National Library of Energy BETA

Sample records for al mo mn

  1. Role of Ce<mn>4mn>+> in the scintillation mechanism of codoped Gd<mn>3mn>Ga<mn>3mn>Al>2mn>O<mn>12mn>:>Ce

    SciTech Connect (OSTI)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12?Ce?(GGAG?Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-level diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.

  2. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Gilli, Adrian

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  3. Magnetic cluster excitations in the antiferromagnetic phase of a-MnMoO4 

    E-Print Network [OSTI]

    Ochsenbein, Stefan T; Chaboussant, Gregory; Sieber, Andreas; Gudel, Hans U; Janssen, Stefan; Furrer, Albert; Attfield, J. Paul

    2003-01-01

    The tetramer-based compound a-MnMoO4 exhibits four prominent peaks in the inelastic neutron scattering (INS) spectrum between 0.5 and 2.0 meV below 10 K. They are assigned to magnetic excitations of the (Mn2+)4 rhombus ...

  4. Solution-based thermodynamic modeling of the Ni-Al-Mo system...

    Office of Scientific and Technical Information (OSTI)

    (Al,Mo,Ni)0.75(Al,Mo,Ni)0.25. Thus, -fcc and -Ni3Al are modeled with a single Gibbs free energy function with appropriate treatment of the chemical ordering contribution. In...

  5. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83?B/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ? 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility ? is anisotropic below 20 K, with a maximum ratio of ?[010]/?[001] ? 3.5. A strong power-lawmore »divergence ?(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.« less

  6. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    SciTech Connect (OSTI)

    Dhital, Chetan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Huq, Ashfia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Paranthaman, Mariappan Parans [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Manivannan, Ayyakkannu [National Energy Technology Lab. (NETL), Morgantown, WV (United States); West Virginia Univ., Morgantown, WV (United States); Torres-Castro, Loraine [Univ. of Puerto Rico, San Juan (Puerto Rico); Shojan, Jifi [Univ. of Puerto Rico, San Juan (Puerto Rico); Julien, Christian M. [Univ. Pierre et Marie Curie, Paris (France); Katiyar, Ram S. [Univ. of Puerto Rico, San Juan (Puerto Rico)

    2015-01-01

    Li?MnO? is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li?MnO?, Li1.5Al0.17MnO?, Li1.0Al0.33MnO? and Li0.5Al0.5MnO? were synthesized by a sol-gel Pechini method. All the samples were characterized with XRD, Raman, XPS, SEM, Tap density and BET analyzer. XRD patterns indicated the presence of monoclinic phase for pristine Li?MnO? and mixed monoclinic/spinel phases (Li2-xMn1-yAlx+yO3+z) for Al-substituted Li?MnO? compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. XPS analysis for Mn 2p orbital reveal a significant decrease in binding energy for Li1.0Al0.33MnO? and Li0.5Al0.5MnO? compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g?¹ for Li?MnO?, 68mAh g?¹ for Li1.5Al0.17MnO?, 58 mAh g?¹ for Li1.0Al0.33MnO? and 74 mAh g?¹ for Li0.5Al0.5MnO? were obtained. Aluminum substitutions increased the discharge capacity and the spinel phase.

  7. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectronmore »spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. Aluminum substitutions increased the formation of spinel phase which is responsible for cycling.« less

  8. Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures

    E-Print Network [OSTI]

    Ruan, Shiyun

    Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

  9. Manganese valence and coordination structure in Mn,Mg-codoped {gamma}-AlON green phosphor

    SciTech Connect (OSTI)

    Takeda, Takashi; Xie, Rong-Jun; Hirosaki, Naoto; Matsushita, Yoshitaka; Honma, Tetuso

    2012-10-15

    The valence and coordination structure of manganese in a Mn,Mg-codoped {gamma}-AlON spinel-type oxynitride green phosphor were studied by synchrotron X-ray diffraction and absorption fine structure measurements. The absorption edge position of the XANES revealed the bivalency of Mn. Two cation sites are available in the spinel structure for cation doping: a tetrahedral site and an octahedral site. The pre-edge of the XANES and the distance to the nearest neighbor atoms obtained from the EXAFS measurement showed that Mn was situated at the tetrahedral site. Rietveld analysis showed that the vacancy occupied the octahedral site. The preferential occupation of the tetrahedral site by Mn and the roles of N and Mg are discussed in relation to the spinel crystal structure. - Graphical Abstract: Fourier transform of EXAFS of Mn K-edge for Mn,Mg-codoped green phosphor and Mn coordination structure. Highlights: Black-Right-Pointing-Pointer Mn, Mg-codoped {gamma}-AlON green phosphor for white LED. Black-Right-Pointing-Pointer The valence of Mn is divalent. Black-Right-Pointing-Pointer Mn occupies the tetrahedral site in the spinel structure.

  10. Activity and structure of hydrotreating Ni, Mo, and Ni-Mo sulfide catalysts supported on {gamma}-Al{sub 2}O{sub 3}--USY zeolite

    SciTech Connect (OSTI)

    Li, D.; Nishijima, A.; Morris, D.E.; Guthrie, G.D.

    1999-11-15

    The catalytic hydrocracking (HC) of diphenylmethane (DPM) and hydrodesulfurization (HDS) of dibenzothiophene (DBT) over Ni, Mo, and Ni-Mo sulfide catalysts supported on a mixed ultrastable Y (USY) zeolite and gamma-Al{sub 2}O{sub 3} were studied. The catalysts were characterized using NH{sub 3} temperature-programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR diffuse reflectance spectroscopy (DRS), high-resolution transmission electron microscopy (HRTEM), and chemical composition analysis. Because addition of zeolite to a conventional alumina support improves acidity, Ni, Mo, and Ni-Mo catalysts supported on the combined supports had much higher HC activity. Ni was found to be uniformly distributed throughout the catalysts; however, Mo preferentially entered the structure of {gamma}-Al{sub 2}O{sub 3} or was accommodated as oxide aggregates on {gamma}-Al{sub 2}O{sub 3}, rather than associating with zeolite. Ni and Mo catalysts supported on {gamma}-Al{sub 2}O{sub 3}-USY zeolite were good HDS catalysts and showed a shallow maximum in catalytic activity at a NiO and MoO{sub 3} content of 5 mol%. The higher activity at this content occurred because Ni or Mo species had higher surface concentrations, higher dispersion, and were more easily sulfided. Ni-Mo catalysts supported on {gamma}-Al{sub 2}O{sub 3}-USY zeolite had high HDS activity, which showed a prominent maximum at a NiO/(NiO + MoO{sub 3}) ratio of about 0.4, because at this ratio the surface species of Ni and Mo were well dispersed and more easily sulfided to form a Ni-Mo-S phase responsible for the high HDS activity. The Ni-Mo catalysts supported on gamma-Al{sub 2}O{sub 3}-USY zeolite have slightly higher HDS activity than {gamma}-Al{sub 2}O{sub 3}-USY zeolite have slightly higher HDS activity than {gamma}-Al{sub 2}O{sub 3}-supported Ni-Mo catalysts.

  11. FeAl and Mo-Si-B Intermetallic Coatings Prepared by Thermal Spraying

    SciTech Connect (OSTI)

    Totemeier, T.C.; Wright, R.N.; Swank, W.D.

    2003-04-22

    FeAl and Mo-Si-B intermetallic coatings for elevated temperature environmental resistance were prepared using high-velocity oxy-fuel (HVOF) and air plasma spray (APS) techniques. For both coating types, the effect of coating parameters (spray particle velocity and temperature) on the microstructure and physical properties of the coatings was assessed. Fe-24Al (wt.%) coatings were prepared using HVOF thermal spraying at spray particle velocities varying from 540 m/s to 700 m/s. Mo-13.4Si-2.6B coatings were prepared using APS at particle velocities of 180 and 350 m/s. Residual stresses in the HVOF FeAl coatings were compressive, while stresses in the APS Mo-Si-B coatings were tensile. In both cases, residual stresses became more compressive with increasing spray particle velocity due to increased peening imparted by the spray particles. The hardness and elastic moduli of FeAl coatings also increased with increasing particle velocity, again due to an increased peening effect. For Mo-Si-B coatings, plasma spraying at 180 m/s resulted in significant oxidation of the spray particles and conversion of the T1 phase into amorphous silica and {alpha}-Mo. The T1 phase was retained after spraying at 350 m/s.

  12. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 – 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea’s KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  13. Improved performance of U-Mo dispersion fuel by Si addition in Al matrix.

    SciTech Connect (OSTI)

    Kim, Y S; Hofman, G L [Nuclear Engineering Division

    2011-06-01

    The purpose of this report is to collect in one publication and fit together work fragments presented in many conferences in the multi-year time span starting 2002 to the present dealing with the problem of large pore formation in U-Mo/Al dispersion fuel plates first observed in 2002. Hence, this report summarizes the excerpts from papers and reports on how we interpreted the relevant results from out-of-pile and in-pile tests and how this problem was dealt with. This report also provides a refined view to explain in detail and in a quantitative manner the underlying mechanism of the role of silicon in improving the irradiation performance of U-Mo/Al.

  14. Perpendicularly magnetized {tau}-MnAl (001) thin films epitaxied on GaAs

    SciTech Connect (OSTI)

    Nie, S. H.; Zhu, L. J.; Lu, J.; Pan, D.; Wang, H. L.; Yu, X. Z.; Xiao, J. X.; Zhao, J. H.

    2013-04-15

    Perpendicularly magnetized {tau}-MnAl films have been epitaxied on GaAs (001) by molecular-beam epitaxy. Crystalline quality and magnetic properties of the samples were strongly dependent on growth temperature. The highest coercivity of 10.7 kOe, saturation magnetization of 361.4 emu/cm{sup 3}, perpendicular magnetic anisotropy constant of 13.65 Merg/cm{sup 3}, and magnetic energy product of 4.44 MGOe were achieved. These tunable magnetic properties make MnAl films valuable as excellent and cost-effective alternative for not only high density perpendicular magnetic recording storage and spintronics devices but also permanent magnets.

  15. First-principles study of spin-transfer torque in Co{sub 2}MnSi/Al/Co{sub 2}MnSi spin-valve

    SciTech Connect (OSTI)

    Tang, Ling, E-mail: lingtang@zjut.edu.cn; Yang, Zejin, E-mail: zejinyang@zjut.edu.cn [Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China)

    2013-11-21

    The spin-transfer torque (STT) in Co{sub 2}MnSi(CMS)/Al/Co{sub 2}MnSi spin-valve system with and without interfacial disorder is studied by a first-principles noncollinear wave-function-matching method. It is shown that in the case of clean interface the angular dependence of STT for CoCo/Al (the asymmetry parameter ??4.5) is more skewed than that for MnSi/Al (??2.9), which suggests the clean CoCo/Al architecture is much more efficient for the application on radio frequency oscillation. We also find that even with interfacial disorder the spin-valve of half-metallic CMS still has a relatively large parameter ? compared to that of conventional ferromagnet. In addition, for clean interface the in-plane torkance of MnSi/Al is about twice as large as that of CoCo/Al. However, as long as the degree of interfacial disorder is sufficiently large, the CoCo/Al and MnSi/Al will show approximately the same magnitude of in-plane torkance. Furthermore, our results demonstrate that CMS/Al/CMS system has very high efficiency of STT to switch the magnetic layer of spin-valve.

  16. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 °C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 °C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 °C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 °C, and AgVO{sub 3} and molybdate for 900 °C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: • NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. • AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. • NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. • Phase composition on the worn surface was varied with temperatures. • Self-adjusted action was responsible for the improvement of tribological properties.

  17. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke; Zhang, F; Miller, Michael K; Liu, Chain T; Huang, Shenyan; Chou, Y.T.; Tien, R; Chang, Y A; Liaw, Peter K

    2012-01-01

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  18. Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel using Atom Probe Tomography

    SciTech Connect (OSTI)

    Pereloma, E. V.; Stohr, R A; Miller, Michael K; Ringer, S. P.

    2009-01-01

    We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe){sub 3}Ti and (Ni,Fe){sub 3}(Al,Mn) precipitates eventually form after isothermal aging for {approx}60 seconds. The morphology of the (Ni,Fe){sub 3}Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe){sub 3}(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe){sub 3}Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation.

  19. Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal aluminides

    E-Print Network [OSTI]

    Morse, Michael D.

    Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal, Utah 84112 (Received 9 May 1994; accepted 28 June 1994) Jet-cooled diatomic AlMn has been

  20. Role of Si on the Diffusional Interactions between U-Mo and Al-Si Alloys at 823 K (550 degrees C)

    SciTech Connect (OSTI)

    E. Perez; Y.H. Sohn; D.D. Keiser, Jr.

    2013-01-01

    U-Mo dispersions in Al-alloy matrix and monolithic fuels encased in Al-alloy are under development to fulfill the requirements for research and test reactors to use low-enriched molybdenum stabilized uranium alloys fuels. Significant interaction takes place between the U-Mo fuel and Al during manufacturing and in-reactor irradiation. The interactions products are Al-rich phases with physical and thermal characteristics that adversely affect fuel performance and lead to premature failure. Detailed analysis of the interdiffusion and microstructural development of this system was carried through diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo and U-12wt.%Mo in contact with pure Al, Al-2wt.%Si, and Al-5wt.%Si, annealed at 823K for 1, 5 and 20 hours. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed for the analysis. Diffusion couples consisting of U-Mo vs. pure Al contained UAl3, UAl4, U6Mo4Al43, and UMo2Al20 phases. The addition of Si to the Al significantly reduced the thickness of the interdiffusion zone. The interdiffusion zones developed Al and Si enriched regions, whose locations and size depended on the Si and Mo concentrations in the terminal alloys. In the couples, the (U,Mo)(Al,Si)3 phase was observed throughout interdiffusion zone, and the U6Mo4Al43 and UMo2Al20 phases were observed only where the Si concentrations were low.

  1. Scanning Electron Microscopy Analysis of Fuel/Matrix Interaction Layers in Highly-Irradiated U–Mo Dispersion Fuel Plates with Al and Al–Si Alloy Matrices

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Brandon D. Miller; Jian Gan; Adam B. Robinson; Pavel Medvedev; James Madden; Dan Wachs; Mitch Meyer

    2014-04-01

    In order to investigate how the microstructure of fuel/matrix-interaction (FMI) layers change during irradiation, different U–7Mo dispersion fuel plates have been irradiated to high fission density and then characterized using scanning electron microscopy (SEM). Specifially, samples from irradiated U–7Mo dispersion fuel elements with pure Al, Al–2Si and AA4043 (~4.5 wt.%Si) matrices were SEM characterized using polished samples and samples that were prepared with a focused ion beam (FIB). Features not observable for the polished samples could be captured in SEM images taken of the FIB samples. For the Al matrix sample, a relatively large FMI layer develops, with enrichment of Xe at the FMI layer/Al matrix interface and evidence of debonding. Overall, a significant penetration of Si from the FMI layer into the U–7Mo fuel was observed for samples with Si in the Al matrix, which resulted in a change of the size (larger) and shape (round) of the fission-gas bubbles. Additionally, solid-fission-product phases were observed to nucleate and grow within these bubbles. These changes in the localized regions of the microstructure of the U–7Mo may contribute to changes observed in the macroscopic swelling of fuel plates with Al–Si matrices.

  2. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.2×1021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  3. Prediction of U-Mo dispersion nuclear fuels with Al-Si alloy using artificial neural network

    SciTech Connect (OSTI)

    Susmikanti, Mike; Sulistyo, Jos

    2014-09-30

    Dispersion nuclear fuels, consisting of U-Mo particles dispersed in an Al-Si matrix, are being developed as fuel for research reactors. The equilibrium relationship for a mixture component can be expressed in the phase diagram. It is important to analyze whether a mixture component is in equilibrium phase or another phase. The purpose of this research it is needed to built the model of the phase diagram, so the mixture component is in the stable or melting condition. Artificial neural network (ANN) is a modeling tool for processes involving multivariable non-linear relationships. The objective of the present work is to develop code based on artificial neural network models of system equilibrium relationship of U-Mo in Al-Si matrix. This model can be used for prediction of type of resulting mixture, and whether the point is on the equilibrium phase or in another phase region. The equilibrium model data for prediction and modeling generated from experimentally data. The artificial neural network with resilient backpropagation method was chosen to predict the dispersion of nuclear fuels U-Mo in Al-Si matrix. This developed code was built with some function in MATLAB. For simulations using ANN, the Levenberg-Marquardt method was also used for optimization. The artificial neural network is able to predict the equilibrium phase or in the phase region. The develop code based on artificial neural network models was built, for analyze equilibrium relationship of U-Mo in Al-Si matrix.

  4. Magnetic and transport properties of Mn{sub 2}CoAl oriented films

    SciTech Connect (OSTI)

    Jamer, Michelle E.; Assaf, Badih A.; Devakul, Trithep; Heiman, Don

    2013-09-30

    The structure, magnetic, and transport properties of thin films of the Heusler ferrimagnet Mn{sub 2}CoAl have been investigated for properties related to spin gapless semiconductors. Oriented films were grown by molecular beam epitaxy on GaAs substrates and the structure was found to transform from tetragonal to cubic for increasing annealing temperature. The anomalous Hall resistivity is found to be proportional to the square of the longitudinal resistivity and magnetization expected for a topological Berry curvature origin. A delicate balance of the spin-polarized carrier type when coupled with voltage gate-tuning could significantly impact advanced electronic devices.

  5. Epitaxial {tau} phase MnAl thin films on MgO (001) with thickness-dependent magnetic anisotropy

    SciTech Connect (OSTI)

    Cui Yishen; Chen Wei [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Yin Wenjing; Lu Jiwei [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Wolf, Stuart A. [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2011-11-15

    In this study, ferromagnetic MnAl films were prepared by alternating Al/Mn quasi-monolayer deposition using a novel biased target ion beam deposition (BTIBD) technique. XRD results showed that the magnetic {tau} phase was well formed in MnAl thin films ({approx}10 nm), which grew epitaxially on single crystal MgO (001) substrates. The optimized saturation magnetization was {approx}394 emu/cc. Furthermore, we observed a thickness-dependent uniaxial anisotropy in ferromagnetic MnAl films, which was attributed to the change of the tetragonal lattice distortion as a function of film thickness. The relationship between the film thicknesses and saturation magnetizations suggested the existence of a magnetically dead layer {approx}2.7 nm with an extrapolated saturation moment around 523 emu/cc ({approx}1.90 {mu}{sub B}/Mn). This value has exceeded the experimental value in bulk materials and is close to the theoretically predicted magnetization ({approx}1.975 {mu}{sub B}/Mn).

  6. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  7. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Sterbinsky, G. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Assaf, B. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Arena, D. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Heiman, D. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics

    2014-12-07

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  8. Results of U-xMo (x=7, 10, 12 wt.%) Alloy versus Al-6061 Cladding Diffusion Couple Experiments Performed at 500, 550 and 600 Degrees C

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Yongho Sohn

    2013-04-01

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been developing low enrichment fuel systems encased in Al 6061 for use in research and test reactors. U–Mo alloys in contact with Al and Al alloys can undergo diffusional interactions that can result in the development of interdiffusion zones with complex fine-grained microstructures composed of multiple phases. A monolithic fuel currently being developed by the RERTR program has local regions where the U–Mo fuel plate is in contact with the Al 6061 cladding and, as a result, the program finds information about interdiffusion zone development at high temperatures of interest. In this study, the microstructural development of diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo, and U-12wt.%Mo vs. Al 6061 (or 6061 aluminum) cladding, annealed at 500, 550, 600 degrees C for 1, 5, 20, 24, or 132 hours, was analyzed by backscatter electron microscopy and x-ray energy dispersive spectroscopy on a scanning electron microscope. Concentration profiles were determined by standardized wavelength dispersive spectroscopy and standardless x-ray energy dispersive spectroscopy. The results of this work shows that the presence of surface layers at the U–Mo/Al 6061 interface can dramatically impact the overall interdiffusion behavior in terms of rate of interaction and uniformity of the developed interdiffusion zones. It further reveals that relatively uniform interaction layers with higher Si concentrations can develop in U–Mo/Al 6061 couples annealed at shorter times and that longer times at temperature result in the development of more non-uniform interaction layers with more areas that are enriched in Al. At longer annealing times and relatively high temperatures, U–Mo/Al 6061 couples can exhibit more interaction compared to U–Mo/pure Al couples. The minor alloying constituents in Al 6061 cladding can result in the development of many complex phases in the interaction layer of U–Mo/Al–6061 cladding couples, and some phases in the interdiffusion zones of U–Mo/Al–6061 cladding couples are likely similar to those observed for U–Mo/pure Al couples.

  9. Calculations of structural, elastic, electronic, magnetic and phonon properties of FeNiMnAl by the first principles

    SciTech Connect (OSTI)

    U?ur, ?ule; ?yigör, Ahmet

    2014-10-06

    The electronic, elastic and dynamical properties of the quaternary alloy FeNiMnAl have been investigated using a pseudopotential plane wave method within the generalized gradient approximation (GGA). We determined the lattice parameters and the bulk modulus B. In addition, the elastic properties such as elastic constans (C{sub 11}, C{sub 12} and C{sub 44}), the shear modulus G, the young modulus E, the poisson's ratio ? and the B/G ratio are also given. The FeNiMnAl Heusler alloy exhibit a ferromagnetic half-metallic behavior with the total magnetic moment of 4.02 ?{sub B}. The phonon dispersion of FeNiMnAl has been performed using the density functional theory and the direct method with 2×2×2 supercell.

  10. SEM in situ MiniCantilever Beam Bending of U-10Mo/Zr/Al Fuel Elements

    SciTech Connect (OSTI)

    Mook, William; Baldwin, Jon K.; Martinez, Ricardo M.; Mara, Nathan A.

    2014-06-16

    In this work, the fracture behavior of Al/Zr and Zr/dU-10Mo interfaces was measured via the minicantilever bend technique. The energy dissipation rates were found to be approximately 3.7-5 mj/mm2 and 5.9 mj/mm2 for each interface, respectively. It was found that in order to test the Zr/U-10Mo interface, location of the hinge of the cantilever was a key parameter. While this test could be adapted to hot cell use through careful alignment fixturing and measurement of crack lengths with an optical microscope (as opposed to SEM, which was used here out of convenience), machining of the cantilevers via MiniMill in such a way as to locate the interfaces at the cantilever hinge, as well as proper placement of a femtosecond laser notch will continue to be key challenges in a hot cell environment.

  11. Deformation and fracture behavior of Ni-Mo-Al (. gamma. /. gamma. -. cap alpha. ) in-situ composite

    SciTech Connect (OSTI)

    Siramamurthy, A.M.; Tewari, S.N.

    1984-10-01

    Tensile properties for directionally solidified (DS) eutectic alloy of a nominal composition Ni-33 Mo-5.7 Al (weight percent) have been investigated at room and elevated temperatures. The microstructure-mechanical property relationship has been studied for the as-DS and heat-treated conditions. Changes in yield strength, work hardening behavior, and fracture morphology are explained in terms of microstructural changes due to heat treatment. The yield drops are attributed to microdebonding due to segregation of impurities at the fiber-matrix interface and partly to strain aging.

  12. Magneto-transport properties of oriented Mn{sub 2}CoAl films sputtered on thermally oxidized Si substrates

    SciTech Connect (OSTI)

    Xu, G. Z.; Du, Y.; Zhang, X. M.; Liu, E. K.; Wang, W. H. Wu, G. H.; Zhang, H. G.

    2014-06-16

    Spin gapless semiconductors are interesting family of materials by embracing both magnetism and semiconducting due to their unique band structure. Its potential application in future spintronics requires realization in thin film form. In this Letter, we report fabrication and transport properties of spin gapless Mn{sub 2}CoAl films prepared on thermally oxidized Si substrates by magnetron sputtering deposition. The films deposited at 673?K are well oriented to (001) direction and display a uniform-crystalline surface. Magnetotransport measurements on the oriented films reveal a semiconducting-like resistivity, small anomalous Hall conductivity, and linear magnetoresistance representative of the transport signatures of spin gapless semiconductors. The magnetic properties of the films have also been investigated and compared to that of bulk Mn{sub 2}CoAl, showing small discrepancy induced by the composition deviation.

  13. Conditions for spin-gapless semiconducting behavior in Mn{sub 2}CoAl inverse Heusler compound

    SciTech Connect (OSTI)

    Galanakis, I., E-mail: galanakis@upatras.gr [Department of Materials Science, School of Natural Sciences, University of Patras, GR-26504 Patra (Greece); Özdo?an, K., E-mail: kozdogan@yildiz.edu.tr [Department of Physics, Yildiz Technical University, 34210 ?stanbul (Turkey); ?a??o?lu, E.; Blügel, S. [Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, 52425 Jülich (Germany)

    2014-03-07

    Employing ab initio electronic structure calculations, we investigate the conditions for spin-gapless semiconducting (SGS) behavior in the inverse Mn{sub 2}CoAl Heusler compound. We show that tetragonalization of the lattice, which can occur during films growth, keeps the SGS character of the perfect cubic compound. On the contrary, atomic swaps even between sites with different local symmetry destroy the SGS character giving rise to a half-metallic state. Furthermore, the occurrence of Co-surplus leads also to half-metallicity. Thus, we propose that in order to achieve SGS behavior during the growth of Mn{sub 2}CoAl (and similar SGS Heusler compounds) thin films, one should minimize the occurrence of defects, while small deformations of the lattice, due to the lattice mismatch with the substrate, do not play a crucial role.

  14. Irradiation behavior of the interaction product of U-Mo fuel particle dispersion in an Al matrix.

    SciTech Connect (OSTI)

    Kim, Y.S.; Hofman, G. (Nuclear Engineering Division)

    2012-06-01

    Irradiation performance of U-Mo fuel particles dispersed in Al matrix is stable in terms of fuel swelling and is suitable for the conversion of research and test reactors from highly enriched uranium (HEU) to low enriched uranium (LEU). However, tests of the fuel at high temperatures and high burnups revealed obstacles caused by the interaction layers forming between the fuel particle and matrix. In some cases, fission gas filled pores grow and interconnect in the interdiffusion layer resulting in fuel plate failure. Postirradiation observations are made to examine the behavior of the interdiffusion layers. The interdiffusion layers show a fluid-like behavior characteristic of amorphous materials. In the amorphous interdiffusion layers, fission gas diffusivity is high and the material viscosity is low so that the fission gas pores readily form and grow. Based on the observations, a pore formation mechanism is proposed and potential remedies to suppress the pore growth are also introduced.

  15. Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural Characterization and Catalytic Function

    E-Print Network [OSTI]

    Iglesia, Enrique

    Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural of stoichiometric reduction in H2, and the oxidative dehydrogenation of propane. VOx domains on Al2O3 modified The oxidative dehydrogenation (ODH) of propane provides an attractive route for the synthesis of propene.1

  16. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect (OSTI)

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  17. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U–7Mo/Al matrix dispersion fuel plate

    SciTech Connect (OSTI)

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U–7 wt.% Mo (U–7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 ?m-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U–7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 °C using ZrN-coated U–7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U–7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U–7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  18. Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4 Qi Wan, Ping storage properties of MgH2-LiAlH4, prepared by ball milling, are studied for the first time. The hydrogen/L) densities are extremely eager for on-board hydrogen storage in fuel cell vehicles according to the U.S. DOE

  19. Functioning mechanism of AlF3 coating on the Li- and Mn-rich cathode materials

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Xiao, Jie; Polzin, Bryant; Yan, Pengfei; Chen, Xilin; Wang, Chong M.; Zhang, Jiguang

    2014-11-25

    Li- and Mn-rich (LMR) material is a very promising cathode for lithium ion batteries because of their high theoretical energy density (~900 Wh kg-1) and low cost. However, their poor long-term cycling stability, voltage fade, and low rate capability are significant barriers hindered their practical applications. Surface coating, e.g. AlF3 coating, can significantly improve the capacity retention and enhance the rate capability. However, the fundamental mechanism of this improvement and the microstructural evolution related to the surface coating is still not well understood. Here, we report systematic studies of the microstructural changes of uncoated and AlF3-coated materials before and after cycling using aberration-corrected scanning/transmission electron microscopy and electron energy loss spectroscopy. The results reveal that surface coating can reduce the oxidation of electrolyte at high voltage, thus suppressing the accumulation of SEI layer on electrode particle surface. Surface coating also enhances structural stability of the surface region (especially the electrochemically transformed spinel-like phase), and protects the electrode from severe etching/corrosion by the acidic species in the electrolyte, therefore limiting the degradation of the material. Moreover, surface coating can alleviate the undesirable voltage fade by minimize layered-spinel phase transformation in the bulk region of the materials. These fundamental findings may also be widely applied to explain the functioning mechanism of other surface coatings used in a broad range of electrode materials.

  20. Formation of voids and secondary-phase precipitates in the Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si steel under high-doze neutron irradiation and during post-irradiation annealing

    SciTech Connect (OSTI)

    Portnykh, I. A. Kozlov, A. V.; Shcherbakov, E. N.; Asiptsov, O. I.

    2009-12-15

    The effect of high-dose neutron irradiation on the structural changes in Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si austenitic steel have been investigated. Samples irradiated at temperatures of 390, 500, and 600{sup o} to damage doses of 46, 86, and 46 dpa, respectively, were analyzed by electron microscopy and dilatometry. The quantitative characteristics of radiation voids and secondary-phase precipitates formed under neutron irradiation are obtained. Their behavior upon heating to 700{sup o}C and annealing at this temperature for 2 h is studied. It is shown that annealing leads to the dissociation of small voids, which is accompanied by the growth of large ones. The secondary-phase precipitates are partially dissolved upon annealing, and their volume fraction decreases.

  1. Thermal expansion of Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12} solid solutions

    SciTech Connect (OSTI)

    Ari, M.; Jardim, P.M.; Marinkovic, B.A. Rizzo, F.; Ferreira, F.F.

    2008-06-15

    The transition temperature from monoclinic to orthorhombic and the thermal expansion of the orthorhombic phase were investigated for three systems of the family A{sub 2}M{sub 3}O{sub 12}: Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12}. It was possible to obtain a single-phase solid solution in all studied samples (x=0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1). A linear relationship between the transition temperature and the fraction of A{sup 3+} cations (x) was observed for each system. In all orthorhombic solid solutions studied here the observed thermal expansion was anisotropic. These anisotropic thermal expansion properties of crystallographic axes a, b and c result in a low positive or near-zero overall linear coefficient of thermal expansion ({alpha}{sub l}={alpha}{sub V}/3). The relationship between the size of A{sup 3+} cations in A{sub 2}M{sub 3}O{sub 12} and the coefficient of thermal expansion is discussed. Near-zero thermal expansion of Cr{sub 2}Mo{sub 3}O{sub 12} is explained by the behavior of Cr-O and Mo-O bond distances, Cr-Mo non-bond distances and Cr-O-Mo bond angles with increasing temperature, estimated by Rietveld analysis of synchrotron X-ray powder diffraction data. - Graphical abstract: In this figure, all published overall linear coefficients of thermal expansion for orthorhombic A{sub 2}M{sub 3}O{sub 12} family obtained through diffraction methods as a function of A{sup 3+} cation radii size, together with dilatometric results, are plotted. Our results indicate that Cr{sub 2}Mo{sub 3}O{sub 12} does not exactly follow the established relationship.

  2. Al{sub 70}Pd{sub 21.5}Mn{sub 8.5}: A quasicrystal showing the de haas-van Alphen effect

    SciTech Connect (OSTI)

    Haanappel, E.G. [National High Magnetic Field Laboratory, Los Alamos, NM (United States). Pulsed Field Facility; Kycia, S.W.; Harmon, B.N.; Canfield, P.C.; Goldman, A.I. [Iowa State Univ., Ames, IA (United States). Ames Lab.; Rabson, D.A.; Thompson, J.D.; Mueller, F.M. [Los Alamos National Lab., NM (United States)

    1995-07-01

    We have measured the de Haas-van Alphen effect in the icosahedral quasicrystal Al{sub 70}Pd{sub 21.5}Mn{sub 8.5}. We have found two well-defined frequencies with the magnetic field parallel to a five-fold axis, and two different ones with the field parallel to a two-fold axis. On increasing the temperature, the amplitude of the oscillations substantially decreased, suggesting that the carriers have large masses.

  3. Effects of Irradiation on the Microstructure of U-7Mo Dispersion Fuel with Al-2Si Matrix

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Adam B. Robinson; Pavel Medvedev; Jian Gan; Brandon D. Miller; Daniel M. Wachs; Glenn A. Moore; Curtis R. Clark; Mitchell K. Meyer; M. Ross Finlay

    2012-06-01

    The Reduced Enrichment for Research and Test Reactor program is developing low-enriched uranium U-Mo dispersion fuels for application in research and test reactors around the world. As part of this development, fuel plates have been irradiated in the Advanced Test Reactor and then characterized using optical metallography (OM) and scanning electron microscopy (SEM) to determine the as-irradiated microstructure. To demonstrate the irradiation performance of U-7Mo dispersion fuel plates with 2 wt% Si added to the matrix, fuel plates were tested to medium burnups at intermediate fission rates as part of the RERTR-6 experiment. Further testing was performed to higher fission rates as part of the RERTR-7A experiment, and very aggressive testing (high temperature, high fission density, high fission rate) was performed in the RERTR-9A, RERTR-9B and AFIP-1 experiments. As-irradiated microstructures were compared to those observed after fabrication to determine the effects of irradiation on the microstructure. Based on comparison of the microstructural characterization results for each irradiated sample, some general conclusions can be drawn about how the microstructure evolves during irradiation: there is growth of the fuel/matrix interaction layer (FMI), which was present in the samples to some degree after fabrication, during irradiation; Si diffuses from the FMI layer to deeper depths in the U-7Mo particles as the irradiation conditions are made more aggressive; lowering of the Si content in the FMI layer results in an increase in the size of the fission gas bubbles; as the FMI layer grows during irradiation more Si diffuses from the matrix to the FMI layer/matrix interface, and interlinking of fission gas bubbles in the fuel plate microstructure that may indicate breakaway swelling is not observed.

  4. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai

    2014-05-26

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  5. Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations 

    E-Print Network [OSTI]

    Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

    2007-01-01

    A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, Ga...

  6. Scanning tuneeling microscopy studies of fivefold surfaces of icosahedral Al-Pd-Mn quasicrystals and of thin silver films on those surfaces

    SciTech Connect (OSTI)

    Unal, Baris

    2008-12-01

    The present work in this dissertation mainly focuses on the clean fivefold surfaces of i-Al-Pd-Mn quasicrystals as well as the nucleation and growth of Ag films on these surfaces. In addition, Ag film growth on NiAl(110) has been explored in the frame of this dissertation. First, we have investigated the equilibration of a fivefold surface of icosahedral Al-Pd-Mn quasicrystal at 900-915 K and 925-950 K, using Omicron variable temperature scanning tunneling microscope (STM). Annealing at low temperatures resulted in many voids on some terraces while the others were almost void-free. After annealing at 925-950K, void-rich terraces became much rarer. Our STM images suggest that through growth and coalescence of the voids, a different termination becomes exposed on host terraces. All of these observations in our study indicate that even after the quasicrystalline terrace-step structure appears, it evolves with time and temperature. More specifically, based on the STM observations, we conclude that during the annealing a wide range of energetically similar layers nucleate as surface terminations, however, with increasing temperature (and time) this distribution gets narrower via elimination of the metastable void-rich terraces. Next, we have examined the bulk structural models of icosahedral Al-Pd-Mn quasicrystal in terms of the densities, compositions and interplanar spacings for the fivefold planes that might represent physical surface terminations. In our analyses, we mainly have focused on four deterministic models which have no partial or mixed occupancy but we have made some comparisons with an undeterministic model. We have compared the models with each other and also with the available experimental data including STM, LEED-IV, XPD and LEIS. In all deterministic models, there are two different families of layers (a pair of planes), and the nondeterministic model contains similar group of planes. These two families differ in terms of the chemical decoration of their top planes. Hence, we name them as Pd+(with Pd) and Pd-(without Pd). Based on their planer structure and the step height, it can be said that these two families can be viable surface terminations. However, besides the Pd content, these two sets differ in terms of relative densities of their top planes as well as the gap separating the layer from the nearest atomic plane. The experimental data and other arguments lead to the conclusion that the Pd- family is favored over the Pd+. This has an important implication on the interpretation of local motifs seen in the high resolution STM images. In other words, the dark stars are not formed by cut-Bergmans rather they are formed by cut-Mackays.

  7. Effects of intercritical annealing temperature on mechanical properties of Fe-7.9Mn-0.14Si-0.05Al-0.07C steel

    SciTech Connect (OSTI)

    Zhao, Xianming [Northeastern Univ., Shenyang (China); Shen, Yongfeng [Northeastern Univ., Shenyang (China); Qiu, Lina [Northeastern Univ., Shenyang (China); Liu, Yandong [Northeastern Univ., Shenyang (China); Sun, Xin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Zuo, Liang [Northeastern Univ., Shenyang (China)

    2014-12-01

    A medium Mn steel has been designed to achieve an excellent combination of strength and ductility based on the TRIP (Transformation Induced Plasticity) concept for automotive applications. Following six passes of hot rolling at 850 °C, the Fe-7.9Mn-0.14Si-0.05Al-0.07C (wt.%) steel was warm-rolled at 630 °C for seven passes and subsequently air cooled to room temperature. The sample was subsequently intercritically annealed at various temperatures for 30 min to promote the reverse transformation of martensite into austenite. The obtained results show that the highest volume fraction of austenite is 39% for the sample annealed at 600 °C. This specimen exhibits a yield stress of 910 MPa and a high ultimate tensile stress of 1600 MPa, with an elongation-to-failure of 0.29 at a strain rate of 1 × 10?³/s. The enhanced work-hardening ability of the investigated steel is closely related to martensitic transformation and the interaction of dislocations. Especially, the alternate arrangement of acicular ferrite (soft phase) and ultrafine austenite lamellae (50–200 nm, strong and ductile phase) is the key factor contributing to the excellent combination of strength and ductility. On the other hand, the as-warm-rolled sample also exhibits the excellent combination of strength and ductility, with elongation-to-failure much higher than those annealed at temperatures above 630 °C.

  8. Effects of Intercritical Annealing Temperature on Mechanical Properties of Fe-7.9Mn-0.14Si-0.05Al-0.07C Steel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Xianming; Shen, Yongfeng; Qiu, Lina; Liu, Yandong; Sun, Xin; Zuo, Liang

    2014-12-09

    A medium Mn steel has been designed to achieve an excellent combination of strength and ductility based on the TRIP (Transformation Induced Plasticity) concept for automotive applications. Following six passes of hot rolling at 850 °C, the Fe-7.9Mn-0.14Si-0.05Al-0.07C (wt.%) steel was warm-rolled at 630 °C for seven passes and subsequently air cooled to room temperature. The sample was subsequently intercritically annealed at various temperatures for 30 min to promote the reverse transformation of martensite into austenite. The obtained results show that the highest volume fraction of austenite is 39% for the sample annealed at 600 °C. This specimen exhibits amore »yield stress of 910 MPa and a high ultimate tensile stress of 1600 MPa, with an elongation-to-failure of 0.29 at a strain rate of 1 × 10?³/s. The enhanced work-hardening ability of the investigated steel is closely related to martensitic transformation and the interaction of dislocations. Especially, the alternate arrangement of acicular ferrite (soft phase) and ultrafine austenite lamellae (50–200 nm, strong and ductile phase) is the key factor contributing to the excellent combination of strength and ductility. On the other hand, the as-warm-rolled sample also exhibits the excellent combination of strength and ductility, with elongation-to-failure much higher than those annealed at temperatures above 630 °C.« less

  9. Effects of Intercritical Annealing Temperature on Mechanical Properties of Fe-7.9Mn-0.14Si-0.05Al-0.07C Steel

    SciTech Connect (OSTI)

    Zhao, Xianming; Shen, Yongfeng; Qiu, Lina; Liu, Yandong; Sun, Xin; Zuo, Liang

    2014-12-09

    A medium Mn steel has been designed to achieve an excellent combination of strength and ductility based on the TRIP (Transformation Induced Plasticity) concept for automotive applications. Following six passes of hot rolling at 850 °C, the Fe-7.9Mn-0.14Si-0.05Al-0.07C (wt.%) steel was warm-rolled at 630 °C for seven passes and subsequently air cooled to room temperature. The sample was subsequently intercritically annealed at various temperatures for 30 min to promote the reverse transformation of martensite into austenite. The obtained results show that the highest volume fraction of austenite is 39% for the sample annealed at 600 °C. This specimen exhibits a yield stress of 910 MPa and a high ultimate tensile stress of 1600 MPa, with an elongation-to-failure of 0.29 at a strain rate of 1 × 10?³/s. The enhanced work-hardening ability of the investigated steel is closely related to martensitic transformation and the interaction of dislocations. Especially, the alternate arrangement of acicular ferrite (soft phase) and ultrafine austenite lamellae (50–200 nm, strong and ductile phase) is the key factor contributing to the excellent combination of strength and ductility. On the other hand, the as-warm-rolled sample also exhibits the excellent combination of strength and ductility, with elongation-to-failure much higher than those annealed at temperatures above 630 °C.

