National Library of Energy BETA

Sample records for alcohol blended fuels

  1. Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels

    Broader source: Energy.gov [DOE]

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

  2. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  3. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoidance Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel BiodieselFuelManagementBestPracticesReport.pdf

  4. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications

    Broader source: Energy.gov [DOE]

    Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations

  5. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15

  6. Alternative Fuels Data Center: Biodiesel Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Blends to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blends on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blends on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blends on Google Bookmark Alternative Fuels Data Center: Biodiesel Blends on Delicious Rank Alternative Fuels Data Center: Biodiesel Blends on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blends on AddThis.com... More in this section... Biodiesel Basics

  7. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II. PDF icon deer12_ickes.pdf More Documents & Publications Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Drop In Fuels: Where the Road Leads

  8. Alcohol-fuel symposium

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A symposium was conducted on the state-of-the-art of ethanol production and use. The following topics were discussed: ethanol as a fuel for internal combustion engines; ethanol production system design; the economics of producing fuel alcohol in form size plants; alternate feedstocks for ethanol stillage as a cattle feed; high energy sorghum, ethanol versus other alternative fuels; alcohol-fuel; legal and policy issues in ethanol production; and small scale fuel alcohol production. (DMC)

  9. Low-Level Ethanol Fuel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    This fact sheet addresses: (a) why Clean Cities promotes ethanol blends; (b) how these blends affect emissions; (c) fuel performance and availability; and (d) cost, incentives, and regulations.

  10. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications Title A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition...

  11. Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI Exhaust Speciation - ORNL Reference Fuel Blends Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends *Accurately measure exhaust profile from an HCCI engine with a ...

  12. Fuel alcohol opportunities for Indiana

    SciTech Connect (OSTI)

    Greenglass, Bert

    1980-08-01

    Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

  13. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  14. Alcohol fuels program technical review

    SciTech Connect (OSTI)

    1981-07-01

    The last issue of the Alcohol Fuels Process R/D Newsletter contained a work breakdown structure (WBS) of the SERI Alcohol Fuels Program that stressed the subcontracted portion of the program and discussed the SERI biotechnology in-house program. This issue shows the WBS for the in-house programs and contains highlights for the remaining in-house tasks, that is, methanol production research, alcohol utilization research, and membrane research. The methanol production research activity consists of two elements: development of a pressurized oxygen gasifier and synthesis of catalytic materials to more efficiently convert synthesis gas to methanol and higher alcohols. A report is included (Finegold et al. 1981) that details the experimental apparatus and recent results obtained from the gasifier. The catalysis research is principally directed toward producing novel organometallic compounds for use as a homogeneous catalyst. The utilization research is directed toward the development of novel engine systems that use pure alcohol for fuel. Reforming methanol and ethanol catalytically to produce H/sub 2/ and CO gas for use as a fuel offers performance and efficiency advantages over burning alcohol directly as fuel in an engine. An application of this approach is also detailed at the end of this section. Another area of utilization is the use of fuel cells in transportation. In-house researchers investigating alternate electrolyte systems are exploring the direct and indirect use of alcohols in fuel cells. A workshop is being organized to explore potential applications of fuel cells in the transportation sector. The membrane research group is equipping to evaluate alcohol/water separation membranes and is also establishing cost estimation and energy utilization figures for use in alcohol plant design.

  15. Alcohol fuel from Ohio farms

    SciTech Connect (OSTI)

    Jones, J.D.

    1984-01-01

    This booklet provides an introduction to technical, marketing, and regulatory issues involved in on-farm alcohol fuel production. Discussed are ethanol production provcesses, investment, potential returns, regulations and permits, and sources of financial and technical assistance. 2 figures. (DMC)

  16. Farmstead production of fuel alcohol

    SciTech Connect (OSTI)

    Badger, P.C.; Pile, R.S.; Waddell, E.L. Jr.

    1981-01-01

    The Tennessee Valley Authority Agricultural Energy Applications Section (Muscle Shoals, AL) has designed and constructed a small-scale fuel alcohol production facility which can produce 10 gph of 190-proof alcohol. Information presented includes some factors relative to facility design, layout, and construction, plus operation and performance experiences.

  17. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T.

    2011-08-01

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

  18. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  19. Alcohol Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Fuels Alcohol Fuels Goals Advance a multiscale approach to collaborative reaction kinetic model development and validation, by focusing team efforts on particular alcohol fuels. The team's initial focus has been on n-butanol. This has recently broadened to include detailed kinetic modeling of other isomeric butanols, plus some comparisons with smaller alcohols and the corresponding ketones, aldehydes, and enols. In the future we expect to use what we have learned from the butanol study

  20. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Requirement Suppliers that import gasoline for sale in North Carolina must offer fuel that is not pre-blended with fuel alcohol but that is suitable for future blending. Future contract provisions that restrict distributors or retailers from blending gasoline with fuel alcohol are void. (Reference North Carolina General Statutes 75-90, 105-449.60

  2. Pressure dispensable gelled alcohol fuel

    SciTech Connect (OSTI)

    Monick, J.A.

    1982-12-28

    A pressurized fuel gel composition particularly suitable for igniting wood and charcoal consisting essentially of, by weight, 42-90% of at least one c1-c6 monohydric alcohol, 0.5-6% of water-soluble gelling agent, up to about 24% water and a correlated amount of propellant from 0.5% to 30% characterized by a gel structure which forms a shape retaining mass upon contact with wood or charcoal that is maintained during the burning of said composition. Also within the scope of the invention is an aerosol product comprising said pressurized composition enclosed within a pressure-tight container having valve means for expelling the composition.

  3. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and

  4. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  5. Third international symposium on alcohol fuels technology

    SciTech Connect (OSTI)

    1980-04-01

    At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

  6. Jilin Fuel Alcohol Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    Alcohol Company Ltd Jump to: navigation, search Name: Jilin Fuel Alcohol Company Ltd Place: Jilin, Jilin Province, China Zip: 132011 Product: One of the four Chinese government...

  7. Alcohol fuel from Ohio farms

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Brief descriptions of on-farm ethanol production methods including feedstock preparation, cooking, fermentation, and distillation are presented. Safety conditions are described. Investment in on-farm ethanol production facilities and their potential returns are addressed. The market for ethanol and ethanol blends as well as for by-products is encouraging. Legal aspects for permitting and environmental regulations both for Ohio and federal agencies are discussed. (DMC)

  8. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  9. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks | Department of Energy Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Breakout Session 2-B: New/Emerging Pathways Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend

  10. Farm alcohol fuel project. Final report

    SciTech Connect (OSTI)

    Demmel, D.

    1981-11-15

    The Small Energy Project is a research and demonstration effort designed to assist small farmers in the utilization of energy conservation techniques on their farms. The Farm Alcohol Project was designed to demonstrate the production of alcohol fuels on small farms in order to reduce purchased liquid fuel requirements. The Project considered the use of on-farm raw materials for process heat and the production of fuel grade, low prood ethanol in volumes up to 10,000 gallons per year. The fuel would be used entirely on the farm. The approach considered low-cost systems the farmer could build himself from local resources. Various crops were considered for ethanol production. The interest in farm alcohol production reached a peak in 1980 and then decreased substantially as farmers learned that the process of alcohol production on the farm was much more complicated than earlier anticipated. Details of Alcohol Project experiences in ethanol production, primarily from corn, are included in this report. A one-bushel distillation plant was constructed as a learning tool to demonstrate the production of ethanol. The report discusses the various options in starch conversion, fermentation and distillation that can be utilized. The advantages and disavantages of atmospheric and the more complicated process of vacuum distillation are evaluated. Larger farm plants are considered in the report, although no experience in operating such plants was gained through the Project. Various precautions and other considerations are included for farm plant designs. A larger community portable distillery is also evaluated. Such a plant was considered for servicing farms with limited plant equipment. The farms serviced would perform only fermentation tasks, with the portable device performing distillation and starch conversion.

  11. Fuel alcohol: the road to independence

    SciTech Connect (OSTI)

    Stull, C.B.

    1982-01-01

    This report describes the production of ethanol using an on-farm fuel alcohol still. Directions are given in lay-language, easily understandable to novices in the field of fermentation. Preparation of the mash, fermentation, and distillation are discussed along with some basic background information on these processes. The design and construction of the still is presented. Off-the-shelf equipment was used in the construction. Vats, pumps, and testing equipment used in the processing are described. Diagrams and a glossary are included. The alcohol produced is used for space heating of a house and greenhouse. (DMC)

  12. Identification and quantification of organic chemicals in supplemental fuel blends

    SciTech Connect (OSTI)

    Salter, F.

    1996-12-31

    Continental Cement Company, Inc. (Continental) burns waste fuels to supplement coal in firing the kiln. It is to be expected that federal and state agencies want an accounting of the chemicals burned. As rules and regulations become more plentiful, a company such as Continental must demonstrate that it has made a reasonable attempt to identify and quantify many specific organic compounds. The chemicals on the SARA 313 list can change frequently. Also the number and concentrations of compounds that can disqualify a material from consideration as a supplemental fuel at Continental continues to change. A quick and reliable method of identifying and quantifying organics in waste fuel blends is therefore crucial. Using a Hewlett-Packard 5972 GC/MS system Continental has developed a method of generating values for the total weight of compounds burned. A similar procedure is used to verify that waste streams meet Continental`s acceptance criteria.

  13. Alcohol Fuels Program technical review, Spring 1984

    SciTech Connect (OSTI)

    Not Available

    1984-10-01

    The alcohol fuels program consists of in-house and subcontracted research for the conversion of lignocellulosic biomass into fuel alcohols via thermoconversion and bioconversion technologies. In the thermoconversion area, the SERI gasifier has been operated on a one-ton per day scale and produces a clean, medium-Btu gas that can be used to manufacture methanol with a relatively small gas-water shift reaction requirement. Recent research has produced catalysts that make methanol and a mixture of higher alcohols from the biomass-derived synthetic gas. Three hydrolysis processes have emerged as candidates for more focused research. They are: a high-temperature, dilute-acid, plug-flow approach based on the Dartmouth reactor; steam explosion pretreatment followed by hydrolysis using the RUT-C30 fungal organism; and direct microbial conversion of the cellulose to ethanol using bacteria in a single or mixed culture. Modeling studies, including parametric and sensitivity analyses, have recently been completed. The results of these studies will lead to a better definition of the present state-of-the-art for these processes and provide a framework for establishing the research and process engineering issues that still need resolution. In addition to these modeling studies, economic feasibility studies are being carried out by commercial engineering firms. Their results will supplement and add commercial validity to the program results. The feasibility contractors will provide input at two levels: Technical and economic assessment of the current state-of-the-art in alcohol production from lignocellulosic biomass via thermoconversion to produce methanol and higher alcohol mixtures and bioconversion to produce ethanol; and identification of research areas having the potential to significantly reduce the cost of production of alcohols.

  14. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre L. Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2002-07-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. This project complements another ongoing project titled ''Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus Demonstration Project''. The objectives of that research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, they have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, the activities have covered two areas: development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward completion of both experimental systems and a summary of the plan for completion of the project objectives.

  15. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2004-04-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. Our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. The first two of these areas have resulted in valuable information about the limitations of lubricity and viscosity additives that are presently available in terms of their impact on the viscosity of DME and on wear rates on injector hardware. The third area, that of development of an injector durability test stand, has not resulted in a functioning experiment. Some information is provided in this report to identify the remaining tasks that need to be performed to make the injector stand operational. The key observations from the work are that when blended at 25 wt.% in either diesel fuel or Biodiesel fuel, DME requires more than 5 wt.% additive of all viscosity and lubricity additives tested here to even approach the lower limit of the ASTM diesel fuel viscosity requirement. To treat neat DME sufficiently to make DME comply with the ASTM diesel fuel viscosity requirement would require a viscosity additive with 10{sup 45} cSt viscosity, which is not possible with current additive technologies.

  16. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2003-06-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward evaluation of the viscosity impacts of lubricity additives, completion of both experimental systems and a summary of the plan for completion of the project objectives.

  17. Electrocatalyst for alcohol oxidation in fuel cells

    DOE Patents [OSTI]

    Adzic, Radoslav R.; Marinkovic, Nebojsa S.

    2001-01-01

    Binary and ternary electrocatalysts are provided for oxidizing alcohol in a fuel cell. The binary electrocatalyst includes 1) a substrate selected from the group consisting of NiWO.sub.4 or CoWO.sub.4 or a combination thereof, and 2) Group VIII noble metal catalyst supported on the substrate. The ternary electrocatalyst includes 1) a substrate as described above, and 2) a catalyst comprising Group VIII noble metal, and ruthenium oxide or molybdenum oxide or a combination thereof, said catalyst being supported on said substrate.

  18. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However, the strength of the secondary flow is found nearly the same behind the first and the second vortex generator pair as well as far from the second vortex generator pair in the case of Duct2. Both ducts are able to create a counter-rotating and a second set of twin foci. Duct2 is able to create the second set of twin foci in an earlier streamwise location than Duct1, as these foci are well-known to their heat transfer augmentation. A larger vortex formation area and a greater induced vorticity field between vortex pairs are observed for Duct2 compared with Duct1. As the induced flow field between the vortex pairs increases the heat transfer, and as the flow field between the vortex cores is found larger in the case of Duct2, therefore, it is expected to obtain better heat transfer characteristics for Duct2 compared with Duct1. (author)

  19. Comparing liquid fuel costs: grain alcohol versus sunflower oil

    SciTech Connect (OSTI)

    Reining, R.C.; Tyner, W.E.

    1983-08-01

    This paper compares the technical and economic feasibility of small-scale production of fuel grade grain alcohol with sunflower oil. Three scales of ethanol and sunflower oil production are modeled, and sensitivity analysis is conducted for various operating conditions and costs. The general conclusion is that sunflower oil costs less to produce than alcohol. Government subsidies for alcohol, but not sunflower oil, could cause adoption of more expensive alcohol in place of cheaper sunflower oil. However, neither sunflower oil nor alcohol are competitive with diesel fuel. 7 references.

  20. Office of Alcohol Fuels Program plan, FY 1981

    SciTech Connect (OSTI)

    1980-10-01

    The goal of the Office of Alcohol Fuels is to promote the production, distribution, and use of alcohol fuels. The program objectives are defined and the strategy for implementation is described. An organizational model of the operation is included. The roles of the 3 program offices and various field offices are described. (DMC)

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85% or more of alcohol with gasoline; natural gas and liquid fuels domestically produced from natural gas; liquefied petroleum gas (propane); coal-derived liquid fuels; hydrogen; electricity; pure biodiesel (B100); fuels, other than alcohol, derived from biological materials; and P-Series fuels. In addition, the U.S.

  2. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  3. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay Keller of Sandia National Laboratories at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 PDF icon cng_h2_workshop_2_keller.pdf More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Overview of HyRAM (Hydrogen

  4. Cold-Start Performance and Emissions Behavior of Alcohol Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Using Transient Hardware-In-Loop Test Meth Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth ...

  5. Proceedings of the alcohol fuel production and utilization conference

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A conference was held to provide farmers, businesses, industries, and specialty groups with the best available information on current and projected activities related to the production and utilization of biomass for alcohol fuels. All aspects of the alcohol fuel production and utilization process were discussed. From biomass sources, through conversion processes to end-use products and applications were topics discussed by numerous experts. Other experts took this basic information and put it together into total systems. Speakers presented overviews on alcohol fuel related activities on state, regional, and national levels. Finally, commercialization incentives, funding sources, environmental considerations, research developments, safety considerations, and regulatory requirements were discussed as factors which must be addressed when considering the production and utilization of alcohol fuels. Separate abstracts have been prepared for items within the scope of the Energy Data Base.

  6. Use of alcohol in farming applications: alternative fuels utilization program

    SciTech Connect (OSTI)

    Borman, G.L.; Foster, D.E.; Uyehara, O.A.; McCallum, P.W.; Timbario, T.J.

    1980-11-01

    The use of alcohol with diesel fuel has been investigated as a means of extending diesel fuel supplies. The ability to use ethanol in diesel-powered farm equipment could provide the means for increasing the near-term fuels self-sufficiency of the American farmer. In the longer term, the potential availability of methanol (from coal) in large quantities could serve to further decrease the dependency on diesel fuel. This document gives two separate overviews of the use of alcohols in farm equipment. Part I of this document compares alcohol with No. 1 and No. 2 diesel fuels and describes several techniques for using alcohol in farm diesels. Part II of this document discusses the use of aqueous ethanol in diesel engines, spark ignition engines and provides some information on safety and fuel handling of both methanol and ethanol. This document is not intended as a guide for converting equipment to utilize alcohol, but rather to provide information such that the reader can gain insight on the advantages and disadvantages of using alcohol in existing engines currently used in farming applications.

  7. Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines

    SciTech Connect (OSTI)

    Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

    1999-05-05

    Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

  8. Electrocatalysts for Alcohol Oxidation in Fuel Cells - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electrocatalysts for Alcohol Oxidation in Fuel Cells Brookhaven National Laboratory Contact BNL About This Technology <p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the best commercially available catalyst for methanol oxidation.</p> Higher current indicates higher activity for catalyzing methanol oxidation in a fuel cell. Here the ternary electrocatalyst is comparable to the

  9. Mid-Blend Ethanol Fuels – Implementation Perspectives

    Broader source: Energy.gov [DOE]

    Breakout Session 2: Frontiers and Horizons Session 2–B: End Use and Fuel Certification Bill Woebkenberg, Fuels Technical and Regulatory Affairs Senior Engineer, Mercedes-Benz

  10. Design report: small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of a small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. Volume one contains background information and a general description of the plant and process.

  11. Modeling and cold start in alcohol-fueled engines

    SciTech Connect (OSTI)

    Markel, A.J.; Bailey, B.K.

    1998-05-01

    Neat alcohol fuels offer several benefits over conventional gasoline in automotive applications. However, their low vapor pressure and high heat of vaporization make it difficult to produce a flammable vapor composition from a neat alcohol fuel during a start under cold ambient conditions. Various methods have been introduced to compensate for this deficiency. In this study, the authors applied computer modeling and simulation to evaluate the potential of four cold-start technologies for engines fueled by near-neat alcohol. The four technologies were a rich combustor device, a partial oxidation reactor, a catalytic reformer, and an enhanced ignition system. The authors ranked the competing technologies by their ability to meet two primary criteria for cold starting an engine at {minus}25 deg C and also by several secondary parameters related to commercialization. Their analysis results suggest that of the four technologies evaluated, the enhanced ignition system is the best option for further development.

  12. Underground Storage Tanks: New Fuels and Compatibility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 1980 1984 1990 1995 1981 1985 1988 2005 Prior to Oct. 1980: No single or double wall tanks are warrantied for any alcohol or alcohol blended fuels. Oct. 1980 to Jun. 1984: ...

  13. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  14. Demonstration of alcohol as an aviation fuel

    SciTech Connect (OSTI)

    1996-07-01

    A recently funded Southeastern Regional Biomass Energy Program (SERBEP) project with Baylor University will demonstrate the effectiveness of ethanols as an aviation fuel while providing several environmental and economic benefits. Part of this concern is caused by the petroleum industry. The basis for the petroleum industry to find an alternative aviation fuel will be dictated mainly by economic considerations. Three other facts compound the problem. First is the disposal of oil used in engines burning leaded fuel. This oil will contain too much lead to be burned in incinerators and will have to be treated as a toxic waste with relatively high disposal fees. Second, as a result of a greater demand for alkalites to be used in the automotive reformulated fuel, the costs of these components are likely to increase. Third, the Montreal Protocol will ban in 1998 the use of Ethyl-Di-Bromide, a lead scavenger used in leaded aviation fuel. Without a lead scavenger, leaded fuels cannot be used. The search for alternatives to leaded aviation fuels has been underway by different organizations for some time. As part of the search for alternatives, the Renewable Aviation Fuels Development Center (RAFDC) at Baylor University in Waco, Texas, has received a grant from the Federal Aviation Administration (FAA) to improve the efficiencies of ethanol powered aircraft engines and to test other non-petroleum alternatives to aviation fuel.

  15. Alcohol fuels bibliography, 1901-March 1980

    SciTech Connect (OSTI)

    Not Available

    1981-04-01

    This annotated bibliography is subdivided by subjects, as follows: general; feedstocks-general; feedstocks-sugar; feedstocks-starch; feedstocks-cellulose crops and residues; production; coproducts; economics; use as vehicle fuel; government policies; and environmental effects and safety. (MHR)

  16. NREL UL Fuel Dispensing Infrastructure Intermediate Blends Performance Testing (Presentation)

    SciTech Connect (OSTI)

    Moriarty, K.; Clark, W.

    2011-01-01

    Presentation provides an overview of NREL's project to determine compatibility and safe performance of installed fuel dispensing infrastructure with E15.

  17. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  18. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav; Kowal, Andrzej

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  19. NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2012-01-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  20. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

  1. Alcohol injection cuts diesel consumption on turbocharged tractors

    SciTech Connect (OSTI)

    Edson, D.V.

    1980-07-21

    M and W Gear Co. of Gibson City, IL, are marketing a new alcohol- injection system that permits turbocharged diesel engines to burn alcohol and claims to cut diesel consumption by 30% and more. The alcohol fuel, a blend of alcohol and water, does not meet the diesel fuel until the alcohol has been atomized and sprayed through the intake manifold into the cylinders. It permits farmers to use home- still-produced ethanol without the added expense of refining to anhydrous composition.

  2. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-05-13

    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.

  3. Design for a small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Berglund, G.R.; Richardson, J.G.

    1982-08-01

    The paper describes the small-scale fuel alcohol plant (SSFAT) which was designed as a small-scale chemical processing plant. The DOE publication, Fuel from Farms, set forth the basic design requirements. To lower operating costs, it was important that all the processes required to produce alcohol were integrated. Automated control was also an important consideration in the design to reduce the number of operators and operator time, thus reducing operating costs. Automated control also provides better quality control of the final product. The plant is presently operating in a test mode to evaluate operating characteristics. The discussion covers the following topics - design requirements; plan operations; fermentation; distillation; microprocessor control; automatic control; operating experience. 1 ref.

  4. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  5. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  6. Design for a small-scale fuel alcohol plant

    SciTech Connect (OSTI)

    Berglund, G.R.; Richardson, J.G.

    1982-08-01

    The fuel alcohol plant described in this article was designed, constructed and is being operated for the US DOE by EG and G Idaho. The plant can be operated by a single owner and produces 100 L of ethanol per hour and wet stillage for animal feed using corn as the primary feedstock. Existing technology and off-the-shelf equipment have been used whenever possible. The operation of the plant and microprocessor control of the process are described. (Refs. 1).

  7. Economic analysis of small-scale fuel alcohol plants

    SciTech Connect (OSTI)

    Schafer, J.J. Jr.

    1980-01-01

    To plan Department of Energy support programs, it is essential to understand the fundamental economics of both the large industrial size plants and the small on-farm size alcohol plants. EG and G Idaho, Inc., has designed a 25 gallon per hour anhydrous ethanol plant for the Department of Energy's Alcohol Fuels Office. This is a state-of-the-art reference plant, which will demonstrate the cost and performance of currently available equipment. The objective of this report is to examine the economics of the EG and G small-scale alcohol plant design and to determine the conditions under which a farm plant is a financially sound investment. The reference EG and G Small-Scale Plant is estimated to cost $400,000. Given the baseline conditions defined in this report, it is calculated that this plant will provide an annual after-tax of return on equity of 15%, with alcohol selling at $1.62 per gallon. It is concluded that this plant is an excellent investment in today's market, where 200 proof ethanol sells for between $1.80 and $2.00 per gallon. The baseline conditions which have a significant effect on the economics include plant design parameters, cost estimates, financial assumptions and economic forecasts. Uncertainty associated with operational variables will be eliminated when EG and G's reference plant begins operation in the fall of 1980. Plant operation will verify alcohol yield per bushel of corn, labor costs, maintenance costs, plant availability and by-product value.

  8. Energy-efficient alcohol-fuel production. Technical final report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The proposed utilization schedule for the alcohol fuel plant and methane generator is to produce 180 proof ethanol during the spring, summer, and fall (April to October). The ethanol will be used in the farm tractors and trucks during the planting, growing, and harvesting seasons. Some alcohol can be stored for use during the winter. The still will not be operated during the winter (November to March) when the methane from the digester will be used to replace fuel oil for heating a swine farrowing building. There are tentative plans to develop a larger methane generator, which will utilize all of the manure (dairy, beef, horses, and swine) produced on the ISU farm. If this project is completed, there will be enough methane to produce all of the alcohol fuel needed to operate all of the farm equipment, heat the buildings, and possibly generate electricity for the farm. The methane generating system developed is working so well that there is a great deal of interest in expanding the project to where it could utilize all of the livestock waste on the farm for methane production.

  9. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  10. Fuel alcohol production from agricultural lignocellulosic feedstocks

    SciTech Connect (OSTI)

    Farina, G.E.; Barrier, J.W.; Forsythe, M.L. )

    1988-01-01

    A two-stage, low-temperature, ambient pressure, acid hydrolysis process that utilizes separate unit operations to convert hemicellulose and cellulose in agricultural residues and crops to fermentable sugars is being developed and tested. Based on the results of the bench-scale tests, an acid hydrolysis experimental plant to demonstrate the concepts of low-temperature acid hydrolysis on a much larger scale was built. Plant tests using corn stover have been conducted for more that a year and conversion efficiences have equaled those achieved in the laboratory. Laboratory tests to determine the potential for low-temperature acid hydrolysis of other feedstocks - including red clover, alfalfa, kobe lespedeza, winter rape, and rye grass - are being conducted. Where applicable, process modifications to include extraction before or after hydrolysis also are being studied. This paper describes the experimental plant and process, results obtained in the plant, results of alternative feedstocks testing in the laboratory, and a plan for an integrated system that will produce other fuels, feed, and food from crops grown on marginal land.

  11. On-farm anaerobic digester and fuel alcohol plant

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    An anaerobic digestion system was constructed and set up on a southern Illinois farm. The anaerobic digestion system was designed to be coupled with a fuel alcohol plant constructed by the farm family as part of an integrated farm energy system. The digester heating can be done using waste hot water from the alcohol plant and biogas from the digester can be used as fuel for the alcohol production. The anaerobic digestion system is made up of the following components. A hog finishing house, which already had a slotted floor and manure pit beneath it, was fitted with a system to scrape the manure into a feed slurry pit constructed at one end of the hog house. A solids handling pump feeds the manure from the feed slurry pit into the digester, a 13,000 gallon tank car body which has been insulated with styrofoam and buried underground. Another pump transfers effluent (digested manure) from the digester to a 150,000 gallon storage tank. The digested manure is then applied to cropland at appropriate times of the year. The digester temperature is maintained at the required level by automated hot water circulation through an internal heat exchanger. The biogas produced in the digester is pumped into a 32,000 gallon gas storage tank.

