanisms (c. 1980) for apparently simple fuels such as methane (Warnatz, 1980) or methanol (Westbrook and Dryer, 1979) included perhaps 25 species, current detailed mechanisms for much larger, more complex fuels such as hexadecane (Fournet et al., 2001; Ristori et al., 2001; Westbrook et al., 2008) or methyl ester methyl decanoate (Herbinet et al., 2008) have as many as 2000 or even 3000 species. Rapid growth in capabilities of modern computers has been an essential feature in this rapid growth in the size and complexity of chemical kinetic reaction mechanisms.

  11. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  12. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

    2008-08-31T23:59:59.000Z

    Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

  13. Lagrangian Simulation of Combustion

    SciTech Connect (OSTI)

    Ahmed F. Ghoniem

    2008-05-01T23:59:59.000Z

    A Lagrangian approach for the simulation of reactive flows has been developed during the course of this project, and has been applied to a number of significant and challenging problems including the transverse jet simulations. An efficient strategy for parallel domain decomposition has also been developed to enable the implementation of the approach on massively parallel architecture. Since 2005, we focused our efforts on the development of a semi-Lagrangian treatment of diffusion, and fast and accurate Lagrangian simulation tools for multiphysics problems including combustion.

  14. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01T23:59:59.000Z

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  15. Microwave-Assisted Ignition for Improved Internal Combustion Engine Efficiency

    E-Print Network [OSTI]

    DeFilippo, Anthony Cesar

    2013-01-01T23:59:59.000Z

    Gas-Phase Combustion .41 Gas-Phase combustionfor traditional gas- phase combustion modeling are presented

  16. Sandia National Laboratories: control early combustion stages

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control early combustion stages Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF,...

  17. Sandia National Laboratories: direct measurement of combustion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    direct measurement of combustion intermediate Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling &...

  18. Premix charge, compression ignition combustion system optimization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Premix charge, compression ignition combustion system optimization Premix charge, compression ignition combustion system optimization Presentation given at DEER 2006, August 20-24,...

  19. Advanced Computational Methods for Turbulence and Combustion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Computational Methods for Turbulence and Combustion Advanced Computational Methods for Turbulence and Combustion Bell.png Key Challenges: Development and application of...

  20. H2 ICE Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2 ICE Combustion Share Description Hydrogen combustion inside a direct injection H2 engine Topic Energy Energy efficiency Vehicles Hydrogen & fuel cells Credit S. Ciatti This...

  1. TURBULENT FRBRNNING MVK130 Turbulent Combustion

    E-Print Network [OSTI]

    TURBULENT FÖRBRÄNNING MVK130 Turbulent Combustion Poäng: 3.0 Betygskala: TH Valfri för: M4 to combustion, McGraw-Hill 1996. #12;

  2. Thermodynamic Advantages of Low Temperature Combustion Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use...

  3. Improved Solvers for Advanced Engine Combustion Simulation

    Broader source: Energy.gov [DOE]

    Document:  ace076_mcnenly_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Matthew McNenlyPresenting Organization: Lawrence Livermore National Laboratory ...

  4. H2 Internal Combustion Engine Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H 2 Internal Combustion Engine Research* H Internal Combustion Engine Research 2 Thomas Wallner Argonne National Laboratory 2008 DOE Merit Review Bethesda, Maryland February 25 th...

  5. Hydrogen engine and combustion control process

    DOE Patents [OSTI]

    Swain, Michael R. (Coral Gables, FL); Swain, Matthew N. (Miami, FL)

    1997-01-01T23:59:59.000Z

    Hydrogen engine with controlled combustion comprises suction means connected to the crankcase reducing or precluding flow of lubricating oil or associated gases into the combustion chamber.

  6. Improved Solvers for Advanced Engine Combustion Simulation |...

    Broader source: Energy.gov (indexed) [DOE]

    Improved Solvers for Advanced Engine Combustion Simulation Improved Solvers for Advanced Engine Combustion Simulation 2013 DOE Hydrogen and Fuel Cells Program and Vehicle...

  7. Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nozzle Flow, Spray, Combustion, & Emission Modeling using KH-ACT Primary Breakup Model & Detailed Chemistry Integrated Nozzle Flow, Spray, Combustion, & Emission Modeling using...

  8. Progress of the Engine Combustion Network

    Broader source: Energy.gov (indexed) [DOE]

    the Progress of the Engine Combustion Network Engine Combustion Network Lyle M. Pickett Sandia National Laboratories Sponsor: DOE Office of Vehicle Technologies Program Manager:...

  9. Optimization of Advanced Diesel Engine Combustion Strategies

    Broader source: Energy.gov (indexed) [DOE]

    - UW-ERC 1 "University Research in Advanced Combustion and Emissions Control" Optimization of Advanced Diesel Engine Combustion Strategies Profs. Rolf Reitz, D. Foster, J....

  10. Optimization of Advanced Diesel Engine Combustion Strategies...

    Broader source: Energy.gov (indexed) [DOE]

    Optimization of Advanced Diesel Engine Combustion Strategies Optimization of Advanced Diesel Engine Combustion Strategies 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  11. Sandia National Laboratories: predictive engine spray combustion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    predictive engine spray combustion modeling Sandia Expands an International Collaboration and Web Database on Engine Fuel Spray Combustion Research On November 13, 2012, in CRF,...

  12. Sandia National Laboratories: spray combustion model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spray combustion model Sandia Expands an International Collaboration and Web Database on Engine Fuel Spray Combustion Research On November 13, 2012, in CRF, Energy, Energy...

  13. Sandia National Laboratories: Combustion Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Behavior On June 13, 2014, in Turbulent Combustion Laboratory The Turbulent Combustion Laboratory (TCL) provides a well-controlled, lab-scale environment for testing...

  14. Sandia National Laboratories: Combustion Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    amount of excess air or recirculated exhaust gas that is compressed in the combustion chamber until it autoignites. The resulting combustion is a flameless and...

  15. Sandia National Laboratories: Silver Combustion Medal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silver Combustion Medal Two CRF Papers Named "Distinguished" for 34th International Symposium on Combustion On October 22, 2013, in Computational Modeling & Simulation, CRF,...

  16. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  17. Multi-phase Combustion and Transport Processes Under the Influence of Acoustic Excitation

    E-Print Network [OSTI]

    Wegener, Jeffrey Lewis

    2014-01-01T23:59:59.000Z

    Fuel Droplet Combustion . . . . . . . . . . . . . . . . .Droplet Combustion . . . . . . . . . . . . . . . . . .on Fuel Droplet Combustion . . . . . . . . . . Shear-Coaxial

  18. Droplet Combustion and Non-Reactive Shear-Coaxial Jets with Transverse Acoustic Excitation

    E-Print Network [OSTI]

    Teshome, Sophonias

    2012-01-01T23:59:59.000Z

    Related Works in Droplet Combustion . . . . . . . .of Acoustics on Droplet Combustion . . . . . . . . . . . .Fuel Droplet Combustion . . . . . . . . . . . . . . .

  19. Twenty-Seventh Symposium (International) on Combustion/The Combustion Institute, 1998/pp. 28152820 FINGERING INSTABILITY IN SOLID FUEL COMBUSTION

    E-Print Network [OSTI]

    Moses, Elisha

    2815 Twenty-Seventh Symposium (International) on Combustion/The Combustion Institute, 1998/pp. 2815­2820 FINGERING INSTABILITY IN SOLID FUEL COMBUSTION: THE CHARACTERISTIC SCALES OF THE DEVELOPED STATE ORY ZIK, Israel We present new results on the fingering instability in solid fuel combustion. The instability

  20. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08T23:59:59.000Z

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  1. Synthesis, droplet combustion, and sooting characteristics of biodiesel produced from waste vegetable oils

    SciTech Connect (OSTI)

    Li, T. X.; Zhu, D. L.; Akafuah, N.; Saito, K.; Law, C. K.

    2011-01-01T23:59:59.000Z

    In light of the potential of fatty acid methyl ester (FAME, i.e. biodiesel) as a renewable energy source, an innovative acid catalyzed process was developed for the synthesis of biodiesel from waste vegetable oils. The synthesized biodiesels were analytically characterized for their major components, molar fraction and molecular weight of each component, the average molecular weight, and the heat of combustion. Their droplet combustion characteristics in terms of the burning rate, flame size, and sooting tendency were subsequently determined in a high-temperature, freely-falling droplet apparatus. Results show that the biodiesel droplet has higher burning rate, and that biodiesel in general has a lower propensity to soot because its molecular oxygen content promotes the oxidation of the soot precursors.

  2. Stretch Efficiency for Combustion Engines: Exploiting New Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    portfolio: - long term, high risk approaches for reducing thermodynamic losses in combustion Fuel Efficiency 40-42% Losses 58-60% Fuel Efficiency 50-60% Losses 40-50% Today's...

  3. Combustion-gas recirculation system

    DOE Patents [OSTI]

    Baldwin, Darryl Dean (Lacon, IL)

    2007-10-09T23:59:59.000Z

    A combustion-gas recirculation system has a mixing chamber with a mixing-chamber inlet and a mixing-chamber outlet. The combustion-gas recirculation system may further include a duct connected to the mixing-chamber inlet. Additionally, the combustion-gas recirculation system may include an open inlet channel with a solid outer wall. The open inlet channel may extend into the mixing chamber such that an end of the open inlet channel is disposed between the mixing-chamber inlet and the mixing-chamber outlet. Furthermore, air within the open inlet channel may be at a pressure near or below atmospheric pressure.

  4. Generating Resources Combined Cycle Combustion Turbine

    E-Print Network [OSTI]

    11/17/2014 1 Generating Resources Combined Cycle Combustion Turbine Utility Scale Solar PV Steven doing recently around two key supply-side resource technologies 1. Combined Cycle Combustion Turbine #12;11/17/2014 4 Combined Cycle Combustion Turbine Background Primary Components Gas-fired combustion

  5. COMBUSTION SYNTHESIS OF ADVANCED MATERIALS: PRINCIPLESAND APPLICATIONS

    E-Print Network [OSTI]

    Mukasyan, Alexander

    COMBUSTION SYNTHESIS OF ADVANCED MATERIALS: PRINCIPLESAND APPLICATIONS Arvind Varma, Alexander S. Gasless Combustion SynthesisFrom Elements B. Combustion Synthesis in Gas-Solid Systems C. Products of Thermite-vpe SHS D. Commercial Aspects IV. Theoretical Considerations A. Combustion Wave Propagation Theory

  6. COMBUSTION ISSUES AND APPROACHES FOR CHEMICAL MICROTHRUSTERS

    E-Print Network [OSTI]

    Yang, Vigor

    1 COMBUSTION ISSUES AND APPROACHES FOR CHEMICAL MICROTHRUSTERS Richard A. Yetter, Vigor Yang, Ming and the effects of downsizing on combustion performance. In particular, combustion of liquid nitromethane in a thruster combustion chamber with a volume of 108 mm3 and diameter of 5 mm was experimentally investigated

  7. Residential Wood Residential wood combustion (RWC) is

    E-Print Network [OSTI]

    Residential Wood Combustion Residential wood combustion (RWC) is increasing in Europe because PM2.5. Furthermore, other combustion- related sources of OA in Europe may need to be reassessed. Will it affect global OA emission estimates? Combustion of biofuels is globally one of the major OA sources

  8. Intramolecular Heck couplings of unactivated alkyl electrophiles : synthetic and mechanistic studies

    E-Print Network [OSTI]

    Firmansjah, Luke

    2007-01-01T23:59:59.000Z

    A method for the palladium-catalyzed intramolecular Heck coupling of unactivated alkyl bromides and chlorides is described. The optimal catalyst system was composed of Pd2(MeO-dba)3 as the metal source and N-heterocyclic ...

  9. Use of Methionine Alkylation to Prepare Cationic and Zwitterionic Block Copolypeptide Vesicles

    E-Print Network [OSTI]

    Rodriguez, AR; Choe, U-J; Kamei, DT; Deming, TJ

    2015-01-01T23:59:59.000Z

    poly(L-methionine) 65 -block- poly(L-leucine 0.5 -stat-L-phenylalanine 0.5 ) 20 , M65 (L 0.5 /F 0.5 ) 20 , by its direct alkylation in water

  10. Reducing mode circulating fluid bed combustion

    DOE Patents [OSTI]

    Lin, Yung-Yi (Katy, TX); Sadhukhan, Pasupati (Katy, TX); Fraley, Lowell D. (Sugarland, TX); Hsiao, Keh-Hsien (Houston, TX)

    1986-01-01T23:59:59.000Z

    A method for combustion of sulfur-containing fuel in a circulating fluid bed combustion system wherein the fuel is burned in a primary combustion zone under reducing conditions and sulfur captured as alkaline sulfide. The reducing gas formed is oxidized to combustion gas which is then separated from solids containing alkaline sulfide. The separated solids are then oxidized and recycled to the primary combustion zone.

  11. Optimizing Low Temperature Diesel Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Consortium 2008 DOE Merit Review - UW-ERC 1 Optimizing Low Temperature Diesel Combustion Profs. Rolf Reitz, P. Farrell, D. Foster, J. Ghandhi, C. Rutland, S. Sanders Engine...

  12. Predictive modeling of combustion processes

    E-Print Network [OSTI]

    Sharma, Sandeep, Ph. D. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    Recently, there has been an increasing interest in improving the efficiency and lowering the emissions from operating combustors, e.g. internal combustion (IC) engines and gas turbines. Different fuels, additives etc. are ...

  13. Combustion Science for Cleaner Fuels

    SciTech Connect (OSTI)

    Ahmed, Musahid

    2014-10-17T23:59:59.000Z

    Musahid Ahmed discusses how he and his team use the Advanced Light Source (ALS) to study combustion chemistry at our '8 Big Ideas' Science at the Theater event on October 8th, 2014, in Oakland, California.

  14. High Efficiency, Clean Combustion

    SciTech Connect (OSTI)

    Donald Stanton

    2010-03-31T23:59:59.000Z

    Energy use in trucks has been increasing at a faster rate than that of automobiles within the U.S. transportation sector. According to the Energy Information Administration (EIA) Annual Energy Outlook (AEO), a 23% increase in fuel consumption for the U.S. heavy duty truck segment is expected between 2009 to 2020. The heavy duty vehicle oil consumption is projected to grow between 2009 and 2050 while light duty vehicle (LDV) fuel consumption will eventually experience a decrease. By 2050, the oil consumption rate by LDVs is anticipated to decrease below 2009 levels due to CAFE standards and biofuel use. In contrast, the heavy duty oil consumption rate is anticipated to double. The increasing trend in oil consumption for heavy trucks is linked to the vitality, security, and growth of the U.S. economy. An essential part of a stable and vibrant U.S. economy is a productive U.S. trucking industry. Studies have shown that the U.S. gross domestic product (GDP) is strongly correlated to freight transport. Over 90% of all U.S. freight tonnage is transported by diesel power and over 75% is transported by trucks. Given the vital role that the trucking industry plays in the economy, improving the efficiency of the transportation of goods was a central focus of the Cummins High Efficient Clean Combustion (HECC) program. In a commercial vehicle, the diesel engine remains the largest source of fuel efficiency loss, but remains the greatest opportunity for fuel efficiency improvements. In addition to reducing oil consumption and the dependency on foreign oil, this project will mitigate the impact on the environment by meeting US EPA 2010 emissions regulations. Innovation is a key element in sustaining a U.S. trucking industry that is competitive in global markets. Unlike passenger vehicles, the trucking industry cannot simply downsize the vehicle and still transport the freight with improved efficiency. The truck manufacturing and supporting industries are faced with numerous challenges to reduce oil consumption and greenhouse gases, meet stringent emissions regulations, provide customer value, and improve safety. The HECC program successfully reduced engine fuel consumption and greenhouse gases while providing greater customer valve. The US EPA 2010 emissions standard poses a significant challenge for developing clean diesel powertrains that meet the DoE Vehicle Technologies Multi-Year Program Plan (MYPP) for fuel efficiency improvement while remaining affordable. Along with exhaust emissions, an emphasis on heavy duty vehicle fuel efficiency is being driven by increased energy costs as well as the potential regulation of greenhouse gases. An important element of the success of meeting emissions while significantly improving efficiency is leveraging Cummins component technologies such as fuel injection equipment, aftertreatment, turbomahcinery, electronic controls, and combustion systems. Innovation in component technology coupled with system integration is enabling Cummins to move forward with the development of high efficiency clean diesel products with a long term goal of reaching a 55% peak brake thermal efficiency for the engine plus aftertreatment system. The first step in developing high efficiency clean products has been supported by the DoE co-sponsored HECC program. The objectives of the HECC program are: (1) To design and develop advanced diesel engine architectures capable of achieving US EPA 2010 emission regulations while improving the brake thermal efficiency by 10% compared to the baseline (a state of the art 2007 production diesel engine). (2) To design and develop components and subsystems (fuel systems, air handling, controls, etc) to enable construction and development of multi-cylinder engines. (3) To perform an assessment of the commercial viability of the newly developed engine technology. (4) To specify fuel properties conducive to improvements in emissions, reliability, and fuel efficiency for engines using high-efficiency clean combustion (HECC) technologies. To demonstrate the technology is compatible with B2

  15. Combustion method for simultaneous control of nitrogen oxides and products of incomplete combustion

    SciTech Connect (OSTI)

    Ho, Min-Da.

