National Library of Energy BETA

Sample records for alcohol ethanol blended

  1. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

    Broader source: Energy.gov [DOE]

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

  2. Vehicle Technologies Office: Intermediate Ethanol Blends

    Broader source: Energy.gov [DOE]

    Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

  3. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

  4. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  5. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  6. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Environmental Management (EM)

    Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of...

  7. Key Benefits in Using Ethanol-Diesel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benefits in Using Ethanol-Diesel Blends Key Benefits in Using Ethanol-Diesel Blends Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER...

  8. Evaluation of Ethanol Blends for PHEVs using Simulation andEngine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop 2011 DOE Hydrogen and Fuel Cells...

  9. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Downsized SI Engines Using Alcohol DI for Knock Avoidance Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and...

  10. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Environmental Management (EM)

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol...

  11. Mid-Level Ethanol Blends | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy6-09.doc Microsoft WordBlends Mid-Level Ethanol Blends

  12. Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    1 Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung-ho Ahn, Anna G. Stefanopoulou, and Mrdjan Jankovic Abstract--Ethanol is being increasingly flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up

  13. Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    -source simulations imply that high-ethanol blends (e.g., E85) pose a lower risk of benzene reaching a receptor via gasoline, 15 years for E10, 9 years for E50, and 3 years for E85), indicating greater natural attenuationModeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels

  14. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  15. Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content on the lifespan and maximum length of benzene plumes Diego E. Gomez1 and Pedro 10 March 2009. [1] A numerical model was used to evaluate how the concentration of ethanol

  16. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Book)

    SciTech Connect (OSTI)

    Moriarty, K.

    2013-09-01

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  17. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends

    SciTech Connect (OSTI)

    2013-09-17

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  18. The Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    none,

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

  19. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  20. Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels

    Broader source: Energy.gov [DOE]

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

  1. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  2. Knock limits in spark ignited direct injected engines using gasoline/ethanol blends

    E-Print Network [OSTI]

    Kasseris, Emmanuel P

    2011-01-01

    Direct Fuel Injection (DI) extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in DI is therefore ...

  3. Low and intermediate temperature oxidation of ethanol and ethanol-PRF blends: An experimental and modeling study

    SciTech Connect (OSTI)

    Haas, Francis M.; Chaos, Marcos; Dryer, Frederick L.

    2009-12-15

    In this brief communication, we present new experimental species profile measurements for the low and intermediate temperature oxidation of ethanol under knock-prone conditions. These experiments show that ethanol exhibits no global low temperature reactivity at these conditions, although we note the heterogeneous decomposition of ethanol to ethylene and water. Similar behavior is reported for an E85 blend in n-heptane. Kinetic modeling results are presented to complement these experiments and elucidate the interaction of ethanol and primary reference fuels undergoing cooxidation. (author)

  4. Numerical Model Investigation for Potential Methane Explosion and Benzene Vapor Intrusion Associated with High-Ethanol Blend

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Associated with High-Ethanol Blend Releases Jie Ma, Hong Luo, George E. DeVaull,§ William G. Rixey, and Pedro ABSTRACT: Ethanol-blended fuel releases usually stimulate methanogenesis in the subsurface, which could conditions exist. Ethanol- derived methane may also increase the vapor intrusion potential of toxic fuel

  5. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  6. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  7. Effects of Mid-Level Ethanol Blends on Conventional Vehicle Emissions

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Huff, S.; Thomas, J.; Orban, J.; Cooper, C.

    2010-06-01

    Tests were conducted in 2008 on 16 late-model conventional vehicles (1999-2007) to determine short-term effects of mid-level ethanol blends on performance and emissions. Vehicle odometer readings ranged from 10,000 to 100,000 miles, and all vehicles conformed to federal emissions requirements for their federal certification level. The LA92 drive cycle, also known as the Unified Cycle, was used for testing because it more accurately represents real-world acceleration rates and speeds than the Federal Test Procedure. Test fuels were splash-blends of up to 20 volume percent ethanol with federal certification gasoline. Both regulated and unregulated air-toxic emissions were measured. For the 16-vehicle fleet, increasing ethanol content resulted in reductions in average composite emissions of both nonmethane hydrocarbons and carbon monoxide and increases in average emissions of ethanol and aldehydes.

  8. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  9. Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines*

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung as an alternative fuel to petroleum-based gasoline and diesel derivatives. Currently available flexible fuel the closed-loop air-to-fuel ratio (AFR) control which maintains automatically operation around

  10. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  11. An enzyme-amplified microtiter plate assay for ethanol: Its application to the detection of peanut ethanol and alcohol dehydrogenase

    SciTech Connect (OSTI)

    Chung, S.Y.; Vercellotti, J.R. [USDA-ARS-SRRC, New Orleans, LA (United States); Sanders, T.H. [USDA-ARS-NCSU, Raleigh, NC (United States)

    1995-12-01

    A calorimetric microliter plate assay for ethanol amplified by aldehyde dehydrogenase (ALDH) was developed. In the assay ethanol from a sample took part in a chain-reaction catalyzed by alcohol dehydrogenase (ADH) and amplified by ALDH in the presence of NAD{sup +}, diaphorase, and p-ibdonitrotetrazolium-violet (INT-violet)(a precursor of red product). The resultant reaction gave a red color, the intensity of which was proportional to the amount of ethanol present. Using the technique, the content of activity from peanuts of differing maturity and curing stages were determined respectively. Data showed that immature peanuts had a higher level of ethanol and a lower ADH activity than mature peanuts, and that the level of ethanol and ADH activity decreased with the curing time. This indicates that peanut maturity and curing have an effect on ethanol. Also, this implies that other peanut volatiles could be affected in the same way as ethanol, a major volatile in peanuts.

  12. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

    2009-02-01

    Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

  13. Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends

    E-Print Network [OSTI]

    Kar, Kenneth

    The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

  14. Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends

    E-Print Network [OSTI]

    Dimou, Iason

    The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

  15. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  16. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingREnergyDepartment of Energy ImprovingCooling

  17. Correct quantitative determination of ethanol and volatile compounds in alcohol products

    E-Print Network [OSTI]

    Charapitsa, Siarhei; Sytova, Svetlana; Yakuba, Yurii

    2014-01-01

    Determination of the volume content of ethanol in the alcohol products in practice is usually determined by pycnometry, electronic densimetry, or densimetry using a hydrostatic balance in accordance with Commission Regulation No 2870/2000. However, these methods determine directly only density of the tested liquid sample and does not take into account the effects of other volatile components such as aldehydes, esters and higher alcohols. So they are appropriate only for binary water-ethanol solutions in accordance with international table adopted by the International Legal Metrology Organization in its Recommendation No 22. Availability notable concentrations of the higher alcohols and ethers in different alcohol-based products, e. g. in whisky, cognac, brandy, wine as well as in waste alcohol and alcohol beverage production, leads to the significant contribution of these compounds in the value of the density of tested alcohol-containing sample. As a result, determination of the volume of ethanol content for ...

  18. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  19. Technical Issues Associated With the Use of Intermediate Ethanol Blends (>E10) in the U.S. Legacy Fleet

    SciTech Connect (OSTI)

    Rich, Bechtold; Thomas, John F; Huff, Shean P; Szybist, James P; West, Brian H; Theiss, Timothy J; Timbario, Tom; Goodman, Marc

    2007-08-01

    The Oak Ridge National Laboratory (ORNL) supports the U.S. Department of Energy (DOE) in assessing the impact of using intermediate ethanol blends (E10 to E30) in the legacy fleet of vehicles in the U.S. fleet. The purpose of this report is to: (1) identify the issues associated with intermediate ethanol blends with an emphasis on the end-use or vehicle impacts of increased ethanol levels; (2) assess the likely severity of the issues and whether they will become more severe with higher ethanol blend levels, or identify where the issue is most severe; (3) identify where gaps in knowledge exist and what might be required to fill those knowledge gaps; and (4) compile a current and complete bibliography of key references on intermediate ethanol blends. This effort is chiefly a critical review and assessment of available studies. Subject matter experts (authors and selected expert contacts) were consulted to help with interpretation and assessment. The scope of this report is limited to technical issues. Additional issues associated with consumer, vehicle manufacturer, and regulatory acceptance of ethanol blends greater than E10 are not considered. The key findings from this study are given.

  20. Investigation of critical equivalence ratio and chemical speciation in flames of ethylbenzene-ethanol blends

    SciTech Connect (OSTI)

    Therrien, Richard J.; Ergut, Ali; Levendis, Yiannis A.; Richter, Henning; Howard, Jack B.; Carlson, Joel B.

    2010-02-15

    This work investigates five different one-dimensional, laminar, atmospheric pressure, premixed ethanol/ethylbenzene flames (0%, 25%, 50%, 75% and 90% ethanol by weight) at their soot onset threshold ({phi}{sub critical}). Liquid ethanol/ethylbenzene mixtures were pre-vaporized in nitrogen, blended with an oxygen-nitrogen mixture and, upon ignition, burned in premixed one-dimensional flames at atmospheric pressure. The flames were controlled so that each was at its visual soot onset threshold, and all had similar temperature profiles (determined by thermocouples). Fixed gases, light volatile hydrocarbons, polycyclic aromatic hydrocarbons (PAH), and oxygenated aromatic hydrocarbons were directly sampled at three locations in each flame. The experimental results were compared with a detailed kinetic model, and the modeling results were used to perform a reaction flux analysis of key species. The critical equivalence ratio was observed to increase in a parabolic fashion as ethanol concentration increased in the fuel mixture. The experimental results showed increasing trends of methane, ethane, and ethylene with increasing concentrations of ethanol in the flames. Carbon monoxide was also seen to increase significantly with the increase of ethanol in the flame, which removes carbon from the PAH and soot formation pathways. The PAH and oxygenated aromatic hydrocarbon values were very similar in the 0%, 25% and 50% ethanol flames, but significantly lower in the 75% and 90% ethanol flames. These results were in general agreement with the model and were reflected by the model soot predictions. The model predicted similar soot profiles for the 0%, 25% and 50% ethanol flames, however it predicted significantly lower values in the 75% and 90% ethanol flames. The reaction flux analysis revealed benzyl to be a major contributor to single and double ring aromatics (i.e., benzene and naphthalene), which was identified in a similar role in nearly sooting or highly sooting ethylbenzene flames. The presence of this radical was significantly reduced as ethanol concentration was increased in the flames, and this effect in combination with the lower carbon to oxygen ratios and the enhanced formation of carbon monoxide, are likely what allowed higher equivalence ratios to be reached without forming soot. (author)

  1. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  2. Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth

    Broader source: Energy.gov [DOE]

    Discusses results of cold- and hot-start transient tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol)

  3. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos (Oak Ridge, TN); Graves, Ronald Lee (Knoxville, TN); Storey, John Morse Elliot (Oak Ridge, TN); Lewis, Sr., Samuel Arthur (Andersonville, TN); Sluder, Charles Scott (Knoxville, TN); Thomas, John Foster (Powell, TN)

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  4. Fuel-Cycle energy and emission impacts of ethanol-diesel blends in urban buses and farming tractors.

    SciTech Connect (OSTI)

    Wang, M.; Saricks, C.; Lee, H.

    2003-09-11

    About 2.1 billion gallons of fuel ethanol was used in the United States in 2002, mainly in the form of gasoline blends containing up to 10% ethanol (E10). Ethanol use has the potential to increase in the U.S. blended gasoline market because methyl tertiary butyl ether (MTBE), formerly the most popular oxygenate blendstock, may be phased out owing to concerns about MTBE contamination of the water supply. Ethanol would remain the only viable near-term option as an oxygenate in reformulated gasoline production and to meet a potential federal renewable fuels standard (RFS) for transportation fuels. Ethanol may also be blended with additives (co-solvents) into diesel fuels for applications in which oxygenation may improve diesel engine emission performance. Numerous studies have been conducted to evaluate the fuel-cycle energy and greenhouse gas (GHG) emission effects of ethanol-gasoline blends relative to those of gasoline for applications in spark-ignition engine vehicles (see Wang et al. 1997; Wang et al. 1999; Levelton Engineering et al. 1999; Shapouri et al. 2002; Graboski 2002). Those studies did not address the energy and emission effects of ethanol-diesel (E-diesel or ED) blends relative to those of petroleum diesel fuel in diesel engine vehicles. The energy and emission effects of E-diesel could be very different from those of ethanol-gasoline blends because (1) the energy use and emissions generated during diesel production (so-called ''upstream'' effects) are different from those generated during gasoline production; and (2) the energy and emission performance of E-diesel and petroleum diesel fuel in diesel compression-ignition engines differs from that of ethanol-gasoline blends in spark-ignition (Otto-cycle-type) engine vehicles. The Illinois Department of Commerce and Community Affairs (DCCA) commissioned Argonne National Laboratory to conduct a full fuel-cycle analysis of the energy and emission effects of E-diesel blends relative to those of petroleum diesel when used in the types of diesel engines that will likely be targeted first in the marketplace. This report documents the results of our study. The draft report was delivered to DCCA in January 2003. This final report incorporates revisions by the sponsor and by Argonne.

  5. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  6. Effects of High Octane Ethanol Blends on Four Legacy Flex-Fuel Vehicles, and a Turbocharged GDI Vehicle

    SciTech Connect (OSTI)

    Thomas, John F; West, Brian H; Huff, Shean P

    2015-03-01

    The U.S. Department of Energy (DOE) is supporting engine and vehicle research to investigate the potential of high-octane fuels to improve fuel economy. Ethanol has very high research octane number (RON) and heat of vaporization (HoV), properties that make it an excellent spark ignition engine fuel. The prospects of increasing both the ethanol content and the octane number of the gasoline pool has the potential to enable improved fuel economy in future vehicles with downsized, downsped engines. This report describes a small study to explore the potential performance benefits of high octane ethanol blends in the legacy fleet. There are over 17 million flex-fuel vehicles (FFVs) on the road today in the United States, vehicles capable of using any fuel from E0 to E85. If a future high-octane blend for dedicated vehicles is on the horizon, the nation is faced with the classic chicken-and-egg dilemma. If today’s FFVs can see a performance advantage with a high octane ethanol blend such as E25 or E30, then perhaps consumer demand for this fuel can serve as a bridge to future dedicated vehicles. Experiments were performed with four FFVs using a 10% ethanol fuel (E10) with 88 pump octane, and a market gasoline blended with ethanol to make a 30% by volume ethanol fuel (E30) with 94 pump octane. The research octane numbers were 92.4 for the E10 fuel and 100.7 for the E30 fuel. Two vehicles had gasoline direct injected (GDI) engines, and two featured port fuel injection (PFI). Significant wide open throttle (WOT) performance improvements were measured for three of the four FFVs, with one vehicle showing no change. Additionally, a conventional (non-FFV) vehicle with a small turbocharged direct-injected engine was tested with a regular grade of gasoline with no ethanol (E0) and a splash blend of this same fuel with 15% ethanol by volume (E15). RON was increased from 90.7 for the E0 to 97.8 for the E15 blend. Significant wide open throttle and thermal efficiency performance improvement was measured for this vehicle, which achieved near volumetric fuel economy parity on the aggressive US06 drive cycle, demonstrating the potential for improved fuel economy in forthcoming downsized, downsped engines with high-octane fuels.

  7. Molecular control of the induction of alcohol dehydrogenase by ethanol in Drosophila melanogaster larvae

    SciTech Connect (OSTI)

    Kapoun, A.M.; Geer, B.W.; Heinstra, P.W.H. ); Corbin, V. ); McKechnie, S.W. )

    1990-04-01

    The activity of alcohol dehydrogenase, the initial enzyme in the major pathway for ethanol degradation, is induced in Drosophila melanogaster larvae by low concentrations of dietary ethanol. Two lines of evidence indicate that the metabolic products of the ADH pathway for ethanol degradation are not directly involved in the induction of Adh. First, the accumulation of the proximal transcript in Adh{sup n2} larvae was increased when the intracellular level of ethanol was elevated. In addition, the ADH activity, the proximal Adh mRNA, and the intracellular concentration of ethanol were elevated coordinately in wild-type larvae fed hexadeuterated-ethanol, which is metabolized more slowly than normal ethanol.l An examination of P element transformant lines with specific deletions in the 5{prime} regulatory DNA of the Adh gene showed that the DNA sequence between +604 and +634 of the start site of transcription from the distal promoter was essential for this induction. The DNA sequence between {minus}660 and about {minus}5,000 of the distal transcript start site was important for the down-regulation of the induction response.

  8. Effects of blending a heavy alcohol (C20H40O with diesel in a heavy-duty compression-ignition engine

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    Effects of blending a heavy alcohol (C20H40O with diesel in a heavy-duty compression phytol (C20H40O) with diesel in 5%, 10%, and 20% by volume blends. 3-D, transient, turbulent nozzle flow and emissions experiments of the different phytol/diesel blends. Combustion event depicted by high

  9. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non?Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith [National Renewable Energy Laboratory (NREL); West, Brian H [ORNL; Clark, Wendy [National Renewable Energy Laboratory (NREL); Graves, Ronald L [ORNL; Orban, John [Battelle, Columbus; Przesmitzki, Steve [National Renewable Energy Laboratory (NREL); Theiss, Timothy J [ORNL

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2 (Experimental Setup) provides details concerning test fuels, vehicle and SNRE selection, and test methods used to conduct the studies presented in this report. Section 3 (Results and Discussion) summarizes the vehicle and SNRE studies and presents data from testing completed to date. Section 4 (Next Steps) describes planned future activities. The appendixes provide test procedure details, vehicle and SNRE emissions standards, analysis details, and additional data and tables from vehicle and SNRE tests.

  10. Alcohol injection cuts diesel consumption on turbocharged tractors

    SciTech Connect (OSTI)

    Edson, D.V.

    1980-07-21

    M and W Gear Co. of Gibson City, IL, are marketing a new alcohol- injection system that permits turbocharged diesel engines to burn alcohol and claims to cut diesel consumption by 30% and more. The alcohol fuel, a blend of alcohol and water, does not meet the diesel fuel until the alcohol has been atomized and sprayed through the intake manifold into the cylinders. It permits farmers to use home- still-produced ethanol without the added expense of refining to anhydrous composition.

  11. Conducting polymer blends: Polypyrrole and polythiophene blends with polystyrene, polycarbonate resin, poly(vinyl alcohol) and poly(vinyl methyl ketone)

    SciTech Connect (OSTI)

    Wang, H.L.

    1992-01-01

    Various aromatic compounds can be polymerized by electrochemical oxidation in solution containing a supporting electrolyte. Most studies have been devoted to polypyrrole and polythiophene. In situ doping during electrochemical polymerization yields free standing conductive polymer film. One major approach to making conducting polymer blends is electrochemical synthesis after coating the host polymer on a platinum electrode. In the electrolysis of pyrrole or thiophene monomer, using (t-Bu[sub 4]N)BF[sub 4] as supporting electrolyte, and acetonitrile as solvent, monomer can diffuse through the polymer film, to produce a polypyrrole or polythiophene blend in the film. Doping occurs along with polymerization to form a conducting polymer alloy. The strongest molecular interaction in polymers, and one that is central to phase behavior, is hydrogen bonding. This mixing at the molecular level enhances the degree of miscibility between two polymers and results in macroscopic properties indicative of single phase behavior. In this dissertation, the authors describes the syntheses of conducting polymer blends: polypyrrole and polythiophene blends with polystyrene, poly(bisphenol-A-carbonate), polyvinyl alcohol and poly(vinyl methyl ketone). The syntheses are performed both electrochemically and chemically. Characterization of these blends was carried out by Fourier Transform Infrared spectroscopy, Differential Scanning Calorimetry, Thermogravimetric Analysis, Scanning Electron Microscopy, and X-ray diffraction. Percolating threshold conductivities occur from 7% to 20% for different polymer blends. The low threshold conductivity is attributed to blend homogeneity enhanced by hydrogen bonding between the carbonyl group in the insulating polymer and the N-H group in polypyrrole. Thermal stability, environmental stability, mechanical properties, crystallinity and morphological structure are also discussed. The authors have also engaged in the polymerization of imidazoles.

  12. Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

    SciTech Connect (OSTI)

    Merritt, P. M.; Ulmet, V.; McCormick, R. L.; Mitchell, W. E.; Baumgard, K. J.

    2005-11-01

    Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent). Benzene emissions were reduced by up to 50 percent with the ethanol-blended fuels. Emissions of 1,3-butadiene were also substantially decreased, with reductions ranging from 24 to 82 percent. Isolated trends were noted for certain PAHs. There was a decrease in 1-nitropyrene with use of ethanol in all cases. Particulate phase 1-nitropyrene was reduced from 18 to 62 percent. There was also a general increase in the proportion of heavy PAHs in the particulate phase with ethanol use, and although less pronounced, a general decrease in light PAHs in the particulate phase.

  13. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations

  14. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  15. Durability testing of a diesel fuel, methyl tallowate, and ethanol blend in a Cummins N14-410 diesel engine

    SciTech Connect (OSTI)

    Ali, Y.; Hanna, M.A. [Univ. of Nebraska, Lincoln, NE (United States)

    1996-05-01

    A Cummins N14-410 diesel engine was operated on an 80:13:7% (v/v) blend of diesel fuel: methyl tallowate: ethanol. The standard 200-h Engine Manufacturers Association (EMA) test procedure was followed to test engine durability. Engine performance was evaluated in terms of power produced at rated speed, peak torque produced at a speed of 1200 rpm, and brake specific fuel consumption at both speeds. Engine exhaust emissions analyses were performed, and the engine oil was analyzed for accumulation of heavy metals at 45 h intervals. It was observed that engine performance was satisfactory for 148 h at which time the injector in cylinder 2 failed. The injector was changed, and after an additional 11 h (159 h total) of operation the injector in cylinder 5 failed. That injector was also replaced, and the 200-h procedure was continued. The test was discontinued after 197 h when the supply of the fuel blend was exhausted. The injectors were removed and the injector in cylinder 1 was observed to be coked. This injector was sent to the Cummins Engine Co. for analysis. It was found that failure of this injector was not because of the fuel used, but because of a crack had developed across the tip due to an excessively tight overhead adjustment. Engine oil analyses performed for accumulation of wear metals did not reveal any excessive wear on the engine parts. 12 refs., 4 figs., 3 tabs.

  16. Techno-Economics for Conversion of Lignocellulosic Biomass to Ethanol by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Abhijit Dutta; Michael Talmadge; Jesse Hensley; Matt Worley; Doug Dudgeon; David Barton; Peter Groenendijk; Daniela Ferrari; Brien Stears; Erin Searcy; Christopher Wright; J. Richard Hess

    2012-07-01

    This techno-economic study investigates the production of ethanol and a higher alcohols coproduct by conversion of lignocelluosic biomass to syngas via indirect gasification followed by gas-to-liquids synthesis over a precommercial heterogeneous catalyst. The design specifies a processing capacity of 2,205 dry U.S. tons (2,000 dry metric tonnes) of woody biomass per day and incorporates 2012 research targets from NREL and other sources for technologies that will facilitate the future commercial production of cost-competitive ethanol. Major processes include indirect steam gasification, syngas cleanup, and catalytic synthesis of mixed alcohols, and ancillary processes include feed handling and drying, alcohol separation, steam and power generation, cooling water, and other operations support utilities. The design and analysis is based on research at NREL, other national laboratories, and The Dow Chemical Company, and it incorporates commercial technologies, process modeling using Aspen Plus software, equipment cost estimation, and discounted cash flow analysis. The design considers the economics of ethanol production assuming successful achievement of internal research targets and nth-plant costs and financing. The design yields 83.8 gallons of ethanol and 10.1 gallons of higher-molecular-weight alcohols per U.S. ton of biomass feedstock. A rigorous sensitivity analysis captures uncertainties in costs and plant performance.

  17. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more components of the elastomers (by the solvent). This extraction of additives can negatively change the properties of the elastomer, leading to reduced performance and durability. For a seal application, some level of volume swell is acceptable, since the expansion will serve to maintain a seal. However, the acceptable level of swell is dependent on the particular application of the elastomer product. It is known that excessive swell can lead to unacceptable extrusion of the elastomer beyond the sealed interface, where it becomes susceptible to damage. Also, since high swell is indicative of high solubility, there is a heightened potential for fluid to seep through the seal and into the environment. Plastics, on the other hand, are used primarily in structural applications, such as solid components, including piping and fluid containment. Volume change, especially in a rigid system, will create internal stresses that may negatively affect performance. In order to better understand and predict the compatibility for a given polymer type and fuel composition, an analysis based on Hansen solubility theory was performed for each plastic and elastomer material. From this study, the solubility distance was calculated for each polymer material and test fuel combination. Using the calculated solubility distance, the ethanol concentration associated with peak swell and overall extent of swell can be predicted for each polymer. The bulk of the material discussion centers on the plastic materials, and their compatibility with Fuel C, CE25a, CE50a, and CE85a. The next section of this paper focuses on the elastomer compatibility with the higher ethanol concentrations with comparison to results obtained previously for the lower ethanol levels. The elastomers were identical to those used in the earlier study. Hansen solubility theory is also applied to the elastomers to provide added interpretation of the results. The final section summarizes the performance of the metal coupons.

  18. Feasibility study of fuel grade ethanol plant for Alcohol Fuels of Mississippi, Inc. , Vicksburg, Mississippi

    SciTech Connect (OSTI)

    None

    1981-01-01

    The results are presented of a feasibility study performed to determine the technical and economic viability of constructing an alcohol plant utilizing the N.Y.U. continuous acid hydrolysis process to convert wood wastes to fuel grade alcohol. The following is a summary of the results: (1) The proposed site in the Vicksburg Industrial Foundation Corporation Industrial Park is adequate from all standpoints, for all plant capacities envisioned. (2) Local hardwood sawmills can provide adequate feedstock for the facility. The price per dry ton varies between $5 and $15. (3) Sale of fuel ethanol would be made primarily through local distributors and an adequate market exists for the plant output. (4) With minor modifications to the preparation facilities, other waste cellulose materials can also be utilized. (5) There are no anticipated major environmental, health, safety or socioeconomic risks related to the construction and operation of the proposed facility. (6) The discounted cash flow and rate of return analysis indicated that the smallest capacity unit which should be built is the 16 million gallon per year plant, utilizing cogeneration. This facility has a 3.24 year payback. (7) The 25 million gallon per year plant utilizing cogeneration is an extremely attractive venture, with a zero interest break-even point of 1.87 years, and with a discounted rate of return of 73.6%. (8) While the smaller plant capacities are unattractive from a budgetary viewpoint, a prudent policy would dictate that a one million gallon per year plant be built first, as a demonstration facility. This volume contains process flowsheets and maps of the proposed site.