  12. Preliminary report on blending strategies for inert-matrix fuel recycling in LWRs.

    SciTech Connect (OSTI)

    Hoffman, E. A.; Nuclear Engineering Division

    2005-04-29

    Various recycle strategies have been proposed to manage the inventory of transuranics in commercial spent nuclear fuel (CSNF), with a particular goal of increasing the loading capacity of spent fuel and reprocessing wastes in the Yucca Mountain repository. Transuranic recycling in commercial LWRs can be seen as a viable means of slowing the accumulation of transuranics in the nationwide CSNF stockpile. Furthermore, this type of approach is an important first step in demonstrating the benefits of a nuclear fuel cycle which incorporates recycling, such as envisioned for Generation-IV reactor systems under development. Recycling strategies of this sort are not proposed as an attempt to eliminate the need of a geologic nuclear waste repository, but as a means to enhance the usefulness of the repository currently under construction in the U.S., perhaps circumventing the need for a second facility. A US-DOE Secretarial recommendation on the need for the construction of a second geologic repository is required by 2010. The Advanced Fuel Cycle Initiative (AFCI) has supported a breadth of work to evaluate the ideal transuranic separation and recycle strategy. Previous AFCI studies of LWR-based transmutation have considered the benefits of homogeneously recycling plutonium, plutonium and neptunium, and all transuranic (TRU) species. A study of a wide range of hypothetical separation schemes (Pu, Pu+Np, Pu+Np+Am, etc.) with multi-recycling has also been performed, focusing on the proliferation resistance of the various fuel cycles and fuel handling issues. The direct recycle of the recovered TRU from spent inert-matrix fuel (IMF) into new IMF was found to be quite limited due to the rapid burndown of the fissile plutonium. The IMF is very effective at destroying the fissile fraction of the TRU with destruction rates in excess of 80% of the fissile material without recycling the IMF. Blending strategies have been proposed to mitigate the rapid burndown of the fissile plutonium by mixing high fissile feed from new sources (e.g., spent UO{sub 2} pins) with the low fissile material recovered from the recycled transmutation fuel. The blending of the fuels is anticipated to aid the multi-recycle of the transuranics. A systematic study of blending strategies (for both IMF and MOX) has been initiated and is currently ongoing. This work extends the previous study that considered separation strategies for plutonium, neptunium, and americium recycling in MOX, CORAIL, and IMF{sub 6} by considering blending schemes and approach to continuous recycle. Plutonium and americium are recycled in order to reduce the intermediate term (100 to 1500 years after spent fuel irradiation) decay heat of the disposed waste which accounts for the bulk of the repository heating. Since the long-term released dose from the repository is dominated by neptunium, it is sensible to consume it by transmutation in a reactor, as well. Curium accounts for {approx}0.6% of the TRU mass in spent UO{sub 2} fuel ({approx}0.008% of the heavy metal), but does constitute significantly higher fractions in spent transmutation fuels. This initial evaluation will focus on blending strategies for the multirecycling of Pu+Np+Am. The impact of curium recycle will be investigated as part of the systematic study of blending strategies. The initial study focuses on understanding a simple strategy for IMF recycle and blending. More complex strategies (i.e., heterogeneous assemblies) will be evaluated later in the year, including enriched uranium support options. Currently, a preliminary study of a serial blending strategy has been performed in order to evaluate the impact of blending on the performance of the IMF recycle and to evaluate the potential for continuous or infinite recycle. The continuous recycle of Pu+Np+Am in IMF would allow for complete destruction of all heat contributing actinides in the same LWRs that originally produced them. The only transuranics sent to the repository would be those lost in reprocessing and curium if it is not eventually recycled.

  13. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection

    Broader source: Energy.gov [DOE]

    Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions.

  14. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  15. Effects of High Octane Ethanol Blends on Four Legacy Flex-Fuel Vehicles, and a Turbocharged GDI Vehicle

    SciTech Connect (OSTI)

    Thomas, John F; West, Brian H; Huff, Shean P

    2015-03-01

    The U.S. Department of Energy (DOE) is supporting engine and vehicle research to investigate the potential of high-octane fuels to improve fuel economy. Ethanol has very high research octane number (RON) and heat of vaporization (HoV), properties that make it an excellent spark ignition engine fuel. The prospects of increasing both the ethanol content and the octane number of the gasoline pool has the potential to enable improved fuel economy in future vehicles with downsized, downsped engines. This report describes a small study to explore the potential performance benefits of high octane ethanol blends in the legacy fleet. There are over 17 million flex-fuel vehicles (FFVs) on the road today in the United States, vehicles capable of using any fuel from E0 to E85. If a future high-octane blend for dedicated vehicles is on the horizon, the nation is faced with the classic chicken-and-egg dilemma. If today’s FFVs can see a performance advantage with a high octane ethanol blend such as E25 or E30, then perhaps consumer demand for this fuel can serve as a bridge to future dedicated vehicles. Experiments were performed with four FFVs using a 10% ethanol fuel (E10) with 88 pump octane, and a market gasoline blended with ethanol to make a 30% by volume ethanol fuel (E30) with 94 pump octane. The research octane numbers were 92.4 for the E10 fuel and 100.7 for the E30 fuel. Two vehicles had gasoline direct injected (GDI) engines, and two featured port fuel injection (PFI). Significant wide open throttle (WOT) performance improvements were measured for three of the four FFVs, with one vehicle showing no change. Additionally, a conventional (non-FFV) vehicle with a small turbocharged direct-injected engine was tested with a regular grade of gasoline with no ethanol (E0) and a splash blend of this same fuel with 15% ethanol by volume (E15). RON was increased from 90.7 for the E0 to 97.8 for the E15 blend. Significant wide open throttle and thermal efficiency performance improvement was measured for this vehicle, which achieved near volumetric fuel economy parity on the aggressive US06 drive cycle, demonstrating the potential for improved fuel economy in forthcoming downsized, downsped engines with high-octane fuels.

  16. Addendum: Tenth International Symposium on Alcohol Fuels, The road to commercialization

    SciTech Connect (OSTI)

    Not Available

    1994-05-01

    The Tenth International Symposium on ALCOHOL FUELS ``THE ROAD TO COMMERCIALIZATION`` was held at the Broadmoor Hotel, Colorado Springs, Colorado, USA November 7--10, 1993. Twenty-seven papers on the production of alcohol fuels, specifications, their use in automobiles, buses and trucks, emission control, and government policies were presented. Individual papers have been processed separately for entry into the data base.

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Specifications Ethanol-blended gasoline must conform to ASTM D4814, E85 must conform to ASTM D4806, and biodiesel-blended fuel containing at least 6%, but no more than 20%, biodiesel must conform to ASTM D7467. Additionally, biobutanol must be an agriculturally derived isobutyl alcohol that meets ASTM D7862 for butanol for blending with gasoline for use as a motor fuel. Gasoline blended with biobutanol must conform to ASTM D4814. The state defers to the U.S. Environmental Protection

  18. Overview of fuel alcohol from agricultural crops with emphasis on the Tennessee Valley. Bulletin Y-171

    SciTech Connect (OSTI)

    Roetheli, J.C.; Pile, R.S.; Young, H.C.

    1982-02-01

    An overview is presented of the factors and concerns associated with producing fuel alcohol from agricultural crops. Areas covered include: an assessment of energy used in agriculture; a categorization of grain crop production, land suitable for energy crop production, and livestock production in the 201-county TVA region; a summary of technical and economic information on fuel alcohol production; a discussion of acreages required to produce fuel for benchmark farms in the Tennessee Valley and possible erosion impacts; and a discussion of other pertinent advantages and disadvantages of fuel alcohol production from crops.

  19. Fuel and Fuel Additive Registration Testing of Ethanol-Diesel Blend for O2Diesel, Inc.

    SciTech Connect (OSTI)

    Fanick, E. R.

    2004-02-01

    O2 Diesel Inc. (formerly AAE Technologies Inc.) tested a heavy duty engine with O2Diesel (diesel fuel with 7.7% ethanol and additives) for regulated emissions and speciation of vapor-phase and semi-volatile hydrocarbon compounds. This testing was performed in support of EPA requirements for registering designated fuels and fuel additives as stipulated by sections 211(b) and 211(e) of the Clean Air Act.

  20. Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth

    Broader source: Energy.gov [DOE]

    Discusses results of cold- and hot-start transient tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol)

  1. Plasma-Enhanced Combustion of Hydrocarbon Fuels and Fuel Blends Using Nanosecond Pulsed Discharges

    SciTech Connect (OSTI)

    Cappelli, Mark; Mungal, M Godfrey

    2014-10-28

    This project had as its goals the study of fundamental physical and chemical processes relevant to the sustained premixed and non-premixed jet ignition/combustion of low grade fuels or fuels under adverse flow conditions using non-equilibrium pulsed nanosecond discharges.

  2. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION...

    Office of Scientific and Technical Information (OSTI)

    ... Charbonneau, P., Slodowske, W., Mikkelson, S.-E., and McCandless, J., "A New Clean Diesel Technology: Demonstration of ULEV Emissions on a Navistar Diesel Engine Fueled with ...

  3. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2009-07-21

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

  4. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  5. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2010-05-15

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet-stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines. (author)

  6. Emission Characteristics of a Diesel Engine Operating with In-Cylinder Gasoline and Diesel Fuel Blending

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Curran, Scott; Barone, Teresa L; Lewis Sr, Samuel Arthur; Storey, John Morse; Cho, Kukwon; Wagner, Robert M; Parks, II, James E

    2010-01-01

    Advanced combustion regimes such as homogeneous charge compression ignition (HCCI) and premixed charge compression ignition (PCCI) offer benefits of reduced nitrogen oxides (NOx) and particulate matter (PM) emissions. However, these combustion strategies often generate higher carbon monoxide (CO) and hydrocarbon (HC) emissions. In addition, aldehydes and ketone emissions can increase in these modes. In this study, the engine-out emissions of a compression-ignition engine operating in a fuel reactivity- controlled PCCI combustion mode using in-cylinder blending of gasoline and diesel fuel have been characterized. The work was performed on a 1.9-liter, 4-cylinder diesel engine outfitted with a port fuel injection system to deliver gasoline to the engine. The engine was operated at 2300 rpm and 4.2 bar brake mean effective pressure (BMEP) with the ratio of gasoline to diesel fuel that gave the highest engine efficiency and lowest emissions. Engine-out emissions for aldehydes, ketones and PM were compared with emissions from conventional diesel combustion. Sampling and analysis was carried out following micro-tunnel dilution of the exhaust. Particle geometric mean diameter, number-size distribution, and total number concentration were measured by a scanning mobility particle sizer (SMPS). For the particle mass measurements, samples were collected on Teflon-coated quartz-fiber filters and analyzed gravimetrically. Gaseous aldehydes and ketones were sampled using dinitrophenylhydrazine-coated solid phase extraction cartridges and the extracts were analyzed by liquid chromatography/mass spectrometry (LC/MS). In addition, emissions after a diesel oxidation catalyst (DOC) were also measured to investigate the destruction of CO, HC and formaldehydes by the catalyst.

  7. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    D. Straub; D. Ferguson; K. Casleton; G. Richards

    2006-03-01

    U.S. natural gas composition is expected to be more variable in the future. Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Unconventional gas supplies, like coal-bed methane, are also expected to grow. As a result of these anticipated changes, the composition of fuel sources may vary significantly from existing domestic natural gas supplies. To allow the greatest use of gas supplies, end-use equipment should be able to accommodate the widest possible gas composition. For this reason, the effect of gas composition on combustion behavior is of interest. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 589K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx emissions. These results vary from data reported in the literature for some engine applications and potential reasons for these differences are discussed.

  8. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  9. On-farm production of fuel-alcohol in Mid-America technical and economic potential

    SciTech Connect (OSTI)

    Hohmann, M.A.

    1980-03-01

    Alcohol fuel production is suggested as an alternative to high energy costs for the Mid-American farmer. The steps involved in producing alcohol from biomass are reviewed. Fermentation equipment and procedures are readily available. The utilization of by-products for animal feeds is discussed. Combustion characteristics and chemical properties of ethanol are reviewed. Estimates are made of costs involved in alcohol production in the mid-west region. Regional agricultural consumption of gasoline is estimated and 3 scenarios are developed. Benefits of on-farm fuel production are outlined. (DMC)

  10. Feasibility study of fuel grade ethanol plant for Alcohol Fuels of Mississippi, Inc. , Vicksburg, Mississippi

    SciTech Connect (OSTI)

    1981-01-01

    The results are presented of a feasibility study performed to determine the technical and economic viability of constructing an alcohol plant utilizing the N.Y.U. continuous acid hydrolysis process to convert wood wastes to fuel grade alcohol. The following is a summary of the results: (1) The proposed site in the Vicksburg Industrial Foundation Corporation Industrial Park is adequate from all standpoints, for all plant capacities envisioned. (2) Local hardwood sawmills can provide adequate feedstock for the facility. The price per dry ton varies between $5 and $15. (3) Sale of fuel ethanol would be made primarily through local distributors and an adequate market exists for the plant output. (4) With minor modifications to the preparation facilities, other waste cellulose materials can also be utilized. (5) There are no anticipated major environmental, health, safety or socioeconomic risks related to the construction and operation of the proposed facility. (6) The discounted cash flow and rate of return analysis indicated that the smallest capacity unit which should be built is the 16 million gallon per year plant, utilizing cogeneration. This facility has a 3.24 year payback. (7) The 25 million gallon per year plant utilizing cogeneration is an extremely attractive venture, with a zero interest break-even point of 1.87 years, and with a discounted rate of return of 73.6%. (8) While the smaller plant capacities are unattractive from a budgetary viewpoint, a prudent policy would dictate that a one million gallon per year plant be built first, as a demonstration facility. This volume contains process flowsheets and maps of the proposed site.

  11. Design report small-scale fuel alcohol plant. Volume II. Detailed construction information

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of a small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. Volume two includes equipment and instrumentation data sheets, instrument loop wiring diagrams, and vendor lists.

  12. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  13. Small-scale production of alcohol fuel: not feasible for the farmer

    SciTech Connect (OSTI)

    Miles, J.D.

    1980-10-01

    On-farm alcohol fuel production is not too promising at this time because of the present state of small-scale technology and marketing and some problems with utilization. Small-scale production shows a significant decrease in yield and unacceptable water levels, which makes the cost uncompetitive with large producers. The advantages of on-farm production are that farmers can produce homegrown feedstocks and provide a reliable source of fuel for their own needs as well as an alternative market for surplus grain. Engine modifications must be made, however, in order to use either straight alcohol or combinations of alcohol with gasoline or diesel fuel. Production problems include the need for constant monitoring and temperature control, the high cost of intermittent operation, variations in grain prices, and the difficulty for many farmers of selecting appropriate equipment and complying with regulations. Cooperatives may be the answer to some of these problems. 2 tables. (DCK)

  14. Use of alcohol fuel: engine-conversion demonstration. Final report

    SciTech Connect (OSTI)

    Marsh, W.K.

    1982-01-01

    The use of ethanol as a fuel extender when mixed with gasoline, and the use of both hydrated and anhydrous ethanol as a fuel in gasoline and diesel engines are discussed. Required engine modifications for efficient use of ethanol are described, and include engine compression alterations, carburetor adjustments, and arrangement for fuel preheating. In 1981 and 1982 a demonstration of ethanol use in spark ignition engines was conducted at a major public park in South Carolina. The demonstration included a controlled road test with a pick-up truck and a demonstration of ethanol use in small, air cooled gasoline engines. One problem that was identified was that of contaminated fuel that clogged the fuel system after a few days' operation. (LEW)

  15. Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

    SciTech Connect (OSTI)

    Kirby S. Chapman; Amar Patil

    2007-06-30

    Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.

  16. On-farm anaerobic digester and fuel-alcohol plant. Final report

    SciTech Connect (OSTI)

    Bengtson, H.H.

    1985-12-01

    An anaerobic-digestion system, coupled with a fuel-alcohol plant, was constructed and set up on a southern Illinois farm as part of an integrated farm-energy system. The digester heating can be done using waste hot water from the alcohol plant and biogas from the digester can be used as fuel for the alcohol production. The anaerobic digestion system is made up of the following components; a hog finishing house with a manure pit; a solids handling pump to feed the manure; and a 13,000-gallon railroad tank car as the main digester vessel and pump to transfer effluent from the digester to a 150,000 gallon storage tank. The digester was operated for sufficient time to demonstrate the use of hot water in an automated digester temperature control system. Sufficient biogas was produced to demonstrate the use of biogas in a converted propane boiler.

  17. Missouri Renewable Fuel Standard Brochure

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    The Missouri Renewable Fuel Standard requires ethanol in most gasoline beginning January 1, 2008. ARE YOU READY? TEN THINGS MISSOURI TANK OWNERS AND OPERATORS NEED TO KNOW ABOUT ETHANOL 1. Ethanol is a type of alcohol made usually from corn in Missouri and other states. 2. E10 is a blend of 10% ethanol and 90% unleaded gasoline. E85 is a blend of 75% to 85% fuel ethanol and 25% to 15% unleaded gasoline. Blends between E10 and E85 are not allowed to be sold at retail. 3. Any vehicle or small

  18. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  19. New Analysis Methods Estimate a Critical Property of Ethanol Fuel Blends (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods developed at NREL disclose the impact of ethanol on gasoline blend heat of vaporization with potential for improved efficiency of spark-ignition engines. More stringent standards for fuel economy, regulation of greenhouse gas emissions, and the mandated increase in the use of renew- able fuel are driving research to improve the efficiency of spark ignition engines. When fuel properties such as octane number and evaporative cooling (heat of vaporization or HOV) are insufficient, they

  20. Design report small-scale fuel alcohol palnt. Volume III. Drawings

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    The objectives of the report are to (a) provide potential alcohol producers with a reference design and (b) provide a complete, demonstrated design of small-scale fuel alcohol plant. This report describes a small-scale fuel alcohol plant designed and constructed for the DOE by EG and G Idaho, Inc., an operating contractor at the Idaho National Engineering Laboratory. The plant is reasonably complete, having the capability for feedstock preparation, cooking, saccharification, fermentation, distillation, by-product dewatering, and process steam generation. An interesting feature is an instrumentation and control system designed to allow the plant to run 24 hours per day with only four hours of operator attention. Where possible, this document follows the design requirements established in the DOE publication Fuel From Farms, which was published in February 1980. For instance, critical requirements such as using corn as the primary feedstock, production of 25 gallons of 190 proof ethanol per hour, and using batch fermentation were taken from Fuel From Farms. One significant deviation is alcohol dehydration. Fuel From Farms recommends the use of a molecular sieve for dehydration, but a preliminary design raised significant questions about the cost effectiveness of this approach. A cost trade-off study is currently under way to establish the best alcohol dehydration method and will be the subject of a later report. This volume contains the equipment and construction drawings used to build the small-scale ethanol plant. The design in this volume represents the design at completion of construction and before continuous production began.

  1. U.S. Department of Energy FreedomCAR & Vehicle Technologies Program Advanced Vehicle Testing Activity, Hydrogen/CNG Blended Fuels Performance Testing in a Ford F-150

    SciTech Connect (OSTI)

    James E. Francfort

    2003-11-01

    Federal regulation requires energy companies and government entities to utilize alternative fuels in their vehicle fleets. To meet this need, several automobile manufacturers are producing compressed natural gas (CNG)-fueled vehicles. In addition, several converters are modifying gasoline-fueled vehicles to operate on both gasoline and CNG (Bifuel). Because of the availability of CNG vehicles, many energy company and government fleets have adopted CNG as their principle alternative fuel for transportation. Meanwhile, recent research has shown that blending hydrogen with CNG (HCNG) can reduce emissions from CNG vehicles. However, blending hydrogen with CNG (and performing no other vehicle modifications) reduces engine power output, due to the lower volumetric energy density of hydrogen in relation to CNG. Arizona Public Service (APS) and the U.S. Department of Energy’s Advanced Vehicle Testing Activity (DOE AVTA) identified the need to determine the magnitude of these effects and their impact on the viability of using HCNG in existing CNG vehicles. To quantify the effects of using various blended fuels, a work plan was designed to test the acceleration, range, and exhaust emissions of a Ford F-150 pickup truck operating on 100% CNG and blends of 15 and 30% HCNG. This report presents the results of this testing conducted during May and June 2003 by Electric Transportation Applications (Task 4.10, DOE AVTA Cooperative Agreement DEFC36- 00ID-13859).

  2. Alcohol as a fuel for farm and construction equipment

    SciTech Connect (OSTI)

    Borman, G L; Foster, D E; Meyers, P S; Uyehara, O A

    1982-06-01

    Work in three areas dealing with the utilization of ethanol as fuel for farm and construction diesels is summarized. The first part is a review of what is known about the retrofitting of diesels for use of ethanol and the combustion problems involved. The second part is a discussion of the work that has been done under the contract on the performance of a single-cylinder, open-chamber diesel using solutions and emulsions of diesel fuel with ethanol. Data taken include performance, emissions and cylinder pressure-time for diesel fuel with zero to forty percent ethanol by volume. Analysis of the data includes calculation of heat release rates using a single zone model. The third part is a discussion of work done retrofitting a multicylinder turbocharged farm tractor diesel to use ethanol by fumigation. Three methods of ethanol introduction are discussed; spraying ethanol upstream and downstream of the compressor and prevaporization of the ethanol. Data on performance and emissions are given for the last two methods. A three zone heat release model is described and results from the model are given. A correlation of the ignition delay using prevaporized ethanol fumigation data is also given. Comparisons are made between fumigation in DI and IDI engines.

  3. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P.; Scahill, John W.; Chum, Helena L.; Evans, Robert J.; Rejai, Bahman; Bain, Richard L.; Overend, Ralph P.

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  4. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  5. Liquid Fuel From Renewable Electricity and Bacteria: Electro-Autotrophic Synthesis of Higher Alcohols

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: UCLA is utilizing renewable electricity to power direct liquid fuel production in genetically engineered Ralstonia eutropha bacteria. UCLA is using renewable electricity to convert carbon dioxide into formic acid, a liquid soluble compound that delivers both carbon and energy to the bacteria. The bacteriaare genetically engineered to convert the formic acid into liquid fuelin this case alcohols such as butanol. The electricity required for the process can be generated from sunlight, wind, or other renewable energy sources. In fact, UCLAs electricity-to-fuel system could be a more efficient way to utilize these renewable energy sources considering the energy density of liquid fuel is much higher than the energy density of other renewable energy storage options, such as batteries.

  6. Small-scale fuel alcohol production. Technical report

    SciTech Connect (OSTI)

    Not Available

    1980-03-01

    This report describes in substantial detail technical and economic aspects of small-scale ethanol production from on-farm units producing up to 360,000 gallons per year and community plants producing up to 2 million gallons per year. The description of feedstock materials is limited to those containing starches and sugars, not cellulosic materials. Factors influencing the introduction of small-scale ethanol production are evaluated, including the availability and technical capabilities of production equipment. Also discussed are the types and sizes of farms and community operations for which ethanol production is appropriate. The report describes the characteristics of ethanol and its use as a motor fuel, the production and use of co-products, and problems typically encountered by small-scale producers. Information on investment, operation, maintenance and feedstock costs is estimated and analyzed. A sensitivity analysis describes changes in the cost of ethanol production resulting from changes in the major cost elements.

  7. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more components of the elastomers (by the solvent). This extraction of additives can negatively change the properties of the elastomer, leading to reduced performance and durability. For a seal application, some level of volume swell is acceptable, since the expansion will serve to maintain a seal. However, the acceptable level of swell is dependent on the particular application of the elastomer product. It is known that excessive swell can lead to unacceptable extrusion of the elastomer beyond the sealed interface, where it becomes susceptible to damage. Also, since high swell is indicative of high solubility, there is a heightened potential for fluid to seep through the seal and into the environment. Plastics, on the other hand, are used primarily in structural applications, such as solid components, including piping and fluid containment. Volume change, especially in a rigid system, will create internal stresses that may negatively affect performance. In order to better understand and predict the compatibility for a given polymer type and fuel composition, an analysis based on Hansen solubility theory was performed for each plastic and elastomer material. From this study, the solubility distance was calculated for each polymer material and test fuel combination. Using the calculated solubility distance, the ethanol concentration associated with peak swell and overall extent of swell can be predicted for each polymer. The bulk of the material discussion centers on the plastic materials, and their compatibility with Fuel C, CE25a, CE50a, and CE85a. The next section of this paper focuses on the elastomer compatibility with the higher ethanol concentrations with comparison to results obtained previously for the lower ethanol levels. The elastomers were identical to those used in the earlier study. Hansen solubility theory is also applied to the elastomers to provide added interpretation of the results. The final section summarizes the performance of the metal coupons.

  8. TVA application of integrated onfarm fuel alcohol production system. Annual report

    SciTech Connect (OSTI)

    Badger, P C; Pile, R S

    1980-01-01

    This contract has provided for the documentation of the feasibility of fuel alcohol production with small onfarm facilities, and for the design and construction of an efficient and easily constructed production facility. A feasibility study and a preliminary design report have been prepared. A prototype facility has been designed and constructed with a design production rate of 10 gallons per hour of 190-proof ethanol. The components of the facility are readily available through normal equipment supply channels or can be primarily owner-constructed. Energy efficiency was also of prime consideration in the design, and heat recovery equipment is included where practical. A renewable fuel boiler is used for process heat. Applicable safety standards and environmental requirements were also incorporated into the design. Other project activities included modification of a pickup truck to use the hydrous alcohol produced, evaluation of vacuum distillation for onfarm units, and development of a computer program to allow detailed economic analyses of fuel alcohol production. Efforts were also initiated to evaluate nongrain feedstocks, develop a preliminary design for a low-cost wood-fired boiler, and evaluate packed distillation columns constructed of plastic pipe.

  9. NREL UL E15 Fuel Dispensing Infrastructure Intermediate Blends Performance Testing (Presentation)

    SciTech Connect (OSTI)

    Moriarty, K.; Clark, W.

    2011-02-01

    Presentation provides an overview of NREL's project to determine compatibility and safe performance of installed fuel dispensing infrastructure with E15.

  10. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos; Graves, Ronald Lee; Storey, John Morse Elliot; Lewis, Sr., Samuel Arthur; Sluder, Charles Scott; Thomas, John Foster

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  11. Alcohol-fueled vehicles: An alternative fuels vehicle, emissions, and refueling infrastructure technology assessment

    SciTech Connect (OSTI)

    McCoy, G.A.; Kerstetter, J.; Lyons, J.K.

    1993-06-01

    Interest in alternative motor vehicle fuels has grown tremendously over the last few years. The 1990 Clean Air Act Amendments, the National Energy Policy Act of 1992 and the California Clean Air Act are primarily responsible for this resurgence and have spurred both the motor fuels and vehicle manufacturing industries into action. For the first time, all three U.S. auto manufacturers are offering alternative fuel vehicles to the motoring public. At the same time, a small but growing alternative fuels refueling infrastructure is beginning to develop across the country. Although the recent growth in alternative motor fuels use is impressive, their market niche is still being defined. Environmental regulations, a key driver behind alternative fuel use, is forcing both car makers and the petroleum industry to clean up their products. As a result, alternative fuels no longer have a lock on the clean air market and will have to compete with conventional vehicles in meeting stringent future vehicle emission standards. The development of cleaner burning gasoline powered vehicles has signaled a shift in the marketing of alternative fuels. While they will continue to play a major part in the clean vehicle market, alternative fuels are increasingly recognized as a means to reduce oil imports. This new role is clearly defined in the National Energy Policy Act of 1992. The Act identifies alternative fuels as a key strategy for reducing imports of foreign oil and mandates their use for federal and state fleets, while reserving the right to require private and municipal fleet use as well.

