Sample records for al mo mn

  1. Charge and magnetic states of Mn-, Fe-, and Co-doped monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Lin, Xianqing [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China); Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China); Ni, Jun, E-mail: junni@mail.tsinghua.edu.cn [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100084 (China)

    2014-07-28T23:59:59.000Z

    First-principles calculations have been performed to investigate the electronic and magnetic properties of monolayer MoS{sub 2} substitutionally doped with Mn, Fe, and Co in possible charge states (q). We find that the Mn, Fe, and Co dopants substituting for a Mo atom in monolayer MoS{sub 2} (Mn@Mo, Fe@Mo, and Co@Mo) are all magnetic in their neutral and charge states except in the highest positive charge states. Mn@Mo, Fe@Mo, and Co@Mo have the same highest negative charge states of q=?2 for chemical potential of electron just below the conduction band minimum, which corresponds to the electron doping. In the q=?2 state, Mn@Mo has a much larger magnetic moment than its neutral state with the antiferromagnetic coupling between the Mn dopant and its neighboring S atoms maintained, while Fe@Mo and Co@Mo have equal or smaller magnetic moments than their neutral states. The possible charge states of Mn@Mo, Fe@Mo, and Co@Mo and the variation of the magnetic moments for different dopants and charge states are due to the change of the occupation and energy of the anti-bonding defect levels in the band gap. The rich magnetic properties of the neutral and charge states suggest possible realization of the substitutionally Mn-, Fe-, and Co-doped monolayer MoS{sub 2} as dilute magnetic semiconductors.

  2. Supercapacitor behavior of ?-MnMoO{sub 4} nanorods on different electrolytes

    SciTech Connect (OSTI)

    Purushothaman, K.K., E-mail: purushoth_gri@yahoo.co.in [Department of Physics, TRP Engineering College (SRM Group), Irungalur, Trichy, Tamilnadu (India); Cuba, M. [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)] [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India); Muralidharan, G., E-mail: muralg@rediffmail.com [Department of Physics, Gandhigram Rural Institute – Deemed University, Gandhigram, Tamilnadu (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: SEM image of ?-MnMoO{sub 4} nanorods on FTO substrate. Highlights: ? Synthesis of ?-MnMoO{sub 4} nanorods by spin coating method. ? First study on the effect of electrolyte on the pseudocapacitance behavior. ? ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g. ? At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior. -- Abstract: ?-MnMoO{sub 4} nanorods were prepared on conducting glass substrate via sol–gel spin coating method at the optimum doping level. The effect of electrolyte on the pseudocapacitance behavior of the ?-MnMoO{sub 4} nanorods was studied using para toluene sulfonic acid (p-TSA), sulfuric acid (H{sub 2}SO{sub 4}) and hydrochloric acid (HCl) as electrolytes. X-ray diffraction analysis reveals the formation of ?-MnMoO{sub 4} in monoclinic phase. FTIR spectra contain vibrational bands associated with Mo=O, M–O and Mo–O–Mo bonds. SEM image reveals the formation of nanorods. Supercapacitor behavior has been studied using cyclic voltammetry (CV) analysis. ?-MnMoO{sub 4} nanorods exhibit maximum specific capacitance of 998 F/g at a scan rate of 5 mV/s in H{sub 2}SO{sub 4} electrolyte while a specific capacitance of 784 F/g and 530 F/g have been obtained using p-TSA and HCl electrolytes, respectively. At higher scan rates p-TSA electrolyte exhibits superior capacitive behavior than H{sub 2}SO{sub 4}.

  3. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  4. Magnetic cluster excitations in the antiferromagnetic phase of a-MnMoO4 

    E-Print Network [OSTI]

    Ochsenbein, Stefan T; Chaboussant, Gregory; Sieber, Andreas; Gudel, Hans U; Janssen, Stefan; Furrer, Albert; Attfield, J. Paul

    2003-01-01T23:59:59.000Z

    The tetramer-based compound a-MnMoO4 exhibits four prominent peaks in the inelastic neutron scattering (INS) spectrum between 0.5 and 2.0 meV below 10 K. They are assigned to magnetic excitations of the (Mn2+)4 rhombus ...

  5. Identification of phases in the interaction layer between U-Mo-Zr/Al and U-Mo-Zr/Al-Si

    SciTech Connect (OSTI)

    Varela, C.L. Komar; Arico, S.F.; Mirandou, M.; Balart, S.N. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); Gribaudo, L.M. [Departamento Materiales, GIDAT, GAEN, CNEA, Avda. Gral Paz 1499, B1650KNA, San Martin (Argentina); CONICET, Avda. Rivadavia 1917, C1033AAJ, Buenos Aires (Argentina)

    2008-07-15T23:59:59.000Z

    Out-of-pile diffusion experiments were performed between U-7wt.% Mo-1wt.% Zr and Al or Al A356 (7,1wt.% Si) at 550 deg. C. In this work morphological characterization and phase identification on both interaction layer are presented. They were carried out by the use of different techniques: optical and scanning electron microscopy, X-Ray diffraction and WDS microanalysis. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al, the phases UAl{sub 3}, UAl{sub 4}, Al{sub 20}Mo{sub 2}U and Al{sub 43}Mo{sub 4}U{sub 6} were identified. In the interaction layer U-7wt.% Mo-1wt.% Zr/Al A356, the phases U(Al, Si) with 25at.% Si and Si{sub 5}U{sub 3} were identified. This last phase, with a higher Si concentration, was identified with XRD Synchrotron radiation performed at the National Synchrotron Light Laboratory (LNLS), Campinas, Brasil. (author)

  6. Metastable phase boundaries of quasicrystalline phases. [Al-Mn; Al-Ru

    SciTech Connect (OSTI)

    Follstaedt, D.M.; Knapp, J.A.

    1987-01-01T23:59:59.000Z

    The melting curve (T/sub 0/) of the metastable icosahedral phase and the liquidus of the decagonal phase of Al-Mn have been obtained for 14 to 22 at. % Mn. Icosahedral Al-Mn has a congruent melting point of 910 +- 20/sup 0/C at 20 at. % Mn, and melts approx.30/sup 0/C lower than crystalline compounds with the same composition. Icosahedral Al/sub 82/Ru/sub 18/ was determined to melt at 1260 +- 30/sup 0/C. These results were obtained by forming single-phase icosahedral alloys with ion beam mixing, and by rapid heating to accurately known temperatures with electron beams.

  7. Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C

    SciTech Connect (OSTI)

    Rayment, J.J.; Thomas, G.

    1982-03-01T23:59:59.000Z

    Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

  8. Spark plasma sintering of Mn-Al-C hard magnets , E Fazakas2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Spark plasma sintering of Mn-Al-C hard magnets A Pasko1 , M LoBue1 , E Fazakas2 , L K Varga2 and F characterization of isotropic Mn-Al-C bulk samples obtained by spark plasma sintering (SPS) is reported by spark plasma sintering (SPS). This technique, to our knowledge, has not been used for preparation of Mn

  9. Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures

    E-Print Network [OSTI]

    Ruan, Shiyun

    Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

  10. Effect of Mo Dispersion Size and Water Vapor on Oxidation of Two-Phase Directionally Solidified NiAl-9Mo In-Situ Composites

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL] [ORNL; Bei, Hongbin [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Tortorelli, Peter F [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Oxidation of two-phase NiAl-9Mo eutectics with 3 different growth rates/2nd phase Mo dispersion sizes were investigated at 900 C in air and air with 10% water vapor. Good oxidation resistance via alumina formation was observed in dry air, with Mo volatilization loss minimized by fine submicron Mo dispersions. However, extensive Mo volatilization and in-place internal oxidation of prior Mo phase regions was observed in wet air oxidation. Ramifications of this phenomenon for the development of multi-phase high-temperature alloys are discussed

  11. Precipitation in cold-rolled Al–Sc–Zr and Al–Mn–Sc–Zr alloys prepared by powder metallurgy

    SciTech Connect (OSTI)

    Vlach, M., E-mail: martin.vlach@mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Stulikova, I.; Smola, B.; Kekule, T.; Kudrnova, H.; Danis, S. [Charles University in Prague, Faculty of Mathematics and Physics, Ke Karlovu 3, CZ-121 16 Prague (Czech Republic); Gemma, R. [King Abdullah University of Science and Technology (KAUST), Physical Sciences and Engineering Division, 23955-6900 Thuwal (Saudi Arabia); Ocenasek, V. [SVÚM a.s., Podnikatelská 565, CZ-190 11 Prague (Czech Republic); Malek, J. [Czech Technical University in Prague, Faculty of Mechanical Engineering, CZ-120 00 Prague (Czech Republic); Tanprayoon, D.; Neubert, V. [Institut für Materialprüfung und Werkstofftechnik, Freiberger Strasse 1, D-38678 Clausthal-Zellerfeld (Germany)

    2013-12-15T23:59:59.000Z

    The effects of cold-rolling on thermal, mechanical and electrical properties, microstructure and recrystallization behaviour of the AlScZr and AlMnScZr alloys prepared by powder metallurgy were studied. The powder was produced by atomising in argon with 1% oxygen and then consolidated by hot extrusion at 350 °C. The electrical resistometry and microhardness together with differential scanning calorimetry measurements were compared with microstructure development observed by transmission and scanning electron microscopy, X-ray diffraction and electron backscatter diffraction. Fine (sub)grain structure developed and fine coherent Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles precipitated during extrusion at 350 °C in the alloys studied. Additional precipitation of the Al{sub 3}Sc and/or Al{sub 3}(Sc,Zr) particles and/or their coarsening was slightly facilitated by the previous cold rolling. The presence of Sc,Zr-containing particles has a significant antirecrystallization effect that prevents recrystallization at temperatures minimally up to 420 °C. The precipitation of the Al{sub 6}Mn- and/or Al{sub 6}(Mn,Fe) particles of a size ? 1.0 ?m at subgrain boundaries has also an essential antirecrystallization effect and totally suppresses recrystallization during 32 h long annealing at 550 °C. The texture development of the alloys seems to be affected by high solid solution strengthening by Mn. The precipitation of the Mn-containing alloy is highly enhanced by a cold rolling. The apparent activation energy of the Al{sub 3}Sc particles formation and/or coarsening and that of the Al{sub 6}Mn and/or Al{sub 6}(Mn,Fe) particle precipitation in the powder and in the compacted alloys were determined. The cold deformation has no effect on the apparent activation energy values of the Al{sub 3}Sc-phase and the Al{sub 6}Mn-phase precipitation. - Highlights: • The Mn, Sc and Zr additions to Al totally suppresses recrystallization at 550 °C. • The Sc,Zr-containing particle precipitation is slightly facilitated by cold rolling. • The Mn-containing particle precipitation is highly enhanced by cold rolling. • Cold rolling has no effect on activation energy of the Al{sub 3}Sc and Al{sub 6}Mn precipitation. • The texture development is affected by high solid solution strengthening by Mn.

  12. Surface alloys of icosahedral AlMnSi with phason distortions

    SciTech Connect (OSTI)

    Follstaedt, D.M.; Knapp, J.A.

    1986-12-01T23:59:59.000Z

    The microstructures produced by electron-beam melting and by ion-beam mixing Al/Mn and Al/Mn/Si layers on Si substrates are examined. The treatments were found to incorporate Si from the substrate into the surface alloy. Several phases formed, depending on treatment, including ..cap alpha..- and ..beta..-AlMnSi, ..mu..-AlMn (epitaxial on Si(111), and amorphous and icosahedral AlMnSi. The observed microstructures relate the novel icosahedral phase to other phases and elucidate its formation kinetics. Diffraction patterns from large icosahedral grains (up to 5 ..mu..m) show distortions in the position and shape of weak (but not strong) reflections, as predicted for phason defects in a quasicrystalline lattice, one of the structures proposed for icosahedral phases.

  13. Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals

    SciTech Connect (OSTI)

    Shen, Z.

    1999-02-12T23:59:59.000Z

    In this dissertation, the author reports on the surface structure of i-Al-Pd-Mn twofold, threefold, fivefold and i-Al-Cu-Fe fivefold surfaces. The LEED studies indicate the existence of two distinct stages in the regrowth of all four surfaces after Ar{sup +} sputtering. In the first stage, upon annealing at relatively low temperature: 500K--800K (depending on different surfaces), a cubic phase appears. The cubic LEED patterns transform irreversibly to unreconstructed quasicrystalline patterns upon annealing to higher temperatures, indicating that the cubic overlayers are metastable. Based upon the data for three chemically-identical, but symmetrically-inequivalent surfaces, a model is developed for the relation between the cubic overlayers and the quasicrystalline substrate. The model is based upon the related symmetries of cubic close-packed and icosahedral-packed materials. These results may be general among Al-rich, icosahedral materials. STM study of Al-Pd-Mn fivefold surface shows that terrace-step-kink structures start to form on the surface after annealing above 700K. Large, atomic ally-flat terraces were formed after annealing at 900K. Fine structures with fivefold icosahedral symmetry were found on those terraces. Data analysis and comparison of the STM images and structure model of icosahedral Al-Pd-Mn suggest that the fine structures in the STM images may be the pseudo Mackay (PMI) clusters which are the structure units of the structure model. Based upon his results, he can conclude that quasicrystalline structures are the stable structures of quasicrystal surfaces. In other words, quasicrystalline structures extend from the bulk to the surface. As a result of the effort reported in this dissertation, he believes that he has increased his understanding of the surface structure of icosahedral quasicrystals to a new level.

  14. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01T23:59:59.000Z

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 – 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Korea’s KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  15. Effects of rhenium alloying on the microstructures and mechanical properties of directionally solidified NiAl-Mo eutectic alloy

    SciTech Connect (OSTI)

    Misra, A.; Wu, Z.L.; Gibala, R. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering

    1997-12-31T23:59:59.000Z

    Low ductility of the reinforcing bcc metal phase at room temperature and weak interfaces can limit the intrinsic toughness and ductility of NiAl-bcc metal eutectic composites. The potential of rhenium (Re) addition, which is known to solid solution soften and lower the ductile-to-brittle transition temperature of various bcc metals, to enhance the ductility and toughness of a directionally solidified NiAl-9 at.% Mo eutectic alloy was investigated. Re partitioned to the bcc metal phase and formed a substitutional solid solution. The interface morphology was changed from a faceted to a non-faceted one. Re alloying caused softening of the Mo fibers, and as a result NiAl-Mo(Re) alloys were softer in compression and flexure and had {approximately}20% higher fracture toughness values as compared to the transverse orientation toughness of NiAl-9Mo alloy. The toughness of the NiAl-Mo(Re) alloys was lower than the longitudinal orientation toughness of the NiAl-9Mo alloy due to the poor alignment of the Mo(Re) phase with the growth direction. The toughening mechanisms have been evaluated and schemes for processing NiAl-Mo(Re) alloys for higher toughness in the longitudinal orientation are suggested. The role of the residual interstitial impurities and partitioning of Ni and Al to Mo fibers on the mechanical properties are highlighted.

  16. Melting point measurements for quasicrystalline phases. [Al-Mn; icosahedral and decagonal phases

    SciTech Connect (OSTI)

    Knapp, J.A.; Follstaedt, D.M.

    1986-01-01T23:59:59.000Z

    Melting transitions of metastable quasicrystalline phases of Al-Mn have been observed using rapid electron-beam heating of fine-grained icosahedral surface layers. The congruent melting point for icosahedral Al/sub 80/Mn/sub 20/ was directly measured to be 910 +- 20/sup 0/C. Heating to higher temperatures shows another transition which is inferred to correspond to the liquidus of the decagonal phase at 965 +- 20/sup 0/C for 20 at. % Mn. The microstructure and formation kinetics of the decagonal phase are discussed, and its electron diffraction is described.

  17. Improved performance of U-Mo dispersion fuel by Si addition in Al matrix.

    SciTech Connect (OSTI)

    Kim, Y S; Hofman, G L [Nuclear Engineering Division

    2011-06-01T23:59:59.000Z

    The purpose of this report is to collect in one publication and fit together work fragments presented in many conferences in the multi-year time span starting 2002 to the present dealing with the problem of large pore formation in U-Mo/Al dispersion fuel plates first observed in 2002. Hence, this report summarizes the excerpts from papers and reports on how we interpreted the relevant results from out-of-pile and in-pile tests and how this problem was dealt with. This report also provides a refined view to explain in detail and in a quantitative manner the underlying mechanism of the role of silicon in improving the irradiation performance of U-Mo/Al.

  18. Transparent Conducting ZnO Thin Films Doped with Al and Mo

    SciTech Connect (OSTI)

    Duenow, J.; Gessert, T.; Wood, D.; Young, D.; Coutts, T.

    2007-01-01T23:59:59.000Z

    Transparent conducting oxide (TCO) thin films are a vital part of photovoltaic cells, flat-panel displays, and electrochromic windows. ZnO-based TCOs, due to the relative abundance of Zn, may reduce production costs compared to those of the prevalent TCO In2O3:Sn (ITO). Undoped ZnO, ZnO:Al (0.5, 1, and 2 wt.% Al2O3), and ZnO:Mo (2 wt.%) films were deposited by RF magnetron sputtering. Controlled incorporation of H2 in the Ar sputtering ambient increased mobility of undoped ZnO by a factor of ~20 to 48 cm2V-1s-1. H2 also appears to catalyze ionization of dopants. This enabled lightly doped ZnO:Al to provide comparable conductivity to the standard 2 wt.%-doped ZnO:Al while demonstrating reduced infrared absorption. Mo was found to be an n-type dopant of ZnO, though material properties did not match those of ZnO:Al. Scattering mechanisms were investigated using temperature-dependent Hall measurements and the method of four coefficients. This abstract is subject to government rights.

  19. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke [ORNL; Zhang, F [CompuTherm LLC, Madison, WI; Miller, Michael K [ORNL; Liu, Chain T [Hong Kong Polytechnic University; Huang, Shenyan [ORNL; Chou, Y.T. [Multi-Phase Services Inc., Knoxville; Tien, R [Multi-Phase Services Inc., Knoxville; Chang, Y A [ORNL; Liaw, Peter K [University of Tennessee, Knoxville (UTK)

    2012-01-01T23:59:59.000Z

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  20. Mo-Al{sub 2}O{sub 3} cermet research and development

    SciTech Connect (OSTI)

    Glass, S.J.; Monroe, S.L.; Stephens, J.J.; Moore, R.H. [and others

    1997-08-01T23:59:59.000Z

    This report describes the results to date of a program that was initiated to predict and measure residual stresses in Mo-Al{sub 2}O{sub 3} cermet-containing components and to develop new materials and processes that would lead to the reduction or elimination of the thermal mismatch stresses. The period of performance includes work performed CY95-97. Excessive thermal mismatch stresses had produced cracking in some cermet-containing neutron tube components. This cracking could lead to a loss of hermeticity or decreased tube reliability. Stress predictions were conducted using finite element models of the various components, along with the thermal coefficient of expansion (CTE), Young`s modulus, and strength properties. A significant portion of the program focused on the property measurements for the existing cermet materials, processing conditions, and the measurement technique. The effects of differences in the properties on the predicted residual stresses were calculated for existing designs. Several potential approaches were evaluated for reducing the residual stresses and cracking in cermet-containing parts including reducing the Mo content of the cermet, substituting a ternary alloy with a better CTE match with alumina, and substituting Nb for Mo. Processing modifications were also investigated for minimizing warpage that occurs during sintering due to differential sintering. These modifications include changing the pressing of the 94ND2 alumina and changing to a 96% alumina powder from AlSiMag.

  1. Dynamical x-ray diffraction from an icosahedral Al-Pd-Mn quasicrystal

    SciTech Connect (OSTI)

    Kycia, S.

    1996-04-23T23:59:59.000Z

    Primary extinction effects in diffraction from single grains of Al-Pd- Mn, and presumably many other FCI alloys, may be significant and should be corrected for prior to use of diffraction data in structural determinations. Probes based on dynamical diffraction effects, such as x-ray standing wave fluorescence, multiple beam interference, and x-ray transmission topographs, may now be used to study the bulk and surface structure of some quasicrystals. The observation of dynamical diffraction from icosahedral Al-Pd-Mn is a striking confirmation of the fact that quasicrystals can present a degree of structural perfection comparable to that found in the best periodic intermetallic crystals.

  2. First-principles study of spin-transfer torque in Co{sub 2}MnSi/Al/Co{sub 2}MnSi spin-valve

    SciTech Connect (OSTI)

    Tang, Ling, E-mail: lingtang@zjut.edu.cn; Yang, Zejin, E-mail: zejinyang@zjut.edu.cn [Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China)

    2013-11-21T23:59:59.000Z

    The spin-transfer torque (STT) in Co{sub 2}MnSi(CMS)/Al/Co{sub 2}MnSi spin-valve system with and without interfacial disorder is studied by a first-principles noncollinear wave-function-matching method. It is shown that in the case of clean interface the angular dependence of STT for CoCo/Al (the asymmetry parameter ??4.5) is more skewed than that for MnSi/Al (??2.9), which suggests the clean CoCo/Al architecture is much more efficient for the application on radio frequency oscillation. We also find that even with interfacial disorder the spin-valve of half-metallic CMS still has a relatively large parameter ? compared to that of conventional ferromagnet. In addition, for clean interface the in-plane torkance of MnSi/Al is about twice as large as that of CoCo/Al. However, as long as the degree of interfacial disorder is sufficiently large, the CoCo/Al and MnSi/Al will show approximately the same magnitude of in-plane torkance. Furthermore, our results demonstrate that CMS/Al/CMS system has very high efficiency of STT to switch the magnetic layer of spin-valve.

  3. Chobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC

    E-Print Network [OSTI]

    Boyer, Edmond

    by chronic carbon tetrachloride (CCl4) administration for 6 weeks, in combination with chronic; CCl4, carbon tetrachloride; CK19, cytokeratin 19; CCR2, chemokine C-C motif receptor 2; EMTChobert MN et al LIVER PRECURSOR CELLS INCREASE HEPATIC FIBROSIS INDUCED BY CHRONIC CARBON

  4. Carriers-mediated ferromagnetic enhancement in Al-doped ZnMnO dilute magnetic semiconductors

    SciTech Connect (OSTI)

    Saleem, Murtaza [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Siddiqi, Saadat A. [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS Institute of Information Technology, Defence Road, Off Raiwind Road, Lahore (Pakistan); Atiq, Shahid, E-mail: shahidatiqpasrur@yahoo.com [Centre of Excellence in Solid State Physics, University of the Punjab, Lahore-54590 (Pakistan); Anwar, M. Sabieh; Hussain, Irshad [School of Science and Engineering (SSE), Lahore University of Management Sciences (LUMS), Opposite Sector U, D.H.A. Lahore Cantt-54792 (Pakistan); Alam, Shahzad [Pakistan Council for Scientific and Industrial Research (PCSIR) Laboratories Complex, Lahore (Pakistan)

    2011-11-15T23:59:59.000Z

    Nano-crystalline Zn{sub 0.95-x}Mn{sub 0.05}Al{sub x}O (x = 0, 0.05, 0.10) dilute magnetic semiconductors (DMS) were synthesized by sol-gel derived auto-combustion. X-ray diffraction (XRD) analysis shows that the samples have pure wurtzite structure typical of ZnO without the formation of secondary phases or impurity. Crystallite sizes were approximated by Scherrer formula while surface morphology and grain sizes were measured by field emission scanning electron microscopy. Incorporation of Mn and Al into the ZnO structure was confirmed by energy-dispersive X-ray analysis. Temperature dependent electrical resistivity measurements showed a decreasing trend with the doping of Al in ZnMnO, which is attributable to the enhancement of free carriers. Vibrating sample magnetometer studies confirmed the presence of ferromagnetic behavior at room temperature. The results indicate that Al doping results in significant variation in the concentration of free carriers and correspondingly the carrier-mediated magnetization and room temperature ferromagnetic behavior, showing promise for practical applications. We attribute the enhanced saturation magnetization and electrical conductivity to the exchange interaction mediated by free electrons.

  5. Scanning Electron Microscopy Analysis of Fuel/Matrix Interaction Layers in Highly-Irradiated U–Mo Dispersion Fuel Plates with Al and Al–Si Alloy Matrices

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Brandon D. Miller; Jian Gan; Adam B. Robinson; Pavel Medvedev; James Madden; Dan Wachs; Mitch Meyer

    2014-04-01T23:59:59.000Z

    In order to investigate how the microstructure of fuel/matrix-interaction (FMI) layers change during irradiation, different U–7Mo dispersion fuel plates have been irradiated to high fission density and then characterized using scanning electron microscopy (SEM). Specifially, samples from irradiated U–7Mo dispersion fuel elements with pure Al, Al–2Si and AA4043 (~4.5 wt.%Si) matrices were SEM characterized using polished samples and samples that were prepared with a focused ion beam (FIB). Features not observable for the polished samples could be captured in SEM images taken of the FIB samples. For the Al matrix sample, a relatively large FMI layer develops, with enrichment of Xe at the FMI layer/Al matrix interface and evidence of debonding. Overall, a significant penetration of Si from the FMI layer into the U–7Mo fuel was observed for samples with Si in the Al matrix, which resulted in a change of the size (larger) and shape (round) of the fission-gas bubbles. Additionally, solid-fission-product phases were observed to nucleate and grow within these bubbles. These changes in the localized regions of the microstructure of the U–7Mo may contribute to changes observed in the macroscopic swelling of fuel plates with Al–Si matrices.

  6. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01T23:59:59.000Z

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.2×1021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  7. Determination of Mn valence states in mixed-valent manganates by XANES spectroscopy AlAin MAnceAu,1,

    E-Print Network [OSTI]

    Cedex 9, France 2 Advanced Light Source, Lawrence Berkeley National Laboratory, One Cyclotron Road and phyllomanganates with no or little Mn3+ in the MnO2 layer exhibit intensi- ties, shapes, and relative energy catalysis, hazardous waste remediation, and rechargeable battery technology (Thackeray 1997; Toupin et al

  8. Prediction of U-Mo dispersion nuclear fuels with Al-Si alloy using artificial neural network

    SciTech Connect (OSTI)

    Susmikanti, Mike, E-mail: mike@batan.go.id [Center for Development of Nuclear Informatics, National Nuclear Energy Agency, PUSPIPTEK, Tangerang (Indonesia); Sulistyo, Jos, E-mail: soj@batan.go.id [Center for Nuclear Facilities Engineering, National Nuclear Energy Agency, PUSPIPTEK, Tangerang (Indonesia)

    2014-09-30T23:59:59.000Z

    Dispersion nuclear fuels, consisting of U-Mo particles dispersed in an Al-Si matrix, are being developed as fuel for research reactors. The equilibrium relationship for a mixture component can be expressed in the phase diagram. It is important to analyze whether a mixture component is in equilibrium phase or another phase. The purpose of this research it is needed to built the model of the phase diagram, so the mixture component is in the stable or melting condition. Artificial neural network (ANN) is a modeling tool for processes involving multivariable non-linear relationships. The objective of the present work is to develop code based on artificial neural network models of system equilibrium relationship of U-Mo in Al-Si matrix. This model can be used for prediction of type of resulting mixture, and whether the point is on the equilibrium phase or in another phase region. The equilibrium model data for prediction and modeling generated from experimentally data. The artificial neural network with resilient backpropagation method was chosen to predict the dispersion of nuclear fuels U-Mo in Al-Si matrix. This developed code was built with some function in MATLAB. For simulations using ANN, the Levenberg-Marquardt method was also used for optimization. The artificial neural network is able to predict the equilibrium phase or in the phase region. The develop code based on artificial neural network models was built, for analyze equilibrium relationship of U-Mo in Al-Si matrix.

  9. Epitaxial {tau} phase MnAl thin films on MgO (001) with thickness-dependent magnetic anisotropy

    SciTech Connect (OSTI)

    Cui Yishen; Chen Wei [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Yin Wenjing; Lu Jiwei [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Wolf, Stuart A. [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2011-11-15T23:59:59.000Z

    In this study, ferromagnetic MnAl films were prepared by alternating Al/Mn quasi-monolayer deposition using a novel biased target ion beam deposition (BTIBD) technique. XRD results showed that the magnetic {tau} phase was well formed in MnAl thin films ({approx}10 nm), which grew epitaxially on single crystal MgO (001) substrates. The optimized saturation magnetization was {approx}394 emu/cc. Furthermore, we observed a thickness-dependent uniaxial anisotropy in ferromagnetic MnAl films, which was attributed to the change of the tetragonal lattice distortion as a function of film thickness. The relationship between the film thicknesses and saturation magnetizations suggested the existence of a magnetically dead layer {approx}2.7 nm with an extrapolated saturation moment around 523 emu/cc ({approx}1.90 {mu}{sub B}/Mn). This value has exceeded the experimental value in bulk materials and is close to the theoretically predicted magnetization ({approx}1.975 {mu}{sub B}/Mn).

  10. Results of U-xMo (x=7, 10, 12 wt.%) Alloy versus Al-6061 Cladding Diffusion Couple Experiments Performed at 500, 550 and 600 Degrees C

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Yongho Sohn

    2013-04-01T23:59:59.000Z

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been developing low enrichment fuel systems encased in Al 6061 for use in research and test reactors. U–Mo alloys in contact with Al and Al alloys can undergo diffusional interactions that can result in the development of interdiffusion zones with complex fine-grained microstructures composed of multiple phases. A monolithic fuel currently being developed by the RERTR program has local regions where the U–Mo fuel plate is in contact with the Al 6061 cladding and, as a result, the program finds information about interdiffusion zone development at high temperatures of interest. In this study, the microstructural development of diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo, and U-12wt.%Mo vs. Al 6061 (or 6061 aluminum) cladding, annealed at 500, 550, 600 degrees C for 1, 5, 20, 24, or 132 hours, was analyzed by backscatter electron microscopy and x-ray energy dispersive spectroscopy on a scanning electron microscope. Concentration profiles were determined by standardized wavelength dispersive spectroscopy and standardless x-ray energy dispersive spectroscopy. The results of this work shows that the presence of surface layers at the U–Mo/Al 6061 interface can dramatically impact the overall interdiffusion behavior in terms of rate of interaction and uniformity of the developed interdiffusion zones. It further reveals that relatively uniform interaction layers with higher Si concentrations can develop in U–Mo/Al 6061 couples annealed at shorter times and that longer times at temperature result in the development of more non-uniform interaction layers with more areas that are enriched in Al. At longer annealing times and relatively high temperatures, U–Mo/Al 6061 couples can exhibit more interaction compared to U–Mo/pure Al couples. The minor alloying constituents in Al 6061 cladding can result in the development of many complex phases in the interaction layer of U–Mo/Al–6061 cladding couples, and some phases in the interdiffusion zones of U–Mo/Al–6061 cladding couples are likely similar to those observed for U–Mo/pure Al couples.

  11. Anti-site disorder and improved functionality of Mn?NiX (X = Al, Ga, In, Sn) inverse Heusler alloys

    SciTech Connect (OSTI)

    Paul, Souvik; Kundu, Ashis; Ghosh, Subhradip, E-mail: subhra@iitg.ernet.in [Department of Physics, Indian Institute of Technology Guwahati, Guwahati, Assam 781039 (India); Sanyal, Biplab [Department of Physics and Astronomy, Uppsala University, Box 516, 75120 Uppsala (Sweden)

    2014-10-07T23:59:59.000Z

    Recent first-principles calculations have predicted Mn?NiX (X = Al, Ga, In, Sn) alloys to be magnetic shape memory alloys. Moreover, experiments on Mn?NiGa and Mn?NiSn suggest that the alloys deviate from the perfect inverse Heusler arrangement and that there is chemical disorder at the sublattices with tetrahedral symmetry. In this work, we investigate the effects of such chemical disorder on phase stabilities and magnetic properties using first-principles electronic structure methods. We find that except Mn?NiAl, all other alloys show signatures of martensitic transformations in presence of anti-site disorder at the sublattices with tetrahedral symmetry. This improves the possibilities of realizing martensitic transformations at relatively low fields and the possibilities of obtaining significantly large inverse magneto-caloric effects, in comparison to perfect inverse Heusler arrangement of atoms. We analyze the origin of such improvements in functional properties by investigating electronic structures and magnetic exchange interactions.