    1993-05-25T23:59:59.000Z

    A method is described for combusting material with controlled generation of both nitrogen oxides and products of incomplete combustion comprising: (A) combusting material in a first combustion zone to produce gaseous exhaust containing products of incomplete combustion and products of complete combustion; (B) passing the gaseous exhaust from the first combustion zone into a second combustion zone having a width and an axial direction; (C) injecting through a lance with an orientation substantially parallel to said axial direction at least one stream of oxidant, without fuel, having a diameter less than 1/100 of the width of the second combustion zone and having an oxygen concentration of at least 30% into the second combustion zone at a high velocity of at least 300 feet per second; (D) aspirating products of incomplete combustion into the high velocity oxidant; (E) combusting products of incomplete combustion aspirated into the high velocity oxidant with high velocity oxidant within the second combustion zone to carry out a stable combustion by the mixing of the aspirated products of incomplete combustion with the high velocity oxidant; and (F) spreading out the combustion reaction by aspiration of products of complete combustion into the oxidant, said products of complete combustion also serving as a heat sink, to inhibit NO[sub x] formation.

  16. Modelling paradigms for MILD combustion

    E-Print Network [OSTI]

    Minamoto, Y.; Swaminathan, N.

    2014-04-26T23:59:59.000Z

    agreement because it does not include the effects of reaction zone interactions. Keywords: MILD combustion, Flameless combustion, Direct numerical simulation (DNS), Perfectly stirred reactor (PSR), presumed PDF, LES, RANS, Modelling 2 1 Introduction Moderate... ). In most RANS studies, the mean velocity and temperature fields show consistent trends with the experi- mental results. However, quantitative agreement of the calculated and measured tempera- ture values becomes unsatisfactory as the dilution level...

  17. Polyol esters as HFC-134a compressor lubricants

    SciTech Connect (OSTI)

    Komatsuzaki, S.; Homma, Y.; Itoh, Y. [Hitachi Ltd. (Japan)] [and others

    1994-10-01T23:59:59.000Z

    A polyol ester-based lubricant has been applied to HFC-134a household refrigerator compressors, because of its good miscibility with HFC-134a refrigerant, and there is a possibility that it will be applied to automobile air conditions. For better performance, further improvements are needed regarding miscibility, lubricity and chemical stability of the lubricant, because such systems are often used under extreme conditions. This report discusses the required properties and ways to improve performance of polyol esters as HFC-134a compressor lubricants. 7 refs., 14 figs., 4 tabs.

  18. Electrophilic Metal Alkyl Chemistry in New Ligand Environments

    SciTech Connect (OSTI)

    Jordan, Richard F. [University of Chicago] University of Chicago

    2013-06-30T23:59:59.000Z

    The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

  19. Effects of alkyl polyglycoside (APG) on composting of agricultural wastes

    SciTech Connect (OSTI)

    Zhang Fabao [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China); Gu Wenjie, E-mail: guwenjie1982@yahoo.cn [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China); Xu Peizhi; Tang Shuanhu; Xie Kaizhi; Huang Xu; Huang Qiaoyi [Soil and Fertilizer Institute, Guangdong Academy of Agricultural Sciences, Guangdong Key Laboratory of Nutrient Cycling and Farmland Conservation, Guangzhou 510640 (China)

    2011-06-15T23:59:59.000Z

    Composting is the biological degradation and transformation of organic materials under controlled conditions to promote aerobic decomposition. To find effective ways to accelerate composting and improve compost quality, numerous methods including additive addition, inoculation of microorganisms, and the use of biosurfactants have been explored. Studies have shown that biosurfactant addition provides more favorable conditions for microorganism growth, thereby accelerating the composting process. However, biosurfactants have limited applications because they are expensive and their use in composting and microbial fertilizers is prohibited. Meanwhile, alkyl polyglycoside (APG) is considered a 'green' surfactant. This study aims to determine whether APG addition into a compost reaction vessel during 28-day composting can enhance the organic matter degradation and composting process of dairy manure. Samples were periodically taken from different reactor depths at 0, 3, 5, 7, 14, 21, and 28 days. pH levels, electrical conductivity (EC), ammonium and nitrate nitrogen, seed germination indices, and microbial population were determined. Organic matter and total nitrogen were also measured. Compared with the untreated control, the sample with APG exhibited slightly increased microbial populations, such as bacteria, fungi, and actinomycetes. APG addition increased temperatures without substantially affecting compost pH and EC throughout the process. After 28 days, APG addition increased nitrate nitrogen concentrations, promoted matter degradation, and increased seed germination indices. The results of this study suggest that the addition of APG provides more favorable conditions for microorganism growth, slightly enhancing organic matter decomposition and accelerating the composting process, improving the compost quality to a certain extent.

  20. Soybean and Coconut Biodiesel Fuel Effects on Combustion Characteristics in a Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Han, Manbae [ORNL; Cho, Kukwon [ORNL; Sluder, Scott [ORNL; Wagner, Robert M [ORNL

    2008-01-01T23:59:59.000Z

    This study investigated the effects of soybean- and coconut-derived biodiesel fuels on combustion characteristics in a 1.7-liter direct injection, common rail diesel engine. Five sets of fuels were studied: 2007 ultra-low sulfur diesel (ULSD), 5% and 20% volumetric blends of soybean biodiesel with ULSD (soybean B5 and B20), and 5% and 20% volumetric blends of coconut biodiesel with ULSD (coconut B5 and B20). In conventional diesel combustion mode, particulate matter (PM) and nitrogen oxides (NO/dx) emissions were similar for all fuels studied except soybean B20. Soybean B20 produced the lowest PM but the highest NO/dx emissions. Compared with conventional diesel combustion mode, high efficiency clean combustion (HECC) mode, achieved by increased EGR and combustion phasing, significantly reduced both PM and NO/dx emissions for all fuels studied at the expense of higher hydrocarbon (HC) and carbon monoxide (CO) emissions and an increase in fuel consumption (less than 4%). ULSD, soybean B5, and coconut B5 showed no difference in exhaust emissions. However, PM emissions increased slightly for soybean B20 and coconut B20. NO/dx emissions increased significantly for soybean B20, while those for coconut B20 were comparable to ULSD. Differences in the chemical and physical properties of soybean and coconut biodiesel fuels compared with ULSD, such as higher fuel-borne oxygen, greater viscosity, and higher boiling temperatures, play a key role in combustion processes and, therefore, exhaust emissions. Furthermore, the highly unsaturated ester composition in soybean biodiesel can be another factor in the increase of NO/dx emissions.

  1. Oxy-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion Oxy-Combustion Chemical Looping Combustion Program Plan Project Portfolio Project Information FAQs POSTED January 27, 2015 - Funding Opportunity Announcement DE-FOA-...

  2. PHYSICAL AND CHEMICAL PROPERTIES OF COMBUSTION GENERATED SOOT

    E-Print Network [OSTI]

    Toossi, Reza

    2010-01-01T23:59:59.000Z

    APPARATA Introduction Combustion Chamber -iv- SamplingIN A PLUME OF COMBUSTION PRODUCTS Introduction . . • • . •methods," 9th Symposium on Combustion, 587 (1963). Gaydon,

  3. EXPERIMENTAL STUDY OF COMBUSTION IN A TURBULENT BOUNDARY LAYER

    E-Print Network [OSTI]

    Cheng, R.K.

    2011-01-01T23:59:59.000Z

    States Section of the Combustion Institute, Stanford, CA,Cheng, R. K. , "Catalyzed Combustion of H2/ Air Mixtures inWorkshop on Catalytic Combustion, Asheville, North Carolina,

  4. Microwave-Assisted Ignition for Improved Internal Combustion Engine Efficiency

    E-Print Network [OSTI]

    DeFilippo, Anthony Cesar

    2013-01-01T23:59:59.000Z

    OH. ” Proceedings of the Combustion Institute: 32(2):3171-Thermochemical Database for Combustion. ” Argonne NationalMicrowave Radiation. ” Combustion Science and Technology:

  5. PARAMETRIC STUDY OF SUBMICRON PARTICULATES FROM PULVERIZED COAL COMBUSTION

    E-Print Network [OSTI]

    Pennucci, J.

    2014-01-01T23:59:59.000Z

    Chemistry of Coal during Combustion and the Emissions fromParticulates Generated by Combustion of Pulverized Coal,Particles from Coal Combustion, presented at the Eighteenth

  6. Low-Temperature Diesel Combustion Cross-Cut Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Combustion Cross-Cut Research Low-Temperature Diesel Combustion Cross-Cut Research Lyle M. Pickett Combustion Research Facility Sandia National Laboratories Sponsor: DOEOVT...

  7. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    1979. J.B. Heywood, Internal Combustion Engine Fundamentals.Ignition Engine with Optimal Combustion Control. ” US PatentIntroduction to Internal Combustion Engines (3rd Edition).

  8. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01T23:59:59.000Z

    J.M. , liThe F1uidised Combustion of Coal," Sixteenth Sm osium {International} on Combustion, August 1976 (to beof Various Polymers Under Combustion Conditions," Fourteenth

  9. COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES

    E-Print Network [OSTI]

    Matthews, Ronald D.

    2013-01-01T23:59:59.000Z

    SAE Paper 750173, 1975. L. , Fifteenth Symposium Combustion,The Combustion Institute, International Pittsburgh, on 64.chemistry of products of combustion: nitrogenous The

  10. Multicylinder Diesel Engine for Low Temperature Combustion Operation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Low Temperature Combustion Operation Multicylinder Diesel Engine for Low Temperature Combustion Operation Fuel injection strategies to extend low temperature combustion...

  11. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Simulation of Natural Gas HCCI Combustion: Gas Compositionfor heating the flowing gas. Combustion timing is consideredup. Exhaust gas samples were collected at varying combustion

  12. COMBUSTION SOURCES OF UNREGULATED GAS PHASE NITROGENEOUS SPECIES

    E-Print Network [OSTI]

    Matthews, Ronald D.

    2013-01-01T23:59:59.000Z

    produced by coal and oil combustion. Stationary combustioncalculated that combustion plant coal and fuel oil couldoil and coal 8 it is anticipated production that the combustion

  13. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    1979. J.B. Heywood, Internal Combustion Engine Fundamentals.Introduction to Internal Combustion Engines (3rd Edition).Coefficient in the Internal Combustion Engine,” SAE Paper

  14. Microwave-Assisted Ignition for Improved Internal Combustion Engine Efficiency

    E-Print Network [OSTI]

    DeFilippo, Anthony Cesar

    2013-01-01T23:59:59.000Z

    J. B. (1988) Internal Combustion Engine Fundamentals.novel microwave internal combustion engine ignition source,in the Internal Combustion Engine." SAE Technical Paper

  15. Combustion Air Zone (CAZ) Best Practices | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Combustion Air Zone (CAZ) Best Practices Combustion Air Zone (CAZ) Best Practices Combustion Air Zone (CAZ) Best Practices Webinar. Presentation More Documents & Publications...

  16. Jet plume injection and combustion system for internal combustion engines

    DOE Patents [OSTI]

    Oppenheim, A.K.; Maxson, J.A.; Hensinger, D.M.

    1993-12-21T23:59:59.000Z

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure. 24 figures.

  17. Jet plume injection and combustion system for internal combustion engines

    DOE Patents [OSTI]

    Oppenheim, Antoni K. (Kensington, CA); Maxson, James A. (Berkeley, CA); Hensinger, David M. (Albany, CA)

    1993-01-01T23:59:59.000Z

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

  18. DIETARY UPTAKE AND BIOTRANSFORMATION OF PHTHALATE ESTERS IN

    E-Print Network [OSTI]

    Phthalate esters (PEs) are a group of organic chemicals used mainly as plasticizers. Due to their widespread that DPEs do not biomagnify in marine food webs. Biotransformation is believed to limit DPE bioaccumulation measured in the food, stomach, intestine, liver and muscle tissue over time. Results show that phthalate di

  19. Combustion Byproducts Recycling Consortium

    SciTech Connect (OSTI)

    Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

    2008-08-31T23:59:59.000Z

    The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F-fly ash. Some developed technologies have similar potential in the longer term. (3) Laboratory studies have been completed that indicate that much higher amounts of fly ash could be added in cement-concrete applications under some circumstances. This could significantly increase use of fly ash in cement-concrete applications. (4) A study of the long-term environmental effects of structural fills in a surface mine in Indiana was completed. This study has provided much sought after data for permitting large-volume management options in both beneficial as well as non-beneficial use settings. (5) The impact of CBRC on CCBs utilization trends is difficult to quantify. However it is fair to say that the CBRC program had a significant positive impact on increased utilization of CCBs in every region of the USA. Today, the overall utilization of CCBs is over 43%. (6) CBRC-developed knowledge base led to a large number of other projects completed with support from other sources of funding. (7) CBRC research has also had a large impact on CCBs management across the globe. Information transfer activities and visitors from leading coal producing countries such as South Africa, Australia, England, India, China, Poland, Czech Republic and Japan are truly noteworthy. (8) Overall, the CBRC has been a truly successful, cooperative research program. It has brought together researchers, industry, government, and regulators to deal with a major problem facing the USA and other coal producing countries in the world.

  20. Internal combustion engine

    SciTech Connect (OSTI)

    Evans, H.G.; Speer, S.

    1991-12-31T23:59:59.000Z

    This patent describes improvement in a 2-cycle, diesel cycle internal combustion engine comprising a single in-line engine block, internal wall surfaces defining at least one cylinder within the engine block, the central longitudinal axis of each cylinder being within a common plane extending longitudinally of the engine block, the axially extending internal wall surface of each cylinder being closed at one end and having at least one air intake port therethrough, a piston axially and reciprocally movable within each cylinder over a permitted stroke distance, so as to alternately cover and expose each air intake port for a finite time period; an exhaust port at the closed end of the cylinder above the piston, and a mechanically operated valve for opening and closing such exhaust port located immediately adjacent such port, a substantially rigid connecting rod pivotably connected at one end of each piston, and a crankshaft, rotatably connected to the second end of each connecting rod, such that the crankshaft is caused to rotate connecting means between the piston and the connecting rod. The improvement comprises the diameter of the cylinder is greater than the permitted stroke distance of the piston within the cylinder, and the axis of the crankshaft is parallel to and laterally offset from the common plane by a distance sufficient to form an angle alpha between the connecting rod and the axis of the cylinder, when the piston is at top-dead center, of at least about 12 degrees, such that the time during which each air intake port is exposed is increased when the direction of crankshaft rotation is opposite to the direction of the crankshaft offset from the common plane.

  1. Method and apparatus for detecting combustion instability in continuous combustion systems

    DOE Patents [OSTI]

    Benson, Kelly J.; Thornton, Jimmy D.; Richards, George A.; Straub, Douglas L.

    2006-08-29T23:59:59.000Z

    An apparatus and method to sense the onset of combustion stability is presented. An electrode is positioned in a turbine combustion chamber such that the electrode is exposed to gases in the combustion chamber. A control module applies a voltage potential to the electrode and detects a combustion ionization signal and determines if there is an oscillation in the combustion ionization signal indicative of the occurrence of combustion stability or the onset of combustion instability. A second electrode held in a coplanar but spaced apart manner by an insulating member from the electrode provides a combustion ionization signal to the control module when the first electrode fails. The control module broadcasts a notice if the parameters indicate the combustion process is at the onset of combustion instability or broadcasts an alarm signal if the parameters indicate the combustion process is unstable.

  2. Turbulent Combustion in SDF Explosions

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E

    2009-11-12T23:59:59.000Z

    A heterogeneous continuum model is proposed to describe the dispersion and combustion of an aluminum particle cloud in an explosion. It combines the gas-dynamic conservation laws for the gas phase with a continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models. It incorporates a combustion model based on the mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the C-4 booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Numerical simulations of the explosion fields from 1.5-g Shock-Dispersed-Fuel (SDF) charge in a 6.6 liter calorimeter were used to validate the combustion model. Then the model was applied to 10-kg Al-SDF explosions in a an unconfined height-of-burst explosion. Computed pressure histories are compared with measured waveforms. Differences are caused by physical-chemical kinetic effects of particle combustion which induce ignition delays in the initial reactive blast wave and quenching of reactions at late times. Current simulations give initial insights into such modeling issues.