  19. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W. (Marietta, GA)

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  20. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  1. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    Advancing Cellulosic Ethanol for Large Scale SustainableHydrogen Batteries Nuclear By Lee Lynd, Dartmouth Ethanol •Ethanol, ethyl alcohol, fermentation ethanol, or just “

  2. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012.

  3. Thermochemical ethanol via indirect gasification and mixed alcohol synthesis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot level by 2012.

  4. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesof Energy ServicesEnergy4thwritesOfficeEstimation

  5. Thermochemical Design Report: Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot-unit level by 2012.

  6. Thermochemical Ethanol via Direct Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Dutta, A.; Phillips, S. D.

    2009-07-01

    This report evaluates process design and technoeconomic criteria for a direct gasification process for conversion of biomass to ethanol. Follow-up to NREL/TP-510-41168.

  7. Prenatal ethanol exposure programs an increased susceptibility of non-alcoholic fatty liver disease in female adult offspring rats

    SciTech Connect (OSTI)

    Shen, Lang; Liu, Zhongfen; Gong, Jun; Zhang, Li; Wang, Linlong; Magdalou, Jacques; Chen, Liaobin; Wang, Hui

    2014-01-15

    Prenatal ethanol exposure (PEE) induces dyslipidemia and hyperglycemia in fetus and adult offspring. However, whether PEE increases the susceptibility to non-alcoholic fatty liver disease (NAFLD) in offspring and its underlying mechanism remain unknown. This study aimed to demonstrate an increased susceptibility to high-fat diet (HFD)-induced NAFLD and its intrauterine programming mechanisms in female rat offspring with PEE. Rat model of intrauterine growth retardation (IUGR) was established by PEE, the female fetus and adult offspring that fed normal diet (ND) or HFD were sacrificed. The results showed that, in PEE + ND group, serum corticosterone (CORT) slightly decreased and insulin-like growth factor-1 (IGF-1) and glucose increased with partial catch-up growth; In PEE + HFD group, serum CORT decreased, while serum IGF-1, glucose and triglyceride (TG) increased, with notable catch-up growth, higher metabolic status and NAFLD formation. Enhanced liver expression of the IGF-1 pathway, gluconeogenesis, and lipid synthesis as well as reduced expression of lipid output were accompanied in PEE + HFD group. In PEE fetus, serum CORT increased while IGF-1 decreased, with low body weight, hyperglycemia, and hepatocyte ultrastructural changes. Hepatic IGF-1 expression as well as lipid output was down-regulated, while lipid synthesis significantly increased. Based on these findings, we propose a “two-programming” hypothesis for an increased susceptibility to HFD-induced NAFLD in female offspring of PEE. That is, the intrauterine programming of liver glucose and lipid metabolic function is “the first programming”, and postnatal adaptive catch-up growth triggered by intrauterine programming of GC-IGF1 axis acts as “the second programming”. - Highlights: • Prenatal ethanol exposure increase the susceptibility of NAFLD in female offspring. • Prenatal ethanol exposure reprograms fetal liver’s glucose and lipid metabolism . • Prenatal ethanol exposure cause the adaptive change of glucocorticoid-IGF1 axis.

  8. U.S. Ethanol Policy: The Unintended

    E-Print Network [OSTI]

    Meagher, Mary

    petroleum and to cut greenhouse gas emissions. A new blend of ethanol and conventional gasoline was to cost- tive, the current blend of E10 (or 10% ethanol) gasoline offers pros and cons. The btu efficiency of a gallon of ethanol is about 40% less than a gallon of conventional gasoline. So, an E10 blend requires 4

  9. ~A four carbon alcohol. It has double the amount of carbon of ethanol, which equates to a substantial increase in harvestable energy (Btu's).

    E-Print Network [OSTI]

    Toohey, Darin W.

    when consumed in an internal combustion engine yields no SOX, NOX or carbon monoxide allButanol ~A four carbon alcohol. It has double the amount of carbon of ethanol, which equates environmentally harmful byproducts of combustion. CO2 is the combustion byproduct of butanol, and is considered

  10. IEA Implementing Agreement on Advanced Motor Fuels Ethanol as a Fuel for

    E-Print Network [OSTI]

    .................................................................................................... 27 WATER AND BLENDING ISSUES........................................................................................ 28 Ethanol/Gasoline/Water Miscibility

  11. Method for producing gasoline-alcohol fuels

    SciTech Connect (OSTI)

    Black, C.

    1983-05-10

    A process for producing gasoline-ethanol blends comprises purifying dilute ethanol by extractive distillation and concentrating the ethanol by distillation followed by one or both of the following steps: (A) liquid extraction of ethanol into heated gasoline or (B) azeotropic distillation of ethanol with an entrainer followed by blending with gasoline.

  12. Alternative Fuel Tool Kit How to Implement: Ethanol (E85)

    E-Print Network [OSTI]

    is a renewable alternative transportation fuel blend of gasoline and ethanol. Ethanol (C2H5OH, a.k.a. ethyl, and Dispensing E85 and Other Ethanol-Gasoline Blends" by the US Department of Energy ( US DOE).1,2 The dominant ethanol/gasoline blends in the United States are up to 10% ethanol (E10) and up to 83% ethanol (E85). More

  13. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  14. Ethanol's Effect on Stem Cell Subpopulations And The Implications For Cortical Patterning And Development In Fetal Alcohol Syndrome 

    E-Print Network [OSTI]

    Tingling, Joseph Duane

    that is ethanol sensitive and serves to indentify a neural stem cell (NSC) subpopulation that is reduced with ethanol exposure. The data presented identifies CD24 as a cell surface marker expressed in mouse neurosphere culture that is decreased with ethanol...

  15. Thermal decomposition of ethanol and growth of vertically aligned single-walled carbon nanotubes by alcohol catalytic chemical vapor deposition

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Thermal decomposition of ethanol and growth of vertically aligned single-walled carbon nanotubes. In this study, we have investigated the thermal decomposition of ethanol at various temperatures, as well National Meeting, San Francisco, CA, September 10-14, 2006 1/1 PRES 29 - Thermal decomposition of ethanol

  16. Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    plume lengths in subsurface environments following accidental spills of ethanol-blended gasoline. Two, 8% of all the gasoline sold in the United States contained ethanol. By 1998, ethanol-blended fuels. As a result, the use of ethanol-blended gasoline is expected to in- crease in the United States over the next

  17. Brain reward deficits accompany withdrawal (hangover) from acute ethanol in rats

    E-Print Network [OSTI]

    Schulteis, Gery; Liu, Jian

    2006-01-01

    stimulation reward: effects of ethanol. Alcohol Clin Exp Resstimulus produced by ethanol withdrawal. J Pharmacol Expthe "anxiogenic" response to ethanol withdrawal in the rat.

  18. Ethanol Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to...

  19. Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater

    E-Print Network [OSTI]

    Scow, K M; MacKay, Douglas

    2008-01-01

    Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

  20. Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol: Thermochemical Pathway by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Dutta, A.; Talmadge, M.; Hensley, J.; Worley, M.; Dudgeon, D.; Barton, D.; Groendijk, P.; Ferrari, D.; Stears, B.; Searcy, E. M.; Wright, C. T.; Hess, J. R.

    2011-05-01

    This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing. The design features a processing capacity of 2,205 U.S. tons (2,000 metric tonnes) of dry biomass per day and an ethanol yield of 83.8 gallons per dry U.S. ton of feedstock. The ethanol selling price corresponding to this design is $2.05 per gallon in 2007 dollars, assuming a 30-year plant life and 40% equity financing with a 10% internal rate of return and the remaining 60% debt financed at 8% interest. This ethanol selling price corresponds to a gasoline equivalent price of $3.11 per gallon based on the relative volumetric energy contents of ethanol and gasoline.

  1. Mid-Level Ethanol Blends

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE SafetyofDepartment. "National SecurityWM'04At the

  2. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Using Ethanol-Diesel Blends Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration Strategies Diesel Injection Shear-Stress Advanced Nozzle (DISSAN)...

  3. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

    2010-04-01

    Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

  4. Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions

    Broader source: Energy.gov [DOE]

    Characterized particulate emissions from U.S.-legal stoichiometric GDI and European certified lean-burn GDI vehicles operating on ethanol blends

  5. U.S. Ethanol Policy: The Unintended Consequences 

    E-Print Network [OSTI]

    Griffin, James M.; Soto, Maricio Cifuentes

    2012-01-01

    The Energy Independence and Security Act of 2007 (EISA) mandated a steep rise in domestic ethanol production. The goals were to ease dependency on imported petroleum and to cut greenhouse gas emissions. A new blend of ethanol and conventional...

  6. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  7. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  8. O P I N I O N Ethanol from sugarcane in Brazil: a `midway' strategy for

    E-Print Network [OSTI]

    DeLucia, Evan H.

    in the 1970s, generated by the oil crisis, led Brazil to start a program to substitute ethanol for gasoline the `blending wall', which limited th

  9. Microsoft Word - Int_blends_Rpt1_Updated.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NRELTP-540-43543 ORNLTM-2008117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll...

  10. Modeling the Effect of Fuel Ethanol Concentration on Cylinder Pressure Evolution in Direct-Injection Flex-Fuel Engines

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Modeling the Effect of Fuel Ethanol Concentration on Cylinder Pressure Evolution in Direct the fuel vaporization pro- cess for ethanol-gasoline fuel blends and the associated charge cooling effect experimental cylinder pressure for different gasoline-ethanol blends and various speeds and loads on a 2.0 L

  11. 2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection Engines Using In (FFVs) are able to operate on a blend of ethanol and gasoline in any volumetric concen- tration of up to 85% ethanol (93% in Brazil). The estima- tion of ethanol content is crucial for optimized and robust

  12. Ethanol Demand in United States Gasoline Production

    SciTech Connect (OSTI)

    Hadder, G.R.

    1998-11-24

    The Oak Ridge National Laboratory (OWL) Refinery Yield Model (RYM) has been used to estimate the demand for ethanol in U.S. gasoline production in year 2010. Study cases examine ethanol demand with variations in world oil price, cost of competing oxygenate, ethanol value, and gasoline specifications. For combined-regions outside California summer ethanol demand is dominated by conventional gasoline (CG) because the premised share of reformulated gasoline (RFG) production is relatively low and because CG offers greater flexibility for blending high vapor pressure components like ethanol. Vapor pressure advantages disappear for winter CG, but total ethanol used in winter RFG remains low because of the low RFG production share. In California, relatively less ethanol is used in CG because the RFG production share is very high. During the winter in California, there is a significant increase in use of ethanol in RFG, as ethanol displaces lower-vapor-pressure ethers. Estimated U.S. ethanol demand is a function of the refiner value of ethanol. For example, ethanol demand for reference conditions in year 2010 is 2 billion gallons per year (BGY) at a refiner value of $1.00 per gallon (1996 dollars), and 9 BGY at a refiner value of $0.60 per gallon. Ethanol demand could be increased with higher oil prices, or by changes in gasoline specifications for oxygen content, sulfur content, emissions of volatile organic compounds (VOCS), and octane numbers.

  13. Web-based intervention for alcohol use in women of childbearing potential

    E-Print Network [OSTI]

    Howlett, Katia Delrahim

    2010-01-01

    assessing self-reported ethanol consumption. In J. Allen, &biases in self- reported alcohol consumption and harms.Retrospective self-report of alcohol consumption: Test-

  14. Intermediate Ethanol Blends: Plans and Status

    Broader source: Energy.gov [DOE]

    Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

  15. Mid-Blend Ethanol Fuels – Implementation Perspectives

    Broader source: Energy.gov [DOE]

    Breakout Session 2: Frontiers and Horizons Session 2–B: End Use and Fuel Certification Bill Woebkenberg, Fuels Technical and Regulatory Affairs Senior Engineer, Mercedes-Benz

  16. Intermediate Ethanol Blends: Plans and Status

    Office of Environmental Management (EM)

    etc. * Testing is underway 7 MY2003 & 2007 Most popular Cars & trucks 6 OEMs Task V1: Vehicle Pilot Study Task V2: EmissionsEPAct Program with EPA * EPADOE Cooperation *...

  17. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender Pump Dispensers to someoneElectricity

  18. Ethanol Production and Gasoline Prices: A Spurious Correlation

    E-Print Network [OSTI]

    Smith, Aaron

    Ethanol made from corn comprises 10% of U.S. gasoline, up from 3% in 2003. This dramatic increase was spurred by recent policy initiatives such as the Renewable Fuel Standard and state-level blend mandates and supported ...

  19. WSU Program for TBI Research Summer School Neuroprotection & Mechanism of Ethanol

    E-Print Network [OSTI]

    VandeVord, Pamela

    6/12/2013 1 WSU Program for TBI Research Summer School Neuroprotection & Mechanism of Ethanol Surgery June 7, 2013 Department of Neurological Surgery Wayne State University History of Alcohol (Ethanol) ·The earliest evidence of alcohol (ethanol) use is the discovery of beer jugs from the Neolithic age

  20. The Renewable Fuel Standard and Ethanol Pricing: A Sensitivity Analysis 

    E-Print Network [OSTI]

    McNair, Robert

    2014-04-18

    and gasoline. In 2014, it is projected oil refineries will hit the blend wall (BW). In short, oil refineries are required to blend more ethanol into gasoline than is allowed by the Environmental Protection Agency (EPA). As a consequence, the EPA will need...

  1. Ethanol production in recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal; Barbosa-Alleyne, Maria D.

    2005-02-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  2. Vaporizer design criteria for ethanol fueled internal combustion engines 

    E-Print Network [OSTI]

    Ariyaratne, Arachchi Rallage

    1985-01-01

    to gasoline. Rogowski and Taylor (1941) showed that alcohol could be used as an anti-knock agent for gasoline, but that alcohol could not compete economically with petroleum fuels as an engine fuel. These and many other studies show the potential... been identified in conversion of diesel engines of farm tractors for using alcohol fuels. Distillation at atmospheric pressure does not yield 200 proof ethanol, (Winston, 1981), so with present technology, ethanol produced on farms is aqueous. A...

  3. Nucleic acid molecules conferring enhanced ethanol tolerance and microorganisms having enhanced tolerance to ethanol

    DOE Patents [OSTI]

    Brown, Steven; Guss, Adam; Yang, Shihui; Karpinets, Tatiana; Lynd, Lee; Shao, Xiongjun

    2014-01-14

    The present invention provides isolated nucleic acid molecules which encode a mutant acetaldehyde-CoA/alcohol dehydrogenase or mutant alcohol dehydrogenase and confer enhanced tolerance to ethanol. The invention also provides related expression vectors, genetically engineered microorganisms having enhanced tolerance to ethanol, as well as methods of making and using such genetically modified microorganisms for production of biofuels based on fermentation of biomass materials.

  4. HD Applications of Significantly Downsized SI Engines Using Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding...

  5. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Environmental Management (EM)

    place in the future. This design case establishes cost targets for converting MSW to ethanol and other mixed alcohols via gasification. Design Case Summary: Production of Mixed...

  6. Modeling benzene plume elongation mechanisms exerted by ethanol using RT3D with a general

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    E10 gasoline (i.e., a blend with 10% vol/vol ethanol/ gasoline) showed that mean benzene plume of E10 gasoline (10% vol/vol ethanol), which compares favorably to field observations. For low benzene Act requirements. The widespread use of ethanol in gasoline has led to an increase in its potential

  7. TOLERANT ETHANOL ESTIMATION IN FLEX-FUEL VEHICLES DURING MAF SENSOR DRIFTS

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    TOLERANT ETHANOL ESTIMATION IN FLEX-FUEL VEHICLES DURING MAF SENSOR DRIFTS Kyung-ho Ahn, Anna G Engineering Dearborn, Michigan 48121 ABSTRACT Flexible fuel vehicles (FFVs) can operate on a blend of ethanol and gasoline in any volumetric concentration of up to 85% ethanol (93% in Brazil). Existing FFVs rely

  8. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Fowler, David E. (Gainesville, FL); Horton, Philip G. (Gainesville, FL); Ben-Bassat, Arie (Gainesville, FL)

    1996-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  9. Ethanol production by recombinant hosts

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Beall, David S. (Gainesville, FL); Burchhardt, Gerhard F. H. (Gainesville, FL); Guimaraes, Walter V. (Vicosa, BR); Ohta, Kazuyoshi (Miyazaki, JP); Wood, Brent E. (Gainesville, FL); Shanmugam, Keelnatham T. (Gainesville, FL)

    1995-01-01

    Novel plasmids comprising genes which code for the alcohol dehydrogenase and pyruvate decarboxylase are described. Also described are recombinant hosts which have been transformed with genes coding for alcohol dehydrogenase and pyruvate. By virtue of their transformation with these genes, the recombinant hosts are capable of producing significant amounts of ethanol as a fermentation product. Also disclosed are methods for increasing the growth of recombinant hosts and methods for reducing the accumulation of undesirable metabolic products in the growth medium of these hosts. Also disclosed are recombinant host capable of producing significant amounts of ethanol as a fermentation product of oligosaccharides and plasmids comprising genes encoding polysaccharases, in addition to the genes described above which code for the alcohol dehydrogenase and pyruvate decarboxylase. Further, methods are described for producing ethanol from oligomeric feedstock using the recombinant hosts described above. Also provided is a method for enhancing the production of functional proteins in a recombinant host comprising overexpressing an adhB gene in the host. Further provided are process designs for fermenting oligosaccharide-containing biomass to ethanol.

  10. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  11. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  12. High compression ratio turbo gasoline engine operation using alcohol enhancement

    E-Print Network [OSTI]

    Lewis, Raymond (Raymond A.)

    2013-01-01

    Gasoline - ethanol blends were explored as a strategy to mitigate engine knock, a phenomena in spark ignition engine combustion when a portion of the end gas is compressed to the point of spontaneous auto-ignition. This ...

  13. ESTIMATION OF ETHANOL CONTENT IN FLEX-FUEL VEHICLES USING AN EXHAUST GAS OXYGEN SENSOR: MODEL, TUNING AND SENSITIVITY

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    ESTIMATION OF ETHANOL CONTENT IN FLEX-FUEL VEHICLES USING AN EXHAUST GAS OXYGEN SENSOR: MODEL periods of intense interest in using ethanol as an alternative fuel to petroleum-based gasoline and diesel derivatives. Currently available flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol

  14. The slowpoke Gene Is Necessary for Rapid Ethanol Tolerance in Drosophila

    E-Print Network [OSTI]

    Atkinson, Nigel

    ). The cost of alcohol abuse in the United States exceeds $200 billion a year (Harwood et al., 1992). Like prior exposure to ethanol did not cause a change in the ethanol clearance rate. Conclusions: Rapid, and finally death (Julien, 2004). Consumption of alcohol causes long-term physiological changes, including

  15. Increasing atmospheric burden of ethanol in the United States J. A. de Gouw,1,2

    E-Print Network [OSTI]

    Goldstein, Allen

    that a widespread use of E85 (a fuel blend with 85% ethanol and 15% gasoline) could lead to significant increases blended into gasoline) for regular gasoline vehicles. Fuel sale data from the Energy Information as a transportation fuel in the U.S. increased significantly from 2000­2009, and in 2010 nearly all gasoline contained

  16. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1996-01-09

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  17. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, L.O.; Barbosa-Alleyne, M.D.F.

    1999-06-29

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase. 2 figs.

  18. Ethanol production in Gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal (Gainesville, FL); Barbosa-Alleyne, Maria D. F. (Gainesville, FL)

    1996-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  19. Ethanol production in gram-positive microbes

    DOE Patents [OSTI]

    Ingram, Lonnie O'Neal (Gainesville, FL); Barbosa-Alleyne, Maria D. F. (Gainesville, FL)

    1999-01-01

    The subject invention concerns the transformation of Gram-positive bacteria with heterologous genes which confer upon these microbes the ability to produce ethanol as a fermentation product. Specifically exemplified is the transformation of bacteria with genes, obtainable from Zymomonas mobilis, which encode pyruvate decarboxylase and alcohol dehydrogenase.

  20. Alcohol synthesis from CO or CO.sub.2

    DOE Patents [OSTI]

    Hu, Jianli [Kennewick, WA; Dagle, Robert A [Richland, WA; Holladay, Jamelyn D [Kennewick, WA; Cao, Chunshe [Houston, TX; Wang, Yong [Richland, WA; White, James F [Richland, WA; Elliott, Douglas C [Richland, WA; Stevens, Don J [Richland, WA

    2010-12-28

    Methods for producing alcohols from CO or CO.sub.2 and H.sub.2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C.sub.2+ oxygenates can produced utilizing Rh--Mn or a Fisher-Tropsch catalyst.

  1. Ethanol Can Contribute to Energy and Environmental Goals

    E-Print Network [OSTI]

    Kammen, Daniel M.

    blended into gasoline in 2004 amounted to about 2% of all gasoline sold by volume and 1.3% (2.5 Â 1017 J studies indicated that current corn ethanol technologies are much less petroleum-intensive than gasoline but have greenhouse gas emissions similar to those of gasoline. However, many important environmental

  2. Assessing deployment strategies for ethanol and flex fuel vehicles in the U.S. light-duty vehicle fleet

    E-Print Network [OSTI]

    McAulay, Jeffrey L. (Jeffrey Lewis)

    2009-01-01

    Within the next 3-7 years the US light duty fleet and fuel supply will encounter what is commonly referred to as the "blend wall". This phenomenon describes the situation when more ethanol production has been mandated than ...

  3. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  4. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  5. Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser/Time-of-Flight Mass Spectrometry

    E-Print Network [OSTI]

    Goddard III, William A.

    Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser distributions and geometries of vapor clusters equilibrated with methanol-ethanol (Me-Et) liquid mixtures were distributions of vapor clusters equilibrated with liquids, ranging from neat alcohols1,2 to methanol-ethanol (Me

  6. Interaction Between Family History of Alcoholism and Locus of Control in the Opioid Regulation of Impulsive

    E-Print Network [OSTI]

    choice, motor inhibition, and attentional bias after ingestion of moderate ethanol (0.3 g / kg, n = 30 ethanol intake is important. Our previous study of abstinent alcoholics and control subjects showed Making, Delay Discounting, Ethanol, Impulsivity, Naltrexone. N ALTREXONE (NTX), AN opioid antagonist

  7. Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

    SciTech Connect (OSTI)

    James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

    2011-07-29

    The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing at realistic conditions (e.g., elevated pressures) and differential conversions (to measure true kinetics, to avoid deactivation, and to avoid condensable concentrations of products in the outlet gas).

  8. Greenhouse gases in the corn-to-fuel ethanol pathway.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-06-18

    Argonne National Laboratory (ANL) has applied its Greenhouse gas, Regulated Emissions and Energy in Transportation (GREET) full-fuel-cycle analysis model to examine greenhouse gas (GHG) emissions of corn-feedstock ethanol, given present and near-future production technology and practice. On the basis of updated information appropriate to corn farming and processing operations in the four principal corn- and ethanol-producing states (Illinois, Iowa, Minnesota, and Nebraska), the model was used to estimate energy requirements and GHG emissions of corn farming; the manufacture, transportation to farms, and field application of fertilizer and pesticide; transportation of harvested corn to ethanol plants; nitrous oxide emissions from cultivated cornfields; ethanol production in current average and future technology wet and dry mills; and operation of cars and light trucks using ethanol fuels. For all cases examined on the basis of mass emissions per travel mile, the corn-to-ethanol fuel cycle for Midwest-produced ethanol used in both E85 and E10 blends with gasoline outperforms conventional (current) and reformulated (future) gasoline with respect to energy use and GHG production. Also, GHG reductions (but not energy use) appear surprisingly sensitive to the value chosen for combined soil and leached N-fertilizer conversion to nitrous oxide. Co-product energy-use attribution remains the single key factor in estimating ethanol's relative benefits because this value can range from 0 to 50%, depending on the attribution method chosen.

  9. Ethanol Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2015-01-01

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  10. Dispensing Equipment Testing with Mid-Level Ethanol/Gasoline Test Fluid: Summary Report

    SciTech Connect (OSTI)

    Boyce, K.; Chapin, J. T.

    2010-11-01

    The National Renewable Energy Laboratory's (NREL) Nonpetroleum-Based Fuel Task addresses the hurdles to commercialization of biomass-derived fuels and fuel blends. One such hurdle is the unknown compatibility of new fuels with current infrastructure, such as the equipment used at service stations to dispense fuel into automobiles. The U.S. Department of Energy's (DOE) Vehicle Technology Program and the Biomass Program have engaged in a joint project to evaluate the potential for blending ethanol into gasoline at levels higher than nominal 10 volume percent. This project was established to help DOE and NREL better understand any potentially adverse impacts caused by a lack of knowledge about the compatibility of the dispensing equipment with ethanol blends higher than what the equipment was designed to dispense. This report provides data about the impact of introducing a gasoline with a higher volumetric ethanol content into service station dispensing equipment from a safety and a performance perspective.

  11. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  12. Fact Sheet: Effects of Intermediate Ethanol Blends | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRD Report to Congress MoreHyd rog enOffice|

  13. Vehicle Technologies Office: Intermediate Ethanol Blends | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReport FY 2009,BiofuelsLetEnergyResearch,and Testing |Department

  14. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergy (AZ, CA,EnergystudentThisWear |Non-Road Engines, Report 1 …

  15. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 InfographiclighbulbsDepartmentDeveloping new U.S.

  16. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementofApril 25,EVthe nextof Energy

  17. Mid-Level Ethanol Blends Test Program | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy6-09.doc Microsoft Word

  18. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender PumpVehiclesThe Heat IsHeavy-Duty Waste Hauler

  19. Conversion of Methanol, Ethanol and Propanol over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-04

    Renewable fuel from lignocellulosic biomass has recently attracted more attention due to its environmental and the potential economic benefits over the crude oil [1]. In particular the production of fuel range hydrocarbon (HC) from alcohol generated lots of interest since the alcohol can be produced from biomass via thermochemical [2] (mixed alcohol from gasification derived synthesis gas) as well as the biochemical routes [3] (alcohol fermentation). Along with the development of ZSM5 synthesis and the discovery of methanol-to-gasoline (MTG) process by Mobil in 1970’s triggered lots of interest in research and development arena to understand the reaction mechanisms of alcohols over zeolites in particular ZSM5 [4]. More detailed research on methanol conversion was extensively reported [5] and in recent times the research work can be found on ethanol [6] and other alcohols as well but comprehensive comparison of catalyst activity and the deactivation mechanism of the conversion of various alcohols over zeolites has not been reported. The experiments were conducted on smaller alcohols such as methanol, ethanol and 1-propanol over HZSM5. The experimental results on the catalyst activity and the catalyst deactivation mechanism will be discussed.

