National Library of Energy BETA

Sample records for alkali flat area

  1. Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado, USA August 2010 Jody K. Nelson PDF icon Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado, USA ...

  2. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    GEA Development Phase: Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean...

  3. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean Capacity: Click "Edit With...

  4. Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008...

    Open Energy Info (EERE)

    Mark Coolbaugh, Chris Sladek, Rick Zehner, Robin Penfield, Ben Delwiche (2008) A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  5. Data Acquisition Scan for Large Area Flat Panel Digital X-ray Detector Array

    Energy Science and Technology Software Center (OSTI)

    2004-05-01

    Interface large area flat panel digital detector and motion control system for computed tomographic data acquisition.

  6. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E.; Reed, William H.; Berkey, Edgar

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  7. 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open...

    Open Energy Info (EERE)

    Mark Coolbaugh, Chris Sladek, Rick Zehner, Robin Penfield, Ben Delwiche (2008) A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  8. Plutonium contamination in soils in open space and residential areas near Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Litaor, M.I.

    1999-02-01

    Spatial analysis of the {sup 240}Pu:{sup 239}Pu isotopic ratio of 42 soil samples collected around Rocky Flats Plant near Golden, Colorado, was conducted to assess the effect of Rocky Flats Plant activity on the soil environment. Two probability maps that quantified the uncertainty of the spatial distribution of plutonium isotopic ratios were constructed using the sequential Gaussian simulation technique (sGs). Assuming a plutonium isotopic ratio range of 0.152 {+-} 0.003 to 0.169 {+-} 0.009 is characteristic to global fallout in Colorado, and a mean value of 0.155 is representative for the Rocky Flats Plant area, the main findings of the current work were (1) the areas northwest and southwest of Rocky Flats Plant exhibited a plutonium ratio {ge}0.155, this were minimally impacted by the plant activity; (2) he study area east of Rocky Flats Plant exhibited a plutonium isotopic ratio {le}0.155, which is a definitive indicator of Rocky Flats Plant-derived plutonium; and (3) inventory calculations across the study area exhibited large standard error of estimates. These errors were originated from the high variability in plutonium activity over a small sampling scale and the uncertainty in the global fallout isotopic ratio. Using the mean simulated estimates of plutonium isotopic ratio, coupled with plutonium activity measured at 11 soil pits and additional plutonium information published elsewhere, the plutonium loading on the open space and residential areas amounted to 111.2 GBq, with a standard error of estimate of 50.8 GBq.

  9. Sub-crop geologic map of pre-Tertiary rocks in the Yucca Flat and northern Frenchman Flat areas, Nevada Test Site, southern Nevada

    SciTech Connect (OSTI)

    Cole, J.C.; Harris, A.G.; Wahl, R.R.

    1997-10-02

    for ground water flow through pre-Tertiary rocks beneath the Yucca Flat and northern Frenchman Flat areas, and has consequences for ground water modeling and model validation. Our data indicate that the Mississippian Chainman Shale is not laterally extensive confining unit in the western part of the basin because it is folded back onto itself by the convergent structures of the Belted Range and CP thrust systems. Early and Middle Paleozoic limestone and dolomite are present beneath most of both basins and, regardless of structural complications, are interpreted to form a laterally continuous and extensive carbonate aquifer. Structural culmination that marks the French Peak accommodation zone along the topographic divide between the two basins provides a lateral pathway through highly fractured rock between the volcanic aquifers of Yucca Flat and the regional carbonate aquifer. This pathway may accelerate the migration of ground-water contaminants introduced by underground nuclear testing toward discharge areas beyond the Nevada Test Site boundaries. Predictive three-dimensional models of hydrostratigraphic units and ground-water flow in the pre-Tertiary rocks of subsurface Yucca Flat are likely to be unrealistic due to the extreme structural complexities. The interpretation of hydrologic and geochemical data obtained from monitoring wells will be difficult to extrapolate through the flow system until more is known about the continuity of hydrostratigraphic units. 1 plate

  10. Vascular flora of the Rocky Flats area, Jefferson County, Colorado, USA

    SciTech Connect (OSTI)

    Nelson, Jody K.

    2010-08-01

    The Rocky Flats Site (Site) is a U.S. Department of Energy (DOE) facility near Golden, Colorado that produced nuclear weapons components during the Cold War. Like many federal properties that have been off-limits to public access for decades, it has become a refugia for biodiversity as surrounding landscapes have been lost to agriculture and urbanization. A floristic study of the area was conducted on approximately 2,505 ha (6,189 ac) and includes the parcels currently managed and operated by DOE and the U.S. Fish and Wildlife Service (Rocky Flats National Wildlife Refuge). A flora of 630 species of vascular plants in 84 families and 340 genera was documented, including 12 species endemic to the southern Rocky Mountains and seven species considered rare or imperiled by the Colorado Natural Heritage Program. The flora of the Site is characterized by a predominantly Western North American floristic element, however, an Adventive floristic element contributes the greatest number of species. The vegetation is dominated by xeric tallgrass prairie and mixed grass prairie, with areas of wetland, shrubland, and riparian woodland.

  11. Vascular flora of the Rocky Flats area, Jefferson County, Colorado, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nelson, Jody K.

    2010-08-01

    The Rocky Flats Site (Site) is a U.S. Department of Energy (DOE) facility near Golden, Colorado that produced nuclear weapons components during the Cold War. Like many federal properties that have been off-limits to public access for decades, it has become a refugia for biodiversity as surrounding landscapes have been lost to agriculture and urbanization. A floristic study of the area was conducted on approximately 2,505 ha (6,189 ac) and includes the parcels currently managed and operated by DOE and the U.S. Fish and Wildlife Service (Rocky Flats National Wildlife Refuge). A flora of 630 species of vascular plants inmore » 84 families and 340 genera was documented, including 12 species endemic to the southern Rocky Mountains and seven species considered rare or imperiled by the Colorado Natural Heritage Program. The flora of the Site is characterized by a predominantly Western North American floristic element, however, an Adventive floristic element contributes the greatest number of species. The vegetation is dominated by xeric tallgrass prairie and mixed grass prairie, with areas of wetland, shrubland, and riparian woodland.« less

  12. External Peer Review Team Report Underground Testing Area Subproject for Frenchman Flat, Revision 1

    SciTech Connect (OSTI)

    Sam Marutzky

    2010-09-01

    An external peer review was conducted to review the groundwater models used in the corrective action investigation stage of the Underground Test Area (UGTA) subproject to forecast zones of potential contamination in 1,000 years for the Frenchman Flat area. The goal of the external peer review was to provide technical evaluation of the studies and to assist in assessing the readiness of the UGTA subproject to progress to monitoring activities for further model evaluation. The external peer review team consisted of six independent technical experts with expertise in geology, hydrogeology,'''groundwater modeling, and radiochemistry. The peer review team was tasked with addressing the following questions: 1. Are the modeling approaches, assumptions, and model results for Frenchman Flat consistent with the use of modeling studies as a decision tool for resolution of environmental and regulatory requirements? 2. Do the modeling results adequately account for uncertainty in models of flow and transport in the Frenchman Flat hydrological setting? a. Are the models of sufficient scale/resolution to adequately predict contaminant transport in the Frenchman Flat setting? b. Have all key processes been included in the model? c. Are the methods used to forecast contaminant boundaries from the transport modeling studies reasonable and appropriate? d. Are the assessments of uncertainty technically sound and consistent with state-of-the-art approaches currently used in the hydrological sciences? 3. Are the datasets and modeling results adequate for a transition to Corrective Action Unit monitoring studies—the next stage in the UGTA strategy for Frenchman Flat? The peer review team is of the opinion that, with some limitations, the modeling approaches, assumptions, and model results are consistent with the use of modeling studies for resolution of environmental and regulatory requirements. The peer review team further finds that the modeling studies have accounted for uncertainty

  13. Interim Letter Report - Verification Survey of 19 Grids in the Lester Flat Area, David Witherspoon Inc. 1630 Site Knoxville, Tennessee

    SciTech Connect (OSTI)

    P.C. Weaver

    2008-10-17

    Perform verification surveys of 19 available grids located in the Lester Flat Area at the Davod Witherspoon Site. The survey grids included E11, E12, E13, F11, F12, F13, F14, F15, G15, G16, G17, H16, H17, H18, X16, X17, X18, K16, and J16.

  14. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  15. Closure Report for Corrective Action Unit 104: Area 7 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada

    SciTech Connect (OSTI)

    2013-06-27

    This Closure Report (CR) presents information supporting closure of Corrective Action Unit (CAU) 104, Area 7 Yucca Flat Atmospheric Test Sites, and provides documentation supporting the completed corrective actions and confirmation that closure objectives for CAU 104 were met. This CR complies with the requirements of the Federal Facility Agreement and Consent Order (FFACO) that was agreed to by the State of Nevada; the U.S. Department of Energy (DOE), Environmental Management; the U.S. Department of Defense; and DOE, Legacy Management. CAU 104 consists of the following 15 Corrective Action Sites (CASs), located in Area 7 of the Nevada National Security Site: · CAS 07-23-03, Atmospheric Test Site T-7C · CAS 07-23-04, Atmospheric Test Site T7-1 · CAS 07-23-05, Atmospheric Test Site · CAS 07-23-06, Atmospheric Test Site T7-5a · CAS 07-23-07, Atmospheric Test Site - Dog (T-S) · CAS 07-23-08, Atmospheric Test Site - Baker (T-S) · CAS 07-23-09, Atmospheric Test Site - Charlie (T-S) · CAS 07-23-10, Atmospheric Test Site - Dixie · CAS 07-23-11, Atmospheric Test Site - Dixie · CAS 07-23-12, Atmospheric Test Site - Charlie (Bus) · CAS 07-23-13, Atmospheric Test Site - Baker (Buster) · CAS 07-23-14, Atmospheric Test Site - Ruth · CAS 07-23-15, Atmospheric Test Site T7-4 · CAS 07-23-16, Atmospheric Test Site B7-b · CAS 07-23-17, Atmospheric Test Site - Climax Closure activities began in October 2012 and were completed in April 2013. Activities were conducted according to the Corrective Action Decision Document/Corrective Action Plan for CAU 104. The corrective actions included No Further Action and Clean Closure. Closure activities generated sanitary waste, mixed waste, and recyclable material. Some wastes exceeded land disposal limits and required treatment prior to disposal. Other wastes met land disposal restrictions and were disposed in appropriate onsite landfills. The U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office

  16. The Hydrogeologic Character of the Lower Tuff Confining Unit and the Oak Springs Butte Confining Unit in the Tuff Pile Area of Central Yucca Flat

    SciTech Connect (OSTI)

    Drellack, Jr., Sigmund L.; Prothro, Lance B.; Gonzales, Jose L.; Mercadante, Jennifer M.

    2010-07-30

    The lower tuff confining unit (LTCU) in the Yucca Flat Corrective Action Unit (CAU) consists of a monotonous sequence of pervasively zeolitized volcanic tuff (i.e., mostly bedded with lesser nonwelded to poorly welded tuff; not fractured) (Bechtel Nevada, 2006). The LTCU is an important confining unit beneath Yucca Flat because it separates the alluvial and volcanic aquifers, where many underground nuclear tests were conducted, from the regional lower carbonate aquifer. Recent sub-CAU-scale modeling by Los Alamos National Laboratory in the Tuff Pile area of Yucca Flat (Boryta, et al., in review) includes postulated low-porosity, high-permeability zones (i.e., fractured welded-tuff aquifers) within the LTCU. This scenario indicates that such postulated low-porosity, high-permeability zones could provide fast-path lateral conduits to faults, and eventually to the lower carbonate aquifer. A fractured and faulted lower carbonate aquifer is postulated to provide a flow path(s) for underground test-derived contaminants to potential offsite receptors. The ramifications of such a scenario are obvious for groundwater flow and contaminant migration beneath Yucca Flat. This paper describes the reasoning for not including postulated low-porosity, high-permeability zones within the LTCU in the Tuff Pile area or within the LTCU in the Yucca Flat CAU-scale model. Both observational and analytical data clearly indicate that the LTCU in the Tuff Pile area consists of pervasively zeolitic, nonwelded to poorly welded tuffs that are classified as tuff confining units (i.e., high-porosity, low-permeability). The position regarding the LTCU in the Tuff Pile area is summarized as follows: The LTCU in the Tuff Pile area consists of a monotonous sequence of predominantly zeolitic nonwelded to poorly welded tuffs, and thus is accurately characterized hydrogeologically as a tuff confining unit (aquitard) in the Yucca Flat-Climax Mine hydrostratigraphic framework model (Bechtel Nevada, 2006

  17. Corrective Action Decision Document/Closure Report for Corrective Action Unit 105: Area 2 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada, Revision 1

    SciTech Connect (OSTI)

    Matthews, Patrick

    2014-01-01

    The purpose of this Corrective Action Decision Document/Closure Report is to provide justification and documentation supporting the recommendation that no further corrective action is needed for CAU 105 based on the implementation of the corrective actions. Corrective action investigation (CAI) activities were performed from October 22, 2012, through May 23, 2013, as set forth in the Corrective Action Investigation Plan for Corrective Action Unit 105: Area 2 Yucca Flat Atmospheric Test Sites; and in accordance with the Soils Activity Quality Assurance Plan, which establishes requirements, technical planning, and general quality practices.

  18. Corrective Action Decision Document/Closure Report for Corrective Action Unit 570: Area 9 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Matthews, Patrick

    2013-11-01

    This Corrective Action Decision Document/Closure Report presents information supporting the closure of Corrective Action Unit (CAU) 570: Area 9 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada. This complies with the requirements of the Federal Facility Agreement and Consent Order (FFACO) that was agreed to by the State of Nevada; U.S. Department of Energy (DOE), Environmental Management; U.S. Department of Defense; and DOE, Legacy Management. The purpose of the CADD/CR is to provide justification and documentation supporting the recommendation that no further corrective action is needed.

  19. Corrective Action Decision Document/Closure Report for Corrective Action Unit 105: Area 2 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Matthews, Patrick

    2013-09-01

    This Corrective Action Decision Document/Closure Report presents information supporting the closure of Corrective Action Unit (CAU) 105: Area 2 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada. CAU 105 comprises the following five corrective action sites (CASs): -02-23-04 Atmospheric Test Site - Whitney Closure In Place -02-23-05 Atmospheric Test Site T-2A Closure In Place -02-23-06 Atmospheric Test Site T-2B Clean Closure -02-23-08 Atmospheric Test Site T-2 Closure In Place -02-23-09 Atmospheric Test Site - Turk Closure In Place The purpose of this Corrective Action Decision Document/Closure Report is to provide justification and documentation supporting the recommendation that no further corrective action is needed for CAU 105 based on the implementation of the corrective actions. Corrective action investigation (CAI) activities were performed from October 22, 2012, through May 23, 2013, as set forth in the Corrective Action Investigation Plan for Corrective Action Unit 105: Area 2 Yucca Flat Atmospheric Test Sites; and in accordance with the Soils Activity Quality Assurance Plan, which establishes requirements, technical planning, and general quality practices.

  20. Alkali metal ion battery with bimetallic electrode

    DOE Patents [OSTI]

    Boysen, Dane A; Bradwell, David J; Jiang, Kai; Kim, Hojong; Ortiz, Luis A; Sadoway, Donald R; Tomaszowska, Alina A; Wei, Weifeng; Wang, Kangli

    2015-04-07

    Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten the alkali metal and the electrode comprising the combined alkali/non-alkali metals.

  1. Methods of recovering alkali metals

    SciTech Connect (OSTI)

    Krumhansl, James L; Rigali, Mark J

    2014-03-04

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  2. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y.; Clavenna, Le Roy R.; Eakman, James M.; Kalina, Theodore

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  3. Corrective Action Decision Document/Closure Report for Corrective Action Unit 106: Area 5, 11 Frenchman Flat Atmospheric Sites, Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews and Dawn Peterson

    2011-09-01

    Corrective Action Unit 106 comprises four corrective action sites (CASs): (1) 05-20-02, Evaporation Pond; (2) 05-23-05, Atmospheric Test Site - Able; (3) 05-45-04, 306 GZ Rad Contaminated Area; (4) 05-45-05, 307 GZ Rad Contaminated Area. The purpose of this CADD/CR is to provide justification and documentation supporting the recommendation that no further corrective action is needed for CAU 106 based on the implementation of corrective actions. The corrective action of clean closure was implemented at CASs 05-45-04 and 05-45-05, while no corrective action was necessary at CASs 05-20-02 and 05-23-05. Corrective action investigation (CAI) activities were performed from October 20, 2010, through June 1, 2011, as set forth in the Corrective Action Investigation Plan for Corrective Action Unit 106: Areas 5, 11 Frenchman Flat Atmospheric Sites. The approach for the CAI was divided into two facets: investigation of the primary release of radionuclides, and investigation of other releases (mechanical displacement and chemical releases). The purpose of the CAI was to fulfill data needs as defined during the data quality objective (DQO) process. The CAU 106 dataset of investigation results was evaluated based on a data quality assessment. This assessment demonstrated the dataset is complete and acceptable for use in fulfilling the DQO data needs. Investigation results were evaluated against final action levels (FALs) established in this document. A radiological dose FAL of 25 millirem per year was established based on the Industrial Area exposure scenario (2,250 hours of annual exposure). The only radiological dose exceeding the FAL was at CAS 05-45-05 and was associated with potential source material (PSM). It is also assumed that additional PSM in the form of depleted uranium (DU) and DU-contaminated debris at CASs 05-45-04 and 05-45-05 exceed the FAL. Therefore, corrective actions were undertaken at these CASs that consisted of removing PSM and collecting verification

  4. PROCESS OF RECOVERING ALKALI METALS

    DOE Patents [OSTI]

    Wolkoff, J.

    1961-08-15

    A process is described of recovering alkali metal vapor by sorption on activated alumina, activated carbon, dehydrated zeolite, activated magnesia, or Fuller's earth preheated above the vaporization temperature of the alkali metal and subsequent desorption by heating the solvent under vacuum. (AEC)

  5. Flat | Open Energy Information

    Open Energy Info (EERE)

    ENERGYGeothermal Home Print PDF Flat Dictionary.png Flat: A relatively smooth landscape with no topographic relief Other definitions:Wikipedia Reegle Topographic Features...

  6. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Gregory, Kevin M.

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  7. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  8. Windy Flats | Open Energy Information

    Open Energy Info (EERE)

    Flats Jump to: navigation, search Name Windy Flats Facility Windy Flats Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Cannon Power Group...

  9. Hydrothermal alkali metal catalyst recovery process

    DOE Patents [OSTI]

    Eakman, James M.; Clavenna, LeRoy R.

    1979-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles primarily in the form of water soluble alkali metal formates by treating the particles with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of added carbon monoxide. During the treating process the water insoluble alkali metal compounds comprising the insoluble alkali metal residues are converted into water soluble alkali metal formates. The resultant aqueous solution containing water soluble alkali metal formates is then separated from the treated particles and any insoluble materials formed during the treatment process, and recycled to the gasification process where the alkali metal formates serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. This process permits increased recovery of alkali metal constituents, thereby decreasing the overall cost of the gasification process by reducing the amount of makeup alkali metal compounds necessary.

  10. Corrective Action Decision Document/Closure Report for Corrective Action Unit 569: Area 3 Yucca Flat Atmospheric Test Sites Nevada National Security Site, Nevada with ROTC 1, Revision 0

    SciTech Connect (OSTI)

    Sloop, Christy

    2013-04-01

    This Corrective Action Decision Document/Closure Report presents information supporting the closure of Corrective Action Unit (CAU) 569: Area 3 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada. CAU 569 comprises the following nine corrective action sites (CASs): • 03-23-09, T-3 Contamination Area • 03-23-10, T-3A Contamination Area • 03-23-11, T-3B Contamination Area • 03-23-12, T-3S Contamination Area • 03-23-13, T-3T Contamination Area • 03-23-14, T-3V Contamination Area • 03-23-15, S-3G Contamination Area • 03-23-16, S-3H Contamination Area • 03-23-21, Pike Contamination Area The purpose of this Corrective Action Decision Document/Closure Report is to provide justification and documentation supporting the recommendation that no further corrective action is needed for CAU 569 based on the implementation of the corrective actions listed in Table ES-2.

  11. Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator

    DOE Patents [OSTI]

    Joshi, Ashok V.; Balagopal, Shekar; Pendelton, Justin

    2011-12-13

    Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

  12. DHS Flat Stanley Project

    Broader source: Energy.gov [DOE]

    To provide information on the DHS Flat Stanley Project. The goal of the project is to help kids learn about the importance of cybersecurity.

  13. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  14. Corrective Action Investigation Plan for Corrective Action Unit 569: Area 3 Yucca Flat Atmospheric Test Sites Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews; Christy Sloop

    2012-02-01

    Corrective Action Unit (CAU) 569 is located in Area 3 of the Nevada National Security Site, which is approximately 65 miles northwest of Las Vegas, Nevada. Corrective Action Unit 569 comprises the nine numbered corrective action sites (CASs) and one newly identified site listed below: (1) 03-23-09, T-3 Contamination Area (hereafter referred to as Annie, Franklin, George, and Moth); (2) 03-23-10, T-3A Contamination Area (hereafter referred to as Harry and Hornet); (3) 03-23-11, T-3B Contamination Area (hereafter referred to as Fizeau); (4) 03-23-12, T-3S Contamination Area (hereafter referred to as Rio Arriba); (5) 03-23-13, T-3T Contamination Area (hereafter referred to as Catron); (6) 03-23-14, T-3V Contamination Area (hereafter referred to as Humboldt); (7) 03-23-15, S-3G Contamination Area (hereafter referred to as Coulomb-B); (8) 03-23-16, S-3H Contamination Area (hereafter referred to as Coulomb-A); (9) 03-23-21, Pike Contamination Area (hereafter referred to as Pike); and (10) Waste Consolidation Site 3A. Because CAU 569 is a complicated site containing many types of releases, it was agreed during the data quality objectives (DQO) process that these sites will be grouped. These sites are being investigated because existing information on the nature and extent of potential contamination is insufficient to evaluate and recommend corrective action alternatives (CAAs). Additional information will be obtained by conducting a corrective action investigation before evaluating CAAs and selecting the appropriate corrective action for each study group. The results of the field investigation will support a defensible evaluation of viable CAAs that will be presented in the Corrective Action Decision Document. The sites will be investigated based on the DQOs developed on September 26, 2011, by representatives of the Nevada Division of Environmental Protection and the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office. The DQO

  15. SHEPHERDS FLAT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SHEPHERDS FLAT SHEPHERDS FLAT DOE-LPO_Project-Posters_WIND_Shepherds-Flat.pdf (381.97 KB) More Documents & Publications EIS-0183: Record of Decision EIS-0183: Record of Decision EIS-0419: Supplement Analysis

  16. Regenerable activated bauxite adsorbent alkali monitor probe

    DOE Patents [OSTI]

    Lee, Sheldon H. D.

    1992-01-01

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases.

  17. Regenerable activated bauxite adsorbent alkali monitor probe

    DOE Patents [OSTI]

    Lee, S.H.D.

    1992-12-22

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

  18. Rocky flats teams forming

    SciTech Connect (OSTI)

    1994-08-01

    Bidding teams are shaping up to go after the $3.5-billion, five-year contract to manage ongoing operations and cleanup of the US Dept. of Energy`s Rocky Flats nuclear weapon plant near Denver.

  19. Rocky Flats Overview

    Broader source: Energy.gov [DOE]

    At the August 20, 2014 NNMCAB Site Tour Scott Surovchak DOE, Provided Information on Activities that Took Place on the Rocky Flats Site. Information on the Clean-up Process was Also Given.

  20. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, D.F.; Kwan, S.W.

    1997-04-08

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

  1. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, David F.; Kwan, Simon W.

    1997-01-01

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide.

  2. Corrective Action Investigation Plan for Corrective Action Unit 106: Areas 5, 11 Frenchman Flat Atmospheric Sites, Nevada Test Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews

    2010-04-01

    Corrective Action Unit (CAU) 106 is located in Area 5 of the Nevada Test Site, which is approximately 65 miles northwest of Las Vegas, Nevada. Corrective Action Unit 106 comprises the five corrective action sites (CASs) listed below: •05-23-02, GMX Alpha Contaminated Area •05-23-05, Atmospheric Test Site - Able •05-45-01, Atmospheric Test Site - Hamilton •05-45-04, 306 GZ Rad Contaminated Area •05-45-05, 307 GZ Rad Contaminated Area These sites are being investigated because existing information on the nature and extent of potential contamination is insufficient to evaluate and recommend corrective action alternatives (CAAs). Additional information will be obtained by conducting a corrective action investigation before evaluating CAAs and selecting the appropriate corrective action for each CAS. The results of the field investigation will support a defensible evaluation of viable CAAs that will be presented in the Corrective Action Decision Document. The sites will be investigated based on the data quality objectives (DQOs) developed on January 19, 2010, by representatives of the Nevada Division of Environmental Protection and the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office. The DQO process was used to identify and define the type, amount, and quality of data needed to develop and evaluate appropriate corrective actions for CAU 106. The presence and nature of contamination at CAU 106 will be evaluated based on information collected from a field investigation. The CAU includes land areas impacted by the release of radionuclides from a weapons-effect tower test (CAS 05-45-01), a weapons-related airdrop test (CAS 05-23-05), “equation of state” experiments (CAS 05-23-02), and unknown support activities at two sites (CAS 05-45-04 and CAS 05-45-05). Surface-deposited radiological contamination will be evaluated based on a comparison of the total effective dose (TED) at sample plot locations to the dose

  3. Corrective Action Investigation Plan for Corrective Action Unit 106: Areas 5, 11 Frenchman Flat Atmospheric Sites, Nevada National Security Site, Nevada

    SciTech Connect (OSTI)

    Patrick Matthews

    2011-07-01

    Corrective Action Unit 106 comprises the four corrective action sites (CASs) listed below: • 05-20-02, Evaporation Pond • 05-23-05, Atmospheric Test Site - Able • 05-45-04, 306 GZ Rad Contaminated Area • 05-45-05, 307 GZ Rad Contaminated Area These sites are being investigated because existing information on the nature and extent of potential contamination is insufficient to evaluate and recommend corrective action alternatives (CAAs). Additional information will be obtained by conducting a corrective action investigation before evaluating CAAs and selecting the appropriate corrective action for each CAS. The results of the field investigation will support a defensible evaluation of viable CAAs that will be presented in the Corrective Action Decision Document. The sites will be investigated based on the data quality objectives (DQOs) developed on January 19, 2010, by representatives of the Nevada Division of Environmental Protection and the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office. The DQO process was used to identify and define the type, amount, and quality of data needed to develop and evaluate appropriate corrective actions for CAU 106. The presence and nature of contamination at CAU 106 will be evaluated based on information collected from a field investigation. The CAU includes land areas impacted by the release of radionuclides from groundwater pumping during the Radionuclide Migration study program (CAS 05-20-02), a weapons-related airdrop test (CAS 05-23-05), and unknown support activities at two sites (CAS 05-45-04 and CAS 05-45-05). The presence and nature of contamination from surface-deposited radiological contamination from CAS 05-23-05, Atmospheric Test Site - Able, and other types of releases (such as migration and excavation as well as any potential releases discovered during the investigation) from the remaining three CASs will be evaluated using soil samples collected from the locations

  4. Process for the disposal of alkali metals

    DOE Patents [OSTI]

    Lewis, Leroy C.

    1977-01-01

    Large quantities of alkali metals may be safely reacted for ultimate disposal by contact with a hot concentrated caustic solution. The alkali metals react with water in the caustic solution in a controlled reaction while steam dilutes the hydrogen formed by the reaction to a safe level.

  5. Corrective Action Investigation Plan for Corrective Action Unit 570: Area 9 Yucca Flat Atmospheric Test Sites Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews

    2012-08-01

    CAU 570 comprises the following six corrective action sites (CASs): • 02-23-07, Atmospheric Test Site - Tesla • 09-23-10, Atmospheric Test Site T-9 • 09-23-11, Atmospheric Test Site S-9G • 09-23-14, Atmospheric Test Site - Rushmore • 09-23-15, Eagle Contamination Area • 09-99-01, Atmospheric Test Site B-9A These sites are being investigated because existing information on the nature and extent of potential contamination is insufficient to evaluate and recommend corrective action alternatives (CAAs). Additional information will be obtained by conducting a corrective action investigation before evaluating CAAs and selecting the appropriate corrective action for each CAS. The results of the field investigation will support a defensible evaluation of viable CAAs that will be presented in the Corrective Action Decision Document. The sites will be investigated based on the data quality objectives (DQOs) developed on April 30, 2012, by representatives of the Nevada Division of Environmental Protection and the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office. The DQO process was used to identify and define the type, amount, and quality of data needed to develop and evaluate appropriate corrective actions for CAU 570. The site investigation process will also be conducted in accordance with the Soils Activity Quality Assurance Plan, which establishes requirements, technical planning, and general quality practices to be applied to this activity. The presence and nature of contamination at CAU 570 will be evaluated based on information collected from a field investigation. Radiological contamination will be evaluated based on a comparison of the total effective dose at sample locations to the dose-based final action level. The total effective dose will be calculated as the total of separate estimates of internal and external dose. Results from the analysis of soil samples will be used to calculate internal radiological

  6. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, Raymond D.; McPheeters, Charles C.

    1980-01-01

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  7. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, R.D.; McPheeters, C.C.

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  8. Corrective Action Investigation Plan for Corrective Action Unit 104: Area 7 Yucca Flat Atmospheric Test Sites, Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews

    2011-08-01

    of the total effective dose (TED) to the dose-based final action level (FAL). The presence of TED exceeding the FAL is considered a radiological contaminant of concern (COC). Anything identified as a COC will require corrective action. The TED will be calculated as the total of separate estimates of internal and external dose. Results from the analysis of soil samples will be used to calculate internal radiological dose. Thermoluminescent dosimeters will be used to measure external radiological dose. Based on process knowledge of the releases associated with the nuclear tests and radiological survey information about the location and shape of the resulting contamination plume, it was determined that the releases from the nuclear tests are co-located and will be investigated concurrently. A field investigation will be performed to define areas where TED exceeds the FAL and to determine whether other COCs are present at the site. The investigation will also collect information to determine the presence and nature of contamination associated with migration and excavation, as well as any potential releases discovered during the investigation. Appendix A provides a detailed discussion of the DQO methodology and the DQOs specific to each CAS.

  9. Corrective Action Investigation Plan for Corrective Action Unit 105: Area 2 Yucca Flat Atmospheric Test Sites Nevada National Security Site, Nevada, Revision 0

    SciTech Connect (OSTI)

    Patrick Matthews

    2012-09-01

    Corrective Action Unit (CAU) 105 is located in Area 2 of the Nevada National Security Site, which is approximately 65 miles northwest of Las Vegas, Nevada. CAU 105 is a geographical grouping of sites where there has been a suspected release of contamination associated with atmospheric nuclear testing. This document describes the planned investigation of CAU 105, which comprises the following corrective action sites (CASs): • 02-23-04, Atmospheric Test Site - Whitney • 02-23-05, Atmospheric Test Site T-2A • 02-23-06, Atmospheric Test Site T-2B • 02-23-08, Atmospheric Test Site T-2 • 02-23-09, Atmospheric Test Site - Turk These sites are being investigated because existing information on the nature and extent of potential contamination is insufficient to evaluate and recommend corrective action alternatives (CAAs). Additional information will be obtained by conducting a corrective action investigation before evaluating CAAs and selecting the appropriate corrective action for each CAS. The results of the field investigation will support a defensible evaluation of viable CAAs that will be presented in the Corrective Action Decision Document. The sites will be investigated based on the data quality objectives (DQOs) developed on April 30, 2012, by representatives of the Nevada Division of Environmental Protection and the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office. The DQO process was used to identify and define the type, amount, and quality of data needed to develop and evaluate appropriate corrective actions for CAU 105. The site investigation process will also be conducted in accordance with the Soils Activity Quality Assurance Plan, which establishes requirements, technical planning, and general quality practices to be applied to this activity. The potential contamination sources associated with all CAU 105 CASs are from atmospheric nuclear testing activities. The presence and nature of contamination at CAU

  10. Diesel prices flat

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices flat The U.S. average retail price for on-highway diesel fuel saw no movement from last week. Prices remained flat at $3.89 a gallon on Monday, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the West Coast states at 4.05 a gallon, up 2-tenths of a penny from a week ago. Prices were lowest in the Gulf Coast region at 3.80 a gallon, up 3-tenths of a penny

  11. Is flat fair?

    SciTech Connect (OSTI)

    Bunzl, Martin

    2010-07-15

    Dynamic pricing holds out the promise of shifting peak demand as well as reducing overall demand. But it also raises thorny issues of fairness. All practical pricing systems involve tradeoffs between equity and efficiency. I examine the circumstances under which equity ought to be allowed to trump efficiency and whether or not this constitutes a defense of flat pricing. (author)

  12. Whiskey Flats Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Well Name: Location: Depth: Initial Flow Rate: "ad" is not declared as a valid unit of measurement for this property. The given value was not understood. Flow Test Comment:...

  13. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A.; Beach, Raymond J.; Dawson, Jay W.; Krupke, William F.

    2007-10-23

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  14. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A.; Beach, Raymond J.; Dawson, Jay W.; Krupke, William F.

    2006-07-26

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  15. Diesel prices flat nationally

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices flat nationally The U.S. average retail price for on-highway diesel fuel remained the same from a week ago at $3.98 a gallon on Monday, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the West Coast states at 4.14 a gallon, up 1.4 cents from a week ago. Prices were lowest in the Gulf Coast region at 3.90 a gallon, up a tenth of a penny.

  16. SU-E-I-53: Comparison of Kerma-Area-Product Between the Micro-Angiographic Fluoroscope (MAF) and a Flat Panel Detector (FPD) as Used in Neuro-Endovascular Procedures

    SciTech Connect (OSTI)

    Vijayan, S; Rana, V; Nagesh, S Setlur; Xiong, Z; Rudin, S; Bednarek, D

    2015-06-15

    Purpose: To determine the reduction of integral dose to the patient when using the micro-angiographic fluoroscope (MAF) compared to when using the standard flat-panel detector (FPD) for the techniques used during neurointerventional procedures. Methods: The MAF is a small field-of-view, high resolution x-ray detector which captures 1024 x 1024 pixels with an effective pixel size of 35μm and is capable of real-time imaging up to 30 frames per second. The MAF was used in neuro-interventions during those parts of the procedure when high resolution was needed and the FPD was used otherwise. The technique parameters were recorded when each detector was used and the kerma-area-product (KAP) per image frame was determined. KAP values were calculated for seven neuro interventions using premeasured calibration files of output as a function of kVp and beam filtration and included the attenuation of the patient table for the frontal projections to be more representative of integral patient dose. The air kerma at the patient entrance was multiplied by the beam area at that point to obtain the KAP values. The ranges of KAP values per frame were determined for the range of technique parameters used during the clinical procedures. To appreciate the benefit of the higher MAF resolution in the region of interventional activity, DA technique parameters were generally used with the MAF. Results: The lowest and highest values of KAP per frame for the MAF in DA mode were 4 and 50 times lower, respectively, compared to those of the FPD in pulsed fluoroscopy mode. Conclusion: The MAF was used in those parts of the clinical procedures when high resolution and image quality was essential. The integral patient dose as represented by the KAP value was substantially lower when using the MAF than when using the FPD due to the much smaller volume of tissue irradiated. This research was supported in part by Toshiba Medical Systems Corporation and NIH Grant R01EB002873.

  17. SHEPHERDS FLAT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    It is expected to prevent 1,000,000 metric tons of carbon dioxide emissions annually. PROJECT STATISTICS: SHEPHERDS FLAT PROJECT SUMMARY OWNER Caithness Energy, LLC LOCATIONS ...

  18. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, W.Y.

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide to precipitate silicon constituents, the pH of the resultant solution is increased, preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  19. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a...

  20. Salts of alkali metal anions and process of preparing same

    DOE Patents [OSTI]

    Dye, James L.; Ceraso, Joseph M.; Tehan, Frederick J.; Lok, Mei Tak

    1978-01-01

    Compounds of alkali metal anion salts of alkali metal cations in bicyclic polyoxadiamines are disclosed. The salts are prepared by contacting an excess of alkali metal with an alkali metal dissolving solution consisting of a bicyclic polyoxadiamine in a suitable solvent, and recovered by precipitation. The salts have a gold-color crystalline appearance and are stable in a vacuum at -10.degree. C. and below.

  1. METATHESIS OF PLUTONIUM CARRIER LANTHANUM FLUORIDE PRECIPITATE WITH AN ALKALI

    DOE Patents [OSTI]

    Duffield, R.B.

    1960-04-01

    A plutonium fluoride precipitate is converted to plutonium hydroxide by digesting the precipitate with an aqueous alkali metal hydroxide solution.

  2. Alkali resistant optical coatings for alkali lasers and methods of production thereof

    DOE Patents [OSTI]

    Soules, Thomas F; Beach, Raymond J; Mitchell, Scott C

    2014-11-18

    In one embodiment, a multilayer dielectric coating for use in an alkali laser includes two or more alternating layers of high and low refractive index materials, wherein an innermost layer includes a thicker, >500 nm, and dense, >97% of theoretical, layer of at least one of: alumina, zirconia, and hafnia for protecting subsequent layers of the two or more alternating layers of high and low index dielectric materials from alkali attack. In another embodiment, a method for forming an alkali resistant coating includes forming a first oxide material above a substrate and forming a second oxide material above the first oxide material to form a multilayer dielectric coating, wherein the second oxide material is on a side of the multilayer dielectric coating for contacting an alkali.

  3. Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deng, Zhi; Mo, Yifei; Ong, Shyue Ping

    2016-03-25

    The facile conduction of alkali ions in a crystal host is of crucial importance in rechargeable alkali-ion batteries, the dominant form of energy storage today. In this review, we provide a comprehensive survey of computational approaches to study solid-state alkali diffusion. We demonstrate how these methods have provided useful insights into the design of materials that form the main components of a rechargeable alkali-ion battery, namely the electrodes, superionic conductor solid electrolytes and interfaces. We will also provide a perspective on future challenges and directions. Here, the scope of this review includes the monovalent lithium- and sodium-ion chemistries that aremore » currently of the most commercial interest.« less

  4. Absolute calibration of optical flats

    DOE Patents [OSTI]

    Sommargren, Gary E.

    2005-04-05

    The invention uses the phase shifting diffraction interferometer (PSDI) to provide a true point-by-point measurement of absolute flatness over the surface of optical flats. Beams exiting the fiber optics in a PSDI have perfect spherical wavefronts. The measurement beam is reflected from the optical flat and passed through an auxiliary optic to then be combined with the reference beam on a CCD. The combined beams include phase errors due to both the optic under test and the auxiliary optic. Standard phase extraction algorithms are used to calculate this combined phase error. The optical flat is then removed from the system and the measurement fiber is moved to recombine the two beams. The newly combined beams include only the phase errors due to the auxiliary optic. When the second phase measurement is subtracted from the first phase measurement, the absolute phase error of the optical flat is obtained.

  5. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, Craig R.

    1998-01-01

    A microgap flat panel display which includes a thin gas-filled display tube that utilizes switched X-Y "pixel" strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a "pixel" in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel.

  6. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, C.R.

    1998-12-08

    A microgap flat panel display is disclosed which includes a thin gas-filled display tube that utilizes switched X-Y ``pixel`` strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a ``pixel`` in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel. 6 figs.

  7. Flat panel display development activities at Sandia National Laboratories

    SciTech Connect (OSTI)

    DiBello, E.G.; Worobey, W.; Burchett, S.; Hareland, W.; Felter, T.; Mays, B.

    1994-12-31

    The flat panel display development activities underway at Sandia National Laboratories are described. Research is being conducted in the areas of glass substrates, phosphors, large area processes, and electron emissions. Projects are focused on improving process yield, developing large area processes, and using modeling techniques to predict design performance.

  8. Alkali metal recovery from carbonaceous material conversion process

    DOE Patents [OSTI]

    Sharp, David W.; Clavenna, LeRoy R.; Gorbaty, Martin L.; Tsou, Joe M.

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced in the gasifier or similar reaction zone, alkali metal constitutents are recovered from the particles by withdrawing and passing the particles from the reaction zone to an alkali metal recovery zone in the substantial absence of molecular oxygen and treating the particles in the recovery zone with water or an aqueous solution in the substantial absence of molecular oxygen. The solution formed by treating the particles in the recovery zone will contain water-soluble alkali metal constituents and is recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preventing contact of the particles with oxygen as they are withdrawn from the reaction zone and during treatment in the recovery zone avoids the formation of undesirable alkali metal constituents in the aqueous solution produced in the recovery zone and insures maximum recovery of water-soluble alkali metal constituents from the alkali metal residues.

  9. Towards a flat 45%-efficient concentrator module

    SciTech Connect (OSTI)

    Mohedano, Rubén Hernandez, Maikel; Vilaplana, Juan; Chaves, Julio; Sorgato, S.; Falicoff, Waqidi; Miñano, Juan C.; Benitez, Pablo

    2015-09-28

    The so-called CCS{sup 4}FK is an ultra-flat photovoltaic system of high concentration and high efficiency, with potential to convert, ideally, the equivalent of a 45% of direct solar radiation into electricity by optimizing the usage of sun spectrum and by collecting part of the diffuse radiation, as a flat plate does. LPI has recently finished a design based on this concept and is now developing a prototype based on this technology, thanks to the support of FUNDACION REPSOL-Fondo de Emprendedores, which promotes entrepreneur projects in different areas linked to energy. This works shows some details of the actual design and preliminary potential performance expected, according to accurate spectral simulations.

  10. Flat Ridge Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Flat Ridge Wind Farm Jump to: navigation, search Name Flat Ridge Wind Farm Facility Flat Ridge Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  11. Removal of Retired Alkali Metal Test Systems

    SciTech Connect (OSTI)

    BREHM, W.F.

    2003-01-01

    This paper describes the successful effort to remove alkali metals, alkali metal residues, and piping and structures from retired non-radioactive test systems on the Hanford Site. These test systems were used between 1965 and 1982 to support the Fast Flux Test Facility and the Liquid Metal Fast Breeder Reactor Program. A considerable volume of sodium and sodium-potassium alloy (NaK) was successfully recycled to the commercial sector; structural material and electrical material such as wiring was also recycled. Innovative techniques were used to safely remove NaK and its residues from a test system that could not be gravity-drained. The work was done safely, with no environmental issues or significant schedule delays.

  12. Flat Water Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Water Wind Farm Jump to: navigation, search Name Flat Water Wind Farm Facility Flat Water Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  13. Windy Flats IIa extension | Open Energy Information

    Open Energy Info (EERE)

    IIa extension Jump to: navigation, search Name Windy Flats IIa extension Facility Windy Flats IIa extension Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  14. Windy Flats Phase III | Open Energy Information

    Open Energy Info (EERE)

    Phase III Jump to: navigation, search Name Windy Flats Phase III Facility Windy Flats Phase III Sector Wind energy Facility Type Commercial Scale Wind Facility Status Proposed...

  15. Alkali metal protective garment and composite material

    DOE Patents [OSTI]

    Ballif, III, John L.; Yuan, Wei W.

    1980-01-01

    A protective garment and composite material providing satisfactory heat resistance and physical protection for articles and personnel exposed to hot molten alkali metals, such as sodium. Physical protection is provided by a continuous layer of nickel foil. Heat resistance is provided by an underlying backing layer of thermal insulation. Overlying outer layers of fireproof woven ceramic fibers are used to protect the foil during storage and handling.

  16. DOE - Office of Legacy Management -- Rocky Flats External Resources

    Office of Legacy Management (LM)

    Rocky Flats Site, Colorado External Resources Rocky Flats Stewardship Council Disclaimer Rocky Flats Cold War Museum Disclaimer U.S. Fish and Wildlife Service Rocky Flats National ...

  17. Revegetation of the Rocky Flats Site | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Revegetation of the Rocky Flats Site Revegetation of the Rocky Flats Site Revegetation of the Rocky Flats, Colorado Site PDF icon Revegetation of the Rocky Flats Site More...

  18. Method for the safe disposal of alkali metal

    DOE Patents [OSTI]

    Johnson, Terry R.

    1977-01-01

    Alkali metals such as those employed in liquid metal coolant systems can be safely reacted to form hydroxides by first dissolving the alkali metal in relatively inert metals such as lead or bismuth. The alloy thus formed is contacted with a molten salt including the alkali metal hydroxide and possibly the alkali metal carbonate in the presence of oxygen. This oxidizes the alkali metal to an oxide which is soluble within the molten salt. The salt is separated and contacted with steam or steam-CO.sub.2 mixture to convert the alkali metal oxide to the hydroxide. These reactions can be conducted with minimal hydrogen evolution and with the heat of reaction distributed between the several reaction steps.

  19. Electrochemical devices utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Hitchcock, David C.; Mailhe, Catherine C.; De Jonghe, Lutgard C.

    1986-01-01

    Electrochemical cells are provided with a reactive metal to reduce the oxide of the alkali metal electrode-reactant. Cells employing a molten alkali metal electrode, e.g., sodium, in contact with a ceramic electrolyte, which is a conductor of the ions of the alkali metal forming the electrode, exhibit a lower resistance when a reactive metal, e.g., vanadium, is allowed to react with and reduce the alkali metal oxide. Such cells exhibit less degradation of the electrolyte and of the glass seals often used to joining the electrolyte to the other components of the cell under cycling conditions.

  20. Jidong Chlorine and Alkali Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Place: Tangshan, Hebei Province, China Zip: 63021 Sector: Hydro Product: Chinese chemical products manufacturer whose products including chlorine, alkali, hydrochloric acid...