  3. HCCl Combustion: Analysis and Experiments

    SciTech Connect (OSTI)

    Aceves, S M; Flowers, D L; Martinez-Frias, J; Smith, J R; Dibble, R; Au, M; Girard, J

    2001-05-04T23:59:59.000Z

    Homogeneous charge compression ignition (HCCI) is a new combustion technology that may develop as an alternative to diesel engines with high efficiency and low NOx and particulate matter emissions. This paper describes the HCCI research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work. On analysis, we have developed two powerful tools: a single zone model and a multi-zone model. The single zone model has proven very successful in predicting start of combustion and providing reasonable estimates for peak cylinder pressure, indicated efficiency and NOX emissions. This model is being applied to develop detailed engine performance maps and control strategies, and to analyze the problem of engine startability. The multi-zone model is capable of very accurate predictions of the combustion process, including HC and CO emissions. The multi-zone model has applicability to the optimization of combustion chamber geometry and operating conditions to achieve controlled combustion at high efficiency and low emissions. On experimental work, we have done a thorough evaluation of operating conditions in a 4-cylinder Volkswagen TDI engine. The engine has been operated over a wide range of conditions by adjusting the intake temperature and the fuel flow rate. Satisfactory operation has been obtained over a wide range of operating conditions. Cylinder-to-cylinder variations play an important role in limiting maximum power, and should be controlled to achieve satisfactory performance.

  4. HCCI Combustion: Analysis and Experiments

    SciTech Connect (OSTI)

    Salvador M. Aceves; Daniel L. Flowers; Joel Martinez-Frias; J. Ray Smith; Robert Dibble; Michael Au; James Girard

    2001-05-14T23:59:59.000Z

    Homogeneous charge compression ignition (HCCI) is a new combustion technology that may develop as an alternative to diesel engines with high efficiency and low NOx and particulate matter emissions. This paper describes the HCCI research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work. On analysis, we have developed two powerful tools: a single zone model and a multi-zone model. The single zone model has proven very successful in predicting start of combustion and providing reasonable estimates for peak cylinder pressure, indicated efficiency and NOX emissions. This model is being applied to develop detailed engine performance maps and control strategies, and to analyze the problem of engine startability. The multi-zone model is capable of very accurate predictions of the combustion process, including HC and CO emissions. The multi-zone model h as applicability to the optimization of combustion chamber geometry and operating conditions to achieve controlled combustion at high efficiency and low emissions. On experimental work, we have done a thorough evaluation of operating conditions in a 4-cylinder Volkswagen TDI engine. The engine has been operated over a wide range of conditions by adjusting the intake temperature and the fuel flow rate. Satisfactory operation has been obtained over a wide range of operating conditions. Cylinder-to-cylinder variations play an important role in limiting maximum power, and should be controlled to achieve satisfactory performance.

  5. COMBUSTION RESEARCH PROGRAM. CHAPTER FROM ENERGY & ENVIRONMENT ANNUAL REPORT 1977

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    of Combustion in Internal Combustion Engines," Paper 750890,that occur in an internal combustion engine. Our goal is theLAG process in an internal combustion engine, con- ducted at

  6. Effects of Advanced Combustion Technologies on Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics...

  7. Combustion instability modeling and analysis

    SciTech Connect (OSTI)

    Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States); Sheppard, E.J. [Tuskeggee Univ., Tuskegee, AL (United States). Dept. of Aerospace Engineering

    1995-12-31T23:59:59.000Z

    It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

  8. Free Energy and Internal Combustion Engine Cycles

    E-Print Network [OSTI]

    Harris, William D

    2012-01-01T23:59:59.000Z

    The performance of one type (Carnot) of Internal Combustion Engine (ICE) cycle is analyzed within the framework of thermodynamic free energies. ICE performance is different from that of an External Combustion Engine (ECE) which is dictated by Carnot's rule.

  9. Combustion Catalysts in Industry- An Update

    E-Print Network [OSTI]

    Merrell, G. A.; Knight, R. S.

    Combustion catalysts improve boiler efficiency by extracting more heat energy from the fuel and by reducing heat losses when operating at minimum excess air. In addition, an effective combustion catalyst may reduce the level of smoke and solid...

  10. TURBULENT FRBRNNING MVK 130 Turbulent Combustion

    E-Print Network [OSTI]

    TURBULENT FÖRBRÄNNING MVK 130 Turbulent Combustion Antal poäng: 3.0. Valfri för: M4. Kursansvarig program med hänsyn till de modeller som används. Litteratur S.R. Turns: An introduction to combustion, Mc

  11. Free Energy and Internal Combustion Engine Cycles

    E-Print Network [OSTI]

    William D. Harris

    2012-01-11T23:59:59.000Z

    The performance of one type (Carnot) of Internal Combustion Engine (ICE) cycle is analyzed within the framework of thermodynamic free energies. ICE performance is different from that of an External Combustion Engine (ECE) which is dictated by Carnot's rule.

  12. Formation mechanisms of combustion chamber deposits

    E-Print Network [OSTI]

    O'Brien, Christopher J. (Christopher John)

    2001-01-01T23:59:59.000Z

    Combustion chamber deposits are found in virtually all internal combustion engines after a few hundred hours of operation. Deposits form on cylinder, piston, and head surfaces that are in contact with fuel-air mixture ...

  13. Engine Combustion Network Experimental Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maintained by the Engine Combustion Department of Sandia National Laboratories, data currently available on the website includes reacting and non-reacting sprays in a constant-volume chamber at conditions typical of diesel combustion. The data are useful for model development and validation because of the well-defined boundary conditions and the wide range of conditions employed. A search utility displays data based on experimental conditions such as ambient temperature, ambient density, injection pressure, nozzle size, fuel, etc. Experiment-related visualizations are also available. The search utility for experimental data is located at http://public.ca.sandia.gov/ecn/cvdata/frameset.html (Specialized Interface)

  14. Pulse atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The overall objective of the program is the development of a pulsed atmospheric fluidized-bed combustion (PAFBC) technology to burn coal and to provide heat and steam to commercial, institutional, and small industrial applications at a reasonable price in an environmentally acceptable manner. During this reporting period, a total of eight shakedown and debugging coal combustion tests were performed in the AFBC. A start-up procedure was established, system improvements implemented, and preliminary material and heat balances made based on these tests. The pulse combustor for the AFBC system was fabricated and installed and a series of tests was conducted on the system. 17 figs., 5 tabs.

  15. Chemical kinetics and combustion modeling

    SciTech Connect (OSTI)

    Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

  16. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, Richard G. (Livermore, CA); Walton, Otis R. (Livermore, CA); Lewis, Arthur E. (Los Altos, CA); Braun, Robert L. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650.degree.-700.degree. C. for use as a process heat source.

  17. Combustion heater for oil shale

    DOE Patents [OSTI]

    Mallon, R.; Walton, O.; Lewis, A.E.; Braun, R.

    1983-09-21T23:59:59.000Z

    A combustion heater for oil shale heats particles of spent oil shale containing unburned char by burning the char. A delayed fall is produced by flowing the shale particles down through a stack of downwardly sloped overlapping baffles alternately extending from opposite sides of a vertical column. The delayed fall and flow reversal occurring in passing from each baffle to the next increase the residence time and increase the contact of the oil shale particles with combustion supporting gas flowed across the column to heat the shale to about 650 to 700/sup 0/C for use as a process heat source.

  18. ME 6990 -Combustion Catalog Data: ME 6990: Combustion. Sem. 2. Class 3, Credit 3 (el.).

    E-Print Network [OSTI]

    Panchagnula, Mahesh

    ME 6990 - Combustion Catalog Data: ME 6990: Combustion. Sem. 2. Class 3, Credit 3 (el.). Physical and chemical aspects of basic combustion phenomena. Classification of flames. Measurement of laminar flame. Fuels. Atomization and evaporation of liquid fuels. Theories of ignition, stability and combustion

  19. Supersonic combustion studies using a multivariate quadrature based method for combustion modeling

    E-Print Network [OSTI]

    Raman, Venkat

    Supersonic combustion studies using a multivariate quadrature based method for combustion modeling function (PDF) of thermochemical variables can be used for accurately computing the combustion source term of predictive models for supersonic combustion is a critical step in design and development of scramjet engines

  20. Combustion Synthesis of Silicon Carbide 389 Combustion Synthesis of Silicon Carbide

    E-Print Network [OSTI]

    Mukasyan, Alexander

    Combustion Synthesis of Silicon Carbide 389 X Combustion Synthesis of Silicon Carbide Alexander S. Mukasyan University of Notre Dame USA 1. Introduction Combustion synthesis (CS) is an effective technique by which combustion synthesis can occur: self - propagating high-temperature synthesis (SHS) and volume

  1. Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

    DOE Patents [OSTI]

    Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

    2008-10-07T23:59:59.000Z

    This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

  2. Improving alternative fuel utilization: detailed kinetic combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improving alternative fuel utilization: detailed kinetic combustion modeling & experimental testing Salvador Aceves, Daniel Flowers, Bill Pitz, Charlie Westbrook, Emma Silke,...

  3. FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE

    E-Print Network [OSTI]

    M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

    combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm

  4. Combustor nozzle for a fuel-flexible combustion system

    DOE Patents [OSTI]

    Haynes, Joel Meier (Niskayuna, NY); Mosbacher, David Matthew (Cohoes, NY); Janssen, Jonathan Sebastian (Troy, NY); Iyer, Venkatraman Ananthakrishnan (Mason, OH)

    2011-03-22T23:59:59.000Z

    A combustor nozzle is provided. The combustor nozzle includes a first fuel system configured to introduce a syngas fuel into a combustion chamber to enable lean premixed combustion within the combustion chamber and a second fuel system configured to introduce the syngas fuel, or a hydrocarbon fuel, or diluents, or combinations thereof into the combustion chamber to enable diffusion combustion within the combustion chamber.

  5. Fifteen Lectures on Laminar and Turbulent Combustion

    E-Print Network [OSTI]

    Peters, Norbert

    Fifteen Lectures on Laminar and Turbulent Combustion N. Peters RWTH Aachen Ercoftac Summer School in Combustion Systems 1 Lecture 2: Calculation of Adiabatic Flame Temperatures and Chemical Equilibria 20: Laminar Diffusion Flames: Different Flow Geometries 156 Lecture 11: Turbulent Combustion: Introduction

  6. INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING

    E-Print Network [OSTI]

    INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

  7. Combustion joining of refractory materials: Carboncarbon composites

    E-Print Network [OSTI]

    Mukasyan, Alexander

    Combustion joining of refractory materials: Carbon­carbon composites Jeremiah D.E. White Department­carbon composite is achieved by employing self-sustained, oxygen-free, high-temperature combustion reactions to a used "core" to produce a brake that meets the performance specifications. The combustion-joining (CJ

  8. Understanding Combustion Processes Through Microgravity Research

    E-Print Network [OSTI]

    such as Lewis number effects. Examples from premixed-gas combustion, non-premixed gas-jet flames, droplet. COMPARISON OF TIME SCALES FOR PREMIXED-GAS COMBUSTION To determine the conditions where gravity can affectUnderstanding Combustion Processes Through Microgravity Research Paul D. Ronney Department

  9. Separation of regenerated catalyst from combustion products

    SciTech Connect (OSTI)

    Benslay, R. M.

    1984-10-16T23:59:59.000Z

    A method and apparatus for separating regenerated catalyst from gaseous combustion products within a regenerator. The apparatus comprises a downcomer within the regenerator vessel through which the catalyst and gaseous combustion products flow. Means are provided at the lower end of the downcomer for utilizing the momentum of the catalyst particles to separate them from the gaseous combustion products.

  10. State of Industrial Fluidized Bed Combustion

    E-Print Network [OSTI]

    Mesko, J. E.

    1982-01-01T23:59:59.000Z

    is expectOO. Direct combustion of oil shale, combustion of wxxi ani municipil refuse also has been deron stratOO, either as primary fuels or as additives in units primarily firOO with coal. Combustion of liquid fuels, such as residual oils containing...

  11. Nickel-catalyzed cross-couplings of unactivated secondary and tertiary alkyl halides and photoinduced copper-mediated asymmetric C-N cross-couplings

    E-Print Network [OSTI]

    Zultanski, Susan L. (Susan Lyn)

    2013-01-01T23:59:59.000Z

    Chapter 1 describes the development of two nickel-catalyzed Suzuki cross-coupling methodologies that employ alkyl halides as electrophiles. In Section 1.1, asymmetric [gamma]-alkylation relative to a carbonyl group is ...

  12. Structural Analysis of Combustion Models

    E-Print Network [OSTI]

    Tóth, J; Zsély, I

    2013-01-01T23:59:59.000Z

    Using ReactionKinetics, a Mathematica based package a few dozen detailed models for combustion of hydrogen, carbon monoxide and methanol are investigated. Essential structural characteristics are pulled out, and similarities and differences of the mechanisms are highlighted. These investigations can be used before or parallel with usual numerical investigations, such as pathway analysis, sensitivity analysis, parameter estimation, or simulation.

  13. Syntheses of 11 F-labeled carboxylic esters within a

    E-Print Network [OSTI]

    Shen, Jun

    and with reduced infusion rate. Radioactive methyl ester 4b was obtained from the reaction of 1 (10 mM) with 2b in 56% decay-corrected radiochemical yield (RCY) at an infusion rate of 10 mL min21 , and when the infusion rate was reduced to 1 mL min21 , the RCY increased to 88%. The synthesis of the non

  14. Combustive management of oil spills

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris.

  15. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, B.D.; Confer, G.L.; Zujing Shen; Hapeman, M.J.; Flynn, P.L.

    1993-12-21T23:59:59.000Z

    Apparatus and a method of introducing a primary fuel, which may be a coal water slurry, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure. 19 figures.

  16. Method of combustion for dual fuel engine

    DOE Patents [OSTI]

    Hsu, Bertrand D. (Erie, PA); Confer, Gregory L. (Erie, PA); Shen, Zujing (Erie, PA); Hapeman, Martin J. (Edinboro, PA); Flynn, Paul L. (Fairview, PA)

    1993-12-21T23:59:59.000Z

    Apparatus and a method of introducing a primary fuel, which may be a coal water slutty, and a high combustion auxiliary fuel, which may be a conventional diesel oil, into an internal combustion diesel engine comprises detecting the load conditions of the engine, determining the amount of time prior to the top dead center position of the piston to inject the main fuel into the combustion chamber, and determining the relationship of the timing of the injection of the auxiliary fuel into the combustion chamber to achieve a predetermined specific fuel consumption, a predetermined combustion efficiency, and a predetermined peak cylinder firing pressure.

  17. Combustion engineering issues for solid fuel systems

    SciTech Connect (OSTI)

    Bruce Miller; David Tillman [Pennsylvania State University, University Park, PA (United States). Energy Institute

    2008-05-15T23:59:59.000Z

    The book combines modeling, policy/regulation and fuel properties with cutting edge breakthroughs in solid fuel combustion for electricity generation and industrial applications. This book provides real-life experiences and tips for addressing the various technical, operational and regulatory issues that are associated with the use of fuels. Contents are: Introduction; Coal Characteristics; Characteristics of Alternative Fuels; Characteristics and Behavior of Inorganic Constituents; Fuel Blending for Combustion Management; Fuel Preparation; Conventional Firing Systems; Fluidized-Bed Firing Systems; Post-Combustion Emissions Control; Some Computer Applications for Combustion Engineering with Solid Fuels; Gasification; Policy Considerations for Combustion Engineering.

  18. Combustion diagnostic for active engine feedback control

    DOE Patents [OSTI]

    Green, Jr., Johney Boyd (Knoxville, TN); Daw, Charles Stuart (Knoxville, TN); Wagner, Robert Milton (Knoxville, TN)

    2007-10-02T23:59:59.000Z

    This invention detects the crank angle location where combustion switches from premixed to diffusion, referred to as the transition index, and uses that location to define integration limits that measure the portions of heat released during the combustion process that occur during the premixed and diffusion phases. Those integrated premixed and diffusion values are used to develop a metric referred to as the combustion index. The combustion index is defined as the integrated diffusion contribution divided by the integrated premixed contribution. As the EGR rate is increased enough to enter the low temperature combustion regime, PM emissions decrease because more of the combustion process is occurring over the premixed portion of the heat release rate profile and the diffusion portion has been significantly reduced. This information is used to detect when the engine is or is not operating in a low temperature combustion mode and provides that feedback to an engine control algorithm.