  10. Mo-99

    National Nuclear Security Administration (NNSA)

    NorthStar Medical Radioisotopes to further develop its technology to produce Mo-99 via neutron capture, bringing the total NNSA support to this project to the maximum of 25...

  11. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  12. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  13. Structural and Functional Characterization of Redox Mn and Co Sites in AlPO Materials and Their Role in Alkane Oxidation Catalysis

    E-Print Network [OSTI]

    Iglesia, Enrique

    and at similar rates, indicating excellent agreement between these techniques. No H2O or CO2 were detected during could be accurately described by Arrhenius-type behavior, and H2/Me ratios showed that only a fraction of all Me cations undergo reversible redox cycles. This fraction was 0.86 for MnAPO-18 (atomic Mn/P ) 0

  14. Quantification of corrosion resistance of a new-class of criticality control materials: thermal-spray coatings of high-boron iron-based amorphous metals - Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Shaw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-03-28

    An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was produced as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. Earlier studies have shown that ingots and melt-spun ribbons of these materials have good passive film stability in these environments. Thermal spray coatings of these materials have now been produced, and have undergone a variety of corrosion testing, including both atmospheric and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here.

  15. Microstructural evolution of U(Mo)–Al(Si) dispersion fuel under irradiation – Destructive analyses of the LEONIDAS E-FUTURE plates

    SciTech Connect (OSTI)

    A. Leenaers; S. Van den Berghe; J. Van Eyken; E. Koonen; F. Charollais; P. Lemoine; Y. Calzavara; H. Guyon; C. Jarousse; D. Geslin; D. Wachs; D. Keiser; A. Robinson; G. Hofman; Y. S. Kim

    2013-10-01

    Several irradiation experiments have confirmed the positive effect of adding Si to the matrix of an U(Mo) dispersion fuel plate on its in-pile irradiation behavior. E-FUTURE, the first experiment of the LEONIDAS program, was performed to select an optimum Si concentration and fuel plate heat treatment parameters for further qualification. It consisted of the irradiation of 4 distinct (regarding Si content and heat treatments), full size flat fuel plates in the BR2 reactor under bounding conditions (470 W/cm2 peak BOL power, approximately 70% peak burn-up). After the irradiation, the E-FUTURE plates were examined non-destructively and found to have pillowed in the highest burn-up positions. The destructive post-irradiation examination confirmed that the fuel evolves in a stable way up to a burn-up of 60%235U. Even in the deformed area (pillow) the U(Mo) fuel itself shows stable behavior and remaining matrix material was present. From the calculation of the volume fractions, the positive effect of a higher Si amount added to the matrix and the higher annealing temperature can be derived.

  16. Long-Term Corrosion Tests of Prototypical SAM2X5 (Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4) Coatings

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Saw, C K; Rebak, R H; Day, S D; Lian, T; Hailey, P D; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-05-10

    An iron-based amorphous metal with good corrosion resistance and a high absorption cross-section for thermal neutrons has been developed and is reported here. This amorphous alloy has the approximate formula Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} and is known as SAM2X5. Chromium (Cr), molybdenum (Mo) and tungsten (W) were added to provide corrosion resistance, while boron (B) was added to promote glass formation and the absorption of thermal neutrons. Since this amorphous metal has a higher boron content than conventional borated stainless steels, it provides the nuclear engineer with design advantages for criticality control structures with enhanced safety. While melt-spun ribbons with limited practical applications were initially produced, large quantities (several tons) of gas atomized powder have now been produced on an industrial scale, and applied as thermal-spray coatings on prototypical half-scale spent nuclear fuel containers and neutron-absorbing baskets. These prototypes and other SAM2X5 samples have undergone a variety of corrosion testing, including both salt-fog and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here. While these coatings have less corrosion resistance than melt-spun ribbons and optimized coatings produced in the laboratory, substantial corrosion resistance has been achieved.

  17. Corrosion Resistance of Amorphous Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 coating - a new criticality-controlled material

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Saw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-03-28

    An iron-based amorphous metal with good corrosion resistance and a high absorption cross-section for thermal neutrons has been developed and is reported here. This amorphous alloy has the approximate formula Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} and is known as SAM2X5. Chromium (Cr), molybdenum (Mo) and tungsten (W) were added to provide corrosion resistance, while boron (B) was added to promote glass formation and the absorption of thermal neutrons. Since this amorphous metal has a higher boron content than conventional borated stainless steels, it provides the nuclear engineer with design advantages for criticality control structures with enhanced safety. While melt-spun ribbons with limited practical applications were initially produced, large quantities (several tons) of gas atomized powder have now been produced on an industrial scale, and applied as thermal-spray coatings on prototypical half-scale spent nuclear fuel containers and neutron-absorbing baskets. These prototypes and other SAM2X5 samples have undergone a variety of corrosion testing, including both salt-fog and long-term immersion testing. Modes and rates of corrosion have been determined in various relevant environments, and are reported here. While these coatings have less corrosion resistance than melt-spun ribbons and optimized coatings produced in the laboratory, substantial corrosion resistance has been achieved.

  18. Table 2 -Lime use and practices on Corn, major producing states, 2001 CO GA IL IN IA KS KY MI MN MO NE NY NC ND OH PA SD TX WI Area

    E-Print Network [OSTI]

    Kammen, Daniel M.

    MO NE NY NC ND OH PA SD TX WI Area Lime applied NR 85 81 85 67 16 72 55 27 65 10 57 53 NR 70 95 3 1 50 51 Lime (tons treated acre) NR 1.0 2.1 1.9 2.5 2.1 2.4 2.0 2.6 2.8 1.5 1.9 1.1 NR 1.9 1.7 NR 0.5 2 NC ND OH PA SD TX WI Area Lime applied NR 95 90 69 18 69 71 14 77 16 76 99 NR 82 80 NR 5 58 54 Lime

  19. Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes

    SciTech Connect (OSTI)

    Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

    2009-05-28

    Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

  20. Ferromagnetism in Mn-and Cr-Implanted AlGaP M.E. Overberg a,*, G.T. Thaler a

    E-Print Network [OSTI]

    Hebard, Arthur F.

    ­15]. This raises the possi- bility of spintronic devices such as transistors which exploit the spin of the electron to integrate GaP-based spintronic devices with existing Si microcircuitry. Recent reports have shown room for room temperature spintronic devices is AlGaP doped with transition ele- ments. The bandgap is larger

  1. ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000.

    E-Print Network [OSTI]

    LBNL-44422 Mo-420 ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000. This work was supported by the Assistant Secretary for Energy

  2. Nonuniversal gaugino masses and muong<mo>->2mn>

    SciTech Connect (OSTI)

    Gogoladze, Ilia [Univ. of Delaware, Newark, DE (United States); Nasir, Fariha [Univ. of Delaware, Newark, DE (United States); Shafi, Qaisar [Univ. of Delaware, Newark, DE (United States); Ün, Cem Salih [Univ. of Delaware, Newark, DE (United States)

    2014-08-01

    We consider two classes of supersymmetric models with nonuniversal gaugino masses at the grand unification scale MGUT in an attempt to resolve the apparent muon g-2 anomaly encountered in the Standard Model. We explore two distinct scenarios, one in which all gaugino masses have the same sign at MGUT, and a second case with opposite sign gaugino masses. The sfermion masses in both cases are assumed to be universal at MGUT. We exploit the nonuniversality among gaugino masses to realize large mass splitting between the colored and noncolored sfermions. Thus, the sleptons can have masses in the few hundred GeV range, whereas the colored sparticles turn out to be an order of magnitude or so heavier. In both models the resolution of the muon g-2 anomaly is compatible, among other things, with a 125–126 GeV Higgs boson mass and the WMAP dark matter bounds.

  3. Ab initio defect energetics of perovskite (001) surfaces for solid oxide fuel cells: A comparative study of LaMnO[subscript 3] versus SrTiO[subscript 3] and LaAlO[subscript 3

    E-Print Network [OSTI]

    Lee, Yueh-Lin

    In this paper, we perform a comparative study based on ab initio modeling for perovskite ABO[subscript 3] (001) surfaces and surface defect energetics in order to understand the influence of polarity and redox active Mn ...

  4. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01

    ferromagnetic Mn 5 Ge 3 for spintronic applications. Phys.Wolf, S. A. et al. Spintronics: a spin-based electronicsdopants of interest for spintronic applications, where both

  5. Electric modulation of magnetization at the BaTiO3/La0.67Sr0.33MnO3 H. Lu, T. A. George, Y. Wang, I. Ketsman, J. D. Burton et al.

    E-Print Network [OSTI]

    Eom, Chang Beom

    Electric modulation of magnetization at the BaTiO3/La0.67Sr0.33MnO3 interfaces H. Lu, T. A. George. Phys. 113, 043914 (2013) Electrical control of magnetic reversal processes in magnetostrictive://apl.aip.org/about/rights_and_permissions #12;Electric modulation of magnetization at the BaTiO3/La0.67Sr0.33MnO3 interfaces H. Lu,1 T. A

  6. An APFIM and TEM study of Ni{sub 4}Mo precipitation in a commercial Ni-28% Mo-1.4% Fe-0.4% Cr wt. % alloy

    SciTech Connect (OSTI)

    Thomson, R.C.; Brown, N.; Bates, J.S. [Loughborough Univ. (United Kingdom). Inst. of Polymer Technology and Materials Engineering; Russell, K.F.; Miller, M.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-02-01

    Ni-Mo alloys containing at least 26 wt.% Mo have a negligible corrosion rate in boiling 10% hydrochloric acid and are therefore used in corrosive environments. A series of commercial Ni-Mo alloys has been developed with subtle variations in chemical composition. These alloys usually contain {approximately} 28 wt.% Mo with additions of up to 5% Fe and Cr. A significant amount of research has been performed to understand the microstructure and properties of these alloys, although most of the effort has concentrated on the Ni-Mo binary system. In some alloys with low Fe and Cr contents, a severe embrittlement problem has been observed due to the formation of the Ni{sub 4}Mo (D1{sub a}-ordered) phase within the microstructure. This research focuses on a commercial alloy with nominal composition Ni-28% Mo-1.4% Fe-0.4% Cr-0.1% Mn-0.003 wt.% C. The material supplied was a heat treatment coupon which had been attached to a large vessel during fabrication. Assessment of the chemical analysis of the alloy suggested that detrimental phases could be present or might appear during subsequent repair work. Therefore, it was important to assess the microstructural condition of the vessel, and in particular the kinetics of precipitation of Ni{sub 4}Mo.

  7. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  8. Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas E.

    2013-01-01

    materials for Li-ion batteries Thomas E. Conry, a,b Apurvamaterials in Li-ion batteries. Synchrotron-based high-materials for Li-ion batteries. LiNi z Mn z Co 1-2z O 2 (NMC

  9. Adsorption studies of Mo and V onto ferrihydrite *, L. G. BENNING

    E-Print Network [OSTI]

    Benning, Liane G.

    2 National Oceanography Centre, Southampton SO14 3ZH, UK ABSTRACT In this paper, the kinetics of Mo the availability of different ions in terrestrial environ- ments (Goldberg et al., 2002; Metz and Trefry 1988 for FHY surface sites. In addition, kinetic information about Mo and V adsorption as a function of pH were

  10. MO. RIV. MO. ALSEP Array D Subpackages 1 & 2

    E-Print Network [OSTI]

    Rathbun, Julie A.

    are based upon mechanical vibration data recorded at the LM/ALSEP interface during the LTA-3DR acoustic~ ·:~: -~ ' ' ' MO. RIV. MO. ALSEP Array D Subpackages 1 & 2 Vibration Test Results ATM-993 PAGI 1 Of OATI 12-15-71 This technical memorandum represents the design limit level vibration test report

  11. CRAD, NNSA- Maintenance (MN)

    Broader source: Energy.gov [DOE]

    CRAD for Maintenance (MN). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and thorough assessment of elements of safety and health programs.

  12. Letter Report Documenting Progress of Second Generation ATF FeCrAl Alloy Fabrication

    SciTech Connect (OSTI)

    Yamamoto,, Y.; Yang, Y.; Field, K. G.; Terrani, K.; Pint, B. A.; Snead, L. L.

    2014-06-10

    Development of the 2nd generation ATF FeCrAl alloy has been initiated, and a candidate alloy was selected for trial tube fabrication through hot-extrusion and gun-drilling processes. Four alloys based on Fe-13Cr-4.5Al-0.15Y in weight percent were newly cast with minor alloying additions of Mo, Si, Nb, and C to promote solid-solution and second-phase precipitate strengthening. The alloy compositions were selected with guidance from computational thermodynamic tools. The lab-scale heats of ~ 600g were arc-melted and drop-cast, homogenized, hot-forged and -rolled, and then annealed producing plate shape samples. An alloy with Mo and Nb additions (C35MN) processed at 800°C exhibits very fine sub-grain structure with the sub-grain size of 1-3?m which exhibited more than 25% better yield and tensile strengths together with decent ductility compared to the other FeCrAl alloys at room temperature. It was found that the Nb addition was key to improving thermal stability of the fine sub-grain structure. Optimally, grains of less than 30 microns are desired, with grains up to and order of magnitude in desired produced through Nb addition. Scale-up effort of the C35MN alloy was made in collaboration with a commercial cast company who has a capability of vacuum induction melting. A 39lb columnar ingot with ~81mm diameter and ~305mm height (with hot-top) was commercially cast, homogenized, hot-extruded, and annealed providing 10mm-diameter bar-shape samples with the fine sub-grain structure. This commercial heat proved consistent with materials produced at ORNL at the lab-scale. Tubes and end caps were machined from the bar sample and provided to another work package for the ATF-1 irradiation campaign in the milestone M3FT-14OR0202251.

  13. Measured lifetimes of metastable levels of Mn X, Mn XI, Mn XII, and Mn XIII ions 

    E-Print Network [OSTI]

    Moehs, D. P.; Church, David A.

    1999-01-01

    An ion storage technique, based on the capture of metastable multiply charged ions from an external ion source into a Kingdon ion trap, has been used to measure the lifetimes of eight metastable levels of Mn ions with 3s(2)3p(k) configurations, k...

  14. A novel organic–inorganic hybrid with Anderson type polyanions as building blocks: (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]·6H{sub 2}O

    SciTech Connect (OSTI)

    Thabet, Safa; Ayed, Brahim; Haddad, Amor

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of a novel inorganic–organic hybrid compound based on Anderson polyoxomolybdates. ? Characterization by X-ray diffraction, IR and UV–Vis spectroscopies of the new compound. ? Potential applications in catalysis, biochemical analysis and electrical conductivity of the organic–inorganic compound. -- Abstract: A new organic–inorganic hybrid compound based on Anderson polyoxomolybdates, (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]·6H{sub 2}O (1) have been isolated by the conventional solution method and characterized by single-crystal X-ray diffraction, infrared, ultraviolet spectroscopy and Thermogravimetric Analysis (TGA). This compound crystallized in the triclinic system, space group P?1, with a = 94.635(1) ?, b = 10.958(1) ?, c = 11.602(1) ?, ? = 67.525(1)°, ? = 71.049(1)°, ? = 70.124(1)° and Z = 1. The crystal structures of the compounds exhibit three-dimensional supramolecular assembly based on the extensive hydrogen bonding interactions between organic cations, sodium cations, water molecules and Anderson polyoxoanions. The infrared spectrum fully confirms the X-ray crystal structure and the UV spectrum of the title compound exhibits an absorption peak at 210 nm.

  15. Investigation of Interdiffusion Behavior in the Mo-Zr Binary System via Diffusion Couple Studies

    SciTech Connect (OSTI)

    A. Paz y Puente; J. Dickson; D.D. Keiser, Jr.; Y.H. Sohn

    2014-03-01

    Zirconium has recently garnered attention for use as a diffusion barrier between U–Mo metallic nuclear fuels and Al alloy cladding. In order to gain a fundamental understanding of the diffusional interactions, the interdiffusion behavior in the binary Mo–Zr system was investigated via solid-to-solid diffusion couples annealed in the temperature range of 750 to 1050 degrees C. A combination of scanning electron microscopy, X-ray energy dispersive spectroscopy, and electron probe microanalysis were used to examine the microstructure and concentration profiles across the interdiffusion zone. A large __-Zr (cI2) solid solution layer and a thin (approximately 1–2 um) layer of Mo2Zr (cF24) developed in all couples. Parabolic growth constants and concentration dependent interdiffusion coefficients were calculated for the Mo2Zr and Zr solid solution phases, respectively. The pre-exponential factor and activation energy for growth of the Mo2Zr phase were determined to be approximately 6.5 × 10- 15 m2/s and 90 kJ/mol, respectively. The interdiffusion coefficient in ___-Zr solid solution decreased with an increase in Mo concentration. Both the pre-exponential factors (2 × 10- 8 m2/s at 2 at.% Mo to near 5 × 10- 8 m2/s at 9 at.% Mo) and activation energies (140 kJ/mol at 2 at.% Mo to approximately 155 kJ/mol at 9 at.% Mo) of interdiffusion coefficients were determined to increase with an increase in Mo concentration.

  16. ,{ MO. REV. NO. THERMAL DESIGN

    E-Print Network [OSTI]

    Rathbun, Julie A.

    ,{ MO. REV. NO. LRRR 300 THERMAL DESIGN FINAL REPORT ATM-931 PAGE i OF iv DATE 1 S Dec 1970 The results of thermal design/analyses performed on the 300 corner Laser Ranging Retro-Reflector (LRRR 300 performance profiles are contained herein, The entire LRRR thermal design effort is des- cribed commendng

  17. Comparison of Pb, Zn, Cd, As, Cr, Mo and Sb Adsorption onto Natural Surface Coatings in a Stream Draining Natural As

    E-Print Network [OSTI]

    Comparison of Pb, Zn, Cd, As, Cr, Mo and Sb Adsorption onto Natural Surface Coatings in a Stream Science+Business Media New York 2014 Abstract Natural surface coatings (biofilms) were col- lected elements Á Distribution coefficient Á Biogenic Mn oxide Natural surface coatings are ubiquitous

  18. Momentum distributions for H<mn>2mn><mo>(mo>e<mo>,mo>e<mo>?p)>

    SciTech Connect (OSTI)

    Ford, William P. [Univ. of Southern Mississippi, Hattiesburg, MS (United States) Dept. of Physics and Astronomy; Jeschonnek, Sabine [The Ohio State Univ., Columbus, OH (United States) Dept. of Physics; Van Orden, J. W. [Old Dominion Univ., Norfolk, VA (United States); Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States)

    2014-12-01

    [Background] A primary goal of deuteron electrodisintegration is the possibility of extracting the deuteron momentum distribution. This extraction is inherently fraught with difficulty, as the momentum distribution is not an observable and the extraction relies on theoretical models dependent on other models as input. [Purpose] We present a new method for extracting the momentum distribution which takes into account a wide variety of model inputs thus providing a theoretical uncertainty due to the various model constituents. [Method] The calculations presented here are using a Bethe-Salpeter like formalism with a wide variety of bound state wave functions, form factors, and final state interactions. We present a method to extract the momentum distributions from experimental cross sections, which takes into account the theoretical uncertainty from the various model constituents entering the calculation. [Results] In order to test the extraction pseudo-data was generated, and the extracted "experimental'' distribution, which has theoretical uncertainty from the various model inputs, was compared with the theoretical distribution used to generate the pseudo-data. [Conclusions] In the examples we compared the original distribution was typically within the error band of the extracted distribution. The input wave functions do contain some outliers which are discussed in the text, but at least this procedure can provide an upper bound on the deuteron momentum distribution. Due to the reliance on the theoretical calculation to obtain this quantity any extraction method should account for the theoretical error inherent in these calculations due to model inputs.

  19. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB<mn>2mn>I<mn>5mn><mo>:Eu>2mn>+>(A<mo>=mo>Li<mo>–>Cs;B<mo>=>Sr, Ba)

    SciTech Connect (OSTI)

    Fang, C.? M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer the B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.

  20. Synthesis and Electrochemistry of Li3MnO4: Mn in the +5 Oxidation State

    E-Print Network [OSTI]

    Saint, Juliette.A.; Doeff, Marca M.; Reed, John

    2008-01-01

    Synthesis and Electrochemistry of Li 3 MnO 4 : Mn in the +5A study describing the electrochemistry of Li 2 MnO 3 in ainvestigation into the electrochemistry of this system

  1. Model studies of hydrodesulfurization by Mo

    SciTech Connect (OSTI)

    Friend, C.M.

    1992-01-01

    Effects of surface modifiers (Co, S) on activity and selectivity of Mo(110) for desulfurization processes were studied. S generally increases the selectivity for desulfurization while decreasing overall reactivity. Co promots C-H activation processes on Mo(110). The Mo(110)-(9x2)-Co surface affects the desulfurization of 2,5- dihydrothiophene and methanethiol. Vibrational spectroscopy is being used for determining molecular orientation; vibrational frequencies were calculated for four labeled 2-propoxide isomers on Mo(110) and found to agree with experiment.

  2. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  3. Study of e<mo>+>e<mo>- stretchy='false'>?mo>pp<mo accent='true' stretchy='false'>¯mo>?>0mn> in the vicinity of the ?<mo stretchy='false'>(mo>>3770mn> stretchy='false'>)mo>

    SciTech Connect (OSTI)

    Ablikim, M.; Achasov, M. ?N.; Ai, X.? C.; Albayrak, O.; Albrecht, M.; Ambrose, D. ?J.; An, F. ?F.; An, Q.; Bai, J. ?Z.; Baldini Ferroli, R.; Ban, Y.; Bennett, J.? V.; Bertani, M.; Bian, J.? M.; Boger, E.; Bondarenko, O.; Boyko, I.; Braun, S.; Briere, R.? A.; Cai, H.; Cai, X.; Cakir, O.; Calcaterra, A.; Cao, G.? F.; Cetin, S.? A.; Chang, J.? F.; Chelkov, G.; Chen, G.; Chen, H.? S.; Chen, J.? C.; Chen, M.? L.; Chen, S.? J.; Chen, X.; Chen, X.? R.; Chen, Y.? B.; Cheng, H.? P.; Chu, X.? K.; Chu, Y.? P.; Cronin-Hennessy, D.; Dai, H.? L.; Dai, J.? P.; Dedovich, D.; Deng, Z.? Y.; Denig, A.; Denysenko, I.; Destefanis, M.; Ding, W.? M.; Ding, Y.; Dong, C.; Dong, J.; Dong, L.? Y.; Dong, M. ?Y.; Du, S.? X.; Fan, J.? Z.; Fang, J.; Fang, S. ?S.; Fang, Y.; Fava, L.; Feng, C. ?Q.; Fu, C. ?D.; Fuks, O.; Gao, Q.; Gao, Y.; Geng, C.; Goetzen, K.; Gong, W.? X.; Gradl, W.; Greco, M.; Gu, M. ?H.; Gu, Y.? T.; Guan, Y.? H.; Guo, A.? Q.; Guo, L.? B.; Guo, T.; Guo, Y.? P.; Han, Y.? L.; Harris, F.? A.; He, K.? L.; He, M.; He, Z.? Y.; Held, T.; Heng, Y.? K.; Hou, Z.? L.; Hu, C.; Hu, H.? M.; Hu, J. ?F.; Hu, T.; Huang, G.? M.; Huang, G. ?S.; Huang, H.? P.; Huang, J.? S.; Huang, L.; Huang, X. ?T.; Huang, Y.; Hussain, T.; Ji, C. ?S.; Ji, Q.; Ji, Q.? P.; Ji, X. ?B.; Ji, X.? L.; Jiang, L. ?L.; Jiang, L.? W.; Jiang, X.? S.; Jiao, J.? B.; Jiao, Z.; Jin, D.? P.; Jin, S.; Johansson, T.; Kalantar-Nayestanaki, N.; Kang, X. ?L.; Kang, X.? S.; Kavatsyuk, M.; Kloss, B.; Kopf, B.; Kornicer, M.; Kühn, W.; Kupsc, A.; Lai, W.; Lange, J.? S.; Lara, M.; Larin, P.; Leyhe, M.; Li, C.? H.; Li, Cheng; Li, Cui; Li, D.; Li, D.? M.; Li, F.; Li, G.; Li, H.? B.; Li, J.? C.; Li, K.; Li, K.; Li, Lei; Li, P. ?R.; Li, Q.? J.; Li, T.; Li, W.? D.; Li, W.? G.; Li, X.? L.; Li, X.? N.; Li, X.? Q.; Li, Z.? B.; Liang, H.; Liang, Y.? F.; Liang, Y.? T.; Lin, D.? X.; Liu, B.? J.; Liu, C. ?L.; Liu, C.? X.; Liu, F.? H.; Liu, Fang; Liu, Feng; Liu, H. ?B.; Liu, H.? H.; Liu, H.? M.; Liu, J.; Liu, J.? P.; Liu, K.; Liu, K.? Y.; Liu, P.? L.; Liu, Q.; Liu, S.? B.; Liu, X.; Liu, Y.? B.; Liu, Z.? A.; Liu, Zhiqiang; Liu, Zhiqing; Loehner, H.; Lou, X.? C.; Lu, G.? R.; Lu, H.? J.; Lu, H.? L.; Lu, J.? G.; Lu, X.? R.; Lu, Y.; Lu, Y.? P.; Luo, C.? L.; Luo, M.? X.; Luo, T.; Luo, X.? L.; Lv, M.; Ma, F.? C.; Ma, H. ?L.; Ma, Q.? M.; Ma, S.; Ma, T.; Ma, X. ?Y.; Maas, F. ?E.; Maggiora, M.; Malik, Q.? A.; Mao, Y.? J.; Mao, Z.? P.; Messchendorp, J.? G.; Min, J.; Min, T.? J.; Mitchell, R.? E.; Mo, X.? H.; Mo, Y.? J.; Moeini, H.; Morales Morales, C.; Moriya, K.; Muchnoi, N.? Yu.; Muramatsu, H.; Nefedov, Y.; Nikolaev, I. ?B.; Ning, Z.; Nisar, S.; Niu, X.? Y.; Olsen, S.? L.; Ouyang, Q.; Pacetti, S.; Pelizaeus, M.; Peng, H.? P.; Peters, K.; Ping, J.? L.; Ping, R.? G.; Poling, R.; Q., N.; Qi, M.; Qian, S.; Qiao, C.? F.; Qin, L.? Q.; Qin, X.? S.; Qin, Y.; Qin, Z. ?H.; Qiu, J. ?F.; Rashid, K.? H.; Redmer, C.? F.; Ripka, M.; Rong, G.; Ruan, X.? D.; Sarantsev, A.; Schoenning, K.; Schumann, S.; Shan, W.; Shao, M.; Shen, C.? P.; Shen, X.? Y.; Sheng, H.? Y.; Shepherd, M.? R.; Song, W.? M.; Song, X. ?Y.; Spataro, S.; Spruck, B.; Sun, G.? X.; Sun, J. ?F.; Sun, S.? S.; Sun, Y.? J.; Sun, Y. ?Z.; Sun, Z. ?J.; Sun, Z.? T.; Tang, C.? J.; Tang, X.; Tapan, I.; Thorndike, E.? H.; Toth, D.; Ullrich, M.; Uman, I.; Varner, G.? S.; Wang, B.; Wang, D.; Wang, D.? Y.; Wang, K.; Wang, L.? L.; Wang, L. ?S.; Wang, M.; Wang, P.; Wang, P.? L.; Wang, Q.? J.; Wang, S.? G.; Wang, W.; Wang, X.? F.; Wang, Y.? D.; Wang, Y.? F.; Wang, Y.? Q.; Wang, Z.; Wang, Z. ?G.; Wang, Z.? H.; Wang, Z.? Y.; Wei, D.? H.; Wei, J.? B.; Weidenkaff, P.; Wen, S. ?P.; Werner, M.; Wiedner, U.; Wolke, M.; Wu, L.? H.; Wu, N.; Wu, Z.; Xia, L.? G.; Xia, Y.; Xiao, D.; Xiao, Z.? J.; Xie, Y.? G.; Xiu, Q.? L.; Xu, G.? F.; Xu, L.; Xu, Q. ?J.; Xu, Q.? N.; Xu, X.? P.; Xue, Z.; Yan, L.; Yan, W.? B.; Yan, W.? C.; Yan, Y.? H.; Yang, H.? X.; Yang, L.; Yang, Y.; Yang, Y.? X.; Ye, H.; Ye, M.; Ye, M.? H.; Yu, B. ?X.; Yu, C. ?X.; Yu, H.? W.; Yu, J.? S.; Yu, S.? P.; Yuan, C. ?Z.; Yuan, W.? L.; Yuan, Y.; Yuncu, A.; Zafar, A. ?A.; Zallo, A.; Zang, S.? L.; Zeng, Y.; Zhang, B. ?X.; Zhang, B.? Y.; Zhang, C.; Zhang, C. ?B.; Zhang, C.? C.; Zhang, D.? H.; Zhang, H.? H.; Zhang, H.? Y.; Zhang, J.? J.; Zhang, J.? Q.; Zhang, J.? W.; Zhang, J.? Y.; Zhang, J. ?Z.; Zhang, S.? H.; Zhang, X. ?J.; Zhang, X.? Y.; Zhang, Y.; Zhang, Y.? H.; Zhang, Z.? H.; Zhang, Z.? P.; Zhang, Z.? Y.; Zhao, G.

    2014-08-22

    The process e+e-?pp¯?0 has been studied by analyzing data collected at ?s=3.773 GeV, at s?=3.650 GeV, and during a ?(3770) line shape scan with the BESIII detector at the BEPCII collider. The Born cross section of pp¯?0 in the vicinity of the ?(3770) is measured, and the Born cross section of ?(3770)?pp¯?0 is extracted considering interference between resonant and continuum production amplitudes. Two solutions with the same probability and a significance of 1.5? are found. The solutions for the Born cross section of ?(3770)?pp¯?0 are 33.8±1.8±2.1 pb and 0.06+0.10-0.04+0.01-0.01 pb (<0.22 pb at a 90% confidence level). Using the estimated cross section and a constant decay amplitude approximation, the cross section ?(pp¯??(3770)?0) is calculated for the kinematic situation of the planned P¯ANDA experiment. The maximum cross section corresponding to the two solutions is expected to be less than 0.79 nb at 90% confidence level and 122±10 nb at a center-of-mass energy of 5.26 GeV.

  4. The influence of the iron content on the reductive decomposition of A{sub 3?x}Fe{sub x}Al{sub 2}Si{sub 3}O{sub 12} garnets (A = Mg, Mn; 0.47 ? x ? 2.85)

    SciTech Connect (OSTI)

    Aparicio, Claudia, E-mail: claudia.aparicio@upol.cz; Filip, Jan, E-mail: claudia.aparicio@upol.cz; Mashlan, Miroslav, E-mail: claudia.aparicio@upol.cz; Zboril, Radek, E-mail: claudia.aparicio@upol.cz [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science, Palacky University, 17. listopadu 1192/12, 77146 Olomouc (Czech Republic)

    2014-10-27

    Thermally-induced reductive decomposition of natural iron-bearing garnets of the almandine-pyrope and almandine-spessartine series were studied at temperatures up to 1200 °C (heating rate of 10 °C/min) under atmosphere of forming gas (10% of H{sub 2} in N{sub 2}). Crystallochemical formula of the studied garnet was calculated as {sup VIII}(A{sub 3?x}Fe{sub x}{sup 2+}){sup VI}(Al,Fe{sup 3+}){sub 2}Si{sub 3}O{sub 12}, where the amount of Fe{sup 3+} in the octahedral sites is negligible with the exception of pyrope, A = Mg, Mn, and 0.47 ? x ? 2.85. The observed decomposition temperature, determined from differential scanning calorimetry and thermogravimetry, is greater than 1000 °C in all cases and showed almost linear dependence on the iron content in the dodecahedral sites of the studied garnets, with the exception of garnet with a near-pyrope composition (Prp{sub 80}Alm{sub 20}). The initial garnet samples and decomposition products were characterized in details by means of X-ray powder diffraction and {sup 57}Fe Mössbauer spectroscopy. We found that all studied garnets have common decomposition products such as metallic iron (in general, rounded particles below 4 ?m) and Fe-spinel; the other identified decomposition products depend on starting chemical composition of the garnet: Fe-cordierite, olivine (fayalite or tephroite), cristobalite, pyroxene (enstatite or pigeonite), and anorthite. Anorthite and pigeonite were only present in garnets with Ca in the dodecahedral site. All the identified phases were usually well crystallized.

  5. Boric acid flux synthesis, structure and magnetic property of MB??O??(OH)?? (M=Mn, Fe, Zn)

    SciTech Connect (OSTI)

    Yang, Dingfeng; Cong, Rihong [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Gao, Wenliang, E-mail: gaowl@cqu.edu.cn [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Yang, Tao, E-mail: taoyang@cqu.edu.cn [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China)

    2013-05-01

    Three new borates MB??O??(OH)?? (M=Mn, Fe, Zn) have been synthesized by boric acid flux methods, which are isotypic to NiB??O??(OH)??. Single-crystal XRD was performed to determine the crystal structures in detail. They all crystallize in the monoclinic space group P2?/c. The size of MO{sub 6} (M=Mg, Mn, Fe, Co, Ni, Zn) octahedron shows a good agreement with the Shannon effective ionic radii of M²?. Magnetic measurements indicate MnB??O??(OH)?? is antiferromagnetic without a long-range ordering down to 2 K. The values of its magnetic superexchange constants were evaluated by DFT calculations, which explain the observed magnetic behavior. The UV–vis diffuse reflectance spectrum of ZnB??O??(OH)?? suggests a band gap ~4.6 eV. DFT calculations indicate it has a direct band gap 4.9 eV. The optical band gap is contributed by charge transfers from the occupied O 2p to the unoccupied Zn 4s states. - Graphical abstract: Experimental and theoretical studies indicate MnB??O??(OH)?? is antiferromagnetic without a long-range ordering. DFT calculations show ZnB??O??(OH)?? has a direct band gap of 4.9 eV. Highlights: • MB??O??(OH)?? (M=Mn, Fe, Zn) are synthesized by two-step boric acid flux method. • Single-crystal XRD was performed to determine the crystal structures in detail. • Size of MO? (M=Mg, Mn, Fe, Co, Ni, Zn) agrees with the effective ionic radii. • MnB??O??(OH)?? is antiferromagnetic without a long-range ordering down to 2 K. • DFT calculations indicate ZnB??O??(OH)?? has a direct band gap 4.9 eV.

  6. Highly Active Yeast MnSOD has a Novel Mechanism Involving Six-coordinate Mn(3+) Species

    E-Print Network [OSTI]

    Sheng, Yuewei

    2012-01-01

    2009) Functional roles of the tetramer organization of malicGrez, M. (2010) Dimer-tetramer transition controls RUNX1/ETOdimer, Å) Mn•••Mn (A/C, tetramer, Å) Mn•••Mn (A/D, tetramer,

  7. Wideband saturable absorption in few-layer molybdenum diselenide (MoSe2) for Q-switching Yb-, Er- and Tm-doped fiber lasers

    E-Print Network [OSTI]

    Woodward, R. I.; Howe, R. C. T.; Runcorn, T. H.; Hu, G.; Torrisi, F.; Kelleher, E. J. R.; Hasan, T.

    2015-06-23

    nm) gap for monolayer MoSe2 [30, 35]. The nonlinear optical properties of few-layer MoSe2 have been studied by Wang et al. for UALPE MoSe2 dispersed in cyclo- hexylpyrrolidone (CHP) [11], and by Dong et al. in N-methyl-pyrrolidone (NMP) [36]; both... than considering only the surface energies or Hildebrand solubility pa- rameters of the solvents and materials [40, 41]. Experimental evidence suggests that NMP and CHP are two of the more suitable solvents for TMDs [41]. However, it is challenging...

  8. Mo-98(p,d)mo-97 Reaction and Core Coupling in Mo-97 and Nb-97 

    E-Print Network [OSTI]

    Bindal, P. K.; Youngblood, David H.; Kozub, R. L.; Hoffmannpinther, P. H.

    1975-01-01

    . Hoffmann-Pinther Physics Department, Ohio University, Athens, Ohio 45701 Q,eceived 14 April 1975). The Mo(P, d)9 Mo reaction has been used at a bombarding energy of 38.6 MeV to popu- late neutron hole states of S~Mo. Excitation energies and angular... distributions were mea- sured for levels up to 4.5 MeV in excitation. A distorted-wave-Born-approximation analy- sis was used to make l assignments and to obtain spectroscopic factors. Three distinct groups of weakly excited levels, one corresponding to l=4...

  9. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect (OSTI)

    KAPLAN, DANIEL

    2005-09-13

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

  10. Balance the reaction MnO4 (aq) MnO2(s) + SO4

    E-Print Network [OSTI]

    Peterson, Kirk A.

    Balance the reaction MnO4 Ð (aq) + SO3 2Ð (aq) MnO2(s) + SO4 2Ð (aq) in basic solution Oxidation 2Ð SO4 2Ð (b) 2) These are already balanced in Mn and S 3) Balance O in (a) by adding H2OÕs to the right-hand-side MnO4 Ð MnO2 + 2H2O 4) Balance H by adding H + to the left-hand-side MnO4 Ð + 4H + MnO2

  11. Observation of a new charged charmoniumlike state inB<mo stretchy='false'>¯mo>>0mn> stretchy='false'>?mo>J<mo>/mo>?K<mo>-mo>?<mo>+>decays

    SciTech Connect (OSTI)

    Chilikin, K.; Mizuk, R.; Adachi, I.; Aihara, H.; Al Said, S.; Arinstein, K.; Asner, D.?M.; Aulchenko, V.; Aushev, T.; Ayad, R.; Aziz, T.; Bakich, A.?M.; Bansal, V.; Bondar, A.; Bonvicini, G.; Bozek, A.; Bra?ko, M.; Browder, T.?E.; ?ervenkov, D.; Chekelian, V.; Chen, A.; Cheon, B.?G.; Chistov, R.; Cho, K.; Chobanova, V.; Choi, S.-K.; Choi, Y.; Cinabro, D.; Danilov, M.; Doležal, Z.; Drásal, Z.; Drutskoy, A.; Dutta, K.; Eidelman, S.; Epifanov, D.; Farhat, H.; Fast, J.?E.; Ferber, T.; Frost, O.; Gaur, V.; Gabyshev, N.; Ganguly, S.; Garmash, A.; Gillard, R.; Goh, Y.?M.; Golob, B.; Grzymkowska, O.; Haba, J.; Hara, T.; Hayasaka, K.; Hayashii, H.; He, X.?H.; Hou, W.-S.; Huschle, M.; Hyun, H.?J.; Ishikawa, A.; Itoh, R.; Iwasaki, Y.; Jaegle, I.; Joo, K.?K.; Julius, T.; Kawasaki, T.; Kiesling, C.; Kim, D.?Y.; Kim, H.?J.; Kim, J.?H.; Kim, M.?J.; Kim, Y.?J.; Kinoshita, K.; Ko, B.?R.; Korpar, S.; Križan, P.; Krokovny, P.; Kuhr, T.; Kuzmin, A.; Kwon, Y.-J.; Lange, J.?S.; Li, Y.; Li Gioi, L.; Libby, J.; Liu, Y.; Liventsev, D.; Lukin, P.; Miyabayashi, K.; Miyata, H.; Mohanty, G.?B.; Moll, A.; Mori, T.; Mussa, R.; Nakano, E.; Nakao, M.; Nanut, T.; Natkaniec, Z.; Nedelkovska, E.; Nisar, N.?K.; Nishida, S.; Ogawa, S.; Okuno, S.; Olsen, S.?L.; Pakhlov, P.; Pakhlova, G.; Park, C.?W.; Park, H.; Pedlar, T.?K.; Petri?, M.; Piilonen, L.?E.; Ribežl, E.; Ritter, M.; Rostomyan, A.; Sakai, Y.; Sandilya, S.; Santelj, L.; Sanuki, T.; Sato, Y.; Savinov, V.; Schneider, O.; Schnell, G.; Schwanda, C.; Seon, O.; Shebalin, V.; Shen, C.?P.; Shibata, T.-A.; Shiu, J.-G.; Shwartz, B.; Sibidanov, A.; Simon, F.; Sohn, Y.-S.; Sokolov, A.; Solovieva, E.; Stari?, M.; Steder, M.; Sumisawa, K.; Sumiyoshi, T.; Tamponi, U.; Tanida, K.; Tatishvili, G.; Teramoto, Y.; Thorne, F.; Trabelsi, K.; Uchida, M.; Uehara, S.; Uglov, T.; Unno, Y.; Uno, S.; Urquijo, P.; Van Hulse, C.; Vanhoefer, P.; Varner, G.; Vinokurova, A.; Wagner, M.?N.; Wang, C.?H.; Wang, M.-Z.; Wang, P.; Wang, X.?L.; Watanabe, Y.; Wehle, S.; Williams, K.?M.; Won, E.; Yamaoka, J.; Yashchenko, S.; Zhang, Z.?P.; Zhilich, V.; Zhulanov, V.; Zupanc, A.