  20. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  1. Liver proteomics in progressive alcoholic steatosis

    SciTech Connect (OSTI)

    Fernando, Harshica; Wiktorowicz, John E.; Soman, Kizhake V.; Kaphalia, Bhupendra S.; Khan, M. Firoze; Shakeel Ansari, G.A.

    2013-02-01

    Fatty liver is an early stage of alcoholic and nonalcoholic liver disease (ALD and NALD) that progresses to steatohepatitis and other irreversible conditions. In this study, we identified proteins that were differentially expressed in the livers of rats fed 5% ethanol in a Lieber–DeCarli diet daily for 1 and 3 months by discovery proteomics (two-dimensional gel electrophoresis and mass spectrometry) and non-parametric modeling (Multivariate Adaptive Regression Splines). Hepatic fatty infiltration was significantly higher in ethanol-fed animals as compared to controls, and more pronounced at 3 months of ethanol feeding. Discovery proteomics identified changes in the expression of proteins involved in alcohol, lipid, and amino acid metabolism after ethanol feeding. At 1 and 3 months, 12 and 15 different proteins were differentially expressed. Of the identified proteins, down regulation of alcohol dehydrogenase (? 1.6) at 1 month and up regulation of aldehyde dehydrogenase (2.1) at 3 months could be a protective/adaptive mechanism against ethanol toxicity. In addition, betaine-homocysteine S-methyltransferase 2 a protein responsible for methionine metabolism and previously implicated in fatty liver development was significantly up regulated (1.4) at ethanol-induced fatty liver stage (1 month) while peroxiredoxin-1 was down regulated (? 1.5) at late fatty liver stage (3 months). Nonparametric analysis of the protein spots yielded fewer proteins and narrowed the list of possible markers and identified D-dopachrome tautomerase (? 1.7, at 3 months) as a possible marker for ethanol-induced early steatohepatitis. The observed differential regulation of proteins have potential to serve as biomarker signature for the detection of steatosis and its progression to steatohepatitis once validated in plasma/serum. -- Graphical abstract: The figure shows the Hierarchial cluster analysis of differentially expressed protein spots obtained after ethanol feeding for 1 (1–3) and 3 (4–6) months. C and E represent pair-fed control and ethanol-fed rats, respectively. Highlights: ? Proteins related to ethanol-induced steatosis and mild steatohepatitis are identified. ? ADH1C and ALDH2 involved in alcohol metabolism are differentially expressed at 1 and 3 months. ? Discovery proteomics identified a group of proteins to serve as potential biomarkers. ? Using nonparametric analysis DDT is identified as a possible marker for liver damage.

  2. Fermentation method producing ethanol

    DOE Patents [OSTI]

    Wang, Daniel I. C. (Belmont, MA); Dalal, Rajen (Chicago, IL)

    1986-01-01

    Ethanol is the major end product of an anaerobic, thermophilic fermentation process using a mutant strain of bacterium Clostridium thermosaccharolyticum. This organism is capable of converting hexose and pentose carbohydrates to ethanol, acetic and lactic acids. Mutants of Clostridium thermosaccharolyticum are capable of converting these substrates to ethanol in exceptionally high yield and with increased productivity. Both the mutant organism and the technique for its isolation are provided.

  3. Brown's second alcohol fuel cookbook

    SciTech Connect (OSTI)

    Brown, M.H.

    1981-01-01

    Instructions are given for making and using various types of alcohol fuels in internal combustion engines. The distillation column is treated at some length as well as stripper columns for sugar substances, reflux ratio and proof concentration, condensers, and junkyard steam boilers. Safety features are stressed as well as plant layout. Enzymes for alcohol production and starch fermentation are described as well as commercial enzyme production, continuous fermentation, distillation of crude oil, alcohol production from cellulose (sawdust), and preparation of alcohol fuel and other products (butanol, acetone, ether) without distillation. Production of dry ice (solidified CO/sub 2/) is described. The conversion of carburetor jets in auto engines for different fuel blends, and the use of heat risers and pre-heaters to facilitate engine starting are discussed at length. In an appendix, a patent for production of acetone and alcohol by bacteriological action is included as well as congressional testimony on a hearing dealing with biomass, renewable fuel sources, fuel economy of engines and related topics. (MJJ)

  4. Solid state fermentation system for production of ethanol from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.; Lee, C.Y.; Woodams, E.E.

    1982-01-01

    A solid state fermentation system for the production of ethanol from apple pomace with a Montrachet strain of Saccharomyces cerevisiae is described. The yields of ethanol varied from about 29 g to more than 40 g/kg of apple pomace, depending on the samples fermented. Separation of up to 99% of the ethanol from spent qpple pomace was achieved with a rotary vacuum evaporator. Alcohol fermentation of apple pomace might be an efficient method of alleviating waste disposal problems with the concomitant production of ethanol.

  5. An Update on Ethanol Production and Utilization in Thailand—2014

    SciTech Connect (OSTI)

    Bloyd, Cary N.; Foster, Nikolas AF

    2014-09-01

    In spite of the recent political turmoil, Thailand has continued to develop its ethanol based alternative fuel supply and demand infrastructure. Its support of production and sales of ethanol contributed to more than doubling the production over the past five years alone. In April 2014, average consumption stood at 3.18 million liter per day- more than a third on its way to its domestic consumption goal of 9 million liters per day by 2021. Strong government incentives and the phasing out of non-blended gasoline contributed substantially. Concurrently, exports dropped significantly to their lowest level since 2011, increasing the pressure on Thai policy makers to best balance energy independency goals with other priorities, such as Thailand’s trade balance and environmental aspirations. Utilization of second generation biofuels might have the potential to further expand Thailand’s growing ethanol market. Thailand has also dramatically increased its higher ethanol blend vehicle fleet, with all new vehicles sold in the Thai market now being E20 capable and the number of E85 vehicles increasing three fold in the last year from 100,000 in 2013 to 300,000 in 2014.

  6. Catalyst Activity Comparison of Alcohols over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-01-01

    Alcohol transformation to transportation fuel range hydrocarbon on HZSM-5 (SiO2 / Al2O3 = 30) catalyst was studied at 360oC and 300psig. Product distributions and catalyst life were compared using methanol, ethanol, 1-propanol or 1-butanol as a feed. The catalyst life for 1-propanol and 1-butanol was more than double compared to that for methanol and ethanol. For all the alcohols studied, the product distributions (classified to paraffin, olefin, napthene, aromatic and naphthalene compounds) varied with time on stream (TOS). At 24 hours TOS, liquid product from 1-propanol and 1-butanol transformation primarily contains higher olefin compounds. The alcohol transformation process to higher hydrocarbon involves a complex set of reaction pathways such as dehydration, oligomerization, dehydrocyclization, and hydrogenation. Compared to ethylene generated from methanol and ethanol, oligomerization of propylene and butylene has a lower activation energy and can readily take place on weaker acidic sites. On the other hand, dehydrocyclization of propylene and butylene to form the cyclic compounds requires the sits with stronger acid strength. Combination of the above mentioned reasons are the primary reasons for olefin rich product generated in the later stage of the time on stream and for the extended catalyst life time for 1 propanol and 1 butanol compared to methanol and ethanol conversion over HZSM-5.

  7. A model system for QTL analysis: Effects of alcohol dehydrogenase genotype on alcohol pharmacokinetics

    SciTech Connect (OSTI)

    Martin, N.G.; Nightingale, B.; Whitfield, J.B.

    1994-09-01

    There is much interest in the detection of quantitative trait loci (QTL) - major genes which affect quantitative phenotypes. The relationship of polymorphism at known alcohol metabolizing enzyme loci to alcohol pharmacokinetics is a good model system. The three class I alcohol dehydrogenase genes are clustered on chromosome 4 and protein electrophoresis has revealed polymorphisms at the ADH2 and ADH3 loci. While different activities of the isozymes have been demonstrated in vitro, little work has been done in trying to relate ADH polymorphism to variation in ethanol metabolism in vivo. We previously measured ethanol metabolism and psychomotor reactivity in 206 twin pairs and demonstrated that most of the repeatable variation was genetic. We have now recontacted the twins to obtain DNA samples and used PCR with allele specific primers to type the ADH2 and ADH3 polymorphisms in 337 individual twins. FISHER has been used to estimate fixed effects of typed polymorphisms simultaneously with remaining linked and unlinked genetic variance. The ADH2*1-2 genotypes metabolize ethanol faster and attain a lower peak blood alcohol concentration than the more common ADH2*1-1 genotypes, although less than 3% of the variance is accounted for. There is no effect of ADH3 genotype. However, sib-pair linkage analysis suggests that there is a linked polymorphism which has a much greater effect on alcohol metabolism that those typed here.

  8. Ethanol Myths: Under the Microscope

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    , transport to facility, convert to ethanol, and distribute Future biomass feedstocks will come primarily from

  9. Catalyst for producing lower alcohols

    DOE Patents [OSTI]

    Rathke, Jerome W. (Bolingbrook, IL); Klingler, Robert J. (Woodridge, IL); Heiberger, John J. (Glen Ellyn, IL)

    1987-01-01

    A process and system for the production of the lower alcohols such as methanol, ethanol and propanol involves the reaction of carbon monoxide and water in the presence of a lead salt and an alkali metal formate catalyst combination. The lead salt is present as solid particles such as lead titanate, lead molybdate, lead vanadate, lead zirconate, lead tantalate and lead silicates coated or in slurry within molten alkali metal formate. The reactants, carbon monoxide and steam are provided in gas form at relatively low pressures below 100 atmospheres and at temperatures of 200-400.degree. C. The resulted lower alcohols can be separated into boiling point fractions and recovered from the excess reactants by distillation.

  10. Deficits in Eye Movement Control in Children With Fetal Alcohol Spectrum Disorders

    E-Print Network [OSTI]

    Munoz, Douglas Perry

    subjects. Conclusion: These results reflect deficits in executive function and motor control CONSEQUENCE of prenatal ethanol exposure is fetal alcohol syndrome (FAS) (Astley and Clarren, 2000; Chudley et), and deficits in these functions are now recognized as a hallmark of prenatal ethanol exposure. Individuals

  11. Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles

    SciTech Connect (OSTI)

    Karavalakis, Georgios; Durbin, Thomas; Shrivastava, ManishKumar B.; Zheng, Zhongqing; Villella, Phillip M.; Jung, Hee-Jung

    2012-03-30

    The study investigated the impact of ethanol blends on criteria emissions (THC, NMHC, CO, NOx), greenhouse gas (CO2), and a suite of unregulated pollutants in a fleet of gasoline-powered light-duty vehicles. The vehicles ranged in model year from 1984 to 2007 and included one Flexible Fuel Vehicle (FFV). Emission and fuel consumption measurements were performed in duplicate or triplicate over the Federal Test Procedure (FTP) driving cycle using a chassis dynamometer for four fuels in each of seven vehicles. The test fuels included a CARB phase 2 certification fuel with 11% MTBE content, a CARB phase 3 certification fuel with a 5.7% ethanol content, and E10, E20, E50, and E85 fuels. In most cases, THC and NMHC emissions were lower with the ethanol blends, while the use of E85 resulted in increases of THC and NMHC for the FFV. CO emissions were lower with ethanol blends for all vehicles and significantly decreased for earlier model vehicles. Results for NOx emissions were mixed, with some older vehicles showing increases with increasing ethanol level, while other vehicles showed either no impact or a slight, but not statistically significant, decrease. CO2 emissions did not show any significant trends. Fuel economy showed decreasing trends with increasing ethanol content in later model vehicles. There was also a consistent trend of increasing acetaldehyde emissions with increasing ethanol level, but other carbonyls did not show strong trends. The use of E85 resulted in significantly higher formaldehyde and acetaldehyde emissions than the specification fuels or other ethanol blends. BTEX and 1,3-butadiene emissions were lower with ethanol blends compared to the CARB 2 fuel, and were almost undetectable from the E85 fuel. The largest contribution to total carbonyls and other toxics was during the cold-start phase of FTP.

  12. Ethanol production from lignocellulose

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Wood, Brent E. (Gainesville, FL)

    2001-01-01

    This invention presents a method of improving enzymatic degradation of lignocellulose, as in the production of ethanol from lignocellulosic material, through the use of ultrasonic treatment. The invention shows that ultrasonic treatment reduces cellulase requirements by 1/3 to 1/2. With the cost of enzymes being a major problem in the cost-effective production of ethanol from lignocellulosic material, this invention presents a significant improvement over presently available methods.

  13. BLENDED AND ONLINE LEARNING IN

    E-Print Network [OSTI]

    Ellis, Randy

    ) "Flipped classroom" - focus on active learning and enhanced student engagement in the classroom #12;First dissatisfied with student learning experience #12;Blended Learning Initiative Large, first-year courses student engagement improve student learning outcomes improve knowledge retention #12;Framework for Blended

  14. Impact of demand-enhancing farm policy on the agricultural sector: a firm level simulation of ethanol production subsidies 

    E-Print Network [OSTI]

    Wasson, Leta Susanne

    1990-01-01

    to a 60 cent per gallon subsidy on each gallon of ethanol blended with gasoline. Other federal incentives include the Crude Oil Windfall Profit Tax of 1980 which gave blenders of ethanol an income tax credit and extended the gasoline tax exemption... subsidies providing for all off- highway uses of diesel fuel and gasoline to be exempt from Federal Excise taxes. Also, the Federal Crop Insurance Corporation has provided insurance against production losses due to weather and other perils at subsidized...

  15. Analysis of Fuel Ethanol Transportation Activity and Potential Distribution Constraints

    SciTech Connect (OSTI)

    Das, Sujit; Peterson, Bruce E; Chin, Shih-Miao

    2010-01-01

    This paper provides an analysis of fuel ethanol transportation activity and potential distribution constraints if the total 36 billion gallons of renewable fuel use by 2022 is mandated by EPA under the Energy Independence and Security Act (EISA) of 2007. Ethanol transport by domestic truck, marine, and rail distribution systems from ethanol refineries to blending terminals is estimated using Oak Ridge National Laboratory s (ORNL s) North American Infrastructure Network Model. Most supply and demand data provided by EPA were geo-coded and using available commercial sources the transportation infrastructure network was updated. The percentage increases in ton-mile movements by rail, waterways, and highways in 2022 are estimated to be 2.8%, 0.6%, and 0.13%, respectively, compared to the corresponding 2005 total domestic flows by various modes. Overall, a significantly higher level of future ethanol demand would have minimal impacts on transportation infrastructure. However, there will be spatial impacts and a significant level of investment required because of a considerable increase in rail traffic from refineries to ethanol distribution terminals.

  16. Separation and concentration of lower alcohols from dilute aqueous solutions

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Eakin, David E. (Kennewick, WA); Baker, Eddie G. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1991-01-01

    A process for producing, from a dilute aqueous solution of a lower (C.sub.1 -C.sub.5) alcohol, a concentrated liquid solution of the alcohol in an aromatic organic solvent is disclosed. Most of the water is removed from the dilute aqueous solution of alcohol by chilling sufficiently to form ice crystals. Simultaneously, the remaining liquid is extracted at substantially the same low temperature with a liquid organic solvent that is substantially immiscible in aqueous liquids and has an affinity for the alcohol at that temperature, causing the alcohol to transfer to the organic phase. After separating the organic liquid from the ice crystals, the organic liquid can be distilled to enrich the concentration of alcohol therein. Ethanol so separated from water and concentrated in an organic solvent such as toluene is useful as an anti-knock additive for gasoline.

  17. Decomposition method for the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    for many applications 4 · Gasoline and crude oil blending · Raw material feed scheduling · StorageDecomposition method for the Multiperiod Blending Problem Irene Lotero, Francisco Trespalacios algorithm #12;Supply Tanks (s) Blending Tanks (b) Demand Tanks (d) Multiperiod blending problem is defined

  18. Use of ethyl-t-butyl ether (ETBE) as a gasoline blending component

    SciTech Connect (OSTI)

    Shiblom, C.M.; Schoonveld, G.A.; Riley, R.K.; Pahl, R.H.

    1990-01-01

    The U.S. Treasury Department recently ruled that the ethanol blenders tax credit applies to ethanol used to make ETBE for blending with gasoline. As a result, ETBE may soon become a popular gasoline blending component. Like MTBE ETBE adds oxygen to the fuel while contributing to other performance properties of the gasoline. Phillips Petroleum Company has completed limited driveability and material compatibility studies on gasolines containing ETBE and has determined the effect on various performance parameters such as octane, volatility, and distillation of ETBE in gasoline. Levels of ETBE ranging from 0.0 to 23.5 volume percent (3.7 weight percent oxygen) in gasoline were included in the investigation. Use in gasoline is currently limited to only 12.7 volume percent (2.0 weight percent oxygen) by the gasoline substantially similar rule. No detrimental effects of the ETBE on metal or elastomeric parts common to gasoline delivery and fueling system were found. Also, several favorable blending properties of eTBE in gasoline are apparent as compared to either MTBE or ethanol. This paper presents details of these results.

  19. Production and Use of Alcohol on the Farm. 

    E-Print Network [OSTI]

    O'Neal, Henry; Rothe, Joe M.

    1981-01-01

    : '_ ? ? .r :' ' : , Production and Use of Alcohol on the Farm Henry O'Neal and Joe M. Rothe* To become energy independent, many ag ricultural producers have considered on-farm fuel production. The most popular home-made fuel is ethyl alcohol (ethanol... duction is as easy as making corn liquor. Howev er, moonshiners produce a product of only 80 to 100 proof. Modern alcohol fuel plants produce a product up to 200 proof in large quantities. Such production is not a simple operation and takes careful...

  20. Ethanol Myths Fact Sheet

    SciTech Connect (OSTI)

    None

    2009-10-27

    Ethanol is a clean, renewable fuel that is helping to reduce our nation’s dependence on oil and can offer additional economic and environmental benefits in the future. This fact sheet is intended to address some common misconceptions about this important alternative fuel.

  1. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Dahlberg, Jeff; Wolfrum, Ed

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called �dedicated bioenergy crops� including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  2. Sorghum to Ethanol Research

    SciTech Connect (OSTI)

    Jeff Dahlberg, Ph D; Ed Wolfrum, Ph D

    2010-06-30

    The development of a robust source of renewable transportation fuel will require a large amount of biomass feedstocks. It is generally accepted that in addition to agricultural and forestry residues, we will need crops grown specifically for subsequent conversion into fuels. There has been a lot of research on several of these so-called "dedicated bioenergy crops" including switchgrass, miscanthus, sugarcane, and poplar. It is likely that all of these crops will end up playing a role as feedstocks, depending on local environmental and market conditions. Many different types of sorghum have been grown to produce syrup, grain, and animal feed for many years. It has several features that may make it as compelling as other crops mentioned above as a renewable, sustainable biomass feedstock; however, very little work has been done to investigate sorghum as a dedicated bioenergy crop. The goal of this project was to investigate the feasibility of using sorghum biomass to produce ethanol. The work performed included a detailed examination of the agronomics and composition of a large number of sorghum varieties, laboratory experiments to convert sorghum to ethanol, and economic and life-cycle analyses of the sorghum-to-ethanol process. This work showed that sorghum has a very wide range of composition, which depended on the specific sorghum cultivar as well as the growing conditions. The results of laboratory- and pilot-scale experiments indicated that a typical high-biomass sorghum variety performed very similarly to corn stover during the multi-step process required to convert biomass feedstocks to ethanol; yields of ethanol for sorghum were very similar to the corn stover used as a control in these experiments. Based on multi-year agronomic data and theoretical ethanol production, sorghum can achieve more than 1,300 gallons of ethanol per acre given the correct genetics and environment. In summary, sorghum may be a compelling dedicated bioenergy crop that could help provide a major portion of the feedstocks required to produce renewable domestic transportation fuels.

  3. Federal / State Legislative & Regulatory Changes Required for...

    Office of Environmental Management (EM)

    Required for Introduction of E15 More Documents & Publications Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols High Octane Fuels Can Make Better Use of...

  4. Protective effect of tetrahydrocoptisine against ethanol-induced gastric ulcer in mice

    SciTech Connect (OSTI)

    Li, Weifeng Huang, Huimin; Niu, Xiaofeng Fan, Ting; Mu, Qingli; Li, Huani

    2013-10-01

    Excessive alcohol consumption can lead to gastric ulcer and the present work was aimed to examine the protective effect of tetrahydrocoptisine (THC) in the model of ethanol-induced gastric ulcer in mice. Fasted mice treated with ethanol 75% (0.5 ml/100 g) were pre-treated with THC (10 or 20 mg/kg, ip), cimetidine (100 mg/kg, ip) or saline in different experimental sets for a period of 3 days, and animals were euthanized 4 h after ethanol ingestion. Gross and microscopic lesions, immunological and biochemical parameters were taken into consideration. The results showed that ethanol induced gastric damage, improving nitric oxide (NO) level, increased pro-inflammatory cytokine (TNF-? and IL-6) levels and myeloperoxidase (MPO) activity, as well as the expression of nuclear factor-?B (NF-?B) in the ethanol group. Pretreatment of THC at doses of 10 and 20 mg/kg bodyweight significantly attenuated the gastric lesions as compared to the ethanol group. These results suggest that the gastroprotective activity of THC is attributed to reducing NO production and adjusting the pro-inflammatory cytokine, inhibited neutrophil accumulation and NF-?B expression. - Highlights: • THC decreased ethanol-induced pro-inflammatory cytokine release. • THC inhibited the production of NO in serum and gastric tissue. • THC reduced NF-?B expression and MPO accumulation in ethanol-induced gastric tissue.

  5. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Shao, Xiongjun; Raman, Babu; Zhu, Mingjun; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Lynd, Lee R

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1-2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  6. Mutant selection and phenotypic and genetic characterization of ethanol-tolerant strains of Clostridium thermocellum

    SciTech Connect (OSTI)

    Lynd, Lee R; Shao, Xiongjun; Raman, Babu; Mielenz, Jonathan R; Brown, Steven D; Guss, Adam M; Zhu, Mingjun

    2011-01-01

    Clostridium thermocellum is a model microorganism for converting cellulosic biomass into fuels and chemicals via consolidated bioprocessing. One of the challenges for industrial application of this organism is its low ethanol tolerance, typically 1 2% (w/v) in wild-type strains. In this study, we report the development and characterization of mutant C. thermocellum strains that can grow in the presence of high ethanol concentrations. Starting from a single colony, wild-type C. thermocellum ATCC 27405 was sub-cultured and adapted for growth in up to 50 g/L ethanol using either cellobiose or crystalline cellulose as the growth substrate. Both the adapted strains retained their ability to grow on either substrate and displayed a higher growth rate and biomass yield than the wild-type strain in the absence of ethanol. With added ethanol in the media, the mutant strains displayed an inverse correlation between ethanol concentration and growth rate or biomass yield. Genome sequencing revealed six common mutations in the two ethanol-tolerant strains including an alcohol dehydrogenase gene and genes involved in arginine/pyrimidine biosynthetic pathway. The potential role of these mutations in ethanol tolerance phenotype is discussed.

  7. Direct Conversion of Plant Biomass to Ethanol by Engineered Caldicellulosiruptor bescii

    SciTech Connect (OSTI)

    Chung, Daehwan; Cha, Minseok; Guss, Adam M; Westpheling, Janet

    2014-01-01

    Ethanol is the most widely used renewable transportation biofuel in the United States, with the production of 13.3 billion gallons in 2012 [John UM (2013) Contribution of the Ethanol Industry to the Economy of the United States]. Despite considerable effort to produce fuels from lignocellulosic biomass, chemical pretreatment and the addition of saccharolytic enzymes before microbial bioconversion remain economic barriers to industrial deployment [Lynd LR, et al. (2008) Nat Biotechnol 26(2):169-172]. We began with the thermophilic, anaerobic, cellulolytic bacterium Caldicellulosiruptor bescii, which efficiently uses unpretreated biomass, and engineered it to produce ethanol. Here we report the direct conversion of switchgrass, a nonfood, renewable feedstock, to ethanol without conventional pretreatment of the biomass. This process was accomplished by deletion of lactate dehydrogenase and heterologous expression of a Clostridium thermocellum bifunctional acetaldehyde/alcohol dehydrogenase. Whereas wild-type C. bescii lacks the ability to make ethanol, 70% of the fermentation products in the engineered strain were ethanol [12.8 mM ethanol directly from 2% (wt/vol) switchgrass, a real-world substrate] with decreased production of acetate by 38% compared with wild-type. Direct conversion of biomass to ethanol represents a new paradigm for consolidated bioprocessing, offering the potential for carbon neutral, cost-effective, sustainable fuel production.

  8. High-throughput detection of ethanol-producing cyanobacteria in a microdroplet platform

    E-Print Network [OSTI]

    Abalde-Cela, Sara; Gould, Anna; Liu, Xin; Kazamia, Elena; Smith, Alison G.; Abell, Chris

    2015-03-17

    . Both negative controls show essen- lation of cells. Those containing BG11 7. Azevedo AM, Prazeres DMF, Cabral JMS, Fonseca LP. 2005 Ethanol biosensors based on alcohol oxidase. Biosens. Bioelectron. 21, 235–247. (doi:10.1016/j. bios.2004.09.030) 8...

  9. Autothermal Partial Oxidation of Ethanol and Alcohols - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass andAtomsVehicles and Fuels Vehicles and

  10. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram: Report15 MeetingDevelopmentDepartmentof

  11. Intrinsically safe moisture blending system

    DOE Patents [OSTI]

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  12. Ethanol Consumption by Rat Dams During Gestation,

    E-Print Network [OSTI]

    Galef Jr., Bennett G.