  12. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Sterbinsky, G. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Assaf, B. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Arena, D. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Heiman, D. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics

    2014-12-07T23:59:59.000Z

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  13. Calculations of structural, elastic, electronic, magnetic and phonon properties of FeNiMnAl by the first principles

    SciTech Connect (OSTI)

    U?ur, ?ule [Central Research and Practice Laboratory (AH?LAB), Ahi Evran University, 40100 K?r?ehir (Turkey); ?yigör, Ahmet [Department of Physics, Faculty of Science, Gazi University, 06500 Ankara (Turkey)

    2014-10-06T23:59:59.000Z

    The electronic, elastic and dynamical properties of the quaternary alloy FeNiMnAl have been investigated using a pseudopotential plane wave method within the generalized gradient approximation (GGA). We determined the lattice parameters and the bulk modulus B. In addition, the elastic properties such as elastic constans (C{sub 11}, C{sub 12} and C{sub 44}), the shear modulus G, the young modulus E, the poisson's ratio ? and the B/G ratio are also given. The FeNiMnAl Heusler alloy exhibit a ferromagnetic half-metallic behavior with the total magnetic moment of 4.02 ?{sub B}. The phonon dispersion of FeNiMnAl has been performed using the density functional theory and the direct method with 2×2×2 supercell.

  14. Unoccupied electronic states of icosahedral Al-Pd-Mn quasicrystals: Evidence of image potential resonance and pseudogap

    SciTech Connect (OSTI)

    Maniraj, M [UGC-DAE Confortium for Scientific Research; Rai, Abhishek [UGC-DAE Confortium for Scientific Research; Barman, S R [UGC-DAE Confortium for Scientific Research; Krajci, M [Slovak Academy of Sciences; Schlagel, Deborah L [Ames Laboratory; Lograsso, Thomas A [Ames Laboratory; Horn, K [Fritz-Haber-Institut der Max-Planck-Gesellschaft

    2014-09-01T23:59:59.000Z

    We study the unoccupied region of the electronic structure of the fivefold symmetric surface of an icosahedral (i) Al-Pd-Mn quasicrystal. A feature that exhibits parabolic dispersion with an effective mass of (1.15±0.1)me and tracks the change in the work function is assigned to an image potential resonance because our density functional calculation shows an absence of band gap in the respective energy region. We show that Sn grows pseudomorphically on i?Al?Pd?Mn as predicted by density functional theory calculations, and the energy of the image potential resonance tracks the change in the work function with Sn coverage. The image potential resonance appears much weaker in the spectrum from the related crystalline Al-Pd-Mn surface, demonstrating that its strength is related to the compatibility of the quasiperiodic wave functions in i?Al?Pd?Mn with the free-electron-like image potential states. Our investigation of the energy region immediately above EF provides unambiguous evidence for the presence of a pseudogap, in agreement with our density functional theory calculations.

  15. Shock compaction of rapidly solidified nickel based Mo--Al--W alloy powders with pressure up to 1. 2 mbar

    SciTech Connect (OSTI)

    Staudhammer, K.P.

    1988-01-01T23:59:59.000Z

    The alloy described in this paper is a high strength nickel alloy containing 10 wt% Mo, 6.8 wt% Al, and 6 wt% W. It cannot be easily prepared by conventional casting methods without gross segregation occurring in the form of massive dendrites. Gas atomization to form fine powders reduces the dendrite size and therefore, the segregation. The spacing of the secondary dendrite arm has been used to estimate the cooling rate of this powder. The experimental investigation of shock compaction is based in part on mach stem lens formation work. One of the fortuitous aspects of the cylindrical explosion design is its suitability as a screening tool with its very high success rate of recovery. Use of the radial implosion design has allowed for the determination of optimum pressures required for consolidation of RSR Ni--10Mo--6.8Al--6W alloy powders as a function of initial packing density. These sets of experiments are in line with previous work on other shock consolidated powders showed that an increase of initial density decreased the melt zone, and only required a slight increase in the pressure to consolidate. 4 refs., 8 figs.

  16. Conditions for spin-gapless semiconducting behavior in Mn{sub 2}CoAl inverse Heusler compound

    SciTech Connect (OSTI)

    Galanakis, I., E-mail: galanakis@upatras.gr [Department of Materials Science, School of Natural Sciences, University of Patras, GR-26504 Patra (Greece); Özdo?an, K., E-mail: kozdogan@yildiz.edu.tr [Department of Physics, Yildiz Technical University, 34210 ?stanbul (Turkey); ?a??o?lu, E.; Blügel, S. [Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, 52425 Jülich (Germany)

    2014-03-07T23:59:59.000Z

    Employing ab initio electronic structure calculations, we investigate the conditions for spin-gapless semiconducting (SGS) behavior in the inverse Mn{sub 2}CoAl Heusler compound. We show that tetragonalization of the lattice, which can occur during films growth, keeps the SGS character of the perfect cubic compound. On the contrary, atomic swaps even between sites with different local symmetry destroy the SGS character giving rise to a half-metallic state. Furthermore, the occurrence of Co-surplus leads also to half-metallicity. Thus, we propose that in order to achieve SGS behavior during the growth of Mn{sub 2}CoAl (and similar SGS Heusler compounds) thin films, one should minimize the occurrence of defects, while small deformations of the lattice, due to the lattice mismatch with the substrate, do not play a crucial role.

  17. Magneto-transport properties of oriented Mn{sub 2}CoAl films sputtered on thermally oxidized Si substrates

    SciTech Connect (OSTI)

    Xu, G. Z.; Du, Y.; Zhang, X. M.; Liu, E. K.; Wang, W. H., E-mail: wenhong.wang@iphy.ac.cn; Wu, G. H. [State Key Laboratory for Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Zhang, H. G. [College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124 (China)

    2014-06-16T23:59:59.000Z

    Spin gapless semiconductors are interesting family of materials by embracing both magnetism and semiconducting due to their unique band structure. Its potential application in future spintronics requires realization in thin film form. In this Letter, we report fabrication and transport properties of spin gapless Mn{sub 2}CoAl films prepared on thermally oxidized Si substrates by magnetron sputtering deposition. The films deposited at 673?K are well oriented to (001) direction and display a uniform-crystalline surface. Magnetotransport measurements on the oriented films reveal a semiconducting-like resistivity, small anomalous Hall conductivity, and linear magnetoresistance representative of the transport signatures of spin gapless semiconductors. The magnetic properties of the films have also been investigated and compared to that of bulk Mn{sub 2}CoAl, showing small discrepancy induced by the composition deviation.

  18. Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4 Qi Wan, Ping States *S Supporting Information ABSTRACT: The catalytic effects of MnFe2O4 nanoparticles on the hydrogen storage properties of MgH2-LiAlH4, prepared by ball milling, are studied for the first time. The hydrogen

  19. Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural Characterization and Catalytic Function

    E-Print Network [OSTI]

    Bell, Alexis T.

    Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural of stoichiometric reduction in H2, and the oxidative dehydrogenation of propane. VOx domains on Al2O3 modified The oxidative dehydrogenation (ODH) of propane provides an attractive route for the synthesis of propene.1

  20. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    SciTech Connect (OSTI)

    Jamer, M. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Sterbinsky, G. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Assaf, B. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Arena, D. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Heiman, D. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics

    2014-12-07T23:59:59.000Z

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  1. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  2. The effects of small metal additions ,,Co,Cu,Ga,Mn,Al,Bi,Sn... on the magnetocaloric properties of the Gd5Ge2Si2 alloy

    E-Print Network [OSTI]

    Kletetschka, Gunther

    .1 X=Fe,Cu,Co,Ga,Mn, or Al alloys are superior magnetic refrigerants compared to the undoped Gd5Ge2Si2 magnetic refrigerant because of its large "giant" magnetocaloric effect Sm between 270 and 300 K.1 more useful magnetic refrigerant than the undoped Gd5Ge2Si2 compound. Further, it was concluded

  3. Functioning mechanism of AlF3 coating on the Li- and Mn-rich cathode materials

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Xiao, Jie; Polzin, Bryant; Yan, Pengfei; Chen, Xilin; Wang, Chong M.; Zhang, Jiguang

    2014-11-25T23:59:59.000Z

    Li- and Mn-rich (LMR) material is a very promising cathode for lithium ion batteries because of their high theoretical energy density (~900 Wh kg-1) and low cost. However, their poor long-term cycling stability, voltage fade, and low rate capability are significant barriers hindered their practical applications. Surface coating, e.g. AlF3 coating, can significantly improve the capacity retention and enhance the rate capability. However, the fundamental mechanism of this improvement and the microstructural evolution related to the surface coating is still not well understood. Here, we report systematic studies of the microstructural changes of uncoated and AlF3-coated materials before and after cycling using aberration-corrected scanning/transmission electron microscopy and electron energy loss spectroscopy. The results reveal that surface coating can reduce the oxidation of electrolyte at high voltage, thus suppressing the accumulation of SEI layer on electrode particle surface. Surface coating also enhances structural stability of the surface region (especially the electrochemically transformed spinel-like phase), and protects the electrode from severe etching/corrosion by the acidic species in the electrolyte, therefore limiting the degradation of the material. Moreover, surface coating can alleviate the undesirable voltage fade by minimize layered-spinel phase transformation in the bulk region of the materials. These fundamental findings may also be widely applied to explain the functioning mechanism of other surface coatings used in a broad range of electrode materials.

  4. Electronic Phase Separation in Pr sub 1 sub x (Ca, Sr) sub x MnO sub 3 subdelta and Tunneling Magnetoresistance in Sr sub 2 FeMoO sub 6

    E-Print Network [OSTI]

    Niebieskikwiat, D G

    2003-01-01T23:59:59.000Z

    In this work, we approach two aspects of the physics of magnetic perovskites presenting colossal magnetoresistance (CMR). Firstly, we go deeply into the phase separation (PS) between the ferromagnetic (FM) metallic state and the antiferro-magnetic (AFM) charge ordered (CO) insulating state, in manganites of the type Pr sub 1 sub x (Ca,Sr) sub x MnO sub 3 subdelta. Secondly, and more briefly, we analyze the problem of the influence of the grain boundary insulating barriers on the tunneling magnetoresistance in the Sr sub 2 FeMoO sub 6 double perovskite.The use of different measurement techniques allowed us to make a complete characterization of the PS state in the compounds Pr sub 0.65Ca sub 0 sub . sub 3 sub 5 sub - sub y Sr sub y MnO sub 3 for 0 ) keeping constant the carrier concentration (x = 0.35). This material presents an evolution from a CO insulating phase for small (y =0), towards the FM metallic phase for large (y = 0.20). In t

  5. Effect of Processing and Microalloying Elements on the Thermal Stability of Cr-Cr3Si and NiAl-Mo Eutectic Alloys

    SciTech Connect (OSTI)

    Gali, Aravind [ORNL; Bei, Hongbin [ORNL; George, Easo P [ORNL

    2007-01-01T23:59:59.000Z

    The thermal stability of multiphase intermetallics at temperatures to 1400 C was investigated by studying two model eutectic systems: Cr-Cr{sub 3}Si having a lamellar microstructure and NiAl-Mo having a fibrous microstructure. In drop cast Cr-Cr{sub 3}Si, coarsening was found to be interface controlled. The coarsening rate could be reduced by microalloying with Ce and Re, two elements which were chosen because they were expected to segregate to the Cr-Cr{sub 3}Si interfaces and decrease their energies. Similarly, directional solidification, which is also expected to lower the Cr-Cr{sub 3}Si interfacial energy, was found to dramatically decrease the coarsening rate. In the case of NiAl-Mo, coarsening was found to occur by fault migration and annihilation. Microalloying with B was found to significantly decrease the coarsening rate. The fiber density in the B-doped alloy was smaller than in the undoped alloy, suggesting that B affects the coarsening rate by lowering the fault density.

  6. Alpha phase precipitation from phase-separated beta phase in a model Ti-Mo-Al alloy studied by direct coupling of transmission electron microscopy and atom probe tomography

    SciTech Connect (OSTI)

    Devaraj, Arun; Nag, Soumya; Banerjee, Rajarshi

    2013-10-19T23:59:59.000Z

    The benefit of direct coupling of APT with TEM dark field imaging to investigate early stages of phase transformation in multicomponent alloys is demonstrated by analyzing alpha phase precipitated in a model Ti-10 at% Mo-10 at% Al alloy during annealing at 400oC. Through such a direct coupling approach a thermodynamically unexpected solute partitioning trend between beta matrix and alpha precipitate is observed in the early stages of precipitation, which is explained based on possible nucleation of alpha phase in the Ti rich (Mo and Al depleted regions) created as a result of phase separation in beta matrix. On further higher temperature annealing at 600oC for 1 hour, the alpha precipitates were shown to grow and get enriched in Al and further depleted in Mo reaching the thermodynamic equilibrium.

  7. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai, E-mail: Kai.Zhu@nrel.gov [Chemical and Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2014-05-26T23:59:59.000Z

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  8. The design and optimization of two low frequency energy harvesters employing 3C-SiC/AlN/Mo composite layers

    SciTech Connect (OSTI)

    Iqbal, Abid, E-mail: abid.iqbal@griffithuni.edu.au; Mohd-Yasin, Faisal, E-mail: abid.iqbal@griffithuni.edu.au; Dimitrijev, Sima, E-mail: abid.iqbal@griffithuni.edu.au [Queensland Micro- and Nanotechnology Centre, Griffith University, Brisbane, QLD 4111 (Australia)

    2014-10-24T23:59:59.000Z

    This paper presents the design and simulation of twocantilever-based energy harvesters that employs cubic silicon carbide on silicon (3C-SiC-on-Si) wafer as the base material and bottom electrode. Aluminum Nitride (AlN) is employed as the piezoelectric/middle layer due to its excellent material properties and high stability in varying temperature and harsh environment. Molybdenum (Mo) serves as the top layer/electrode. The thickness of the structural layers are optimized through MATLAB and also analyzed via Finite Element Analysis using Intellisuite. Two designs are proposed at low resonant frequency, one with conventional cantilever beam, the other being a T-shaped cantilever beam. Both structures are simulated and their performances are compared.

  9. Structure of Co-Mo/UPSILON-Al/sub 7/O/sub 3/ catalysts and relationship to HDS and hydrogenation activity. [Hydrodesulfurization (HDS)

    SciTech Connect (OSTI)

    Bennet, B.A. (Imperial Coll., London, England); Chadwick, D.; Jawahery, A.R.; Breysse, M.; Vrinat, M.

    1982-09-01T23:59:59.000Z

    From Mossbauer spectroscopy studies of catalysts of typical industrial compositions and activity measurements it was shown that catalysts containing the ''Co-Mo-S'' phase have relatively higher hydrodesulfurization (HDS) activities. It was also found that the use of Co in the first impregnation step favored the formation of Co/sub 9/S/sub 8/ (in addition to Co in alumina), while the reverse impregnation order produced mainly the ''Co-Mo-S'' phase. Avoiding Co/sub 3/O/sub 4/ formation in the oxide precursor was important for the formation of the ''Co-Mo-S'' phase and this was achieved by the impregnation of Mo before Co. There was also evidence that when Co was used in the second impregnation step, there was significant Mo, Co interaction. This interaction my produce a CoMo surface phase which is disordered and well dispersed and sulfides to the ''Co-Mo-S'' phase. (JMT)

  10. Scanning tuneeling microscopy studies of fivefold surfaces of icosahedral Al-Pd-Mn quasicrystals and of thin silver films on those surfaces

    SciTech Connect (OSTI)

    Unal, Baris

    2008-12-01T23:59:59.000Z

    The present work in this dissertation mainly focuses on the clean fivefold surfaces of i-Al-Pd-Mn quasicrystals as well as the nucleation and growth of Ag films on these surfaces. In addition, Ag film growth on NiAl(110) has been explored in the frame of this dissertation. First, we have investigated the equilibration of a fivefold surface of icosahedral Al-Pd-Mn quasicrystal at 900-915 K and 925-950 K, using Omicron variable temperature scanning tunneling microscope (STM). Annealing at low temperatures resulted in many voids on some terraces while the others were almost void-free. After annealing at 925-950K, void-rich terraces became much rarer. Our STM images suggest that through growth and coalescence of the voids, a different termination becomes exposed on host terraces. All of these observations in our study indicate that even after the quasicrystalline terrace-step structure appears, it evolves with time and temperature. More specifically, based on the STM observations, we conclude that during the annealing a wide range of energetically similar layers nucleate as surface terminations, however, with increasing temperature (and time) this distribution gets narrower via elimination of the metastable void-rich terraces. Next, we have examined the bulk structural models of icosahedral Al-Pd-Mn quasicrystal in terms of the densities, compositions and interplanar spacings for the fivefold planes that might represent physical surface terminations. In our analyses, we mainly have focused on four deterministic models which have no partial or mixed occupancy but we have made some comparisons with an undeterministic model. We have compared the models with each other and also with the available experimental data including STM, LEED-IV, XPD and LEIS. In all deterministic models, there are two different families of layers (a pair of planes), and the nondeterministic model contains similar group of planes. These two families differ in terms of the chemical decoration of their top planes. Hence, we name them as Pd+(with Pd) and Pd-(without Pd). Based on their planer structure and the step height, it can be said that these two families can be viable surface terminations. However, besides the Pd content, these two sets differ in terms of relative densities of their top planes as well as the gap separating the layer from the nearest atomic plane. The experimental data and other arguments lead to the conclusion that the Pd- family is favored over the Pd+. This has an important implication on the interpretation of local motifs seen in the high resolution STM images. In other words, the dark stars are not formed by cut-Bergmans rather they are formed by cut-Mackays.

  11. Intrinsic magnetic, structural and resistivity properties of ferromagnetic Mn{sub 0.5}Zn{sub 0.5}Al{sub x}Fe{sub 2?x}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Haralkar, S.J. [Department of Physics, Kulswamini College, Tuljapur, Osmanabad, MS (India); Kadam, R.H. [Materials Research Laboratory, Srikrishna Mahavidyalaya Gunjoti, Omerga, Osmanabad 413613, MS (India); More, S.S. [Department of Physics, Yashwantrao Chavan Mahavidyalaya, Tuljapur, Osmanabad, MS (India); Shirsath, Sagar E., E-mail: shirsathsagar@hotmail.com [Spin Device Technology Center, Faculty of Engineering, Shinshu University, Nagano 380-8553 (Japan); Mane, M.L. [Department of Physics, S.G.R.G. Shinde Mahavidyalaya, Paranda 413502, MS (India); Patil, Swati [Materials Research Laboratory, Srikrishna Mahavidyalaya Gunjoti, Omerga, Osmanabad 413613, MS (India); Mane, D.R. [Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, MS (India)

    2013-03-15T23:59:59.000Z

    Highlights: ? Al{sup 3+} ion substituted Mn–Zn ferrite nanoparticles. ? Single phase cubic spinel structure changes with Al{sup 3+} substitution. ? Magnetization and coercivity decreased with increasing Al{sup 3+}. ? Resistivity increased with Al{sup 3+} substitution. - Abstract: In this work the nano-structural, magnetic and resistivity properties of Al{sup 3+} substituted Mn–Zn ferrites powders were investigated. Mn{sub 0.5}Zn{sub 0.5}Al{sub x}Fe{sub 2?x}O{sub 4} powders, where x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5 were obtained by the sol–gel auto-combustion method. X-ray diffraction data indicate that, after substitution, all the samples consisted of the main spinel phase in combination with a small amount of a foreign Al{sub 2}O{sub 3} phase. The addition of Al{sup 3+} resulted in a reduction of particle size and density of the prepared samples. Cation distribution in the present study was estimated by using X-ray diffraction data. The tetrahedral site radii initially increased with Al{sup 3+} content while the octahedral site radii decreased with the Al{sup 3+} substitution. FTIR spectra show two strong absorption bands at 529–548 cm{sup ?1} and 445–452 cm{sup ?1} which are the typical bands for the cubic spinel crystal structure. The magnetic properties were measured by employing a vibrating sample magnetometer. It was observed that the saturation magnetization, coercivity and anisotropy field decreased with the increase of Al{sup 3+} substitution. Introduction of Al{sup 3+} ions into the Mn–Zn ferrite increased the values of the resistivity, especially in the lower temperature range.

  12. Dissolved trace metals (Ni, Zn, Co, Cd, Pb, Al, and Mn) around the Crozet Islands, Southern Ocean

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of trace elements such as Zn, Co, and Cd may be influenced by complexing ligands [e.g., Zn: Bruland, 1989; Ellwood and van den Berg, 2000; Co: Ellwood and van den Berg, 2001; Saito et al., 2004; Cd: Bruland, 1992

  13. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  14. Ferromagnetism and magneto-transport properties of Mn{sub 0.92}Ca{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate

    SciTech Connect (OSTI)

    Dung, Dang Duc; Van Thiet, Duong [Department of Physics, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Department of General Physics, School of Engineering Physics, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Ha Noi (Viet Nam); Anh Tuan, Duong; Cho, Sunglae, E-mail: slcho@ulsan.ac.kr [Department of Physics, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Feng, Wuwei [School of Materials Science and Engineering, China University of Geosciences, Beijing 100083 (China)

    2014-05-07T23:59:59.000Z

    The epitaxial Mn{sub 0.92}Ca{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 340?K was enhanced with the addition of Ca, compared to that of bulk MnAs (T{sub C}???318?K). The maxima magnetoresistance, ?2.08% at 0.7?T, was observed near the critical magnetic transition temperature. Moreover, the giant magnetocaloric effect was found with the maximum magnetic entropy change, ?200?J/kgK, around 330?K at 5?T.

  15. Giant magnetocaloric effect of Mn{sub 0.92}Ba{sub 0.08}As thin film grown on Al{sub 2}O{sub 3}(0001) substrate

    SciTech Connect (OSTI)

    Dang Duc Dung [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of); Department of General Physics, School of Engineering, Ha Noi University of Science and Technology, 1 Dai Co Viet road, Ha Noi (Viet Nam); Duong Anh Tuan; Duong Van Thiet; Shin, Yooleemi; Cho, Sunglae [Department of Physics, University of Ulsan, Ulsan 690-749 (Korea, Republic of)

    2012-04-01T23:59:59.000Z

    The epitaxial Mn{sub 0.92}Ba{sub 0.08}As thin film was grown on Al{sub 2}O{sub 3}(0001) substrate by molecular beam epitaxy. The Curie temperature (T{sub C}) around 350 K was enhanced with the addition of Ba, compared to that of bulk MnAs (T{sub C} {approx} 318 K). We have observed the linear resistivity versus the square of temperature and high negative magnetoresistance near Curie temperature. Moreover, the giant magnetocaloric effect was found with maximum magnetic entropy change, 65 J/kgK, around room temperature at 5 T.

  16. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

    2010-07-13T23:59:59.000Z

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  17. Microstructural evolution of U(Mo)–Al(Si) dispersion fuel under irradiation – Destructive analyses of the LEONIDAS E-FUTURE plates

    SciTech Connect (OSTI)

    A. Leenaers; S. Van den Berghe; J. Van Eyken; E. Koonen; F. Charollais; P. Lemoine; Y. Calzavara; H. Guyon; C. Jarousse; D. Geslin; D. Wachs; D. Keiser; A. Robinson; G. Hofman; Y. S. Kim

    2013-10-01T23:59:59.000Z

    Several irradiation experiments have confirmed the positive effect of adding Si to the matrix of an U(Mo) dispersion fuel plate on its in-pile irradiation behavior. E-FUTURE, the first experiment of the LEONIDAS program, was performed to select an optimum Si concentration and fuel plate heat treatment parameters for further qualification. It consisted of the irradiation of 4 distinct (regarding Si content and heat treatments), full size flat fuel plates in the BR2 reactor under bounding conditions (470 W/cm2 peak BOL power, approximately 70% peak burn-up). After the irradiation, the E-FUTURE plates were examined non-destructively and found to have pillowed in the highest burn-up positions. The destructive post-irradiation examination confirmed that the fuel evolves in a stable way up to a burn-up of 60%235U. Even in the deformed area (pillow) the U(Mo) fuel itself shows stable behavior and remaining matrix material was present. From the calculation of the volume fractions, the positive effect of a higher Si amount added to the matrix and the higher annealing temperature can be derived.

  18. MO. REV. MO. MAGNETIC CLEANLINESS GUIDELINES

    E-Print Network [OSTI]

    Rathbun, Julie A.

    MO. REV. MO. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 1 Of 3 DATE 4/6/70 The purpose of this ATM is to update the ALSEP Magnetic Cleanliness Guidelines as delineated in A TM-294, dated 1 June. ATM-865 MAGNETIC CLEANLINESS GUIDELINES PAGE 2 OF 3 DATE 4/6/70 A review of the ALSEP Magnetic

  19. Corrosion Resistance of Amorphous Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4 coating - a new criticality-controlled material

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Saw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-03-28T23:59:59.000Z

    An iron-based amorphous metal with good corrosion resistance and a high absorption cross-section for thermal neutrons has been developed and is reported here. This amorphous alloy has the approximate formula Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} and is known as SAM2X5. Chromium (Cr), molybdenum (Mo) and tungsten (W) were added to provide corrosion resistance, while boron (B) was added to promote glass formation and the absorption of thermal neutrons. Since this amorphous metal has a higher boron content than conventional borated stainless steels, it provides the nuclear engineer with design advantages for criticality control structures with enhanced safety. While melt-spun ribbons with limited practical applications were initially produced, large quantities (several tons) of gas atomized powder have now been produced on an industrial scale, and applied as thermal-spray coatings on prototypical half-scale spent nuclear fuel containers and neutron-absorbing baskets. These prototypes and other SAM2X5 samples have undergone a variety of corrosion testing, including both salt-fog and long-term immersion testing. Modes and rates of corrosion have been determined in various relevant environments, and are reported here. While these coatings have less corrosion resistance than melt-spun ribbons and optimized coatings produced in the laboratory, substantial corrosion resistance has been achieved.

  20. Interdiffusion between Zr Diffusion Barrier and U-Mo Alloy

    SciTech Connect (OSTI)

    K. Huang; Y. Park; Y. H. Sohn

    2012-12-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment uranium fuels under the Reduced Enrichment for Research and Test Reactor (RERTR) program. Significant reactions have been observed between U-Mo fuels and Al or Al alloy matrix. Refractory metal Zr has been proposed as barrier material to reduce the interactions. In order to investigate the compatibility and barrier effects between U-Mo alloy and Zr, solid-to-solid U-10wt.%Mo vs. Zr diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 °C for various times. The microstructures and concentration profiles due to interdiffusion and reactions were examined via scanning electron microscopy and electron probe microanalysis, respectively. Intermetallic phase Mo2Zr was found at the interface and its population increased when annealing temperature decreased. Diffusion paths were also plotted on the U-Mo-Zr ternary phase diagrams with good consistency. The growth rate of interdiffusion zone between U-10wt.%Mo and Zr was also calculated under the assumption of parabolic diffusion, and was determined to be about 103 times lower than the growth rate of diffusional interaction layer found in diffusion couples U-10wt.%Mo vs. Al or Al-Si alloy. Other desirable physical properties of Zr as barrier material, such as neutron adsorption rate, melting point and thermal conductivity are presented as supplementary information to demonstrate the great potential of Zr as the diffusion barrier for U-Mo fuel systems in RERTR.

  1. Spin–glass transition in La{sub 0.75}Sr{sub 0.25}Mn{sub 0.5}Cr{sub 0.5?x}Al{sub x}O{sub 3??} perovskites

    SciTech Connect (OSTI)

    Azad, Abul K., E-mail: aka7@st-andrews.ac.uk [School of Chemistry, University of St. Andrews, Fife KY16 9ST (United Kingdom); Sanchez-Benitez, Javier [Centre for Science at Extreme Conditions, University of Edinburgh, Erskine Building, Edinburgh EH9 3JZ (United Kingdom); Irvine, John T.S. [School of Chemistry, University of St. Andrews, Fife KY16 9ST (United Kingdom)

    2013-07-15T23:59:59.000Z

    Graphical abstract: In-phase and out-of-phase ac susceptibility measurements at the magnetic field 1000 Oe show the shifting of transition temperature with frequency (i.e. spin–glass transition) in La{sub 0.75}Sr{sub 0.25}Mn{sub 0.5}Cr{sub 0.3}Al{sub 0.2}O{sub 3??}. - Highlights: • Spin–glass transition at low temperature (around 50 K). • Al-doping decreases the antiferromagnetic transition temperature. • Ferromagnetic around room temperature. - Abstract: The structural and magnetic properties of the Al-doped La{sub 0.75}Sr{sub 0.25}Mn{sub 0.5}Cr{sub 0.5?x}Al{sub x}O{sub 3??} (x = 0.0, 0.1, 0.2, 0.3) were investigated by X-ray powder diffraction, neutron powder diffraction and magnetization measurements. Rietveld refinement of the diffraction data confirms that the compounds crystallize in rhombohedral symmetry (space group, R-3C). Unit cell volume decreases with increasing concentration of Al at the B-site. Upon cooling from room temperature, we have observed multiple magnetic phase transitions, i.e. paramagnetic (PM), ferromagnetic (FM), antiferromagnetic (AFM) and spin–glass (SG), in the samples. A low temperature magnetic hysteresis study demonstrates the presence of ferromagnetic domains for all compositions. The antiferromagnetic transition temperature decreases with the Al-doping AC susceptibility measurements at 97 Hz and 1 Oe show SG behaviors with a spin-freezing temperature close to 50 K for all samples. The in-phase ac susceptibility (?{sup /}) decreases in magnitude and spin–glass transition (T{sub SG}) increase toward higher temperature with increasing frequency. The spin–glass behavior accompanied by the anomalous magnetic transitions is due to the competing interactions between FM and AFM. The results also shows that a part of the samples lose magnetic order to form a SG state accompanied by an AFM state at low temperature.

  2. Structure and Electrochemistry of LiNi1/3Co1/3-yMyMn1/3O2 (M=Ti, Al, Fe) Positive Electrode Materials

    SciTech Connect (OSTI)

    Wilcox, James; Patoux, Sebastien; Doeff, Marca

    2009-01-14T23:59:59.000Z

    A series of materials based on the LiNi1/3Co1/3-yMyMn1/3O2 (M = Ti,Al,Fe) system has been synthesized and examined structurally and electrochemically. It is found that the changes in electrochemical performance depend highly on the nature of the substituting atom and its effect on the crystal structure. Substitution with small amounts of Ti4+ (y = 1/12) leads to the formation of a high-capacity and high-rate positive electrode material. Iron substituted materials suffer from an increased antisite defect concentration and exhibit lower capacities and poor rate capabilities. Single-phase materials are found for LiNi1/3Co1/3-yAlyMn1/3O2 when y<_ 1/4 and all exhibit decreased capacities when cycled to 4.3 V. However, an increase in rate performance and cycle stability upon aluminum substitution is correlated with an improved lamellar structure.

  3. Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes

    SciTech Connect (OSTI)

    Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

    2009-05-28T23:59:59.000Z

    Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

  4. Wetting of metals and glasses on Mo

    SciTech Connect (OSTI)

    Saiz, Eduardo; Tomsia, Antoni P.; Saiz, Eduardo; Lopez-Esteban, Sonia; Benhassine, Mehdi; de Coninck, Joel; Rauch, Nicole; Ruehle, Manfred

    2008-01-08T23:59:59.000Z

    The wetting of low melting point metals and Si-Ca-Al-Ti-O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.