  1. Evaluation of alkali concentration in conditions relevant to...

    Office of Scientific and Technical Information (OSTI)

    Conference: Evaluation of alkali concentration in conditions relevant to oxygennatural gas glass furnaces by laser-induced breakdown spectroscopy. Citation Details In-Document ...

  2. Effect of furnace operating conditions on alkali vaporization...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ALKALI METALS; EVAPORATION; FURNACES; ...

  3. Electrochemical devices utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Hitchcock, D.C.; Mailhe, C.C.; De Jonghe, L.C.

    1985-07-10

    Electrochemical cells are provided with a reactive metal to reduce the oxide of the alkali metal electrode-reactant. Cells employing a molten alkali metal electrode, e.g., sodium, in contact with a ceramic electrolyte, which is a conductor of the ions of the alkali metal forming the electrode, exhibit a lower resistance when a reactive metal, e.g., vanadium, is allowed to react with and reduce the alkali metal oxide. Such cells exhibit less degradation of the electrolyte and of the glass seals often used to joining the electrolyte to the other components of the cell under cycling conditions.

  4. Diode-Pumped Alkali Laser: A New Combination

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser-Compton Light Source Technology Short-Pulse Lasers High-Powered Lasers Journal Articles home science photon science directed energy Diode-Pumped Alkali Laser: A ...

  5. Cathode architectures for alkali metal / oxygen batteries

    SciTech Connect (OSTI)

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  6. Magnetotelluric Data, Northern Frenchman Flat, Nevada Test Site Nevada

    SciTech Connect (OSTI)

    J.M. Williams; B.D. Rodriguez, and T. H. Asch

    2005-11-23

    Nuclear weapons are integral to the defense of the United States. The U.S. Department of Energy, as the steward of these devices, must continue to gauge the efficacy of the individual weapons. This could be accomplished by occasional testing at the Nevada Test Site (NTS) in Nevada, northwest of Las Vegas. Yucca Flat Basin is one of the testing areas at the NTS. One issue of concern is the nature of the somewhat poorly constrained pre-Tertiary geology and its effects on ground-water flow in the area subsequent to a nuclear test. Ground-water modelers would like to know more about the hydrostratigraphy and geologic structure to support a hydrostratigraphic framework model that is under development for the Yucca Flat Corrective Action Unit (CAU). During 2003, the U.S. Geological Survey (USGS) collected and processed Magnetotelluric (MT) and Audio-magnetotelluric (AMT) data at the Nevada Test Site in and near Yucca Flat to help characterize this pre-Tertiary geology. That work will help to define the character, thickness, and lateral extent of pre-Tertiary confining units. In particular, a major goal has been to define the upper clastic confining unit (UCCU) in the Yucca Flat area. Interpretation will include a three-dimensional (3-D) character analysis and two-dimensional (2-D) resistivity model. The purpose of this report is to release the MT sounding data for Frenchman Flat Profile 3, as shown in Figure 1. No interpretation of the data is included here.

  7. Risk, media, and stigma at Rocky Flats

    SciTech Connect (OSTI)

    Flynn, J.; Peters, E.; Mertz, C.K.; Slovic, P.

    1998-12-01

    Public responses to nuclear technologies are often strongly negative. Events, such as accidents or evidence of unsafe conditions at nuclear facilities, receive extensive and dramatic coverage by the news media. These news stories affect public perceptions of nuclear risks and the geographic areas near nuclear facilities. One result of these perceptions, avoidance behavior, is a form of technological stigma that leads to losses in property values near nuclear facilities. The social amplification of risk is a conceptual framework that attempts to explain how stigma is created through media transmission of information about hazardous places and public perceptions and decisions. This paper examines stigma associated with the US Department of energy`s Rocky Flats facility, a major production plant in the nation`s nuclear weapons complex, located near Denver, Colorado. This study, based upon newspaper analyses and a survey of Denver area residents, finds that the social amplification theory provides a reasonable framework for understanding the events and public responses that took place in regard to Rocky Flats during a 6-year period, beginning with an FBI raid of the facility in 1989.

  8. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y.

    1984-01-01

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  9. COMPLEX FLUORIDES OF PLUTONIUM AND AN ALKALI METAL

    DOE Patents [OSTI]

    Seaborg, G.T.

    1960-08-01

    A method is given for precipitating alkali metal plutonium fluorides. such as KPuF/sub 5/, KPu/sub 2/F/sub 9/, NaPuF/sub 5/, and RbPuF/sub 5/, from an aqueous plutonium(IV) solution by adding hydrogen fluoride and alkali-metal- fluoride.

  10. Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site January 13, 2015 - 5:18pm Addthis What does this project do? Goal 1. Protect human health and the environment. A project to reconfigure the East Trenches Plume Treatment System (ETPTS) at the Rocky Flats site, to improve treatment effectiveness and meet the strict water quality standards in the area, is scheduled to be completed

  11. Graphene folding on flat substrates

    SciTech Connect (OSTI)

    Chen, Xiaoming; Zhao, Yadong; Ke, Changhong; Zhang, Liuyang; Wang, Xianqiao

    2014-10-28

    We present a combined experimental-theoretical study of graphene folding on flat substrates. The structure and deformation of the folded graphene sheet are experimentally characterized by atomic force microscopy. The local graphene folding behaviors are interpreted based on nonlinear continuum mechanics modeling and molecular dynamics simulations. Our study on self-folding of a trilayer graphene sheet reports a bending stiffness of about 6.57?eV, which is about four times the reported values for monolayer graphene. Our results reveal that an intriguing free sliding phenomenon occurs at the interlayer van der Waals interfaces during the graphene folding process. This work demonstrates that it is a plausible venue to quantify the bending stiffness of graphene based on its self-folding conformation on flat substrates. The findings reported in this work are useful to a better understanding of the mechanical properties of graphene and in the pursuit of its applications.

  12. Residue management at Rocky Flats

    SciTech Connect (OSTI)

    Olencz, J.

    1995-12-31

    Past plutonium production and manufacturing operations conducted at the Rocky Flats Environmental Technology Site (RFETS) produced a variety of plutonium-contaminated by-product materials. Residues are a category of these materials and were categorized as {open_quotes}materials in-process{close_quotes} to be recovered due to their inherent plutonium concentrations. In 1989 all RFETS plutonium production and manufacturing operations were curtailed. This report describes the management of plutonium bearing liquid and solid wastes.

  13. Flat space physics from holography

    SciTech Connect (OSTI)

    Bousso, Raphael

    2004-02-06

    We point out that aspects of quantum mechanics can be derived from the holographic principle, using only a perturbative limit of classical general relativity. In flat space, the covariant entropy bound reduces to the Bekenstein bound. The latter does not contain Newton's constant and cannot operate via gravitational backreaction. Instead, it is protected by--and in this sense, predicts--the Heisenberg uncertainty principle.

  14. Corrugated cover plate for flat plate collector

    DOE Patents [OSTI]

    Hollands, K. G. Terry; Sibbitt, Bruce

    1978-01-01

    A flat plate radiant energy collector is providing having a transparent cover. The cover has a V-corrugated shape which reduces the amount of energy reflected by the cover away from the flat plate absorber of the collector.

  15. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    SciTech Connect (OSTI)

    Ward, Patrick A.; Teprovich, Jr., Jospeph A.; Compton, Robert N.; Schwartz, Viviane; Veith, Gabriel M.; Zidan, Ragiay

    2015-01-11

    Here, alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm and 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.

  16. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ward, Patrick A.; Teprovich, Jr., Jospeph A.; Compton, Robert N.; Schwartz, Viviane; Veith, Gabriel M.; Zidan, Ragiay

    2015-01-11

    Here, alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm andmore » 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.« less

  17. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    SciTech Connect (OSTI)

    Ward, Patrick; Teprovich, Jospeph A.; Compton, Robert; Affholter, Kathleen A; Schwartz, Viviane; Veith, Gabriel M; Zidan, Ragiay

    2015-01-01

    Alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm and 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.

  18. Controlled in-situ dissolution of an alkali metal

    DOE Patents [OSTI]

    Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

    2012-09-11

    A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

  19. ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 | Department of Energy

    Energy Savers [EERE]

    AUG 2006 ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 PDF icon Rocky Flats Closure Project-Lessons Learned-August 2006.pdf More Documents & Publications Rocky Flats Overview...

  20. Independent Oversight Special Review, Rocky Flats Closure Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Closure Project Site - April 2001 Independent Oversight Special Review, Rocky Flats Closure Project Site - April 2001 April 2001 Special Review of the Rocky Flats...

  1. Preliminary surficial geologic map of the Rocky Flats Plant and vicinity, Jefferson and Boulder Counties, Colorado

    SciTech Connect (OSTI)

    Shroba, R.R.; Carrara, P.E.

    1994-11-01

    This report contains a 1:6000 scale map of the 3-mile by 4-mile rectangular area surrounding the Rocky Flats Plant. The map shows the surface deposits estimated to be at least one meter thick. The accompanying report contains a detailed description of the map units, a discussion of the Rocky Flats alluvium and landslides, and cited references. 37 references.

  2. Increasing Class C fly ash reduces alkali silica reactivity

    SciTech Connect (OSTI)

    Hicks, J.K.

    2007-07-01

    Contrary to earlier studies, it has been found that incremental additions of Class C fly ash do reduce alkali silica reactivity (ASR), in highly reactive, high alkali concrete mixes. AST can be further reduced by substituting 5% metakaolin or silica fume for the aggregate in concrete mixes with high (more than 30%) Class C fly ash substitution. The paper reports results of studies using Class C fly ash from the Labadie Station plant in Missouri which typically has between 1.3 and 1.45% available alkalis by ASTM C311. 7 figs.

  3. Electrochemical cell utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Virkar, Anil V.; Miller, Gerald R.

    1983-11-04

    An improved electrochemical cell comprising an additive-modified molten alkali metal electrode-reactant and/or electrolyte is disclosed. Various electrochemical cells employing a molten alkali metal, e.g., sodium, electrode in contact with a cationically conductive ceramic membrane experience a lower resistance and a lower temperature coefficient of resistance whenever small amounts of selenium are present at the interface of the electrolyte and the molten alkali metal. Further, cells having small amounts of selenium present at the electrolyte-molten metal interface exhibit less degradation of the electrolyte under long term cycling conditions.

  4. Responses of estuarine circulation and salinity to the loss of intertidal flats – A modeling study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Zhaoqing; Wang, Taiping

    2015-08-25

    Intertidal flats in estuaries are coastal wetlands that provide critical marine habitats to support wide ranges of marine species. Over the last century many estuarine systems have experienced significant loss of intertidal flats due to anthropogenic impacts. This paper presents a modeling study conducted to investigate the responses of estuarine hydrodynamics to the loss of intertidal flats caused by anthropogenic actions in Whidbey Basin of Puget Sound on the northwest coast of North America. Changes in salinity intrusion limits in the estuaries, salinity stratification, and circulation in intertidal flats and estuaries were evaluated by comparing model results under the existingmore » baseline condition and the no-flat condition. Model results showed that loss of intertidal flats results in an increase in salinity intrusion, stronger mixing, and a phase shift in salinity and velocity fields in the bay front areas. Model results also indicated that loss of intertidal flats enhances two-layer circulation, especially the bottom water intrusion. Loss of intertidal flats increases the mean salinity but reduces the salinity range in the subtidal flats over a tidal cycle because of increased mixing. Salinity intrusion limits extend upstream in all three major rivers discharging into Whidbey Basin when no intertidal flats are present. Changes in salinity intrusion and estuarine circulation patterns due to loss of intertidal flats affect the nearshore habitat and water quality in estuaries and potentially increase risk of coastal hazards, such as storm surge and coastal flooding. Furthermore, model results suggested the importance of including intertidal flats and the wetting-and-drying process in hydrodynamic simulations when intertidal flats are present in the model domain.« less

  5. Rocky Flats Closure Unit Cost Data

    SciTech Connect (OSTI)

    Sanford, P.C.; Skokan, B.

    2007-07-01

    The Rocky Flats Closure Project has completed the process of stabilizing residual nuclear materials, decommissioning nuclear facilities, remediating environmental media and closing the Rocky Flats Site (Site). The project cost approximately $4.1 B and included the decommissioning of over 700 structures including 5 major plutonium facilities and 5 major uranium facilities, shipping over 14,600 cubic meters of transuranic and 565,000 cubic meters of low level radioactive waste, and remediating a 385-acre industrial area and the surrounding land. Actual costs were collected for a large variety of closure activities. These costs can be correlated with metrics associated with the facilities and environmental media to capture cost factors from the project that could be applicable to a variety of other closure projects both within and outside of the Department of Energy's weapons complex. The paper covers four general topics: the process to correlate the actual costs and metrics, an example of the correlated data for one large sub-project, a discussion of the results, and the additional activities that are planned to correlate and make this data available to the public. The process to collect and arrange the project control data of the Closure Project relied on the actual Closure Project cost information. It was used to correlate these actual costs with the metrics for the physical work, such as building area or waste generated, to support the development of parametric cost factors. The example provides cost factors for the Industrial Sites Project. The discussion addresses the strengths and weaknesses of the data, followed by a section identifying future activities to improve and extend the analyses and integrate it within the Department's Environmental Cost Analysis System. (authors)

  6. IBM's New Flat Panel Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by J. Stöhr (SSRL), M. Samant (IBM), J. Lüning (SSRL) Today's laptop computers utilize flat panel displays where the light transmission from the back to the front of the display is modulated by orientation changes in liquid crystal (LC) molecules. Details are discussed in Ref. 2 below. One of the key steps in the manufacture of the displays is the alignment of the LC molecules in the display. Today this is done by mechanical rubbing of two polymer surfaces and then sandwiching the LC between

  7. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or...

  8. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1995-08-22

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  9. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, Marca M.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard

    1995-01-01

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  10. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons.

  11. Electrochemical cell having an alkali-metal-nitrate electrode

    DOE Patents [OSTI]

    Roche, M.F.; Preto, S.K.

    1982-06-04

    A power-producing secondary electrochemical cell includes a molten alkali metal as the negative-electrode material and a molten-nitrate salt as the positive-electrode material. The molten material in the respective electrodes are separated by a solid barrier of alkali-metal-ion conducting material. A typical cell includes active materials of molten sodium separated from molten sodium nitrate and other nitrates in mixture by a layer of sodium ..beta..'' alumina.

  12. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Characterization of Selective Binding of Alkali Cations with Carboxylate Print Wednesday, 24 September 2008 00:00 During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of

  13. Solvation Structure and Transport Properties of Alkali Cations in Dimethyl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sulfoxide Under Exogenous Static Electric Fields - Joint Center for Energy Storage Research June 14, 2015, Research Highlights Solvation Structure and Transport Properties of Alkali Cations in Dimethyl Sulfoxide Under Exogenous Static Electric Fields Top: Snapshots of molecular dynamics simulations of alkali ions in DMSO at 298 K and zero-applied electric field: (left) Li+ and (right) Cs+. Sulfur atoms are shown in yellow, oxygen atoms in red, and methyl groups in gray. Graph: Average

  14. Closing Rocky Flats by 2006

    SciTech Connect (OSTI)

    Tuor, N. R.; Schubert, A. L.

    2002-02-26

    Safely accelerating the closure of Rocky Flats to 2006 is a goal shared by many: the State of Colorado, the communities surrounding the site, the U.S. Congress, the Department of Energy, Kaiser-Hill and its team of subcontractors, the site's employees, and taxpayers across the country. On June 30, 2000, Kaiser-Hill (KH) submitted to the Department of Energy (DOE), KH's plan to achieve closure of Rocky Flats by December 15, 2006, for a remaining cost of $3.96 billion (February 1, 2000, to December 15, 2006). The Closure Project Baseline (CPB) is the detailed project plan for accomplishing this ambitious closure goal. This paper will provide a status report on the progress being made toward the closure goal. This paper will: provide a summary of the closure contract completion criteria; give the current cost and schedule variance of the project and the status of key activities; detail important accomplishments of the past year; and discuss the challenges ahead.

  15. Alkali metal yttrium neo-pentoxide double alkoxide precursors to alkali metal yttrium oxide nanomaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boyle, Timothy J.; Neville, Michael L.; Sears, Jeremiah Matthew; Cramer, Roger

    2016-03-15

    In this study, a series of alkali metal yttrium neo-pentoxide ([AY(ONep)4]) compounds were developed as precursors to alkali yttrium oxide (AYO2) nanomaterials. The reaction of yttrium amide ([Y(NR2)3] where R=Si(CH3)3) with four equivalents of H-ONep followed by addition of [A(NR2)] (A=Li, Na, K) or Ao (Ao=Rb, Cs) led to the formation of a complex series of AnY(ONep)3+n species, crystallographically identified as [Y2Li3(μ3-ONep)(μ3-HONep)(μ-ONep)5(ONep)3(HONep)2] (1), [YNa2(μ3-ONep)4(ONep)]2 (2), {[Y2K3(μ3-ONep)3(μ-ONep)4(ONep)2(ηξ-tol)2][Y4K2(μ4-O)(μ3-ONep)8(ONep)4]•ηx-tol]} (3), [Y4K2(μ4-O)(μ3-ONep)8(ONep)4] (3a), [Y2Rb3(μ4-ONep)3(μ-ONep)6] (4), and [Y2Cs4(μ6-O)(μ3-ONep)6(μ3-HONep)2(ONep)2(ηx-tol)4]•tol (5). Compounds 1–5 were investigated as single source precursors to AYOx nanomaterials following solvothermal routes (pyridine, 185 °C for 24h). The final products after thermal processing weremore » found by powder X-ray diffraction experiments to be Y2O3 with variable sized particles based on transmission electron diffraction. Energy dispersive X-ray spectroscopy studies indicated that the heavier alkali metal species were present in the isolated nanomaterials.« less

  16. Two-phase alkali-metal experiments in reduced gravity

    SciTech Connect (OSTI)

    Antoniak, Z.I.

    1986-06-01

    Future space missions envision the use of large nuclear reactors utilizing either a single or a two-phase alkali-metal working fluid. The design and analysis of such reactors require state-of-the-art computer codes that can properly treat alkali-metal flow and heat transfer in a reduced-gravity environment. A literature search of relevant experiments in reduced gravity is reported on here, and reveals a paucity of data for such correlations. The few ongoing experiments in reduced gravity are noted. General plans are put forth for the reduced-gravity experiments which will have to be performed, at NASA facilities, with benign fluids. A similar situation exists regarding two-phase alkali-metal flow and heat transfer, even in normal gravity. Existing data are conflicting and indequate for the task of modeling a space reactor using a two-phase alkali-metal coolant. The major features of past experiments are described here. Data from the reduced-gravity experiments with innocuous fluids are to be combined with normal gravity data from the two-phase alkali-metal experiments. Analyses undertaken here give every expectation that the correlations developed from this data base will provide a valid representation of alkali-metal heat transfer and pressure drop in reduced gravity.

  17. Independent Oversight Review, Rocky Flats Environmental Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of the Rocky Flats Environmental Technology Site Transportation Emergency Management Program This report provides the results of an independent review of the Transportation ...

  18. Stable Flats LLC | Open Energy Information

    Open Energy Info (EERE)

    to build the first multi-family LEED (Leadership in Energy & Environmental Design) Gold certified structure in the country. References: Stable Flats LLC1 This article is a...

  19. Rocky Flats beryllium health surveillance

    SciTech Connect (OSTI)

    Stange, A.W.; Furman, F.J.; Hilmas, D.E.

    1996-10-01

    The Rocky Flats Beryllium Health Surveillance Program (BHSP), initiated in June 1991, was designed to provide medical surveillance for current and former employees exposed to beryllium. The BHSP identifies individuals who have developed beryllium sensitivity using the beryllium lymphocyte proliferation test (BeLPT). A detailed medical evaluation to determine the prevalence of chronic beryllium disease (CBD) is offered to individuals identified as beryllium sensitized or to those who have chest X-ray changes suggestive of CBD. The BHSP has identified 27 cases of CBD and another 74 cases of beryllium sensitization out of 4268 individuals tested. The distribution of BeLPT values for normal, sensitized, and CBD-identified individuals is described. Based on the information collected during the first 3 1/3 years of the BHSP, the BeLPT is the most effective means for the early identification of beryllium-sensitized individuals and to identify individuals who may have CBD. The need for BeLPT retesting is demonstrated through the identification of beryllium sensitization in individuals who previously tested normal. Posterior/anterior chest X-rays were not effective in the identification of CBD. 12 refs., 8 tabs.

  20. A Hydrostratigraphic Framework Model and Alternatives for the Groundwater Flow and Contaminant Transport Model of Corrective Action Unit 98: Frenchman Flat, Clark, Lincoln and Nye Counties, Nevada

    SciTech Connect (OSTI)

    Bechtel Nevada

    2005-09-01

    A new, revised three-dimensional (3-D) hydrostratigraphic framework model for Frenchman Flat was completed in 2004. The area of interest includes Frenchman Flat, a former nuclear testing area at the Nevada Test Site, and proximal areas. Internal and external reviews of an earlier (Phase I) Frenchman Flat model recommended additional data collection to address uncertainties. Subsequently, additional data were collected for this Phase II initiative, including five new drill holes and a 3-D seismic survey.

  1. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  2. Magnetic states of the two-leg-ladder alkali metal iron selenides...

    Office of Scientific and Technical Information (OSTI)

    states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Prev Next Title: Magnetic states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Authors: Luo, ...

  3. Ternary alkali-metal and transition metal or metalloid acetylides as alkali-metal intercalation electrodes for batteries

    DOE Patents [OSTI]

    Nemeth, Karoly; Srajer, George; Harkay, Katherine C; Terdik, Joseph Z

    2015-02-10

    Novel intercalation electrode materials including ternary acetylides of chemical formula: A.sub.nMC.sub.2 where A is alkali or alkaline-earth element; M is transition metal or metalloid element; C.sub.2 is reference to the acetylide ion; n is an integer that is 0, 1, 2, 3 or 4 when A is alkali element and 0, 1, or 2 when A is alkaline-earth element. The alkali elements are Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs) and Francium (Fr). The alkaline-earth elements are Berilium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra). M is a transition metal that is any element in groups 3 through 12 inclusive on the Periodic Table of Elements (elements 21 (Sc) to element 30 (Zn)). In another exemplary embodiment, M is a metalloid element.

  4. Rocky Flats ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Winstead, M.L.

    1995-09-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

  5. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan. Revision 1

    SciTech Connect (OSTI)

    1992-11-01

    The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, as well as for activities associated with nuclear energy development. The 300 Area of the Hanford Site contains reactor fuel manufacturing facilities and several research and development laboratories. The 3718-F Alkali Metal Treatment and Storage Facility (3718-F Facility), located in the 300 Area, was used to store and treat alkali metal wastes. Therefore, it is subject to the regulatory requirements for the storage and treatment of dangerous wastes. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610 (Ecology 1989) and 40 CFR 270.1. Closure also will satisfy the thermal treatment facility closure requirements of 40 CFR 265.381. This closure plan presents a description of the 3718-F Facility, the history of wastes managed, and the approach that will be followed to close the facility. Only hazardous constituents derived from 3718-F Facility operations will be addressed.

  6. Windy Flats(3Q09 portion) | Open Energy Information

    Open Energy Info (EERE)

    Flats(3Q09 portion) Jump to: navigation, search Name Windy Flats(3Q09 portion) Facility Windy Flats(3Q09 portion) Sector Wind energy Facility Type Commercial Scale Wind Facility...

  7. ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 PDF icon Rocky Flats Closure Project-Lessons Learned-August 2006.pdf More Documents & Publications...

  8. Modeling of alkali aggregate reaction effects in concrete dams

    SciTech Connect (OSTI)

    Capra, B.; Bournazel, J.P.; Bourdarot, E.

    1995-12-31

    Alkali Aggregate Reactions (AAR) are difficult to model due to the random distribution of the reactive sites and the imperfect knowledge of these chemical reactions. A new approach, using fracture mechanics and probabilities, capable to describe the anisotropic swelling of a structure is presented.

  9. PVC waterproofing membranes and alkali-aggregated reaction in dams

    SciTech Connect (OSTI)

    Scuero, A.M.

    1995-12-31

    A waterproofing polyvinylchloride (PVC) based geocomposite was installed on two dams subject to alkali-aggregate reaction, to eliminate water intrusion and to protect the facing from further deterioration. The installation system allows drainage of the infiltrated water, thus accomplishing dehydration of the dam body. On one dam, the membrane also provided protection for future slot cutting.

  10. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, P.E.; Bell, J.E.; Harlow, R.A.; Chase, G.G.

    1983-03-01

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed there between. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants there through at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed there between. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal there between. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal. 4 figs.

  11. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, Perry E.; Bell, Jerry E.; Harlow, Richard A.; Chase, Gordon G.

    1983-01-01

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed therebetween. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants therethrough at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed therebetween. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal therebetween. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal.

  12. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F.; Pantier, Earl A.

    1982-05-18

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  13. Effect of silicate modulus and metakaolin incorporation on the carbonation of alkali silicate-activated slags

    SciTech Connect (OSTI)

    Bernal, Susan A.; Mejia de Gutierrez, Ruby; Provis, John L.; Rose, Volker

    2010-06-15

    Accelerated carbonation is induced in pastes and mortars produced from alkali silicate-activated granulated blast furnace slag (GBFS)-metakaolin (MK) blends, by exposure to CO{sub 2}-rich gas atmospheres. Uncarbonated specimens show compressive strengths of up to 63 MPa after 28 days of curing when GBFS is used as the sole binder, and this decreases by 40-50% upon complete carbonation. The final strength of carbonated samples is largely independent of the extent of metakaolin incorporation up to 20%. Increasing the metakaolin content of the binder leads to a reduction in mechanical strength, more rapid carbonation, and an increase in capillary sorptivity. A higher susceptibility to carbonation is identified when activation is carried out with a lower solution modulus (SiO{sub 2}/Na{sub 2}O ratio) in metakaolin-free samples, but this trend is reversed when metakaolin is added due to the formation of secondary aluminosilicate phases. High-energy synchrotron X-ray diffractometry of uncarbonated paste samples shows that the main reaction products in alkali-activated GBFS/MK blends are C-S-H gels, and aluminosilicates with a zeolitic (gismondine) structure. The main crystalline carbonation products are calcite in all samples and trona only in samples containing no metakaolin, with carbonation taking place in the C-S-H gels of all samples, and involving the free Na{sup +} present in the pore solution of the metakaolin-free samples. Samples containing metakaolin do not appear to have the same availability of Na{sup +} for carbonation, indicating that this is more effectively bound in the presence of a secondary aluminosilicate gel phase. It is clear that claims of exceptional carbonation resistance in alkali-activated binders are not universally true, but by developing a fuller mechanistic understanding of this process, it will certainly be possible to improve performance in this area.

  14. Landfill Cover Revegetation at the Rocky Flats Environmental Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Site | Department of Energy Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site (507.34 KB) More Documents & Publications Revegetation of the Rocky Flats Site Smooth Brome Monitoring at Rocky Flats-2005 Results EIS-0285-SA-134:

  15. Microsoft Word - TurtleFlats_CX

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turtle Flats Property Acquisition Funding Fish and Wildlife Project No.: 2011-003-00, ... This is part of BPA's ongoing efforts to mitigate for the impacts to fish and wildlife ...

  16. Rocky Flats Ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Funston, G.A.

    1995-06-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. The test will provide information to determine charge sizes, soak times and mesh screen sizes (if available at time of test) for stabilization of Rocky Flats Ash items to be processed in the HC-21C Muffle Furnace Process. Once the charge size and soak times have been established, a program for the temperature controller of the HC-21C Muffle Furnace process will be generated for processing Rocky Flats Ash.

  17. Rocky Flats resumes shipments to WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rocky Flats Resumes Shipments to WIPP CARLSBAD, N.M., March 11, 2000 - The U.S. Department of Energy (DOE) has resumed transuranic radioactive waste shipments from DOE's Rocky Flats Environmental Technology Site (RFETS) to the Waste Isolation Pilot Plant (WIPP). A shipment consisting of 28 drums of transuranic waste today arrived safely at WIPP at 5:07 p.m. (Mountain Standard Time). The truck, carrying two TRUPACT-II (Transuranic Packaging Transporter Model II) shipping containers, departed

  18. Flat panel ferroelectric electron emission display system

    DOE Patents [OSTI]

    Sampayan, Stephen E.; Orvis, William J.; Caporaso, George J.; Wieskamp, Ted F.

    1996-01-01

    A device which can produce a bright, raster scanned or non-raster scanned image from a flat panel. Unlike many flat panel technologies, this device does not require ambient light or auxiliary illumination for viewing the image. Rather, this device relies on electrons emitted from a ferroelectric emitter impinging on a phosphor. This device takes advantage of a new electron emitter technology which emits electrons with significant kinetic energy and beam current density.

  19. Flat panel ferroelectric electron emission display system

    DOE Patents [OSTI]

    Sampayan, S.E.; Orvis, W.J.; Caporaso, G.J.; Wieskamp, T.F.

    1996-04-16

    A device is disclosed which can produce a bright, raster scanned or non-raster scanned image from a flat panel. Unlike many flat panel technologies, this device does not require ambient light or auxiliary illumination for viewing the image. Rather, this device relies on electrons emitted from a ferroelectric emitter impinging on a phosphor. This device takes advantage of a new electron emitter technology which emits electrons with significant kinetic energy and beam current density. 6 figs.

  20. Preliminary Notice of Violation , Rocky Flats Environmental Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Violation , Rocky Flats Environmental Technology Site - EA-96-05 Preliminary Notice of Violation , Rocky Flats Environmental Technology Site - EA-96-05 October 7, 1996 Preliminary...

  1. LM Records Handling System (LMRHS01) - Rocky Flats Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy ...

  2. Rocky Flats Environmental Technology Site Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky ...

  3. Procedure for measuring the solar reflectance of flat or curved...

    Office of Scientific and Technical Information (OSTI)

    Procedure for measuring the solar reflectance of flat or curved roofing assemblies Citation Details In-Document Search Title: Procedure for measuring the solar reflectance of flat ...

  4. DOE - Office of Legacy Management -- Rocky Flats Archive

    Office of Legacy Management (LM)

    ... Memorandum Regarding Instrumentation and Monitoring at the Rocky Flats OLF Appendix F Solar-Powered Air Stripping at the Rocky Flats Site, Colorado Appendix G RFLMA Contact ...

  5. Rocky Flats Site Expands Solar Power for Treating Groundwater...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Site Expands Solar Power for Treating Groundwater Rocky Flats Site Expands Solar Power for Treating Groundwater April 17, 2013 - 1:26pm Addthis Subcontractor personnel ...

  6. Analysis of offsite Emergency Planning Zones for Rocky Flats Plant

    SciTech Connect (OSTI)

    Inger, J.R. ); Brown-Strattan, M.A. . Rocky Flats Plant)

    1991-01-01

    The purpose of this quality assurance program was to ensure the quality and technical adequacy of Phase 2 of the Analysis of Offsite Emergency Planning Zones (EPZ) for the Rocky Flats Plant project. Quality assurance was accomplished by managing and controlling the processes in the development of the product. The quality assurance task team conducted audits, reviews, and surveillances of project and related activities. This process contributed to identifying areas where the quality assurance plan was not fully implemented, areas needing improvement, and/or corrective actions resulting in a improved product. During the reviews and audits, several key areas were identified where quality assurance plan implementation needed to be improved. These areas included maintaining adequate documentation, reviewing technical results, making inputs traceable to technical results, and understanding that all personnel are responsible for quality.

  7. Rocky Flats Compliance Program; Technology summary

    SciTech Connect (OSTI)

    1994-02-01

    The Department of Energy (DOE) established the Office of Technology Development (EM-50) (OTD) as an element of Environmental Restoration and Waste Management (EM) in November 1989. The primary objective of the Office of Technology Development, Rocky Flats Compliance Program (RFCP), is to develop altemative treatment technologies for mixed low-level waste (wastes containing both hazardous and radioactive components) to use in bringing the Rocky Flats Plant (RFP) into compliance with Federal and state regulations and agreements. Approximately 48,000 cubic feet of untreated low-level mixed waste, for which treatment has not been specified, are stored at the RFP. The cleanup of the Rocky Flats site is driven by agreements between DOE, the Environmental Protection Agency (EPA), and the Colorado Department of Health (CDH). Under these agreements, a Comprehensive Treatment and Management Plan (CTMP) was drafted to outline the mechanisms by which RFP will achieve compliance with the regulations and agreements. This document describes DOE`s strategy to treat low-level mixed waste to meet Land Disposal Restrictions and sets specific milestones related to the regulatory aspects of technology development. These milestones detail schedules for the development of technologies to treat all of the mixed wastes at the RFP. Under the Federal Facilities Compliance Act (FFCA), the CTMP has been incorporated into Rocky Flats Plant Conceptual Site Treatment Plan (CSTP). The CSTP will become the Rocky Flats Plant site Treatment Plan in 1995 and will supersede the CTMP.

  8. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W.

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  9. Deep Resistivity Structure of Yucca Flat, Nevada Test Site, Nevada.

    SciTech Connect (OSTI)

    Theodore H. Asch, Brian D. Rodriguez; Jay A. Sampson; Erin L. Wallin; and Jackie M. Williams.

    2006-09-18

    The Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) at their Nevada Site Office are addressing groundwater contamination resulting from historical underground nuclear testing through the Environmental Management program and, in particular, the Underground Test Area project. One issue of concern is the nature of the somewhat poorly constrained pre Tertiary geology and its effects on ground-water flow in the area adjacent to a nuclear test. Ground water modelers would like to know more about the hydrostratigraphy and geologic structure to support a hydrostratigraphic framework model that is under development for the Yucca Flat Corrective Action Unit (CAU). During 2003, the U.S. Geological Survey, supported by the DOE and NNSA-NSO, collected and processed data from 51 magnetotelluric (MT) and audio-magnetotelluric (AMT) stations at the Nevada Test Site in and near Yucca Flat to assist in characterizing the pre-Tertiary geology in that area. The primary purpose was to refine the character, thickness, and lateral extent of pre Tertiary confining units. In particular, a major goal has been to define the upper clastic confining unit (late Devonian Mississippian-age siliciclastic rocks assigned to the Eleana Formation and Chainman Shale) in the Yucca Flat area. The MT and AMT data have been released in separate USGS Open File Reports. The Nevada Test Site magnetotelluric data interpretation presented in this report includes the results of detailed two-dimensional (2 D) resistivity modeling for each profile (including alternative interpretations) and gross inferences on the three dimensional (3 D) character of the geology beneath each station. The character, thickness, and lateral extent of the Chainman Shale and Eleana Formation that comprise the Upper Clastic Confining Unit are generally well determined in the upper 5 km. Inferences can be made regarding the presence of the Lower Clastic Confining Unit at depths below 5 km. Large fault

  10. An improved method for flat-field correction of flat panel x-ray detector

    SciTech Connect (OSTI)

    Kwan, Alexander L.C.; Seibert, J. Anthony; Boone, John M.

    2006-02-15

    In this Technical Note, the effects of different flat-field techniques are examined for a cesium iodide flat panel detector, which exhibited a slightly nonlinear exposure response. The results indicate that the variable flat-field correction method with the appropriate polynomial fit provides excellent correction throughout the entire exposure range. The averaged normalized variation factor, used to assess the nonuniformity of the flat-field correction, decreased from 30.76 for the fixed correction method to 4.13 for the variable flat-field correction method with a fourth-order polynomial fit for the 60 kVp spectrum, and from 16.42 to 3.97 for the 95 kVp spectrum.

  11. Solid waste recycling programs at Rocky Flats

    SciTech Connect (OSTI)

    Millette, R.L.; Blackman, T.E.; Shepard, M.D.

    1994-12-31

    The Rocky Flats (RFP) recycling programs for solid waste materials have been in place for over ten years. Within the last three years, the programs were centralized under the direction of the Rocky Flats Waste Minimization department, with the assistance of various plant organizations (e.g., Trucking, Building Services, Regulated Waste Operations, property Utilization and Disposal and Security). Waste Minimization designs collection and transportation systems for recyclable materials and evaluates recycling markets for opportunities to add new commodities to the existing programs. The Waste Minimization department also promotes employee participation in the Rocky Flats Recycling Programs, and collects all recycling data for publication. A description of the program status as of January 1994 is given.

  12. Lithological influence of aggregate in the alkali-carbonate reaction

    SciTech Connect (OSTI)

    Lopez-Buendia, A.M. . E-mail: angel.lopez@aidico.es; Climent, V. . E-mail: vcliment@grupogla.com; Verdu, P.

    2006-08-15

    The reactivity of carbonate rock with the alkali content of cement, commonly called alkali-carbonate reaction (ACR), has been investigated. Alkali-silica reaction (ASR) can also contribute in the alkali-aggregate reaction (AAR) in carbonate rock, mainly due to micro- and crypto-crystalline quartz or clay content in carbonate aggregate. Both ACR and ASR can occur in the same system, as has been also evidenced on this paper. Carbonate aggregate samples were selected using lithological reactivity criteria, taking into account the presence of dedolomitization, partial dolomitization, micro- and crypto-crystalline quartz. Selected rocks include calcitic dolostone with chert (CDX), calcitic dolostone with dedolomitization (CDD), limestone with chert (LX), marly calcitic dolostone with partial dolomitization (CD), high-porosity ferric dolostone with clays (FD). To evaluate the reactivity, aggregates were studied using expansion tests following RILEM AAR-2, AAR-5, a modification using LiOH AAR-5Li was also tested. A complementary study was done using petrographic monitoring with polarised light microscopy on aggregates immersed in NaOH and LiOH solutions after different ages. SEM-EDAX has been used to identify the presence of brucite as a product of dedolomitization. An ACR reaction showed shrinkage of the mortar bars in alkaline solutions explained by induced dedolomitization, while an ASR process typically displayed expansion. Neither shrinkage nor expansion was observed when mortar bars were immersed in solutions of lithium hydroxide. Carbonate aggregate classification with AAR pathology risk has been elaborated based on mechanical behaviours by expansion and shrinkage. It is proposed to be used as a petrographic method for AAR diagnosis to complement the RILEM AAR1 specifically for carbonate aggregate. Aggregate materials can be classified as I (non-reactive), II (potentially reactive), and III (probably reactive), considering induced dedolomitization ACR

  13. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel,

  14. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel,

  15. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  16. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  17. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  18. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  19. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  20. Issues evaluation process at Rocky Flats Plant

    SciTech Connect (OSTI)

    Smith, L.C.

    1992-04-16

    This report describes the issues evaluation process for Rocky Flats Plant as established in July 1990. The issues evaluation process was initiated February 27, 1990 with a Charter and Process Overview for short-term implementation. The purpose of the process was to determine the projects required for completion before the Phased Resumption of Plutonium Operations. To determine which projects were required, the issues evaluation process and emphasized risk mitigation, based on a ranking system. The purpose of this report is to document the early design of the issues evaluation process to record the methodologies used that continue as the basis for the ongoing Issues Management Program at Rocky Flats Plant.

  1. Chemical tracking at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Costain, D.B.

    1994-04-01

    EG&G Rocky Flats, Inc., has developed a chemical tracking system to support compliance with the Emergency Planning and community Right-to-Know Act (EPCRA) at the Rocky Flats Plant. This system, referred to as the EPCRA Chemical Control system (ECCS), uses bar code technology to uniquely identify and track the receipt, distribution, and use of chemicals. Chemical inventories are conducted using hand-held electronic scanners to update a site wide chemical database on a VAX 6000 computer. Information from the ECCS supports preparation of the EPCRA Tier II and Form R reports on chemical storage and use.

  2. Neal Lane: Science in a Flat World

    SciTech Connect (OSTI)

    Neal Lane

    2006-09-12

    Lane discusses the changes that have taken place in the world since World War II that have made it "flatter," referring to Thomas L. Friedman's book, The World is Flat. Friedman's main premise is that inexpensive telecommunications is bringing about unhampered international competition, the demise of economic stability, and a trend toward outsourcing services, such as computer programming, engineering and science research.

  3. Neal Lane: Science in a Flat World

    ScienceCinema (OSTI)

    Neal Lane

    2010-09-01

    Lane discusses the changes that have taken place in the world since World War II that have made it "flatter," referring to Thomas L. Friedman's book, The World is Flat. Friedman's main premise is that inexpensive telecommunications is bringing about unhampered international competition, the demise of economic stability, and a trend toward outsourcing services, such as computer programming, engineering and science research.

  4. Preliminary gravity inversion model of basins east of Yucca Flat, Nevada Test Site, Nevada.

    SciTech Connect (OSTI)

    Geoffrey A. Phelps; Carter W. Roberts, and Barry C. Moring

    2006-03-17

    The Yucca Flat eastern extension study area, a 14 kilometer by 45 kilometer region contiguous to Yucca Flat on the west and Frenchman Flat on the south, is being studied to expand the boundary of the Yucca Flat hydrogeologic model. The isostatic residual gravity anomaly was inverted to create a model of the depth of the geologic basins within the study area. Such basins typically are floored by dense pre-Tertiary basement rocks and filled with less-dense Tertiary volcanic and sedimentary rocks and Quaternary alluvium, a necessary condition for the use of gravity modeling to predict the depth to the pre-Tertiary basement rocks within the basins. Three models were created: a preferred model to represent the best estimate of depth to pre-Tertiary basement rocks in the study area, and two end-member models to demonstrate the possible range of solutions. The preferred model predicts shallow basins, generally less than 1,000m depth, throughout the study area, with only Emigrant Valley reaching a depth of 1,100m. Plutonium valley and West Fork Scarp Canyon have maximum depths of 800m and 1,000m, respectively. The end-member models indicate that the uncertainty in the preferred model is less than 200m for most of the study area.

  5. Crystallized alkali-silica gel in concrete from the late 1890s

    SciTech Connect (OSTI)

    Peterson, Karl . E-mail: cee@mtu.edu; Gress, David . E-mail: dlgress@unh.edu; Van Dam, Tom . E-mail: cee@mtu.edu; Sutter, Lawrence . E-mail: cee@mtu.edu

    2006-08-15

    The Elon Farnsworth Battery, a concrete structure completed in 1898, is in an advanced state of disrepair. To investigate the potential for rehabilitation, cores were extracted from the battery. Petrographic examination revealed abundant deposits of alkali silica reaction products in cracks associated with the quartz rich metasedimentary coarse aggregate. The products of the alkali silica reaction are variable in composition and morphology, including both amorphous and crystalline phases. The crystalline alkali silica reaction products are characterized by quantitative X-ray energy dispersive spectrometry (EDX) and X-ray diffraction (XRD). The broad extent of the reactivity is likely due to elevated alkali levels in the cements used.

  6. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tulane University: 2016 Energy Expo Tulane University: 2016 Energy Expo September 9, 2016 9:00AM to 5:00PM EDT Location: 1200 Louisiana Street, Houston, TX 77002 Attendees: Morgan McKnight

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic

  7. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  8. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.; Franco, Sofia C. S.

    1994-01-01

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  9. Cubic Ionic Conductor Ceramics for Alkali Ion Batteries - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cuban Missile Crisis Cuban Missile Crisis Cuba Reconnaissance reveals Soviet missiles in Cuba. The United States blockades Cuba for 13 days until the Soviet Union agrees to remove its missiles Portal

    Advanced Materials Advanced Materials Find More Like This Return to Search Cubic Ionic Conductor Ceramics for Alkali Ion Batteries Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ionic conduction in cubic Na3TiP3O9N, a secondary Na-ion

  10. Release fractions for Rocky Flats specific accidents

    SciTech Connect (OSTI)

    Weiss, R.C.

    1992-09-01

    As Rocky Flats and other DOE facilities begin the transition process towards decommissioning, the nature of the scenarios to be studied in safety analysis will change. Whereas the previous emphasis in safety accidents related to production, now the emphasis is shifting to accidents related tc decommissioning and waste management. Accident scenarios of concern at Rocky Flats now include situations of a different nature and different scale than are represented by most of the existing experimental accident data. This presentation will discuss approaches@to use for applying the existing body of release fraction data to this new emphasis. Mention will also be made of ongoing efforts to produce new data and improve the understanding of physical mechanisms involved.

  11. Emergent universe in spatially flat cosmological model

    SciTech Connect (OSTI)

    Zhang, Kaituo; Yu, Hongwei; Wu, Puxun E-mail: wpx0227@gmail.com

    2014-01-01

    The scenario of an emergent universe provides a promising resolution to the big bang singularity in universes with positive or negative spatial curvature. It however remains unclear whether the scenario can be successfully implemented in a spatially flat universe which seems to be favored by present cosmological observations. In this paper, we study the stability of Einstein static state solutions in a spatially flat Shtanov-Sahni braneworld scenario. With a negative dark radiation term included and assuming a scalar field as the only matter energy component, we find that the universe can stay at an Einstein static state past eternally and then evolve to an inflation phase naturally as the scalar field climbs up its potential slowly. In addition, we also propose a concrete potential of the scalar field that realizes this scenario.

  12. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  13. Status Update: Closing Rocky Flats by 2006

    SciTech Connect (OSTI)

    Tuor, N.; Schubert, A.

    2003-02-25

    Safely closing Rocky Flats by December 2006 is a goal shared by many: the State of Colorado, the communities surrounding the site, the U.S. Congress, the Department of Energy (DOE), Kaiser-Hill and its team of subcontractors, the site's employees and taxpayers across the country. This paper will: provide a status of the Closure Project to date; describe important accomplishments of the past year; describe some of the closure-enhancing technologies enabling acceleration; and discuss the remaining challenges ahead.

  14. Microwave solidification development for Rocky Flats waste

    SciTech Connect (OSTI)

    Dixon, D.; Erle, R.; Eschen, V.