    Ethanol Consumption by Rat Dams During Gestation, Lactation and Weaning Increases Ethanol examined effects of ethanol consumption in rat dams during gestation, lactation, and weaning on voluntary ethanol consumption by their adolescent young. We found that exposure to an ethanol-ingesting dam

  13. Ethanol production by Zymomonas mobilis

    SciTech Connect (OSTI)

    Strandberg, G.W.; Scott, C.D.; Donaldson, T.L.; Worden, R.M.

    1983-01-01

    Research progress is described on the development of laboratory-scale columnar bioreactors utilizing the flocculent bacterium, X. mobilis, for ethanol production. X. mobilis forms stable, ball-like aggregates which maintain structural integrity even when subjected to the high shear forces generated in the active 3-phase fluidized-bed reactors. Cell retention and ethanol production were studied using 3 bioreactor configurations. Ethanol productivity appeared to be primarily affected by glucose feed concentration. In addition, it was found that in the absence of nutrients, the level of ethanol productivity can be maintained for at least 1 h before a severe drop occurred. Ethanol inhibition is considered to be a limiting factor in ethanol production. (DMC)

  14. Controlling the Morphology of Polymer and Fullerene Blends in Organic Photovoltaics Through Sequential Processing and Self-Assembly

    E-Print Network [OSTI]

    Aguirre, Jordan C.

    2015-01-01

    Blend Casting . . . . . . . . . . . . . . . . . . . .Blend Casting 41 Introduction . . . . . . . . . . . . . . .and tra- ditional blend casting: Nanoscale structure and

  15. Federal and State Ethanol and Biodiesel Requirements (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    The Energy Policy Act 2005 requires that the use of renewable motor fuels be increased from the 2004 level of just over 4 billion gallons to a minimum of 7.5 billion gallons in 2012, after which the requirement grows at a rate equal to the growth of the gasoline pool. The law does not require that every gallon of gasoline or diesel fuel be blended with renewable fuels. Refiners are free to use renewable fuels, such as ethanol and biodiesel, in geographic regions and fuel formulations that make the most sense, as long as they meet the overall standard. Conventional gasoline and diesel can be blended with renewables without any change to the petroleum components, although fuels used in areas with air quality problems are likely to require adjustment to the base gasoline or diesel fuel if they are to be blended with renewables.

  16. Algenol Announces Commercial Algal Ethanol Fuel Partnership ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Algenol Announces Commercial Algal Ethanol Fuel Partnership Algenol Announces Commercial Algal Ethanol Fuel Partnership October 21, 2015 - 10:35am Addthis An error occurred. Try...

  17. Louisiana: Verenium Cellulosic Ethanol Demonstration Facility...

    Office of Environmental Management (EM)

    Louisiana: Verenium Cellulosic Ethanol Demonstration Facility Louisiana: Verenium Cellulosic Ethanol Demonstration Facility April 9, 2013 - 12:00am Addthis In 2010, Verenium...

  18. Algenol Announces Commercial Algal Ethanol Fuel Partnership ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Algenol Announces Commercial Algal Ethanol Fuel Partnership Algenol Announces Commercial Algal Ethanol Fuel Partnership October 2, 2015 - 11:28am Addthis An error occurred. Try...

  19. Ethanol production in non-recombinant hosts

    DOE Patents [OSTI]

    Kim, Youngnyun; Shanmugam, Keelnatham; Ingram, Lonnie O.

    2013-06-18

    Non-recombinant bacteria that produce ethanol as the primary fermentation product, associated nucleic acids and polypeptides, methods for producing ethanol using the bacteria, and kits are disclosed.

  20. Interactions mixing alcohol

    E-Print Network [OSTI]

    Rau, Don C.

    --including many popular painkillers and cough, cold, and allergy remedies--contain more than one ingredient. Cough syrup and laxatives may have some of the high- est alcohol concentrations. ALCOHOL AFFECTS WOMEN

  1. Corn Ethanol -April 2006 11 Cover Story

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Corn Ethanol - April 2006 11 Cover Story orn ethanol is the fuel du jour. It's domestic. It's not oil. Ethanol's going to help promote "energy independence." Magazines trumpet it as the motor vehicle Midwest fields, waiting to rot or be processed into ethanol. Interestingly, the National Corn Growers

  2. Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2 Feedstock Petroleum Petroleum & Natural Gas Natural Gas Petroleum & Coal Coal Sulfur (ppm by mass) 1148 699 19 658 22 Alkanes (% vol.) 50

  3. Ascorbic acid suppresses endotoxemia and NF-?B signaling cascade in alcoholic liver fibrosis in guinea pigs: A mechanistic approach

    SciTech Connect (OSTI)

    Abhilash, P.A.; Harikrishnan, R.; Indira, M.

    2014-01-15

    Alcohol consumption increases the small intestinal bacterial overgrowth (SIBO) and intestinal permeability of endotoxin. The endotoxin mediated inflammatory signaling plays a major role in alcoholic liver fibrosis. We evaluated the effect of ascorbic acid (AA), silymarin and alcohol abstention on the alcohol induced endotoxemia and NF-?B activation cascade pathway in guinea pigs (Cavia porcellus). Guinea pigs were administered ethanol at a daily dose of 4 g/kg b.wt for 90 days. After 90 days, ethanol administration was stopped. The ethanol treated animals were divided into abstention, silymarin (250 mg/kg b.wt) and AA (250 mg/kg b.wt) supplemented groups and maintained for 30 days. The SIBO, intestinal permeability and endotoxin were significantly increased in the ethanol group. The mRNA expressions of intestinal proteins claudin, occludin and zona occludens-1 were significantly decreased in ethanol group. The mRNA levels of inflammatory receptors, activity of IKK? and the protein expressions of phospho-I?B?, NF-?B, TNF-?, TGF-?{sub 1} and IL-6 were also altered in ethanol group. The expressions of fibrosis markers ?-SMA, ?{sub 1} (I) collagen and sirius red staining in the liver revealed the induction of fibrosis. But the supplementation of AA could induce greater reduction of ethanol induced SIBO, intestinal barrier defects, NF-?B activation and liver fibrosis than silymarin. The possible mechanism may be the inhibitory effect of AA on SIBO, intestinal barrier defect and IKK?, which decreased the activation of NF-?B and synthesis of cytokines. This might have led to suppression of HSCs activation and liver fibrosis. - Highlights: • Alcohol increases intestinal bacterial overgrowth and permeability of endotoxin. • Endotoxin mediated inflammation plays a major role in alcoholic liver fibrosis. • Ascorbic acid reduces endotoxemia, NF-?B activation and proinflammatory cytokines. • AA's action is by inhibition of SIBO, IKK? and alteration of intestinal permeability. • This might have led to suppression of HSCs activation and liver fibrosis.

  4. The role of acetate in alcohol-induced alterations of uterine glucose metabolism in the mouse during pregnancy

    SciTech Connect (OSTI)

    Simm, B. ); Murdoch, R.N. )

    1990-01-01

    The acute exposure of mice to ethanol during post-implantation pregnancy has been reported to cause alterations in the levels of several glycolytic intermediates in the uterus, suggesting a possible indirect mechanism of alcohol embryo-toxicity. The present study was undertaken to assess whether the ethanol metabolite, acetate is implicated in this phenomenon. Blood and uterine alcohol concentrations in day 9 - pregnant Quackenbush Swiss mice were maximal 15 minutes after the intraperitoneal injection of ethanol, and fell to almost negligible levels 6 hours later. In response to this treatment, the levels of blood and uterine acetate increased, liver glycogen decreased, plasma glucose increased, and uterine glucose, glucose-6-phosphate (G-6-P), fructose-6-phosphate (F-6-P), and citrate increased. When acetate was administered to pregnant mice in amounts approximating those generated by exposure to alcohol, the levels of uterine F-6-P and citrate increased while other metabolic parameters remained unaffected. The administration of 4-methylpyrazole to mice subsequently treated with alcohol produced conditions of alcohol exposure in the absence of ethanol-derived acetate and depressed the ethanol-induced rise in uterine G-6-P and citrate.

  5. Exciting careers blending engineering, science, and ecology

    E-Print Network [OSTI]

    Tullos, Desiree

    Exciting careers blending engineering, science, and ecology New Opportunities Making the world incorporate a broad range of biological systems as components, and emphasize mutual improvement of both human

  6. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    study (over 140 samples) to examine effects of several variables on Cloud Point (CP): Saturated Monoglyceride (SMG) Effects on Biodiesel Blend Low-Temperature Performance...

  7. Response of rat brain protein synthesis to ethanol and sodium barbital

    SciTech Connect (OSTI)

    Tewari, S.; Greenberg, S.A.; Do, K.; Grey, P.A.

    1987-01-01

    Central nervous system (CNS) depressants such as ethanol and barbiturates under acute or chronic conditions can induce changes in rat brain protein synthesis. While these data demonstrate the individual effects of drugs on protein synthesis, the response of brain protein synthesis to alcohol-drug interactions is not known. The goal of the present study was to determine the individual and combined effects of ethanol and sodium barbital on brain protein synthesis and gain an understanding of the mechanisms by which these alterations in protein synthesis are produced. Specifically, the in vivo and in vitro effects of sodium barbital (one class of barbiturates which is not metabolized by the hepatic tissue) were examined on brain protein synthesis in rats made physically dependent upon ethanol. Using cell free brain polysomal systems isolated from Control, Ethanol and 24 h Ethanol Withdrawn rats, data show that sodium barbital, when intubated intragastrically, inhibited the time dependent incorporation of /sup 14/C) leucine into protein by all three groups of ribosomes. Under these conditions, the Ethanol Withdrawn group displayed the largest inhibition of the /sup 14/C) leucine incorporation into protein when compared to the Control and Ethanol groups. In addition, sodium barbital when added at various concentrations in vitro to the incubation medium inhibited the incorporation of /sup 14/C) leucine into protein by Control and Ethanol polysomes. The inhibitory effects were also obtained following preincubation of ribosomes in the presence of barbital but not cycloheximide. Data suggest that brain protein synthesis, specifically brain polysomes, through interaction with ethanol or barbital are involved in the functional development of tolerance. These interactions may occur through proteins or polypeptide chains or alterations in messenger RNA components associated with the ribosomal units.

  8. Ethanol Waivers: Needed or Irrelevant? 

    E-Print Network [OSTI]

    Griffin, James M.; Dahl, Rachel

    2012-01-01

    Because of the magnitude of the existing corn harvest shortfall coupled with the large ethanol mandates, policymakers face extreme uncertainties looking into the future with potentially large economic ramifications. Precisely, because neither...

  9. A stochastic feasibility study of Texas ethanol production: analysis of Texas Legislature ethanol subsidy proposal 

    E-Print Network [OSTI]

    Gill, Robert Chope

    2002-01-01

    The recent resurgence of interest in ethanol production has prompted the Texas State Legislature to investigate the feasibility of ethanol production in Texas. The reasons for the increased interest in ethanol production ...

  10. Analyzing the effects of alcohol on IGF-I in bone and plasma and on IGF-I mRNA in the liver and bone 

    E-Print Network [OSTI]

    Stine, Christina Nicole

    2001-01-01

    ; an alcohol-fed group, a pair-fed group that was matched in energy intake to the alcohol-fed group, and a pellet-fed group that was maintained on standard rat pellets for two weeks. Food was administered according to the Lieber-Decarli technique of ethanol...

  11. Nitrate addition to groundwater impacted by ethanol-blended fuel accelerates ethanol removal and mitigates the associated

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    , Santa Catarina, Brazil b University of Exeter, Centre for Water Systems, Exeter, Devon EX4 4QF, United, Florianópolis, Santa Catarina CEP: 88040-970, Brazil. Tel.: + 55 48 3721 2130; fax: +55 48 3234 6459. E

  12. Glossary

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    A blend of finished motor gasoline and alcohol (generally ethanol but sometimes methanol) in which 10 percent or less of the product is alcohol. For the purposes of this...

  13. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be...

  14. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay...

  15. Sandia Energy - Biofuels Blend Right In: Researchers Show Ionic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Home Renewable Energy Energy Transportation Energy Biofuels...

  16. Green emitting phosphors and blends thereof

    DOE Patents [OSTI]

    Setlur, Anant Achyut (Niskayuna, NY); Siclovan, Oltea Puica (Rexford, NY); Nammalwar, Prasanth Kumar (Bangalore, IN); Sathyanarayan, Ramesh Rao (Bangalore, IN); Porob, Digamber G. (Goa, IN); Chandran, Ramachandran Gopi (Bangalore, IN); Heward, William Jordan (Saratoga Springs, NY); Radkov, Emil Vergilov (Euclid, OH); Briel, Linda Jane Valyou (Niskayuna, NY)

    2010-12-28

    Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

  17. Decomposition method for the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Decomposition method for the Multiperiod Blending Problem Francisco Trespalacios, Irene Lotero Engineering Carnegie Mellon University Pittsburgh, PA 15213 #12;2 Motivation and goals Multiperiod blending problem is a general model for many applications, and it is difficult to solve · Gasoline and crude oil

  18. PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)

    SciTech Connect (OSTI)

    CERTA, P.J.

    2006-02-22

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

  19. Viscoelastic properties of bidisperse homopolymer blends 

    E-Print Network [OSTI]

    Juliani

    2000-01-01

    Linear and nonlinear stress relaxation dynamics of well entangled polymer liquids were studied using a series of entangled, bidisperse 1,4-polybutadiene blends. Blend systems comprising high-(M[L]) and low-(M[S]) molecular weight components with M...

  20. Ethanol as Internal Standard for Quantitative Determination of Volatile Compounds in Spirit Drinks by Gas Chromatography

    E-Print Network [OSTI]

    Charapitsa, Siarhei V; Kulevich, Nikita V; Makoed, Nicolai M; Mazanik, Arkadzi L; Sytova, Svetlana N

    2012-01-01

    The new methodical approach of using ethanol as internal standard in gas chromatographic analysis of volatile compounds in spirit drinks in daily practice of testing laboratories is proposed. This method provides determination of volatile compounds concentrations in spirit drinks directly expressed in milligrams per liter (mg/L) of absolute alcohol according to official methods without measuring of alcohol strength of analyzed sample. The experimental demonstration of this method for determination of volatile compounds in spirit drinks by gas chromatography is described. Its validation was carried out by comparison with experimental results obtained by internal standard method and external standard method.

  1. Role of Nrf2 in preventing ethanol-induced oxidative stress and lipid accumulation

    SciTech Connect (OSTI)

    Wu, Kai Connie; Liu, Jie; Klaassen, Curtis D.

    2012-08-01

    Oxidative stress and lipid accumulation play important roles in alcohol-induced liver injury. Previous reports showed that, in livers of nuclear factor erythroid 2-related factor 2 (Nrf2)-activated mice, genes involved in antioxidant defense are induced, whereas genes involved in lipid biosynthesis are suppressed. To investigate the role of Nrf2 in ethanol-induced hepatic alterations, Nrf2-null mice, wild-type mice, kelch-like ECH-associated protein 1-knockdown (Keap1-KD) mice with enhanced Nrf2, and Keap1-hepatocyte knockout (Keap1-HKO) mice with maximum Nrf2 activation, were treated with ethanol (5 g/kg, po). Blood and liver samples were collected 6 h thereafter. Ethanol increased alanine aminotransferase and lactate dehydrogenase activities as well as thiobarbituric acid reactive substances in serum of Nrf2-null and wild-type mice, but not in Nrf2-enhanced mice. After ethanol administration, mitochondrial glutathione concentrations decreased markedly in Nrf2-null mice but not in Nrf2-enhanced mice. H{sub 2}DCFDA staining of primary hepatocytes isolated from the four genotypes of mice indicates that oxidative stress was higher in Nrf2-null cells, and lower in Nrf2-enhanced cells than in wild-type cells. Ethanol increased serum triglycerides and hepatic free fatty acids in Nrf2-null mice, and these increases were blunted in Nrf2-enhanced mice. In addition, the basal mRNA and nuclear protein levels of sterol regulatory element-binding protein 1(Srebp-1) were decreased with graded Nrf2 activation. Ethanol further induced Srebp-1 mRNA in Nrf2-null mice but not in Nrf2-enhanced mice. In conclusion, Nrf2 activation prevented alcohol-induced oxidative stress and accumulation of free fatty acids in liver by increasing genes involved in antioxidant defense and decreasing genes involved in lipogenesis. -- Highlights: ? Ethanol depleted mitochondrial GSH in Nrf2-null mice but not in Keap1-KD mice. ? Ethanol increased ROS in hepatocytes isolated from Nrf2-null and wild-type mice. ? Nrf2 blunted ethanol-induced increase of triglycerides and free fatty acids. ? The mRNA and nuclear protein of Srebp-1 were decreased with Nrf2 activation. ? The mRNA of Scd1 was increased in Nrf2-null mice after ethanol exposure.

  2. Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification

    SciTech Connect (OSTI)

    None

    2010-03-01

    The Biomass Program develops design cases to understand the current state of conversion technologies and to determine where improvements need to take place in the future. This design case establishes cost targets for converting MSW to ethanol and other mixed alcohols via gasification.

  3. Alcohol chemical vapor deposition growth of millimeter-sized single-crystal of graphene

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Alcohol chemical vapor deposition growth of millimeter-sized single-crystal of graphene Sungjin Kim@photon,t,u-tokyo.ac.jp Abstract: The growth of large-sized single crystalline graphene with mono layer is necessary for large-scale integration of graphene devices. Ethanol as a precursor has proven effective in the chemical vapor deposition

  4. ORIGINAL ARTICLE Utilization of diets containing graded levels of ethanol

    E-Print Network [OSTI]

    ORIGINAL ARTICLE Utilization of diets containing graded levels of ethanol production co to manufacture fuel ethanol (Rosentrater and Muthukumarappan, 2006). In 2008, 174 operating ethanol plants.1 billion liters (RFA, 2009). With this exponential growth in ethanol production, significant quantities

  5. Feasibility study of a corn-to-ethanol plant in Sardis, Mississippi

    SciTech Connect (OSTI)

    Not Available

    1982-06-01

    A technical description of a chemical processing facility capable of producing 5 million gallons per year of denatured anhydrous ethanol (power alcohol) is presented. In addition, certain equipment options are evaluated on the basis of availability, reliability, and budget constraints. Analysis of logistics and sensitivity of financial decision making criteria to market variables is not within the scope of this study. Consequently, concluding statements are limited to a discussion of technical feasibility and a statement of capital cost for turn-key construction.

  6. Ethanol production method and system

    DOE Patents [OSTI]

    Chen, M.J.; Rathke, J.W.

    1983-05-26

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  7. Furfuryl alcohol cellular product

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-05-26

    Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

  8. Biofuel alternatives to ethanol: pumping the microbial well

    E-Print Network [OSTI]

    Fortman, J.L.

    2011-01-01

    Biofuel alternatives to ethanol: pumping the microbialtechnologies that enable biofuel production. Decades of workstrategy for producing biofuel. Although ethanol currently

  9. Transportation risk assessment for ethanol transport 

    E-Print Network [OSTI]

    Shelton Davis, Anecia Delaine

    2008-10-10

    This research is aimed at assessing the quantitative risks involved with an ethanol pipeline. Pipelines that run from the Midwest, where the vast majority of ethanol is produced, to the target areas where reformulated gasoline is required...

  10. Transportation risk assessment for ethanol transport 

    E-Print Network [OSTI]

    Shelton Davis, Anecia Delaine

    2009-05-15

    This research is aimed at assessing the quantitative risks involved with an ethanol pipeline. Pipelines that run from the Midwest, where the vast majority of ethanol is produced, to the target areas where reformulated gasoline is required...

  11. Ethanol's Effect on Grain Supply and Prices

    SciTech Connect (OSTI)

    2008-01-01

    This document provides graphical information about ethanol's effect on grain supply and prices, uses of corn, and grain price trends.

  12. Re-engineering bacteria for ethanol production

    DOE Patents [OSTI]

    Yomano, Lorraine P; York, Sean W; Zhou, Shengde; Shanmugam, Keelnatham; Ingram, Lonnie O

    2014-05-06

    The invention provides recombinant bacteria, which comprise a full complement of heterologous ethanol production genes. Expression of the full complement of heterologous ethanol production genes causes the recombinant bacteria to produce ethanol as the primary fermentation product when grown in mineral salts medium, without the addition of complex nutrients. Methods for producing the recombinant bacteria and methods for producing ethanol using the recombinant bacteria are also disclosed.

  13. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  14. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  15. Electrooxidation of Alcohols Catalyzed by Amino Alcohol Ligated Ruthenium Complexes

    E-Print Network [OSTI]

    Zare, Richard N.

    Alcohols are attractive chemical fuels for fuel cells due to their high energy densities, established, even the most highly optimized alcohol electrooxidation catalysts suffer from kinetic limitations

  16. Effects of ethanol preservation on otolith microchemistry

    E-Print Network [OSTI]

    Effects of ethanol preservation on otolith microchemistry K. J. HEDGES*, S. A. LUDSIN*§ AND B. J coupled plasma-mass spectrometry was used to examine the effects of exposure time to ethanol (0, 1, 3, 9, 27 and 81 days) and ethanol quality (ACS- v. HPLC- grade) on strontium (Sr) and barium (Ba

  17. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures

    Office of Energy Efficiency and Renewable Energy (EERE)

    Alcohols as gasoline blending agent at up to 85 vol-% levels were evaluated in a 2.2L direct injection SI engine for combustion, engine efficiency, and engine-out emissions effects at steady-state and transient test conditions

  18. Marshall University Ethyl Alcohol

    E-Print Network [OSTI]

    Sanyal, Suman

    or obliterate the marks, brand, and labels required by this chapter to be placed on packages of tax-free alcohol. (b) A person may not destroy or obliterate the marks, brands or labels until the package or drum has and brands. (a) Any person who empties a package containing tax-free alcohol shall immediately destroy

  19. Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes

    SciTech Connect (OSTI)

    Boehm, H.; Braun-Unkhoff, M.

    2008-04-15

    This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

  20. BLENDING PROBLEM A refinery blends four petroleum components into three grades of

    E-Print Network [OSTI]

    Shier, Douglas R.

    BLENDING PROBLEM A refinery blends four petroleum components into three grades of gasoline/day $/barrel #1 5,000 $9.00 #2 2,400 7.00 #3 4,000 12.00 #4 1,500 6.00 Blending formulas and selling price 4,000 x4R + x4P + x4L 1,500 #12;blending: (1) x1R / (x1R + x2R + x3R + x4R) .40 or x1R .40(x1R

  1. Continuous blending of dry pharmaceutical powders

    E-Print Network [OSTI]

    Pernenkil, Lakshman

    2008-01-01

    Conventional batch blending of pharmaceutical powders coupled with long quality analysis times increases the production cycle time leading to strained cash flows. Also, scale-up issues faced in process development causes ...

  2. Carnegie Mellon Multiperiod Blend Scheduling Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Department of Chemical Engineering Center for Advanced Process Decision-making Carnegie Mellon University frequently in the petrochemical industry. -Large cost savings can be achieved if the correct blending

  3. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office�¢����s (SEO) primary mission is to implement cost�¢���effective, reliable, balanced, and environmentally�¢���friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  4. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  5. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  6. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlenderBusiness Case for E85 FuelDispenser

  7. Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlenderBusiness Case forbutton highlightedPublicD, Table

  8. Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlenderBusiness Case forbutton highlightedPublicD, TableA2:

  9. Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlenderBusiness Case forbutton highlightedPublicD,

  10. Blending World MapBlending World Map ProjectionsProjections Bernhard Jenny, Oregon State University, USA

    E-Print Network [OSTI]

    Clarke, Keith

    Blending World MapBlending World Map ProjectionsProjections Bernhard Jenny, Oregon State University via combination of two projections is well established. Some of the most popular world map projections Tripel projection). These two methods for creating new world map projections are included in the latest

  11. Activation of farnesoid X receptor attenuates hepatic injury in a murine model of alcoholic liver disease

    SciTech Connect (OSTI)

    Wu, Weibin; Institutes of Biomedical Science, Fudan University, Shanghai 200032 ; Zhu, Bo; Peng, Xiaomin; Zhou, Meiling; Jia, Dongwei; Gu, Jianxin; Institutes of Biomedical Science, Fudan University, Shanghai 200032

    2014-01-03

    Highlights: •FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. •Activation of FXR attenuated alcohol-induced liver injury and steatosis. •Activation of FXR attenuated cholestasis and oxidative stress in mouse liver. -- Abstract: Alcoholic liver disease (ALD) is a common cause of advanced liver disease, and considered as a major risk factor of morbidity and mortality worldwide. Hepatic cholestasis is a pathophysiological feature observed in all stages of ALD. The farnesoid X receptor (FXR) is a member of the nuclear hormone receptor superfamily, and plays an essential role in the regulation of bile acid, lipid and glucose homeostasis. However, the role of FXR in the pathogenesis and progression of ALD remains largely unknown. Mice were fed Lieber-DeCarli ethanol diet or an isocaloric control diet. We used a specific agonist of FXR WAY-362450 to study the effect of pharmacological activation of FXR in alcoholic liver disease. In this study, we demonstrated that FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. Activation of FXR by specific agonist WAY-362450 protected mice from the development of ALD. We also found that WAY-362450 treatment rescued FXR activity, suppressed ethanol-induced Cyp2e1 up-regulation and attenuated oxidative stress in liver. Our results highlight a key role of FXR in the modulation of ALD development, and propose specific FXR agonists for the treatment of ALD patients.

  12. Elimination of hydrogenase post-translational modification blocks H2 production and increases ethanol yield in Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Zheng, Tianyong; Olson, Daniel G.; Lynd, Lee R; Guss, Adam M

    2015-01-01

    The native ability of Clostridium thermocellum to rapidly consume cellulose and produce ethanol makes it a leading candidate for a consolidated bioprocessing (CBP) biofuel production strategy. C. thermocellum also synthesizes lactate, formate, acetate, H2, and amino acids that compete with ethanol production for carbon and electrons. Elimination of H2 production could redirect carbon flux towards ethanol production by making more electrons available for acetyl-CoA reduction to ethanol. C. thermocellum encodes four hydrogenases and rather than delete each individually, we targeted a hydrogenase maturase gene (hydG), involved in converting the three [FeFe] hydrogenase apoenzymes into holoenzymes. Further deletion of the [NiFe] hydrogenase (ech) resulted in a mutant that functionally lacks all four hydrogenases. H2 production in hydG ech was undetectable and ethanol yield increased nearly 2-fold compared to wild type. Interestingly, mutant growth improved upon the addition of acetate, which led to increased expression of genes related to sulfate metabolism, suggesting these mutants may use sulfate as a terminal electron acceptor to balance redox reactions. Genomic analysis of hydG revealed a mutation in adhE, resulting in a strain with both NADH- and NADPH-dependent alcohol dehydrogenase activities. While this same adhE mutation is found in ethanol tolerant C. thermocellum strain E50C, hydG and hydG ech are not more ethanol tolerant than wild type, illustrating the complicated interactions between redox balancing and ethanol tolerance in C. thermocellum. The dramatic increase in ethanol production here suggests that targeting protein post-translational modification is a promising new approach for inactivation of multiple enzymes simultaneously for metabolic engineering.