  5. Evidence for ? c <mo stretchy="false">(mo> <mn>2mn> S <mo stretchy="false">)mo> in ? <mo stretchy="false">(mo> <mn>3686mn> <mo stretchy="false">)mo> <mo>?> ? K S <mn>0mn> K <mo>±> ? <mo>?> ? <mo>+> ? <mo>?>

    SciTech Connect (OSTI)

    Ablikim, M.; Achasov, M. N.; Albayrak, O.; Ambrose, D. J.; An, F. F.; An, Q.; Bai, J. Z.; Baldini Ferroli, R.; Ban, Y.; Becker, J.; Bennett, J. V.; Bertani, M.; Bian, J. M.; Boger, E.; Bondarenko, O.; Boyko, I.; Briere, R. A.; Bytev, V.; Cai, H.; Cai, X.; Cakir, O.; Calcaterra, A.; Cao, G. F.; Cetin, S. A.; Chang, J. F.; Chelkov, G.; Chen, G.; Chen, H. S.; Chen, J. C.; Chen, M. L.; Chen, S. J.; Chen, X.; Chen, Y. B.; Cheng, H. P.; Chu, Y. P.; Cronin-Hennessy, D.; Dai, H. L.; Dai, J. P.; Dedovich, D.; Deng, Z. Y.; Denig, A.; Denysenko, I.; Destefanis, M.; Ding, W. M.; Ding, Y.; Dong, L. Y.; Dong, M. Y.; Du, S. X.; Fang, J.; Fang, S. S.; Fava, L.; Feng, C. Q.; Friedel, P.; Fu, C. D.; Fu, J. L.; Gao, Y.; Geng, C.; Goetzen, K.; Gong, W. X.; Gradl, W.; Greco, M.; Gu, M. H.; Gu, Y. T.; Guan, Y. H.; Guo, A. Q.; Guo, L. B.; Guo, T.; Guo, Y. P.; Han, Y. L.; Harris, F. A.; He, K. L.; He, M.; He, Z. Y.; Held, T.; Heng, Y. K.; Hou, Z. L.; Hu, C.; Hu, H. M.; Hu, J. F.; Hu, T.; Huang, G. M.; Huang, G. S.; Huang, J. S.; Huang, L.; Huang, X. T.; Huang, Y.; Huang, Y. P.; Hussain, T.; Ji, C. S.; Ji, Q.; Ji, Q. P.; Ji, X. B.; Ji, X. L.; Jiang, L. L.; Jiang, X. S.; Jiao, J. B.; Jiao, Z.; Jin, D. P.; Jin, S.; Jing, F. F.; Kalantar-Nayestanaki, N.; Kavatsyuk, M.; Kopf, B.; Kornicer, M.; Kuehn, W.; Lai, W.; Lange, J. S.; Leyhe, M.; Li, C. H.; Li, Cheng; Li, Cui; Li, D. M.; Li, F.; Li, G.; Li, H. B.; Li, J. C.; Li, K.; Li, Lei; Li, Q. J.; Li, S. L.; Li, W. D.; Li, W. G.; Li, X. L.; Li, X. N.; Li, X. Q.; Li, X. R.; Li, Z. B.; Liang, H.; Liang, Y. F.; Liang, Y. T.; Liao, G. R.; Liao, X. T.; Lin, D.; Liu, B. J.; Liu, C. L.; Liu, C. X.; Liu, F. H.; Liu, Fang; Liu, Feng; Liu, H.; Liu, H. B.; Liu, H. H.; Liu, H. M.; Liu, H. W.; Liu, J. P.; Liu, K.; Liu, K. Y.; Liu, Kai; Liu, P. L.; Liu, Q.; Liu, S. B.; Liu, X.; Liu, Y. B.; Liu, Z. A.; Liu, Zhiqiang; Liu, Zhiqing; Loehner, H.; Lu, G. R.; Lu, H. J.; Lu, J. G.; Lu, Q. W.; Lu, X. R.; Lu, Y. P.; Luo, C. L.; Luo, M. X.; Luo, T.; Luo, X. L.; Lv, M.; Ma, C. L.; Ma, F. C.; Ma, H. L.; Ma, Q. M.; Ma, S.; Ma, T.; Ma, X. Y.; Maas, F. E.; Maggiora, M.; Malik, Q. A.; Mao, Y. J.; Mao, Z. P.; Messchendorp, J. G.; Min, J.; Min, T. J.; Mitchell, R. E.; Mo, X. H.; Morales Morales, C.; Muchnoi, N. Yu.; Muramatsu, H.; Nefedov, Y.; Nicholson, C.; Nikolaev, I. B.; Ning, Z.; Olsen, S. L.; Ouyang, Q.; Pacetti, S.; Park, J. W.; Pelizaeus, M.; Peng, H. P.; Peters, K.; Ping, J. L.; Ping, R. G.; Poling, R.; Prencipe, E.; Qi, M.; Qian, S.; Qiao, C. F.; Qin, L. Q.; Qin, X. S.; Qin, Y.; Qin, Z. H.; Qiu, J. F.; Rashid, K. H.; Rong, G.; Ruan, X. D.; Sarantsev, A.; Schaefer, B. D.; Shao, M.; Shen, C. P.; Shen, X. Y.; Sheng, H. Y.; Shepherd, M. R.; Song, X. Y.; Spataro, S.; Spruck, B.; Sun, D. H.; Sun, G. X.; Sun, J. F.; Sun, S. S.; Sun, Y. J.; Sun, Y. Z.; Sun, Z. J.; Sun, Z. T.; Tang, C. J.; Tang, X.; Tapan, I.; Thorndike, E. H.; Toth, D.; Ullrich, M.; Uman, I. U.; Varner, G. S.; Wang, B. Q.; Wang, D.; Wang, D. Y.; Wang, K.; Wang, L. L.; Wang, L. S.; Wang, M.; Wang, P.; Wang, P. L.; Wang, Q. J.; Wang, S. G.; Wang, X. F.; Wang, X. L.; Wang, Y. D.; Wang, Y. F.; Wang, Y. Q.; Wang, Z.; Wang, Z. G.; Wang, Z. Y.; Wei, D. H.; Wei, J. B.; Weidenkaff, P.; Wen, Q. G.; Wen, S. P.; Werner, M.; Wiedner, U.; Wu, L. H.; Wu, N.; Wu, S. X.; Wu, W.; Wu, Z.; Xia, L. G.; Xia, Y. X.; Xiao, Z. J.; Xie, Y. G.; Xiu, Q. L.; Xu, G. F.; Xu, G. M.; Xu, Q. J.; Xu, Q. N.; Xu, X. P.; Xu, Z. R.; Xue, F.; Xue, Z.; Yan, L.; Yan, W. B.; Yan, Y. H.; Yang, H. X.; Yang, Y.; Yang, Y. X.; Ye, H.; Ye, M.; Ye, M. H.; Yu, B. X.; Yu, C. X.; Yu, H. W.; Yu, J. S.; Yu, S. P.; Yuan, C. Z.; Yuan, Y.; Zafar, A. A.; Zallo, A.; Zeng, Y.; Zhang, B. X.; Zhang, B. Y.; Zhang, C.; Zhang, C. C.; Zhang, D. H.; Zhang, H. H.; Zhang, H. Y.; Zhang, J. Q.; Zhang, J. W.; Zhang, J. Y.; Zhang, J. Z.; Zhang, LiLi; Zhang, R.; Zhang, S. H.; Zhang, X. J.; Zhang, X. Y.; Zhang, Y.; Zhang, Y. H.; Zhang, Z. P.; Zhang, Z. Y.; Zhang, Zhenghao; Zhao, G.; Zhao, H. S.; Zhao, J. W.; Zhao, K. X.; Zhao, Lei; Zhao, Ling; Zhao, M. G.; Zhao, Q.; Zhao, Q. Z.; Zhao, S. J.; Zhao, T. C.; Zhao, X. H.; Zhao, Y. B.; Zhao, Z. G.; Zhemchugov, A.; Zheng, B.; Zheng, J. P.; Zheng, Y. H.; Zhong, B.; Zhong, Z.; Zhou, L.; Zhou, X.; Zhou, X. K.; Zhou, X. R.; Zhu, C.; Zhu, K.; Zhu, K. J.; Zhu, S. H.; Zhu, X. L.; Zhu, Y. C.; Zhu, Y. M.; Zhu, Y. S.; Zhu, Z. A.; Zhuang, J.; Zou, B. S.; Zou, J. H.

    2013-03-01T23:59:59.000Z

    We search for the M1 radiative transition ?(3686)???c(2S) by reconstructing the exclusive ?c(2S)?K?SK±?????? decay using 1.06×10? ?(3686) events collected with the BESIII detector. The signal is observed with a statistical significance of greater than 4 standard deviations. The measured mass of the ?c(2S) is 3646.9±1.6(stat)±3.6(syst) MeV/c², and the width is 9.9±4.8(stat)±2.9(syst) MeV/c². The product branching fraction is measured to be B(?(3686)???c(2S))×B(?c(2S)?K0SK±??????)=(7.03±2.10(stat)±0.70(syst))×10??. This measurement complements a previous BESIII measurement of ?(3686)???c(2S) with ?c(2S)?K?SK±?? and K?K???.

  6. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01T23:59:59.000Z

    Li, A. P. et al. Magnetism in Mn x Ge 1-x semiconductorsElectronic Structure and Magnetism for Mn in Amorphous Sistructure that determines magnetism. Figure 3 shows XAS data

  7. Diffusion Barrier Selection from Refractory Metals (Zr, Mo and Nb) via Interdiffusion Investigation for U-Mo RERTR Fuel Alloy

    SciTech Connect (OSTI)

    K. Huang; C. Kammerer; D. D. Keiser, Jr.; Y. H. Sohn

    2014-04-01T23:59:59.000Z

    U-Mo alloys are being developed as low enrichment monolithic fuel under the Reduced Enrichment for Research and Test Reactor (RERTR) Program. Diffusional interactions between the U-Mo fuel alloy and Al-alloy cladding within the monolithic fuel plate construct necessitate incorporation of a barrier layer. Fundamentally, a diffusion barrier candidate must have good thermal conductivity, high melting point, minimal metallurgical interaction, and good irradiation performance. Refractory metals, Zr, Mo, and Nb are considered based on their physical properties, and the diffusion behavior must be carefully examined first with U-Mo fuel alloy. Solid-to-solid U-10wt.%Mo vs. Mo, Zr, or Nb diffusion couples were assembled and annealed at 600, 700, 800, 900 and 1000 degrees C for various times. The interdiffusion microstructures and chemical composition were examined via scanning electron microscopy and electron probe microanalysis, respectively. For all three systems, the growth rate of interdiffusion zone were calculated at 1000, 900 and 800 degrees C under the assumption of parabolic growth, and calculated for lower temperature of 700, 600 and 500 degrees C according to Arrhenius relationship. The growth rate was determined to be about 10 3 times slower for Zr, 10 5 times slower for Mo and 10 6 times slower for Nb, than the growth rates reported for the interaction between the U-Mo fuel alloy and pure Al or Al-Si cladding alloys. Zr, however was selected as the barrier metal due to a concern for thermo- mechanical behavior of UMo/Nb interface observed from diffusion couples, and for ductile-to-brittle transition of Mo near room temperature.

  8. An APFIM and TEM study of Ni{sub 4}Mo precipitation in a commercial Ni-28% Mo-1.4% Fe-0.4% Cr wt. % alloy

    SciTech Connect (OSTI)

    Thomson, R.C.; Brown, N.; Bates, J.S. [Loughborough Univ. (United Kingdom). Inst. of Polymer Technology and Materials Engineering; Russell, K.F.; Miller, M.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-02-01T23:59:59.000Z

    Ni-Mo alloys containing at least 26 wt.% Mo have a negligible corrosion rate in boiling 10% hydrochloric acid and are therefore used in corrosive environments. A series of commercial Ni-Mo alloys has been developed with subtle variations in chemical composition. These alloys usually contain {approximately} 28 wt.% Mo with additions of up to 5% Fe and Cr. A significant amount of research has been performed to understand the microstructure and properties of these alloys, although most of the effort has concentrated on the Ni-Mo binary system. In some alloys with low Fe and Cr contents, a severe embrittlement problem has been observed due to the formation of the Ni{sub 4}Mo (D1{sub a}-ordered) phase within the microstructure. This research focuses on a commercial alloy with nominal composition Ni-28% Mo-1.4% Fe-0.4% Cr-0.1% Mn-0.003 wt.% C. The material supplied was a heat treatment coupon which had been attached to a large vessel during fabrication. Assessment of the chemical analysis of the alloy suggested that detrimental phases could be present or might appear during subsequent repair work. Therefore, it was important to assess the microstructural condition of the vessel, and in particular the kinetics of precipitation of Ni{sub 4}Mo.

  9. Ab initio defect energetics of perovskite (001) surfaces for solid oxide fuel cells: A comparative study of LaMnO[subscript 3] versus SrTiO[subscript 3] and LaAlO[subscript 3

    E-Print Network [OSTI]

    Lee, Yueh-Lin

    In this paper, we perform a comparative study based on ab initio modeling for perovskite ABO[subscript 3] (001) surfaces and surface defect energetics in order to understand the influence of polarity and redox active Mn ...

  10. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01T23:59:59.000Z

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 µm thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500°C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500°C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500°C.

  11. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Ethanol Conversion on Cyclic (MO3)3 (M Mo, W) Clusters. Abstract: Oxides of molybdenum and tungsten are an important class of...

  12. Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas E.

    2013-01-01T23:59:59.000Z

    materials for Li-ion batteries Thomas E. Conry, a,b Apurvamaterials in Li-ion batteries. Synchrotron-based high-materials for Li-ion batteries. LiNi z Mn z Co 1-2z O 2 (NMC

  13. Letter Report Documenting Progress of Second Generation ATF FeCrAl Alloy Fabrication

    SciTech Connect (OSTI)

    Yamamoto,, Y. [ORNL] [ORNL; Yang, Y. [ORNL] [ORNL; Field, K. G. [ORNL] [ORNL; Terrani, K. [ORNL] [ORNL; Pint, B. A. [ORNL] [ORNL; Snead, L. L. [ORNL] [ORNL

    2014-06-10T23:59:59.000Z

    Development of the 2nd generation ATF FeCrAl alloy has been initiated, and a candidate alloy was selected for trial tube fabrication through hot-extrusion and gun-drilling processes. Four alloys based on Fe-13Cr-4.5Al-0.15Y in weight percent were newly cast with minor alloying additions of Mo, Si, Nb, and C to promote solid-solution and second-phase precipitate strengthening. The alloy compositions were selected with guidance from computational thermodynamic tools. The lab-scale heats of ~ 600g were arc-melted and drop-cast, homogenized, hot-forged and -rolled, and then annealed producing plate shape samples. An alloy with Mo and Nb additions (C35MN) processed at 800°C exhibits very fine sub-grain structure with the sub-grain size of 1-3?m which exhibited more than 25% better yield and tensile strengths together with decent ductility compared to the other FeCrAl alloys at room temperature. It was found that the Nb addition was key to improving thermal stability of the fine sub-grain structure. Optimally, grains of less than 30 microns are desired, with grains up to and order of magnitude in desired produced through Nb addition. Scale-up effort of the C35MN alloy was made in collaboration with a commercial cast company who has a capability of vacuum induction melting. A 39lb columnar ingot with ~81mm diameter and ~305mm height (with hot-top) was commercially cast, homogenized, hot-extruded, and annealed providing 10mm-diameter bar-shape samples with the fine sub-grain structure. This commercial heat proved consistent with materials produced at ORNL at the lab-scale. Tubes and end caps were machined from the bar sample and provided to another work package for the ATF-1 irradiation campaign in the milestone M3FT-14OR0202251.

  14. The resistance to cavitation erosion of CrMnN stainless steels

    SciTech Connect (OSTI)

    Fu, W.T. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Harbin Inst. of Tech. (China); Jing, T.F.; Zheng, Y.Z. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; Yang, Y.B. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Bohai Aluminum Industries Co., Ltd., Qinhuangdao (China); Yao, M. [Harbin Inst. of Tech. (China)] [Harbin Inst. of Tech. (China)

    1998-12-01T23:59:59.000Z

    The resistance to cavitation erosion (CE) was measured using a magnetostrictive device and a rotating disk device for some CrMnN stainless steels (Chinese patent ZL 90 1 02197.0). The microstructural changes in the surface layer before and after CE were analyzed by use of Mossbauer spectra. Results show that the resistance to CE of duplex austenitic-martensitic CrMnN stainless steels is much better than that of ZG0Cr13Ni4-6Mo and ZG0Cr16Ni5Mo steel, which are in common use for hydraulic turbine runners. The metastable austenite and its changes in the process of CE are the key factors why the CrMnN stainless steels have excellent resistance to cavitation erosion.

  15. Pseudo-elastic deformation behavior in a Ti/Mo-based alloy , M. Aindow a,*, S.P. Alpay a

    E-Print Network [OSTI]

    Alpay, S. Pamir

    , and are increasingly finding applications in aerospace, oil well systems and automotive parts [1]. Alloys in the metaPseudo-elastic deformation behavior in a Ti/Mo-based alloy T. Zhou a , M. Aindow a,*, S.P. Alpay 2003 Abstract It is shown that the pseudo-elastic response in a series of Ti­Mo­V­Nb­Al alloys with 8

  16. Bulk modulus and specific heat of B-site doped (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B=Fe, Cr, Ru, Al, Ga)

    SciTech Connect (OSTI)

    Srivastava, Archana, E-mail: archanasaran01@gmail.com [Department of Physics, Sri Sathya Sai College for Women, Bhopal-462024 (India); Thakur, Rasna; Gaur, N. K. [Department of Physics, Barkatullah University, Bhopal-462026 (India)

    2014-04-24T23:59:59.000Z

    Specific heat (C{sub p}) thermal expansion (?) and Bulk modulus (B{sub T}) of lightly doped Rare Earth manganites (La{sub 0.3}Pr{sub 0.7}){sub 0.65}Ca{sub 0.35}Mn{sub 1?x}B{sub x}O{sub 3} (B{sup 3+}?=?Fe{sup 3+},Cr{sup 3+},Ga{sup 3+},Al{sup 3+},Ru4+); (0.3Mn{sub 0.97}Fe{sub 0.03}O{sub 3} as a function of temperature (10K?T? 200K) is found to be in agreement with the published data. The trend of variation of Debye temperature with B-site cationic radius is predicted probably for the first time for the B-site doped rare earth manganites.

  17. A novel organic–inorganic hybrid with Anderson type polyanions as building blocks: (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]·6H{sub 2}O

    SciTech Connect (OSTI)

    Thabet, Safa, E-mail: safathabet@hotmail.fr [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia)] [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia); Ayed, Brahim, E-mail: brahimayed@yahoo.fr [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia)] [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia); Haddad, Amor [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia)] [Laboratoire de matériaux et cristallochimie, Département de chimie, Institut Supérieur des Sciences Appliquées et Technologier, Avenue El Mourouj, 5111 Mahdia (Tunisia)

    2012-11-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Synthesis of a novel inorganic–organic hybrid compound based on Anderson polyoxomolybdates. ? Characterization by X-ray diffraction, IR and UV–Vis spectroscopies of the new compound. ? Potential applications in catalysis, biochemical analysis and electrical conductivity of the organic–inorganic compound. -- Abstract: A new organic–inorganic hybrid compound based on Anderson polyoxomolybdates, (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]·6H{sub 2}O (1) have been isolated by the conventional solution method and characterized by single-crystal X-ray diffraction, infrared, ultraviolet spectroscopy and Thermogravimetric Analysis (TGA). This compound crystallized in the triclinic system, space group P?1, with a = 94.635(1) ?, b = 10.958(1) ?, c = 11.602(1) ?, ? = 67.525(1)°, ? = 71.049(1)°, ? = 70.124(1)° and Z = 1. The crystal structures of the compounds exhibit three-dimensional supramolecular assembly based on the extensive hydrogen bonding interactions between organic cations, sodium cations, water molecules and Anderson polyoxoanions. The infrared spectrum fully confirms the X-ray crystal structure and the UV spectrum of the title compound exhibits an absorption peak at 210 nm.

  18. al-2 o-3 surfaces: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MoO3, ZrMo2O8, and Al2(MoO4)3 suggests that the behavior Iglesia, Enrique 151 European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 2AO.1.4...

  19. Electrodeposition of high Mo content Ni-Mo alloys under forced convection

    SciTech Connect (OSTI)

    Podlaha, E.J.; Matlosz, M.; Landolt, D. (Ecole Polytechnique Federale de Lausanne, Lausanee (Switzerland). Dept. des materiaux)

    1993-10-01T23:59:59.000Z

    Bright, compact, adherent, metallic Ni-Mo alloys, containing over 48 wt % Mo have been electrodeposited from an aqueous solution. The Mo content, which is the highest achieved so far in induced codeposition of Ni-Mo, was determined by X-ray fluorescence spectroscopy. The absence of oxygen was verified by Auger electron spectroscopy. Electrodeposition experiments were performed on rotating cylinder electrodes and demonstrate that the Mo content of the alloy is strongly influenced by convective transport.

  20. Enhanced absorption of monolayer MoS{sub 2} with resonant back reflector

    SciTech Connect (OSTI)

    Liu, Jiang-Tao, E-mail: jtliu@semi.ac.cn; Liu, Nian-Hua [Nanoscale Science and Technology Laboratory, Institute for Advanced Study, Nanchang University, Nanchang 330031 (China); Department of Physics, Nanchang University, Nanchang 330031 (China); Wang, Tong-Biao [Department of Physics, Nanchang University, Nanchang 330031 (China); Li, Xiao-Jing [College of Physics and Energy, Fujian Normal University, Fuzhou 350007 (China)

    2014-05-21T23:59:59.000Z

    The optical absorption of monolayer MoS{sub 2} on top of one-dimensional photonic crystal (1DPC) or metal films with spacer layers is theoretically investigated by extracting the permittivity of monolayer MoS{sub 2} from existing experimental results [K. F. Mak et al., Phys. Rev. Lett. 105, 136805 (2010)]. The absorption of graphene with 1DPC across a broad spectral range is substantially enhanced because of the photonic localization at the optical micro-cavity on top of the 1DPC or metal films. The absorption of monolayer MoS{sub 2} can be tuned by varying either the distance between the monolayer MoS{sub 2} and the back reflector or the thickness of the cover layers.

  1. US WNC MO Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalThe Outlook269,023Year69,023USWNC MO Site

  2. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01T23:59:59.000Z

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  3. alvos contendo mo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed. Annenkov, A N;...

  4. TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun?

    E-Print Network [OSTI]

    Singer, Andrew C

    TURBO EQUALIZATIONWITH AN UNKNOWN CHANNEL SeongwookSong', Andrew C. Singer2,Koeng-MoSun? l t 2Univ the method of turbo equalization originally de- veloped by Douillard, et al. [3]. In its original form, turbo and without training data. The resultingjoint channeland data estimator is shown to outperform standard turbo

  5. Diffusional Interactions between U-Mo and Zr at 650°C as a Function of Time

    SciTech Connect (OSTI)

    Y. Park; Y. H. Sohn; D. D. Keiser, Jr.

    2015-01-01T23:59:59.000Z

    Development of monolithic U-Mo alloy fuel (typically U-10wt.%Mo) for the Reduced Enrichment for Research and Test Reactors (RERTR) program requires a use of Zr diffusion barrier to eliminate the diffusional interaction between the fuel alloy and Al-alloy cladding. The application of Zr barrier to the U-Mo fuel requires co-rolling process that utilizes a soaking temperature of 650°C, which represents the highest temperature the fuel system is exposed to during both fuel manufacturing and reactor application. Therefore, in this study, development of phase constituents, microstructure and diffusion kinetics of U-10wt.%Mo and Zr was examined using solid-to-solid diffusion couples annealed at 650°C for 240, 480 and 720 hours. Diffusional interactions were analyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Within the diffusion zone, a single-phase layer of ß-Zr was observed along with a discontinuous layer of Mo2Zr at the interface between the terminal ?-U(Mo) alloy and ß-Zr. In the vicinity of Mo2Zr phase, islands of ß-U and a-Zr phases were also found. In addition, accicular a-Zr phases were observed within the ?-U(Mo). Growth rate of this diffuaional interaction layer was determined to be 8.76 x 10-15 m2/sec, however with an assumption of certain incubation period. Consistency in these observation along with concentration profiles and diffusion paths are presented and discussed with respect to the diffusion couple that was furnace-cooled, annealed at 700°C in our previous study, and isothermal ternary phase diagram at 700°C.

  6. Electronic structure of the molecule-based magnet MnN,,CN...22 from theory and experiment

    E-Print Network [OSTI]

    Liu, Amy Y.

    of SmCo5 and Nd2Fe14B2.2 For Mn N(CN)2 2, Kurmoo et al.2 report that the structure be- haves as a canted

  7. MoS2 Nanoribbons Thermoelectric Generators

    E-Print Network [OSTI]

    Arab, Abbas

    2015-01-01T23:59:59.000Z

    In this work, we have designed and simulated new thermoelectric generator based on monolayer and few-layer MoS2 nanoribbons. The proposed thermoelectric generator is composed of thermocouples made of both n-type and p-type MoS2 nanoribbon legs. Density Functional Tight-Binding Non-Equilibrium Green's Function (DFTB-NEGF) method has been used to calculate the transmission spectrum of MoS2 armchair and zigzag nanoribbons. Phonon transmission spectrum are calculated based on parameterization of Stillinger-Weber potential. Thermoelectric figure of merit, ZT, is calculated using these electronic and phonon transmission spectrum. Monolayer and bilayer MoS2 armchair nanoribbons are found to have the highest ZT value for p-type and n-type legs, repectively. Moreover, we have compared the thermoelectric current of doped monolayer MoS2 armchair nanoribbons and SZi thin films. Results indicate that thermoelectric current of MoS2 monolayer nanoribbons is several orders of magnitude higher than that of Si thin films.

  8. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01T23:59:59.000Z

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  9. al fe mn: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    magnetic properties of both high magnetization and large magnetocrystalline anisotropy energy, and (more) Geng, Yunlong 2014-01-01 3 Partial pair distribution functions in...

  10. Highly Active Yeast MnSOD has a Novel Mechanism Involving Six-coordinate Mn(3+) Species

    E-Print Network [OSTI]

    Sheng, Yuewei

    2012-01-01T23:59:59.000Z

    2009) Functional roles of the tetramer organization of malicGrez, M. (2010) Dimer-tetramer transition controls RUNX1/ETOdimer, Å) Mn•••Mn (A/C, tetramer, Å) Mn•••Mn (A/D, tetramer,

  11. Structure and magnetic properties of rf thermally plasma synthesized Mn and MnZn ferrite nanoparticles

    E-Print Network [OSTI]

    McHenry, Michael E.

    Structure and magnetic properties of rf thermally plasma synthesized Mn and Mn­Zn ferrite has previously been shown to be a viable route to producing nanocrystalline magnetite and Ni ferrite nanoparticles. In this work nanocrystalline powders of Mn and Mn­Zn ferrites have been synthesized using a 50 k

  12. Electronic states and cyclotron resonance in n-type InMnAs G. D. Sanders, Y. Sun, F. V. Kyrychenko, and C. J. Stanton

    E-Print Network [OSTI]

    Kono, Junichiro

    and their heterostructures with AlGaSb, the first grown III-V magnetic semiconductor,1,5,6 serve as a prototype s : 75.50.Pp, 78.20.Ls, 78.40.Fy I. INTRODUCTION Recently, there has been much interest in III-V magnetic semiconductors such as InMnAs Ref. 1 and GaMnAs Ref. 2 . The ferromagnetic exchange coupling between Mn ions

  13. Interaction Layer Characteristics in U-xMo Dispersion/Monolithic Fuels

    SciTech Connect (OSTI)

    D. L. Porter

    2010-11-01T23:59:59.000Z

    Published data concerning the interaction layer (IL) formed between U-xMo fuel alloy and aluminum (Al)-based matrix or cladding materials was reviewed, including the effects of silicon (Si) content in the matrix/cladding, molybdenum (Mo) content in the fuel, pre irradiation thermal treatments, irradiation, and test temperature. The review revealed that tests conducted in the laboratory produce results different from those conducted in an irradiation environment. However, the laboratory testing relates well to thermal treatments performed prior to irradiation and helps in understanding the effects that these pre irradiation treatments have on in reactor performance. A pre-formed, Si-enriched IL seems to be important in delaying the onset of rapid growth of fission gas bubbles at low irradaiiation temperatures. Several other conclusions can be drawn: 1. An IL with phases akin to UAl3 is desired for optimum fuel performance, but at low temperatures, and especially in an irradiation atmosphere, the desired (Al+Si)/(U+Mo) ratio of three is difficult to produce. When the fuel operating temperature is low, it is important to create a pre-irradiation IL, enriched in Si. This pre-formed IL is relatively stable, performs well in terms of swelling resistance, and prevents rapid IL growth during irradiation. 2. At higher operating temperatures (>150–170°C), IL formation in reactor may not be so dependent on pre-irradiation IL formation, especially at high burnup; a pre-fabricated IL seems to be less stable at high burnup and high operating temperature. Moreover, the (Al+SI)/(U+Mo) ratio of three occurs more often at higher temperature. For these two reasons, it is important at high operating temperature to also have a matrix with significant Si content to create an IL in reactor with the right characteristics. 3. Out-of-reactor testing seems to indicate that Si in the matrix material is required in some concentration (2%, 5%, ?) to provide for a thin, Si-enriched IL formed before irradiation of a fuel plate. It ensures that the IL contains beneficial phases, or prevents formation of some known to promote poor fuel performance. Significant progress has been made in determining the desired characteristics of the IL. 4. The use of a fuel with stable gamma phase appears to allow more predictable performance regarding both a beneficial pre-irradiation layer, and the fuel performance (low swelling) to high burnup. Destabilization of the gamma phase may create problems with IL breakaway growth. 5. A theory whereby prevention of the U6Mo4Al43 complex phase in interaction layers formed during fabrication may be a key to good irradiation performance. Si additions to the matrix allow for solubility of Mo in the desirable (U,Mo)(Al,Si)3 or perhaps (U,Mo)(Al,Si)4 phase, helping to prevent formation of the complex phase. Keeping alloy Mo content as low as possible may also help so long as decomposition does not occur in fabrication, forcing Mo into the interaction layer. This theory may explain a number of apparent anomalies observed in testing results. 6. More work is needed in order to prescribe the conditions to best produce a beneficial IL. Another necessity is a better understanding of any correlation between beneficial characteristics of the pre-fabricated IL and the irradiation conditions to which it will be subjected.

  14. Prompt {gamma}-ray spectroscopy of the {sup 104}Mo and {sup 108}Mo fission fragments

    SciTech Connect (OSTI)

    Guessous, A.; Schulz, N.; Bentaleb, M.; Lubkiewicz, E. [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France)] [Centre de Recherches Nucleaires, Institut National de Physique Nucleaire et de Physique des Particules, Centre National de la Recherche Scientifique, Universite Louis Pasteur, 67037 Strasbourg (France); Durell, J.L.; Pearson, C.J.; Phillips, W.R.; Shannon, J.A.; Urban, W.; Varley, B.J. [Department of Physics, University of Manchester, M13 9PL (United Kingdom)] [Department of Physics, University of Manchester, M13 9PL (United Kingdom); Ahmad, I.; Lister, C.J.; Morss, L.R.; Nash, K.L.; Williams, C.W. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Argonne National Laboratory, Argonne, Illinois 60439 (United States); Khazrouni, S. [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)] [Laboratoire de Physique Nucleaire Appliquee, Faculte des Sciences, Kenitra, Maroc (France)

    1996-03-01T23:59:59.000Z

    The level structures of the neutron-rich {sup 104}Mo and {sup 108}Mo nuclei have been investigated by observing prompt {gamma} rays emitted in the spontaneous fission of {sup 248}Cm with the EUROGAM spectrometer. Levels with spins up to 12{h_bar} have been observed and {gamma} branching obtained. The data can be satisfactorily described when {sup 104,108}Mo are considered as axially symmetric nuclei: in {sup 104}Mo, rotational bands based on the ground state, the one-phonon and the two-phonon {gamma}-vibrational states and a quasiparticle state have been observed, whereas in {sup 108}Mo the information is limited to the yrast band and the one phonon {gamma} band. {copyright} {ital 1996 The American Physical Society.}

  15. Tunable MoS{sub 2} bandgap in MoS{sub 2}-graphene heterostructures

    SciTech Connect (OSTI)

    Ebnonnasir, Abbas [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States); Narayanan, Badri; Ciobanu, Cristian V., E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Kodambaka, Suneel, E-mail: cciobanu@mines.edu, E-mail: kodambaka@ucla.edu [Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States)

    2014-07-21T23:59:59.000Z

    Using density functional theory calculations with van der Waals corrections, we investigated how the interlayer orientation affects the structure and electronic properties of MoS{sub 2}-graphene bilayer heterostructures. Changing the orientation of graphene with respect to MoS{sub 2} strongly influences the type and the value of the electronic bandgap in MoS{sub 2}, while not significantly altering the binding energy between the layers or the interlayer spacing. We show that the physical origin of this tunable bandgap arises from variations in the S–S interplanar distance (MoS{sub 2} thickness) with the interlayer orientation, variations which are caused by electron transfer away from the Mo–S bonds.