    2014-12-16

    We present the results of an amplitude analysis of B¯0?J/?K-?+ decays. A new charged charmoniumlike state Zc(4200)+ decaying to J/??+ is observed with a significance of 6.2?. The mass and width of the Zc(4200)+ are 4196+31-29+17-13 MeV/c2 and 370+70-70+70-132 MeV, respectively; the preferred assignment of the quantum numbers is JP=1+. In addition, we find evidence for Zc(4430)+?J/??+. The analysis is based on a 711 fb-1 data sample collected by the Belle detector at the asymmetric-energy e+e- collider KEKB.

  12. Neutron Hole States of Mo-99 

    E-Print Network [OSTI]

    Bindal, P. K.; Youngblood, David H.; Kozub, R. L.; Hoffmannpinther, P. H.

    1975-01-01

    V; measured o(0), 99Mo levels, deduced l, S; calculated J, 7(, 8, particle-core-coupling model. I. INTRODUCTION II. EXPERIMENTAL PROCEDURE AND RESULTS Recent studies of proton and neutron configura- tions of odd-A nuclei in the mass region of 90?100 have... of "'"'"Nb was obtained' ' using a quasiparticle core coupling model. Also, study of the ~'Mo(P, d)~Mo reaction' revealed three distinct groups of weakly excited neutron hole states, one corresponding to an l = 4 transf er and two corresponding...

  13. Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney

    E-Print Network [OSTI]

    Nagurney, Anna

    of considering waste management. Ladimer S. Nagurney The 99 Mo Supply Chain #12;Nuclear Medicine To createThe 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney Department of Electrical November 13, 2012 #12;Nuclear Medicine: Meeting Patient Needs with 99 Mo Ladimer S. Nagurney The 99 Mo

  14. Fast-timing measurements in 95,96Mo

    E-Print Network [OSTI]

    S. Kisyov; S. Lalkovski; N. Marginean; D. Bucurescu; L. Atanasova; D. Balabanski; Gh. Cata-Danil; I. Cata-Danil; D. Deleanu; P. Detistov; D. Filipescu; D. Ghita; T. Glodariu; R. Marginean; C. Mihai; A. Negret; S. Pascu; T. Sava; L. Stroe; G. Suliman; N. V. Zamfir; M. Zhekova

    2012-01-12

    Half-lives of the 19/2+ and 21/2+ states in 95Mo and of the 8+ and 10+ states in 96Mo were measured. Matrix elements for yrast transitions in 95Mo and 96Mo are discussed.

  15. 100 E. Normal Street Kirksville, MO 63501

    E-Print Network [OSTI]

    Gering, Jon C.

    . Curran Prendergast Repertoire The 2015 Midwest Band Conductors' Symposium" and address to: Dr. Curran Prendergast, 100 East Normal St. Kirksville, MO 63501.truman.edu/mbcs Clinicians: Dr. Paul Popiel, Director of Bands, University of Kansas Dr. Curran

  16. Relationship between microstructure and acoustic emission in Mn-Mo-Ni A533B steel

    E-Print Network [OSTI]

    Wadley, Haydn

    . Titchmarsh, and H. N. G. Wadley are with AERE Harwell, Oxon, and C. Jones is in the Department of Metallurgy

  17. Materials Data on BaLaMnMoO6 (SG:216) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-19

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. MoS2 Nanoribbons Thermoelectric Generators

    E-Print Network [OSTI]

    Arab, Abbas

    2015-01-01

    In this work, we have designed and simulated new thermoelectric generator based on monolayer and few-layer MoS2 nanoribbons. The proposed thermoelectric generator is composed of thermocouples made of both n-type and p-type MoS2 nanoribbon legs. Density Functional Tight-Binding Non-Equilibrium Green's Function (DFTB-NEGF) method has been used to calculate the transmission spectrum of MoS2 armchair and zigzag nanoribbons. Phonon transmission spectrum are calculated based on parameterization of Stillinger-Weber potential. Thermoelectric figure of merit, ZT, is calculated using these electronic and phonon transmission spectrum. Monolayer and bilayer MoS2 armchair nanoribbons are found to have the highest ZT value for p-type and n-type legs, repectively. Moreover, we have compared the thermoelectric current of doped monolayer MoS2 armchair nanoribbons and SZi thin films. Results indicate that thermoelectric current of MoS2 monolayer nanoribbons is several orders of magnitude higher than that of Si thin films.

  19. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  20. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect (OSTI)

    Liu, Hao; Gao, G. Y. Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L.

    2014-01-21

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52?eV and the magnetic moment of 1.00??{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  1. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

    1987-01-01

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  2. MoS{sub 2} functionalization for ultra-thin atomic layer deposited dielectrics

    SciTech Connect (OSTI)

    Azcatl, Angelica; McDonnell, Stephen; Santosh, K.C.; Peng, Xin; Dong, Hong; Qin, Xiaoye; Addou, Rafik; Lu, Ning; Kim, Moon J.; Cho, Kyeongjae; Wallace, Robert M., E-mail: rmwallace@utdallas.edu [Department of Materials Science and Engineering, The University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080 (United States); Mordi, Greg I. [Department of Electrical Engineering, The University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080 (United States); Kim, Jiyoung [Department of Materials Science and Engineering, The University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080 (United States); Department of Electrical Engineering, The University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080 (United States)

    2014-03-17

    The effect of room temperature ultraviolet-ozone (UV-O{sub 3}) exposure of MoS{sub 2} on the uniformity of subsequent atomic layer deposition of Al{sub 2}O{sub 3} is investigated. It is found that a UV-O{sub 3} pre-treatment removes adsorbed carbon contamination from the MoS{sub 2} surface and also functionalizes the MoS{sub 2} surface through the formation of a weak sulfur-oxygen bond without any evidence of molybdenum-sulfur bond disruption. This is supported by first principles density functional theory calculations which show that oxygen bonded to a surface sulfur atom while the sulfur is simultaneously back-bonded to three molybdenum atoms is a thermodynamically favorable configuration. The adsorbed oxygen increases the reactivity of MoS{sub 2} surface and provides nucleation sites for atomic layer deposition of Al{sub 2}O{sub 3}. The enhanced nucleation is found to be dependent on the thin film deposition temperature.

  3. Tunable MoS{sub 2} bandgap in MoS{sub 2}-graphene heterostructures

    SciTech Connect (OSTI)

    Ebnonnasir, Abbas [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States); Narayanan, Badri; Ciobanu, Cristian V., E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Kodambaka, Suneel, E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States)

    2014-07-21

    Using density functional theory calculations with van der Waals corrections, we investigated how the interlayer orientation affects the structure and electronic properties of MoS{sub 2}-graphene bilayer heterostructures. Changing the orientation of graphene with respect to MoS{sub 2} strongly influences the type and the value of the electronic bandgap in MoS{sub 2}, while not significantly altering the binding energy between the layers or the interlayer spacing. We show that the physical origin of this tunable bandgap arises from variations in the S–S interplanar distance (MoS{sub 2} thickness) with the interlayer orientation, variations which are caused by electron transfer away from the Mo–S bonds.

  4. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

    E-Print Network [OSTI]

    and oxidatively degrade or trans- form numerous organic and inorganic compounds, includ- ing humic and fulvic acids, aromatic hydrocarbons, Cr(III), Co(II), and hydrogen sulfide (Jenne, 1967; Huang, 1991(II)-oxidizing microorganisms in the envi- ronment (Tebo et al., 2004) and upon the much faster rates of Mn(II) oxidation

  5. High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel

    DOE Patents [OSTI]

    Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Oak Ridge, TN) [Oak Ridge, TN

    2010-07-13

    An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.

  6. Elevated Temperature Tensile Tests on DU–10Mo Rolled Foils

    SciTech Connect (OSTI)

    Schulthess, Jason

    2014-09-01

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U–10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU–10Mo) mechanical behavior is representative of the low enriched U–10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  7. Comprehensive amplitude analysis of ??<mo stretchy='false'>?mo>?<mo>+mo>?<mo>-,?>0mn>?>0mn> and K<mo accent='true' stretchy='true'>¯mo>K below 1.5 GeV

    SciTech Connect (OSTI)

    Dai, Ling-Yun; Pennington, Michael R.

    2014-08-15

    In this paper we perform an amplitude analysis of essentially all published pion and kaon pair production data from two photon collisions below 1.5 GeV. This includes all the high statistics results from Belle, as well as older data from Mark II at SLAC, CELLO at DESY, Crystal Ball at SLAC. The purpose of this analysis is to provide as close to a model-independent determination of the ?? to meson pair amplitudes as possible. Having data with limited angular coverage, typically |cos?| < 0.6-0.8, and no polarization information for reactions in which spin is an essential complication, the determination of the underlying amplitudes might appear an intractable problem. However, imposing the basic constraints required by analyticity, unitarity, and crossing-symmetry makes up for the experimentally missing information. Above 1.5 GeV multi-meson production channels become important and we have too little information to resolve the amplitudes. Nevertheless, below 1.5 GeV the two photon production of hadron pairs serves as a paradigm for the application of S-matrix techniques. Final state interactions among the meson pairs is critical to this analysis. To fix these, we include the latest ?? ? ??, K?K scattering amplitudes given by dispersive analyses, supplemented in the K?K threshold region by the recent precision Dalitz plot analysis from BaBar. With these hadronic amplitudes built into unitarity, we can constrain the overall description of ?? ? ?? and K?K datasets, both integrated and differential cross-sections, including the high statistics charged and neutral pion data from Belle. A region of solutions is found for the ?? ? ?? partial waves with both isospin 0 and 2. Since this analysis invokes coupled hadronic channels, even the relatively poor integrated cross-section data on ?? ? K?K narrows the patch of solutions to essentially a single form. For this we present the complete partial wave amplitudes, show how well they fit all the available data, and give the two photon couplings of scalar and tensor resonances that appear.

  8. Search for proton decay via p<mo stretchy='false'>?mo>?K<mo>+> using <mn>260mn> kiloton<mo>·>year data of Super-Kamiokande

    SciTech Connect (OSTI)

    Abe, K.; Hayato, Y.; Iyogi, K.; Kameda, J.; Miura, M.; Moriyama, S.; Nakahata, M.; Nakayama, S.; Wendell, R.?A.; Sekiya, H.; Shiozawa, M.; Suzuki, Y.; Takeda, A.; Takenaga, Y.; Ueno, K.; Yokozawa, T.; Kaji, H.; Kajita, T.; Kaneyuki, K.; Lee, K.?P.; Okumura, K.; McLachlan, T.; Labarga, L.; Kearns, E.; Raaf, J.?L.; Stone, J.?L.; Sulak, L.?R.; Goldhaber, M.; Bays, K.; Carminati, G.; Kropp, W.?R.; Mine, S.; Renshaw, A.; Smy, M.?B.; Sobel, H.?W.; Ganezer, K.?S.; Hill, J.; Keig, W.?E.; Jang, J.?S.; Kim, J.?Y.; Lim, I.?T.; Albert, J.?B.; Scholberg, K.; Walter, C.?W.; Wongjirad, T.; Ishizuka, T.; Tasaka, S.; Learned, J.?G.; Matsuno, S.; Smith, S.?N.; Hasegawa, T.; Ishida, T.; Ishii, T.; Kobayashi, T.; Nakadaira, T.; Nakamura, K.; Nishikawa, K.; Oyama, Y.; Sakashita, K.; Sekiguchi, T.; Tsukamoto, T.; Suzuki, A.?T.; Takeuchi, Y.; Ieki, K.; Ikeda, M.; Kubo, H.; Minamino, A.; Murakami, A.; Nakaya, T.; Fukuda, Y.; Choi, K.; Itow, Y.; Mitsuka, G.; Miyake, M.; Mijakowski, P.; Hignight, J.; Imber, J.; Jung, C.?K.; Taylor, I.; Yanagisawa, C.; Ishino, H.; Kibayashi, A.; Koshio, Y.; Mori, T.; Sakuda, M.; Takeuchi, J.; Kuno, Y.; Kim, S.?B.; Okazawa, H.; Choi, Y.; Nishijima, K.; Koshiba, M.; Totsuka, Y.; Yokoyama, M.; Martens, K.; Marti, Ll.; Obayashi, Y.; Vagins, M.?R.; Chen, S.; Sui, H.; Yang, Z.; Zhang, H.; Connolly, K.; Dziomba, M.; Wilkes, R.?J.

    2014-10-14

    We have searched for proton decay via p??K+ using Super-Kamiokande data from April 1996 to February 2013, 260 kiloton•year exposure in total. No evidence for this proton decay mode is found. A lower limit of the proton lifetime is set to ?/B(p??K+)>5.9×1033 years at 90% confidence level.

  9. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  10. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  11. Mn/DOT's Project Peer Review

    E-Print Network [OSTI]

    Minnesota, University of

    issue we share with peers) ·Benchmark Mn/DOT's project management practices ·Initial step in a change decision- making ·Able to manage project change #12;Project Management Opportunities and Challenges ·TheMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research

  12. Accelerator Production Options for 99MO

    SciTech Connect (OSTI)

    Bertsche, Kirk; /SLAC

    2010-08-25

    Shortages of {sup 99}Mo, the most commonly used diagnostic medical isotope, have caused great concern and have prompted numerous suggestions for alternate production methods. A wide variety of accelerator-based approaches have been suggested. In this paper we survey and compare the various accelerator-based approaches.

  13. Temperature and composition phase diagram in the iron-based ladder compounds Ba <mn>1mn> <mo>-> x Cs x Fe <mn>2mn> Se <mn>3mn>

    SciTech Connect (OSTI)

    Hawai, Takafumi; Nambu, Yusuke; Ohgushi, Kenya; Du, Fei; Hirata, Yasuyuki; Avdeev, Maxim; Uwatoko, Yoshiya; Sekine, Yurina; Fukazawa, Hiroshi; Ma, Jie; Chi, Songxue; Ueda, Yutaka; Yoshizawa, Hideki; Sato, Taku J.

    2015-05-28

    We investigated the iron-based ladder compounds (Ba,Cs)Fe?Se?. Their parent compounds BaFe?Se? and CsFe?Se? have different space groups, formal valences of Fe, and magnetic structures. Electrical resistivity, specific heat, magnetic susceptibility, x-ray diffraction, and powder neutron diffraction measurements were conducted to obtain a temperature and composition phase diagram of this system. Block magnetism observed in BaFe?Se? is drastically suppressed with Cs doping. In contrast, stripe magnetism observed in CsFe?Se? is not so fragile against Ba doping. A new type of magnetic structure appears in intermediate compositions, which is similar to stripe magnetism of CsFe?Se?, but interladder spin configuration is different. Intermediate compounds show insulating behavior, nevertheless a finite T-linear contribution in specific heat was obtained at low temperatures.

  14. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H.; Karppinen, M.

    2011-05-15

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  15. Development of CaMoO4 crystal scintillators for double beta decay experiment with 100-Mo

    E-Print Network [OSTI]

    A. N. Annenkov; O. A. Buzanov; F. A. Danevich; A. Sh. Georgadze; S. K. Kim; H. J. Kim; Y. D. Kim; V. V. Kobychev; V. N. Kornoukhov; M. Korzhik; J. I. Lee; O. Missevitch; V. M. Mokina; S. S. Nagorny; A. S. Nikolaiko; D. V. Poda; R. B. Podviyanuk; D. J. Sedlak; O. G. Shkulkova; J. H. So; I. M. Solsky; V. I. Tretyak; S. S. Yurchenko

    2007-07-10

    Energy resolution, alpha/beta ratio, pulse-shape discrimination for gamma rays and alpha particles, temperature dependence of scintillation properties, and radioactive contamination were studied with CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed.

  16. SSL Demonstration: Bridge Lighting, Minneapolis, MN

    SciTech Connect (OSTI)

    2014-10-01

    DOE Solid-State Lighting GATEWAY summary brief for Phase II report on the longer-term performance of LED lighting installed in 2008 on the I-35W Bridge in Minneapolis, MN.

  17. Measurement of Double-Polarization Asymmetries in the Quasielastic He<mo stretchy='true'>?mo>>3mn> stretchy='false'>(mo>e<mo stretchy='false'>?mo><mo>,mo>e<mo>'d stretchy='false'>)mo> Process

    SciTech Connect (OSTI)

    Mihovilovic, M.; Jin, G.; Long, E.; Zhang, Y. -W.; Allada, K.; Anderson, B.; Annand, J. R.M.; Averett, T.; Boeglin, W.; Bradshaw, P.; Camsonne, A.; Canan, M.; Cates, G. D.; Chen, C.; Chen, J. P.; Chudakov, E.; De Leo, R.; Deng, X.; Deltuva, A.; Deur, A.; Dutta, C.; El Fassi, L.; Flay, D.; Frullani, S.; Garibaldi, F.; Gao, H.; Gilad, S.; Gilman, R.; Glamazdin, O.; Golak, J.; Golge, S.; Gomez, J.; Hansen, O.; Higinbotham, D. W.; Holmstrom, T.; Huang, J.; Ibrahim, H.; de Jager, C. W.; Jensen, E.; Jiang, X.; Jones, M.; Kang, H.; Katich, J.; Khanal, H. P.; Kievsky, A.; King, P.; Korsch, W.; LeRose, J.; Lindgren, R.; Lu, H. -J.; Luo, W.; Marcucci, L. E.; Markowitz, P.; Meziane, M.; Michaels, R.; Moffit, B.; Monaghan, P.; Muangma, N.; Nanda, S.; Norum, B. E.; Pan, K.; Parno, D.; Piasetzky, E.; Posik, M.; Punjabi, V.; Puckett, A. J.R.; Qian, X.; Qiang, Y.; Qui, X.; Riordan, S.; Saha, A.; Sauer, P. U.; Sawatzky, B.; Schiavilla, R.; Schoenrock, B.; Shabestari, M.; Shahinyan, A.; Sirca, S.; Skibinski, R.; St John, J.; Subedi, R.; Sulkosky, V.; Tobias, W. A.; Tireman, W.; Urciuoli, G. M.; Viviani, M.; Wang, D.; Wang, K.; Wang, Y.; Watson, J.; Wojtsekhowski, B.; Witala, H.; Ye, Z.; Zhan, X.; Zhang, Y.; Zheng, X.; Zhao, B.; Zhu, L.

    2014-12-05

    We present a precise measurement of double-polarization asymmetries in the 3He(e,e'd) reaction. This particular process is a uniquely sensitive probe of hadron dynamics in 3He and the structure of the underlying electromagnetic currents. The measurements have been performed in and around quasi-elastic kinematics at Q2=0.25(GeV/c)2 for missing momenta up to 270MeV/c. The asymmetries are in fair agreement with the state-of-the-art calculations in terms of their functional dependencies on pm and omega, but are systematically offset. Beyond the region of the quasi-elastic peak, the discrepancies become even more pronounced. Thus, our measurements have been able to reveal deficiencies in the most sophisticated calculations of the three-body nuclear system, and indicate that further refinement in the treatment of their two- and/or three-body dynamics is required.

  18. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS Users'ALS

  19. Effective Landé factor in a GaMnAs quantum dot; with the effects of sp-d exchange on a bound polaron

    SciTech Connect (OSTI)

    Lalitha, D., E-mail: a.john.peter@gmail.com; Peter, A. John, E-mail: a.john.peter@gmail.com [Dept. of Physics, Government Arts College, Melur-625106, Tamilnadu (India)

    2014-04-24

    The effective g-factor of conduction (valence) band electron (hole) is obtained in the GaMnAs quantum dot. Magneto bound polaron in a GaMnAs/Ga{sub 0.6}Al{sub 0.4}As quantum dot is investigated with the inclusion of exchange interaction effects due to Mn alloy content and the geometrical confinement. The spin polaronic energy of the heavy hole exciton is studied with the spatial confinement using a mean field theory in the presence of magnetic field strength.

  20. Demonstration of LED Street Lighting in Kansas City, MO Kinzey...

    Office of Scientific and Technical Information (OSTI)

    Street Lighting in Kansas City, MO Kinzey, Bruce R.; Royer, Michael P.; Hadjian, M.; Kauffman, Rick LED streetlighting; field illuminance measurement LED streetlighting; field...

  1. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

    2001-01-01

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  2. Local environment of Mn in Mn delta-doped Si layers

    SciTech Connect (OSTI)

    Xiao, Q.F.; Kahwaji, S.; Monchesky, T.L.; Gordon, R.A.; Crozier, E.D.

    2009-11-09

    Dilute magnetic semiconductors combine both magnetic ordering and semiconducting behaviour, leading to potential spintronic applications. Silicon containing dilute Mn impurities is a potential dilute magnetic semiconductor. We have grown Mn delta-doped films by deposition of 0.7 of a monolayer of Mn on Si(001) by molecular beam epitaxy and capping the film with Si. The magnetic properties are likely sensitive to the distribution of Mn on substitutional or interstitial sites and the formation of metallic precipitates. We have used polarization-dependent XAFS to examine the local structure. We compare to a thicker MnSi film grown on Si(111) and also examine the influence of lead on the manganese environment when used as a surfactant in the growth process.

  3. Mo-99 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal of Honor recipients honored at Y-12CONTROLLEDStatements |Mo-99 |

  4. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect (OSTI)

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  5. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar ?-MoC(001) and orthorhombic C- or Mo-terminated polar ?-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on ?-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on ?-MoC(001), indicating that the Mo:C ratio and the surface polarity playmore »a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated ?-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.« less

  6. Magnetic fields of HgMn stars

    E-Print Network [OSTI]

    Hubrig, S; Ilyin, I; Korhonen, H; Schoeller, M; Savanov, I; Arlt, R; Castelli, F; Curto, G Lo; Briquet, M; Dall, T H

    2012-01-01

    The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. We re-analyse available spectropolarimetric material by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD65949 and the hotter analog of HgMn stars, the PGa star HD19400, using FORS2 installed at the VLT. We also give new measurements of the eclipsing system AR Aur with a primary star of HgMn peculiarity which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. We downloaded from the ESO archive the publically available HARPS spectra for eight HgMn stars and one normal and one superficially normal B-type star obtained in 2010. The application of the moment technique to the HARPS and SOFIN spectra allowed us to study the presence of the longitudina...

  7. Identification of a high-spin isomer in {sup 99}Mo.

    SciTech Connect (OSTI)

    Jones, G. A.; Regan, P. H.; Walker, P. M.; Podolyak, Zs.; Steveson, P. D.; Carpenter, M. P.; Janssens, R. V. F.; Khoo, T. L.; Kondev, F. G.; Lane, G. J.; Liu, Z.; Seweryniak, D.; Thompson, N. J.; Zhu, S.; Williams, S. J.; Carroll, J. J.; Chakrawarthy, R. S.; Chowdhury, P.; Garnsworthy, A. B.; Carroll, J. J.; Chakrawarthy, R. S.; Univ. of Surrey; Youngstown Univ.; TRIUMF; Univ. of Massachusetts Lowell; Australian National Univ.

    2007-10-01

    A previously unreported isomer has been identified in {sup 99}Mo at an excitation energy of E{sub x} = 3010 keV, decaying with a half-life of T{sub 1/2} = 8(2) ns. The nucleus of interest was produced following fusion-fission reactions between a thick {sup 27}Al target frame and a {sup 178}Hf beam at a laboratory energy of 1150 MeV. This isomeric state is interpreted as an energetically favored, maximally aligned configuration of {nu}h 11/2 {circle_times} {pi}(g 9/2){sup 2}.

  8. Identification of a high-spin isomer in {sup 99}Mo

    SciTech Connect (OSTI)

    Jones, G. A.; Regan, P. H.; Walker, P. M.; Podolyak, Zs.; Stevenson, P. D.; Garnsworthy, A. B.; Liu, Z.; Thompson, N. J. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); Carpenter, M. P.; Janssens, R. V. F.; Khoo, T. L.; Seweryniak, D.; Zhu, S. [Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Carroll, J. J. [Department of Physics and Astronomy, Youngstown, Ohio 44555 (United States); Chakrawarthy, R. S. [TRIUMF, 4004 Westbrook Mall, Vancouver, British Columbia V6T 2A3 (Canada); Chowdhury, P. [University of Massachusetts Lowell, Lowell, Massachusetts 01854 (United States); Kondev, F. G. [Nuclear Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Lane, G. J. [Department of Nuclear Physics, RSPhysSE, Australian National University, Canberra 0200 (Australia); Williams, S. J. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); TRIUMF, 4004 Westbrook Mall, Vancouver, British Columbia V6T 2A3 (Canada)

    2007-10-15

    A previously unreported isomer has been identified in {sup 99}Mo at an excitation energy of E{sub x}=3010 keV, decaying with a half-life of T{sub 1/2}=8(2) ns. The nucleus of interest was produced following fusion-fission reactions between a thick {sup 27}Al target frame and a {sup 178}Hf beam at a laboratory energy of 1150 MeV. This isomeric state is interpreted as an energetically favored, maximally aligned configuration of {nu}h{sub (11/2)} x {pi}(g{sub (9/2)}){sup 2}.

  9. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore »a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) ?B and 0.81(4)?B, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  10. AL. I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VANaval Ordnance,:n5.5.8GE 1A L L'-AL.

  11. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level79AJ01)19^ U N I TALSALSSpectroscopyALS

  12. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS Users'ALSQuick

  13. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS

  14. Industry @ ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumpsfacility doe logoInIndustry @ ALS

  15. Reviw Al

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996 2.003 1990-2016 East CoastReviw Al now ..

  16. Energy absorption in Ni-Mn-Ga/ polymer composites

    E-Print Network [OSTI]

    Feuchtwanger, Jorge

    2006-01-01

    In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

  17. Fragile structural transition in Mo3Sb7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-08-10

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near amore »critical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.« less

  18. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  19. Theory of weak localization in ferromagnetic (Ga,Mn)As 

    E-Print Network [OSTI]

    Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

    2009-01-01

    We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

  20. Mo-O bond doping and related-defect assisted enhancement of photoluminescence in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Wei, Xiaoxu; Yu, Zhihao; Cheng, Ying; Yu, Linwei; Wang, Junzhuan Wang, Xinran; Shi, Yi; Hu, Fengrui; Wang, Xiaoyong; Xiao, Min

    2014-12-15

    In this work, we report a strong photoluminescence (PL) enhancement of monolayer MoS{sub 2} under different treatments. We find that by simple ambient annealing treatment in the range of 200?°C to 400?°C, the PL emission can be greatly enhanced by a factor up to two orders of magnitude. This enhancement can be attributed to two factors: first, the formation of Mo-O bonds during ambient exposure introduces an effective p-doping in the MoS{sub 2} layer; second, localized electrons formed around Mo-O bonds related defective sites where the electrons can be effectively localized with higher binding energy resulting in efficient radiative excitons recombination. Time resolved PL decay measurement showed that longer lifetime of the treated sample consistent with the higher quantum efficiency in PL. These results give more insights to understand the luminescence properties of the MoS{sub 2}.

  1. Cd{sub 1?x}Mn{sub x}Te ultrasmall quantum dots growth in a silicate glass matrix by the fusion method

    SciTech Connect (OSTI)

    Dantas, Noelio Oliveira; Lima Fernandes, Guilherme de; Almeida Silva, Anielle Christine [Laboratório de Novos Materiais Isolantes e Semicondutores (LNMIS), Instituto de Física, Universidade Federal de Uberlândia, 38408-100 Uberlândia, MG (Brazil); Baffa, Oswaldo; Gómez, Jorge Antônio [Departamento de Física, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, 14040-901 Ribeirão Preto, SP (Brazil)

    2014-09-29

    In this study, we synthesized Cd{sub 1?x}Mn{sub x}Te ultrasmall quantum dots (USQDs) in SiO{sub 2}-Na{sub 2}CO{sub 3}-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3} glass system using the fusion method. Growth of these Cd{sub 1?x}Mn{sub x}Te USQDs was confirmed by optical absorption, atomic force microscopy (AFM), magnetic force microscopy (MFM), scanning transmission electron microscopy (TEM), and electron paramagnetic resonance (EPR) measurements. The blueshift of absorption transition with increasing manganese concentration gives evidence of incorporation of manganese ions (Mn{sup 2+}) in CdTe USQDs. AFM, TEM, and MFM confirmed, respectively, the formation of high quality Cd{sub 1?x}Mn{sub x}Te USQDs with uniformly distributed size and magnetic phases. Furthermore, EPR spectra showed six lines associated to the S?=?5/2 spin half-filled d-state, characteristic of Mn{sup 2+}, and confirmed that Mn{sup 2+} are located in the sites core and surface of the CdTe USQD. Therefore, synthesis of high quality Cd{sub 1?x}Mn{sub x}Te USQDs may allow the control of optical and magnetic properties.

  2. Formation of MnSb during the growth of MnSi layers in the presence of an Sb flux

    E-Print Network [OSTI]

    Pennycook, Steve

    Epitaxial growth of silicide layers on Si substrates has attracted much attention due to their technologicalFormation of MnSb during the growth of MnSi layers in the presence of an Sb flux K. Matsuda, Y have been performed to elucidate the growth mechanism. The MnSi layer was grown by reactive deposition

  3. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    SciTech Connect (OSTI)

    Taylor, Alice E [ORNL; Berlijn, Tom [ORNL; Hahn, Steven E [ORNL; May, Andrew F [ORNL; Williams, Travis J [ORNL; Poudel, Lekhanath N [ORNL; Calder, Stuart A [ORNL; Fishman, Randy Scott [ORNL; Stone, Matthew B [ORNL; Aczel, Adam A [ORNL; Cao, Huibo [ORNL; Lumsden, Mark D [ORNL; Christianson, Andrew D [ORNL

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int

  4. ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries

    SciTech Connect (OSTI)

    Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

    2012-01-01

    Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0.04Co02O2 electrode containing 5 wt% single-walled carbon nanotubes as the conductive additive and demonstrated both high rate capability as well as the ability to cycle the cathode to 5 V vrs. Li/Li+. Finally, we coated a Celgard (TM) separator and enabled stable cycling in a high dielectric electrolyte. These results will be presented in detail.

  5. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect (OSTI)

    Goetsch, Ryan J; Anand, V K; Johnston, David C

    2014-08-01

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  6. Materials Data on Mn3Mo2H34C22N16O5 (SG:15) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-05-17

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on Mn3Mo2H34C22N16O5 (SG:15) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Observation of D<mn>0mn> meson nuclear modifications in Au<mo>+>Au collisions at sNN<mo>=>200mn> GeV

    SciTech Connect (OSTI)

    Adamczyk, L.; Adkins, J.?K.; Agakishiev, G.; Aggarwal, M.?M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Anson, C.?D.; Aparin, A.; Arkhipkin, D.; Aschenauer, E.?C.; Averichev, G.?S.; Banerjee, A.; Beavis, D.?R.; Bellwied, R.; Bhasin, A.; Bhati, A.?K.; Bhattarai, P.; Bichsel, H.; Bielcik, J.; Bielcikova, J.; Bland, L.?C.; Bordyuzhin, I.?G.; Borowski, W.; Bouchet, J.; Brandin, A.?V.; Brovko, S.?G.; Bültmann, S.; Bunzarov, I.; Burton, T.?P.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Cebra, D.; Cendejas, R.; Cervantes, M.?C.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, H.?F.; Chen, J.?H.; Chen, L.; Cheng, J.; Cherney, M.; Chikanian, A.; Christie, W.; Chwastowski, J.; Codrington, M.?J.?M.; Contin, G.; Cramer, J.?G.; Crawford, H.?J.; Cui, X.; Das, S.; Davila Leyva, A.; De Silva, L.?C.; Debbe, R.?R.; Dedovich, T.?G.; Deng, J.; Derevschikov, A.?A.; Derradi de Souza, R.; Dhamija, S.; di Ruzza, B.; Didenko, L.; Dilks, C.; Ding, F.; Djawotho, P.; Dong, X.; Drachenberg, J.?L.; Draper, J.?E.; Du, C.?M.; Dunkelberger, L.?E.; Dunlop, J.?C.; Efimov, L.?G.; Engelage, J.; Engle, K.?S.; Eppley, G.; Eun, L.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Fedorisin, J.; Filip, P.; Finch, E.; Fisyak, Y.; Flores, C.?E.; Gagliardi, C.?A.; Gangadharan, D.?R.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Gliske, S.; Greiner, L.; Grosnick, D.; Gunarathne, D.?S.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Haag, B.; Hamed, A.; Han, L.-X.; Haque, R.; Harris, J.?W.; Heppelmann, S.; Hirsch, A.; Hoffmann, G.?W.; Hofman, D.?J.; Horvat, S.; Huang, B.; Huang, H.?Z.; Huang, X.; Huck, P.; Humanic, T.?J.; Igo, G.; Jacobs, W.?W.; Jang, H.; Judd, E.?G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H.?W.; Keane, D.; Kechechyan, A.; Kesich, A.; Khan, Z.?H.; Kikola, D.?P.; Kisel, I.; Kisiel, A.; Koetke, D.?D.; Kollegger, T.; Konzer, J.; Koralt, I.; Kotchenda, L.; Kraishan, A.?F.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R.?A.; Lamont, M.?A.?C.; Landgraf, J.?M.; Landry, K.?D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J.?H.; LeVine, M.?J.; Li, C.; Li, W.; Li, X.; Li, X.; Li, Y.; Li, Z.?M.; Lisa, M.?A.; Liu, F.; Ljubicic, T.; Llope, W.?J.; Lomnitz, M.; Longacre, R.?S.; Luo, X.; Ma, G.?L.; Ma, Y.?G.; Madagodagettige Don, D.?M.?M.?D.; Mahapatra, D.?P.; Majka, R.; Margetis, S.; Markert, C.; Masui, H.; Matis, H.?S.; McDonald, D.; McShane, T.?S.; Minaev, N.?G.; Mioduszewski, S.; Mohanty, B.; Mondal, M.?M.; Morozov, D.?A.; Mustafa, M.?K.; Nandi, B.?K.; Nasim, Md.; Nayak, T.?K.; Nelson, J.?M.; Nigmatkulov, G.; Nogach, L.?V.; Noh, S.?Y.; Novak, J.; Nurushev, S.?B.; Odyniec, G.; Ogawa, A.; Oh, K.; Ohlson, A.; Okorokov, V.; Oldag, E.?W.; Olvitt, D.?L.; Pachr, M.; Page, B.?S.; Pal, S.?K.; Pan, Y.?X.; Pandit, Y.; Panebratsev, Y.; Pawlak, T.; Pawlik, B.; Pei, H.; Perkins, C.; Peryt, W.; Pile, P.; Planinic, M.; Pluta, J.; Poljak, N.; Porter, J.; Poskanzer, A.?M.; Pruthi, N.?K.; Przybycien, M.; Pujahari, P.?R.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R.?L.; Riley, C.?K.; Ritter, H.?G.; Roberts, J.?B.; Rogachevskiy, O.?V.; Romero, J.?L.; Ross, J.?F.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N.?R.; Sahu, P.?K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sangaline, E.; Sarkar, A.; Schambach, J.; Scharenberg, R.?P.; Schmah, A.?M.; Schmidke, W.?B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P.?V.; Shao, M.; Sharma, B.; Shen, W.?Q.; Shi, S.?S.; Shou, Q.?Y.; Sichtermann, E.?P.; Singaraju, R.?N.; Skoby, M.?J.; Smirnov, D.; Smirnov, N.; Solanki, D.; Sorensen, P.; Spinka, H.?M.; Srivastava, B.; Stanislaus, T.?D.?S.; Stevens, J.?R.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Sun, X.; Sun, X.?M.; Sun, Y.; Sun, Z.; Surrow, B.; Svirida, D.?N.; Symons, T.?J.?M.; Szelezniak, M.?A.; Takahashi, J.; Tang, A.?H.; Tang, Z.; Tarnowsky, T.; Thomas, J.?H.; Timmins, A.?R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R.?E.; Tribedy, P.; Trzeciak, B.?A.; Tsai, O.?D.; Turnau, J.; Ullrich, T.; Underwood, D.?G.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Vanfossen, J.?A.; Varma, R.; Vasconcelos, G.?M.?S.; Vasiliev, A.?N.; Vertesi, R.; Videbæk, F.; Viyogi, Y.?P.; Vokal, S.; Vossen, A.; Wada, M.; Wang, F.; Wang, G.; Wang, H.; Wang, J.?S.; Wang, X.?L.; Wang, Y.; Wang, Y.; Webb, G.; Webb, J.?C.; Westfall, G.?D.; Wieman, H.; Wissink, S.?W.; Witt, R.; Wu, Y.?F.; Xiao, Z.; Xie, W.; Xin, K.; Xu, H.; Xu, J.; Xu, N.

    2014-09-30

    We report the first measurement of charmed-hadron (D0) production via the hadronic decay channel (D0?K-+?+) in Au+Au collisions at ?sNN=200 GeV with the STAR experiment. The charm production cross section per nucleon-nucleon collision at midrapidity scales with the number of binary collisions, Nbin, from p+p to central Au+Au collisions. The D0 meson yields in central Au+Aucollisions are strongly suppressed compared to those in p+p scaled by Nbin, for transverse momenta pT>3 GeV/c, demonstrating significant energy loss of charm quarks in the hot and dense medium. An enhancement at intermediate pT is also observed. Model calculations including strong charm-medium interactions and coalescence hadronization describe our measurements.

  9. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  10. Q value of the 100Mo Double-Beta Decay

    E-Print Network [OSTI]

    S. Rahaman; V. -V. Elomaa; T. Eronen; J. Hakala; A. Jokinen; J. Julin; A. Kankainen; A. Saastamoinen; J. Suhonen; C. Weber; J. Äystö

    2007-12-20

    Penning trap measurements using mixed beams of 100Mo - 100Ru and 76Ge - 76Se have been utilized to determine the double-beta decay Q-values of 100Mo and 76Ge with uncertainties less than 200 eV. The value for 76Ge, 2039.04(16) keV is in agreement with the published SMILETRAP value. The new value for 100Mo, 3034.40(17) keV is 30 times more precise than the previous literature value, sufficient for the ongoing neutrinoless double-beta decay searches in 100Mo. Moreover, the precise Q-value is used to calculate the phase-space integrals and the experimental nuclear matrix element of double-beta decay.

  11. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    Sullivan, John M.

    MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians and na* *tural scientists. When discretized, such energies can lead to effective algorith* *ms

  12. Co-Mo Electric Cooperative- Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to its residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. Heat...

  13. Microstructures in rapidly solidified Ni-Mo alloys

    SciTech Connect (OSTI)

    Jayaraman, N.; Tewari, S.N.; Hemker, K.J.; Glasgow, T.K.