  19. Light Duty Efficient, Clean Combustion

    SciTech Connect (OSTI)

    Donald Stanton

    2010-12-31T23:59:59.000Z

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy's Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of the following objectives were met with fuel efficiency improvement targets exceeded: (1) Improve light duty vehicle (5000 lb. test weight) fuel efficiency by 10.5% over today's state-of-the-art diesel engine on the FTP city drive cycle; (2) Develop and design an advanced combustion system plus aftertreatment system that synergistically meets Tier 2 Bin 5 NOx and PM emissions standards while demonstrating the efficiency improvements; (3) Maintain power density comparable to that of current conventional engines for the applicable vehicle class; and (4) Evaluate different fuel components and ensure combustion system compatibility with commercially available biofuels. Key accomplishments include: (1) A 25% improvement in fuel efficiency was achieved with the advanced LDECC engine equipped with a novel SCR aftertreatment system compared to the 10.5% target; (2) An 11% improvement in fuel efficiency was achieved with the advanced LDECC engine and no NOx aftertreamtent system; (3) Tier 2 Bin 5 and SFTP II emissions regulations were met with the advanced LDECC engine equipped with a novel SCR aftertreatment system; (4) Tier 2 Bin 5 emissions regulations were met with the advanced LDECC engine and no NOx aftertreatment, but SFTP II emissions regulations were not met for the US06 test cycle - Additional technical barriers exist for the no NOx aftertreatment engine; (5) Emissions and efficiency targets were reached with the use of biodiesel. A variety of biofuel feedstocks (soy, rapeseed, etc.) was investigated; (6) The advanced LDECC engine with low temperature combustion was compatible with commercially available biofuels as evaluated by engine performance testing and not durability testing; (7) The advanced LDECC engine equipped with a novel SCR aftertreatment system is the engine system architecture that is being further developed by the Cummins product development organization. Cost reduction and system robustness activities have been identified for future deployment; (8) The new engine and aftertreatment component technologies are being developed by the Cummins Component Business units (e.g. fuel system, turbomachinery, aftertreatment, electronics, etc.) to ensure commercial viability and deployment; (9) Cummins has demonstrated that the technologies developed for this program are scalable across the complete light duty engine product offerings (2.8L to 6.7L engines); and (10) Key subsystems developed include - sequential two stage turbo, combustions system for low temperature combustion, novel SCR aftertreatment system with feedback control, and high pressure common rail fuel system. An important element of the success of this project was leveraging Cummins engine component technologies. Innovation in component technology coupled with system integration is enabling Cummins to move forward with the development of high efficiency clean diesel products with a long term goal of reaching a 40% improvement in thermal efficiency for the engine plus aftertreatment system. The 40% improvement is in-line with the current light duty vehicle efficiency targets set by the 2010 DoE Vehicle Technologies MYPP and supported through co-operative projects such as the Cummins Advanced Technology Powertrains for Light-Duty Vehicles (ATP-LD) started in 2010.

  20. Light Duty Efficient, Clean Combustion

    SciTech Connect (OSTI)

    Stanton, Donald W

    2011-06-03T23:59:59.000Z

    Cummins has successfully completed the Light Duty Efficient Clean Combustion (LDECC) cooperative program with DoE. This program was established in 2007 in support of the Department of Energy’s Vehicles Technologies Advanced Combustion and Emissions Control initiative to remove critical barriers to the commercialization of advanced, high efficiency, emissions compliant internal combustion (IC) engines for light duty vehicles. Work in this area expanded the fundamental knowledge of engine combustion to new regimes and advanced the knowledge of fuel requirements for these diesel engines to realize their full potential. All of the following objectives were met with fuel efficiency improvement targets exceeded: 1. Improve light duty vehicle (5000 lb. test weight) fuel efficiency by 10.5% over today’s state-ofthe- art diesel engine on the FTP city drive cycle 2. Develop & design an advanced combustion system plus aftertreatment system that synergistically meets Tier 2 Bin 5 NOx and PM emissions standards while demonstrating the efficiency improvements. 3. Maintain power density comparable to that of current conventional engines for the applicable vehicle class. 4. Evaluate different fuel components and ensure combustion system compatibility with commercially available biofuels. Key accomplishments include: ? A 25% improvement in fuel efficiency was achieved with the advanced LDECC engine equipped with a novel SCR aftertreatment system compared to the 10.5% target ? An 11% improvement in fuel efficiency was achieved with the advanced LDECC engine and no NOx aftertreamtent system ? Tier 2 Bin 5 and SFTP II emissions regulations were met with the advanced LDECC engine equipped with a novel SCR aftertreatment system ? Tier 2 Bin 5 emissions regulations were met with the advanced LDECC engine and no NOx aftertreatment, but SFTP II emissions regulations were not met for the US06 test cycle – Additional technical barriers exist for the no NOx aftertreatment engine ? Emissions and efficiency targets were reached with the use of biodiesel. A variety of biofuel feedstocks (soy, rapeseed, etc.) was investigated. ? The advanced LDECC engine with low temperature combustion was compatible with commercially available biofuels as evaluated by engine performance testing and not durability testing. ? The advanced LDECC engine equipped with a novel SCR aftertreatment system is the engine system architecture that is being further developed by the Cummins product development organization. Cost reduction and system robustness activities have been identified for future deployment. ? The new engine and aftertreatment component technologies are being developed by the Cummins Component Business units (e.g. fuel system, turbomachinery, aftertreatment, electronics, etc.) to ensure commercial viability and deployment ? Cummins has demonstrated that the technologies developed for this program are scalable across the complete light duty engine product offerings (2.8L to 6.7L engines) ? Key subsystems developed include – sequential two stage turbo, combustions system for low temperature combustion, novel SCR aftertreatment system with feedback control, and high pressure common rail fuel system An important element of the success of this project was leveraging Cummins engine component technologies. Innovation in component technology coupled with system integration is enabling Cummins to move forward with the development of high efficiency clean diesel products with a long term goal of reaching a 40% improvement in thermal efficiency for the engine plus aftertreatment system. The 40% improvement is in-line with the current light duty vehicle efficiency targets set by the 2010 DoE Vehicle Technologies MYPP and supported through co-operative projects such as the Cummins Advanced Technology Powertrains for Light- Duty Vehicles (ATP-LD) started in 2010.

  1. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    Emissions from Fuel Oil Combustion," Combustion, 21, August,K #4 Fuel Oil Bituminous Coal (Group 4) The lower combustion

  2. N-Alkyl-polyethylenimine 2 kDastabilized superparamagnetic iron oxide nanoparticles for MRI cell tracking

    E-Print Network [OSTI]

    Levin, Judith G.

    nanoparticles need to be coated with organic polymers or other materials for efficient cell labeling. This surface coating increases the stability of SPIO nanoparticles and allows further chemical modificationsN-Alkyl-polyethylenimine 2 kDa­stabilized superparamagnetic iron oxide nanoparticles for MRI cell

  3. Molecular simulation study of nanoscale friction for alkyl monolayers on Si,,111...

    E-Print Network [OSTI]

    Zhang, Luzheng

    . To calculate friction in MD simulations, two Si 111 surfaces coated with the alkyl monolayers were slid against is critical to the design of coatings for microelectromechanical systems. © 2002 American Institute of Physics, such as membranes, gears, motors, pumps and valves.1­3 The integration of miniaturized mechanical components

  4. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, Paul S. (Baltimore, MD); Ts'o, Paul O.P. (Lutherville, MD)

    1999-06-15T23:59:59.000Z

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid and includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional.

  5. ADSORPTION/DESORPTION STUDIES ON SOLID ACID ALKYLATION CATALYSTS USING A TAPERED ELEMENT OSCILLATING MICROBALANCE (TEOM)

    E-Print Network [OSTI]

    Gong, Kening

    2008-10-23T23:59:59.000Z

    four times more active than SiO2-supported Nafion while providing > 80% C 80% C8 alkylates selectivity for the process to be economically viable. A tapered element oscillating microbalance (TEOM) was used to elucidate for the first time the adsorption...

  6. Electronic desorption of alkyl monolayers from silicon by very highly charged ions

    E-Print Network [OSTI]

    -assembled alkyl monolayers SAM on Si 111 .13 AFM images of SAMs after exposure to Xe41 and Au63 show craters ions, like Xe41 and Th73 . Atomic force microscope images show craters from single ion impacts be used to modify surfaces at very low impact energies. Impact energies are limited by the image charge

  7. Oligonucleoside alkyl or arylphosphonate derivatives capable of crosslinking with or cleaving nucleic acids

    DOE Patents [OSTI]

    Miller, P.S.; Ts'o, P.O.P.

    1999-06-15T23:59:59.000Z

    A composition for inactivating a target nucleic acid which comprises an oligonucleoside alkyl or arylphosphonate analogue which is complementary to the sequence of the target nucleic acid is provided. It includes a functional group which reacts with the target nucleic acid to render the target nucleic acid inactive or nonfunctional. 16 figs.

  8. Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

    DOE Patents [OSTI]

    Roberts, Jr., Charles E.; Chadwell, Christopher J.

    2004-09-21T23:59:59.000Z

    The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

  9. COMBUSTION RESEARCH Chapter from the Energy and Environment Division Annual Report 1980

    E-Print Network [OSTI]

    Authors, Various

    2013-01-01T23:59:59.000Z

    Heat Transfer with Combustion R. Greif, H. Heperkan, J.H. Stewart . • . • • . COMBUSTION CHEMISTRY AND POLLUTANTInternational) on Combustion, The Combustion institute,

  10. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Ojeda, William de

    2010-07-31T23:59:59.000Z

    The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally, the transient demonstration was performed in Phase IV. The project demonstrated the achievement of meeting US10 emissions without NOx aftertreatment. The successful execution of the project has served to highlight the effectiveness of closely matched combustion predictive tools to engine testing. It has further served to highlight the importance of key technologies and future areas of research and development. In this regard, recommendations are made towards further improvements in the areas of engine hardware, fuel injection systems, controls and fuels.

  11. Combustion synthesis continuous flow reactor

    DOE Patents [OSTI]

    Maupin, G.D.; Chick, L.A.; Kurosky, R.P.

    1998-01-06T23:59:59.000Z

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor. 10 figs.

  12. Optical investigation of the combustion behaviour inside the engine operating in HCCI mode and using alternative diesel fuel

    SciTech Connect (OSTI)

    Mancaruso, E.; Vaglieco, B.M. [Istituto Motori - CNR, Via Marconi, 8, 80125 Napoli (Italy)

    2010-04-15T23:59:59.000Z

    In order to understand the effect of both the new homogeneous charge compression ignition (HCCI) combustion process and the use of biofuel, optical measurements were carried out into a transparent CR diesel engine. Rape seed methyl ester was used and tests with several injection pressures were performed. OH and HCO radical were detected and their evolutions were analyzed during the whole combustion. Moreover, soot concentration was measured by means the two colour pyrometry method. The reduction of particulate emission with biodiesel as compared to the diesel fuel was noted. Moreover, this effect resulted higher increasing the injection pressure. In the case of RME the oxidation of soot depends mainly from O{sub 2} content of fuel and OH is responsible of the NO formation in the chamber as it was observed for NO{sub x} exhaust emission. Moreover, it was investigated the evolution of HCO and CO into the cylinder. HCO was detected at the start of combustion. During the combustion, HCO oxidizes due to the increasing temperature and it produces CO. Both fuels have similar trend, the highest concentrations are detected for low injection pressure. This effect is more evident for the RME fuel. (author)

  13. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15T23:59:59.000Z

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  14. Combustion Engine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuildingCoal Combustion Products

  15. Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters...

    Broader source: Energy.gov (indexed) [DOE]

    in advanced engines for transportation applications." Second Generation and Optimal Biodiesel Howell (DEER 2007) pointed to optimizing the fatty acid ester distribution...

  16. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    Kolker, A.; Sarofim, A.F.; Palmer, C.A.; Huggins, F.E.; Huffman, G.P.; Lighty, J.; Veranth, J.; Helble, J.J.; Wendt, J.O.L.; Ames, M.R.; Finkelman, R.; Mamani-Paco, M.; Sterling, R.; Mroczkowsky, S.J.; Panagiotou, T.; Seames, W.

    1999-05-10T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environ-mental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 January 1999 to 31 March 1999. During this period, a full Program Review Meeting was held at the University of Arizona. At this meeting, the progress of each group was reviewed, plans for the following 9 month period were discussed, and action items (principally associated with the transfer of samples and reports among the various investigators) were identified.

  17. A determination of the heats of combustion of the five-carbon fatty acids and their methyl and ethyl esters

    E-Print Network [OSTI]

    Gilby, Ralph F

    1952-01-01T23:59:59.000Z

    ; g7;P~. X% FATTI ACXDS ND TAX'. K~~~. Ah. ' RKg', Ei~K'~ P~ FuXVQJ~ ef %he 1&aydgewetie fea %he Twine of ~ of . "-elmer F~ F QQXly xy, ay~ Oe esther w9atew to thank Lh ~ C+ K ~ eeet W 9 H~ Vetoes ebs 45xoe~ @de esesaveh The ~ also ~ to thsnk N... of preparation had to be used? Tbongh sane diff ioalt and tins oonsnaing than sxxidationx the prsparatdon through the Orignard synthesis prosed quite satisfaotory? Isobntyl ~ prepared frcxa the aloohol was converted to isobutgrl nayvvxtuxs bread, de whioh...

  18. A determination of the heats of combustion of the five-carbon fatty acids and their methyl and ethyl esters 

    E-Print Network [OSTI]

    Gilby, Ralph F

    1952-01-01T23:59:59.000Z

    ; g7;P~. X% FATTI ACXDS ND TAX'. K~~~. Ah. ' RKg', Ei~K'~ P~ FuXVQJ~ ef %he 1&aydgewetie fea %he Twine of ~ of . "-elmer F~ F QQXly xy, ay~ Oe esther w9atew to thank Lh ~ C+ K ~ eeet W 9 H~ Vetoes ebs 45xoe~ @de esesaveh The ~ also ~ to thsnk N... of preparation had to be used? Tbongh sane diff ioalt and tins oonsnaing than sxxidationx the prsparatdon through the Orignard synthesis prosed quite satisfaotory? Isobntyl ~ prepared frcxa the aloohol was converted to isobutgrl nayvvxtuxs bread, de whioh...

  19. Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL

    2009-12-01T23:59:59.000Z

    The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

  20. NISTIR 6458 Characterization of the Inlet Combustion Air in

    E-Print Network [OSTI]

    Magee, Joseph W.

    NISTIR 6458 Characterization of the Inlet Combustion Air in NIST's Reference Spray Combustion January 2000 #12;ii Contents page Introduction 1 Reference Spray Combustion Facility 3 Numerical;1 Characterization of the Inlet Combustion Air in NIST's Reference Spray Combustion Facility: Effect of Vane Angle

  1. ME 374C Combustion Engine Processes ABET EC2000 syllabus

    E-Print Network [OSTI]

    Ben-Yakar, Adela

    ME 374C ­ Combustion Engine Processes Page 1 ABET EC2000 syllabus ME 374C ­ Combustion Engine combustion engines, fuels, carburetion, combustion, exhaust emissions, knock, fuel injection, and factors to an appropriate major sequence in engineering. Textbook(s): Internal Combustion Engines and Automotive Engineering

  2. Sandia Combustion Research Program: Annual report, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01T23:59:59.000Z

    This report presents research results of the past year, divided thematically into some ten categories. Publications and presentations arising from this work are included in the appendix. Our highlighted accomplishment of the year is the announcement of the discovery and demonstration of the RAPRENOx process. This new mechanism for the elimination of nitrogen oxides from essentially all kinds of combustion exhausts shows promise for commercialization, and may eventually make a significant contribution to our nation's ability to control smog and acid rain. The sections of this volume describe the facility's laser and computer system, laser diagnostics of flames, combustion chemistry, reacting flows, liquid and solid propellant combustion, mathematical models of combustion, high-temperature material interfaces, studies of engine/furnace combustion, coal combustion, and the means of encouraging technology transfer. 182 refs., 170 figs., 12 tabs.

  3. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was carried out during August at the Advanced Photon Source (APS), the new synchrotron facility at Argonne National Laboratory, Chicago, IL. Further analysis of small-scale combustion experiments conducted at PSI in Phase I was completed this quarter. The results of these experiments for the first time suggest almost complete vaporization of certain trace elements (Se, Zn) from coal combustion in the flame zone, in accordance with theoretical equilibrium predictions. Other elements (As, Sb, Cr) appeared considerably less volatile and may react with constituents in the bulk ash at combustion temperatures. The combustion section of the University of Arizona's Downflow Combustor was completely rebuilt. The University of Utah worked on setting up EPA Method 26A to give the capability to measure chlorine in flue gas. The chlorine kinetic calculations performed as part of the Phase I program were found to have an error in the initial conditions. Therefore, the calculations were re-done this quarter with the correct starting conditions. Development of a quasi-empirical emissions model based on reported emissions of particulate matter from field measurements was continued this quarter. As a first step in developing the ToPEM, we developed a sub-model that calculates the evaporation of major elements (Na, K, Fe, Si, Al, Ca and Mg) from both inherent and extraneous minerals of coal. During this quarter, this sub-model was included into EMAF, which formed the ToPEM. Experimental data from the Phase I program were used to test and modify the sub-model and the ToPEM.

  4. Synthesis and Decarboxylative Coupling of Sulfonyl Acetic Esters

    E-Print Network [OSTI]

    Weaver, Jimmie Dean

    2010-04-28T23:59:59.000Z

    -product salts with CO 2 -making it a green alternative. Despite the potential of this methodology, surprisingly, very little 10 was done over the next two decades since Saegusa and Tsuji provided proof of concept. 8 In 2004, 11 Erin Burger, a fellow... the concentration; most of these reactions were run with an initial ester concentration of ~0.1 M. Increasing the reaction concentration to 0.2 M, with respect to substrate, typically results in 23 ~10% higher yields compared to those shown Table 1...

  5. The relative reactivity of formic esters with aromatic amines

    E-Print Network [OSTI]

    Markley, Max C.