  12. Estimating Impacts of Diesel Fuel Reformulation with Vector-based Blending

    SciTech Connect (OSTI)

    Hadder, G.R.

    2003-01-23

    The Oak Ridge National Laboratory Refinery Yield Model has been used to study the refining cost, investment, and operating impacts of specifications for reformulated diesel fuel (RFD) produced in refineries of the U.S. Midwest in summer of year 2010. The study evaluates different diesel fuel reformulation investment pathways. The study also determines whether there are refinery economic benefits for producing an emissions reduction RFD (with flexibility for individual property values) compared to a vehicle performance RFD (with inflexible recipe values for individual properties). Results show that refining costs are lower with early notice of requirements for RFD. While advanced desulfurization technologies (with low hydrogen consumption and little effect on cetane quality and aromatics content) reduce the cost of ultra low sulfur diesel fuel, these technologies contribute to the increased costs of a delayed notice investment pathway compared to an early notice investment pathway for diesel fuel reformulation. With challenging RFD specifications, there is little refining benefit from producing emissions reduction RFD compared to vehicle performance RFD. As specifications become tighter, processing becomes more difficult, blendstock choices become more limited, and refinery benefits vanish for emissions reduction relative to vehicle performance specifications. Conversely, the emissions reduction specifications show increasing refinery benefits over vehicle performance specifications as specifications are relaxed, and alternative processing routes and blendstocks become available. In sensitivity cases, the refinery model is also used to examine the impact of RFD specifications on the economics of using Canadian synthetic crude oil. There is a sizeable increase in synthetic crude demand as ultra low sulfur diesel fuel displaces low sulfur diesel fuel, but this demand increase would be reversed by requirements for diesel fuel reformulation.

  13. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications

    SciTech Connect (OSTI)

    Pei, Yuanjiang; Mehl, Marco; Liu, Wei; Lu, Tianfeng; Pitz, William J.; Som, Sibendu

    2015-05-12

    A mixture of n-dodecane and m-xylene is investigated as a diesel fuel surrogate for compression ignition engine applications. Compared to neat n-dodecane, this binary mixture is more representative of diesel fuel because it contains an alkyl-benzene which represents an important chemical class present in diesel fuels. A detailed multi-component mechanism for n-dodecane and m-xylene was developed by combining a previously developed n-dodecane mechanism with a recently developed mechanism for xylenes. The xylene mechanism is shown to reproduce experimental ignition data from a rapid compression machine and shock tube, speciation data from the jet stirred reactor and flame speed data. This combined mechanism was validated by comparing predictions from the model with experimental data for ignition in shock tubes and for reactivity in a flow reactor. The combined mechanism, consisting of 2885 species and 11754 reactions, was reduced to a skeletal mechanism consisting 163 species and 887 reactions for 3D diesel engine simulations. The mechanism reduction was performed using directed relation graph (DRG) with expert knowledge (DRG-X) and DRG-aided sensitivity analysis (DRGASA) at a fixed fuel composition of 77% of n-dodecane and 23% m-xylene by volume. The sample space for the reduction covered pressure of 1 – 80 bar, equivalence ratio of 0.5 – 2.0, and initial temperature of 700 – 1600 K for ignition. The skeletal mechanism was compared with the detailed mechanism for ignition and flow reactor predictions. Finally, the skeletal mechanism was validated against a spray flame dataset under diesel engine conditions documented on the Engine Combustion Network (ECN) website. These multi-dimensional simulations were performed using a Representative Interactive Flame (RIF) turbulent combustion model. Encouraging results were obtained compared to the experiments with regards to the predictions of ignition delay and lift-off length at different ambient temperatures.

  14. No Fossils in This Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plan for Environmental Teaching GM Environmental Science Club No Fossils in This Fuel Your PlanET Sixth through Eighth Grades (Can be easily adapted to any elementary/middle school level) Ingredients: Yeast, sugar ... what are you making? Sweet rolls? Not in Science Class! You're blending these ingredients to make an innovative form of fuel! That's right ... when these two simple ingredients are mixed, the yeast  a simple, living organism  breaks the sugar down into ethyl alcohol, or

  15. Method of producing a diesel fuel blend having a pre-determined flash-point and pre-determined increase in cetane number

    DOE Patents [OSTI]

    Waller, Francis Joseph; Quinn, Robert

    2004-07-06

    The present invention relates to a method of producing a diesel fuel blend having a pre-determined flash-point and a pre-determined increase in cetane number over the stock diesel fuel. Upon establishing the desired flash-point and increase in cetane number, an amount of a first oxygenate with a flash-point less than the flash-point of the stock diesel fuel and a cetane number equal to or greater than the cetane number of the stock diesel fuel is added to the stock diesel fuel in an amount sufficient to achieve the pre-determined increase in cetane number. Thereafter, an amount of a second oxygenate with a flash-point equal to or greater than the flash-point of the stock diesel fuel and a cetane number greater than the cetane number of the stock diesel fuel is added to the stock diesel fuel in an amount sufficient to achieve the pre-determined increase in cetane number.

  16. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W.

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  17. Biodiesel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    A 2-page fact sheet discussing general biodiesel blends and the improvement in engine performance and emissions.

  18. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  19. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Biofuels and Biofuel Blends Robert McCormick Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies May 16, 2013 Project ID: FT003 This ...

  20. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Methanol ......with gas injection of sulfur dioxide, membrane saccharification, high-tolerance ... and performance under load, passing, etc. ...

  1. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A.; Andazola, Arthur H.; Reinhardt, Frederick W.

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  2. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Diesel Fuel Blend Tax Exemption The biodiesel or ethanol portion of blended fuel containing taxable diesel is exempt from the diesel fuel tax. The biodiesel or ethanol fuel blend must be clearly identified on the retail pump, storage tank, and sales invoice in order to be eligible for the exemption. (Reference Texas Statutes, Tax Code 162.2

  4. A Comparison of HCCI Engine Performance Data and Kinetic Modeling Results over a Wide Rangeof Gasoline Range Surrogate Fuel Blends

    Broader source: Energy.gov [DOE]

    Kinetic models of fuels are needed to allow the simulation of engine performance for research, design, or verification purposes.

  5. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  6. In-Cylinder Fuel Blending of Gasoline/Diesel for Improved Efficiency and Lowest Possible Emissions on a Multi-Cylinder Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Curran, Scott; Prikhodko, Vitaly Y; Wagner, Robert M; Parks, II, James E; Cho, Kukwon; Sluder, Scott; Kokjohn, Sage; Reitz, Rolf

    2010-01-01

    In-cylinder fuel blending of gasoline/diesel fuel is investigated on a multi-cylinder light-duty diesel engine as a potential strategy to control in-cylinder fuel reactivity for improved efficiency and lowest possible emissions. This approach was developed and demonstrated at the University of Wisconsin through modeling and single-cylinder engine experiments. The objective of this study is to better understand the potential and challenges of this method on a multi-cylinder engine. More specifically, the effect of cylinder-to-cylinder imbalances, heat rejection, and in-cylinder charge motion as well as the potential limitations imposed by real-world turbo-machinery were investigated on a 1.9-liter four-cylinder engine. This investigation focused on one engine condition, 2300 rpm, 4.2 bar brake mean effective pressure (BMEP). Gasoline was introduced with a port-fuel-injection system. Parameter sweeps included gasoline-to-diesel fuel ratio, intake air mixture temperature, in-cylinder swirl number, and diesel start-of-injection phasing. In addition, engine parameters were trimmed for each cylinder to balance the combustion process for maximum efficiency and lowest emissions. An important observation was the strong influence of intake charge temperature on cylinder pressure rise rate. Experiments were able to show increased thermal efficiency along with dramatic decreases in oxides of nitrogen (NOX) and particulate matter (PM). However, indicated thermal efficiency for the multi-cylinder experiments were less than expected based on modeling and single-cylinder results. The lower indicated thermal efficiency is believed to be due increased heat transfer as compared to the model predictions and suggest a need for improved cylinder-to-cylinder control and increased heat transfer control.

  7. Hige Compression Ratio Turbo Gasoline Engine Operation Using Alcohol Enhancement

    SciTech Connect (OSTI)

    Heywood, John; Jo, Young Suk; Lewis, Raymond; Bromberg, Leslie; Heywood, John

    2015-10-31

    The overall objective of this project was to quantify the potential for improving the performance and efficiency of gasoline engine technology by use of alcohols to suppress knock. Knock-free operation is obtained by direct injection of a second “anti-knock” fuel such as ethanol, which suppresses knock when, with gasoline fuel, knock would occur. Suppressing knock enables increased turbocharging, engine downsizing, and use of higher compression ratios throughout the engine’s operating map. This project combined engine testing and simulation to define knock onset conditions, with different mixtures of gasoline and alcohol, and with this information quantify the potential for improving the efficiency of turbocharged gasoline spark-ignition engines, and the on-vehicle fuel consumption reductions that could then be realized. The more focused objectives of this project were therefore to: Determine engine efficiency with aggressive turbocharging and downsizing and high compression ratio (up to a compression ratio of 13.5:1) over the engine’s operating range; Determine the knock limits of a turbocharged and downsized engine as a function of engine speed and load; Determine the amount of the knock-suppressing alcohol fuel consumed, through the use of various alcohol-gasoline and alcohol-water gasoline blends, for different driving cycles, relative to the gasoline consumed; Determine implications of using alcohol-boosted engines, with their higher efficiency operation, in both light-duty and medium-duty vehicle sectors.

  8. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were ...

  9. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    F7: Distillate Fuel Oil Consumption Estimates, 2014 State Residential Commercial ... value less than 0.05. Notes: Distillate fuel oil estimates include biodiesel blended ...

  10. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

    2010-04-01

    Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

  11. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  12. Modifications for use of methanol or methanol-gasoline blends in automotive vehicles, September 1976-January 1980

    SciTech Connect (OSTI)

    Patterson, D.J.; Bolt, J.A.; Cole, D.E.

    1980-01-01

    Methanol or blends of methanol and gasoline as automotive fuels may be attractive means for extending the nation's petroleum reserves. The present study was aimed at identifying potential problems and solutions for this use of methanol. Retrofitting of existing vehicles as well as future vehicle design have been considered. The use of ethanol or higher alcohols was not addressed in this study but will be included at a later date. Several potentially serious problems have been identified with methanol use. The most attractive solutions depend upon an integrated combination of vehicle modifications and fuel design. No vehicle problems were found which could not be solved with relatively minor developments of existing technology providing the methanol or blend fuel was itself engineered to ameliorate the solution. Research needs have been identified in the areas of lubrication and materials. These, while apparently solvable, must precede use of methanol or methanol-gasoline blends as motor fuels. Because of the substantial costs and complexities of a retrofitting program, use of methanol must be evaluated in relation to other petroleum-saving alternatives. Future vehicles can be designed initially to operate satisfactorily on these alternate fuels. However a specific fuel composition must be specified around which the future engines and vehicles can be designed.

  13. Vehicle Technologies Office: Intermediate Ethanol Blends

    Broader source: Energy.gov [DOE]

    Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

  14. Alternative Fuels Data Center | Open Energy Information

    Open Energy Info (EERE)

    and resources to enable the use of alternative fuels, in addition to other petroleum reduction options such as advanced vehicles, fuel blends, idle reduction, and fuel...

  15. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  16. Performance and emissions characteristics of alternative fuels in spark ignition engines

    SciTech Connect (OSTI)

    Swain, M.R.; Maxwell, R.L.; Swain, M.N.; Bedsworth, K.; Adt, R.R. Jr.; Pappas, J.M.

    1984-01-01

    A formal ongoing program to characterize the performance and exhaust characteristics of automotive-type powerplants fueled by conventional and alternative fuels is reported. This report contains the information obtained during the past three years when four alternative fuels and two baseline fuels were evaluated in three engines. The four alternative fuels were a simulated gasoline made to represent coal derived gasoline, methyl aryl ethers blended at the 10% level in an unleaded gasoline, gasoline made from methanol, and a blend of Indolene plus methanol and higher alcohols. The two baseline fuels were, Indolene and Gulf unleaded regular gasoline. The engines tested were a pre-mixed carbureted SI (spark ignition) engine, a carbureted three-valve stratified-charge SI engine and a pre-mixed carbureted SI engine with a closed-loop three-way catalyst emission control system.

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Use and Vehicle Acquisition Requirements State agency fleets with more than 15 vehicles, excluding emergency and law enforcement vehicles, may not purchase or lease a motor vehicle unless the vehicle uses compressed or liquefied natural gas, propane, ethanol or fuel blends of at least 85% ethanol (E85), methanol or fuel blends of at least 85% methanol (M85), biodiesel or fuel blends of at least 20% biodiesel (B20), or electricity (including plug-in hybrid electric vehicles).

  18. Vehicle Technologies Office: Intermediate Ethanol Blends | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Intermediate Ethanol Blends Vehicle Technologies Office: Intermediate Ethanol Blends Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy Policy Act of 2005 and the Energy Security and Independence Act of 2007) requires the country use as much as 36 billion gallons of renewable fuels annually by 2022, most of which will be ethanol. However,

  19. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2008-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber o-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile o-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fuIly synthetic jet fuel in the place of petroleum-derived fueL

  20. Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels

    SciTech Connect (OSTI)

    Gormley, R.J.; Link, D.D.; Baltrus, J.P.; Zandhuis, P.H.

    2009-01-01

    A transition from petroleum-derived jet fuels to blends with Fischer-Tropsch (F-T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived fuel as did both the fuel and additive for a synthetic F-T jet fuel additized with benzyl alcohol, but less for the unadditized synthetic fuel. The specific compounds or classes of compounds involved in the partitioning were identified and a semiquantitative comparison of relative partitioning of the compounds of interest was made. The results provide another step forward in improving the confidence level of using additized, fully synthetic jet fuel in the place of petroleum-derived fuel.

  1. Fuels Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels Technologies Fuels Technologies Overview of DOE Fuels Technologies R&D activities, including fuels for advanced combustion engines, advanced petroleum-based and non-petroleum based fuels, and biofuels. PDF icon deer08_stork.pdf More Documents & Publications Mid-Level Ethanol Blends Mid-Level Ethanol Blends Test Program Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  2. The economical production of alcohol fuels from coal-derived synthesis gas. Seventh quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    An analysis of the current base cases has been undertaken to determine if the economic status of the proposed alcohol fuels may benefit from economies of scale. This analysis was based on a literature review which suggested that plants of capacities substantially below 5000 metric tons/day are unlikely to be competitive for the bulk production of alcohols for fuel consumption or chemicals manufacture. The preliminary results of this scale up procedure would indicate that the capacity of the current base cases be increased by a factor of eight. This would yield annual production of 4.1 million metric tons and essentially reduce the plant gate cost by approximately 41 percent in both cases. A facility of this size would be the equivalent of a medium sized oil refinery and would be capable of sustaining local market demands for fuel oxygenates. The actual competitiveness of this product with current oxygenates such as MTBE remains to be determined. The alcohol synthesis loop is being used to evaluate optimization procedures which will eventually be used to optimize the entire process. A more detailed design of the synthesis reactor is required, and a preliminary design of this reactor has been completed.

  3. H.R. 5299: A Bill to amend the Internal Revenue Code of 1986 to phase out the tax subsidies for alcohol fuels involving alcohol produced from feedstocks eligible to receive Federal agricultural subsidies. Introduced in the House of Representatives, One Hundred Third Congress, Second Session, November 29, 1994

    SciTech Connect (OSTI)

    1994-12-31

    The report H.R. 5299 is a bill to amend the Internal Revenue Code of 1986 to phase out the tax subsidies of alcohol fuels involving alcohol produced from feedstocks eligible to receive Federal agriculture subsidies. The proposed legislative text is included.

  4. Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report

    SciTech Connect (OSTI)

    Dombek, B.D.

    1996-03-01

    The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

  5. Elastomer Compatibility Testing of Renewable Diesel Fuels

    SciTech Connect (OSTI)

    Frame, E.; McCormick, R. L.

    2005-11-01

    In this study, the integrity and performance of six elastomers were tested with ethanol-diesel and biodiesel fuel blends.

  6. Preparation and characterization of polymer blend based on sulfonated poly (ether ether ketone) and polyetherimide (SPEEK/PEI) as proton exchange membranes for fuel cells

    SciTech Connect (OSTI)

    Hashim, Nordiana; Ali, Ab Malik Marwan; Lepit, Ajis; Rasmidi, Rosfayanti; Subban, Ri Hanum Yahaya; Yahya, Muhd Zu Azhan

    2015-08-28

    Blends of sulfonated poly (ether ether ketone) (SPEEK) and polyetherimide (PEI) were prepared in five different weight ratios using N-methyl-2-pyrrolidone (NMP) as solvent by the solution cast technique. The degree of sulfonation (DS) of the sulfonated PEEK was determined from deuterated dimethyl sulfoxide (DMSO-d{sub 6}) solution of the purified polymer using {sup 1}H NMR method. The properties studied in the present investigation includes conductivity, water uptake, thermal stability and structure analysis of pure SPEEK as well as SPEEK-PEI polymer blend membranes. The experimental results show that the conductivity of the membranes increased with increase in temperature from 30 to 80°C, except for that of pure SPEEK membrane which increased with temperature from 30 to 60°C while its conductivity decreased with increasing temperature from 60 to 80°C. The conductivity of 70wt.%SPEEK-30wt.%PEI blend membrane at 80% relative humidity (RH) is found to be 1.361 × 10{sup −3} Scm{sup −1} at 30°C and 3.383 × 10{sup −3} Scm{sup −1} at 80°C respectively. It was also found that water uptake and thermal stability of the membranes slightly improved upon blending with PEI. Structure analysis was carried out using Fourier Transform Infrared (FTIR) spectroscopy which revealed considerable interactions between sulfonic acid group of SPEEK and imide groups of PEI. Modification of SPEEK by blending with PEI shows good potential for improving the electrical and physical properties of proton exchange membranes.

  7. Hygroscopicity of fuels with anti-icing additives

    SciTech Connect (OSTI)

    Bedrik, B.G.; Golubushkin, V.N.; Uspenskii, S.I.

    1984-03-01

    This article investigates the accumulation of water by hydrocarbon fuels under static and dynamic conditions. Standard TS-1 fuel (aviation kerosine) is examined without an anti-icing additive (AIA) and blended with ethyl cellosolve or tetrahydrofurfuryl alcohol in the concentrations that are added to fuel before refueling flight vehicles under service conditions in order to prevent the formation of ice crystals in the fuel. The fuel hygroscopicity under static conditions is measured in desiccators over saturated salt solutions giving air relative humidities from 37% to 97% at 20/sup 0/C. It is determined that tetrahydrofurfuryl alcohol increases the fuel hygroscopicity to a greater degree than does the ethyl cellosolve. The fuel containing the AIA becomes a medium for the transfer of water from the ambient medium to the emulsion droplets, and these droplets in turn form a liquid phase. It is shown that the rate at which the fuel with the AIA becomes saturated with water under dynamic conditions is much greater than under static conditions. In the fuel without the AIA no water emulsion is formed, even with prolonged contact (more than 2 days) with 100% humidity air, whereas in the fuel with the AIA (even with 0.1% ethyl cellosolve), emulsion and liquid phase are formed. It is concluded that the physical stability of fuel containing AIA depends on the AIA concentration. Includes 3 tables.

  8. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Valkenburt, Corinne

    2009-05-01

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). However, biomass is not always available in sufficient quantity at a price compatible with fuels production. Municipal solid waste (MSW) on the other hand is readily available in large quantities in some communities and is considered a partially renewable feedstock. Furthermore, MSW may be available for little or no cost. This report provides a techno-economic analysis of the production of mixed alcohols from MSW and compares it to the costs for a wood based plant. In this analysis, MSW is processed into refuse derived fuel (RDF) and then gasified in a plant co-located with a landfill. The resulting syngas is then catalytically converted to mixed alcohols. At a scale of 2000 metric tons per day of RDF, and using current technology, the minimum ethanol selling price at a 10% rate of return is approximately $1.85/gallon ethanol (early 2008 $). However, favorable economics are dependent upon the toxicity characteristics of the waste streams and that a market exists for the by-product scrap metal recovered from the RDF process.

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol and Methanol Tax Ethyl alcohol and methyl alcohol motor fuels are taxed at a rate of $0.14 per gallon when used as a motor fuel. Ethyl alcohol is defined as a motor fuel that is typically derived from agricultural products that have been denatured. Methyl alcohol is a motor fuel that is most commonly derived from wood products. (Reference South Dakota Statutes 10-47B-3 and 10-47B-4

  10. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to 80% of the proceeds from the sale of fuel blends containing between 1% and 10% biodiesel and the sale of fuels containing 10% ethanol (E10) made between July 1, 2003, and...

  11. Performance of Biofuels and Biofuel Blends | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft003_mccormick_2012_o.pdf More Documents & Publications Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Recent Research to Address Technical Barriers to Increased Use of Biodiesel

  12. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Renewable Fuel Standard (RFS) Program The national RFS Program was developed to increase the volume of renewable fuel that is blended into transportation fuels. As required by the Energy Policy Act of 2005, the U.S. Environmental Protection Agency (EPA) finalized RFS Program regulations, effective September 1, 2007. The Energy Independence and Security Act of 2007 (EISA) increased and expanded this standard. By 2022, 36 billion gallons of renewable fuel must be blended into domestic

  14. Biogas and alcohol fuels production. Proceedings of the Seminar on Biomass, Energy for City, Farm, and Industry, Chicago, IL, October 25, 26, 1979

    SciTech Connect (OSTI)

    Goldstein, J.

    1980-01-01

    Basic principles of anaerobic digestion are considered along with the status of the Imperial Valley Biogas Project, the Department of Energy program for the recovery of energy and materials from urban waste, the principles of alcohol production from wastes, the mechanical recovery of a refuse-derived cellulosic feedstock for ethanol production, and the production of ethanol from cellulosic biomass. Attention is given to on-farm alcohol fuel production, the current status and future role of gasohol production, methane generation from small scale farms, farmsite installations of energy harvester anaerobic digesters, biogas/composting and landfill recovery, farm-scale composting as an option to anaerobic digestion, designing a high-quality biogas system, and methane as fuel of the future. A description is presented of subjects which are related to landfill gas recovery, biogas purification with permselective membranes, and anaerobic digestion of marine biomass. Other topics studied include the application of biogas technology in India, biogas production in China, biogasification of organic wastes in the Republic of the Philippines, and economics and operational experience of full-scale anaerobic dairy manure digester.

  15. Impact of Biodiesel on Fuel System Component Durability

    SciTech Connect (OSTI)

    Terry, B.

    2005-09-01

    A study of the effects of biodiesel blends on fuel system components and the physical characteristics of elastomer materials.

  16. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Karner, D.; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  17. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Don Karner; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen–50% CNG fuel.

  18. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund The North Carolina State Energy Office administers the Energy Policy Act (EPAct) Credit Banking and Selling Program, which enables the state to generate funds from the sale of EPAct 1992 credits. The funds that EPAct credit sales generate are deposited into the Alternative Fuel Revolving Fund (Fund) for state agencies to offset the incremental costs of purchasing biodiesel blends of at least 20% (B20) or ethanol blends of at least 85%

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Compatibility Requirements for Underground Storage Tanks (USTs) Fueling station owners and operators must notify the appropriate state and local implementing agencies at least 30 days before switching USTs to store ethanol blends greater than 10%, biodiesel blends greater than 20%, or any other regulated fuel the agency has identified. This notification timeframe allows agencies to request information on UST compatibility before the owner or operator stores the fuel. Owners and operators

  1. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  2. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  3. High Octane Fuels Can Make Better Use of Renewable Transportation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Blend Ethanol Fuels - Implementation Perspectives Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" The Impact of Low Octane Hydrocarbon ...

  4. NREL: Transportation Research - Fuel Chemistry Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photo by Dennis Schroeder, NREL NREL's fuel chemistry research explores how biofuels, advanced petroleum-based fuels, fuel blends, and natural gas perform in vehicles as well as in ...

  5. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  6. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  7. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fueling the Next Generation of Vehicle Technology Fueling the Next Generation of Vehicle Technology February 6, 2013 - 11:20am Addthis Professor Jack Brouwer, Associate Director and Chief Technology Officer of the National Fuel Cell Research Center, points out the tri-generation facility that uses biogas from Orange County Sanitation District’s wastewater treatment plant to produce hydrogen, heat and power. | Photo courtesy of the Energy Department. Professor Jack Brouwer, Associate

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Blend Mandate All diesel fuel sold to state agencies, political subdivisions of the state, and public schools for use in on-road motor vehicles must contain at least 5%...

  9. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ethanol Fuel Blend Standard At least 85% of gasoline supplied to a retailer or sold in Hawaii must contain a minimum of 10% ethanol (E10), unless the Director determines that...

  10. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Where shown, (s) Btu value less than 0.05. Notes: Motor gasoline estimates include fuel ethanol blended into motor gasoline. * Totals may not equal sum of components due to ...

  11. Fuel Tables.indd

    Gasoline and Diesel Fuel Update (EIA)

    ... Where shown, (s) Physical unit value less than 0.5 or Btu value less than 0.05. Notes: Total petroleum includes fuel ethanol blended into motor gasoline. * Totals may not equal ...

  12. Fuel Tables.indd

    Gasoline and Diesel Fuel Update (EIA)

    ... 3,709.1 863,909.0 Where shown, (s) Expenditure value less than 0.05. Notes: Total petroleum includes fuel ethanol blended into motor gasoline. * Totals may not equal sum

  13. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  14. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  15. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Tax Exemption Biodiesel blends containing at least 20% biodiesel derived from used cooking oil are exempt from the $0.30 per gallon state fuel excise tax. The exemption does not apply to fuel used in vehicles with a gross vehicle weight rating of 26,001 pounds or more, fuel not sold in retail operations, or fuel sold in operations involving fleet fueling or bulk sales. The exemption expires after December 31, 2019. (Reference Oregon Revised Statutes 319.530

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Special Fuel Definitions The definition of alternative fuel includes liquefied petroleum gas (propane). Special fuel is defined as all combustible gases and liquids that are suitable for powering an internal combustion engine or motor or are used exclusively for heating, industrial, or farm purposes. Special fuels include biodiesel, blended biodiesel, and natural gas products, including liquefied and compressed natural gas. (Reference Indiana Code 6-6-2.5-1 and 6-6-2.5-22

  18. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen-50% CNG fuel.

  19. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Labeling Requirements Alternative fuel dispensers must be labeled with information to help consumers make informed decisions about fueling a vehicle, including the name of the fuel and the minimum percentage of the main component of the fuel. Labels may also list the percentage of other fuel components. This requirement applies to, but is not limited to, the following fuel types: methanol, denatured ethanol, and/or other alcohols; mixtures containing 85% or more by volume of

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fueling Infrastructure Tax Credit for Residents Through the Residential Energy Tax Credit program, qualified residents may receive a tax credit for 25% of alternative fuel infrastructure project costs, up to $750. Qualified residents may receive a tax credit for 50% of project costs, up to $750. Qualified alternative fuels include electricity, natural gas, gasoline blended with at least 85% ethanol (E85), propane, and other fuels that the Oregon Department of Energy approves. A

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    and Infrastructure Tax Credit for Businesses Business owners and others may be eligible for a tax credit of 35% of eligible costs for qualified alternative fuel infrastructure projects, or the incremental or conversion cost of two or more AFVs. Qualified infrastructure includes facilities for mixing, storing, compressing, or dispensing fuels for vehicles operating on alternative fuels. Qualified alternative fuels include electricity, natural gas, gasoline blended with at least 85% ethanol (E85),

  3. Vehicle Technologies Office Merit Review 2014: Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by NREL at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about performance of biofuels and biofuel blends.