    1994-04-01

    The Microwave Engineering Team at the Rocky Flats Plant has developed a production-scale system for the treatment of hazardous, radioactive, and mixed wastes using microwave energy. The system produces a vitreous final form which meets the acceptance criteria for shipment and disposal. The technology also has potential for application on various other waste streams from the public and private sectors. Technology transfer opportunities are being identified and pursued for commercialization of the microwave solidification technology.

  15. Basic TRUEX process for Rocky Flats Plant

    SciTech Connect (OSTI)

    Leonard, R.A.; Chamberlain, D.B.; Dow, J.A.; Farley, S.E.; Nunez, L.; Regalbuto, M.C.; Vandegrift, G.F.

    1994-08-01

    The Generic TRUEX Model was used to develop a TRUEX process flowsheet for recovering the transuranics (Pu, Am) from a nitrate waste stream at Rocky Flats Plant. The process was designed so that it is relatively insensitive to changes in process feed concentrations and flow rates. Related issues are considered, including solvent losses, feed analysis requirements, safety, and interaction with an evaporator system for nitric acid recycle.

  16. SLIDESHOW: Shepherds Flat Wind Farm | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shepherds Flat Wind Farm SLIDESHOW: Shepherds Flat Wind Farm Addthis 1 of 5 Image: Caithness Energy 2 of 5 Image: Caithness Energy 3 of 5 Image: Caithness Energy 4 of 5 Image: Caithness Energy 5 of 5 Image: Caithness Energy

  17. Sandia National Laboratories: Better flat-panel displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facebook Twitter YouTube Flickr RSS News Better, brighter, cheaper flat-panel displays By ... colors and better images for flat-panel displays built from less expensive ...

  18. Salt Wells, Eight Mile Flat | Open Energy Information

    Open Energy Info (EERE)

    Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau...

  19. An Alternative High Luminosity LHC with Flat Optics and Long...

    Office of Scientific and Technical Information (OSTI)

    with Flat Optics and Long-Range Beam-Beam Compensation Citation Details In-Document Search Title: An Alternative High Luminosity LHC with Flat Optics and Long-Range Beam-Beam ...

  20. DOE - Office of Legacy Management -- Rocky Flats Regulatory Documents

    Office of Legacy Management (LM)

    Notification that GS01 is no longer an RFLMA Point of Compliance (POC) Third Five-Year Review Report for the Rocky Flats Site Rocky Flats Legacy Management Agreement Environmental ...

  1. An Alternative High Luminosity LHC with Flat Optics and Long...

    Office of Scientific and Technical Information (OSTI)

    LHC with Flat Optics and Long-Range Beam-Beam Compensation Citation Details In-Document Search Title: An Alternative High Luminosity LHC with Flat Optics and Long-Range ...

  2. Final Transuranic Waste Shipment Leaves Rocky Flats | Department...

    Office of Environmental Management (EM)

    Transuranic Waste Shipment Leaves Rocky Flats Final Transuranic Waste Shipment Leaves Rocky Flats April 19, 2005 - 12:23pm Addthis Cleanup Ahead of Schedule, On Track to Save ...

  3. DOE - NNSA/NFO -- News & Views Frenchman Flat

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frenchman Flat Photo - Wooden bleachers at Yucca Flats Between January 27, 1951 and March 25, 1968 fourteen atmospheric and five underground tests were detonated at Frenchman Flat. The 320-square-kilometer (123-square-mile) dry lake bed is one of three major closed desert valley basins at the Nevada Test Site, the others being Yucca and Jackass Flats. From 1953 to 1958, reinforced structures were exposed to of nuclear blasts and accompanying overpressures. Among the items exposed to the blasts

  4. Independent Oversight Review, Rocky Flats Environmental Technology Site -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2000 | Department of Energy Rocky Flats Environmental Technology Site - March 2000 Independent Oversight Review, Rocky Flats Environmental Technology Site - March 2000 March 2000 Review of the Rocky Flats Environmental Technology Site Transportation Emergency Management Program This report provides the results of an independent review of the Transportation Emergency Management Program at the Department of Energy's Rocky Flats Environmental Technology Site that was conducted by the

  5. Independent Oversight Special Review, Rocky Flats Closure Project Site -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 2001 | Department of Energy Rocky Flats Closure Project Site - April 2001 Independent Oversight Special Review, Rocky Flats Closure Project Site - April 2001 April 2001 Special Review of the Rocky Flats Closure Project Site This report provides the results of a Special Review at the Rocky Flats Closure Project that was performed U.S. Department of Energy's (DOE) Office of Independent Environment, Safety, and Health Oversight. The Special Review was conducted in February and March 2001

  6. LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Database, Office of Legacy Management | Department of Energy Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management (470.9 KB) More Documents

  7. Synthesis and studies on microhardness of alkali zinc borate glasses

    SciTech Connect (OSTI)

    Subhashini, Bhattacharya, Soumalya Shashikala, H. D. Udayashankar, N. K.

    2014-04-24

    The mixed alkali effect on zinc borate glasses have been reported. The glass systems of nominal composition 10Zn+xLi{sub 2}O+yNa{sub 2}O+80B{sub 2}O{sub 3} (x = y = 0, 5, 10, 15 mol%) were prepared using standard melt quenching method. The structural, physical and mechanical properties of the samples have been studied using X-ray diffraction(XRD), density measurement and Vickers hardness measurement, respectively. A consistent increase in the density was observed, which explains the role of the modifiers (Li{sub 2}O and Na{sub 2}O) in the network modification of borate structure. The molar volume is decreasing linearly with the alkali concentration, which is attributed to the conversion of tetrahedral boron (BO{sub 4/2}){sup −} into (BO{sub 3/2}){sup −}. The microhardness studies reveals the anisotropy nature of the material. It further confirms that the samples belong to hard glass category.

  8. Thermodynamic Properties Of Alkali Species In Coal Based Combined Cycle Power Systems

    SciTech Connect (OSTI)

    Willenborg, W.; Wolf, K.J.; Fricke, C.; Moeller, M.; Prikhodovsky, A.; Hilpert, K.; Singheiser, L.

    2002-09-20

    The aim of this project is to support the development of a concept for a successful alkali removal. Two strategies are possible: optimizing the alkali retention potential of the coal ash slag in the combustion chamber and the liquid slag separators and separate alkali removal with solid sorbents (getters) at temperatures below 1450 C. Therefore in a first step the alkali partial pressure over coal ash slag should be determined in order to get information about the retention potential of the slag. The influence of additives on the retention potential of the slag should be investigated. The measurements should show if the alkali partial pressure over the slag is generally low enough in case of thermodynamic equilibrium. In case of too high alkali partial pressures a separate alkali removal is needed. Therefore in a second step commercial sorbent materials should be investigated concerning their sorption potential for alkalis. To get information about the influence of getter components on the sorption potential some mixtures of pure components, predicted by thermodynamic modeling to be most effective, should be investigated.

  9. Hanford/Rocky Flats collaboration on development of supercritical carbon dioxide extraction to treat mixed waste

    SciTech Connect (OSTI)

    Hendrickson, D.W.; Biyani, R.K.; Brown, C.M.; Teter, W.L.

    1995-11-01

    Proposals for demonstration work under the Department of Energy`s Mixed Waste Focus Area, during the 1996 through 1997 fiscal years included two applications of supercritical carbon dioxide to mixed waste pretreatment. These proposals included task RF15MW58 of Rocky Flats and task RL46MW59 of Hanford. Analysis of compatibilities in wastes and work scopes yielded an expectation of substantial collaboration between sites whereby Hanford waste streams may undergo demonstration testing at Rocky Flats, thereby eliminating the need for test facilities at Hanford. This form of collaboration is premised the continued deployment at Rocky Flats and the capability for Hanford samples to be treated at Rocky Flats. The recent creation of a thermal treatment contract for a facility near Hanford may alleviate the need to conduct organic extraction upon Rocky Flats wastes by providing a cost effective thermal treatment alternative, however, some waste streams at Hanford will continue to require organic extraction. Final site waste stream treatment locations are not within the scope of this document.

  10. Risk-Quantified Decision-Making at Rocky Flats

    SciTech Connect (OSTI)

    Myers, Jeffrey C.

    2008-01-15

    Surface soils in the 903 Pad Lip Area of the Rocky Flats Environmental Technology Site (RFETS) were contaminated with {sup 239/240}Pu by site operations. To meet remediation goals, accurate definition of areas where {sup 239/240}Pu activity exceeded the threshold level of 50 pCi/g and those below 50- pCi/g needed definition. In addition, the confidence for remedial decisions needed to be quantified and displayed visually. Remedial objectives needed to achieve a 90 percent certainty that unremediated soils had less than a 10 percent chance of {sup 239/240}Pu activity exceeding 50-pCi/g. Removing areas where the chance of exceedance is greater than 10 percent creates a 90 percent confidence in the remedial effort results. To achieve the stipulated goals, the geostatistical approach of probability kriging (Myers 1997) was implemented. Lessons learnt: Geostatistical techniques provided a risk-quantified approach to remedial decision-making and provided visualizations of the excavation area. Error analysis demonstrated compliance and confirmed that more than sufficient soils were removed. Error analysis also illustrated that any soils above the threshold that were not removed would be of nominal activity. These quantitative approaches were useful from a regulatory, engineering, and stakeholder satisfaction perspective.

  11. Repackaging Rocky Flats Legacy Transuranic Waste

    SciTech Connect (OSTI)

    McTaggart, Jerri Lynne

    2008-01-15

    Repackaging legacy Transuranic (TRU), Transuranic Mixed (TRM), Low Level Waste (LLW), and Low Level Mixed (LLM) waste requires good characterization skills and the ability to adapt to less than ideal conditions. Repackaging legacy waste in a facility that is not undergoing Decontamination and Decommission (D and D) is optimum. However, repackaging any waste in a D and D facility, under cold and dark conditions, can be difficult. Cold and dark conditions are when the heating and air conditioning are no longer in service and the lighting consists of strands of lights hung throughout each of the rooms. Working under these conditions adds an additional level of stress and danger that must be addressed. The use of glovebags was very useful at Rocky Flats during the D and D of many buildings. Glovebags can be adapted for many different types of wastes and unusual conditions. Repackaging of legacy TRU waste, in a D and D facility, can be accomplished safely and cost effectively with the use of glovebags. In conclusion: the use of glovebags to repackage legacy TRU, TRM, LLW, or LLM waste was done safely and cost effectively at Rocky Flats. The cost of using glovebags was minimal. Glovebags are easily adaptable to whatever the waste configuration is. The use of glovebags, for repackaging of Legacy waste, allows D and D efforts to stay on schedule and on task. Without the use of glovebags, additional gloveboxes would have been required at Rocky Flats. Larger items, such as the HEPA filters, would have required the construction of a new large item repackaging glovebox. Repackaging in glovebags allows the freedom to either locate the glovebag by the waste or locate the glovebag in a place that least impacts D and D efforts. The use of glovebags allowed numerous configurations of waste to be repackaged without the use of gloveboxes. During the D and D of the Rocky Flats facility, which was in a cold and dark stage, D and D work was not impacted by the repackaging activity

  12. Geometrical Wake of a Smooth Flat Collimator

    SciTech Connect (OSTI)

    Stupakov, G.V.; /SLAC

    2011-09-09

    A transverse geometrical wake generated by a beam passing through a smooth flat collimator with a gradually varying gap between the upper and lower walls is considered. Based on generalization of the approach recently developed for a smooth circular taper we reduce the electromagnetic problem of the impedance calculation to the solution of two much simpler static problems - a magnetostatic and an electrostatic ones. The solution shows that in the limit of not very large frequencies, the impedance increases with the ratio h/d where h is the width and d is the distance between the collimating jaws. Numerical results are presented for the NLC Post Linac collimator.

  13. Alkali-silica reaction and its effectes on concrete

    SciTech Connect (OSTI)

    Stark, D.

    1995-12-31

    Alkali-silica reactivity (ASR) has resulted in cracking of concrete in numerous dams in the United States and elsewhere. Many of these dams were constructed prior to the initial discovery of ASR in California in the late 1930`s, thus no special precautions could have been taken to prevent its development Since that time, ASR has been identified in all types of structures located in many parts of the world. Voluminous research has been carried out to better characterize its development, to more completely understand the mechanisms of expansion and distress, and to design means to mitigate its development in new and existing construction. Based on this work, this paper describes the nature of ASR, its effects on concrete, and means to control its development, with special reference to dams.

  14. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan

    SciTech Connect (OSTI)

    1991-12-01

    Since 1987, Westinghouse Hanford Company has been a major contractor to the U.S. Department of Energy-Richland Operations Office and has served as co-operator of the 3718-F Alkali Metal Treatment and Storage Facility, the waste management unit addressed in this closure plan. The closure plan consists of a Part A Dangerous waste Permit Application and a RCRA Closure Plan. An explanation of the Part A Revision (Revision 1) submitted with this document is provided at the beginning of the Part A section. The closure plan consists of 9 chapters and 5 appendices. The chapters cover: introduction; facility description; process information; waste characteristics; groundwater; closure strategy and performance standards; closure activities; postclosure; and references.

  15. Influence of lithium hydroxide on alkali-silica reaction

    SciTech Connect (OSTI)

    Bulteel, D.; Garcia-Diaz, E.; Degrugilliers, P.

    2010-04-15

    Several papers show that the use of lithium limits the development of alkali-silica reaction (ASR) in concrete. The aim of this study is to improve the understanding of lithium's role on the alteration mechanism of ASR. The approach used is a chemical method which allowed a quantitative measurement of the specific degree of reaction of ASR. The chemical concrete sub-system used, called model reactor, is composed of the main ASR reagents: reactive aggregate, portlandite and alkaline solution. Different reaction degrees are measured and compared for different alkaline solutions: NaOH, KOH and LiOH. Alteration by ASR is observed with the same reaction degrees in the presence of NaOH and KOH, accompanied by the consumption of hydroxyl concentration. On the other hand with LiOH, ASR is very limited. Reaction degree values evolve little and the hydroxyl concentration remains about stable. These observations demonstrate that lithium ions have an inhibitor role on ASR.

  16. Vitrification of simulated radioactive Rocky Flats plutonium containing ash residue with a Stir Melter System

    SciTech Connect (OSTI)

    Marra, J.C.; Kormanyos, K.R.; Overcamp, T.J.

    1996-10-01

    A demonstration trial has been completed in which a simulated Rocky Flats ash consisting of an industrial fly-ash material doped with cerium oxide was vitrified in an alloy tank Stir-Melter{trademark} System. The cerium oxide served as a substitute for plutonium oxide present in the actual Rocky Flats residue stream. The glass developed falls within the SiO{sub 2} + Al{sub 2}O{sub 3}/{Sigma}Alkali/B{sub 2}O{sub 3} system. The glass batch contained approximately 40 wt% of ash, the ash was modified to contain {approximately} 5 wt% CeO{sub 2} to simulate plutonium chemistry in the glass. The ash simulant was mixed with water and fed to the Stir-Melter as a slurry with a 60 wt% water to 40 wt% solids ratio. Glass melting temperature was maintained at approximately 1,050 C during the melting trials. Melting rates as functions of impeller speed and slurry feed rate were determined. An optimal melting rate was established through a series of evolutionary variations of the control variables` settings. The optimal melting rate condition was used for a continuous six hour steady state run of the vitrification system. Glass mass flow rates of the melter were measured and correlated with the slurry feed mass flow. Melter off-gas was sampled for particulate and volatile species over a period of four hours during the steady state run. Glass composition and durability studies were run on samples collected during the steady state run.

  17. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S. . Rocky Flats Plant); Rivera, M.A. )

    1993-01-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  18. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S.; Rivera, M.A.

    1993-03-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  19. Immobilization of Rocky Flats Graphite Fines Residues

    SciTech Connect (OSTI)

    Rudisill, T. S.

    1998-11-06

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt percent graphite, 15 wt percent calcium fluoride (CaF2), and 12 wt percent plutonium oxide (PuO2). Approximately 950 kilograms of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 degrees C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO2 concentration in the residue averages 12 wt percent, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF2 dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO2) as a surrogate for PuO2 and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF2 and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.In general, the

  20. A light water excess heat reaction suggests that cold fusion may be alkali-hydrogen fusion

    SciTech Connect (OSTI)

    Bush, R.T. )

    1992-09-01

    This paper reports that Mills and Kneizys presented data in support of a light water excess heat reaction obtained with an electrolytic cell highly reminiscent of the Fleischmann-Pons cold fusion cell. The claim of Mills and Kneizys that their excess heat reaction can be explained on the basis of a novel chemistry, which supposedly also explains cold fusion, is rejected in favor of their reaction being, instead, a light water cold fusion reaction. It is the first known light water cold fusion reaction to exhibit excess heat, it may serve as a prototype to expand our understanding of cold fusion. From this new reactions are deduced, including those common to past cold fusion studies. This broader pattern of nuclear reactions is typically seen to involve a fusion of the nuclides of the alkali atoms with the simplest of the alkali-type nuclides, namely, protons, deuterons, and tritons. Thus, the term alkali-hydrogen fusion seems appropriate for this new type of reaction with three subclasses: alkali-hydrogen fusion, alkali-deuterium fusion, and alkali-tritium fusion. A new three-dimensional transmission resonance model (TRM) is sketched. Finally, preliminary experimental evidence in support of the hypothesis of a light water nuclear reaction and alkali-hydrogen fusion is reported. Evidence is presented that appears to strongly implicate the transmission resonance phenomenon of the new TRM.

  1. Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization

    SciTech Connect (OSTI)

    Karpenko, A. Iablonskyi, D.; Kettunen, J. A.; Cao, W.; Huttula, M.; Aksela, H.; Urpelainen, S.

    2014-05-28

    The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr.

  2. MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments

    DOE Patents [OSTI]

    Peascoe-Meisner, Roberta A [Knoxville, TN; Keiser, James R [Oak Ridge, TN; Hemric, James G [Knoxville, TN; Hubbard, Camden R [Oak Ridge, TN; Gorog, J Peter [Kent, WA; Gupta, Amul [Jamestown, NY

    2008-10-21

    A method includes containing a high-temperature alkali salt containing environment using a refractory containment liner containing MgAl.sub.2O.sub.4 spinel. A method, includes forming a refractory brick containing MgAl.sub.2O.sub.4 spinel having an exterior chill zone defined by substantially columnar crystallization and an interior zone defined by substantially equiaxed crystallization; and removing at least a portion of the exterior chill zone from the refractory brick containing MgAl.sub.2O.sub.4 spinel by scalping the refractory brick containing MgAl.sub.2O.sub.4 spinel to define at least one outer surface having an area of substantially equiaxed crystallization. A product of manufacture includes a refractory brick containing MgAl.sub.2O.sub.4 spinel including an interior zone defined by substantially equiaxed crystallization; and at least one outer surface having an area of substantially equiaxed crystallization.

  3. Flat minimal quantizations of Stckel systems and quantum separability

    SciTech Connect (OSTI)

    B?aszak, Maciej; Doma?ski, Ziemowit; Silindir, Burcu

    2014-12-15

    In this paper, we consider the problem of quantization of classical Stckel systems and the problem of separability of related quantum Hamiltonians. First, using the concept of Stckel transform, natural Hamiltonian systems from a given Riemann space are expressed by some flat coordinates of related Euclidean configuration space. Then, the so-called flat minimal quantization procedure is applied in order to construct an appropriate Hermitian operator in the respective Hilbert space. Finally, we distinguish a class of Stckel systems which remains separable after any of admissible flat minimal quantizations. - Highlights: Using Stckel transform, separable Hamiltonians are expressed by flat coordinates. The concept of admissible flat minimal quantizations is developed. The class of Stckel systems, separable after minimal flat quantization is established. Separability of related stationary Schrdinger equations is presented in explicit form.

  4. Near-field modeling in Frenchman Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Pohlmann, K.; Shirley, C.; Andricevic, R.

    1996-12-01

    The US Department of Energy (DOE) is investigating the effects of nuclear testing in underground test areas (the UGTA program) at the Nevada Test Site. The principal focus of the UGTA program is to better understand and define subsurface radionuclide migration. The study described in this report focuses on the development of tools for generating maps of hydrogeologic characteristics of subsurface Tertiary volcanic units at the Frenchman Flat corrective Action Unit (CAU). The process includes three steps. The first step involves generation of three-dimensional maps of the geologic structure of subsurface volcanic units using geophysical logs to distinguish between two classes: densely welded tuff and nonwelded tuff. The second step generates three-dimensional maps of hydraulic conductivity utilizing the spatial distribution of the two geologic classes obtained in the first step. Each class is described by a correlation structure based on existing data on hydraulic conductivity, and conditioned on the generated spatial location of each class. The final step demonstrates the use of the maps of hydraulic conductivity for modeling groundwater flow and radionuclide transport in volcanic tuffs from an underground nuclear test at the Frenchman Flat CAU. The results indicate that the majority of groundwater flow through the volcanic section occurs through zones of densely welded tuff where connected fractures provide the transport pathway. Migration rates range between near zero to approximately four m/yr, with a mean rate of 0.68 m/yr. This report presents the results of work under the FY96 Near-Field Modeling task of the UGTA program.

  5. ELECTROLUMINESCENT MATERIAL FOR FLAT PANEL DISPLAY

    SciTech Connect (OSTI)

    Smith, D.B.

    2000-11-13

    The purpose of this Cooperative Research and Development Agreement (CRADA) was to develop a new-generation electroluminescent (EL) material for flat panel displays and related applications by using unique and complementary research capabilities at Oak Ridge National Laboratory and OSRAM Sylvania, Inc. The goal was to produce an EL material with a luminance 10 times greater than conventional EL phosphors. An EL material with this increased luminance would have immediate applications for flat panel display devices (e.g., backlighting for liquid-crystal diodes) and for EL lamp technology. OSRAM Sylvania proposed that increased EL phosphor luminance could be obtained by creating composite EL materials capable of alignment under an applied electric field and capable of concentrating the applied electric field. Oak Ridge National Laboratory used pulsed laser deposition as a method for making these composite EL materials. The materials were evaluated for electroluminescence at laboratory facilities at OSRAM Sylvania, Inc. Many composite structures were thus made and evaluated, and it was observed that a composite structure based on alternating layers of a ferroelectric and a phosphor yielded electroluminescence. An enabling step that was not initially proposed but was conceived during the cooperative effort was found to be crucial to the success of the composite structure. The CRADA period expired before we were able to make quantitative measurements of the luminance and efficiency of the composite EL material. Future cooperative work, outside the scope of the CRADA, will focus on making these measurements and will result in the production of a prototype composite EL device.

  6. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance...

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site .........9 2.2.3 Solar Ponds Plume Treatment System ...

  7. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance...

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site .........8 2.2.3 Solar Ponds Plume Treatment System ...

  8. Microsoft Word - RockyFlatsPropLR111406.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BACKGROUND Nuclear weapons production operations at Rocky Flats were discontinued in 1992. ... Department's Office of Defense Programs to the Office of Environmental Management. ...

  9. Big Flat Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Electric Coop Inc Jump to: navigation, search Name: Big Flat Electric Coop Inc Place: Montana Phone Number: 406-654-2040 Website: bigflatelectric.comindex.htm Outage Hotline:...

  10. Long-Term Surveillance and Maintenance at Rocky Flats: Early...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Overview EA-1747: Final Environmental Assessment The Use of Ecological Restoration Principles To Achieve Remedy Protection at the Fernald Preserve and Weldon Spring ...

  11. Big Flats, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Big Flats, Wisconsin: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 44.111913, -89.8079032 Show Map Loading map... "minzoom":false,"mappingse...

  12. 2006 Annual Ecology Report for the Rocky Flats Site

    Office of Legacy Management (LM)

    Ecology Report for the Rocky Flats Site Click on the links below to access different portions of the electronic annual report. 2006 Annual Report Sections Diffuse Knapweed...

  13. EIS-0276: Rocky Flats Plutonium Storage, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed action to provide safe interim storage of approximately 10 metric tons of plutonium at the Rocky Flats Environmental Technology Site (RFETS).

  14. DOE - Office of Legacy Management -- Rocky Flats SOG

    Office of Legacy Management (LM)

    Guide Appendixes Appendix A: Annual Site Inspection Checklist Appendix B: Example Contact Record Appendix C: Rocky Flats Site Soil Disturbance Evaluation Procedure Appendix D:...

  15. Unique process combination decontaminates mixed wastewater at Rocky Flats

    SciTech Connect (OSTI)

    Kelso, William J.; Cirillo, J. Russ

    1999-08-01

    This paper describes the Sitewide Water Treatment Facility (SWTF) used to process environmental remediation wastewaters found at the Rocky Flats Environmental Technology Site.

  16. Method and composition for testing for the presence of an alkali metal

    DOE Patents [OSTI]

    Guon, Jerold

    1981-01-01

    A method and composition for detecting the presence of an alkali metal on the surface of a body such as a metal plate, tank, pipe or the like is provided. The method comprises contacting the surface with a thin film of a liquid composition comprising a light-colored pigment, an acid-base indicator, and a nonionic wetting agent dispersed in a liquid carrier comprising a minor amount of water and a major amount of an organic solvent selected from the group consisting of the lower aliphatic alcohols, ketones and ethers. Any alkali metal present on the surface in elemental form or as an alkali metal hydroxide or alkali metal carbonate will react with the acid-base indicator to produce a contrasting color change in the thin film, which is readily discernible by visual observation or automatic techniques.

  17. Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure and method of processing

    DOE Patents [OSTI]

    Brown, Jr., Jesse J.; Hirschfeld, Deidre A.; Li, Tingkai

    1993-12-07

    Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure are created using sol-gel processes. The processes have particular application in creating calcium magnesium zirconium phosphate, CMZP, coatings and foams.

  18. Technical Safety Appraisal of the Rocky Flats Plant

    SciTech Connect (OSTI)

    Brown, Blake P.

    1989-01-01

    This report provides the results of a Technical Safety Appraisal (TSA) of the Rocky Flats Plant (RFP) conducted November 14 to 18 and November 28 to December 9, 1988. This appraisal covered the effectiveness and improvements in the RFP safety program across the site, evaluating progress to date against standards of accepted practice. The appraisal included coverage of the timeliness and effectiveness of actions taken in response to the recommendations/concerns in three previous Technical Safety Appraisals (TSAs) of RFP Bldg. 707 conducted in July 1986, Bldgs. 771/774 conducted in October/November 1986, and Bldgs. 776/777 conducted in January/February 1988. Results of this appraisal are given in Section IV for each of 14 technical safety areas at RFP. These results include a discussion, conclusions and any new safety concerns for each technical safety area. Appendix A contains a description of the system for categorizing concerns, and the concerns are tabulated in Appendix B. Appendix C reports on the evaluation of the contractor's actions and the current status of each of the 230 recommendations and concerns contained in the three previous TSA reports.

  19. Environmental Survey preliminary report, Rocky Flats Plant, Golden, Colorado

    SciTech Connect (OSTI)

    Not Available

    1987-06-01

    This report presents the preliminary findings of the Environmental Survey of the United States Department of Energy (DOE), Rocky Flats Plant (RFP), conducted August 11 through 22, 1986. The Survey is being conducted by an multidisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team members are outside experts supplied by a private contractor. The objective of the Survey is to identify environmental problems and areas of environmental risk associated with the RFP. The Survey covers all environmental media and all areas of environmental regulations. It is being performed in accordance with the DOE Environmental Survey Manual. The on-site phase of the Survey involves the review of existing site environmental data observations of the operations carried on at RFP, and interviews with site personnel. The Survey team developed a Sampling and Analysis Plan to assist in further assessing certain environmental problems identified during its on-site activates. The Sampling and Analysis Plan is being executed by DOE's Oak Ridge National Laboratory. When completed, the results will be incorporated into the RFP Environmental Survey Interim Report. The Interim Report will reflect the final determinations of the RFP Survey. 75 refs., 24 figs., 33 tabs.

  20. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, Jr., George D.; Carey, J. William

    1998-01-01

    A method using concentrated aqueous solutions of sodium cobaltinitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na--K--Ca--Si gels are identified by yellow staining, and alkali-poor, Ca--Si gels are identified by pink staining.

  1. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, G.D. Jr.; Carey, J.W.

    1998-04-14

    A method using concentrated aqueous solutions of sodium cobalt nitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na-K-Ca-Si gels are identified by yellow staining, and alkali-poor, Ca-Si gels are identified by pink staining.

  2. In situ formation of coal gasification catalysts from low cost alkali metal salts

    DOE Patents [OSTI]

    Wood, Bernard J.; Brittain, Robert D.; Sancier, Kenneth M.

    1985-01-01

    A carbonaceous material, such as crushed coal, is admixed or impregnated with an inexpensive alkali metal compound, such as sodium chloride, and then pretreated with a stream containing steam at a temperature of 350.degree. to 650.degree. C. to enhance the catalytic activity of the mixture in a subsequent gasification of the mixture. The treatment may result in the transformation of the alkali metal compound into another, more catalytically active, form.

  3. Solvation structure and transport properties of alkali cations in dimethyl sulfoxide under exogenous static electric fields

    SciTech Connect (OSTI)

    Kerisit, Sebastien; Vijayakumar, M. E-mail: karl.mueller@pnnl.gov; Han, Kee Sung; Mueller, Karl T. E-mail: karl.mueller@pnnl.gov

    2015-06-14

    A combination of molecular dynamics simulations and pulsed field gradient nuclear magnetic resonance spectroscopy is used to investigate the role of exogenous electric fields on the solvation structure and dynamics of alkali ions in dimethyl sulfoxide (DMSO) and as a function of temperature. Good agreement was obtained, for select alkali ions in the absence of an electric field, between calculated and experimentally determined diffusion coefficients normalized to that of pure DMSO. Our results indicate that temperatures of up to 400 K and external electric fields of up to 1 V nm{sup −1} have minimal effects on the solvation structure of the smaller alkali cations (Li{sup +} and Na{sup +}) due to their relatively strong ion-solvent interactions, whereas the solvation structures of the larger alkali cations (K{sup +}, Rb{sup +}, and Cs{sup +}) are significantly affected. In addition, although the DMSO exchange dynamics in the first solvation shell differ markedly for the two groups, the drift velocities and mobilities are not significantly affected by the nature of the alkali ion. Overall, although exogenous electric fields induce a drift displacement, their presence does not significantly affect the random diffusive displacement of the alkali ions in DMSO. System temperature is found to have generally a stronger influence on dynamical properties, such as the DMSO exchange dynamics and the ion mobilities, than the presence of electric fields.

  4. Long-Term Surveillance and Maintenance at Rocky Flats: Early Experiences and Lessons Learned

    SciTech Connect (OSTI)

    Surovchak, S.; Kaiser, L.; DiSalvo, R.; Boylan, J.; Squibb, G.; Nelson, J.; Darr, B.; Hanson, M.

    2008-07-01

    The U.S. Department of Energy's (DOE's) Rocky Flats Site was established in 1951 as part of the United States' nationwide nuclear weapons complex to manufacture nuclear weapons components. In 1992 weapons production halted, and the Rocky Flats mission changed to include environmental investigations, cleanup, and site closure. In October 2005, DOE and its contractor completed an accelerated 10-year, $7 billion cleanup of chemical and radiological contamination left from nearly 50 years of production. The cleanup required the decommissioning, decontamination, demolition, and removal of more than 800 structures; removal of more than 500,000 cubic meters of low-level radioactive waste; and remediation of more than 360 potentially contaminated environmental sites. The final remedy for the site was selected in September 2006 and included institutional controls, physical controls, and continued monitoring for the former industrial portion of the site. The remainder of the site, which served as a buffer zone surrounding the former industrial area, was transferred to the U.S. Fish and Wildlife Service in July 2007 for a national wildlife refuge. DOE's Office of Legacy Management is responsible for the long-term surveillance and maintenance of Rocky Flats, which includes remedy implementation activities and general site maintenance. Several factors have complicated the transition from closure to post-closure at Rocky Flats. The early experiences associated with the two years since the physical cleanup and closure work were completed have led to several valuable lessons learned. (authors)

  5. Analysis of Fracture in Cores from the Tuff Confining Unit beneath Yucca Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Lance Prothro

    2008-03-01

    The role fractures play in the movement of groundwater through zeolitic tuffs that form the tuff confining unit (TCU) beneath Yucca Flat, Nevada Test Site, is poorly known. This is an important uncertainty, because beneath most of Yucca Flat the TCU lies between the sources of radionuclide contaminants produced by historic underground nuclear testing and the regional carbonate aquifer. To gain a better understanding of the role fractures play in the movement of groundwater and radionuclides through the TCU beneath Yucca Flat, a fracture analysis focusing on hydraulic properties was performed on conventional cores from four vertical exploratory holes in Area 7 of Yucca Flat that fully penetrate the TCU. The results of this study indicate that the TCU is poorly fractured. Fracture density for all fractures is 0.27 fractures per vertical meter of core. For open fractures, or those observed to have some aperture, the density is only 0.06 fractures per vertical meter of core. Open fractures are characterized by apertures ranging from 0.1 to 10 millimeter, and averaging 1.1 millimeter. Aperture typically occurs as small isolated openings along the fracture, accounting for only 10 percent of the fracture volume, the rest being completely healed by secondary minerals. Zeolite is the most common secondary mineral occurring in 48 percent of the fractures observed.

  6. Kenaf Bast Fibers—Part I: Hermetical Alkali Digestion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Jinshu; Shi, Sheldon Q.; Barnes, H. Michael; Horstemeyer, Mark; Wang, Jinwu; Hassan, El-Barbary M.

    2011-01-01

    The objective of this study was to develop a hermetical alkali digestion process to obtain single cellulosic fibers from kenaf bast. Kenaf bast were hermetically digested into single fiber using a 5% sodium hydroxide solution for one hour at four different temperatures (80 ° C, 110 ° C, 130 ° C, and 160 ° C). The hermetical digestion process used in this study produced fibers with high cellulose content (84.2–92.3%) due to the removal of lignin and hemicelluloses. The surface hardness and elastic modulus of the fibers digested at 130 ° C and 160 ° C were improved significantlymore » compared with those digested at 80 ° C. The tensile modulus and tensile strength of the individual fibers reduced as the digestion temperature increased from 110 ° C to 160 ° C. Micropores were generated in fiber cell wall when the fibers were digested at 130 ° C and 160 ° C. The studies on the composites that were made from polypropylene reinforced with the digested fibers indicated that the compatibility between the digested fibers and polypropylene matrix was poor.« less

  7. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  8. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  9. Microfabricated alkali vapor cell with anti-relaxation wall coating

    SciTech Connect (OSTI)

    Straessle, R.; Ptremand, Y.; Briand, D.; Rooij, N. F. de; Pellaton, M.; Affolderbach, C.; Mileti, G.

    2014-07-28

    We present a microfabricated alkali vapor cell equipped with an anti-relaxation wall coating. The anti-relaxation coating used is octadecyltrichlorosilane and the cell was sealed by thin-film indium-bonding at a low temperature of 140?C. The cell body is made of silicon and Pyrex and features a double-chamber design. Depolarizing properties due to liquid Rb droplets are avoided by confining the Rb droplets to one chamber only. Optical and microwave spectroscopy performed on this wall-coated cell are used to evaluate the cell's relaxation properties and a potential gas contamination. Double-resonance signals obtained from the cell show an intrinsic linewidth that is significantly lower than the linewidth that would be expected in case the cell had no wall coating but only contained a buffer-gas contamination on the level measured by optical spectroscopy. Combined with further experimental evidence this proves the presence of a working anti-relaxation wall coating in the cell. Such cells are of interest for applications in miniature atomic clocks, magnetometers, and other quantum sensors.

  10. Method of treating alkali metal sulfide and carbonate mixtures

    DOE Patents [OSTI]

    Kohl, Arthur L.; Rennick, Robert D.; Savinsky, Martin W.

    1978-01-01

    A method of removing and preferably recovering sulfur values from an alkali metal sulfide and carbonate mixture comprising the steps of (1) introducing the mixture in an aqueous medium into a first carbonation zone and reacting the mixture with a gas containing a major amount of CO.sub.2 and a minor amount of H.sub.2 S; (2) introducing the resultant product from step 1 into a stripping zone maintained at subatmospheric pressure, and contacting this product with steam to produce a gaseous mixture, comprising H.sub.2 S and water vapor, and a liquor of reduced sulfide content; (3) introducing the liquor of reduced sulfide content into a second carbonation zone, and reacting the liquor with substantially pure gaseous CO.sub.2 in an amount sufficient to precipitate bicarbonate crystals and produce an offgas containing CO.sub.2 and H.sub.2 S for use in step 1; (4) recovering the bicarbonate crystals from step 3, and thermally decomposing the crystals to produce an alkaline metal carbonate product and a substantially pure CO.sub.2 offgas for use in step 3.

  11. Numerical Simulation of Inter-basin Groundwater Flow into Northern Yucca Flat, Nevada National Security Site, Using the Death Valley Regional Flow System Model

    SciTech Connect (OSTI)

    Pohlmann Karl,Ye Ming

    2012-03-01

    Models of groundwater flow for the Yucca Flat area of the Nevada National Security Site (NNSS) are under development by the U.S. Department of Energy (DOE) for corrective action investigations of the Yucca Flat-Climax Mine Corrective Action Unit (CAU). One important aspect of these models is the quantity of inter-basin groundwater flow from regional systems to the north. This component of flow, together with its uncertainty, must be properly accounted for in the CAU flow models to provide a defensible regional framework for calculations of radionuclide transport that will support determinations of the Yucca Flat-Climax Mine contaminant boundary. Because characterizing flow boundary conditions in northern Yucca Flat requires evaluation to a higher level of detail than the scale of the Yucca Flat-Climax Mine CAU model can efficiently provide, a study more focused on this aspect of the model was required.

  12. Seismic hazard analysis at Rocky Flats Plant

    SciTech Connect (OSTI)

    McGuire, R.K.

    1993-10-01

    A probabilistic seismic hazard analysis is being conducted for the DOE Rocky Flats Plant, Jefferson County, Colorado. This is part of the overall review of the seismic exposure to facilities being conducted by DOE. The study has four major elements. (1) The historical seismicity in Colorado is being reviewed and synthesized to estimate historical rates of earthquake activity in the region of the site. (2) The geologic and tectonic evidence in Colorado and along the Front Range is being reviewed to determine appropriate seismic zones, potentially active faults, and constraints on fault slip rates. (3) Earthquake ground motion equations are being derived based on seismological knowledge of the earth`s crust. Site specific soil amplification factors are also being developed using on-site shear wave velocity measurements. (4) The probability of exceedence of various seismic ground motion levels is being calculated based on the inputs developed on tectonic sources, faults, ground motion, and soil amplification. Deterministic ground motion estimates are also being made. This study is a state-of-the-art analysis of seismic hazard. It incorporates uncertainties in the major aspects governing seismic hazard, and has a documented basis founded on solid data interpretations for the ranges of inputs used. The results will be a valid basis on which to evaluate plant structures, equipment, and components for seismic effects.

  13. The Critical Mass Laboratory at Rocky Flats

    SciTech Connect (OSTI)

    Rothe, Robert E

    2003-10-15

    The Critical Mass Laboratory (CML) at Rocky Flats northwest of Denver, Colorado, was built in 1964 and commissioned to conduct nuclear experiments on January 28, 1965. It was built to attain more accurate and precise experimental data to ensure nuclear criticality safety at the plant than were previously possible. Prior to its construction, safety data were obtained from long extrapolations of subcritical data (called in situ experiments), calculated parameters from reactor engineering 'models', and a few other imprecise methods. About 1700 critical and critical-approach experiments involving several chemical forms of enriched uranium and plutonium were performed between then and 1988. These experiments included single units and arrays of fissile materials, reflected and 'bare' systems, and configurations with various degrees of moderation, as well as some containing strong neutron absorbers. In 1989, a raid by the Federal Bureau of Investigation (FBI) caused the plant as a whole to focus on 'resumption' instead of further criticality safety experiments. Though either not recognized or not admitted for a few years, that FBI raid did sound the death knell for the CML. The plant's optimistic goal of resumption evolved to one of deactivation, decommissioning, and plantwide demolition during the 1990s. The once-proud CML facility was finally demolished in April of 2002.

  14. Unclassified Source Term and Radionuclide Data for Corrective Action Unit 98: Frenchman Flat Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2005-09-01

    Frenchman Flat is one of several areas of the Nevada Test Site (NTS) used for underground nuclear testing (Figure 1-1). These nuclear tests resulted in groundwater contamination in the vicinity of the underground test areas. As a result, the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) is currently conducting a corrective action investigation (CAI) of the Frenchman Flat underground test areas. Since 1996, the Nevada Division of Environmental Protection (NDEP) has regulated NNSA/NSO corrective actions through the ''Federal Facility Agreement and Consent Order'' ([FFACO], 1996). Appendix VI of the FFACO agreement, ''Corrective Action Strategy'', was revised on December 7, 2000, and describes the processes that will be used to complete corrective actions, including those in the Underground Test Area (UGTA) Project. The individual locations covered by the agreement are known as corrective action sites (CASs), which are grouped into corrective action units (CAUs). The UGTA CASs are grouped geographically into five CAUs: Frenchman Flat, Central Pahute Mesa, Western Pahute Mesa, Yucca Flat/Climax Mine, and Rainier Mesa/Shoshone Mountain (Figure 1-1). These CAUs have distinctly different contaminant source, geologic, and hydrogeologic characteristics related to their location (FFACO, 1996). The Frenchman Flat CAU consists of 10 CASs located in the northern part of Area 5 and the southern part of Area 11 (Figure 1-1). This report documents the evaluation of the information and data available on the unclassified source term and radionuclide contamination for Frenchman Flat, CAU 98. The methodology used to estimate hydrologic source terms (HSTs) for the Frenchman Flat CAU is also documented. The HST of an underground nuclear test is the portion of the total inventory of radionuclides that is released over time into the groundwater following the test. The total residual inventory of radionuclides associated with one or

  15. Adsorption of superplasticizer admixtures on alkali-activated slag pastes

    SciTech Connect (OSTI)

    Palacios, M. Houst, Y.F.; Bowen, P.; Puertas, F.

    2009-08-15

    Alkali-activated slag (AAS) binders are obtained by a manufacturing process less energy-intensive than ordinary Portland cement (OPC) and involves lower greenhouse gasses emission. These alkaline cements allow the production of high mechanical strength and durable concretes. In the present work, the adsorption of different superplasticizer admixtures (naphthalene-based, melamine-based and a vinyl copolymer) on the slag particles in AAS pastes using alkaline solutions with different pH values have been studied in detail. The effect of the superplasticizers on the yield stress and plastic viscosity of the AAS and OPC pastes have been also evaluated. The results obtained allowed us to conclude that the adsorption of the superplasticizers on AAS pastes is independent of the pH of the alkaline solutions used and lower than on OPC pastes. However, the effect of the admixtures on the rheological parameters depends directly on the type and dosage of the superplasticizer as well as of the binder used and, in the case of the AAS, on the pH of the alkaline activator solution. In 11.7-pH NaOH-AAS pastes the dosages of the superplasticizers required to attain similar reduction in the yield stress are ten-fold lower than for Portland cement. In this case the superplasticizers studied show a fluidizing effect considerably higher in 11.7-pH NaOH-AAS pastes than in OPC pastes. In 13.6-pH NaOH-AAS pastes, the only admixture observed to affect the rheological parameters is the naphthalene-based admixture due to its higher chemical stability in such extremely alkaline media.

  16. Thermodynamical description of stationary, asymptotically flat solutions with conical singularities

    SciTech Connect (OSTI)

    Herdeiro, Carlos; Rebelo, Carmen; Radu, Eugen

    2010-05-15

    We examine the thermodynamical properties of a number of asymptotically flat, stationary (but not static) solutions having conical singularities, with both connected and nonconnected event horizons, using the thermodynamical description recently proposed in [C. Herdeiro, B. Kleihaus, J. Kunz, and E. Radu, Phys. Rev. D 81, 064013 (2010).]. The examples considered are the double-Kerr solution, the black ring rotating in either S{sup 2} or S{sup 1}, and the black Saturn, where the balance condition is not imposed for the latter two solutions. We show that not only the Bekenstein-Hawking area law is recovered from the thermodynamical description, but also the thermodynamical angular momentum is the Arnowitt-Deser-Misner angular momentum. We also analyze the thermodynamical stability and show that, for all these solutions, either the isothermal moment of inertia or the specific heat at constant angular momentum is negative, at any point in parameter space. Therefore, all these solutions are thermodynamically unstable in the grand canonical ensemble.

  17. Rocky Flats 100th Shipments Arrives at WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE Rocky Flats For Immediate Release Contact: Karen Lutz, DOE RFFO, 303/966-4546 01-08 Jennifer Thompson, Kaiser-Hill, 303/966-6285 Kate Foster, Westinghouse TRU Solutions, 505/234-7589 Rocky Flats' 100 th Shipment Arrives at Waste Isolation Pilot Plant DENVER, Colo., March 14, 2001- The 100 th shipment of transuranic waste from the U.S. Department of Energy's (DOE) Rocky Flats Environmental Technology Site (RFETS) has arrived at DOE's Waste Isolation Pilot Plant (WIPP) in New Mexico. Rocky

  18. DOE - NNSA/NFO -- Frenchman Flat Peer Review

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frenchman Flat Peer Review NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office Click to subscribe to NNSS News Frenchman Flat Peer Review Following are the Frenchman Flat Peer Review documents: PDF icon Completion Report for Well Cluster ER-5-3 DOE/NV-11718-1093 [PDF, 5.8 MB] PDF icon Completion Report for Well Cluster ER-5-4 DOE/NV-11718-998 [PDF, 5.2 MB] PDF icon Errata for Nevada National Security Site Radionuclide Inventory, Bowen et al LA-13859-MS [PDF, 96 KB] PDF icon Evaluation

  19. Eddy-current transducer based on flat spiral coils

    SciTech Connect (OSTI)

    Franyuk, V.A.; Ivan'kovich, L.F.