    1922-01-01T23:59:59.000Z

    .MARKLEY I Vies* S ma y c . l k f c V i M t s RDQOSS 38M30 PREFACE. The purpose of this thesis was to determine the relative reactivity between aromatic amines and the esters of formic acid.It was proposed to first: deter­ mine the reactivity... be given Br .Ray Q,.Brewster , the director of this work, for his help and directions for carrying out this work, and to Br.Prank B.Bains for his kind assistance in many ways. 1.Broil,Journal fur Practische Chemie,1875,vol. 12,page 208. ( 2 ) TABLE...

  6. Combustion with reduced carbon in the ash

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2005-12-27T23:59:59.000Z

    Combustion of coal in which oxygen is injected into the coal as it emerges from burner produces ash having reduced amounts of carbon.

  7. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Broader source: Energy.gov (indexed) [DOE]

    ace066yilmaz2013o.pdf More Documents & Publications Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency Light Duty Vehicles Vehicle...

  8. Stretch Efficiency - Thermodynamic Analysis of New Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037) C. Stuart Daw, Josh A. Pihl, A. Lou Qualls, V. Kalyana Chakravarthy, Johney B. Green, Jr.,...

  9. Combustion & Fuels Waste Heat Recovery & Utilization Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion & Fuels Waste Heat Recovery & Utilization Project Project Technical Lead - Thermoelectric Analysis & Materials 27 February 2008 2008 DOE OVT Annual Merit Review 2008...

  10. KIVA Modeling to Support Diesel Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Merit Review KIVA Modeling to Support Diesel Combustion Research DOE Vehicle Technologies Program Annual Merit Review, FY2008 David Torres Los Alamos National Laboratory...

  11. Modeling of High Efficiency Clean Combustion Engines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lawrence Livermore National Laboratory Modeling of high efficiency clean combustion engines Daniel Flowers Salvador Aceves Tom Piggott Daniel Flowers, Salvador Aceves, Tom Piggott,...

  12. Advanced Combustion and Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Fuels Advanced Combustion and Fuels 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting...

  13. Sandia National Laboratories: Combustion Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  14. Internal Combustion Engine Energy Retention (ICEER)

    Broader source: Energy.gov (indexed) [DOE]

    ICEER Internal Combustion Engine Energy Retention PI: Jeffrey Gonder Team: Eric Wood & Sean Lopp National Renewable Energy Laboratory June 18, 2014 Project ID: VSS126 This...

  15. Chemical Kinetic Models for Advanced Engine Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Models for Advanced Engine Combustion William J. Pitz (PI) Marco Mehl, Charles K. Westbrook Lawrence Livermore National Laboratory June 17, 2014 DOE National Laboratory Advanced...

  16. Engine Valve Actuation For Combustion Enhancement

    DOE Patents [OSTI]

    Reitz, Rolf Deneys (Madison, WI); Rutland, Christopher J. (Madison, WI); Jhavar, Rahul (Madison, WI)

    2004-05-18T23:59:59.000Z

    A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-stroke combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

  17. Engine valve actuation for combustion enhancement

    DOE Patents [OSTI]

    Reitz, Rolf Deneys (Madison, WI); Rutland, Christopher J. (Madison, WI); Jhavar, Rahul (Madison, WI)

    2008-03-04T23:59:59.000Z

    A combustion chamber valve, such as an intake valve or an exhaust valve, is briefly opened during the compression and/or power strokes of a 4-strokes combustion cycle in an internal combustion engine (in particular, a diesel or CI engine). The brief opening may (1) enhance mixing withing the combustion chamber, allowing more complete oxidation of particulates to decrease engine emissions; and/or may (2) delay ignition until a more desirable time, potentially allowing a means of timing ignition in otherwise difficult-to-control conditions, e.g., in HCCI (Homogeneous Charge Compression Ignition) conditions.

  18. Sandia National Laboratories: Internal Combustion Engine Division...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Internal Combustion Engine Division conference CRF Researchers Received "Best Paper" Award for Paper Presented at American Society of Mechanical Engineers' (ASME) 2012 Internal...

  19. Sandia National Laboratories: internal combustion engine fuel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    internal combustion engine fuel efficiency Measurements of Thermal Stratification in a Homogenous Charge Compression Ignition Engine On February 27, 2013, in CRF, Energy,...

  20. Plasmatron Fuel Reformer Development and Internal Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications* L. Bromberg MIT Plasma Science and Fusion Center Cambridge MA 02139 * Work supported by US...

  1. Sandia National Laboratories: Engine Combustion Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engine Combustion Network Lyle Pickett Named a Society of Automotive Engineers Fellow On October 22, 2013, in CRF, Energy, Facilities, News, News & Events, Transportation Energy...

  2. Fuels For Advanced Combustion Engines (FACE)

    Broader source: Energy.gov (indexed) [DOE]

    Fuels For Advanced Combustion Engines (FACE) Presented by: Scott Sluder, Ron Graves, John Storey Oak Ridge National Laboratory Brad Zigler, Wendy Clark National Renewable Energy...

  3. Sandia National Laboratories: extend the complete combustion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extend the complete combustion zone Sandia Maps Multiple Paths to Cleaner, Low-Temp Diesels On October 22, 2013, in CRF, Energy, Facilities, News, News & Events, Partnership,...

  4. 2008-01-0984 Active Combustion Control of Diesel HCCI Engine: Combustion

    E-Print Network [OSTI]

    2008-01-0984 Active Combustion Control of Diesel HCCI Engine: Combustion Timing M. Hillion, J according to the air path dynamics on a Diesel HCCI engine. This approach complements existing airpath Com- bustion modes (HPC), including Homogeneous Charge Com- pression Ignition (HCCI). HCCI combustion

  5. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    2003-06-24T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  6. Photodissociation Dynamics and Spectroscopy of Free Radical Combustion Intermediates

    E-Print Network [OSTI]

    Osborn, David L.

    2010-01-01T23:59:59.000Z

    F. L . Dryer, Progr. Energy Combustion Sei. 10,1 (1984); W.1994); S. Zabarnick, Combustion Flame 85,27 (1991); D. B.81,2514 (1977). J. Warnatz, Combustion Chemistry, ed. W. C.

  7. COMBUSTION DIAGNOSTICS BY TUNABLE ATOMIC LINE MOLECULAR SPECTROSCOPY

    E-Print Network [OSTI]

    Cuellar, Enrique

    2014-01-01T23:59:59.000Z

    17th Symp. (Int. ) Combustion, 867 (1979). 3. H. Koizumi, T.Meetin~OCUM£ T of the Combustion Institute, Bordeaux,N S July 20-25, 1981 AND COMBUSTION DIAGNOSTICS BY TUNABLE

  8. Physical aspects and modelling of turbulent MILD combustion

    E-Print Network [OSTI]

    Minamoto, Yuki

    2014-02-04T23:59:59.000Z

    Moderate or Intense Low-oxygen Dilution (MILD) combustion is one of combustion technologies which can improve efficiency and reduce emissions simultaneously. This combustion type is characterised by the highly preheated reactant temperature...

  9. AN EXPERIMENTAL AND THEORETICAL STUDY OF HEAT TRANSFER WITH COMBUSTION

    E-Print Network [OSTI]

    Heperkan, Hasan A.

    2013-01-01T23:59:59.000Z

    HDyna.mics of the Exothermic Process in Combustion,n 15thSymposium (International) on Combustion, Tokyo, 1974. H, S.Methods L Glassman, Combustion, Academic Press, 1977. D. J.

  10. NUMERICAL MODELING OF TURBULENT FLOW IN A COMBUSTION TUNNEL

    E-Print Network [OSTI]

    Ghoniem, A.F.

    2013-01-01T23:59:59.000Z

    1VJcDona·ld, H. (1979) Combustion r 1 iodeJ·ing in Two and1979) Practical Turbulent-Combustion Interaction Models forInternation on Combustors. Combustion The 17th Symposium

  11. An Energy Analysis of the Catalytic Combustion Burner

    E-Print Network [OSTI]

    Dong, Q.; Zhang, S.; Duan, Z.; Zhou, Q.

    2006-01-01T23:59:59.000Z

    The gas boilers of conventional flame always produce varying degrees of combustion products NOx and CO, which pollute the environment and waste energy. As a new way of combustion, catalytic combustion breaks the flammable limits of conventional...

  12. Vehicle Technologies Office: 2009 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Advanced Combustion R&D Annual Progress Report Vehicle Technologies Office: 2009 Advanced Combustion R&D Annual Progress Report The Advanced Combustion Engine R&D subprogram...

  13. COMBUSTION RESEARCH PROGRAM. CHAPTER FROM ENERGY & ENVIRONMENT ANNUAL REPORT 1977

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    Applied to Turbulent Combustion Flows J. W. Daily and C.Metals from Pulverized Coal Combustion P. Sherman and F.Applied to Turbulent Combustion Flows J. W. Daily and C.

  14. Sub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments

    E-Print Network [OSTI]

    Walter, M.Todd

    -dependent, sphero-symmetric droplet combustion simulation that includes detailed gas phase chemical kineticsSub-millimeter sized methyl butanoate droplet combustion: Microgravity experiments and detailed 2012 Abstract Combustion characteristics of isolated sub-millimeter sized methyl butanoate (MB

  15. Pulsed atmospheric fluidized bed combustion

    SciTech Connect (OSTI)

    Not Available

    1989-11-01T23:59:59.000Z

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  16. Carbon-Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond

    E-Print Network [OSTI]

    Jones, William D.

    esters in the presence of trialkylphosphines to give -allyl addition products.2 Acetate and benzoate-O oxidative addition to give -allyl products. Vinyl esters (acetate and benzoate) were also reported of the solution. Reaction with Allyl Acetate. Treatment of 1 with 10 equiv of allyl acetate in p-xylene-d10 at 160

  17. Theoretical studies of combustion dynamics

    SciTech Connect (OSTI)

    Bowman, J.M. [Emory Univ., Atlanta, GA (United States)

    1993-12-01T23:59:59.000Z

    The basic objectives of this research program are to develop and apply theoretical techniques to fundamental dynamical processes of importance in gas-phase combustion. There are two major areas currently supported by this grant. One is reactive scattering of diatom-diatom systems, and the other is the dynamics of complex formation and decay based on L{sup 2} methods. In all of these studies, the authors focus on systems that are of interest experimentally, and for which potential energy surfaces based, at least in part, on ab initio calculations are available.

  18. Single event kinetic modeling of solid acid alkylation of isobutane with butenes over proton-exchanged Y-Zeolites 

    E-Print Network [OSTI]

    Martinis Coll, Jorge Maximiliano

    2006-04-12T23:59:59.000Z

    Complex reaction kinetics of the solid acid alkylation of isobutane with butenes over a proton-exchanged Y-zeolite has been modeled at the elementary step level. Starting with a computer algorithm that generated the reaction ...

  19. Single event kinetic modeling of solid acid alkylation of isobutane with butenes over proton-exchanged Y-Zeolites

    E-Print Network [OSTI]

    Martinis Coll, Jorge Maximiliano

    2006-04-12T23:59:59.000Z

    runs. An experimental investigation of the solid acid alkylation process was carried out in a fixed bed catalytic reactor operating with an excess of isobutane under isothermal conditions at moderate temperatures (353-393 K) in liquid phase...

  20. Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

    E-Print Network [OSTI]

    Fu, Gregory C.

    The first Suzuki cross-couplings of unactivated tertiary alkyl electrophiles are described. The method employs a readily accessible catalyst (NiBr[subscript 2]·diglyme/4,4?-di-tert-butyl-2,2?-bipyridine, both commercially ...

  1. Nuclear magnetic resonance (N.M.R.) studies of alkyl formates and of alcohol-water azeotropes

    E-Print Network [OSTI]

    O'Brien, Patrick William

    1966-01-01T23:59:59.000Z

    NUCLEAR MAGNETIC RESONANCE (N. M. R. ) STUDIES OF ALKYL FORMATES AND OF ALCOHOL-WATER AZEOTROPES A Thesis By PATRICK WILLIAM O' BRIEN Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE January 1966 Major Subject: Chemistry NUCLEAR MAGNETIC RESONANCE (N. M. R. ) STUDIES OF ALKYL FORMATES AND OF ALCOHOL-WATER AZEOTROPES A Thesis By PATRICK WILLIAM O' BRIEN Approved as to style and content by...

  2. Dry low NOx combustion system with pre-mixed direct-injection secondary fuel nozzle

    DOE Patents [OSTI]

    Zuo, Baifang; Johnson, Thomas; Ziminsky, Willy; Khan, Abdul

    2013-12-17T23:59:59.000Z

    A combustion system includes a first combustion chamber and a second combustion chamber. The second combustion chamber is positioned downstream of the first combustion chamber. The combustion system also includes a pre-mixed, direct-injection secondary fuel nozzle. The pre-mixed, direct-injection secondary fuel nozzle extends through the first combustion chamber into the second combustion chamber.

  3. Alkylation of mixed olefins with isobutane in a stratco chemical reactor

    SciTech Connect (OSTI)

    Vichailak, M. [ABB Lummus Global Inc., Houston, TX (United States); Hopper, J.R.; Yaws, C.L. [Lamar Univ., Beaumont, TX (United States); Pike, R.W. [Louisiana State Univ., Baton Rouge, LA (United States)

    1996-12-31T23:59:59.000Z

    The 17 reaction model for the sulfuric acid alkylation of isobutane with propylene as proposed by Langley and Pike has been used to simulate the effluent refrigeration reactor. The simulation conditions selected to minimize the formation of light and heavy by-product were determined to be: Temperature: 9 - 10 {degrees}C,- Isobutane/Olefin Ratio: 8 - 10; % Volume of Acid: 50 %. The reactor effluent composition from the simulation program has been used to compare with several sets of published data with reasonable agreement. This model has been extrapolated to simulate the alkylation of isobutane with butylenes and amylenes. The model will be optimized with commercial data. 9 refs., 6 figs., 1 tab.

  4. Solid catalyzed isoparaffin alkylation at supercritical fluid and near-supercritical fluid conditions

    DOE Patents [OSTI]

    Ginosar, Daniel M. (Idaho Falls, ID); Fox, Robert V. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2000-01-01T23:59:59.000Z

    This invention relates to an improved method for the alkylation reaction of isoparaffins with olefins over solid catalysts including contacting a mixture of an isoparaffin, an olefin and a phase-modifying material with a solid acid catalyst member under alkylation conversion conditions at either supercritical fluid, or near-supercritical fluid conditions, at a temperature and a pressure relative to the critical temperature(T.sub.c) and the critical pressure(P.sub.c) of the reaction mixture. The phase-modifying phase-modifying material is employed to promote the reaction's achievement of either a supercritical fluid state or a near-supercritical state while simultaneously allowing for decreased reaction temperature and longer catalyst life.

  5. US DRIVE Advanced Combustion and Emission Control Technical Team...

    Energy Savers [EERE]

    Advanced Combustion and Emission Control Technical Team Roadmap US DRIVE Advanced Combustion and Emission Control Technical Team Roadmap The ACEC focuses on advanced engine and...

  6. Adaptive Control to Improve Low Temperature Diesel Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control to Improve Low Temperature Diesel Engine Combustion Adaptive Control to Improve Low Temperature Diesel Engine Combustion Presentation given at DEER 2006, August 20-24,...

  7. Modeling Combustion Control for High Power Diesel Mode Switching...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Control for High Power Diesel Mode Switching Modeling Combustion Control for High Power Diesel Mode Switching Poster presentation given at the 16th Directions in...

  8. Heavy-Duty Low Temperature Combustion Development Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Development Activities at Caterpillar Heavy-Duty Low Temperature Combustion Development Activities at Caterpillar Presentation given at the 2007 Diesel...

  9. Cylinder Head Gasket with Integrated Combustion Pressure Sensors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cylinder Head Gasket with Integrated Combustion Pressure Sensors Cylinder Head Gasket with Integrated Combustion Pressure Sensors Poster presented at the 16th Directions in...

  10. Sandia National Laboratories: high-fidelity engine combustion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    engine combustion models Direct Measurement of Key Molecule Will Increase Accuracy of Combustion Models On March 3, 2015, in Computational Modeling & Simulation, CRF, Energy,...

  11. asme internal combustion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conference on Fluidised Bed Combustion Fossil Fuels Websites Summary: COMBUSTION OF HIGH-PVC SOLID WASTE WITH HCl RECOVERY Loay Saeed, Antti Tohka, Ron Zevenhoven*...

  12. Vehicle Technologies Office: Materials for High-Efficiency Combustion...

    Office of Environmental Management (EM)

    High-Efficiency Combustion Engines Vehicle Technologies Office: Materials for High-Efficiency Combustion Engines The Vehicle Technologies Office (VTO) is supporting work to improve...

  13. Vehicle Technologies Office: 2008 Advanced Combustion R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion R&D Annual Progress Report Vehicle Technologies Office: 2008 Advanced Combustion R&D Annual Progress Report 2008advcombustionengine.pdf More Documents & Publications...