    1985-01-01

    Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by chill block melt spinning in vacuum and were examined by optical metallography, x-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

  14. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  15. Low-Cost High-Performance Solid-State Asymmetric Supercapacitors Based on MnO2 Nanowires and Fe2O3 Nanotubes

    E-Print Network [OSTI]

    Wang, Zhong L.

    performance. For example, Lu et al. developed a solid-state flexible ASC device with hydrogenated TiO2@MnO2 core-shell nanowires (NWs) as the positive electrode and hydro- genated TiO2@C core-shell NWs Nanotubes Peihua Yang, Yong Ding, Ziyin Lin, Zhongwei Chen, Yuzhi Li, Pengfei Qiang, Masood Ebrahimi, Wenjie

  16. Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM ) Mo2, MoW, and W2)

    E-Print Network [OSTI]

    Turro, Claudia

    Quadruply Bonded Dimetal Units Supported by 2,4,6-Triisopropylbenzoates MM(TiPB)4 (MM ) Mo2, Mo, and cyclic voltammetry) of the new compounds MM(TiPB)4, where MM ) MoW and W2 and TiPB ) 2 in the visible region of the spectrum that are assigned to MM to arylcarboxylate * transitions, 1 MLCT. Each

  17. Materials Data on LiAl(MoO4)2 (SG:2) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. BUDVYTIS ET AL.: MOT FOR VIDEO SEGMENTATION 1 MoT -Mixture of Trees Probabilistic

    E-Print Network [OSTI]

    Martin, Ralph R.

    occlusion handling, label drift caused by round-off errors, high cost of multi- label MAP inference for this model to estimate super-pixel labels and their confidences in nearly realtime. The effi- cacy of our as in [19],[8]. However for tasks requiring semantic label propagation in video sequences, satisfactory

  19. Solution-based thermodynamic modeling of the Ni-Al-Mo system using

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System in the CERNimmobilize spent electrochemical

  20. Reactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    A T O C H A , * , E V E R T J . E L Z I N G A , A N D D O N A L D L . S P A R K S DepartmentReactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface C H R I S T O P H E R J . M and surface functional groups on R-Al2O3 depending on the specific surface site exposed. The uptake of Pb

  1. Tuning magnetism of monolayer MoS{sub 2} by doping vacancy and applying strain

    SciTech Connect (OSTI)

    Zheng, Huiling; Yang, Baishun; Han, Ruilin; Du, Xiaobo; Yan, Yu; Wang, Dingdi

    2014-03-31

    In view of important role of inducing and manipulating the magnetism in two-dimensional materials for the development of low-dimensional spintronic devices, the influences of strain on electronic structure and magnetic properties of commonly observed vacancies doped monolayer MoS{sub 2} are investigated using first-principles calculations. It is shown that unstrained V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} systems are nonmagnetic, while the ground state of unstrained V{sub MoS6} doped system is magnetic and the magnetic moment is contributed mainly by six Mo atoms around V{sub MoS6}. In particular, tensile strain can induce magnetic moments in V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} due to the breaking of Mo–Mo metallic bonds around the vacancies, while the magnetization induced by V{sub MoS6} can be effectively manipulated by equibiaxial strain due to the change of Mo–Mo metallic bonds around V{sub MoS6} under strains.

  2. Ni.sub.3 Al-based intermetallic alloys having improved strength above 850.degree. C.

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN)

    2000-01-01

    Intermetallic alloys composed essentially of: 15.5% to 17.0% Al, 3.5% to 5.5% Mo, 4% to 8% Cr, 0.04% to 0.2% Zr, 0.04% to 1.5% B, balance Ni, are characterized by melting points above 1200.degree. C. and superior strengths at temperatures above 1000.degree. C.

  3. Experimental and first-principles study of ferromagnetism in Mn-doped zinc stannate nanowires

    SciTech Connect (OSTI)

    Deng Rui; Zhou Hang; Qin Jieming; Wan Yuchun; Jiang Dayong; Liang Qingcheng [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Li Yongfeng [Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012 (China); Wu, Tom [Physical Sciences and Engineering Division, Solar and Photovoltaics Engineering Research Center, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Saudi Arabia); Yao Bin [State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012 (China); Liu Lei [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, No.3888 Dongnanhu Road, Changchun 130033 (China)

    2013-07-21

    Room temperature ferromagnetism was observed in Mn-doped zinc stannate (ZTO:Mn) nanowires, which were prepared by chemical vapor transport. Structural and magnetic properties and Mn chemical states of ZTO:Mn nanowires were investigated by X-ray diffraction, superconducting quantum interference device (SQUID) magnetometry and X-ray photoelectron spectroscopy. Manganese predominantly existed as Mn{sup 2+} and substituted for Zn (Mn{sub Zn}) in ZTO:Mn. This conclusion was supported by first-principles calculations. Mn{sub Zn} in ZTO:Mn had a lower formation energy than that of Mn substituted for Sn (Mn{sub Sn}). The nearest neighbor Mn{sub Zn} in ZTO stabilized ferromagnetic coupling. This observation supported the experimental results.

  4. Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof 

    E-Print Network [OSTI]

    Seo, Dongmin

    2009-05-15

    This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

  5. Electron tunneling studies of Mn12-Acetate 

    E-Print Network [OSTI]

    Ma, Lianxi

    2008-10-10

    laser deposition (PLD) was used to deposit two monolayers of Mn 12 -Acetate on thin Pt wires (diame- ter 0.001 in). The electron tunneling current was measured with typical bias voltages from -1 to 1 V at liquid helium temperature, 4.2 K. I, dI/dV, and d... 2 I/dV 2 signals were directly acquired with the aid of a current amplifier and two lock-in-amplifiers. Results show that the differential conductance is approximately 10 ?6 S for bias volt- ages 0.04 V ?|V |? 1 V and exhibits a strong voltage...

  6. Spin caloritronics in graphene with Mn

    SciTech Connect (OSTI)

    Torres, Alberto Lima, Matheus P. Fazzio, A.; Silva, Antônio J. R. da

    2014-02-17

    We show that graphene with Mn adatoms trapped at single vacancies features spin-dependent Seebeck effect, thus enabling the use of this material for spin caloritronics. A gate potential can be used to tune its thermoelectric properties in a way it presents either a total spin polarized current, flowing in one given direction, or currents for both spins flowing in opposite directions without net charge transport. Moreover, we show that the thermal magnetoresistance can be tuned between ?100% and +100% by varying a gate potential.

  7. Adsorption and Electronic States of Benzene on Ordered MgO and Al2O3 Thin Films S. C. Street, Q. Guo, C. Xu, and D. W. Goodman*

    E-Print Network [OSTI]

    Goodman, Wayne

    Adsorption and Electronic States of Benzene on Ordered MgO and Al2O3 Thin Films S. C. Street, Q structure of benzene (C6H6) on thin film MgO(100)/Mo(100) and highly ordered Al2O3/Mo(110) substrates have, upright (end-on) adsorption of benzene on the monolayer-covered surface. Large exposures of benzene yield

  8. Ligand Bridging-Angle-Driven Assembly of Molecular Architectures Based on Quadruply Bonded Mo-Mo Dimers

    SciTech Connect (OSTI)

    Li, Jian-Rong; Yakovenko, Andrey A; Lu, Weigang; Timmons, Daren J; Zhuang, Wenjuan; Yuan, Daqiang; Zhou, Hong-Cai

    2010-12-15

    A systematic exploration of the assembly of Mo?(O?C-)?-based metal–organic molecular architectures structurally controlled by the bridging angles of rigid organic linkers has been performed. Twelve bridging dicarboxylate ligands were designed to be of different sizes with bridging angles of 0, 60, 90, and 120° while incorporating a variety of nonbridging functional groups, and these ligands were used as linkers. These dicarboxylate linkers assemble with quadruply bonded Mo–Mo clusters acting as nodes to give 13 molecular architectures, termed metal–organic polygons/polyhedra with metal cluster node arrangements of a linear shape, triangle, octahedron, and cuboctahedron/anti-cuboctahedron. The syntheses of these complexes have been optimized and their structures determined by single-crystal X-ray diffraction. The results have shown that the shape and size of the resulting molecular architecture can be controlled by tuning the bridging angle and size of the linker, respectively. Functionalization of the linker can adjust the solubility of the ensuing molecular assembly but has little or no effect on the geometry of the product. Preliminary gas adsorption, spectroscopic, and electrochemical properties of selected members were also studied. The present work is trying to enrich metal-containing supramolecular chemistry through the inclusion of well-characterized quadruply bonded Mo–Mo units into the structures, which can widen the prospect of additional electronic functionality, thereby leading to novel properties.

  9. ALS User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS User Meeting Print web banner ALS User Meeting: October 5-7, 2015 Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User Meeting...

  10. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

    2014-08-21

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  11. Magnetic coupling in neutral and charged Cr{sub 2}, Mn{sub 2}, and CrMn dimers

    SciTech Connect (OSTI)

    Desmarais, N. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Reuse, F. A. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Khanna, S. N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    2000-04-01

    Theoretical ab initio studies of neutral, cationic and anionic Cr{sub 2}, Mn{sub 2}, and CrMn dimers have been carried out to explore the progression of magnetic coupling with the number of electrons. It is shown that while Cr{sub 2} and Cr{sub 2}{sup -} have antiferromagnetically coupled atomic spins, Cr{sub 2}{sup +} has a ferromagnetic ground state closely followed by an antiferromagnetic state. On the other hand, all Mn{sub 2} dimers are ferromagnetic, irrespective of the charge. The neutral CrMn is ferrimagnetic while the charged CrMn are antiferromagnetic. In all cases, the charged dimers are found to be more stable than the neutral ones. The results are compared with available calculations and experiments and the difficulties associated with theoretical description and the experimental interpretations are discussed. (c) 2000 American Institute of Physics.

  12. One Jump Ahead: Interspecies Interations and Distribution of Jumping Spiders on Mo'orea

    E-Print Network [OSTI]

    Pena, Danielle L

    2009-01-01

    Unlike continents, an island system such as Mo’orea oftenflora and fauna. In island systems, these relationships can

  13. Scintillating bolometers based on ZnMoO$_4$ and Zn$^{100}$MoO$_4$ crystals to search for 0$?$2$?$ decay of $^{100}$Mo (LUMINEU project): first tests at the Modane Underground Laboratory

    E-Print Network [OSTI]

    D. V. Poda; E. Armengaud; Q. Arnaud; C. Augier; A. Benoît; A. Benoît; L. Bergé; R. S. Boiko; T. Bergmann; J. Blümer; A. Broniatowski; V. Brudanin; P. Camus; A. Cazes; B. Censier; M. Chapellier; F. Charlieux; D. M. Chernyak; N. Coron; P. Coulter; G. A. Cox; F. A. Danevich; T. de Boissière; R. Decourt; M. De Jesus; L. Devoyon; A. -A. Drillien; L. Dumoulin; K. Eitel; C. Enss; D. Filosofov; A. Fleischmann; N. Fourches; J. Gascon; L. Gastaldo; G. Gerbier; A. Giuliani; M. Gros; L. Hehn; S. Henry; S. Hervé; G. Heuermann; V. Humbert; I. M. Ivanov; A. Juillard; C. Kéfélian; M. Kleifges; H. Kluck; V. V. Kobychev; F. Koskas; V. Kozlov; H. Kraus; V. A. Kudryavtsev; H. Le Sueur; M. Loidl; P. Magnier; E. P. Makarov; M. Mancuso; P. de Marcillac; S. Marnieros; C. Marrache-Kikuchi; A. Menshikov; S. G. Nasonov; X-F. Navick; C. Nones; E. Olivieri; P. Pari; B. Paul; Y. Penichot; G. Pessina; M. C. Piro; O. Plantevin; T. Redon; M. Robinson; M. Rodrigues; S. Rozov; V. Sanglard; B. Schmidt; V. N. Shlegel; B. Siebenborn; O. Strazzer; D. Tcherniakhovski; M. Tenconi; L. Torres; V. I. Tretyak; L. Vagneron; Ya. V. Vasiliev; M. Velazquez; O. Viraphong; R. J. Walker; M. Weber; E. Yakushev; X. Zhang; V. N. Zhdankov

    2015-02-04

    The technology of scintillating bolometers based on zinc molybdate (ZnMoO$_4$) crystals is under development within the LUMINEU project to search for 0$\

  14. Running A Conference Justin Zobel # Alistair Mo#at +

    E-Print Network [OSTI]

    Zobel, Justin

    Running A Conference Justin Zobel # Alistair Mo#at + Last updated August 2003 1 Introduction Much of the research in computer science is published in conferences, often complex a#airs in­ cluding paper presentations, tutorials, workshops, invited speakers, and tours and entertainment. Even a small conference has

  15. ECE 1228 Electromagnetics Theory Instructor Name: Mo Mojahedi

    E-Print Network [OSTI]

    Mojahedi, Mohammad

    ECE 1228 Electromagnetics Theory Instructor Name: Mo Mojahedi Office Location: Room SF2001D Tel: 416-978-0908 Email: mojahedi@waves.utoronto.ca Course Name and number: Electromagnetics Theory, ECE in Electromagnetics and Photonics. It revisits and expands some of the more fundamental electromagnetic laws

  16. (Robert P. Biuk-Aghai), , , : robertb@umac.mo

    E-Print Network [OSTI]

    Biuk-Aghai, Robert P.

    1 * (Robert P. Biuk-Aghai), , , : robertb@umac.mo (GIS) TM 30 1111 (PC) (PDAs) (ITU) 2002 [1] (PDAs) (GIS) (GIS)- 2 34 5 * . #12;2 2222 2001 2002 (PDA) PalmOS Pocket Telecommunication Union, 2003. http://www.itu.org/. 2. Robert P. Biuk-Aghai. A mobile GIS application for heavily

  17. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H.; Bennett, Wendy D.; Doherty, Ann L.; Fuller, E. S.; Hardy, John S.; Omberg, Ronald P.

    2014-08-28

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30°C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  18. NeMO 2004 Cruise Report R/V Thomas G. Thompson

    E-Print Network [OSTI]

    NeMO 2004 Cruise Report R/V Thomas G. Thompson Compiled by Shannon Ristau and Susan Merle TN 173 18: Pictures from ROPOS Dives............................................................3 Figure 1: NeMO 2004....................................................9 1.0 NeMO 2004 SCIENCE SUMMARY (Bill Chadwick)........................................11 1

  19. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01

    Mn-Si (red squares) and Mn-Ge distances (blue circles) d asof the number of Si or Ge nearest neighbours N c ; (c) localthree Mn atoms with different N c in a-Mn 0.094 Ge 0.906 .

  20. Study of the beta delayed particle emission from 48Mn and its relevance for explosive nucleosynthesis

    E-Print Network [OSTI]

    Martel, I

    2015-01-01

    Study of the beta delayed particle emission from 48Mn and its relevance for explosive nucleosynthesis

  1. Inverse spin Hall effect in Pt/(Ga,Mn)As

    SciTech Connect (OSTI)

    Nakayama, H.; Chen, L.; Chang, H. W.; Ohno, H.; Matsukura, F.

    2015-06-01

    We investigate dc voltages under ferromagnetic resonance in a Pt/(Ga,Mn)As bilayer structure. A part of the observed dc voltage is shown to originate from the inverse spin Hall effect. The sign of the inverse spin Hall voltage is the same as that in Py/Pt bilayer structure, even though the stacking order of ferromagnetic and nonmagnetic layers is opposite to each other. The spin mixing conductance at the Pt/(Ga,Mn)As interface is determined to be of the order of 10{sup 19?}m{sup ?2}, which is about ten times greater than that of (Ga,Mn)As/p-GaAs.

  2. Scintillating bolometers based on ZnMoO$_4$ and Zn$^{100}$MoO$_4$ crystals to search for 0$\

    E-Print Network [OSTI]

    Poda, D V; Arnaud, Q; Augier, C; Benoît, A; Bergé, L; Boiko, R S; Bergmann, T; Blümer, J; Broniatowski, A; Brudanin, V; Camus, P; Cazes, A; Censier, B; Chapellier, M; Charlieux, F; Chernyak, D M; Coron, N; Coulter, P; Cox, G A; Danevich, F A; de Boissière, T; Decourt, R; De Jesus, M; Devoyon, L; Drillien, A -A; Dumoulin, L; Eitel, K; Enss, C; Filosofov, D; Fleischmann, A; Fourches, N; Gascon, J; Gastaldo, L; Gerbier, G; Giuliani, A; Gros, M; Hehn, L; Henry, S; Hervé, S; Heuermann, G; Humbert, V; Ivanov, I M; Juillard, A; Kéfélian, C; Kleifges, M; Kluck, H; Kobychev, V V; Koskas, F; Kozlov, V; Kraus, H; Kudryavtsev, V A; Sueur, H Le; Loidl, M; Magnier, P; Makarov, E P; Mancuso, M; de Marcillac, P; Marnieros, S; Marrache-Kikuchi, C; Menshikov, A; Nasonov, S G; Navick, X-F; Nones, C; Olivieri, E; Pari, P; Paul, B; Penichot, Y; Pessina, G; Piro, M C; Plantevin, O; Redon, T; Robinson, M; Rodrigues, M; Rozov, S; Sanglard, V; Schmidt, B; Shlegel, V N; Siebenborn, B; Strazzer, O; Tcherniakhovski, D; Tenconi, M; Torres, L; Tretyak, V I; Vagneron, L; Vasiliev, Ya V; Velazquez, M; Viraphong, O; Walker, R J; Weber, M; Yakushev, E; Zhang, X; Zhdankov, V N

    2015-01-01

    The technology of scintillating bolometers based on zinc molybdate (ZnMoO$_4$) crystals is under development within the LUMINEU project to search for 0$\

  3. Facile synthesis of MoS{sub 2} and Mo{sub x}W{sub 1-x}S{sub 2} triangular monolayers

    SciTech Connect (OSTI)

    Lin, Zhong; Thee, Michael T.; Elías, Ana Laura; Feng, Simin; Fujisawa, Kazunori; Perea-López, Néstor; Carozo, Victor [Department of Physics and Center for 2Dimensional and Layered Materials, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Zhou, Chanjing [Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Terrones, Humberto [Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, New York 122180 (United States); Terrones, Mauricio, E-mail: mut11@psu.edu [Department of Physics and Center for 2Dimensional and Layered Materials, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

    2014-09-01

    Single- and few-layered transition metal dichalcogenides, such as MoS{sub 2} and WS{sub 2}, are emerging two-dimensional materials exhibiting numerous and unusual physico-chemical properties that could be advantageous in the fabrication of unprecedented optoelectronic devices. Here we report a novel and alternative route to synthesize triangular monocrystals of MoS{sub 2} and Mo{sub x}W{sub 1-x}S{sub 2} by annealing MoS{sub 2} and MoS{sub 2}/WO{sub 3} precursors, respectively, in the presence of sulfur vapor. In particular, the Mo{sub x}W{sub 1-x}S{sub 2} triangular monolayers show gradual concentration profiles of W and Mo whereby Mo concentrates in the islands’ center and W is more abundant on the outskirts of the triangular monocrystals. These observations were confirmed by atomic force microscopy, and high-resolution transmission electron microscopy, as well as Raman and photoluminescence spectroscopy. The presence of tunable PL signals depending on the Mo{sub x}W{sub 1-x}S{sub 2} stoichiometries in 2D monocrystals opens up a wide range of applications in electronics and optoelectronics.

  4. NaAlH4 dehydrogenation properties enhanced by MnFe2O4 nanoparticles

    E-Print Network [OSTI]

    Volinsky, Alex A.

    , University of Science and Technology Beijing, Beijing 100083, China d Department of Mechanical Engineering hydrides have received increased attention due to their high volumetric and gravimetric hydrogen storage. Among various complex metal hydrides [1,8e17], sodium alanates are considered to be a prom- ising solid

  5. Materials Data on MnAlCo2 (SG:225) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on MnAlCo2 (SG:225) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Thermal transport properties of metal/MoS{sub 2} interfaces from first principles

    SciTech Connect (OSTI)

    Mao, Rui; Kong, Byoung Don; Kim, Ki Wook, E-mail: kwk@ncsu.edu [Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, North Carolina 27695-7911 (United States)

    2014-07-21

    Thermal transport properties at the metal/MoS{sub 2} interfaces are analyzed by using an atomistic phonon transport model based on the Landauer formalism and first-principles calculations. The considered structures include chemisorbed Sc(0001)/MoS{sub 2} and Ru(0001)/MoS{sub 2}, physisorbed Au(111)/MoS{sub 2}, as well as Pd(111)/MoS{sub 2} with intermediate characteristics. Calculated results illustrate a distinctive dependence of thermal transfer on the details of interfacial microstructures. More specifically, the chemisorbed case with a stronger bonding exhibits a generally smaller interfacial thermal resistance than the physisorbed. Comparison between metal/MoS{sub 2} and metal/graphene systems suggests that metal/MoS{sub 2} is significantly more resistive. Further examination of lattice dynamics identifies the presence of multiple distinct atomic planes and bonding patterns at the interface as the key origins of the observed large thermal resistance.

  8. Electronic interactions between gold films and mn12-acetate 

    E-Print Network [OSTI]

    Means, Joel Lewis

    2009-05-15

    Interactions between Mn12–acetate molecular magnets and thin gold films have been explored in light of the theory of weak localization. Low-temperature measurements of the magnetoresistance of gold films of varying thicknesses, with and without...

  9. Ambi-site substitution of Mn in lanthanum germanate apatites

    SciTech Connect (OSTI)

    Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2009-08-05

    A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

  10. Undercooled and rapidly quenched Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid.

  11. Does MoSE cope with inland tsunamis hazard?

    E-Print Network [OSTI]

    Panza, Giuliano Francesco; Romanelli, Fabio

    2014-01-01

    In this work we use morphostructural zonation and pattern recognition techniques to identify a potential seismic source located inland very near Venice, and then we evaluate how a tsunami wave generated from this source can affect the MoSE gates if they are standing up (closed) during the tsunami event. From our simulation we get both peaks and troughs as first arrivals: the behavior of the barriers in these two situations could be a very important design matter.

  12. Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II

    SciTech Connect (OSTI)

    Mishra, A.; Yano, J.; Pushkar, Y.; Abboud, K.A.; Yachandra, V.K.; Christou, G.

    2009-06-03

    Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

  13. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle; Marra, James; Fox, Kevin; Reppert, Jason; Crum, Jarrod; Tang, Ming

    2012-09-17

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  14. Interdiffusion and Reaction between Zr and Al Alloys from 425 degrees to 625 degrees C

    SciTech Connect (OSTI)

    J. Dickson; L. Zhou; A. Ewh; M. Fu; D. D. Keiser, Jr.; Y. H. Sohn; A. Paz y Puente

    2014-06-01

    Zirconium has recently garnered attention for use as a diffusion barrier between U–Mo nuclear fuels and Al cladding alloys. Interdiffusion and reactions between Zr and Al, Al-2 wt.% Si, Al-5 wt.% Si or AA6061 were investigated using solid-to-solid diffusion couples annealed in the temperature range of 425 degrees to 625 degrees C. In the binary Al and Zr system, the Al3Zr and Al2Zr phases were identified, and the activation energy for the growth of the Al3Zr phase was determined to be 347 kJ/mol. Negligible diffusional interactions were observed for diffusion couples between Zr vs. Al-2 wt.% Si, Al-5 wt.% Si and AA6061 annealed at or below 475 degrees C. In diffusion couples with the binary Al–Si alloys at 560 degrees C, a significant variation in the development of the phase constituents was observed including the thick t1 (Al5SiZr2) with Si content up to 12 at.%, and thin layers of (Si,Al)2Zr, (Al,Si)3Zr, Al3SiZr2 and Al2Zr phases. The use of AA6061 as a terminal alloy resulted in the development of both T1 (Al5SiZr2) and (Al,Si)3Zr phases with a very thin layer of (Al,Si)2Zr. At 560 degrees C, with increasing Si content in the Al–Si alloy, an increase in the overall rate of diffusional interaction was observed; however, the diffusional interaction of Zr in contact with multicomponent AA6061 with 0.4–0.8 wt.% Si was most rapid.

  15. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01

    Magnetization data for a-Mn 0.15 Ge 0.85 ?lms mea- suredSi 1?x and a-Mn x Ge 1?x samples. . . . . . . . . . . . . .both a-Mn x Si 1?x and a-Mn x Ge 1?x as a func- tion of Mn

  16. High-performance MoS{sub 2} transistors with low-resistance molybdenum contacts

    SciTech Connect (OSTI)

    Kang, Jiahao; Liu, Wei; Banerjee, Kaustav, E-mail: kaustav@ece.ucsb.edu [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

    2014-03-03

    In this Letter, molybdenum (Mo) is introduced and evaluated as an alternative contact metal to atomically-thin molybdenum disulphide (MoS{sub 2}), and high-performance field-effect transistors are experimentally demonstrated. In order to understand the physical nature of the interface and highlight the role of the various factors contributing to the Mo-MoS{sub 2} contacts, density functional theory (DFT) simulations are employed, which reveal that Mo can form high quality contact interface with monolayer MoS{sub 2} with zero tunnel barrier and zero Schottky barrier under source/drain contact, as well as an ultra-low Schottky barrier (0.1?eV) at source/drain-channel junction due to strong Fermi level pinning. In agreement with the DFT simulations, high mobility, high ON-current, and low contact resistance are experimentally demonstrated on both monolayer and multilayer MoS{sub 2} transistors using Mo contacts. The results obtained not only reveal the advantages of using Mo as a contact metal for MoS{sub 2} but also highlight the fact that the properties of contacts with 2-dimensional materials cannot be intuitively predicted by solely considering work function values and Schottky theory.

  17. Ferromagnetic response of multiferroic TbMnO{sub 3} films mediated by epitaxial strain and chemical pressure

    SciTech Connect (OSTI)

    Izquierdo, J.; Morán, O.; Astudillo, A.; Bolaños, G.; Arnache, O.

    2014-05-07

    High quality Tb{sub 1?x}Al{sub x}MnO{sub 3} (x?=?0, 0.3) films have been grown under different values of compressive/tensile strain using (001)-oriented SrTiO{sub 3} and MgO substrates. The films were grown by means of rf sputtering at substrate temperature of 800??°C. X-ray diffraction analysis shows that films are single phase, preferentially oriented in the (111) and (122) directions for films deposited on SrTiO{sub 3} and MgO substrates, respectively. Although the TbMnO{sub 3} target shows antiferromagnetic order, the films deposited on both substrates show weak ferromagnetic phase at low temperature coexisting with the antiferromagnetic phase. The introduction of Al in the films clearly enhances their ferromagnetic behavior, improving the magnetic performance of this material. Indeed, M(H) measurements at 5?K show a well-defined hysteresis for films grown on both substrates. However, a stronger magnetic signal (larger values of remanence and coercive field) is observed for films deposited on MgO substrates. The chemical pressure generated by Al doping together with the substrate-induced strain seem to modify the subtle competition between magnetic interactions in the system. It is speculated that such modification could lead to a non-collinear magnetic state that may be tuned by strain modifications. This may be performed by varying the thickness of the films and/or considering other substrate materials.

  18. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Electron phonon coupling in a system with broken symmetry Surface of math mrow mi Be mi mo mo mn mn mo mo mrow math Chien TeYu He Xiaobo Mo Sung Kwan Hashimoto Makoto Hussain Zahid...

  19. Electron-phonon coupling in a system with broken symmetry: Surface

    Office of Scientific and Technical Information (OSTI)

    Electron-phonon coupling in a system with broken symmetry: Surface ofBe<mo>(>0001<mn>)> Chien, TeYu; He, Xiaobo; Mo, Sung-Kwan;...

  20. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Electron-phonon coupling in a system with broken symmetry: Surface ofBe<mo>(>0001<mn>)>","Chien, TeYu; He, Xiaobo; Mo,...

    1. Segregation of Mn2+ Dopants as Interstitials in SrTiO3 Grain Boundaries

      SciTech Connect (OSTI)

      Yang, Hao; Kotula, Paul G.; Sato, Yukio; Chi, Miaofang; Ikuhara, Yuichi; Browning, Nigel D.

      2013-10-03

      Mn doped SrTiO3 shows promising magnetic and electrical properties, but the doping mechanism remains unclear. In this research Mn4+ is found to substitute Ti in bulk SrTiO3, but Mn2+ segregates inside grain boundaries at both Sr and interstitial sites. Mn interstitial doping has never been reported, but is found possible with the formation of Sr vacancies. This finding is significantly different from the amphoteric doping of Mn2+ substituting Sr and Mn4+ substituting Ti sites, therefore leads to different understanding on the defect mediated electrical and magnetic properties of transition metal doped perovskites.

    2. Functional Mn–Mg{sub k} cation complexes in GaN featured by Raman spectroscopy

      SciTech Connect (OSTI)

      Devillers, T. Bonanni, A.; Leite, D. M. G.; Department of Physics, São Paulo State University, Bauru–SP ; Dias da Silva, J. H.

      2013-11-18

      The evolution of the optical branch in the Raman spectra of (Ga,Mn)N:Mg epitaxial layers as a function of the Mn and Mg concentrations, reveals the interplay between the two dopants. We demonstrate that the various Mn-Mg-induced vibrational modes can be understood in the picture of functional Mn–Mg{sub k} complexes formed when substitutional Mn cations are bound to k substitutional Mg through nitrogen atoms, the number of ligands k being driven by the ratio between the Mg and the Mn concentrations.

    3. Spectroscopic variability and magnetic fields of HgMn stars

      E-Print Network [OSTI]

      Hubrig, S; Ilyin, I; Korhonen, H; Savanov, I S; Dall, T; Schoeller, M; Cowley, C R; Briquet, M; Arlt, R

      2011-01-01

      The discovery of exotic abundances, chemical inhomogeneities, and weak magnetic fields on the surface of late B-type primaries in spectroscopic binaries has important implications not only for our understanding of the formation mechanisms of stars with Hg and Mn peculiarities themselves, but also for the general understanding of B-type star formation in binary systems. The origin of the abundance anomalies observed in late B-type stars with HgMn peculiarity is still poorly understood. The connection between HgMn peculiarity and membership in binary and multiple systems is supported by our observations during the last decade. The important result achieved in our studies of a large sample of HgMn stars is the finding that most HgMn stars exhibit spectral variability of various chemical elements, proving that the presence of an inhomogeneous distribution on the surface of these stars is a rather common characteristic and not a rare phenomenon. Further, in the studied systems, we found that all components are che...

    4. The blue supergiant MN18 and its bipolar circumstellar nebula

      E-Print Network [OSTI]

      Gvaramadze, V V; Bestenlehner, J M; Bodensteiner, J; Langer, N; Greiner, J; Grebel, E K; Berdnikov, L N; Beletsky, Y

      2015-01-01

      We report the results of spectrophotometric observations of the massive star MN18 revealed via discovery of a bipolar nebula around it with the Spitzer Space Telescope. Using the optical spectrum obtained with the Southern African Large Telescope, we classify this star as B1 Ia. The evolved status of MN18 is supported by the detection of nitrogen overabundance in the nebula, which implies that it is composed of processed material ejected by the star. We analysed the spectrum of MN18 by using the code CMFGEN, obtaining a stellar effective temperature of \\approx 21 kK. The star is highly reddened, E(B-V)\\approx 2 mag. Adopting an absolute visual magnitude of M_V=-6.8\\pm0.5 (typical of B1 supergiants), MN18 has a luminosity of log L/Lsun \\approx 5.42\\pm0.30, a mass-loss rate of \\approx (2.8-4.5)\\times10^{-7} Msun/yr, and resides at a distance of \\approx 5.6^{+1.5} _{-1.2} kpc. We discuss the origin of the nebula around MN18 and compare it with similar nebulae produced by other blue supergiants in the Galaxy (She...

    5. Cmara et al.Cmara et al.Cmara et al.Cmara et al. A Unified Framework For Spatial Data MoA Unified Framework For Spatial Data MoA Unified Framework For Spatial Data MoA Unified Framework For Spatial Data Moddddelselselsels Towards A Unified Framework ForTo

      E-Print Network [OSTI]

      de Figueiredo, Luiz Henrique

      , interoperabilty issues and language proposal. Keywords: Geographical Information Systems,Spatial Databases into a GIS (geographical information system) is a process which includes: · An informal description- eral in any information system, these decisions are cru- cially important in the case of spatial data

    6. NNSA NPO M&O Contract Placement Team receives DOE 2015 Secretary...

      National Nuclear Security Administration (NNSA)

      NPO M&O Contract Placement Team receives DOE 2015 Secretary's Achievement Award | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission...

    7. Model studies of hydrodesulfurization by Mo. Annual technical progress report, December 1, 1991--November 30, 1992

      SciTech Connect (OSTI)

      Friend, C.M.

      1992-11-01

      Effects of surface modifiers (Co, S) on activity and selectivity of Mo(110) for desulfurization processes were studied. S generally increases the selectivity for desulfurization while decreasing overall reactivity. Co promots C-H activation processes on Mo(110). The Mo(110)-(9x2)-Co surface affects the desulfurization of 2,5- dihydrothiophene and methanethiol. Vibrational spectroscopy is being used for determining molecular orientation; vibrational frequencies were calculated for four labeled 2-propoxide isomers on Mo(110) and found to agree with experiment.

    8. Origin of the high work function and high conductivity of MoO3

      E-Print Network [OSTI]

      Guo, Yuzheng; Robertson, John

      2014-12-04

      ) and organic photovoltaics (OPVs) [6-12], and as an anode or hole transfer dopant for graphene and MoS2 devices [10-15]. Given its high work function, band gap and defect induced conductivity, it is important to understand how these properties arise... functional. The partial DOS in Fig 2(b) shows that CBM consists of Mo d orbitals while the VBM consists of O p orbitals. This is because MoO3 is a standard closed shell d0 system. The Mo-O bonds are polar, resulting in a large band gap. We now discuss...

    9. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

      SciTech Connect (OSTI)

      Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

      2010-01-01

      {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

    10. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

      SciTech Connect (OSTI)

      Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

      2014-09-30

      To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

    11. Management and Operating (M&O) Contracts | U.S. DOE Office of...

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Management and Operating (M&O) Contracts Integrated Support Center (ISC) ISC Home About Services Freedom of Information Act (FOIA) Privacy Act NEPA Documents Contact Information...

    12. Synthesis of molybdenum disulfide (MoS{sub 2}) for lithium ion battery applications

      SciTech Connect (OSTI)

      Feng Chuanqi; Ma Jun; Li Hua; Zeng Rong; Guo Zaiping; Liu Huakun

      2009-09-15

      This paper reports the use of a rheological phase reaction method for preparing MoS{sub 2} nanoflakes. The characterization by powder X-ray diffraction indicated that MoS{sub 2} had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS{sub 2} nanoflakes had started to curve and partly form MoS{sub 2} nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS{sub 2} nanoflake electrode was also investigated. It was found that the MoS{sub 2} nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS{sub 2} nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS{sub 2} nanoflakes obtained by this method make it possible for MoS{sub 2} to be used as a promising anode material.

    13. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

      SciTech Connect (OSTI)

      Washington Division of URS

      2008-07-01

      This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

    14. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

      Office of Legacy Management (LM)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont,Manufacturing -NevadaCentralPetrolite Corp - MO 08

    15. DOE - Office of Legacy Management -- St Louis Airport - MO 01

      Office of Legacy Management (LM)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co - OH 51SavannahMillKSAirport - MO 01

    16. DOE - Office of Legacy Management -- Washington University - MO 07

      Office of Legacy Management (LM)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VA 03Washington University - MO 07

    17. DOE - Office of Legacy Management -- West Lake Landfill - MO 05

      Office of Legacy Management (LM)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VA 03WashingtonLake Landfill - MO

    18. Co-Mo Electric Coop Inc | Open Energy Information

      Open Energy Info (EERE)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company) JumpIowa: Energy Resources JumpCloverly,Hill,Mo Electric Coop

    19. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Lendinez, S.; Billinge, S. J. L.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

      2015-01-06

      We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amore »single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.« less

    20. HgMn Stars as apparent X-ray emitters

      E-Print Network [OSTI]

      Hubrig, S; Mathys, G

      1998-01-01

      In the ROSAT all-sky survey 11 HgMn stars were detected as soft X-ray emitters (Berghoefer, Schmitt & Cassinelli 1996). Prior to ROSAT, X-ray observations with the Einstein Observatory had suggested that stars in the spectral range B5-A7 are devoid of X-ray emission. Since there is no X-ray emitting mechanism available for these stars (also not for HgMn stars), the usual argument in the case of an X-ray detected star of this spectral type is the existence of an unseen low-mass companion which is responsible for the X-ray emission. The purpose of the present work is to use all available data for our sample of X-ray detected HgMn stars and conclude on the nature of possible companions.

    1. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

      SciTech Connect (OSTI)

      Lendinez, S. [Univ. de Barcelona, Barcelona, Spain (Europe); Billinge, S. J. L. [Columbia Univ., New York, NY (United States); Zarzuela, R. [Univ. de Barcelona, Barcelona, Spain (Europe); Tejada, J. [Univ. de Barcelona, Barcelona, Spain (Europe); Terban, M. W. [Columbia Univ., New York, NY (United States); Espin, J. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Imaz, I. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Maspoch, D. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Chudnovsky, E. M. [City Univ. of New York, Bronx, NY (United States)

      2015-01-01

      We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for a single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.

    2. Assessment of the Diffusive Gradients in Thin-films (DGT) technique to assess the plant availability of Mn in soils.

      E-Print Network [OSTI]

      Mundus, Simon; Husted, Søren; Lombi, Enzo

      2009-01-01

      predicts copper availability to plants. EnvironmentalAttempts to assess Mn availability have been impeded due towill influence the Mn availability. Often flooding of soils

    3. Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)

      E-Print Network [OSTI]

      Guchhait, S.

      2011-01-01

      segregation in Mn-doped Ge”, Journal of Applied Physics 101,Room-temperature ferromagnetism in Ge 1-x Mn x nanowires”,BC high-?/metal gate Ge/C alloy pMOSFETs fabricated directly

    4. Single-molecule magnets assembled from oxime stabilized Mn?III triangles

      E-Print Network [OSTI]

      Stephenson, Casey Justin

      2009-01-01

      100, 157203. Chapter Three “Double-Decker” [NX 4 ] 2 [Mn 8 (76 Chapter Three “Double-Decker” [NX 4 ] 2 [Mn 8 (salox) 6 Opacking effects in two “double decker” complexes of the

    5. Activation of a MnO2 cathode by water-stimulated Mg2+ insertion...

      Office of Scientific and Technical Information (OSTI)

      Activation of a MnO2 cathode by water-stimulated Mg2+ insertion for a magnesium ion battery Citation Details In-Document Search Title: Activation of a MnO2 cathode by...

    6. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation...

      Office of Scientific and Technical Information (OSTI)

      X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in...

    7. Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal

      E-Print Network [OSTI]

      , and absorption spectroscopy. Fe is speciated as goethite, and Mn as romanechite (psilomelane) and 10 A is separated from the other type by goethite. The binary Mn oxide banding pattern is interpreted by a two

    8. In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function...

      Office of Scientific and Technical Information (OSTI)

      In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function of "x" and Size Citation Details In-Document Search Title: In-situ Electrical Conductivity of LixMnO2 Nanowires...

    9. Mn12-acetate thin film patterns and their interaction with superconductors 

      E-Print Network [OSTI]

      Kim, Kyongwan

      2009-05-15

      Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

    10. Magnetization relaxation in (Ga,Mn)As ferromagnetic semiconductors 

      E-Print Network [OSTI]

      Sinova, Jairo; Jungwirth, T.; Liu, X.; Sasaki, Y.; Furdyna, JK; Atkinson, WA; MacDonald, AH.

      2004-01-01

      stream_source_info PhysRevB.69.085209.pdf.txt stream_content_type text/plain stream_size 32392 Content-Encoding ISO-8859-1 stream_name PhysRevB.69.085209.pdf.txt Content-Type text/plain; charset=ISO-8859-1 n . s re... of the theory of the Mn spin- wave dispersion, and reflect the retarded and nonlocal char- acter of the valence-band-hole mediated interactions between Mn moments.11 The Gilbert damping of magnetization pre- cession discussed here is the aspect of this long...