  4. Determination of alternative fuels combustion products: Phase 3 report

    SciTech Connect (OSTI)

    Whitney, K.A.

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Dispenser Requirement A retail motor fuel dispenser that dispenses fuel containing more than 10% ethanol by volume must be labeled with the capital letter "E" followed by the numerical value representing the volume percentage of ethanol, such as E85, as specified in Kansas Department of Agriculture guidelines. (Reference Kansas Administrative Regulations 99-25-10

  6. Measurement of biodiesel blend and conventional diesel spray structure using x-ray radiography.

    SciTech Connect (OSTI)

    Kastengren, A. L.; Powell, C. F.; Wang, Y. J.; IM, K. S.; Wang, J.

    2009-11-01

    The near-nozzle structure of several nonevaporating biodiesel-blend sprays has been studied using X-ray radiography. Radiography allows quantitative measurements of the fuel distribution in sprays to be made with high temporal and spatial resolution. Measurements have been made at different values of injection pressure, ambient density, and with two different nozzle geometries to understand the influences of these parameters on the spray structure of the biodiesel blend. These measurements have been compared with corresponding measurements of Viscor, a diesel calibration fluid, to demonstrate the fuel effects on the spray structure. Generally, the biodiesel-blend spray has a similar structure to the spray of Viscor. For the nonhydroground nozzle used in this study, the biodiesel-blend spray has a slightly slower penetration into the ambient gas than the Viscor spray. The cone angle of the biodiesel-blend spray is generally smaller than that of the Viscor spray, indicating that the biodiesel-blend spray is denser than the Viscor spray. For the hydroground nozzle, both fuels produce sprays with initially wide cone angles that transition to narrow sprays during the steady-state portion of the injection event. These variations in cone angle with time occur later for the biodiesel-blend spray than for the Viscor spray, indicating that the dynamics of the injector needle as it opens are somewhat different for the two fuels.

  7. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization PDF icon deer12_szybist.pdf More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel Effects on Advanced

  8. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuels Program Impact Studies The Oregon Department of Energy (ODOE) must conduct periodic impact studies related to the biofuels industry in the state. These studies should evaluate such criteria as: jobs created; current and projected feedstock availability; amount of biofuels blends produced and consumed in the state; cost comparison of biofuels blends and petroleum fuel; environmental impacts; and the extent to which Oregon producers import biofuels or biofuels feedstocks from outside the

  10. Extracting alcohols from aqueous solutions. [USDOE patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1981-12-02

    The objective is to provide an efficient process for extracting alcohols in aqueous solutions into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. This is done by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5-18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is then mixed with one or more of a group of polyoxyalkylene polymers to extract the alcohol into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  11. NREL: State and Local Governments - Renewable Fuel Standards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to RFS effectiveness: Imposing stringency to require use of higher blends of ethanol or alternative fuels. Adopting an implementation plan that can ease measurement and...

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Signage The Ohio Turnpike Commission allows businesses to place their logos on directional signs within the right-of-way of state turnpikes. An alternative fuel retailer may include a marking or symbol within their logo indicating that it sells one or more types of alternative fuel. Alternative fuels are defined as E85, fuel blends containing at least 20% biodiesel (B20), natural gas, propane, hydrogen, or any fuel that the U.S. Department of Energy determines, by final rule, to be

  13. NREL: Transportation Research - Alternative Fuels Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alternative Fuels Characterization Find out about other biomass research projects at NREL. NREL alternative fuels projects help overcome technical barriers and expand markets for renewable, biodegradable vehicle fuels. These liquid fuels include higher-level ethanol blends, butanol, biodiesel, renewable diesel, other biomass-derived fuels, and natural gas. By studying the fuel chemistry as well as combustion and emissions impacts of alternative fuels, NREL helps improve engine efficiency, reduce

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Clean Cities The mission of Clean Cities is to advance the energy, economic, and environmental security of the United States by supporting local initiatives to adopt practices that reduce the use of petroleum in the transportation sector. Clean Cities carries out this mission through a network of nearly 100 volunteer coalitions, which develop public/private partnerships to promote alternative fuels and advanced vehicles, fuel blends, fuel economy, hybrid vehicles, and idle reduction. Clean

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Federal Fleets Under the Energy Policy Act (EPAct) of 1992, 75% of new light-duty vehicles acquired by covered federal fleets must be alternative fuel vehicles (AFVs). As amended in January 2008, Section 301 of EPAct 1992 defines AFVs to include hybrid electric vehicles, fuel cell vehicles, and advanced lean burn vehicles. Fleets that use fuel blends containing at least 20% biodiesel (B20) may earn credits toward their annual requirements. Federal fleets are also required to use alternative

  16. South Texas Blending | Open Energy Information

    Open Energy Info (EERE)

    search Name: South Texas Blending Place: Laredo, Texas Zip: 78045 Product: Biodiesel producer based in Texas. References: South Texas Blending1 This article is a stub....

  17. Alcohol conversion

    DOE Patents [OSTI]

    Wachs, Israel E.; Cai, Yeping

    2002-01-01

    Preparing an aldehyde from an alcohol by contacting the alcohol in the presence of oxygen with a catalyst prepared by contacting an intimate mixture containing metal oxide support particles and particles of a catalytically active metal oxide from Groups VA, VIA, or VIIA, with a gaseous stream containing an alcohol to cause metal oxide from the discrete catalytically active metal oxide particles to migrate to the metal oxide support particles and to form a monolayer of catalytically active metal oxide on said metal oxide support particles.

  18. Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) to someone by E-mail Share Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) on Facebook Tweet about Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Requirement for School Buses Every school bus that is capable of operating on diesel fuel must be capable of operating using blends of at least 20% biodiesel (B20). At least 2% of the total volume of fuel purchased annually by local school districts statewide for use in diesel school buses must be a minimum of B20, to the extent that biodiesel blends are available and compatible with the technology of the vehicles and the equipment used. (Reference North Carolina General Statutes 115C-240(c) and

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Mixture Excise Tax Credit NOTE: This incentive was retroactively extended multiple times, most recently through December 31, 2016, by H.R. 2029. An alternative fuel blender that is registered with the Internal Revenue Service (IRS) may be eligible for a tax incentive on the sale or use of the alternative fuel blend (mixture) for use as a fuel in the blender's trade or business. The credit is in the amount of $0.50 per gallon of alternative fuel used to produce a mixture

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Vehicle (AFV) Parking Space Regulation An individual is not allowed to park a motor vehicle within any parking space specifically designated for public parking and fueling of AFVs unless the motor vehicle is an AFV fueled by electricity, natural gas, methanol, propane, gasoline blended with at least 85% ethanol (E85), or other fuel the Oregon Department of Energy approves. Eligible AFVs must also be in the process of fueling or charging to park in the space. A person found responsible for a

  2. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for gasoline, which is knock-prone at these high CR, in order to maintain compatibility. By using EIVC and LIVC strategies, good efficiency is maintained with gasoline, but power is reduced by about 34%.

  3. Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model

    SciTech Connect (OSTI)

    Toulson, Dr. Elisa; Allen, Casey M; Miller, Dennis J; McFarlane, Joanna; Schock, Harold; Lee, Tonghun

    2011-01-01

    There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.

  4. Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.

    SciTech Connect (OSTI)

    Miers, S. A.; Carlson, R. W.; McConnell, S. S.; Ng, H. K.; Wallner, T.; LeFeber, J.; Energy Systems; Esper Images Video & Multimedia

    2008-10-01

    The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.

  5. Fact #588: September 14, 2009 Fuel Economy Changes Due to Ethanol Content

    Broader source: Energy.gov [DOE]

    The fuel economy of a vehicle is dependent on many things, one of which is the fuel used in the vehicle. Two National Laboratories recently studied the effects that ethanol blends have on the fuel...

  6. The Advanced Petroleum-Based Fuels Program DECSE and APBF Overview

    SciTech Connect (OSTI)

    2000-04-11

    The following topics are summarized: Role of fuel blends in controlling engine-out emissions; Effect of fuels and lubricants on emission control devices; and Effect of fuels and lubricants on vehicle emissions and operations.

  7. Indiana Brings Alternative Fuels to the Forefront | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of technologies and fuels in both light and heavy-duty vehicles, including natural gas, propane, hybrid electric drive, and E85 (a fuel blend containing up to 85% ethanol)....

  8. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  9. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  10. Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report

    SciTech Connect (OSTI)

    McCormick, R. L.; Westbrook, S. R.

    2007-05-01

    The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

  11. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2009-02-01

    This report (February 2009) is an update of the original version, which was published in October 2008. This report is the result of the U.S. Department of Energy's test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels.

  12. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Broader source: Energy.gov (indexed) [DOE]

    Engine-in-the-Loop | Department of Energy 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon vss049_shidore_2011_o.pdf More Documents & Publications Evaluation of the Fuel Economy Impacts of Low Temperature Combustion (LTC) using Engine-in-the-Loop Cold-Start Performance and Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Meth Tradeoff between Fuel Consumption and

  13. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  14. Blender Pump Fuel Survey: CRC Project E-95

    SciTech Connect (OSTI)

    Alleman, T. L.

    2011-07-01

    To increase the number of ethanol blends available in the United States, several states have 'blender pumps' that blend gasoline with flex-fuel vehicle (FFV) fuel. No specification governs the properties of these blended fuels, and little information is available about the fuels sold at blender pumps. No labeling conventions exist, and labeling on the blender pumps surveyed was inconsistent.; The survey samples, collected across the Midwestern United States, included the base gasoline and FFV fuel used in the blends as well as the two lowest blends offered at each station. The samples were tested against the applicable ASTM specifications and for critical operability parameters. Conventional gasoline fuels are limited to 10 vol% ethanol by the U.S. EPA. The ethanol content varied greatly in the samples. Half the gasoline samples contained some ethanol, while the other half contained none. The FFV fuel samples were all within the specification limits. No pattern was observed for the blend content of the higher ethanol content samples at the same station. Other properties tested were specific to higher-ethanol blends. This survey also tested the properties of fuels containing ethanol levels above conventional gasoline but below FFV fuels.

  15. The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI Combustion

    Broader source: Energy.gov [DOE]

    Almost 2 dozen gasoline fuels, blending components, and surrogates were evaluated in a single-cylinder HCCI gasoline engine for combustion, emissions, and efficiency performance.

  16. Power Ecalene Fuels Inc | Open Energy Information

    Open Energy Info (EERE)

    Arvada, Colorado Zip: 80007 Region: Rockies Area Sector: Biofuels Product: Mixed alcohol transportation fuel Website: www.powerecalene.com Coordinates: 39.862942,...

  17. Intrinsically safe moisture blending system

    DOE Patents [OSTI]

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Prohibition of the Sale of Ethanol-Blended Gasoline A person or distributor may not offer, sell, or distribute gasoline that contains ethanol at a level greater than 10% (E10) or contains corn-based ethanol as an additive. The prohibition does not take effect until at least two of the six New England states, in addition to Maine, have enacted laws preventing the sale of these fuel blends. (Reference Maine Revised Statutes Title 38, Section 585M and Title 10, Section 1457-B

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tax Special fuels, including biodiesel, biodiesel blends, biomass-based diesel, biomass-based diesel blends, and liquefied natural gas (LNG), have a reduced tax rate of $0.27 per gallon. Liquefied petroleum gas (LPG or propane) and compressed natural gas (CNG) used to operate a motor vehicle is taxed at a rate of $0.064 and $0.21 per gallon, respectively. For taxation purposes, 126.67 cubic feet of CNG, 36.3 cubic feet (4.2 pounds (lbs.)) of propane, or 6.06 lbs. of LNG is considered equal to

  20. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Distillation Curve Method | Department of Energy Supercritical transesterification processing permits efficient fuel system and combustion chamber designs to optimize fuel utilization in diesel engines., PDF icon p-01_anitescu.pdf More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Algae Biofuels Technology

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive Fleet Card. The program offers a rebate of $0.03 per gallon for purchases of less than 1,000 gallons of biofuel per month, and $0.05 per gallon for purchases of 1,000 gallons or more per month. The rebate is

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive WEX fleet card. The program offers a rebate of $0.05 per gallon for purchases of more than 500 gallons of biofuel per month. The rebate is applied at the end of each monthly billing cycle. For more

  3. Development and Demonstration of Hydrogen and Compressed Natural Gas (H/CNG) Blend Transit Buses: October 15, 2002--September 30, 2004

    SciTech Connect (OSTI)

    Del Toro, A.; Frailey, M.; Lynch, F.; Munshi, S.; Wayne, S.

    2005-11-01

    The report covers literature and laboratory analyses to identify modification requirements of a Cummins Westport B Gas Plus engine for transit buses using a hydrogen/compressed natural fuel blend.

  4. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. Within the Combustion Laboratory of the Penn State Energy Institute, they have installed and equipped a Navistar V-8 direct-injection turbodiesel engine for measurement of gaseous and particulate emissions and examination of the impact of fuel composition on diesel combustion. They have also reconfigured a high-pressure viscometer for studies of the viscosity, bulk modulus (compressibility) and miscibility of blends of diesel fuel, dimethyl ether and lubricity additives. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have examined blends of an oxygenated fuel additive (a liquid fuel called CETANER{trademark}) produced by Air Products, for comparison with dimethyl ether blended at the same weight of oxygen addition, 2 wt.%. While they have not operated the engine on DME yet, they are now preparing to do so. A fuel system for delivery of DME/Diesel blends has been configured and initial investigations at low DME blend ratios (around 5-10 vol%) will begin shortly. They have also performed viscosity measurements on diesel fuel, DME and 50-50 blends of DME in diesel. These tests have verified that DME has a much lower viscosity than the diesel fuel and that the viscosity of the blended fuel is also much lower than the diesel base fuel. This has implications for the injection and atomization of the DME/diesel blends.

  5. Characteristics of isopentanol as a fuel for HCCI engines.

    SciTech Connect (OSTI)

    Simmons, Blake Alexander; Dec, John E.; Yang, Yi; Dronniou, Nicolas

    2010-05-01

    Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C{sub 4}-C{sub 5} alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C{sub 5} alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity. Similar to ethanol but unlike gasoline, isopentanol does not show two-stage ignition even at very low engine speed (350 rpm) or with considerable intake pressure boost (200 kPa abs.). However, isopentanol does show considerable intermediate temperature heat release (ITHR) that is comparable to gasoline. Our previous work has found that ITHR is critical for maintaining combustion stability at the retarded combustion phasings required to achieve high loads without knock. The stronger ITHR causes the combustion phasing of isopentanol to be less sensitive to intake temperature variations than ethanol. With the capability to retard combustion phasing, a maximum IMEP{sub g} of 5.4 and 11.6 bar was achieved with isopentanol at 100 and 200 kPa intake pressure, respectively. These loads are even slightly higher than those achieved with gasoline. The ITHR of isopentanol depends on operating conditions and is enhanced by simultaneously increasing pressures and reducing temperatures. However, increasing the temperature seems to have little effect on ITHR at atmospheric pressure, but it does promote hot ignition. Finally, the dependence of ignition timing on equivalence ratio, here called {phi}-sensitivity, is measured at atmospheric intake pressure, showing that the ignition of isopentanol is nearly insensitive to equivalence ratio when thermal effects are removed. This suggests that partial fuel stratification, which has been found effective to control the HRR with two-stage ignition fuels, may not work well with isopentanol at these conditions. Overall, these results indicate that isopentanol has a good potential as a HCCI fuel, either in neat form or in blend with gasoline.

  6. Compression-ignition fuel properties of Fischer-Tropsch syncrude

    SciTech Connect (OSTI)

    Suppes, G.J.; Terry, J.G.; Burkhart, M.L.; Cupps, M.P.

    1998-05-01

    Fischer-Tropsch conversion of natural gas to liquid hydrocarbon fuel typically includes Fischer-Tropsch synthesis followed by refining (hydrocracking and distillation) of the syncrude into mostly diesel or kerosene with some naphtha (a feedstock for gasoline production). Refining is assumed necessary, possibly overlooking the exception fuel qualities of syncrude for more direct utilization as a compression-ignition (CI) fuel. This paper evaluates cetane number, viscosity, cloud-point, and pour-point properties of syncrude and blends of syncrude with blend stocks such as ethanol and diethyl ether. The results show that blends comprised primarily of syncrude are potentially good CI fuels, with pour-point temperature depression being the largest development obstacle. The resulting blends may provide a much-needed and affordable alternative CI fuel. Particularly good market opportunities exist with Environmental Policy Act (EPACT) applications.

  7. Fuel Injector Holes | Department of Energy

    Office of Environmental Management (EM)

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  8. Table B1. Pipe Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    B1. Pipe Manufacturer Compatibility with Ethanol Blends Manufacturer Product Model Ethanol Compatibility Piping-All Companies have UL 971 listing for E100 Advantage Earth Products Piping 1.5", 2", 3", 4" E0-E100 Brugg Piping FLEXWELL-HL, SECON-X, NITROFLEX, LPG E0-E100 Franklin Fueling Piping Franklin has third-party certified piping compatible with up to E85. Contact manufacturer for specific part numbers. E0-E85 OPW Piping FlexWorks, KPS, Pisces (discontinued) E0-E100 NOV

  9. Tropexx - Blending System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Tropexx - Blending System Y-12 National Security Complex Contact Y12 About This Technology Publications: PDF Document Publication Fact Sheet (784 KB) PDF Document Publication Patent (88 KB) Technology Marketing SummaryThe Tropexx Blending System is a high-resolution blending system that works with gases, vapors and volatile (readily vaporizable) liquids in addition to moisture. Tropexx can be used to check

  10. Fuel from Bacteria: Bioconversion of Carbon Dioxide to Biofuels by Facultatively Autotrophic Hydrogen Bacteria

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: Ohio State is genetically modifying bacteria to efficiently convert carbon dioxide directly into butanol, an alcohol that can be used directly as a fuel blend or converted to a hydrocarbon, which closely resembles a gasoline. Bacteria are typically capable of producing a certain amount of butanol before it becomes too toxic for the bacteria to survive. Ohio State is engineering a new strain of the bacteria that could produce up to 50% more butanol before it becomes too toxic for the bacteria to survive. Finding a way to produce more butanol more efficiently would significantly cut down on biofuel production costs and help make butanol cost competitive with gasoline. Ohio State is also engineering large tanks, or bioreactors, to grow the biofuel-producing bacteria in, and they are developing ways to efficiently recover biofuel from the tanks.

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Infrastructure Grants and Loan Guarantees The Rural Energy for America Program (REAP) provides loan guarantees and grants to agricultural producers and rural small businesses to purchase renewable energy systems or make energy efficiency improvements. Eligible renewable energy systems include flexible fuel pumps, or blender pumps, that dispense intermediate ethanol blends. The maximum loan guarantee is $25 million and the maximum grant funding is 25% of project costs. At least 20% of the

  12. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  13. Fact# 905: December 28, 2015 Alternative Fuels Account for One...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in 2013. Beginning in the mid-2000's biodiesel, a diesel fuel based on vegetable oil or animal fat was also used in transit buses. Biodiesel is typically blended with ...

  14. Flexible Fuel Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Vehicles » Flexible Fuel Vehicle Basics Flexible Fuel Vehicle Basics August 20, 2013 - 9:05am Addthis Photo of a gray van with 'E85 Ethanol' written on the side. Flexible fuel vehicles (FFVs) have an internal combustion engine and are capable of operating on gasoline, E85 (a high-level blend of gasoline and ethanol), or a mixture of both. There are more than 10.6 million flexible fuel vehicles on U.S. roads today. However, many flexible fuel vehicle owners don't realize

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Renewable Fuels Mandate All gasoline sold in the state must be blended with 10% ethanol (E10). Gasoline with an octane rating of 91 or above is exempt from this mandate, as is gasoline sold for use in certain non-road applications. Gasoline that contains at least 9.2% agriculturally derived ethanol that meets ASTM specification D4806 complies with the mandate. For the purpose of the mandate, ethanol must meet ASTM specification D4806. The governor may suspend the renewable fuels mandate for

  16. Sandia Energy - Biofuels Blend Right In: Researchers Show Ionic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Home Renewable Energy Energy Transportation Energy Biofuels...

  17. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  18. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and ...

  19. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Mid-Level Ethanol Blends Test ...

  20. PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)

    SciTech Connect (OSTI)

    CERTA, P.J.

    2006-02-22

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

  1. Green emitting phosphors and blends thereof

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Siclovan, Oltea Puica; Nammalwar, Prasanth Kumar; Sathyanarayan, Ramesh Rao; Porob, Digamber G.; Chandran, Ramachandran Gopi; Heward, William Jordan; Radkov, Emil Vergilov; Briel, Linda Jane Valyou

    2010-12-28

    Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Production Facility Tax Exemption Any newly constructed or expanded biomass-to-energy facility is exempt from state property taxes for up to 10 taxable years immediately following the taxable year in which construction or installation is completed. A biomass-to-energy facility includes any industrial process plant that uses biomass to produce at least 500,000 gallons of cellulosic alcohol fuel, liquid or gaseous fuel, or other source of energy in a quantity with energy content at least

  3. Analysis of Coconut-Derived Biodiesel and Conventional Diesel Fuel Samples from the Philippines: Task 2 Final Report

    SciTech Connect (OSTI)

    Alleman, T. L.; McCormick, R. L.

    2006-01-01

    NREL tested Philippines coconut biodiesel samples of neat and blended fuels. Results show that the current fuel quality standards were met with very few exceptions. Additional testing is recommended.

  4. Advanced Vehicle Testing Activity: Hydrogen-Fueled Mercedes Sprinter Van -- Operating Summary

    SciTech Connect (OSTI)

    Karner, D.; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure- hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of testing conducted over 6,864 kilometers (4,265 miles) of operation using the pure-hydrogen-fueled Mercedes Sprinter van.

  5. Advanced Vehicle Testing Activity: Hydrogen-Fueled Mercedes Sprinter Van Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of testing conducted over 6,864 kilometers (4,265 miles) of operation using the pure-hydrogen-fueled Mercedes Sprinter van.

  6. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  7. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect (OSTI)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic reductions in sulfur dioxide emissions are measured with the blends. Again, consistent with our past experience with biodiesel blends, significant reductions in nitrogen oxide emissions nearing 50% with 100% Jatropha oil, were also measured. This is in contrast with the use of biodiesel in diesel engines, where the NOx has a tendency to increase. In addition to the gaseous emission measurements, particulate emissions were measured using an EPA CTM-39 system to obtain both particulates, of sizes below 2.5 microns, so-called PM2.5, and of sizes larger than 2.5 microns. The results show that the particulate emissions are lower with the blending of Jatropha oil. Overall, one can conclude that the blending of Jatropha oil with residual oil is a feasible approach to using non-edible plant oil to provide a renewable content to residual oil, with significant benefits in the reduction of pollutant emissions such as sulfur dioxide, nitrogen oxides and particulates.

  8. Recovery and Blend-Down Uranium for Beneficial use in Commercial Reactors - 13373

    SciTech Connect (OSTI)

    Magoulas, Virginia [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

    2013-07-01

    In April 2001 the Department of Energy (DOE) and the Tennessee Valley Authority (TVA) signed an Interagency Agreement to transfer approximately 33 MT of off-specification (off-spec) highly enriched uranium (HEU) from DOE to TVA for conversion to commercial reactor fuel. Since that time additional surplus off-spec HEU material has been added to the program, making the total approximately 46 MT off-spec HEU. The disposition path for approximately half (23 MT) of this 46 MT of surplus HEU material, was down blending through the H-canyon facility at the Savannah River Site (SRS). The HEU is purified through the H-canyon processes, and then blended with natural uranium (NU) to form low enriched uranium (LEU) solution with a 4.95% U-235 isotopic content. This material was then transported to a TVA subcontractor who converted the solution to uranium oxide and then fabricated into commercial light water reactor (LWR) fuel. This fuel is now powering TVA reactors and supplying electricity to approximately 1 million households in the TVA region. There is still in excess of approximately 10 to 14 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for use in either currently designed light water reactors, ?5% enriched LEU, or be made available for use in subsequent advanced 'fast' reactor fuel designs, ?19% LEU. (authors)

  9. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  10. HIGHLY ENRICHED URANIUM BLEND DOWN PROGRAM AT THE SAVANNAH RIVER SITE PRESENT AND FUTURE

    SciTech Connect (OSTI)

    Magoulas, V; Charles Goergen, C; Ronald Oprea, R

    2008-06-05

    The Department of Energy (DOE) and Tennessee Valley Authority (TVA) entered into an Interagency Agreement to transfer approximately 40 metric tons of highly enriched uranium (HEU) to TVA for conversion to fuel for the Browns Ferry Nuclear Power Plant. Savannah River Site (SRS) inventories included a significant amount of this material, which resulted from processing spent fuel and surplus materials. The HEU is blended with natural uranium (NU) to low enriched uranium (LEU) with a 4.95% 235U isotopic content and shipped as solution to the TVA vendor. The HEU Blend Down Project provided the upgrades needed to achieve the product throughput and purity required and provided loading facilities. The first blending to low enriched uranium (LEU) took place in March 2003 with the initial shipment to the TVA vendor in July 2003. The SRS Shipments have continued on a regular schedule without any major issues for the past 5 years and are due to complete in September 2008. The HEU Blend program is now looking to continue its success by dispositioning an additional approximately 21 MTU of HEU material as part of the SRS Enriched Uranium Disposition Project.

  11. DOE small scale fuel alcohol plant design

    SciTech Connect (OSTI)

    LaRue, D.M.; Richardson, J.G.

    1980-01-01

    The Department of Energy, in an effort to facilitate the deployment of rural-based ethanol production capability, has undertaken this effort to develop a basic small-scale plant design capable of producing anhydrous ethanol. The design, when completed, will contain all necessary specifications and diagrams sufficient for the construction of a plant. The design concept is modular; that is, sections of the plant can stand alone or be integrated into other designs with comparable throughput rates. The plant design will be easily scaled up or down from the designed flow rate of 25 gallons of ethanol per hour. Conversion factors will be provided with the final design package to explain scale-up and scale-down procedures. The intent of this program is to provide potential small-scale producers with sound information about the size, engineering requirements, costs and level of effort in building such a system.