  14. Advanced Post-Combustion CO2 Capture Prepared for the

    E-Print Network [OSTI]

    Advanced Post-Combustion CO2 Capture Prepared for the Clean Air Task Force under a grant from...................................................................................... 3 2. Current Status of Post-Combustion Capture

  15. World's Largest Post-Combustion Carbon Capture Project Begins...

    Office of Environmental Management (EM)

    World's Largest Post-Combustion Carbon Capture Project Begins Construction World's Largest Post-Combustion Carbon Capture Project Begins Construction July 15, 2014 - 9:55am Addthis...

  16. Enabling Low Temperature Combustion Through Thermo-Chemical Recuperati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Through Thermo-Chemical Recuperation Enabling Low Temperature Combustion Through Thermo-Chemical Recuperation Poster presentation from the 2007 Diesel...

  17. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and...

  18. Non-Petroleum Based Fuel Effects on Advanced Combustion (Agreement...

    Energy Savers [EERE]

    Petroleum Based Fuel Effects on Advanced Combustion (Agreement 13425) Non-Petroleum Based Fuel Effects on Advanced Combustion (Agreement 13425) Presentation from the U.S. DOE...

  19. High-Efficiency Clean Combustion Engine Designs for Compression...

    Energy Savers [EERE]

    High-Efficiency Clean Combustion Engine Designs for Compression Ignition Engines High-Efficiency Clean Combustion Engine Designs for Compression Ignition Engines Presentation from...

  20. Dilute Clean Diesel Combustion Achieves Low Emissions and High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dilute Clean Diesel Combustion Achieves Low Emissions and High Efficiency While Avoiding Control Problems of HCCI Dilute Clean Diesel Combustion Achieves Low Emissions and High...

  1. Low Temperature Combustion with Thermo-chemical Recuperation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion with Thermo-chemical Recuperation to Maximize In-use Engine Efficiency Low Temperature Combustion with Thermo-chemical Recuperation to Maximize In-use...

  2. Enabling High Efficiency Clean Combustion with Micro-Variable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel Injector and Adaptive PCCI Enabling High Efficiency Clean Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel...

  3. Complete Fuel Combustion for Diesel Engines Resulting in Greatly...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Complete Fuel Combustion for Diesel Engines Resulting in Greatly Reduced Emissions and Improved Fuel Efficiency Complete Fuel Combustion for Diesel Engines Resulting in Greatly...

  4. HCCI and Stratified-Charge CI Engine Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charg HCCI and Stratified-Char e CI Engine ge CI Engine Combustion Research Combustion Research John E. Dec, Magnus Sjberg, and Wontae Hwang Sandia National Laboratories DOE...

  5. A University Consortium on Low Temperature Combustion (LTC) for...

    Energy Savers [EERE]

    A University Consortium on Low Temperature Combustion (LTC) for High Efficiency, Ultra-Low Emission Engines A University Consortium on Low Temperature Combustion (LTC) for High...

  6. 2.61 Internal Combustion Engines, Spring 2004

    E-Print Network [OSTI]

    Heywood, John B.

    Fundamentals of how the design and operation of internal combustion engines affect their performance, operation, fuel requirements, and environmental impact. Study of fluid flow, thermodynamics, combustion, heat transfer ...

  7. Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Optimization for High Thermal Efficiency Targeting EPA 2010 Emissions Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency Targeting EPA 2010 Emissions...

  8. CFD Combustion Modeling with Conditional Moment Closure using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry CFD Combustion Modeling with Conditional Moment Closure using Tabulated Chemistry A method is...

  9. Advancement in Fuel Spray and Combustion Modeling for Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine Applications Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine...

  10. Improving Combustion Software to Solve Detailed Chemical Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Software to Solve Detailed Chemical Kinetics for HECC Improving Combustion Software to Solve Detailed Chemical Kinetics for HECC 2012 DOE Hydrogen and Fuel Cells Program...

  11. High-Efficiency Clean Combustion Design for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Clean Combustion Design for Compression Ignition Engines High-Efficiency Clean Combustion Design for Compression Ignition Engines Presentation given at DEER 2006,...

  12. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  13. Exploring Advanced Combustion Regimes for Efficiency and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploring Advanced Combustion Regimes for Efficiency and Emissions Exploring Advanced Combustion Regimes for Efficiency and Emissions 2003 DEER Conference Presentation: Oak Ridge...

  14. Use of Low Cetane Fuel to Enable Low Temperature Combustion

    Broader source: Energy.gov [DOE]

    Document:  ace011_ciatti_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Steve CiattiPresenting Organization: Argonne National Laboratory (ANL...

  15. Code Gaps and Future Research Needs of Combustion Safety: Building...

    Energy Savers [EERE]

    Code Gaps and Future Research Needs of Combustion Safety: Building America Expert Meeting Update Code Gaps and Future Research Needs of Combustion Safety: Building America Expert...

  16. Particulate Produced from Advanced Combustion Operation in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produced from Advanced Combustion Operation in a Compression Ignition Engine Particulate Produced from Advanced Combustion Operation in a Compression Ignition Engine Determine...

  17. Factors Affecting HCCI Combustion Phasing for Fuels with Single...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004...

  18. 2014 Annual Merit Review Results Report - Advanced Combustion...

    Energy Savers [EERE]

    Advanced Combustion Engine Technologies 2014 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research...

  19. 3-D Combustion Simulation Strategy Status, Future Potential,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Simulation Strategy Status, Future Potential, and Application Issues 3-D Combustion Simulation Strategy Status, Future Potential, and Application Issues 2004 Diesel...

  20. Demonstrating Optimum HCCI Combustion with Advanced Control Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimum HCCI Combustion with Advanced Control Technology Demonstrating Optimum HCCI Combustion with Advanced Control Technology Presentation given at the 2007 Diesel...

  1. Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assisted Diesel Combustion in a Common Rail Turbodiesel Engine Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine This study measured the effects of hydrogen...

  2. Combustion, Efficiency, and Fuel Effects in a Spark-Assisted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine Combustion, Efficiency, and Fuel Effects in a Spark-Assisted HCCI Gasoline Engine 2004 Diesel...

  3. Catalyst for Improving the Combustion Efficiency of Petroleum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines Catalyst for Improving the Combustion Efficiency of Petroleum Fuels in Diesel Engines 2005 Diesel...

  4. Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel Engines Glow Plug Integrated Piezo-Ceramic Combustion Sensor for Diesel Engines 2005 Diesel Engine Emissions...

  5. Accurate Predictions of Fuel Effects on Combustion and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry Accurate Predictions of Fuel Effects on Combustion...

  6. A University Consortium on High Pressure, Lean Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure, Lean Combustion for Efficient and Clean IC Engines (UM - lead, MIT, UCB) A University Consortium on High Pressure, Lean Combustion for Efficient and Clean IC Engines...

  7. Computationally Efficient Modeling of High-Efficiency Clean Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines...

  8. Fuel Effects on Ignition and Their Impact on Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ignition and Their Impact on Advanced Combustion Engines Fuel Effects on Ignition and Their Impact on Advanced Combustion Engines Presentation given at DEER 2006, August 20-24,...

  9. 2011 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2011 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research...

  10. 2012 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2012 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research...

  11. 2008 Annual Merit Review Results Summary - 7. Combustion Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7. Combustion Research 2008 Annual Merit Review Results Summary - 7. Combustion Research DOE Vehicle Technologies Annual Merit Review 2008meritreview7.pdf More Documents &...

  12. 2013 Annual Merit Review Results Report - Advanced Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engine Technologies 2013 Annual Merit Review Results Report - Advanced Combustion Engine Technologies Merit review of DOE Vehicle Technologies research...

  13. Large Eddy Simulation (LES) Applied to Advanced Engine Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    Flow Research - 8353 Combustion Chemistry - 8362 Engine Combustion - 8365 ThermalFluid Science and Engineering * Professor W. Anderson, Purdue * Professor J. -Y. Chen, UC...

  14. Large Eddy Simulation (LES) Applied to Advanced Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Engine Combustion Research Large Eddy Simulation (LES) Applied to Advanced Engine Combustion Research 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  15. Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel...

    Broader source: Energy.gov (indexed) [DOE]

    Assisted Diesel Combustion in a Common Rail Turbodiesel Engine P-3 Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine P-3 Gregory Lilik, Jos Martn...

  16. Heavy-Duty Low Temperature Combustion Development Activities...

    Broader source: Energy.gov (indexed) [DOE]

    combustion Develop a fundamental understanding of low-temperature combustion process Collaborate with technology experts Optical Engine Testing with Sandia National...

  17. 2008 DOE Annual Merit Review Advanced Combustion Engines and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion Engines and Fuels R&DTechnology Integration Plenary Session Overview 2008 DOE Annual Merit Review Advanced Combustion Engines and Fuels R&DTechnology...

  18. Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines

    Broader source: Energy.gov [DOE]

    Document:  ace012_flowers_2013_o.pdfTechnology Area: Advanced Combustion; Combustion and Emissions ControlPresenter: Dan FlowersPresenting Organization: Lawrence Livermore National Laboratory (LLNL...

  19. active combustion control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1999-01-01 3 2008-01-0984 Active Combustion Control of Diesel HCCI Engine: Combustion Energy Storage, Conversion and Utilization Websites Summary: strategies focus on...

  20. Vehicle Technologies Office Merit Review 2014: Internal Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    4: Internal Combustion Engine Energy Retention (ICEER) Vehicle Technologies Office Merit Review 2014: Internal Combustion Engine Energy Retention (ICEER) Presentation given by...

  1. Fuel Formulation Effects on Diesel Fuel Injection, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission...

  2. AMO Fuel and Feedstock Flexibility: Fuel-Flexible Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    AMO Fuel and Feedstock Flexibility: Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters AMO Fuel and Feedstock Flexibility: Fuel-Flexible Combustion...

  3. Enabling High Efficiency Low Temperature Combustion by Adaptive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion by Adaptive In-Situ Jet Cooling Enabling High Efficiency Low Temperature Combustion by Adaptive In-Situ Jet Cooling A new approach, called...

  4. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Simulation of Natural Gas HCCI Combustion: Gas CompositionPeroxide (DTBP) Additive on HCCI Combustion of Fuel BlendsCharge Compression Ignition (HCCI) Engines: Key Research and

  5. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters -...

  6. CRADA with Cummins on Characterization and Reduction of Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cummins on Characterization and Reduction of Combustion Variations CRADA with Cummins on Characterization and Reduction of Combustion Variations 2012 DOE Hydrogen and Fuel Cells...

  7. alternative combustion regimes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is a Novel Materials Science Websites Summary: Systems Not suitable for nano-material synthesis Reactive Sample Volume Combustion Product Heaters Self Combustion Product:...

  8. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis...

  9. Unregulated Emissions from High-Efficiency Clean Combustion Modes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Unregulated Emissions from High-Efficiency Clean Combustion Modes - ORNL-FEERC Poster presentation at...

  10. Idling Emissions Reduction Technology with Low Temperature Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Idling Emissions Reduction Technology with Low Temperature Combustion of DI Biodiesel and PFI n-Butanol Idling Emissions Reduction Technology with Low Temperature Combustion of DI...

  11. Syngas Enhanced High Efficiency Low Temperature Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

  12. Advanced High Efficiency Clean Diesel Combustion with Low Cost...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Combustion with Micro-Variable Circular-Orifice (MVCO) Fuel Injector and Adaptive PCCI Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines...

  13. Evaluation of High Efficiency Clean Combustion (HECC) Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean Combustion (HECC) Strategies for Meeting Future Emissions Regulations in Light-Duty Engines Evaluation of High Efficiency Clean Combustion (HECC) Strategies for Meeting...

  14. Particulate Produced from Advanced Combustion Operation in a...

    Broader source: Energy.gov (indexed) [DOE]

    Produced From Advanced Combustion Operation in a Compression Ignition Engine P-1 Particulate Produced From Advanced Combustion Operation in a Compression Ignition Engine P-1...

  15. NETL- High-Pressure Combustion Research Facility

    ScienceCinema (OSTI)

    None

    2014-06-26T23:59:59.000Z

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  16. Sandia combustion research program: Annual report, 1987

    SciTech Connect (OSTI)

    Palmer, R.E.; Sanders, B.R.; Ivanetich, C.A. (eds.)

    1988-01-01T23:59:59.000Z

    More than a decade ago, in response to a national energy crisis, Sandia proposed to the US Department of Energy a new, ambitious program in combustion research. Our strategy was to apply the rapidly increasing capabilities in lasers and computers to combustion science and technology. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''User Facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative--involving US universities, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions of several research projects which have been stimulated by Working Groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship Program has been instrumental in the success of some of the joint efforts. The remainder of this report presents research results of calendar year 1987, separated thematically into nine categories. Refereed journal articles appearing in print during 1987, along with selected other publications, are included at the end of Section 10. In addition to our ''traditional'' research--chemistry, reacting flow, diagnostics, engine combustion, and coal combustion--you will note continued progress in somewhat recent themes: pulse combustion, high temperature materials, and energetic materials, for example. Moreover, we have just started a small, new effort to understand combustion-related issues in the management of toxic and hazardous materials.

  17. Injector tip for an internal combustion engine

    DOE Patents [OSTI]

    Shyu, Tsu Pin; Ye, Wen

    2003-05-20T23:59:59.000Z

    This invention relates to a the tip structure of a fuel injector as used in a internal combustion engine. Internal combustion engines using Homogeneous Charge Compression Ignition (HCCI) technology require a tip structure that directs fuel spray in a downward direction. This requirement necessitates a tip design that is capable of withstanding mechanical stresses associated with the design.

  18. FLUIDIZED BED COMBUSTION UNIT FOR OIL SHALE

    E-Print Network [OSTI]

    M. Hammad; Y. Zurigat; S. Khzai; Z. Hammad; O. Mubydeem

    A fluidized bed combustion unit has been designed and installed to study the fluidized bed combustion performance using oil shale as fuel in direct burning process. It is a steel column of 18 cm inside diameter and 130 cm height fitted with a perforated plate air distributor of 611 holes, each of 1

  19. Method and system for controlled combustion engines

    DOE Patents [OSTI]

    Oppenheim, A. K. (Berkeley, CA)

    1990-01-01T23:59:59.000Z

    A system for controlling combustion in internal combustion engines of both the Diesel or Otto type, which relies on establishing fluid dynamic conditions and structures wherein fuel and air are entrained, mixed and caused to be ignited in the interior of a multiplicity of eddies, and where these structures are caused to sequentially fill the headspace of the cylinders.

  20. NETL- High-Pressure Combustion Research Facility

    SciTech Connect (OSTI)

    None

    2013-07-08T23:59:59.000Z

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  1. Coal slurry combustion and technology. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1983-01-01T23:59:59.000Z

    Volume II contains papers presented at the following sessions of the Coal Slurry Combustion and Technology Symposium: (1) bench-scale testing; (2) pilot testing; (3) combustion; and (4) rheology and characterization. Thirty-three papers have been processed for inclusion in the Energy Data Base. (ATT)

  2. Sensitivity Analysis of Combustion Timing of Homogeneous

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    to predict the start of combustion in a homogeneous charge compression ignition (HCCI) engine. Qualitative and quantitative information on the individual effects of fuel and exhaust gas recirculation on the HCCI combustion-injection gasoline HCCI engine, we find that temperature is the dominant factor in determining the start

  3. A model for premixed combustion oscillations

    SciTech Connect (OSTI)

    Janus, M.C.; Richards, G.A.

    1996-09-01T23:59:59.000Z

    This paper describes a simulation based on a time dependent, nonlinear control volume analysis. The combustion is modeled as a well-stirred reactor having finite kinetics. Flow properties and species in the nozzle, combustion, and tailpipe regions are determined using a control volume formulation of the conservation equation.

  4. A hybrid 2-zone/WAVE engine combustion model for simulating combustion instabilities during dilute operation

    SciTech Connect (OSTI)

    Edwards, Kevin Dean [ORNL; Wagner, Robert M [ORNL; Chakravarthy, Veerathu K [ORNL; Daw, C Stuart [ORNL; Green Jr, Johney Boyd [ORNL

    2006-01-01T23:59:59.000Z

    Internal combustion engines are operated under conditions of high exhaust gas recirculation (EGR) to reduce NO x emissions and promote enhanced combustion modes such as HCCI. However, high EGR under certain conditions also promotes nonlinear feedback between cycles, leading to the development of combustion instabilities and cyclic variability. We employ a two-zone phenomenological combustion model to simulate the onset of combustion instabilities under highly dilute conditions and to illustrate the impact of these instabilities on emissions and fuel efficiency. The two-zone in-cylinder combustion model is coupled to a WAVE engine-simulation code through a Simulink interface, allowing rapid simulation of several hundred successive engine cycles with many external engine parametric effects included. We demonstrate how this hybrid model can be used to study strategies for adaptive feedback control to reduce cyclic combustion instabilities and, thus, preserve fuel efficiency and reduce emissions.