  13. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330°C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  14. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  15. Ethanol annual report FY 1990

    SciTech Connect (OSTI)

    Texeira, R.H.; Goodman, B.J.

    1991-01-01

    This report summarizes the research progress and accomplishments of the US Department of Energy (DOE) Ethanol from Biomass Program, field managed by the Solar Energy Research Institute, during FY 1990. The report includes an overview of the entire program and summaries of individual research projects. These projects are grouped into the following subject areas: technoeconomic analysis; pretreatment; cellulose conversion; xylose fermentation; and lignin conversion. Individual papers have been indexed separately for inclusion on the data base.

  16. Bioenergy Impacts … Cellulosic Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Researchof Energy|Make Fuels andfor its cellulosic ethanol

  17. Alternative Fuels Data Center: Ethanol

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places toEthanol Printable Version Share

  18. Diagram of the Biofuel Production Process (SPORL -Alcohol Production):Introduction: The Northwest Advanced Renewables Alliance (NARA) is an organization

    E-Print Network [OSTI]

    Collins, Gary S.

    Pretreatment for Cellulosic Ethanol Production: Technology and Energy Consumption Evaluation." BioresourceDiagram of the Biofuel Production Process (SPORL - Alcohol Production):Introduction: The Northwest production industry in the Northwest United States. One of NARA's goals is to develop a production process

  19. Food for fuel: The price of ethanol

    E-Print Network [OSTI]

    Albino, Dominic K; Bar-Yam, Yaneer

    2012-01-01

    Conversion of corn to ethanol in the US since 2005 has been a major cause of global food price increases during that time and has been shown to be ineffective in achieving US energy independence and reducing environmental impact. We make three key statements to enhance understanding and communication about ethanol production's impact on the food and fuel markets: (1) The amount of corn used to produce the ethanol in a gallon of regular gas would feed a person for a day, (2) The production of ethanol is so energy intensive that it uses only 20% less fossil fuel than gasoline, and (3) The cost of gas made with ethanol is actually higher per mile because ethanol reduces gasoline's energy per gallon.

  20. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  1. The Role of Cellulosic Ethanol in Transportation

    SciTech Connect (OSTI)

    Robert M. Neilson, Jr.

    2007-10-01

    Petroleum provides essentially all of the energy used today in the transportation sector. To reduce this dependence on fossil energy, other fuels are beginning to be used, notably ethanol and biodiesel. Almost all fuel ethanol is produced by the conversion of corn grain to starch with subsequent fermentation to ethanol. In 2006, almost 5 billion gallons of fuel ethanol were produced, which used 17% of domestic corn production. The DOE has a goal to displace 30% of motor gasoline demand or 60 billion gallons per year by 2030. To achieve this goal, production of ethanol from lignocellulosic sources (e.g., agricultural residues, forest residues, and dedicated energy crops) is needed. This paper will describe the production of cellulosic ethanol as well as the issues and benefits associated with its production.

  2. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  3. Blending of diblock and triblock copolypeptide amphiphiles yields cell penetrating vesicles with low toxicity

    E-Print Network [OSTI]

    2015-01-01

    vesicles by blending of different component amphiphilescomponents. [9] In these studies, an important requirement for successful blending

  4. Innovative Breakthrough Demonstrated for Biological Ethanol Production...

    Broader source: Energy.gov (indexed) [DOE]

    nearly doubled bio-ethanol productivity, increased conversion yields, and minimized microbial contaminants. The process showed increased productivity and efficiency, therefore...

  5. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, Lars G. (Athens, GA); Carriera, Laura H. (Athens, GA)

    1983-01-01

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  6. High ethanol producing derivatives of Thermoanaerobacter ethanolicus

    DOE Patents [OSTI]

    Ljungdahl, L.G.; Carriera, L.H.

    1983-05-24

    Derivatives of the newly discovered microorganism Thermoanaerobacter ethanolicus which under anaerobic and thermophilic conditions continuously ferment substrates such as starch, cellobiose, glucose, xylose and other sugars to produce recoverable amounts of ethanol solving the problem of fermentations yielding low concentrations of ethanol using the parent strain of the microorganism Thermoanaerobacter ethanolicus are disclosed. These new derivatives are ethanol tolerant up to 10% (v/v) ethanol during fermentation. The process includes the use of an aqueous fermentation medium, containing the substrate at a substrate concentration greater than 1% (w/v).

  7. Ethanol: Producting Food, Feed, and Fuel

    Broader source: Energy.gov [DOE]

    At the August 7, 2008 joint quarterly Web conference of DOE's Biomass and Clean Cities programs, Todd Sneller (Nebraska Ethanol Board) discussed the food versus fuel issue.

  8. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were...

  9. Exploration of parameters for the continuous blending of pharmaceutical powders

    E-Print Network [OSTI]

    Lin, Ben Chien Pang

    2011-01-01

    The transition from traditional batch blending to continuous blending is an opportunity for the pharmaceutical industry to reduce costs and improve quality control. This operational shift necessitates a deeper understanding ...

  10. Natural and Anthropogenic Ethanol Sources in North America and Potential Atmospheric Impacts of Ethanol

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    S1 Natural and Anthropogenic Ethanol Sources in North America and Potential Atmospheric Impacts of Ethanol Fuel Use Dylan B. Millet*,1 , Eric Apel2 , Daven K. Henze3 , Jason Hill1 , Julian D. Marshall1 INFORMATION Supporting Information contains a total of 12 pages, 1 table, and 7 figures. 1. AIRBORNE ETHANOL

  11. Natural and Anthropogenic Ethanol Sources in North America and Potential Atmospheric Impacts of Ethanol Fuel Use

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    Natural and Anthropogenic Ethanol Sources in North America and Potential Atmospheric Impacts of Ethanol Fuel Use Dylan B. Millet,*, Eric Apel, Daven K. Henze,§ Jason Hill, Julian D. Marshall, Hanwant B-Chem chemical transport model to constrain present-day North American ethanol sources, and gauge potential long

  12. Mississippi Ethanol Gasification Project, Final Scientific / Technical Report

    SciTech Connect (OSTI)

    Pearson, Larry, E.

    2007-04-30

    The Mississippi Ethanol (ME) Project is a comprehensive effort to develop the conversion of biomass to ethanol utilizing a proprietary gasification reactor technology developed by Mississippi Ethanol, LLC. Tasks were split between operation of a 1/10 scale unit at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) of Mississippi State University (MSU) and the construction, development, and operation of a full scale pilot unit located at the ME facility in Winona, Mississippi. In addition to characterization of the ME reactor gasification system, other areas considered critical to the operational and economic viability of the overall ME concept were evaluated. These areas include syngas cleanup, biological conversion of syngas to alcohol, and effects of gasification scale factors. Characterization of run data from the Pre-Pilot and Pilot Units has allowed development of the factors necessary for scale-up from the small unit to the larger unit. This scale range is approximately a factor of 10. Particulate and tar sampling gave order of magnitude values for preliminary design calculations. In addition, sampling values collected downstream of the ash removal system show significant reductions in observed loadings. These loading values indicate that acceptable particulate and tar loading rates could be attained with standard equipment additions to the existing configurations. Overall operation both the Pre-Pilot and Pilot Units proceeded very well. The Pilot Unit was operated as a system, from wood receiving to gas flaring, several times and these runs were used to address possible production-scale concerns. Among these, a pressure feed system was developed to allow feed of material against gasifier system pressure with little or no purge requirements. Similarly, a water wash system, with continuous ash collection, was developed, installed, and tested. Development of a biological system for alcohol production was conducted at Mississippi State University with much progress. However, the current state of biological technology is not deemed to be ready commercially. A preliminary estimate of capital and operating costs of a 12000 gallon per day gasification/biological facility was developed for comparison purposes. In addition, during the biological organism screening and testing, some possible alternative products were identified. One such possibility is the biological production of bio-diesel. Additional research is necessary for further evaluation of all of the biological concepts.

  13. Observational constraints on the global atmospheric budget of ethanol

    E-Print Network [OSTI]

    2010-01-01

    global atmospheric budget of ethanol V. Naik 1,2,* , A. M.nitrate formation from ethanol-fueled ve- hicular emissions,A. : Ambient concentrations of ethanol and methyl tert-butyl

  14. Effects of ethanol and reactive species on Hepatitis C virus

    E-Print Network [OSTI]

    Seronello, Scott E.

    2010-01-01

    Barlow, M. ; Choi, J. (2010) Ethanol and both endogenous andT. , and Choi, J. (2010) Ethanol enhances hepatitis C virusthe levels of NADH like ethanol but generates acetone

  15. Blended Shelf: Reality-based Presentation and Exploration of Library

    E-Print Network [OSTI]

    Reiterer, Harald

    Blended library; shelf browsing; digital library ACM Classification Keywords H.5.2. [InformationBlended Shelf: Reality-based Presentation and Exploration of Library Collections Abstract We location of the library. Blended Shelf offers a 3D visualization of library collections

  16. FOREST ENTOMOLOGY Blending Synthetic Pheromones of Cerambycid Beetles to Develop

    E-Print Network [OSTI]

    Hanks, Lawrence M.

    (F.),Neoclytusmucronatus(F.),andXylotrechuscolonus(F.).Beetlesofthesespecieswere signiÞcantly attracted to synthetic blends that contained their pheromone components (isomers of 3FOREST ENTOMOLOGY Blending Synthetic Pheromones of Cerambycid Beetles to Develop Trap Lures.1603/EC11434 ABSTRACT We evaluated attraction of cerambycid beetle species to blends of known cerambycid

  17. A Novel Global Optimization Approach to the Multiperiod Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ­ Overall Flows ­ Individual Components (Blending) · Flow/Inventory Bounds · Operational ConstraintsA Novel Global Optimization Approach to the Multiperiod Blending Problem Scott Kolodziej Advisor · Maximum total profit of blending operation Fs3,t Cs3 Fs2,t Cs2 Fd1,t CL d1-CU d1 Fd2,t CL d2-CU d2 Fd3,t

  18. The viscoelastic properties of linear-star blends 

    E-Print Network [OSTI]

    Lee, Jung Hun

    2000-01-01

    prediction for linear-star blend than the existing blend model. Due to the simplified scaling for constraint release, the generality of the linear-star blend model of present work is limited only for the high ML and low [Ø]S. Even though such restriction...

  19. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  20. Diversified Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstrumentsArea (DOE GTP)DisplacementTudorOpen EnergyPage EditEthanol

  1. Orion Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg, Oregon:OGEProjects/DefinitionsOrchidx AmericaOrion Ethanol

  2. Ethanol Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpA Jump to:EnergyEthanol Ventures Place: London,

  3. Dakota Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstruments Inc Jump to:67-2006-12DabbrookAssociation Jump to:Ethanol

  4. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, Paul T. (Arlington Heights, IL)

    1996-01-01

    A process is provided for the production of branched C.sub.4+ oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  5. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, P.T.

    1996-09-24

    A process is provided for the production of branched C{sub x} oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  6. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B:...

  7. Infrastructure Requirements for an Expanded Fuel Ethanol Industry

    SciTech Connect (OSTI)

    Reynolds, Robert E.

    2002-01-15

    This report provides technical information specifically related to ethanol transportation, distribution, and marketing issues. This report required analysis of the infrastructure requirements for an expanded ethanol industry.

  8. Review of Recent Pilot Scale Cellulosic Ethanol Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Review of Recent Pilot Scale Cellulosic Ethanol Demonstration Opening Plenary Session: Celebrating Successes-The...

  9. Reaction Rates and Catalysts in Ethanol Production (1 Activity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reaction Rates and Catalysts in Ethanol Production (1 Activity) Reaction Rates and Catalysts in Ethanol Production (1 Activity) Below is information about the student activity...

  10. Report to Congress: Dedicated Ethanol Pipeline Feasability Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report to Congress: Dedicated Ethanol Pipeline Feasability Study - Energy Independence and Security Act of 2007 Section 243 Report to Congress: Dedicated Ethanol Pipeline...

  11. Dispensing Equipment Testing With Mid-Level Ethanol/Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid Dispensing Equipment Testing With Mid-Level EthanolGasoline Test Fluid The National Renewable Energy...

  12. Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress...

    Office of Scientific and Technical Information (OSTI)

    Systems biology analysis of Zymomonas mobilis ZM4 ethanol stress responses Citation Details In-Document Search Title: Systems biology analysis of Zymomonas mobilis ZM4 ethanol...

  13. Biofuel alternatives to ethanol: pumping the microbial well

    E-Print Network [OSTI]

    Fortman, J. L.

    2010-01-01

    2007) Cellulosic ethanol: biofuel researchers prepare toBiofuel alternatives to ethanol: pumping the microbial welltechnologies that enable biofuel production. Decades of work

  14. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  15. BIODIESEL BLENDS IN SPACE HEATING EQUIPMENT.

    SciTech Connect (OSTI)

    KRISHNA,C.R.

    2001-12-01

    Biodiesel is a diesel-like fuel that is derived from processing vegetable oils from various sources, such as soy oil, rapeseed or canola oil, and also waste vegetable oils resulting from cooking use. Brookhaven National laboratory initiated an evaluation of the performance of blends of biodiesel and home heating oil in space heating applications under the sponsorship of the Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL). This report is a result of this work performed in the laboratory. A number of blends of varying amounts of a biodiesel in home heating fuel were tested in both a residential heating system and a commercial size boiler. The results demonstrate that blends of biodiesel and heating oil can be used with few or no modifications to the equipment or operating practices in space heating. The results also showed that there were environmental benefits from the biodiesel addition in terms of reductions in smoke and in Nitrogen Oxides (NOx). The latter result was particularly surprising and of course welcome, in view of the previous results in diesel engines where no changes had been seen. Residential size combustion equipment is presently not subject to NOx regulation. If reductions in NOx similar to those observed here hold up in larger size (commercial and industrial) boilers, a significant increase in the use of biodiesel-like fuel blends could become possible.

  16. Market penetration of biodiesel and ethanol 

    E-Print Network [OSTI]

    Szulczyk, Kenneth Ray

    2007-09-17

    that for the ranges studied, gasoline prices have a major impact on aggregate ethanol production but only at low prices. At higher prices, one runs into a capacity constraint that limits expansion on the capacity of ethanol production. Aggregate biodiesel production...

  17. Ethanol Production: Energy, Economic, and Environmental Losses

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    of biomass convert solar energy into plant material, but this conversion requires suitable soil, nutrients.1% of the solar energy. Two early studies by the U.S. Department of Energy (USDOE) con- cerning ethanol productionEthanol Production: Energy, Economic, and Environmental Losses David Pimentel, Tad Patzek

  18. Ethanol production using engineered mutant E. coli

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Clark, David P. (Carbondale, IL)

    1991-01-01

    The subject invention concerns novel means and materials for producing ethanol as a fermentation product. Mutant E. coli are transformed with a gene coding for pyruvate decarboxylase activity. The resulting system is capable of producing relatively large amounts of ethanol from a variety of biomass sources.

  19. Outlook for Biomass Ethanol Production and Demand

    Reports and Publications (EIA)

    2000-01-01

    This paper presents a midterm forecast for biomass ethanol production under three different technology cases for the period 2000 to 2020, based on projections developed from the Energy Information Administration's National Energy Modeling System. An overview of cellulose conversion technology and various feedstock options and a brief history of ethanol usage in the United States are also presented.

  20. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution.

  1. Dual-fueling turbocharged diesels with ethanol

    SciTech Connect (OSTI)

    Cruz, J.M.; Rotz, C.A.; Watson, D.H.

    1982-09-01

    Spray addition and carburetion methods were tested for dual-fueling a turbocharged, 65 kW diesel tractor. Approximately 30 percent of the fuel energy for the tractor was supplied by spraying ethanol into the intake air and about 46 percent by carburetion with little affect on the engine thermal efficiency. Further substitution of diesel fuel with ethanol was limited by knock. As the amount of ethanol fed into the engine was increased, ignition apparently changed from the steady burning process which normally occurs in a diesel engine to a rapid explosion which caused knock. The best fuel for the spray approach was a 50 percent ethanol/water solution and with the carburetor it was an 80 percent ethanol/water solution. (Refs. 6).

  2. High Ethanol Fuel Endurance: A Study of the Effects of Running Gasoline with 15% Ethanol Concentration in Current Production Outboard Four-Stroke Engines and Conventional Two-Stroke Outboard Marine Engines

    SciTech Connect (OSTI)

    Hilbert, D.

    2011-10-01

    Three Mercury Marine outboard marine engines were evaluated for durability using E15 fuel -- gasoline blended with 15% ethanol. Direct comparison was made to operation on E0 (ethanol-free gasoline) to determine the effects of increased ethanol on engine durability. Testing was conducted using a 300-hour wide-open throttle (WOT) test protocol, a typical durability cycle used by the outboard marine industry. Use of E15 resulted in reduced CO emissions, as expected for open-loop, non-feedback control engines. HC emissions effects were variable. Exhaust gas and engine operating temperatures increased as a consequence of leaner operation. Each E15 test engine exhibited some deterioration that may have been related to the test fuel. The 9.9 HP, four-stroke E15 engine exhibited variable hydrocarbon emissions at 300 hours -- an indication of lean misfire. The 300HP, four-stroke, supercharged Verado engine and the 200HP, two-stroke legacy engine tested with E15 fuel failed to complete the durability test. The Verado engine failed three exhaust valves at 285 endurance hours while the 200HP legacy engine failed a main crank bearing at 256 endurance hours. All E0-dedicated engines completed the durability cycle without incident. Additional testing is necessary to link the observed engine failures to ethanol in the test fuel.

  3. Ethanol from sugar cane: flask experiments using the EX-FERM technique

    SciTech Connect (OSTI)

    Rolz, C.; Cabrera, S.

    1980-09-01

    Alcohol production at the laboratory scale from sugar cane pieces by the EX-FERM technique was studied with 37 strains of Saccharomyces spp. The EX-FERM process is novel in that it employs the simultaneous extraction and fermentation of the sucrose in a cane-water suspension. The final ethanol concentration reached 4.27 to 5.37g per 100 ml, and sugar consumption was above 98% in three cases during a second EX-FERM cycle employing previously air-dried chips and pith. Product yields were within accepted values. Cane treatment did not appear to affect the results at this level.

  4. Production of ethanol from refinery waste gases. Phase 3. Engineering development. Annual report, April 1, 1995--May 15, 1996

    SciTech Connect (OSTI)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C; Gaddy, J.L.

    1996-11-01

    Refineries discharge large volumes of H2, CO, and CO 2 from cracking, coking, and hydrotreating operations. This R&D program seeks to develop, demonstrate, and commercialize a biological process for converting these waste gases into ethanol for blending with gasoline. A 200,000 BPD refinery could produce up to 38 million gallons ethanol per year. The program is being conducted in 3 phases: II, technology development; III, engineering development; and IV, demonstration. Phase I, exploratory development, has been completed. The research effort has yielded two strains (Isolates O-52 and C-01) which are to be used in the pilot studies to produce ethanol from CO, CO2, and H2 in petroleum waste gas. Results from single continuous stirred tank reactor (CSTR) laboratory tests have shown that 20-25 g/L ethanol can be produced with < 5 g/L acetic acid byproduct. Laboratory studies with two CSTRs in series have yielded ethanol concentrations of 30-35 g/L with 2-4 g/L acetic acid byproduct. Water recycle from distillation back to the fermenter shows that filtration of the water before distillation eliminates the recycle of toxic materials back to the fermenter. Product recovery in the process will use direct distillation to the azeotrope, followed by adsorption to produce neat ethanol. This is less energy intensive than e.g. solvent extraction, azeotropic distillation, or pervaporation. Economic projections are quite attractive; the economics are refinery stream dependent and thus vary depending on refinery location and operation.

  5. Ethanol Distribution, Dispensing, and Use: Analysis of a Portion of the Biomass-to-Biofuels Supply Chain Using System Dynamics

    SciTech Connect (OSTI)

    Vimmerstedt, L. J.; Bush, B.; Peterson, S.

    2012-05-01

    The Energy Independence and Security Act of 2007 targets use of 36 billion gallons of biofuels per year by 2022. Achieving this may require substantial changes to current transportation fuel systems for distribution, dispensing, and use in vehicles. The U.S. Department of Energy and the National Renewable Energy Laboratory designed a system dynamics approach to help focus government action by determining what supply chain changes would have the greatest potential to accelerate biofuels deployment. The National Renewable Energy Laboratory developed the Biomass Scenario Model, a system dynamics model which represents the primary system effects and dependencies in the biomass-to-biofuels supply chain. The model provides a framework for developing scenarios and conducting biofuels policy analysis. This paper focuses on the downstream portion of the supply chain-represented in the distribution logistics, dispensing station, and fuel utilization, and vehicle modules of the Biomass Scenario Model. This model initially focused on ethanol, but has since been expanded to include other biofuels. Some portions of this system are represented dynamically with major interactions and feedbacks, especially those related to a dispensing station owner's decision whether to offer ethanol fuel and a consumer's choice whether to purchase that fuel. Other portions of the system are modeled with little or no dynamics; the vehicle choices of consumers are represented as discrete scenarios. This paper explores conditions needed to sustain an ethanol fuel market and identifies implications of these findings for program and policy goals. A large, economically sustainable ethanol fuel market (or other biofuel market) requires low end-user fuel price relative to gasoline and sufficient producer payment, which are difficult to achieve simultaneously. Other requirements (different for ethanol vs. other biofuel markets) include the need for infrastructure for distribution and dispensing and widespread use of high ethanol blends in flexible-fuel vehicles.

  6. Hepatic lipid profiling of deer mice fed ethanol using {sup 1}H and {sup 31}P NMR spectroscopy: A dose-dependent subchronic study

    SciTech Connect (OSTI)

    Fernando, Harshica; Bhopale, Kamlesh K.; Boor, Paul J.; Ansari, G.A. Shakeel; Kaphalia, Bhupendra S.

    2012-11-01

    Chronic alcohol abuse is a 2nd major cause of liver disease resulting in significant morbidity and mortality. Alcoholic liver disease (ALD) is characterized by a wide spectrum of pathologies starting from fat accumulation (steatosis) in early reversible stage to inflammation with or without fibrosis and cirrhosis in later irreversible stages. Previously, we reported significant steatosis in the livers of hepatic alcohol dehydrogenase (ADH)-deficient (ADH{sup ?}) vs. hepatic ADH-normal (ADH{sup +}) deer mice fed 4% ethanol daily for 2 months [Bhopale et al., 2006, Alcohol 39, 179–188]. However, ADH{sup ?} deer mice fed 4% ethanol also showed a significant mortality. Therefore, a dose-dependent study was conducted to understand the mechanism and identify lipid(s) involved in the development of ethanol-induced fatty liver. ADH{sup ?} and ADH{sup +} deer mice fed 1, 2 or 3.5% ethanol daily for 2 months and fatty infiltration in the livers were evaluated by histology and by measuring dry weights of extracted lipids. Lipid metabolomic changes in extracted lipids were determined by proton ({sup 1}H) and {sup 31}phosphorus ({sup 31}P) nuclear magnetic resonance (NMR) spectroscopy. The NMR data was analyzed by hierarchical clustering (HC) and principle component analysis (PCA) for pattern recognition. Extensive vacuolization by histology and significantly increased dry weights of total lipids found only in the livers of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls suggest a dose-dependent formation of fatty liver in ADH{sup ?} deer mouse model. Analysis of NMR data of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls shows increases for total cholesterol, esterified cholesterol, fatty acid methyl esters (FAMEs), triacylglycerides and unsaturation, and decreases for free cholesterol, phospholipids and allylic and diallylic protons. Certain classes of neutral lipids (cholesterol esters, fatty acyl chain (-COCH{sub 2}-) and FAMEs) were also mildly increased in ADH{sup ?} deer mice fed 1 or 2% ethanol. Only small increases were observed for allylic and diallylic protons, FAMEs and unsaturations in ADH{sup +} deer mice fed 3.5% ethanol vs. pair-fed controls. PCA of NMR data showed increased clustering by gradual separation of ethanol-fed ADH{sup ?} deer mice groups from their respective pair-fed control groups and corresponding ethanol-fed ADH{sup +} deer mice groups. Our data indicate that dose of ethanol and hepatic ADH deficiency are two key factors involved in initiation and progression of alcoholic fatty liver disease. Further studies on characterization of individual lipid entities and associated metabolic pathways altered in our deer mouse model after different durations of ethanol feeding could be important to delineate mechanism(s) and identify potential biomarker candidate(s) of early stage ALD. -- Highlights: ? Dose-dependent ethanol-induced fatty liver was studied in deer mouse model. ? A NMR-based lipidomic approach with histology and dry lipid weights was used. ? We used principal component analysis (PCA) to analyze the NMR lipidomic data. ? Dose-dependent clustering patterns by PCA were compared among the groups.

  7. Ethanol Production, Distribution, and Use: Discussions on Key Issues (Presentation)

    SciTech Connect (OSTI)

    Harrow, G.

    2008-05-14

    From production to the environment, presentation discusses issues surrounding ethanol as a transportation fuel.

  8. Ethanol Pathways in the 2050 North American Transportation Futures Study

    SciTech Connect (OSTI)

    2009-01-18

    A paper discussing the various ethanol pathways in the 2050 North American Transportation Futures Study

  9. Ethanol Tolerance Caused by slowpoke Induction in Drosophila

    E-Print Network [OSTI]

    Atkinson, Nigel

    Ethanol Tolerance Caused by slowpoke Induction in Drosophila Roshani B. Cowmeadow, Harish R in the ethanol response. Caenorhabditis elegans carrying mutations in this gene have altered ethanol sensitivity and Drosophila mutant for this gene are unable to acquire rapid tolerance to ethanol or anesthetics

  10. Environmental analysis of biomass-ethanol facilities

    SciTech Connect (OSTI)

    Corbus, D.; Putsche, V.