    11. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

      SciTech Connect (OSTI)

      Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

      2014-05-07

      Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

    12. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

      E-Print Network [OSTI]

      Zeng, Li

      2010-01-01

      ferromagnetic Mn 5 Ge 3 for spintronic applications. Phys.dopants of interest for spintronic applications, where both

    13. Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa

      SciTech Connect (OSTI)

      Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

      2011-05-03

      Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

    14. Characterization of U-Mo Foils for AFIP-7

      SciTech Connect (OSTI)

      Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

      2012-11-07

      Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

    15. Elements Strategy Initiative for Structural Materials: ESISM -Cu-Al 600 nm0.6

      E-Print Network [OSTI]

      Takada, Shoji

      ~3% (1) d d (1) d/d (1) (1) [1] ARB dislocation (1) annealing 210 1.2m m ESISM 31 36 49 Mn Cu-Al SUS304 FCC [2] 0.1m [3] Advanced High Strength Steels: AHSS [2,3] -[3}ABCABACBA B twin annealing twindeformation twin C edge dislocation[6] D [6] E FCC {111}[6] #12

    16. Electrochemical Performance of LiMnPO[subscript 4] Synthesized with Off-Stoichiometry

      E-Print Network [OSTI]

      Kang, Byoungwoo

      LiMnPO[subscript 4] was synthesized from an off-stoichiometric mix of starting materials with nominal composition LiMn[subscript 0.9]P[subscript 0.95]O[subscript 4??]. Stoichiometric LiMnPO[subscript 4] with particle size ...

    17. Bis(?[subscript 2]-?[superscript 2]:?[superscript 2]-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo-Mo)

      E-Print Network [OSTI]

      Moroz, Yurii S.

      The title compound, [Mo[subscript 2](C[subscript 11]H[subscript 16]N)[subscript 4](C[subscript 10]H[subscript 11]N)[subscript 2

    18. Magnetic properties of transition metal doped AlN nanosheet: First-principle studies

      SciTech Connect (OSTI)

      Shi, Changmin; Qin, Hongwei Zhang, Yongjia; Hu, Jifan; Ju, Lin

      2014-02-07

      We carry out our first-principles calculations within density functional theory to study the 3d transition metal (TM) doped AlN nanosheets. The calculated results indicate that a stoichiometric AlN nanosheet is graphene-like structure and nonmagnetic. The TM impurities can induce magnetic moments, localized mainly on the 3d TM atoms and neighboring N atoms. Our calculated results of TM-doped nanosheet systems indicate a strong interaction between 3d orbit of TM atom and the 2p orbit of N atoms. In addition, the Mn- and Ni-doped AlN nanosheet with half-metal characters seems to be good candidates for spintronic applications. When substituting two Al atoms, the relative energies of the states between ferromagnetic and antiferromagnetic coupling are investigated sufficiently. The exchange coupling of Co- and Ni-doped AlN nanosheets exhibits a transformation with different distances of two TM atoms and that of Cr-, Mn-, and Fe-doped AlN nanosheets is not changed.

    19. Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}

      SciTech Connect (OSTI)

      López, C.A.; Saleta, M.E.; Pedregosa, J.C.; Sánchez, R.D.; Alonso, J.A.; and others

      2014-02-15

      We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

    20. Nucleosynthesis simulations for the production of the p-nuclei $^{\\text{92}}$Mo and $^{\\text{94}}$Mo in a Supernova type II model

      E-Print Network [OSTI]

      Göbel, Kathrin; Koloczek, Alexander; Pignatari, Marco; Reifarth, René; Schach, René; Sonnabend, Kerstin

      2015-01-01

      We present a nucleosynthesis sensitivity study for the $\\gamma$-process in a Supernova type II model within the NuGrid research platform. The simulations aimed at identifying the relevant local production and destruction rates for the p-nuclei of molybdenum and at determining the sensitivity of the final abundances to these rates. We show that local destruction rates strongly determine the abundance of $^{92}$Mo and $^{94}$Mo, and quantify the impact.

    1. Stability of Graphene doping with MoO_3 and I_2

      E-Print Network [OSTI]

      D’Arsié, Lorenzo; Esconjauregui, Santiago; Weatherup, Robert; Guo, Yuzheng; Bhardwaj, Sunil; Centeno, Alba; Zurutuza, Amaia; Cepek, Cinzia; Robertson, John

      2014-09-08

      We dope graphene by evaporation of MoO_3 or by solution-deposition of I_2 and assess the doping stability for its use as transparent electrodes. Electrical measurements show that both dopants increase the graphene sheet conductivity and find that Mo...

    2. Heme-Solvent Coupling: A Mo ssbauer Study of Myoglobin in Sucrose H. Lichtenegger,* W. Doster,#

      E-Print Network [OSTI]

      Lichtenegger, Helga C.

      Heme-Solvent Coupling: A Mo¨ ssbauer Study of Myoglobin in Sucrose H. Lichtenegger,* W. Doster,# T% sucrose/water, a protein-stabilizing solvent, to vibrational and diffusive modes of the heme iron of CO the iron is fully exposed in the same solvent. The temperature dependence of the Mo¨ ssbauer parameters

    3. AutoMoDe Notations, Methods, and Tools for Model-Based Development of Automotive Software

      E-Print Network [OSTI]

      Braun, Peter

      05AE-268 AutoMoDe ­ Notations, Methods, and Tools for Model-Based Development of Automotive describes the first results from the AutoMoDe project (Automotive Model-based Development), where an integrated methodology for model-based development of automotive control software is being developed

    4. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

      SciTech Connect (OSTI)

      Haider, Julfikar; Hashmi, M. S. J.

      2011-01-17

      In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

    5. Phase Transformations and Microstructural Evolution of Mo-Bearing Stainless Steels

      E-Print Network [OSTI]

      DuPont, John N.

      Phase Transformations and Microstructural Evolution of Mo-Bearing Stainless Steels T.D. ANDERSON, J Transformations and Microstructural Evolution of Mo-Bearing Stainless Steels T.D. ANDERSON, J.N. DUPONT, M.J. PERRICONE, and A.R. MARDER The good corrosion resistance of superaustenitic stainless steel (SASS) alloys

    6. Growing the renewable chemicals and advanced biofuels cluster in MN

      E-Print Network [OSTI]

      Levinson, David M.

      Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

    7. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

      E-Print Network [OSTI]

      Sansongsiri, Sakon

      2008-01-01

      and Related Materials Electrical properties of a-C:Mo filmsNo. DE-AC02-05CH11231. Electrical properties of a-C:Mo filmsair. Film resistivity and electrical activation energy were

    8. Photo-oxidation method using MoS2 nanocluster materials

      DOE Patents [OSTI]

      Wilcoxon, Jess P. (Albuquerque, NM)

      2001-01-01

      A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

    9. Use of micromechanical exfoliation of bulk graphite and MoS2 to establish a graphene/MoS2 junction Rebecca Cioffi1, Geoff Musick2, Yunhao Cao3, Tu Hong3, Yaqiong Xu3

      E-Print Network [OSTI]

      . This will form a Schottky barrier between the graphene, a semimetal and MoS2, a p-type doped semiconductor processing and the semiconductor industry [1]. Two such promising 2-D materials are graphene and molybdenumUse of micromechanical exfoliation of bulk graphite and MoS2 to establish a graphene/MoS2 junction

    10. Synthesis and characterization of model MgO supported catalyst with Pt-Mo interactions.

      SciTech Connect (OSTI)

      Alexeev, O.; Kawi, S.; Gates, B.C. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States); Shelef, M. [Ford Motor Co., Dearborn, MI (United States)] [Ford Motor Co., Dearborn, MI (United States)

      1996-01-04

      MgO supported platinum and platinum-molybdenum catalysts were prepared from organometallic precursors and charaterized structurally to determine how the nature of the bimetallic precursors and the treatment conditions affected the interaction between the two metals. Samples were prepared from [PtCl{sub 2}(PhCN){sub 2}], [PtCl{sub 2}(PhCN){sub 2}] + [Mo(CO){sub 6}], and [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@ characterized by infrared and extended X-ray absorption fine structure (EXAFS) spectroscopies, tranmission electron microscopy, and chemisorption of H{sub 2}, CO, and O{sub 2}. The samples were treated in H{sub 2} at 400{degree}C prior to most of the characterizatons. Incorporation of Mo reduced the chemisorption of CO and of H{sub 2}. EXAFS spectra measured at the Pt L{sub III} edge and at the Mo K edge showed substantial Pt-Mo contributions with a Pt-Mo cordination number of about 2 and an average distance of 2.63 A for the sample prepared from [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@. In constract, no significant Pt-Mo contribution was observed for the sample prepared from [PtCl{sub 2}(PhCN){sub 2}]+ [Mo(CO){sub 6}]. Electron micrographs and EXAFS results show that interaction between Pt and Mo ions in the former sample helped to maintain the platinum in a highly dispersed form, with supported platinum clusters being smaller than about 10 A. 53 refs., 9 figs., 9 tabs.

    11. An Experimental Study of Mn12-Family Molecular Magnets in Isolation with High Spatial Resolution 

      E-Print Network [OSTI]

      Reaves, Kelley Thomas

      2014-12-17

      atoms. The radius of the Mn atoms has been modified from their ionic radius for clarity. . . . . . . . . . . . . 15 2.4 Magnetization of Mn12-Ph powder sample as a function of applied magnetic field at different temperatures, 1.8K ? T ? 10K. The measured... large circles are Mn3+ ions, the lighter colored large circles are Mn4+ ions, the smaller black circles are O atoms, and the lines indicate a chemical bond (of O to Mn). This double shell has tetragonal symmetry and consists of an inner shell...

    12. Effect of Mn substitution on the transport properties of co-sputtered Fe{sub 3?x}Mn{sub x}Si epilayers

      SciTech Connect (OSTI)

      Tang, M.; Jin, C.; Bai, H. L.

      2014-11-07

      Motivated by the theoretical calculations that Fe{sub 3?x}Mn{sub x}Si can simultaneously exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical properties of Fe{sub 3?x}Mn{sub x}Si, we have investigated the effect of Mn substitution on the transport properties of epitaxial Fe{sub 3?x}Mn{sub x}Si (0?x?1) films systematically. The Fe{sub 3?x}Mn{sub x}Si films were epitaxially grown on MgO(001) plane with 45° rotation. The magnetization for various x shows enhanced irreversibility, implying the antiferromagnetic ordering induced by the substitution of Mn. A metal-semiconductor crossover was observed due to the enhanced disorders of interactions and the local lowering of symmetry induced by the substitution of Mn. The single-domain state in the Fe{sub 3?x}Mn{sub x}Si films leads to twofold symmetric curves of the anisotropic magnetoresistance and planar Hall resistivity.

    13. Role of t{sub 2g} electrons in Mn-Tb coupling of multiferroic TbMnO{sub 3}

      SciTech Connect (OSTI)

      Guo, Y. Y.; Wang, Y. L.; Liu, J.-M.; Wei, T.

      2014-08-14

      We investigate the effect of Cr-doping in polycrystalline TbMn{sub 1?x}Cr{sub x}O{sub 3} (x???6%) ceramics on the magnetism, ferroelectricity, and dielectricity. The Cr substitution gradually suppresses the ferroelectricity induced by the Mn spiral spin ordering, and results in a stronger modulation of polarization by magnetic field with increasing x. However, the transition temperature T{sub Tb} corresponding to onset of Tb magnetic ordering has barely shifted with Cr doping. In other words, although the Cr-doping obviously disrupts the Mn spiral spin ordering, the exchange field J{sub Mn-Tb} acting on the Tb moments from the Mn-spin structure is hardly impacted. Our work demonstrates that the e{sub g} electron of Mn{sup 3+} plays an important role in forming the Mn spiral spin order, but the f-d exchange interaction between the Mn 3d spins and the Tb 4f moments in multiferroic TbMnO{sub 3} almost involves only the t{sub 2g} electrons.

    14. Biological Mn(II) oxidation in freshwater and marine systems : new perspectives on reactants, mechanisms and microbial catalysts of Mn cycling in the environment

      E-Print Network [OSTI]

      Clement, Brian Gregory

      2006-01-01

      a mining-related acid drainage problem. Applied Geochemistrya mining-related acid drainage problem. Applied GeochemistryBioremediation of Acid Mine Drainage: Mn(II) Oxidation at

    15. Controlling Mn depth profiles in GaMnAs during high-temperature molecular beam epitaxial growth

      E-Print Network [OSTI]

      Thibado, Paul M.

      , or spintronics [1]. The reason for this is that, compared to conventional electronic devices, spin-based devices be suitable for spintronics. For example, the discovery of ferromagnetism in Mn-doped GaAs grown by MBE [4] has led to interest in it as an ideal material for spintronics applications [5,6]. The future success

    16. Electronic structure and magnetism of Mn{sub 12}O{sub 12} clusters

      SciTech Connect (OSTI)

      Pederson, M.R. [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States)] [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States); Khanna, S.N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

      1999-01-01

      To address the ferrimagnetic state of the Mn{sub 12} acetate matrix [Mn{sub 12}O{sub 12}(CH{sub 3}COO){sub 16}(H{sub 2}O){sub 4}] we have performed all-electron gradient-corrected density-functional calculations on (MnO){sub n} with n=1, 2, 4, and 12. In contrast to bulk MnO which is antiferromagnetic, the small (MnO){sub n} (n=1, 2, and 4) clusters are ferromagnetic with Mn moments of 5.0{mu}{sub B} but the ground state of Mn{sub 12}O{sub 12} is ferrimagnetic with a total magnetic moment of 20.0{mu}{sub B} as observed experimentally. The inner Mn sites in Mn{sub 12}O{sub 12} are found to have localized moments of 4.1{mu}{sub B} which are antiferromagnetically coupled to two types of outer Mn with moments of 4.2{mu}{sub B}. The cluster is shown to be marked by ionic as well as covalent bonds between Mn d and O p electrons and a strong intracluster magnetic coupling. {copyright} {ital 1999} {ital The American Physical Society}

    17. Microstructure of cosputter-deposited metal-and oxide-MoS2 solid lubricant thin films

      E-Print Network [OSTI]

      Marks, Laurence D.

      Microstructure of cosputter-deposited metal- and oxide-MoS2 solid lubricant thin films M. R of cosputtering small amounts of Ni (3%, 9%) and SbOx (20%) on the final microstructure of MoS2 lubricant thin performance is discussed. I. INTRODUCTION Sputter-deposited films of MoS2 have been used as solid lubricants

    18. Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin "lms

      E-Print Network [OSTI]

      Rockett, Angus

      1999-01-01

      "lms during annealing Marika Bodega rd *, Karin Granath , Lars Stolt , Angus Rockett Uppsala University Mo thin "lms used as back contacts for Cu(In,Ga)Se solar cells. The samples were analysed glass substrate into the Mo "lm. The oxygen content of the rf diode sputtered Mo "lms was 8 at% as found

    19. Catalytic pyrolysis of methane on Mo/H-ZSM5 with continuous hydrogen removal by permeation through dense oxide lms

      E-Print Network [OSTI]

      Iglesia, Enrique

      Catalytic pyrolysis of methane on Mo/H-ZSM5 with continuous hydrogen removal by permeation through ®lms, chain-limiting catalytic pyrolysis reactions on Mo/H-ZSM5, and CO2 co-reactants led to stable simulations in tubular reactors with permeable walls. KEY WORDS: methane pyrolysis; membrane reactors; Mo

    20. Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal Programmed Desorption

      E-Print Network [OSTI]

      Goodman, Wayne

      Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal, 2000 The adsorption of methanol (CH3OH) and water (D2O) on the MgO(100)/Mo(100) surface at 100 K has covered MgO(100)/Mo(100) surface. On the other hand, the formation of a methanol multilayer desorption

    1. Giant Magnetic Moments and Magnetic Bistability of Stoichiomatric MnO Clusters

      SciTech Connect (OSTI)

      Nayak, S.K.; Jena, P. [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

      1998-10-01

      {ital Abthinspthinspinitio} calculations based on density functional theory and generalized gradient approximation reveal many unusual features of stoichiometric (MnO){sub x} (x{le}9) clusters that contrast with their bulk behavior. The clusters are ferromagnetic and carry atomiclike magnetic moments ranging from 4{mu}{sub B} to 5{mu}{sub B} per MnO unit, and the moments are localized at the Mn sites. The (MnO){sub 8} cluster, in particular, exhibits nearly degenerate ferromagnetic and atypical antiferromagnetic solutions with the ferromagnetic structure carrying a moment of 40{mu}{sub B} . The structures of (MnO){sub x} clusters are also unique with cubic and hexagonal forms competing for stability. (MnO){sub 2} and (MnO){sub 3} are unusually stable and form the foundation for further growth. {copyright} {ital 1998} {ital The American Physical Society}

    2. X-ray absorption study of the electronic structure of Mn-doped amorphous Si

      SciTech Connect (OSTI)

      Arenholz, Elke; Zeng, Li; Huegel, A.; Helgren, E.; Hellman, F.; Piamonteze, C.; Arenholz, E.

      2008-03-08

      The electronic structure of Mn in amorphous Si (a-Mn{sub x}Si{sub 1?x}) is studied by X-ray absorption spectroscopy at the Mn L{sub 3,2} edges for x = 0.005-0.18. Except the x = 0.005 sample, which shows a slight signature of Mn{sup 2+} atomic multiplets associated with a local Mn moment, all samples have broad and featureless L{sub 3,2} absorption peaks, corresponding to an itinerant state for all 3d electrons. The broad X-ray absorption spectra exclude the possibility of a localized 3d moment and explain the unexpectedly quenched Mn moment in this magnetically-doped amorphous semiconductor. Such a fully delocalized d state of Mn dopant in Si has not been previously suggested.

    3. Atomic-resolution study of Mn tetramer clusters using scanning tunneling Rong Yang, Haiqiang Yang, and Arthur R. Smitha

      E-Print Network [OSTI]

      Atomic-resolution study of Mn tetramer clusters using scanning tunneling microscopy Rong Yang clusters is investigated. The clusters are composed of a quadrant array of Mn atoms forming a tetramer of manganese nitride, on which are stabilized peri- odic, self-organized array of MnN-bonded Mn tetramer clus

    4. (Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor

      SciTech Connect (OSTI)

      Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C.; Han, W.; Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J.; Ning, F. L.; Munsie, T. J. S.; Medina, T.; Luke, G. M.; Carlo, J. P.; Munevar, J.; Zhang, G. M.; Jin, C. Q.

      2014-10-28

      Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?Mn doping, ferromagnetic order is accompanied by an interaction between the local spin and mobile charge, giving rise to a minimum in resistivity at low temperatures and localizing the conduction electrons. The system provides an ideal platform for studying the interaction of the local spins and conduction electrons.

    5. Surface Structures of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Monte Carlo Simulations

      SciTech Connect (OSTI)

      Wang, Guofeng; Van Hove, M.A.; Ross, P.N.; Baskes, M.I.

      2005-03-31

      The surface structures of cubo-octahedral Pt-Mo nanoparticles have been investigated using the Monte Carlo method and modified embedded atom method potentials that we developed for Pt-Mo alloys. The cubo-octahedral Pt-Mo nanoparticles are constructed with disordered fcc configurations, with sizes from 2.5 to 5.0 nm, and with Pt concentrations from 60 to 90 at. percent. The equilibrium Pt-Mo nanoparticle configurations were generated through Monte Carlo simulations allowing both atomic displacements and element exchanges at 600 K. We predict that the Pt atoms weakly segregate to the surfaces of such nanoparticles. The Pt concentrations in the surface are calculated to be 5 to 14 at. percent higher than the Pt concentrations of the nanoparticles. Moreover, the Pt atoms preferentially segregate to the facet sites of the surface, while the Pt and Mo atoms tend to alternate along the edges and vertices of these nanoparticles. We found that decreasing the size or increasing the Pt concentration leads to higher Pt concentrations but fewer Pt-Mo pairs in the Pt-Mo nanoparticle surfaces.

    6. $?$-Decay Half-Life of the $rp$-Process Waiting Point Nuclide $^{84}$Mo

      E-Print Network [OSTI]

      J. B. Stoker; P. F. Mantica; D. Bazin; A. Becerril; J. S. Berryman; H. L. Crawford; A. Estrade; C. J. Guess; G. W. Hitt; G. Lorusso; M. Matos; K. Minamisono; F. Montes; J. Pereira; G. Perdikakis; H. Schatz; K. Smith; R. G. T. Zegers

      2009-01-08

      A half-life of 2.2 $\\pm$ 0.2 s has been deduced for the ground-state $\\beta$ decay of $^{84}$Mo, more than 1$\\sigma$ shorter than the previously adopted value. $^{84}$Mo is an even-even N = Z nucleus lying on the proton dripline, created during explosive hydrogen burning in Type I X-ray bursts in the rapid proton capture ($rp$) process. The effect of the measured half-life on $rp$-process reaction flow is explored. Implications on theoretical treatments of nuclear deformation in $^{84}$Mo are also discussed.

    7. K. Czarnecki et al. (Eds.): MoDELS 2008, LNCS 5301, pp. 264279, 2008. Springer-Verlag Berlin Heidelberg 2008

      E-Print Network [OSTI]

      van Schyndel, Ron

      UML, X3D, 3D Software Visualization, VRML. 1 Introduction Computers in current day software development houses are now capable of rendering quality real time 3D visualisations. In the past, 3D into the overall benefit of completing common and critical software engineer- ing tasks with UML extended using 3D

    8. Optimization of chemical compositions in low-carbon Al-killed enamel steel produced by ultra-fast continuous annealing

      SciTech Connect (OSTI)

      Dong, Futao; Du, Linxiu; Liu, Xianghua; Xue, Fei

      2013-10-15

      The influence of Mn,S and B contents on microstructural characteristics, mechanical properties and hydrogen trapping ability of low-carbon Al-killed enamel steel was investigated. The materials were produced and processed in a laboratory and the ultra-fast continuous annealing processing was performed using a continuous annealing simulator. It was found that increasing Mn,S contents in steel can improve its hydrogen trapping ability which is attributed by refined ferrite grains, more dispersed cementite and added MnS inclusions. Nevertheless, it deteriorates mechanical properties of steel sheet. Addition of trace boron results in both good mechanical properties and significantly improved hydrogen trapping ability. The boron combined with nitrogen segregating at grain boundaries, cementite and MnS inclusions, provides higher amount of attractive hydrogen trapping sites and raises the activation energy for hydrogen desorption from them. - Highlights: • We study microstructures and properties in low-carbon Al-killed enamel steel. • Hydrogen diffusion coefficients are measured to reflect fish-scale resistance. • Manganese improves hydrogen trapping ability but decrease deep-drawing ability. • Boron improves both hydrogen trapping ability and deep-drawing ability. • Both excellent mechanical properties and fish-scale resistance can be matched.

    9. Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys 

      E-Print Network [OSTI]

      Karaca, Haluk Ersin

      2009-05-15

      The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single ...

    10. Distribution of water extractable heavy metals (Cd, Co, Mn and Mo) in the topsoil of Osijek-Baranja County (Eastern Croatia)

      E-Print Network [OSTI]

      Ivezic, Vladimir; Almås, Åsgeir R.; Loncaric, Zdenko; Singh, Bal Ram

      2009-01-01

      and Calcareous Soils in Croatia. VII. Alps- Adria Scientificagricultural region of Croatia and therefore food qualityHungary, Serbia and Croatia. Based on the pedological map 74

    11. Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys

      SciTech Connect (OSTI)

      Lobo, D. N.; Priolkar, K. R.; Emura, S.; Nigam, A. K.

      2014-11-14

      The structure, magnetic, and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD), and EXAFS. While Ni{sub 2}MnIn{sub 1?x}Fe{sub x} (0???x???0.6) alloys are ferromagnetic and non martensitic, the martensitic transformation temperature in Ni{sub 2}Mn{sub 1.5}In{sub 1?y}Fe{sub y} and Ni{sub 2}Mn{sub 1.6}In{sub 1?y}Fe{sub y} increases for lower Fe concentrations (y???0.05) before decreasing sharply for higher Fe concentrations. XRD analysis reveals presence of cubic and tetragonal structural phases in Ni{sub 2}MnIn{sub 1?x}Fe{sub x} at room temperature with tetragonal phase content increasing with Fe doping. Even though the local structure around Mn and Ni in these Fe doped alloys is similar to martensitic Mn rich Ni-Mn-In alloys, presence of ferromagnetic interactions and structural disorder induced by Fe affect Mn-Ni-Mn antiferromagnetic interactions resulting in suppression of martensitic transformation in these Fe doped alloys.

    12. Effect of composition and heat treatment on MnBi magnetic materials

      SciTech Connect (OSTI)

      Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

      2014-10-01

      The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of Mn–Bi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

    13. On the state of Mn impurity implanted in Si

      SciTech Connect (OSTI)

      Orlov, A. F.; Bublik, V. T.; Vdovin, V. I.; Agafonov, Yu. A.; Balagurov, L. A.; Zinenko, V. I.; Kulemanov, I. V.; Shcherbachev, K. D.

      2009-07-15

      The state of manganese impurity in implanted silicon at implantation doses of up to 5 x 10{sup 16} cm{sup -2} has been investigated by X-ray diffraction and transmission electron microscopy. It is established that, after short-term vacuum annealing at 850{sup o}C, most of the implanted manganese impurities are in microinclusions up to 20 nm in size formed by a tetragonal silicide phase of the Mn{sub 15}Si{sub 26} type.

    14. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

      SciTech Connect (OSTI)

      Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Université de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

      2014-04-21

      The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

    15. Growth of nanocrystalline MoO{sub 3} on Au(111) studied by in situ scanning tunneling microscopy

      SciTech Connect (OSTI)

      Biener, Monika M.; Biener, Juergen; Schalek, Richard; Friend, Cynthia M. [Department of Chemistry, Harvard University, Cambridge, Massachusetts 02138 (United States); Division of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States); Center for Imaging and Mesoscale Structures, Harvard University, Cambridge, Massachusetts 02138 (United States); Center for Imaging and Mesoscale Structures, Harvard University, Cambridge, Massachusetts 02138 (United States); Department of Chemistry, Harvard University, Cambridge, Massachusetts 02138 (United States); Division of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

      2004-12-15

      The growth of nanocrystalline MoO{sub 3} islands on Au(111) using physical vapor deposition of Mo has been studied by scanning tunneling microscopy and low energy electron diffraction. The growth conditions affect the shape and distribution of the MoO{sub 3} nanostructures, providing a means of preparing materials with different percentages of edge sites that may have different chemical and physical properties than atoms in the interior of the nanostructures. MoO{sub 3} islands were prepared by physical vapor deposition of Mo and subsequent oxidation by NO{sub 2} exposure at temperatures between 450 K and 600 K. They exhibit a crystalline structure with a c(4x2) periodicity relative to unreconstructed Au(111). While the atomic-scale structure is identical to that of MoO{sub 3} islands prepared by chemical vapor deposition, we demonstrate that the distribution of MoO{sub 3} islands on the Au(111) surface reflects the distribution of Mo clusters prior to oxidation although the growth of MoO{sub 3} involves long-range mass transport via volatile MoO{sub 3} precursor species. The island morphology is kinetically controlled at 450 K, whereas an equilibrium shape is approached at higher preparation temperatures or after prolonged annealing at the elevated temperature. Mo deposition at or above 525 K leads to the formation of a Mo-Au surface alloy as indicated by the observation of embedded MoO{sub 3} islands after oxidation by NO{sub 2}. Au vacancy islands, formed when Mo and Au dealloy to produce vacancies, are observed for these growth conditions.

    16. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

      E-Print Network [OSTI]

      Bekker, T B; Danevich, F A; Degoda, V Ya; Giuliani, A; Grigorieva, V D; Ivannikova, N V; Mancuso, M; de Marcillac, P; Moroz, I M; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tretyak, V I; Velazquez, M

      2014-01-01

      Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

    17. Micromagnetic simulation of spin-transfer switching in a full-Heusler Co2FeAl0.5Si0.5 alloy spin-valve nanopillar

      E-Print Network [OSTI]

      Chen, Long-Qing

      Micromagnetic simulation of spin-transfer switching in a full-Heusler Co2FeAl0.5Si0.5 alloy spin-valve. Related Articles Bi-quadratic interlayer exchange coupling in Co2MnSi/Ag/Co2MnSi pseudo spin-valve J. Appl://jap.aip.org/about/rights_and_permissions #12;Micromagnetic simulation of spin-transfer switching in a full-Heusler Co2FeAl0.5Si0.5 alloy spin-valve

    18. Microscopic origin of low frequency noise in MoS{sub 2} field-effect transistors

      SciTech Connect (OSTI)

      Ghatak, Subhamoy; Jain, Manish; Ghosh, Arindam; Mukherjee, Sumanta; Sarma, D. D.

      2014-09-01

      We report measurement of low frequency 1/f noise in molybdenum di-sulphide (MoS{sub 2}) field-effect transistors in multiple device configurations including MoS{sub 2} on silicon dioxide as well as MoS{sub 2}-hexagonal boron nitride (hBN) heterostructures. All as-fabricated devices show similar magnitude of noise with number fluctuation as the dominant mechanism at high temperatures and density, although the calculated density of traps is two orders of magnitude higher than that at the SiO{sub 2} interface. Measurements on the heterostructure devices with vacuum annealing and dual gated configuration reveals that along with the channel, metal-MoS{sub 2} contacts also play a significant role in determining noise magnitude in these devices.

    19. Intrinsic Electronic Transport Properties of High-Quality Monolayer and Bilayer MoS[subscript 2

      E-Print Network [OSTI]

      Baugher, Britton W. H.

      We report electronic transport measurements of devices based on monolayers and bilayers of the transition-metal dichalcogenide MoS[subscript 2]. Through a combination of in situ vacuum annealing and electrostatic gating ...

    20. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

      SciTech Connect (OSTI)

      Sen, H. Sener; Sahin, H.; Peeters, F. M.; Durgun, E.

      2014-08-28

      First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

    1. Combining Formal Methods and Safety Analysis -The ForMoSA Approach

      E-Print Network [OSTI]

      Reif, Wolfgang

      and quantitative analysis. The For- MoSA approach combines these techniques to answer these safety rele- vant level of con- fidence formal methods from software engineering have been used. Safety rele- vant

    2. MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS

      E-Print Network [OSTI]

      Kusner, Robert B.

      MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS energies, especially those which are invariant under M"obius transforma- tions of space. We describe computer experiments with such energies, and discuss ways of extending these to energies

    3. AB INITIO Modeling of Thermomechanical Properties of Mo-Based Alloys for Fossil Energy Conversion

      SciTech Connect (OSTI)

      Ching, Wai-Yim

      2013-12-31

      In this final scientific/technical report covering the period of 3.5 years started on July 1, 2011, we report the accomplishments on the study of thermo-mechanical properties of Mo-based intermetallic compounds under NETL support. These include computational method development, physical properties investigation of Mo-based compounds and alloys. The main focus is on the mechanical and thermo mechanical properties at high temperature since these are the most crucial properties for their potential applications. In particular, recent development of applying ab initio molecular dynamic (AIMD) simulations to the T1 (Mo{sub 5}Si{sub 3}) and T2 (Mo{sub 5}SiB{sub 2}) phases are highlighted for alloy design in further improving their properties.

    4. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Jin, Wencan; Sadowski, Jerzy T.; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Herman, Irving P.; Osgood, Jr., Richard M.; Sutter, Peter; et al

      2015-03-17

      We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss itsmore »possible origin.« less

    5. Substrate interactions with suspended and supported monolayer MoS2: Angle-resolved photoemission spectroscopy

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Jin, Wencan; Yeh, Po -Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Barinov, Alexey; Yablonskikh, Mikhail; Sadowski, Jerzy T.; Sutter, Peter; et al

      2015-03-17

      We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. Thus, a suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ?¯ and ?¯ of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?¯?¯ to the vicinity of ?¯ and briefly discussmore »its possible origin.« less

    6. Investigation of double beta decay of $^{100}$Mo to excited states of $^{100}$Ru

      E-Print Network [OSTI]

      R. Arnold; C. Augier; A. S. Barabash; . ..

      2014-02-28

      Double beta decay of $^{100}$Mo to the excited states of daughter nuclei has been studied using a 600 cm$^3$ low-background HPGe detector and an external source consisting of 2588 g of 97.5% enriched metallic $^{100}$Mo, which was formerly inside the NEMO-3 detector and used for the NEMO-3 measurements of $^{100}$Mo. The half-life for the two-neutrino double beta decay of $^{100}$Mo to the excited 0$^+_1$ state in $^{100}$Ru is measured to be $T_{1/2}=[7.5 \\pm{0.6}(stat) \\pm {0.6}(syst)]\\cdot 10^{20}$ yr. For other $(0\

    7. Investigation of structure, magnetic, and transport properties of Mn-doped SiC films

      SciTech Connect (OSTI)

      Sun Xianke [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); Guo Ruisong [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); An Yukai [Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Liu Jiwen [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

      2013-07-15

      Mn-doped SiC films were fabricated by radio frequency magnetron sputtering technique. The structure, composition, and magnetic and transport properties of the films were investigated. The results show the films have the 3C-SiC crystal structure and the doped Mn atoms in the form of Mn{sup 2+} ions substitute for C sites in SiC lattice. All the films are ferromagnetic at 300 K, and the ferromagnetism in films arises from the doped Mn atoms and some extended defects. In addition, the saturation magnetization increases with the Mn-doped concentration increasing. The Mn doping does not change the semiconductor characteristics of the SiC films.

    8. Ge{sub 1-x}Mn{sub x} heteroepitaxial quantum dots: Growth, morphology, and magnetism

      SciTech Connect (OSTI)

      Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

      2013-02-21

      Heteroepitaxial Ge{sub 1-x}Mn{sub x} quantum dots (QDs) were grown on Si (001) by molecular beam epitaxial co-deposition, with x = 0 to 0.10, in order to explore the interaction between Mn content, surface morphological evolution, and magnetism. Morphological evolution typical of the Ge/Si (001) system was observed, where the effect of Mn on surface morphology is surprisingly minimal at low Mn content, with no obvious surface morphological indicators of second phase formation. As the Mn content increases, secondary phase formation becomes evident, appearing to heterogeneously nucleate on or within Ge QDs. Still higher Mn concentrations lead to extensive second phase formation interspersed with an array of Ge QDs. Although ferromagnetism up to 220 K is observed, likely arising from intermetallic precipitates, there is no clear evidence for room-temperature ferromagnetism associated with a dilute magnetic solution phase.

    9. Time resolved magneto-optical studies of ferromagnetic InMnSb films

      SciTech Connect (OSTI)

      Frazier, M.; Kini, R. N.; Nontapot, K.; Khodaparast, G. A. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Wojtowicz, T. [Institute of Physics, Polish Academy of Sciences 02-668 Warsaw (Poland); Liu, X.; Furdyna, J. K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

      2008-02-11

      We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples' Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples' growth conditions.

    10. High Pressure Transformation of La4Cu3MoO12 to a Layered Perovskite

      E-Print Network [OSTI]

      Poeppelmeier, Kenneth R.

      High Pressure Transformation of La4Cu3MoO12 to a Layered Perovskite Douglas A. Vander Griend it stabilizes the perovskite structure. In this paper, we describe the HP synthesis of a new copper-rich layered perovskite, La4Cu3MoO12, which is isotypic with La2- CuSnO6.1 When synthesized at ambient pressure (AP

    11. MoS{sub 2} nanoribbons as promising thermoelectric materials

      SciTech Connect (OSTI)

      Fan, D. D.; Liu, H. J., E-mail: phlhj@whu.edu.cn; Cheng, L.; Jiang, P. H.; Shi, J. [Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Tang, X. F. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070 (China)

      2014-09-29

      The thermoelectric properties of MoS{sub 2} armchair nanoribbons with different width are studied by using first-principles calculations and Boltzmann transport theory, where the relaxation time is predicted from deformation potential theory. Due to the dangling bonds at the armchair edge, there is obvious structure reconstruction of the nanoribbons which plays an important role in governing the electronic and transport properties. The investigated armchair nanoribbons are found to be semiconducting with indirect gaps, which exhibit interesting width-dependent oscillation behavior. The smaller gap of nanoribbon with width N?=?4 (Here, N represents the number of dimer lines or zigzag chains across the ribbon width) leads to a much larger electrical conductivity at 300?K, which outweighs the relatively larger electronic thermal conductivity when compared with those of N?=?5, 6. As a result, the ZT values can be optimized to 3.4 (p-type) and 2.5 (n-type) at room temperature, which significantly exceed the performance of most laboratory results reported in the literature.

    12. Electrochemical Testing of Ni-Cr-Mo-Gd Alloys

      SciTech Connect (OSTI)

      T. E. Lister; R. E. Mizia; H. Tian

      2005-10-01

      The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

    13. Thermo-physical Properties of DU-10 wt.% Mo Alloys

      SciTech Connect (OSTI)

      Douglas E. Burkes; Cynthia A. Papesch; Andrew P. Maddison; Thomas Hartmann; Francine J. Rice

      2010-08-01

      Low-enriched uranium alloyed with 10 wt% molybdenum is under consideration by the Global Threat Reduction Initiative reactor convert program as a very high density fuel to enable the conversion of high-performance research reactors away from highly-enriched uranium fuels. As with any fuel development program, the thermophysical properties of the fuel as a function of temperature are extremely important and must be well characterized in order to effectively model and predict fuel behavior under normal and off-normal irradiation conditions. For the alloy system under investigation, there is a lack of thermophysical property data, and in most cases, the data is relatively inconsistent and lacks sufficient explanation. Available literature on this alloy system comes mainly from studies done during the 1960s and 1970s, and often does not include sufficient information on fabrication history or conditions to draw conclusions for the current application. The current paper has investigated specific heat capacity, coefficient of linear thermal expansion, density, and thermal diffusivity that were then used to calculate alloy thermal conductivity as a function of temperature. The data obtained from this investigation was compared to available literature on similar U-Mo alloys, and in most cases are in good agreement.

    14. Cr(OH)?(s) Oxidation Induced by Surface Catalyzed Mn(II) Oxidation

      SciTech Connect (OSTI)

      Namgung, Seonyi; Kwon, M.; Qafoku, Nikolla; Lee, Gie Hyeon

      2014-09-16

      This study examined the feasibility of Cr(OH)?(s) oxidation mediated by surface catalyzed Mn(II) oxidation under common groundwater pH conditions as a potential pathway of natural Cr(VI) contaminations. Dissolved Mn(II) (50 ?M) was reacted with or without synthesized Cr(OH)?(s) (1.0 g/L) at pH 7 – 9 under oxic or anoxic conditions. In the absence of Cr(OH)?(s), homogeneous Mn(II) oxidation by dissolved O? was not observed at pH ? 8.0 for 50 d. At pH 9.0, by contrast, dissolved Mn(II) was completely removed within 8 d and precipitated as hausmannite. When Cr(OH)?(s) was present, this solid was oxidized and released substantial amounts of Cr(VI) as dissolved Mn(II) was added into the suspension at pH ? 8.0 under oxic conditions. Our results suggest that Cr(OH)?(s) was readily oxidized by a newly formed Mn oxide as a result of Mn(II) oxidation catalyzed on Cr(OH)?(s) surface. XANES analysis of the residual solids after the reaction between 1.0 g/L Cr(OH)?(s) and 204 ?M Mn(II) at pH 9.0 for 22 d revealed that the product of surface catalyzed Mn(II) oxidation resembled birnessite. The rate and extent of Cr(OH)?(s) oxidation was likely controlled by those of surface catalyzed Mn(II) oxidation as the production of Cr(VI) increased with increasing pH and initial Mn(II) concentrations. This study evokes the potential environmental hazard of sparingly soluble Cr(OH)?(s) that can be a source of Cr(VI) in the presence of dissolved Mn(II).

    15. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

      2015-07-28

      The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore »been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3?B/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

    16. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

      SciTech Connect (OSTI)

      Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

      2012-08-17

      Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

    17. Stability of precipitate phases in Fe-rich Fe-Cr-Ni-Mo alloys

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Yang, Ying; Tan, Lizhen; Busby, Jeremy T

      2015-01-01

      Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the and phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. Two key findings resulted from this work. One is that the phase is stable at high temperature and transformed into the phase at lowmore »temperature. The other is that both the and phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.« less

    18. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

      2015-06-12

      Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed intomore »the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.« less

    19. High reflectance and low stress Mo2C/Be multilayers

      DOE Patents [OSTI]

      Bajt, Sasa (Livermore, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

      2001-01-01

      A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

    20. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

      SciTech Connect (OSTI)

      Visic, B.; Gunde, M. Klanjsek; Kovac, J.; Iskra, I.; Jelenc, J.; Remskar, M.; Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana

      2013-02-15

      Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultraviolet–visible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

    1. Effects of thermal treatment on the co-rolled U-Mo fuel foils

      SciTech Connect (OSTI)

      Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

      2014-11-01

      A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

    2. Enhancing SMM properties via axial distortion of Mn-3(III) clusters 

      E-Print Network [OSTI]

      Parsons S.; Brechin, E.K.; Collins A.; Karotsis G.; Jones L.F.; Inglis R.; Wernsdorfer W.; Perlepes S.P.