  5. Identification of the Wax Ester Synthase/Acyl-Coenzyme A:Diacylglycerol Acyltransferase WSD1 Required for

    E-Print Network [OSTI]

    Kunst, Ljerka

    Identification of the Wax Ester Synthase/Acyl-Coenzyme A:Diacylglycerol Acyltransferase WSD1 Required for Stem Wax Ester Biosynthesis in Arabidopsis1,2[W][OA] Fengling Li, Xuemin Wu, Patricia Lam Columbia, Canada V6T 1Z1 (R.J.) Wax esters are neutral lipids composed of aliphatic alcohols and acids

  6. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

    2012-01-01T23:59:59.000Z

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?¢ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?¢ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?¢ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?¢ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?¢ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?¢ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

  7. Alkyl chain length-dependent surface reaction of dodecahydro-N-alkylcarbazoles on Pt model catalysts

    SciTech Connect (OSTI)

    Gleichweit, Christoph; Amende, Max; Bauer, Udo; Schernich, Stefan; Höfert, Oliver; Lorenz, Michael P. A.; Zhao, Wei; Bachmann, Philipp; Papp, Christian, E-mail: christian.papp@fau.de [Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany); Müller, Michael; Koch, Marcus [Lehrstuhl für Chemische Reaktionstechnik, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany); Wasserscheid, Peter [Lehrstuhl für Chemische Reaktionstechnik, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany); Erlangen Catalysis Resource Center, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany); Libuda, Jörg; Steinrück, Hans-Peter [Lehrstuhl für Physikalische Chemie II, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany); Erlangen Catalysis Resource Center, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)

    2014-05-28T23:59:59.000Z

    The concept of liquid organic hydrogen carriers (LOHC) holds the potential for large scale chemical storage of hydrogen at ambient conditions. Herein, we compare the dehydrogenation and decomposition of three alkylated carbazole-based LOHCs, dodecahydro-N-ethylcarbazole (H{sub 12}-NEC), dodecahydro-N-propylcarbazole (H{sub 12}-NPC), and dodecahydro-N-butylcarbazole (H{sub 12}-NBC), on Pt(111) and on Al{sub 2}O{sub 3}-supported Pt nanoparticles. We follow the thermal evolution of these systems quantitatively by in situ high-resolution X-ray photoelectron spectroscopy. We show that on Pt(111) the relevant reaction steps are not affected by the different alkyl substituents: for all LOHCs, stepwise dehydrogenation to NEC, NPC, and NBC is followed by cleavage of the C–N bond of the alkyl chain starting at 380–390 K. On Pt/Al{sub 2}O{sub 3}, we discern dealkylation on defect sites already at 350 K, and on ordered, (111)-like facets at 390 K. The dealkylation process at the defects is most pronounced for NEC and least pronounced for NBC.

  8. 2003 Laser Diagnostic in Combustion Conference

    SciTech Connect (OSTI)

    Mark G. Allen

    2004-09-10T23:59:59.000Z

    The GRC Laser Diagnostics in Combustion aims at bringing together scientists and engineers working in the front edge of research and development to discuss and find new ways to solve problems connected to combustion diagnostics. Laser-based techniques have proven to be very efficient tools for studying combustion processes thanks to features as non-intrusiveness in combination with high spatial and temporal resolution. Major tasks for the community are to develop and apply techniques for quantitative measurements with high precision e.g of species concentrations, temperatures, velocities and particles characteristics (size and concentration). These issues are of global interest, considering that the major part of the World's energy conversion comes from combustion sources and the influence combustion processes have on the environment and society.

  9. Second Law Analysis of Constant Temperature Diesel Combustion

    SciTech Connect (OSTI)

    Druecke, Dr. Ben [University of Wisconsin; Foster, Prof. Dave [University of Wisconsin; Klein, Prof. Sandy [University of Wisconsin; Daw, C Stuart [ORNL; Chakravarthy, Veerathu K [ORNL; Graves, Ronald L [ORNL

    2006-01-01T23:59:59.000Z

    The results from a second law analysis of a constant temperature diesel combustion process are presented and show that this process is not significantly more reversible than conventional combustion. In addition to quantifying the total availability destruction in combustion, the magnitudes of the combustion irreversibilities attributable to each irreversible subprocess (mixing, oxidation and internal heat transfer) were determined. The primary contributor to combustion irreversibilities is the thermal interaction of reacting and non-reacting species during the oxidation and internal thermal energy transfer subprocesses. Increasing combustion temperature significantly decreases availability destruction by making the oxidation and internal thermal energy transfer processes more reversible. While increasing combustion temperature decreases combustion irreversibility, it also results in an increase in exhaust temperature. A tradeoff exists between large availability destruction at low combustion temperatures and large amounts of availability discarded in the exhaust at high combustion temperatures. The optimum amount of work was found to occur for a combustion temperature of approximately 1600 K.

  10. A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS

    SciTech Connect (OSTI)

    Huggins, John Mitchell

    1980-06-01T23:59:59.000Z

    I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

  11. Quantitative relationships between structure and reactivity of aliphatic esters

    E-Print Network [OSTI]

    Yager, Billy Joe

    1960-01-01T23:59:59.000Z

    ~rity of' cstor and bsso s~lution (100 nl. ), 0. 02/76 ii &ol~rfty of nixture of' base and ester solution, 0. 01186 '! t, R& "inutco Qhm 1176 1/d x 10 (1/R 1/R ) x 10 1/t (1/2 - 1 ~Rt} x 1(P o 0 0, (~90' 7 9, 0 11. 0 1': 6 Q, ypCQ 1 940 Jg.... 210 1. 1$ 0, y~? -l. r4 0, 215 -O. g Wtc on i'. ethyl a b 0 1' 0. 00 -0. 'V -0, 67 1, 06 -0, 70 -1. 24 -1. 74 -2. 46 -0 69 (n-y) loC ~k 1 ~ 2iFgG 1, 169' d. 87l7 &47100 O. -fPjO 0. 1752 -0. 1700 a b a, :al'erenoe 5', roI'orenoo 9...

  12. Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

    2014-11-13T23:59:59.000Z

    Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packing—in the solid-state—to be scrutinized in detail.

  13. Combustion fume structure and dynamics

    SciTech Connect (OSTI)

    Flagan, R.C.

    1992-08-01T23:59:59.000Z

    The focus of this research program is on elucidating the fundamental processes that determine the particle size distribution, composition, and agglomerate structures of coal ash fumes. The ultimate objective of this work is the development and validation of a model for the dynamics of combustion fumes, describing both the evolution of the particle size distribution and the particle morphology. The study employs model systems to address the fundamental questions and to provide rigorous validation of the models to be developed. This first phase of the project has been devoted to the development of a detailed experimental strategy that will allow agglomerates with a broad range of fractal dimensions to be studied in the laboratory. (VC)

  14. Effect of alkyl glycerophosphate on the activation of peroxisome proliferator-activated receptor gamma and glucose uptake in C2C12 cells

    SciTech Connect (OSTI)

    Tsukahara, Tamotsu, E-mail: ttamotsu@shinshu-u.ac.jp [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Integrative Physiology and Bio-System Control, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Haniu, Hisao [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan)] [Department of Orthopedic Surgery, Shinshu University School of Medicine, 3-1-1 Asahi, Matsumoto, Nagano 390-8621 (Japan); Matsuda, Yoshikazu [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)] [Clinical Pharmacology Educational Center, Nihon Pharmaceutical University, Ina-machi, Saitama 362-0806 (Japan)

    2013-04-12T23:59:59.000Z

    Highlights: •Alkyl-LPA specifically interacts with PPAR?. •Alkyl-LPA treatments induces lipid accumulation in C2C12 cells. •Alkyl-LPA enhanced glucose uptake in C2C12 cells. •Alkyl-LPA-treated C2C12 cells express increased amounts of GLUT4 mRNA. •Alkyl-LPA is a novel therapeutic agent that can be used for the treatment of obesity and diabetes. -- Abstract: Studies on the effects of lipids on skeletal muscle cells rarely examine the effects of lysophospholipids. Through our recent studies, we identified select forms of phospholipids, such as alkyl-LPA, as ligands for the intracellular receptor peroxisome proliferator-activated receptor gamma (PPAR?). PPAR? is a nuclear hormone receptor implicated in many human diseases, including diabetes and obesity. We previously showed that alkyl-LPA is a specific agonist of PPAR?. However, the mechanism by which the alkyl-LPA–PPAR? axis affects skeletal muscle cells is poorly defined. Our objective in the present study was to determine whether alkyl-LPA and PPAR? activation promotes glucose uptake in skeletal muscle cells. Our findings indicate that PPAR?1 mRNA is more abundant than PPAR?2 mRNA in C2C12 cells. We showed that alkyl-LPA (3 ?M) significantly activated PPAR? and increased intracellular glucose levels in skeletal muscle cells. We also showed that incubation of C2C12 cells with alkyl-LPA led to lipid accumulation in the cells. These findings suggest that alkyl-LPA activates PPAR? and stimulates glucose uptake in the absence of insulin in C2C12 cells. This may contribute to the plasma glucose-lowering effect in the treatment of insulin resistance.

  15. Chaotic Combustion in Spark Ignition Engines

    E-Print Network [OSTI]

    M. Wendeker; J. Czarnigowski; G. Litak; K. Szabelski

    2002-12-27T23:59:59.000Z

    We analyse the combustion process in a spark ignition engine using the experimental data of an internal pressure during the combustion process and show that the system can be driven to chaotic behaviour. Our conclusion is based on the observation of unperiodicity in the time series, suitable stroboscopic maps and a complex structure of a reconstructed strange attractor. This analysis can explain that in some circumstances the level of noise in spark ignition engines increases considerably due to nonlinear dynamics of a combustion process.

  16. Annual Report: Advanced Combustion (30 September 2012)

    SciTech Connect (OSTI)

    Hawk, Jeffrey [NETL] [NETL; Richards, George

    2012-09-30T23:59:59.000Z

    The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

  17. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Section B (NIMB) Using Biofuel Tracers to Study Alternativeinjection. We investigate biofuel HCCI combustion, and use

  18. Pulse combustion: an assessment of opportunities for increased efficiency

    SciTech Connect (OSTI)

    Brenchley, D.L.; Bomelburg, H.J.

    1984-12-01T23:59:59.000Z

    The results of a literature review on pulse combustion are discussed. Current, near-future, and potential opportunities for pulse combustion applications are summarized, and the barriers to developing and using pulse combustion technology are discussed, along with research and development needs. Also provided are the proceedings of a pulse combustion workshop held in May, 1984 in Seattle, Washington. (LEW)

  19. Coal Combustion Science quarterly progress report, April--June 1990

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.

  20. Improved Economic Performance Municipal Solid Waste Combustion Plants

    E-Print Network [OSTI]

    Van den Hof, Paul

    Improved Economic Performance of Municipal Solid Waste Combustion Plants by Model Based Combustion Control #12;#12;Improved Economic Performance of Municipal Solid Waste Combustion Plants by Model Based-of-the-art and challenges in the operation of MSWC plants . . . 1 1.1.1 The aims of municipal solid waste combustion

  1. Using Biofuel Tracers to Study Alternative Combustion Regimes

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L.; Buchholz, Bruce A.; Dibble, Robert W.

    2006-01-01T23:59:59.000Z

    Internal Combustion Engines The methods described below for tracing fuel component carbon in the emissions

  2. Microwave-Assisted Ignition for Improved Internal Combustion Engine Efficiency

    E-Print Network [OSTI]

    DeFilippo, Anthony Cesar

    2013-01-01T23:59:59.000Z

    internal combustion engine applications. Advanced engines can achieve higher efficiencies and reduced emissions

  3. Progress in Energy and Combustion Science 34 (2008) 377416 Discrete reaction waves: Gasless combustion of solid powder mixtures

    E-Print Network [OSTI]

    Mukasyan, Alexander

    2008-01-01T23:59:59.000Z

    Progress in Energy and Combustion Science 34 (2008) 377­416 Discrete reaction waves: Gasless combustion of solid powder mixtures A.S. Mukasyana,Ã, A.S. Rogachevb a Department of Chemical Abstract This review considers a specific domain in combustion science, so-called discrete combustion waves

  4. Proceedings of the Combustion Institute, Volume 28, 2000/pp. 16631669 COMBUSTION CHEMISTRY OF PROPANE: A CASE STUDY OF DETAILED

    E-Print Network [OSTI]

    Wang, Hai

    1663 Proceedings of the Combustion Institute, Volume 28, 2000/pp. 1663­1669 COMBUSTION CHEMISTRY Detailed chemical reaction mechanisms describing hydrocarbon combustion chemistry are conceptually to small-hydrocarbon combustion data are secure foundations upon which to optimize the rate parameters

  5. Combustion, Explosion, and Shock Waves, Vol. 46, No. 3, pp. , 2010 Combustion of Heterogeneous Nanostructural Systems (Review)

    E-Print Network [OSTI]

    Mukasyan, Alexander

    Combustion, Explosion, and Shock Waves, Vol. 46, No. 3, pp. ­, 2010 Combustion of Heterogeneous submitted November 26, 2009. The current status of research in the field of combustion of heterogeneous mechanisms of combustion in such systems and prospects of their further applications are discussed. Key words

  6. BIBLIOGRAPHY ON INTERNAL COMBUSTION ENGINES 1. F. Obert, Internal Combustion Engines and Air Pollution, Intext Educational Publishers, 1973

    E-Print Network [OSTI]

    Goldwasser, Shafi

    BIBLIOGRAPHY ON INTERNAL COMBUSTION ENGINES 1. F. Obert, Internal Combustion Engines and Air, The Internal Combustion Engine, International Textbook Company, 1961. (A basic text now out of print and somewhat dated.) 3. C.F. Taylor, The Internal Combustion Engine in Theory and Practice. Volumes I and II, M

  7. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    tools for understanding fuel-property effects on - Combustion - Engine efficiency optimization - Emissions Partners Project lead: Sandia - C.J. Mueller (PI); C.J. Polonowski...

  8. Vortex driven flame dynamics and combustion instability

    E-Print Network [OSTI]

    Altay, Hurrem Murat

    2005-01-01T23:59:59.000Z

    Combustion instability in premixed combustors mostly arises due to the coupling between heat release rate dynamics and system acoustics. It is crucial to understand the instability mechanisms to design reliable, high ...

  9. Active combustion control : modeling, design and implementation

    E-Print Network [OSTI]

    Park, Sungbae, 1973-

    2004-01-01T23:59:59.000Z

    Continuous combustion systems common in propulsion and power generation applications are susceptible to thermoacoustic instability, which occurs under lean burn conditions close to the flammability where most emissions and ...

  10. Engine combustion control via fuel reactivity stratification

    DOE Patents [OSTI]

    Reitz, Rolf Deneys; Hanson, Reed M; Splitter, Derek A; Kokjohn, Sage L

    2013-12-31T23:59:59.000Z

    A compression ignition engine uses two or more fuel charges having two or more reactivities to control the timing and duration of combustion. In a preferred implementation, a lower-reactivity fuel charge is injected or otherwise introduced into the combustion chamber, preferably sufficiently early that it becomes at least substantially homogeneously dispersed within the chamber before a subsequent injection is made. One or more subsequent injections of higher-reactivity fuel charges are then made, and these preferably distribute the higher-reactivity matter within the lower-reactivity chamber space such that combustion begins in the higher-reactivity regions, and with the lower-reactivity regions following thereafter. By appropriately choose the reactivities of the charges, their relative amounts, and their timing, combustion can be tailored to achieve optimal power output (and thus fuel efficiency), at controlled temperatures (and thus controlled NOx), and with controlled equivalence ratios (and thus controlled soot).

  11. Two phase exhaust for internal combustion engine

    DOE Patents [OSTI]

    Vuk, Carl T. (Denver, IA)

    2011-11-29T23:59:59.000Z

    An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

  12. Coal Combustion By-Products (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment is responsible for regulating fugitive air emissions from the transportation of coal combustion by-products and the permissible beneficial uses of these by...

  13. Researchers create successful predictions of combustion reaction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    successful predictions of combustion reaction rates By Jared Sagoff * January 5, 2015 Tweet EmailPrint Researchers at the U.S. Department of Energy's Argonne and Sandia National...

  14. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    advanced control concepts and enabling system to manage multi-modemulti-fuel combustion events and achieve an up to 30 percent fuel economy improvement deer11yilmaz.pdf...

  15. Flex-flame burner and combustion method

    DOE Patents [OSTI]

    Soupos, Vasilios (Chicago, IL); Zelepouga, Serguei (Hoffman Estates, IL); Rue, David M. (Chicago, IL); Abbasi, Hamid A. (Naperville, IL)

    2010-08-24T23:59:59.000Z

    A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

  16. Fluid Bed Combustion Applied to Industrial Waste

    E-Print Network [OSTI]

    Mullen, J. F.; Sneyd, R. J.

    Because of its unique ability to handle a wide variety of liquids and solids in an energy efficient and environmentally acceptable manner, fluid bed combustion is being increasingly applied to the utilization of waste materials and low grade fuels...