  12. Optimally Controlled Flexible Fuel Powertrain System

    SciTech Connect (OSTI)

    Duncan Sheppard; Bruce Woodrow; Paul Kilmurray; Simon Thwaite

    2011-06-30

    A multi phase program was undertaken with the stated goal of using advanced design and development tools to create a unique combination of existing technologies to create a powertrain system specification that allowed minimal increase of volumetric fuel consumption when operating on E85 relative to gasoline. Although on an energy basis gasoline / ethanol blends typically return similar fuel economy to straight gasoline, because of its lower energy density (gasoline ~ 31.8MJ/l and ethanol ~ 21.1MJ/l) the volume based fuel economy of gasoline / ethanol blends are typically considerably worse. This project was able to define an initial engine specification envelope, develop specific hardware for the application, and test that hardware in both single and multi-cylinder test engines to verify the ability of the specified powertrain to deliver reduced E85 fuel consumption. Finally, the results from the engine testing were used in a vehicle drive cycle analysis tool to define a final vehicle level fuel economy result. During the course of the project, it was identified that the technologies utilized to improve fuel economy on E85 also enabled improved fuel economy when operating on gasoline. However, the E85 fueled powertrain provided improved vehicle performance when compared to the gasoline fueled powertrain due to the improved high load performance of the E85 fuel. Relative to the baseline comparator engine and considering current market fuels, the volumetric fuel consumption penalty when running on E85 with the fully optimized project powertrain specification was reduced significantly. This result shows that alternative fuels can be utilized in high percentages while maintaining or improving vehicle performance and with minimal or positive impact on total cost of ownership to the end consumer. The justification for this project was two-fold. In order to reduce the US dependence on crude oil, much of which is imported, the US Environmental Protection Agency (EPA) developed the Renewable Fuels Standard (RFS) under the Energy Policy Act of 2005. The RFS specifies targets for the amount of renewable fuel to be blended into petroleum based transportation fuels. The goal is to blend 36 billion gallons of renewable fuels into transportation fuels by 2022 (9 billion gallons were blended in 2008). The RFS also requires that the renewable fuels emit fewer greenhouse gasses than the petroleum fuels replaced. Thus the goal of the EPA is to have a more fuel efficient national fleet, less dependent on petroleum based fuels. The limit to the implementation of certain technologies employed was the requirement to run the developed powertrain on gasoline with minimal performance degradation. The addition of ethanol to gasoline fuels improves the fuels octane rating and increases the fuels evaporative cooling. Both of these fuel property enhancements make gasoline / ethanol blends more suitable than straight gasoline for use in downsized engines or engines with increased compression ratio. The use of engine downsizing and high compression ratios as well as direct injection (DI), dual independent cam phasing, external EGR, and downspeeding were fundamental to the fuel economy improvements targeted in this project. The developed powertrain specification utilized the MAHLE DI3 gasoline downsizing research engine. It was a turbocharged, intercooled, DI engine with dual independent cam phasing utilizing a compression ratio of 11.25 : 1 and a 15% reduction in final drive ratio. When compared to a gasoline fuelled 2.2L Ecotec engine in a Chevrolet HHR, vehicle drive cycle predictions indicate that the optimized powertrain operating on E85 would result in a reduced volume based drive cycle fuel economy penalty of 6% compared to an approximately 30% penalty for current technology engines.

  13. Ethanol Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials collectively known as "biomass." Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that

  14. Low-Temperature Biodiesel Research Reveals Potential Key to Successful Blend Performance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-02-01

    Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being widely adopted. Some biodiesel blends have exhibited unexplained low-temperature performance problems even at blend levels as low as 2% by volume. The most common low-temperature performance issue is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. Research at the National Renewable Energy Laboratory (NREL) reveals the properties responsible for these problems, clearing a path for the development of solutions and expanded use of energy-conserving and low-emissions alternative fuel. NREL researchers set out to study the unpredictable nature of biodiesel crystallization, the condition that impedes the flow of fuel in cold weather. Their research revealed for the first time that saturated monoglyceride impurities common to the biodiesel manufacturing process create crystals that can cause fuel filter clogging and other problems when cooling at slow rates. Biodiesel low-temperature operational problems are commonly referred to as 'precipitates above the cloud point (CP).' NREL's Advanced Biofuels team spiked distilled soy and animal fat-derived B100, as well as B20, B10, and B5 biodiesel blends with three saturated monoglycerides (SMGs) at concentration levels comparable to those of real-world fuels. Above a threshold or eutectic concentration, the SMGs (monomyristin, monopalmitin, and monostearin) were shown to significantly raise the biodiesel CP, and had an even greater impact on the final melting temperature. Researchers discovered that upon cooling, monoglyceride initially precipitates as a metastable crystal, but it transforms over time or upon slight heating into a more stable crystal with a much lower solubility and higher melting temperature - and with increased potential to cause vehicle performance issues. This explains why fuel-filter clogging typically occurs over the course of long, repeated diurnal cooling cycles. The elevated final melting points mean that restarting vehicles with clogged filters can be difficult even after ambient temperatures have warmed to well above CP. By examining how biodiesel impurities affect filtration and crystallization during warming and cooling cycles, NREL researchers uncovered an explanation for poor biodiesel performance at low temperatures. The observation of a eutectic point, or a concentration below which SMGs have no effect, indicates that SMGs do not have to be completely removed from biodiesel to solve low-temperature performance problems.

  15. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Overview of HyRAM (Hydrogen Risk Assessment Models) Software for Science-Based Safety, Codes, ...

  16. Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends | Department

    Broader source: Energy.gov (indexed) [DOE]

    This document lists the course modules for building science courses offered at Cornell's Collaborator Sustainable Buildingi Practice course. PDF icon course_module.pdf More Documents & Publications Building America Building Science Education Roadmap Opportunities for Building America Research to Address Energy Upgrade Technical Challenges: HVAC, Envelope and IAQ (301) Building America Program Research-to-Market Plan of Energy

    *Accurately measure exhaust profile from an HCCI engine

  17. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office?¢????s (SEO) primary mission is to implement cost?¢???effective, reliable, balanced, and environmentally?¢???friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  18. Fuel from Waste Helps Power Two Tribes | Department of Energy

    Energy Savers [EERE]

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  19. SAVANNAH RIVER SITE'S H-CANYON FACILITY: RECOVERY AND DOWN BLEND URANIUM FOR BENEFICIAL USE

    SciTech Connect (OSTI)

    Magoulas, V.

    2013-05-27

    For over fifty years, the H Canyon facility at the Savannah River Site (SRS) has performed remotely operated radiochemical separations of irradiated targets to produce materials for national defense. Although the materials production mission has ended, the facility continues to play an important role in the stabilization and safe disposition of proliferable nuclear materials. As part of the US HEU Disposition Program, SRS has been down blending off-specification (off-spec) HEU to produce LEU since 2003. Off-spec HEU contains fission products not amenable to meeting the American Society for Testing and Material (ASTM) commercial fuel standards prior to purification. This down blended HEU material produced 301 MT of ~5% enriched LEU which has been fabricated into light water reactor fuel being utilized in Tennessee Valley Authority (TVA) reactors in Tennessee and Alabama producing economic power. There is still in excess of ~10 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for beneficial use as either ~5% enriched LEU, or for use in subsequent LEU reactors requiring ~19.75% enriched LEU fuel.

  20. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, Alicia L.; Griffith, William L.; Dorsey, George F.; West, Brian H.

    1998-01-01

    A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  1. Low emissions diesel fuel

    DOE Patents [OSTI]

    Compere, A.L.; Griffith, W.L.; Dorsey, G.F.; West, B.H.

    1998-05-05

    A method and matter of composition for controlling NO{sub x} emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO{sub x} produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

  2. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  3. Furfuryl alcohol cellular product

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-05-26

    Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

  4. Advanced Petroleum Based Fuels Research at NREL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    9 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_09_zigler.pdf More Documents & Publications Advanced Petroleum-Based Fuels Research at NREL Quality, Performance, and Emission Impacts of Biodiesel Blends 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels Technologies

  5. Engine Materials Compatibility with Alternate Fuels | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm039_pawel_2012_o.pdf More Documents & Publications Engine Materials Compatibility with Alternate Fuels Mid-Level Ethanol Blends Vehicle Technologies Office: 2012 Propulsion Materials R&D Annual Progress Report

  6. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  7. Extracting alcohols from aqueous solutions

    DOE Patents [OSTI]

    Compere, Alicia L.; Googin, John M.; Griffith, William L.

    1984-01-01

    Hydrocarbon and surfactants are contacted with a solution of alcohol and water to extract the alcohol into the hydrocarbon-surfactant mixture.

  8. Cold start characteristics of ethanol as an automobile fuel

    DOE Patents [OSTI]

    Greiner, Leonard

    1982-01-01

    An alcohol fuel burner and decomposer in which one stream of fuel is preheated by passing it through an electrically heated conduit to vaporize the fuel, the fuel vapor is mixed with air, the air-fuel mixture is ignited and combusted, and the combustion gases are passed in heat exchange relationship with a conduit carrying a stream of fuel to decompose the fuel forming a fuel stream containing hydrogen gas for starting internal combustion engines, the mass flow of the combustion gas being increased as it flows in heat exchange relationship with the fuel carrying conduit, is disclosed.

  9. Blending Hydrogen into Natural Gas Pipeline Networks: A Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues The United States has 11 ...

  10. Proceedings of the 6. international conference on stability and handling of liquid fuels. Volume 2

    SciTech Connect (OSTI)

    Giles, H.N.

    1998-12-01

    Volume 2 of these proceedings contain 42 papers arranged under the following topical sections: Fuel blending and compatibility; Middle distillates; Microbiology; Alternative fuels; General topics (analytical methods, tank remediation, fuel additives, storage stability); and Poster presentations (analysis methods, oxidation kinetics, health problems).

  11. Mid-Level Ethanol Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Mid-Level Ethanol Blends 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ft_05_knoll.pdf More Documents & Publications Mid-Level Ethanol Blends Test Program Biofuels Quality Surveys Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  12. Fuel farms: croplands of the future

    SciTech Connect (OSTI)

    Brown, L.R.

    1980-06-01

    A comprehensive report is given of the use of farmlands for the production of fuel, particularly the production of alcohol to produce gasohol (10% alcohol; 90% petroleum products). Brought about by increasing costs of oil, production of gasohol is proceeding on a worldwide basis led by Brazil, USA, South Africa, New Zealand and Australia. Trends are discussed as well as tax incentives for greater use of gasohol. Various crops are compared in terms of efficiency of conversion to alcohol and limits to production of alcohol by farmlands are considered. Worldwide interest and the competition between the affluent minority and the poorly nourished in developing countries for the products of farmlands are discussed (full tanks, empty stomachs). Economics of the alcohol fuel programs are considered as well as the by-products of the modified alcohol production process (which may be used for animal feed). It is concluded that an alcohol fuel industry is desirable, but many factors (economic, topsoil depletion, proper choice of crop, international communication and cooperation, priorities, uses of the fuel produced, political aspects, etc.) must be considered on a global scale. (MJJ)

  13. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  14. Experimental Investigation of Spark-Ignited Combustion with High-Octane Biofuels and EGR. 2. Fuel and EGR Effects on Knock-Limited Load and Speed

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2013-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in midlevel alcohol gasoline blends with 24% vol/vol isobutanol gasoline (IB24) and 30% vol/vol ethanol gasoline (E30). A single-cylinder research engine is used with an 11.85:1 compression ratio, hydraulically actuated valves, laboratory intake air, and was capable of external exhaust gas recirculation (EGR). Experiments were conducted with all fuels to full-load conditions with = 1, using both 0% and 15% external-cooled EGR. Higher octane number biofuel blends exhibited increased stoichiometric torque capability at this compression ratio, where the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with E30 as compared to that of 87AKI, up to 20 bar IMEPg (indicating mean effective pressure gross) at = 1. The results demonstrate that for all fuels, EGR is a key enabler for increasing engine efficiency but is less useful for knock mitigation with E30 than for 87AKI gasoline or IB24. Under knocking conditions, 15% EGR is found to offer 1 CA of CA50 timing advance with E30, whereas up to 5 CA of CA50 advance is possible with knock-limited 87AKI gasoline. Compared to 87AKI, both E30 and IB24 are found to have reduced adiabatic flame temperature and shorter combustion durations, which reduce knocking propensity beyond that indicated by the octane number. However, E30+0% EGR is found to exhibit the better antiknock properties than either 87AKI+15% EGR or IB24+15% EGR, expanding the knock limited operating range and engine stoichiometric torque capability at high compression ratio. Furthermore, the fuel sensitivity (S) of E30 was attributed to reduced speed sensitivity of E30, expanding the low-speed stoichiometric torque capability at high compression ratio. The results illustrate that intermediate alcohol gasoline blends exhibit exceptional antiknock properties and performance beyond that indicated by the octane number tests, particularly E30.

  15. Development of Kinetic Mechanisms for Next-Generation Fuels and CFD Simulation of Advanced Combustion Engines

    SciTech Connect (OSTI)

    Pitz, William J.; McNenly, Matt J.; Whitesides, Russell; Mehl, Marco; Killingsworth, Nick J.; Westbrook, Charles K.

    2015-12-17

    Predictive chemical kinetic models are needed to represent next-generation fuel components and their mixtures with conventional gasoline and diesel fuels. These kinetic models will allow the prediction of the effect of alternative fuel blends in CFD simulations of advanced spark-ignition and compression-ignition engines. Enabled by kinetic models, CFD simulations can be used to optimize fuel formulations for advanced combustion engines so that maximum engine efficiency, fossil fuel displacement goals, and low pollutant emission goals can be achieved.

  16. Ethanol fuel modification for highway vehicle use. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    A number of problems that might occur if ethanol were used as a blending stock or replacement for gasoline in present cars are identified and characterized as to the probability of occurrence. The severity of their consequences is contrasted to those found with methanol in a previous contract study. Possibilities for correcting several problems are reported. Some problems are responsive to fuel modifications but others require or are better dealt with by modification of vehicles and the bulk fuel distribution system. In general, problems with ethanol in blends with gasoline were found to be less severe than those with methanol. Phase separation on exposure to water appears to be the major problem with ethanol/gasoline blends. Another potentially serious problem with blends is the illict recovery of ethanol for beverage usage, or bootlegging, which might be discouraged by the use of select denaturants. Ethanol blends have somewhat greater tendency to vapor lock than base gasoline but less than methanol blends. Gasoline engines would require modification to operate on fuels consisting mostly of ethanol. If such modifications were made, cold starting would still be a major problem, more difficult with ethanol than methanol. Startability can be provided by adding gasoline or light hydrocarbons. Addition of gasoline also reduces the explosibility of ethanol vapor and furthermore acts as denaturant.

  17. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  18. HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal

    SciTech Connect (OSTI)

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation.

  19. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  20. Carbon-Type Analysis and Comparison of Original and Reblended FACE Diesel Fuels (FACE 2, FACE 4, and FACE 7)

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.; O'Hagan, Molly J.

    2012-10-01

    This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of Fuels for Advanced Combustion Engines (FACE) diesel blends, FD-2B, FD 4B, and FD-7B, and makes comparison of the new blends with the original FACE diesel blends, FD 2A, FD 4A, and FD-7A, respectively. Generally, FD-2A and FD-2B are more similar than the A and B blends of FD-4 and FD-7. The aromatic carbon content is roughly equivalent, although the new FACE blends have decreased monoaromatic content and increased di- and tri-cycloaromatic content, as well as a higher overall aromatic content, than the original FACE blends. The aromatic components of the new FACE blends generally have a higher alkyl substitution with longer alkyl substituents. The naphthenic and paraffinic contents remained relatively consistent. Based on aliphatic methyl and methylene carbon ratios, cetane numbers for FD-2A and -2B, and FD-7A and -7B are predicted to be consistent, while the cetane number for FD-4B is predicted to be higher than FD-4A. Overall, the new FACE fuel blends are fairly consistent with the original FACE fuel blends, but there are observable differences. In addition to providing important comparative compositional information on reformulated FACE diesel blends, this report also provides important information about the capabilities of the team at Pacific Northwest National Laboratory in the use of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  1. Effects of Mid-Level Ethanol Blends on Conventional Vehicle Emissions

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Huff, S.; Thomas, J.; Orban, J.; Cooper, C.

    2010-06-01

    Tests were conducted in 2008 on 16 late-model conventional vehicles (1999-2007) to determine short-term effects of mid-level ethanol blends on performance and emissions. Vehicle odometer readings ranged from 10,000 to 100,000 miles, and all vehicles conformed to federal emissions requirements for their federal certification level. The LA92 drive cycle, also known as the Unified Cycle, was used for testing because it more accurately represents real-world acceleration rates and speeds than the Federal Test Procedure. Test fuels were splash-blends of up to 20 volume percent ethanol with federal certification gasoline. Both regulated and unregulated air-toxic emissions were measured. For the 16-vehicle fleet, increasing ethanol content resulted in reductions in average composite emissions of both nonmethane hydrocarbons and carbon monoxide and increases in average emissions of ethanol and aldehydes.

  2. 5-Carbon Alcohols for Drop-in Gasoline Replacement - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search 5-Carbon Alcohols for Drop-in Gasoline Replacement Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryJay Keasling and Howard Chou of Berkeley Lab and the Joint BioEnergy Institute (JBEI) have invented a fermentation process to produce 5-carbon alcohols from genetically modified E. coli host cells regardless of the

  3. Alternative transportation fuels

    SciTech Connect (OSTI)

    Askew, W.S.; McNamara, T.M.; Maxfield, D.P.

    1980-01-01

    The commercialization of alternative fuels is analyzed. Following a synopsis of US energy use, the concept of commercialization, the impacts of supply shortages and demand inelasticity upon commercialization, and the status of alternative fuels commercialization to date in the US are discussed. The US energy market is viewed as essentially numerous submarkets. The interrelationship among these submarkets precludes the need to commercialize for a specific fuel/use. However, the level of consumption, the projected growth in demand, and the inordinate dependence upon foreign fuels dictate that additional fuel supplies in general be brought to the US energy marketplace. Commercialization efforts encompass a range of measures designed to accelerate the arrival of technologies or products in the marketplace. As discussed in this paper, such a union of willing buyers and willing sellers requires that three general conditions be met: product quality comparable to existing products; price competitiveness; and adequate availability of supply. Product comparability presently appears to be the least problematic of these three requirements. Ethanol/gasoline and methanol/gasoline blends, for example, demonstrate the fact that alternative fuel technologies exist. Yet price and availability (i.e., production capacity) remain major obstacles. Given inelasticity (with respect to price) in the US and abroad, supply shortages - actual or contrived - generate upward price pressure and should make once-unattractive alternative fuels more price competitive. It is noted, however, that actual price competitiveness has been slow to occur and that even with price competitiveness, the lengthy time frame needed to achieve significant production capacity limits the near-term impact of alternative fuels.

  4. Effects of Ignition Quality and Fuel Composition on Critical Equivalence

    Broader source: Energy.gov (indexed) [DOE]

    Ratio | Department of Energy Our research shows that fuel can be blended to have a low ignition quality, which is desirable for high-efficiency advanced combustion, and with a high n-paraffin content to reduce CO and THC. PDF icon deer12_lilik.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Fuel Properties to Enable Lifted Flame Combustion Advancement in Fuel Spray and Combustion Modeling for Compression Ignition Engine Applications A University

  5. METHOD OF PREPARING A CERAMIC FUEL ELEMENT

    DOE Patents [OSTI]

    Ross, W.T.; Bloomster, C.H.; Bardsley, R.E.

    1963-09-01

    A method is described for preparing a fuel element from -325 mesh PuO/ sub 2/ and -20 mesh UO/sub 2/, and the steps of screening --325 mesh UO/sub 2/ from the -20 mesh UO/sub 2/, mixing PuO/sub 2/ with the --325 mesh UO/sub 2/, blending this mixture with sufficient --20 mesh UO/sub 2/ to obtain the desired composition, introducing the blend into a metal tube, repeating the procedure until the tube is full, and vibrating the tube to compact the powder are included. (AEC)

  6. Rapid engine test to measure injector fouling in diesel engines using vegetable oil fuels

    SciTech Connect (OSTI)

    Korus, R.A.; Jaiduk, J.; Peterson, C.L.

    1985-11-01

    Short engine tests were used to determine the rate of carbon deposition on direct injection diesel nozzles. Winter rape, high-oleic and high-linoleic safflower blends with 50% diesel were tested for carbon deposit and compared to that with D-2 Diesel Control Fuel. Deposits were greatest with the most unsaturated fuel, high-linoleic safflower, and least with winter rape. All vegetable oil blends developed power similar to diesel fueled engines with a 6 to 8% greater fuel consumption. 8 references.

  7. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  8. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  9. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Fuel Interchangeability Considerations for Gas Turbine Combustion

    SciTech Connect (OSTI)

    Ferguson, D.H.

    2007-10-01

    In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

  11. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A.

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  12. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  13. Fermentative alcohol production

    DOE Patents [OSTI]

    Wilke, Charles R.; Maiorella, Brian L.; Blanch, Harvey W.; Cysewski, Gerald R.

    1982-01-01

    An improved fermentation process for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using "water load balancing" (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  14. Blending municipal solid waste with corn stover for sugar production using ionic liquid process

    SciTech Connect (OSTI)

    Sun, Ning; Xu, Feng; Sathitsuksanoh, Noppadon; Thompson, Vicki S.; Cafferty, Kara; Li, Chenlin; Tanjore, Deepti; Narani, Akash; Pray, Todd R.; Simmons, Blake A.; Singh, Seema

    2015-06-01

    Municipal solid waste (MSW) represents an attractive cellulosic resource for sustainable fuel production because of its abundance and its low or perhaps negative cost. However, the significant heterogeneity and toxic contaminants are barriers to efficient conversion to ethanol and other products. In this study, we generated MSW paper mix, blended with corn stover (CS), and have shown that both MSW paper mix alone and MSW/CS blends can be efficiently pretreated in certain ionic liquids (ILs) with high yields of fermentable sugars. After pretreatment in 1-ethyl-3-methylimidazolium acetate ([C2C1Im][OAc]), over 80% glucose has been released with enzymatic saccharification. We have also applied an enzyme free process by adding mineral acid and water directly into the IL/biomass slurry to induce hydrolysis. With the acidolysis process in the IL 1-ethyl-3-methylimidazolium chloride ([C2C1Im]Cl), up to 80% glucose and 90% xylose are released for MSW. The results indicate the feasibility of incorporating MSW as a robust blending agent for biorefineries.

  15. Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower Fuel Economy and Emmissions of the Ethanol-Optimized Saab 9-5 Biopower This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending

  16. ESE Alcohol | Open Energy Information

    Open Energy Info (EERE)

    ESE Alcohol Jump to: navigation, search Name: ESE Alcohol Place: Leoti, Kansas Zip: 67861 Product: Owner of a 6.6m litre per year ethanol plant Coordinates: 38.481425,...

  17. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A.; Schmidt, Lanny D.

    2007-08-14

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  18. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    content of emulsions (exclusive of water), and petroleum distillates blended with ... Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline ...

  19. Washington/Incentives | Open Energy Information

    Open Energy Info (EERE)

    - Residential Energy Efficiency Rebate Programs (Washington) Utility Rebate Program Yes Biodiesel and Alcohol Fuel Blend Sales Tax Exemption (Washington) Sales Tax Incentive No...

  20. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures PDF icon p-19seong.pdf ...

  1. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol ...

  2. Alcoholes Biocarburantes de Extremadura Albiex | Open Energy...

    Open Energy Info (EERE)

    search Name: Alcoholes Biocarburantes de Extremadura (Albiex) Place: Spain Product: Spanish bioethanol producer building a plant in Extremadura. References: Alcoholes...

  3. Geothermal source potential and utilization for alcohol production

    SciTech Connect (OSTI)

    Austin, J.C.

    1981-11-01

    A study was conducted to assess the technical and economic feasibility of using a potential geothermal source to drive a fuel grade alcohol plant. Test data from the well at the site indicated that the water temperature at approximately 8500 feet should approach 275/sup 0/F. However, no flow data was available, and so the volume of hot water that can be expected from a well at this site is unknown. Using the available data, numerous fuel alcohol production processes and various heat utilization schemes were investigated to determine the most cost effective system for using the geothermal resource. The study found the direct application of hot water for alcohol production based on atmospheric processes using low pressure steam to be most cost effective. The geothermal flow rates were determined for various sizes of alcohol production facility using 275/sup 0/F water, 235/sup 0/F maximum processing temperature, 31,000 and 53,000 Btu per gallon energy requirements, and appropriate process approach temperatures. It was determined that a 3 million gpy alcohol plant is the largest facility that can practically be powered by the flow from one large geothermal well. An order-of-magnitude cost estimate was prepared, operating costs were calculated, the economic feasibility of the propsed project was examined, and a sensitivity analysis was performed.

  4. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The laboratory studies have included work with a Navistar V-8 turbodiesel engine, demonstration of engine operation on DME-diesel blends and instrumentation for evaluating fuel properties. The field studies have involved performance, efficiency and emissions measurements with the Champion Motorcoach ''Defender'' shuttle bus which will be converted to DME-fueling. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have completed engine combustion studies on DME-diesel blends up to 30 wt% DME addition.

  5. Conductive Polymer/Fullerene Blend Thin Films with Honeycomb...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Conductive PolymerFullerene Blend Thin Films with Honeycomb Framework Brookhaven National Laboratory...

  6. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark...

  7. Fact Sheet: Effects of Intermediate Ethanol Blends | Department...

    Broader source: Energy.gov (indexed) [DOE]

    initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program ...

  8. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  9. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  10. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techno-economic Evaluation of the Production of Mixed Alcohols | Department of Energy 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S.

  11. HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model

    SciTech Connect (OSTI)

    Andrae, J.C.G.; Head, R.A.

    2009-04-15

    Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature and high intake pressure and less resistant to autoignition for high intake temperature and low intake pressure. A sensitivity analysis shows that at high intake temperature the chemistry of the fuels ethanol, toluene and diisobutylene helps to advance ignition. This is consistent with the trend that fuels with the least Negative Temperature Coefficient (NTC) behavior show the highest octane sensitivity, and become less resistant to autoignition at high intake temperatures. For high intake pressure the sensitivity analysis shows that fuels in the fuel blend with no NTC behavior consume OH radicals and acts as a radical scavenger for the fuels with NTC behavior. This is consistent with the observed trend of an increase in RON and fuel sensitivity. With data from shock tube experiments in the literature and HCCI modeling in this work, a correlation between the reciprocal pressure exponent on the ignition delay to the fuel sensitivity and volume percentage of single-stage ignition fuel in the fuel blend was found. Higher fuel sensitivity and single-stage fuel content generally gives a lower value of the pressure exponent. This helps to explain the results obtained while boosting the intake pressure in the HCCI engine. (author)

  12. Alternatives to traditional transportation fuels 1994. Volume 1

    SciTech Connect (OSTI)

    1996-02-01

    In this report, alternative and replacement fuels are defined in accordance with the EPACT. Section 301 of the EPACT defines alternative fuels as: methanol, denatured ethanol, and other alcohols; mixtures containing 85% or more (or such other percentage, but not less than 70%, as determined by the Secretary of Energy, by rule, to provide for requirements relating to cold start, safety, or vehicle functions) by volume of methanol, denatured ethanol, and other alcohols with gasoline or other fuels; natural gas; liquefied petroleum gas; hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials; electricity (including electricity from solar energy); and any other fuel the Secretary determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. The EPACT defines replacement fuels as the portion of any motor fuel that is methanol, ethanol, or other alcohols, natural gas, liquefied petroleum gas, hydrogen, coal-derived liquid fuels, fuels (other than alcohol) derived from biological materials, electricity (including electricity from solar energy), ethers, or any other fuel the Secretary of Energy determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. This report covers only those alternative and replacement fuels cited in the EPACT that are currently commercially available or produced in significant quantities for vehicle demonstration purposes. Information about other fuels, such as hydrogen and biodiesel, will be included in later reports as those fuels become more widely used. Annual data are presented for 1992 to 1996. Data for 1996 are based on plans or projections for 1996.