    1988-12-01

    The article deals with the experimental investigation of flat-coil eddy current transducers with spiral windings. It is shown that it is possible to use them for detecting discontinuities on electrically conducting products with different configuration of the surface. The instrument is described. The use of crossed flat coils makes it possible effectively to detect flaws in electrically conducting products of any shape. A transducer containing crossed flat coils helps, in addition to detecting flaws, in evaluating anisotropy (magnetic and mechanical) from which conclusions as to the physicomechanical properties of the product can be drawn.

  20. The direct observation of alkali vapor species in biomass combustion and gasification

    SciTech Connect (OSTI)

    French, R.J.; Dayton, D.C.; Milne, T.A.

    1994-01-01

    This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

  1. Geomorphic Surface Maps of Northern Frenchman Flat, Nevada Test Site, Southern Nevada

    SciTech Connect (OSTI)

    Bechtel Nevada

    2005-08-01

    Large-scale (1:6000) surficial geology maps of northern Frenchman Flat were developed in 1995 as part of comprehensive site characterization required to operate a low-level radioactive waste disposal facility in that area. Seven surficial geology maps provide fundamental data on natural processes and are the platform needed to reconstruct the Quaternary history of northern Frenchman Flat. Reconstruction of the Quaternary history provides an understanding of the natural processes that act to develop the landscape, and the time-frames involved in landscape development. The mapping was conducted using color and color-infrared aerial photographs and field verification of map unit composition and boundaries. Criteria for defining the map unit composition of geomorphic surface units are based on relative geomorphic position, landform morphology, and degree of preservation of surface morphology. Seven geomorphic surfaces (Units 1 through 7) are recognized, spanning from the early Quaternary to present time.

  2. Air Quality Scoping Study for Sarcobatus Flat, Nevada (EMSI April 2007)

    SciTech Connect (OSTI)

    Engelbrecht, Johann; Kavouras, Ilias; Campbell, Dave; Campbell, Scott; Kohl, Steven; Shafer, David

    2007-04-01

    The Desert Research Institute (DRI) is performing a scoping study as part of the U.S. Department of Energys Yucca Mountain Environmental Monitoring Systems Initiative (EMSI). The main objective is to obtain baseline air quality information for Yucca Mountain and an area surrounding the Nevada Test Site (NTS). Air quality and meteorological monitoring and sampling equipment housed in a mobile trailer (shelter) is collecting data at seven sites outside the NTS, including Ash Meadows National Wildlife Refuge, Sarcobatus Flat, Beatty, Rachel, Caliente, Pahranagat National Wildlife Refuge, and Crater Flat, and at four sites on the NTS. The trailer is stationed at any one site for approximately eight weeks at a time. Letter reports provide summaries of air quality and meteorological data, on completion of each sites sampling program.

  3. Rocky Flats Environmental Technology Site Ecological Monitoring Program 1995 annual report

    SciTech Connect (OSTI)

    1995-05-31

    The Ecological Monitoring Program (ECMP) was established at the Rocky Flats Environmental Technology Site (Site) in September 1992. At that time, EcMP staff developed a Program Plan that was peer-reviewed by scientists from western universities before submittal to DOE RFFO in January 1993. The intent of the program is to measure several quantitative variables at different ecological scales in order to characterize the Rocky Flats ecosystem. This information is necessary to document ecological conditions at the Site in impacted and nonimpacted areas to determine if Site practices have had ecological impacts, either positive or negative. This information can be used by managers interested in future use scenarios and CERCLA activities. Others interested in impact analysis may also find the information useful. In addition, these measurements are entered into a database which will serve as a long-term information repository that will document long-term trends and potential future changes to the Site, both natural and anthropogenic.

  4. Water Monitoring Flume Replaced at the Rocky Flats, Colorado, Site

    Broader source: Energy.gov [DOE]

    In August of this year the U.S. Department of Energy (DOE) Office of Legacy Management (LM) Rocky Flats, site took advantage of an existing water diversion structure that was no longer needed, to...

  5. Flat-Plate Photovoltaic Module Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Module Basics Flat-Plate Photovoltaic Module Basics August 20, 2013 - 4:25pm Addthis ... a high transmission in the wavelengths that can be used by the solar cells in the module. ...

  6. Benchmarking and performance improvement at Rocky Flats Technology Site

    SciTech Connect (OSTI)

    Elliott, C.; Doyle, G.; Featherman, W.L.

    1997-03-01

    The Rocky Flats Environmental Technology Site has initiated a major work process improvement campaign using the tools of formalized benchmarking and streamlining. This paper provides insights into some of the process improvement activities performed at Rocky Flats from November 1995 through December 1996. It reviews the background, motivation, methodology, results, and lessons learned from this ongoing effort. The paper also presents important gains realized through process analysis and improvement including significant cost savings, productivity improvements, and an enhanced understanding of site work processes.

  7. 2006 Annual Ecology Report for the Rocky Flats Site

    Office of Legacy Management (LM)

    Ecology Report for the Rocky Flats Site Click on the links below to access different portions of the electronic annual report. 2006 Annual Report Sections Diffuse Knapweed Biocontrol Monitoring Report Dalmatian Toadflax Monitoring Report High-Value Vegetation Monitoring Report Revegetation Monitoring Report Present and Original Landfill Revegetation Monitoring Report Frog Vocalization Monitoring Report Appendix A (Files below comprise Appendix A for the above listed reports.) Rocky Flats Flora

  8. 2D 'Flat' Boron Yields a Superconducting Surprise

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2D 'Flat' Boron Yields a Superconducting Surprise 2D 'Flat' Boron Yields a Superconducting Surprise Simulations Run at NERSC Help Reveal Material's Superconducting Superpowers April 22, 2016 2Dboron Electrons with opposite momenta and spins pair up via lattice vibrations at low temperatures in 2D boron and give it superconducting properties. Image: Evgeni Penev, Rice University Density functional theory simulations run at NERSC helped Rice University researchers determine that two-dimensional

  9. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance

    Office of Legacy Management (LM)

    Second Quarter Calendar Year 2013 October 2013 LMS/RFS/S10694 This page intentionally left blank LMS/RFS/S10694 Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance and Maintenance Activities Second Quarter Calendar Year 2013 October 2013 This page intentionally left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site Surveillance and Maintenance Activities-2nd Quarter CY 2013 October 2013 Doc. No. S10694 Page i Contents Abbreviations

  10. Averaged null energy condition violation in a conformally flat spacetime

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-01-15

    We show that the averaged null energy condition can be violated by a conformally coupled scalar field in a conformally flat spacetime in 3+1 dimensions. The violation is dependent on the quantum state and can be made as large as desired. It does not arise from the presence of anomalies, although anomalous violations are also possible. Since all geodesics in conformally flat spacetimes are achronal, the achronal averaged null energy condition is likewise violated.

  11. LPO5-002-Proj-Poster-WIND-ShepardsFlat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SHEPHERDS FLAT Spanning two counties of working heritage ranch land in eastern Oregon, Shepherds Flat is one of the world's largest wind farms. INVESTING in AMERICAN ENERGY OWNER Caithness Energy, LLC LOCATIONS Gilliam County & Morrow County, Oregon LOAN AMOUNT $1.3 Billion ISSUANCE DATE December 2010 GENERATION CAPACITY 845 MW PROJECTED ANNUAL GENERATION 1,800,000 MWh CLIMATE BENEFIT 1,000,000 Metric Tons of CO 2 Prevented Annually

  12. The use of performance parameters in monitoring the safety of dams experiencing alkali-aggregate reaction

    SciTech Connect (OSTI)

    Veesaert, C.J.; LaBoon, J.H.

    1995-12-31

    As the Bureau of Reclamation (Reclamation) moves away from design and construction of new water resource projects toward optimizing the management of existing water resource projects, monitoring the condition of high risk structures such as dams becomes very important. To address this need, Reclamation has developed a logical approach of monitoring the safety of a dam over time. This approach analyzes visual and instrumentation performance parameters unique to each dam, Performance parameters specify the expected performance (behavior) of both embankment and concrete dams, including those concrete dams effected by alkali-aggregate reaction. This paper presents an overview of the concept of performance parameters in monitoring the safety of dams, which have experienced alkali-aggregate reaction. Three case studies are presented to illustrate the use of performance parameters in monitoring a dam`s behavior over time, relative to the effects of alkali-aggregate reaction.

  13. Geologic Characterization of Young Alluvial Basin-Fill Deposits from Drill Hole Data in Yucca Flat, Nye County, Nevada.

    SciTech Connect (OSTI)

    Donald S. Sweetkind; Ronald M. Drake II

    2007-01-22

    Yucca Flat is a topographic and structural basin in the northeastern part of the Nevada Test Site (NTS) in Nye County, Nevada, that has been the site of numerous underground nuclear tests; many of these tests occurred within the young alluvial basin-fill deposits. The migration of radionuclides to the Paleozoic carbonate aquifer involves passage through this thick, heterogeneous section of Tertiary and Quaternary rock. An understanding of the lateral and vertical changes in the material properties of young alluvial basin-fill deposits will aid in the further development of the hydrogeologic framework and the delineation of hydrostratigraphic units and hydraulic properties required for simulating ground-water flow in the Yucca Flat area. This report by the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, presents data and interpretation regarding the three-dimensional variability of the shallow alluvial aquifers in areas of testing at Yucca Flat, data that are potentially useful in the understanding of the subsurface flow system. This report includes a summary and interpretation of alluvial basin-fill stratigraphy in the Yucca Flat area based on drill hole data from 285 selected drill holes. Spatial variations in lithology and grain size of the Neogene basin-fill sediments can be established when data from numerous drill holes are considered together. Lithologic variations are related to different depositional environments within the basin including alluvial fan, channel, basin axis, and playa deposits.

  14. Evaluation of alkali metal sulfate dew point measurement for detection of hot corrosion conditions in PFBC flue gas

    SciTech Connect (OSTI)

    Helt, J.E.

    1980-11-01

    Hot corrosion in combustion systems is, in general, the accelerated oxidation of nickel, cobalt, and iron-base alloys which occurs in the presence of small amounts of impurities - notably, sodium, sulfur, chlorine, and vanadium. There is no real consensus on which mechanisms are primarily responsible for high-temperature corrosion. One point generally accepted, however, is that corrosion reactions take place at an appreciable rate only in the presence of a liquid phase. When coal is the fuel for combustion, hot corrosion may occur in the form of accelerated sulfidation. It is generally agreed by investigators that molten alkali metal sulfates (Na/sub 2/SO/sub 4/ and K/sub 2/SO/sub 4/) are the principal agents responsible for the occurrence of sulfidation. Although molten sodium sulfate by itself appears to have little or no effect on the corrosion of metal alloys, its presence may increase the accessibility of the bare metal surface to the external atmosphere. If this atmosphere contains either a reductant and/or an oxide such as SiO/sub 2/, SO/sub 3/, or NaOH(Na/sub 2/O), corrosion is likely to occur. Alkali metal sulfate dew point measurement was evaluated as a means of anticipating hot corrosion in the gas turbine of a pressurized fluidized-bed combustion system. The hot corrosion mechanism and deposition rate theory were reviewed. Two methods of dew point measurement, electrical conductivity and remote optical techniques, were identified as having a potential for this application. Both techniques are outlined; practical measurement systems are suggested; and potential problem areas are identified.

  15. Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report

    SciTech Connect (OSTI)

    Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

    1994-02-01

    Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

  16. Theory of magic optical traps for Zeeman-insensitive clock transitions in alkali-metal atoms

    SciTech Connect (OSTI)

    Derevianko, Andrei

    2010-05-15

    Precision measurements and quantum-information processing with cold atoms may benefit from trapping atoms with specially engineered, 'magic' optical fields. At the magic trapping conditions, the relevant atomic properties remain immune to strong perturbations by the trapping fields. Here we develop a theoretical analysis of magic trapping for especially valuable Zeeman-insensitive clock transitions in alkali-metal atoms. The involved mechanism relies on applying a magic bias B field along a circularly polarized trapping laser field. We map out these B fields as a function of trapping laser wavelength for all commonly used alkalis. We also highlight a common error in evaluating Stark shifts of hyperfine manifolds.

  17. A three-dimensional spatial model of plutonium in soil near Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Webb, S.B.; Ibrahim, S.A.; Whicker, F.W.

    1997-08-01

    The horizontal and depth distribution of plutonium was measured in soil east of the Rocky Flats Environmental Technology Site (formerly the Rocky Flats Plant) near Denver, Colorado, during 1992-1994. The study area was centered on the eastern plume of plutonium contamination and included transacts extending from 0.2 km east of the primary origin of the contamination (the 903 Pad) to distances of up to 19 km northeast, east, southeast and south-southeast of the 903 Pad. Soil was collected in 3 cm layers down to 21 cm at exponentially increasing distances along the four transacts. Plutonium concentrations decreased rapidly with depth, distance from the 903 Pad, and angle from due east. Depth distributions were independent of distance and angle from the 903 Pad, and our profile model can be used to adjust to a common basis, historical measurements made from sampling to different depths. Based on a total of {approximately}1,400 independent measurements, mathematical functions were developed to describe the distance, directional, and depth relationships. These equations, combined with soil density and rock measurements, provided a new method to estimate the plutonium concentration or total deposition per unit area anywhere within the study area. Total deposition per unit area measurements at 50 sites provided an independent test of the model`s predictive accuracy. Sampling coefficients of variation based on replicate samples at the main sampling locations averaged 33%, but ranged from 12 to 98%. The analytical measurement coefficient of variation averaged 8%. Mean 0-3 cm soil concentrations of {sup 239}Pu among 10 Front Range {open_quotes}background{close_quotes} and 11 community locations near Rocky Flats were 2.1 and 2.3 Bq kg{sup -1}, respectively. 45 refs., 8 figs., 1 tab.

  18. Value of information analysis for corrective action unit No. 98: Frenchman Flat

    SciTech Connect (OSTI)

    NONE

    1997-06-01

    A value of information analysis has been completed as part of the corrective action process for Frenchman Flat, the first Nevada Test Site underground test area to be scheduled for the corrective action process. A value of information analysis is a cost-benefit analysis applied to the acquisition of new information which is needed to reduce the uncertainty in the prediction of a contaminant boundary surrounding underground nuclear tests in Frenchman Flat. The boundary location will be established to protect human health and the environment from the consequences of using contaminated groundwater on the Nevada Test Site. Uncertainties in the boundary predictions are assumed to be the result of data gaps. The value of information analysis in this document compares the cost of acquiring new information with the benefit of acquiring that information during the corrective action investigation at Frenchman Flat. Methodologies incorporated into the value of information analysis include previous geological modeling, groundwater flow modeling, contaminant transport modeling, statistics, sensitivity analysis, uncertainty analysis, and decision analysis.

  19. Technical safety appraisal: Buildings 776/777 Rocky Flats Plant

    SciTech Connect (OSTI)

    Field, H C

    1988-03-01

    Buildings 776/777 at the Rocky Flats Plant are major components of the production complex at the plant site. They have been in operation since 1957. The operations taking place in the buildings are nuclear weapons production support, processing of weapons assemblies returned from Pantex, waste processing, research and development in support of production, special projects, and those generated by support groups, such as maintenance. The appraisal team identified nine deficiencies that it believed required prompt attention. DOE management for EH, the program office (Defense Programs), and the field office analyzed the information provided by the appraisal team and instituted compensatory measures for closer monitoring of contractor activities by knowledgeable DOE staff and staff from other sites. Concurrently, the contractor was requested to address both short-term and long-term remedial measures to correct the identified issues as well as the underlying problems. The contractor has provided his action plan, which is included. This plan was under evaluation by EH and the DOE program office at the time this report was prepared. In addressing the major areas of concern identified above, a well as the specific deficiencies identified by the appraisal team, the contractor and the field office are cautioned to search for the root causes for the problems and to direct corrective actions to those root causes rather than solely to the symptoms to assure the sustainability of the improvements being made. The results of prior TSAs led DOE to conclude that previous corrective actions were not sufficient in that a large number of the individual findings are recurrent. Pending completion of remedial actions over the next few months, enhanced DOE oversight of the contractor is warranted.

  20. Historical Exposures to Chemicals at the Rocky Flats Nuclear Weapons Plant: A Pilot Retrospective Exposure Assessment

    SciTech Connect (OSTI)

    Janeen Denise Robertson

    1999-02-01

    In a mortality study of white males who had worked at the Rocky Flats Nuclear Weapons Plant between 1952 and 1979, an increased number of deaths from benign and unspecified intracranial neoplasms was found. A case-control study nested within this cohort investigated the hypothesis that an association existed between brain tumor death and exposure to either internally deposited plutonium or external ionizing radiation. There was no statistically significant association found between estimated radiation exposure from internally deposited plutonium and the development of brain tumors. Exposure by job or work area showed no significant difference between the cohort and the control groups. An update of the study found elevated risk estimates for (1) all lymphopoietic neoplasms, and (2) all causes of death in employees with body burdens greater than or equal to two nanocuries of plutonium. There was an excess of brain tumors for the entire cohort. Similar cohort studies conducted on worker populations from other plutonium handling facilities have not yet shown any elevated risks for brain tumors. Historically, the Rocky Flats Nuclear Weapons Plant used large quantities of chemicals in their production operations. The use of solvents, particularly carbon tetrachloride, was unique to Rocky Flats. No investigation of the possible confounding effects of chemical exposures was done in the initial studies. The objectives of the present study are to (1) investigate the history of chemical use at the Rocky Flats facility; (2) locate and analyze chemical monitoring information in order to assess employee exposure to the chemicals that were used in the highest volume; and (3) determine the feasibility of establishing a chemical exposure assessment model that could be used in future epidemiology studies.

  1. Corrective Action Investigation Plan for Corrective Action Unit 98: Frenchman Flat, Nevada Test Site, Nevada (Revision 1)

    SciTech Connect (OSTI)

    USDOE/NV

    1999-07-01

    This Corrective Action Investigation Plan (CAIP) has been developed for Frenchman Flat Corrective Action Unit (CAU) 98. The Frenchman Flat CAU is located along the eastern border of the Nevada Test Site (NTS) and includes portions of Areas 5 and 11. The Frenchman Flat CAU constitutes one of several areas of the Nevada Test Site used for underground nuclear testing in the past. The nuclear tests resulted in groundwater contamination in the vicinity as well as downgradient of the underground test areas. The CAIP describes the Corrective Action Investigation (CAI) to be conducted at the Frenchman Flat CAU to evaluate the extent of contamination in groundwater due to the underground nuclear testing. The Frenchman Flat CAI will be conducted by the Underground Test Area (UGTA) Project which is a part of the U.S. Department of Energy, Nevada Operations Office (DOE/NV) Environmental Restoration Project. The CAIP is a requirement of the Federal Facility Agreement and Consent Order (FFACO) (1996 ) agreed to by the U.S. Department of Energy (DOE), the Nevada Division of Environmental Protection (NDEP), and the U.S. Department of Defense (DoD). Based on the general definition of a CAI from Section IV.14 of the FFACO, the purpose of the CAI is ''...to gather data sufficient to characterize the nature, extent, and rate of migration or potential rate of migration from releases or discharges of pollutants or contaminants and/or potential releases or discharges from corrective action units identified at the facilities...'' (FFACO, 1996). However, for the Underground Test Area (UGTA) CAUs, ''...the objective of the CAI process is to define boundaries around each UGTA CAU that establish areas that contain water that may be unsafe for domestic and municipal use.'', as stated in Appendix VI of the FFACO (1996). According to the UGTA strategy (Appendix VI of the FFACO), the CAI of a given CAU starts with the evaluation of the existing data. New data collection activities are generally

  2. Method for inhibiting alkali metal corrosion of nickel-containing alloys

    DOE Patents [OSTI]

    DeVan, Jackson H.; Selle, James E.

    1983-01-01

    Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

  3. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A.

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  4. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M.; Peng, Marcus Y.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard C.

    1996-01-01

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  5. High temperature alkali corrosion of ceramics in coal gas: Final report

    SciTech Connect (OSTI)

    Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

    1994-12-31

    There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.

  6. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  7. Alkali slurry ozonation to produce a high capacity nickel battery material

    DOE Patents [OSTI]

    Jackovitz, John F.; Pantier, Earl A.

    1984-11-06

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  8. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  9. Dissolution of HTGR TRISO beads by the alkali fluoride fusion method

    SciTech Connect (OSTI)

    Byster, S.E.

    1980-07-01

    The alkali fluoride fusion method for the dissolution of HTGR TRISO fuel beads offers significant time advantage over other commonly used fusion procedures when applied to samples weighing less than three grams. The method is straightforward, utilizes standard analytical laboratory equipment, and yields solutions which may be utilized by customary procedures.

  10. Improvements to the Rocky Flats Metrology Laboratories Velocity Meter Calibration System

    SciTech Connect (OSTI)

    Abercrombie, K.R.

    1992-03-12

    The Rocky Flats Standards Laboratory has undertaken a project to improve calibration of air velocity meters by reducing the uncertainty of the Velocity Meter Calibration System. The project was accomplished by analyzing the governing equation in order to determine which areas within the system contributed most to the overall system uncertainty. Then, based upon this new analysis, new components were selected to replace the components identified in the analysis. Finally, the system was re-evaluated to determine the new systematic uncertainty for the system.

  11. Implementation of IAEA safeguards at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Giacomini, J.J.; Finleon, C.A.; Larsen, R.K.; Lucas, M.; Langner, D.

    1995-07-01

    When President Clinton spoke to the United Nations General Assembly in September 1993, he offered to place US excess defense nuclear material under International Atomic Energy Agency (IAEA) safeguards, before the next Nuclear Nonproliferation Treaty (NPT) Extension Conference. This set in motion a flurry of activities at three DOE facilities, including Rocky Flats Environmental Technology Site (Site). With general guidance from DOE Headquarters, the facility selected a suitable storage area, identified appropriate materials, and acquired the necessary instrumentation to implement full-scale IAEA safeguards on excess plutonium oxide.

  12. Surficial Geology and Landscape Development in Northern Frenchman Flat, Interim Summary and Soil Data

    SciTech Connect (OSTI)

    Raytheon Services Nevada Environmental Restoration and Waste Management Division

    1995-09-01

    This report summarizes geologic studies by Raytheon Services Nevada near the Area 5 Radioactive Waste Management Site at the Nevada Test Site. These studies are part of a program to satisfy data needs of (1) the Greater Confinement Disposal (GCD) Program Performance Assessment (PA), (2) the low-level waste (LLW) PA, and (3) the Resource Conservation and Recovery Act (RCRA) permit application. The geologic studies were integrated into a single program that worked toward a landscape evolution model of northern Frenchman Flat, with more detailed geologic studies of particular topics as needed. Only the Holocene tectonism and surficial geology components of the landscape model are presented in this report.

  13. Adsorbent Alkali Conditioning for Uranium Adsorption from Seawater. Adsorbent Performance and Technology Cost Evaluation

    SciTech Connect (OSTI)

    Tsouris, Costas; Mayes, Richard T.; Janke, Christopher James; Dai, Sheng; Das, S.; Liao, W. -P.; Kuo, Li-Jung; Wood, Jordana; Gill, Gary; Byers, Maggie Flicker; Schneider, Eric

    2015-09-30

    The Fuel Resources program of the Fuel Cycle Research and Development program of the Office of Nuclear Energy (NE) is focused on identifying and implementing actions to assure that nuclear fuel resources are available in the United States. An immense source of uranium is seawater, which contains an estimated amount of 4.5 billion tonnes of dissolved uranium. This unconventional resource can provide a price cap and ensure centuries of uranium supply for future nuclear energy production. NE initiated a multidisciplinary program with participants from national laboratories, universities, and research institutes to enable technical breakthroughs related to uranium recovery from seawater. The goal is to develop advanced adsorbents to reduce the seawater uranium recovery technology cost and uncertainties. Under this program, Oak Ridge National Laboratory (ORNL) has developed a new amidoxime-based adsorbent of high surface area, which tripled the uranium capacity of leading Japanese adsorbents. Parallel efforts have been focused on the optimization of the physicochemical and operating parameters used during the preparation of the adsorbent for deployment. A set of parameters that need to be optimized are related to the conditioning of the adsorbent with alkali solution, which is necessary prior to adsorbent deployment. Previous work indicated that alkali-conditioning parameters significantly affect the adsorbent performance. Initiated in 2014, this study had as a goal to determine optimal parameters such as base type and concentration, temperature, and duration of conditioning that maximize the uranium adsorption performance of amidoxime functionalized adsorbent, while keeping the cost of uranium production low. After base-treatment at various conditions, samples of adsorbent developed at ORNL were tested in this study with batch simulated seawater solution of 8-ppm uranium concentration, batch seawater spiked with uranium nitrate at 75-100 ppb uranium, and continuous

  14. Rocky Flats Plant Site Environmental Report, January--December 1990

    SciTech Connect (OSTI)

    Cirrincione, D.A.; Costain, D.B.

    1990-12-31

    This report provides information to the public about the impact of the Rocky Flats Plant on the environment and public health. The report contains a compliance summary, a description of environmental monitoring programs, and radiation dose estimates for the surrounding population for the period January 1 through December 31, 1990. An environmental surveillance program has been ongoing at the Rocky Flats Plant since the 1950s. Early programs focused on radiological impacts to the environment. The current program examines potential impacts to air, surface water, groundwater, and soils from radiological and nonradiological sources. Environmental operations at Rocky Flats Plant are under the jurisdiction of several local, state, and federal agencies, most notably the Colorado Department of Health, Environmental Protection Agency, and Department of Energy. A variety of reports are prepared at different intervals for these and other agencies in addition to the annual environmental report.

  15. NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS

    SciTech Connect (OSTI)

    Hemrick, James Gordon; Smith, Jeffrey D; O'Hara, Kelley; Rodrigues-Schroer, Angela; Colavito,

    2012-08-01

    A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new

  16. Proceedings of the Flat-Plate Solar Array Project Research Forum on the design of flat-plate photovoltaic arrays for central stations

    SciTech Connect (OSTI)

    1983-01-01

    The Flat-Plate Solar Array Project, managed by the Jet Propulsion Laboratory for the US Department of Energy, has focused on advancing technologies relevant to the design and construction of megawatt-level central-station systems. Photovoltaic modules and arrays for flat-plate central-station or other large-scale electric power production facilities require the establishment of a technical base that resolves design issues and results in practical and cost-effective configurations. The Central Station Research Forum addressed design, qualification and maintenance issues related to central-station arrays derived from the engineering and operating experiences of early applications and parallel laboratory research activities. Technical issues were examined from the viewpoint of the utility engineer, architect-engineer and laboratory researcher. The forum included presentations on optimum source-circuit designs, module insulation design for high system voltages, array safety, structural interface design, measurements and array operation and maintenance. The Research Forum focused on current capabilities as well as design difficulties requiring additional technological thrusts and/or continued research emphasis. Session topic summaries highlighting major points during group discussions, identifying promising technical approaches or areas of future research, are presented.

  17. Benchmarking and Performance Improvement at Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Elliott, C. , Doyle, D. , Featherman, W.D.

    1997-12-31

    The Rocky Flats Environmental Technology Site (RFETS) has initiated a major work process improvement campaign using the tools of formalized benchmarking and streamlining. This paper provides insights into some of the process improvement activities performed at Rocky Flats from November 1995 through December 1996. It reviews the background, motivation, methodology, results, and lessons learned from this ongoing effort. The paper also presents important gains realized through process analysis and improvement including significant cost savings, productivity improvements, and an enhanced understanding of site work processes.

  18. Hydrogeologic characterization report for the Rocky Flats environmental technology site

    SciTech Connect (OSTI)

    Reeder, D.C.; Burcar, S.; Smith, R.

    1996-12-31

    The Denver groundwater basin encompasses approximately 6,700 square miles, extending east from the Front Range of the Rocky Mountains. This structural basin contains four Cretaceous bedrock aquifers overlain by a regional Quaternary alluvial aquifer. The Rocky Flats Site is located on the northwest margin of the basin. The shallow groundwater system at the Rocky Flats Site is divided into upper and lower hydrostratigraphic units (UHSU and LHSU, respectively). The UHSU at the Rocky Flats site comprises Quaternary alluvium, colluvium, valley-fill alluvium, artificial fill, weathered bedrock of the undifferentiated Arapahoe and Laramie formations and all sandstones that are hydraulically connected with overlying surficial groundwater. The LHSU comprises unweathered claystone with interbedded siltstones and sandstones of the undifferentiated Arapahoe and Laramie formations. The contact separating the UHSU and LHSU is identified as the base of the weathered zone. The separation of hydrostratigraphic units is supported by the contrasting permeabilities of the units comprising the UHSU and LHSU, well hydrograph data indicating that the units respond differently to seasonal recharge events, and geochemical data reflecting distinct major ion chemistries in the groundwaters of the UHSU and LHSU. Surface-water/groundwater interactions at the Rocky Flats site generally respond to seasonal fluctuations in precipitation, recharge, groundwater storage, and stream and ditch flow. Effluent conditions are dominant in the spring along western stream segments and influent conditions are common in the late summer and fall along most stream reaches.

  19. Rocky Flats Cleanup Agreement implementation successes and challenges

    SciTech Connect (OSTI)

    Shelton, D.C.

    1997-02-01

    On July 19, 1996 the US Department of Energy (DOE), State of Colorado (CDPHE), and US Environmental Protection Agency (EPA) entered into an agreement called the Rocky Flats Cleanup Agreement (RFCA) for the cleanup and closure of the Rocky Flats Environmental Technology Site (RFETS or Rocky Flats). Major elements of the agreement include: an Integrated Site-Wide Baseline; up to twelve significant enforceable milestones per year; agreed upon soil and water action levels and standards for cleanup; open space as the likely foreseeable land use; the plutonium and TRU waste removed by 2015; streamlined regulatory process; agreement with the Defense Nuclear Facilities Safety Board (DNFSB) to coordinate activities; and a risk reduction focus. Successful implementation of RFCA requires a substantial effort by the parties to change their way of thinking about RFETS and meet the deliverables and commitments. Substantial progress toward Site closure through the implementation of RFCA has been accomplished in the short time since the signing, yet much remains to be done. Much can be learned from the Rocky Flats experience by other facilities in similar situations.

  20. TGS measurements of pyrochemical salts at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D. J.; Hansen, J. S.; Lestone, J. P.; Prettyman, T. H.

    2001-01-01

    A new skid-mounted tomographic gamma scanner (TGS) was designed to assist in the decommissioning of Rocky Flats Building 37 1, This instrument was used to assay pyrochemical salts as a prerequisite for disposal at the Waste Isolation Pilot Plant (WIPP). The following paper discusses measurement challenges and results from the first year of operation of the instrument.

  1. Site wide integration of the Rocky Flats closure project

    SciTech Connect (OSTI)

    Burdge, L.F.; Golan, P.

    1998-06-01

    The prime contractor for the Rocky Flats Closure Project (RFCP), Kaiser-Hill, in concert with the Department of Energy--Rocky Flats Field Office (DOE-RFFO) has applied a fully integrated, life-cycle, critical path schedule and work planning system to manage the work that is required to close the Site. The closure of the Site is complex, in that it houses over 700 facilities, 19,600 kilograms of Special Nuclear Material (Plutonium and Uranium), and over 160,000 cubic meters of Transuranic, Low Level, and Hazardous Waste. The deactivation, decommissioning, decontaminating, and demolition of this large number of facilities, while at the same time accommodating difficult on-going activities, significantly increases the sophistication required in the planning process. The Rocky Flats team has overcome these difficulties by establishing a money oriented critical path process, to provide a least-cost avenue to supporting on-going activities and a line-of-balance process for production oriented activities. These processes, when integrated with a typical activity-based project planning system, guide the way to the shortest and most cost-effective course for the closure of the Rocky Flats Site.

  2. Adsorption study for uranium in Rocky Flats groundwater

    SciTech Connect (OSTI)

    Laul, J.C.; Rupert, M.C.; Harris, M.J.; Duran, A.

    1995-01-01

    Six adsorbents were studied to determine their effectiveness in removing uranium in Rocky Flats groundwater. The bench column and batch (Kd) tests showed that uranium can be removed (>99.9%) by four adsorbents. Bone Charcoal (R1O22); F-1 Alumina (granular activated alumina); BIOFIX (immobilized biological agent); SOPBPLUS (mixed metal oxide); Filtrasorb 300 (granular activated carbon); and Zeolite (clinoptilolite).

  3. An assessment of criticality safety at the Department of Energy Rocky Flats Plant, Golden, Colorado, July--September 1989

    SciTech Connect (OSTI)

    Mattson, Roger J.

    1989-09-01

    This is a report on the 1989 independent Criticality Safety Assessment of the Rocky Flats Plant, primarily in response to public concerns that nuclear criticality accidents involving plutonium may have occurred at this nuclear weapon component fabrication and processing plant. The report evaluates environmental issues, fissile material storage practices, ventilation system problem areas, and criticality safety practices. While no evidence of a criticality accident was found, several recommendations are made for criticality safety improvements. 9 tabs.

  4. Petrography study of two siliceous limestones submitted to alkali-silica reaction

    SciTech Connect (OSTI)

    Monnin, Y. . E-mail: monnin@ensm-douai.fr; Degrugilliers, P.; Bulteel, D.; Garcia-Diaz, E.

    2006-08-15

    This study presents the contribution of petrography to the comprehension of the alkali-silica reaction mechanism applied to two siliceous limestones. A petrography study was made on the two aggregates before reaction to define their relative proportions and types of reactive silica and to observe their distribution in the microstructure. Then a model reactor, constituted by the reactive siliceous limestone aggregate, portlandite and NaOH, was used to measure the swelling due to reaction of the silica with alkalis and the free expansion of the aggregates. The volume evolution between both aggregates was very different and could be explained by the preliminary petrographic study. It appears that the swelling of the aggregates is conditioned by the microstructure of the carbonated matrix, the quantity and the distribution of the reactive silica.

  5. An Aqueous Redox Flow Battery Based on Neutral Alkali Metal Ferri/ferrocyanide and Polysulfide Electrolytes

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Xia, Gordon; Kirby, Brent W.; Thomsen, Edwin C.; Li, Bin; Nie, Zimin; Graff, Gordon L.; Liu, Jun; Sprenkle, Vincent L.; Wang, Wei

    2015-11-13

    Aiming to explore low-cost redox flow battery systems, a novel iron-polysulfide (Fe/S) flow battery has been demonstrated in a laboratory cell. This system employs alkali metal ferri/ferrocyanide and alkali metal polysulfides as the redox electrolytes. When proper electrodes, such as pretreated graphite felts, are used, 78% energy efficiency and 99% columbic efficiency are achieved. The remarkable advantages of this system over current state-of-the-art redox flow batteries include: 1) less corrosive and relatively environmentally benign redox solutions used; 2) excellent energy and utilization efficiencies; 3) low cost for redox electrolytes and cell components. These attributes can lead to significantly reduced capital cost and make the Fe/S flow battery system a promising low-cost energy storage technology. The major drawbacks of the present cell design are relatively low power density and possible sulfur species crossover. Further work is underway to address these concerns.

  6. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, John W.; Wender, Irving; Palekar, Vishwesh M.

    1995-01-01

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  7. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-31

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  8. Second international conference on alkali-aggregate reactions in hydroelectric plants and dams

    SciTech Connect (OSTI)

    1995-12-31

    This document is the report of the Second International Conference on Alkali-Aggregate Reactions in Hydroelectric Plants and Dams. This conference was held in October 1995 in Chattanooga, TN and sponsored by the Tennessee Valley Authority. Thirty five papers were presented, with technical sessions covering: (1) The TVA experience, (2) AAR in Hydroelectric Powerplants, (3) AAR in Dams and Spillways, and (4) Long-term management of AAR. Additionally, there were several workshop sessions.

  9. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation

    SciTech Connect (OSTI)

    Bernal, Susan A.; Provis, John L.; Walkley, Brant; San Nicolas, Rackel; Gehman, John D.; Brice, David G.; Kilcullen, Adam R.; Duxson, Peter; Deventer, Jannie S.J. van

    2013-11-15

    Binders formed through alkali-activation of slags and fly ashes, including ‘fly ash geopolymers’, provide appealing properties as binders for low-emissions concrete production. However, the changes in pH and pore solution chemistry induced during accelerated carbonation testing provide unrealistically low predictions of in-service carbonation resistance. The aluminosilicate gel remaining in an alkali-activated slag system after accelerated carbonation is highly polymerised, consistent with a decalcification mechanism, while fly ash-based binders mainly carbonate through precipitation of alkali salts (bicarbonates at elevated CO{sub 2} concentrations, or carbonates under natural exposure) from the pore solution, with little change in the binder gel identifiable by nuclear magnetic resonance spectroscopy. In activated fly ash/slag blends, two distinct gels (C–A–S–H and N–A–S–H) are formed; under accelerated carbonation, the N–A–S–H gel behaves comparably to fly ash-based systems, while the C–A–S–H gel is decalcified similarly to alkali-activated slag. This provides new scope for durability optimisation, and for developing appropriate testing methodologies. -- Highlights: •C-A-S-H gel in alkali-activated slag decalcifies during accelerated carbonation. •Alkali-activated fly ash gel changes much less under CO{sub 2} exposure. •Blended slag-fly ash binder contains two coexisting gel types. •These two gels respond differently to carbonation. •Understanding of carbonation mechanisms is essential in developing test methods.

  10. Colorado and the Accelerated Cleanup at Rocky Flats

    SciTech Connect (OSTI)

    Spreng, C.

    2007-07-01

    When the Rocky Flats closure project was declared complete in October 2005, it was the largest environmental cleanup to date. Even more impressive, it was ahead of schedule and well under budget. Several factors combined to produce this success including a performance-based contract with financial incentives, development and application of innovative technologies, and a regulator-backed accelerated approach to the cleanup process. The factor in this success in which the State of Colorado had the largest role was in developing and enforcing the Rocky Flats Cleanup Agreement. In compliance with this agreement, cleanup was accomplished by means of multiple interim actions that led to a comprehensive final decision at the end. A key element that allowed the accelerated cleanup was constant consultation among DOE, its contractor, and the regulators plus collaboration with stakeholders. (authors)

  11. Facility overview for commercial application of selected Rocky Flats facilities

    SciTech Connect (OSTI)

    1996-11-01

    The purpose of this Facility Overview is to support the Rocky Flats Local Impacts Initiative`s Request for Interest, to solicit interest from commercial corporations for utilizing buildings 865 and 883, and the equipment contained within each building, for a commercial venture. In the following sections, this document describes the Rocky Flats Site, the buildings available for lease, the equipment within these buildings, the site services available to a tenant, the human resources available to support operations in buildings 865 and 883, and the environmental condition of the buildings and property. In addition, a brief description is provided of the work performed to date to explore the potential products that might be manufactured in Buildings 865 and 883, and the markets for these products.

  12. Polymer solidification of mixed wastes at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Faucette, A.M.; Logsdon, B.W.; Lucerna, J.J.; Yudnich, R.J.

    1994-02-01

    The Rocky Flats Plant is pursuing polymer solidification as a viable treatment option for several mixed waste streams that are subject to land disposal restrictions within the Resource Conservation and Recovery Act provisions. Tests completed to date using both surrogate and actual wastes indicate that polyethylene microencapsulation is a viable treatment option for several mixed wastes at the Rocky Flats Plant, including nitrate salts, sludges, and secondary wastes such as ash. Treatability studies conducted on actual salt waste demonstrated that the process is capable of producing waste forms that comply with all applicable regulatory criteria, including the Toxicity Characteristic Leaching Procedure. Tests have also been conducted to evaluate the feasibility of macroencapsulating certain debris wastes in polymers. Several methods and plastics have been tested for macroencapsulation, including post-consumer recycle and regrind polyethylene.

  13. Actinide solution processing at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    1995-04-01

    The Department of Energy (DOE) has prepared an Environmental Assessment (EA), DOE/EA-1039, for radioactive solution removal and processing at Rocky Flats Environmental Technology Site, Golden, Colorado. The proposal for solution removal and processing is in response to independent safety assessments and an agreement with the State of Colorado to remove mixed residues at Rocky Flats and reduce the risk of future accidents. Monthly public meetings were held during the scoping and preparation of the EA. The scope of the EA included evaluations of alternative methods and locations of solution processing. A comment period from February 20, 1995 through March 21, 1995 was provided to the public and the State of Colorado to offer written comment on the EA. Comments were received from the State of Colorado and the U.S. Environmental Protection Agency. A response to the agency comments is included in the Final EA.

  14. Interacting agegraphic quintessence dark energy in non-flat universe

    SciTech Connect (OSTI)

    Sheykhi, A.; Bagheri, A.; Yazdanpanah, M.M. E-mail: ali.bagheri25@yahoo.com

    2010-09-01

    We establish a correspondence between interacting agegraphic dark energy model and the quintessence scalar field in a non-flat universe. We demonstrate that the agegraphic evolution of the universe can be described completely by a single quintessence scalar field. We also reconstruct the potential of the interacting agegraphic quintessence dark energy as well as the dynamics of the quintessence scalar field which describe the quintessence cosmology.

  15. MEASURING THE JET POWER OF FLAT-SPECTRUM RADIO QUASARS

    SciTech Connect (OSTI)

    Shabala, S. S.; Santoso, J. S.; Godfrey, L. E. H.

    2012-09-10

    We use frequency-dependent position shifts of flat-spectrum radio cores to estimate the kinetic power of active galactic nucleus (AGN) jets. We find a correlation between the derived jet powers and AGN narrow-line luminosity, consistent with the well-known relation for radio galaxies and steep spectrum quasars. This technique can be applied to intrinsically weak jets even at high redshift.

  16. Inspection of management of excess personal property at Rocky Flats

    SciTech Connect (OSTI)

    Not Available

    1993-05-17

    Inspection revealed that immediate management attention is needed to properly control, store, and dispose of excess personal property at Rocky Flats. Current system of operation does not allow for efficient, timely, cost effective management; current storage and disposal practices are not consistent with contract requirements or DOE policies and procedures. Other deficiencies are pointed out. Results of inspection are divided into 4 sections: contract changeover issues, moratorium issues, additional excess property issues, and award fee observations. Recommendations are outlined.

  17. Rocky Flats Plant Site Environmental Report: 1993 Highlights

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    The Rocky Flats Plant Site Environmental Report provides summary information on the plant`s environmental monitoring programs and the results recorded during 1993. The report contains a compliance summary, results of environmental monitoring and other related programs, a review of environmental remediation activities, information on external gamma radiation dose monitoring, and radiation dose estimates for the surrounding population. This section provides an overview of these topics and summarizes more comprehensive discussions found in the main text of this annual report.

  18. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Argonne National Laboratory Contact ANL About This Technology <p align="center"> New <em>ALD reaction chamber containing 12-in x 12-in piece of plate glass</em></p> New ALD reaction

  19. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells | Argonne National Laboratory Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells Improved coating precision uses less material and reduces cost PDF icon

  20. DECOMMISSIONING CHALLENGES AT THE ROCKY FLATS ENVIRONMENTAL TECHNOLOGY SITE

    SciTech Connect (OSTI)

    Dorr, K. A.; Hoover, J.

    2002-02-25

    This paper presents a discussion of the demolition of the Building 788 cluster at the Rocky Flats Environmental Technology Site (RFETS) in Golden, Colorado. The Building 788 Cluster was a Resource Conservation and Recovery Act (RCRA) permitted storage facilities and ancillary structures. Topics covered include the methods employed for Project Planning, Regulatory Compliance, Waste Management, Hazard Identification, Radiological Controls, Risk Management, Field Implementation, and Cost Schedule control, and Lessons Learned and Project Closeout.

  1. Low-cost solar flat-plate-collector development

    SciTech Connect (OSTI)

    Wilhelm, W.G.

    1981-01-01

    Cost goals were developed for the collector which led to the rejection of conventional approaches and to the exploration of thin-film technology. A thin-film sola absorber suited for high-speed continous-roll manufacture at low cost was designed. The absorber comprises two sheets of aluminum-foil/polymeric-material laminate bonded together at intervals to form channels with water as the heat transfer fluid. Several flat-plate panels were fabricated and tested. (MHR)

  2. Asymptotically flat radiating solutions in third order Lovelock gravity

    SciTech Connect (OSTI)

    Dehghani, M. H.; Farhangkhah, N.

    2008-09-15

    In this paper, we present an exact spherically symmetric solution of third order Lovelock gravity in n dimensions which describes the gravitational collapse of a null dust fluid. This solution is asymptotically (anti-)de Sitter or flat depending on the choice of the cosmological constant. Using the asymptotically flat solution for n{>=}7 with a power-law form of the mass as a function of the null coordinate, we present a model for a gravitational collapse in which a null dust fluid radially injects into an initially flat and empty region. It is found that a naked singularity is inevitably formed whose strength is different for the n=7 and n{>=}8 cases. In the n=7 case, the limiting focusing condition for the strength of curvature singularity is satisfied. But for n{>=}8, the strength of curvature singularity depends on the rate of increase of mass of the spacetime. These considerations show that the third order Lovelock term weakens the strength of the curvature singularity.