  17. Smouldering Combustion Phenomena in Science and Technology 

    E-Print Network [OSTI]

    Rein, Guillermo

    Smouldering is the slow, low-temperature, flameless form of combustion of a condensed fuel. It poses safety and environmental hazards and allows novel technological application but its fundamentals remain mostly unknown ...

  18. Combustion characteristics of alternative liquid fuels

    E-Print Network [OSTI]

    Chong, Cheng Tung

    2011-11-08T23:59:59.000Z

    atomizer are investigated using a phase Doppler anemometry (PDA) under non-reacting conditions. The droplet size and velocity distribution of biodiesels are compared to conventional fuels. For spray combustion investigations, a generic gas turbine...

  19. Light-Duty Advanced Diesel Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    contains no proprietary or confidential information Light-Duty Advanced Diesel Combustion Research Program Manager: Gurpreet Singh, EERE-OVT M O F E Y D P A R T E N T N E E R...

  20. Control of NOx by combustion process modifications

    E-Print Network [OSTI]

    Ber?, J. M.

    1981-01-01T23:59:59.000Z

    A theoretical and experimental study was carried out to determine lower bounds of NOx emission from staged combustion of a 0.7%N #6 fuel oil. Thermodynamic and chemical kinetic calculations have shown minimum NOx emissions ...

  1. Improved Solvers for Advanced Engine Combustion Simulation

    Broader source: Energy.gov (indexed) [DOE]

    53560 Improved Solvers for Advanced Engine Combustion Simulation M. J. McNenly (PI), S. M. Aceves, D. L. Flowers, N. J. Killingsworth, G. M. Oxberry, G. Petitpas and R. A....

  2. Circulating Fluidized Bed Combustion Boiler Project

    E-Print Network [OSTI]

    Farbstein, S. B.; Moreland, T.

    1984-01-01T23:59:59.000Z

    The project to build a PYROFLOW circulating fluidized bed combustion (FBC) boiler at the BFGoodrich Chemical Plant at Henry, Illinois, is described. This project is being partially funded by Illinois to demonstrate the feasibility of utilizing high...

  3. Predicting combustion properties of hydrocarbon fuel mixtures

    E-Print Network [OSTI]

    Goldsmith, Claude Franklin, III

    2010-01-01T23:59:59.000Z

    In this thesis, I applied computational quantum chemistry to improve the accuracy of kinetic mechanisms that are used to model combustion chemistry. I performed transition state theory calculations for several reactions ...

  4. Combustion properties of Kraft Black Liquors

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

    1993-04-01T23:59:59.000Z

    In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.

  5. State of Fluidized Bed Combustion Technology

    E-Print Network [OSTI]

    Pope, M.

    1979-01-01T23:59:59.000Z

    A new combustion technology has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal EPA limits. Low quality fuels can be burned...

  6. Combustion systems for power-MEMS applications

    E-Print Network [OSTI]

    Spadaccini, Christopher M. (Christopher Michael), 1974-

    2004-01-01T23:59:59.000Z

    As part of an effort to develop a micro-scale gas turbine engine for power generation and micro-propulsion applications, this thesis presents the design, fabrication, experimental testing, and modeling of the combustion ...

  7. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  8. Oil shale retorting and combustion system

    DOE Patents [OSTI]

    Pitrolo, Augustine A. (Fairmont, WV); Mei, Joseph S. (Morgantown, WV); Shang, Jerry Y. (Fairfax, VA)

    1983-01-01T23:59:59.000Z

    The present invention is directed to the extraction of energy values from l shale containing considerable concentrations of calcium carbonate in an efficient manner. The volatiles are separated from the oil shale in a retorting zone of a fluidized bed where the temperature and the concentration of oxygen are maintained at sufficiently low levels so that the volatiles are extracted from the oil shale with minimal combustion of the volatiles and with minimal calcination of the calcium carbonate. These gaseous volatiles and the calcium carbonate flow from the retorting zone into a freeboard combustion zone where the volatiles are burned in the presence of excess air. In this zone the calcination of the calcium carbonate occurs but at the expense of less BTU's than would be required by the calcination reaction in the event both the retorting and combustion steps took place simultaneously. The heat values in the products of combustion are satisfactorily recovered in a suitable heat exchange system.

  9. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Broader source: Energy.gov (indexed) [DOE]

    * Baseline Powertrain: 3.6L V6, PFI, 6 Speed * Target Powertrain: 2.0L I4, DI, Turbo, 6 Speed -Multi Mode Combustion SIHCCI * 30% Fuel Economy Improvement Compared to...

  10. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Broader source: Energy.gov (indexed) [DOE]

    concepts. * Target Multi Mode Combustion Engine is based on the GM Ecotec 2.0 L DI Turbo platform * Base Engine HW design, improvements for target engine configuration and...

  11. Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities

    SciTech Connect (OSTI)

    Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

    2012-07-01T23:59:59.000Z

    Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

  12. Internal combustion engine and method for control

    DOE Patents [OSTI]

    Brennan, Daniel G

    2013-05-21T23:59:59.000Z

    In one exemplary embodiment of the invention an internal combustion engine includes a piston disposed in a cylinder, a valve configured to control flow of air into the cylinder and an actuator coupled to the valve to control a position of the valve. The internal combustion engine also includes a controller coupled to the actuator, wherein the controller is configured to close the valve when an uncontrolled condition for the internal engine is determined.

  13. Coal-Fired Fluidized Bed Combustion Cogeneration

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    COAL-FIRED FLUIDIZED BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed... combustion, has encouraged many steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However...

  14. Building America Expert Meeting: Combustion Safety

    SciTech Connect (OSTI)

    Brand, L.

    2013-03-01T23:59:59.000Z

    This is a meeting overview of 'The Best Approach to Combustion Safety in a Direct Vent World', held June 28, 2012, in San Antonio, Texas. The objective of this Expert Meeting was to identify gaps and barriers that need to be addressed by future research, and to develop data-driven technical recommendations for code updates so that a common approach for combustion safety can be adopted by all members of the building energy efficiency and code communities.

  15. Plug repairs of marine glass fiber / vinyl ester laminates subjected to uniaxial tension

    E-Print Network [OSTI]

    Michelis, Alexandros

    2009-01-01T23:59:59.000Z

    Glass fiber/vinyl ester composite laminates are currently being used and proposed for the hulls, bulkheads, and superstructures of large ships. This thesis examines the effectiveness of the repair of such laminates using ...

  16. Rapid Hydrolysis of Organophosphorous Esters Induced by Nanostructured, Fluorine-Doped Titania Replicas of Diatom Frustules

    E-Print Network [OSTI]

    Huang, Ching-Hua

    of the organophosphorous esters, methyl paraoxon (MOX), and methyl parathion (MTH) (Fig. 1), in the absence of light and at near neutral pH condi- tions. MOX and MTH are widely used insecticides in crop and fruit production

  17. Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides

    E-Print Network [OSTI]

    Biscoe, Mark R.

    Simple, efficient procedures for the monoarylation of acetate esters and aryl methyl ketones using aryl chlorides are presented. Previously, no general method was available to ensure the highly selective monoarylation of ...

  18. Coal Combustion Products Extension Program

    SciTech Connect (OSTI)

    Tarunjit S. Butalia; William E. Wolfe

    2006-01-11T23:59:59.000Z

    This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to 40% by 2010, the CCP Extension Program be expanded at OSU, with support from state and federal agencies, utilities, trade groups, and the university, to focus on the following four specific areas of promise: (a) Expanding use in proven areas (such as use of fly ash in concrete); (b) Removing or reducing regulatory and perceptual barriers to use (by working in collaboration with regulatory agencies); (c) Developing new or under-used large-volume market applications (such as structural fills); and (d) Placing greater emphasis on FGD byproducts utilization.

  19. Dust Combustion Safety Issues for Fusion Applications

    SciTech Connect (OSTI)

    L. C. Cadwallader

    2003-05-01T23:59:59.000Z

    This report summarizes the results of a safety research task to identify the safety issues and phenomenology of metallic dust fires and explosions that are postulated for fusion experiments. There are a variety of metal dusts that are created by plasma erosion and disruptions within the plasma chamber, as well as normal industrial dusts generated in the more conventional equipment in the balance of plant. For fusion, in-vessel dusts are generally mixtures of several elements; that is, the constituent elements in alloys and the variety of elements used for in-vessel materials. For example, in-vessel dust could be composed of beryllium from a first wall coating, tungsten from a divertor plate, copper from a plasma heating antenna or diagnostic, and perhaps some iron and chromium from the steel vessel wall or titanium and vanadium from the vessel wall. Each of these elements has its own unique combustion characteristics, and mixtures of elements must be evaluated for the mixture’s combustion properties. Issues of particle size, dust temperature, and presence of other combustible materials (i.e., deuterium and tritium) also affect combustion in air. Combustion in other gases has also been investigated to determine if there are safety concerns with “inert” atmospheres, such as nitrogen. Several coolants have also been reviewed to determine if coolant breach into the plasma chamber would enhance the combustion threat; for example, in-vessel steam from a water coolant breach will react with metal dust. The results of this review are presented here.

  20. A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

    SciTech Connect (OSTI)

    Wan, Shun [ORNL; Jiang, Xueguang [ORNL; Guo, Bingkun [ORNL; Dai, Sheng [ORNL; Sun, Xiao-Guang [ORNL

    2015-01-01T23:59:59.000Z

    A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

  1. Removal patterns of some alkyl phenyl ketones in a heterogeneous bacterial system

    E-Print Network [OSTI]

    Salitros, James Joseph

    1969-01-01T23:59:59.000Z

    never lrave been wri t ten, I can only say thank you. TABLE OF CONTENTS pacCe ABSTRACT ACKNONLEDGEMENTS iLIST OF TABLES LIST OF FIGURES SECTION I Introduction and Literature Review SECTION II Apparatus and Materials Reactor Gas Chromatograph... 2 3 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 3 0 Gas Gas Gas Gas Gas Gas Gas Gas Gas hyl Alkyl Gas Gas Gas Gas Chemical Nomenclature Inorganic i'Jutrients Test A. Reactor Conditions Test A...

  2. Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The US DOE pressurized fluidized bed combustion (PFBC) research and development program is designed to develop the technology and data base required for the successful commercialization of the PFBC concept. A cooperative program with the US, West Germany, and the UK has resulted in the construction of the 25 MWe IEA-Grimethorpe combined-cycle pilot plant in England which will be tested in 1981. A 13 MWe coal-fired gas turbine (air cycle) at Curtis-Wright has been designed and construction scheduled. Start-up is planned to begin in early 1983. A 75 MWe pilot plant is planned for completion in 1986. Each of these PFBC combined-cycle programs is discussed. The current status of PFB technology may be summarized as follows: turbine erosion tolerance/hot gas cleanup issues have emerged as the barrier technology issues; promising turbine corrosion-resistant materials have been identified, but long-term exposure data is lacking; first-generation PFB combustor technology development is maturing at the PDU level; however, scale-up to larger size has not been demonstrated; and in-bed heat exchanger materials have been identified, but long-term exposure data is lacking. The DOE-PFB development plan is directed at the resolution of these key technical issues. (LCL)

  3. Combustion kinetics and reaction pathways

    SciTech Connect (OSTI)

    Klemm, R.B.; Sutherland, J.W. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01T23:59:59.000Z

    This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

  4. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2010-01-01T23:59:59.000Z

    from Fuel Combustion in 2004.. 34Emissions from Fuel Combustion in California, Million MetricEmission Estimates from the Combustion of Fossil Fuels in

  5. An acoustic energy framework for predicting combustion- driven acoustic instabilities in premixed gas-turbines

    E-Print Network [OSTI]

    Ibrahim, Zuhair M. A.

    2007-01-01T23:59:59.000Z

    Swirl Vane Location on Combustion Dynamics," ASME Turbo-ExpoC.E. , " Passive Control of Combustion Instability in Lean2] Williams, F. A. , " Combustion Theory," Second ed. 1985,

  6. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    E-Print Network [OSTI]

    McMeeking, Gavin R.

    2009-01-01T23:59:59.000Z

    Emissions from laboratory combustion of wildland fuels:range transport of combustion-derived aerosols, Science,from the laboratory combustion of wildland fuels: Particle

  7. An Explicit Runge-Kutta Iteration for Diffusion in the Low Mach Number Combustion Code

    E-Print Network [OSTI]

    Grcar, Joseph F.

    2007-01-01T23:59:59.000Z

    usion in the Low Mach Number Combustion Code Joseph F. Grcarthe low Mach number combustion code. Contents 1 Introductionthe low Mach number combustion code, LMC. The multicomponent

  8. CATALYZED COMBUSTION IN A FLAT PLATE BOUNDARY LAYER II. NUMERICAL CALCULATIONS

    E-Print Network [OSTI]

    Schefer, R.

    2010-01-01T23:59:59.000Z

    D.G. , Fourteenth Sympo- sium (International) on Combustion,The Combustion Institute, Pittsburgh, 107 (1973). Wilson,Program for Calculation of Combustion Reaction Equilibrium

  9. CATALYZED COMBUSTION IN A FLAT PLATE BOUNDARY LAYER I. EXPERIMENTAL MEASUREMENTS AND COMPARISON WITH NUMERICAL CALCULATIONS

    E-Print Network [OSTI]

    Robben, R.

    2010-01-01T23:59:59.000Z

    l~ Roberts, "Catathermal Combustion: A New Process for Lm'l-significant gas phase combustion is induced by the presenceInternational) on Combustion (to be published), The

  10. THE COMBUSTION OF SOLVENT REPINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME

    E-Print Network [OSTI]

    Chin, W.K.

    2011-01-01T23:59:59.000Z

    pyrolysis of various polymers under combustion conditions.Fourteenth Symposium (International) on Combustion,The Combustion Institute Pittsburgh, 1177. Chin, W.K. and

  11. A Topological Framework for the Interactive Exploration of Large Scale Turbulent Combustion

    E-Print Network [OSTI]

    Bremer, Peer-Timo

    2010-01-01T23:59:59.000Z

    comparison of terascale combustion simulation data. Mathe-premixed hydrogen ?ames. Combustion and Flame, [7] J. L.of Large Scale Turbulent Combustion Peer-Timo Bremer 1 ,

  12. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    1973) Enthalpies of Combustion and Maximum Temperatures ofBurner Assembly Combustion Chamber Exhaust System. . CHAPTERIlMeasurement of NO and N02 in Combustion Systems," Western

  13. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion &...

  14. Application of Genetic Algorithms and Thermogravimetry to Determine the Kinetics of Polyurethane Foam in Smoldering Combustion

    E-Print Network [OSTI]

    Rein, Guillermo; Lautenberger, Chris; Fernandez-Pello, Carlos; Torero, Jose; Urban, David

    2006-01-01T23:59:59.000Z

    dimensional smoldering combustion. Figure 10. Results forModeling of Smoldering Combustion Propagation, Progressin Energy and Combustion Science 11, pp. 277-310. 2. T.J.

  15. Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II

    E-Print Network [OSTI]

    Rapp, Vi H.

    2014-01-01T23:59:59.000Z

    for Natural-Draft Gas Combustion Appliances: Validatingfor Natural-Draft Gas Combustion Appliances: A Validation ofs ability to predict combustion gas spillage events due to

  16. An acoustic energy framework for predicting combustion- driven acoustic instabilities in premixed gas-turbines

    E-Print Network [OSTI]

    Ibrahim, Zuhair M. A.

    2007-01-01T23:59:59.000Z

    During Premix Gas Turbine Combustion," Journal ofApplication to Gas-Turbine Combustion Instability Analysis,"Clavin, P. , " Premixed Combustion and Gas Dynamics," Annual

  17. COMBUSTION RESEARCH Chapter from the Energy and Environment Division Annual Report 1980

    E-Print Network [OSTI]

    Authors, Various

    2013-01-01T23:59:59.000Z

    the post- combustion environment of prototype oil fuels. Thein a laboratory combustion tunnel fired with light fuel oilsfuel oil. The tem- perature of the products of combustion

  18. Amine Degradation in CO2 Capture. 2. New degradation products of MEA. Pyrazine and alkyl pyrazines: analysis, mechanism of formation and toxicity.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Amine Degradation in CO2 Capture. 2. New degradation products of MEA. Pyrazine and alkyl pyrazines Degradation in CO2 Capture. 2. New degradation products of MEA. Pyrazine and alkyl pyrazines: analysis degradation products, and some of them could be potentially dangerous to humans or environment according

  19. Theoretical Investigation of Benzene Alkylation with Ethene over H-ZSM-5 Niels Hansen,*, Till Bruggemann, Alexis T. Bell,*, and Frerich J. Keil

    E-Print Network [OSTI]

    Bell, Alexis T.

    Theoretical Investigation of Benzene Alkylation with Ethene over H-ZSM-5 Niels Hansen,*, Till Bru Benzene alkylation with ethene over zeolite H-ZSM-5 has been investigated using density functional theory with the formation of a stable ethoxide intermediate which subsequently reacts with benzene to form the reaction

  20. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    None

    2009-12-01T23:59:59.000Z

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.