  16. CHEN ET AL. VOL. XXX ' NO. XX ' 000000 ' XXXX www.acsnano.org

    E-Print Network [OSTI]

    Zhou, Chongwu

    beyond graphene have at- tracted huge amounts of attention especially for those transition metal dichal graphene coupled by weak van der Waals forces between adja- cent layers. But more than that, each TMDC and Kalantar-zadeh et al. have shown the preparation of thin MoS2 flakes by evaporation of sulfur and MoO3

  17. Comparative Study on the Corrosion Resistance of Fe-Based Amorphous Metal, Borated Stainless Steel and Ni-Cr-Mo-Gd Alloy

    SciTech Connect (OSTI)

    Lian, Tiangan; Day, Daniel; Hailey, Phillip; Choi, Jor-Shan; Farmer, Joseph [Lawrence Livermore National Laboratory, Livermore, CA, 94550 (United States)

    2007-07-01T23:59:59.000Z

    Iron-based amorphous alloy Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} was compared to borated stainless steel and Ni-Cr-Mo-Gd alloy on their corrosion resistance in various high-concentration chloride solutions. The melt-spun ribbon of this iron-based amorphous alloy have demonstrated a better corrosion resistance than the bulk borated stainless steel and the bulk Ni-Cr-Mo-Gd alloy, in high-concentration chloride brines at temperatures 90 deg. C or higher. (authors)

  18. Elevated Temperature Tensile Tests on DU–10Mo Rolled Foils

    SciTech Connect (OSTI)

    Jason Schulthess

    2014-09-01T23:59:59.000Z

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U–10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU–10Mo) mechanical behavior is representative of the low enriched U–10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  19. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02T23:59:59.000Z

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  20. Effect of Mn Concentration on the Structural, optical and Magnetic Properties of GaMnN

    SciTech Connect (OSTI)

    Thaler, G.; Frazier, R.; Gila, B.; Stapleton, J.; Davidson, M.; Abernathy, C.R.; Pearton, S.J.; Segre, C.U. (IIT); (Florida)

    2010-11-16T23:59:59.000Z

    The room temperature magnetization of GaMnN films grown by molecular beam epitaxy on (0001) sapphire substrates with Mn concentrations varying from 0 to 9 at. % was found to depend on Mn concentration, with a maximum magnetization found at -3 at. % Mn. High-resolution x-ray diffraction measurements show that the c-plane lattice constant initially decreases with increasing Mn concentration, then increases when the Mn content increases above -3 at. %. This increase is accompanied by a decrease in the full width at half maximum of the rocking curves. Extended x-ray absorption fine structure results indicate that the nonsubstitutional Mn is not present in the form of Ga{sub x}Mn{sub y} clusters and thus is most likely present in the form of an interstitial. Optical absorption measurements show only a slight increase in the band gap for material with 3 at. % Mn, relative to undoped GaN.

  1. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01T23:59:59.000Z

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot “co-rolling” process is employed to establish a ~25-µm-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  2. Effect of disorder on the magnetic properties of cubic Mn{sub 2}Ru{sub x}Ga compounds: A first-principles study

    SciTech Connect (OSTI)

    Galanakis, I., E-mail: galanakis@upatras.gr [Department of Materials Science, School of Natural Sciences, University of Patras, GR-26504 Patra (Greece); Özdo?an, K., E-mail: kozdogan@yildiz.edu.tr [Department of Physics, Yildiz Technical University, 34210 ?stanbul (Turkey); ?a??o?lu, E., E-mail: e.sasioglu@fz-juelich.de; Blügel, S. [Peter Grünberg Institut and Institute for Advanced Simulation, Forschungszentrum Jülich and JARA, 52425 Jülich (Germany)

    2014-07-21T23:59:59.000Z

    We perform first-principles electronic structure calculations to explain the anomalous magnetic behavior of the Mn{sub 2}Ru{sub x}Ga compounds upon Ru doping as shown experimentally recently by Kurt et al. [Phys. Rev. Lett. 112, 027201 (2014)]. Our results suggest that disorder caused by the distribution of the Mn and Ru atoms at various sites reproduces the experimental data. All compounds present antiparallel alignment of the neighboring Mn magnetic moments and, with the exception of Mn{sub 2}RuGa, none of them presents half metallic behavior.

  3. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect (OSTI)

    Liu, Hao; Gao, G. Y., E-mail: guoying-gao@mail.hust.edu.cn; Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L. [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-01-21T23:59:59.000Z

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52?eV and the magnetic moment of 1.00??{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  4. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

    1987-01-01T23:59:59.000Z

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  5. High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel

    DOE Patents [OSTI]

    Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Oak Ridge, TN) [Oak Ridge, TN

    2010-07-13T23:59:59.000Z

    An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.

  6. Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney

    E-Print Network [OSTI]

    Nagurney, Anna

    The 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney Department of Electrical November 13, 2012 #12;Nuclear Medicine: Meeting Patient Needs with 99 Mo Ladimer S. Nagurney The 99 Mo Supply Chain #12;Background and Motivation Study of Nuclear Medicine Supply Chains is a combination

  7. Behavior of vortices near twin boundaries in underdoped Ba(Fe <mn>1mn> <mo>?> x Co x <mo stretchy="false">)mo> <mn>2mn> As <mn>2mn>

    SciTech Connect (OSTI)

    Kalisky, B.; Kirtley, J. R.; Analytis, J. G.; Chu, J.-H.; Fisher, I. R.; Moler, K. A.

    2011-02-01T23:59:59.000Z

    We use scanning superconducting quantum interference device (SQUID) microscopy to investigate the behavior of vortices in the presence of twin boundaries in the pnictide superconductor Ba(Fe1-xCox)?As?. We show that the vortices avoid pinning on twin boundaries. Individual vortices move in a preferential way when manipulated with the SQUID: They tend to not cross a twin boundary, but rather to move parallel to it. This behavior can be explained by the observation of enhanced superfluid density on twin boundaries in Ba(Fe1-xCox)?As?. The observed repulsion from twin boundaries may be a mechanism for enhanced critical currents observed in twinned samples in pnictides and other superconductors.

  8. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H. [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland); Karppinen, M., E-mail: maarit.karppinen@aalto.f [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland)

    2011-05-15T23:59:59.000Z

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  9. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    SciTech Connect (OSTI)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01T23:59:59.000Z

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  10. Development of CaMoO4 crystal scintillators for double beta decay experiment with 100-Mo

    E-Print Network [OSTI]

    A. N. Annenkov; O. A. Buzanov; F. A. Danevich; A. Sh. Georgadze; S. K. Kim; H. J. Kim; Y. D. Kim; V. V. Kobychev; V. N. Kornoukhov; M. Korzhik; J. I. Lee; O. Missevitch; V. M. Mokina; S. S. Nagorny; A. S. Nikolaiko; D. V. Poda; R. B. Podviyanuk; D. J. Sedlak; O. G. Shkulkova; J. H. So; I. M. Solsky; V. I. Tretyak; S. S. Yurchenko

    2007-07-10T23:59:59.000Z

    Energy resolution, alpha/beta ratio, pulse-shape discrimination for gamma rays and alpha particles, temperature dependence of scintillation properties, and radioactive contamination were studied with CaMoO4 crystal scintillators. A high sensitivity experiment to search for neutrinoless double beta decay of 100-Mo by using CaMoO4 scintillators is discussed.

  11. Thermal Stability of MnBi Magnetic Materials. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    because Mn is easy to react with oxygen. MnO formation is irreversible and causes degradation to the magnetic properties. In this paper, we report our effort on developing MnBi...

  12. Re Effects on Phase Stability and Mechanical Properties of MoSS+Mo3Si+Mo5SiB2 alloys

    SciTech Connect (OSTI)

    Yang, Ying [ORNL; Bei, Hongbin [ORNL; George, Easo P [ORNL; Tiley, Jaimie [Air Force Research Laboratory, Wright-Patterson AFB, OH

    2013-01-01T23:59:59.000Z

    Because of their high melting points and good oxidation resistance Mo-Si-B alloys are of interest as potential ultrahigh-temperature structural materials. But their major drawbacks are poor ductility and fracture toughness at room temperature. Since alloying with Re has been suggested as a possible solution, we investigate here the effects of Re additions on the microstructure and mechanical properties of a ternary alloy with the composition Mo-12.5Si-8.5B (at.%). This alloy has a three-phase microstructure consisting of Mo solid-solution (MoSS), Mo3Si, and Mo5SiB2 and our results show that up to 8.4 at.% Re can be added to it without changing its microstructure or forming any brittle phase at 1600 C. Three-point bend tests using chevron-notched specimens showed that Re did not improve fracture toughness of the three-phase alloy. Nanoindentation performed on the MoSS phase in the three-phase alloy showed that Re increases Young s modulus, but does not lower hardness as in some Mo solid solution alloys. Based on our thermodynamic calculations and microstructural analyses, the lack of a Re softening effect is attributed to the increased Si levels in the Re-containing MoSS phase since Si is known to increase its hardness. This lack of softening is possibly why there is no Re-induced improvement in fracture toughness.

  13. Microstructural analysis of a single pass 2.25% Cr-1.0% Mo steel weld metal with different manganese contents

    SciTech Connect (OSTI)

    Guimares de Souza, Luis Felipe [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET-RJ), Av. Maracana, 229, Rio de Janeiro, RJ, 20271-110 (Brazil); Souza Bott, Ivani de [Pontificia Universidade Catolica (PUC-RIO), R. Marques de SaoVicente, 225, Rio de Janeiro, RJ, 22453-900 (Brazil); Ferreira Jorge, Jorge Carlos [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET-RJ), Av. Maracana, 229, Rio de Janeiro, RJ, 20271-110 (Brazil); Sauer Guimaraes, Ari [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), Caixa Postal 68.505, Cidade Universitaria, Ilha do Fundao, RJ, 21945-970 (Brazil); Pinheiro Rocha Paranhos, Ronaldo [Universidade Estadual do Norte Fluminense (UENF), Av. Alberto Lamego, 2000, Campos, RJ, 28013-602 (Brazil)]. E-mail: paranhos@uenf.br

    2005-07-15T23:59:59.000Z

    Weld metals of the 2.25% Cr-1.0% Mo type with 0.84%, 1.21% and 2.3% Mn produced by submerged-arc welding were analyzed in the as-welded (AW), post weld heat treatment (PWHT) and PWHT followed by step-cooling (SC) heat treatment conditions. Fracture surface analysis revealed an evolution in the mode of fracture due to Mn content variations and heat treatment conditions, the occurrence of intergranular fracture being observed in welds with 2.30% Mn that were step-cooled. Transmission electron microscopy revealed that the microstructure was predominantly composed of bainite, although martensite was also observed for high Mn contents. A marked carbide precipitation was observed, preferentially at grain boundaries. This could be attributed to the SC heat treatment and associated with the embrittlement. However, the application of a de-embrittlement heat treatment to this step cooled weld metal has proved efficient, because the impact energy levels after this heat treatment surpassed those obtained in the stress relieved condition. This indicates that segregation of impurities to grain boundaries was responsible for the low impact energy levels observed after SC of weld metal containing > 0.84% Mn.

  14. Effect of Mn doping on the structural, morphological, optical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mn doping on the structural, morphological, optical and magnetic properties of indium tin oxide films. Effect of Mn doping on the structural, morphological, optical and magnetic...

  15. First-principles study of site occupancy of 3d, 4d and 5d transition-metal elements in L10TiAl

    SciTech Connect (OSTI)

    Jiang, Chao [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Using a statistical-mechanical Wagner-Schottky model parametrized by first-principles density-functional (DFT-GGA) calculations on 32-atom supercells, we predict the lattice site occupancy of 3d (Ti-Cu), 4d (Zr-Ag) and 5d (Hf-Au) transition-metal elements in L10 TiAl intermetallic compound as a function of both alloy composition and temperature. The effects of local atomic relaxations, anisotropic lattice distortions, as well as magnetism on point defect energetics are fully taken into account. Our calculations show that, at all alloy compositions and temperatures, Zr and Hf consistently show a preference for the Ti sublattice, while Co, Ru, Rh, Pd, Ag, Re, Os, Ir, Pt and Au consistently show a preference for the Al sublattice. In contrast, the site preference of V, Cr, Mn, Fe, Ni, Cu, Nb, Mo, Tc, Ta and W strongly depend on both alloy stoichiometry and temperature. Our calculated results compare favorably with the existing theoretical and experimental studies in the literature.

  16. Photoluminescence properties of Tb-Eu-Mn-codoped fluoroborate glasses under ?-irradiation

    SciTech Connect (OSTI)

    Hari Babu, B.; Ravi Kanth Kumar, V. V. [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)] [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)

    2013-09-28T23:59:59.000Z

    We report here an energy transfer from Tb{sup 3+} to Eu{sup 3+}, Mn{sup 2+} and Eu{sup 2+} to Tb{sup 3+} and Mn{sup 2+} for an un-irradiated and ?-irradiated B{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-Na{sub 2}O-SrF{sub 2} glass samples, respectively. The blue emission from Eu{sup 2+} ions as well as green and red emission from Tb{sup 3+}, Eu{sup 3+}, and Mn{sup 2+} ions will contribute to the generation of white light while excited at 339 nm using a xenon lamp. Furthermore, the chromaticity color coordinates, correlated color temperature, and quantum efficiency parameters are calculated for all the glass samples, and their relative variations with respect to ?-irradiation dose are presented.

  17. Upcoming Management and Operating (M&O) Contract Competition...

    National Nuclear Security Administration (NNSA)

    Upcoming Management and Operating (M&O) Contract Competition | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile...

  18. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

    2001-01-01T23:59:59.000Z

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  19. Novel Solar Energy Conversion Materials by Design of Mn(II) Oxides

    SciTech Connect (OSTI)

    Lany, S.; Peng, H.; Ndione, P.; Zakutayev, A.; Ginley, D. S.

    2013-01-01T23:59:59.000Z

    Solar energy conversion materials need to fulfill simultaneously a number of requirements in regard of their band-structure, optical properties, carrier transport, and doping. Despite their desirable chemical properties, e.g., for photo-electrocatalysis, transition-metal oxides usually do not have desirable semiconducting properties. Instead, oxides with open cation d-shells are typically Mott or charge-transfer insulators with notoriously poor transport properties, resulting from large effective electron/hole masses or from carrier self-trapping. Based on the notion that the electronic structure features (p-d interaction) supporting the p-type conductivity in d10 oxides like Cu2O and CuAlO2 occurs in a similar fashion also in the d5 (high-spin) oxides, we recently studied theoretically the band-structure and transport properties of the prototypical binary d5 oxides MnO and Fe2O3 [PRB 85, 201202(R)]. We found that MnO tends to self-trap holes by forming Mn+III, whereas Fe2O3 self-traps electrons by forming Fe+II. However, the self-trapping of holes is suppressed by when Mn is tetrahedrally coordinated, which suggests specific routes to design novel solar conversion materials by considering ternary Mn(II) oxides or oxide alloys. We are presenting theory, synthesis, and initial characterization for these novel energy materials.

  20. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name:24,High824 2.839 2.8352.747 2.759 2.699Mo

  1. IMPROVEMENT OF CdMnTe DETECTOR PERFORMANCE BY MnTe PURIFICATION

    SciTech Connect (OSTI)

    Kim, K.H.; Bolotnikov, A.E.; Camarda, G.S.; Tappero, R.; Hossain, A.; Cui, Y.; Yang, G.; Gul, R.; and James, R.B.

    2011-04-25T23:59:59.000Z

    Residual impurities in manganese (Mn) are a big obstacle to obtaining high-performance CdMnTe (CMT) X-ray and gamma-ray detectors. Generally, the zone-refining method is an effective way to improve the material's purity. In this work, we purified the MnTe compounds combining the zone-refining method with molten Te, which has a very high solubility for most impurities. We confirmed the improved purity of the material by glow-discharge mass spectrometry (GDMS). We also found that CMT crystals from a multiply-refined MnTe source, grown by the vertical Bridgman method, yielded better performing detectors.

  2. Co layer thickness dependence of exchange biasing for IrMnCo and FeMnCo

    E-Print Network [OSTI]

    Reilly, Anne

    Co layer thickness dependence of exchange biasing for IrMnÕCo and FeMnÕCo K. A. Seua) and H. Huang) in IrMn/Co and FeMn/Co bilayers using the magneto-optical Kerr effect. Samples are sputtered wedges on silicon with Co thicknesses ranging from 1 to 17 nm. The IrMn/Co with exchange bias interface energy of 0

  3. Neutron Hole States of Mo-93,95

    E-Print Network [OSTI]

    Bindal, P. K.; Youngblood, David H.; Kozub, R. L.

    1977-01-01T23:59:59.000Z

    - topes but less than half is observed for '"Mo. The hole strength distributions for l =1 and 4 are displayed in Fig. 10 for all the Mo isotopes. It is apparent from this figure that the states corres- ponding to lgg/2 2Py/2 and 2P, /, orbitals, which...

  4. SARKAR ET AL. VOL. 8 ' NO. 4 ' 39924003 ' 2014 www.acsnano.org

    E-Print Network [OSTI]

    SARKAR ET AL. VOL. 8 ' NO. 4 ' 3992­4003 ' 2014 www.acsnano.org 3992 March 03, 2014 C 2014 American Chemical Society MoS2 Field-Effect Transistor for Next- Generation Label-Free Biosensors Deblina Sarkar ARTICLE #12;SARKAR ET AL. VOL. 8 ' NO. 4 ' 3992­4003 ' 2014 www.acsnano.org 3993 have also been used

  5. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09T23:59:59.000Z

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  6. Demonstration of resonant photopumping of Mo VII by Mo XII for a VUV laser near 600 {Angstrom}

    SciTech Connect (OSTI)

    Ilcisin, K.J.; Aumayr, F.; Schwob, J.L.; Suckewer, S.

    1993-09-01T23:59:59.000Z

    We present data of experiments on the resonant photopumping of Mo VII by Mo XII as a method of generating a coherent VUV source near 600 {angstrom}. The experiment is based on a scheme proposed by Feldman and Reader in which the 4p{sup 6} -- 4p{sup 5}6s transition in Mo VII in resonantly photopumped by the 5s {sup 2}S{sub 1/2} -- 4p {sup 2}P{sub 1/2} transition in Mo XII. Results of the laser produced plasma experiments show the successful enhancement of the population of the Mo VII 4p{sup 5}6s upper lasing level when pumped by an adjacent Mo VII plasma. No enhancement was seen in a control experiment where the Mo VII plasma was pumped by a Zr X plasma. Improvements of the intensity of the Mo XII pump source, achieved using an additional pump laser, lead to the generation of a population inversion for the VUV transition.

  7. arXiv:1002.0800v1[astro-ph.GA]3Feb2010 Mon. Not. R. Astron. Soc. 000, 000000 (0000) Printed 3 February 2010 (MN LATEX style file v2.2)

    E-Print Network [OSTI]

    Evans, Dan

    February 2010 (MN LATEX style file v2.2) High resolution X-ray spectroscopy and imaging of Mrk 573 Stefano Astronomico di Roma (INAF), Via Frascati 33, I-00040 Monte Porzio Catone, Italy 3 February 2010 ABSTRACT We et al. 2003; Bianchi et al. 2006). Since the NLR is also believed to be #12;2 Stefano Bianchi, et al

  8. First-principles calculations of the electronic, vibrational, and elastic properties of the magnetic laminate Mn?GaC

    SciTech Connect (OSTI)

    Thore, A., E-mail: andth@ifm.liu.se; Dahlqvist, M., E-mail: madah@ifm.liu.se, E-mail: bjoal@ifm.liu.se, E-mail: johro@ifm.liu.se; Alling, B., E-mail: madah@ifm.liu.se, E-mail: bjoal@ifm.liu.se, E-mail: johro@ifm.liu.se; Rosén, J., E-mail: madah@ifm.liu.se, E-mail: bjoal@ifm.liu.se, E-mail: johro@ifm.liu.se [Thin Film Physics Division, Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping (Sweden)

    2014-09-14T23:59:59.000Z

    In this paper, we report the by first-principles predicted properties of the recently discovered magnetic MAX phase Mn?GaC. The electronic band structure and vibrational dispersion relation, as well as the electronic and vibrational density of states, have been calculated. The band structure close to the Fermi level indicates anisotropy with respect to electrical conductivity, while the distribution of the electronic and vibrational states for both Mn and Ga depend on the chosen relative orientation of the Mn spins across the Ga sheets in the Mn–Ga–Mn trilayers. In addition, the elastic properties have been calculated, and from the five elastic constants, the Voigt bulk modulus is determined to be 157?GPa, the Voigt shear modulus 93?GPa, and the Young's modulus 233?GPa. Furthermore, Mn?GaC is found relatively elastically isotropic, with a compression anisotropy factor of 0.97, and shear anisotropy factors of 0.9 and 1, respectively. The Poisson's ratio is 0.25. Evaluated elastic properties are compared to theoretical and experimental results for M?AC phases where M?=?Ti, V, Cr, Zr, Nb, Ta, and A?=?Al, S, Ge, In, Sn.

  9. 21.st IAEA FEC TH/3-2 Electron fishbones: theory and experimental evidence 1 IAEA FEC 2006 F. Zonca et al.

    E-Print Network [OSTI]

    Zonca, Fulvio

    . (Wong et al, PRL 85, 996, 2000). Excitation by barely trapped suprathermal electrons, characterized. Chen, et al., PRL 52, 1122, 1984) Fast electron kinetic response (L. Chen, et al., PRL 52, 1122, 1984) Ideal MHD response (M.N. Bussac, et al., PRL 35, 1638, 1975) #12;21.st IAEA FEC TH/3-2 Electron

  10. Effect of Mo substitution by W on impact property of heat affected zone in duplex stainless steels

    SciTech Connect (OSTI)

    Huh, M.J.; Kim, S.B.; Paik, K.W.; Kim, Y.G. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering] [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering

    1997-04-01T23:59:59.000Z

    The duplex stainless steels are characterized by two phase structures composed of a mixture of austenite and ferrite phases. They offer high toughness, good weldability, satisfactory corrosion protection, excellent stress corrosion cracking resistance and high strength. Because of these characteristics, these steels have been widely used in various applications such as oil, gas, and chemical industries. Duplex stainless steels generally have suffered embrittlement when exposed at elevated temperature, i.e. above 300 C. To avoid this embrittlement, conventional duplex stainless steels are subject to solution treatment followed by water quenching in the final stage of production or fabrication, which limits the size of products. Kim et al. have recently reported that embrittlement can be greatly reduced by the partial or full replacement of Mo by W in 22Cr-base duplex stainless steels. For the processing of duplex stainless steel, fusion welding is a major fabrication method for corrosion resistant applications. Therefore the welding behavior of these materials has to be fully defined. The purpose of this study is to investigate the effect of Mo substitution by W on the impact property of simulated heat affected zones in 22Cr duplex stainless steels. Structural transformation associated with Mo substitution by W in HAZ has been also investigated on W-containing alloys and conventional 3% Mo duplex stainless steel.

  11. A novel three dimensional semimetallic MoS{sub 2}

    SciTech Connect (OSTI)

    Tang, Zhen-Kun [Beijing Computational Science Research Center, Beijing 100084 (China); Departments of Physics and Electronics, Hengyang Normal University, Hengyang 421008 (China); Zhang, Hui; Liu, Li-Min, E-mail: limin.liu@csrc.ac.cn [Beijing Computational Science Research Center, Beijing 100084 (China); Liu, Hao [Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China); Lau, Woon-Ming [Beijing Computational Science Research Center, Beijing 100084 (China); Chengdu Green Energy and Green Manufacturing Technology R and D Center, Chengdu, Sichuan 610207 (China)

    2014-05-28T23:59:59.000Z

    Transition metal dichalcogenides (TMDs) have many potential applications, while the performances of TMDs are generally limited by the less surface active sites and the poor electron transport efficiency. Here, a novel three-dimensional (3D) structure of molybdenum disulfide (MoS{sub 2}) with larger surface area was proposed based on first-principle calculations. 3D layered MoS{sub 2} structure contains the basal surface and joint zone between the different nanoribbons, which is thermodynamically stable at room temperature, as confirmed by first principles molecular dynamics calculations. Compared the two-dimensional layered structures, the 3D MoS{sub 2} not only owns the large surface areas but also can effectively avoid the aggregation. Interestingly, although the basal surface remains the property of the intrinsic semiconductor as the bulk MoS{sub 2}, the joint zone of 3D MoS{sub 2} exhibits semimetallic, which is derived from degenerate 3d orbitals of the Mo atoms. The high stability, large surface area, and high conductivity make 3D MoS{sub 2} have great potentials as high performance catalyst.

  12. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship inALSALS Spectrum PrintALS

  13. Reviw Al

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection TechnicalResonant Soft X-RayReview/Verify3 JuneReviw Al now ..

  14. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals New StateALS

  15. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals NewALSUsers'ALS

  16. AL. I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -KWatertown Arsenal'.I Y.it ! ( , . /'-AL.

  17. Energy absorption in Ni-Mn-Ga/ polymer composites

    E-Print Network [OSTI]

    Feuchtwanger, Jorge

    2006-01-01T23:59:59.000Z

    In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

  18. Fracture and fatigue resistance of MoSiB alloys for ultrahigh-temperature structural applications

    E-Print Network [OSTI]

    Ritchie, Robert

    Fracture and fatigue resistance of Mo­Si­B alloys for ultrahigh-temperature structural applications­Mo3Si­Mo5SiB2 alloys, which utilize a continuous a-Mo matrix to achieve unprecedented room. Introduction For applications such as aerospace engines and power generation, future advancements are limited

  19. Oxidation, Reduction, and Condensation of Alcohols over (MO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohols over (MO3)3 (MMo, W) Nanoclusters . Abstract: The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic...

  20. Co-Mo Electric Cooperative- Residential Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. The...

  1. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27T23:59:59.000Z

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  2. Q value of the 100Mo Double-Beta Decay

    E-Print Network [OSTI]

    S. Rahaman; V. -V. Elomaa; T. Eronen; J. Hakala; A. Jokinen; J. Julin; A. Kankainen; A. Saastamoinen; J. Suhonen; C. Weber; J. Äystö

    2007-12-20T23:59:59.000Z

    Penning trap measurements using mixed beams of 100Mo - 100Ru and 76Ge - 76Se have been utilized to determine the double-beta decay Q-values of 100Mo and 76Ge with uncertainties less than 200 eV. The value for 76Ge, 2039.04(16) keV is in agreement with the published SMILETRAP value. The new value for 100Mo, 3034.40(17) keV is 30 times more precise than the previous literature value, sufficient for the ongoing neutrinoless double-beta decay searches in 100Mo. Moreover, the precise Q-value is used to calculate the phase-space integrals and the experimental nuclear matrix element of double-beta decay.

  3. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06T23:59:59.000Z

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  4. Theory of weak localization in ferromagnetic (Ga,Mn)As

    E-Print Network [OSTI]

    Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

    2009-01-01T23:59:59.000Z

    We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

  5. ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries

    SciTech Connect (OSTI)

    Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

    2012-01-01T23:59:59.000Z

    Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0.04Co02O2 electrode containing 5 wt% single-walled carbon nanotubes as the conductive additive and demonstrated both high rate capability as well as the ability to cycle the cathode to 5 V vrs. Li/Li+. Finally, we coated a Celgard (TM) separator and enabled stable cycling in a high dielectric electrolyte. These results will be presented in detail.

  6. Mn/DOT's Project Peer Review

    E-Print Network [OSTI]

    Minnesota, University of

    and sustain this culture #12;Project Management #12;Recent National Work in Transportation Project ManagementMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research a Peer Review? Why Project Management? ·Improve project delivery performance ­ on time, on budget (an

  7. MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM

    E-Print Network [OSTI]

    MN4602 Crouch 2004 REASSESSING WEAPON SYSTEM OPERATIONAL TEST & EVALUATION METHODOLOGIES LTC Thom support assessing a weapon systems true cost and performance characteristics? S1: Can/should cost, operational effectiveness and suitability be assessed independent of one another? S2: Do current test

  8. Materials Data on Mn3Mo2H34C22N16O5 (SG:15) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Valence-state Model of Strain-dependent Mn L2,3 X-ray Magnetic Circular Dichroism from Ferromagnetic Semiconductors

    SciTech Connect (OSTI)

    van der Laan, G.; Edmonds, K. W.; Arenholz, E.; Farley, N. R. S.; Gallagher, B. L.

    2010-03-30T23:59:59.000Z

    We present a valence-state model to explain the characteristics of a recently observed pre-edge feature in Mn L{sub 3} x-ray magnetic circular dichroism (XMCD) of ferromagnetic (Ga,Mn)As and (Al,Ga,Mn)As thin films. The prepeak XMCD shows a uniaxial anisotropy, contrary to the cubic symmetry of the main structures induced by the crystalline electric field. Reversing the strain in the host lattice reverses the sign of the uniaxial anisotropy. With increasing carrier localization, the prepeak height increases, indicating an increasing 3d character of the hybridized holes. Hence, the feature is ascribed to transitions from the Mn 2p core level to unoccupied p-d hybridized valence states. The characteristics of the prepeak are readily reproduced by the model calculation taking into account the symmetry of the strain-, spin-orbit-, and exchange-split valence states around the zone center.

  10. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    SciTech Connect (OSTI)

    Taylor, Alice E [ORNL; Berlijn, Tom [ORNL; Hahn, Steven E [ORNL; May, Andrew F [ORNL; Williams, Travis J [ORNL; Poudel, Lekhanath N [ORNL; Calder, Stuart A [ORNL; Fishman, Randy Scott [ORNL; Stone, Matthew B [ORNL; Aczel, Adam A [ORNL; Cao, Huibo [ORNL; Lumsden, Mark D [ORNL; Christianson, Andrew D [ORNL

    2015-01-01T23:59:59.000Z

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int

  11. Evidence of N substitution by Mn in GaN

    E-Print Network [OSTI]

    Pereira, LMC; Decoster, S; Correia, JG; da Silva, MR; Vantomme, A; Araújo, JP

    2012-01-01T23:59:59.000Z

    We report on the lattice location of Mn in wurtzite GaN using beta? emission channeling. In addition to the majority substituting for Ga, we locate up to 20% of the Mn atoms in N sites. We propose that the incorporation of Mn in N sites is enabled under sufficiently high concentrations of N vacancies, and stabilized by a highly charged state of the Mn cations. Since N substitution by Mn impurities in wurtzite GaN has never been observed experimentally or even considered theoretically before, it challenges the current paradigm of transition metal incorporation in wide-gap dilute magnetic semiconductors.

  12. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect (OSTI)

    Goetsch, Ryan J [Ames Laboratory; Anand, V K [Ames Laboratory; Johnston, David C [Ames Laboratory

    2014-08-01T23:59:59.000Z

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  13. MoSe2 thin films synthesized by solid state reactions between Mo and Se J. Pouzet (1) and J. C. Bernede (2)

    E-Print Network [OSTI]

    Boyer, Edmond

    807 MoSe2 thin films synthesized by solid state reactions between Mo and Se thin films J. Pouzet (1 reaction, induced by annealing, between the Mo and Se constituents in thin films form. The films have been thin films annealed under selenium pressure at only 770 K are well crystallized. The electrical

  14. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn

    SciTech Connect (OSTI)

    Provino, A.; Paudyal, D.; Fornasini, ML; Dhiman, I.; Dhar, SK.; Das, A.; Mudryk, Y.; Manfrinetti, P.; Pecharsky, VK

    2013-01-29T23:59:59.000Z

    We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the MnCu2In and MnCu2Sn alloys. In contrast, the homologous compound MnCu4Sn, which crystallizes in the cubic MgCu4Sn-type, orders antiferromagnetically with TN = 110 K. The neutron diffraction studies show ferromagnetic spin orientation in the {1 0 1} plane in MnCu4In with a magnetic moment of 4.5 ?B/Mn at 22 K, and a corresponding value of 4.7 ?B/Mn in the antiferromagnetic MnCu4Sn with propagation vector View the MathML source. The first-principles electronic structure calculations show that the unexpected difference in both magnetic and crystal structures of MnCu4In and MnCu4Sn is due to the difference in the Mn-3d bands and exchange interactions relating to different crystal anisotropy, coordination numbers, and interatomic distances.