  13. Catalyst Activity Comparison of Alcohols over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-01-01

    Alcohol transformation to transportation fuel range hydrocarbon on HZSM-5 (SiO2 / Al2O3 = 30) catalyst was studied at 360oC and 300psig. Product distributions and catalyst life were compared using methanol, ethanol, 1-propanol or 1-butanol as a feed. The catalyst life for 1-propanol and 1-butanol was more than double compared to that for methanol and ethanol. For all the alcohols studied, the product distributions (classified to paraffin, olefin, napthene, aromatic and naphthalene compounds) varied with time on stream (TOS). At 24 hours TOS, liquid product from 1-propanol and 1-butanol transformation primarily contains higher olefin compounds. The alcohol transformation process to higher hydrocarbon involves a complex set of reaction pathways such as dehydration, oligomerization, dehydrocyclization, and hydrogenation. Compared to ethylene generated from methanol and ethanol, oligomerization of propylene and butylene has a lower activation energy and can readily take place on weaker acidic sites. On the other hand, dehydrocyclization of propylene and butylene to form the cyclic compounds requires the sits with stronger acid strength. Combination of the above mentioned reasons are the primary reasons for olefin rich product generated in the later stage of the time on stream and for the extended catalyst life time for 1 propanol and 1 butanol compared to methanol and ethanol conversion over HZSM-5.

  14. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid particles have higher density and/or larger size than indicated by previous analysis of SRS sludge and sludge simulants. (5) Tank 21 waste characterization, laboratory settling tests, and additional field turbidity measurements during mixing evolutions are recommended to better understand potential risk for extended (> 60 days) settling times in Tank 21.

  15. VALIDATION OF FIRESIDE PERFORMANCE INDICES: FOULING/CORROSION EVALUATION OF MDF PARTICLEBOARD AND BLENDS WITH WHEAT STRAW BOARD

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Jay R. Gunderson; Donald P. McCollor

    1999-02-01

    Sauder Woodworking currently fires a large portion of all wood wastes in a boiler producing process steam. It is investigating using particleboard made from wheat straw in its manufacturing process and is concerned with the effects of the inorganics on its boiler. Wheat straw board contains higher ash contents and increased levels of potassium, creating concern over fouling characteristics in Sauder's tight boiler design. In addition, the wheat straw board contains high concentrations of chlorine, which may affect boiler tube corrosion when fired in combination with the particleboard wastes currently generated. Sauder has engaged the services of the Energy & Environmental Research Center (EERC) at the University of North Dakota to investigate the potential detrimental effects of firing blends containing wheat straw on boiler tube fouling and corrosion. Additional funding for this project was provided through the U.S. Department of Energy Jointly Sponsored Research Program (DOE JSRP) project ''Validation of Fireside Performance Indices'' to validate, improve, and expand the PCQUEST (Predictive Coal Quality Effects Screening Tool) program. The PCQUEST fuel database is constantly expanding and adding new fuels, for which the algorithms may need refinement and additional verification in order to accurately predict index values. A key focus is on performing advanced and conventional fuel analyses and adding these analyses to the PCQUEST database. Such fuels include coals of all ranks and origins, upgraded coals, petroleum coke, biomass and biomass-coal blends, and waste materials blended with coal. Since there are differences in the chemical and mineral form of the inorganic content in biomass and substantial differences in organic matrix characteristics, analysis and characterization methods developed for coal fuels may not be applicable. The project was seen to provide an excellent opportunity to test and improve the ability of PCQUEST to handle nontypical soil and biomass minerals.

  16. Maintenance and operation of the US Alternative Fuel Center

    SciTech Connect (OSTI)

    Erwin, J.; Ferrill, J.L.; Hetrick, D.L.

    1994-08-01

    The Alternative Fuels Utilization Program (AFUP) of the Office of Energy Efficiency and Renewable Energy has investigated the possibilities and limitations of expanded scope of fuel alternatives and replacement means for transportation fuels from alternative sources. Under the AFUP, the Alternative Fuel Center (AFC) was created to solve problems in the DOE programs that were grappling with the utilization of shale oil and coal liquids for transportation fuels. This report covers the first year at the 3-year contract. The principal objective was to assist the AFUP in accomplishing its general goals with two new fuel initiatives selected for tasks in the project year: (1) Production of low-sulfur, low-olefin catalytically cracked gasoline blendstock; and (2) production of low-reactivity/low-emission gasoline. Supporting goals included maintaining equipment in good working order, performing reformulated gasoline tests, and meeting the needs of other government agencies and industries for fuel research involving custom processing, blending, or analysis of experimental fuels.

  17. Methods of making transportation fuel

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Mo, Weijian; Muylle, Michel Serge Marie; Mandema, Remco Hugo; Nair, Vijay

    2012-04-10

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

  18. Synthetic carbonaceous fuels and feedstocks

    DOE Patents [OSTI]

    Steinberg, Meyer

    1980-01-01

    This invention relates to the use of a three compartment electrolytic cell in the production of synthetic carbonaceous fuels and chemical feedstocks such as gasoline, methane and methanol by electrolyzing an aqueous sodium carbonate/bicarbonate solution, obtained from scrubbing atmospheric carbon dioxide with an aqueous sodium hydroxide solution, whereby the hydrogen generated at the cathode and the carbon dioxide liberated in the center compartment are combined thermocatalytically into methanol and gasoline blends. The oxygen generated at the anode is preferably vented into the atmosphere, and the regenerated sodium hydroxide produced at the cathode is reused for scrubbing the CO.sub.2 from the atmosphere.

  19. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Karnesky, Richard A. (Richland, WA); Leggett, Robert D. (Richland, WA); Baker, Ronald B. (Richland, WA)

    1989-01-01

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  20. Fuel pin

    DOE Patents [OSTI]

    Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

    1987-11-24

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  1. Fuel Options

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cycle Research & Development Fuel Cycle Research & Development Fuel Cycle Research & Development The mission of the Fuel Cycle Research and Development (FCRD) program is to conduct research and development to help develop sustainable fuel cycles, as described in the Nuclear Energy Research and Development Roadmap. Sustainable fuel cycle options are those that improve uranium resource utilization, maximize energy generation, minimize waste generation, improve safety, and limit

  2. Growing attraction of refuse-derived fuels

    SciTech Connect (OSTI)

    Singh, R.

    1981-09-08

    A review of Dr. Andrew Porteous' book, Refuse Derived Fuels is presented. The escalating price of fossil fuel, particularily oil, together with the high cost of handling and transporting refuse makes the idea of refuse-derived fuel production an attractive and economic proposition. Refuse-derived fuel production is discussed and the various manufacturing processes in the UK and the USA are described. The pyrolysis of refuse for the production of gas, oil or heat and the production of methane and ethyl alcohol or other possibilities for refuse conversion.

  3. Alternative Fuels Data Center: Fuel Prices

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicles Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Prices to someone by E-mail Share Alternative Fuels Data Center: Fuel Prices on Facebook Tweet about Alternative Fuels Data Center: Fuel Prices on Twitter Bookmark Alternative Fuels Data Center: Fuel Prices on Google Bookmark Alternative Fuels Data Center: Fuel Prices on Delicious Rank Alternative Fuels Data Center: Fuel Prices on Digg Find More places to share Alternative Fuels Data Center: Fuel

  4. Methods to enhance the characteristics of hydrothermally prepared slurry fuels

    DOE Patents [OSTI]

    Anderson, Chris M.; Musich, Mark A.; Mann, Michael D.; DeWall, Raymond A.; Richter, John J.; Potas, Todd A.; Willson, Warrack G.

    2000-01-01

    Methods for enhancing the flow behavior and stability of hydrothermally treated slurry fuels. A mechanical high-shear dispersion and homogenization device is used to shear the slurry fuel. Other improvements include blending the carbonaceous material with a form of coal to reduce or eliminate the flocculation of the slurry, and maintaining the temperature of the hydrothermal treatment between approximately 300.degree. to 350.degree. C.

  5. Accurate Predictions of Fuel Effects on Combustion and Emissions in Engines Using CFD Simulations With Detailed Fuel Chemistry

    Broader source: Energy.gov [DOE]

    Accurate fuel models with hundreds of species in advanced CFD with reasonable simulation times. Reaction workbench used for surrogate blend formulation and model reduction. FORTE CFD used for HCCI and LTC diesel engine and validated for PRF-ethanol and diesel

  6. Effects of Turbulence on the Combustion Properties of Partially Premixed Flames of Canola Methyl Ester and Diesel Blends

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhamale, N.; Parthasarathy, R. N.; Gollahalli, S. R.

    2011-01-01

    Canola methyl ester (CME) is a biofuel that is a renewable alternative energy resource and is produced by the transesterification of canola oil. The objective of this study was to document the effects of turbulence on the combustion characteristics of blends of CME and No 2 diesel fuel in a partially-premixed flame environment. The experiments were conducted with mixtures of pre-vaporized fuel and air at an initial equivalence ratio of 7 and three burner exit Reynolds numbers, 2700, 3600, and 4500. Three blends with 25, 50, and 75% volume concentration of CME were studied. The soot volume fraction was highestmore » for the pure diesel flames and did not change significantly with Reynolds number due to the mutually compensating effects of increased carbon input rate and increased air entrainment as the Reynolds number was increased. The global NOx emission index was highest and the CO emission index was the lowest for the pure CME flame, and varied non-monotonically with biofuel content in the blend The mean temperature and the NOx concentration at three-quarter flame height were generally correlated, indicating that the thermal mechanism of NOx formation was dominant in the turbulent biofuel flames also.« less

  7. Solid fuel applications to transportation engines

    SciTech Connect (OSTI)

    Rentz, Richard L.; Renner, Roy A.

    1980-06-01

    The utilization of solid fuels as alternatives to liquid fuels for future transportation engines is reviewed. Alternative liquid fuels will not be addressed nor will petroleum/solid fuel blends except for the case of diesel engines. With respect to diesel engines, coal/oil mixtures will be addressed because of the high interest in this specific application as a result of the large number of diesel engines currently in transportation use. Final assessments refer to solid fuels only for diesel engines. The technical assessments of solid fuels utilization for transportation engines is summarized: solid fuel combustion in transportation engines is in a non-developed state; highway transportation is not amenable to solid fuels utilization due to severe environmental, packaging, control, and disposal problems; diesel and open-cycle gas turbines do not appear worthy of further development, although coal/oil mixtures for slow speed diesels may offer some promise as a transition technology; closed-cycle gas turbines show some promise for solid fuels utilization for limited applications as does the Stirling engine for use of cleaner solid fuels; Rankine cycle engines show good potential for limited applications, such as for locomotives and ships; and any development program will require large resources and sophisticated equipment in order to advance the state-of-the-art.

  8. Comparative Emissions Testing of Vehicles Aged on E0, E15 and E20 Fuels

    SciTech Connect (OSTI)

    Vertin, K.; Glinsky, G.; Reek, A.

    2012-08-01

    The Energy Independence and Security Act passed into law in December 2007 has mandated the use of 36 billion ethanol equivalent gallons per year of renewable fuel by 2022. A primary pathway to achieve this national goal is to increase the amount of ethanol blended into gasoline. This study is part of a multi-laboratory test program coordinated by DOE to evaluate the effect of higher ethanol blends on vehicle exhaust emissions over the lifetime of the vehicle.

  9. Acute aquatic toxicity and biodegradation potential of biodiesel fuels

    SciTech Connect (OSTI)

    Haws, R.A.; Zhang, X.; Marshall, E.A.; Reese, D.L.; Peterson, C.L.; Moeller, G.

    1995-12-31

    Recent studies on the biodegradation potential and aquatic toxicity of biodiesel fuels are reviewed. Biodegradation data were obtained using the shaker flask method observing the appearance of CO{sub 2} and by observing the disappearance of test substance with gas chromatography. Additional BOD{sub 5} and COD data were obtained. The results indicate the ready biodegradability of biodiesel fuels as well as the enhanced co-metabolic biodegradation of biodiesel and petroleum diesel fuel mixtures. The study examined reference diesel, neat soy oil, neat rape oil, and the methyl and ethyl esters of these vegetable oils as well as various fuel blends. Acute toxicity tests on biodiesel fuels and blends were performed using Oncorhynchus mykiss (Rainbow Trout) in a static non-renewal system and in a proportional dilution flow replacement system. The study is intended to develop data on the acute aquatic toxicity of biodiesel fuels and blends under US EPA Good Laboratory Practice Standards. The test procedure is designed from the guidelines outlined in Methods for Measuring the Acute Toxicity of Effluents and Receiving Waters to Freshwater and Marine Organisms and the Fish Acute Aquatic Toxicity Test guideline used to develop aquatic toxicity data for substances subject to environmental effects test regulations under TSCA. The acute aquatic toxicity is estimated by an LC50, a lethal concentration effecting mortality in 50% of the test population.

  10. Chemical Kinetic Modeling of Advanced Transportation Fuels

    SciTech Connect (OSTI)

    PItz, W J; Westbrook, C K; Herbinet, O

    2009-01-20

    Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

  11. Alternative Fuels Data Center: Emerging Fuels

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Emerging Fuels to someone by E-mail Share Alternative Fuels Data Center: Emerging Fuels on Facebook Tweet about Alternative Fuels Data Center: Emerging Fuels on Twitter Bookmark Alternative Fuels Data Center: Emerging Fuels on Google Bookmark Alternative Fuels Data Center: Emerging Fuels on Delicious Rank Alternative Fuels Data Center: Emerging Fuels on Digg Find More places to share Alternative

  12. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in

  13. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on

  14. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  15. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  16. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations

  17. Alternative Fuels Data Center: Propane Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Google Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Delicious Rank Alternative Fuels Data Center: Propane Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Propane Fueling Stations on

  18. Calcination of calcium carbonate and blend therefor

    DOE Patents [OSTI]

    Mallow, William A.; Dziuk, Jr., Jerome J.

    1989-01-01

    A method for calcination of a calcium carbonate material comprising heating the calcium carbonate material to a temperature and for a time sufficient to calcine the material to the degree desired while in the presence of a catalyst; said catalyst comprising at least one fused salt having the formula MCO.sub.3.CaCO.sub.3.CaO.H.sub.2 O.sub.x, wherein M is an alkali metal and x is 0 to 1 and formed by fusing MCO.sub.3 and CaCO.sub.3 in a molar ratio of about 1:2 to 2:1, and a blend adapted to be heated to CaO comprising a calcium carbonate material and at least one such fused salt.

  19. Global Assessment of Hydrogen Technologies - Task 2 Report Comparison of Performance and Emissions from Near-Term Hydrogen Fueled Light Duty Vehicles

    SciTech Connect (OSTI)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Ng, Henry K.; Waller, Thomas

    2007-12-01

    An investigation was conducted on the emissions and efficiency from hydrogen blended compressed natural gas (CNG) in light duty vehicles. The different blends used in this investigation were 0%, 15%, 30%, 50%, 80%, 95%, and ~100% hydrogen, the remainder being compressed natural gas. The blends were tested using a Ford F-150 and a Chevrolet Silverado truck supplied by Arizona Public Services. Tests on emissions were performed using four different driving condition tests. Previous investigation by Don Karner and James Frankfort on a similar Ford F-150 using a 30% hydrogen blend showed that there was substantial reduction when compared to gasoline in carbon monoxide (CO), nitrogen oxide (NOx), and carbon dioxide (CO2) emissions while the reduction in hydrocarbon (HC) emissions was minimal. This investigation was performed using different blends of CNG and hydrogen to evaluate the emissions reducing capabilities associated with the use of the different fuel blends. The results were then tested statistically to confirm or reject the hypotheses on the emission reduction capabilities. Statistically analysis was performed on the test results to determine whether hydrogen concentration in the HCNG had any effect on the emissions and the fuel efficiency. It was found that emissions from hydrogen blended compressed natural gas were a function of driving condition employed. Emissions were found to be dependent on the concentration of hydrogen in the compressed natural gas fuel blend.

  20. Syngas Mixed Alcohol Cost Validation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2013 DOE Bioenergy Technologies Office: Project Peer Review Syngas Mixed Alcohol Cost Validation Abhijit Dutta, NREL This presentation does not contain any proprietary, ...

  1. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  2. Transportation Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels DOE would invest $52 million to fund a major fleet transformation at Idaho National Laboratory, along with the installation of nine fuel management systems, purchase of additional flex fuel cars and one E85 ethanol fueling station. Transportation projects, such as the acquisition of highly efficient and alternative-fuel vehicles, are not authorized by ESPC legislation. DOE has twice proportion of medium vehicles and three times as many heavy vehicles as compared to the Federal agency

  3. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  4. Multiple fuel supply system for an internal combustion engine

    DOE Patents [OSTI]

    Crothers, William T.

    1977-01-01

    A multiple fuel supply or an internal combustion engine wherein phase separation of components is deliberately induced. The resulting separation permits the use of a single fuel tank to supply components of either or both phases to the engine. Specifically, phase separation of a gasoline/methanol blend is induced by the addition of a minor amount of water sufficient to guarantee separation into an upper gasoline phase and a lower methanol/water phase. A single fuel tank holds the two-phase liquid with separate fuel pickups and separate level indicators for each phase. Either gasoline or methanol, or both, can be supplied to the engine as required by predetermined parameters. A fuel supply system for a phase-separated multiple fuel supply contained in a single fuel tank is described.

  5. Fuel-tolerance tests with the Ford PROCO engine

    SciTech Connect (OSTI)

    Choma, M.A.; Havstad, P.H.; Simko, A.O.; Stockhausen, W.F.

    1981-01-01

    A variety of fuel tolerance tests were conducted utilizing Ford's PROCO engine, a direct fuel injection stratified charge engine developed for light duty vehicles. These engine tests were run on the dynamometer and in vehicles. Data indicate an 89 RON octane requirement, relatively low sensitivity to volatility characteristics and good fuel economy, emission control and operability on a certain range of petroleum fuel and alcohol mixes including 100% methanol. Fuels such as JP-4 and Diesel fuel are not at present suitable for this engine. There were no engine modifications tested that might improve the match between the engine and a particular fuel. The 100% methanol test was conducted with a modified fuel injection pump. Durability aspects including compatibility of various fuels with the materials in the fuel system were not addressed.

  6. fuel cells | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    fuel cells

  7. Phosphor blends for high-CRI fluorescent lamps

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Srivastava, Alok Mani; Comanzo, Holly Ann; Manivannan, Venkatesan; Beers, William Winder; Toth, Katalin; Balazs, Laszlo D.

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  8. RIVER PROTECTION PROJECT MISSION ANALYSIS WASTE BLENDING STUDY

    SciTech Connect (OSTI)

    SHUFORD DH; STEGEN G

    2010-04-19

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  9. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  10. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  12. Development of HC-SCR System Using Diesel Fuel as a Reductant | Department

    Broader source: Energy.gov (indexed) [DOE]

    in Gas Turbines - Fact Sheet, May 2014 | Department of Energy GE Global Research developed and tested new fuel-flexible gas turbine nozzle technology concepts that will enable end users to efficiently generate power and heat from industrial off-gases and gasified industrial, agricultural, or municipal waste streams, as well as blends of these opportunity fuels with readily available pipeline gases. PDF icon fuel-flexible_combustion_systems_factsheet.pdf More Documents & Publications

  13. Alternative Fuels Data Center: Flexible Fuel Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Flexible Fuel Vehicles to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicles on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicles on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicles on Digg

  14. Methanol with dimethyl ether ignition promotor as fuel for compression ignition engines

    SciTech Connect (OSTI)

    Brook, D.L.; Cipolat, D.; Rallis, C.J.

    1984-08-01

    Reduction of the world dependence upon crude oil necessitates the use of long term alternative fuels for internal combustion engines. Alcohols appear to offer a solution as in the short term they can be manufactured from natural gas and coal, while ultimately they may be produced from agricultural products. A fair measure of success has been achieved in using alcohols in spark ignition engines. However the more widely used compression ignition engines cannot utilize unmodified pure alcohols. The current techniques for using alcohol fuels in compression ignition engines all have a number of shortcomings. This paper describes a novel technique where an ignition promotor, dimethyl ether (DME), is used to increase the cetane rating of methanol. The systems particular advantage is that the DME can be catalyzed from the methanol base fuel, in situ. This fuel system matches the performance characteristics of diesel oil fuel.

  15. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  16. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  17. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank; Hoover, David S.; Garg, Diwaker

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  18. Photonic polymer-blend structures and method for making

    DOE Patents [OSTI]

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  19. Conversion and Blending Facility highly enriched uranium to low enriched uranium as metal. Revision 1

    SciTech Connect (OSTI)

    1995-07-05

    The mission of this Conversion and Blending Facility (CBF) will be to blend surplus HEU metal and alloy with depleted uranium metal to produce an LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

  20. Downregulation of Cinnamyl Alcohol Dehydrogenase (CAD) Leads...

    Office of Scientific and Technical Information (OSTI)

    Alcohol Dehydrogenase (CAD) Leads to Improved Saccharification Efficiency in Switchgrass Citation Details In-Document Search Title: Downregulation of Cinnamyl Alcohol Dehydrogenase ...

  1. FUEL FORMULATION EFFECTS ON DIESEL FUEL INJECTION, COMBUSTION, EMISSIONS AND EMISSION CONTROL

    SciTech Connect (OSTI)

    Boehman, A; Alam, M; Song, J; Acharya, R; Szybist, J; Zello, V; Miller, K

    2003-08-24

    This paper describes work under a U.S. DOE sponsored Ultra Clean Fuels project entitled ''Ultra Clean Fuels from Natural Gas,'' Cooperative Agreement No. DE-FC26-01NT41098. In this study we have examined the incremental benefits of moving from low sulfur diesel fuel and ultra low sulfur diesel fuel to an ultra clean fuel, Fischer-Tropsch diesel fuel produced from natural gas. Blending with biodiesel, B100, was also considered. The impact of fuel formulation on fuel injection timing, bulk modulus of compressibility, in-cylinder combustion processes, gaseous and particulate emissions, DPF regeneration temperature and urea-SCR NOx control has been examined. The primary test engine is a 5.9L Cummins ISB, which has been instrumented for in-cylinder combustion analysis and in-cylinder visualization with an engine videoscope. A single-cylinder engine has also been used to examine in detail the impacts of fuel formulation on injection timing in a pump-line-nozzle fueling system, to assist in the interpretation of results from the ISB engine.

  2. Macrophase Separation of Blends of Diblock Copolymers in Thin Films

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Macrophase Separation of Blends of Diblock Copolymers in Thin Films Citation Details In-Document Search Title: Macrophase Separation of Blends of Diblock Copolymers in Thin Films Authors: Williamson, Lance D. ; Nealey, Paul F. [1] + Show Author Affiliations (UC) Publication Date: 2015-08-26 OSTI Identifier: 1203744 Resource Type: Journal Article Resource Relation: Journal Name: Macromolecules; Journal Volume: 48; Journal Issue: (12) ; 06, 2015 Research

  3. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  4. Electro-autotrophic synthesis of higher alcohols

    DOE Patents [OSTI]

    Liao, James C.; Cho, Kwang Myung

    2015-10-06

    The disclosure provides a process that converts CO.sub.2 to higher alcohols (e.g. isobutanol) using electricity as the energy source. This process stores electricity (e.g. from solar energy, nuclear energy, and the like) in liquid fuels that can be used as high octane number gasoline substitutes. Instead of deriving reducing power from photosynthesis, this process derives reducing power from electrically generated mediators, either H.sub.2 or formate. H.sub.2 can be derived from electrolysis of water. Formate can be generated by electrochemical reduction of CO.sub.2. After delivering the reducing power in the cell, formate becomes CO.sub.2 and recycles back. Therefore, the biological CO.sub.2 fixation process can occur in the dark.

  5. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut fr Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  6. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  7. Fuel Economy

    Broader source: Energy.gov [DOE]

    The Energy Department is investing in groundbreaking research that will make cars weigh less, drive further and consume less fuel.

  8. Fuels Technologies

    Energy Savers [EERE]

    Fuels Technologies Program Mission To develop more energy efficient and environmentally friendly highway transportation technologies that enable America to use less petroleum. --EERE Strategic Plan, October 2002-- Kevin Stork, Team Leader Fuel Technologies & Technology Deployment Vehicle Technologies Program Energy Efficiency and Renewable Energy U.S. Department of Energy DEER 2008 August 6, 2008 Presentation Outline n Fuel Technologies Research Goals Fuels as enablers for advanced engine

  9. Low and intermediate temperature oxidation of ethanol and ethanol-PRF blends: An experimental and modeling study

    SciTech Connect (OSTI)

    Haas, Francis M.; Chaos, Marcos; Dryer, Frederick L.

    2009-12-15

    In this brief communication, we present new experimental species profile measurements for the low and intermediate temperature oxidation of ethanol under knock-prone conditions. These experiments show that ethanol exhibits no global low temperature reactivity at these conditions, although we note the heterogeneous decomposition of ethanol to ethylene and water. Similar behavior is reported for an E85 blend in n-heptane. Kinetic modeling results are presented to complement these experiments and elucidate the interaction of ethanol and primary reference fuels undergoing cooxidation. (author)

  10. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  11. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    SciTech Connect (OSTI)

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People`s Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  12. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    SciTech Connect (OSTI)

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People's Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  13. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  14. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  15. Blender Pump Fuel Survey: CRC Project E-95-2

    SciTech Connect (OSTI)

    Williams, A.; Alleman, T. L.

    2014-05-01

    With the increasing fuel diversity in the marketplace, the Coordinating Research Council and the U.S. Department of Energy's National Renewable Energy Laboratory conducted a survey of mid-level ethanol blends (MLEBs) in the market. A total of 73 fuel samples were collected from 20 retail stations. To target Class 4 volatility, the fuel samples were collected primarily in the midwestern United States in the month of February. Samples included the gasoline (E0), Flex Fuel, and every MLEB that was offered from each of the 20 stations. Photographs of each station were taken at the time of sample collection, detailing the pump labeling and configuration. The style and labeling of the pump, hose, and dispenser nozzle are all important features to prevent misfueling events. The physical location of the MLEB product relative to the gasoline product can also be important to prevent misfueling. In general, there were many differences in the style and labeling of the blender pumps surveyed in this study. All samples were analyzed for volatility and ethanol content. For the MLEB samples collected, the fuels tended to be lower in ethanol content than their indicated amount; however, the samples were all within 10 vol% of their indicated blend level. One of the 20 Flex Fuel samples was outside of the allowable limits for ethanol content. Four of the 20 Flex Fuel samples had volatility below the minimum requirement for Class 4.

  16. Engine Materials Compatability with Alternative Fuels

    SciTech Connect (OSTI)

    Pawel, Steve; Moore, D.

    2013-04-05

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined were accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  17. Engine Materials Compatibility with Alternate Fuels

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-05-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined were accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  18. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  19. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  20. Engine performance comparison associated with carburetor icing during aviation grade fuel and automotive grade fuel operation. Final report Jan-Jul 82

    SciTech Connect (OSTI)

    Cavage, W.; Newcomb, J.; Biehl, K.