    1995-12-01

    This report analyzes the environmental regulatory requirements for several process configurations of a biomass-to-ethanol facility. It also evaluates the impact of two feedstocks (municipal solid waste [MSW] and agricultural residues) and three facility sizes (1000, 2000, and 3000 dry tons per day [dtpd]) on the environmental requirements. The basic biomass ethanol process has five major steps: (1) Milling, (2) Pretreatment, (3) Cofermentation, (4) Enzyme production, (5) Product recovery. Each step could have environmental impacts and thus be subject to regulation. Facilities that process 2000 dtpd of MSW or agricultural residues would produce 69 and 79 million gallons of ethanol, respectively.

  11. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A. (UMM)

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  12. Guide to commercial-scale ethanol production and financing

    SciTech Connect (OSTI)

    1980-11-01

    This document is designed to lead the potential investor through all the steps necessary to develop a business plan and prepare a feasibility analysis for a site-specific project. Emphasis is placed on marketing, financing, management, and incentives rather than primarily technical matters. The introduction provides an overview of the perspectives and issues in the alcohol fuels industry. Chapter II seeks to surface factors which affect the decisionmaking process. The chapter attempts to lead the investor step-by-step through the series of decisions and choices to be made before reaching the final decision to enter the business. Chapter III describes the types of feedstocks available and relates them to areas within the United States. Trends and fluctuations in the price of the major grain feedstocks are also discussed in terms of their potential use and value compared to other feeds. Chapter IV discusses the market potential of ethanol and its coproducts, and examines how the location of the ethanol markets in relation to those of the feedstock supplies may influence selection of a plant site. Various aspects of plant design are discussed. A 50 million gallon per year plant is analyzed to provide the general technical background and costing data required in analyzing plants of various sizes and designs. Safety aspects and environmental concerns are treated in Chapters VI and VII. The regulations are reviewed and their impact on plant design and operation is discussed. The basic elements of a business plan are described which lead to an approach for development of the feasibility study. Other information on financial assistance, regulations, current legislation, and reference material is given in the Appendices.

  13. The feasibility of ethanol production in Texas 

    E-Print Network [OSTI]

    Herbst, Brian Keith

    2003-01-01

    been done in Texas. Previous studies are typically for a generic location and only looked at ethanol production from corn. This study looks at four different plant sizes in three different regions using corn and grain sorghum. This study incorporates...

  14. Natural Gas Ethanol Flex-Fuel

    E-Print Network [OSTI]

    Natural Gas Propane Electric Ethanol Flex-Fuel Biodiesel Vehicle Buyer's Guide Clean Cities 2012 . . . . . . . . . . . . . . . . . . . . . . . . 4 About This Guide . . . . . . . . . . . . . . . . . . . 5 Compressed Natural Gas and emissions. Alternative fueling infrastructure is expanding in many regions, making natural gas, propane

  15. QER- Comment of ND Ethanol Council

    Broader source: Energy.gov [DOE]

    To whom it may concern, Attached please find comments from the North Dakota Ethanol Council regarding infrastructure constraints in preparation for the OER Public Meeting, which will be held in Bismarck, N.D., on August 8. Sincerely, Deana Wies

  16. Treatment of biomass to obtain ethanol

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Elander, Richard T. (Evergreen, CO); Tucker, III, Melvin P. (Lakewood, CO); Hennessey, Susan Marie (Avondale, PA)

    2011-08-16

    Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  17. Energy Utilization in Fermentation Ethanol Production 

    E-Print Network [OSTI]

    Easley, C. E.

    1987-01-01

    valid consideration when high grade fuel such as petroleum or natural gas is the energy source for the ethanol plant. But for plants running on coal or other solid fuels, ethanol production can be considered to be a form of "coal liquefaction.... The three main steps are cooking, which opens the starch bundles (called gelatinization) making them accessible for enzymatic action; liquefaction, in which large starch molecules are cut into smaller segments by enzymes, thus making the starch...

  18. High Speed/ Low Effluent Process for Ethanol

    SciTech Connect (OSTI)

    M. Clark Dale

    2006-10-30

    n this project, BPI demonstrated a new ethanol fermentation technology, termed the High Speed/ Low Effluent (HS/LE) process on both lab and large pilot scale as it would apply to wet mill and/or dry mill corn ethanol production. The HS/LE process allows very rapid fermentations, with 18 to 22% sugar syrups converted to 9 to 11% ethanol ‘beers’ in 6 to 12 hours using either a ‘consecutive batch’ or ‘continuous cascade’ implementation. This represents a 5 to 8X increase in fermentation speeds over conventional 72 hour batch fermentations which are the norm in the fuel ethanol industry today. The ‘consecutive batch’ technology was demonstrated on a large pilot scale (4,800 L) in a dry mill corn ethanol plant near Cedar Rapids, IA (Xethanol Biofuels). The pilot demonstrated that 12 hour fermentations can be accomplished on an industrial scale in a non-sterile industrial environment. Other objectives met in this project included development of a Low Energy (LE) Distillation process which reduces the energy requirements for distillation from about 14,000 BTU/gal steam ($0.126/gal with natural gas @ $9.00 MCF) to as low as 0.40 KW/gal electrical requirements ($0.022/gal with electricity @ $0.055/KWH). BPI also worked on the development of processes that would allow application of the HS/LE fermentation process to dry mill ethanol plants. A High-Value Corn ethanol plant concept was developed to produce 1) corn germ/oil, 2) corn bran, 3) ethanol, 4) zein protein, and 5) nutritional protein, giving multiple higher value products from the incoming corn stream.

  19. A novel copper(II)-Schiff base complex containing pyrrole ring: Synthesis, characterization and its modified electrodes applied in oxidation of aliphatic alcohols

    E-Print Network [OSTI]

    Boyer, Edmond

    , ethanol and benzyl alcohol. The electro-reduction of carbon dioxide was also examined. Keywords: Copper] and carbon dioxide [9]. So, in continuation of our recent papers [10], we have undertaken a covalent grafting. Thus, conducting polymeric films of polypyrrole were obtained on the surfaces of glassy carbon and ITO

  20. Role of water activity in ethanol fermentations

    SciTech Connect (OSTI)

    Jones, R.P.; Greenfield, P.F.

    1986-01-01

    A separate role for water activity in the conversion of sugars to ethanol by two strains of yeast is identified. During fermentation of both single and mixed sugar substrates, the water activity was shown to remain constant during the logarithmic growth phase. This is despite the changes in concentration of substrates and production, the constancy reflecting the fact that the greater influence of ethanol on the solution activity is counterbalanced, in the early stages of the fermentation, by its low yield. The end of the log phase of growth coincides with the start of a period of gradually decreasing water activity. For the more ethanol-tolerant strain UQM66Y, growth was found to cease at a constant value of water activity while that for the less tolerant strain UQM70Y depended on both ethanol concentration and water activity. It is argued that water activity is a more appropriate variable than ethanol concentration for describing some of the nonspecific inhibitory effects apparent in ethanol fermentations. A straightforward method for the calculation of water activity during such fermentations based on the use of solution osmolarity is presented.

  1. Discrimination of alcoholics from non-alcoholics using supervised learning on resting EEG

    E-Print Network [OSTI]

    Brooks, Joel David

    2014-01-01

    Alcoholism is a widespread problem that can have serious medical consequences. Alcoholism screening tests are used to identify patients who are at risk for complications from alcohol abuse, but accurate diagnosis of alcohol ...

  2. Development of Energy Balances for the State of California

    E-Print Network [OSTI]

    Murtishaw, Scott; Price, Lynn; de la Rue du Can, Stephane; Masanet, Eric; Worrell, Ernst; Sahtaye, Jayant

    2005-01-01

    of MTBE, blending ethanol with motor gasoline is expected toFor this reason, the ethanol blended with motor gasoline isincluding ethanol for blending into motor gasoline) were

  3. Fuel alcohol opportunities for Indiana

    SciTech Connect (OSTI)

    Greenglass, Bert

    1980-08-01

    Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

  4. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  5. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  6. PROCESS DEVELOPMENT STUDIES ON THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, Charles R.

    2011-01-01

    60,700 ETHANOL RECOVERY Dist. Column CondenserF2 Steam Exchanger Ethanol Absorber 10 ft. diameter. 38Cellulose and Production of Ethanol," Progress Report, LBL-

  7. Length of Stay Following Trauma is not Affected by Ethnicity When Controlled for Ethanol Intoxication

    E-Print Network [OSTI]

    Mangum, Craig; LoVecchio, Frank; Mathieson, Kathleen

    2007-01-01

    When Controlled for Ethanol Intoxication Craig Mangum, MD;properly controlled for ethanol and drug intoxication. Wepatients, controlling for ethanol intoxication. Methods:

  8. PILOT PLANT STUDIES OF THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, C.R.

    2010-01-01

    5 EthanolBazua, D.C. and C.R. Wilke, "Ethanol Effects on the Kineticsto the Production of Ethanol, LBL-5963. (Submitted to

  9. PROCESS DEVELOPMENT STUDIES ON THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, C.R.

    2011-01-01

    BIOCONVERSION TO SUGARS AND ETHANOL BERKELEY PROGRAM--JulyXylose Fermentation to Ethanol (a) (b) Fusarium oxysporum (OF CELLULOSE AND PRODUCTION OF ETHANOL under auspices of

  10. PROCESS DEVELOPMENT STUDIES ON THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, Charles R.

    2012-01-01

    13 Javier Perez I II. ETHANOL FERMENTATION STUDIES A. B.Development Studies of Ethanol Production--------------- 19of Cellulose and Production of Ethanol." (June 1979) and (b)

  11. PROCESS DEVELOPMENT STUDIES ON THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, C.R.

    2011-01-01

    EthanolOf Cellulose And Production Of Ethanol I Charles R. WilkeCELLULOSE AND PRODUCTION OF ETHANOL under auspices of U.S.

  12. Recovery of near-anhydrous ethanol as gasoline additive from fermentation products

    SciTech Connect (OSTI)

    Boukouvalas, C.; Markoulaki, E.; Magoulas, K.; Tassios, D. [National Technical Univ. of Athens (Greece)

    1995-06-01

    The use of near-anhydrous ethanol, obtained from fermentation products through low pressure distillation, as a gasoline additive is examined. To this purpose, a reliable model for predicting the azeotropic composition of an ethanol-water mixture as a function of the pressure is presented. It is developed by considering the available thermodynamic consistent experimental data and using the Wilson and the virial equations for the liquid-and vapor-phase nonideality, respectively. It is concluded that, for an area with no extremely cold winters-minimum ambient temperature -20{degrees}C-alcohol with 96.5%(wt) purity can be used in a 90/10 (vol) gasohol mixture. Such an alcohol can be produced with a single distillation column operating at 140 mmHg pressure with an energy consumption of 5150 kJ/kg of product; or with a system of two columns with lower energy consumption but higher capital cost. These energy consumptions are very sensitive to the accuracy of the predicted azeotropic composition at the operating pressures.

  13. Process of concentrating ethanol from dilute aqueous solutions thereof

    DOE Patents [OSTI]

    Oulman, Charles S. [Ames, IA; Chriswell, Colin D. [Slater, IA

    1981-07-07

    Relatively dilute aqueous solutions of ethanol are concentrated by passage through a bed of a crystalline silica polymorph, such as silicalite, to adsorb the ethanol with residual dilute feed in contact with the bed, which is displaced by passing concentrated aqueous ethanol through the bed without displacing the adsorbed ethanol. A product concentrate is then obtained by removing the adsorbed ethanol from the bed together with at least a portion of the concentrated aqueous ethanol used as the displacer liquid. This process permits ethanol to be concentrated from dilute fermentation beers, which may contain from 6 to 10% ethanol, to obtain a concentrate product at very low energy cost having an ethanol concentration in excess of 95%, such as a concentration of from 98 to 99.5%.

  14. A comparative experimental and computational study of methanol, ethanol, and n-butanol flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Wang, Yang L.; Egolfopoulos, Fokion N.; Westbrook, Charles K.

    2010-10-15

    Laminar flame speeds and extinction strain rates of premixed methanol, ethanol, and n-butanol flames were determined experimentally in the counterflow configuration at atmospheric pressure and elevated unburned mixture temperatures. Additional measurements were conducted also to determine the laminar flame speeds of their n-alkane/air counterparts, namely methane, ethane, and n-butane in order to compare the effect of alkane and alcohol molecular structures on high-temperature flame kinetics. For both propagation and extinction experiments the flow velocities were determined using the digital particle image velocimetry method. Laminar flame speeds were derived through a non-linear extrapolation approach based on direct numerical simulations of the experiments. Two recently developed detailed kinetics models of n-butanol oxidation were used to simulate the experiments. The experimental results revealed that laminar flame speeds of ethanol/air and n-butanol/air flames are similar to those of their n-alkane/air counterparts, and that methane/air flames have consistently lower laminar flame speeds than methanol/air flames. The laminar flame speeds of methanol/air flames are considerably higher compared to both ethanol/air and n-butanol/air flames under fuel-rich conditions. Numerical simulations of n-butanol/air freely propagating flames, revealed discrepancies between the two kinetic models regarding the consumption pathways of n-butanol and its intermediates. (author)

  15. Purification Testing for HEU Blend Program

    SciTech Connect (OSTI)

    Thompson, M.C. [Westinghouse Savannah River Company, AIKEN, SC (United States); Pierce, R.A.

    1998-06-01

    The Savannah River Site (SRS) is working to dispose of the inventory of enriched uranium (EU) formerly used to make fuel for production reactors. The Tennessee Valley Authority (TVA) has agreed to take the material after blending the EU with either natural or depleted uranium to give a {sup 235}U concentration of 4.8 percent low-enriched uranium will be fabricated by a vendor into reactor fuel for use in TVA reactors. SRS prefers to blend the EU with existing depleted uranium (DU) solutions, however, the impurity concentrations in the DU and EU are so high that the blended material may not meet specifications agreed to with TVA. The principal non-radioactive impurities of concern are carbon, iron, phosphorus and sulfur. Neptunium and plutonium contamination levels are about 40 times greater than the desired specification. Tests of solvent extraction and fuel preparation with solutions of SRS uranium demonstrate that the UO{sub 2} prepared from these solutions will meet specifications for Fe, P and S, but may not meet the specifications for carbon. The reasons for carbon remaining in the oxide at such high levels is not fully understood, but may be overcome either by treatment of the solutions with activated carbon or heating the UO{sub 3} in air for a longer time during the calcination step of fuel preparation.Calculations of the expected removal of Np and Pu from the solutions show that the specification cannot be met with a single cycle of solvent extraction. The only way to ensure meeting the specification is dilution with natural U which contains no Np or Pu. Estimations of the decontamination from fission products and daughter products in the decay chains for the U isotopes show that the specification of 110 MEV Bq/g U can be met as long as the activities of the daughters of U- 235 and U-238 are excluded from the specification.

  16. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid particles have higher density and/or larger size than indicated by previous analysis of SRS sludge and sludge simulants. (5) Tank 21 waste characterization, laboratory settling tests, and additional field turbidity measurements during mixing evolutions are recommended to better understand potential risk for extended (> 60 days) settling times in Tank 21.

  17. Coupling of alcohols to ethers: The dominance of the surface S{sub N}2 reaction pathway

    SciTech Connect (OSTI)

    Klier, K.; Feeley, O.C.; Johansson, M.; Herman, R.G.

    1996-12-31

    Coupling of alcohols to ethers, important high value oxygenates, proceeds on acid catalysts via general pathways that uniquely control product composition, oxygen retention, chirality inversion, and kinetics. The dominant pathway is the S{sub N}2 reaction with competition of the alcohols for the surface acid sites. This is exemplified by formation of methyl(ethyl) isobutylether (M(E)IBE) from methanol(ethanol)/isobutanol mixtures, retention of oxygen ({sup 18}O) of the heavier alcohol, and optimum rate as a function of concentration of either reactant alcohol. The S{sub N}2 pathway in the confinement of zeolite pores exhibits additional features of a near-100% selectivity to dimethylether (DME) in H-mordenite and a near-100% selectivity to chiral inversion in 2-pentanol/ethanol coupling to 2-ethoxypentane in HZSM-5. A minor reaction pathway entails olefin or carbenium intermediates, as exemplified by the formation of methyl tertiarybutyl ether (MTBE) from methanol/isobutanol mixtures with oxygen retention of the lighter alcohol. Calculations of transition state and molecular modeling of the oxonium-involving pathways dramatically demonstrate how the reaction path selects the products.

  18. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  19. An Indirect Route for Ethanol Production

    SciTech Connect (OSTI)

    Eggeman, T.; Verser, D.; Weber, E.

    2005-04-29

    The ZeaChem indirect method is a radically new approach to producing fuel ethanol from renewable resources. Sugar and syngas processing platforms are combined in a novel way that allows all fractions of biomass feedstocks (e.g. carbohydrates, lignins, etc.) to contribute their energy directly into the ethanol product via fermentation and hydrogen based chemical process technologies. The goals of this project were: (1) Collect engineering data necessary for scale-up of the indirect route for ethanol production, and (2) Produce process and economic models to guide the development effort. Both goals were successfully accomplished. The projected economics of the Base Case developed in this work are comparable to today's corn based ethanol technology. Sensitivity analysis shows that significant improvements in economics for the indirect route would result if a biomass feedstock rather that starch hydrolyzate were used as the carbohydrate source. The energy ratio, defined as the ratio of green energy produced divided by the amount of fossil energy consumed, is projected to be 3.11 to 12.32 for the indirect route depending upon the details of implementation. Conventional technology has an energy ratio of 1.34, thus the indirect route will have a significant environmental advantage over today's technology. Energy savings of 7.48 trillion Btu/yr will result when 100 MMgal/yr (neat) of ethanol capacity via the indirect route is placed on-line by the year 2010.

  20. Achieving High Chilled Water Delta T Without Blending Station 

    E-Print Network [OSTI]

    Wang, Z.; Wang, G.; Xu, K.; Yu, Y.; Liu, M.

    2007-01-01

    Typically a blending station is designed to ensure that its user is able to avoid low chilled water return temperature in the district cooling system. When the chilled water return temperature drops to a low limit, building return water is blended...

  1. Does blending of chlorophyll data bias temporal trend?

    E-Print Network [OSTI]

    Myers, Ransom A.

    Does blending of chlorophyll data bias temporal trend? ARISING FROM D. G. Boyce, M. R. Lewis & B of the bias component. To obtain a larger and longer data set, Boyce et al.1 pooled estimates of local, CT 5 457 D22.37 . Blending of data types can introduce error unless their expected values E(CT) and E

  2. Tribological Properties of Blends of Melamine-Formaldehyde Resin With

    E-Print Network [OSTI]

    North Texas, University of

    Tribological Properties of Blends of Melamine-Formaldehyde Resin With Low Density Polyethylene the miscibility behavior and thermal properties of LDPE þ melamine-formaldehyde resin (MFR) blends containing 1, 5 LDPE was supplied by Aldrich Chemicals. Melamine, C3H6N6 (2,4,6-triamino-1,3,5-triazine); formaldehyde

  3. Effects of Age on Pavlovian Autoshaping of Ethanol Drinking in Non-Deprived Rats

    E-Print Network [OSTI]

    Tomie, Arthur; Mohamed, Walaa M.; Pohorecky, Larissa A.

    2005-01-01

    Differential effects of ethanol on motor coordination into the motor-impairing effects of ethanol (Silveri & Spear,the present study. Ethanol’s effects on motor impairment are

  4. Ethanol from biomass: A status report

    SciTech Connect (OSTI)

    Walker, R.

    1996-12-31

    Programmatic and technical activities of SWAN Biomass, a company formed by Amoco Corporation and Stone & Webster, to convert non-grain biomass material to ethanol, are highlighted in this presentation. The potential ethanol markets identified are: (1) fuel oxygenate and octane additive, and (2) waste reduction in the agricultural and forestry industries and in municipal waste streams. Differences in the SWAN process from that used in corn-based ethanol facilities include more intense pretreatment of lignocellulosic biomass, different enzymes, hydrolysis and fermentation of sugar polymers is performed in the same vessel, and a typical solid residue of lignin. The major market and technical risks have been assessed as being manageable. 8 figs., 8 tabs.

  5. State-level workshops on ethanol for transportaton

    SciTech Connect (OSTI)

    Graf, Angela

    2004-01-01

    The Ethanol Workshop Series (EWS) was intended to provide a forum for interest groups to gather and discuss what needs to be accomplished to facilitate ethanol production in-state using local biomass resources.

  6. Investigation of the Photocatalytic Degradation of Ethanol and Acetone 

    E-Print Network [OSTI]

    Liu, Y.; Ding, B.; Dong, S.

    2006-01-01

    In-situ transmission Fourier-transform infrared spectroscopy has been used to study the photocatalytic oxidation of acetone, ethanol and the interaction between acetone and ethanol. Compared with the degradation of acetone alone, it cannot...

  7. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    all but one energy source: petroleum – We use more petroleumMetrics for Ethanol Petroleum in/Energy out Fossil energyMetrics for Ethanol Petroleum in/Energy out Fossil energy

  8. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1980-05-21

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by-product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  9. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

    1981-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

  10. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

    1983-01-01

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  11. Method and system for ethanol production

    DOE Patents [OSTI]

    Feder, H.M.; Chen, M.J.

    1981-09-24

    A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium, ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

  12. Alternative Fuels Data Center: Ethanol Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanol Benefits andFuelingEthanol

  13. Ethanol Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01

    This document lists codes and standards typically used for U.S. ethanol vehicle and infrastructure projects.

  14. Clean Cities: Ethanol Basics, Fact Sheet, October 2008

    SciTech Connect (OSTI)

    Not Available

    2008-10-01

    Document answers frequently asked questions about ethanol as a transportation fuel, including those on production, environmental effects, and vehicles.

  15. Renewable Fuels Association’s National Ethanol Conference

    Broader source: Energy.gov [DOE]

    Mark Elless, a BETO technology manager, will be representing BETO at the 20th anniversary of the National Ethanol Conference.

  16. EA-1694: Department of Energy Loan Guarantee to Highlands Ethanol, LLC, for the Cellulosic Ethanol Facility in Highlands County, Florida

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of a proposal to issue a Federal loan guarantee to Highlands Ethanol, LLC, for a cellulosic ethanol facility in Highlands County, Florida. This EA is on hold.

  17. Ethanol Production and Gasoline Prices: A Spurious Correlation

    E-Print Network [OSTI]

    Rothman, Daniel

    Ethanol Production and Gasoline Prices: A Spurious Correlation Christopher R. Knittel and Aaron proponents of ethanol have argued that ethanol production greatly lowers gasoline prices, with one industry group claiming it reduced gasoline prices by 89 cents in 2010 and $1.09 in 2011. The estimates have been

  18. Ethanol Can Contribute to Energy and Environmental Goals

    E-Print Network [OSTI]

    Ethanol Can Contribute to Energy and Environmental Goals Alexander E. Farrell,1 * Richard J. Plevin the potential effects of increased biofuel use, we evaluated six representative analyses of fuel ethanol studies indicated that current corn ethanol technologies are much less petroleum-intensive than gasoline

  19. RESEARCH Open Access Simultaneous cell growth and ethanol production

    E-Print Network [OSTI]

    Chen, Wilfred

    RESEARCH Open Access Simultaneous cell growth and ethanol production from cellulose steps to their practical usage for ethanol production. Ideally, a recombinant microorganism, possessing the capability to utilize cellulose for simultaneous growth and ethanol production, is of great interest. We have

  20. What is (and is not) vital to advancing cellulosic ethanol

    E-Print Network [OSTI]

    California at Riverside, University of

    What is (and is not) vital to advancing cellulosic ethanol Charles E. Wyman Chemical of Engineering, University of California, Riverside, CA 92506, USA Ethanol made biologically from cellulosic ethanol; however, government policies are needed to overcome the per- ceived risk of first applications

  1. ORIGINAL INVESTIGATION Inhibition of phosphodiesterase-4 decreases ethanol intake

    E-Print Network [OSTI]

    ORIGINAL INVESTIGATION Inhibition of phosphodiesterase-4 decreases ethanol intake in mice Wei Hu Rationale Cyclic AMP (cAMP)­protein kinase A signal- ing has been implicated in the regulation of ethanol intracellular cAMP levels in the brain. However, the role of PDE4 in ethanol consumption remains unknown

  2. The Real Corn-Ethanol Transportation Tad W. Patzek

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    The Real Corn-Ethanol Transportation System Tad W. Patzek Department of Civil and Environmental of ethanol in the US is essentially equal to the unleaded gasoline prices in Europe research, mass transit systems, highway upgrades, etc. Corn and ethanol subsidies in the US channel money

  3. Biofuel derived from Microalgae Corn-based Ethanol

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    · E10 vs. E85 choice · Examined of corn-based ethanol fuel systems on the following: - environmentalBiofuel derived from Microalgae Corn-based Ethanol #12;Outline · Production processes for each;Definitions Biofuel: clean fuel made from animal and plant fats and tissues (Hollebone, 2008) Ethanol

  4. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  5. December 2012 Queen's University Alcohol Policy

    E-Print Network [OSTI]

    Fletcher, Robin

    . The university recognizes that the misuse of alcohol can create risks, threaten individual health, compromise of the use and abuse of alcohol; Discourage high-risk alcohol-related behaviours and practices through-based practices and ongoing evaluation guide the practices surrounding alcohol use at Queen's University. SECTION

  6. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  7. NOx Aftertreatment Using Ethanol as Reductant

    Broader source: Energy.gov [DOE]

    The hydrocarbon-SCR that was developed using ethanol and E85 as the reductant showed high NOx reduction, no need for thawing, use of existing infrastructure, and reduced system cost making it a viable alternative to urea-based SCR

  8. Biotech Breakthrough Produces Ethanol from Waste Glycerin

    E-Print Network [OSTI]

    Stuart, Steven J.

    , it actually assists with waste processing, vitamin K production and food absorption. The same principleBiotech Breakthrough Produces Ethanol from Waste Glycerin Doing something about global warming that this process creates large quantities of waste glycerin, that was so far impossible to put to good use

  9. Differences in the Physical Characteristics of Diesel PM with Increasing Biofuel Blend Level

    Broader source: Energy.gov [DOE]

    Measure physical characteristics, carbon state, and surface bound oxygen of soot from biodiesel blends.