  15. al-mo powder processing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    support surface was developed with LANL for fabrication of robust hydrogen separation membranes from Pd alloy thin films, approximately 2m thick, for advanced coal-fired power...

  16. BUDVYTIS ET AL.: MOT FOR VIDEO SEGMENTATION 1 MoT -Mixture of Trees Probabilistic

    E-Print Network [OSTI]

    Martin, Ralph R.

    occlusion handling, label drift caused by round-off errors, high cost of multi- label MAP inference for this model to estimate super-pixel labels and their confidences in nearly realtime. The effi- cacy of our as in [19],[8]. However for tasks requiring semantic label propagation in video sequences, satisfactory

  17. Compound and Elemental Analysis At Valles Caldera - Redondo Geothermal...

    Open Energy Info (EERE)

    for Al, As, Ba, Ca, Fe, K, Li, Mg, Mn, Mo, Na, Si, Sr, and Zn; Fire AssayAtomic Absorption (AA) spectroscopy using a graphite furnace for Ag, Al3+, Cd, Co, Cr, Cu, Ni, Pb, and...

  18. Multiphonon resonant Raman scattering in MoS{sub 2}

    SciTech Connect (OSTI)

    Go?asa, K., E-mail: Katarzyna.Golasa@fuw.edu.pl; Grzeszczyk, M.; Wysmo?ek, A.; Babi?ski, A. [Faculty of Physics, University of Warsaw, ul. Ho?a 69, 00-681 Warszawa (Poland); Leszczy?ski, P.; Faugeras, C.; Nicolet, A. A. L.; Potemski, M. [Laboratoire National des Champs Magnétiques Intenses, CNRS-UJF-UPS-INSA, 25, avenue des Martyrs, 38042 Grenoble (France)

    2014-03-03T23:59:59.000Z

    Optical emission spectrum of a resonantly (??=?632.8?nm) excited molybdenum disulfide (MoS{sub 2}) is studied at liquid helium temperature. More than 20 peaks in the energy range spanning up to 1400?cm{sup ?1} from the laser line, which are related to multiphonon resonant Raman scattering processes, are observed. The attribution of the observed lines involving basic lattice vibrational modes of MoS{sub 2} and both the longitudinal (LA(M)) and the transverse (TA(M) and/or ZA(M)) acoustic phonons from the vicinity of the high-symmetry M point of the MoS{sub 2} Brillouin zone is proposed.

  19. Hydrotreatment of Athabasca bitumen derived gas oil over Ni-Mo, Ni-W, and Co-Mo catalysts

    SciTech Connect (OSTI)

    Diaz-Real, R.A.; Mann, R.S.; Sambi, I.S. (Univ. of Ottawa, Ontario (Canada). Dept. of Chemical Engineering)

    1993-07-01T23:59:59.000Z

    The hydrotreatment of Athabasca bitumen derived heavy gas oil containing 4.08% S and 0.49% N was carried out in a trickle bed reactor over Ni-W, Ni-Mo, and Co-Mo catalysts supported on zeolite-alumina-silica at 623-698 K, LHSV of 1-4, gas flow rate 890 m[sup 3][sub H2]/m[sup 3][sub oil] (5,000 sef/bbl), and pressure of 6.89 MPa. Analyses for viscosity, density, aniline point, ASTM mid boiling point distillation, C/H ratio, and percentage of N and S in the final product were carried out to characterize the product oil. The amounts of N and S removed indicated the hydrodenitrogenation and hydrodesulfurization activity of the catalysts. Results of zeolite-alumina-silica-supported catalysts are compared to those obtained with commercially available Ni-Mo, Ni-W, and Co-Mo on [gamma]-alumina. Ni-Mo supported on zeolite-alumina-silica was most active and could remove as much as 99 % S and 89% N present in the oil at 698 K. The data for HDN and HDS fitted the pseudo first order model. The kinetic model is described in detail.

  20. Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure

    SciTech Connect (OSTI)

    Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Moog Chow, Gan, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2014-05-07T23:59:59.000Z

    The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{sub g} orbitals decreased and the density of states above the Fermi level increased in the relaxed MnO{sub 6} octahedron, as reflected by a wider separation between two sub-peaks in the pre-edge XANES spectra.

  1. Ni.sub.3 Al-based intermetallic alloys having improved strength above 850.degree. C.

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN)

    2000-01-01T23:59:59.000Z

    Intermetallic alloys composed essentially of: 15.5% to 17.0% Al, 3.5% to 5.5% Mo, 4% to 8% Cr, 0.04% to 0.2% Zr, 0.04% to 1.5% B, balance Ni, are characterized by melting points above 1200.degree. C. and superior strengths at temperatures above 1000.degree. C.

  2. Synthesis and characterization of a novel tube-in-tube nanostructured PPy/MnO{sub 2}/CNTs composite for supercapacitor

    SciTech Connect (OSTI)

    Li, Juan, E-mail: lj-panpan@163.com [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China) [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China); Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Que, Tingli [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China)] [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China); Huang, Jianbin, E-mail: JBhuang@pku.edu.cn [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China) [College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046 (China); Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)

    2013-02-15T23:59:59.000Z

    Graphical abstract: A novel tube-in-tube nanostructured PPy/MnO{sub 2}/CNTs composite have been successfully fabricated. Its inner tubules are CNTs and the outer tubules are template-synthesized PPy. Most MnO{sub 2} nanoparticles are sandwiched between the inner and outer wall, some relatively large particles are also latched onto the outside wall of the PPy tube. The composite yields a good electrochemical reversibility through 1000 cycles’ cyclic voltammogram (CV) test and galvanostatic charge–discharge experiments at different current densities. Display Omitted Highlights: ? We fabricate a ternary organic–inorganic complex of PPy/MnO{sub 2}/CNTs composite. ? We characterize its morphological structures and properties by several techniques. ? The composite possesses the typical tube-in-tube nanostructures. ? Most MnO{sub 2} nanoparticles are sandwiched between the inner CNTs and outer PPy wall. ? The composite has good electrochemical reversibility for supercapacitor. -- Abstract: Ternary organic–inorganic complex of polypyrrole/manganese dioxide/carbon nanotubes (PPy/MnO{sub 2}/CNTs) composite was prepared by in situ chemical oxidation polymerization of pyrrole in the host of inorganic matrix of MnO{sub 2} and CNTs, using complex of methyl orange (MO)/FeCl{sub 3} was used as a reactive self-degraded soft-template. The morphological structures of the composite were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopic (HRTEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD), respectively. All the results indicate that the PPy/MnO{sub 2}/CNTs composite possesses the typical tube-in-tube nanostructures: the inner tubules are CNTs and the outer tubules are template-synthesized PPy. MnO{sub 2} nanoparticles may either sandwich the space between the inner and outer tubules or directly latch onto the wall of the PPy tubes. The composite yields a good electrochemical reversibility through 1000 cycles’ cyclic voltammogram (CV) test in the potential range of ?0.6 to 0.4 V and its specific capacitance was up to 402.7 F g{sup ?1} at a current density of 1 A g{sup ?1} in galvanostatic charge–discharge experiment.

  3. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Structure And Radiation Damage Behavior Of Epitaxial CrxMo1-x Alloy Thin Films On MgO. Abstract:...

  4. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Potassium on the MoS2(100) Surface: A First-Principles Investigation. Adsorption of Potassium on the MoS2(100) Surface: A First-Principles Investigation. Abstract: Periodic density...

  5. High Capacity MoO3 Nanoparticle Li-Ion Battery Anode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energy functional were employed.) 10 AccomplishmentStatus Theoretical changes in Li-ion intercalated -MoO 3 Mo Li O * Four Li inserted in a theoretical nanoparticle. * 9 ps...

  6. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99...

  7. ,"International Falls, MN Natural Gas Pipeline Imports From Canada...

    U.S. Energy Information Administration (EIA) Indexed Site

    International Falls, MN Natural Gas Pipeline Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of...

  8. ,"Noyes, MN Natural Gas Pipeline Imports From Canada (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Noyes, MN...

  9. ,"Warroad, MN Natural Gas Pipeline Imports From Canada (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    Imports From Canada (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Warroad, MN...

  10. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Bennett, Wendy D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Doherty, Ann L. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Fuller, E. S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Hardy, John S. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US); Omberg, Ronald P. [Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

    2014-08-28T23:59:59.000Z

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30°C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  11. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    Sullivan, John M.

    for divergence-free vector fields which arise in modeling incompressible fluid flow.6,7These new knot energies MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  12. MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER

    E-Print Network [OSTI]

    for divergence-free vector fields which arise in modeling incompressible fluid flow.? These new knot energies may MO"BIUS-INVARIANT KNOT ENERGIES R.B. KUSNER, Urbana, IL, USA 61801-2975 There has been recent interest in knot energies among mathematicians

  13. Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo),

    E-Print Network [OSTI]

    Barton, Mark D.

    55 Introduction THE YERINGTON DISTRICT, Nevada, contains porphyry Cu(Mo), Cu skarn, Fe oxide with the Jurassic Yerington batholith, which serves as either host rock or as source for heat and ma- terials of the Yerington Porphyry Copper District: Magmatic to Nonmagmatic Sources of Hydrothermal Fluids, Their Flow Paths

  14. Polarized x-ray spectroscopy of quaternary ferromagnetic semiconductor (Ga,Mn)(As,P)

    E-Print Network [OSTI]

    Wadley, P.

    2011-01-01T23:59:59.000Z

    quaternary diluted magnetic semiconductor (Ga,Mn)(As,P) as aIn diluted magnetic semiconductors such as (Ga,Mn)As, whichquaternary diluted magnetic semiconductors such as (Ga,Mn)(

  15. Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof

    E-Print Network [OSTI]

    Seo, Dongmin

    2009-05-15T23:59:59.000Z

    This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

  16. Experimental and first-principles study of ferromagnetism in Mn-doped zinc stannate nanowires

    SciTech Connect (OSTI)

    Deng Rui; Zhou Hang; Qin Jieming; Wan Yuchun; Jiang Dayong; Liang Qingcheng [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Li Yongfeng [Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012 (China); Wu, Tom [Physical Sciences and Engineering Division, Solar and Photovoltaics Engineering Research Center, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Saudi Arabia); Yao Bin [State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012 (China); Liu Lei [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, No.3888 Dongnanhu Road, Changchun 130033 (China)

    2013-07-21T23:59:59.000Z

    Room temperature ferromagnetism was observed in Mn-doped zinc stannate (ZTO:Mn) nanowires, which were prepared by chemical vapor transport. Structural and magnetic properties and Mn chemical states of ZTO:Mn nanowires were investigated by X-ray diffraction, superconducting quantum interference device (SQUID) magnetometry and X-ray photoelectron spectroscopy. Manganese predominantly existed as Mn{sup 2+} and substituted for Zn (Mn{sub Zn}) in ZTO:Mn. This conclusion was supported by first-principles calculations. Mn{sub Zn} in ZTO:Mn had a lower formation energy than that of Mn substituted for Sn (Mn{sub Sn}). The nearest neighbor Mn{sub Zn} in ZTO stabilized ferromagnetic coupling. This observation supported the experimental results.

  17. Minnesota Guidestar www.dot.state.mn.us/guidestar

    E-Print Network [OSTI]

    Minnesota, University of

    .dot.state.mn.us/guidestar What is ITS? · Application of technology to improve the safety and efficiency of the transportation system. #12;Minnesota Guidestar www.dot.state.mn.us/guidestar What is ITS? · Traffic Management ­ Signal Systems ­ Ramp Meters · Emergency Response ­ Mobile Data Terminals ­ 911 Dispatch ­ RF Data Networks

  18. The growth and characterization of LiGd?(Mo0?)? single crystals

    E-Print Network [OSTI]

    Reimund, James Allyn

    1981-01-01T23:59:59.000Z

    ' C/second 37 Pyroelectric Current vs. Temperature dT/dt = 30' C/second 180' Domains (Gd (MoO ) ) 37 39 INTRODUCTION This thesis discusses the growth and some single crystalline properties of lithium-gadolinium-molybdate of the type LiGd (Mo...O ) 3 45' This compound is one of the three thus far discovered compounds of the lithium ? gadolinium-molybdate (LGMO) system. In general, this system can be expressed as Li2Mo04. XGd2(Mo04)3, where LiGd3(MoO, )5 4 5 single crystals synthesize when X...

  19. Exploration of R2XM2 (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge): Structural Motifs, the novel Compound Gd2AlGe2 and Analysis of the U3Si2 and Zr3Al2 Structure Types

    SciTech Connect (OSTI)

    Sean William McWhorter

    2006-05-01T23:59:59.000Z

    In the process of exploring and understanding the influence of crystal structure on the system of compounds with the composition Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} several new compounds were synthesized with different crystal structures, but similar structural features. In Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, the main feature of interest is the magnetocaloric effect (MCE), which allows the material to be useful in magnetic refrigeration applications. The MCE is based on the magnetic interactions of the Gd atoms in the crystal structure, which varies with x (the amount of Si in the compound). The crystal structure of Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4} can be thought of as being formed from two 3{sup 2}434 nets of Gd atoms, with additional Gd atoms in the cubic voids and Si/Ge atoms in the trigonal prismatic voids. Attempts were made to substitute nonmagnetic atoms for magnetic Gd using In, Mg and Al. Gd{sub 2}MgGe{sub 2} and Gd{sub 2}InGe{sub 2} both possess the same 3{sup 2}434 nets of Gd atoms as Gd{sub 5}(Si{sub x}Ge{sub 1-x}){sub 4}, but these nets are connected differently, forming the Mo{sub 2}FeB{sub 2} crystal structure. A search of the literature revealed that compounds with the composition R{sub 2}XM{sub 2} (R=Sc, Y, Ti, Zr, Hf, rare earth; X=main group element; M=transition metal, Si, Ge) crystallize in one of four crystal structures: the Mo{sub 2}FeB{sub 2}, Zr{sub 3}Al{sub 2}, Mn{sub 2}AlB{sub 2} and W{sub 2}CoB{sub 2} crystal structures. These crystal structures are described, and the relationships between them are highlighted. Gd{sub 2}AlGe{sub 2} forms an entirely new crystal structure, and the details of its synthesis and characterization are given. Electronic structure calculations are performed to understand the nature of bonding in this compound and how electrons can be accounted for. A series of electronic structure calculations were performed on models with the U{sub 3}Si{sub 2} and Zr{sub 3}Al{sub 2} structures, using Zr and A1 as the building blocks. The starting point for these models was the U{sub 3}Si{sub 2} structure, and models were created to simulate the transition from the idealized U{sub 3}Si{sub 2} structure to the distorted Zr{sub 3}Al{sub 2} structure. Analysis of the band structures of the models has shown that the transition from the U{sub 3}Si{sub 2} structure to the Zr{sub 3}Al{sub 2} structure lifts degeneracies along the {Lambda} {yields} Z direction, indicating a Peierls-type mechanism for the displacement occurring in the positions of the Zr atoms.

  20. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

    2014-08-21T23:59:59.000Z

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  1. Spectroscopy of Mn atoms isolated in solid {sup 4}He

    SciTech Connect (OSTI)

    Moroshkin, P., E-mail: petr.moroshkin@riken.jp; Lebedev, V.; Weis, A. [Department of Physics, University of Fribourg, Chemin du Musée 3, 1700 Fribourg (Switzerland)

    2014-06-07T23:59:59.000Z

    We present an experimental study of the laser-induced luminescence spectra of Mn atoms in solid helium matrices. We observe transitions of the valence electron and of inner-shell electrons. We find that the Mn-He interaction perturbs the inner-shell transitions to a lesser extent than the valence-electron transitions. The observed lineshapes of the inner-shell transitions of Mn are similar to those of an inner-shell transition in Ba studied earlier. At the same time, they are more strongly perturbed than the corresponding transitions in Au and Cu under the same conditions. We suggest a qualitative explanation of these observations based on the atomic bubble model. Our results also suggest that the inner-shell transitions of Mn in solid He are more strongly perturbed than the same lines of Mn isolated in solid Ar or Kr matrices.

  2. Precipitation sensitivity to alloy composition in Fe-Cr-Mn austenitic steels developed for reduced activation for fusion application

    SciTech Connect (OSTI)

    Maziasz, P.J.; Klueh, R.L.

    1988-01-01T23:59:59.000Z

    Special austenitic steels are being designed in which alloying elements like Mo, Nb, and Ni are replaced with Mn, W, V, Ti, and/or Ta to reduce the long-term radioactivity induced by fusion reactor irradiation. However, the new steels still need to have properties otherwise similar to commercial steels like type 316. Precipitation strongly affects strength and radiation-resistance in austenitic steels during irradiation at 400--600/degree/C, and precipitation is also usually quite sensitive to alloy composition. The initial stage of development was to define a base Fe-Cr-Mn-C composition that formed stable austenite after annealing and cold-working, and resisted recovery or excessive formation of coarse carbide and intermetallic phases during elevated temperature annealing. These studies produced a Fe-12Cr-20Mn-0.25C base alloy. The next stage was to add the minor alloying elements W, Ti, V, P, and B for more strength and radiation-resistance. One of the goals was to produce fine MC precipitation behavior similar to the Ti-modified Fe-Cr-Ni prime candidate alloy (PCA). Additions of Ti+V+P+B produced fine MC precipitation along network dislocations and recovery/recrystallization resistance in 20% cold worked material aged at 800/degree/C for 166h, whereas W, Ti, W+Ti, or Ti+P+B additions did not. Addition of W+Ti+V+P+B also produced fine MC, but caused some sigma phase formation and more recrystallization as well. 29 refs., 14 figs., 9 tabs.

  3. Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO{sub 2}

    SciTech Connect (OSTI)

    Casey, P.; Bogan, J.; Hughes, G. [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland); Lozano, J. G.; Nellist, P. D. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

    2011-09-01T23:59:59.000Z

    In this study, Mn silicate (MnSiO{sub 3}) barrier layers were formed on thermally grown SiO{sub 2} using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in determining the extent of the interaction between the deposited Mn and the SiO{sub 2} substrate. Using x-ray photoelectron spectroscopy, it has been shown that a metallic Mn film with an approximate thickness of 1 nm cannot be fully converted to Mn silicate following vacuum annealing to 500 deg. C. Transmission electron microscopy (TEM) analysis suggests the maximum MnSiO{sub 3} layer thickness obtainable using metallic Mn is {approx}1.7 nm. In contrast, a {approx}1 nm partially oxidized Mn film can be fully converted to Mn silicate following thermal annealing to 400 deg. C, forming a MnSiO{sub 3} layer with a measured thickness of 2.6 nm. TEM analysis also clearly shows that MnSiO{sub 3} growth results in a corresponding reduction in the SiO{sub 2} layer thickness. It has also been shown that a fully oxidized Mn oxide thin film can be converted to Mn silicate, in the absence of metallic Mn. Based on these results it is suggested that the presence of Mn oxide species at the Mn/SiO{sub 2} interface facilitates the conversion of SiO{sub 2} to MnSiO{sub 3}, in agreement with previously published studies.

  4. Magnetic coupling in neutral and charged Cr{sub 2}, Mn{sub 2}, and CrMn dimers

    SciTech Connect (OSTI)

    Desmarais, N. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Reuse, F. A. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Khanna, S. N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    2000-04-01T23:59:59.000Z

    Theoretical ab initio studies of neutral, cationic and anionic Cr{sub 2}, Mn{sub 2}, and CrMn dimers have been carried out to explore the progression of magnetic coupling with the number of electrons. It is shown that while Cr{sub 2} and Cr{sub 2}{sup -} have antiferromagnetically coupled atomic spins, Cr{sub 2}{sup +} has a ferromagnetic ground state closely followed by an antiferromagnetic state. On the other hand, all Mn{sub 2} dimers are ferromagnetic, irrespective of the charge. The neutral CrMn is ferrimagnetic while the charged CrMn are antiferromagnetic. In all cases, the charged dimers are found to be more stable than the neutral ones. The results are compared with available calculations and experiments and the difficulties associated with theoretical description and the experimental interpretations are discussed. (c) 2000 American Institute of Physics.

  5. NEGLIGIBLE CREEP CONDITIONS FOR MOD 9 CR 1 MO STEEL

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Riou, Bernard [AREVA Group; Escaravage, Claude [AREVA Group; Swindeman, Robert W [ORNL; Cabrillat, Marie-Th?r?se [CEA Cadarache, St. Paul lex Durance, France; Allais, Lucien [CEA, Saclay, France

    2006-01-01T23:59:59.000Z

    Mod 9 Cr 1 Mo Steel (grade 91) is one of the materials envisaged for the Reactor Pressure Vessel of Very High Temperature Reactors. To avoid the implementation of a surveillance program covering the monitoring of the creep damage throughout the whole life of the reactor, it is recommended to operate the Reactor Pressure Vessel in the negligible creep regime. In this paper, the background of negligible creep criteria available in nuclear Codes is first recalled and their limitations were analyzed. Then, guidance for deriving criteria more appropriate for mod 9 Cr 1 Mo steel is provided. Finally, R&D actions in the U. S. and France to support the new approaches are discussed and recommended.

  6. Dislocations With Edge Components in Nanocrystalline bcc Mo

    SciTech Connect (OSTI)

    G. M. Cheng; W. Z. Xu; W. W. Jian; H. Yuan; M. H. Tsai; Y. T. Zhu; Y. F. Zhang; Paul C. Millett

    2013-07-01T23:59:59.000Z

    We report high-resolution transmission electron microscopy (HRTEM) observation of a high density of dislocations with edge components (approximately 1016 m-2) in nanocrystalline (NC) body-centered cubic (bcc) Mo prepared by high-pressure torsion. We also observed for the first time of the 1/2 <111> and <001> pure edge dislocations in NC Mo. Crystallographic analysis and image simulations reveal that the best way using HRTEM to study dislocations with edge components in bcc systems is to take images along <110> zone axis, from which it is possible to identify 1/2 <111> pure edge dislocations, and edge components of 1/2 <111> and <001> mixed dislocations. The <001> pure edge dislocations can only be identified from <100> zone axis. The high density of dislocations with edge components is believed to play a major role in the reduction of strain rate sensitivity in NC bcc metals and alloys.

  7. NO. REV. MO. _ ALSEP/LCRU EMC Test Results

    E-Print Network [OSTI]

    Rathbun, Julie A.

    NO. REV. MO. ATM 1050 _ ALSEP/LCRU EMC Test Results PAGE 1 OF 10 DATE 19 August 1971 The results of the ALSEP/LCRU EMC test are reported in this ATM. C~.·--~ s--·~e'Jn~,__')!).Prepared by:__~~~"f--.;;.~-------- Approved by: ~JM.MD. ithian #12;NO. RIV. NO. ATM 1050 ALSEP/LCRU EMC Test Results 2 10PAGE OF Aall

  8. Long-term corrosion of Cr-Mo steels in superheated steam at 482 and 538/sup 0/C. [21/4 Cr-1 Mo; 9 Cr-1 Mo; Sumitomo 9 Cr-2 Mo; Sandvik HT-9

    SciTech Connect (OSTI)

    Griess, J.C.; DeVan, J.H.; Maxwell, W.A.

    1980-01-01T23:59:59.000Z

    The corrosion of several Cr-Mo ferritic steels was investigated in superheated steam at an operating power plant. Tests were conducted at 482 and 538/sup 0/C (900 and 1000/sup 0/F) in a once-through loop for times up to 28,000 h. Chromium concentrations ranged from 2.0 to 11.3%, and the effect of surface preparation on corrosion was investigated. Only one of many specimens showed evidence of exfoliation at 482/sup 0/C, but at 538/sup 0/C exfoliation occurred on at least some of the specimens of most materials; the exceptions were the alloy with the highest chromium content (Sandvik HT-9), one heat of 9 Cr-1 Mo steel with the highest silicon content, and Sumitomo 9 Cr-2 Mo steel, which was in test for only 19,000 h. Parabolic oxidation kinetics adequately described the corrosion process for about the first year, after which corrosion rates were constant and lower than predicted from extrapolation of the initial part of the penetration versus time curves. With chromium concentrations between 2 and 9%, corrosion behavior was independent of chromium content, and corrosion was only slightly less with Sandvik HT-9. Corrosion was nearly independent of surface preparation, but in two cases the presence of mill scale on the surface prior to steam exposure seemed to retard oxidation in steam. 11 figures, 5 tables.

  9. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle [Savannah River Site (SRS), Aiken, SC (United States); Marra, James [Savannah River Site (SRS), Aiken, SC (United States); Fox, Kevin [Savannah River Site (SRS), Aiken, SC (United States); Reppert, Jason [Savannah River Site (SRS), Aiken, SC (United States); Crum, Jarrod [Paci fic Northwest National Laboratory , Richland, WA (United States); Tang, Ming [Los Alamos National Laboratory , Los Alamos, NM (United States)

    2012-09-17T23:59:59.000Z

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  10. High-performance MoS{sub 2} transistors with low-resistance molybdenum contacts

    SciTech Connect (OSTI)

    Kang, Jiahao; Liu, Wei; Banerjee, Kaustav, E-mail: kaustav@ece.ucsb.edu [Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106 (United States)

    2014-03-03T23:59:59.000Z

    In this Letter, molybdenum (Mo) is introduced and evaluated as an alternative contact metal to atomically-thin molybdenum disulphide (MoS{sub 2}), and high-performance field-effect transistors are experimentally demonstrated. In order to understand the physical nature of the interface and highlight the role of the various factors contributing to the Mo-MoS{sub 2} contacts, density functional theory (DFT) simulations are employed, which reveal that Mo can form high quality contact interface with monolayer MoS{sub 2} with zero tunnel barrier and zero Schottky barrier under source/drain contact, as well as an ultra-low Schottky barrier (0.1?eV) at source/drain-channel junction due to strong Fermi level pinning. In agreement with the DFT simulations, high mobility, high ON-current, and low contact resistance are experimentally demonstrated on both monolayer and multilayer MoS{sub 2} transistors using Mo contacts. The results obtained not only reveal the advantages of using Mo as a contact metal for MoS{sub 2} but also highlight the fact that the properties of contacts with 2-dimensional materials cannot be intuitively predicted by solely considering work function values and Schottky theory.

  11. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01T23:59:59.000Z

    Mn-Si (red squares) and Mn-Ge distances (blue circles) d asof the number of Si or Ge nearest neighbours N c ; (c) localthree Mn atoms with different N c in a-Mn 0.094 Ge 0.906 .

  12. El-Mo’alla to El-Deir

    E-Print Network [OSTI]

    Manassa, Colleen

    2011-01-01T23:59:59.000Z

    stopping point along the Wadi Falaj al-Hunud Road.rock inscriptions 1 - 45 and Wadi el-Hôl rock inscriptionsby the author. Figure 2. Wadi Falaj al-Hunud. Photograph by

  13. Cumulative Effects Guidance 2007 MnDOT Environmental

    E-Print Network [OSTI]

    Minnesota, University of

    relevant for actions requiring an environmental impact statement § Analysis for projects processed as EACumulative Effects Guidance 2007 MnDOT Environmental Stewardship & Streamlining Workshop Presented by Dave Gamble Federal Highway Administration Resource Center Environmental Technical Service Team #12

  14. Transverse acoustic actuation of Ni-Mn-Ga single crystals

    E-Print Network [OSTI]

    Simon, Jesse Matthew

    2007-01-01T23:59:59.000Z

    Two methods for the transverse acoustic actuation of {110}-cut Ni-Mn-Ga single crystals are discussed. In this actuation mode, crystals are used that have the {110}- type twinning planes parallel to the base of the crystal. ...

  15. PRECIPITATION-STRENGTHENED AUSTENITIC FE-MN-TI ALLOYS

    E-Print Network [OSTI]

    Chiang, K.-M.

    2010-01-01T23:59:59.000Z

    energy spectrums showing that precipitates are rich in titanium, andtitanium additions can reduce the austenitic stacking fault energyfault energy of the Fe-Mn austenite is lowered by titanium

  16. Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

    E-Print Network [OSTI]

    Marinescu, Smaranda C.

    Exposure of heptane solutions of Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OAr) (1a; Ar = 2,6-diisopropylphenyl), Mo(NAr)(CHCMe3)(Me2Pyr)[OCMe(CF3)2] (1b), and Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OSiPh3) (1c) to one atmosphere of ethylene for 12 h ...

  17. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

    SciTech Connect (OSTI)

    Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

    2010-01-01T23:59:59.000Z

    {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

  18. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

    2014-09-30T23:59:59.000Z

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  19. Ambi-site substitution of Mn in lanthanum germanate apatites

    SciTech Connect (OSTI)

    Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2009-08-05T23:59:59.000Z

    A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

  20. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect (OSTI)

    Washington Division of URS

    2008-07-01T23:59:59.000Z

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  1. Phase transitions in the adsorption system Li/Mo(112)

    E-Print Network [OSTI]

    Fedorus, A.; Kolthoff, D.; Koval, V.; Lyuksyutov, Igor F.; Naumovets, AG; Pfnur, H.

    2000-01-01T23:59:59.000Z

    limit can be quasi-one-dimensional. Such model systems are formed upon submonolayer adsorption on surfaces with strongly an- PRB 620163-1829/2000/62~4!/2852~10!/$15.00 n system Li?Mo?112? ,1,3 A. G. Naumovets,1 and H. Pfnu?r2,* , Prospect Nauki 46... W/Re thermocouple and was con- trolled by a computerized feedback circuit with a resolution of 0.01 K. The source of lithium was constructed and outgassed as PRB 62 PHASE TRANSITIONS IN TH described in Ref. 6. The LEED patterns have been taken...

  2. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, Sherry L. (Pleasanton, CA); Vernon, Stephen P. (Pleasanton, CA); Stearns, Daniel G. (Los Altos, CA)

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO.sub.2 overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  3. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, S.L.; Vernon, S.P.; Stearns, D.G.

    1997-12-16T23:59:59.000Z

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO{sub 2} overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates. 5 figs.

  4. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp - CTOregonPetrolite Corp - MO 08 FUSRAP

  5. Estimations of Mo X-pinch plasma parameters on QiangGuang-1 facility by L-shell spectral analyses

    SciTech Connect (OSTI)

    Wu, Jian; Qiu, Aici [State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Shaanxi 710049 (China) [State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Shaanxi 710049 (China); State Key Laboratory of Intense Pulsed Radiation Simulation and Effect, Northwest Institute of Nuclear Technology, Xi'an 710024 (China); Li, Mo; Wang, Liangping; Wu, Gang; Ning, Guo; Qiu, Mengtong [State Key Laboratory of Intense Pulsed Radiation Simulation and Effect, Northwest Institute of Nuclear Technology, Xi'an 710024 (China)] [State Key Laboratory of Intense Pulsed Radiation Simulation and Effect, Northwest Institute of Nuclear Technology, Xi'an 710024 (China); Li, Xingwen [State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Shaanxi 710049 (China)] [State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Shaanxi 710049 (China)

    2013-08-15T23:59:59.000Z

    Plasma parameters of molybdenum (Mo) X-pinches on the 1-MA QiangGuang-1 facility were estimated by L-shell spectral analysis. X-ray radiation from X-pinches had a pulsed width of 1 ns, and its spectra in 2–3 keV were measured with a time-integrated X-ray spectrometer. Relative intensities of spectral features were derived by correcting for the spectral sensitivity of the spectrometer. With an open source, atomic code FAC (flexible atomic code), ion structures, and various atomic radiative-collisional rates for O-, F-, Ne-, Na-, Mg-, and Al-like ionization stages were calculated, and synthetic spectra were constructed at given plasma parameters. By fitting the measured spectra with the modeled, Mo X-pinch plasmas on the QiangGuang-1 facility had an electron density of about 10{sup 21} cm{sup ?3} and the electron temperature of about 1.2 keV.