    1983-05-01

    A comprehensive sea-level-static test cell data collection and evaluation effort to review operational characteristics of 'off-the-shelf' carburetor ice detection/warning devices for general aviation piston engine aircraft during operation on aviation grade fuel and automotive grade fuel. Presented herein are results, observations and conclusions drawn from over 250 hours of test cell engine operation on 100LL aviation grade fuel, unleaded premium and unleaded regular grade automotive fuel. Sea-level-static test cell engine operations were conducted utilizing a Teledyne Continental Motors 0-200A engine and a Cessna 150 fuel system to review engine operational characteristics of 100LL aviation grade fuel and various blends of automotive grade fuel as well as carburetor ice detectors/warning devices sensitivity/effectiveness during actual carburetor icing. The primary purpose of test cell engine operation was to observe real-time carburetor icing characteristics associated with possible automotive grade fuel utilization by piston-powered light general aviation aircraft. In fulfillment of this task, baseline engine operations were established with 100LL aviation grade fuel followed by various blend of automotive grade fuel prior to imposing carburetor icing conditions and assessing operational characteristics.

  1. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  2. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cells Fact Sheets Research Team Members Key Contacts Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per 1000 hours over a

  3. Controlled differential pressure system for an enhanced fluid blending apparatus

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  4. Effect of Biodiesel Blending on the Speciation of Soluble Organic Fraction from a Light Duty Diesel Engine

    SciTech Connect (OSTI)

    Strzelec, Andrea; Storey, John Morse; Lewis Sr, Samuel Arthur; Daw, C Stuart; Foster, Prof. Dave; Rutland, Prof. Christopher J.

    2010-01-01

    Soy methyl ester (SME) biodiesel was volumetrically blended with 2007 certification ultra low sulfur diesel (ULSD) fuel and run in a 1.7L direct-injection common rail diesel engine at one speed-load point (1500rpm, 2.6bar BMEP). Engine fueling rate and injection timing were adjusted to maintain a constant load, while particulate samples were collected in a diesel particulate filter (DPF) and with a dilution tunnel sampling train. The samples collected at these two locations were found to contain different levels of soluble organic fraction (SOF) and the different hydrocarbon species in the SOF. This observation indicates that traditional SOF measurements, in light of the specific sampling procedure used, may not be appropriate to DPF applications.

  5. Solar energy assisted alcohol fuel system for farm

    SciTech Connect (OSTI)

    Eyrich, F.H.

    1984-02-01

    A project is briefly described which would produce ethanol on a farm using LP gas as a heat source and heat recovered from the fermenter to preheat water. (DMC)

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Labeling Requirements Pumps that dispense ethanol-blended gasoline available for purchase must be labeled with the registered brand name and the volume percentage, or blend level, of the ethanol (10% or less, 10-15%, 15-85% or 85%). The labels must be affixed to the front panel of the pump in a position that is clearly visible to the vehicle driver. Graphics requirements apply. (Reference North Carolina Administrative Code Title 2, Chapter 42, Subchapter .0401; and North Carolina

  7. Fuel Model | NISAC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels Model This model informs analyses of the availability of transportation fuel in the event the fuel supply chain is disrupted. The portion of the fuel supply system...

  8. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines June 22, 2015 - ...

  9. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Presented at the DOE-DOD Shipboard APU Workshop on March 29, 2011. PDF icon apu2011_6_roychoudhury.pdf More Documents & Publications System Design - Lessons Learned, Generic Concepts, Characteristics & Impacts Fuel Cells For Transportation - 1999 Annual Progress Report Energy Conversion Team Fuel Cell Systems Annual Progress Report

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Tax Deduction Entities and individuals that receive or manufacture and deliver biodiesel within the state for blending or resale are eligible for a tax deduction for the...

  11. Performance and emissions of non-petroleum fuels in a direct-injection stratified charge Sl engine

    SciTech Connect (OSTI)

    Freeman, L.E.; Chui, G.K.; Roby, R.J.

    1982-10-01

    Seven fuels derived from coal and shale resources were evaluated using a direct-injection stratified charge engine. The fuels were refined to different degrees which ranged from those typical of gasoline blending components to those similar to current gasoline. Results showed that fuels refined to have properties similar to gasoline performed like gasoline. The less refined fuels were limited in performance. The total carbon monoxide and the hydrocarbon emissions varied with the volatility of the fuels. Most fuels with a higher overall distillation curve generally gave higher hydrocarbon and carbon monoxide emissions. The NOx emissions increased with the percent aromatics in the fuels. The hydrocarbon emissions were found to increase with fuel viscosity. Within the range of engine operation, nearly all the fuels evaluated gave satisfactory performance. With some modifications, even the less refined fuels can be potentially suitable for use in this engine.

  12. Hydrogen Fuel Pilot Plant and Hydrogen ICE Vehicle Testing

    SciTech Connect (OSTI)

    J. Francfort

    2005-03-01

    The U.S. Department Energy's Advanced Vehicle Testing Activity (AVTA) teamed with Electric Transportation Applications (ETA) and Arizona Public Service (APS) to develop the APS Alternative Fuel (Hydrogen) Pilot Plant that produces and compresses hydrogen on site through an electrolysis process by operating a PEM fuel cell in reverse; natural gas is also compressed onsite. The Pilot Plant dispenses 100% hydrogen, 15 to 50% blends of hydrogen and compressed natural gas (H/CNG), and 100% CNG via a credit card billing system at pressures up to 5,000 psi. Thirty internal combustion engine (ICE) vehicles (including Daimler Chrysler, Ford and General Motors vehicles) are operating on 100% hydrogen and 15 to 50% H/CNG blends. Since the Pilot Plant started operating in June 2002, they hydrogen and H/CNG ICE vehicels have accumulated 250,000 test miles.

  13. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  14. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  15. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  16. California Fuel Cell Partnership: Alternative Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Partnership - Alternative Fuels Research TNS Automotive Chris White Communications Director cwhite@cafcp.org 2 TNS Automotive for California Fuel Cell Partnership ...

  17. Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles

    SciTech Connect (OSTI)

    Karavalakis, Georgios; Durbin, Thomas; Shrivastava, ManishKumar B.; Zheng, Zhongqing; Villella, Phillip M.; Jung, Hee-Jung

    2012-03-30

    The study investigated the impact of ethanol blends on criteria emissions (THC, NMHC, CO, NOx), greenhouse gas (CO2), and a suite of unregulated pollutants in a fleet of gasoline-powered light-duty vehicles. The vehicles ranged in model year from 1984 to 2007 and included one Flexible Fuel Vehicle (FFV). Emission and fuel consumption measurements were performed in duplicate or triplicate over the Federal Test Procedure (FTP) driving cycle using a chassis dynamometer for four fuels in each of seven vehicles. The test fuels included a CARB phase 2 certification fuel with 11% MTBE content, a CARB phase 3 certification fuel with a 5.7% ethanol content, and E10, E20, E50, and E85 fuels. In most cases, THC and NMHC emissions were lower with the ethanol blends, while the use of E85 resulted in increases of THC and NMHC for the FFV. CO emissions were lower with ethanol blends for all vehicles and significantly decreased for earlier model vehicles. Results for NOx emissions were mixed, with some older vehicles showing increases with increasing ethanol level, while other vehicles showed either no impact or a slight, but not statistically significant, decrease. CO2 emissions did not show any significant trends. Fuel economy showed decreasing trends with increasing ethanol content in later model vehicles. There was also a consistent trend of increasing acetaldehyde emissions with increasing ethanol level, but other carbonyls did not show strong trends. The use of E85 resulted in significantly higher formaldehyde and acetaldehyde emissions than the specification fuels or other ethanol blends. BTEX and 1,3-butadiene emissions were lower with ethanol blends compared to the CARB 2 fuel, and were almost undetectable from the E85 fuel. The largest contribution to total carbonyls and other toxics was during the cold-start phase of FTP.

  18. Fuel agglomerates and method of agglomeration

    DOE Patents [OSTI]

    Wen, Wu-Wey (Murrysville, PA)

    1986-01-01

    Solid fuel agglomerates are prepared of particulate coal or other carbonaceous material with a binder having a high humic acid or humate salt content. The humic acid is extracted from oxidized carbonaceous material with a mild aqueous alkali solution of, for instance, ammonia. The particulate material is blended with the extract which serves as the binder for the agglomerates. The water-resistant agglomerates are formed such as by pelletizing, followed by drying to remove moisture and solidify the humic acid binder throughout the agglomerate.

  19. Evaluation of unthrottled combustion system options for light duty applications with future syncrude derived fuels. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Needham, J. R.; Cooper, B. M.; Norris-Jones, S. R.

    1982-12-01

    An experimental program examining the interaction between several fuel and light duty automotive engine combinations is detailed. Combustion systems addressed covered indirect and direct injection diesel and spark ignited stratified charge. Fuels primarily covered D2, naphtha and intermediate broadcut blends. Low ignition quality diesel fuels were also evaluated. The results indicate the baseline fuel tolerance of each combustion system and enable characteristics of the systems to be compared. Performance, gaseous and particulate emissions aspects were assessed. The data obtained assists in the selection of candidate combustion systems for potential future fuels. Performance and environmental penalties as appropriate are highlighted relative to the individual candidates. Areas of further work for increased understanding are also reviewed.

  20. Supply Chain Based Solution to Prevent Fuel Tax Evasion: Proof of Concept Final Report

    SciTech Connect (OSTI)

    Capps, Gary J; Lascurain, Mary Beth; Franzese, Oscar; Earl, Dennis Duncan; West, David L; McIntyre, Timothy J; Chin, Shih-Miao; Hwang, Ho-Ling; Connatser, Raynella M; Lewis Sr, Samuel Arthur; Moore, Sheila A

    2011-12-01

    The goal of this research was to provide a proof-of-concept (POC) system for preventing non-taxable (non-highway diesel use) or low-taxable (jet fuel) petrochemical products from being blended with taxable fuel products and preventing taxable fuel products from cross-jurisdiction evasion. The research worked to fill the need to validate the legitimacy of individual loads, offloads, and movements by integrating and validating, on a near-real-time basis, information from global positioning system (GPS), valve sensors, level sensors, and fuel-marker sensors.

  1. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  2. The Effects of Fuel Characteristics on Stoichiometric Spark-Assisted HCCI

    SciTech Connect (OSTI)

    Weall, Adam J; Szybist, James P

    2012-01-01

    The characteristics of fuel lean HCCI operation using a variety of fuels are well known and have been demonstrated using different engine concepts in the past. In contrast, stoichiometric operation of HCCI is less well documented. Recent studies have highlighted the benefits of operating at a stoichiometric condition in terms of load expansion combined with the applicability of three way catalyst technology to reduce NOx emissions. In this study the characterization of stoichiometric HCCI using gasoline-like fuels was undertaken. The fuels investigated are gasoline, a 50 vol% blend of iso-butanol and gasoline (IB50), and an 85% vol blend of ethanol and gasoline (E85). A single cylinder engine operating with direct injection and spark assist combined with a fully variable hydraulic valve actuation system allowed a wide range of operating parameters to be studied. The resultant fuel properties which differed in terms of octane rating, fuel oxygenation and heat of vaporization show that stoichiometric HCCI is possible using a range of fuels but that these fuel characteristics do have some effect on the combustion characteristics. How these fuel properties can enable an increased engine operating envelope to be achieved, in comparison with both fuel lean HCCI and conventional spark ignited combustion, is then discussed.

  3. Carbon dioxide emission index as a mean for assessing fuel quality

    SciTech Connect (OSTI)

    Furimsky, E.

    2008-07-01

    Carbon dioxide emission index, defined as the amount of CO{sub 2} released per unit of energy value, was used to rate gaseous, liquid and solid fuels. The direct utilization of natural gas is the most efficient option. The conversion of natural gas to synthesis gas for production of liquid fuels represents a significant decrease in fuel value of the former. The fuel value of liquids, such as gasoline, diesel oil, etc. is lower than that of natural gas. Blending gasoline with ethanol obtained either from bio-mass or via synthesis may decrease fuel value of the blend when CO{sub 2} emissions produced during the production of ethanol are included in total emissions. The introduction of liquid fuels produced by pyrolysis and liquefaction of biomass would result in the increase in the CO{sub 2} emissions. The CO{sub 2} emissions from the utilization of coal and petroleum coke are much higher than those from gaseous and liquid fuels. However, for petroleum coke, this is offset by the high value gaseous and liquid fuels that are simultaneously produced during coking. Conversion of low value fuels such as coal and petroleum coke to a high value chemicals via synthesis gas should be assessed as means for replacing natural gas and making it available for fuel applications.

  4. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  5. Modeling the Effects of Steam-Fuel Reforming Products on Low Temperature

    Broader source: Energy.gov (indexed) [DOE]

    Combustion of n-Heptane | Department of Energy The effects of blends of base fuel (n-heptane) and fuel-reformed products on the low-temperature combustion process were investigated. PDF icon deer08_posada.pdf More Documents & Publications Low Temperature Combustion with Thermo-chemical Recuperation to Maximize In-use Engine Efficiency Enabling Low Temperature Combustion Through Thermo-Chemical Recuperation Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

  6. Diesel engine performance and emissions using different fuel/additive combinations

    SciTech Connect (OSTI)

    Sutton, D.L.; Rush, M.W.; Richards, P.

    1988-01-01

    It is probable that diesel fuel quality in Europe will fall as the need to blend conversion components into the diesel pool increases. In particular diesel ignition quality and stability could decrease and carbon residue and aromatic content increase. This paper discusses the effects of worsening fuel quality on combustion, injection characteristics and emissions and the efficacy of appropriate additives in overcoming these effects. Both direct injection and indirect injection engines were used in the investigations.

  7. Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy This page contains information on the recently released BioPower engines. PDF icon analysis_saab2007.pdf More Documents & Publications Enabling High Efficiency Ethanol Engines Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization

    Andy Oare Andy Oare Former New Media Strategist, Office of Public Affairs What does this

  8. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  9. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  10. Renewable Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Fuels 5 th Annual Green Technologies Conference IEEE IEEE Ch IEEE IEEE H l Helena L L. Chum April 5 April 5 th 2013 , 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. Outline * Renewable Fuels Renewable Fuels * Biomass and Bioenergy Today C di i i i i /d l i * Commoditization existing/developing * Sustainability y Considerations to Imp prove Agriculture and

  11. FUEL ELEMENT

    DOE Patents [OSTI]

    Bean, R.W.

    1963-11-19

    A ceramic fuel element for a nuclear reactor that has improved structural stability as well as improved cooling and fission product retention characteristics is presented. The fuel element includes a plurality of stacked hollow ceramic moderator blocks arranged along a tubular raetallic shroud that encloses a series of axially apertured moderator cylinders spaced inwardly of the shroud. A plurality of ceramic nuclear fuel rods are arranged in the annular space between the shroud and cylinders of moderator and appropriate support means and means for directing gas coolant through the annular space are also provided. (AEC)

  12. TIME-VARYING FLAME IONIZATION SENSING APPLIED TO NATURAL GAS AND PROPANE BLENDS IN A PRESSURIZED LEAN PREMIXED (LPM) COMBUSTOR

    SciTech Connect (OSTI)

    D. L. Straub; B. T. Chorpening; E. D. Huckaby; J. D. Thornton; W. L. Fincham

    2008-06-13

    In-situ monitoring of combustion phenomena is a critical need for optimal operation and control of advanced gas turbine combustion systems. The concept described in this paper is based on naturally occurring flame ionization processes that accompany the combustion of hydrocarbon fuels. Previous work has shown that flame ionization techniques may be applied to detect flashback, lean blowout, and some aspects of thermo-acoustic combustion instabilities. Previous work has focused on application of DC electric fields. By application of time-varying electric fields, significant improvements to sensor capabilities have been observed. These data have been collected in a lean premixed combustion test rig operating at 0.51-0.76 MPa (5-7.5 atm) with air preheated to 588 K (600F). Five percent of the total fuel flow is injected through the centerbody tip as a diffusion pilot. The fuel composition is varied independently by blending approximately 5% (volume) propane with the pipeline natural gas. The reference velocity through the premixing annulus is kept constant for all conditions at a nominal value of 70 m/s. The fuel-air equivalence ratio is varied independently from 0.46 0.58. Relative to the DC field version, the time-varying combustion control and diagnostic sensor (TV-CCADS) shows a significant improvement in the correlation between the measured flame ionization current and local fuel-air equivalence ratio. In testing with different fuel compositions, the triangle wave data show the most distinct change in flame ionization current in response to an increase in propane content. Continued development of this sensor technology will improve the capability to control advanced gas turbine combustion systems, and help address issues associated with variations in fuel supplies.

  13. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non?Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian H; Clark, Wendy; Graves, Ronald L; Orban, John; Przesmitzki, Steve; Theiss, Timothy J

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2 (Experimental Setup) provides details concerning test fuels, vehicle and SNRE selection, and test methods used to conduct the studies presented in this report. Section 3 (Results and Discussion) summarizes the vehicle and SNRE studies and presents data from testing completed to date. Section 4 (Next Steps) describes planned future activities. The appendixes provide test procedure details, vehicle and SNRE emissions standards, analysis details, and additional data and tables from vehicle and SNRE tests.

  14. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  15. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje

    1984-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  16. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, T.

    A polymer blend is disclosed of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  17. Production of chemicals and fuels from biomass

    DOE Patents [OSTI]

    Woods, Elizabeth M.; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

    2015-12-15

    Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  18. Fuel economizer

    SciTech Connect (OSTI)

    Zwierzelewski, V.F.

    1984-06-26

    A fuel economizer device for use with an internal combustion engine fitted with a carburetor is disclosed. The fuel economizer includes a plate member which is mounted between the carburetor and the intake portion of the intake manifold. The plate member further has at least one aperture formed therein. One tube is inserted through the at least one aperture in the plate member. The one tube extends longitudinally in the passage of the intake manifold from the intake portion toward the exit portion thereof. The one tube concentrates the mixture of fuel and air from the carburetor and conveys the mixture of fuel and air to a point adjacent but spaced away from the inlet port of the internal combustion engine.

  19. Fuel Economy and Emissions of a Vehicle Equipped with an Aftermarket Flexible-Fuel Conversion Kit

    SciTech Connect (OSTI)

    Thomas, John F; Huff, Shean P; West, Brian H

    2012-04-01

    The U.S. Environmental Protection Agency (EPA) grants Certificates of Conformity for alternative fuel conversion systems and also offers other forms of premarket registration of conversion kits for use in vehicles more than two model years old. Use of alternative fuels such as ethanol, natural gas, and propane are encouraged by the Energy Policy Act of 1992. Several original equipment manufacturers (OEMs) produce emissions-certified vehicles capable of using alternative fuels, and several alternative fuel conversion system manufacturers produce EPA-approved conversion systems for a variety of alternative fuels and vehicle types. To date, only one manufacturer (Flex Fuel U.S.) has received EPA certifications for ethanol fuel (E85) conversion kits. This report details an independent evaluation of a vehicle with a legal installation of a Flex Fuel U.S. conversion kit. A 2006 Dodge Charger was baseline tested with ethanol-free certification gasoline (E0) and E20 (gasoline with 20 vol % ethanol), converted to flex-fuel operation via installation of a Flex Box Smart Kit from Flex Fuel U.S., and retested with E0, E20, E50, and E81. Test cycles included the Federal Test Procedure (FTP or city cycle), the highway fuel economy test (HFET), and the US06 test (aggressive driving test). Averaged test results show that the vehicle was emissions compliant on E0 in the OEM condition (before conversion) and compliant on all test fuels after conversion. Average nitrogen oxide (NOx) emissions exceeded the Tier 2/Bin 5 intermediate life NO{sub X} standard with E20 fuel in the OEM condition due to two of three test results exceeding this standard [note that E20 is not a legal fuel for non-flexible-fuel vehicles (non-FFVs)]. In addition, one E0 test result before conversion and one E20 test result after conversion exceeded the NOX standard, although the average result in these two cases was below the standard. Emissions of ethanol and acetaldehyde increased with increasing ethanol, while nonmethane organic gas and CO emissions remained relatively unchanged for all fuels and cycles. Higher fraction ethanol blends appeared to decrease NO{sub X} emissions on the FTP and HFET (after conversion). As expected, fuel economy (miles per gallon) decreased with increasing ethanol content in all cases.

  20. State of Michigan Bulletin Regarding E85 Fuel Dispensers

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    State Fire Marshal Bulletin 11 E-85 Fuel Dispensers We have become aware of the lack of an approved national standard for the dispensers and connected appurtenances involved in the dispensing of fuel, which contains more than 15% alcohol (E-85). The Michigan State Fire Code currently requires all dispensing equipment to be listed by a nationally recognized testing laboratory; however, since there is no standard, no listing can currently be placed on these systems. We have discussed this issue

  1. Wear mechanism and wear prevention in coal-fueled diesel engines. Task 7, Extended wear testing

    SciTech Connect (OSTI)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  2. Wear mechanism and wear prevention in coal-fueled diesel engines

    SciTech Connect (OSTI)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  3. Microfabricated fuel heating value monitoring device

    DOE Patents [OSTI]

    Robinson, Alex L.; Manginell, Ronald P.; Moorman, Matthew W.

    2010-05-04

    A microfabricated fuel heating value monitoring device comprises a microfabricated gas chromatography column in combination with a catalytic microcalorimeter. The microcalorimeter can comprise a reference thermal conductivity sensor to provide diagnostics and surety. Using microfabrication techniques, the device can be manufactured in production quantities at a low per-unit cost. The microfabricated fuel heating value monitoring device enables continuous calorimetric determination of the heating value of natural gas with a 1 minute analysis time and 1.5 minute cycle time using air as a carrier gas. This device has applications in remote natural gas mining stations, pipeline switching and metering stations, turbine generators, and other industrial user sites. For gas pipelines, the device can improve gas quality during transfer and blending, and provide accurate financial accounting. For industrial end users, the device can provide continuous feedback of physical gas properties to improve combustion efficiency during use.

  4. Combustion characteristics of alternative gaseous fuels

    SciTech Connect (OSTI)

    Park, O.; Veloo, Peter S.; Liu, N.; Egolfopoulos, Fokion N.

    2011-01-01

    Fundamental flame properties of mixtures of air with hydrogen, carbon monoxide, and C{sub 1}C{sub 4} saturated hydrocarbons were studied both experimentally and numerically. The fuel mixtures were chosen in order to simulate alternative gaseous fuels and to gain insight into potential kinetic couplings during the oxidation of fuel mixtures. The studies included the use of the counterflow configuration for the determination of laminar flame speeds, as well as extinction and ignition limits of premixed flames. The experiments were modeled using the USC Mech II kinetic model. It was determined that when hydrocarbons are added to hydrogen flames as additives, flame ignition, propagation, and extinction are affected in a counterintuitive manner. More specifically, it was found that by substituting methane by propane or n-butane in hydrogen flames, the reactivity of the mixture is reduced both under pre-ignition and vigorous burning conditions. This behavior stems from the fact that propane and n-butane produce higher amounts of methyl radicals that can readily recombine with atomic hydrogen and reduce thus the rate of the H + O{sub 2} ? O + OH branching reaction. The kinetic model predicts closely the experimental data for flame propagation and extinction for various fuel mixtures and pressures, and for various amounts of carbon dioxide in the fuel blend. On the other hand, it underpredicts, in general, the ignition temperatures.

  5. Optimally Controlled Flexible Fuel Powertrain System

    SciTech Connect (OSTI)

    Hakan Yilmaz; Mark Christie; Anna Stefanopoulou

    2010-12-31

    The primary objective of this project was to develop a true Flex Fuel Vehicle capable of running on any blend of ethanol from 0 to 85% with reduced penalty in usable vehicle range. A research and development program, targeting 10% improvement in fuel economy using a direct injection (DI) turbocharged spark ignition engine was conducted. In this project a gasoline-optimized high-technology engine was considered and the hardware and configuration modifications were defined for the engine, fueling system, and air path. Combined with a novel engine control strategy, control software, and calibration this resulted in a highly efficient and clean FFV concept. It was also intended to develop robust detection schemes of the ethanol content in the fuel integrated with adaptive control algorithms for optimized turbocharged direct injection engine combustion. The approach relies heavily on software-based adaptation and optimization striving for minimal modifications to the gasoline-optimized engine hardware system. Our ultimate objective was to develop a compact control methodology that takes advantage of any ethanol-based fuel mixture and not compromise the engine performance under gasoline operation.

  6. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  7. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  8. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell ...

  9. Method for sintering fuel cell electrodes using a carrier

    DOE Patents [OSTI]

    Donelson, R.; Bryson, E.S.

    1995-03-28

    A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  10. Method for sintering fuel cell electrodes using a carrier

    DOE Patents [OSTI]

    Donelson, Richard; Bryson, E. S.

    1995-01-01

    A carrier for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  11. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Design - Lessons Learned, Generic Concepts, Characteristics & Impacts Fuel Cells For Transportation - 1999 Annual Progress Report Energy Conversion Team Fuel Cell Systems ...

  12. Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE)

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tools Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... Fuel Properties Search Fuel Properties Comparison Create a custom chart

  14. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High-Octane Mid-Level Ethanol Blend Market Assessment Caley Johnson, Emily Newes, Aaron Brooker, and Robert McCormick National Renewable Energy Laboratory Steve Peterson Lexidyne, LLC Paul Leiby, Rocio Uria Martinez, and Gbadebo Oladosu Oak Ridge National Laboratory Maxwell L. Brown Colorado School of Mines Technical Report NREL/TP-5400-63698 December 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance

  15. Effect of Biodiesel Blends on NOx Emissions | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_pedersen.pdf More Documents & Publications Key Benefits in Using Ethanol-Diesel Blends Diesel Injection Shear-Stress Advanced Nozzle (DISSAN) Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration

  16. Fuel supply and control for turbocharged engines. (Latest citations from the Patent Bibliographic Database with Exemplary Claims). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The bibliography contains citations of selected patents concerning means for supplying a fuel air charge to turbocharged internal combustion engines. Adjustments and control techniques vary the fuel supply with changes in charge pressure and operating conditions. The citations generally refer to diesel and gasoline engines, but a few reference multi-fuels, such as alcohol and hydrogen additions to the primary fuel. (Contains a minimum of 137 citations and includes a subject term index and title list.)

  17. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E.

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  18. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, R.E.

    1988-03-08

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

  19. Alternative Fuels Data Center: Hydrogen Fueling Infrastructure Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling

  20. Catalyst for producing lower alcohols

    DOE Patents [OSTI]

    Rathke, Jerome W.; Klingler, Robert J.; Heiberger, John J.

    1987-01-01

    A process and system for the production of the lower alcohols such as methanol, ethanol and propanol involves the reaction of carbon monoxide and water in the presence of a lead salt and an alkali metal formate catalyst combination. The lead salt is present as solid particles such as lead titanate, lead molybdate, lead vanadate, lead zirconate, lead tantalate and lead silicates coated or in slurry within molten alkali metal formate. The reactants, carbon monoxide and steam are provided in gas form at relatively low pressures below 100 atmospheres and at temperatures of 200-400.degree. C. The resulted lower alcohols can be separated into boiling point fractions and recovered from the excess reactants by distillation.

  1. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  2. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  3. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  4. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  5. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  6. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Seminar Orlando, FL Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 1112011 2 | Fuel Cell Technologies Program Source: US ...

  7. Review Of Rheology Models For Hanford Waste Blending

    SciTech Connect (OSTI)

    Koopman, D. C.; Stone, M.