  10. A flow-induced phase inversion in immiscible polymer blends containing a liquid-crystalline polymer

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2 , 3 with being the viscosity ratio of the blend components at the blending shear rate. Luciani etA flow-induced phase inversion in immiscible polymer blends containing a liquid-crystalline polymer0148-6055 00 01504-2 I. INTRODUCTION The increasing application of polymer blends for the elaboration

  11. Robust real-time optimization for the linear oil blending Stefan Janaqia

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    blending process. The blending process consists in determining the optimal mix of components so. The feedback is based on measures of the blends' and components' properties gathered by online analyzers1 Robust real-time optimization for the linear oil blending Stefan Janaqia , Jorge Aguileraa

  12. Phosphor blends for high-CRI fluorescent lamps

    DOE Patents [OSTI]

    Setlur, Anant Achyut (Niskayuna, NY); Srivastava, Alok Mani (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Manivannan, Venkatesan (Clifton Park, NY); Beers, William Winder (Chesterland, OH); Toth, Katalin (Pomaz, HU); Balazs, Laszlo D. (Budapest, HU)

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  13. RIVER PROTECTION PROJECT MISSION ANALYSIS WASTE BLENDING STUDY

    SciTech Connect (OSTI)

    SHUFORD DH; STEGEN G

    2010-04-19

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  14. NREL Proves Cellulosic Ethanol Can Be Cost Competitive (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    Ethanol from non-food sources - known as "cellulosic ethanol" - is a near-perfect transportation fuel: it is clean, domestic, abundant, and renewable, and it can potentially replace 30% of the petroleum consumed in the United States, but its relatively high cost has limited its market. That changed in 2012, when the National Renewable Energy Laboratory (NREL) demonstrated the technical advances needed to produce cellulosic ethanol at a minimum ethanol selling price of $2.15/gallon (in 2007 dollars). Through a multi-year research project involving private industry, NREL has proven that cellulosic ethanol can be cost competitive with other transportation fuels.

  15. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  16. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs,Department of EnergyPROGRAM The

  17. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  18. Photonic polymer-blend structures and method for making

    DOE Patents [OSTI]

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  19. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank (Allentown, PA); Hoover, David S. (New Tripoli, PA); Garg, Diwaker (Macungie, PA)

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  20. Disease resistance and performance of blended populations of creepi 

    E-Print Network [OSTI]

    Abernathy, Scott David

    1999-01-01

    Plant diseases are a major problem on creeping bentgrass greens and can significantly decrease putting quality. Blended populations comprised of two or more cultivars within the same species have been utilized to decrease disease development...

  1. Blending Hydrogen into Natural Gas Pipeline Networks: A Review...

    Broader source: Energy.gov (indexed) [DOE]

    Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues M. W. Melaina, O. Antonia, and M. Penev Technical Report NRELTP-5600-51995 March 2013 NREL is a...

  2. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  3. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut für Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  4. Particulate matter emissions from a DISI engine under cold-fast-idle conditions for ethanol-gasoline blends

    E-Print Network [OSTI]

    Dimou, Iason

    2011-01-01

    In an effort to build internal combustion engines with both reduced brake-specific fuel consumption and better emission control, engineers developed the Direct Injection Spark Ignition (DISI) engine. DISI engines combine ...

  5. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementofApril 25,EVthe next

  6. Pathways for Ethanol Dehydrogenation and Dehydration Catalyzed by Ceria (111) and (100) Surfaces

    SciTech Connect (OSTI)

    Beste, Ariana; Overbury, Steven {Steve} H

    2015-01-01

    We have performed computations to better understand how surface structure affects selectivity in dehydrogenation and dehydration reactions of alcohols. Ethanol reactions on the (111) and (100) ceria surfaces were studied starting from the dominant surface species, ethoxy. We used DFT (PBE+U) to explore reaction pathways leading to ethylene and acetaldehyde and calculated estimates of rate constants employing transition state theory. To assess pathway contributions, we carried out kinetic analysis. Our results show that intermediate and transition state structures are stabilized on the (100) surface compared to the (111) surface. Formation of acetaldehyde over ethylene is kinetically and thermodynamically preferred on both surfaces. Our results are consistent with temperature programmed surface reaction and steady-state experiments, where acetaldehyde was found as the main product and evidence was presented that ethylene formation at higher temperature originates from changes in adsorbate and surface structure.

  7. Comparing matched polymer:Fullerene solar cells made by solution-sequential processing and traditional blend casting: Nanoscale structure and device performance

    E-Print Network [OSTI]

    2014-01-01

    and Traditional Blend Casting: Nanoscale Structure andby traditional blend casting (BC), where the components aresuch networks is the blend-casting (BC) method, wherein the

  8. Ethanol extraction of phytosterols from corn fiber

    DOE Patents [OSTI]

    Abbas, Charles (Champaign, IL); Beery, Kyle E. (Decatur, IL); Binder, Thomas P. (Decatur, IL); Rammelsberg, Anne M. (Decatur, IL)

    2010-11-16

    The present invention provides a process for extracting sterols from a high solids, thermochemically hydrolyzed corn fiber using ethanol as the extractant. The process includes obtaining a corn fiber slurry having a moisture content from about 20 weight percent to about 50 weight percent solids (high solids content), thermochemically processing the corn fiber slurry having high solids content of 20 to 50% to produce a hydrolyzed corn fiber slurry, dewatering the hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, washing the residual corn fiber, dewatering the washed, hydrolyzed corn fiber slurry to achieve a residual corn fiber having a moisture content from about 30 to 80 weight percent solids, and extracting the residual corn fiber with ethanol and separating at least one sterol.

  9. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanol Benefits and

  10. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  11. Simultaneous cell growth and ethanol production from cellulose by an engineered yeast consortium displaying a functional mini-cellulosome

    E-Print Network [OSTI]

    Goyal, Garima; Tsai, Shen-Long; Madan, Bhawna; DaSilva, Nancy A; Chen, Wilfred

    2011-01-01

    Cellulase, clostridia, and ethanol. Microbiol Mol Biol RevNext- generation cellulosic ethanol technologies and theirProduction of cellulosic ethanol in Saccharomyces cerevisiae

  12. Direct Use of Wet Ethanol in a Homogeneous Charge Compression Ignition (HCCI) Engine: Experimental and Numerical Results

    E-Print Network [OSTI]

    Mack, John Hunter; Flowers, Daniel L; Aceves, Salvador M; Dibble, Robert W

    2007-01-01

    The energy balance of corn ethanol revisited, Transaction offor autoignition. The wet ethanol modeling study [REF] usedengine running on wet ethanol. Fuel mixtures studied range

  13. Energy, Carbon Dioxide and Water Use Implications of Hydrous Ethanol Production

    E-Print Network [OSTI]

    Saffy, Howard A.; Northrop, William; Kittelson, David; Boies, Adam M.

    2015-08-24

    than anhydrous ethanol. In this study, we investigate corn ethanol production from a dry-mill, natural gas-fired corn ethanol refinery, producing ethanol with a range of ethanol concentrations from 58°wt% - 100°wt% to determine the effect on energy use...

  14. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  15. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  16. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-04-01

    A number of different yeasts are now recognized as being capable of fermenting the pentose sugar, D-xylose, into ethanol. The most prominent among these are Pachysolen tannophilus and several Candida species. D-Xylose is found principally in lignocellulosic materials where it occurs as the main constitutent of the hemicellulosic xylans (1,4-..beta..-D-heteroxylans). With the exception of Candida XF-217, the conversion yields of xylose into ethanol for most yeasts were generally low (less than 70% of theoretical when grown on at least 50 g/l xylose). The low ethanol yields are attributable to a number of factors: 1) fermentation was not performed under conditions that maximize ethanol formation; 2) ethanol was not the major fermentation end-product, (e.g., acetic acid xylitol, and arabinitol are also known products, 3) ethanol toxicity; 4) ethanol is assimilated when the substrate becomes limiting; 4.8 and 5) osmotic sensitivity to high substrate levels, i.e. substrate inhibition. Attempts to increase ethanol yields of yeasts by adding exogenous lipids (e.g., oleic and linoleic acids, or ergosterol or its ester, lipid mixtures, or protein-lipid mixtures) to nutrient medium have succeeded in improving ethanol yields and also in reducing fermentation times. These lipids, when added to the nutrient medium, were incorporated into the yeast's cellular membrane. The protective action of these lipids was to alleviate the inhibitory effect of ethanol which then allowed the cells to tolerate higher ethanol levels. This communication reports on improved ethanol yields arising from the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. 17 references.

  17. Lipid-enhanced ethanol production from xylose by Pachysolen tannophilus

    SciTech Connect (OSTI)

    Dekker, R.F.H.

    1986-01-01

    This paper reports improved ethanol yields following the fermentation of xylose by a Pachysolen tannophilus strain when grown semi-aerobically in the presence of exogenous-added lipids. Profiles for ethanol production from 45 g/L xylose when grown on a medium containing ergosterol, linoleic acid, Tween-80, a mixture of the three lipids and no lipids (control) are presented. The enhancement in the amount of ethanol produced was most pronounced after 72 h fermentation.

  18. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore »its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  19. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  20. Alcohol and HIV Disease Progression: Weighing the Evidence

    E-Print Network [OSTI]

    Hahn, Judith A.; Samet, Jeffrey H.

    2010-01-01

    Glass TR, et al. : Self-reported alcohol consumption and itsself-administering model of chronic alcohol consumption. J

  1. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  2. DOE Selects Five Ethanol Conversion Projects for $23 Million...

    Broader source: Energy.gov (indexed) [DOE]

    of 35 billion gallons of ethanol a year by 2017. Funding for these projects, an integral part of the President's Biofuels Initiative, will enable biorefineries to produce...

  3. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    What is Holding Back Cellulosic Ethanol? • Capital costs arehigh • The cost of capital is high – particularly for newCost Elements Biomass Feedstock Feed Handling Capital

  4. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia...

    Energy Savers [EERE]

    "The production of cost-competitive cellulosic ethanol is a significant part of America's energy future. This new facility, one of six commercial scale biorefineries to be...

  5. Effects of ethanol and reactive species on Hepatitis C virus

    E-Print Network [OSTI]

    Seronello, Scott E.

    2010-01-01

    the mutation rate of hepatitis C virus RNA. Manuscript inreactive oxygen species during hepatitis C virus infection.2010) Ethanol enhances hepatitis C virus replication through

  6. Evolved strains of Scheffersomyces stipitis achieving high ethanol...

    Office of Scientific and Technical Information (OSTI)

    Lignocellulosic biomass is an abundant, renewable feedstock useful for the production of fuel-grade ethanol via the processing steps of pretreatment, enzyme hydrolysis, and...

  7. Biofuel alternatives to ethanol: pumping the microbial well

    E-Print Network [OSTI]

    Fortman, J.L.

    2011-01-01

    ethanol and plant-based biodiesel ( Box 1). Although bio-acid pathway Currently, biodiesel production uses plant oilsbeen developed for use as biodiesel. However, if biodiesel

  8. Biofuel alternatives to ethanol: pumping the microbial well

    E-Print Network [OSTI]

    Fortman, J. L.

    2010-01-01

    costs and benefits of biodiesel and ethanol biofuels. Proc.187 24 Fukuda, H. et al. (2001) Biodiesel fuel production by26 Chisti, Y. (2007) Biodiesel from microalgae. Biotechnol.

  9. An Environmental and Policy Evaluation of Cellulosic Ethanol 

    E-Print Network [OSTI]

    Hurtado, Lisa Diane

    2012-07-16

    of energy crops. A new policy is proposed to support the sustainable, environmentally responsible development of cellulosic ethanol in the US....

  10. Biochemical Production of Ethanol from Corn Stover: 2007 State...

    Broader source: Energy.gov (indexed) [DOE]

    Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover Process Design and...

  11. Lignocellulosic Biomass to Ethanol Process Design and Economics...

    Broader source: Energy.gov (indexed) [DOE]

    Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover Process...

  12. Appendix D: 2012 Cellulosic Ethanol Success, Bioenergy Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    produce cellulosic ethanol at commercial-scale costs that are competitive with gasoline production at 110barrel of crude oil. Many industry partners are also demonstrating...

  13. Hydrogen assisted combustion of ethanol in Diesel enginesHydrogen assisted combustion of ethanol in Diesel engines Anil Singh Bika, Luke Franklin, Prof. David B. Kittelson

    E-Print Network [OSTI]

    Minnesota, University of

    Hydrogen assisted combustion of ethanol in Diesel enginesHydrogen assisted combustion of ethanol a means of using nearly pure ethanol as a diesel engine fuel by using hydrogen rich gases to facilitate of combustion (SOC) · A good diesel fuel has a low ignition delay period and hence a high CN · Ethanol has

  14. Divergence in Cactophilic Drosophila: The Evolutionary Significance of Adult Ethanol Metabolism

    E-Print Network [OSTI]

    Etges, William J.

    Divergence in Cactophilic Drosophila: The Evolutionary Significance of Adult Ethanol Metabolism IN CACTOPHILIC DROSOPHILA: THE EVOLUTIONARY SIGNIFICANCE OF ADULT ETHANOL METABOLISM WILLIAMJ. ETGES~ Department of volatile com- pounds, particularly ethanol, than Opuntia or other Sonoran Desert columnar cacti, because

  15. RAW MATERIALS EVALUATION AND PROCESS DEVELOPMENT STUDIES FOR CONVERSION OF BIOMASS TO SUGARS AND ETHANOL

    E-Print Network [OSTI]

    Wilke, C.R.

    2011-01-01

    OF BIOMASS TO SUGARS AND ETHANOL C. R. Wilke, R. D. Yang,of Cellulose Conversion on Ethanol Cost. References Wilke,of Hydrolyzate to Ethanol and Single Cell Protein,"

  16. PROCESS DEVELOPMENT STUDIES ON THE BIOCONVERSION OF CELLULOSE AND PRODUCTION OF ETHANOL

    E-Print Network [OSTI]

    Wilke, C.R.

    2011-01-01

    OF CELLULOSE AND PRODUCTION OF ETHANOL under auspices of22 Mohammad Riaz ETHANOL FERMENTATION STUDIES II I. A. B.Hydrolyzates to Ethanol J2 Ren-Der Yang

  17. Comparative analysis of hospital and forensic laboratory ethanol concentrations: A 15 month investigation of antemortem specimens

    E-Print Network [OSTI]

    Saitman, A; Estrada, J; Fitzgerald, RL; McIntyre, IM

    2015-01-01

    evident at lower blood ethanol concentrations and provideAW. Interpreting results of ethanol analysis in postmortemA. Fast quanti?cation of ethanol in whole blood specimens by

  18. Controlled differential pressure system for an enhanced fluid blending apparatus

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis (Knoxville, TN)

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  19. NMR and NQR parameters of ethanol crystal

    E-Print Network [OSTI]

    Milinkovic, M

    2012-01-01

    Electric field gradients and chemical shielding tensors of the stable monoclinic crystal phase of ethanol are computed. The projector-augmented wave (PAW) and gauge-including projector-augmented wave (GIPAW) models in the periodic plane-wave density functional theory are used. The crystal data from X-ray measurements, as well as the structures where either all atomic, or only hydrogen atom positions are optimized in the density functional theory are analyzed. These structural models are also studied by including the semi-empirical Van der Waals correction to the density functional theory. Infrared spectra of these five crystal models are calculated.

  20. Great Valley Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia:Oregon: EnergyGreat Basin GeothermalValley Ethanol

  1. Didion Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstrumentsArea (DOE GTP) Jump to:SouthBar,eólicoDidion Ethanol LLC

  2. Michigan Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPRO is developedShores,Ethanol LLC Jump to:

  3. Millennium Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPROLLC JumpEthanol LLC Jump to: navigation, search

  4. Kaapa Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder atHills,New York:Just Hot ResourcesEnergyKaapa Ethanol LLC

  5. North Country Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPI VenturesNew Hampshire: EnergyReservoirBrookfield,CapeCastle,Country Ethanol

  6. Northern Lights Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPI VenturesNew Hampshire:sourceNortheast Aitkin,SHRM WindLights Ethanol LLC

  7. East Coast Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of the NationalDynetek EuropeEPG| OpenEXLEasleyEthanol Jump

  8. Cardinal Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation, search Name: Carbon TradeEthanol LLC Jump

  9. Missouri Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbH JumpLLC JumpMissouri Ethanol LLC Place:

  10. Ethanol Management Company | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpA Jump to:Energy TechLtdaEstelarIllinoisEthanol

  11. Horizon Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen RiverScoring Tool Jump to:Ethanol LLC Jump to:

  12. Show Me Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbH Jump to: navigation,Show Me Ethanol LLC Jump to:

  13. Algodyne Ethanol Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen5 -TelephoneInformation AlgerAlgodyne Ethanol

  14. BlueFire Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut:NgBlueFire Ethanol Jump

  15. Central Indiana Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to:RAPIDCavallo EnergyOhio: EnergyFalls,Indiana Ethanol

  16. Ethanol Capital Funding | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdisto Electric Coop,Erosion Flume Jump to:Ethanol Capital Funding Jump

  17. Ethanol Capital Management | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdisto Electric Coop,Erosion Flume Jump to:Ethanol Capital Funding

  18. Kansas Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:onItronKanosh Town Corporation (UtilityEthanol LLC Jump to:

  19. Brazil Ethanol Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac BiomassInformationSystemsBradfieldBravo WindEthanol

  20. Prairie Ethanol LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly SmartDB-2, BluePoulsen Hybrid, LLCBiofuelsEthanol LLC Jump to:

  1. BlueFire Ethanol | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, IncBio Centers AnnouncementandBlog BlogBlueFire Ethanol

  2. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanol Benefits andFueling Stations

  3. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  4. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

  5. Theoretical and experimental investigation of particle interactions in pharmaceutical powder blending

    E-Print Network [OSTI]

    Pu, Yu, Ph. D. Massachusetts Institute of Technology

    2007-01-01

    In pharmaceutical manufacturing practices, blending of active pharmaceutical ingredient (API) with excipients is a crucial step in that homogeneity of active ingredient after blending is a key issue for the quality assurance ...

  6. Transportation and its Infrastructure

    E-Print Network [OSTI]

    2007-01-01

    to the manufacturer. gasoline blending of up to 20%. Ethanolthat with 10% ethanol-gasoline blending and 20% biodiesel-fuels (ethanol blending by gasoline tax - through imposition

  7. The U.S. Dry-Mill Ethanol Industry: Biobased Products and Bioenergy Initiative Success Stories

    SciTech Connect (OSTI)

    2009-10-28

    This fact sheet provides an overview of the history of ethanol production in the United States and describes innovations in dry-mill ethanol production.

  8. Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes

    E-Print Network [OSTI]

    Saxena, Priyank

    2007-01-01

    of formaldehyde pyrolysis”, Proceedings of Combustionmodeling of ethanol pyrolysis and combustion”, Journal deG.I. , “High-temperature pyrolysis of ethanol”, Soviet

  9. Red wine but not ethanol at low doses can protect against the toxicity of methamphetamine

    E-Print Network [OSTI]

    Bondy, Stephen Bondy C

    2010-01-01

    C.F. , Chen, C. , 2002. Melatonin in concentrated ethanoland ethanol alone attenuate methamphetamine-induced dopaminewine polyphenol, attenuates ethanol-induced oxidative stress

  10. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Low-Cost Hydrogen-from-Ethanol: A Distributed Production System (Presentation) Presented at the 2007...

  11. Red wine but not ethanol at low doses can protect against the neurotoxicity of methamphetamine

    E-Print Network [OSTI]

    Bondy, SC; Ali, SF

    2010-01-01

    C.F. , Chen, C. , 2002. Melatonin in concentrated ethanoland ethanol alone attenuate methamphetamine-induced dopaminewine polyphenol, attenuates ethanol-induced oxidative stress

  12. Investigation of Bio-Ethanol Steam Reforming over Cobalt-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation) Presented at the 2007...

  13. A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Pre-Treatment Model for Ethanol Production Using a Colorimetric Analysis of Starch Solutions (1 Activity) A Pre-Treatment Model for Ethanol Production Using a Colorimetric...

  14. Making Better Use of Ethanol as a Transportation Fuel With "Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Breakout...

  15. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI...

  16. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Presentation given at the...

  17. Direct and correlated responses to selection for larval ethanol tolerance in Drosophila melanogaster

    E-Print Network [OSTI]

    Fry, James D.

    heterogeneity; phenotypic plasticity; polymorphism; trade-offs. Abstract Ethanol is an important larval resource and toxin for natural Drosophila melanogaster populations, and ethanol tolerance is genetically variable

  18. Vapour Phase Hydration of Blended Oxide Magnox Waste Glasses Neil C. Hyatt,1*

    E-Print Network [OSTI]

    Sheffield, University of

    level waste (HLW) arising from the reprocessing of spent Oxide (UO2) and Magnox nuclear fuels is blended

  19. Thermodynamics of the Corn-Ethanol Biofuel Cycle

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Thermodynamics of the Corn-Ethanol Biofuel Cycle Tad W. Patzek Department of Civil Sustainability & Renewability 28 1 Introduction 28 2 Disclaimer 28 #12;ii Thermodynamics of corn-ethanol biofuel. . . Web Version 3 Preliminaries 29 4 Laws of Thermodynamics 29 5 Thermodynamics and Economics 31 6

  20. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  1. Weaving Versus Blending: a quantitative assessment of the information carrying capacities of two alternative methods for

    E-Print Network [OSTI]

    Healey, Christopher G.

    as the number of components increases from 4 to 6. We found no significant advantages, in either color blendingWeaving Versus Blending: a quantitative assessment of the information carrying capacities of two: color blending and color weaving. We begin with a baseline experiment in which we assess participants

  2. Segmental Dynamics of Head-to-Head Polypropylene and Polyisobutylene in Their Blend and Pure Components

    E-Print Network [OSTI]

    Colby, Ralph H.

    to determine the local motion of each component in the blend through isotopic labeling. The spin in the component dynamics upon blending, but the shift becomes larger at lower temperatures. One factor in predicting the changes in component dynamics upon blending for hhPP, while it describes the temperature

  3. Feedback control and optimization for the production of commercial fuels by blending

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    propose can be used in various situations where non-reactive components are blended and linearly impactFeedback control and optimization for the production of commercial fuels by blending M. Ch`ebre, Y presents a control algorithm for blending systems. Such systems are used in refining to produce mixtures

  4. Motivating effective use of online components by students in flipped/blended learning formats

    E-Print Network [OSTI]

    Collins, Gary S.

    Motivating effective use of online components by students in flipped/blended learning formats Tom the online components of a course, particularly in use with flipped/blended course formats. What I present's my take on flipped/blended formats exclusively: The Challenge In my experience, the most challenging

  5. PLA-PHA BLENDS: MORPHOLOGY, THERMAL AND MECHANICAL T. Grard, T. Budtova

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the pure components. The physical and mechanical properties of blends can be tuned by choosing the properPLA-PHA BLENDS: MORPHOLOGY, THERMAL AND MECHANICAL PROPERTIES T. Gérard, T. Budtova Mines Paris polymers. One is poor mechanical properties which limit their practical applications. Blending of polymers

  6. Handling parameter ranking, equalities and bounds in adaptive control of blending

    E-Print Network [OSTI]

    be formulated in various applications where non- reactive components are blended and linearly impactHandling parameter ranking, equalities and bounds in adaptive control of blending systems Mériam in the production of com- mercial fuels by blending. The control problem under consideration is a multi

  7. A Novel Global Op-miza-on Approach to the Mul-period Blending Problem

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ­ Overall Flows ­ Individual Components (Blending) · Flow/Inventory Bounds · OperaA Novel Global Op-miza-on Approach to the Mul-period Blending Problem Sco · Minimize total cost of blending opera-on Fs3,t Cs3 Fs2,t Cs2 Fd1,t CL d1-CU d1

  8. Increase in ethanol yield via elimination of lactate production in an ethanol-tolerant mutant of Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Prabhu, Sandeep; Lynd, Lee R; Guss, Adam M

    2014-01-01

    Large-scale production of lignocellulosic biofuel is a potential solution to sustainably meet global energy needs. One-step consolidated bioprocessing (CBP) is a potentially advantageous approach for the production of biofuels, but requires an organism capable of hydrolyzing biomass to sugars and fermenting the sugars to ethanol at commercially viable titers and yields. Clostridium thermocellum, a thermophilic anaerobe, can ferment cellulosic biomass to ethanol and organic acids, but low yield, low titer, and ethanol sensitivity remain barriers to industrial production. Here, we deleted the hypoxanthine phosphoribosyltransferase gene in ethanol tolerant strain of C. thermocellum adhE*(EA) in order to allow use of previously developed gene deletion tools, then deleted lactate dehydrogenase (ldh) to redirect carbon flux towards ethanol. Upon deletion of ldh, the adhE*(EA) ldh strain produced 30% more ethanol than wild type on minimal medium. The adhE*(EA) ldh strain retained tolerance to 5% v/v ethanol, resulting in an ethanol tolerant platform strain of C. thermocellum for future metabolic engineering efforts.

  9. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, C.E.

    1999-02-09

    A method is described for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process. 2 figs.

  10. Sterilization of fermentation vessels by ethanol/water mixtures

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO)

    1999-02-09

    A method for sterilizing process fermentation vessels with a concentrated alcohol and water mixture integrated in a fuel alcohol or other alcohol production facility. Hot, concentrated alcohol is drawn from a distillation or other purification stage and sprayed into the empty fermentation vessels. This sterilizing alcohol/water mixture should be of a sufficient concentration, preferably higher than 12% alcohol by volume, to be toxic to undesirable microorganisms. Following sterilization, this sterilizing alcohol/water mixture can be recovered back into the same distillation or other purification stage from which it was withdrawn. The process of this invention has its best application in, but is not limited to, batch fermentation processes, wherein the fermentation vessels must be emptied, cleaned, and sterilized following completion of each batch fermentation process.