  6. Tunneling spectroscopy of superconducting MoN and NbTiN grown by atomic layer deposition

    SciTech Connect (OSTI)

    Groll, Nickolas R., E-mail: ngroll@anl.gov; Klug, Jeffrey A.; Claus, Helmut; Pellin, Michael J.; Proslier, Thomas, E-mail: proslier@anl.gov [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Cao, Chaoyue; Becker, Nicholas G.; Zasadzinski, John F. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, Illinois Institute of Technology, Chicago, Illinois 60616 (United States); Altin, Serdar [Fen Edebiyat Fakultesi, Fizik Bolumu, Inonu Universitesi, 44280 Malatya (Turkey)

    2014-03-03T23:59:59.000Z

    A tunneling spectroscopy study is presented of superconducting MoN and Nb{sub 0.8}Ti{sub 0.2}N thin films grown by atomic layer deposition (ALD). The films exhibited a superconducting gap of 2?meV and 2.4?meV, respectively, with a corresponding critical temperature of 11.5?K and 13.4?K, among the highest reported T{sub c} values achieved by the ALD technique. Tunnel junctions were obtained using a mechanical contact method with a Au tip. While the native oxides of these films provided poor tunnel barriers, high quality tunnel junctions with low zero bias conductance (below ?10%) were obtained using an artificial tunnel barrier of Al{sub 2}O{sub 3} on the film's surface grown ex situ by ALD. We find a large critical current density on the order of 4?×?10{sup 6}?A/cm{sup 2} at T?=?0.8T{sub c} for a 60?nm MoN film and demonstrate conformal coating capabilities of ALD onto high aspect ratio geometries. These results suggest that the ALD technique offers significant promise for thin film superconducting device applications.

  7. Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility

    E-Print Network [OSTI]

    Minnesota, University of

    Application of Mn/DOT Utility Coordination Process to Local Agencies Based on national best practices, the Minnesota Department of Transportation (Mn/DOT) Utility Coordination Process incorporates Processes There are projects where the full process is not necessary. The Mn/DOT Utilities Manual provides

  8. Solid state phase equilibria and intermetallic compounds of the Al-Cr-Ho system

    SciTech Connect (OSTI)

    Pang, Mingjun [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China) [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); SAIC-GM-Wuling Automobile Co., Ltd., Liuzhou, Guangxi 545007 (China); Zhan, Yongzhong, E-mail: zyzmatres@yahoo.com.cn [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China)] [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)] [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

    2013-02-15T23:59:59.000Z

    The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C were experimentally investigated. The phase relations at 500 Degree-Sign C are governed by 14 three-phase regions, 29 two-phase regions and 15 single-phase regions. The existences of 10 binary compounds and 2 ternary phases have been confirmed. Al{sub 11}Cr{sub 2}, Al{sub 11}Cr{sub 4} and Al{sub 17}Ho{sub 2} were not found at 500 Degree-Sign C. Crystal structures of Al{sub 9}Cr{sub 4} and Al{sub 8}Cr{sub 4}Ho were determined by the Rietveld X-ray powder data refinement. Al{sub 9}Cr{sub 4} was found to exhibit cubic structure with space group I4-bar 3m (no. 217) and lattice parameters a=0.9107(5) nm. Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} structure type with space group I4/mmm (no. 139) and lattice parameters a=0.8909(4) nm, c=0.5120(5) nm. It is concluded that the obtained Al{sub 4}Cr phase in this work should be {mu}-Al{sub 4}Cr by comparing with XRD pattern of the hexagonal {mu}-Al{sub 4}Mn compound. - Graphical abstract: The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Al-Cr-Ho system has been investigated. Black-Right-Pointing-Pointer Al{sub 9}Cr{sub 4} has cubic structure with space group I4-bar 3m. Black-Right-Pointing-Pointer Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} type with space group I4/mmm. Black-Right-Pointing-Pointer Al{sub 4}Cr phase is {mu}-type at 500 Degree-Sign C.

  9. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01T23:59:59.000Z

    Magnetization data for a-Mn 0.15 Ge 0.85 ?lms mea- suredSi 1?x and a-Mn x Ge 1?x samples. . . . . . . . . . . . . .both a-Mn x Si 1?x and a-Mn x Ge 1?x as a func- tion of Mn

  10. Identification of single nucleotides in MoS2 nanopores

    E-Print Network [OSTI]

    Jiandong Feng; Ke Liu; Roman D. Bulushev; Sergey Khlybov; Dumitru Dumcenco; Andras Kis; Aleksandra Radenovic

    2015-05-07T23:59:59.000Z

    Ultrathin membranes have drawn much attention due to their unprecedented spatial resolution for DNA nanopore sequencing. However, the high translocation velocity (3000-50000 nt/ms) of DNA molecules moving across such membranes limits their usability. To this end, we have introduced a viscosity gradient system based on room-temperature ionic liquids (RTILs) to control the dynamics of DNA translocation through a nanometer-size pore fabricated in an atomically thin MoS2 membrane. This allows us for the first time to statistically identify all four types of nucleotides with solid state nanopores. Nucleotides are identified according to the current signatures recorded during their transient residence in the narrow orifice of the atomically thin MoS2 nanopore. In this novel architecture that exploits high viscosity of RTIL, we demonstrate single-nucleotide translocation velocity that is an optimal speed (1-50 nt/ms) for DNA sequencing, while keeping the signal to noise ratio (SNR) higher than 10. Our findings pave the way for future low-cost and rapid DNA sequencing using solid-state nanopores.

  11. Characterization of U-Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

    2012-11-07T23:59:59.000Z

    Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

  12. A comparison of alumina, carbon, and carbon-covered alumina as supports for Ni-Mo-F additives: Carbon deposition and model compound reaction studies

    SciTech Connect (OSTI)

    Boorman, P.M.; Chong, K.; Kydd, R.A.; Lewis, J.M. (Univ. of Calgary, Alberta (Canada))

    1991-04-01T23:59:59.000Z

    Fluoride-promoted Ni-Mo catalysts supported on alumina, carbon, and carbon-coveres alumina have been investigated for their activity in cumene cracking, hydrocracking (reduced and sulfided forms), and thiophene HDS. The carbon-covered alumina was prepared by pyrolysis of cyclohexene over either {gamma}-alumina or boehmite and the carbon deposition followed adsorption isotherm-type behavior. The cumene reaction studies indicate that the resulting support system successfully merges the properties of carbon and alumina, possessing improved dehydrogenation-hydrogenation functionality due to carbon and acidic properties due to alumina, such as the generation of Broensted acidity upon fluoride impregnation. In the thiophene HDS reaction the catalyst activities followed the order Al{sub 2} > C-Al{sub 2}O{sub 3} > C, suggesting that alumina, and not carbon, is the superior HDS support at atmospheric H{sub 2} pressure and at the metal loadings used in this study. Carbon deposition onto Ni-Mo-F/Al{sub 2}O{sub 3} catalysts revealed that cyclohexene polymerization is promoted by the metal centers, resulting in multilayer islands on these sites, and not by the fluoride-associated Broensted acid sites. However, the Broensted acid sites do promote coke formation when the polymerization reaction is easier such as for {alpha}-methylstyrene.

  13. Hydrothermal synthesis and catalytic properties of {alpha}- and {beta}-MnO{sub 2} nanorods

    SciTech Connect (OSTI)

    Cao, Guangsheng, E-mail: daqingcgs@163.com [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China); Su, Ling; Zhang, Xiaojuan; Li, Hui [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)

    2010-04-15T23:59:59.000Z

    One-dimensional {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} single-crystalline nanostructures were prepared by hydrothermal process. The products were characterized in detail by multiform techniques: X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Experimental results indicate that the temperature plays important roles in determining produce {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods. In addition, the as-prepared {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods showed excellent catalytic performance in the Fenton-like reaction.

  14. Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses

    E-Print Network [OSTI]

    Osterloh, Frank

    -iodopropionic acid treated LiMo3Se3 nanowire bundles with oleic acid-stabilized Fe3O4 nanoparticles of 2.8, 5Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses Frank E. Osterloh,*, Hiroki A scaleable chemical approach to functional nanoscale analogues of the magnetic compasses in magnetotactic

  15. Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,,

    E-Print Network [OSTI]

    Javey, Ali

    Hole Selective MoOx Contact for Silicon Solar Cells Corsin Battaglia,,, Xingtian Yin,,,§, Maxwell Laboratory, Xi'an Jiaotong University, Xi'an, 710049 Shaanxi, People's Republic of China Joint Center/silicon solar cell with a power conversion efficiency of 14.3%. While MoOx is commonly considered

  16. MoIAC Pre-Audit Form Ways to submit this form

    E-Print Network [OSTI]

    Noble, James S.

    information: #12;MoIAC Pre-Audit Form Major Energy Consuming Equipment: Please provide informationMoIAC Pre-Audit Form Ways to submit this form: 1. Fill up the form and fax it to 573-882-2693 Attn: Dr. Bin Wu 2. Print and return this form by mail to: Dr. Bin Wu University of Missouri

  17. Adsorption studies of Mo and V onto ferrihydrite *, L. G. BENNING

    E-Print Network [OSTI]

    Benning, Liane G.

    Adsorption studies of Mo and V onto ferrihydrite L. BRINZA 1, *, L. G. BENNING 1 AND P. J. STATHAM-sorbate experiments, 100% adsorption was observed at pH values below 6 and 8, respectively. Above the point of zero charge (PZC = 7.97) of FHY, the adsorption efficiency for Mo dropped dramatically (20% at pH 8) while V

  18. Stability of Graphene doping with MoO_3 and I_2

    E-Print Network [OSTI]

    D’Arsié, Lorenzo; Esconjauregui, Santiago; Weatherup, Robert; Guo, Yuzheng; Bhardwaj, Sunil; Centeno, Alba; Zurutuza, Amaia; Cepek, Cinzia; Robertson, John

    2014-09-08T23:59:59.000Z

    We dope graphene by evaporation of MoO_3 or by solution-deposition of I_2 and assess the doping stability for its use as transparent electrodes. Electrical measurements show that both dopants increase the graphene sheet conductivity and find that Mo...

  19. Student Financial Aid 11 Jesse Hall University of Missouri Columbia Columbia, MO 65211-1600

    E-Print Network [OSTI]

    Taylor, Jerry

    Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE;Student Financial Aid 11 Jesse Hall University of Missouri ­ Columbia Columbia, MO 65211-1600 PHONE (573 ________________________________________________________________________________________________________________________ Name of Host Institution (College or University you will be attending or taking additional classes

  20. Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+

    E-Print Network [OSTI]

    Huang, Jiaxing

    Ligand Conjugation of Chemically Exfoliated MoS2 Stanley S. Chou,+ Mrinmoy De,+ Jaemyung Kim,+ Segi and chemical properties. Here, we demonstrate ligand conjugation of chemically exfoliated MoS2 using thiol-nitrilotriacetic acid chelation.13 However, colloidal sur- face modification of water dispersible, chemically exfoliated

  1. Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co-Mo

    E-Print Network [OSTI]

    Resasco, Daniel

    Characterization of Single-Walled Carbon Nanotubes (SWNTs) Produced by CO Disproportionation on Co Received November 15, 2001. Revised Manuscript Received February 6, 2002 The disproportionation of CO over Co-Mo/SiO2 catalysts with low Co/Mo ratios results in a high selectivity to single-walled carbon

  2. Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant

    E-Print Network [OSTI]

    Shull, Kenneth R.

    ! ! ! Corrosion Behavior of Solution- Annealed CoCrMo Medical Implant Alloys Pooja Panigrahi University June 6, 2011 #12;! ! ""! Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant Alloys and Applied Sciences Northwestern University June 6, 2011 Abstract Corrosion behavior of solution annealed

  3. Double beta decays and solar neutrinos with 100 MOON(Mo Observatory Of Neutrinos)

    E-Print Network [OSTI]

    Washington at Seattle, University of

    nuclear laboratory for spectroscopic studies of neutrinos Neutrinos are key particles for new frontiers) are sensitive and realistic experiments for studying the Majorana nature of the neutrino and the absolute massDouble beta decays and solar neutrinos with 100 Mo ­MOON(Mo Observatory Of Neutrinos)­ May 24, 2005

  4. Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors

    E-Print Network [OSTI]

    Fischer, Emily V.

    Posting type Advisory Subject Shifts in Mo-anode XRF element calibration factors Module/Species A@crocker.ucdavis.edu Supporting information A molybdenum-anode XRF instrument is used to analyze the heavier elements (Ni, Cu, Zn with lighter deposits were acquired and used in the Mo-anode XRF system. The new calibration foils resulted

  5. A comparative study of magnetic behaviors in TbNi{sub 2}, TbMn{sub 2} and TbNi{sub 2}Mn

    SciTech Connect (OSTI)

    Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Md Din, M. F.; Hong, F.; Cheng, Z. X.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Kennedy, S. J.; Studer, A. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China)

    2014-05-07T23:59:59.000Z

    All TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn compounds exhibit the cubic Laves phase with AB{sub 2}-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi{sub 2}Mn is 1:3. Rietveld refinement indicates that in TbNi{sub 2}Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a?=?14.348?Å (space group F-43?m), 7.618?Å, and 7.158?Å (space group Fd-3?m) for TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn, respectively. The magnetic transition temperatures T{sub C} were found to be T{sub C}?=?38?K and T{sub C}?=?148?K for TbNi{sub 2} and TbNi{sub 2}Mn, respectively, while two magnetic phase transitions are detected for TbMn{sub 2} at T{sub 1}?=?20?K and T{sub 2}?=?49?K. Clear magnetic history effects in a low magnetic field are observed in TbMn{sub 2} and TbNi{sub 2}Mn. The magnetic entropy changes have been obtained.

  6. Spin dependent transport properties of Mn-Ga/MgO/Mn-Ga magnetic tunnel junctions with metal(Mg, Co, Cr) insertion layer

    SciTech Connect (OSTI)

    Liang, S. H.; Tao, L. L.; Liu, D. P., E-mail: dpliu@iphy.ac.cn; Han, X. F., E-mail: xfhan@iphy.ac.cn [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Lu, Y. [Institut Jean Lamour, UMR 7198, CNRS-Nancy Université, BP 239, 54506 Vandoeuvre (France)

    2014-04-07T23:59:59.000Z

    We report a first principles theoretical investigation of spin polarized quantum transport in Mn{sub 2}Ga/MgO/Mn{sub 2}Ga and Mn{sub 3}Ga/MgO/Mn{sub 3}Ga magnetic tunneling junctions (MTJs) with the consideration of metal(Mg, Co, Cr) insertion layer effect. By changing the concentration of Mn, our calculation shows a considerable disparity in transport properties: A tunneling magnetoresistance (TMR) ratio of 852% was obtained for Mn{sub 2}Ga-based MTJs, however, only a 5% TMR ratio for Mn{sub 3}Ga-based MTJs. In addition, the influence of insertion layer has been considered in our calculation. We found the Co insertion layer can increase the TMR of Mn{sub 2}Ga-based MTJ to 904%; however, the Cr insertion layer can decrease the TMR by 668%; A negative TMR ratio can be obtained with Mg insertion layer. Our work gives a comprehensive understanding of the influence of different insertion layer in Mn-Ga based MTJs. It is proved that, due to the transmission can be modulated by the interfacial electronic structure of insertion, the magnetoresistance ratio of Mn{sub 2}Ga/MgO/Mn{sub 2}Ga MTJ can be improved by inserting Co layer.

  7. AgriculturAl Development

    E-Print Network [OSTI]

    1 SLU Global AgriculturAl ScienceS for globAl Development -- Slu's contribution #12;2 the mission of the Swedish university of Agricultural Sciences (Slu) is "to develop the understanding, management for global Development (pgu). research capacity building provision of expertise Agricultural Sciences

  8. Photo-oxidation method using MoS2 nanocluster materials

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

  9. Unique light-induced degradation in yellow-emitting K?SiF?:Mn²? phosphor

    SciTech Connect (OSTI)

    Oyama, Takuya; Adachi, Sadao, E-mail: adachi@el.gunma-u.ac.jp [Division of Electronics and Informatics, Faculty of Science and Technology, Gunma University, Kiryu-shi, Gunma 376-8515 (Japan)

    2014-10-07T23:59:59.000Z

    Photo-induced luminescence intensity degradation in yellow-emitting K?SiF?:Mn²? phosphor is studied using x-ray diffraction measurement, photoluminescence (PL) analysis, PL excitation (PLE) spectroscopy, PL decay analysis, and electron spin resonance (ESR) measurement. The yellow-emitting K?SiF?:Mn²? phosphor exhibits remarkable degradation in the PL intensity under Xe lamp exposure. Coherent laser irradiation also induces degradation and its degree is in the order of He–Cd (? = 325 nm) > Ar? (488 nm) > He–Ne laser (632.8 nm). The degradation mechanism is proposed to be due to change in the valence state of manganese ions from Mn²? to Mn³? by the photooxidation (Mn²? ? Mn³?) or disproportionation reaction (2Mn²? ? Mn? + Mn³?). The ESR measurement confirms the decreased Mn²? spin density in the sample exposed with Xe lamp. The PLE spectrum suggests that the excitation of Mn³? ions occurs through energy transfer upon absorption of exciting radiation by the Mn²? ions. Thermal annealing of the degraded samples at ?200 °C causes a blueshift in the PL emission band with an appearance of the Mn??-related sharp red emission lines.

  10. Phase transformation of ZnMoO{sub 4} by localized thermal spike

    SciTech Connect (OSTI)

    Agarwal, D. C.; Avasthi, D. K.; Kabiraj, D. [Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi 110067 (India); Varma, S. [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005 (India); Kremer, Felipe; Ridgway, M. C. [Australian National University, Canberra ACT 0200 (Australia)

    2014-04-28T23:59:59.000Z

    We show that ZnMoO{sub 4} remains in stable phase under thermal annealing up to 1000?°C, whereas it decomposes to ZnO and MoO{sub 3} under transient thermal spike induced by 100?MeV Ag irradiation. The transformation is evidenced by X-ray diffraction (XRD), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). Thin films of ZnMoO{sub 4} were synthesized by thermal evaporation and subsequent annealing in oxygen ambient at 600?°C for 4?h. XRD results show that as the irradiation fluence increases, the peak related to ZnMoO{sub 4} decreases gradually and eventually disappear, whereas peaks related to ZnO grow steadily up to fluence of 3?×?10{sup 12} ions/cm{sup 2} and thereafter remain stable till highest fluence. This indicates that polycrystalline ZnMoO{sub 4} film has transformed to polycrystalline ZnO thin film. The Raman lines related to ZnMoO{sub 4} are observed to have disappeared with increasing irradiation fluence. XPS results show modification in bonding and depletion of Mo from near surface region after the ion irradiation. Cross-sectional transmission electron microscopy result shows the formation of ion track of diameter 12–16?nm. These results demonstrate that ion beam methods provide the means to control phase splitting of ZnMoO{sub 4} to ZnO and MoO{sub 3} within nanometric dimension along the ion track. The observation of phase splitting and Mo loss are explained in the framework of ion beam induced thermal spike formalism.

  11. HgMn Stars as apparent X-ray emitters

    E-Print Network [OSTI]

    Hubrig, S; Mathys, G

    1998-01-01T23:59:59.000Z

    In the ROSAT all-sky survey 11 HgMn stars were detected as soft X-ray emitters (Berghoefer, Schmitt & Cassinelli 1996). Prior to ROSAT, X-ray observations with the Einstein Observatory had suggested that stars in the spectral range B5-A7 are devoid of X-ray emission. Since there is no X-ray emitting mechanism available for these stars (also not for HgMn stars), the usual argument in the case of an X-ray detected star of this spectral type is the existence of an unseen low-mass companion which is responsible for the X-ray emission. The purpose of the present work is to use all available data for our sample of X-ray detected HgMn stars and conclude on the nature of possible companions.

  12. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    SciTech Connect (OSTI)

    Lendinez, S. [Univ. de Barcelona, Barcelona, Spain (Europe); Billinge, S. J. L. [Columbia Univ., New York, NY (United States); Zarzuela, R. [Univ. de Barcelona, Barcelona, Spain (Europe); Tejada, J. [Univ. de Barcelona, Barcelona, Spain (Europe); Terban, M. W. [Columbia Univ., New York, NY (United States); Espin, J. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Imaz, I. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Maspoch, D. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Chudnovsky, E. M. [City Univ. of New York, Bronx, NY (United States)

    2015-01-01T23:59:59.000Z

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for a single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.

  13. Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal Programmed Desorption

    E-Print Network [OSTI]

    Goodman, Wayne

    Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal, 2000 The adsorption of methanol (CH3OH) and water (D2O) on the MgO(100)/Mo(100) surface at 100 K has covered MgO(100)/Mo(100) surface. On the other hand, the formation of a methanol multilayer desorption

  14. Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Influence of Co/Mo Ratio on Synthesis of Single-Walled Carbon Nanotubes from Carbon Monoxide, Bunkyo-ku, Tokyo 113-8656 Co and Mo are often used as catalysts for the catalytic chemical vapor in synthesizing random, vertical and parallel aligned SWNTs on Co and Mo dip-coated quartz substrates from carbon

  15. Assessment of the Diffusive Gradients in Thin-films (DGT) technique to assess the plant availability of Mn in soils.

    E-Print Network [OSTI]

    Mundus, Simon; Husted, Søren; Lombi, Enzo

    2009-01-01T23:59:59.000Z

    predicts copper availability to plants. EnvironmentalAttempts to assess Mn availability have been impeded due towill influence the Mn availability. Often flooding of soils

  16. The Use of Silica Coated MnO Nanoparticles to Control MRI Relaxivity in Response to Specific Physiological Changes

    E-Print Network [OSTI]

    Krishnan, Kannan M.

    -tracing could be observed due to the released Mn2þ . Intravenous infusion of MnO@SiO2 particles showed little

  17. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    E-Print Network [OSTI]

    Chen, Jiajun

    2010-01-01T23:59:59.000Z

    of nanosized LiMnPO 4 by combustion synthesis Figure 2. X-a) nanometric LiMnPO 4 made by combustion synthesis and b)typically formed by combustion synthesis. The average

  18. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    E-Print Network [OSTI]

    Chen, Jiajun

    2008-01-01T23:59:59.000Z

    of nanosized LiMnPO 4 by combustion synthesis Figure 2. X-a) nanometric LiMnPO 4 made by combustion synthesis and b)typically formed by combustion synthesis. The average

  19. Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)

    E-Print Network [OSTI]

    Guchhait, S.

    2011-01-01T23:59:59.000Z

    segregation in Mn-doped Ge”, Journal of Applied Physics 101,Room-temperature ferromagnetism in Ge 1-x Mn x nanowires”,BC high-?/metal gate Ge/C alloy pMOSFETs fabricated directly

  20. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01T23:59:59.000Z

    Mn)As: A new diluted magnetic semiconductor based on GaAs.Mn x Ge 1-x diluted magnetic semiconductor: experiment andx Si 1-x amorphous magnetic semiconductor. Phys. Rev. B 67 ,

  1. Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)

    E-Print Network [OSTI]

    Guchhait, S.

    2011-01-01T23:59:59.000Z

    group-IV-based dilute magnetic semiconductors by electronicMn x Ge 1-x dilute magnetic semiconductor”, Applied Physicsamorphous Ge 1-x Mn x magnetic semiconductor films”, Journal

  2. Mn12-acetate thin film patterns and their interaction with superconductors

    E-Print Network [OSTI]

    Kim, Kyongwan

    2009-05-15T23:59:59.000Z

    Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

  3. On deformation twinning in a 17.5%Mn-TWIP steel: A physically...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological model. On deformation twinning in a 17.5%Mn-TWIP steel: A physically-based phenomenological...

  4. Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal

    E-Print Network [OSTI]

    , and absorption spectroscopy. Fe is speciated as goethite, and Mn as romanechite (psilomelane) and 10 A is separated from the other type by goethite. The binary Mn oxide banding pattern is interpreted by a two

  5. Low-temperature magnetization of (Ga,Mn) As semiconductors

    E-Print Network [OSTI]

    Jungwirth, T.; Masek, J.; Wang, KY; Edmonds, KW; Sawicki, M.; Polini, M.; Sinova, Jairo; MacDonald, AH; Campion, RP; Zhao, LX; Farley, NRS; Johal, TK; van der Laan, G.; Foxon, CT; Gallagher, BL.

    2006-01-01T23:59:59.000Z

    temperature magnetometry and XMCD experiments. A series of #1;Ga,Mn#2;As films with Mn content varying between 1.7?6.7 % in the SQUID experiments and between 2.2 and 8.4 % in the XMCD experiments were grown by low-temperature molecular beam epitaxy #1;MBE.... Magnetometry The magnetic moment of the samples is measured in a SQUID magnetometer, at 5 K and under a 0.3 T external magnetic field. The external field is necessary to overcome in-plane anisotropy fields, so that the magnetization is aligned...

  6. Electron Band Structure of MnGaN Dimiter Alexandrov1

    E-Print Network [OSTI]

    Dietz, Nikolaus

    to this orbital to be occupied. LCAO electron band structure of wurtzite MnxGa1-xN for points c1 and v15 ( = 1 of the wurtzite MnxGa1-xN are determined as well. INTRODUCTION The MnxGa1-xN semiconductor alloy is important model the MnGaN alloy on Mn content. Segregated Mn species in wurtzite GaN containing Mn

  7. Heat treatment effects on microstructure and magnetic properties of MnZn ferrite powders

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Heat treatment effects on microstructure and magnetic properties of Mn­Zn ferrite powders Ping Hu Available online 6 September 2009 Keywords: Mn­Zn ferrite Heat treatment Microstructure Magnetic property a b s t r a c t Mn­Zn ferrite powders (Mn0.5Zn0.5Fe2O4) were prepared by the nitrate­citrate auto

  8. Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa

    SciTech Connect (OSTI)

    Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

    2011-05-03T23:59:59.000Z

    Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

  9. Exchange interaction in hexagonal MnRhP from first-principles studies

    SciTech Connect (OSTI)

    Liu, X. B., E-mail: liuxubo@uta.edu; Zhang, Qiming; Ping Liu, J., E-mail: pliu@uta.edu [Department of Physics, University of Texas at Arlington, Arlington, Texas 76019 (United States); Yue, M. [College of Material Science and Engineering, Beijing University of Technology, 100022 Beijing (China); Altounian, Z. [Centre for the Physics of Materials and Department of Physics, McGill University, Montreal, Quebec H3A 2T8 (Canada)

    2014-05-07T23:59:59.000Z

    Electronic structure and magnetic properties for MnRhP have been studied from a first-principles density functional calculation. The calculated lattice constants, a?=?6.228 Å and c?=?3.571?Å, are in good agreement with the experimental values of a?=?6.223 Å and c?=?3.585?Å. The calculated moment of Mn is 3.1 ?{sub B}/atom, resulting in a total moment of 3.0 ?{sub B}/atom due to small moments induced at Rh and P sites. The magnetic moment of Mn decreases with unit cell size. The exchange interactions are dominated by positive Mn-Mn exchange coupling (J{sub Mn?Mn}), implying a stable ferromagnetic ordering in Mn sublattice. In particular, J{sub Mn?Mn} shows a maximum value (1.5 mRy) at the the optimized unit cell size. The structural distortion or unit cell size change will affect J{sub Mn?Mn}, which is intimately related to the magneto-elastic and magneto-caloric effect.

  10. On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite

    SciTech Connect (OSTI)

    Kwon, K.D.; Refson, K.; Sposito, G.

    2009-06-01T23:59:59.000Z

    Photoreductive dissolution of layer type Mn(IV) oxides (birnessite) under sunlight illumination to form soluble Mn(II) has been observed in both field and laboratory settings, leading to a consensus that this process is a key driver of the biogeochemical cycling of Mn in the euphotic zones of marine and freshwater ecosystems. However, the underlying mechanisms for the process remain unknown, although they have been linked to the semiconducting characteristics of hexagonal birnessite, the ubiquitous Mn(IV) oxide produced mainly by bacterial oxidation of soluble Mn(II). One of the universal properties of this biogenic mineral is the presence of Mn(IV) vacancies, long-identified as strong adsorption sites for metal cations. In this paper, the possible role of Mn vacancies in photoreductive dissolution is investigated theoretically using quantum mechanical calculations based on spin-polarized density functional theory (DFT). Our DFT study demonstrates unequivocally that Mn vacancies significantly reduce the band-gap energy for hexagonal birnessite relative to a hypothetical vacancy-free MnO{sub 2} and thus would increase the concentration of photo-induced electrons available for Mn(IV) reduction upon illumination of the mineral by sunlight. Calculations of the charge distribution in the presence of vacancies, although not fully conclusive, show a clear separation of photo-induced electrons and holes, implying a slow recombination of these charge-carriers that facilitates the two-electron reduction of Mn(IV) to Mn(II).

  11. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    3, 1976 LBL-5401 l NICKEL-FREE Fe-12Mn-O. 2Ti ALLOY STEELowned rights. I v LBL-540l NICKEL-FREE Fe-12Mn-0.2Ti ALLOY94720 USA ABSTRACT A nickel-free Fe-12Mn-0.2Ti alloy steel

  12. LICENSE HISTORY MO.8 Petrolite Corporation, St. Louis

    Office of Legacy Management (LM)

    et al Multiple. . 70-621, 12-15-61, SNM license for 0.5 kg. of U-235, 93% enriched as a fuel loading and star-up curce for Webster Groves, Missouri reactor. l Discussion:...

  13. Investigation of the optical properties of MoS{sub 2} thin films using spectroscopic ellipsometry

    SciTech Connect (OSTI)

    Yim, Chanyoung; O'Brien, Maria; Winters, Sinéad [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); McEvoy, Niall [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Mirza, Inam; Lunney, James G. [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); School of Physics, Trinity College Dublin, Dublin 2 (Ireland); Duesberg, Georg S., E-mail: duesberg@tcd.ie [School of Chemistry, Trinity College Dublin, Dublin 2 (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Advanced Materials and BioEngineering Research (AMBER) Centre, Trinity College Dublin, Dublin 2 (Ireland)

    2014-03-10T23:59:59.000Z

    Spectroscopic ellipsometry (SE) characterization of layered transition metal dichalcogenide (TMD) thin films grown by vapor phase sulfurization is reported. By developing an optical dispersion model, the extinction coefficient and refractive index, as well as the thickness of molybdenum disulfide (MoS{sub 2}) films, were extracted. In addition, the optical band gap was obtained from SE and showed a clear dependence on the MoS{sub 2} film thickness, with thinner films having a larger band gap energy. These results are consistent with theory and observations made on MoS{sub 2} flakes prepared by exfoliation, showing the viability of vapor phase derived TMDs for optical applications.

  14. Masters of Nursing (MN) Degree Clinical Nurse Leader (CNL)

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Masters of Nursing (MN) Degree Clinical Nurse Leader (CNL) 4 Semester Program of Study Fall Design of Healthcare Delivery Systems ­ Lab (required) 1 (1 clinical lab) 611 Program Planning and Eval, Outcomes, & QI (required) 3 (3 lec) 510 Program Planning and Eval, Outcomes, & QI - Lab (required) 1 (1

  15. Masters of Nursing (MN) Degree Clinical Nurse Leader (CNL)

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    , & QI (required) 3 (3 lec) 510 Program Planning and Eval, Outcomes, & QI - Lab (required) 1 (1 clinicalMasters of Nursing (MN) Degree Clinical Nurse Leader (CNL) 6 Semester Program of Study Fall Systems - Lab (required) 1 (1 clinical lab) 613 Finance and Budget (required) 2 6 (required) 612 Ethics

  16. Growing the renewable chemicals and advanced biofuels cluster in MN

    E-Print Network [OSTI]

    Levinson, David M.

    Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

  17. 1 Copyright 2006 by ASME Proceedings of MN2006

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    1 Copyright © 2006 by ASME Proceedings of MN2006 Multifunctional Nanocomposites 2006 September 20 of nanoparticles (including nanofibers and functional nanocomposites) in common fluids, have a potential to meet-physical characteristics. Development of new-hybrid, drag-reducing nanofluids may lead to enhanced flow and heat transfer

  18. Mn/DOT's Ombudsman Program Collaboration and Process

    E-Print Network [OSTI]

    Minnesota, University of

    Mn/DOT's Ombudsman Program Collaboration and Process #12;Overview Ombudsman exists to rebuild trust on the environmental and municipal consent processes can be critical #12;A Large Organization #12;Tragedy;Ombudsman Does Not... ·! Advocate for one party or point of view ·! Own any formal process or policy

  19. High damage-resistant Mo mirror for high-power TEA CO/sub 2/ laser systems

    SciTech Connect (OSTI)

    Ichikawa, Y.; Yoshida, K.; Tsunawaki, Y.; Yamanaka, M.; Yamanaka, T.; Yamanaka, C.; Okamoto, H.; Matsusue, N.; Kitajima, K.

    1987-09-01T23:59:59.000Z

    A high-purity molybdenum (Mo) mirror was developed by an electron-beam melting method (e.b.m. Mo mirror). For high-power TEA CO/sub 2/ laser, the e.b.m. Mo mirror has two to four times higher surface damage threshold than that of an Au-coated glass mirror and three times longer lifetime than that of a powder metallurgy Mo mirror (p.m. Mo mirror) when laser energy density lower than 60 J/cm/sup 2/ was irradiated with a 0.5-pps repetition rate. It was found that the difference between the e.b.m. Mo mirror and the p.m. Mo mirror at the laser-damage threshold was due to the five surface without voids and the small amount of impurities.

  20. 0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core

    E-Print Network [OSTI]

    Gilli, Adrian

    1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

  1. InteRventIonAL PAIn FoR MoRe InFoRMAtIon

    E-Print Network [OSTI]

    Thompson, Michael

    , SGB, Suprascapular, Piriformis, Ilioinguinal nerve, Joint block ­ Philip Peng 12:30-1:10 LuncH 01:10-02:00 Interventional cancer pain management ­ Celiac plexus, superior hypogastric plexus, Ganglion of impar block lumbar and cervical medial branch block ­ Anuj Bhatia, Howard Intrater 03:20-03:40 BReAk 03:40-04:30 SIJ

  2. Characterization and hydrodesulfurization activity of CoMo catalysts supported on sol-gel prepared Al2O3

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    catalyst that was designed and manufactured for deep HDS of diesel fuel fractions. Furthermore, the HDS, thiophene, DBT, 4,6-DMDBT 2 #12;1. Introduction The increasing demand for protection of the environment has content in diesel fuel in European countries has been reduced from 350 ppm to 50 ppm in 2005 [1]. To meet

  3. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    T. B. Bekker; N. Coron; F. A. Danevich; V. Ya. Degoda; A. Giuliani; V. D. Grigorieva; N. V. Ivannikova; M. Mancuso; P. de Marcillac; I. M. Moroz; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; V. I. Tretyak; M. Velazquez

    2014-12-17T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  4. Aboveground test of an advanced Li$_2$MoO$_4$ scintillating bolometer to search for neutrinoless double beta decay of $^{100}$Mo

    E-Print Network [OSTI]

    Bekker, T B; Danevich, F A; Degoda, V Ya; Giuliani, A; Grigorieva, V D; Ivannikova, N V; Mancuso, M; de Marcillac, P; Moroz, I M; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tretyak, V I; Velazquez, M

    2014-01-01T23:59:59.000Z

    Large lithium molybdate (Li$_2$MoO$_4$) crystal boules were produced by using the low thermal gradient Czochralski growth technique from deeply purified molybdenum. A small sample from one of the boules was preliminary characterized in terms of X-ray-induced and thermally-excited luminescence. A large cylindrical crystalline element (with a size of $\\oslash 40\\times40$ mm) was used to fabricate a scintillating bolometer, which was operated aboveground at $\\sim 15$ mK by using a pulse-tube cryostat housing a high-power dilution refrigerator. The excellent detector performance in terms of energy resolution and $\\alpha$ background suppression along with preliminary positive indications on the radiopurity of this material show the potentiality of Li$_2$MoO$_4$ scintillating bolometers for low-counting experiment to search for neutrinoless double beta decay of $^{100}$Mo.

  5. Temperature dependence of the on-resonance portion Mn-NMR spectrum of a Mn(IV,IV) dimer

    E-Print Network [OSTI]

    --the tightly coupled techniques of cutting-edge cryogenic NMR experiments and highly electron correlated of leading-edge cryogenic nuclear magnetic resonance (NMR) measurements and advanced electronic structure with experimentally measureable parameters such as electric field gradient (EFG) tensor, electron's g-factor, 55 Mn

  6. The Mn effect on magnetic structure of FeMn-B amorphous metals , D.M.C. Nicholson2

    E-Print Network [OSTI]

    Widom, Michael

    magnetization and high permeability, which make them a good candidate for magnetic core materials in transformers and electrical motors. Lately, high Mn content, Fe-based bulk amorphous metals have been movement during the quenching process is determined by molecular dynamics simulation using the Vienna Ab

  7. Atomistic simulation of the electronic states of adatoms in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Chang, Jiwon; Larentis, Stefano; Tutuc, Emanuel; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2014-04-07T23:59:59.000Z

    Using an ab initio density functional theory based electronic structure method, we study the effects of adatoms on the electronic properties of monolayer transition metal dichalcogenide Molybdenum-disulfide (MoS{sub 2}). We consider the 1st (Li, Na, K) and 7th (F, Cl, Br) column atoms and metals (Sc, Ti, Ta, Mo, Pd, Pt, Ag, Au). Three high symmetry sites for the adatom on the surface of monolayer MoS{sub 2} are examined as starting points to search for the most energetically stable configuration for each adatom-monolayer MoS{sub 2} system, as well as the type of associated bonding. For the most stable adatom positions, we characterize the emergence of adatom-induced electronic states including any dopant states.

  8. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

    SciTech Connect (OSTI)

    Sen, H. Sener [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Sahin, H.; Peeters, F. M. [Department of Physics, University of Antwerp, 2610 Antwerp (Belgium); Durgun, E., E-mail: durgun@unam.bilkent.edu.tr [UNAM-National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey)

    2014-08-28T23:59:59.000Z

    First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

  9. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan; Sadowski, Jerzy T.; Yeh, Po-Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Herman, Irving P.; Osgood, Jr., Richard M.; Sutter, Peter; et al

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss itsmore »possible origin.« less

  10. Substrate interactions with suspended and supported monolayer MoS?: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan [Columbia Univ., New York, NY (United States); Sadowski, Jerzy T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yeh, Po-Chun [Columbia Univ., New York, NY (United States); Zaki, Nader [Columbia Univ., New York, NY (United States); Zhang, Datong [Columbia Univ., New York, NY (United States); Liou, Jonathan T. [Columbia Univ., New York, NY (United States); Dadap, Jerry I. [Columbia Univ., New York, NY (United States); Herman, Irving P. [Columbia Univ., New York, NY (United States); Osgood, Jr., Richard M. [Columbia Univ., New York, NY (United States); Sutter, Peter [Brookhaven National Lab. (BNL), Upton, NY (United States); Barinov, Alexey [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy); Yablonskikh, Mikhail [Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy)

    2015-03-01T23:59:59.000Z

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS?) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS? elucidate the effects of interaction with a substrate. A suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS? crystals. For suspended MoS?, a careful investigation of the measured uppermost valence band gives an effective mass at ? and ? of 2.00m? and 0.43m?, respectively. We also measure an increase in the band linewidth from the midpoint of ?? to the vicinity of ? and briefly discuss its possible origin.

  11. Intrinsic Electronic Transport Properties of High-Quality Monolayer and Bilayer MoS[subscript 2

    E-Print Network [OSTI]

    Baugher, Britton W. H.

    We report electronic transport measurements of devices based on monolayers and bilayers of the transition-metal dichalcogenide MoS[subscript 2]. Through a combination of in situ vacuum annealing and electrostatic gating ...

  12. MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS

    E-Print Network [OSTI]

    Kusner, Robert B.

    MO"BIUS ENERGIES FOR KNOTS AND LINKS, SURFACES AND SUBMANIFOLDS energies, especially those which are invariant under M"obius transforma- tions of space. We describe computer experiments with such energies, and discuss ways of extending these to energies

  13. Isothermal activation of Mo2O5 ZSM-5 precursors during

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isothermal activation of Mo2O5 21 ­ZSM-5 precursors during methane reactions: effects of reaction to petrochemicals and liquid fuels and chemicals remains a formidable technological challenge.1 Exchanged cations

  14. AB INITIO Modeling of Thermomechanical Properties of Mo-Based Alloys for Fossil Energy Conversion

    SciTech Connect (OSTI)

    Ching, Wai-Yim

    2013-12-31T23:59:59.000Z

    In this final scientific/technical report covering the period of 3.5 years started on July 1, 2011, we report the accomplishments on the study of thermo-mechanical properties of Mo-based intermetallic compounds under NETL support. These include computational method development, physical properties investigation of Mo-based compounds and alloys. The main focus is on the mechanical and thermo mechanical properties at high temperature since these are the most crucial properties for their potential applications. In particular, recent development of applying ab initio molecular dynamic (AIMD) simulations to the T1 (Mo{sub 5}Si{sub 3}) and T2 (Mo{sub 5}SiB{sub 2}) phases are highlighted for alloy design in further improving their properties.

  15. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    E-Print Network [OSTI]

    Endrino, Jose L.

    2010-01-01T23:59:59.000Z

    dual-cathode arc deposition (PDC-FCVA) source containingand metal cathodes [2]. The PDC-FCVA system in combinationCu,Mo) incorporation in a-C by PDC-FCVA. The modification of

  16. Electronic structure and magnetism of Mn{sub 12}O{sub 12} clusters

    SciTech Connect (OSTI)

    Pederson, M.R. [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States)] [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States); Khanna, S.N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    1999-01-01T23:59:59.000Z

    To address the ferrimagnetic state of the Mn{sub 12} acetate matrix [Mn{sub 12}O{sub 12}(CH{sub 3}COO){sub 16}(H{sub 2}O){sub 4}] we have performed all-electron gradient-corrected density-functional calculations on (MnO){sub n} with n=1, 2, 4, and 12. In contrast to bulk MnO which is antiferromagnetic, the small (MnO){sub n} (n=1, 2, and 4) clusters are ferromagnetic with Mn moments of 5.0{mu}{sub B} but the ground state of Mn{sub 12}O{sub 12} is ferrimagnetic with a total magnetic moment of 20.0{mu}{sub B} as observed experimentally. The inner Mn sites in Mn{sub 12}O{sub 12} are found to have localized moments of 4.1{mu}{sub B} which are antiferromagnetically coupled to two types of outer Mn with moments of 4.2{mu}{sub B}. The cluster is shown to be marked by ionic as well as covalent bonds between Mn d and O p electrons and a strong intracluster magnetic coupling. {copyright} {ital 1999} {ital The American Physical Society}

  17. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory ALS Evidence Confirms Combustion Theory Print Wednesday, 22 October 2014 11:43 Researchers recently uncovered the first step in the process...

  18. Distribution of water extractable heavy metals (Cd, Co, Mn and Mo) in the topsoil of Osijek-Baranja County (Eastern Croatia)

    E-Print Network [OSTI]

    Ivezic, Vladimir; Almås, Åsgeir R.; Loncaric, Zdenko; Singh, Bal Ram

    2009-01-01T23:59:59.000Z

    and Calcareous Soils in Croatia. VII. Alps- Adria Scientificagricultural region of Croatia and therefore food qualityHungary, Serbia and Croatia. Based on the pedological map 74

  19. Physical mechanisms of thermal-diffusivity depth-profile generation in a hardened low-alloy Mn, Si, Cr, Mo steel reconstructed

    E-Print Network [OSTI]

    Mandelis, Andreas

    hardening, and coating deposition.1 For determining the metallurgical properties of case-treated materials ability to produce high-core strength and toughness and is widely used in such applications as gears

  20. (Ca,Na)(Zn,Mn){sub 2}As{sub 2}: A new spin and charge doping decoupled diluted ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Zhao, K.; Chen, B. J.; Deng, Z.; Zhao, G. Q.; Zhu, J. L.; Liu, Q. Q.; Wang, X. C. [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Han, W. [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Department of Physics, Chengde Mingzu College, Chengde (China); Frandsen, B.; Liu, L.; Cheung, S.; Uemura, Y. J. [Department of Physics, Columbia University, New York, New York 10027 (United States); Ning, F. L. [Department of Physics, Zhejiang University, Hangzhou 310027 (China); Munsie, T. J. S.; Medina, T.; Luke, G. M. [Department of Physics and Astronomy, McMaster University, Hamilton, L8S 4M1 (Canada); Carlo, J. P. [Department of Physics, Villanova University, Villanova, Pennsylvania 19085 (United States); Munevar, J. [Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro (Brazil); Zhang, G. M. [Department of Physics, Tsinghua University, Beijing (China); Jin, C. Q., E-mail: JIN@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Collaborative Innovation Center of Quantum Matter, Beijing (China); Department of Physics, Columbia University, New York, New York 10027 (United States)

    2014-10-28T23:59:59.000Z

    Here, we report the successful synthesis of a spin- and charge-decoupled diluted magnetic semiconductor (DMS) (Ca,Na)(Zn,Mn){sub 2}As{sub 2}, crystallizing into the hexagonal CaAl{sub 2}Si{sub 2} structure. The compound shows a ferromagnetic transition with a Curie temperature up to 33?K with 10% Na doping, which gives rise to carrier density of n{sub p}???10{sup 20?}cm{sup ?3}. The new DMS is a soft magnetic material with H{sub C}?Mn doping, ferromagnetic order is accompanied by an interaction between the local spin and mobile charge, giving rise to a minimum in resistivity at low temperatures and localizing the conduction electrons. The system provides an ideal platform for studying the interaction of the local spins and conduction electrons.

  1. Giant Magnetic Moments and Magnetic Bistability of Stoichiomatric MnO Clusters

    SciTech Connect (OSTI)

    Nayak, S.K.; Jena, P. [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    1998-10-01T23:59:59.000Z

    {ital Abthinspthinspinitio} calculations based on density functional theory and generalized gradient approximation reveal many unusual features of stoichiometric (MnO){sub x} (x{le}9) clusters that contrast with their bulk behavior. The clusters are ferromagnetic and carry atomiclike magnetic moments ranging from 4{mu}{sub B} to 5{mu}{sub B} per MnO unit, and the moments are localized at the Mn sites. The (MnO){sub 8} cluster, in particular, exhibits nearly degenerate ferromagnetic and atypical antiferromagnetic solutions with the ferromagnetic structure carrying a moment of 40{mu}{sub B} . The structures of (MnO){sub x} clusters are also unique with cubic and hexagonal forms competing for stability. (MnO){sub 2} and (MnO){sub 3} are unusually stable and form the foundation for further growth. {copyright} {ital 1998} {ital The American Physical Society}

  2. ALS Beamlines Directory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG,ALS Beamlines Directory PrintALS

  3. ALS User Meeting Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS Reveals NewALS TechniqueALS

  4. Bending properties of epoxy resin matrix composites filled with NiMnGa ferromagnetic shape memory alloy powders

    E-Print Network [OSTI]

    Zheng, Yufeng

    Bending properties of epoxy resin matrix composites filled with Ni­Mn­Ga ferromagnetic shape memory­Mn­Ga Composite materials Mechanical properties Microstructure Two types of epoxy resin matrix composites filled­Mn­Ga epoxy resin composites were reported, yet the bending property of Ni­Mn­Ga-polymer smart composites has

  5. Atomic-resolution study of Mn tetramer clusters using scanning tunneling Rong Yang, Haiqiang Yang, and Arthur R. Smitha

    E-Print Network [OSTI]

    Atomic-resolution study of Mn tetramer clusters using scanning tunneling microscopy Rong Yang clusters is investigated. The clusters are composed of a quadrant array of Mn atoms forming a tetramer of manganese nitride, on which are stabilized peri- odic, self-organized array of MnN-bonded Mn tetramer clus

  6. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

    SciTech Connect (OSTI)

    Visic, B., E-mail: bojana.visic@ijs.si [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gunde, M. Klanjsek [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia)] [National Institute of Chemistry, Hajdrihova 19, SI-1000 Ljubljana (Slovenia); Kovac, J.; Iskra, I. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Jelenc, J.; Remskar, M. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia) [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2013-02-15T23:59:59.000Z

    Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultraviolet–visible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

  7. High reflectance and low stress Mo2C/Be multilayers

    DOE Patents [OSTI]

    Bajt, Sasa (Livermore, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

  8. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01T23:59:59.000Z

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  9. Photoluminescent BaMoO{sub 4} nanopowders prepared by complex polymerization method (CPM)

    SciTech Connect (OSTI)

    Azevedo Marques, Ana Paula de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil)]. E-mail: apamarques@liec.ufscar.br; Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Paskocimas, Carlos A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Joya, Miryam R. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, CMDMC, Departamento de Quimica, Universidade Federal de Sao Carlos 13565-905, Sao Carlos, SP (Brazil); Longo, Elson [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2006-03-15T23:59:59.000Z

    The BaMoO{sub 4} nanopowders were prepared by the Complex Polymerization Method (CPM). The structure properties of the BaMoO{sub 4} powders were characterized by FTIR transmittance spectra, X-ray diffraction (XRD), Raman spectra, photoluminescence spectra (PL) and high-resolution scanning electron microscopy (HR-SEM). The XRD, FTIR and Raman data showed that BaMoO{sub 4} at 300 deg. C was disordered. At 400 deg. C and higher temperature, BaMoO{sub 4} crystalline scheelite-type phases could be identified, without the presence of additional phases, according to the XRD, FTIR and Raman data. The calculated average crystallite sizes, calculated by XRD, around 40 nm, showed the tendency to increase with the temperature. The crystallite sizes, obtained by HR-SEM, were around of 40-50 nm. The sample that presented the highest intensity of the red emission band was the one heat treated at 400 deg. C for 2 h, and the sample that displayed the highest intensity of the green emission band was the one heat treated at 700 deg. C for 2 h. The CPM was shown to be a low cost route for the production of BaMoO{sub 4} nanopowders, with the advantages of lower temperature, smaller time and reduced cost. The optical properties observed for BaMoO{sub 4} nanopowders suggested that this material is a highly promising candidate for photoluminescent applications.

  10. Synthesis and characterization of the ((CO)/sub 4/MoS/sub 2/MS/sub 2/)/sup 2 -/ and ((CO)/sub 4/MoS/sub 2/MS/sub 2/Mo(CO)/sub 4/)/sup 2 -/ ions (M = Mo, W): species containing group VI (6) metals in widely separated formal oxidation states

    SciTech Connect (OSTI)

    Rosenhein, L.D.; McDonald, J.W.

    1987-10-07T23:59:59.000Z

    Dinuclear and trinuclear sulfide-bridged complexes of the types (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)) and (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)/sub 2/) were prepared by the reaction of one or two equivalents of Mo(CO)/sub 4/(C/sub 7/H/sub 8/) (C/sub 7/H/sub 8/ = norbornadiene) with (Et/sub 4/N)/sub 2/(MS/sub 4/) (M = Mo, W) in methyl alcohol. Elemental analyses were consistent with the proposed formulae. Infrared spectra of all four compounds contain strong bands in the carbonyl region and low-energy bands characteristic of terminal and bridging M-S vibrations in linear, polynuclear, and sulfido-bridged species. Electrochemical experimental results support the hypothesis that the di- and trinuclear species contain both M(IV) (M = Mo, W) and Mo(0) oxidation states in the same complex. 33 references, 2 tables.

  11. Food and Drug Administration process validation activities to support 99Mo production at Sandia National Laboratories

    SciTech Connect (OSTI)

    McDonald, M.J.; Bourcier, S.C.; Talley, D.G.

    1997-07-01T23:59:59.000Z

    Prior to 1989 {sup 99}Mo was produced in the US by a single supplier, Cintichem Inc., Tuxedo, NY. Because of problems associated with operating its facility, in 1989 Cintichem elected to decommission the facility rather than incur the costs for repair. The demise of the {sup 99}Mo capability at Cintichem left the US totally reliant upon a single foreign source, Nordion International, located in Ottawa Canada. In 1992 the DOE purchased the Cintichem {sup 99}Mo Production Process and Drug Master File (DMF). In 1994 the DOE funded Sandia National Laboratories (SNL) to produce {sup 99}Mo. Although Cintichem produced {sup 99}Mo and {sup 99m}Tc generators for many years, there was no requirement for process validation which is now required by the Food and Drug Administration (FDA). In addition to the validation requirement, the requirements for current Good manufacturing Practices were codified into law. The purpose of this paper is to describe the process validation being conducted at SNL for the qualification of SNL as a supplier of {sup 99}Mo to US pharmaceutical companies.

  12. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng [Yangzhou Univ., Yangzhou, Jiangsu (China); Liu, Ping [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among the systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.

  13. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng; Liu, Ping

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among themore »systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.« less

  14. Smith et al Supporting Information

    E-Print Network [OSTI]

    Jarvis, Erich D.

    Smith et al 1 Supporting Information for Smith et al. 2006, PLoS Computational Biology 2:e161-hyperpallium apicale; HF-hippocampal formation, and M-mesopallium. #12;Smith et al 2 FigureS2,nolinkswerefoundbetweenelectrodesindifferentbirds,andnolinkswerefoundintothesoundstimulusvariable. CombinedAnalysisofAllBirds'ElectrodesPlusSound #12;Smith et al 3 Analysis of Data from Subsections

  15. Optimization of chemical compositions in low-carbon Al-killed enamel steel produced by ultra-fast continuous annealing

    SciTech Connect (OSTI)

    Dong, Futao, E-mail: dongft@sina.com [The State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Du, Linxiu; Liu, Xianghua [The State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Xue, Fei [College of Electrical Engineering, Hebei United University, Tangshan 063000 (China)

    2013-10-15T23:59:59.000Z

    The influence of Mn,S and B contents on microstructural characteristics, mechanical properties and hydrogen trapping ability of low-carbon Al-killed enamel steel was investigated. The materials were produced and processed in a laboratory and the ultra-fast continuous annealing processing was performed using a continuous annealing simulator. It was found that increasing Mn,S contents in steel can improve its hydrogen trapping ability which is attributed by refined ferrite grains, more dispersed cementite and added MnS inclusions. Nevertheless, it deteriorates mechanical properties of steel sheet. Addition of trace boron results in both good mechanical properties and significantly improved hydrogen trapping ability. The boron combined with nitrogen segregating at grain boundaries, cementite and MnS inclusions, provides higher amount of attractive hydrogen trapping sites and raises the activation energy for hydrogen desorption from them. - Highlights: • We study microstructures and properties in low-carbon Al-killed enamel steel. • Hydrogen diffusion coefficients are measured to reflect fish-scale resistance. • Manganese improves hydrogen trapping ability but decrease deep-drawing ability. • Boron improves both hydrogen trapping ability and deep-drawing ability. • Both excellent mechanical properties and fish-scale resistance can be matched.

  16. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 ? 2?$ decay of $^{100}$Mo with the LUMINEU experiment

    E-Print Network [OSTI]

    A. S. Barabash; D. M. Chernyak; F. A. Danevich; A. Giuliani; I. M. Ivanov; E. P. Makarov; M. Mancuso; S. Marnieros; S. G. Nasonov; C. Nones; E. Olivieri; G. Pessina; D. V. Poda; V. N. Shlegel; M. Tenconi; V. I. Tretyak; Ya. V. Vasiliev; M. Velazquez; V. N. Zhdankov

    2014-07-05T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass pattern.

  17. Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys

    E-Print Network [OSTI]

    Karaca, Haluk Ersin

    2009-05-15T23:59:59.000Z

    The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase...

  18. Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439

    E-Print Network [OSTI]

    Haskel, Daniel

    Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

  19. Charge transport properties of CdMnTe radiation detectors

    SciTech Connect (OSTI)

    Kim K.; Rafiel, R.; Boardman, M.; Reinhard, I.; Sarbutt, A.; Watt, G.; Watt, C.; Uxa, S.; Prokopovich, D.A.; Belas, E.; Bolotnikov, A.E.; James, R.B.

    2012-04-11T23:59:59.000Z

    Growth, fabrication and characterization of indium-doped cadmium manganese telluride (CdMnTe)radiation detectors have been described. Alpha-particle spectroscopy measurements and time resolved current transient measurements have yielded an average charge collection efficiency approaching 100 %. Spatially resolved charge collection efficiency maps have been produced for a range of detector bias voltages. Inhomogeneities in the charge transport of the CdMnTe crystals have been associated with chains of tellurium inclusions within the detector bulk. Further, it has been shown that the role of tellurium inclusions in degrading chargecollection is reduced with increasing values of bias voltage. The electron transit time was determined from time of flight measurements. From the dependence of drift velocity on applied electric field the electron mobility was found to be n = (718 55) cm2/Vs at room temperature.

  20. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect (OSTI)

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Université de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21T23:59:59.000Z

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  1. Control of absorption of monolayer MoS$_{2}$ thin-film transistor in one-dimensional defective photonic crystal

    E-Print Network [OSTI]

    Yang, Fang-Fang; Xiao, Wen-bo; Liu, Jiang-Tao; Liu, Nian-Hua

    2014-01-01T23:59:59.000Z

    The light absorption and transmission of monolayer MoS$_{2}$ in a one-dimensional defective photonic crystal (d-1DPC) is theoretically investigated. The study shows that the strong interference effect decreases photon density in particular areas of the microcavity. The d-1DPC can reduce light absorption of monolayer MoS$_{2}$ and enhance light transmission. The impact of monolayer MoS$_{2}$ light absorption on the localization effect of photon is investigated when monolayer MoS$_{2}$ and the organic light-emitting diode are located in the same microcavity. However, monolayer MoS$_{2}$ does not reduce the localization effect of light by regulating the position of monolayer MoS$_{2}$ in the microcavity.

  2. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01T23:59:59.000Z

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  3. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Grover, S. Blaine (Idaho Falls, ID); Petti, David A. (Idaho Falls, ID); Terry, William K. (Idaho Falls, ID); Yoon, Woo Y. (Idaho Falls, ID)

    1998-01-01T23:59:59.000Z

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  4. An in situ x-ray spectroscopic study of Mo?{sup +} speciation in supercritical aqueous solutions

    SciTech Connect (OSTI)

    Yan, Hao [Missouri State University, Springfield, MO (United States); Mayanovic, Robert A. [Missouri State University, Springfield, MO (United States); Anderson, Alan J. [St. Francis Xavier Univ., Antigonish, NS (Canada); Meredith, Peter R. [St. Francis Xavier Univ., Antigonish, NS (Canada)

    2011-09-01T23:59:59.000Z

    In situ XRF and Mo K-edge XAS measurements were made on the ID20-B beam line at the APS on MoO? in 1 M H?O? aqueous solution, at temperatures between 400 and 600 °C. The samples were analyzed using a modified Bassett-type hydrothermal diamond anvil cell. Our XRF measurements show that MoO? is highly soluble in the supercritical H?O? aqueous fluid. Analysis of XAS spectra shows that the Mo?{sup +} ion exhibits consistent speciation in the H?O? aqueous solution at temperatures ranging from 400 to 600 °C.

  5. Mechanical properties of MoS2/graphene heterostructures Jin-Wu Jiang and Harold S. Park

    E-Print Network [OSTI]

    of the heterostructure is considerably smaller than the MoS2 due to lateral buckling of the outer graphene layers owning

  6. Ge{sub 1-x}Mn{sub x} heteroepitaxial quantum dots: Growth, morphology, and magnetism

    SciTech Connect (OSTI)

    Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

    2013-02-21T23:59:59.000Z

    Heteroepitaxial Ge{sub 1-x}Mn{sub x} quantum dots (QDs) were grown on Si (001) by molecular beam epitaxial co-deposition, with x = 0 to 0.10, in order to explore the interaction between Mn content, surface morphological evolution, and magnetism. Morphological evolution typical of the Ge/Si (001) system was observed, where the effect of Mn on surface morphology is surprisingly minimal at low Mn content, with no obvious surface morphological indicators of second phase formation. As the Mn content increases, secondary phase formation becomes evident, appearing to heterogeneously nucleate on or within Ge QDs. Still higher Mn concentrations lead to extensive second phase formation interspersed with an array of Ge QDs. Although ferromagnetism up to 220 K is observed, likely arising from intermetallic precipitates, there is no clear evidence for room-temperature ferromagnetism associated with a dilute magnetic solution phase.

  7. Time resolved magneto-optical studies of ferromagnetic InMnSb films

    SciTech Connect (OSTI)

    Frazier, M.; Kini, R. N.; Nontapot, K.; Khodaparast, G. A. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Wojtowicz, T. [Institute of Physics, Polish Academy of Sciences 02-668 Warsaw (Poland); Liu, X.; Furdyna, J. K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

    2008-02-11T23:59:59.000Z

    We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples' Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples' growth conditions.

  8. Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina

    E-Print Network [OSTI]

    Spila, Timothy P.

    and EVs), they must meet a range of stringent criteria: for instance, energy densities high enoughImproving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive-ion Atomic layer deposition Al2O3 Coating Secondary ion mass spectrometry Layered oxide a b s t r a c

  9. Elementary Steps of Syngas Reactions on Mo2C(001): Adsorption Thermochemistry and Bond Dissociation

    SciTech Connect (OSTI)

    Medford, Andrew

    2012-02-16T23:59:59.000Z

    Density functional theory (DFT) and ab initio thermodynamics are applied in order to investigate the most stable surface and subsurface terminations of Mo{sub 2}C(001) as a function of chemical potential and in the presence of syngas. The Mo-terminated (001) surface is then used as a model surface to evaluate the thermochemistry and energetic barriers for key elementary steps in syngas reactions. Adsorption energy scaling relations and Broensted-Evans-Polanyi relationships are established and used to place Mo{sub 2}C into the context of transition metal surfaces. The results indicate that the surface termination is a complex function of reaction conditions and kinetics. It is predicted that the surface will be covered by either C{sub 2}H{sub 2} or O depending on conditions. Comparisons to transition metals indicate that the Mo-terminated Mo{sub 2}C(001) surface exhibits carbon reactivity similar to transition metals such as Ru and Ir, but is significantly more reactive towards oxygen.

  10. Beta. -MoO sub 3 produced from a novel freeze drying route

    SciTech Connect (OSTI)

    Parise, J.B. (State Univ. of New York, Stony Brook (United States)); McCarron, E.M. III (E.I. Dupont de Nemours and Co., Inc., Wilmington, DE (United States)); Von Dreele, R.; Goldstone, J.A. (Los Alamos National Lab., NM (United States))

    1991-07-01T23:59:59.000Z

    Powdered samples of {beta}-MoO{sub 3} have been produced by the gentle heat treatment of freeze-dried molybdic acid at 350{degree}C for 1 hr. The samples, yellow-green in appearance, contained varying amounts of the thermodynamically stable {alpha}-MoO{sub 3}, depending upon the time and temperature of heat treatment. Neutron diffraction data were collected at 300 K. all peaks, not attributable to {alpha}-MoO{sub 3}, were indexed on the basis of a monoclinic cell, P2{sub 1}/c, {alpha} = 7.1228(7), b = 5.3660(6), c = 5.5665(6), {beta} = 92.01(1){degree}, V = 212.62(6){angstrom}{sup 3}. The structure, which is related to ReO{sub 3}, contains two crystallographically independent octahedra. Both show evidence of disorder at the Mo and O sites. Two distinct orientations of a short mo-O distance, suggestive of the type of molybdenyl bond observed in both the {alpha} and {beta}{prime}-forms, are primarily responsible for the observed disordering.

  11. Oxidation and creep behavior of Mo*5*Si*3* based materials

    SciTech Connect (OSTI)

    Meyer, M.