    2013-09-26

    The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations are not necessarily satisfactory (justified) for interpolations, due to the number of unknown variables equal the number of known data points, resulting in a coefficient of determination of one. SRS has had some success predicting the rheology of waste blends for similar waste types using rheological properties of the individual wastes and empirical blending viscosity equations. Both the Kendall-Monroe and Olney-Carlson equations were used. High accuracy was not obtained, but predictions were reasonable compared to measured flow curves. Blending SRS processed waste with frit slurry (much larger particles and the source of SRS glass formers) is a different sort of problem than that of two similar slurries of precipitated waste particles. A different approach to rheology prediction has had some success describing the incorporation of large frit particles into waste than the one used for blending two wastes. In this case, the Guth-Simha equation was used. If Hanford waste is found to have significant particles in the >100 μm diameter range, then it might be necessary to handle those particles differently from broadly distributed waste particles that are primarily <30 μm in diameter. The following are recommendations for the Hanford tank farms: Investigate the impact of large-scale mixing operations on yield stress for one or more Hanford tanks to see if Hanford waste rheological properties change to become more like SRS waste during both tank retrieval and tank qualification operations; Determine rheological properties of mobilized waste slurries by direct measurement rather than by prediction; Collect and characterize samples during the waste feed qualification process for each campaign; o From single source tanks that feed the qualification tanks; o Blends from the qualification tanks; Predictive rheological models must be used with caution, due to the lack of data to support such models and the utilization of the results that come from these models in making process decisions (e.g. the lack of actual operation experience). As experience is gained, the use of blending models that have been validated with real waste may become useful to predict future blends; Obtain more data measurements to check the validity of unknown coefficients for a given blending equation.

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Mid-level Ethanol Blend Retailer Tax Credit Retail stations dispensing mid-level blends of ethanol in gasoline between 15% (E15) up to 69% (E69) for use in motor vehicles may be eligible for a tax credit. Credit amounts vary by date: September 16 through May 31 the credit is equal to $0.03 per gallon and June 1 through September 15 the credit is equal to $0.10 per gallon. The tax credit expires December 31, 2017. Eligible taxpayers may also claim the Ethanol Blend Retailer Tax Credit for the

  9. Emissions from Buses with DDC 6V92 Engines Using Synthetic Diesel Fuel

    SciTech Connect (OSTI)

    Paul Norton; Keith Vertin; Nigel N. Clark; Donald W. Lyons; Mridul Gautam; Stephen Goguen; James Eberhardt

    1999-05-03

    Synthetic diesel fuel can be made from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, synthetic diesel fuels may also economically competitive with California diesel fuel if .roduced in large volumes. Previous engine laboratory and field tests using a heavy-duty chassis dynamometer indicate that synthetic diesel fuel made using the Fischer-Tropsch (F-T) catalytic conversion process is a promising alternative fuel, because it can be used in unmodified diesel engines, and can reduce exhaust emissions substantially. The objective of this study was a preliminary assessment of the emissions from older model transit operated on Mossgas synthetic diesel fuel. The study compared emissions from transit buses operating on Federal no. 2 Diesel fuel, Mossgas synthetic diesel (MGSD), and a 50/50 blend of the two fuels. The buses were equipped with unmodified Detroit Diesel 6V92 2-stroke diesel engines. Six 40-foot buses were tested. Three of the buses had recently rebuilt engines and were equipped with an oxidation catalytic converter. Vehicle emissions measurements were performed using West Virginia University's unique transportable chassis dynamometer. The emissions were measured over the Central Business District (CBD) driving cycle. The buses performed well on both neat and blended MGSD fuel. Three buses without catalytic converters were tested. Compared to their emissions when operating on Federal no. 2 diesel fuel, these buses emitted an average of 5% lower oxides of nitrogen (NOx) and 20% lower particulate matter (PM) when operating on neat MGSD fuel. Catalyst equipped buses emitted an average of 8% lower NOx and 31% lower PM when operating on MGSD than when operating on Federal no. 2 diesel fuel.

  10. Analysis of Underground Storage Tanks System Materials to Increased Leak Potential Associated with E15 Fuel

    SciTech Connect (OSTI)

    Kass, Michael D; Theiss, Timothy J; Janke, Christopher James; Pawel, Steven J

    2012-07-01

    The Energy Independence and Security Act (EISA) of 2007 was enacted by Congress to move the nation toward increased energy independence by increasing the production of renewable fuels to meet its transportation energy needs. The law establishes a new renewable fuel standard (RFS) that requires the nation to use 36 billion gallons annually (2.3 million barrels per day) of renewable fuel in its vehicles by 2022. Ethanol is the most widely used renewable fuel in the US, and its production has grown dramatically over the past decade. According to EISA and RFS, ethanol (produced from corn as well as cellulosic feedstocks) will make up the vast majority of the new renewable fuel requirements. However, ethanol use limited to E10 and E85 (in the case of flex fuel vehicles or FFVs) will not meet this target. Even if all of the E0 gasoline dispensers in the country were converted to E10, such sales would represent only about 15 billion gallons per year. If 15% ethanol, rather than 10% were used, the potential would be up to 22 billion gallons. The vast majority of ethanol used in the United States is blended with gasoline to create E10, that is, gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85, a gasoline blend with as much as 85% ethanol that can only be used in FFVs. Although DOE remains committed to expanding the E85 infrastructure, that market will not be able to absorb projected volumes of ethanol in the near term. Given this reality, DOE and others have begun assessing the viability of using intermediate ethanol blends as one way to transition to higher volumes of ethanol. In October of 2010, the EPA granted a partial waiver to the Clean Air Act allowing the use of fuel that contains up to 15% ethanol for the model year 2007 and newer light-duty motor vehicles. This waiver represents the first of a number of actions that are needed to move toward the commercialization of E15 gasoline blends. On January 2011, this waiver was expanded to include model year 2001 light-duty vehicles, but specifically prohibited use in motorcycles and off-road vehicles and equipment. UST stakeholders generally consider fueling infrastructure materials designed for use with E0 to be adequate for use with E10, and there are no known instances of major leaks or failures directly attributable to ethanol use. It is conceivable that many compatibility issues, including accelerated corrosion, do arise and are corrected onsite and, therefore do not lead to a release. However, there is some concern that higher ethanol concentrations, such as E15 or E20, may be incompatible with current materials used in standard gasoline fueling hardware. In the summer of 2008, DOE recognized the need to assess the impact of intermediate blends of ethanol on the fueling infrastructure, specifically located at the fueling station. This includes the dispenser and hanging hardware, the underground storage tank, and associated piping. The DOE program has been co-led and funded by the Office of the Biomass Program and Vehicle Technologies Program with technical expertise from the Oak Ridge National Laboratory (ORNL) and the National Renewable Energy Laboratory (NREL). The infrastructure material compatibility work has been supported through strong collaborations and testing at Underwriters Laboratories (UL). ORNL performed a compatibility study investigating the compatibility of fuel infrastructure materials to gasoline containing intermediate levels of ethanol. These results can be found in the ORNL report entitled Intermediate Ethanol Blends Infrastructure Materials Compatibility Study: Elastomers, Metals and Sealants (hereafter referred to as the ORNL intermediate blends material compatibility study). These materials included elastomers, plastics, metals and sealants typically found in fuel dispenser infrastructure. The test fuels evaluated in the ORNL study were SAE standard test fuel formulations used to assess material-fuel compatibility within a relatively short timeframe. Initially, these material studies included test fuels of Fuel C, CE10a, CE17a, and CE25a. The CE17a test fuel was selected to represent E15 since surveys have shown that the actual ethanol upper limit can be as high as 17%. Later, CE50a and CE85a test fuels were added to the investigation and these results are being compiled for a follow-on report to be published in 2012. Fuel C was used as the baseline reference and is a 50:50 blend of isooctane and toluene. This particular composition was used to represent premium-grade gasoline and was also used as the base fuel for the ethanol blends, where it is denoted by 'C' in the fuel name. The level of ethanol is represented by the number following the letter E. Therefore a 10% blend of ethanol in Fuel C is written as CE10a, where 'a' represents an aggressive formulation of the ethanol that contains water, NaCl, acetic and sulfuric acids per the SAE J1681 protocol.

  11. FUEL INTERCHANGEABILITY FOR LEAN PREMIXED COMBUSTION IN GAS TURBINE ENGINES

    SciTech Connect (OSTI)

    Don Ferguson; Geo. A. Richard; Doug Straub

    2008-06-13

    In response to environmental concerns of NOx emissions, gas turbine manufacturers have developed engines that operate under lean, pre-mixed fuel and air conditions. While this has proven to reduce NOx emissions by lowering peak flame temperatures, it is not without its limitations as engines utilizing this technology are more susceptible to combustion dynamics. Although dependent on a number of mechanisms, changes in fuel composition can alter the dynamic response of a given combustion system. This is of particular interest as increases in demand of domestic natural gas have fueled efforts to utilize alternatives such as coal derived syngas, imported liquefied natural gas and hydrogen or hydrogen augmented fuels. However, prior to changing the fuel supply end-users need to understand how their system will respond. A variety of historical parameters have been utilized to determine fuel interchangeability such as Wobbe and Weaver Indices, however these parameters were never optimized for todays engines operating under lean pre-mixed combustion. This paper provides a discussion of currently available parameters to describe fuel interchangeability. Through the analysis of the dynamic response of a lab-scale Rijke tube combustor operating on various fuel blends, it is shown that commonly used indices are inadequate for describing combustion specific phenomena.

  12. Assessment for advanced fuel cycle options in CANDU

    SciTech Connect (OSTI)

    Morreale, A.C.; Luxat, J.C.; Friedlander, Y.

    2013-07-01

    The possible options for advanced fuel cycles in CANDU reactors including actinide burning options and thorium cycles were explored and are feasible options to increase the efficiency of uranium utilization and help close the fuel cycle. The actinide burning TRUMOX approach uses a mixed oxide fuel of reprocessed transuranic actinides from PWR spent fuel blended with natural uranium in the CANDU-900 reactor. This system reduced actinide content by 35% and decreased natural uranium consumption by 24% over a PWR once through cycle. The thorium cycles evaluated used two CANDU-900 units, a generator and a burner unit along with a driver fuel feedstock. The driver fuels included plutonium reprocessed from PWR, from CANDU and low enriched uranium (LEU). All three cycles were effective options and reduced natural uranium consumption over a PWR once through cycle. The LEU driven system saw the largest reduction with a 94% savings while the plutonium driven cycles achieved 75% savings for PWR and 87% for CANDU. The high neutron economy, online fuelling and flexible compact fuel make the CANDU system an ideal reactor platform for many advanced fuel cycles.

  13. SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS

    Office of Scientific and Technical Information (OSTI)

    PRODUCTION WITH ILLINOIS COAL (Other) | SciTech Connect Other: SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL Citation Details In-Document Search Title: SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three

  14. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel cells are the most energy efficient devices for extracting power from fuels. Capable of running on a variety of fuels, including hydrogen, natural gas, and biogas, fuel cells ...

  15. California Fuel Cell Partnership: Alternative Fuels Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    provides information about alternative fuels research. PDF icon cafcpinitiativescall.pdf More Documents & Publications The Department of Energy Hydrogen and Fuel Cells Program ...

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Prohibition of the Sale of Ethanol-Blended Gasoline A person or distributor may not offer, sell, or distribute gasoline that contains ethanol at a level greater than 10% (E10) or...

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    the business' or individual's total diesel sales within three years of the initial credit. ... The credit can be claimed up to two tax years before the taxpayer begins blending ...

  18. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engines | Department of Energy Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines June 22, 2015 - 4:39pm Addthis The U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy's Bioenergy Technologies Office has released a Request for Information (RFI) seeking stakeholder input on the following topics related to the use of advanced biofuel blends in small engines:

  19. Electronic and structural characteristics of zinc-blende wurtzite biphasic homostructure GaN nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jacobs, Benjamin W.; Ayres, Virginia M.; Petkov, Mihail P.; Halpern, Joshua B.; He, Maoqi; Baczewski, Andrew D.; McElroy, Kaylee; Crimp, Martin A.; Zhang, Jiaming; Shaw, Harry C.

    2016-02-01

    Here, we report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High-resolution transmission electron microscopy was used to identify distinct wurtzite and zinc-blende crystalline phases within single nanowires through the use of selected area electron diffraction, electron dispersive spectroscopy, electron energy loss spectroscopy, and fast Fourier transform techniques. A mechanism for growth is identified.

  20. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel ...

  1. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    IMPACT OF LOW OCTANE HYDROCARBON BLENDING STREAMS ON "E85" ENGINE OPTIMIZATION Jim Szybist ... Year ETHANOL IS CURRENTLY THE LARGEST VOLUME BIOFUEL, VERY IMPORTANT FOR EISA COMPLIANCE * ...

  2. Determining the Impact of MSW as a Feedstock Blending Agent Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Oral Presentation for 11th Annual World Congress on Industrial Biotechnology. May 12-15, ... from optimal blends and process on fermentation to determine any negative (or ...

  3. Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Infrastructure

  4. Alternative Fuels Data Center: Propane Fueling Infrastructure Development

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Propane Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Propane Fueling Infrastructure

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two different co-processed fuel oils were tested: one that had been partially hydrotreated, and the other a product of fractionation before hydrotreating. Task 5 focused on examining refining methods that would utilize coal and produce thermally stable jet fuel, included delayed coking and solvent extraction. Delayed coking was done on blends of decant oil and coal, with the goal to produce a premium carbon product and liquid fuels. Coking was done on bench scale and large laboratory scale cokers. Two coals were examined for co-coking, using Pittsburgh seam coal and Marfork coal product. Reactions in the large, laboratory scaled coker were reproducible in yields of products and in quality of products. While the co-coke produced from both coals was of sponge coke quality, minerals left in the coke made it unacceptable for use as anode or graphite grade filler.

  6. Alternative Fuels Data Center: Filling CNG Fuel Tanks

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Filling CNG Fuel Tanks to someone by E-mail Share Alternative Fuels Data Center: Filling CNG Fuel Tanks on Facebook Tweet about Alternative Fuels Data Center: Filling CNG Fuel Tanks on Twitter Bookmark Alternative Fuels Data Center: Filling CNG Fuel Tanks on Google Bookmark Alternative Fuels Data Center: Filling CNG Fuel Tanks on Delicious Rank Alternative Fuels Data Center: Filling CNG Fuel Tanks on Digg Find More places to share Alternative Fuels Data Center: Filling CNG Fuel Tanks on

  7. Alternative Fuels Data Center: Natural Gas Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  8. Alternative Fuels Data Center: Natural Gas Fuel Safety

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Safety to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Fuel Safety on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Fuel Safety on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Fuel Safety on Google Bookmark Alternative Fuels Data Center: Natural Gas Fuel Safety on Delicious Rank Alternative Fuels Data Center: Natural Gas Fuel Safety on Digg Find More places to share Alternative Fuels Data Center: Natural Gas Fuel Safety on

  9. The potential for alcohols and related ethers to displace conventional gasoline components

    SciTech Connect (OSTI)

    Hadder, G.R.; McNutt, B.D.

    1996-02-01

    The United States Department of Energy is required by law to determine the feasibility of producing sufficient replacement fuels to replace 30 percent of the projected United States consumption of motor fuels by light duty vehicles in the year 2010. A replacement fuel is a non-petroleum portion of gasoline, including alcohols, natural gas and certain other components. A linear program has been used to study refinery impacts for production of ``low petroleum`` gasolines, which contain replacement fuels. The analysis suggests that high oxygenation is the key to meeting the replacement fuel target, and major contributors to cost increase can include investment in processes to produce olefins for etherification with alcohols. High oxygenation can increase the costs of control of vapor pressure, distillation properties, and pollutant emissions of gasolines. Year-round low petroleum gasoline with near-30 percent non-petroleum might be produced with cost increases of 23 to 37 cents per gallon, with substantial decreases in greenhouse gas emissions in some cases. Cost estimates are sensitive to assumptions about extrapolation of a national model for pollutant emissions, availability of raw materials and other issues. Reduction in crude oil use, a major objective of the low petroleum gasoline program, is 10 to 17 percent in the analysis.

  10. Synthetic fuels

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    In January 1982, the Department of Energy guaranteed a loan for the construction and startup of the Great Plains project. On August 1, 1985, the partnership defaulted on the $1.54 billion loan, and DOE acquired control of, and then title to, the project. DOE continued to operate the plant, through the ANG Coal Gasification Company, and sell synthetic fuel. The DOE's ownership and divestiture of the plant is discussed.

  11. Formation of alcohol conversion catalysts

    DOE Patents [OSTI]

    Wachs, Israel E.; Cai, Yeping

    2001-01-01

    The method of the present invention involves a composition containing an intimate mixture of (a) metal oxide support particles and (b) a catalytically active metal oxide from Groups VA, VIA, or VIIA, its method of manufacture, and its method of use for converting alcohols to aldehydes. During the conversion process, catalytically active metal oxide from the discrete catalytic metal oxide particles migrates to the oxide support particles and forms a monolayer of catalytically active metal oxide on the oxide support particle to form a catalyst composition having a higher specific activity than the admixed particle composition.

  12. Geothermal source potential and utilization for methane generation and alcohol production

    SciTech Connect (OSTI)

    Austin, J.C.

    1981-11-01

    A study was conducted to assess the technical and economic feasibility of integrating a geothermally heated anaerobic digester with a fuel alcohol plant and cattle feedlot. Thin stillage produced from the alcohol production process and manure collected from the cattle feedlot would be digested in anaerobic digesters to produce biogas, a mixture of methane and carbon dioxide, and residue. The energy requirements to maintain proper digester temperatures would be provided by geothermal water. The biogas produced in the digesters would be burned in a boiler to produce low-pressure steam which would be used in the alcohol production process. The alcohol plant would be sized so that the distiller's grains byproduct resulting from the alcohol production would be adequate to supply the daily cattle feed requirements. A portion of the digester residue would substitute for alfalfa hay in the cattle feedlot ration. The major design criterion for the integrated facilty was the production of adequate distiller's grain to supply the daily requirements of 1700 head of cattle. It was determined that, for a ration of 7 pounds of distiller's grain per head per day, a 1 million gpy alcohol facility would be required. An order-of-magnitude cost estimate was prepared for the proposed project, operating costs were calculated for a facility based on a corn feedstock, the economic feasibility of the proposed project was examined by calculating its simple payback, and an analysis was performed to examine the sensitivity of the project's economic viability to variations in feedstock costs and alcohol and distiller's grain prices.

  13. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  14. On-farm production of soybean oil and its properties as a fuel

    SciTech Connect (OSTI)

    Suh, S.R.

    1983-01-01

    This study presents the design of a system for on-farm production of soybean oil for use as a fuel in compression ignition engines. The soybean oil production system consists of a heat exchanger to heat the beans with the exhaust gas of an engine, a screw press and a system for water degumming and drying the expressed crude oil. Optimum parameters of the oil production system were found. The rheological properties of soybean oil, ester of soybean oil and blends of the above with diesel fuel and diesel fuel additives are given. Data on soybean temperature, outlet gas temperature and thermal efficiency were obtained from a developed mathematical model of the heat exchanger. Chemical analyses show that crude oil from the press is similar to that of commercially degummed oil. The degumming process is not needed for the crude oil to be used as a fuel in compression ignition engines. Rheological properties of the soybean oil and soybean oil diesel fuel mixture show that the fluids have viscosities of time independent characteristics and are Newtonian fluids. Diesel fuel additives having low viscosities can be used to lower the viscosity of soybean oil and blends with diesel fuel but the effect is insignificant.

  15. Engineered fuel: Renewable fuel of the future?

    SciTech Connect (OSTI)

    Tomczyk, L.

    1997-01-01

    The power generation and municipal solid waste management industries share an interest in the use of process engineered fuel (PEF) comprised mainly of paper and plastics as a supplement to conventional fuels. PEF is often burned in existing boilers, making PEF an alternative to traditional refuse derived fuels (RDF). This paper describes PEF facilities and makes a comparison of PEF and RDF fuels.

  16. Table A1: Tank Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    A1: Tank Manufacturer Compatibility with Ethanol Blends E10 E100 E10 E100 Manufacturer ✔ ✔ Continued from below FIBERGLASS a Highland Tank ✔ ✔ Containment Solutions ✔ ✔ J.L. Houston Co. ✔ ✔ Owens Corning (single wall 1965-1994) ✔ ✘ Kennedy Tank and Manufacturing Co., Inc. ✔ ✔ Owens Corning (double wall 1965- July 1, 1990) ✔ ✘ Lancaster Tanks and Steel Products ✔ ✔ Owens Corning (double wall July 2, 1990-December 31, 1994) ✔ ✔ Lannon Tank Corporation ✔ ✔

  17. Hydrogen effects on materials for CNG/H2 blends.

    SciTech Connect (OSTI)

    Farese, David; Keller, Jay O.; Somerday, Brian P.

    2010-09-01

    No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

  18. Production of alcohol from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.; Lee, C.Y.; Woodams, E.E.; Cooley, H.J.

    1981-12-01

    Production of ethyl alcohol from apple pomace with a Montrachet strain of Saccharomyces cerevisiae is described. More than 43 grams of the ethyl alcohol could be produced per kg of apple pomace fermented at 30 degrees Celcius in 24 hours. The fermentation efficiency of this process was approximately 89%. (Refs. 9).

  19. Alternative Fuels Data Center: Fuel Cell Electric Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Cell Electric Vehicles to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Google Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Delicious Rank Alternative Fuels Data Center: Fuel

  20. Alternative Fuels Data Center: Strategies to Conserve Fuel

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Strategies to Conserve Fuel to someone by E-mail Share Alternative Fuels Data Center: Strategies to Conserve Fuel on Facebook Tweet about Alternative Fuels Data Center: Strategies to Conserve Fuel on Twitter Bookmark Alternative Fuels Data Center: Strategies to Conserve Fuel on Google Bookmark Alternative Fuels Data Center: Strategies to Conserve Fuel on Delicious Rank Alternative Fuels Data Center: Strategies to Conserve Fuel on Digg Find More places to share Alternative Fuels Data Center:

  1. Alternative Fuels Data Center: Natural Gas Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  2. Alternative Fuels Data Center: Test Your Alternative Fuel IQ

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Test Your Alternative Fuel IQ to someone by E-mail Share Alternative Fuels Data Center: Test Your Alternative Fuel IQ on Facebook Tweet about Alternative Fuels Data Center: Test Your Alternative Fuel IQ on Twitter Bookmark Alternative Fuels Data Center: Test Your Alternative Fuel IQ on Google Bookmark Alternative Fuels Data Center: Test Your Alternative Fuel IQ on Delicious Rank Alternative Fuels Data Center: Test Your Alternative Fuel IQ on Digg Find More places to share Alternative Fuels Data

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Local Examples Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local Examples

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Incentives Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local Examples

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Federal Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local Examples Summary

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    State Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local Examples Summary

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tools Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... Truckstop Electrification Truck Stop Electrification Locator Locate

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... Vehicle and Infrastructure Cash-Flow Evaluation Model VICE 2.0: Vehicle

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Vehicle (AFV) Decal The state motor fuel tax does not apply to passenger vehicles, certain buses, or commercial vehicles that are powered by an alternative fuel, if they obtain an AFV decal. Owners or operators of such vehicles that also own or operate their own personal fueling stations are required to pay an annual alternative fuel decal fee, as listed below. Motor vehicles licensed as historic vehicles that are powered by alternative fuels are exempt from the motor fuels tax

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition and Specifications Alternative fuels include biofuel, ethanol, methanol, hydrogen, coal-derived liquid fuels, electricity, natural gas, propane gas, or a synthetic transportation fuel. Biofuel is defined as a renewable, biodegradable, combustible liquid or gaseous fuel derived from biomass or other renewable resources that can be used as transportation fuel, combustion fuel, or refinery feedstock and that meets ASTM specifications and federal quality requirements for

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Incentives Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local Examples

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Incentives » Federal Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... More in this section... Search Federal State Local

  13. Process for the synthesis of unsaturated alcohols

    DOE Patents [OSTI]

    Maughon, Bob R.; Burdett, Kenneth A.; Lysenko, Zenon

    2007-02-13

    A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.

  14. STEP 1: TO BE COMPLETED BY ALCOHOL TECHNICIAN

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Human Reliability Program (HRP) Alcohol Testing Form (Instructions for completing this form are attached.) STEP 1: TO BE COMPLETED BY ALCOHOL TECHNICIAN A. Employee Name ...

  15. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via ...

  16. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis ...

  17. Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

    SciTech Connect (OSTI)

    Merritt, P. M.; Ulmet, V.; McCormick, R. L.; Mitchell, W. E.; Baumgard, K. J.

    2005-11-01

    Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent). Benzene emissions were reduced by up to 50 percent with the ethanol-blended fuels. Emissions of 1,3-butadiene were also substantially decreased, with reductions ranging from 24 to 82 percent. Isolated trends were noted for certain PAHs. There was a decrease in 1-nitropyrene with use of ethanol in all cases. Particulate phase 1-nitropyrene was reduced from 18 to 62 percent. There was also a general increase in the proportion of heavy PAHs in the particulate phase with ethanol use, and although less pronounced, a general decrease in light PAHs in the particulate phase.

  18. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethylether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operation in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges have continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. As of late June 2002, it appears that the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head is being installed on the system to alleviate this problem and get the shuttle bus back in operation. In summary, the conversion is completed but there have been operational challenges in the field. They continue to work to make the shuttle bus as reliable to operate on DME-diesel blends as possible.

  19. The Effects of Fuel Characteristics on Stoichiometric Spark-Assisted HCCI

    SciTech Connect (OSTI)

    Weall, Adam J; Szybist, James P

    2011-01-01

    The characteristics of fuel lean HCCI operation using a variety of fuels are well known and have been demonstrated using different engine concepts in the past. In contrast, stoichiometric operation of HCCI is less well documented. Recent studies have highlighted the benefits of operating at a stoichiometric condition in terms of load expansion combined with the applicability of three way catalyst technology to reduce NOx emissions. In this study the characterization of stoichiometric HCCI using gasoline-like fuels was undertaken. The fuels investigated are gasoline, a 50 vol% blend of iso-butanol and gasoline (IB50), and an 85% vol blend of ethanol and gasoline (E85). A single cylinder engine operating with direct injection and spark assist combined with a fully variable hydraulic valve actuation system allowed a wide range of operating parameters to be studied. This included the effects of negative valve overlap duration, intake valve closing and valve lift. Furthermore, the interaction between fuel injection timing and spark and how they can affect the required valve timing to achieve stoichiometric HCCI combustion are also studied. A comprehensive combustion and emissions analysis is conducted using gasoline, IB50 and E85 at an engine speed of 2000rpm over a range of operating loads. The resultant fuel properties which differed in terms of octane rating, fuel oxygenation and heat of vaporization show that stoichiometric HCCI is possible using a range of fuels but that these fuel characteristics do have some effect on the combustion characteristics. How these fuel properties can enable an increased engine operating envelope to be achieved, in comparison with both fuel lean HCCI and conventional spark ignited combustion, is then discussed.

  20. Hydrogen Fueling for Current and Anticipated Fuel Cell Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Download presentation slides from the DOE Fuel Cell Technologies Office webinar "Hydrogen Fueling ...