  3. Phase II Transport Model of Corrective Action Unit 98: Frenchman Flat, Nevada Test Site, Nye County, Nevada, Revision 1

    SciTech Connect (OSTI)

    Gregg Ruskuaff

    2010-01-01

    This document, the Phase II Frenchman Flat transport report, presents the results of radionuclide transport simulations that incorporate groundwater radionuclide transport model statistical and structural uncertainty, and lead to forecasts of the contaminant boundary (CB) for a set of representative models from an ensemble of possible models. This work, as described in the Federal Facility Agreement and Consent Order (FFACO) Underground Test Area (UGTA) strategy (FFACO, 1996; amended 2010), forms an essential part of the technical basis for subsequent negotiation of the compliance boundary of the Frenchman Flat corrective action unit (CAU) by Nevada Division of Environmental Protection (NDEP) and National Nuclear Security Administration Nevada Site Office (NNSA/NSO). Underground nuclear testing via deep vertical shafts was conducted at the Nevada Test Site (NTS) from 1951 until 1992. The Frenchman Flat area, the subject of this report, was used for seven years, with 10 underground nuclear tests being conducted. The U.S. Department of Energy (DOE), NNSA/NSO initiated the UGTA Project to assess and evaluate the effects of underground nuclear tests on groundwater at the NTS and vicinity through the FFACO (1996, amended 2010). The processes that will be used to complete UGTA corrective actions are described in the “Corrective Action Strategy” in the FFACO Appendix VI, Revision No. 2 (February 20, 2008).

  4. The US Department of Energy`s facility reuse at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    1998-08-01

    This audit was initiated to determine whether the Rocky Flats Environmental Technology Site was maximizing its reuse of excess facilities.

  5. Integrated Weed Control for Land Stewardship at Legacy Management's Rocky Flats Site in Colorado - 13086

    SciTech Connect (OSTI)

    Nelson, Jody K.

    2013-07-01

    Land stewardship is one of nine sustainability programs in the U.S. Department of Energy's Environmental Management System. Land stewardship includes maintaining and improving ecosystem health. At the Rocky Flats Site near Westminster, Colorado, land stewardship is an integral component of the Office of Legacy Management's post-closure monitoring and management at the site. Nearly 263 hectares (650 acres) were disturbed and re-vegetated during site cleanup and closure operations. Proactive management of revegetation areas is critical to the successful reestablishment of native grasslands, wetlands, and riparian communities. The undisturbed native plant communities that occur at the site also require active management to maintain the high-quality wetlands and other habitats that are home to numerous species of birds and other wildlife such as elk and deer, rare plant communities, and the federally listed threatened Preble's meadow jumping mouse. Over the past several decades, an increase of Noxious weeds has impacted much of Colorado's Front Range. As a result, weed control is a key component of the land stewardship program at Rocky Flats. Thirty-three species of state-listed Noxious weeds are known to occur in the Central and Peripheral Operable Units at Rocky Flats, along with another five species that are considered invasive at the site. Early detection and rapid response to control new invasive species is crucial to the program. An integrated weed control/vegetation management approach is key to maintaining healthy, sustainable plant communities that are able to resist Noxious weed invasions. Weed mapping, field surveys, and field-staff training sessions (to learn how to identify new potential problem species) are conducted to help detect and prevent new weed problems. The integrated approach at Rocky Flats includes administrative and cultural techniques (prevention), mechanical controls, biological controls, and chemical controls. Several species of biocontrol

  6. Reactive barrier technologies for treatment of contaminated groundwater at Rocky Flats

    SciTech Connect (OSTI)

    Marozas, D.C.; Bujewski, G.E.; Castaneda, N.

    1997-12-31

    The U.S. Department of Energy (DOE) Office of Science and Technology Subsurface Contaminants Focus Area is supporting the investigation of reactive barrier technologies to mitigate the risks associated with mixed organic/radioactive waste at several DOE sites. Groundwater from a small contaminated plume at the Rocky Flats Environmental Technology Site (RFETS) is being used to evaluate passive reactive material treatment. Permeable reactive barriers which intercept contaminants and destroy the VOC component while containing radionuclides are attractive for a number of reasons relating to public and regulatory acceptance. In situ treatment keeps contaminants away from the earth`s surface, there is no above-ground treatment equipment that could expose workers and the public and operational costs are expected to be lower than currently used technologies. This paper will present results from preliminary site characterization and in-field small-scale column testing of reactive materials at RFETS. Successful demonstration is expected to lead to full-scale implementation of the technology at several DOE sites, including Rocky Flats.

  7. U-234/U-238 ratio: Qualitative estimate of groundwater flow in Rocky Flats monitoring wells

    SciTech Connect (OSTI)

    Laul, J.C.

    1994-02-01

    Groundwater movement through various pathways is the primary mechanism for the transport of radionuclides and trace elements in a water/rock interaction. About three dozen wells, installed in the Rocky Flats Plant (RFP) Solar Evaporation Ponds (SEP) area, are monitored quarterly to evaluate the extent of any lateral and downgradient migration of contaminants from the Solar Evaporation Ponds: 207-A; 207-B North, 207-B Center, and 207-B South; and 207-C. The Solar Ponds are the main source for the various contaminants: radionuclides (U-238, U-234, Pu-239, 240 and Am-241); anions; and trace metals to groundwaters. The U-238 concentrations in Rocky Flats groundwaters vary from <0.2 to 69 pCi/I (IpCi = 3 ug). However, the activity U-234/U-238 ratios are low and range mostly 1.2 to 2.7. The low activity ratios can be interpreted to suggest that the groundwaters are moving slow (

  8. A flat-cathode thermionic injector for the PHERMEX Radiographic Facility

    SciTech Connect (OSTI)

    Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S.; Hughes, T.

    1993-06-01

    The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

  9. A flat-cathode thermionic injector for the PHERMEX Radiographic Facility

    SciTech Connect (OSTI)

    Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S. ); Hughes, T. )

    1993-01-01

    The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

  10. Preliminary Correlation Map of Geomorphic Surfaces in North-Central Frenchman Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Bechtel Nevada

    2005-08-01

    This correlation map (scale = 1:12,000) presents the results of a mapping initiative that was part of the comprehensive site characterization required to operate the Area 5 Radioactive Waste Management Site, a low-level radioactive waste disposal facility located in northern Frenchman Flat at the Nevada Test Site. Eight primary map units are recognized for Quaternary surfaces: remnants of six alluvial fan or terrace surfaces, one unit that includes colluvial aprons associated with hill slopes, and one unit for anthropogenically disturbed surfaces. This surficial geology map provides fundamental data on natural processes for reconstruction of the Quaternary history of northern Frenchman Flat, which in turn will aid in the understanding of the natural processes that act to develop the landscape, and the time-frames involved in landscape development. The mapping was conducted using color and color-infrared aerial photographs and field verification of map unit composition and boundaries. Criteria for defining the map unit composition of geomorphic surface units are based on relative geomorphic position, landform morphology, and degree of preservation of surface morphology. The bedrock units identified on this map were derived from previous published mapping efforts and are included for completeness.

  11. Letter Report Yucca Mountain Environmental Monitoring Systems Initiative - Air Quality Scoping Study for Crater Flat, Nye County, Nevada

    SciTech Connect (OSTI)

    J. Engelbrecht; I. Kavouras; D. Campbell; S.Campbell; S. Kohl; D. Shafer

    2009-04-02

    The Desert Research Institute (DRI) is performing a scoping study as part of the U.S. Department of Energy's Yucca Mountain Environmental Monitoring Systems Initiative (EMSI). The main objective is to obtain baseline air quality information for Yucca Mountain and an area surrounding the Nevada Test Site (NTS). Air quality and meteorological monitoring and sampling equipment housed in a mobile trailer (shelter) (cover page figure) is collecting data at eight sites outside the NTS, including Ash Meadows National Wildlife Refuge (NWR), Beatty, Sarcobatus Flats, Rachel, Caliente, Pahranagat NWR, Crater Flat, and Tonopah Airport, and at four sites on the NTS (Engelbrecht et al., 2007a-d). The trailer is stationed at any one site for approximately eight weeks at a time. This letter report provides a summary of air quality and meteorological data, on completion of the site's sampling program.

  12. Letter Report: Yucca Mountain Environmental Monitoring Systems Initiative - Air Quality Scoping Study for Crater Flat, Nye County, Nevada

    SciTech Connect (OSTI)

    J. Engelbrecht; I. Kavouras; D. Campbell; S. Campbell; S. Kohl; D. Shafer

    2008-08-01

    The Desert Research Institute (DRI) is performing a scoping study as part of the U.S. Department of Energy's Yucca Mountain Environmental Monitoring Systems Initiative (EMSI). The main objective is to obtain baseline air quality information for Yucca Mountain and an area surrounding the Nevada Test Site (NTS). Air quality and meteorological monitoring and sampling equipment housed in a mobile trailer (shelter) (cover page figure) is collecting data at eight sites outside the NTS, including Ash Meadows National Wildlife Refuge (NWR), Beatty, Sarcobatus Flats, Rachel, Caliente, Pahranagat NWR, Crater Flat, and Tonopah Airport, and at four sites on the NTS (Engelbrecht et al., 2007a-d). The trailer is stationed at any one site for approximately eight weeks at a time. This letter report provides a summary of air quality and meteorological data, on completion of the site's sampling program.

  13. EIS-0183: Shepherds Flat Wind Project in Gilliam and Morrow counties, OR |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 183: Shepherds Flat Wind Project in Gilliam and Morrow counties, OR EIS-0183: Shepherds Flat Wind Project in Gilliam and Morrow counties, OR Documents Available for Download October 19, 2010 EIS-0183: Revised Record of Decision Offer of Conditional Commitment for a Loan Guarantee for, and Electrical Interconnection of, the Shepherds Flat Wind Project; Bonneville Power Administration

  14. Review and reconnaissance of the hydrogeology of Tertiary sedimentary rocks in the vicinity of Frenchman Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Prothro, L.B.; Drellack, S.L. Jr.

    1997-09-01

    Work is currently underway within the Underground Test Area (UGTA) subproject of the US Department of Energy/Nevada Operations Office Environmental Restoration Program to develop corrective action plans in support of the overall corrective action strategy for the Nevada Test Site (NTS) as established in the Federal Facility Agreement and Consent Order (FFACO, 1996). A closure plan is currently being developed for Frenchman Flat, which has been identified in the FFACO as a Corrective Action Unit (CAU). Part of this effort requires that hydrogeologic data be compiled for inclusion in a CAU-specific hydrologic flow and transport model that will be used to predict contaminant boundaries. Hydrogeologic maps and cross sections are currently being prepared for use in the model to define the nature and extent of aquifers and confining units that might influence the flow of contaminated groundwater from underground nuclear tests conducted in Frenchman Flat. During this effort, it has been found that older Tertiary-age sediments might be hydrogeologically important in the Frenchman Flat model area. Although the character and extent of these units are poorly known, there is reason to believe that in some parts of Frenchman Flat they may lie between the regional Lower Carbonate Aquifer (LCA) and the younger Tertiary saturated alluvium and volcanic units in which several underground nuclear tests were conducted. It was not possible to quickly determine their extent, or ascertain whether or not these units might act as confining units or aquifers. The work described in this report was done to gain a better understanding of the hydrogeology of these rocks.

  15. Intrinsic differences in atomic ordering of calcium (alumino)silicate hydrates in conventional and alkali-activated cements

    SciTech Connect (OSTI)

    White, Claire E.; Daemen, Luke L.; Hartl, Monika; Page, Katharine

    2015-01-15

    The atomic structures of calcium silicate hydrate (C–S–H) and calcium (–sodium) aluminosilicate hydrate (C–(N)–A–S–H) gels, and their presence in conventional and blended cement systems, have been the topic of significant debate over recent decades. Previous investigations have revealed that synthetic C–S–H gel is nanocrystalline and due to the chemical similarities between ordinary Portland cement (OPC)-based systems and low-CO{sub 2} alkali-activated slags, researchers have inferred that the atomic ordering in alkali-activated slag is the same as in OPC–slag cements. Here, X-ray total scattering is used to determine the local bonding environment and nanostructure of C(–A)–S–H gels present in hydrated tricalcium silicate (C{sub 3}S), blended C{sub 3}S–slag and alkali-activated slag, revealing the large intrinsic differences in the extent of nanoscale ordering between C–S–H derived from C{sub 3}S and alkali-activated slag systems, which may have a significant influence on thermodynamic stability, and material properties at higher length scales, including long term durability of alkali-activated cements.

  16. Performance of 3-Sun Mirror Modules on Sun Tracking Carousels on Flat Roof Buildings

    SciTech Connect (OSTI)

    Fraas, Dr. Lewis; Avery, James E.; Minkin, Leonid M; Maxey, L Curt; Gehl, Anthony C; Hurt, Rick A; Boehm, Robert F

    2008-01-01

    Commercial buildings represent a near term market for cost competitive solar electric power provided installation costs and solar photovoltaic module costs can be reduced. JX Crystals has developed a carousel sun tracker that is prefabricated and can easily be deployed on building flat roof tops without roof penetration. JX Crystals is also developing 3-sun PV mirror modules where less expensive mirrors are substituted for two-thirds of the expensive single crystal silicon solar cell surface area. Carousels each with four 3-sun modules have been set up at two sites, specifically at Oak Ridge National Lab and at the University of Nevada in Las Vegas. The test results for these systems are presented.

  17. Accurate potential energy, dipole moment curves, and lifetimes of vibrational states of heteronuclear alkali dimers

    SciTech Connect (OSTI)

    Fedorov, Dmitry A.; Varganov, Sergey A.; Derevianko, Andrei

    2014-05-14

    We calculate the potential energy curves, the permanent dipole moment curves, and the lifetimes of the ground and excited vibrational states of the heteronuclear alkali dimers XY (X, Y = Li, Na, K, Rb, Cs) in the X{sup 1}?{sup +} electronic state using the coupled cluster with singles doubles and triples method. All-electron quadruple-? basis sets with additional core functions are used for Li and Na, and small-core relativistic effective core potentials with quadruple-? quality basis sets are used for K, Rb, and Cs. The inclusion of the coupled cluster non-perturbative triple excitations is shown to be crucial for obtaining the accurate potential energy curves. A large one-electron basis set with additional core functions is needed for the accurate prediction of permanent dipole moments. The dissociation energies are overestimated by only 14 cm{sup ?1} for LiNa and by no more than 114 cm{sup ?1} for the other molecules. The discrepancies between the experimental and calculated harmonic vibrational frequencies are less than 1.7 cm{sup ?1}, and the discrepancies for the anharmonic correction are less than 0.1 cm{sup ?1}. We show that correlation between atomic electronegativity differences and permanent dipole moment of heteronuclear alkali dimers is not perfect. To obtain the vibrational energies and wave functions the vibrational Schrdinger equation is solved with the B-spline basis set method. The transition dipole moments between all vibrational states, the Einstein coefficients, and the lifetimes of the vibrational states are calculated. We analyze the decay rates of the vibrational states in terms of spontaneous emission, and stimulated emission and absorption induced by black body radiation. In all studied heteronuclear alkali dimers the ground vibrational states have much longer lifetimes than any excited states.

  18. Research Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Areas Our Vision National User Facilities Research Areas In Focus Global Solutions ⇒ Navigate Section Our Vision National User Facilities Research Areas In Focus Global Solutions Biosciences The Biosciences Area forges multidisciplinary teams to solve national challenges in energy, environment and health issues; and to advance the engineering of biological systems for sustainable manufacturing. Biosciences Area research is coordinated through three divisions and is enabled by Berkeley

  19. Rocky Flats Neutron Detector Testing at Valduc, France

    SciTech Connect (OSTI)

    Kim, S S; Dulik, G M

    2011-01-03

    Recent program requirements of the US Department of Energy/NNSA have led to a need for a criticality accident alarm system to be installed at a newly activated facility. The Criticality Safety Group of the Lawrence Livermore National Laboratory (LLNL) was able to recover and store for possible future use approximately 200 neutron criticality detectors and 20 master alarm panels from the former Rocky Flats Plant in Golden, Colorado when the plant was closed. The Criticality Safety Group participated in a facility analysis and evaluation, the engineering design and review process, as well as the refurbishment, testing, and recalibration of the Rocky Flats criticality alarm system equipment to be used in the new facility. In order to demonstrate the functionality and survivability of the neutron detectors to the effects of an actual criticality accident, neutron detector testing was performed at the French CEA Valduc SILENE reactor from October 7 to October 19, 2010. The neutron detectors were exposed to three criticality events or pulses generated by the SILENE reactor. The first excursion was performed with a bare or unshielded reactor, and the second excursion was made with a lead shielded/reflected reactor, and the third excursion with a polyethylene reflected core. These tests of the Rocky Flats neutron detectors were performed as a part of the 2010 Criticality Accident Alarm System Benchmark Measurements at the SILENE Reactor. The principal investigators for this series of experiments were Thomas M. Miller and John C. Wagner of the Oak Ridge National Laboratory, with Nicolas Authier and Nathalie Baclet of CEA Valduc. Several other organizations were also represented, including the Y-12 National Security Complex, Lawrence Livermore National Laboratory, Los Alamos National Laboratory, CEA Saclay, and Babcock International Group.

  20. DuraLith Alkali-Aluminosilicate Geopolymer Waste Form Testing for Hanford Secondary Waste

    SciTech Connect (OSTI)

    Gong, W. L.; Lutz, Werner; Pegg, Ian L.

    2011-07-21

    The primary objective of the work reported here was to develop additional information regarding the DuraLith alkali aluminosilicate geopolymer as a waste form for liquid secondary waste to support selection of a final waste form for the Hanford Tank Waste Treatment and Immobilization Plant secondary liquid wastes to be disposed in the Integrated Disposal Facility on the Hanford Site. Testing focused on optimizing waste loading, improving waste form performance, and evaluating the robustness of the waste form with respect to waste variability.

  1. Oxygen-consuming chlor alkali cell configured to minimize peroxide formation

    DOE Patents [OSTI]

    Chlistunoff, Jerzy B.; Lipp, Ludwig; Gottesfeld, Shimshon

    2006-08-01

    Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.

  2. Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; Rawn, Claudia J.; Richardson, Jim

    2016-01-01

    When appropriately activated, alkali rare-earth double phosphates of the form: M3RE(PO4)2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K3RE(PO4)2 with RE = Lu, Er, Ho, Dy, Gd, Nd, Ce, plus Ymore » and Sc - as well as the compounds: A3Lu(PO4)2, with A = Rb, and Cs. The double phosphate K3Lu(PO4)2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K3Lu(PO4)2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K3Lu(PO4)2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K3Yb(PO4)2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single-crystal growth methods structural systematics, and thermal expansion properties of the present series of alkali rare-earth double phosphates, as determined by X-ray and neutron diffraction methods, are treated here.« less

  3. Structural and Crystal Chemical Properties of Alkali Rare-earth Double Phosphates

    SciTech Connect (OSTI)

    Farmer, James Matthew; Boatner, Lynn A.; Chakoumakos, Bryan C.; Rawn, Claudia J.; Richardson, Jim

    2016-01-01

    When appropriately activated, alkali rare-earth double phosphates of the form: M3RE(PO4)2 (where M denotes an alkali metal and RE represents either a rare-earth element or Y or Sc) are of interest for use as inorganic scintillators for radiation detection at relatively long optical emission wavelengths. These compounds exhibit layered crystal structures whose symmetry properties depend on the relative sizes of the rare-earth and alkali-metal cations. Single-crystal X-ray and powder neutron diffraction methods were used here to refine the structures of the series of rare-earth double phosphate compounds: K3RE(PO4)2 with RE = Lu, Er, Ho, Dy, Gd, Nd, Ce, plus Y and Sc - as well as the compounds: A3Lu(PO4)2, with A = Rb, and Cs. The double phosphate K3Lu(PO4)2 was reported and structurally refined previously. This material had a hexagonal unit cell at room temperature with the Lu ion six-fold coordinated with oxygen atoms of the surrounding phosphate groups. Additionally two lower-temperature phases were observed for K3Lu(PO4)2. The first phase transition to a monoclinic P21/m phase occurred at ~230 K, and the Lu ion retained its six-fold coordination. The second K3Lu(PO4)2 phase transition occurred at ~130 K. The P21/m space group symmetry was retained, however, one of the phosphate groups rotated to increase the oxygen coordination number of Lu from six to seven. This structure then became isostructural with the room-temperature form of the compound K3Yb(PO4)2 reported here that also exhibits an additional high-temperature phase which occurs at T = 120 °C with a transformation to hexagonal P-3 space group symmetry and a Yb-ion coordination number reduction from seven to six. This latter result was confirmed using EXAFS. The single

  4. Half metallic ferromagnetism in alkali metal nitrides MN (M = Rb, Cs): A first principles study

    SciTech Connect (OSTI)

    Murugan, A. Rajeswarapalanichamy, R. Santhosh, M. Sudhapriyanga, G.; Kanagaprabha, S.

    2014-04-24

    The structural, electronic and elastic properties of two alkali metal nitrides (MN: M= Rb, Cs) are investigated by the first principles calculations based on density functional theory using the Vienna ab-initio simulation package. At ambient pressure the two nitrides are stable in ferromagnetic state with CsCl structure. The calculated lattice parameters are in good agreement with the available results. The electronic structure reveals that these materials are half metallic in nature. A pressure-induced structural phase transition from CsCl to ZB phase is observed in RbN and CsN.

  5. Final Land Configuration for the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Stegen, R. L.; Kapinos, J. M.; Wehner, J. P.; Snyder, B.; Davis, R. W.

    2006-07-01

    Closure of the Rocky Flats Environmental Technology Site (RFETS) has been completed. The future land use of the site is designated as a National Wildlife Refuge. A joint effort between Kaiser-Hill, Department of Energy, U.S. Fish and Wildlife Service, Environmental Protection Agency, State of Colorado, and other stakeholders was initiated to provide direction for developing the final land configuration. Through early identification of issues and developing mutually agreeable solutions, the final land configuration of the site was successfully completed. (authors)

  6. Microsoft Word - FINAL Rocky Flats LBNL report Batch #1.docx

    Office of Legacy Management (LM)

    the First Batch of Rocky Flats Water Samples Submitted to LBNL John N. Christensen Report date 9/16/13 Thirteen samples were submitted by SM Stoller to Lawrence Berkeley National Laboratory for uranium isotopic and concentration analysis- 12 surface water samples from two sites (WALPOC and GS10) covering the period Sept. 2011 to April 2013, and one groundwater sample taken on 5/14/12 from well 79102 (Table 1). Uranium isotopic compositions of the samples were determined at LBNL by MC- ICPMS

  7. Flat 3-brane with Tension in Cascading Gravity

    SciTech Connect (OSTI)

    Rham, Claudia de; Khoury, Justin; Tolley, Andrew

    2009-10-16

    In the cascading gravity brane-world scenario, our 3-brane lies within a succession of lower-codimension branes, each with their own induced gravity term, embedded into each other in a higher-dimensional space-time. In the (6+1)-dimensional version of this scenario, we show that a 3-brane with tension remains flat, at least for sufficiently small tension that the weak-field approximation is valid. The bulk solution is singular nowhere and remains in the perturbative regime everywhere.

  8. Rocky Flats plant qualification testing for PRES Program

    SciTech Connect (OSTI)

    Kautz, D.D.; Tanaka, G.J.

    1994-06-24

    The authors recently completed several tests for EG&G - Rocky Flats, Inc. (RFP) to qualify welding procedures for the PRESS program. The welds that were tested were the Monel 400 to vanadium friction weld used in the Sail-A and the vanadium electron beam welds from the Mast Inner Subassembly. Tests were performed to determine the structural properties of the parts under conditions similar to those encountered in a weapons handling and storage environment. These tests included impact, tensile and pressure loading. Metallographic analysis was done where appropriate to document weld quality. All results were satisfactory for PRESS program purposes.

  9. Health Surveillance Outcomes in Former Rocky Flats Radiation Workers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surveillance of Rocky Flats Radiation Workers Janice P. Watkins 1 , Elizabeth D. Ellis 1 , F. Joseph Furman 2 , Roger B. Falk 2 , Joe M. Aldrich 2 , and Donna L. Cragle 1 ORAU Technical Report # 2006-0408 1 Oak Ridge Institute for Science and Education, Center for Epidemiologic Research; P.O. Box 117; Oak Ridge, TN 37831-0117 2 Oak Ridge Institute for Science and Education, Center for Epidemiologic Research; 9950 W. 80 th Avenue, Suite 17; Arvada, CO 80005-3914 This report was funded by

  10. The Rocky Flats Environmental Technology Site beryllium characterization project

    SciTech Connect (OSTI)

    Morrell, D.M.; Miller, J.R.; Allen, D.F.

    1999-06-01

    A site beryllium characterization project was completed at the Rocky Flats Environmental Technology Site (RFETS) in 1997. Information from historical reviews, previous sampling surveys, and a new sampling survey were used to establish a more comprehensive understanding of the locations and levels of beryllium contamination in 35 buildings. A feature of the sampling strategy was to test if process knowledge was a good predictor of where beryllium contamination could be found. Results revealed that this technique was effective at identifying where surface contamination levels might exceed the RFETS smear control level but that it was not effective in identifying where low concentrations of beryllium might be found.

  11. Property:Reference material | Open Energy Information

    Open Energy Info (EERE)

    ARRA Spreadsheet + 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) + A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  12. An Expert Elicitation Process in Support of Groundwater Model Evaluation for Frenchman Flat, Nevada National Security Site

    SciTech Connect (OSTI)

    Chapman Jenny,Pohlmann Karl

    2011-02-01

    The U.S. Department of Energy is implementing corrective actions at facilities where nuclear-related operations were conducted in Nevada. Among the most significant sites being addressed are the locations of underground nuclear tests on the Nevada National Security Site (NNSS). The process for implementing corrective actions for the Underground Test Area (UGTA) locations is defined in Appendix VI of a Federal Facility Agreement and Consent Order (1996, as amended). In broad terms, Appendix VI describes a Corrective Action Investigation followed by a Corrective Action Decision, and implementation of a Corrective Action Plan prior to closure. The Frenchman Flat Corrective Action Unit (CAU) is farthest along in the UGTA corrective action process. It includes ten underground tests within the Frenchman Flat topographic basin, in the southeastern portion of the NNSS. Data have been collected from drilling exploration, hydrologic testing, and field and laboratory studies. Modeling has been completed at a variety of scales and focusing on a variety of flow and transport aspects ranging from regional boundary conditions to process dynamics within a single nuclear cavity. The culmination of the investigations is a transport model for the Frenchman Flat CAU (Stoller Navarro Joint Venture, 2009) that has undergone rigorous peer review and been accepted by the State of Nevada, setting the stage for the Corrective Action Decision and progression from the investigation phase to the corrective action phase of the project.

  13. Alkali metal vapor removal from pressurized fluidized-bed combustor flue gas. Quarterly report, April-June 1980

    SciTech Connect (OSTI)

    Johnson, I.; Swift, W.M.; Lee, S.H.D.; Boyd, W.A.

    1980-07-01

    In the application of pressurized fluidized-bed combustors (PFBC) to the generation of electricity, hot corrosion of gas turbine components by alkali metal compounds is a potential problem. The objective of this investigation is to develop a method for removing these gaseous alkali metal compounds from the high-pressure high-temperature gas from a PFBC before the gas enters the gas turbine. A granular-bed filter, using either diatomaceous earth or activated bauxite as the bed material, is the concept currently being studied. Results are presented for the testing of diatomaceous earth for alkali vapor sorption at 800/sup 0/C and 9-atm pressure, using a simulated flue gas. Activated bauxite sorbent can be regenerated by leaching with water, and the kinetics of the leaching is under study.

  14. Innovative Ballasted Flat Roof Solar PV Racking System

    SciTech Connect (OSTI)

    Peek, Richard T.

    2015-01-23

    The objective of this project was to reduce the cost of racking for PV solar on flat commercial rooftops. Cost reductions would come from both labor savings and material savings related to the installation process. The rack would need to accommodate the majority of modules available on the market. Cascade Engineering has a long history of converting traditional metal type applications over to plastic. Injection molding of plastics have numerous advantages including selection of resin for the application, placing the material exactly where it is needed, designing in features that will speed up the installation process, and weight reduction of the array. A plastic rack would need to meet the requirements of UL2703, Mounting systems, mounting devices, clamping/retention devices, and ground lugs for use with flat-plate photovoltaic modules and panels. Comparing original data to the end of project racking design, racking material costs were reduced 50% and labor costs reduced 64%. The racking product accommodates all 60 and 72 cell panels on the market, meets UL2703 requirements, contributes only 1.3 pounds per square foot of weight to the array, requires little ballast to secure the array, automatically grounds the module when the module is secured, stacks/nests well for shipping/fewer lifts to the roof, provides integrated wire routing, allows water to drain on the roof, and accommodates various seismic roof connections. Project goals were achieved as noted in the original funding application.

  15. Cementation of residue ion exchange resins at Rocky Flats

    SciTech Connect (OSTI)

    Dustin, D.F.; Beckman, T.D.; Madore, C.M.

    1998-03-03

    Ion exchange resins have been used to purify nitric acid solutions of plutonium at Rocky Flats since the 1950s. Spent ion exchange resins were retained for eventual recovery of residual plutonium, typically by incineration followed by the aqueous extraction of plutonium from the resultant ash. The elimination of incineration as a recovery process in the late 1980s and the absence of a suitable alternative process for plutonium recovery from resins led to a situation where spent ion exchange resins were simply placed into temporary storage. This report describes the method that Rocky Flats is currently using to stabilize residue ion exchange resins. The objective of the resin stabilization program is: (1) to ensure their safety during interim storage at the site, and (2) to prepare them for ultimate shipment to the Waste Isolation Pilot Plant (WIPP) in New Mexico. Included in the discussion is a description of the safety concerns associated with ion exchange resins, alternatives considered for their stabilization, the selection of the preferred treatment method, the means of implementing the preferred option, and the progress to date.

  16. Geologic and geotechnical assessment RFETS Building 371, Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Maryak, M.E.; Wyatt, D.E.; Bartlett, S.F.; Lewis, M.R.; Lee, R.C.

    1995-12-13

    This report describes the review and evaluation of the geological, geotechnical and geophysical data supporting the design basis analysis for the Rocky Flats Environmental Test Site (RFETS) Building 371. The primary purpose of the geologic and geotechnical reviews and assessments described herein are to assess the adequacy of the crustal and near surface rock and soil model used in the seismic analysis of Building 371. This review was requested by the RFETS Seismic Evaluation Program. The purpose was to determine the adequacy of data to support the design basis for Building 371, with respect to seismic loading. The objectives required to meet this goal were to: (1) review techniques used to gather data (2) review analysis and interpretations of the data; and (3) make recommendations to gather additional data if required. Where there were questions or inadequacies in data or interpretation, recommendations were made for new data that will support the design basis analysis and operation of Building 371. In addition, recommendations are provided for a geologic and geophysical assessment for a new facility at the Rocky Flats Site.

  17. The September 1957 Rocky Flats fire: A guide to record series of the Department of Energy and its contractors

    SciTech Connect (OSTI)

    1995-07-19

    The primary purpose of this guide is to help the DOE locate and make available information relating to the 1957 Rocky Flats fire. The records are arranged into six categories: administrative and general; facilities and equipment; production and materials handling; waste management; workplace and environmental monitoring; and employee occupational exposure and health. A brief explanation of each category follows. The administrative and general section pertains to the administration of individual contractor organizations and DOE divisions at Rocky Flats. It also contains records which encompass several different subject areas and therefore can not be placed in a single category. The facilities and equipment category relates to the routine construction and maintenance of plant buildings as well as the purchase and installation of equipment. The production and materials handling records relate primarily to the inventory and production of nuclear materials and weapons components. The waste management records series found under this heading relate to the storage, handling, treatment, and disposal of radioactive, chemical or mixed materials produced or used at Rocky Flats. The records consist mostly of waste sampling and shipment records. The workplace and environmental monitoring records series found in this section pertain to monitoring of the workplace. The section also includes records that document efforts to monitor the environment outside of buildings, either onsite or offsite. Records in this category consist of sampling data and environmental impact reports. The employee occupational exposure and health section pertains to documentation relating to the health and occupational exposures of employees and visitors at Rocky Flats. Records series consist generally of dosimeter data, radiation exposure records, and medical records. Many of the records contain personal data pertaining to individual employees and may therefore be Privacy Act systems and records.

  18. Raman Analysis of Perrhenate and Pertechnetate in Alkali Salts and Borosilicate Glasses

    SciTech Connect (OSTI)

    Gassman, Paul L.; McCloy, John S.; Soderquist, Chuck Z.; Schweiger, Michael J.

    2014-01-03

    Sodium borosilicate glasses containing various concentrations of rhenium or technetium were fabricated, and their vibrational spectra studied using a Raman microscope. Spectra were interpreted with reference to new high resolution measurements of alkali pertechnetates and perrhenates NaReO4, KReO4, NaTcO4, and KTcO4. At low concentrations of ReO4- or TcO4-, glass spectra show weak peaks superimposed on a dominant spectrum of glass characteristic of silicate and borate network vibrations. At high concentrations, sharp peaks characteristic of crystal field splitting and C4h symmetry dominate the spectra of glasses, indicating alkali nearby tetrahedral Re or Tc. Often peaks indicative of both the K and Na pertechnetates/ perrhenates are evident in the Raman spectrum, with the latter being favored at high additions of the source chemical, since Na is more prevalent in the glass and ion exchange takes place. These results have significance to immobilization of nuclear waste containing radioactive 99Tc in glass for ultimate disposal.

  19. Optically pumped alkali laser and amplifier using helium-3 buffer gas

    DOE Patents [OSTI]

    Beach, Raymond J.; Page, Ralph; Soules, Thomas; Stappaerts, Eddy; Wu, Sheldon Shao Quan

    2010-09-28

    In one embodiment, a laser oscillator is provided comprising an optical cavity, the optical cavity including a gain medium including an alkali vapor and a buffer gas, the buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Additionally, an optical excitation source is provided. Furthermore, the laser oscillator is capable of outputting radiation at a first frequency. In another embodiment, an apparatus is provided comprising a gain medium including an alkali vapor and a buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Other embodiments are also disclosed.

  20. Hydration of a low-alkali CEM III/B-SiO{sub 2} cement (LAC)

    SciTech Connect (OSTI)

    Lothenbach, Barbara; Le Saout, Gwenn; Ben Haha, Mohsen; Figi, Renato; Wieland, Erich

    2012-02-15

    The hydration of a low-alkali cement based on CEM III/B blended with 10 wt.% of nanosilica has been studied. The nanosilica reacted within the first days and 90% of the slag reacted within 3.5 years. C-S-H (Ca/Si {approx} 1.2, Al/Si {approx} 0.12), calcite, hydrotalcite, ettringite and possibly straetlingite were the main hydrates. The pore water composition revealed ten times lower alkali concentrations than in Portland cements. Reducing conditions (HS{sup -}) and a pH value of 12.2 were observed. Between 1 month and 3.5 years of hydration more hydrates were formed due to the ongoing slag reaction but no significant differences in the composition of the pore solution or solid phase assemblage were observed. On the basis of thermodynamic calculations it is predicted that siliceous hydrogarnet could form in the long-term and, in the presence of siliceous hydrogarnet, also thaumasite. Nevertheless, even after 3.5 year hydration, neither siliceous hydrogarnet nor thaumasite have been observed.

  1. Investigation of anti-Relaxation coatings for alkali-metal vapor cells using surface science techniques

    SciTech Connect (OSTI)

    Seltzer, S. J.; Michalak, D. J.; Donaldson, M. H.; Balabas, M. V.; Barber, S. K.; Bernasek, S. L.; Bouchiat, M.-A.; Hexemer, A.; Hibberd, A. M.; Jackson Kimball, D. F.; Jaye, C.; Karaulanov, T.; Narducci, F. A.; Rangwala, S. A.; Robinson, H. G.; Shmakov, A. K.; Voronov, D. L.; Yashchuk, V. V.; Pines, A.; Budker, D.

    2010-10-11

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of antirelaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10?000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the study of paraffin coatings in order to characterize the properties that enable the effective preservation of alkali spin polarization. These methods include Fourier transform infrared spectroscopy, differential scanning calorimetry, atomic force microscopy, near-edge x-ray absorption fine structure spectroscopy, and x-ray photoelectron spectroscopy. We also compare the light-induced atomic desorption yields of several different paraffin materials. Experimental results include the determination that crystallinity of the coating material is unnecessary, and the detection of C=C double bonds present within a particular class of effective paraffin coatings. Further study should lead to the development of more robust paraffin antirelaxation coatings, as well as the design and synthesis of new classes of coating materials.

  2. Phase II Groundwater Flow Model of Corrective Action Unit 98: Frenchman Flat, Nevada Test Site, Nye County, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    John McCord

    2006-05-01

    The Phase II Frenchman Flat groundwater flow model is a key element in the ''Federal Facility Agreement and Consent Order'' (FFACO) (1996) corrective action strategy for the Underground Test Area (UGTA) Frenchman Flat corrective action unit (CAU). The objective of this integrated process is to provide an estimate of the vertical and horizontal extent of contaminant migration for each CAU to predict contaminant boundaries. A contaminant boundary is the model-predicted perimeter that defines the extent of radionuclide-contaminated groundwater from underground testing above background conditions exceeding the ''Safe Drinking Water Act'' (SDWA) standards. The contaminant boundary will be composed of both a perimeter boundary and a lower hydrostratigraphic unit (HSU) boundary. The computer model will predict the location of this boundary within 1,000 years and must do so at a 95 percent level of confidence. Additional results showing contaminant concentrations and the location of the contaminant boundary at selected times will also be presented. These times may include the verification period, the end of the five-year proof-of-concept period, as well as other times that are of specific interest. This report documents the development and implementation of the groundwater flow model for the Frenchman Flat CAU. Specific objectives of the Phase II Frenchman Flat flow model are to: (1) Incorporate pertinent information and lessons learned from the Phase I Frenchman Flat CAU models. (2) Develop a three-dimensional (3-D), mathematical flow model that incorporates the important physical features of the flow system and honors CAU-specific data and information. (3) Simulate the steady-state groundwater flow system to determine the direction and magnitude of groundwater fluxes based on calibration to Frenchman Flat hydrogeologic data. (4) Quantify the uncertainty in the direction and magnitude of groundwater flow due to uncertainty in parameter values and alternative component

  3. Flat bunch creation and acceleration: a possible path for the LHC luminosity upgrade

    SciTech Connect (OSTI)

    Bhat, C.M.; /Fermilab

    2009-05-01

    Increasing the collider luminosity by replacing bunches having Gaussian line-charge distribution with flat bunches, but with same beam-beam tune shift at collision, has been studied widely in recent years. But, creation of 'stable' flat bunches (and their acceleration) using a multiple harmonic RF system has not been fully explored. Here, we review our experience with long flat bunches in the barrier RF buckets at Fermilab.We presentsome preliminary results from beam dynamics simulations and recent beam studies in the LHC injectors to create stable flat bunches using double harmonic RF systems. The results deduced from these studies will be used to model the necessary scheme for luminosity upgrade in the LHC. We have also described a viable (and economical) way for creation and acceleration of flat bunches in the LHC. The flat bunch scheme may have many advantages over the LHC baseline scenario, particularly because of the reduced momentum spread of the bunch for increased intensities.

  4. Water-Chemistry Evolution and Modeling of Radionuclide Sorption and Cation Exchange during Inundation of Frenchman Flat Playa

    SciTech Connect (OSTI)

    Hershey, Ronald; Cablk, Mary; LeFebre, Karen; Fenstermaker, Lynn; Decker, David

    2013-08-01

    Atmospheric tests and other experiments with nuclear materials were conducted on the Frenchman Flat playa at the Nevada National Security Site, Nye County, Nevada; residual radionuclides are known to exist in Frenchman Flat playa soils. Although the playa is typically dry, extended periods of winter precipitation or large single-event rainstorms can inundate the playa. When Frenchman Flat playa is inundated, residual radionuclides on the typically dry playa surface may become submerged, allowing water-soil interactions that could provide a mechanism for transport of radionuclides away from known areas of contamination. The potential for radionuclide transport by occasional inundation of the Frenchman Flat playa was examined using geographic information systems and satellite imagery to delineate the timing and areal extent of inundation; collecting water samples during inundation and analyzing them for chemical and isotopic content; characterizing suspended/precipitated materials and archived soil samples; modeling water-soil geochemical reactions; and modeling the mobility of select radionuclides under aqueous conditions. The physical transport of radionuclides by water was not evaluated in this study. Frenchman Flat playa was inundated with precipitation during two consecutive winters in 2009-2010 and 2010-2011. Inundation allowed for collection of multiple water samples through time as the areal extent of inundation changed and ultimately receded. During these two winters, precipitation records from a weather station in Frenchman Flat (Well 5b) provided information that was used in combination with geographic information systems, Landsat imagery, and image processing techniques to identify and quantify the areal extent of inundation. After inundation, water on the playa disappeared quickly, for example, between January 25, 2011 and February 10, 2011, a period of 16 days, 92 percent of the areal extent of inundation receded (2,062,800 m2). Water sampling provided

  5. Improving the diversity of manufacturing electroluminescent flat panel displays

    SciTech Connect (OSTI)

    Moss, T.S.; Samuels, J.A.; Smith, D.C.

    1995-09-01

    Crystalline calcium thiogallate with a cerium dopant has been deposited by metal-organic chemical vapor deposition (MOCVD) at temperatures below 600{degrees}C on a low cost glass substrate. An EL luminance of 1.05 fL was observed 40 volts above threshold at 60 Hz. This is more than an order of magnitude improvement over earlier crystalline-as-deposited thiogallate materials. These results pave the way for the use of MOCVD as a potential method for processing full color thin-film electroluminescent (TFEL) flat panel displays. The formation of the CaGa{sub 2}S{sub 4}:Ce phosphor requires precise control over a number of deposition parameters including flow rates, substrate temperature, and reactor pressure. The influence of these parameters will be discussed in terms of structure, uniformity, and TFEL device performance.

  6. Sitewide risk perspectives for the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Olinger, S.J.; Foppe, T.L.

    1998-05-01

    The US Department of Energy (DOE) has recently finalized a closure plan (originally called the Ten Year Plan) for closure and environmental cleanup of previous nuclear weapons facilities. The DOE Rocky Flats Field Office has established priorities for risk reduction work to Support closure activities, as well as addressing those hazards associated with storage and management of radioactive materials and hazardous chemicals. To provide information for future National Environmental Policy Act (NEPA) or other regulatory assessments of specific risk reduction projects identified in the Closure Plan, a risk assessment of normal operations and potential accidents was recently prepared to provide an updated baseline of the cumulative impacts to the worker, public and environment due to the Site`s operations, activities, and environmental conditions in light of the Site`s change in mission, and of future closure projects. This paper summarizes the risk assessment approach, results, and conclusions.

  7. Flat Ge-doped optical fibres for food irradiation dosimetry

    SciTech Connect (OSTI)

    Noor, N. Mohd; Jusoh, M. A.; Razis, A. F. Abdull; Alawiah, A.; Bradley, D. A.

    2015-04-24

    Exposing food to radiation can improve hygiene quality, germination control, retard sprouting, and enhance physical attributes of the food product. To provide for food safety, radiation dosimetry in irradiated food is required. Herein, fabricated germanium doped (Ge-doped) optical fibres have been used. The fibres have been irradiated using a gamma source irradiator, doses in the range 1 kGy to 10 kGy being delivered. Using Ge-doped optical fibres of variable size, type and dopant concentration, study has been made of linearity, reproducibility, and fading. The thermoluminescence (TL) yield of the fibres were obtained and compared. The fibres exhibit a linear dose response over the investigated range of doses, with mean reproducibility to within 2.69 % to 8.77 %, exceeding the dose range of all commercial dosimeters used in evaluating high doses for the food irradiation industry. TL fading of the Ge-doped flat fibres has been found to be < 13%.

  8. System Advisor Model: Flat Plate Photovoltaic Performance Modeling Validation Report

    SciTech Connect (OSTI)

    Freeman, J.; Whitmore, J.; Kaffine, L.; Blair, N.; Dobos, A. P.

    2013-12-01

    The System Advisor Model (SAM) is a free software tool that performs detailed analysis of both system performance and system financing for a variety of renewable energy technologies. This report provides detailed validation of the SAM flat plate photovoltaic performance model by comparing SAM-modeled PV system generation data to actual measured production data for nine PV systems ranging from 75 kW to greater than 25 MW in size. The results show strong agreement between SAM predictions and field data, with annualized prediction error below 3% for all fixed tilt cases and below 8% for all one axis tracked cases. The analysis concludes that snow cover and system outages are the primary sources of disagreement, and other deviations resulting from seasonal biases in the irradiation models and one axis tracking issues are discussed in detail.

  9. Rocky Flats Plant Live-Fire Range Risk Analysis Report

    SciTech Connect (OSTI)

    Nicolosi, S.L.; Rodriguez, M.A.

    1994-04-01

    The objective of the Live-Fire Range Risk Analysis Report (RAR) is to provide an authorization basis for operation as required by DOE 5480.16. The existing Live-Fire Range does not have a safety analysis-related authorization basis. EG&G Rocky Flats, Inc. has worked with DOE and its representatives to develop a format and content description for development of an RAR for the Live-Fire Range. Development of the RAR is closely aligned with development of the design for a baffle system to control risks from errant projectiles. DOE 5480.16 requires either an RAR or a safety analysis report (SAR) for live-fire ranges. An RAR rather than a SAR was selected in order to gain flexibility to more closely address the safety analysis and conduct of operation needs for a live-fire range in a cost-effective manner.

  10. Cementation and solidification of Rocky Flats Plant incinerator ash

    SciTech Connect (OSTI)

    Phillips, J.A.; Semones, G.B.

    1994-04-01

    Cementation studies on various aqueous waste streams at Rocky Flats have shown this technology to be effective for immobilizing the RCRA constituents in the waste. Cementation is also being evaluated for encapsulation of incinerator ash. Experiments will initially evaluate a surrogate ash waste using a Taguchi experimental design to optimize the cement formulation and waste loading levels for this application. Variables of waste loading, fly ash additions, water/cement ratio, and cement type will be tested at three levels each during the course of this work. Tests will finally be conducted on actual waste using the optimized cement formulation developed from this testing. This progression of tests will evaluate the effectiveness of cement encapsulation for this waste stream without generating any additional wastes.