      2008-01-01

      Replacement of carboxylate and solvent with facially capping tripodal ligands enhances the single-molecule magnet (SMM) properties of [Mn-3(III)] triangles.

    3. Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure

      SciTech Connect (OSTI)

      Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

      2014-09-21

      The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}~55 ?C/cm² obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290 K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ~123 emu/cm³. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

    4. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

      SciTech Connect (OSTI)

      Yan, Jun; Wei, Tong; Cheng, Jie; Fan, Zhuangjun; Zhang, Milin

      2010-02-15

      Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

    5. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Liu, Cheng; Liu, Ping

      2015-01-12

      We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among themore »systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.« less

    6. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Liu, Cheng [Yangzhou Univ., Yangzhou, Jiangsu (China); Liu, Ping [Brookhaven National Lab. (BNL), Upton, NY (United States)

      2015-02-06

      We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among the systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.

    7. Microstructure evolution of Li uptake/removal in MoO{sub 2}@C nanoparticles with high lithium storage performance

      SciTech Connect (OSTI)

      Liu, Yulong; Zhang, Hong; Ouyang, Pan; Chen, Wenhao [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Li, Zhicheng, E-mail: zhchli@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China)

      2014-02-01

      Highlights: • The carbon-coated MoO{sub 2} (MoO{sub 2}@C) ultra fine nanoparticles are synthesized by one-pot hydrothermal method. • MoO{sub 2}@C nanoparticles have high specific capacity, excellent cycling performance and rate performance. • Phase transformations for lithium ion uptake/removal are examined carefully by TEM. • Phase transformations are highly reversible during the redox process. - Abstract: A facile one pot strategy of a hydrothermal methodology was applied to synthesize the carbon coated MoO{sub 2} (MoO{sub 2}@C) nanostructured particles, which are composed of ultra fine nanoparticles with homogeneous carbon coating about several nanometers. As an electrode in lithium ion batteries, the MoO{sub 2}@C shows a high specific capacity and reversible capacity (730 mA h g{sup ?1} after 60 cycles). Microstructure investigations, by using a high resolution transmission electron microscopy, of the MoO{sub 2}@C based electrodes employed at various states during the first discharge/charge cycle were conducted to elucidate the lithium ion uptake/removal mechanism and cycling behavior. In the lithium uptake process, the original MoO{sub 2} phase transfers into Li{sub 0.98}MoO{sub 2} through an addition type reaction, and then nanosized metallic Mo emerges as a result of a conversion reaction. In turn, Mo could be oxidized to the intermediate Li{sub 0.98}MoO{sub 2} before converting to hyperfine MoO{sub 2} phase on upcoming lithium removal process.

    8. Al Ogletree & Bob Tankersley 

      E-Print Network [OSTI]

      Unknown

      2011-08-17

      the installation and proper utilization of an EMCS.5 The objective of this report is to determine how successful Energy Management Control Systems have been in reducing energy consumption. 1 Claridge, D.E., et al 1994. "Energy retrofits can cut use and costs...." Mechanical Engineering, August, pp. 64-67. 2 Editor, 1991. Buildings, December, p. 16. 3 Editor, 1992. Buildings, September, p. 34. 4Mumford, S., 1994. Buildings, February, pp. 38-41. 5 Editor, 1993. Buildings, May, p 38. 1 The LoanSTAR Program6 In 1988...

    9. ALS Activity Reports

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level79AJ01)19^ U N I T E D S TALPES20thALS

    10. ALS Beamlines Directory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    11. ALS User Meeting Archives

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    12. ALS Users' Association Charter

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    13. ALS Beamlines Directory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    14. ALS Beamlines Directory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    15. ALS Postdoctoral Fellowship Highlights

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    16. ALS Users' Association Charter

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    17. ALS Beamlines Directory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    18. ALS Communications Group

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    19. ALS in the News

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    20. About the ALS

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    1. Access to the ALS

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    2. Opti-MN Impact House Presentation | Department of Energy

      Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014DepartmentCouncilOffice of theOpen DataHeat &Opti-MN

    3. Doping against the native propensity of MoS?: Degenerate hole doping by cation substitution

      SciTech Connect (OSTI)

      Suh, Joonki; Park, Tae-Eon; Lin, Der-Yuh; Fu, Deyi; Park, Joonsuk; Jung, Hee Joon; Chen, Yabin; Ko, Changhyun; Jang, Chaun; Sun, Yinghui; Sinclair, Robert; Chang, Joonyeon; Tongay, Sefaattin; Wu, Junqiao

      2014-12-10

      Layered transition metal dichalcogenides (TMDs) draw much attention as the key semiconducting material for two-dimensional electrical, optoelectronic, and spintronic devices. For most of these applications, both n- and p-type materials are needed to form junctions and support bipolar carrier conduction. However, typically only one type of doping is stable for a particular TMD. For example, molybdenum disulfide (MoS?) is natively an n-type presumably due to omnipresent electron-donating sulfur vacancies, and stable/controllable p-type doping has not been achieved. The lack of p-type doping hampers the development of charge-splitting p–n junctions of MoS?, as well as limits carrier conduction to spin-degenerate conduction bands instead of the more interesting, spin-polarized valence bands. Traditionally, extrinsic p-type doping in TMDs has been approached with surface adsorption or intercalation of electron-accepting molecules. However, practically stable doping requires substitution of host atoms with dopants where the doping is secured by covalent bonding. In this work, we demonstrate stable p-type conduction in MoS? by substitutional niobium (Nb) doping, leading to a degenerate hole density of ~3 × 10¹? cm?³. Structural and X-ray techniques reveal that the Nb atoms are indeed substitutionally incorporated into MoS? by replacing the Mo cations in the host lattice. van der Waals p–n homojunctions based on vertically stacked MoS? layers are fabricated, which enable gate-tunable current rectification. A wide range of microelectronic, optoelectronic, and spintronic devices can be envisioned from the demonstrated substitutional bipolar doping of MoS?. From the miscibility of dopants with the host, it is also expected that the synthesis technique demonstrated here can be generally extended to other TMDs for doping against their native unipolar propensity.

    4. MCNPX-CINDER'90 Simulation of Photonuclear Mo-99 Production Experiments

      SciTech Connect (OSTI)

      Kelsey, Charles T. IV [Los Alamos National Laboratory; Chemerizov, Sergey D. [Argonne National Laboratory; Dale, Gregory E. [Los Alamos National Laboratory; Harvey, James T. [NorthStar Medical Radioisotopes; Tkac, Peter [Argonne National Laboratory; Vandegrift, George R III [Argonne National Laboratory

      2011-01-01

      The MCNPX and CINDER'90 codes were used to support design of experiments investigating Mo-99 production with a 20-MeV electron beam. Bremsstrahlung photons produced by the electron beam interacting with the target drive the desired Mo-100({gamma},n)Mo-99 reaction, as well as many undesired reactions important to accurate prediction of radiation hazards. MCNPX is a radiation transport code and CINDER'90 is a transmutation code. They are routinely used together for accelerator activation calculations. Low energy neutron fluxes and production rates for nonneutron and high energy neutron induced reactions computed using MCNPX are inputs to CINDER'90. CINDER'90 presently has only a neutron reaction cross section library up to 25 MeV and normally the other reaction rates come from MCNPX physics models. For this work MCNPX photon flux tallies modified by energy response functions prepared from evaluated photonuclear cross section data were used to tally the reaction rates for CINDER'90 input. The cross section evaluations do not provide isomer to ground state yield ratios so a spin based approximation was used. Post irradiation dose rates were calculated using MCNPX with CINDER'90 produced decay photon spectra. The sensitivity of radionuclide activities and dose rates to beam parameters including energy, position, and profile, as well as underlying isomer assumptions, was investigated. Three experimental production targets were irradiated, two natural Mo and one Mo-100 enriched. Natural Mo foils upstream of the targets were used to analyze beam position and profile by exposing Gafchromic film to the foils after each irradiation. Activation and dose rate calculations were rerun after the experiments using measured beam parameters for comparison with measured Mo-99 activities and dose rates.

    5. In Situ Time-Resolved Characterization of Ni-MoO2 Catalysts for the Water-Gas Shift Reaction

      SciTech Connect (OSTI)

      Wen,W.; Calderon, J.; Brito, J.; Marinkovic, N.; Hanson, J.; Rodriquez, J.

      2008-01-01

      Active catalysts for the water-gas shift (WGS, CO + H2O ? H2 + CO2) reaction were synthesized from nickel molybdates ({beta}-NiMoO4 and nH2O{center_dot}NiMoO4) as precursors, and their structural transformations were monitored using in situ time-resolved X-ray diffraction and X-ray absorption near-edge spectroscopy. In general, the nickel molybdates were not stable and underwent partial reduction in the presence of CO or CO/H2O mixtures at high temperatures. The interaction of {beta}-NiMoO4 with the WGS reactants at 500 C led to the formation of a mixture of Ni (24 nm particle size) and MoO2 (10 nm particle size). These Ni-MoO2 systems displayed good catalytic activity at 350, 400, and 500 C. At 350 and 400 C, catalytic tests revealed that the Ni-MoO2 system was much more active than isolated Ni (some activity) or isolated MoO2 (negligible activity). Thus, cooperative interactions between the admetal and oxide support were probably responsible for the high WGS activity of Ni-MoO2. In a second synthetic approach, the NiMoO4 hydrate was reduced to a mixture of metallic Ni, NiO, and amorphous molybdenum oxide by direct reaction with H2 gas at 350 C. In the first pass of the water-gas shift reaction, MoO2 appeared gradually at 500 C with a concurrent increase of the catalytic activity. For these catalysts, the particle size of Ni (4 nm) was much smaller than that of the MoO2 (13 nm). These systems were found to be much more active WGS catalysts than Cu-MoO2, which in turn is superior to commercial low-temperature Cu-ZnO catalysts.

    6. Environmental effect on room-temperature ductility of isothermally forged TiAl-base alloys

      SciTech Connect (OSTI)

      Nakamura, Morihiko; Hashimoto, Kenki (National Research Inst. for Metals, Tokyo (Japan)); Itoh, Naoyuki (Nippon Steel Corp., Chiba (Japan)); Tsujimoto, Tokuzo (Ibaraki Univ. (Japan). Faculty of Engineering); Suzuki, Toshiyuki (Kougakuin Univ., Tokyo (Japan))

      1994-02-01

      Isothermally forged TiAl-base alloy (Al-rich, Mn-containing, and Cr-containing TiAl) were heat-treated in various conditions, and equiaxed grain structures consisting of [gamma] and [alpha][sub 2] or [beta] phases were obtained. The heat-treated alloys were tensile tested in vacuum and air at room temperature, and the environmental effect on tensile elongation was studied. The ductility of the alloys consisting of equiaxed [gamma] grains and a large amount of [alpha][sub 2] grains was not largely affecting by laboratory air, and a decrease in the amount of [alpha][sub 2] grains resulted in a large reduction of ductility in air. The [beta] phase in the Cr-containing alloy improved the ductility in vacuum, but it resulted in a large reduction of ductility in air.

    7. Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling,

      E-Print Network [OSTI]

      Goddard III, William A.

      the cluster. 1. INTRODUCTION Artificial photosynthesis schemes generally involve water as the terminal source, with the MnIV 3CaO4 OEC model being unreactive. The oxidative oxide incorporation into the partial cubane, Mn

    8. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

      E-Print Network [OSTI]

      Zeng, Li

      2007-01-01

      various transition or rare-earth metals provide a rich ?eldTransition Metal (Mn) and Rare Earth (Gd) Doped AmorphousTransition Metal (Mn) and Rare Earth (Gd) Doped Amorphous

    9. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

      DOE Patents [OSTI]

      Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Grover, S. Blaine (Idaho Falls, ID); Petti, David A. (Idaho Falls, ID); Terry, William K. (Idaho Falls, ID); Yoon, Woo Y. (Idaho Falls, ID)

      1998-01-01

      An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

    10. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

      DOE Patents [OSTI]

      Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

      1998-09-01

      An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

    11. Magnetic and structural properties of Zn doped MnV{sub 2}O{sub 4}

      SciTech Connect (OSTI)

      Shahi, Prashant; Shukla, K. K.; Singh, Rahul; Chatterjee, Sandip; Das, A.; Ghosh, A. K.; Nigam, A. K.

      2014-04-24

      The magnetization, Neutron diffraction and X-ray diffraction of Zn doped MnV{sub 2}O{sub 4} as a function of temperature have been measured. It has been observed, with increase of Zn the non-linear orientation of Mn spins with the V spins will decrease which effectively decrease the structural transition temperature more rapidly than Curie Temperature.

    12. Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1

      E-Print Network [OSTI]

      Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. ©2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

    13. MN 555 MEMS: Fabrication and Materials Spring 2004 Department of Manufacturing Engineering

      E-Print Network [OSTI]

      Lin, Xi

      MN 555 MEMS: Fabrication and Materials Spring 2004 Instructor Xin Zhang Department of Manufacturing meetings by appointment) 2003-2004 Catalog Data: MN 555 MEMS: Fabrication and Materials This course will explore the world of microelectromechanical devices and systems (MEMS). This requires an awareness

    14. Dietary resveratrol administration increases MnSOD expression and activity in mouse brain

      E-Print Network [OSTI]

      Stuart, Jeffrey A.

      Dietary resveratrol administration increases MnSOD expression and activity in mouse brain Ellen L May 2008 Available online xxxx Keywords: MnSOD Superoxide dismutase Resveratrol Antioxidant enzyme Brain Heart Liver Mitochondria Reactive oxygen species a b s t r a c t trans-Resveratrol (3,40 ,5

    15. Neutron Diffraction Measurement of Residual Stresses, Dislocation Density and Texture in Zr-bonded U-10Mo “Mini” Fuel Foils and Plates

      SciTech Connect (OSTI)

      Brown, Donald W.; Okuniewski, M. A.; Sisneros, Thomas A.; Clausen, Bjorn; Moore, G. A.; Balogh, L

      2014-08-07

      Aluminum clad monolithic uranium 10 weight percent molybdenum (U-10Mo) fuel plates are being considered for conversion of several research and test nuclear reactors from high-enriched to low-enriched uranium fuel due to the inherently high density of fissile material. Comprehensive neutron diffraction measurements of the evolution of the textures, residual phase stresses, and dislocation densities in the individual phases of the mini-foils throughout several processing steps and following hot-isostatic pressing to the Al cladding, have been completed. Recovery and recrystallization of the bare U-10Mo fuel foil, as indicated by the dislocation density and texture, are observed depending on the state of the material prior to annealing and the duration and temperature of the annealing process. In general, the HIP procedure significantly reduces the dislocation density, but the final state of the clad plate, both texture and dislocation density, depends strongly on the final processing step of the fuel foil. In contrast, the residual stresses in the clad fuel plate do not depend strongly on the final processing step of the bare foil prior to HIP bonding. Rather, the residual stresses are dominated by the thermal expansion mismatch of the constituent materials of the fuel plate.

    16. Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions

      SciTech Connect (OSTI)

      Nishitani, Y.; Endo, M.; Chiba, D.; Matsukura, F.; Ohno, H.

      2010-01-04

      We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

    17. Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation

      SciTech Connect (OSTI)

      Medford, Andrew

      2012-02-16

      Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

    18. Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor

      SciTech Connect (OSTI)

      Wijnheijmer, A. P.; Koenraad, P. M.; Marti, X.; Holy, V.; Cukr, M.; Novak, V.; Jungwirth, T.

      2012-03-12

      We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

    19. Core-level satellites and outer core-level multiplet splitting in Mn model compounds

      SciTech Connect (OSTI)

      Nelson, A. J. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Reynolds, John G. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Roos, Joseph W. [Ethyl Corporation, Richmond, Virginia 23217 (United States)] [Ethyl Corporation, Richmond, Virginia 23217 (United States)

      2000-07-01

      We report a systematic study of the Mn 2p, 3s, and 3p core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the 3d metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn 3s multiplet splitting becomes smaller as the Mn oxidation state increases, and that 3s-3d electron correlation reduces the branching ratio of the {sup 7}S:{sup 5}S states in the Mn 3s spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the 3s spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration-interaction model including intrashell electron correlation, charge transfer, and final-state screening. (c) 2000 American Vacuum Society.

    20. Effects of (Al,Ge) double doping on the thermoelectric properties of higher manganese silicides

      SciTech Connect (OSTI)

      Chen, Xi; Salta, Daniel; Zhang, Libin [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie [Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Zhou, Jianshi; Goodenough, John B.; Shi, Li [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States)

      2013-11-07

      Experiments and analysis have been carried out to investigate the effects of Al and (Al,Ge) doping on the microstructure and thermoelectric properties of polycrystalline higher manganese silicide (HMS) samples, which were prepared by solid-state reaction, ball milling, and followed by spark plasma sintering. It has been found that Al doping effectively increases the hole concentration, which leads to an increase in the electrical conductivity and power factor. By introducing the second dopant Ge into Al-doped HMS, the electrical conductivity is increased, and the Seebeck coefficient is decreased as a result of further increased hole concentration. The peak power factor is found to occur at a hole concentration between 1.8?×?10{sup 21} and 2.2?×?10{sup 21}?cm{sup ?3} measured at room temperature. The (Al,Ge)-doped HMS samples show lower power factors owing to their higher hole concentrations. The mobility of Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} with y?=?0.035 varies approximately as T{sup ?3/2} above 200?K, suggesting acoustic phonon scattering is the dominant scattering mechanism. The thermal conductivity of HMS does not change appreciably by Al or (Al,Ge) doping. The maximum ZT of (Al,Ge)-doped HMS is 0.57 at 823?K, which is similar to the highest value found in the Al-doped HMS samples. The ZT values were reduced in the Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} samples with high Ge concentration of y?=?0.025 and 0.035, because of reduced power factor. In addition, a two-band model was employed to show that the hole contribution to the thermal conductivity dominates the bipolar and electron contributions for all samples from 300 to 823?K and accounts for about 12% of the total thermal conductivity at about 800?K.

    1. Three-Dimensional (3D) Bicontinuous Hierarchically Porous Mn?O? Single Crystals for High Performance Lithium-Ion Batteries

      E-Print Network [OSTI]

      Huang, Shao-Zhuan; Jin, Jun; Cai, Yi; Li, Yu; Deng, Zhao; Zeng, Jun-Yang; Liu, Jing; Wang, Chao; Hasan, Tawfique; Su, Bao-Lian

      2015-10-06

      Bicontinuous hierarchically porous Mn?O? single crystals (BHP-Mn?O?-SCs) with uniform parallelepiped geometry and tunable sizes have been synthesized and used as anode materials for lithium-ion batteries (LIBs). The monodispersed BHP-Mn?O?-SCs...

    2. Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral Phases.

      E-Print Network [OSTI]

      Sparks, Donald L.

      Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral is thought to generally occur through either biologically or mineral-surface mediated Mn(II) oxidation. These two oxidation pathways result in the formation of nanometer-size Mn(IV) minerals. Compared

    3. Synthesis of NiCoMnX (X = In, Al) Heusler-type Magnetic Shape Memory Alloy Thin Films 

      E-Print Network [OSTI]

      Rios, Steven Eli

      2014-08-13

      Magnetic shape memory alloys are a class of shape memory alloys, and therefore exhibit a thermoelastic martensite phase transformation between symmetric and asymmetric crystalline states induced by appropriate temperature ...

    4. Influence of Mn and Ni on the microstructure and toughness of C-Mn-Ni weld metals

      SciTech Connect (OSTI)

      Zhang, Z.; Farrar, R.A. [Univ. of Southampton (United Kingdom). Dept. of Mechanical Engineering

      1997-05-01

      A systematic investigation has been carried out to study the microstructure and toughness of C-Mn-Ni low-alloy shielded metal arc (SMA) weld metals. The manganese and nickel concentrations were progressively changed to determine their influence on weld microstructure and mechanical properties as well as to identify their interactions. The results obtained showed that manganese and nickel have considerable effect on the weld metal microstructure, and both Mn and Ni affect the microstructure in a similar way, i.e., promoting acicular ferrite at the expense of proeutectoid ferrite (grain boundary ferrite and ferrite sideplates). The results in the top bead also showed that there is an optimum composition range that produces an optimum balance of weld metal microstructures. For optimum toughness, a combination of 0.6--1.4% manganese and 1.0--3.7% nickel is suggested. Additions beyond this limit promotes the formation of martensite and other microstructural features, which may be detrimental to weld metal toughness.

    5. Observation of localized states in atomically thin MoS{sub 2} field effect transistor

      SciTech Connect (OSTI)

      Ghatak, Subhamoy; Pal, Atindra Nath; Ghosh, Arindam

      2013-12-04

      We present electrical transport and low frequency (1/f) noise measurements on mechanically exfoliated single, bi and trilayer MoS{sub 2}-based FET devices on Si/SiO{sub 2} substrate. We find that the electronic states in MoS{sub 2} are localized at low temperatures (T) and conduction happens through variable range hopping (VRH). A steep increase of 1/f noise with decreasing T, typical for localized regime was observed in all of our devices. From gate voltage dependence of noise, we find that the noise power is inversely proportional to square of the number density (? 1/n{sup 2}) for a wide range of T, indicating number density fluctuations to be the dominant source of 1/f noise in these MoS{sub 2} FETs.

    6. Electronic and magnetic properties of Mo doped graphene; full potential approach

      SciTech Connect (OSTI)

      Thakur, Jyoti Kashyap, Manish K.; Singh, Mukhtiyar; Saini, Hardev S.

      2015-05-15

      The electronic and magnetic properties of Pristine and Mo doped Graphene have been calculated using WIEN2k implementation of full potential linearized augmented plane wave (FPLAPW) method based on Density Functional Theory (DFT). The exchange and correlation (XC) effects were taken into account by generalized gradient approximation (GGA). The calculated results show that Mo doping creates magnetism in Graphene by shifting the energy levels at E{sub F} and opens up a channel for Graphene to be used in real nanoscale device applications. The unpaired d-electrons of Mo atom are responsible for induced magnetism in Graphene. Magnetic ordering created in Graphene in this way makes it suitable for recording media, magnetic sensors, magnetic inks and spintronic devices.

    7. Highly conducting SrMoO{sub 3} thin films for microwave applications

      SciTech Connect (OSTI)

      Radetinac, Aldin Mani, Arzhang; Ziegler, Jürgen; Alff, Lambert; Komissinskiy, Philipp; Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf

      2014-09-15

      We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???·cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

    8. The development of uranium foil farication technology utilizing twin roll method for Mo-99 irradiation target

      E-Print Network [OSTI]

      Kim, C K; Park, H D

      2002-01-01

      MDS Nordion in Canada, occupying about 75% of global supply of Mo-99 isotope, has provided the irradiation target of Mo-99 using the rod-type UAl sub x alloys with HEU(High Enrichment Uranium). ANL (Argonne National Laboratory) through co-operation with BATAN in Indonesia, leading RERTR (Reduced Enrichment for Research and Test Reactors) program substantially for nuclear non-proliferation, has designed and fabricated the annular cylinder of uranium targets, and successfully performed irradiation test, in order to develop the fabrication technology of fission Mo-99 using LEU(Low Enrichment Uranium). As the uranium foils could be fabricated in laboratory scale, not in commercialized scale by hot rolling method due to significant problems in foil quality, productivity and economic efficiency, attention has shifted to the development of new technology. Under these circumstances, the invention of uranium foil fabrication technology utilizing twin-roll casting method in KAERI is found to be able to fabricate LEU or...

    9. Substrate induced modulation of electronic, magnetic and chemical properties of MoSe{sub 2} monolayer

      SciTech Connect (OSTI)

      Wasey, A. H. M. Abdul; Chakrabarty, Soubhik; Das, G. P., E-mail: msgpd@iacs.res.in [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032 (India)

      2014-04-15

      Monolayer of MoSe{sub 2}, having a typical direct band gap of ?1.5 eV, is a promising material for optoelectronic and solar cell applications. When this 2D semiconductor is supported on transition metal substrates, such as Ni(111) and Cu(111), its electronic structure gets modulated. First principles density functional investigation shows the appearance of de-localized mid-gap states in the density of states. The work function of the semiconductor overlayer gets modified considerably, indicating n-type doping caused by the metal contacts. The charge transfer across the metal-semiconductor junction also significantly enhances the chemical reactivity of the MoSe{sub 2} overlayer, as observed by Hydrogen absorption. Furthermore, for Ni contact, there is a signature of induced magnetism in MoSe{sub 2} monolayer.

    10. Exciton-dominant electroluminescence from a diode of monolayer MoS{sub 2}

      SciTech Connect (OSTI)

      Ye, Yu; Ye, Ziliang; Gharghi, Majid; Zhu, Hanyu; Wang, Yuan; Zhao, Mervin; Yin, Xiaobo; Zhang, Xiang

      2014-05-12

      In two-dimensional monolayer MoS{sub 2}, excitons dominate the absorption and emission properties. However, the low electroluminescent efficiency and signal-to-noise ratio limit our understanding of the excitonic behavior of electroluminescence. Here, we study the microscopic origin of the electroluminescence from a diode of monolayer MoS{sub 2} fabricated on a heavily p-type doped silicon substrate. Direct and bound-exciton related recombination processes are identified from the electroluminescence. At a high electron-hole pair injection rate, Auger recombination of the exciton-exciton annihilation of the bound exciton emission is observed at room temperature. Moreover, the efficient electrical injection demonstrated here allows for the observation of a higher energy exciton peak of 2.255?eV in the monolayer MoS{sub 2} diode, attributed to the excited exciton state of a direct-exciton transition.

    11. Two-step growth of two-dimensional WSe2/MoSe2 heterostructures

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Gong, Yongji; Lei, Sidong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pullikel M.

      2015-08-03

      Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, thismore »two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 ?m) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. As a result, a photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.« less

    12. Thermal aging modeling and validation on the Mo containing Fe-Cr-Ni alloys

      SciTech Connect (OSTI)

      Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

      2015-04-01

      Thermodynamics of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys is critical knowledge to understand thermal aging effect on the phase stability of Mo-containing austenitic steels, which subsequently facilitates alloy design/improvement and degradation mitigation of these materials for reactor applications. Among the intermetallic phases, Chi (?), Laves, and Sigma (?) are often of concern because of their tendency to cause embrittlement of the materials. The focus of this study is thermal stability of the Chi and Laves phases as they were less studied compared to the Sigma phase. Coupled with thermodynamic modeling, thermal stability of intermetallic phases in Mo containing Fe-Cr-Ni alloys was investigated at 1000, 850 and 700 C for different annealing times. The morphologies, compositions and crystal structures of the precipitates of the intermetallic phases were carefully examined by scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and transmission electron microscopy. Three key findings resulted from this study. First, the Chi phase is stable at high temperature, and with decreasing temperature it transforms into the Laves phase that is stable at low temperature. Secondly, Cr, Mo, Ni are soluble in both the Chi and Laves phases, with the solubility of Mo playing a major role in the relative stability of the intermetallic phases. Thirdly, in situ transformation from Chi phase to Laves phase was directly observed, which increased the local strain field, generated dislocations in the intermetallic phases, and altered the precipitate phase orientation relationship with the austenitic matrix. The thermodynamic models that were developed and validated were then applied to evaluating the effect of Mo on the thermal stability of intermetallic phases in type 316 and NF709 stainless steels.

    13. Characterization of metal contacts for two-dimensional MoS{sub 2} nanoflakes

      SciTech Connect (OSTI)

      Walia, Sumeet, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au; Balendhran, Sivacarendran; Sriram, Sharath; Bhaskaran, Madhu, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia) [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia); School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia); Wang, Yichao; Ab Kadir, Rosmalini; Sabirin Zoolfakar, Ahmad; Atkin, Paul; Zhen Ou, Jian; Kalantar-zadeh, Kourosh, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)] [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)

      2013-12-02

      While layered materials are increasingly investigated for their potential in nanoelectronics, their functionality and efficiency depend on charge injection into the materials via metallic contacts. This work explores the characteristics of different metals (aluminium, tungsten, gold, and platinum) deposited on to nanostructured thin films made of two-dimensional (2D) MoS{sub 2} flakes. Metals are chosen based on their work functions relative to the electron affinity of MoS{sub 2}. It is observed, and analytically verified that lower work functions of the contact metals lead to smaller Schottky barrier heights and consequently higher charge carrier injection through the contacts.

    14. Structure of Mo-91 Via (P,d) and (D,t) Reactions 

      E-Print Network [OSTI]

      Kozub, R. L.; Youngblood, David H.

      1973-01-01

      on +Mo have been studied at bombarding energies of 38.6 and 40.6 MeV, respectively. The (p, d) reaction Q value was measured to be -10.446 + 0.015 MeV. Excitation energies and angular distributions were measured for levels up to 3.5 MeV excitation...-model calculations of Iatching. I. INTRODUCTION The properties of N = 49 nuclei have been the sub- )set of recent theoretical" and experimental' ' in- vestigations. Kitching' has recently calculated properties of levels in "Mo up to about 3 MeV ex- citation...

    15. Primary arm spacing in chill block melt spun Ni-Mo alloys

      SciTech Connect (OSTI)

      Tewari, S.N.; Glasgow, T.K.

      1986-01-01

      Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

    16. Al Geist | ornl.gov

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      and research organizations. Al continues to work with researchers in DOE as well as industry to improve the capabilities of electronic notebook software. Among his numerous...

    17. ALS Scientific Advisory Committee Charter

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Scientific Advisory Committee Charter Print This document was revised and approved December 18, 2008. I. FUNCTION AND REPORTING The ALS Scientific Advisory Committee (SAC) is...

    18. ALS Scientific Advisory Committee Charter

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Committee Charter Print This document was revised and approved December 18, 2008. I. FUNCTION AND REPORTING The ALS Scientific Advisory Committee (SAC) is advisory to the...

    19. ALS Evidence Confirms Combustion Theory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

    20. ALS Evidence Confirms Combustion Theory

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process that...

    1. Web Generalisation Service in GiMoDig Towards a Standardised Service for Real-Time Generalisation

      E-Print Network [OSTI]

      Harrie, Lars

      Web Generalisation Service in GiMoDig ­ Towards a Standardised Service for Real-Time Generalisation in the Internet is facilitated by standardised Web Services for the selection, access and presentation of spatial, demand for an internet service for generalisation. In the context of the GiMoDig project, a prototype

    2. Background radioactivity of construction materials, raw substance and ready-made CaMoO4 crystals

      E-Print Network [OSTI]

      Busanov, O A; Gavriljuk, Yu M; Gezhaev, A M; Kazalov, V V; Kornoukhov, V N; Kuzminov, V V; Moseev, P S; Panasenko, S I; Ratkevich, S S; Yakimenko, S P

      2013-01-01

      The results of measurements of natural radioactive isotopes content in different source materials of natural and enriched composition used for CaMoO4 scintillation crystal growing are presented. The crystals are to be used in the experiment to search for double neutrinoless betas-decay of Mo-100.

    3. Kinetics and Mechanism of Ethane Oxidation to Acetic Acid on Catalysts Based on Mo-V-Nb Oxides

      E-Print Network [OSTI]

      Iglesia, Enrique

      Kinetics and Mechanism of Ethane Oxidation to Acetic Acid on Catalysts Based on Mo-V-Nb Oxides and isotopic studies showed that C-H bond activation in ethane by surfaces essentially saturated with lattice oxygens is the sole kinetically relevant step in ethane oxidation on Mo-V-NbOx mixed oxides

    4. Isotopic Mo Neutron Total Cross Section Measurements in the Energy Range 1 to 620 keV

      E-Print Network [OSTI]

      Danon, Yaron

      are of particular importance because stable Mo isotopes can be found in significant concentrations in a nuclear fuel, fuel cladding, and most importantly as an advanced nuclear fuel in the form of U-Mo [2, 3 burst width. More informa- tion on the detector can be found in Reference [1]. Highly-enriched metallic

    5. Role of Microstructure in Promoting Fracture and Fatigue Resistance in Mo-Si-B Alloys J. J. Kruzic*

      E-Print Network [OSTI]

      Ritchie, Robert

      -Si-B based alloys is presented. Fracture toughness and fatigue-crack growth properties are measured at 25º to impart some ductility and fracture resistance to a three phase microstructure also containing Mo3SiRole of Microstructure in Promoting Fracture and Fatigue Resistance in Mo-Si-B Alloys J. J. Kruzic

    6. Temperature activated self-lubrication in CrN/Mo2N nanolayer coatings Robin Abraham Koshy 1,

      E-Print Network [OSTI]

      Marks, Laurence D.

      . Introduction Hard coatings for cutting tools have been in use for many decades , [1­6], and have evolved from coatings Tool coatings Self lubrication Multi-layers Magnetron Sputtering Reactive sputtering CrN Mo2N CrTemperature activated self-lubrication in CrN/Mo2N nanolayer coatings Robin Abraham Koshy 1

    7. CRITICAL BEHAVIOR OF ACOUSTICAL WAVES IN FERROELECTRIC-FERROELASTIC PHASE OF Tb2(MoO4)3

      E-Print Network [OSTI]

      Paris-Sud XI, Université de

      . - Gadolinium molybdate Gd2(MO04). (GMO) and terbium molybdate Tb2(Mo04)3 (TMO) under- goes a ,structural phase]. Ultrasonic measurements [5, 6] and Brillouin diffusion experiments [7, 8] have been carried out on GMO with the Centre National de la Recherche Scienti- fique. for a and c directions in a GMO monodomain : a coupling

    8. Investigations of segregation phenomena in highly strained Mn-doped Ge wetting layers and Ge quantum dots embedded in silicon

      SciTech Connect (OSTI)

      Prestat, E., E-mail: eric.prestat@gmail.com; Porret, C.; Favre-Nicolin, V.; Tainoff, D.; Boukhari, M.; Bayle-Guillemaud, P.; Jamet, M.; Barski, A., E-mail: andre.barski@cea.com [INAC, SP2M, CEA and Université Joseph Fourier, 17 rue des Martyrs, 38054 Grenoble (France)

      2014-03-10

      In this Letter, we investigate manganese diffusion and the formation of Mn precipitates in highly strained, few monolayer thick, Mn-doped Ge wetting layers and nanometric size Ge quantum dot heterostructures embedded in silicon. We show that in this Ge(Mn)/Si system manganese always precipitates and that the size and the position of Mn clusters (precipitates) depend on the growth temperature. At high growth temperature, manganese strongly diffuses from germanium to silicon, whereas decreasing the growth temperature reduces the manganese diffusion. In the germanium quantum dots layers, Mn precipitates are detected, not only in partially relaxed quantum dots but also in fully strained germanium wetting layers between the dots.

    9. Ferromagnetic (Ga,Mn)As nanostructures for spintronic applications

      SciTech Connect (OSTI)

      Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Makosa, Andrzej; Wrobel, Jerzy; Sadowski, Janusz

      2013-12-04

      Magneto-resistive, cross-like nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, composed of two perpendicular nanostripes crossing in the middle of their length, represent four-terminal devices, in which an electric current can be driven through any of the two nanostripes. In these devices, a novel magneto-resistive memory effect, related to a rearrangement of magnetic domain walls in the central part of the device, has been demonstrated. It consists in that the zero-field resistance of a nanostripe depends on the direction of previously applied magnetic field. The nanostructures can thus work as two-state devices providing basic elements of nonvolatile memory cells.

    10. Impedance analysis of MnCoCuO NTC ceramic

      SciTech Connect (OSTI)

      Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

      2005-07-12

      Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

    11. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

      SciTech Connect (OSTI)

      Quereda, J.; Castellanos-Gomez, A.; Agraït, N.; Rubio-Bollinger, G.

      2014-08-04

      We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

    12. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

      SciTech Connect (OSTI)

      Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan

      2014-06-09

      We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

    13. Oxygen reduction activity on perovskite oxide surfaces: a comparative first-principle study of LaMnO$_3$, LaFeO$_3$ and LaCrO$_3$

      E-Print Network [OSTI]

      Wang, Yan

      2012-01-01

      The understanding of oxygen reduction reaction (ORR) activity on perovskite oxide surfaces is essential for promising future fuel cell applications. We report a comparative study of ORR mechanisms on La$B$O$_3$ ($B$=Mn, Fe, Cr) surfaces by first-principles calculations based on density functional theory (DFT). Results obtained from varied DFT methods such as generalized gradient approximation(GGA), GGA+$U$ and the hybrid Hartree-Fock density functional method are reported for comparative purposes. We find that the results calculated from hybrid-functional method suggest that the order of ORR activity is LaMnO$_3$ $>$ LaCrO$_3$ $>$ LaFeO$_3$, which is in better agreement with recent experimental results (Suntivich \\textit{et al.}, Nature Chemistry 3, 546 (2011)) than those using the GGA or GGA+$U$ method.

    14. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

      SciTech Connect (OSTI)

      Liu, Chao-Xing; /Tsinghua U., Beijing /Stanford U., Phys. Dept.; Qi, Xiao-Liang; /Stanford U., Phys. Dept.; Dai, Xi; Fang, Zhong; /Beijing, Inst. Phys.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

      2010-03-19

      The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

    15. Recent progress of magnetocaloric effect and magnetic refrigerant materials of Mn compounds (invited)

      SciTech Connect (OSTI)

      Wada, H. Takahara, T.; Katagiri, K.; Ohnishi, T.; Soejima, K.; Yamashita, K.

      2015-05-07

      Magnetocaloric and related properties of Ru and Ni substituted (MnFe){sub 2}(PSi) are presented. It is found that Ru and Ni are effective doping elements to reduce the thermal hysteresis of (MnFe){sub 2}(PSi). The origin of the thermal hysteresis is discussed on the basis of a thermodynamic model. It is shown that the elastic energy is responsible for the thermal hysteresis. We also show recent developments of the production process of Mn compounds in an industrial scale.

    16. MoIAC Pre-Audit Form Ways to submit this form

      E-Print Network [OSTI]

      Noble, James S.

      If No, please list issues with which you would like our assistance: Water Consumption and Treatment No Describe in-house water treatment facilities if any (filtration, RO, pH, flow rates etc.): Sewage volume (Ext.): E-Mail: Name: Position: Phone (Ext.): E-Mail: #12;MoIAC Pre-Audit Form Products Produced: Raw

    17. Air-Stable Surface Charge Transfer Doping of MoS2 by Benzyl Daisuke Kiriya,,,

      E-Print Network [OSTI]

      Javey, Ali

      Air-Stable Surface Charge Transfer Doping of MoS2 by Benzyl Viologen Daisuke Kiriya,,,§ Mahmut Information ABSTRACT: Air-stable doping of transition metal dichalcogenides is of fundamental importance. The n-doped samples exhibit excellent stability in both ambient air and vacuum. Notably, we obtained

    18. Modelling and characterisation of Mo2C precipitation and cementite dissolution during

      E-Print Network [OSTI]

      Cambridge, University of

      of Fe ­ C ­ Mo martensitic steel S. Yamasaki and H. K. D. H. Bhadeshia The precipitation and Ostwald martensitic steel have been characterised and modelled, taking account of local equilibrium, the capillarity@to.kimitsu.nsc.co.jp) is now with Nippon Steel Corp., 1 Kimitsu, Kimitsu City, 299­ 1141 Japan. Manuscript received 15 July

    19. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Yue, Lanping; Jin, Yunlong; Zhang, Wenyong; Sellmyer, David J.

      2015-01-01

      The addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. The effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox(x=0, 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. The coercivity of the samples increases with the increase in Mo content (x?1.5). The maximum energy product(BH)maxincreases with increasingxfrom 0.5?MGOe forx=0to a maximum value of 4.2?MGOe forx=1.5. The smallest domain size with a relativelymore »short magnetic correlation length of 128?nm and largest root-mean-square phase shift?rmsvalue of 0.66° are observed for thex=1.5. The optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.« less

    20. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

      Broader source: Energy.gov [DOE]

      NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

    1. Equation of state of bcc-Mo by static volume compression to 410?GPa

      SciTech Connect (OSTI)

      Akahama, Yuichi; Hirao, Naohisa; Ohishi, Yasuo; Singh, Anil K.