  11. Inconspicuous Lizards Evolved To Blend In Jeff Mitton

    E-Print Network [OSTI]

    Mitton, Jeffry B.

    on and digging in sand. It grows to a length of about six inches and it is prey to a variety of visual predators predators, such as kestrels, hunt them as well. If avoidance of predators is a matter of blending in, prey

  12. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  13. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  14. IBM Research @ ACM DEV 2014 Conference Enabling Blended Learning in

    E-Print Network [OSTI]

    Toronto, University of

    IBM Research @ ACM DEV 2014 Conference 1 EduPaL: Enabling Blended Learning in Resource Constrained Ramrao Wagh IBM Research India Myntra India IBM Research India IBM Research India IBM Research India University of Southern California University of Goa India #12;IBM Research @ ACM DEV 2014 Conference Problem

  15. Blending world map projections with Flex Projector Bernhard Jennya

    E-Print Network [OSTI]

    Jenny, Bernhard

    Blending world map projections with Flex Projector Bernhard Jennya * and Tom Pattersonb a College projections is well established. Some of the most popular world map projections in use today were devised method calculates the arithmetic means of two projections. These two methods for creating new world map

  16. Lyapunov-based Optimizing Control of Nonlinear Blending Process

    E-Print Network [OSTI]

    Johansen, Tor Arne

    1 Lyapunov-based Optimizing Control of Nonlinear Blending Process Tor A. Johansen£ , Daniel Sb processes consisting of linear dynamics and a static nonlinearity are considered. We propose a control law that optimizes the equilibrium point of the process and regulates the output to the corresponding equilibrium

  17. Lyapunov-based Optimizing Control of Nonlinear Blending Processes

    E-Print Network [OSTI]

    Johansen, Tor Arne

    1 Lyapunov-based Optimizing Control of Nonlinear Blending Processes Tor A. Johansen , Daniel Sb processes consisting of linear dynamics and a static nonlinearity are considered. We propose a control law that optimizes the equilibrium point of the process and regulates the output to the corresponding equilibrium

  18. Sugar-Based Ethanol Biorefinery: Ethanol, Succinic Acid and By-Product Production

    SciTech Connect (OSTI)

    Donal F. Day

    2009-03-31

    The work conducted in this project is an extension of the developments itemized in DE-FG-36-04GO14236. This program is designed to help the development of a biorefinery based around a raw sugar mill, which in Louisiana is an underutilized asset. Some technical questions were answered regarding the addition of a biomass to ethanol facility to existing sugar mills. The focus of this work is on developing technology to produce ethanol and valuable by-products from bagasse. Three major areas are addressed, feedstock storage, potential by-products and the technology for producing ethanol from dilute ammonia pre-treated bagasse. Sugar mills normally store bagasse in a simple pile. During the off season there is a natural degradation of the bagasse, due to the composting action of microorganisms in the pile. This has serious implications if bagasse must be stored to operate a bagasse/biorefinery for a 300+ day operating cycle. Deterioration of the fermentables in bagasse was found to be 6.5% per month, on pile storage. This indicates that long term storage of adequate amounts of bagasse for year-round operation is probably not feasible. Lignin from pretreatment seemed to offer a potential source of valuable by-products. Although a wide range of phenolic compounds were present in the effluent from dilute ammonia pretreatment, the concentrations of each (except for benzoic acid) were too low to consider for extraction. The cellulosic hydrolysis system was modified to produce commercially recoverable quantities of cellobiose, which has a small but growing market in the food process industries. A spin-off of this led to the production of a specific oligosaccharide which appears to have both medical and commercial implications as a fungal growth inhibitor. An alternate use of sugars produced from biomass hydrolysis would be to produce succinic acid as a chemical feedstock for other conversions. An organism was developed which can do this bioconversion, but the economics of succinic acid production were such that it could not compete with current commercial practice. To allow recovery of commercial amounts of ethanol from bagasse fermentation, research was conducted on high solids loading fermentations (using S. cerevisiae) with commercial cellulase on pretreated material. A combination of SHF/SSF treatment with fed-batch operation allowed fermentation at 30% solids loading. Supplementation of the fermentation with a small amount of black-strap molasses had results beyond expectation. There was an enhancement of conversion as well as production of ethanol levels above 6.0% w/w, which is required both for efficient distillation as well as contaminant repression. The focus of fermentation development was only on converting the cellulose to ethanol, as this yeast is not capable of fermenting both glucose and xylose (from hemicellulose). In anticipation of the future development of such an organism, we screened the commercially available xylanases to find the optimum mix for conversion of both cellulose and hemicellulose. A different mixture than the spezyme/novozyme mix used in our fermentation research was found to be more efficient at converting both cellulose and hemicellulose. Efforts were made to select a mutant of Pichia stipitis for ability to co-ferment glucose and xylose to ethanol. New mutation technology was developed, but an appropriate mutant has not yet been isolated. The ability to convert to stillage from biomass fermentations were determined to be suitable for anaerobic degradation and methane production. An economic model of a current sugar factory was developed in order to provide a baseline for the cost/benefit analysis of adding cellulosic ethanol production.

  19. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  20. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje (East Patchogue, NY)

    1984-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  1. Recombinant host cells and media for ethanol production

    DOE Patents [OSTI]

    Wood, Brent E; Ingram, Lonnie O; Yomano, Lorraine P; York, Sean W

    2014-02-18

    Disclosed are recombinant host cells suitable for degrading an oligosaccharide that have been optimized for growth and production of high yields of ethanol, and methods of making and using these cells. The invention further provides minimal media comprising urea-like compounds for economical production of ethanol by recombinant microorganisms. Recombinant host cells in accordance with the invention are modified by gene mutation to eliminate genes responsible for the production of unwanted products other than ethanol, thereby increasing the yield of ethanol produced from the oligosaccharides, relative to unmutated parent strains. The new and improved strains of recombinant bacteria are capable of superior ethanol productivity and yield when grown under conditions suitable for fermentation in minimal growth media containing inexpensive reagents. Systems optimized for ethanol production combine a selected optimized minimal medium with a recombinant host cell optimized for use in the selected medium. Preferred systems are suitable for efficient ethanol production by simultaneous saccharification and fermentation (SSF) using lignocellulose as an oligosaccharide source. The invention also provides novel isolated polynucleotide sequences, polypeptide sequences, vectors and antibodies.

  2. Acculturation, Alcohol Expectancies, and Alcohol Use Among Mexican-American Adolescents 

    E-Print Network [OSTI]

    Flato, Claudia Graciela

    2011-02-22

    in the current study indicated a higher orientation to Mexican culture predicted higher levels of alcohol involvement for boys; whereas, a higher orientation to U.S. culture predicted higher alcohol involvement for girls. Also, identification with Mexican culture...

  3. Implications of ethanol-based fuels for greenhouse gas emissions

    SciTech Connect (OSTI)

    Marland, G. [Oak Ridge National Lab., TN (United States); DeLuchi, M.A. [Univ. of California, Davis, CA (United States). Inst. of Transportation Studies; Wyman, C. [National Renewable Energy Lab., Golden, CO (United States)

    1994-02-14

    The US Environmental Protection Agency has proposed a rule which would mandate that 30% of the oxygen content of reformulated gasoline be provided by renewable oxygenates. The rule would essentially require that biomass-based ethanol, or ETBE derived from ethanol, be used to supply 30% of the oxygen in reformulated gasoline. This short statement addresses the very narrow question, ``Would this rule result in a net decrease in greenhouse gas emissions?`` The challenge then is to determine how much greenhouse gas is emitted during the ethanol fuel cycle, a fuel cycle that is much less mature and less well documented than the petroleum fuel cycle. In the petroleum fuel cycle, most of the greenhouse gas emissions come from fuel combustion. In the ethanol fuel cycle most of the greenhouse gas emissions come from the fuel production processes. Details of corn productivity, fertilizer use, process efficiency, fuel source, etc. become very important. It is also important that the ethanol fuel cycle produces additional products and the greenhouse gas emissions have somehow to be allocated among the respective products. With so many variables in the ethanol fuel cycle, the concern is actually with ethanol-based additives which will be produced in response to the proposed rule, and not necessarily with the average of ethanol which is being produced now. A first important observation is that the difference between standard gasoline and reformulated gasoline is very small so that when differences are drawn against alternative fuels, it makes little difference whether the contrast is against standard or reformulated gasoline. A second observation is that for this base case comparison, emissions of CO{sub 2} alone are roughly 13% less for the ethanol fuel cycle than for the reformulated gasoline cycle.

  4. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  5. Brief Communication Effect of asymmetric radiant heating on monodisperse acetone/ethanol

    E-Print Network [OSTI]

    Miller, Richard S.

    Brief Communication Effect of asymmetric radiant heating on monodisperse acetone/ethanol, exploring bi-component droplets of ace- tone/ethanol and acetone/2-propanol mixtures. The ethanol and 2-component droplets composed of acetone/ethanol and acetone/ 2-propanol mixtures (1:1 volume ratio). Fig. 1 shows

  6. MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol

    E-Print Network [OSTI]

    Saiz, Leonor

    MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

  7. O P I N I O N Ethanol from sugarcane in Brazil: a `midway' strategy for

    E-Print Network [OSTI]

    DeLucia, Evan H.

    O P I N I O N Ethanol from sugarcane in Brazil: a `midway' strategy for increasing ethanol of Illinois, Urbana, IL 61801, USA Abstract This article reviews the history and current state of ethanol. We propose that it is possible to produce ethanol from sugarcane while maintaining or even recovering

  8. Comparison of ethanol production by different Zymomonas strains

    SciTech Connect (OSTI)

    Skotnicki, M.L.; Lee, K.J.; Tribe, D.E.; Rogers, P.L.

    1981-04-01

    A comparison of the rates of growth and ethanol production by 11 different strains of Zymomonas revealed a wide range of characteristics, with some strains being more tolerant of high sugar or ethanol concentrations and high incubation temperatures than others. Some strains were unable to utilize sucrose; others produced large amounts of levan, and one strain grew well but produced no levan. One strain, CP4, was considerably better in all respects than most of the other strains and was chosen as a starting strain for genetic improvement of ethanol production.

  9. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    1992-01-01

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H.sub.2 O and/or CO.sub.2 and H.sub.2 in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate.

  10. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, J.L.; Clausen, E.C.

    1992-12-22

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H[sub 2]O and/or CO[sub 2] and H[sub 2] in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate. 3 figs.

  11. Review Of Rheology Models For Hanford Waste Blending

    SciTech Connect (OSTI)

    Koopman, D. C.; Stone, M.

    2013-09-26

    The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations are not necessarily satisfactory (justified) for interpolations, due to the number of unknown variables equal the number of known data points, resulting in a coefficient of determination of one. SRS has had some success predicting the rheology of waste blends for similar waste types using rheological properties of the individual wastes and empirical blending viscosity equations. Both the Kendall-Monroe and Olney-Carlson equations were used. High accuracy was not obtained, but predictions were reasonable compared to measured flow curves. Blending SRS processed waste with frit slurry (much larger particles and the source of SRS glass formers) is a different sort of problem than that of two similar slurries of precipitated waste particles. A different approach to rheology prediction has had some success describing the incorporation of large frit particles into waste than the one used for blending two wastes. In this case, the Guth-Simha equation was used. If Hanford waste is found to have significant particles in the >100 ?m diameter range, then it might be necessary to handle those particles differently from broadly distributed waste particles that are primarily <30 ?m in diameter. The following are recommendations for the Hanford tank farms: Investigate the impact of large-scale mixing operations on yield stress for one or more Hanford tanks to see if Hanford waste rheological properties change to become more like SRS waste during both tank retrieval and tank qualification operations; Determine rheological properties of mobilized waste slurries by direct measurement rather than by prediction; Collect and characterize samples during the waste feed qualification process for each campaign; o From single source tanks that feed the qualification tanks; o Blends from the qualification tanks; Predictive rheological models must be used with caution, due to the lack of data to support such models and the utilization of the results that come from these models in making process decisions (e.g. the lack of actual operation experience). As experience is ga

  12. Downregulation of Cinnamyl Alcohol Dehydrogenase (CAD) Leads...

    Office of Scientific and Technical Information (OSTI)

    of Cinnamyl Alcohol Dehydrogenase (CAD) Leads to Improved Saccharification Efficiency in Switchgrass Citation Details In-Document Search Title: Downregulation of Cinnamyl...

  13. Gel electrophoretic analysis of Zymomonas mobilis glycolytic and fermentative enzymes: Identification of alcohol dehydrogenase II as a stress protein

    SciTech Connect (OSTI)

    Haejung An; Keshav, K.F.; Ingram, L.O. ); Scopes, R.K.; Rodriguez, M. )

    1991-10-01

    The 13 major enzymes which compose the glycolytic and fermentative pathways in Zymomonas mobilis are particularly abundant and represent one-half of the soluble protein in exponential-phase cells. One- and two-dimensional polyacrylamide gel electrophoresis maps were developed for 12 of these enzymes. Assignments were made by comigration with purified proteins, comparison with overexpressed genes in recombinant strains, and Western blots (immunoblots). Although most glycolytic enzymes appeared resistant to turnover and accumulated in stationary-phase cells, the protein levels of pyruvate kinase, alcohol dehydrogenase I, and glucokinase declined. Alcohol dehydrogenase II was identified as a major stress protein and was induced both by exposure to ethanol and by elevated temperature (45C). This enzyme, encoded by the adhB gene, is expressed from tandem promoters which share partial sequence identity with Escherichia coli consensus sequence for heat shock proteins.

  14. Alcohol and Other Drugs -1 -Approved: 05/09/2014 Alcohol and Other Drugs

    E-Print Network [OSTI]

    Hammack, Richard

    Alcohol and Other Drugs - 1 - Approved: 05/09/2014 Alcohol and Other Drugs Policy Type: Board with the federal Drug Free Workplace Act of 1988, the federal Drug Free Schools and Communities Act of 1989, and the Commonwealth of Virginia's Policy on Alcohol and Other Drugs (AOD), it is the policy of Virginia Commonwealth

  15. Agricultural and Resource Economics Update

    E-Print Network [OSTI]

    2012-01-01

    ming model of gasoline blending. As a blending component,premium high-octane gasoline. line, blending ethanol is notindicating blending would not be profitable if gasoline was

  16. Understanding the Growth of the Cellulosic Ethanol Industry

    SciTech Connect (OSTI)

    Sandor, D.; Wallace, R.; Peterson, S.

    2008-04-01

    This report identifies, outlines, and documents a set of plausible scenarios for producing significant quantities of lignocellulosic ethanol in 2017. These scenarios can provide guidance for setting government policy and targeting government investment to the areas with greatest potential impact.

  17. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia...

    Broader source: Energy.gov (indexed) [DOE]

    million gallons of cellulosic ethanol per year. Funding for these projects is also an integral part of the President's Biofuels Initiative that will lead to the wide-scale use of...

  18. Life cycle analysis of hybrid poplar trees for cellulosic ethanol

    E-Print Network [OSTI]

    Huang, Jessica J

    2007-01-01

    The main purpose of this paper is to assess the energy and environmental benefits of cultivating hybrid poplars as a biomass crop for cellulosic ethanol. A "Life Cycle Assessment" (LCA) methodology is used to systematically ...

  19. Current State of the U.S. Ethanol Industry

    SciTech Connect (OSTI)

    Urbanchuk, John

    2010-11-30

    The objective of this study is to provide a comprehensive overview of the state of the U.S. ethanol industry and to outline the major forces that will affect the development of the industry over the next decade.

  20. Methods for increasing the production of ethanol from microbial fermentation

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Arora, Dinesh K. (Fayetteville, AR); Ko, Ching-Whan (Fayetteville, AR); Phillips, John Randall (Fayetteville, AR); Basu, Rahul (Bethlehem, PA); Wikstrom, Carl V. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    2007-10-23

    A stable continuous method for producing ethanol from the anaerobic bacterial fermentation of a gaseous substrate containing at least one reducing gas involves culturing a fermentation bioreactor anaerobic, acetogenic bacteria in a liquid nutrient medium; supplying the gaseous substrate to the bioreactor; and manipulating the bacteria in the bioreactor by reducing the redox potential, or increasing the NAD(P)H TO NAD(P) ratio, in the fermentation broth after the bacteria achieves a steady state and stable cell concentration in the bioreactor. The free acetic acid concentration in the bioreactor is maintained at less than 5 g/L free acid. This method allows ethanol to be produced in the fermentation broth in the bioreactor at a productivity greater than 10 g/L per day. Both ethanol and acetate are produced in a ratio of ethanol to acetate ranging from 1:1 to 20:1.

  1. Biofuel alternatives to ethanol: pumping the microbial well

    E-Print Network [OSTI]

    Fortman, J. L.

    2010-01-01

    of biodiesel and ethanol biofuels. Proc. Natl. Acad. Sci. U.S. (2006) Bonkers about biofuels. Nat. Biotechnol. 24, 755–Schubert, C. (2006) Can biofuels finally take center stage?

  2. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ethanol production in place * U.S. 13.4 billion galsyear mostly from corn starch * Brazil 6.3 billion galsyear from cane sugar * Rest of world 2.8 billion galsyear *...

  3. Ethanol supply chain and industry overview : more harm than good?

    E-Print Network [OSTI]

    Bruce, Sarah L

    2013-01-01

    This thesis is a comprehensive study that aggregates the key aspects of ethanol including its supply chain, government legislation that impacts the use of, and the inherent material characteristics of the fuel as well as ...

  4. The Latest Unanticipated Consequence in the Ethanol Fiasco 

    E-Print Network [OSTI]

    Griffin, James M.

    2013-01-01

    Until recently, the 2007 ethanol mandates have been a story of very small environmental and security benefits and large, unexpected increases in food prices as corn was diverted from food to fuel uses. Now we have another unforeseen consequence...

  5. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    improve technology and reduce costs • In response to recentuses and to advance technologies to reduce costs Basis of MyEthanol • Operating costs are low • Technology is ready to

  6. Biomass to ethanol : potential production and environmental impacts

    E-Print Network [OSTI]

    Groode, Tiffany Amber, 1979-

    2008-01-01

    This study models and assesses the current and future fossil fuel consumption and greenhouse gas impacts of ethanol produced from three feedstocks; corn grain, corn stover, and switchgrass. A life-cycle assessment approach ...

  7. Effects of ethanol, heat, and lipid treatment of soybean meal on nitrogen utilization by ruminants

    SciTech Connect (OSTI)

    Lynch, G.L.; Berger, L.L.; Fahey, G.C. Jr.

    1987-01-01

    Ruminant nitrogen utilization of soybean meal treated with (1) 70% ethanol at 23 or 78/sup 0/C, (2) 10% coconut oil or tallow, or (3) a combination of 70% ethanol at 78/sup 0/C and coconut oil or tallow was evaluated. Nitrogen solubility was lowest for soybean meal treated with ethanol at 78/sup 0/C, ethanol plus coconut oil and ethanol plus tallow. In situ nitrogen disappearance was lowest for soybean meal treated with ethanol at 78/sup 0/C, ethanol plus coconut oil, and ethanol plus tallow. Rates of nitrogen disappearance between 3 and 12 h were lowest for soybean meal treated with ethanol at 78/sup 0/C, ethanol plus coconut oil, and ethanol plus tallow. Nitrogen retained by lambs was greater for lambs fed soybean meal treated with ethanol at 78/sup 0/C than for those fed untreated soybean meal. Ruminal ammonia 4 h post feeding was lowest for lambs fed soybean meal treated with ethanol at 78/sup 0/C, ethanol plus coconut oil, and coconut oil. These data indicate that the 78/sup 0/C ethanol treatment improved nitrogen utilization.

  8. Direct Ethanol Fuel Cells: Platinum/Rhodium Anode

    E-Print Network [OSTI]

    Petta, Jason

    Direct Ethanol Fuel Cells: Platinum/Rhodium Anode Catalysis Ken Ellis-Guardiola PCCM REU 2010 #12 EtOH+3H2O 12H+ +2CO2+ 12e- Pt C 4H+ + 4e- + O2 2H2O O2 Anode Cathode The Direct Ethanol Fuel Cell #12;The addition of other metals to Platinum improves its fuel cell performance Pt alone is easily

  9. Alcohol Transportation Fuels Demonstration Program

    SciTech Connect (OSTI)

    Kinoshita, C.M. (ed.)

    1990-01-01

    Hawaii has abundant natural energy resources, especially biomass, that could be used to produce alternative fuels for ground transportation and electricity. This report summarizes activities performed during 1988 to June 1991 in the first phase of the Alcohol Transportation Fuels Demonstration Program. The Alcohol Transportation Fuels Demonstration Program was funded initially by the Energy Division of the State of Hawaii's Department of Business, Economic Development and Tourism, and then by the US Department of Energy. This program was intended to support the transition to an altemative transportation fuel, methanol, by demonstrating the use of methanol fuel and methanol-fueled vehicles, and solving the problems associated with that fuel. Specific objectives include surveying renewable energy resources and ground transportation in Hawaii; installing a model methanol fueling station; demonstrating a methanol-fueled fleet of (spark-ignition engine) vehicles; evaluating modification strategies for methanol-fueled diesel engines and fuel additives; and investigating the transition to methanol fueling. All major objectives of Phase I were met (survey of local renewable resources and ground transportation, installation of methanol refueling station, fleet demonstration, diesel engine modification and additive evaluation, and dissemination of information on alternative fueling), and some specific problems (e.g., relating to methanol fuel contamination during handling and refueling) were identified and solved. Several key issues emerging from Phase I (e.g., methanol corrosion, flame luminosity, and methanol-transition technoeconomics) were recommended as topics for follow-on research in subsequent phases of this program.

  10. Development of By-Pass Blending Station System 

    E-Print Network [OSTI]

    Liu, M.; Barnes, D.; Bunz, K.; Rosenberry, N.

    2003-01-01

    Temperature 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 30 40 50 60 70 80 90 100 Ambient Temeprature Ra ti o Load Ratio Power Savings Ratio W/O DP Reset Differential Pressure Ratio Power Savings With DP Reset ICEBO 2003, Development of By-pass Blending...

  11. Ethanol Dehydration to Ethylene in a Stratified Autothermal Millisecond Reactor

    SciTech Connect (OSTI)

    Skinner, MJ; Michor, EL; Fan, W; Tsapatsis, M; Bhan, A; Schmidt, LD

    2011-08-10

    The concurrent decomposition and deoxygenation of ethanol was accomplished in a stratified reactor with 50-80 ms contact times. The stratified reactor comprised an upstream oxidation zone that contained Pt-coated Al(2)O(3) beads and a downstream dehydration zone consisting of H-ZSM-5 zeolite films deposited on Al(2)O(3) monoliths. Ethanol conversion, product selectivity, and reactor temperature profiles were measured for a range of fuel:oxygen ratios for two autothermal reactor configurations using two different sacrificial fuel mixtures: a parallel hydrogen-ethanol feed system and a series methane-ethanol feed system. Increasing the amount of oxygen relative to the fuel resulted in a monotonic increase in ethanol conversion in both reaction zones. The majority of the converted carbon was in the form of ethylene, where the ethanol carbon-carbon bonds stayed intact while the oxygen was removed. Over 90% yield of ethylene was achieved by using methane as a sacrificial fuel. These results demonstrate that noble metals can be successfully paired with zeolites to create a stratified autothermal reactor capable of removing oxygen from biomass model compounds in a compact, continuous flow system that can be configured to have multiple feed inputs, depending on process restrictions.

  12. Production of alcohol from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.; Lee, C.Y.; Woodams, E.E.; Cooley, H.J.

    1981-12-01

    Production of ethyl alcohol from apple pomace with a Montrachet strain of Saccharomyces cerevisiae is described. More than 43 grams of the ethyl alcohol could be produced per kg of apple pomace fermented at 30 degrees Celcius in 24 hours. The fermentation efficiency of this process was approximately 89%. (Refs. 9).

  13. Effect of alcohols on aqueous lysozyme-lysozyme interactions...

    Office of Scientific and Technical Information (OSTI)

    Effect of alcohols on aqueous lysozyme-lysozyme interactions from static light-scattering measurements Citation Details In-Document Search Title: Effect of alcohols on aqueous...

  14. Renewable Hydrogen Production Using Sugars and Sugar Alcohols...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Sugars and Sugar Alcohols (Presentation) Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen...

  15. Process for the synthesis of unsaturated alcohols

    SciTech Connect (OSTI)

    Maughon, Bob R.; Burdett, Kenneth A.; Lysenko, Zenon

    2007-02-13

    A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

  16. Molasses for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis of sugarcane ethanol

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Molasses for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis of sugarcane ethanol This article has been downloaded from IOPscience. Please scroll for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis

  17. An Analysis of the Murine Neocortex: Normal Development and the Impact of Prenatal Ethanol Exposure on Connectivity, Gene Expression, and Behavior

    E-Print Network [OSTI]

    El Shawa, Hani

    2012-01-01

    and  motor  INCs  after   prenatal  ethanol  exposure.    motor  and   sensory  areas,  including  visual  cortex.  It  is  likely  that  ethanol-­?motor  coordination.   Animals  exposed  prenatally  to  ethanol  

  18. Ethanol seeking triggered by environmental context is attenuated by blocking dopamine D1 receptors in the nucleus accumbens core and shell in rats

    E-Print Network [OSTI]

    Chaudhri, Nadia; Sahuque, Lacey L.; Janak, Patricia H.

    2009-01-01

    ment into the prior ethanol self-administration context. SCHreinstatement of responding for ethanol cues triggered byplacement into an ethanol-associated context. Keywords

  19. Conversion and Blending Facility Highly enriched uranium to low enriched uranium as uranium hexafluoride. Revision 1

    SciTech Connect (OSTI)

    NONE

    1995-07-05

    This report describes the Conversion and Blending Facility (CBF) which will have two missions: (1) convert surplus HEU materials to pure HEU UF{sub 6} and a (2) blend the pure HEU UF{sub 6} with diluent UF{sub 6} to produce LWR grade LEU-UF{sub 6}. The primary emphasis of this blending be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The chemical and isotopic concentrations of the blended LEU product will be held within the specifications required for LWR fuel. The blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry.

  20. Process simulation, integration and optimization of blending of petrodiesel with biodiesel 

    E-Print Network [OSTI]

    Wang, Ting

    2009-05-15

    of payback period (PP) for the three options????????100 5.15 Comparison of net CO2 life-cycle emissions for petroleum diesel and biodiesel blends???????...????????????.102 5.16 Net CO2 emission vs. blend price of biodiesel blend... quantities significantly rely on enhanced hydrotreating technology, which is the major method to produce ULSD at this time (EIA, 2001). 4 Conventional hydrotreating is a commercially proven refining process that inputs feedstock together with hydrogen...