  11. Properties of vitrified Rocky Flats TRUW with different waste loadings

    SciTech Connect (OSTI)

    Eddy, T.L.; Sears, J.W.; Grandy, J.D.; Miley, D.V.; Erickson, A.W.; Fransworth, R.N.; Larsen, E.D.

    1994-07-01

    One of the major waste streams at the Idaho National Laboratory (INEL) is a combination of the Rocky Flats Plant 1st and 2nd stage sludges (hydrated metal oxides or H-series), which constitutes about 20 wt % of the buried waste. A similar mass fraction is in interim storage. The buried waste is commingled with about five times as much soil that has become contaminated as the containers have deteriorated. The purpose of this paper is to report on waste form property variations of the H-series waste melted with various fractions of soil, plus volatile and hazardous metals and transuranic surrogates. Optimally, the waste form will minimize the bulk leach rate, maximize the volume reduction, minimize the additives needed, and stabilize the transuranic nuclides. Topics to be discussed include the input and final compositions, the melting and crystallization processes, the test results, and conclusions.

  12. Measure Guideline. Deep Energy Enclosure Retrofit for Zero Energy Ready House Flat Roofs

    SciTech Connect (OSTI)

    Loomis, H.; Pettit, B.

    2015-05-29

    This Measure Guideline provides design and construction information for a deep energy enclosure retrofit solution of a flat roof assembly. It describes the strategies and procedures for an exterior retrofit of a flat wood-framed roof with brick masonry exterior walls using exterior and interior (framing cavity) insulation. The approach supported in this guide could also be adapted for use with flat wood-framed roofs with wood-framed exterior walls.

  13. Measure Guideline: Deep Energy Enclosure Retrofit for Zero Energy Ready House Flat Roofs

    SciTech Connect (OSTI)

    Loomis, H.; Pettit, B.

    2015-05-01

    This Measure Guideline provides design and construction information for a deep energy enclosure retrofit (DEER) solution of a flat roof assembly. It describes the strategies and procedures for an exterior retrofit of a flat, wood-framed roof with brick masonry exterior walls, using exterior and interior (framing cavity) insulation. The approach supported in this guide could also be adapted for use with flat, wood-framed roofs with wood-framed exterior walls.

  14. DOE's Rocky Flats Cleanup Site Named 2006 Project of the Year By Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Management Institute | Department of Energy Rocky Flats Cleanup Site Named 2006 Project of the Year By Project Management Institute DOE's Rocky Flats Cleanup Site Named 2006 Project of the Year By Project Management Institute October 23, 2006 - 9:17am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today announced that the Project Management Institute (PMI) has awarded its 2006 Project of the Year to DOE's Rocky Flats Environmental Technology Site. The award was presented to DOE

  15. Diffractive optics for compact flat panel displays. Final report

    SciTech Connect (OSTI)

    Sweeney, D.; DeLong, K.

    1997-04-29

    Three years ago LLNL developed a practical method to dramatically reduce the chromatic aberration in single element diffractive imaging lenses. High efficiency, achromatic imaging lenses have been fabricated for human vision correction. This LDRD supported research in applying our new methods to develop a unique, diffraction-based optical interface with solid state, microelectronic imaging devices. Advances in microelectronics have led to smaller, more efficient components for optical systems. There have, however, been no equivalent advances in the imaging optics associated with these devices. The goal of this project was to replace the bulky, refractive optics in typical head-mounted displays with micro-thin diffractive optics to directly image flat-panel displays into the eye. To visualize the system think of the lenses of someone`s eyeglasses becoming flat-panel displays. To realize this embodiment, we needed to solve the problems of large chromatic aberrations and low efficiency that are associated with diffraction. We have developed a graceful tradeoff between chromatic aberrations and the diffractive optic thickness. It turns out that by doubling the thickness of a micro-thin diffractive lens we obtain nearly a two-times improvement in chromatic performance. Since the human eye will tolerate one diopter of chromatic aberration, we are able to achieve an achromatic image with a diffractive lens that is only 20 microns thick, versus 3 mm thickness for the comparable refractive lens. Molds for the diffractive lenses are diamond turned with sub-micron accuracy; the final lenses are cast from these molds using various polymers. We thus retain both the micro- thin nature of the diffractive optics and the achromatic image quality of refractive optics. During the first year of funding we successfully extended our earlier technology from 1 cm diameter optics required for vision applications up to the 5 cm diameter optics required for this application. 3 refs., 6 figs.

  16. Research Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in diverse research areas such as cell biology, lithography, infrared microscopy, radiology, and x-ray tomography. Time-Resolved These techniques exploit the pulsed nature of...

  17. Bay Area

    National Nuclear Security Administration (NNSA)

    8%2A en NNSA to Conduct Aerial Radiological Surveys Over San Francisco, Pacifica, Berkeley, And Oakland, CA Areas http:nnsa.energy.govmediaroompressreleasesamsca

  18. Notice of Rocky Flats CERCLA Five-Year Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Notice of Rocky Flats CERCLA Five-Year Review Notice of Rocky Flats CERCLA Five-Year Review June 13, 2016 - 9:23am Addthis NEWS CONTACTS Scott Surovchak, Rocky Flats Site Manager; DOE Office of Legacy Management; (720) 377-9682; Scott.Surovchak@lm.doe.gov Bob Darr, Rocky Flats Site Public Affairs; Navarro Research and Engineering, Inc., Contractor to DOE Office of Legacy Management; (720) 377-9672; Bob.Darr@lm.doe.gov The U.S. Department of Energy Office of Legacy Management is conducting the

  19. Hydraulic model analysis of water distribution system, Rockwell International, Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Perstein, J.; Castellano, J.A.

    1989-01-20

    Rockwell International requested an analysis of the existing plant site water supply distribution system at Rocky Flats, Colorado, to determine its adequacy. On September 26--29, 1988, Hughes Associates, Inc., Fire Protection Engineers, accompanied by Rocky Flats Fire Department engineers and suppression personnel, conducted water flow tests at the Rocky Flats plant site. Thirty-seven flows from various points throughout the plant site were taken on the existing domestic supply/fire main installation to assure comprehensive and thorough representation of the Rocky Flats water distribution system capability. The analysis was completed in four phases which are described, together with a summary of general conclusions and recommendations.

  20. The effect of a small creek valley on drainage flows in the Rocky Flats region

    SciTech Connect (OSTI)

    Porch, W.

    1996-12-31

    Regional scale circulation and mountain-plain interactions and effects on boundary layer development are important for understanding the fate of an atmospheric release from Rocky Flats, Colorado. Numerical modeling of Front Range topographic effects near Rocky Flats have shown that though the Front Range dominates large scale flow features, small-scale terrain features near Rocky Flats are important to local transport during nighttime drainage flow conditions. Rocky Flats has been the focus of interest for the Department of Energy`s Atmospheric Studies in Complex Terrain (ASCOT) program.

  1. Electric dipole polarizabilities at imaginary frequencies for hydrogen, the alkali-metal, alkaline-earth, and noble gas atoms

    SciTech Connect (OSTI)

    Derevianko, Andrei Porsev, Sergey G. Babb, James F.

    2010-05-15

    The electric dipole polarizabilities evaluated at imaginary frequencies for hydrogen, the alkali-metal atoms, the alkaline-earth atoms, and the noble gases are tabulated along with the resulting values of the atomic static polarizabilities, the atom-surface interaction constants, and the dispersion (or van der Waals) constants for the homonuclear and the heteronuclear diatomic combinations of the atoms.

  2. Ultralow-power local laser control of the dimer density in alkali-metal vapors through photodesorption

    SciTech Connect (OSTI)

    Jha, Pankaj K.; Scully, Marlan O. [Texas A and M University, College Station, Texas 77843 (United States); Princeton University, Princeton, New Jersey 08544 (United States); Dorfman, Konstantin E. [Texas A and M University, College Station, Texas 77843 (United States); University of California, Irvine, Irvine, California 92697 (United States); Yi Zhenhuan; Yuan Luqi; Welch, George R. [Texas A and M University, College Station, Texas 77843 (United States); Sautenkov, Vladimir A. [Texas A and M University, College Station, Texas 77843 (United States); Joint Institute of High Temperature, RAS, Moscow 125412 (Russian Federation); Rostovtsev, Yuri V. [University of North Texas, Denton, Texas 76203 (United States); Zheltikov, Aleksei M. [Texas A and M University, College Station, Texas 77843 (United States); M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation)

    2012-08-27

    Ultralow-power diode-laser radiation is employed to induce photodesorption of cesium from a partially transparent thin-film cesium adsorbate on a solid surface. Using resonant Raman spectroscopy, we demonstrate that this photodesorption process enables an accurate local optical control of the density of dimer molecules in alkali-metal vapors.

  3. Rheological properties of water-coal slurries based on brown coal in the presence of sodium lignosulfonates and alkali

    SciTech Connect (OSTI)

    D.P. Savitskii; A.S. Makarov; V.A. Zavgorodnii

    2009-07-01

    The effect of the oxidized surface of brown coal on the structural and rheological properties of water-coal slurries was found. The kinetics of structure formation processes in water-coal slurries based on as-received and oxidized brown coal was studied. The effect of lignosulfonate and alkali additives on the samples of brown coal was considered.

  4. The effects of lithium hydroxide solution on alkali silica reaction gels created with opal

    SciTech Connect (OSTI)

    Mitchell, Lyndon D.; Beaudoin, James J.; Grattan-Bellew, Patrick

    2004-04-01

    The reaction of Nevada opal with calcium hydroxide, potassium hydroxide and lithium hydroxide solutions was investigated. In addition, opal was exposed to a combined solution of these three hydroxides. The progress of the three reactions was followed using X-ray diffraction (XRD), {sup 29}Si nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). The XRD results indicated the presence of a low-angle peak exclusive to the lithium-based reactions. The NMR results suggested a change in the silicate structure in the presence of lithium. These techniques indicated that the reaction of the alkali with the opal starting material is inhibited and perhaps stopped in the presence of lithium hydroxide. SEM revealed that the morphology of the reaction products on the surface of the reacted opal grains is markedly different invariably. It was concluded that evidence to support the theory of a protective layer exists and that the nature of the layer varies with ion type.

  5. Energy conservation in the primary aluminum and chlor-alkali industries

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The primary aluminum and chlor-alkali industries together use nearly 13% of the electrical energy consumed by US industry. As part of its mission to promote energy conservation in basic US industries, the DOE surveys the present technological status of the major electrochemical industries and evaluates promising technological innovations that may lead to reduced energy requirements. This study provides technical and economic analyses in support of a government program of research and development in advanced electrolytic technology. This program is intended to supplement the development efforts directed toward energy savings by private industry. Sections II and III of this report cover aluminum and chlorine production processes only, since these two industries represent over 90% of the electrical energy requirements of all electrolytic industries in the United States. Section IV examines barriers to accelerated research and development by the electrolytic industries, and makes suggestions for government actions to overcome these barriers.

  6. Microstructural Changes Due to Alkali-Silica Reaction during Standard Mortar Test

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shin, Jun-Ho; Struble, Leslie; Kirkpatrick, R.

    2015-12-01

    The microstructural development of mortar bars with silica glass aggregate undergoing alkali-silica reaction (ASR) under the conditions of American Society for Testing and Materials (ASTM) Standard Test C1260 was analyzed using scanning electron microscopy and qualitative X-ray microanalysis. Cracking in the aggregate, the hydrated paste, and the paste-aggregate interface was important in the development of the microstructure. Cracks were characterized according to their location, their relationship to other cracks, and whether they are filled with ASR gel. Expansion of the bars was approximately 1% at 12 days and 2% at 53 days. They fell apart by 63 days. The barsmore » contained two zones, an inner region that was undergoing ASR and an outer and much more highly damaged zone that extended further inward over time. Evidence of ASR was present even during the period when specimens were immersed in water, prior to immersion in NaOH solution.« less

  7. Finite element analysis of three TVA dams with alkali-aggregate reaction

    SciTech Connect (OSTI)

    Grenoble, B.A.; Meisenheimer, J.K.; Wagner, C.D.; Newell, V.A.

    1995-12-31

    Three large Tennessee Valley Authority (TVA) dams are currently experiencing problems caused by alkali-aggregate reaction (AAR). Since the fall of 1990, engineers in Stone & Webster`s Denver, Colorado office have been working with TVA to evaluate how AAR is affecting the dams and to identify measures for controlling the adverse effects of the concrete growth. This paper provides an overview of how finite element analysis is being used to understand the affects of AAR on these structures and to evaluate alternatives for minimizing the adverse effects of the concrete growth. Work on Hiwassee Dam is essentially complete, while that on the Chickamauga and Fontana Projects is still in progress. Consequently, this paper will focus primarily on Hiwassee Dam. The ongoing work on the other two projects will only be discussed briefly.

  8. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, John W.; Wender, Irving; Palekar, Vishwesh M.

    1995-01-01

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  9. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-24

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  10. Ion Segregation and Deliquescence of Alkali Halide Nanocrystals on SiO2

    SciTech Connect (OSTI)

    Arima, Kenta; Jiang, Peng; Lin, Deng-Sung; Verdaguer, Albert; Salmeron, Miquel

    2009-08-11

    The adsorption of water on alkali halide (KBr, KCl, KF, NaCl) nanocrystals on SiO{sub 2} and their deliquescence was investigated as a function of relative humidity (RH) from 8% to near saturation by scanning polarization force microscopy. At low humidity, water adsorption solvates ions at the surface of the crystals and increases their mobility. This results in a large increase in the dielectric constant, which is manifested in an increase in the electrostatic force and in an increase in the apparent height of the nanocrystals. Above 58% RH, the diffusion of ions leads to Ostwald ripening, where larger nanocrystals grow at the expense of the smaller ones. At the deliquescence point, droplets were formed. For KBr, KCl, and NaCl, the droplets exhibit a negative surface potential relative to the surrounding region, which is indicative of the preferential segregation of anions to the air/solution interface.

  11. Silicate species of water glass and insights for alkali-activated green cement

    SciTech Connect (OSTI)

    Jansson, Helén; Bernin, Diana; Ramser, Kerstin

    2015-06-15

    Despite that sodium silicate solutions of high pH are commonly used in industrial applications, most investigations are focused on low to medium values of pH. Therefore we have investigated such solutions in a broad modulus range and up to high pH values (∼14) by use of infrared (IR) spectroscopy and silicon nuclear magnetic resonance ({sup 29}Si-NMR). The results show that the modulus dependent pH value leads to more or less charged species, which affects the configurations of the silicate units. This in turn, influences the alkali-activation process of low CO{sub 2} footprint cements, i.e. materials based on industrial waste or by-products.

  12. The development of high-performance alkali-hybrid polarized He3 targets for electron scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Jaideep T.; Dolph, Peter A.M.; Tobias, William Al; Averett, Todd D.; Kelleher, Aiden; Mooney, K. E.; Nelyubin, Vladimir V.; Wang, Yunxiao; Zheng, Yuan; Cates, Gordon D.

    2015-05-01

    We present the development of high-performance polarized ³He targets for use in electron scattering experiments that utilize the technique of alkali-hybrid spin-exchange optical pumping. We include data obtained during the characterization of 24 separate target cells, each of which was constructed while preparing for one of four experiments at Jefferson Laboratory in Newport News, Virginia. The results presented here document dramatic improvement in the performance of polarized ³He targets, as well as the target properties and operating parameters that made those improvements possible. Included in our measurements were determinations of the so-called X-factors that quantify a temperature-dependent and as-yet poorly understood spin-relaxation mechanism that limits the maximum achievable ³He polarization to well under 100%. The presence of this spin-relaxation mechanism was clearly evident in our data. We also present results from a simulation of the alkali-hydrid spin-exchange optical pumping process that was developed to provide guidance in the design of these targets. Good agreement with actual performance was obtained by including details such as off-resonant optical pumping. Now benchmarked against experimental data, the simulation is useful for the design of future targets. Included in our results is a measurement of the K- ³He spin-exchange rate coefficientmore » $$k^\\mathrm{K}_\\mathrm{se} = \\left ( 7.46 \\pm 0.62 \\right )\\!\\times\\!10^{-20}\\ \\mathrm{cm^3/s}$$ over the temperature range 503 K to 563 K.« less

  13. Density and water content of nanoscale solid C-S-H formed in alkali-activated slag (AAS) paste and implications for chemical shrinkage

    SciTech Connect (OSTI)

    Thomas, Jeffrey J.; Allen, Andrew J.; Jennings, Hamlin M.

    2012-02-15

    Alkali-activated slag (AAS) paste was analyzed using small-angle neutron scattering (SANS). The scattering response indicates that the microstructure consists of a uniform matrix of hydration product with a high surface area studded with unhydrated cores of slag particles. In contrast with portland cement paste, no surface fractal scattering regime was detected, and elevated temperature curing (at 60 Degree-Sign C) had no detectable effect on the microstructure at any length scale studied. The specific surface area of the AAS pastes is about 25% higher than that of a portland cement paste cured under the same conditions. The composition and mass density of the nanoscale solid C-S-H phase formed in the AAS paste was determined using a previously developed neutron scattering method, in conjunction with a hydration model. The result ((CaO){sub 0.99}-SiO{sub 2}-(Al{sub 2}O{sub 3}){sub 0.06}-(H{sub 2}O){sub 0.97}, d = (2.73 {+-} 0.02) g/cm{sup 3}) is significantly lower in calcium and in water as compared to portland cement or pure tricalcium silicate paste. These values were used to calculate the chemical shrinkage that would result from complete hydration of the AAS paste. The result, (12.2 {+-} 1.5) cm{sup 3} of volumetric shrinkage per 100 g of unhydrated cement, is about twice the amount of chemical shrinkage exhibited by normal cement pastes.

  14. Post-Closure Land Jurisdiction Transfer to the US Fish and Wildlife Service at Rocky Flats: Surviving the Safari Through Old Records and Other Lessons Learned

    SciTech Connect (OSTI)

    Schiesswohl, S.; Hanson, M.

    2008-07-01

    The U.S. Department of Energy's (DOE's) Rocky Flats Site (Rocky Flats), located near Denver, Colorado, was listed on the Comprehensive Environmental Response, Compensation, and Liability Act National Priorities List (NPL) in 1989. Subsequent cleanup and closure activities were completed in October 2005 and the final remedy was selected in September 2006. The remedy is 'no further action' for the generally un-impacted Peripheral Operable Unit (OU), formerly known as the Buffer Zone, and institutional and physical controls with continued monitoring for the Central OU, formerly the industrialized area. The Peripheral OU has been deleted from the NPL and jurisdiction over the majority of land in that OU (3,953 acres) was transferred to the U.S. Fish and Wildlife Service (USFWS) on July 12, 2007, to establish the Rocky Flats National Wildlife Refuge. The remaining approximately 929 acres in the Peripheral OU were retained by DOE's Office of Legacy Management where outstanding mineral leases and mining operations exist. As mineral rights are purchased or mining operations and mineral leases are completed and fully reclaimed, jurisdiction of portions of the 929 acres will also be transferred to USFWS for inclusion into the refuge. During the almost 2 years since cleanup and closure work was completed at Rocky Flats, DOE and USFWS have worked the specific legal parameters, timing, and constraints of the 3,953-acre transfer. Many lessons have been learned, based on these early experiences. (authors)

  15. Low-cost, high-performance solar flat-plate collectors for applications in northern latitudes

    SciTech Connect (OSTI)

    Wilhelm, W.G.

    1981-01-01

    Solar flat plate collector designs have been developed which incorporate high performance polymer film and laminate technology that have a projected manufacturing cost approaching $15/m/sup 2/ and potential thermal performance consistent with the best commercial solar flat plate collectors available today.

  16. Handbook: Collecting Groundwater Samples from Monitoring Wells in Frenchman Flat, CAU 98

    SciTech Connect (OSTI)

    Chapman, Jenny; Lyles, Brad; Cooper, Clay; Hershey, Ron; Healey, John

    2015-06-01

    Frenchman Flat basin on the Nevada National Security Site (NNSS) contains Corrective Action Unit (CAU) 98, which is comprised of ten underground nuclear test locations. Environmental management of these test locations is part of the Underground Test Area (UGTA) Activity conducted by the U.S. Department of Energy (DOE) under the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended) with the U.S. Department of Defense (DOD) and the State of Nevada. A Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) has been approved for CAU 98 (DOE, 2011). The CADD/CAP reports on the Corrective Action Investigation that was conducted for the CAU, which included characterization and modeling. It also presents the recommended corrective actions to address the objective of protecting human health and the environment. The recommended corrective action alternative is “Closure in Place with Modeling, Monitoring, and Institutional Controls.” The role of monitoring is to verify that Contaminants of Concern (COCs) have not exceeded the Safe Drinking Water Act (SDWA) limits (Code of Federal Regulations, 2014) at the regulatory boundary, to ensure that institutional controls are adequate, and to monitor for changed conditions that could affect the closure conditions. The long-term closure monitoring program will be planned and implemented as part of the Closure Report stage after activities specified in the CADD/CAP are complete. Groundwater at the NNSS has been monitored for decades through a variety of programs. Current activities were recently consolidated in an NNSS Integrated Sampling Plan (DOE, 2014). Although monitoring directed by the plan is not intended to meet the FFACO long-term monitoring requirements for a CAU (which will be defined in the Closure Report), the objective to ensure public health protection is similar. It is expected that data collected in accordance with the plan will support the transition to long-term monitoring at each

  17. Supercompaction and Repackaging Facility for Rocky Flats Plant transuranic waste

    SciTech Connect (OSTI)

    Barthel, J.M.

    1988-01-01

    The Supercompaction and Repackaging Facility (SaRF) for processing Rocky Flats Plant (RFP) generated transuranic (TRU) waste was conceptualized and has received funding of $1.9 million. The SaRF is scheduled for completion in September, 1989 and will eliminate a labor intensive manual repackaging effort. The semi-automated glovebox-contained SaRF is being designed to process 63,500 cubic feet of TRU waste annually for disposal at the Waste Isolation Pilot Plant (WIPP). Waste will enter the process through an airlock or drum dump and the combustible waste will be precompacted. Drums will be pierced to allow air to escape during supercompaction. Each drum will be supercompacted and transferred to a load out station for final packaging into a 55 gallon drum. Preliminary evaluations indicate an average 5 to 1 volume reduction, 2 to 1 increased processing rate, and 50% reduction in manpower. The SaRF will produce a significant annual savings in labor, material, shipping, and burial costs over the projected 15 year life, and also improve operator safety, reduce personnel exposure, and improve the quality of the waste product. 1 ref., 10 figs., 3 tabs.

  18. Thiogallate Blue Phosphors for Thin Film Electroluminescent Flat Panel Displays

    SciTech Connect (OSTI)

    Dye, Robert C.; Tuenge, Richard T.

    1997-04-03

    This project helped to develop a metal-organic chemical vapor deposition (MOCVD) method that could improve the efficiency of the blue phosphor for full color thin-film electroluminescent (TFEL) flat panel displays. High quality SrS and SrS:Ce thin films were deposited from Sr(thd)2, Ce(thd)4 and H2S via a low pressure MOCVD process. Film characteristics were found to be insensitive to the presence of the cerium dopant in the concn. range investigated. Depositions were carried out for a wide temp. range (250-550°C). Deposition rates were found to be relatively insensitive for the temp. range investigated. The films produced were found to be highly cryst. at all temps. investigated. Deposited material showed texturing as a function of substrate material and temp. FWHM of the a 111 ii reflections were found to have a 2Q values of 0.15-0.18 deg. for all temps. RBS and AES shows stoichiometric 1 : 1 SrS with less than 2% carbon and oxygen contaminates. ERO indicates the films to have 1- 2.5% hydrogen. Films doped with 0.019-0.043 atom % Ce showed weak blue-green to green PL with increasing dopant concn. Doped films yielded up to 3.2 cd/m2 EL emission with CIE coordinates of x = 0.22 and y = 0.32 and turn-on voltages of 150-250 V.

  19. Washing of Rocky Flats Combustible Residues (Conducted March - May 1995)

    SciTech Connect (OSTI)

    Mary E. Barr; Ann R. Schake; David A. Romero; Gordon D. Jarvinen

    1999-03-01

    The scope of this project is to determine the feasibility of washing plutonium-containing combustible residues using ultrasonic disruption as a method for dislodging particulate. Removal of plutonium particulate and, to a lesser extent, solubilized plutonium from the organic substrate should substantially reduce potential fire, explosion or radioactive release hazards due to radiolytic hydrogen generation or high flammability. Tests were conducted on polypropylene filters which were used as pre-filters in the rich-residue ion-exchange process at the Los Alamos Plutonium Facility. These filters are similar to the Ful-Flo{reg_sign} cartridges used at Rocky Flats that make up a substantial fraction of the combustible residues with the highest hazard rating. Batch experiments were run on crushed filter material in order to determine the amount of Pu removed by stirring, stirring and sonication, and stirring and sonication with the introduction of Pu-chelating water-soluble polymers or surfactants. Significantly more Pu is removed using sonication and sonication with chelators than is removed with mechanical stirring alone.

  20. DISPOSITION PATHS FOR ROCKY FLATS GLOVEBOXES: EVALUATING OPTIONS

    SciTech Connect (OSTI)

    Lobdell, D.; Geimer, R.; Larsen, P.; Loveland, K.

    2003-02-27

    The Kaiser-Hill Company, LLC has the responsibility for closure activities at the Rocky Flats Environmental Technology Site (RFETS). One of the challenges faced for closure is the disposition of radiologically contaminated gloveboxes. Evaluation of the disposition options for gloveboxes included a detailed analysis of available treatment capabilities, disposal facilities, and lifecycle costs. The Kaiser-Hill Company, LLC followed several processes in determining how the gloveboxes would be managed for disposition. Currently, multiple disposition paths have been chosen to accommodate the needs of the varying styles and conditions of the gloveboxes, meet the needs of the decommissioning team, and to best manage lifecycle costs. Several challenges associated with developing a disposition path that addresses both the radiological and RCRA concerns as well as offering the most cost-effective solution were encountered. These challenges included meeting the radiological waste acceptance criteria of available disposal facilities, making a RCRA determination, evaluating treatment options and costs, addressing void requirements associated with disposal, and identifying packaging and transportation options. The varying disposal facility requirements affected disposition choices. Facility conditions that impacted decisions included radiological and chemical waste acceptance criteria, physical requirements, and measurement for payment options. The facility requirements also impacted onsite activities including management strategies, decontamination activities, and life-cycle cost.

  1. Completion Report for Model Evaluation Well ER-5-5: Corrective Action Unit 98: Frenchman Flat

    SciTech Connect (OSTI)

    NSTec Underground Test Area and Boreholes Programs and Operations

    2013-01-18

    Model Evaluation Well ER-5-5 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of Nevada Environmental Management Operations at the Nevada National Security Site (formerly known as the Nevada Test Site). The well was drilled in July and August 2012 as part of a model evaluation well program in the Frenchman Flat area of Nye County, Nevada. The primary purpose of the well was to provide detailed geologic, hydrogeologic, chemical, and radiological data that can be used to test and build confidence in the applicability of the Frenchman Flat Corrective Action Unit flow and transport models for their intended purpose. In particular, this well was designed to obtain data to evaluate the uncertainty in model forecasts of contaminant migration from the upgradient underground nuclear test MILK SHAKE, conducted in Emplacement Hole U-5k in 1968, which were considered to be uncertain due to the unknown extent of a basalt lava-flow aquifer present in this area. Well ER-5-5 is expected to provide information to refine the Phase II Frenchman Flat hydrostratigraphic framework model, if necessary, as well as to support future groundwater flow and transport modeling. The 31.1-centimeter (cm) diameter hole was drilled to a total depth of 331.3 meters (m). The completion string, set at the depth of 317.2 m, consists of 16.8-cm stainless-steel casing hanging from 19.4-cm carbon-steel casing. The 16.8-cm stainless-steel casing has one slotted interval open to the basalt lava-flow aquifer and limited intervals of the overlying and underlying alluvial aquifer. A piezometer string was also installed in the annulus between the completion string and the borehole wall. The piezometer is composed of 7.3-cm stainless-steel tubing suspended from 6.0-cm carbon-steel tubing. The piezometer string was landed at 319.2 m, to monitor the basalt lava-flow aquifer. Data collected during and shortly after hole construction include

  2. Comparison of {sup 241}Am, {sup 239,240}Pu, and {sup 137}Cs concentrations in soil around Rocky Flats

    SciTech Connect (OSTI)

    Hulse, S.E.; Ibrahim, S.A.; Whicker, F.W.; Chapman, P.L.

    1999-03-01

    Gamma spectroscopy measurements were used to estimate concentrations of {sup 241}Am and {sup 137}Cs in soil profiles to depths of 21 cm at on-site and off-site locations around the Rocky Flats Environmental Technology Site and at regional background locations east of the Front Range between Colorado`s borders with New Mexico and Wyoming. Concentrations of these radionuclides were compared with concentrations of {sup 239,240}Pu in the same samples. Concentrations of {sup 241}Am in soil from depths of 0 to 3 cm decreased in an easterly direction from more than 5.3 kBq kg{sup {minus}1} 5 to 7 km away at a rate that was nearly proportional to the inverse square of distance. Deposits of {sup 137}Cs were ubiquitous, averaging 0.12 kBq kg{sup {minus}1} in soil from depths of 0 to 3 cm, but were unevenly distributed around Rocky Flats and the regional background locations. Deviations from the uniform exponential rate at which soil concentrations of {sup 137}Cs typically decreased with depth, {minus}0.25 cm{sup {minus}1} at undisturbed sites, enabled the authors to determine that about 10% of their sampling sites had been disturbed by erosion, tillage, or other factors. The mean rate at which {sup 239,240}Pu decreased with depth was about the same, {minus}0.23 cm{sup {minus}1}, throughout the study area. Soil concentrations of {sup 241}Am decreased with depth at a similar mean rate of {minus}0.22 cm{sup {minus}1} at locations close to the 903 pad where measurements were robust. Ratios between {sup 241}Am or {sup 239,240}Pu and {sup 137}Cs proved more useful for delineating the extent and pattern of contamination from Rocky Flats than did activity concentrations in soil.

  3. Approaches to Quantify Potential Contaminant Transport in the Lower Carbonate Aquifer from Underground Nuclear Testing at Yucca Flat, Nevada National Security Site, Nye County, Nevada - 12434

    SciTech Connect (OSTI)

    Andrews, Robert W.; Birdie, Tiraz; Wilborn, Bill; Mukhopadhyay, Bimal

    2012-07-01

    Quantitative modeling of the potential for contaminant transport from sources associated with underground nuclear testing at Yucca Flat is an important part of the strategy to develop closure plans for the residual contamination. At Yucca Flat, the most significant groundwater resource that could potentially be impacted is the Lower Carbonate Aquifer (LCA), a regionally extensive aquifer that supplies a significant portion of the water demand at the Nevada National Security Site, formerly the Nevada Test Site. Developing and testing reasonable models of groundwater flow in this aquifer is an important precursor to performing subsequent contaminant transport modeling used to forecast contaminant boundaries at Yucca Flat that are used to identify potential use restriction and regulatory boundaries. A model of groundwater flow in the LCA at Yucca Flat has been developed. Uncertainty in this model, as well as other transport and source uncertainties, is being evaluated as part of the Underground Testing Area closure process. Several alternative flow models of the LCA in the Yucca Flat/Climax Mine CAU have been developed. These flow models are used in conjunction with contaminant transport models and source term models and models of contaminant transport from underground nuclear tests conducted in the overlying unsaturated and saturated alluvial and volcanic tuff rocks to evaluate possible contaminant migration in the LCA for the next 1,000 years. Assuming the flow and transport models are found adequate by NNSA/NSO and NDEP, the models will undergo a peer review. If the model is approved by NNSA/NSO and NDEP, it will be used to identify use restriction and regulatory boundaries at the start of the Corrective Action Decision Document Corrective Action Plan (CADD/CAP) phase of the Corrective Action Strategy. These initial boundaries may be revised at the time of the Closure Report phase of the Corrective Action Strategy. (authors)

  4. Transportation of pyrochemical salts from Rocky Flats to Los Alamos

    SciTech Connect (OSTI)

    Schreiber, S.B.

    1997-02-01

    Radioactive legacy wastes or residues are currently being stored on numerous Sites around the former Department of Energy`s (DOE) Nuclear Weapons Complex. Since most of the operating facilities were shut down and have not operated since before the declared end to the Cold War in 1993, the historical method for treating these residues no longer exists. The risk associated with continued storage of these residues will dramatically increase with time. Thus, the DOE was directed by the Defense Nuclear Facility Safety Board in its Recommendation 94-1 to address and stabilize these residues and established an eight year time frame for doing so. There are only two options available to respond to this requirement: (1) restart existing facilities to treat and package the residues for disposal or (2) transport the residues to another operating facility within the Complex where they can be treated and packaged for disposal. This paper focuses on one such residue type, pyrochemical salts, produced at one Complex site, the Rocky Flats Plant located northwest of Denver, Colorado. One option for treating the salts is their shipment to Los Alamos, New Mexico, for handling at the Plutonium Facility. The safe transportation of these salts can be accomplished at present with several shipping containers including a DOT 6M, a DOE 9968, Type A or Type B quantity 55-gallon drum overpacks, or even the TRUPACT II. The tradeoffs between each container is examined with the conclusion that none of the available shipping containers is fully satisfactory. Thus, the advantageous aspects of each container must be utilized in an integrated and efficient way to effectively manage the risk involved. 1 fig.

  5. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  6. Multi-cusp ion source for doping process of flat panel display manufacturing

    SciTech Connect (OSTI)

    Inouchi, Yutaka Matsumoto, Takeshi; Dohi, Shojiro; Tanii, Masahiro; Takahashi, Genki; Nishimura, Ippei; Tatemichi, Junichi; Konishi, Masashi; Naito, Masao

    2014-02-15

    We developed a multi-cusp ion source for Nissin ion doping system iG5 which is used in low temperature poly-crystalline silicon processes for flat panel display (FPD) manufacturing. In this ion source, BF{sub 3} or PH{sub 3} diluted H{sub 2} plasmas are produced and large area ribbon ion beams are extracted. In general, ion ratio of B{sup +} in BF{sub 3} plasma is much smaller than BF{sub 2}{sup +} in multi-cusp ion sources. We developed a new method to increase B{sup +} ratio and obtained mass analyzed B{sup +} target current of 130 mA. We employed newly improved multi-slot type electrodes for the beam extraction system and obtained stable beams with the uniformity of below 3%. In BF{sub 3} plasmas, several undesirable metal fluorides are produced in the plasma chamber and deposited on the electrode system, which cause glitches and poor beam uniformity. We introduce several cleaning methods.

  7. A Cold War Battlefield: Frenchman Flat Historic District, Nevada Test Site, Nye County, Nevada

    SciTech Connect (OSTI)

    Johnson, William Gray; Holz, Barbara A; Jones, Robert

    2000-08-01

    This report provides the U.S. Department of Energy, Nevada Operations Office with the documentation necessary to establish the Frenchman Flat Historic District on the Nevada Test Site (NTS). It includes a list of historic properties that contribute to the eligibility of the district for inclusion in the National Register of Historic Places (NRHP) and provides contextual information establishing its significance. The list focuses on buildings, structures and features associated with the period of atmospheric testing of nuclear weapons on the NTS between 1951 and 1962. A total of 157 locations of buildings and structures were recorded of which 115 are considered to be eligible for the NRHP. Of these, 28 have one or more associated features which include instrumentation supports, foundations, etc. The large majority of contributing structures are buildings built to study the blast effects of nuclear weaponry. This has resulted in a peculiar accumulation of deteriorated structures that, unlike most historic districts, is best represented by those that are the most damaged. Limitations by radiological control areas, surface exposure and a focus on the concentration of accessible properties on the dry lake bed indicate additional properties exist which could be added to the district on a case-by-case basis.

  8. TREATMENT OF PLUTONIUM- AND URANIUM-CONTAMINATED OIL FROM ROCKY FLATS ENVIRONMENTAL TECHNOLOGY SITE

    SciTech Connect (OSTI)

    Klasson, KT

    2002-12-05

    A removal method for plutonium and uranium has been tested at the Rocky Flats Environmental Technology Site (RFETS). This alternative treatment technology is applicable to U.S. Department of Energy (DOE) organics (mainly used pump oil) contaminated with actinides. In our studies, greater than 70% removal of the actinides was achieved. The technology is based on contacting the oil with a sorbent powder consisting of a surface modified mesoporous material. The SAMMS (Self-Assembled Monolayers on Mesoporous Support) technology was developed by the Pacific Northwest National Laboratory for removal and stabilization of RCRA (i.e., lead, mercury, cadmium, silver, etc.) and actinides in water and for removal of mercury from organic solvents [1, 2]. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide support provides a high surface area, thereby enhancing the metal-loading capacity. The testing described in this report was conducted on a small scale but larger-scale testing of the technology has been performed on mercury-contaminated oil without difficulty [3].

  9. Methods of use of calcium hexa aluminate refractory linings and/or chemical barriers in high alkali or alkaline environments

    DOE Patents [OSTI]

    McGowan, Kenneth A; Cullen, Robert M; Keiser, James R; Hemrick, James G; Meisner, Roberta A

    2013-10-22

    A method for improving the insulating character/and or penetration resistance of a liner in contact with at least one of an alkali and/or alkaline environments is provided. The method comprises lining a surface that is subject to wear by an alkali environment and/or an alkaline environment with a refractory composition comprising a refractory aggregate consisting essentially of a calcium hexa aluminate clinker having the formula CA.sub.6, wherein C is equal to calcium oxide, wherein A is equal to aluminum oxide, and wherein the hexa aluminate clinker has from zero to less than about fifty weight percent C.sub.12A.sub.7, and wherein greater than 98 weight percent of the calcium hexa aluminate clinker having a particle size ranging from -20 microns to +3 millimeters, for forming a liner of the surface. This method improves the insulating character/and or penetration resistance of the liner.

  10. Formation of compressed flat electron beams with high transverse-emittance ratios

    SciTech Connect (OSTI)

    Zhu, J.; Piot, P.; Mihalcea, D.; Prokop, C. R.

    2014-08-01

    Flat beamsbeams with asymmetric transverse emittanceshave important applications in novel light-source concepts and advanced-acceleration schemes and could possibly alleviate the need for damping rings in lepton colliders. Over the last decade, a flat beam generation technique based on the conversion of an angular-momentum-dominated beam was proposed and experimentally tested. In this paper we explore the production of compressed flat beams. We especially investigate and optimize the flat beam transformation for beams with substantial fractional energy spread. We use as a simulation example the photoinjector of Fermilabs Advanced Superconducting Test Accelerator. The optimizations of the flat beam generation and compression at Advanced Superconducting Test Accelerator were done via start-to-end numerical simulations for bunch charges of 3.2 nC, 1.0 nC, and 20 pC at ?37??MeV. The optimized emittances of flat beams with different bunch charges were found to be 0.25???m (emittance ratio is ?400), 0.13????m, 15 nm before compression, and 0.41???m, 0.20???m, 16 nm after full compression, respectively, with peak currents as high as 5.5 kA for a 3.2?nC flat beam. These parameters are consistent with requirements needed to excite wakefields in asymmetric dielectric-lined waveguides or produce significant photon flux using small-gap micro-undulators.

  11. The role of alumina on performance of alkali-activated slag paste exposed to 50 °C

    SciTech Connect (OSTI)

    Jambunathan, N.; Sanjayan, J.G.; Pan, Z.; Li, G.; Liu, Y.; Korayem, A.H.; Duan, W.H.; Collins, F.

    2013-12-15

    The strength and microstructural evolution of two alkali-activated slags, with distinct alumina content, exposed to 50 °C have been investigated. These two slags are ground-granulated blast furnace slag (containing 13% (wt.) alumina) and phosphorous slag (containing 3% (wt.) alumina). They were hydrated in the presence of a combination of sodium hydroxide and sodium silicate solution at different ratios. The microstructure of the resultant slag pastes was assessed by X-ray diffraction, differential thermogravimetric analysis, and scanning electron microscopy. The results obtained from these techniques reveal the presence of hexagonal hydrates: CAH{sub 10} and C{sub 4}AH{sub 13} in all alkali-activated ground-granulated blast-furnace slag pastes (AAGBS). These hydrates are not observed in pastes formed by alkali-activated ground phosphorous slag (AAGPS). Upon exposure to 50 °C, the aforementioned hydration products of AAGBS pastes convert to C{sub 3}AH{sub 6}, leading to a rapid deterioration in the strength of the paste. In contrast, no strength loss was detected in AAGPS pastes following exposure to 50 °C. -- Highlights: •Strength of alkali-activated slag (AAS) pastes after exposure to 50 °C is studied. •AAS pastes with high alumina content lose strength after the exposure. •C{sub 4}AH{sub 13} and CAH{sub 10} form in these AAS pastes. •Conversion of these calcium alumina hydrates is associated with the strength loss. •AAS pastes with low alumina content maintain its strength after the exposure.

  12. A Hydrostratigraphic Model and Alternatives for the Groundwater Flow and Contaminant Transport Model of Corrective Action Unit 97: Yucca Flat-Climax Mine, Lincoln and Nye Counties, Nevada

    SciTech Connect (OSTI)

    Geotechnical Sciences Group Bechtel Nevada

    2006-01-01

    A new three-dimensional hydrostratigraphic framework model for the Yucca Flat-Climax Mine Corrective Action Unit was completed in 2005. The model area includes Yucca Flat and Climax Mine, former nuclear testing areas at the Nevada Test Site, and proximal areas. The model area is approximately 1,250 square kilometers in size and is geologically complex. Yucca Flat is a topographically closed basin typical of many valleys in the Basin and Range province. Faulted and tilted blocks of Tertiary-age volcanic rocks and underlying Proterozoic and Paleozoic sedimentary rocks form low ranges around the structural basin. During the Cretaceous Period a granitic intrusive was emplaced at the north end of Yucca Flat. A diverse set of geological and geophysical data collected over the past 50 years was used to develop a structural model and hydrostratigraphic system for the basin. These were integrated using EarthVision? software to develop the 3-dimensional hydrostratigraphic framework model. Fifty-six stratigraphic units in the model area were grouped into 25 hydrostratigraphic units based on each unit's propensity toward aquifer or aquitard characteristics. The authors organized the alluvial section into 3 hydrostratigraphic units including 2 aquifers and 1 confining unit. The volcanic units in the model area are organized into 13 hydrostratigraphic units that include 8 aquifers and 5 confining units. The underlying pre-Tertiary rocks are divided into 7 hydrostratigraphic units, including 3 aquifers and 4 confining units. Other units include 1 Tertiary-age sedimentary confining unit and 1 Mesozoic-age granitic confining unit. The model depicts the thickness, extent, and geometric relationships of these hydrostratigraphic units (''layers'' in the model) along with the major structural features (i.e., faults). The model incorporates 178 high-angle normal faults of Tertiary age and 2 low-angle thrust faults of Mesozoic age. The complexity of the model area and the non

  13. Framework for a Risk-Informed Groundwater Compliance Strategy for Corrective Action Unit 98: Frenchman Flat, Nevada National Security Site, Nye County, Nevada, Revision 1

    SciTech Connect (OSTI)

    Marutzky, Sam

    2010-09-01

    Note: This document was prepared before the NTS was renamed the Nevada National Security Site (August 23, 2010); thus, all references to the site herein remain NTS. Corrective Action Unit (CAU) 98, Frenchman Flat, at the Nevada Test Site (NTS) was the location of ten underground nuclear tests between 1965 and 1971. As a result, radionuclides were released in the subsurface in the vicinity of the test cavities. Corrective Action Unit 98 and other CAUs at the NTS and offsite locations are being investigated. The Frenchman Flat CAU is one of five Underground Test Area (UGTA) CAUs at the NTS that are being evaluated as potential sources of local or regional impact to groundwater resources. For UGTA sites, including Frenchman Flat, contamination in and around the test cavities will not be remediated because it is technologically infeasible due to the depth of the test cavities (150 to 2,000 feet [ft] below ground surface) and the volume of contaminated groundwater at widely dispersed locations on the NTS. Instead, the compliance strategy for these sites is to model contaminant flow and transport, estimate the maximum spatial extent and volume of contaminated groundwater (over a period of 1,000 years), maintain institutional controls, and restrict access to potentially contaminated groundwater at areas where contaminants could migrate beyond the NTS boundaries.

  14. Highly Effective Pt-Based Water-Gas Shift Catalysts by Surface Modification with Alkali Hydroxide Salts

    SciTech Connect (OSTI)

    Kusche, Matthias; Bustillo, Karen; Agel, Friederike; Wasserscheid, Peter

    2015-01-29

    Here, we describe an economical and convenient method to improve the performance of Pt/alumina catalysts for the water–gas shift reaction through surface modification of the catalysts with alkali hydroxides according to the solid catalyst with ionic liquid layer approach. The results are in agreement with our findings reported earlier for methanol steam reforming. This report indicates that alkali doping of the catalyst plays an important role in the observed catalyst activation. In addition, the basic and hygroscopic nature of the salt coating contributes to a significant improvement in the performance of the catalyst. During the reaction, a partly liquid film of alkali hydroxide forms on the alumina surface, which increases the availability of H2O at the catalytically active sites. Kinetic studies reveal a negligible effect of the KOH coating on the rate dependence of CO and H2O partial pressures. In conclusion, TEM studies indicate an agglomeration of the active Pt clusters during catalyst preparation; restructuring of Pt nanoparticles occurs under reaction conditions, which leads to a highly active and stable system over 240h time on stream. Excessive pore fillings with KOH introduce a mass transfer barrier as indicated in a volcano-shaped curve of activity versus salt loading. The optimum KOH loading was found to be 7.5wt%.