      2014-12-14

      Unit cell volumes of Mo and Pt have been measured simultaneously to ?400?GPa by x-ray powder diffraction using a diamond anvil cell and synchrotron radiation source. The body-centered cubic (bcc) phase of Mo was found to be stable up to 410 GPa. The equation of state (EOS) of bcc-Mo was determined on the basis of Pt pressure scale. A fit of Vinet EOS to the volume compression data gave K{sub 0}?=?262.3(4.6) GPa, K{sub 0}??=?4.55(16) with one atmosphere atomic volume V{sub 0}?=?31.155(24) A{sup 3}. The EOS was in good agreement with the previous ultrasonic data within pressure difference of 2.5%–3.3% in the multimegabar range, though the EOS of Mo proposed from a shock compression experiment gave lower pressure by 7.2%–11.3% than the present EOS. The agreement would suggest that the Pt pressure scale provides an accurate pressure value in an ultra-high pressure range.

    2. On the Higher-Order MoM-PO Electromagnetic Modeling of Vehicles

      E-Print Network [OSTI]

      Notaros, Branislav M.

      vehicles (cars, airplanes, helicopters, spacecraft, etc.). From the electromagnetic point of view and accurate higher-order, large-domain hybrid computational technique based on the method of moments (Mo the efficiency and accuracy of the hybrid higher-order computational technique and its advantages over

    3. ZnMoO4: a promising bolometer for neutrinoless double beta decay searches

      E-Print Network [OSTI]

      J. W. Beeman; F. Bellini; S. Capelli; L. Cardani; N. Casali; I. Dafinei; S. Di Domizio; F. Ferroni; E. N. Galashov; L. Gironi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; V. N. Shlegel; Ya. V. Vasilyev; C. Tomei; M. Vignati

      2012-02-01

      We investigate the performances of two ZnMoO4 scintillating crystals operated as bolometers, in view of a next generation experiment to search the neutrinoless double beta decay of Mo-100. We present the results of the alpha vs beta/gamma discrimination, obtained through the scintillation light as well as through the study of the shape of the thermal signal alone. The discrimination capability obtained at the 2615 keV line of Tl-208 is 8 sigma, using the heat-light scatter plot, while it exceeds 20 sigma using the shape of the thermal pulse alone. The achieved FWHM energy resolution ranges from 2.4 keV (at 238 keV) to 5.7 keV (at 2615 keV). The internal radioactive contaminations of the ZnMoO4 crystals were evaluated through a 407 hours background measurement. The obtained limit is < 32 microBq/kg for Th-228 and Ra-226. These values were used for a Monte Carlo simulation aimed at evaluating the achievable background level of a possible, future array of enriched ZnMoO4 crystals.

    4. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; et al

      2015-09-11

      We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path throughmore »orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.« less

    5. Data compression trade-offs in sensor networks Mo Chen and Mark L. Fowler

      E-Print Network [OSTI]

      Fowler, Mark

      Data compression trade-offs in sensor networks Mo Chen and Mark L. Fowler Department of Electrical: mfowler@binghamton.edu ABSTRACT This paper first discusses the need for data compression within sensor networks and argues that data compression is a fundamental tool for achieving trade-offs in sensor networks

    6. Statistical Mechanics, CHEM 6481, Fall MWF 10:05-10:55am, MoSE 1224

      E-Print Network [OSTI]

      Sherrill, David

      Statistical Mechanics, CHEM 6481, Fall MWF 10:05-10:55am, MoSE 1224 Course website: T-Square Prerequisites: Advanced quantum mechanics (can be taken concurrently), advanced thermodynamics, multivariate" are considered background material. Required Text: "Introduction to Modern Statistical Mechanics," David Chandler

    7. A Network Model and Computational Approach Mo Supply Chain for Nuclear Medicine

      E-Print Network [OSTI]

      Nagurney, Anna

      in the world. From: The Supply of Medical Radioisotopes: An Economic Study of the Molybdenum-99 Supply Chain to create an image of that site or organ. Technetium, 99mTc, a decay product of Molybdenum, 99Mo, is the most commonly used medical radioisotope, accounting for over 80% of the radioisotope injections

    8. MODULO AND GRID BASED CHANNEL SELECTION IN AD HOC Gareth Owen Mo Adda

      E-Print Network [OSTI]

      Kent, University of

      based. Antenna techniques attempt to reduce the interference or mitigate it by for example, directional, University of Portsmouth Buckingham Building, Lion Terrace, Portsmouth England, PO1 3HE {gareth.owen, mo.adda}@port.ac channels. We analyse many techniques requiring only information available locally and those that do

    9. Synthesis and characterization of CrN/Mo2N multilayers and phases of Molybdenum nitride

      E-Print Network [OSTI]

      Marks, Laurence D.

      ; Nanolayers; Tool coatings 1. Introduction Hard coatings for cutting tools have been in use now for thirty for dry machining [7­10]. If tools (coatings) can effectively tolerate high temperatures or can helpOx and CrN/Mo2N multilayer films were deposited by reactive sputtering. Characterization of the coatings

    10. Lithium Intercalation in Graphene/MoS2 Composites: First-Principles Insights

      E-Print Network [OSTI]

      Shao, Xiji; Pang, Rui; Shi, Xingqiang

      2015-01-01

      As a storage material for Li-ion batteries, graphene/molybdenum disulfide (Gr/MoS2) composites have been intensively studied in experiments. But the relevant theoretical works from first-principles are lacking. In the current work, van-der-Waals-corrected density functional theory calculations are performed to investigate the interaction of Li in Gr/MoS2 composites. Three interesting features are revealed for the intercalated Gr/Li(n)/MoS2 composites (n = 1 to 9). One is the reason for large Li storage capacity of Gr/MoS2: due to the binding energies per Li atom increase with the increasing number of intercalated Li atoms. Secondly, the band gap opening of Gr is found, and the band gap is enlarged with the increasing number of intercalated Li atoms, up to 160 meV with nine Li; hence these results suggest an efficient way to tune the band gap of graphene. Thirdly, the Dirac cone of Gr always preserve for different number of ionic bonded Li atoms.

    11. Spectroscopy of low energy solar neutrinos by MOON -Mo Observatory Of Neutrinos-

      E-Print Network [OSTI]

      Washington at Seattle, University of

      Spectroscopy of low energy solar neutrinos by MOON -Mo Observatory Of Neutrinos- R. Hazamaa , P Be solar 's. The present status of MOON for the low energy solar experiment is briefly discussed the pp solar flux with good accuracy. 1. INTRODUCTION Realtime studies of the high-energy component of 8

    12. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

      2015-05-06

      A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highlymore »active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).« less

    13. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Ramirez, Pedro J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. Central De Venezuela, Caracas (Venesuela); Stachiola, Dario [Brookhaven National Lab. (BNL), Upton, NY (United States); Brito, Joaquin L. [Inst. Venezolano de Investigaciones Cientificas, Caracas (Venezuela)

      2015-05-06

      A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highly active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).

    14. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

      SciTech Connect (OSTI)

      M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

      2004-09-30

      Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

    15. Mn solid solutions in self-assembled Ge/Si (001) quantum dot heterostructures

      SciTech Connect (OSTI)

      Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

      2012-12-10

      Heteroepitaxial Ge{sub 0.98}Mn{sub 0.02} quantum dots (QDs) on Si (001) were grown by molecular beam epitaxy. The standard Ge wetting layer-hut-dome-superdome sequence was observed, with no indicators of second phase formation in the surface morphology. We show that Mn forms a dilute solid solution in the Ge quantum dot layer, and a significant fraction of the Mn partitions into a sparse array of buried, Mn-enriched silicide precipitates directly underneath a fraction of the Ge superdomes. The magnetic response from the ultra-thin film indicates the absence of robust room temperature ferromagnetism, perhaps due to anomalous intermixing of Si into the Ge quantum dots.

    16. Prospects for high temperature ferromagnetism in (Ga,Mn)As semiconductors 

      E-Print Network [OSTI]

      Jungwirth, T.; Wang, KY; Masek, J.; Edmonds, KW; Konig, J.; Sinova, Jairo; Polini, M.; Goncharuk, NA; MacDonald, AH; Sawicki, M.; Rushforth, AW; Campion, RP; Zhao, LX; Foxon, CT; Gallagher, BL.

      2005-01-01

      We report on a comprehensive combined experimental and theoretical study of Curie temperature trends in (Ga,Mn)As ferromagnetic semiconductors. Broad agreement between theoretical expectations and measured data allows us to conclude that T-c in high...

    17. Effect of Mn substitution on the transport properties of co-sputtered...

      Office of Scientific and Technical Information (OSTI)

      exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical...

    18. Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals

      E-Print Network [OSTI]

      Techapiesancharoenkij, Ratchatee, 1979-

      2007-01-01

      Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

    19. Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1

      E-Print Network [OSTI]

      Sparks, Donald L.

      Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano-crystalline

    20. Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy

      E-Print Network [OSTI]

      Niu, Yunyun

      Radiation-induced DNA damage is a precursor to mutagenesis and cytotoxicity. During radiotherapy, exposure of healthy tissues can lead to severe side effects. We explored the potential of mitochondrial SOD (MnSOD) gene ...

    1. Growth of GaMnAs under near-stoichiometric conditions

      SciTech Connect (OSTI)

      Avrutin, V.; Humienik, D.; Frank, S.; Koeder, A.; Schoch, W.; Limmer, W.; Sauer, R.; Waag, A. [Abteilung Halbleiterphysik, Universitaet Ulm, D-89069 Ulm (Germany); Institut fuer Halbleitertechnik, Technische Universitaet (TU) Braunschweig, Hans-Sommer-Strasse 66, D38103 Braunschweig (Germany)

      2005-07-15

      We studied the effect of the V/III flux ratio and substrate temperature on magnetotransport properties and lattice parameters of Ga{sub 0.96}Mn{sub 0.04}As grown by molecular-beam epitaxy. For all the substrate temperatures, the conductivities and Curie temperatures of the layers were found to increase as the V/III flux ratio approaches 1. A Curie temperature as high as 95 K was achieved for the Ga{sub 0.96}Mn{sub 0.04}As samples grown at 240 deg. C and a V/III ratio of about 1.5. The lattice parameter of Ga{sub 0.96}Mn{sub 0.04}As increased with decreasing V/III ratio and/or increasing growth temperature. Possible reasons for the effect of the V/III ratio on the magnetotransport properties and lattice parameter of GaMnAs are discussed.

    2. Dispersive magnetic excitations in the S=1 antiferromagnet Ba3Mn2O8

      SciTech Connect (OSTI)

      Stone, Matthew B [ORNL; Lumsden, Mark D [ORNL; Qiu, Y. [National Institute of Standards and Technology (NIST); Samulon, Eric C [Stanford University; Batista, C. D. [Los Alamos National Laboratory (LANL); Fisher, Ian R [Stanford University

      2008-01-01

      We present powder inelastic neutron scattering measurements of the $S=1$ dimerized antiferromagnet Ba$_3$Mn$_2$O$_8$. The $T=1.4$~K~magnetic spectrum exhibits a spin-gap of $\\Delta = 0.9$~meV and a dispersive spectrum with a bandwidth of approximately $1.74$~meV. Comparison to coupled dimer models describe the dispersion and scattering intensity accurately and determine the exchange constants in Ba$_3$Mn$_2$O$_8$. Interdimer exchange between triangular lattice dimer bilayers in Ba$_3$Mn$_2$O$_8$ is two orders of magnitude weaker than intradimer exchange. Ba$_3$Mn$_2$O$_8$ is thus a quasi-two-dimensional frustrated bilayer triangular lattice of $S=1$ dimers. The wave vector dependent scattering intensity confirms the proposed $S=1$ dimer bond. Temperature dependent measurements of the magnetic excitations indicate the presence of both singlet-triplet and thermally activated triplet-quintet excitations.

    3. Ferromagnetic transition temperature enhancement in (Ga,Mn)As semiconductors by carbon codoping 

      E-Print Network [OSTI]

      Jungwirth, T.; Masek, J.; Sinova, Jairo; MacDonald, AH.

      2003-01-01

      We present a theoretical study of (Ga,Mn)(As,C) diluted magnetic semiconductors with high C acceptor density that combines insights from phenomenological model and microscopic approaches. A tight-binding coherent-potential approximation is used...

    4. Decay of neutron-rich Mn nuclides and deformation of heavy Fe isotopes

      E-Print Network [OSTI]

      M. Hannawald; T. Kautzsch; A. Woehr; W. B. Walters; K. -L. Kratz; V. N. Fedoseyev; V. L. Mishin; W. Boehmer; B. Pfeiffer; V. Sebastian; Y. Jading; U. Koester; J. Lettry; H. L. Ravn; the ISOLDE Collaboration

      1998-12-21

      The use of chemically selective laser ionization combined with beta-delayed neutron counting at CERN/ISOLDE has permitted identification and half-life measurements for 623-ms Mn-61 up through 14-ms Mn-69. The measured half-lives are found to be significantly longer near N=40 than the values calculated with a QRPA shell model using ground-state deformations from the FRDM and ETFSI models. Gamma-ray singles and coincidence spectroscopy has been performed for Mn-64 and Mn-66 decays to levels of Fe-64 and Fe-66, revealing a significant drop in the energy of the first 2+ state in these nuclides that suggests an unanticipated increase in collectivity near N=40.

    5. Quantum Chemical Study of Arsenic (III, V) Adsorption on Mn-Oxides

      E-Print Network [OSTI]

      Sparks, Donald L.

      sites under simulated acidic pH conditions. Therefore, we propose that As(V) adsorption inhibits As(III) oxidation by blocking adsorption sites. Under simulated acidic pH conditions, Mn(IV) sites exhibited

    6. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

      E-Print Network [OSTI]

      Nelson-Cheeseman, B. B.

      2007-01-01

      2 O 4 –Fe 3 O 4 spinel interfaces B. B. Nelson-Cheeseman,isostructural spinel-spinel interface of NiMn 2 O 4 (NMO)–Feis preserved, both bulk and interface sensitive measurements

    7. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

      SciTech Connect (OSTI)

      Tan, Ying-Hua; Yu, Ke Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang

      2014-08-14

      The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

    8. Study of structure of the TiO{sub 2}–MoO{sub 3} bilayer films by Raman spectroscopy

      SciTech Connect (OSTI)

      Santos, Elias de Barros; Sigoli, Fernando Aparecido; Mazali, Italo Odone

      2014-12-15

      Highlights: • TiO{sub 2}–MoO{sub 3} bilayer thin films were easily prepared by dip-coating technique. • Ti and Mo metallo-organic compounds were used as source of its respective oxide. • TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3} were identified. • The bilayer structure was investigated by Raman spectroscopy. - Abstract: In this work, TiO{sub 2}–MoO{sub 3} films were easily prepared by dip-coating technique and metallo-organic decomposition process (MOD). Raman analyses indicate the formation of TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3}. It was observed that the Raman bands intensities attributed to TiO{sub 2} and MoO{sub 3} oxides were dependent on the number of decomposition–deposition cycles (DDC). The different number of DDC generates films with different thicknesses and the Raman signal was sensitive to this variation. Raman analyses provided qualitative information about the bilayer structure of the bi-component TiO{sub 2}–MoO{sub 3} films, which was confirmed by scanning electron microscopy. In this direction, the dip-coating technique and MOD process can be an efficient strategy to facile preparation of many samples to be used in applications.

    9. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

      SciTech Connect (OSTI)

      Pei, L.Z. Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

      2013-07-15

      Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

    10. Magnetic Order and Ferroelectricity in RMnO3 Multiferroic Manganites: Coupline Between R- and Mn-spins

      SciTech Connect (OSTI)

      Aliouane, N.; Prokhnenko, O; Feyerherm, R; Mostovoy, M; Strempfer, J; Habicht, K; Rule, K; Dudzik, E; Wolter, A; et. al.

      2008-01-01

      Combining polarized and unpolarized neutron scattering techniques with x-ray resonant magnetic scattering we have studied the coupling between the Mn- and R-spin-ordering in the multiferroic RMnO3, R = Tb and Dy. Polarized neutron diffraction reveals the moment orientation associated with the various modes describing the complex magnetic ordering observed in TbMnO3, while neutron diffraction in high magnetic fields allows the identification of the origin (Mn versus Tb) of the various modes. In this way we identify significant Cx and Fz contributions from Tb arising from the coupling of Tb moments to the Mn cycloidal ordering. The x-ray studies give further insight into this coupling. In the ferroelectric phase, both TbMnO3 and DyMnO3 show an induced ordering of the R-ion with a propagation vector clamped to the Mn ordering. While in TbMnO3 this clamping leads to a ground state in which the two propagation vectors tTb and tMn obey the relation 3tTb-tMn = 1, in DyMnO3 the ferroelectric polarization is effectively enhanced. The theoretical analysis of these effects not only explains the observed behavior for R = Tb and Dy but can also be applied to understand the Mn-R interaction in the related compounds with R = Gd and Ho. Finally we show both experimentally and theoretically how the Mn-R coupling can enhance the ferroelectric polarization in this manganite's multiferroics.

    11. Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites

      SciTech Connect (OSTI)

      Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

      2013-12-16

      This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

    12. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Hunter, Gary J.; Trinh, Chi H.; Bonetta, Rosalin; Stewart, Emma E.; Cabelli, Diane E.; Hunter, Therese

      2015-08-27

      C. elegans MnSOD-3 has been implicated in the longevity pathway and its mechanism of catalysis is relevant to the aging process and carcinogenesis. The structures of MnSOD-3 provide unique crystallographic evidence of a dynamic region of the tetrameric interface (residues 41–54). We have determined the structure of the MnSOD-3-azide complex to 1.77-Å resolution. The analysis of this complex shows that the substrate analog, azide, binds end-on to the manganese center as a sixth ligand and that it ligates directly to a third and new solvent molecule also positioned within interacting distance to the His30 and Tyr34 residues of the substratemore »access funnel. This is the first structure of a eukaryotic MnSOD-azide complex that demonstrates the extended, uninterrupted hydrogen-bonded network that forms a proton relay incorporating three outer sphere solvent molecules, the substrate analog, the gateway residues, Gln142, and the solvent ligand. This configuration supports the formation and release of the hydrogen peroxide product in agreement with the 5-6-5 catalytic mechanism for MnSOD. The high product dissociation constant k? of MnSOD-3 reflects low product inhibition making this enzyme efficient even at high levels of superoxide.« less

    13. Sr{sub 2}MgMoO{sub 6??} thin films fabricated using pulsed-laser deposition with high concentrations of oxygen vacancies

      SciTech Connect (OSTI)

      Shigematsu, K. [Department of Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan); Chikamatsu, A., E-mail: chikamatsu@chem.s.u-tokyo.ac.jp; Fukumura, T. [Department of Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan); JST-CREST, Bunkyo-ku, Tokyo 113-0033 (Japan); Toyoda, S. [Department of Materials Science and Engineering, Kyoto University, Yoshida-honmachi, Kyoto 606-8501 (Japan); Ikenaga, E. [JASRI/SPring-8, Mikazuki-cho, Hyogo 679-5198 (Japan); Hasegawa, T. [Department of Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan); JST-CREST, Bunkyo-ku, Tokyo 113-0033 (Japan); Kanagawa Academy of Science and Technology (KAST), Kawasaki, Kanagawa 213-0012 (Japan)

      2014-06-30

      We fabricated epitaxial thin films of oxygen-vacant Sr{sub 2}MgMoO{sub 6??} using pulsed laser deposition. The films showed low resistivity of the order of 10{sup ?2} ??cm at 300?K. X-ray diffraction analyses revealed that Mg and Mo ions in the Sr{sub 2}MgMoO{sub 6??} films were considerably disordered, compared to those in bulk Sr{sub 2}MgMoO{sub 6??}. The proportion of oxygen vacancies estimated through hard x-ray photoemission measurements was as large as 0.37, and correlated well with the Mg/Mo ordering.

    14. Real-time x-ray studies of Mo-seeded Si nanodot formation during ion bombardment

      SciTech Connect (OSTI)

      Ozaydin, Gozde; Oezcan, Ahmet S.; Wang, Yiyi; Ludwig, Karl F.; Zhou Hua; Headrick, Randall L.; Siddons, D. Peter [Department of Aerospace and Mechanical Engineering, Boston University, Boston, Massachusetts 02215 (United States); Department of Physics, Boston University, Boston, Massachusetts 02215 (United States); Department of Physics, University of Vermont, Burlington, Vermont 05405 (United States); National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973 (United States)

      2005-10-17

      The formation of self-organized Si nanostructures induced by Mo seeding during normal incidence Ar{sup +} ion bombardment at room temperature is reported. Silicon surfaces without Mo seeding develop only power-law roughness during 1000 eV ion bombardment at normal incidence, in agreement with scaling theory expectations of surface roughening. However, supplying Mo atoms to the surface during ion bombardment seeds the development of highly correlated, nanoscale structures ('dots') that are typically 3 nm high with a spatial wavelength of approximately 30 nm. With time, these saturate and further surface roughening is dominated by the growth of long-wavelength corrugations.

    15. Theoretical study on strain induced variations in electronic properties of 2H-MoS{sub 2} bilayer sheets

      SciTech Connect (OSTI)

      Dong, Liang; Dongare, Avinash M.; Namburu, Raju R.; O'Regan, Terrance P.; Dubey, Madan

      2014-02-03

      The strain dependence of the electronic properties of bilayer sheets of 2H-MoS{sub 2} is studied using ab initio simulations based on density functional theory. An indirect band gap for bilayer MoS{sub 2} is observed for all variations of strain along the basal plane. Several transitions for the indirect band gap are observed for various strains for the bilayer structure. The variation of the band gap and the carrier effective masses for the holes and the electrons for the bilayer MoS{sub 2} structure under conditions of uniaxial strain, biaxial strain, as well as uniaxial stress is investigated.

    16. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

      SciTech Connect (OSTI)

      Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

      2013-09-15

      The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

    17. ROLE OF TRIVALENT Mn IN OXIDATION OF ORGANIC MATTER Christopher J. Matocha and D.L. Sparks

      E-Print Network [OSTI]

      Sparks, Donald L.

      organic matter^ M AT E R I A L S A N D M E T H O D S Reactivity studies of solid Mn(lll,IV) (hydr) oxide of available Mn(lli). R E S U L T S No correlation existed between the initial reductive dissolution ratesROLE OF TRIVALENT Mn IN OXIDATION OF ORGANIC MATTER Christopher J. Matocha and D.L. Sparks Dept

    18. Large scale and fast synthesis of multiferroic TbMn{sub 2}O{sub 5} single-crystalline nanorods

      SciTech Connect (OSTI)

      An, Xiaoxin; Wang, You; Deng, Jinxia; Chen, Jun, E-mail: junchen@ustb.edu.cn; Xing, Xianran, E-mail: xing@ustb.edu.cn

      2014-03-01

      Graphical abstract: - Highlights: • Pure TbMn{sub 2}O{sub 5} phase was synthesized in a wide temperature range for a short time. • Smooth and uniform single-crystalline nanorods were obtained. • The element Mn in TbMn{sub 2}O{sub 5} exhibits a mix Mn{sup 3+/4+} valence state with an average value of 3.5+, and the element Tb exhibits Tb{sup 3+}. - Abstract: Crystalline multiferroic TbMn{sub 2}O{sub 5} nanorods were successfully synthesized by a facile and scalable molten salt synthesis with NaCl–Na{sub 2}SO{sub 4} eutectic salts used in the temperature range of 750–900 °C for only 2 h. The obtained TbMn{sub 2}O{sub 5} could be indexed to an orthorhombic phase by the results of XRD patterns. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), combined with high-resolution TEM (HRTEM), selected area electron diffraction (SAED), and EDS, have been employed to investigate the morphology, size, crystallinity, structure, and composition of the as-synthesized TbMn{sub 2}O{sub 5} nanorods. The TbMn{sub 2}O{sub 5} product exhibits smooth, uniform and crystalline nanorods with diameters of 30–70 nm, and length of varying from 3 to 6 ?m. The results of X-ray photoelectron spectroscopy (XPS) analysis indicate that the elements Mn and Tb in TbMn{sub 2}O{sub 5} exhibit Mn{sup 3+/4+} and Tb{sup 3+}, respectively. The magnetic properties of the as-prepared TbMn{sub 2}O{sub 5} nanorods have been also characterized by physical properties measurement system (PPMS)

    19. Silicon heterojunction solar cell with passivated hole selective MoO{sub x} contact

      SciTech Connect (OSTI)

      Battaglia, Corsin; Yin, Xingtian; Zheng, Maxwell; Javey, Ali, E-mail: ajavey@eecs.berkeley.edu [Electrical Engineering and Computer Sciences Department, University of California, Berkeley, California 94720 (United States); Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Martín de Nicolás, Silvia; De Wolf, Stefaan; Ballif, Christophe [Photovoltaics and Thin Film Electronics Laboratory, Ecole Polytechnique Fédérale de Lausanne, 2000 Neuchâtel (Switzerland)

      2014-03-17

      We explore substoichiometric molybdenum trioxide (MoO{sub x}, x?MoO{sub x}, we observe a substantial gain in photocurrent of 1.9?mA/cm{sup 2} in the ultraviolet and visible part of the solar spectrum, when compared to a p-type amorphous silicon emitter of a traditional silicon heterojunction cell. Our results emphasize the strong potential for oxides as carrier selective heterojunction partners to inorganic semiconductors.

    20. Spectroscopy of Double-Beta and Inverse-Beta Decays from 100Mo for Neutrinos

      E-Print Network [OSTI]

      H. Ejiri; J. Engel; R. Hazama; P. Krastev; N. Kudomi; R. G. H. Robertson

      2000-05-15

      Spectroscopic studies of two beta-rays from 100Mo are shown to be of potential interest for investigating both the Majorana neutrino mass by neutrinoless double beta-decay and low energy solar neutrino's by inverse beta-decay. With a multi-ton 100Mo detector, coincidence studies of correlated beta-beta from neutrinoless double beta-decay, together with the large Q value, permit identification of the neutrino-mass term with a sensitivity of ~ 0.03 eV. Correlation studies of the inverse beta and the successive beta-decay of 100Tc, together with the large capture rates for low energy solar neutrino's, make it possible to detect in realtime individual low energy solar neutrino in the same detector.

    1. Strong exciton-plasmon coupling in MoS2 coupled with plasmonic lattice

      E-Print Network [OSTI]

      Liu, Wenjing; Naylor, Carl H; Ee, Ho-Seok; Park, Joohee; Johnson, A T Charlie; Agarwal, Ritesh

      2015-01-01

      We demonstrate strong exciton-plasmon coupling in silver nanodisk arrays integrated with monolayer MoS2 via angle-resolved reflectance microscopy spectra of the coupled system. Strong exciton-plasmon coupling is observed with the exciton-plasmon coupling strength up to 58 meV at 77 K, which also survives at room temperature. The strong coupling involves three types of resonances: MoS2 excitons, localized surface plasmon resonances (LSPRs) of individual silver nanodisks and plasmonic lattice resonances of the nanodisk array. We show that the exciton-plasmon coupling strength, polariton composition and dispersion can be effectively engineered by tuning the geometry of the plasmonic lattice, which makes the system promising for realizing novel two-dimensional plasmonic polaritonic devices.

    2. Air damping of atomically thin MoS{sub 2} nanomechanical resonators

      SciTech Connect (OSTI)

      Lee, Jaesung; Wang, Zenghui; Feng, Philip X.-L., E-mail: philip.feng@case.edu [Department of Electrical Engineering and Computer Science, Case School of Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States); He, Keliang; Shan, Jie [Department of Physics, College of Arts and Sciences, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States)

      2014-07-14

      We report on experimental measurement of air damping effects in high frequency nanomembrane resonators made of atomically thin molybdenum disulfide (MoS{sub 2}) drumhead structures. Circular MoS{sub 2} nanomembranes with thickness of monolayer, few-layer, and multi-layer up to ?70?nm (?100 layers) exhibit intriguing pressure dependence of resonance characteristics. In completely covered drumheads, where there is no immediate equilibrium between the drum cavity and environment, resonance frequencies and quality (Q) factors strongly depend on environmental pressure due to bulging of the nanomembranes. In incompletely covered drumheads, strong frequency shifts due to compressing-cavity stiffening occur above ?200?Torr. The pressure-dependent Q factors are limited by free molecule flow (FMF) damping, and all the mono-, bi-, and tri-layer devices exhibit lower FMF damping than thicker, conventional devices do.

    3. LANL Experience Rolling Zr-Clad LEU-10Mo Foils for AFIP-7

      SciTech Connect (OSTI)

      Hammon, Duncan L.; Clarke, Kester D.; Alexander, David J.; Kennedy, Patrick K.; Edwards, Randall L.; Duffield, Andrew N.; Dombrowski, David E.

      2015-05-29

      The cleaning, canning, rolling and final trimming of Low Enriched Uranium-10 wt. pct. Molybdenum (LEU-10Mo) foils for ATR (Advanced Test Reactor) fuel plates to be used in the AFIP-7 (ATR Full Size Plate In Center Flux Trap Position) experiments are summarized. Six Zr-clad foils were produced from two LEU-10Mo castings supplied to Los Alamos National Laboratory (LANL) by Y-12 National Security Complex. Details of cleaning and canning procedures are provided. Hot- and cold-rolling results are presented, including rolling schedules, images of foils in-process, metallography and local compositions of regions of interest, and details of final foil dimensions and process yield. This report was compiled from the slides for the presentation of the same name given by Duncan Hammon on May 12, 2011 at the AFIP-7 Lessons Learned meeting in Salt Lake City, UT, with Los Alamos National Laboratory document number LA-UR 11-02898.

    4. Development of Cr-Mo-V-Cb-Ca steel for high pressure and high temperature hydrogenation reactors

      SciTech Connect (OSTI)

      Yamada, Masato; Sakai, Tadamiti; Nose, Shiro [Kobe Steel, Ltd., Takasago, Hyogo (Japan). Energy and Chemical Plant Group

      1995-12-31

      Cr-Mo-V-Cb-Ca steels have been developed as materials for high temperature and high pressure hydrogenation reactors. Cr-Mo-V-Cb-Ca steels have high strength at elevated temperature. The addition of vanadium and columbium also improve the resistance against hydrogen attack and hydrogen embrittlement. Calcium addition, which is a unique feature of this material, effectively reduces the possibility of stress relief cracking in the heat affected zone of the weldment of which susceptibility is otherwise impaired by the addition of vanadium. In 1993, 3Cr-1Mo-V-Cb-Ca steel was approved by ASME as ASME Code Case 2151 and the first hydrocracking reactors made of 3Cr-1Mo-V-Cb-Ca steel were manufactured in 1994 at Kobe Steel, Takasago Works.

    5. Performance of ZnMoO4 crystal as cryogenic scintillating bolometer to search for double beta decay of molybdenum

      E-Print Network [OSTI]

      L. Gironi; C. Arnaboldi; J. W. Beeman; O. Cremonesi; F. A. Danevich; V. Ya. Degoda; L. I. Ivleva; L. L. Nagornaya; M. Pavan; G. Pessina; S. Pirro; V. I. Tretyak; I. A. Tupitsyna

      2010-10-01

      Zinc molybdate (ZnMoO4) single crystals were grown for the first time by the Czochralski method and their luminescence was measured under X ray excitation in the temperature range 85-400 K. Properties of ZnMoO4 crystal as cryogenic low temperature scintillator were checked for the first time. Radioactive contamination of the ZnMoO4 crystal was estimated as <0.3 mBq/kg (228-Th) and 8 mBq/kg (226-Ra). Thanks to the simultaneous measurement of the scintillation light and the phonon signal, the alpha particles can be discriminated from the gamma/beta interactions, making this compound extremely promising for the search of neutrinoless Double Beta Decay of 100-Mo. We also report on the ability to discriminate the alpha-induced background without the light measurement, thanks to a different shape of the thermal signal that characterizes gamma/beta and alpha particle interactions.

    6. Controlling the spontaneous emission rate of monolayer MoS[subscript 2] in a photonic crystal nanocavity

      E-Print Network [OSTI]

      Gan, Xuetao

      We report on controlling the spontaneous emission (SE) rate of a molybdenum disulfide (MoS[subscript 2]) monolayer coupled with a planar photonic crystal (PPC) nanocavity. Spatially resolved photoluminescence (PL) mapping ...

    7. High yield production of inorganic graphene-like materials (MoS?, WS?, BN) through liquid exfoliation testing key parameters

      E-Print Network [OSTI]

      Pu, Fei, S.B. Massachusetts Institute of Technology

      2012-01-01

      Inorganic graphene-like materials such as molybdenum disulfide (MoS?), tungsten sulfide (WS?), and boron nitride (BN) are known to have electronic properties. When exfoliated into layers and casted onto carbon nanofilms, ...

    8. Electron scattering mechanisms in Cu-Mn films for interconnect applications

      SciTech Connect (OSTI)

      Misják, F.; Nagy, K. H.; Radnóczi, G.; Lobotka, P.

      2014-08-28

      Electrical properties and corresponding structural features of Cu-Mn alloy films with potential application as barrier and interconnect layers were studied. Cu-Mn films were deposited by DC magnetron sputtering at room temperature on SiO{sub 2} substrates. Electrical resistivity measurements were made as a function of film composition and temperature. The specific resistivity varies linearly with the Mn content showing a maximum of 205???cm at 80 at. % Mn. The temperature coefficient of resistance (TCR) of all alloy films is low, showing non-metallic conductivity for most compositions. Also a minimum TCR has been observed in the 40–80 at. % Mn range which was attributed to a magnetic transformation around 200–300?K. Electrical resistivity measurements are correlated with the film structure revealed by transmission electron microscopy to clarify the phase regions throughout the composition range. In the 20–40 at. % and 70–80 at. % Mn ranges, two-phase structures were identified, where Cu- or Mn-rich solid solution grains were surrounded by a thin amorphous covering layer. Based on the revealed phase regions and morphologies electron scattering mechanisms in the system were evaluated by combining the Matthiessen's rule and the Mayadas-Schatzkes theory. Grain boundary reflectivity coefficients (r?=?0.6–0.8) were calculated from fitting the model to the measurements. The proposed model indicates that, in a binary system, the special arrangement of the two phases results in new scattering mechanisms. The results are of value in optimizing the various parameters needed to produce a suitable barrier layer.

    9. An internship with San Tomas hunting camp Freeport-McMoRan, Inc. 

      E-Print Network [OSTI]

      Huggins, J. Grant

      1986-01-01

      An Internship with San Tomas Hunting Camp Freeport~NoRan, Inc. : A PRCFESSIQRAL PAPER by J. Grant Huggine Submitted to the College of Agriculture of Texas AN University in Rmrtial fulfillment of the requirements for the degree of NASTER GF... AGRICULTURE December 1986 Najor Subject: Wildlife Science Department of Wildife and Fisheries Sciences An Internship with San Tomas Hunting Camp Fr eeport-McMoRan, Inc. by J. Grant Huggins Approved as to style and content by: Wallace G. Klussmann...

    10. AutoMoDe - Model-Based Development of Automotive Software

      E-Print Network [OSTI]

      Ziegenbein, Dirk; Freund, Ulrich; Bauer, Andreas; Romberg, Jan; Schatz, Bernhard

      2011-01-01

      This paper describes first results from the AutoMoDe (Automotive Model-Based Development) project. The overall goal of the project is to develop an integrated methodology for model-based development of automotive control software, based on problem-specific design notations with an explicit formal foundation. Based on the existing AutoFOCUS framework, a tool prototype is being developed in order to illustrate and validate the key elements of our approach.

    11. Properties of Ga{sub 1-x}Mn{sub x}As with high x (>0.1)

      SciTech Connect (OSTI)

      Chiba, D.; Yu, K. M.; Walukiewicz, W.; Nishitani, Y.; Matsukura, F.; Ohno, H.

      2008-04-01

      We have investigated the magnetic and the crystalline properties of a set of Ga{sub 1-x}Mn{sub x}As layers with high nominal Mn compositions (x=0.101-0.198). Magnetization measurements and combined channeling Rutherford backscattering (c-RBS) and particle induced x-ray emission (c-PIXE) measurements have been performed to determine the effective Mn composition x{sub eff} and the fraction of Mn atoms at various lattice sites. Here, x{sub eff} determined from magnetization measurements, which increases with increasing x, is consistent with the results determined from c-RBS-PIXE measurements.

    12. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

      E-Print Network [OSTI]

      Zeng, Li

      2007-01-01

      a test bed for simple spintronic devices. (In, Mn)As and (in novel electronic and spintronic materials have drawnpotential applications as spintronic materials. While many

    13. Electronic structure study of the magnetoresistance material CaCu3Mn4O12 by LSDA and LSDAU

      E-Print Network [OSTI]

      Gong, Xingao

      -like orbitals (dxy ,dyz , and dxz are almost full-filled, while the spin-up eg-like orbitals (d3z2 r2 and dx2 y2 of Mn3 (t2g 3 eg 1 ) and Mn4 (t2g 3 eg 0 ). Three spin- polarized d electrons in the t2g orbital of Mn3 and Mn4 cations form an inert spin core S 3/2, and the last one eg electron is itinerant. The eg electron

    14. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

      SciTech Connect (OSTI)

      Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

      2008-01-20

      Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

    15. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

      SciTech Connect (OSTI)

      Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

      2012-12-15

      The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

    16. High-spin level structure in {sup 94,95}Mo

      SciTech Connect (OSTI)

      Zhang, Y. H.; Hasegawa, M.; Guo, W. T.; Liu, M. L.; Zhou, X. H. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou (China); De Angelis, G. [Istituto Nazionale di Fisisca Nucleare, Laboratori Nazionali di Legnaro, Legnaro (Italy); Hahn-Meitner-Institut, Berlin (Germany); Axiotis, T. M.; Gadea, A.; Marginean, N.; Martinez; Napoli, D. R.; Rusu, C. [Istituto Nazionale di Fisisca Nucleare, Laboratori Nazionali di Legnaro, Legnaro (Italy); Podolyak, Zs. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); Ur, C.; Bazzacco, D.; Brandolini, F.; Lunardi, S.; Lenzi, S. M.; Menegazzo, R. [Dipartimento di Fisica dell'Universita and Istituto Nazionale di Fisica Nucleare, Sezione di Padova, Padova (Italy); Schwengner, R. [Institut fuer Kern-und Hadronenphysik, Forschungszentrum Rossendorf, Dresden (Germany)] (and others)

      2009-04-15

      High-spin level structures of {sup 94,95}Mo have been reinvestigated via the {sup 16}O({sup 82}Se,xn{gamma}){sup 94,95}Mo(x=4,3) reactions at E({sup 82}Se)=460 MeV. The previously reported level schemes of these two nuclei have been largely modified up to {approx}11 MeV in excitation energy due to identifications of some important linking transitions. Shell-model calculations have been made in the model space of {pi}(p{sub 1/2},g{sub 9/2},d{sub 5/2}){sup 4} and {nu}(d{sub 5/2},s{sub 1/2},d{sub 3/2},g{sub 7/2},h{sub 11/2}){sup 2(3)} and compared with the modified level schemes. The structures of the newly assigned high-spin states in {sup 94,95}Mo have been discussed.

    17. Field fabrication of heavy wall hydrocracking reactors made from advanced Cr-Mo steel

      SciTech Connect (OSTI)

      Flores, E.D. [Pemex, Huasteca (Mexico); Kao, T.; Tasker, K. [HRI, Inc., Princeton, NJ (United States); Festa, F.; Pietrantonio, V. [Snamprogetti, S. Donato Milanese (Italy); Inoue, S.; Iga, H.; Tahara, T. [Japan Steel Works, Ltd., Muroran (Japan)

      1996-12-01

      The manufacture of first commercial hydrocracking reactors made from 3Cr-Mo-1/4V-Ti-B steel was completed in August 1990. Since then, almost 30 units of heavy wall hydrocracking reactors made of the same material have been fabricated. These vessels have been applied to high temperature and high pressure operation of hydrocracking and hydrodesulfurization units. The characteristics of advanced Cr-Mo steel, such as higher resistance to hydrogen atmosphere, higher creep rupture strength and lower susceptibility to long term degradation were verified through enough experiences based on the latest technology of manufacturing and operation of the vessels. Based on these experiences the first field fabrication of the vessels made from 3Cr-1Mo-1/4V-Ti-b steel was started in April, 1995 and successfully completed in October, 1995, at job site in Pemex Tula Refinery, Mexico. This paper is prepared to present the highlights of manufacturing technology for field fabrication based on the actual experience.