  15. Examination of the concrete from an old Portuguese dam: Texture and composition of alkali-silica gel

    SciTech Connect (OSTI)

    Fernandes, Isabel Noronha, Fernando Teles, Madalena

    2007-11-15

    Exudations and pop-outs were identified in the interior galleries of a large dam built in the 1960s. The samples collected were examined by a Scanning Electron Microscope. A dense material with a smooth surface and drying shrinkage cracks or a spongy texture were observed in the samples. The semi-quantitative composition was obtained by energy dispersive spectrometry (EDS) and it was concluded that this material corresponds to alkali-silica gel, composed of SiO{sub 2}-Na{sub 2}O-K{sub 2}O-CaO. A viscous white product in contact with an aggregate particle in a cone sampled from a pop-out was observed through use of the scanning electron microscope and it has characteristics similar to the gel present in the exudations and cavities. Reference is made to the potential alkali reactivity of the aggregate present in the concrete. The texture and composition of the products probably resulting from an alkali-silica reaction are presented, set out in ternary diagrams, and discussed.

  16. Highly Effective Pt-Based Water-Gas Shift Catalysts by Surface Modification with Alkali Hydroxide Salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kusche, Matthias; Bustillo, Karen; Agel, Friederike; Wasserscheid, Peter

    2015-01-29

    Here, we describe an economical and convenient method to improve the performance of Pt/alumina catalysts for the water–gas shift reaction through surface modification of the catalysts with alkali hydroxides according to the solid catalyst with ionic liquid layer approach. The results are in agreement with our findings reported earlier for methanol steam reforming. This report indicates that alkali doping of the catalyst plays an important role in the observed catalyst activation. In addition, the basic and hygroscopic nature of the salt coating contributes to a significant improvement in the performance of the catalyst. During the reaction, a partly liquid filmmore » of alkali hydroxide forms on the alumina surface, which increases the availability of H2O at the catalytically active sites. Kinetic studies reveal a negligible effect of the KOH coating on the rate dependence of CO and H2O partial pressures. In conclusion, TEM studies indicate an agglomeration of the active Pt clusters during catalyst preparation; restructuring of Pt nanoparticles occurs under reaction conditions, which leads to a highly active and stable system over 240h time on stream. Excessive pore fillings with KOH introduce a mass transfer barrier as indicated in a volcano-shaped curve of activity versus salt loading. The optimum KOH loading was found to be 7.5wt%.« less

  17. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  18. DOE Certifies Rocky Flats Cleanup "Complete" | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Certifies Rocky Flats Cleanup "Complete" DOE Certifies Rocky Flats Cleanup "Complete" December 8, 2005 - 4:45pm Addthis Golden, CO - Deputy Secretary of Energy Clay Sell announced today that the environmental cleanup of the former Rocky Flats site has been certified complete by the U.S. Department of Energy. Certification marks the final step in the DOE's successful effort to clean up and eventually turn over the former weapons production site for use as a National Wildlife

  19. About vacuum solutions of Einstein's field equations with flat three-dimensional hypersurfaces

    SciTech Connect (OSTI)

    Wolf, T.

    1986-09-01

    The class of vacuum space-times with a family of flat three-slices and a traceless tensor of exterior curvature K-italic/sub a-italic//sub b-italic/ is examined. Metrics without symmetry and solutions describing gravitational radiation are obtained. It turns out that there is a correlation between rank (K-italic/sub a-italic//sub b-italic/) and the Petrov type. Although the resulting solutions are already known, the richness of the class of space-times with flat slices becomes obvious. An example is given of a metric with one-parameter manifold of families of flat slices.

  20. A groundwater flow and transport model of long-term radionuclide migration in central Frenchman flat, Nevada test site

    SciTech Connect (OSTI)

    Kwicklis, Edward Michael [Los Alamos National Laboratory; Becker, Naomi M [Los Alamos National Laboratory; Ruskauff, Gregory [NAVARRO-INTERA, LLC.; De Novio, Nicole [GOLDER AND ASSOC.; Wilborn, Bill [US DOE NNSA NSO

    2010-11-10

    A set of groundwater flow and transport models were created for the Central Testing Area of Frenchman Flat at the former Nevada Test Site to investigate the long-term consequences of a radionuclide migration experiment that was done between 1975 and 1990. In this experiment, radionuclide migration was induced from a small nuclear test conducted below the water table by pumping a well 91 m away. After radionuclides arrived at the pumping well, the contaminated effluent was discharged to an unlined ditch leading to a playa where it was expected to evaporate. However, recent data from a well near the ditch and results from detailed models of the experiment by LLNL personnel have convincingly demonstrated that radionuclides from the ditch eventually reached the water table some 220 m below land surface. The models presented in this paper combine aspects of these detailed models with concepts of basin-scale flow to estimate the likely extent of contamination resulting from this experiment over the next 1,000 years. The models demonstrate that because regulatory limits for radionuclide concentrations are exceeded only by tritium and the half-life of tritium is relatively short (12.3 years), the maximum extent of contaminated groundwater has or will soon be reached, after which time the contaminated plume will begin to shrink because of radioactive decay. The models also show that past and future groundwater pumping from water supply wells within Frenchman Flat basin will have negligible effects on the extent of the plume.

  1. Sorbent Testing for the Solidification of Unidentified Rocky Flats Laboratory Waste Stored at the Idaho National Laboratory

    SciTech Connect (OSTI)

    Bickford, J.; Kimmitt, R.

    2007-07-01

    At the request of the U.S. Department of Energy (DOE), MSE Technology Applications, Inc. (MSE) evaluated various commercially available sorbents to solidify unidentified laboratory liquids from Rocky Flats that are stored at the Idaho National Laboratory (INL). The liquids are a collection of laboratory wastes that were generated from various experiments and routine analytical laboratory activities carried out at Rocky Flats. The liquids are in bottles discovered inside of buried waste drums being exhumed from the subsurface disposal area at the Radioactive Waste Management Complex (RWMC) by the contractor, CH2M Hill Washington International (CWI). Free liquids are unacceptable at the Waste Isolation Pilot Plant (WIPP), and some of these liquids cannot be returned to the retrieval pit. Stabilization of the liquids into a solid mass will allow these materials to be sent to an appropriate disposal location. The selected sorbent or sorbent combinations should produce a stabilized mass that is capable of withstanding conditions similar to those experienced during storage, shipping, and burial. The final wasteform should release less than 1% liquid by volume per the WIPP Waste Acceptance Criteria (WAC). The absence or presence of free liquid in the solidified waste-forms was detected when tested by SW-846, Method 9095B, Paint Filter Free Liquids, and the amount of liquid released from the wasteform was determined by SW-846, Method 9096, Liquid Release Test. Reactivity testing was also conducted on the solidified laboratory liquids. (authors)

  2. Monitoring, Modeling, and Diagnosis of Alkali-Silica Reaction in Small Concrete Samples

    SciTech Connect (OSTI)

    Agarwal, Vivek; Cai, Guowei; Gribok, Andrei V.; Mahadevan, Sankaran

    2015-09-01

    Assessment and management of aging concrete structures in nuclear power plants require a more systematic approach than simple reliance on existing code margins of safety. Structural health monitoring of concrete structures aims to understand the current health condition of a structure based on heterogeneous measurements to produce high-confidence actionable information regarding structural integrity that supports operational and maintenance decisions. This report describes alkali-silica reaction (ASR) degradation mechanisms and factors influencing the ASR. A fully coupled thermo-hydro-mechanical-chemical model developed by Saouma and Perotti by taking into consideration the effects of stress on the reaction kinetics and anisotropic volumetric expansion is presented in this report. This model is implemented in the GRIZZLY code based on the Multiphysics Object Oriented Simulation Environment. The implemented model in the GRIZZLY code is randomly used to initiate ASR in a 2D and 3D lattice to study the percolation aspects of concrete. The percolation aspects help determine the transport properties of the material and therefore the durability and service life of concrete. This report summarizes the effort to develop small-size concrete samples with embedded glass to mimic ASR. The concrete samples were treated in water and sodium hydroxide solution at elevated temperature to study how ingress of sodium ions and hydroxide ions at elevated temperature impacts concrete samples embedded with glass. Thermal camera was used to monitor the changes in the concrete sample and results are summarized.

  3. X-ray microtomography shows pore structure and tortuosity in alkali-activated binders

    SciTech Connect (OSTI)

    Provis, John L.; Myers, Rupert J.; White, Claire E.; Rose, Volker; Deventer, Jannie S.J. van

    2012-06-15

    Durability of alkali-activated binders is of vital importance in their commercial application, and depends strongly on microstructure and pore network characteristics. X-ray microtomography ({mu}CT) offers, for the first time, direct insight into microstructural and pore structure characteristics in three dimensions. Here, {mu}CT is performed on a set of sodium metasilicate-activated fly ash/slag blends, using a synchrotron beamline instrument. Segmentation of the samples into pore and solid regions is then conducted, and pore tortuosity is calculated by a random walker method. Segmented porosity and diffusion tortuosity are correlated, and vary as a function of slag content (slag addition reduces porosity and increases tortuosity), and sample age (extended curing gives lower porosity and higher tortuosity). This is particularly notable for samples with {>=} 50% slag content, where a space-filling calcium (alumino)silicate hydrate gel provides porosity reductions which are not observed for the sodium aluminosilicate ('geopolymer') gels which do not chemically bind water of hydration.

  4. Cellular morphology of organic-inorganic hybrid foams based on alkali alumino-silicate matrix

    SciTech Connect (OSTI)

    Verdolotti, Letizia; Capasso, Ilaria; Lavorgna, Marino; Liguori, Barbara; Caputo, Domenico; Iannace, Salvatore

    2014-05-15

    Organic-inorganic hybrid foams based on an alkali alumino-silicate matrix were prepared by using different foaming methods. Initially, the synthesis of an inorganic matrix by using aluminosilicate particles, activated through a sodium silicate solution, was performed at room temperature. Subsequently the viscous paste was foamed by using three different methods. In the first method, gaseous hydrogen produced by the oxidization of Si powder in an alkaline media, was used as blowing agent to generate gas bubbles in the paste. In the second method, the porous structure was generated by mixing the paste with a meringue type of foam previously prepared by whipping, under vigorous stirring, a water solution containing vegetal proteins as surfactants. In the third method, a combination of these two methods was employed. The foamed systems were consolidated for 24 hours at 40C and then characterized by FTIR, X-Ray diffraction, scanning electron microscopy (SEM) and compression tests. Low density foams (?500 Kg/m{sup 3}) with good cellular structure and mechanical properties were obtained by combining the meringue approach with the use of the chemical blowing agent based on Si.

  5. Completion Report for Model Evaluation Well ER-11-2: Corrective Action Unit 98: Frenchman Flat

    SciTech Connect (OSTI)

    NSTec Underground Test Area and Boreholes Programs and Operations

    2013-01-22

    Model Evaluation Well ER-11-2 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of Nevada Environmental Management Operations at the Nevada National Security Site (formerly known as the Nevada Test Site). The well was drilled in August 2012 as part of a model evaluation program in the Frenchman Flat area of Nye County, Nevada. The primary purpose of the well was to provide detailed geologic, hydrogeologic, chemical, and radionuclide data that can be used to test and build confidence in the applicability of the Frenchman Flat Corrective Action Unit flow and transport models for their intended purpose. In particular, this well was designed to provide data to evaluate the uncertainty in model forecasts of contaminant migration from the upgradient underground nuclear test PIN STRIPE, conducted in borehole U-11b in 1966. Well ER-11-2 will provide information that can be used to refine the Phase II Frenchman Flat hydrostratigraphic framework model if necessary, as well as to support future groundwater flow and transport modeling. The main 31.1-centimeter (cm) hole was drilled to a total depth of 399.6 meters (m). A completion casing string was not set in Well ER-11-2. However, a piezometer string was installed in the 31.1-cm open hole. The piezometer is composed of 7.3-cm stainless-steel tubing hung on 6.0-cm carbon-steel tubing via a crossover sub. The piezometer string was landed at 394.5 m, for monitoring the lower tuff confining unit. Data collected during and shortly after hole construction include composite drill cuttings samples collected every 3.0 m, various geophysical logs, water quality (including tritium and other test-related radionuclides) measurements, and water level measurements. The well penetrated 42.7 m of Quaternary and Tertiary alluvium and 356.9 m of Tertiary volcanic rock. The water-level measured in the piezometer string on September 25, 2012, was 353.8 m below ground surface. No

  6. Semiconductor-based, large-area, flexible, electronic devices

    DOE Patents [OSTI]

    Goyal, Amit

    2011-03-15

    Novel articles and methods to fabricate the same resulting in flexible, large-area, triaxially textured, single-crystal or single-crystal-like, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  7. Evaluation of Single-Doppler Radar Wind Retrievals in Flat and Complex Terrain

    SciTech Connect (OSTI)

    Newsom, Rob K.; Berg, Larry K.; Pekour, Mikhail S.; Fast, Jerome D.; Xu, Qin; Zhang, Pengfei; Yang, Qing; Shaw, William J.; Flaherty, Julia E.

    2014-08-01

    The accuracy of winds derived from NEXRAD level II data is assessed by comparison with independent observations from 915 MHz radar wind profilers. The evaluation is carried out at two locations with very different terrain characteristics. One site is located in an area of complex terrain within the State Line Wind Energy Center in northeast Oregon. The other site is located in an area of flat terrain on the east-central Florida coast. The National Severe Storm Laboratorys 2DVar algorithm is used to retrieve wind fields from the KPDT (Pendleton OR) and KMLB (Melbourne FL) NEXRAD radars. Comparisons between the 2DVar retrievals and the radar profilers were conducted over a period of about 6 months and at multiple height levels at each of the profiler sites. Wind speed correlations at most observation height levels fell in the range from 0.7 to 0.8, indicating that the retrieved winds followed temporal fluctuations in the profiler-observed winds reasonably well. The retrieved winds, however, consistently exhibited slow biases in the range of1 to 2 ms-1. Wind speed difference distributions were broad with standard deviations in the range from 3 to 4 ms-1. Results from the Florida site showed little change in the wind speed correlations and difference standard deviations with altitude between about 300 and 1400 m AGL. Over this same height range, results from the Oregon site showed a monotonic increase in the wind speed correlation and a monotonic decrease in the wind speed difference standard deviation with increasing altitude. The poorest overall agreement occurred at the lowest observable level (~300 m AGL) at the Oregon site, where the effects of the complex terrain were greatest.

  8. Corrective Action Investigation Plan for Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada National Security Site, Nevada with ROTCs 1, 2, and 3 (Revision 0, September 2000)

    SciTech Connect (OSTI)

    Andrews, Robert; Marutzky, Sam

    2000-09-01

    This Corrective Action Investigation Plan contains the U.S. Department of Energy, Nevada Operations Office's (DOE/NV's) approach to collect the data necessary to evaluate Corrective Action Alternatives (CAAs) appropriate for the closure of Corrective Action Unit (CAU) 97 under the Federal Facility Agreement and Consent Order (FFACO). Corrective Action Unit 97, collectively known as the Yucca Flat/Climax Mine CAU, consists of 720 Corrective Action Sites (CASs). The Yucca Flat/Climax Mine CAU extends over several areas of the NTS and constitutes one of several areas used for underground nuclear testing in the past. The nuclear tests resulted in groundwater contamination in the vicinity as well as downgradient of the underground test areas. Based on site history, the Yucca Flat underground nuclear tests were conducted in alluvial, volcanic, and carbonate rocks; whereas, the Climax Mine tests were conducted in an igneous intrusion located in northern Yucca Flat. Particle-tracking simulations performed during the regional evaluation indicate that the local Climax Mine groundwater flow system merges into the much larger Yucca Flat groundwater flow systems during the 1,000-year time period of interest. Addressing these two areas jointly and simultaneously investigating them as a combined CAU has been determined the best way to proceed with corrective action investigation (CAI) activities. The purpose and scope of the CAI includes characterization activities and model development conducted in five major sequential steps designed to be consistent with FFACO Underground Test Area Project's strategy to predict the location of the contaminant boundary, develop and implement a corrective action, and close each CAU. The results of this field investigation will support a defensible evaluation of CAAs in the subsequent corrective action decision document.

  9. EA-1146: Radioactive Waste Storage at Rocky Flats Environmental Technology Site, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to convert buildings at the U.S. Department of Energy Rocky Flats Environmental Technology Site from their former uses to interim waste...

  10. Preliminary Notice of Violation, Rocky Flats Environmental Technology Site- EA-96-05

    Broader source: Energy.gov [DOE]

    Preliminary Notice of Violation issued to Safe Sites of Colorado related to Radiological and Work Control Deficiencies associated with Two Radiological Release Events at the Rocky Flats Environmental Technology Site, (EA-96-05)

  11. Preparation of atomically flat rutile TiO2(001) surfaces for...

    Office of Scientific and Technical Information (OSTI)

    surfaces for oxide film growth This content will become publicly available on January 1, 2017 Prev Next Title: Preparation of atomically flat rutile TiO2(001) surfaces ...

  12. How are flat demand charges based on the highest peak over the...

    Open Energy Info (EERE)

    How are flat demand charges based on the highest peak over the past 12 months designated in the database (LADWP does this) Home > Groups > Utility Rate Submitted by Marcroper on 11...

  13. DOE's Rocky Flats Cleanup Site Named 2006 Project of the Year...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Cleanup Site Named 2006 Project of the Year By Project Management Institute DOE's ... The award was presented to DOE contractor Kaiser-Hill, LLC during the PMI Global ...

  14. VWZ-0008- In the Matter of EG&G Rocky Flats, Inc.

    Broader source: Energy.gov [DOE]

    This decision will consider a Motion for Partial Dismissal and Limitation on Scope of Complainant's Claims filed by EG&G Rocky Flats, Inc. (EG&G) on June 13, 1997. In its motion, EG&G...

  15. DOE's Former Rocky Flats Weapons Production Site to Become National Wildlife Refuge

    Broader source: Energy.gov [DOE]

    WASHINGTON, DC - The U.S. Department of Energy (DOE) today announced the transfer of nearly 4,000 acres of its former Rocky Flats nuclear weapons production site to the Department of the Interior's...

  16. Comparison and evaluation of turbulence estimation schemes at Rocky Flats Plant

    SciTech Connect (OSTI)

    Bowen, B.M.; Pamp, S.E.

    1993-10-01

    The Rocky Flats Plant (RFP) routinely measures meteorological data to support Air Quality and Emergency Response activities. These data help to characterize the transport and dispersion of actual or potential airborne releases of radionuclides or other hazardous materials.

  17. Council of Athabascan Tribal Government - Wood Energy Program in the Yukon Flats Region

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vision for an Integrated A Vision for an Integrated Biomass Energy Program for Biomass Energy Program for Rural Alaska Rural Alaska DOE NREL Tribal Energy Program DOE NREL Tribal Energy Program 7 November 2007 7 November 2007 CATG CATG - - Alaska Alaska Village Initiatives Village Initiatives Yukon Flats Region Yukon Flats Region Council of Athabascan Tribal Council of Athabascan Tribal Governments Governments Subsistence Lifestyle -- Salmon Fish Wheel Mature Housing New Housing - Fort Yukon

  18. Analytical predictions of liquid and air photovoltaic/thermal flat-plate collector performance

    SciTech Connect (OSTI)

    Raghuraman, P.; Hendrie, S.D.

    1980-01-01

    Two separate one-dimensional analyses have been developed for the prediction of the thermal and electrical performance of both liquid and air flat-plate photovoltaic/thermal (PV/T) collectors. The analyses account for the temperature difference between the primary insolation absorber (the photovoltaic cells) and the secondary absorber (a thermal absorber flat plate). The results of the analyses are compared with test measurements, and therefrom, design recommendations are made to maximize the total energy extracted from the collectors.

  19. AmeriFlux US-Prr Poker Flat Research Range Black Spruce Forest

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Suzuki, Rikie [Japan Agency for Marine-Earth Science and Technology

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Prr Poker Flat Research Range Black Spruce Forest. Site Description - This site is located in a blackspruce forest within the property of the Poker Flat Research Range, University of Alaska, Fairbanks. Time-lapse image of the canopy is measured at the same time to relate flux data to satellite images.

  20. Design and performance of tubular flat-plate solid oxide fuel cell

    SciTech Connect (OSTI)

    Matsushima, T.; Ikeda, D.; Kanagawa, H.

    1996-12-31

    With the growing interest in conserving the environmental conditions, much attention is being paid to Solid Oxide Fuel Cell (SOFC), which has high energy-conversion efficiency. Many organizations have conducted studies on tubular and flat type SOFCs. Nippon Telegraph and Telephone Corporation (NTT) has studied a combined tubular flat-plate SOFC, and already presented the I-V characteristics of a single cell. Here, we report the construction of a stack of this SOFC cell and successful generation tests results.

  1. Idaho National Engineering Laboratory code assessment of the Rocky Flats transuranic waste

    SciTech Connect (OSTI)

    1995-07-01

    This report is an assessment of the content codes associated with transuranic waste shipped from the Rocky Flats Plant in Golden, Colorado, to INEL. The primary objective of this document is to characterize and describe the transuranic wastes shipped to INEL from Rocky Flats by item description code (IDC). This information will aid INEL in determining if the waste meets the waste acceptance criteria (WAC) of the Waste Isolation Pilot Plant (WIPP). The waste covered by this content code assessment was shipped from Rocky Flats between 1985 and 1989. These years coincide with the dates for information available in the Rocky Flats Solid Waste Information Management System (SWIMS). The majority of waste shipped during this time was certified to the existing WIPP WAC. This waste is referred to as precertified waste. Reassessment of these precertified waste containers is necessary because of changes in the WIPP WAC. To accomplish this assessment, the analytical and process knowledge available on the various IDCs used at Rocky Flats were evaluated. Rocky Flats sources for this information include employee interviews, SWIMS, Transuranic Waste Certification Program, Transuranic Waste Inspection Procedure, Backlog Waste Baseline Books, WIPP Experimental Waste Characterization Program (headspace analysis), and other related documents, procedures, and programs. Summaries are provided of: (a) certification information, (b) waste description, (c) generation source, (d) recovery method, (e) waste packaging and handling information, (f) container preparation information, (g) assay information, (h) inspection information, (i) analytical data, and (j) RCRA characterization.

  2. Analysis of offsite Emergency Planning Zones (EPZ) for the Rocky Flats Plant

    SciTech Connect (OSTI)

    Hodgin, C.R.; Armstrong, C.; Daugherty, N.M.; Foppe, T.L.; Petrocchi, A.J.; Southward, B.

    1990-05-01

    This project plan for Phase II summarizes the design of a project to complete analysis of offsite Emergency Planning Zones (EPZ) for the Rocky Flats Plant. Federal, state, and local governments develop emergency plans for facilities that may affect the public in the event of an accidental release of nuclear or hazardous materials. One of the purposes of these plans is to identify EPZs where actions might be necessary to protect public health. Public protective actions include sheltering, evacuation, and relocation. Agencies use EPZs to develop response plans and to determine needed resources. The State of Colorado, with support from the US Department of Energy (DOE) and Rocky Flats contractors, has developed emergency plans and EPZs for the Rocky Flats Plant periodically beginning in 1980. In Phase II, Interim Emergency Planning Zones Analysis, Maximum Credible Accident'' we will utilize the current Rocky Flats maximum credible accident (MCA), existing dispersion methodologies, and upgraded dosimetry methodologies to update the radiological EPZs. Additionally, we will develop recommendations for EPZs for nonradiological hazardous materials releases and evaluate potential surface water releases from the facility. This project will allow EG G Rocky Flats to meet current commitments to the state of Colorado and make steady, tangible improvements in our understanding of risk to offsite populations during potential emergencies at the Rocky Flats Plant. 8 refs., 5 figs., 4 tabs.

  3. Comparative risk analysis for the Rocky Flats Plant Integrated Project Planning

    SciTech Connect (OSTI)

    Jones, M.E.; Shain, D.I.

    1994-12-31

    The Rocky Flats Plant is developing a comprehensive planning strategy that will support transition of the Rocky Flats Plant from a nuclear weapons production facility to site cleanup and final disposition. Final disposition of the Rocky Flats Plant materials and contaminants requires consideration of the interrelated nature of sitewide problems, such as material movement and disposition, facility and land use endstates, costs, relative risks to workers and the public, and waste disposition. Comparative Risk Analysis employs both incremental risk and cumulative risk evaluations to compare risk from postulated options or endstates. Comparative Risk Analysis is an analytical tool for the Rocky Flats Plant Integrated Project Planning which can assist a decision-maker in evaluating relative risks among proposed remedial options or future endstates. It addresses the cumulative risks imposed by the Rocky Flats Plant and provides risk information, both human health and ecological, to aid in reducing unnecessary resource and monetary expenditures. Currently, there is no approved methodology that aggregates various risk estimates. Along with academic and field expert review, the Comparative Risk Analysis methodology is being reviewed and refined. A Rocky Flats Plant Risk Assessment Focus Group was established. Stakeholder involvement in the development provides an opportunity to influence the information delivered to a decision-maker. This paper discusses development of the methodology.

  4. Static SIMS Analysis of Carbonate on Basic Alkali-bearing Surfaces

    SciTech Connect (OSTI)

    Groenewold, Gary Steven; Gianotto, Anita Kay; Cortez, Marnie Michelle; Appelhans, Anthony David; Olsen, J.E.; Shaw, A. D.; Karahan, C.; Avci, R.

    2003-02-01

    Carbonate is a somewhat enigmatic anion in static secondary ion mass spectrometry (SIMS) because abundant ions containing intact CO32- are not detected when analyzing alkaline-earth carbonate minerals common to the geochemical environment. In contrast, carbonate can be observed as an adduct ion when it is bound with alkali cations. In this study, carbonate was detected as the adduct Na2CO3Na+ in the spectra of sodium carbonate, bicarbonate, hydroxide, oxalate, formate and nitrite and to a lesser extent nitrate. The appearance of the adduct Na2CO3Na+ on hydroxide, oxalate, formate and nitrite surfaces was interpreted in terms of these basic surfaces fixing CO2 from the ambient atmosphere. The low abundance of Na2CO3Na+ in the static SIMS spectrum of sodium nitrate, compared with a significantly higher abundance in salts having stronger conjugate bases, suggested that the basicity of the conjugate anions correlated with aggressive CO2 fixation; however, the appearance of Na2CO3Na+ could not be explained simply in terms of solution basicity constants. The oxide molecular ion Na2O+ and adducts NaOHNa+ and Na2ONa+ also constituted part of the carbonate spectral signature, and were observed in spectra from all the salts studied. In addition to the carbonate and oxide ions, a low-abundance oxalate ion series was observed that had the general formula Na2-xHxC2O4Na+, where 0 < x < 2. Oxalate adsorption from the laboratory atmosphere was demonstrated but the oxalate ion series also was likely to be formed from reductive coupling occurring during the static SIMS bombardment event. The remarkable spectral similarity observed when comparing the sodium salts indicated that their surfaces shared common chemical speciation and that the chemistry of the surfaces was very different from the bulk of the particle. Copyright 2003 John Wiley & Sons, Ltd.

  5. Calibration of an amorphous-silicon flat panel portal imager for exit-beam dosimetry

    SciTech Connect (OSTI)

    Chen, Josephine; Chuang, Cynthia F.; Morin, Olivier; Aubin, Michele; Pouliot, Jean

    2006-03-15

    Amorphous-silicon flat panel detectors are currently used to acquire digital portal images with excellent image quality for patient alignment before external beam radiation therapy. As a first step towards interpreting portal images acquired during treatment in terms of the actual dose delivered to the patient, a calibration method is developed to convert flat panel portal images to the equivalent water dose deposited in the detector plane and at a depth of 1.5 cm. The method is based on empirical convolution models of dose deposition in the flat panel detector and in water. A series of calibration experiments comparing the response of the flat panel imager and ion chamber measurements of dose in water determines the model parameters. Kernels derived from field size measurements account for the differences in the production and detection of scattered radiation in the two systems. The dissimilar response as a function of beam energy spectrum is characterized from measurements performed at various off-axis positions and for increasing attenuator thickness in the beam. The flat panel pixel inhomogeneity is corrected by comparing a large open field image with profiles measured in water. To verify the accuracy of the calibration method, calibrated flat panel profiles were compared with measured dose profiles for fields delivered through solid water slabs, a solid water phantom containing an air cavity, and an anthropomorphic head phantom. Open rectangular fields of various sizes and locations as well as a multileaf collimator-shaped field were delivered. For all but the smallest field centered about the central axis, the calibrated flat panel profiles matched the measured dose profiles with little or no systematic deviation and approximately 3% (two standard deviations) accuracy for the in-field region. The calibrated flat panel profiles for fields located off the central axis showed a small -1.7% systematic deviation from the measured profiles for the in-field region

  6. Solar-Powered Air Stripping at the Rocky Flats Site, Colorado - 12361

    SciTech Connect (OSTI)

    Boylan, John A.

    2012-07-01

    The U.S. Department of Energy's Rocky Flats Site (the Site), near Denver, Colorado, is a former nuclear weapons facility that was constructed beginning in 1951. With the end of the Cold War, the Site was cleaned up and closed in 2005. Four gravity-driven groundwater treatment systems were installed during cleanup, and their continued operation was incorporated into the final remedy for the Site. All utilities, including electrical power, were removed as part of this closure, so all Site electrical power needs are now met with small solar-powered systems. The Mound Site Plume Treatment System (MSPTS) was installed in 1998 as an innovative system based on zero-valent iron (ZVI). Groundwater flow from the Mound source area containing elevated concentrations of volatile organic compounds (VOCs), primarily in the tetrachloroethene (PCE)-trichloroethene (TCE) family of chlorinated solvents, is intercepted by a collection trench and routed to twin ZVI treatment cells. Later, in 2005, remediation of VOC-contaminated soils at a second up-gradient source area included adding an electron donor to the backfill to help stimulate biodegradation. This reduced concentrations of primary constituents but caused down-gradient groundwater to contain elevated levels of recalcitrant degradation byproducts, particularly cis-1,2-dichloroethene and vinyl chloride. A gravel drain installed as part of the 2005 remediation directs contaminated groundwater from this second source area to the MSPTS for treatment. This additional contaminant load, coupled with correspondingly reduced residence time within the ZVI media due to the increased flow rate, resulted in reduced treatment effectiveness. Elevated concentrations of VOCs were then detected in MSPTS effluent, as well as in surface water at the downstream performance monitoring location for the MSPTS. Subsequent consultations with the Site regulators led to the decision to add a polishing component to reduce residual VOCs in MSPTS effluent

  7. Hydraulic Characterization of Overpressured Tuffs in Central Yucca Flat, Nevada Test Site, Nye County, Nevada

    SciTech Connect (OSTI)

    K.J. Halford; R.J. Laczniak; D.L. Galloway

    2005-10-07

    A sequence of buried, bedded, air-fall tuffs has been used extensively as a host medium for underground nuclear tests detonated in the central part of Yucca Flat at the Nevada Test Site. Water levels within these bedded tuffs have been elevated hundreds of meters in areas where underground nuclear tests were detonated below the water table. Changes in the ground-water levels within these tuffs and changes in the rate and distribution of land-surface subsidence above these tuffs indicate that pore-fluid pressures have been slowly depressurizing since the cessation of nuclear testing in 1992. Declines in ground-water levels concurrent with regional land subsidence are explained by poroelastic deformation accompanying ground-water flow as fluids pressurized by underground nuclear detonations drain from the host tuffs into the overlying water table and underlying regional carbonate aquifer. A hydraulic conductivity of about 3 x 10-6 m/d and a specific storage of 9 x 10-6 m-1 are estimated using ground-water flow models. Cross-sectional and three-dimensional ground-water flow models were calibrated to measured water levels and to land-subsidence rates measured using Interferometric Synthetic Aperture Radar. Model results are consistent and indicate that about 2 million m3 of ground water flowed from the tuffs to the carbonate rock as a result of pressurization caused by underground nuclear testing. The annual rate of inflow into the carbonate rock averaged about 0.008 m/yr between 1962 and 2005, and declined from 0.005 m/yr in 2005 to 0.0005 m/yr by 2300.

  8. Addendum to Revision 1 of the Corrective Action Investigation Plan for Corrective Action Unit 98: Frenchman Flat, Nevada Test Site, Nevada (Addendum Revision No. 1)

    SciTech Connect (OSTI)

    U.S. Department of Energy, National Nuclear Security Administration Nevada Operations Office

    2001-06-06

    This document is submitted as an addendum to the Corrective Action Investigation Plan (CAIP) for Corrective Action Unit (CAU) 98: Frenchman Flat, Nevada Test Site (NTS), Nevada. The addendum was prepared to propose work activities in response to comments resulting from the U.S. Department of Energy's (DOE's) review of the draft Frenchman Flat CAU model of groundwater flow and contaminant transport completed in April 1999. The reviewers included an external panel of experts and the Nevada Division of Environmental Protection. As a result of the review, additional work scope, including new data-collection and modeling activities, has been identified for the Frenchman Flat CAU. The proposed work scope described in this addendum will be conducted in accordance with the revised Underground Test Area strategy contained in the December 2000 amendment to the Federal Facility Agreement and Consent Order. The Frenchman Flat CAU model is a group of interdependent models designed to predict the extent of contamination in groundwater due to the underground nuclear tests conducted within this CAU. At the time of the DOE review, the CAU model consisted of a CAU groundwater flow and transport model comprised of two major components: a groundwater flow model and a recharge model. The CAU groundwater flow model is supported by a hydrostratigraphic model and a recharge model, whereas the CAU transport model is supported by a source-term model. As part of the modeling activities proposed in this addendum, two new major components may be added to the Frenchman Flat CAU model: a total-system model and two local groundwater flow and transport models. The reviewers identified several issues relating to insufficiency of data and inadequacy of the modeling process that should be addressed to provide additional confidence in the modeling results with respect to the potential for contaminant migration to the Lower Carbonate Aquifer. The proposed additional work scope includes new data

  9. Effects of the foil flatness on irradiation performance of U10Mo monolithic mini-plates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ozaltun, Hakan; Medvedev, Pavel G.; Rabin, Barry H.

    2015-09-03

    Monolithic plate-type fuels comprise of a high density, low enrichment, U10Mo fuel foil encapsulated in a cladding material. This concept generates several fabrication challenges such as flatness, centering or thickness variation. There are concerns, if these parameters have implications on overall performance. To investigate these inquiries, the effects of the foil flatness were studied. For this, a representative plate was simulated for an ideal case. The simulations were repeated for additional cases with various foil curvatures to evaluate the effects on the irradiation performance. The results revealed that the stresses and strains induced by fabrication process are not affected bymore » the flatness of the foil. Furthermore, fabrication stresses in the foil are relieved relatively fast in the reactor. The effects of the foil flatness on peak irradiation stressstrains are minimal. There is a slight increase in temperature for the case with maximum curvature. The major impact is on the displacement characteristics. Furthermore, while the case with a flat foil produces a symmetrical swelling, if the foil is curved, more swelling occurs on the thin-cladding side and the plate bows during irradiation.« less

  10. FINAL REPORT FORMER RADIATION WORKER MEDICAL SURVEILLANCE PROGRAM AT ROCKY FLATS For Department of Energy Programs

    SciTech Connect (OSTI)

    Joe M. Aldrich

    2004-11-01

    The Former Radiation Worker Medical Surveillance Program at Rocky Flats was conducted in Arvada, CO, by Oak Ridge Associated Universities through the Oak Ridge Institute for Science and Education under DOE Contract DE-AC05-00OR22750. Objectives of the program were to obtain information on the value of medical surveillance among at-risk former radiation workers and to provide long-term internal radiation dosimetry information to the scientific community. This program provided the former radiation workers of the Rocky Flats Environmental Technology Site (formerly Rocky Flats Plant) an opportunity to receive follow-up medical monitoring and a re-evaluation of their internal radiation dose. The former Rocky Flats radiation worker population is distinctive because it was a reasonably stable work force that received occupational exposures, at times substantial, over several decades. This report reflects the summation of health outcomes, statistical analyses, and dose assessment information on former Rocky Flats radiation workers to the date of study termination as of March 2004.

  11. Cleanup levels for Am-241, Pu-239, U-234, U-235 & U-238 in soils at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Roberts, R.; Colby, B.; Brooks, L.; Slaten, S.

    1997-07-03

    This presentation briefly outlines a cleanup program at a Rocky Flats site through viewgraphs and an executive summary. Exposure pathway analyses to be performed are identified, and decontamination levels are listed for open space and office worker exposure areas. The executive summary very briefly describes the technical approach, RESRAD computer code to be used for analyses, recommendations for exposure levels, and application of action levels to multiple radionuclide contamination. Determination of action levels for surface and subsurface soils, based on radiation doses, is discussed. 1 tab.

  12. Phase II Documentation Overview of Corrective Action Unit 98: Frenchman Flat, Nevada Test Site, Nye County, Nevada, Revision 1

    SciTech Connect (OSTI)

    Greg Ruskauff

    2010-04-01

    The U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) initiated the Underground Test Area (UGTA) Subproject to assess and evaluate radiologic groundwater contamination resulting from underground nuclear testing at the NTS. These activities are overseen by the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended March 2010). For Frenchman Flat, the UGTA Subproject addresses media contaminated by the underground nuclear tests, which is limited to geologic formations within the saturated zone or 100 meters (m) or less above the water table. Transport in groundwater is judged to be the primary mechanism of migration for the subsurface contamination away from the Frenchman Flat underground nuclear tests. The intent of the UGTA Subproject is to assess the risk to the public from the groundwater contamination produced as a result of nuclear testing. The primary method used to assess this risk is the development of models of flow and contaminant transport to forecast the extent of potentially contaminated groundwater for the next 1,000 years, establish restrictions to groundwater usage, and implement a monitoring program to verify protectiveness. For the UGTA Subproject, contaminated groundwater is that which exceeds the radiological standards of the Safe Drinking Water Act (CFR, 2009) the State of Nevada’s groundwater quality standard to protect human health and the environment. Contaminant forecasts are expected to be uncertain, and groundwater monitoring will be used in combination with land-use control to build confidence in model results and reduce risk to the public. Modeling forecasts of contaminant transport will provide the basis for negotiating a compliance boundary for the Frenchman Flat Corrective Action Unit (CAU). This compliance boundary represents a regulatory-based distinction between groundwater contaminated or not contaminated by underground testing. Transport modeling simulations

  13. Observation and Responses to Post-Closure Instances of Localized Instability and Subsidence at the DOE Legacy Management Rocky Flats Site, Colorado-13052

    SciTech Connect (OSTI)

    DiSalvo, Rick; Darr, Bob; Boylan, John; Surovchak, Scott

    2013-07-01

    The former Rocky Flats Plant in Colorado began operations as part of the nation's nuclear weapons complex in the early 1950's. By the 1980's the associated heavily industrialized area covered approximately 1.2 km{sup 2} (300 acres) and was surrounded by an approximately 25.3 km{sup 2} (6,245 acre) security buffer zone. The federally owned property and adjacent offsite areas were placed on the CERCLA National Priority List in 1989. To complete closure, all buildings and other structures that composed the Rocky Flats industrial complex were removed from the surface, but remnants remain in the subsurface. Contouring and grading to return the surface to approximate conditions that were present prior to the plant's construction was completed in 2005. A goal of the final land configuration was to provide long-term surface and subsurface land stability. Several instances of localized surface subsidence or instability have occurred since the final configuration. The localized nature and the relatively small areas of observed subsidence and instability indicate that, overall, the final configuration is performing well, but responses to these occurrences and the observations that followed may be useful in planning for the closure and designing the final land configuration and post-closure monitoring at other sites. (authors)

  14. Understanding Contaminant Transport Pathways at Rocky Flats - A Basis for the Remediation Strategy

    SciTech Connect (OSTI)

    Paton, Ian

    2008-01-15

    The Rocky Flats Environmental Technology Site (RFETS) is a Department of Energy facility located approximately 16 miles northwest of Denver, Colorado. Processing and fabrication of nuclear weapons components occurred at Rocky Flats from 1952 through 1989. Operations at the Site included the use of several radionuclides, including plutonium-239/240 (Pu), americium-241 (Am), and various uranium (U) isotopes, as well as several types of chlorinated solvents. The historic operations resulted in legacy contamination, including contaminated facilities, process waste lines, buried wastes and surface soil contamination. Decontamination and removal of buildings at the site was completed in late 2005, culminating more than ten years of active environmental remediation work. The Corrective Action Decision/Record of Decision was subsequently approved in 2006, signifying regulatory approval and closure of the site. The use of RFETS as a National Wildlife Refuge is scheduled to be in full operation by 2012. To develop a plan for remediating different types of radionuclide contaminants present in the RFETS environment required understanding the different environmental transport pathways for the various actinides. Developing this understanding was the primary objective of the Actinide Migration Evaluation (AME) project. Findings from the AME studies were used in the development of RFETS remediation strategies. The AME project focused on issues of actinide behavior and mobility in surface water, groundwater, air, soil and biota at RFETS. For the purposes of the AME studies, actinide elements addressed included Pu, Am, and U. The AME program, funded by DOE, brought together personnel with a broad range of relevant expertise in technical investigations. The AME advisory panel identified research investigations and approaches that could be used to solve issues related to actinide migration at the Site. An initial step of the AME was to develop a conceptual model to provide a

  15. Long-term risk stabilization of the Rocky Flats Plant residues

    SciTech Connect (OSTI)

    Melberg, T.A.

    1994-12-31

    The liquid and solid residues continue to be a concern at Rocky Flats, primarily due to safety aspects of long-term storage and of the need for processing them into a form for ultimate disposal. Currently, Rocky Flats is processing the low-level solutions from bottles and tanks by direct cementation for storage and disposal. Plans for actinide precipitation of the high-level solutions are being finalized with an anticipated completion date of 2 to 3 yr. The solid residues present a more difficult challenge because of the numerous forms that these exist. Rocky Flats is developing several strategies to handle these materials for safe long-term storage and eventual disposal.

  16. Comparative risk analysis for the Rocky Flats Plant integrated project planning

    SciTech Connect (OSTI)

    Jones, M.E.; Shain, D.I.

    1994-12-31

    The Rocky Flats Plant is developing, with active stakeholder participation, a comprehensive planning strategy that will support transition of the Rocky Flats Plant from a nuclear weapons production facility to site cleanup and final disposition. Final disposition of the Rocky Flats Plant materials and contaminants requires consideration of the interrelated nature of sitewide problems, such as material movement and disposition, facility and land use endstates, costs, relative risks to workers and the public, and waste disposition. Comparative risk analysis employs both incremental risk and cumulative risk evaluations to compare risks from postulated options or end states. These postulated options or end states can be various remedial alternatives, or future endstate uses of federal land.

  17. The low frequency 2D vibration sensor based on flat coil element

    SciTech Connect (OSTI)

    Djamal, Mitra; Sanjaya, Edi; Islahudin; Ramli

    2012-06-20

    Vibration like an earthquake is a phenomenon of physics. The characteristics of these vibrations can be used as an early warning system so as to reduce the loss or damage caused by earthquakes. In this paper, we introduced a new type of low frequency 2D vibration sensor based on flat coil element that we have developed. Its working principle is based on position change of a seismic mass that put in front of a flat coil element. The flat coil is a part of a LC oscillator; therefore, the change of seismic mass position will change its resonance frequency. The results of measurements of low frequency vibration sensor in the direction of the x axis and y axis gives the frequency range between 0.2 to 1.0 Hz.

  18. Comparative risk analysis for the Rocky Flats Plant integrated project planning

    SciTech Connect (OSTI)

    Jones, M.E.; Shain, D.I.

    1994-05-01

    The Rocky Flats Plant is developing, with active stakeholder a comprehensive planning strategy that will support transition of the Rocky Flats Plant from a nuclear weapons production facility to site cleanup and final disposition. Final disposition of the Rocky Flats Plant materials and contaminants requires consideration of the interrelated nature of sitewide problems, such as material movement and disposition, facility and land use endstates, costs relative risks to workers and the public, and waste disposition. Comparative Risk Analysis employs both incremental risk and cumulative risk evaluations to compare risks from postulated options or endstates. These postulated options or endstates can be various remedial alternatives, or future endstate uses of federal agency land. Currently, there does not exist any approved methodology that aggregates various incremental risk estimates. Comparative Risk Analysis has been developed to aggregate various incremental risk estimates to develop a site cumulative risk estimate. This paper discusses development of the Comparative Risk Analysis methodology, stakeholder participation and lessons learned from these challenges.

  19. Amorphous Diamond Flat Panel Displays - Final Report of ER-LTR CRADA project with SI Diamond Technology

    SciTech Connect (OSTI)

    Ager III, Joel W.

    1998-05-08

    The objective of this project was to determine why diamond-based films are unusually efficient electron emitters (field emission cathodes) at room temperature. Efficient cathodes based on diamond are being developed by SI Diamond Technology (SIDT) as components for bright, sunlight-readable, flat panel displays. When the project started, it was known that only a small fraction (<1%) of the cathode area is active in electron emission and that the emission sites themselves are sub-micron in size. The critical challenge of this project was to develop new microcharacterization methods capable of examining known emission sites. The research team used a combination of cathode emission imaging (developed at SIDT), micro-Raman spectroscopy (LBNL), and electron microscopy and spectroscopy (National Center for Electron Microscopy, LBNL) to examine the properties of known emission sites. The most significant accomplishment of the project was the development at LBNL of a very high resolution scanning probe that, for the first time, measured simultaneously the topography and electrical characteristics of single emission sites. The increased understanding of the emission mechanism helped SIDT to develop a new cathode material,''nano-diamond,'' which they have incorporated into their Field Emission Picture Element (FEPix) product. SIDT is developing large-format flat panel displays based on these picture elements that will be brighter and more efficient than existing outdoor displays such as Jumbotrons. The energy saving that will be realized if field emission displays are introduced commercially is in line with the energy conservation mission of DOE. The unique characterization tools developed in this project (particularly the new scanning microscopy method) are being used in ongoing BES-funded basic research.

  20. Alkali metal cation complexation by 1,3-alternate, mono-ionisable calix[4]arene-benzocrown-6 compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Surowiec, Malgorzata A.; Custelcean, Radu; Surowiec, Kazimierz; Bartsch, Richard A.

    2014-04-23

    Alkali metal cation extraction behavior for two series of 1,3-alternate, mono-ionizable calix[4]arene-benzocrown-6 compounds is examined. In Series 1, the proton-ionizable group is a substituent on the benzo group of the polyether ring that directs it away from the crown ether cavity. In Series 2, the proton-ionizable group is attached to one para position in the calixarene framework, thus positioning it over the crown ether ring. Competitive solvent extraction of alkali metal cations from aqueous solutions into chloroform shows high Cs+ efficiency and selectivity. Single-species extraction pH profiles of Cs+ for Series 1 and 2 ligands with the same proton-ionizable groupmore » are very similar. Thus, association of Cs+ with the calixcrown ring is more important than the the proton-ionizable group’s position in relation to the crown ether cavity. Solid-state structures are presented for two unionized ligands from Series 2, as is a crystal containing two different ionized ligand–Cs+ complexes.« less

  1. Desulfurization of Illinois coals with hydroperoxides of vegetable oils and alkali. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, R.; Cheng, J.; Shi, F.; Wang, Y.

    1995-12-31

    Organic sulfur is removed from coals by treatment with aqueous base, air, and vegetable oils with minimal loss of BTU. Such results were revealed during exploratory experiments on an ICCI funded project to remove organic sulfur from Illinois coals with hydroperoxides of vegetable oils. In fact, prewashing IBC-108 coal with dilute alkali prior to treating with linseed oil and air results in 26% removal of sulfur. This new method will be investigated by treating coals with alkali, impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. During this first quarter the selection of base for pretreatment and extraction (Task 1) has been completed. NaOH is better than NH{sub 4}OH for the pretreatment and Na{sub 2}CO{sub 3} is better than NaOH for the oil extraction. About 40% of sulfur is removed from IBC-108 coal using 5% NaOH for pretreatment followed by linseed oil oxidation in air and Na{sub 2}CO{sub 3} extraction.

  2. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

    2011-03-01

    An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

  3. Alkali metal cation complexation by 1,3-alternate, mono-ionisable calix[4]arene-benzocrown-6 compounds

    SciTech Connect (OSTI)

    Surowiec, Malgorzata A.; Custelcean, Radu; Surowiec, Kazimierz; Bartsch, Richard A.

    2014-04-23

    Alkali metal cation extraction behavior for two series of 1,3-alternate, mono-ionizable calix[4]arene-benzocrown-6 compounds is examined. In Series 1, the proton-ionizable group is a substituent on the benzo group of the polyether ring that directs it away from the crown ether cavity. In Series 2, the proton-ionizable group is attached to one para position in the calixarene framework, thus positioning it over the crown ether ring. Competitive solvent extraction of alkali metal cations from aqueous solutions into chloroform shows high Cs+ efficiency and selectivity. Single-species extraction pH profiles of Cs+ for Series 1 and 2 ligands with the same proton-ionizable group are very similar. Thus, association of Cs+ with the calixcrown ring is more important than the the proton-ionizable group’s position in relation to the crown ether cavity. Solid-state structures are presented for two unionized ligands from Series 2, as is a crystal containing two different ionized ligand–Cs+ complexes.

  4. Comprehensive appraisal of {sup 239+240}Pu in soils around Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Litaor, M.I.; Allen, L.; Ellerbroek, D.

    1995-12-01

    Plutonium contamination of soils around Rocky Flats Environmental & Technology Site, near Golden, Colorado, resulted from past outdoor storage practices and subsequent remobilization due to inadequate cleanup practices. Until now human-health risk assessment has not been performed because of a lack of sufficient information regarding the spatial extent of {sup 239+240}Pu in soils. The purpose of this work was to elucidate the extent of plutonium contamination in surface soils, and to assess the uncertainty associated with the spatial distribution of {sup 239+240}Pu around Rocky Flats Environmental & Technology Site.

  5. Future is new focus at energy department`s Rocky Flats facility

    SciTech Connect (OSTI)

    Lobsenz, G.

    1993-11-12

    After several years of intensive effort to address radioactive pollution threatening nearby communities, officials at the Energy Department`s Rocky Flats plant now are turning their attention to the site`s plutonium buildings and finding a cleanup challenge of equally daunting proportions. Containing and mopping up off-site soil and water contamination remains the first priority at the Colorado facility, but site environmental managers say the huge volumes of plutonium and associated radioactive waste stored in Rocky Flats` aging building pose increasingly urgent safety concerns.

  6. Decontamination and decommissioning of building 889 at Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Dorr, K.A.; Hickman, M.E.; Henderson, B.J.; Sexton, R.J.

    1997-09-01

    At the Rocky Flats site, the building 889 decommissioning project was the first large-scale decommissioning project of a radiologically contaminated facility at Rocky Flats. The scope consisted of removal of all equipment and utility systems from the interior of the building, decontamination of interior building surfaces, and the demolition of the facility to ground level. Details of the project management plan, including schedule, engineering, cost, characterization methodologies, decontamination techniques, radiological control requirements, and demolition methods, are provided in this article. 1 fig., 3 tabs.

  7. Evaluation of an emergency response model for the Rocky Flats Plant: Charter

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This Charter provides a basis for a cooperative, interagency effort to evaluate the Terrain-Responsive Atmospheric Code for emergency response and emergency planning for the Rocky Flats Plant. This document establishes the foundation for the project entitled, Evaluation of an Emergency Response Model for the Rocky Flats Plant'' (to be referred to as the Project). This document meets the following objectives: Identify the Project; establish the project management structure, organizational responsibilities, and organizational commitments for reaching the goals of the Project, and identify a process for model revision and revelation for acceptance. 2 figs.

  8. Failure Rates from Certification Testing to UL and IEC Standards for Flat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plate PV Modules | Department of Energy Rates from Certification Testing to UL and IEC Standards for Flat Plate PV Modules Failure Rates from Certification Testing to UL and IEC Standards for Flat Plate PV Modules Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado pvmrw13_ps2_cfv_pratt.pdf (331.77 KB) More Documents & Publications Agenda for the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado Literature Review of the Effects

  9. Stringy stability of charged dilaton black holes with flat event horizon

    SciTech Connect (OSTI)

    Ong, Yen Chin; Chen, Pisin

    2015-01-15

    Electrically charged black holes with flat event horizon in anti-de Sitter space have received much attention due to various applications in Anti-de Sitter/Conformal Field Theory (AdS/CFT) correspondence, from modeling the behavior of quark-gluon plasma to superconductor. Critical to the physics on the dual field theory is the fact that when embedded in string theory, black holes in the bulk may become vulnerable to instability caused by brane pair-production. Since dilation arises naturally in the context of string theory, we study the effect of coupling dilation to Maxwell field on the stability of flat charged AdS black holes.

  10. Caithness Shephards Flat: The Largest Wind Farm Project in the World |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Caithness Shephards Flat: The Largest Wind Farm Project in the World Caithness Shephards Flat: The Largest Wind Farm Project in the World October 12, 2010 - 5:04pm Addthis Andy Oare Andy Oare Former New Media Strategist, Office of Public Affairs What does this project do? Wind farm project is projected to employ over 400 people in construction phase. It is expected to produce 845 megawatt wind-powered electrical generation, or enough wind energy to supply 235,000 homes.

  11. Rocky Flats CAAS System Recalibrated, Retested, and Analyzed to Install in the Criticality Experiments Facility at the Nevada Test Site

    SciTech Connect (OSTI)

    Kim, S; Heinrichs, D; Biswas, D; Huang, S; Dulik, G; Scorby, J; Boussoufi, M; Liu, B; Wilson, R

    2009-05-27

    Neutron detectors and control panels transferred from the Rocky Flats Plant (RFP) were recalibrated and retested for redeployment to the CEF. Testing and calibration were successful with no failure to any equipment. Detector sensitivity was tested at a TRIGA reactor, and the response to thermal neutron flux was satisfactory. MCNP calculated minimum fission yield ({approx} 2 x 10{sup 15} fissions) was applied to determine the thermal flux at selected detector positions at the CEF. Thermal flux levels were greater than 6.39 x 10{sup 6} (n/cm{sup 2}-sec), which was about four orders of magnitude greater than the minimum alarm flux. Calculations of detector survivable distances indicate that, to be out of lethal area, a detector needs to be placed greater than 15 ft away from a maximum credible source. MCNP calculated flux/dose results were independently verified by COG. CAAS calibration and the testing confirmed that the RFP CAAS system is performing its functions as expected. New criteria for the CAAS detector placement and 12-rad zone boundaries at the CEF are established. All of the CAAS related documents and hardware have been transferred from LLNL to NSTec for installation at the CEF high bay areas.

  12. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    SciTech Connect (OSTI)

    Baxter, Larry L.

    2008-06-09

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt

  13. Internal (Annular) and Compressible External (Flat Plate) Turbulent Flow Heat Transfer Correlations.

    SciTech Connect (OSTI)

    Dechant, Lawrence; Smith, Justin

    2016-01-01

    Here we provide a discussion regarding the applicability of a family of traditional heat transfer correlation based models for several (unit level) heat transfer problems associated with flight heat transfer estimates and internal flow heat transfer associated with an experimental simulation design (Dobranich 2014). Variability between semi-empirical free-flight models suggests relative differences for heat transfer coefficients on the order of 10%, while the internal annular flow behavior is larger with differences on the order of 20%. We emphasize that these expressions are strictly valid only for the geometries they have been derived for e.g. the fully developed annular flow or simple external flow problems. Though, the application of flat plate skin friction estimate to cylindrical bodies is a traditional procedure to estimate skin friction and heat transfer, an over-prediction bias is often observed using these approximations for missile type bodies. As a correction for this over-estimate trend, we discuss a simple scaling reduction factor for flat plate turbulent skin friction and heat transfer solutions (correlations) applied to blunt bodies of revolution at zero angle of attack. The method estimates the ratio between axisymmetric and 2-d stagnation point heat transfer skin friction and Stanton number solution expressions for sub-turbulent Reynolds numbers %3C1x10 4 . This factor is assumed to also directly influence the flat plate results applied to the cylindrical portion of the flow and the flat plate correlations are modified by

  14. Rocky Flats Plant site environmental report for 1988, January through December 1988

    SciTech Connect (OSTI)

    Daugherty, N.M.

    1989-05-01

    This report documents the 1988 environmental surveillance program at the Rocky Flats Plant. The report includes an evaluation of plant compliance with all appropriate guides, environmental limits, and standards. Potential radiation dose to the public was calculated from average radionuclide concentrations measured at the plant property boundary and in surrounding communities. 37 refs., 14 figs., 32 tabs.

  15. Radiological/Health physics program assessement at Rocky Flats, the process

    SciTech Connect (OSTI)

    Psomas, P.O.

    1996-06-01

    The Department of Energy, Rocky Flats Office, Safety and Health Group, Health Physics Team (HPT) is responsible for oversight of the Radiation Protection and Health Physics Program (RPHP) of the Integrating Management Contractor (IMC), Kaiser-Hill (K-H) operations at the Rocky Flats Environmental Technology Site (RFETS). As of 1 January 1996 the Rocky Flats Plant employed 300 DOE and 4,300 contractor personnel (K-H and their subcontractors). WSI is a subcontractor and provides plant security. To accomplish the RPHP program oversight HPT personnel developed a systematic methodology for performing a functional RPHP Assessment. The initial process included development of a flow diagram identifying all programmatic elements and assessment criteria documents. Formulation of plans for conducting interviews and performance of assessments constituted the second major effort. The generation of assessment reports was the final step, based on the results of this process. This assessment will be a 6 person-year effort, over the next three years. This process is the most comprehensive assessment of any Radiation Protection and Health Physics (RPHP) Program ever performed at Rocky Flats. The results of these efforts will establish a baseline for future RPHP Program assessments at RFETS. This methodology has been well-received by contractor personnel and creates no Privacy Act violations or other misunderstandings.

  16. Tools for Closure Project and Contract Management: Development of the Rocky Flats Integrated Closure Project Baseline

    SciTech Connect (OSTI)

    Gelles, C. M.; Sheppard, F. R.

    2002-02-26

    This paper details the development of the Rocky Flats Integrated Closure Project Baseline - an innovative project management effort undertaken to ensure proactive management of the Rocky Flats Closure Contract in support of the Department's goal for achieving the safe closure of the Rocky Flats Environmental Technology Site (RFETS) in December 2006. The accelerated closure of RFETS is one of the most prominent projects within the Department of Energy (DOE) Environmental Management program. As the first major former weapons plant to be remediated and closed, it is a first-of-kind effort requiring the resolution of multiple complex technical and institutional challenges. Most significantly, the closure of RFETS is dependent upon the shipment of all special nuclear material and wastes to other DOE sites. The Department is actively working to strengthen project management across programs, and there is increasing external interest in this progress. The development of the Rocky Flats Integrated Closure Project Baseline represents a groundbreaking and cooperative effort to formalize the management of such a complex project across multiple sites and organizations. It is original in both scope and process, however it provides a useful precedent for the other ongoing project management efforts within the Environmental Management program.

  17. EIS-0064: Rocky Flats Plant Site, Jefferson County, Golden, Colorado (see also ERDA-1545-D)

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the site specific environmental impacts of continuing to conduct nuclear weapons production activities at the Rocky Flats Plant; alternatives for the conduct of such activities; and environmental impacts of the U.S. policy to produce nuclear weapons.

  18. Vitrification of plutonium at Rocky Flats the argument for a pilot plant

    SciTech Connect (OSTI)

    Moore, L.

    1996-05-01

    Current plans for stabilizing and storing the plutonium at Rocky Flats Plant fail to put the material in a form suitable for disposition and resistant to proliferation. Vitrification should be considered as an alternate technology. The vitrification should begin with a small-scale pilot plant.

  19. Mineralogic Zonation Within the Tuff Confining Unit, Yucca Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Lance Prothro

    2005-09-01

    Recently acquired mineralogic data from drill hole samples in Yucca Flat show that the tuff confining unit (TCU) can be subdivided into three mineralogic zones based on the relative abundances of primary and secondary mineral assemblages. These zones are (1) an upper zone characterized by the abundance of the zeolite mineral clinoptilolite with lesser amounts of felsic and clay minerals; (2) a middle zone with felsic minerals dominant over clinoptilolite and clay minerals; and (3) a basal argillic zone where clay minerals are dominant over felsic minerals and clinoptilolite. Interpretation of the mineralogic data, along with lithologic, stratigraphic, and geophysical data from approximately 500 drill holes, reveals a three-layer mineralogic model for the TCU that shows all three zones are extensive beneath Yucca Flat. The mineralogic model will be used to subdivide the TCU in the Yucca Flat hydrostratigraphic framework model, resulting in a more accurate and versatile framework model. In addition, the identification of the type, quantity, and distribution of minerals within each TCU layer will permit modelers to better predict the spatial distribution and extent of contaminant transport from underground tests in Yucca Flat, at both the level of the hydrologic source term and the corrective action unit.

  20. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  1. THE LOW-FREQUENCY RADIO CATALOG OF FLAT-SPECTRUM SOURCES

    SciTech Connect (OSTI)

    Massaro, F.; Giroletti, M.; D'Abrusco, R.; Paggi, A.; Cowperthwaite, Philip S.; Masetti, N.; Tosti, G.; Funk, S.

    2014-07-01

    A well known property of the ?-ray sources detected by Cos-B in the 1970s, by the Compton Gamma-Ray Observatory in the 1990s, and recently by the Fermi observations is the presence of radio counterparts, particularly for those associated with extragalactic objects. This observational evidence is the basis of the radio-?-ray connection established for the class of active galactic nuclei known as blazars. In particular, the main spectral property of the radio counterparts associated with ?-ray blazars is that they show a flat spectrum in the GHz frequency range. Our recent analysis dedicated to search blazar-like candidates as potential counterparts for the unidentified ?-ray sources allowed us to extend the radio-?-ray connection in the MHz regime. We also showed that blazars below 1 GHz maintain flat radio spectra. Thus, on the basis of these new results, we assembled a low-frequency radio catalog of flat-spectrum sources built by combining the radio observations of the Westerbork Northern Sky Survey and of the Westerbork in the southern hemisphere catalog with those of the NRAO Very Large Array Sky survey (NVSS). This could be used in the future to search for new, unknown blazar-like counterparts of ?-ray sources. First, we found NVSS counterparts of Westerbork Synthesis Radio Telescope radio sources, and then we selected flat-spectrum radio sources according to a new spectral criterion, specifically defined for radio observations performed below 1 GHz. We also described the main properties of the catalog listing 28,358 radio sources and their logN-logS distributions. Finally, a comparison with the Green Bank 6 cm radio source catalog was performed to investigate the spectral shape of the low-frequency flat-spectrum radio sources at higher frequencies.

  2. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W.; Wender, Irving; Palekar, Vishwesh M.

    1993-01-01

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  3. Comparative study of alkali-vapour cells with alkane-, alkeneand 1-nonadecylbenzene-based antirelaxation wall coatings

    SciTech Connect (OSTI)

    Balabas, M V; Tretiak, O Yu

    2013-12-31

    The dependence of both longitudinal and transverse relaxation times of ground-state magnetic polarisation in alkali atoms on the coating temperature is experimentally studied for the first time in a rubidium-vapour cell with 1-nonadecylbenzene antirelaxation coating of inner walls. The comparison of these times with the relaxation times in a caesium-vapour cell with alkane wall coatings is presented. It is found that within the studied temperature range (294 340K) the transverse relaxation time decreases with increasing temperature of alkene and 1-nonadecylbenzene coatings. For the alkane coating such a dependence was not explicitly found. The longitudinal relaxation time begins to decrease in all cases when passing a certain critical temperature of the coating material. It is found that the unsaturated radical structure of the coating material molecules strongly affects its antirelaxation properties. (optical pumping)

  4. Alkali injection system with controlled CO.sub.2 /O.sub.2 ratios for combustion of coal

    DOE Patents [OSTI]

    Berry, Gregory F. (Naperville, IL)

    1988-01-01

    A high temperature combustion process for an organic fuel containing sulfur n which the nitrogen of air is replaced by carbon dioxide for combination with oxygen with the ratio of CO.sub.2 /O.sub.2 being controlled to generate combustion temperatures above 2000 K. for a gas-gas reaction with SO.sub.2 and an alkali metal compound to produce a sulfate and in which a portion of the carbon-dioxide rich gas is recycled for mixing with oxygen and/or for injection as a cooling gas upstream from heating exchangers to limit fouling of the exchangers, with the remaining carbon-dioxide rich gas being available as a source of CO.sub.2 for oil recovery and other purposes.

  5. Desulfurization of Illinois coals with hydroperoxides of vegetable oils and alkali, Quarterly report, March 1 - May 31, 1996

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, R.; Cheng, J.; Shi, F.; Wang, Y.

    1996-12-31

    Organic sulfur is removed from coals by treatment with aqueous base, air, and vegetable oils with minimal loss of BTU. Such results were revealed during exploratory experiments on an ICCI funded project to remove organic sulfur from Illinois coals with hydroperoxides of vegetable oils. In fact, prewashing IBC-108 coal with dilute alkali prior to treating with linseed oil and air results in 26% removal of sulfur. This new method is being investigated by treating coals with alkali, impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. During the first quarter the selection of base fro pretreatment and extraction was completed. NaOH is better than NH{sub 4}OH for the pretreatment and Na{sub 2}CO{sub 3} is better than NaOH for the oil extraction. During the second quarter the effectiveness of linseed oil and NaOH for sulfur removal from IBC-108 coal was further tested by pretreating the coal with two base concentrations at four different times followed by treatment with linseed oil at 125{degrees}C for three different times and finally washing with 5% Na{sub 2}CO{sub 3} and methanol. During this third quarter more experimental parameters were systematically varied in order to study the effectiveness of linseed oil and NaOH for sulfur removal from IBC- 108 coal.

  6. Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals

    SciTech Connect (OSTI)

    Nabeel, A.; Khan, T.A.; Sharma, D.K.

    2009-07-01

    The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

  7. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, R.C.; Quigley, G.P.

    1996-12-17

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

  8. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, Robert C.; Quigley, Gerard P.

    1996-01-01

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source. A contamination-free VUV light source having a 225 cm.sup.2 emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm.sup.2 at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing.

  9. The marriage of RCRA and CERCLA at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Shelton, D.C.; Brooks, L.M.

    1998-11-01

    A key goal of the Rocky Flats Cleanup Agreement (RFCA) signed in July of 1996 was to provide a seamless marriage of the Resource Conservation and Recovery Act (RCRA) (and other media specific programs) and the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and the implementing agencies of each. This paper examines the two years since the signing of RFCA and identifies the successes, failures, and stresses of the marriage. RFCA has provided an excellent vehicle for regulatory and substantive progress at the Department of Energy`s Rocky Flats facility. The key for a fully successful marriage is to build on the accomplishments to date and to continually improve the internal and external systems and relationships. To date, the parties can be proud of both the substantial accomplishment of substantive environmental work and the regulatory systems that have enabled the work.

  10. Flat panel display using Ti-Cr-Al-O thin film

    DOE Patents [OSTI]

    Jankowski, Alan F.; Schmid, Anthony P.

    2002-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  11. Effects of self-assembled monolayer and PFPE lubricant on wear characteristics of flat silicon tips.

    SciTech Connect (OSTI)

    Kim, H. J.; Jang, C. E.; Kim, D. E.; Kim, Y. K.; Choa, S. H.; Hong, S.; Materials Science Division; Yonsei Univ.; Samsung Adv. Inst. Science and Technology; Seoul National Univ. of Technology

    2009-01-01

    The effects of self-assembled monolayer (SAM) and perfluoropolyether (PFPE) lubricant on the wear characteristics of flat silicon tips were investigated. The wear test consisted of sliding the silicon tips fabricated on a flat silicon specimen against SAM and PFPE (Z-tetraol) coated silicon (100) wafer. The tips were slid at a low speed for about 15 km under an applied load of 39.2 {micro}N. The wear volume of the tip was obtained by measuring the tip profile using an Atomic Force Microscope (AFM). It was found that the coatings were effective in reducing the wear of the tips by an order of magnitude from 10{sup -6} to 10{sup -7}.

  12. Constraining the neutrino emission of gravitationally lensed Flat-Spectrum Radio Quasars with ANTARES data

    SciTech Connect (OSTI)

    Adrián-Martínez, S.; Ardid, M.; Bou-Cabo, M.; André, M.; Anton, G.; Aubert, J.-J.; Bertin, V.; Brunner, J.; Busto, J.; Basa, S.; Biagi, S.; Capone, A.; Caramete, L.; and others

    2014-11-01

    This paper proposes to exploit gravitational lensing effects to improve the sensitivity of neutrino telescopes to the intrinsic neutrino emission of distant blazar populations. This strategy is illustrated with a search for cosmic neutrinos in the direction of four distant and gravitationally lensed Flat-Spectrum Radio Quasars. The magnification factor is estimated for each system assuming a singular isothermal profile for the lens. Based on data collected from 2007 to 2012 by the ANTARES neutrino telescope, the strongest constraint is obtained from the lensed quasar B0218+357, providing a limit on the total neutrino luminosity of this source of 1.08× 10{sup 46} erg s{sup -1}. This limit is about one order of magnitude lower than those previously obtained in the ANTARES standard point source searches with non-lensed Flat-Spectrum Radio Quasars.

  13. Thermodynamics of asymptotically flat charged black holes in third order Lovelock gravity

    SciTech Connect (OSTI)

    Dehghani, M.H.; Shamirzaie, M.

    2005-12-15

    We present a new class of asymptotically flat charge static solutions in third order Lovelock gravity. These solutions present black hole solutions with two inner and outer event horizons, extreme black holes, or naked singularities provided the parameters of the solutions are chosen suitable. We find that the uncharged asymptotically flat solutions can present black holes with two inner and outer horizons. This kind of solution does not exist in Einstein or Gauss-Bonnet gravity, and it is a special effect in third order Lovelock gravity. We compute temperature, entropy, charge, electric potential, and mass of the black hole solutions, and find that these quantities satisfy the first law of thermodynamics. We also perform a stability analysis by computing the determinant of the Hessian matrix of the mass with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, and show that there exists only an intermediate stable phase.

  14. Selected stratigraphic data for drill holes located in Frenchman Flat, Nevada Test Site. Rev. 1

    SciTech Connect (OSTI)

    Drellack, S.L. Jr.

    1997-02-01

    Stratigraphic data are presented in tabular form for 72 holes drilled in Frenchman Flat, Nevada Test Site, between 1950 and 1993. Three pairs of data presentations are included for each hole: depth to formation tops, formation thicknesses, and formation elevations are presented in both field (English) and metric units. Also included for each hole, where available, are various construction data (hole depth, hole diameter, surface location coordinates) and certain information of hydrogeologic significance (depth to water level, top of zeolitization). The event name is given for holes associated with a particular nuclear test. An extensive set of footnotes is included, which indicates data sources and provides other information. The body of the report describes the stratigraphic setting of Frenchman Flat, gives drill-hole naming conventions and database terminology, and provides other background and reference material.

  15. Rocky Flats 1990--91 winter validation tracer study: Volume 1

    SciTech Connect (OSTI)

    Brown, K.J.

    1991-10-01

    During the winter of 1990--91, North American Weather Consultants (NAWC) and its subcontractor, ABB Environmental Services (ABBES), conducted a Winter Validation Study (WVS) for EG&G Rocky Flats involving 12 separate tracer experiments conducted between February 3 and February 19, 1991. Six experiments were conducted during nighttime hours and four experiments were conducted during daytime hours. In addition, there was one day/night and one night/day transitional experiment conducted. The primary purpose of the WVS was to gather data to further the approval process for the Terrain Responsive Atmospheric Code (TRAC). TRAC is an atmospheric dispersion model developed and operated at the Department of Energy`s (DOE`s) Rocky Flats Plant (RFP) north of Denver, Colorado. A secondary objective was to gather data that will serve to validate the TRAC model physics.

  16. Rocky Flats Plant fluidized-bed incinerator. Engineering design and reference manual

    SciTech Connect (OSTI)

    Meile, L.J.

    1982-11-05

    The information in this manual is being presented to complete the documentation of the fluidized-bed incineration (FBI) process development at the Rocky Flats Plant. The information pertains to the 82-kg/hour demonstration unit at the Rocky Flats Plant. This document continues the presentation of design reference material in the aeas of equipment drawings, space requirements, and unit costs. In addition, appendices contain an operating procedure and an operational safety analysis of the process. The cost figures presented are based on 1978 dollars and have not been converted to a current dollar value. Also, the cost of modifications are not included, since they would be insignificant if they were incorporated into a new installation.

  17. Waste drum gas generation sampling program at Rocky Flats during FY 1989

    SciTech Connect (OSTI)

    Roggenthen, D.K.; Nieweg, R.G.

    1990-10-01

    Rocky Flats Plant transuranic waste drums were sampled for gas composition. Glass, metal, graphite, and solidified inorganic sludge transuranic waste forms were sampled. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values were calculated for the waste drums. G(H{sub 2}) was below 0.6 and G(Total) was below 1.3 for all waste forms discussed in this report. 5 refs., 3 figs., 3 tabs.

  18. Proceedings of the flat-plate solar array project research forum on photovoltaic metallization systems

    SciTech Connect (OSTI)

    1983-11-15

    A Photovoltaic Metallization Research Forum, under the sponsorship of the Jet Propulsion Laboratory's Flat-Plate Solar Array Project and the US Department of Energy, was held March 16-18, 1983 at Pine Mountain, Georgia. The Forum consisted of five sessions, covering (1) the current status of metallization systems, (2) system design, (3) thick-film metallization, (4) advanced techniques and (5) future metallization challenges. Twenty-three papers were presented.

  19. RFLMA Contact Record 2015-01 ROCKY FLATS SITE REGULATORY CONTACT RECORD 2015-01

    Office of Legacy Management (LM)

    5-01 ROCKY FLATS SITE REGULATORY CONTACT RECORD 2015-01 Purpose: Reportable condition for uranium 12-month rolling average at Point of Compliance WALPOC (this Contact Record supersedes RFLMA CR 2014-10) Contact Record Approval Date: January 14, 2015 Site Contact(s)/Affiliation(s): Scott Surovchak, U.S. Department of Energy (DOE); George Squibb, Linda Kaiser, David Ward, Stoller Newport News Nuclear, Inc., (SN3), a wholly owned subsidiary of Huntington Ingalls Industries, Inc. Regulatory

  20. Tomographic gamma scanning of uranium-contaminated waste at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D.J.; Betts, S.E.; Prettyman, T.H.; Rael, C.D.

    1998-12-31

    A tomographic gamma-ray scanning (TGS) instrument was deployed at Rocky Flats Environmental Technology Site (RFETS) to assist with the deactivation of Building 886. Many 208-L drums containing waste contaminated with highly enriched uranium were measured in order to certify these sites for shipment and disposal. This project marks a successful cooperation between RFETS and Los Alamos National Laboratory and is the first major field experience using TGS technology to assay uranium.

  1. Analysis of offsite emergency planning zones for the Rocky Flats Plant

    SciTech Connect (OSTI)

    Hodgin, C.R.; Daugherty, N.M.; Smith, M.L. . Rocky Flats Plant); Bunch, D.; Toresdahl, J.; Verholek, M.G. )

    1991-01-01

    The objective of this report is to fully document technical data and information that have been developed to support offsite emergency planning by the State of Colorado for potential accidents at the Rocky Flats Plant. Specifically, this report documents information and data that will assist the State of Colorado in upgrading its radiological emergency planning zones for Rocky Flats Plant. The Colorado Division of Disaster Emergency Services (DODES) and the Colorado Department of Health (CDH) represent the primary audience for this report. The secondary audience for this document includes the Rocky Flats Plant; federal, State, and local governmental agencies; the scientific community; and the interested public. Because the primary audience has a pre-existing background on the subject, this report assumes some exposure to emergency planning, health physics, and dispersion modeling on the part of the reader. The authors have limited their assumptions of background knowledge as much as possible, recognizing that the topics addressed in the report may be new to some secondary audiences.

  2. Environment, safety and Health Progress Assessment of the Rocky Flats Plant

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    This report documents the result of the US Department of Energy`s (DOE) Environment, Safety and Health (ES&H) Progress Assessment of the DOE Rocky Flats Plant (RFP) in Golden, Colorado. The assessment, which was conducted during the period of May 17 through May 28, 1993, included a selective review of the ES&H management systems and programs of the responsible DOE Headquarters Program Offices (Defense Programs (DP) and Environmental Restoration and Waste Management (EM)), the DOE Rocky Flats Office (RFO), and the site contractor, EG&G Rocky Flats, Inc. (EG&G). Despite the near constant state of flux under which RFP has been required to operate, the Progress Assessment Team has concluded that significant progress has been made in correcting the deficiencies identified in the 1989 Assessment and in responding responsibly to regulations, and DOE directives and guidance that have been issued since that time. The Team concluded that the improvements have been concentrated in the activities associated with plutonium facilities and in regulatory driven programs. Much remains to be done with respect to implementing on a sitewide basis those management systems that anchor an organization`s pursuit of continuous ES&H improvement. Furthermore the Team concluded that the pace of improvement has been constrained by a combination of factors that have limited the site`s ability to manage change in the pursuit of sitewide ES&H excellence.

  3. Preparation of atomically flat rutile TiO2(001) surfaces for oxide film growth

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yang; Lee, Shinbuhm; Vilmercati, P.; Lee, Ho Nyung; Weitering, Hanno; Snijders, Paul C.

    2016-01-01

    The availability of low-index rutile TiO2 single crystal substrates with atomically flat surfaces is essential for enabling epitaxialgrowth of rutile transition metal oxide films. The high surface energy of the rutile (001) surface often leads to surface faceting, which precludes the sputter and annealing treatment commonly used for the preparation of clean and atomically flat TiO2(110) substrate surfaces. In this work, we reveal that stable and atomically flat rutile TiO2(001) surfaces can be prepared with an atomically ordered reconstructedsurface already during a furnace annealing treatment in air. We tentatively ascribe this result to the decrease in surface energy associated withmore » the surface reconstruction, which removes the driving force for faceting. Despite the narrow temperature window where this morphology can initially be formed, we demonstrate that it persists in homoepitaxialgrowth of TiO2(001) thin films. The stabilization of surface reconstructions that prevent faceting of high-surface-energy crystal faces may offer a promising avenue towards the realization of a wider range of high quality epitaxial transition metal oxide heterostructures.« less

  4. Annual collectible energy of a two-axis tracking flat-plate solar collector

    SciTech Connect (OSTI)

    Attalage, R.A.; Reddy, T.A. )

    1992-01-01

    A correlation for annual collectible energy of a two-axis tracking flat-plate solar collector has been developed using simulated results based on typical meteorological year (TMY) data for 26 US locations. A preliminary validation of this correlation has been carried out with data from four Australian locations. With the advent of increasing interest in photovoltaic systems, there are a number of advantages of using a two-axis flat-plate collector. Since the tracking system is generally much cheaper than the collector panel, such a mode permits the incident solar radiation to be collected more efficiently. Incidence angle effects are minimized and, moreover, contrary to concentrating collectors, such a mode enables both the diffuse and beam components of solar radiation to be collected. In tropical locations where the diffuse fraction is generally high, this may be a great advantage. The objective of this study was to develop a correlation for the annual collectible energy of a two-axis tracking flat-plate collector.

  5. Analysis of Ground-Water Levels and Associated Trends in Yucca Flat, Nevada Test Site, Nye County, Nevada, 1951-2003

    SciTech Connect (OSTI)

    J.M. Fenelon

    2005-10-05

    Almost 4,000 water-level measurements in 216 wells in the Yucca Flat area from 1951 to 2003 were quality assured and analyzed. An interpretative database was developed that describes water-level conditions for each water level measured in Yucca Flat. Multiple attributes were assigned to each water-level measurement in the database to describe the hydrologic conditions at the time of measurement. General quality, temporal variability, regional significance, and hydrologic conditions are attributed for each water-level measurement. The database also includes narratives that discuss the water-level history of each well. Water levels in 34 wells were analyzed for variability and for statistically significant trends. An attempt was made to identify the cause of many of the water-level fluctuations or trends. Potential causes include equilibration following well construction or development, pumping in the monitoring well, withdrawals from a nearby supply well, recharge from precipitation, earthquakes, underground nuclear tests, land subsidence, barometric pressure, and Earth tides. Some of the naturally occurring fluctuations in water levels may result from variations in recharge. The magnitude of the overall water-level change for these fluctuations generally is less than 2 feet. Long-term steady-state hydrographs for most of the wells open to carbonate rock have a very similar pattern. Carbonate-rock wells without the characteristic pattern are directly west of the Yucca and Topgallant faults in the southwestern part of Yucca Flat. Long-term steady-state hydrographs from wells open to volcanic tuffs or the Eleana confining unit have a distinctly different pattern from the general water-level pattern of the carbonate-rock aquifers. Anthropogenic water-level fluctuations were caused primarily by water withdrawals and nuclear testing. Nuclear tests affected water levels in many wells. Trends in these wells are attributed to test-cavity infilling or the effects of

  6. Finding of no significant impact. Consolidation and interim storage of special nuclear material at Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    1995-06-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA -- 1060, for the consolidation, processing, and interim storage of Category I and II special nuclear material (SNM) in Building 371 at the Rocky Flats Environmental Technology Site (hereinafter referred to as Rocky Flats or Site), Golden, Colorado. The scope of the EA included alternatives for interim storage including the no action alternative, the construction of a new facility for interim storage at Rocky Flats, and shipment to other DOE facilities for interim storage.

  7. Analysis of offsite Emergency Planning Zones (EPZs) for the Rocky Flats Plant. Phase 3, Sitewide spectrum-of-accidents and bounding EPZ analysis

    SciTech Connect (OSTI)

    Petrocchi, A.J.; Zimmerman, G.A.

    1994-03-14

    During Phase 3 of the EPZ project, a sitewide analysis will be performed applying a spectrum-of-accidents approach to both radiological and nonradiological hazardous materials release scenarios. This analysis will include the MCA but will be wider in scope and will produce options for the State of Colorado for establishing a bounding EPZ that is intended to more comprehensively update the interim, preliminary EPZ developed in Phase 2. EG&G will propose use of a hazards assessment methodology that is consistent with the DOE Emergency Management Guide for Hazards Assessments and other methods required by DOE orders. This will include hazards, accident, safety, and risk analyses. Using this methodology, EG&G will develop technical analyses for a spectrum of accidents. The analyses will show the potential effects from the spectrum of accidents on the offsite population together with identification of offsite vulnerable zones and areas of concern. These analyses will incorporate state-of-the-art technology for accident analysis, atmospheric plume dispersion modeling, consequence analysis, and the application of these evaluations to the general public population at risk. The analyses will treat both radiological and nonradiological hazardous materials and mixtures of both released accidentally to the atmosphere. DOE/RFO will submit these results to the State of Colorado for the State`s use in determining offsite emergency planning zones for the Rocky Flats Plant. In addition, the results will be used for internal Rocky Flats Plant emergency planning.

  8. Evaluation of beryllium exposure assessment and control programs at AWE, Cardiff Facility, Rocky Flats Plant, Oak Ridge Y-12 Plant and Lawrence Livermore National Laboratory. Phase 1

    SciTech Connect (OSTI)

    Johnson, J.S.; Foote, K.L.; Slawski, J.W.; Cogbill, G.

    1995-04-28

    Site visits were made to DOE beryllium handling facilities at the Rocky Flats Plant; Oak Ridge Y-12 Plant, LLNL; as well as to the AWE Cardiff Facility. Available historical data from each facility describing its beryllium control program were obtained and summarized in this report. The AWE Cardiff Facility computerized Be personal and area air-sampling database was obtained and a preliminary evaluation was conducted. Further validation and documentation of this database will be very useful in estimating worker Be. exposure as well as in identifying the source potential for a variety of Be fabrication activities. Although all of the Be control programs recognized the toxicity of Be and its compounds, their established control procedures differed significantly. The Cardiff Facility, which was designed for only Be work, implemented a very strict Be control program that has essentially remained unchanged, even to today. LLNL and the Oak Ridge Y-12 Plant also implemented a strict Be control program, but personal sampling was not used until the mid 1980s to evaluate worker exposure. The Rocky Flats plant implemented significantly less controls on beryllium processing than the three previous facilities. In addition, records were less available, management and industrial hygiene staff turned over regularly, and less control was evident from a management perspective.

  9. Completion Report for the Well ER-6-2 Site Corrective Action Unit 97: Yucca Flat - Climax Mine

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2008-03-01

    Well ER-6-2 and its satellite hole, Well ER-6-2 No.1, were drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. Well ER-6-2 was drilled in two stages in 1993 and 1994; the satellite hole, Well ER-6-2 No.1 was drilled nearby in 1993 but was abandoned. The wells were drilled as part of a hydrogeologic investigation program for the Yucca Flat-Climax Mine Corrective Action Unit Number 97, in the northeastern portion of the Nevada Test Site. The wells are located in Yucca Flat, within Area 6 of the Nevada Test Site. The wells provided information regarding the radiological and hydrogeological environment in a potentially down-gradient position from tests conducted in northern and central Yucca Flat. Construction of Well ER-6-2 began with a 1.2-meter-diameter surface conductor hole, which was drilled and cased off to a depth of 30.8 meters below the surface. A 50.8-centimeter diameter surface hole was then rotary drilled to the depth of 578.5 meters and cased off to the depth of 530.4 meters. The hole diameter was then reduced to 27.0 centimeters, and the borehole was advanced to a temporary depth of 611.4 meters. The borehole was conventionally cored to a total depth of 1,045 meters with a diameter of 14.0 centimeters. Borehole sloughing required cementing and re-drilling of several zones. The open-hole completion accesses the lower carbonate aquifer, the CP thrust fault, and the upper clastic confining unit. A fluid level depth of 543.2 meters was most recently measured in the open borehole in September 2007. No radionuclides were encountered during drilling. The satellite hole Well ER-6-2 No.1 was drilled approximately 15.2 meters north of Well ER-6-2 on the same drill pad. This was planned to be used as an observation well during future hydrologic testing at Well ER-6-2; however, the satellite hole was abandoned at

  10. Detailed Geophysical Fault Characterization in Yucca Flat, Nevada Test Site, Nevada

    SciTech Connect (OSTI)

    Theodore H. Asch; Donald Sweetkind; Bethany L. Burton; Erin L. Wallin

    2009-02-10

    Yucca Flat is a topographic and structural basin in the northeastern part of the Nevada Test Site (NTS) in Nye County, Nevada. Between the years 1951 and 1992, 659 underground nuclear tests took place in Yucca Flat; most were conducted in large, vertical excavations that penetrated alluvium and the underlying Cenozoic volcanic rocks. Radioactive and other potential chemical contaminants at the NTS are the subject of a long-term program of investigation and remediation by the U.S. Department of Energy (DOE), National Nuclear Security Administration, Nevada Site Office, under its Environmental Restoration Program. As part of the program, the DOE seeks to assess the extent of contamination and to evaluate the potential risks to humans and the environment from byproducts of weapons testing. To accomplish this objective, the DOE Environmental Restoration Program is constructing and calibrating a ground-water flow model to predict hydrologic flow in Yucca Flat as part of an effort to quantify the subsurface hydrology of the Nevada Test Site. A necessary part of calibrating and evaluating a model of the flow system is an understanding of the location and characteristics of faults that may influence ground-water flow. In addition, knowledge of fault-zone architecture and physical properties is a fundamental component of the containment of the contamination from underground nuclear tests, should such testing ever resume at the Nevada Test Site. The goal of the present investigation is to develop a detailed understanding of the geometry and physical properties of fault zones in Yucca Flat. This study was designed to investigate faults in greater detail and to characterize fault geometry, the presence of fault splays, and the fault-zone width. Integrated geological and geophysical studies have been designed and implemented to work toward this goal. This report describes the geophysical surveys conducted near two drill holes in Yucca Flat, the data analyses performed, and the

  11. Riparian and Upland Restoration at the U.S. Department of Energy Rocky Flats, Colorado, Site - 12360

    SciTech Connect (OSTI)

    Nelson, Jody K.

    2012-07-01

    Remedial investigation and cleanup at the Rocky Flats, Colorado, Site was completed in 2005. Uplands, riparian, and wetland habitat were disturbed during cleanup and closure activities and required extensive revegetation. Unavoidable disturbances to habitat of the Preble's meadow jumping mouse (a federally listed species) and wetlands required consultation with regulatory agencies and mitigation. Mitigation wetlands were constructed in two drainages, and a third developed naturally where a soil borrow area intercepted the groundwater table. During the 50-plus years of site operations, 12 ponds were constructed in three drainages to manage and retain runoff and sewage treatment plant discharges prior to release off site. A batch-release protocol has been used for the past several decades at the terminal ponds, which has affected the riparian communities downstream. To return the hydrologic regime to a more natural flow-through system similar to the pre-industrial-use conditions, seven interior dams (of 12) have been breached, and the remaining five dams are scheduled for breaching between 2011 and 2020. At the breached dams, the former open water areas have transformed to emergent wetlands, and the stream reaches have returned to a flow-through system. Riparian and wetland vegetation has established very well. The valves of the terminal ponds were opened in fall 2011 to begin flow-through operations and provide water to the downstream plant communities while allowing reestablishment of vegetation in the former pond bottoms prior to breaching. A number of challenges and issues were addressed during the revegetation effort. These included reaching an agreement on revegetation goals, addressing poor substrate quality and soil compaction problems, using soil amendments and topsoil, selecting seeds, determining the timing and location of revegetation projects relative to continuing closure activities, weed control, erosion control, revegetation project field oversight

  12. [100] or [110] aligned, semiconductor-based, large-area, flexible, electronic devices

    SciTech Connect (OSTI)

    Goyal, Amit

    2015-03-24

    Novel articles and methods to fabricate the same resulting in flexible, large-area, [100] or [110] textured, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  13. 300 Area - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    300 Area 324 Building 325 Building 400 AreaFast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim ...

  14. 200 Area - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    300 Area 324 Building 325 Building 400 AreaFast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim ...

  15. 700 Area - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    300 Area 324 Building 325 Building 400 AreaFast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim ...

  16. Sweet Surface Area

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sweet Surface Area Sweet Surface Area Create a delicious root beer float and learn sophisticated science concepts at the same time. Sweet Surface Area Science is all around us, so ...

  17. EIS-0277: Management of Certain Plutonium Residues and Scrub Alloy Stored at the Rocky Flats Environmental Technology Site

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential alternatives and impacts associated with a proposal to process certain plutonium residues and all of the scrub alloy currently stored at Rocky Flats. While ongoing...

  18. Strategic Focus Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategic Focus Areas Lockheed Martin on behalf of Sandia National Laboratories will consider grant requests that best support the Corporation's strategic focus areas and reflect ...

  19. AREA 5 RWMS CLOSURE

    National Nuclear Security Administration (NNSA)

    153 CLOSURE STRATEGY NEVADA TEST SITE AREA 5 RADIOACTIVE WASTE MANAGEMENT SITE Revision 0 ... Closure Strategy Nevada Test Site Area 5 Radioactive Waste Management ...

  20. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-12-01

    An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.