    18. Study on Shielding Requirements for Radioactive Waste Transportation in a Mo-99 Production Plant - 13382

      SciTech Connect (OSTI)

      Melo Rego, Maria Eugenia de; Kazumi Sakata, Solange; Vicente, Roberto; Hiromoto, Goro [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)] [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)

      2013-07-01

      Brazil is currently planning to produce {sup 99}Mo from fission of low enriched uranium (LEU) targets. The planned end of irradiation activity of {sup 99}Mo is about 185 TBq (5 kCi) per week to meet the present domestic demand of {sup 99m}Tc generators. The radioactive wastes from the production plant will be transferred to a waste treatment facility at the same site. The total activity of the actinides, fission and activation products present in the wastes can be predicted based on the yields of fission and activation data for the irradiation conditions, such as composition and mass of uranium targets, irradiation time, neutron flux, production schedule, etc., which were in principle already established by the project management. The transportation of the wastes from the production plant to the treatment facility will be done by means of special shielded packages. An assessment of the shielding required for the packages has been done and the results are presented here, aiming at contributing to the design of the waste management facility for the {sup 99}Mo production plant. (authors)

    19. ALS IR News October 25, 2006

      E-Print Network [OSTI]

      ). And the reflection spectrum of an Al mirror clearly shows the strong AlOx absorptions from the very thin oxide layer

    20. Al

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications Traditional KnowledgeAgenda Agenda NERSC UserAgustin Mihi andAiron the way to

    1. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

      SciTech Connect (OSTI)

      West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory; He, Jian; Hitchcock, Dale; Yan, Yonggao; Hwu, Shiou-Jyh

      2013-10-15

      Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

    2. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

      SciTech Connect (OSTI)

      Renteria, J.; Jiang, C.; Samnakay, R.; Rumyantsev, S. L.; Goli, P.; Balandin, A. A.; Shur, M. S.

      2014-04-14

      We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2?×?10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5?×?10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

    3. Growth-substrate induced performance degradation in chemically synthesized monolayer MoS{sub 2} field effect transistors

      SciTech Connect (OSTI)

      Amani, Matin; Chin, Matthew L.; Mazzoni, Alexander L.; Burke, Robert A.; Dubey, Madan, E-mail: madan.dubey.civ@mail.mil [Sensors and Electron Devices Directorate, US Army Research Laboratory, Adelphi, Maryland 20723 (United States); Najmaei, Sina; Ajayan, Pulickel M.; Lou, Jun [Department of Materials Science and Nanoengineering, Rice University, Houston, Texas 77005 (United States)

      2014-05-19

      We report on the electronic transport properties of single-layer thick chemical vapor deposition (CVD) grown molybdenum disulfide (MoS{sub 2}) field-effect transistors (FETs) on Si/SiO{sub 2} substrates. MoS{sub 2} has been extensively investigated for the past two years as a potential semiconductor analogue to graphene. To date, MoS{sub 2} samples prepared via mechanical exfoliation have demonstrated field-effect mobility values which are significantly higher than that of CVD-grown MoS{sub 2}. In this study, we will show that the intrinsic electronic performance of CVD-grown MoS{sub 2} is equal or superior to that of exfoliated material and has been possibly masked by a combination of interfacial contamination on the growth substrate and residual tensile strain resulting from the high-temperature growth process. We are able to quantify this strain in the as-grown material using pre- and post-transfer metrology and microscopy of the same crystals. Moreover, temperature-dependent electrical measurements made on as-grown and transferred MoS{sub 2} devices following an identical fabrication process demonstrate the improvement in field-effect mobility.

    4. Exchange bias induced by the fully strained La{sub 2/3}Ca{sub 1/3}MnO{sub 3} dead layers

      SciTech Connect (OSTI)

      Xie, Q. Y. [National Lab of Solid State Microstructures, Department of Physics, Nanjing University, Nanijng 210093 (China); College of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210046 (China); Wu, X. S., E-mail: xswu@nju.edu.cn [National Lab of Solid State Microstructures, Department of Physics, Nanjing University, Nanijng 210093 (China); Gao, J. [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); Jia, Q. J. [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China)

      2014-05-07

      A pure compressively strained La{sub 2/3}Ca{sub 1/3}MnO{sub 3} (LCMO) dead layer grown on (001)-oriented LaAlO{sub 3} substrate can show all the rich phenomenon of large bias field shift, coercive field enhancement, and high blocking temperature. The obtained exchange bias field (?350?Oe) and the enhanced coercivity of about 1160?Oe at 5?K under 500?Oe cooling field are superior to that have been reported in LCMO-based ferromagnetic/antiferromagnetic superlattices or nanoscale systems. Our results clearly demonstrate that the inhomogeneous magnetic dead layer of LCMO can induce a strong exchange bias effect, which may be exploited as a very simple structure for spin-valve device application.

    5. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

      SciTech Connect (OSTI)

      Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

      2008-05-15

      Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

    6. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

      SciTech Connect (OSTI)

      Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

      2008-10-12

      Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

    7. Disorder dependent half-metallicity in Mn{sub 2}CoSi inverse Heusler alloy

      SciTech Connect (OSTI)

      Singh, Mukhtiyar; Saini, Hardev S.; Thakur, Jyoti; Reshak, Ali H.; Kashyap, Manish K.

      2013-12-15

      Heusler alloys based thin-films often exhibit a degree of atomic disorder which leads to the lowering of spin polarization in spintronic devices. We present ab-initio calculations of atomic disorder effects on spin polarization and half-metallicity of Mn{sub 2}CoSi inverse Heusler alloy. The five types of disorder in Mn{sub 2}CoSi have been proposed and investigated in detail. The A2{sub a}-type and B2-type disorders destroy the half-metallicity whereas it sustains for all disorders concentrations in DO{sub 3a}- and A2{sub b}-type disorder and for smallest disorder concentration studied in DO{sub 3b}-type disorder. Lower formation energy/atom for A2{sub b}-type disorder than other four disorders in Mn{sub 2}CoSi advocates the stability of this disorder. The total magnetic moment shows a strong dependence on the disorder and the change in chemical environment. The 100% spin polarization even in the presence of disorders explicitly supports that these disorders shall not hinder the use of Mn{sub 2}CoSi inverse Heusler alloy in device applications. - Graphical abstract: Minority-spin gap (E{sub g?}) and HM gap (E{sub sf}) as a function of concentrations of various possible disorder in Mn{sub 2}CoSi inverse Heusler alloy. The squares with solid line (black color)/dotted line (blue color)/dashed line (red color) reperesents E{sub g?} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi and the spheres with solid line (black color)/dottedline (blue color)/dashed line (red color) represents E{sub sf} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi. - Highlights: • The DO{sub 3}- and A2-type disorders do not affect the half-metallicity in Mn{sub 2}CoSi. • The B2-type disorder solely destroys half-metallicity in Mn{sub 2}CoSi. • The A2-type disorder most probable to occur out of all three types. • The total spin magnetic moment strongly depends on the disorder concentrations.

    8. Characterization of few-layer 1T-MoSe{sub 2} and its superior performance in the visible-light induced hydrogen evolution reaction

      SciTech Connect (OSTI)

      Gupta, Uttam; Naidu, B. S.; Maitra, Urmimala; Rao, C. N. R.; Singh, Anjali; Shirodkar, Sharmila N.; Waghmare, Umesh V.

      2014-09-01

      Based on earlier results on the photocatalytic properties of MoS{sub 2}, the 1T form of MoSe{sub 2}, prepared by lithium intercalation and exfoliation of bulk MoSe{sub 2}, has been employed for the visible-light induced generation of hydrogen. 1T-MoSe{sub 2} is found to be superior to both 2H and 1T MoS{sub 2} as well as 2H-MoSe{sub 2} in producing hydrogen from water, the yield being in the 60–75 mmol?h{sup ?1}?g{sup ?1} range with a turn over frequency of 15–19 h{sup ?1}. First principles calculations reveal that 1T-MoSe{sub 2} has a lower work function than 2H-MoSe{sub 2} as well as 1T and 2H-MoS{sub 2}, making it easier to transfer an electron from 1T-MoSe{sub 2} for the production of H{sub 2}.

    9. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

      SciTech Connect (OSTI)

      Chen Miao; Wu Jialing; Liu Yongmei; Cao Yong; Guo Li; He Heyong; Fan Kangnian

      2011-12-15

      A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

    10. High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy

      SciTech Connect (OSTI)

      Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

      2007-08-01

      The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

    11. Transformer Abdullah Al-Otaibi

      E-Print Network [OSTI]

      Masoudi, Husain M.

      Transformer Abdullah Al-Otaibi ID#242374 Section#2 Abstract- this is a brief description for transformer and how it works. I. DEFINITION A transformer is a device that transfers electrical energy from of the transformer in 1831. The transformer is used by Faraday only to demonstrate the principle of electromagnetic

    12. Ordered binary oxide films of V{sub 2}O{sub 3}(0001) on Al{sub 2}O{sub 3}

      SciTech Connect (OSTI)

      Guo, Q.; Kim, D.Y.; Street, S.C.; Goodman, D.W.

      1999-07-01

      Ordered binary oxide films of vanadium oxide have been prepared on an aluminum oxide film supported on Mo(110) under ultrahigh vacuum conditions and characterized by various surface analytical techniques. Auger electron spectroscopy, low energy electron diffraction, high-resolution electron loss spectroscopy, x-ray photoelectron spectroscopy and ion scattering spectroscopy indicate that the vanadia films grow epitaxially on the Al{sub 2}O{sub 3}/Mo(110) surface as V{sub 2}O{sub 3}(0001). The results of electronic structural measurements show an increase in the energy of the a{sub 1g} level in the 3{ital d} band at low temperatures, which is a possible explanation for the metal-to-insulator transition in V{sub 2}O{sub 3}. {copyright} {ital 1999 American Vacuum Society.}

    13. Electronic structural and magnetic properties of Mn{sub 5}Ge{sub 3} clusters

      SciTech Connect (OSTI)

      Yuan, H. K.; Chen, H. Kuang, A. L.; Tian, C. L.; Wang, J. Z.

      2013-11-28

      Theoretical understanding of the stability, ferromagnetism, and spin polarization of Mn{sub 5}Ge{sub 3} clusters has been performed by using the density functional theory with generalized gradient approximation for exchange and correlation. The magnetic moments and magnetic anisotropy energy (MAE) have been calculated for both bulk and clusters, and the enhanced magnetic moment as well as the enlarged MAE have been identified in clusters. The most attractive achievement is that Mn{sub 5}Ge{sub 3} clusters show a fine half-metallic character with large energy scales. The present results may have important implications for potential applications of small Mn{sub 5}Ge{sub 3} clusters as both emerging spintronics and next-generation data-storage technologies.

    14. Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers

      SciTech Connect (OSTI)

      Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

      2014-08-18

      Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

    15. Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides

      SciTech Connect (OSTI)

      Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

      2014-10-23

      Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

    16. Thickness Effect of Al-Doped ZnO Window Layer on Damp Heat Stability of CuInGaSe2 Solar Cells: Preprint

      SciTech Connect (OSTI)

      Pern, F. J.; Mansfield, L.; DeHart, C.; Glick, S. H.; Yan, F.; Noufi, R.

      2011-07-01

      We investigated the damp heat (DH) stability of CuInGaSe2 (CIGS) solar cells as a function of thickness of the Al-doped ZnO (AZO) window layer from the 'standard' 0.12 ?m to a modest 0.50 ?m over an underlying 0.10-?m intrinsic ZnO buffer layer. The CIGS cells were prepared with external electrical contact using fine Au wire to the tiny 'standard' Ni/Al (0.05 ?m/3 ?m) metal grid contact pads. Bare cell coupons and sample sets encapsulated in a specially designed, Al-frame test structure with an opening for moisture ingress control using a TPT backsheet were exposed to DH at 85oC and 85% relative humidity, and characterized by current-voltage (I-V), quantum efficiency (QE), and (electrochemical) impedance spectroscopy (ECIS). The results show that bare cells exhibited rapid degradation within 50-100 h, accompanied by film wrinkling and delamination and corrosion of Mo and AlNi grid, regardless of AZO thickness. In contrast, the encapsulated cells did not show film wrinkling, delamination, and Mo corrosion after 168 h DH exposure; but the trend of efficiency degradation rate showed a weak correlation to the AZO thickness.

    17. Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

      E-Print Network [OSTI]

      2002-01-01

      x MnO 3 -Yttria Stabilized Zirconia Electrodes for Thin-FilmMnO 3 -yttria stabilized zirconia) were deposited onto dense1.5 h in acetone, using zirconia milling media. The LSM- YSZ

    18. MnPASS System Study Phase 2 Prepared for the Minnesota Department of Transportation by Cambridge Systematics, Inc. with SRF

      E-Print Network [OSTI]

      Minnesota, University of

      will be put in place during construction The Next Opportunity See Cayuga Project materials at: http://www.dot.state.mn.us/metro/projects/cayuga/indexPASS onto the Twin City Highway System · Identified a potential MnPASS system ­ Studied cost, operational provide increased trip reliability and user choice in a cost-effective manner (I-394) ­ New lower cost

    19. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

      E-Print Network [OSTI]

      Cui, Yi

      Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

    20. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

      E-Print Network [OSTI]

      Cui, Yi

      Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery-cost, and environ- mentally friendly anode for lithium ion batteries. Our growth-on- graphene approach should offer

    1. Iron-based soft magnetic composites with MnZn ferrite nanoparticles coating obtained by solgel method

      E-Print Network [OSTI]

      Volinsky, Alex A.

      Iron-based soft magnetic composites with Mn­Zn ferrite nanoparticles coating obtained by sol nanoparticles to coat iron powder. The nanocrystalline iron powders, with an average particle diameter of 20 nm­Zn ferrites. Mn­Zn ferrite uniformly coated the surface of the powder particles, resulting in a reduced

    2. Synthesis of MnO{sub 2}-graphene composites with enhanced supercapacitive performance via pulse electrodeposition under supergravity field

      SciTech Connect (OSTI)

      Liu, Tingting; Shao, Guangjie; Ji, Mingtong; Wang, Guiling

      2014-07-01

      A method of pulse electrodeposition under supergravity field was proposed to synthesize MnO{sub 2}-graphene composites. Supergravity is very efficient for promoting mass transfer and decreasing concentration polarization during the electrodeposition process. The synthesis was conducted on our homemade supergravity equipment. The strength of supergravity field depended on the rotating speed of the ring electrode. 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired when the rotating speed was 3000 rpm. Graphene nanosheets play as a role of conductive substrates for MnO{sub 2} growing. The composites are evaluated as electrode materials for supercapacitors. Electrochemical results show that the maximum specific capacitance of the MnO{sub 2}-graphene composite is 595.7 F g{sup ?1} at a current density of 0.5 A g{sup ?1}. In addition, the composite exhibits excellent cycle stability with no capacitance attenuation after 1000 cycles. The approach provides new ideas for developing supercapacitor electrode materials with high performance. - Graphical abstract: 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired at 3000 rpm. - Highlights: • MnO{sub 2}-graphene composites were prepared by pulse electrodeposition under supergravity. • 3D flower like MnO{sub 2} spheres are anchored on the graphene nanosheets. • The MnO{sub 2}-graphene electrode exhibits a specific capacitance of 595.7 F g{sup ?1}.

    3. MnO spin-wave dispersion curves from neutron powder diffraction

      SciTech Connect (OSTI)

      Goodwin, Andrew L.; Dove, Martin T.; Tucker, Matthew G.; Keen, David A.

      2007-02-15

      We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

    4. Graphene in proximity to magnetic insulating LaMnO{sub 3}

      SciTech Connect (OSTI)

      Cheng, Guanghui; Wei, Laiming, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn; Cheng, Long; Liang, Haixing; Zhang, Xiaoqiang; Li, Hui [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yu, Guolin [Shanghai Institute of Technical Physics, Chinese Academy of Science, Shanghai 200083 (China); Zeng, Changgan, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); International Center for Quantum Design of Functional Materials (ICQD), HFNL, University of Science and Technology of China, Hefei, Anhui 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

      2014-09-29

      Proximity to functional substrates may enhance the coupling between the quantum degrees of freedom and thus develop nontrivial quantum effects in graphene. Here, we demonstrate the successful fabrication of graphene in proximity to atomically flat magnetic insulating LaMnO{sub 3} films. The insulating nature of the LaMnO{sub 3} films not only ensures the electronic transport only occur in the graphene layers but also allow them to serve as dielectric layers for gating. Transport measurements reveal anomalous behaviors, including asymmetrical longitudinal magnetoresistivity and nonlinear Hall effect. This work may pave a way toward the realization of intriguing quantum phases in graphene.

    5. Relaxation of photoinduced spins and carriers in ferromagnetic InMnSb films

      SciTech Connect (OSTI)

      Nontapot, K.; Kini, R. N.; Gifford, A.; Merritt, T. R.; Khodaparast, G. A.; Wojtowicz, T.; Liu, X.; Furdyna, J. K. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

      2007-04-02

      The authors report time resolved measurements and control of photoinduced spin and carrier relaxations in InMnSb ferromagnetic films with 2% Mn content (grown by low-temperature molecular beam epitaxy) using femtosecond laser pulses, and compare them to analogous measurements on InBeSb and InSb films. In this work, magneto-optical Kerr effect and standard pump-probe techniques provided a direct measure of the photoexcited spin and carrier lifetimes, respectively. They observe decrease in relaxations times in the high laser fluence regime and an absence of temperature dependence of the relaxation times.

    6. Ferromagnetism in Mn Substituted Zirconia: A Density-functional Theory Study

      E-Print Network [OSTI]

      Xingtao Jia; Wei Yang; Minghui Qin; Xinglai Zhang; Mingai Sun; Jianping Li

      2008-09-05

      We study the electronic structure and magnetism of 25% Mn substituted cubic Zirconia (ZrO2) with several homogeneous and heterogeneous doping profiles using density-functional theory calculations. We find that all doping profiles show half-metallic ferromagnetism (HMF), and delta-doping is most energy favorable while homogeneous doping has largest ferromagnetic stabilization energy. Using crystal field theory, we discuss the formation scheme of HMF. Finally, we speculate the potential spintronics applications for Mn doped ZrO2, especially as spin direction controllment.

    7. Enlarged Mn 3s splitting and room-temperature ferromagnetism in epitaxially grown oxygen doped Mn{sub 2}N{sub 0.86} films

      SciTech Connect (OSTI)

      Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

      2014-11-07

      Single-phase and oxygen doped Mn{sub 2}N{sub 0.86} thin films have been grown on MgO (111) by plasma-assisted molecular beam epitaxy. The films grow under tensile strain and, remarkably, they show ferromagnetic-like interactions at low temperature and ferromagnetic ordering agreed well with the Bloch-law T{sup 3/2} at room-temperature. We further demonstrate the enlarged Mn 3s splitting (6.46?eV) and its possible relation to the observed ferromagnetism. Our study not only provide a strategy for further theoretical work on oxygen doped manganese nitrides, but also shed promising light on utilizing its room-temperature FM property to fabricate spintronic devices.

    8. Microstructures and Mechanical Properties of Compositionally Complex Co-free FeNiMnCr18 FCC Solid Solution Alloy

      SciTech Connect (OSTI)

      Wu, Zhenggang [The University of Tennessee; Bei, Hongbin [ORNL

      2015-01-01

      Recently,a structurally-simplebutcompositionally-complex FeNiCoMnCr highentropyalloywasfoundto haveexcellentmechanicalproperties(e.g.,highstrengthandductility).Tounderstandthepotentialof using highentropyalloysasstructuralmaterialsforadvancednuclearreactorandpowerplants,itis necessary tohaveathoroughunderstandingoftheirstructuralstabilityandmechanicalpropertiesde- gradation underneutronirradiation.ThisrequiresustodevelopasimilarmodelalloywithoutCobe- cause materialwithCowillmakepost-neutron-irradiationtestingdifficult duetotheproductionofthe 60Co radioisotope.Toachievethisgoal,aFCC-structuredsingle-phasealloywithacompositionof FeNiMnCr18 wassuccessfullydeveloped.Thisnear-equiatomicFeNiMnCr18 alloy hasgoodmalleability and itsmicrostructurecanbecontrolledbythermomechanicalprocessing.Byrollingandannealing,the as-cast elongated-grained-microstructureisreplacedbyhomogeneousequiaxedgrains.Themechanical properties (e.g.,strengthandductility)oftheFeNiMnCr18 alloy arecomparabletothoseoftheequiatomic FeNiCoMnCr highentropyalloy.Bothstrengthandductilityincreasewithdecreasingdeformation temperature,withthelargestdifferenceoccurringbetween293and77K.Extensivetwin-bandswhich are bundlesofnumerousindividualtwinsareobservedwhenitistensile-fracturedat77K.Notwin bands aredetectedbyEBSDformaterialsdeformedat293Kandhigher.Theunusualtemperature-de- pendencies ofUTSanduniformelongationcouldbecausedbythedevelopmentofthedensetwin substructure, twin-dislocationinteractionsandtheinteractionsbetweenprimaryandsecondarytwin- ning systemswhichresultinamicrostructurerefinement andhencecauseenhancedstrainhardening and postponednecking.

    9. Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes

      SciTech Connect (OSTI)

      Chen Yong; Liu Chenguang; Liu Chang; Lu Gaoqing; Cheng Huiming

      2007-11-06

      Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

    10. Extraordinary selectivity of CoMo{sub 3}S{sub 13} chalcogel for C{sub 2}H{sub 6} and CO{sub 2} adsorption.

      SciTech Connect (OSTI)

      Shafaei-Fallah, M.; Rothenberger, Z.; Katsoulidis, A. P.; He, J.; Malliakas, C. D.; Kanatzidis, M. G.

      2011-11-09

      The chalcogel CoMo{sub 3}S{sub 13} is obtained from the reaction of (NH{sub 4}){sub 2}[Mo{sub 3}S{sub 13}] with cobalt acetate in solution. The chalcogel has a BET surface area of 570 m{sup 2} g{sup -1}, and pair distribution function analysis (PDF) and infrared spectroscopy indicate that the [Mo{sub 3}S{sub 13}]{sup 2-} cluster is a building block in the porous network. The CoMo{sub 3}S{sub 13} chalcogel exhibits high selectivity for separating ethane and carbon dioxide from hydrogen and methane.

    11. In Situ Time-Resolved Characterization of Novel Cu-MoO2 Catalysts During the Water-Gas Shift Reaction

      SciTech Connect (OSTI)

      Wen ,W.; Liu, J.; White, M.; Marinkovic, N.; Hanson, J.; Rodriguez, J.

      2007-01-01

      A novel and active Cu-MoO{sub 2} catalyst was synthesized by partial reduction of a precursor CuMoO{sub 4} mixed-metal oxide with CO or H{sub 2} at 200-250 C. The phase transformations of Cu-MoO{sub 2} during H{sub 2} reduction and the water-gas shift reaction could be followed by In situ time resolved XRD techniques. During the reduction process the diffraction pattern of the CuMoO{sub 4} collapsed and the copper metal lines were observed on an amorphous material background that was assigned to molybdenum oxides. During the first pass of water-gas shift (WGS) reaction, diffraction lines for Cu{sub 6}Mo{sub 5}O{sub 18} and MoO{sub 2} appeared around 350 C and Cu{sub 6}Mo{sub 5}O{sub 18} was further transformed to Cu/MoO{sub 2} at higher temperature. During subsequent passes, significant WGS catalytic activity was observed with relatively stable plateaus in product formation around 350, 400 and 500 C. The interfacial interactions between Cu clusters and MoO{sub 2} increased the water-gas shift catalytic activities at 350 and 400 C.

    12. Comparison of the crystalline structure, morphology, and magnetic properties of -phase Mn/Cu3Au,,100... ultrathin films by varying the growth temperature

      E-Print Network [OSTI]

      Lin, Minn-Tsong

      Comparison of the crystalline structure, morphology, and magnetic properties of -phase Mn/Cu3Au behaviors in the crystalline structure, morphology, and magnetism. RT-Mn films reveal apparent layer the last de- cade, the pure - and -phase Mn films are prepared by epitaxial growth on single-crystalline

    13. Heteronuclear Mn-Ca/Sr Complexes, and Ca/Sr EXAFS SpectralComparisons with the Oxygen-Evolving Complex of Photosystem II

      SciTech Connect (OSTI)

      Mishra, A.; Yano, J.; Pushkar, Y.; Yachandra, V.K.; Abboud, K.A.; Christou, G.

      2007-12-19

      HeterometallicMn Ca and Mn Sr complexes have been preparedand employed as model complexes for Ca and Sr EXAFS spectral comparisonswith the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); thesehave revealed similarities that support the presence of at least one Oatom bridge between the Mn and Ca/Sr in the OEC.

    14. HDS and deep HDS activity of Co/Mo/S-mesostructured synthetic clays.

      SciTech Connect (OSTI)

      Carrado, K. A.; Song, C.; Kim, J. H.; Castagnola, N.; Fernandez-Saavedra, R.; Marshall, C. L.; Schwartz, M. M.; Penn State Univ.; ICMM-CSIC

      2006-01-01

      The goal of this work is to identify more promising supports from synthetic clay materials to advance hydrotreating catalyst development. Silica sol can be used as the silicon-containing starting material when creating nanoporous layered silicate catalysts with a certain portion of unreacted sol particles incorporated into the final matrix. The resulting structure then has mesoporosity and a unique morphology. Hectorite-based clays have been prepared using different silica sols in order to ascertain the importance of sol characteristics on the final matrix. Several techniques have been applied to characterize the materials, including XRD, TGA, N2 porosimetry, and TEM. For hydrodesulfurization (HDS), the conversion of dibenzothiophene (DBT) to biphenyl was examined at 400 degrees C using CoMoS-loaded mesostructured clay supports. No hydrogenation or hydrocracking was observed with any of the clay supports. The most active clay was derived from Ludox silica sol AS-30 with an activity of 65% DBT conversion and 100% selectivity to biphenyl (BP). For comparison, a reference commercial catalyst displayed 94% BP selectivity. For deep HDS, the conversion of 4,6-dimethyldibenzothiophene was tested at 325 and 350 degrees C. At 325 degrees C, conversions are 92% of commercial catalysts for a CoMoS-loaded mesostructured clay derived from Ludox AM-30 silica sol. A commercially available synthetic hectorite called laponite has very low activity, indicating that the unique morphology of the mesostructured clays is important. Hydrogenolysis vs. hydrogenation pathways are compared for the deep HDS reaction. HR-TEM of the most active deep HDS catalyst revealed a multilayered MoS2 morphology.

    15. Corrosion and degradation of a polyurethane/Co-Ni-Cr-Mo pacemaker lead

      SciTech Connect (OSTI)

      Sung, P.; Fraker, A.C.

      1987-12-01

      An investigation to study changes in the metal surfaces and the polyurethane insulation of heart pacemaker leads under controlled in vitro conditions was conducted. A polyurethane (Pellethane 2363-80A)/Co-Ni-Cr-Mo (MP35N) wire lead was exposed in Hanks' physiological saline solution for 14 months and then analyzed using scanning electron microscopy, x-ray energy dispersive analysis, and small angle x-ray scattering. Results showed that some leakage of solution into the lead had occurred and changes were present on both the metal and the polyurethane surfaces.

    16. Synthesis of AlN/Al Polycrystals along with Al Nanoparticles Using Thermal Plasma Route

      SciTech Connect (OSTI)

      Kanhe, Nilesh S.; Nawale, A. B.; Kulkarni, N. V.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

      2011-07-15

      This paper for the first time reports the (200) oriented growth of hexagonal Aluminum nitride crystals during synthesis of aluminum nanoparticles in dc transferred arc thermal plasma reactor by gas phase condensation in nitrogen plasma. The structural and morphological study of as synthesized AlN crystal and aluminium nanoparticles was done by using the x-ray diffraction method, scanning electron microscopy and transmission electron microscopy.

    17. MO: ZL

      Office of Legacy Management (LM)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700,Grand Junction Office This fact sheet GrandII

    18. Mo-99

      National Nuclear Security Administration (NNSA)

      AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4) August 2012 Guidance for High TemperatureO,

    19. Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application

      SciTech Connect (OSTI)

      Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

      2007-09-01

      Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

    20. LABORATORY EXPERIMENT 11 Determination of microelements (Mn and Cu) in tea leaves

      E-Print Network [OSTI]

      Nazarenko, Alexander

      : · Total contents - Mn and Cu in tea leaves by ashing and acid digestion · Extractable contents: hot water to determine the total contents of a component, such as a metal element, being measured. On the other hand used will depend on the purpose of the study. For example, it may be that the total content of a metal

    1. Correlated chemostratigraphy of Mn-carbonate microbialites (rkt, Hungary) Mrta Polgri a,b,

      E-Print Network [OSTI]

      Mojzsis, Stephen J.

      ) microbialites at the Úrkút black shale-hosted manganese carbonate ore body (central Hungary) is described microbialites mostly behaved as an open system during deposition of black shale under early diagenetic reduction under an oxic water column; more equant types occur at the contact zone of black shale and Mn

    2. In Vitro Study on MgeSneMn Alloy as Biodegradable Metals Zhen Zhen1)

      E-Print Network [OSTI]

      Zheng, Yufeng

      for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China 2) Biomedical Engineering condition) in Hank's solution. Blood compatibility evaluation suggested that Mge3Sne0.5Mn alloy had improve the corrosion resistance, for its high hydrogen overvoltage[22] . In physiology, Sn is a trace

    3. Optical properties of metallic (III, Mn)V ferromagnetic semiconductors in the infrared to visible range 

      E-Print Network [OSTI]

      Hankiewicz, EM; Jungwirth, T.; Dietl, T.; Timm, C.; Sinova, Jairo.

      2004-01-01

      We report on a study of the ac conductivity and magneto-optical properties of metallic ferromagnetic (III, Mn)V semiconductors in the infrared to visible spectrum at zero temperature. Our analysis is based on the successful kinetic exchange model...

    4. Effect of carbon doping on electronic transitions in Mn5Ge3 N. Stojilovic,1,a)

      E-Print Network [OSTI]

      Dordevic, Sasha V.

      these compounds promising candidates for spin injectors for potential spintronics applications. The resistivity mismatch between a metal and a semicon- ductor. Therefore, for spintronics applications, finding a compound is now being considered for use in spintronics applications.4 However, pure Mn5Ge3 has Tc ¼ 293 K,5 which

    5. MN 535 Green Manufacturing Fall'04: M-W noon-2PM

      E-Print Network [OSTI]

      Lin, Xi

      of the Manufacturing Process that aims to efficiently use energy, water and raw materials in order to minimize airMN 535 Green Manufacturing Fall'04: M-W noon-2PM Course Objective Provides a systems view and water pollution and generation of solid waste per unit of the manufactured product Class Discussion

    6. Modified magnetic ground state in NiMn2O4 thin films

      SciTech Connect (OSTI)

      Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Toney, M. F.; Arenholz, E.; Suzuki, Y.; Iwata, J.M.

      2010-08-03

      We demonstrate the stabilization of a magnetic ground state in epitaxial NiMn2O4 (NMO) thin films not observed in their bulk counterpart. Bulk NMO exhibits a magnetic transition from a paramagnetic phase to a collinear ferrimagnetic moment configuration below 110 K and to a canted moment configuration below 70 K. By contrast, as-grown NMO films exhibit a single magnetic transition at 60 K and annealed films exhibit the magnetic behavior found in bulk. Cation inversion and epitaxial strain are ruled out as possible causes for the new magnetic ground state in the as-grown films. However, a decrease in the octahedral Mn{sup 4+}:Mn{sup 3+} concentration is observed and likely disrupts the double exchange that produces the magnetic state at intermediate temperatures. X-ray magnetic circular dichroism and bulk magnetometry indicate a canted ferrimagnetic state in all samples at low temperature. Together these results suggest that the collinear ferrimagnetic state observed in bulk NMO at intermediate temperatures is suppressed in the as grown NMO thin films due to a decrease in octahedral Mn{sup 4+} while the canted moment ferrimagnetic ordering is preserved below 60 K.

    7. FARGO-MOORHEAD METROPOLITAN AREA, ND AND MN FLOOD RISK MANAGEMENT PROJECT

      E-Print Network [OSTI]

      US Army Corps of Engineers

      FARGO-MOORHEAD METROPOLITAN AREA, ND AND MN FLOOD RISK MANAGEMENT PROJECT 23 September 2011, and technically feasible flood risk management for Fargo, North Dakota, Moorhead, Minnesota, and the surrounding area, and a storage area to reduce the existing and future flood risk and damages to public and private

    8. Tracing bottom water oxygenation with sedimentary Mn/Fe ratios in Lake Zurich, Switzerland

      E-Print Network [OSTI]

      Gilli, Adrian

      Tracing bottom water oxygenation with sedimentary Mn/Fe ratios in Lake Zurich, Switzerland and Management, Seestrasse 79, CH-6047 Kastanienbaum, Switzerland b ETH Zurich, Institute for Biogeochemistry and Pollution Dynamics, Universitaetstrasse 16, CH-8092 Zurich, Switzerland c ETH Zurich, Geological Institute

    9. P0805-Hagen Oxidation States of Mn, Cr, and Co in

      E-Print Network [OSTI]

      on metal based interconnects in solid oxide fuel cell (SOFC) stack technology. The nature of the cations of the material, e.g., conductivity, which is of crucial importance in the fuel cell technology. In the present-Mn-Co-O are of great interest as layers of these materials are formed during operation at the metallic interconnects

    10. Spins and magnetic moments of 58;60;62;64Mn ground states and isomers

      E-Print Network [OSTI]

      H. Heylen; C. Babcock; J. Billowes; M. L. Bissell; K. Blaum; P. Campbell; B. Cheal; R. F. Garcia Ruiz; Ch. Geppert; W. Gins; M. Kowalska; K. Kreim; S. M. Lenzi; I. D. Moore; R. Neugart; G. Neyens; W. Nörtershäuser; J. Papuga; D. T. Yordanov

      2015-08-25

      The odd-odd 54;56;58;60;62;64Mn isotopes (Z = 25) were studied using bunched-beam collinear laser spectroscopy at ISOLDE, CERN. From the measured hyperfine spectra the spins and magnetic moments of Mn isotopes up to N = 39 were extracted. The previous tentative ground state spin assignments of 58;60;62;64Mn are now firmly determined to be I = 1 along with an I = 4 assignment for the isomeric states in 58;60;62Mn. The I = 1 magnetic moments show a decreasing trend with increasing neutron number while the I = 4 moments remain quite constant between N = 33 and N = 37. The results are compared to large-scale shell-model calculations using the GXPF1A and LNPS effective interactions. The excellent agreement of the ground state moments with the predictions from the LNPS calculations illustrates the need for an increasing amount of proton excitations across Z = 28 and neutron excitations across N = 40 in the ground state wave functions from N = 37 onwards.

    11. Spins and magnetic moments of 58;60;62;64Mn ground states and isomers

      E-Print Network [OSTI]

      Heylen, H; Billowes, J; Bissell, M L; Blaum, K; Campbell, P; Cheal, B; Ruiz, R F Garcia; Geppert, Ch; Gins, W; Kowalska, M; Kreim, K; Lenzi, S M; Moore, I D; Neugart, R; Neyens, G; Nörtershäuser, W; Papuga, J; Yordanov, D T

      2015-01-01

      The odd-odd 54;56;58;60;62;64Mn isotopes (Z = 25) were studied using bunched-beam collinear laser spectroscopy at ISOLDE, CERN. From the measured hyperfine spectra the spins and magnetic moments of Mn isotopes up to N = 39 were extracted. The previous tentative ground state spin assignments of 58;60;62;64Mn are now firmly determined to be I = 1 along with an I = 4 assignment for the isomeric states in 58;60;62Mn. The I = 1 magnetic moments show a decreasing trend with increasing neutron number while the I = 4 moments remain quite constant between N = 33 and N = 37. The results are compared to large-scale shell-model calculations using the GXPF1A and LNPS effective interactions. The excellent agreement of the ground state moments with the predictions from the LNPS calculations illustrates the need for an increasing amount of proton excitations across Z = 28 and neutron excitations across N = 40 in the ground state wave functions from N = 37 onwards.

    12. Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma,

      E-Print Network [OSTI]

      Demir, Hilmi Volkan

      Se-related blue emission (410 and 435 nm), Zn-related defect state green emission (520 nm), and Mn-dopant related for the purpose of generation of photometrically high quality white light while maintaining the energy efficiency is to combine red-, green-, and blue-emitting NCs in an appropriate ratio.1,2 However, when one simply mixes

    13. Materials Research for Environment and Energy Hydrogen Embrittlement in Fe-Mn-C

      E-Print Network [OSTI]

      Cambridge, University of

      Materials Research for Environment and Energy - 1 - Hydrogen Embrittlement in Fe-Mn-C High Strength Seminar, May 23 #12;Materials Research for Environment and Energy - 2 - I had moved from NIMS to Kyushu.kaneaki@nims.go.jp> ********************* #12;Materials Research for Environment and Energy - 3 - #12;Materials Research for Environment

    14. Shannon D. Scott, RN, BN, MN, PhD Faculty of Nursing, University of Alberta

      E-Print Network [OSTI]

      Machel, Hans

      Shannon D. Scott, RN, BN, MN, PhD Faculty of Nursing, University of Alberta Level 3, 11405 Promotion Studies (Mentor Dr. Ron Plotnikoff), University of Alberta. Funded by: Canadian Institutes of Health Research Fellowship, Alberta Heritage Foundation for Medical Research Fellowship, and the Canadian

    15. CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      McNally, D. E.; Simonson, J. W.; Kistner-Morris, J. J.; Smith, G. J.; Hassinger, J. E.; DeBeer-Schmidt, L.; Kolesnikov, A. I.; Zaliznyak, I.; Aronson, M. C.

      2015-05-22

      We present inelastic neutron scattering measurements of the antiferromagnetic insulator CaMn2Sb2:, which consists of corrugated honeycomb layers of Mn. The dispersion of magnetic excitations has been measured along the H and L directions in reciprocal space, with a maximum excitation energy of ? 24 meV. These excitations are well described by spin waves in a Heisenberg model, including first and second neighbor exchange interactions, J1 and J2, in the Mn plane and also an exchange interaction between planes. The determined ratio J2/J1 ? 1/6 suggests that CaMn2Sb2: is the first example of a compound that lies very close to themore »mean field tricritical point, known for the classical Heisenberg model on the honeycomb lattice, where the N´eel phase and two different spiral phases coexist. The magnitude of the determined exchange interactions reveal a mean field ordering temperature ? 4 times larger than the reported N´eel temperature TN = 85 K, suggesting significant frustration arising from proximity to the tricritical point.« less

    16. MN-583 Product Management Fall 2004 SYLLABUS Instructor: William Hauser wmhauser@bu.edu

      E-Print Network [OSTI]

      Lin, Xi

      MN-583 Product Management Fall 2004 SYLLABUS Instructor: William Hauser wmhauser@bu.edu Office: Room 219, 730 Commonwealth Avenue Classroom: 15 St. Mary's Street, Room 105 617-358-0663 http Nature of the Product Management Task Case: The Hewlett Packard Company, The Sally Project 3 Wed, 15-Sep

    17. Solar DEM Model Proposal : A solar image in color band b, mn pixels,

      E-Print Network [OSTI]

      Wolfe, Patrick J.

      Solar DEM Model Proposal : A solar image in color band b, m×n pixels, containing a particular solar 11 )( #12;Solar DEM Model Proposal : the volume (abundance?) of ion ii : the proportion of the total volume at temperature t t T t bitt I i ib MIE 11 )( #12;Solar Dataset · 15 Filters.txt files

    18. Mn-Substituted Inorganic-Organic Hybrid Materials Based on ZnSe

      E-Print Network [OSTI]

      Li, Jing

      Mn-Substituted Inorganic-Organic Hybrid Materials Based on ZnSe: Nanostructures That May Lead research that deals with synthesis, characterization, and modification of organic-inorganic hybrid to integrate functional materials that utilize both electron charge and spin.1 Thus, the introduction

    19. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

      SciTech Connect (OSTI)

      Kam, Kinson; Doeff, Marca M.

      2010-12-01

      Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

    20. mn header will be provided by the publisher Linear Passive Stationary Scattering Systems

      E-Print Network [OSTI]

      Rovnyak, James

      mn header will be provided by the publisher Linear Passive Stationary Scattering Systems 26, Odessa 65020, Ukraine 2 Department of Mathematics, University of Virginia, P. O. Box 400137@farlep.net Corresponding author: e-mail: rovnyak@Virginia.edu e-mail: sergey saprikin@ukr.net Copyright line