    1995-06-19T23:59:59.000Z

    Mo{sub 5}Si{sub 3} shows promise as a high temperature creep resistant material. The high temperature oxidation resistance of Mo{sub 5}Si{sub 3} has been found to be poor, however, limiting its use in oxidizing atmospheres. Undoped Mo{sub 5}Si{sub 3} exhibits mass loss in the temperature range 800{degrees}-1200{degrees}C due to volatilization of molybdenum oxide, indicating that the silica scale does not provide a passivating layer. The addition of boron results in protective scale formation and parabolic oxidation kinetics in the temperature range of 1050{degrees}-1300{degrees}C. The oxidation rate of Mo{sub 5}Si{sub 3} was decreased by 5 orders of magnitude at 1200{degrees}C by doping with less than two weight percent boron. Boron doping eliminates catastrophic {open_quote}pest{close_quote} oxidation at 800{degrees}C. The mechanism for improved oxidation resistance of boron doped Mo{sub 5}Si{sub 3} is due to scale modification by boron.

  12. Liquid generation during sintering of Fe-3.5%Mo powder compacts with elemental boron additions

    SciTech Connect (OSTI)

    Sarasola, M.; Gomez-Acebo, T.; Castro, F

    2004-09-06T23:59:59.000Z

    The mechanisms for liquid generation and the microstructural development during sintering of a Fe-3.5Mo-0.3B alloy were studied. Interrupted sintering experiments followed by water quenching from specific temperatures within the sintering cycle have been carried out. The influence of Mo, both, on the final microstructure and on the behaviour of boron prior to, during and after the formation of the liquid phase, was studied through observation of the quenched samples under LOM and SEM. The study shows that prior to the formation of the liquid phase, boron diffuses into the metallic particles forming inter and intragranular precipitates of the (Fe,Mo){sub 2}B type. At higher temperatures a continuous Fe/Mo/B liquid phase, with excellent wetting characteristics, is formed thus leading to near fully dense materials. The generation of the liquid is based on a eutectic reaction involving the mixed (Fe,Mo){sub 2}B borides previously formed. The development of the microstructure after liquid formation is described.

  13. Neutron Diffraction Measurement of Residual Stresses, Dislocation Density and Texture in Zr-bonded U-10Mo “Mini” Fuel Foils and Plates

    SciTech Connect (OSTI)

    Brown, Donald W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Okuniewski, M. A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sisneros, Thomas A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Clausen, Bjorn [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Moore, G. A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Balogh, L [Queen's Univ., Kingston, ON (Canada)

    2014-08-07T23:59:59.000Z

    Aluminum clad monolithic uranium 10 weight percent molybdenum (U-10Mo) fuel plates are being considered for conversion of several research and test nuclear reactors from high-enriched to low-enriched uranium fuel due to the inherently high density of fissile material. Comprehensive neutron diffraction measurements of the evolution of the textures, residual phase stresses, and dislocation densities in the individual phases of the mini-foils throughout several processing steps and following hot-isostatic pressing to the Al cladding, have been completed. Recovery and recrystallization of the bare U-10Mo fuel foil, as indicated by the dislocation density and texture, are observed depending on the state of the material prior to annealing and the duration and temperature of the annealing process. In general, the HIP procedure significantly reduces the dislocation density, but the final state of the clad plate, both texture and dislocation density, depends strongly on the final processing step of the fuel foil. In contrast, the residual stresses in the clad fuel plate do not depend strongly on the final processing step of the bare foil prior to HIP boding. Rather, the residual stresses are dominated by the thermal expansion mismatch of the constituent materials of the fuel plate.

  14. IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

  15. Doping-level-dependent optical properties of GaN:Mn O. Gelhausen,a)

    E-Print Network [OSTI]

    Nabben, Reinhard

    for system response. The optical absorption spectra recorded at 2 K of nomi- nally undoped GaN, GaN:Mn, and GaN:Mn:Si are presented in Fig. 1. An absorption band with a zero phonon line ZPL at 1.414 0.002 eDoping-level-dependent optical properties of GaN:Mn O. Gelhausen,a) E. Malguth, and M. R. Phillips

  16. Optical Properties of Mn-doped GaN O. Gelhausen1

    E-Print Network [OSTI]

    Nabben, Reinhard

    measurements. In the GaN:Mn, an intense absorption peak at 1.414 +/- 0.002 eV was observed. This peakOptical Properties of Mn-doped GaN O. Gelhausen1 , E. Malguth1,3 , M. R. Phillips1 , E. M. Goldys2, Germany ABSTRACT Molecular beam epitaxy-grown GaN with different Mn concentrations (5-23 x 1019 cm-3

  17. ALS Activity Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the EnergyTAMANG, APIL.AFTFutureALPES20thALS

  18. ALS Beamlines Directory

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  19. ALS Beamlines Directory

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  20. ALS Chemistry Lab

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  2. ALS Chemistry Lab

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  3. ALS Communications Group

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  4. About the ALS

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  6. ALS Postdoctoral Fellowship Highlights

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  11. Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure

    SciTech Connect (OSTI)

    Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

    2014-09-21T23:59:59.000Z

    The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}???55 ?C/cm{sup 2} obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290?K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ?123?emu/cm{sup 3}. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

  12. Mn(II) Oxidation by an Ascomycete Fungus is Linked to Superoxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Asexual Reproduction. Abstract: Manganese (Mn) oxides are among the most reactive minerals within the environment, where they control the bioavailability of carbon, nutrients,...

  13. Enhancing SMM properties via axial distortion of Mn-3(III) clusters 

    E-Print Network [OSTI]

    Parsons S.; Brechin, E.K.; Collins A.; Karotsis G.; Jones L.F.; Inglis R.; Wernsdorfer W.; Perlepes S.P.

    2008-01-01T23:59:59.000Z

    Replacement of carboxylate and solvent with facially capping tripodal ligands enhances the single-molecule magnet (SMM) properties of [Mn-3(III)] triangles.

  14. HIGH RESOLUTION SCANNING AUGER MICROSCOPIC INVESTIGATION OF INTERGRANULAR FRACTURE IN AS-QUENCHED Fe-12Mn

    E-Print Network [OSTI]

    Lee, H.J.

    2013-01-01T23:59:59.000Z

    contents in Fe-Mn alloys. Scanning electron fractographsTransactions HIGH RESOLUTION SCANNING AUGER MICROSCOPICof Califomia. HIGH RESOLUTION SCANNING AUGER MICROSCOPIC

  15. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

    SciTech Connect (OSTI)

    Yan, Jun; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Cheng, Jie [Research Institute of Chemical Defense, Beijing 100083 (China)] [Research Institute of Chemical Defense, Beijing 100083 (China); Fan, Zhuangjun, E-mail: fanzhj666@163.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

    2010-02-15T23:59:59.000Z

    Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

  16. Magnetization relaxation in (Ga,Mn)As ferromagnetic semiconductors 

    E-Print Network [OSTI]

    Sinova, Jairo; Jungwirth, T.; Liu, X.; Sasaki, Y.; Furdyna, JK; Atkinson, WA; MacDonald, AH.

    2004-01-01T23:59:59.000Z

    description of ferromagnetism in many diluted magnetic semiconductors ~DMS?s!, ~Ga,M- n!As in particular.2,3 Exchange-coupling between local mo- ments and itinerant electrons should also contribute signifi- 0163-1829/2004/69~8!/085209~6!/$22.50 69 085209... suggests g contributes significantly to the damping rate of the g the theoretical Gilbert coefficient with the values typical critical current for spin-transfer magnetization s low as ;105 A cm22. PACS number~s!: 73.20.Mf, 73.40.2c, 85.75.2d curate...

  17. Atomistic full-band simulations of monolayer MoS{sub 2} transistors

    SciTech Connect (OSTI)

    Chang, Jiwon; Register, Leonard F.; Banerjee, Sanjay K. [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)] [Microelectronics Research Center, The University of Texas at Austin, Austin, Texas 78758 (United States)

    2013-11-25T23:59:59.000Z

    We study the transport properties of deeply scaled monolayer MoS{sub 2} n-channel metal-oxide-semiconductor field effect transistors (MOSFETs), using full-band ballistic quantum transport simulations, with an atomistic tight-binding Hamiltonian obtained from density functional theory. Our simulations suggest that monolayer MoS{sub 2} MOSFETs can provide near-ideal subthreshold slope, suppression of drain-induced barrier lowering, and gate-induced drain leakage. However, these full-band simulations exhibit limited transconductance. These ballistic simulations also exhibit negative differential resistance (NDR) in the output characteristics associated with the narrow width in energy of the lowest conduction band, but this NDR may be substantially reduced or eliminated by scattering in MoS{sub 2}.

  18. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin, E-mail: aldin@oxide.tu-darmstadt.de; Mani, Arzhang; Ziegler, Jürgen; Alff, Lambert; Komissinskiy, Philipp, E-mail: komissinskiy@oxide.tu-darmstadt.de [Institute of Materials Science, TU Darmstadt, Alarich-Weiss-Str. 2, 64287 Darmstadt (Germany); Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf [Institute for Microwave Engineering and Photonics, TU Darmstadt, Merckstraße 25, 64283 Darmstadt (Germany)

    2014-09-15T23:59:59.000Z

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???·cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  19. Time exposure performance of Mo-Au Gibbsian segregating alloys for extreme ultraviolet collector optics

    SciTech Connect (OSTI)

    Qiu Huatan; Srivastava, Shailendra N.; Thompson, Keith C.; Neumann, Martin J.; Ruzic, David N

    2008-05-01T23:59:59.000Z

    Successful implementation of extreme ultraviolet (EUV) lithography depends on research and progress toward minimizing collector optics degradation from intense plasma erosion and debris deposition. Thus studying the surface degradation process and implementing innovative methods, which could enhance the surface chemistry causing the mirrors to suffer less damage, is crucial for this technology development. A Mo-Au Gibbsian segregation (GS) alloy is deposited on Si using a dc dual-magnetron cosputtering system and the damage is investigated as a result of time dependent exposure in an EUV source. A thin Au segregating layer is maintained through segregation during exposure, even though overall erosion in the Mo-Au sample is taking place in the bulk. The reflective material, Mo, underneath the segregating layer is protected by this sacrificial layer, which is lost due to preferential sputtering. In addition to theoretical work, experimental results are presented on the effectiveness of the GS alloys to be used as potential EUV collector optics material.

  20. The massive transformation in Ti-Al alloys: mechanistic observations

    SciTech Connect (OSTI)

    Zhang, X.D.; Godfrey, S.; Weaver, M.; Strangwood, M.; Kaufman, M.J.; Loretto, M.H. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; Threadgill, P. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; [TWI, Cambridge (United Kingdom)

    1996-09-01T23:59:59.000Z

    The massive {alpha}{yields}{gamma}{sub m} transformation, as observed using analytical transmission electron microscopy, in Ti-49Al, Ti-48Al-2Nb-2Mn, Ti-55Al-25Ta and Ti-50Al-20Ta alloys is described. Conventional solution heating and quenching experiments have been combined with the more rapid quenching possible using electron beam melting in order to provide further insight into the early stages of the transformation of these alloys. It is shown that the {gamma} develops first at grain boundaries as lamellae in one of the grains and that these lamellae intersect and spread into the adjacent grain in a massive manner. Consequently, there is no orientation relationship between the massive gamma ({gamma}{sub m}) and the grain being consumed whereas there is the expected relation between the {gamma}{sub m} and the first grain which is inherited from the lamellae. It is further shown that the {gamma}{sub m} grows as an f.c.c. phase after initially growing with the L1{sub 0} structure. Furthermore, it is shown that the massive f.c.c. phase then orders to the L1{sub 0} structure producing APDB-like defects which are actually thin 90{degree} domains separating adjacent domains that have the same orientation yet are out of phase. The advancing {gamma}{sub m} interface tends to facet parallel either to one of its four {l_brace}111{r_brace} planes or to the basal plane in the grain being consumed by impinging on existing {gamma} lamellae. Thin microtwins and {alpha}{sub 2} platelets then form in the {gamma}{sub m} presumably due, respectively, to transformation stresses and supersaturation of the {gamma}{sub m} with titanium for alloys containing {approximately}48% Al; indeed, there is a local depletion in aluminium across the {alpha}{sub 2} platelets as determined using fine probe microanalysis.

  1. Structural, textural and catalytic properties of Al-, Ti-pillared clays

    SciTech Connect (OSTI)

    Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

    1996-12-31T23:59:59.000Z

    Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

  2. Neutrino-nucleus scattering of {sup 95,97}Mo and {sup 116}Cd

    SciTech Connect (OSTI)

    Ydrefors, E. [Royal Institute of Technology (KTH), Alba Nova University Center, SE-10691 Stockholm, Sweden and Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland); Almosly, W.; Suhonen, J. [Department of Physics, P.O. Box 35 (YFL), FI-40014 University of Jyväskylä (Finland)

    2013-12-30T23:59:59.000Z

    Accurate knowledge about the nuclear responses to supernova neutrinos for relevant nuclear targets is important both for neutrino detection and for astrophysical applications. In this paper we discuss the cross sections for the charged-current neutrino-nucleus scatterings off {sup 95,97}Mo and {sup 116}Cd. The microscopic quasiparticle-phonon model is adopted for the odd-even nuclei {sup 95,97}Mo. In the case of {sup 116}Cd we present cross sections both for the Bonn one-boson-exchange potential and self-consistent calculations based on modern Skyrme interactions.

  3. Characterization of metal contacts for two-dimensional MoS{sub 2} nanoflakes

    SciTech Connect (OSTI)

    Walia, Sumeet, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au; Balendhran, Sivacarendran; Sriram, Sharath; Bhaskaran, Madhu, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia) [Functional Materials and Microsystems Research Group, RMIT University, Melbourne, Victoria 3000 (Australia); School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia); Wang, Yichao; Ab Kadir, Rosmalini; Sabirin Zoolfakar, Ahmad; Atkin, Paul; Zhen Ou, Jian; Kalantar-zadeh, Kourosh, E-mail: madhu.bhaskaran@rmit.edu.au, E-mail: kourosh.kalantar@rmit.edu.au, E-mail: sumeet.walia@rmit.edu.au [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)] [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3000 (Australia)

    2013-12-02T23:59:59.000Z

    While layered materials are increasingly investigated for their potential in nanoelectronics, their functionality and efficiency depend on charge injection into the materials via metallic contacts. This work explores the characteristics of different metals (aluminium, tungsten, gold, and platinum) deposited on to nanostructured thin films made of two-dimensional (2D) MoS{sub 2} flakes. Metals are chosen based on their work functions relative to the electron affinity of MoS{sub 2}. It is observed, and analytically verified that lower work functions of the contact metals lead to smaller Schottky barrier heights and consequently higher charge carrier injection through the contacts.

  4. Evolution of level density step structures from 56,57-Fe to 96,97-Mo

    E-Print Network [OSTI]

    A. Schiller; E. Tavukcu; L. A. Bernstein; P. E. Garrett; M. Guttormsen; M. Hjorth-Jensen; C. W. Johnson; G. E. Mitchell; J. Rekstad; S. Siem; A. Voinov; W. Younes

    2003-02-24T23:59:59.000Z

    Level densities have been extracted from primary gamma spectra for 56,57-Fe and 96,97-Mo nuclei using (3-He,alpha gamma) and (3-He,3-He') reactions on 57-Fe and 97-Mo targets. The level density curves reveal step structures above the pairing gap due to the breaking of nucleon Cooper pairs. The location of the step structures in energy and their shapes arise from the interplay between single-particle energies and seniority-conserving and seniority-non-conserving interactions.

  5. Protective effects of ebselen (Ebs) and para-aminosalicylic acid (PAS) against manganese (Mn)-induced neurotoxicity

    SciTech Connect (OSTI)

    Marreilha dos Santos, A.P., E-mail: apsantos@ff.ul.pt [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Lucas, Rui L.; Andrade, Vanda; Mateus, M. Luísa [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Milatovic, Dejan; Aschner, Michael [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Batoreu, M. Camila [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)

    2012-02-01T23:59:59.000Z

    Chronic, excessive exposure to manganese (Mn) may induce neurotoxicity and cause an irreversible brain disease, referred to as manganism. Efficacious therapies for the treatment of Mn are lacking, mandating the development of new interventions. The purpose of the present study was to investigate the efficacy of ebselen (Ebs) and para-aminosalicylic acid (PAS) in attenuating the neurotoxic effects of Mn in an in vivo rat model. Exposure biomarkers, inflammatory and oxidative stress biomarkers, as well as behavioral parameters were evaluated. Co-treatment with Mn plus Ebs or Mn plus PAS caused a significant decrease in blood and brain Mn concentrations (compared to rats treated with Mn alone), concomitant with reduced brain E{sub 2} prostaglandin (PGE{sub 2}) and enhanced brain glutathione (GSH) levels, decreased serum prolactin (PRL) levels, and increased ambulation and rearing activities. Taken together, these results establish that both PAS and Ebs are efficacious in reducing Mn body burden, neuroinflammation, oxidative stress and locomotor activity impairments in a rat model of Mn-induced toxicity. -- Highlights: ? The manuscript is unique in its approach to the neurotoxicity of Mn. ? The manuscript incorporates molecular, cellular and functional (behavioral) analyses. ? Both PAS and Ebs are effective in restoring Mn behavioral function. ? Both PAS and Ebs are effective in reducing Mn-induced oxidative stress. ? Both PAS and Ebs led to a decrease in Mn-induced neuro-inflammation.

  6. Opti-MN Impact House Presentation | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagementOPAM PolicyOfEnergy Online1 MarchOpti-MN Impact House

  7. MN Office of Energy Security | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRose Bend < MHKconverter <WAG BuoyYOG < MHKbioWaveTHETugboat/MN

  8. DOE - Office of Legacy Management -- Elk River Reactor - MN 01

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTable ofArizonaBuffalo -Elk River Reactor - MN 01 FUSRAP

  9. Environmental effect on room-temperature ductility of isothermally forged TiAl-base alloys

    SciTech Connect (OSTI)

    Nakamura, Morihiko; Hashimoto, Kenki (National Research Inst. for Metals, Tokyo (Japan)); Itoh, Naoyuki (Nippon Steel Corp., Chiba (Japan)); Tsujimoto, Tokuzo (Ibaraki Univ. (Japan). Faculty of Engineering); Suzuki, Toshiyuki (Kougakuin Univ., Tokyo (Japan))

    1994-02-01T23:59:59.000Z

    Isothermally forged TiAl-base alloy (Al-rich, Mn-containing, and Cr-containing TiAl) were heat-treated in various conditions, and equiaxed grain structures consisting of [gamma] and [alpha][sub 2] or [beta] phases were obtained. The heat-treated alloys were tensile tested in vacuum and air at room temperature, and the environmental effect on tensile elongation was studied. The ductility of the alloys consisting of equiaxed [gamma] grains and a large amount of [alpha][sub 2] grains was not largely affecting by laboratory air, and a decrease in the amount of [alpha][sub 2] grains resulted in a large reduction of ductility in air. The [beta] phase in the Cr-containing alloy improved the ductility in vacuum, but it resulted in a large reduction of ductility in air.

  10. Background radioactivity of construction materials, raw substance and ready-made CaMoO4 crystals

    E-Print Network [OSTI]

    Busanov, O A; Gavriljuk, Yu M; Gezhaev, A M; Kazalov, V V; Kornoukhov, V N; Kuzminov, V V; Moseev, P S; Panasenko, S I; Ratkevich, S S; Yakimenko, S P

    2013-01-01T23:59:59.000Z

    The results of measurements of natural radioactive isotopes content in different source materials of natural and enriched composition used for CaMoO4 scintillation crystal growing are presented. The crystals are to be used in the experiment to search for double neutrinoless betas-decay of Mo-100.

  11. Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin "lms

    E-Print Network [OSTI]

    Rockett, Angus

    Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin, As ngstro( m Solar Center, P.O. Box 534, SE-751 21 Uppsala, Sweden Department of Materials Science Mo thin "lms used as back contacts for Cu(In,Ga)Se solar cells. The samples were analysed

  12. Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS Technique: XPS

    E-Print Network [OSTI]

    Goodman, Wayne

    Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS preparation methods were employed to grow a well-ordered ultra-thin titanium oxide film on Mo(J (2), The tirst: photoemission; titanium oxide; tllin film PACS: 81.15.Gh. 79,60.Dp SPECIMEN DESCRIPTION (Accession #00936) Host

  13. Giant Two-Photon Absorption Coefficient and Frequency Up-Converted Luminescence in Monolayer MoS2

    E-Print Network [OSTI]

    Li, Yuanxin; Zhang, Saifeng; Zhang, Xiaoyan; Feng, Yanyan; Wang, Kangpeng; Zhang, Long; Wang, Jun

    2015-01-01T23:59:59.000Z

    Strong two-photon absorption (TPA) in monolayer MoS2 is demonstrated in contrast to saturable absorption (SA) in multilayer MoS2 under the excitation of femtosecond laser pulses in the near infrared region. MoS2 in the forms of monolayer single crystal and multilayer triangular islands are grown on either quartz or SiO2/Si by employing the seeding method through chemistry vapor deposition. The nonlinear transmission measurements reveal that monolayer MoS2 possesses a giant nonsaturation TPA coefficient, larger than that of conventional semiconductors. As a result of TPA, two-photon pumped frequency up-converted luminescence is observed directly in the monolayer MoS2. For the multilayer MoS2, the SA response is demonstrated with the ratio of the excited-state absorption cross section to ground-state cross section of 0.18. In addition, the laser damage threshold of the monolayer MoS2 is 97 GW/cm2, larger than that of the multilayer MoS2 of 78 GW/cm2.

  14. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

    SciTech Connect (OSTI)

    Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan, E-mail: xiaoganl@umich.edu [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-06-09T23:59:59.000Z

    We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

  15. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

    SciTech Connect (OSTI)

    Quereda, J. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Castellanos-Gomez, A. [Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Agraït, N. [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto Madrileño de Estudios Avanzados en Nanociencia, IMDEA-Nanociencia, E-28049 Madrid (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain); Rubio-Bollinger, G., E-mail: gabino.rubio@uam.es [Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Madrid E-28049 (Spain); Instituto de Ciencia de Materiales Nicolás Cabrera, Campus de Cantoblanco, E-28049 Madrid (Spain); Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, E-28049 Madrid (Spain)

    2014-08-04T23:59:59.000Z

    We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

  16. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect (OSTI)

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28T23:59:59.000Z

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  17. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01T23:59:59.000Z

    various transition or rare-earth metals provide a rich ?eldTransition Metal (Mn) and Rare Earth (Gd) Doped AmorphousTransition Metal (Mn) and Rare Earth (Gd) Doped Amorphous

  18. Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1

    E-Print Network [OSTI]

    Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. ©2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

  19. Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy

    E-Print Network [OSTI]

    Engelward, Bevin

    Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene. Irradiated Esophageal Cells are Protected from Radiation- Induced Recombination by MnSOD Gene Therapy. Radiat,a Bevin Engelward,b Michael Epperlya and Joel S. Greenbergera,1 a Departments of Radiation Oncology

  20. An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS Characterisations.

    E-Print Network [OSTI]

    Boyer, Edmond

    An Analysis of Mn-Zn Ferrite Microstructure by Impedance Spectroscopy, STEM and EDS.loyau@satie.ens-cachan.fr Abstract AC resistivity measurement results on Mn-Zn sintered ferrite were analyzed in the 0.1-500 MHz of the main limitations in frequency increase is the energy dissipations by losses in ferrites that produce

  1. Synthesis and Characterization of NiMnGa Ferromagnetic Shape Memory Alloy Thin Films

    E-Print Network [OSTI]

    Jetta, Nishitha

    2011-10-21T23:59:59.000Z

    for fabricating NiMnGa thin films with desired composition and microstructure and hence unique properties for future MEMS actuator materials and characterize their properties to aid better understanding of their behavior. In this project NiMnGa thin films have...

  2. Short communication The composite rods of MnO and multi-walled carbon nanotubes as

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Short communication The composite rods of MnO and multi-walled carbon nanotubes as anode materialsO as an anode material for lithium ion batteries are significantly improved. The MnO/MWNTs composite shows a Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong

  3. Additive and Competitive Effects of Bacteria and Mn Oxides on Arsenite Oxidation Kinetics

    E-Print Network [OSTI]

    Sparks, Donald L.

    Additive and Competitive Effects of Bacteria and Mn Oxides on Arsenite Oxidation Kinetics L oxidizing As(III) at the same time than for either component alone. The additive effect of the mixed cell even though As(III) was oxidized fastest in a mixed cell--MnO2 system. The additive effect of biotic

  4. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

  5. austenitnoj cr-mn stali: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cr-mn stali First Page Previous Page 1 2 3 4 5 6 Next Page Last Page Topic Index 1 Cavitation erosion of laser processed Fe-Cr-Mn and Fe-Cr-Co alloys CiteSeer Summary: Received...

  6. Single-Crystalline Diluted Magnetic Semiconductor GaN:Mn Nanowires**

    E-Print Network [OSTI]

    Yang, Peidong

    Single-Crystalline Diluted Magnetic Semiconductor GaN:Mn Nanowires** By Heon-Jin Choi*, Han-mediated ferromagnetism. These ferromagnetic GaN:Mn nanowires represent an important class of nanometer-scale building blocks for spintronics. Theoretical studies indicate that transition-metal-doped GaN possesses

  7. Effects of (Al,Ge) double doping on the thermoelectric properties of higher manganese silicides

    SciTech Connect (OSTI)

    Chen, Xi; Salta, Daniel; Zhang, Libin [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie [Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Zhou, Jianshi; Goodenough, John B.; Shi, Li [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2013-11-07T23:59:59.000Z

    Experiments and analysis have been carried out to investigate the effects of Al and (Al,Ge) doping on the microstructure and thermoelectric properties of polycrystalline higher manganese silicide (HMS) samples, which were prepared by solid-state reaction, ball milling, and followed by spark plasma sintering. It has been found that Al doping effectively increases the hole concentration, which leads to an increase in the electrical conductivity and power factor. By introducing the second dopant Ge into Al-doped HMS, the electrical conductivity is increased, and the Seebeck coefficient is decreased as a result of further increased hole concentration. The peak power factor is found to occur at a hole concentration between 1.8?×?10{sup 21} and 2.2?×?10{sup 21}?cm{sup ?3} measured at room temperature. The (Al,Ge)-doped HMS samples show lower power factors owing to their higher hole concentrations. The mobility of Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} with y?=?0.035 varies approximately as T{sup ?3/2} above 200?K, suggesting acoustic phonon scattering is the dominant scattering mechanism. The thermal conductivity of HMS does not change appreciably by Al or (Al,Ge) doping. The maximum ZT of (Al,Ge)-doped HMS is 0.57 at 823?K, which is similar to the highest value found in the Al-doped HMS samples. The ZT values were reduced in the Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} samples with high Ge concentration of y?=?0.025 and 0.035, because of reduced power factor. In addition, a two-band model was employed to show that the hole contribution to the thermal conductivity dominates the bipolar and electron contributions for all samples from 300 to 823?K and accounts for about 12% of the total thermal conductivity at about 800?K.

  8. BBA Electives: M&O Comparison Compiled 11/11/09

    E-Print Network [OSTI]

    Michigan, University of

    University ­ Marriott Organizational Development and Change Teams and Work Groups Human Resource Management Compensation Management Labor Relations and Conflict Management Staffing Organizations Motivation and Work MIT1 BBA Electives: M&O Comparison Compiled 11/11/09 University of Michigan ­ Ross School Management

  9. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

    Broader source: Energy.gov [DOE]

    NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

  10. MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions

    E-Print Network [OSTI]

    Brendel, Volker

    MoDPepInt: An interactive webserver for prediction of modular domain-peptide interactions-Supervised Prediction of SH2-Peptide Interactions from Imbalanced High-Throughput Data PLoS One, 8(5), pp. e62732, 2013-peptide interaction prediction with an application to human SH3 domains Bioinformatics, 29(13), pp. i335-i343, 2013

  11. On the Higher-Order MoM-PO Electromagnetic Modeling of Vehicles

    E-Print Network [OSTI]

    Notaros, Branislav M.

    vehicles (cars, airplanes, helicopters, spacecraft, etc.). From the electromagnetic point of view and accurate higher-order, large-domain hybrid computational technique based on the method of moments (Mo the efficiency and accuracy of the hybrid higher-order computational technique and its advantages over

  12. Enriched Zn$^{100}$MoO$_4$ scintillating bolometers to search for $0 \

    E-Print Network [OSTI]

    Barabash, A S; Danevich, F A; Giuliani, A; Ivanov, I M; Makarov, E P; Mancuso, M; Marnieros, S; Nasonov, S G; Nones, C; Olivieri, E; Pessina, G; Poda, D V; Shlegel, V N; Tenconi, M; Tretyak, V I; Vasiliev, Ya V; Velazquez, M; Zhdankov, V N

    2014-01-01T23:59:59.000Z

    The LUMINEU project aims at performing a demonstrator underground experiment searching for the neutrinoless double beta decay of the isotope $^{100}$Mo embedded in zinc molybdate (ZnMoO$_4$) scintillating bolometers. In this context, a zinc molybdate crystal boule enriched in $^{100}$Mo to 99.5\\% with a mass of 171 g was grown for the first time by the low-thermal-gradient Czochralski technique. The production cycle provided a high yield (the crystal boule mass was 84\\% of initial charge) and an acceptable level -- around 4\\% -- of irrecoverable losses of the costy enriched material. Two crystals of 59 g and 63 g, obtained from the enriched boule, were tested aboveground at milli-Kelvin temperature as scintillating bolometers. They showed a high detection performance, equivalent to that of previously developed natural ZnMoO$_4$ detectors. These results pave the way to future sensitive searches based on the LUMINEU technology, capable to approach and explore the inverted hierarchy region of the neutrino mass p...

  13. Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors

    E-Print Network [OSTI]

    Chiang, Shirley

    Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors Xiubin Qi, Frank E. Osterloh,*, S. A that the temporal and steady-state resistance changes of the films depend on the time following the adsorption and on the number of molecules that adsorb to the nanowire films at a given pressure. The adsorption ability

  14. Investigation of Double Beta Decay of 100Mo to Excited States of 100Ru

    SciTech Connect (OSTI)

    A. J. Caffrey; The NEMO-3 Collaboration

    2014-05-01T23:59:59.000Z

    Double beta decay of 100Mo to the excited states of daughter nuclei has been studied using a 600 cm3 low-background HPGe detector and an external source consisting of 2588 g of 97.5% enriched metallic 100Mo, which was formerly inside the NEMO-3 detector and used for the NEMO-3 measurements of 100Mo. The half-life for the two-neutrino double beta decay of 100Mo to the excited View the MathML source state in 100Ru is measured to be T1/2=[7.5±0.6(stat)±0.6(syst)]·1020 yr. For other (0?+2?) transitions to the View the MathML source, View the MathML source, View the MathML source, View the MathML source and View the MathML source levels in 100Ru, limits are obtained at the level of ~(0.25–1.1)·1022 yr.

  15. Lithium Intercalation in Graphene/MoS2 Composites: First-Principles Insights

    E-Print Network [OSTI]

    Shao, Xiji; Pang, Rui; Shi, Xingqiang

    2015-01-01T23:59:59.000Z

    As a storage material for Li-ion batteries, graphene/molybdenum disulfide (Gr/MoS2) composites have been intensively studied in experiments. But the relevant theoretical works from first-principles are lacking. In the current work, van-der-Waals-corrected density functional theory calculations are performed to investigate the interaction of Li in Gr/MoS2 composites. Three interesting features are revealed for the intercalated Gr/Li(n)/MoS2 composites (n = 1 to 9). One is the reason for large Li storage capacity of Gr/MoS2: due to the binding energies per Li atom increase with the increasing number of intercalated Li atoms. Secondly, the band gap opening of Gr is found, and the band gap is enlarged with the increasing number of intercalated Li atoms, up to 160 meV with nine Li; hence these results suggest an efficient way to tune the band gap of graphene. Thirdly, the Dirac cone of Gr always preserve for different number of ionic bonded Li atoms.

  16. This is MoFo. Scientific/Technical Patent Analysts/Agents

    E-Print Network [OSTI]

    Straight, Aaron

    This is MoFo. Scientific/Technical Patent Analysts/Agents (Los Angeles, CA; McLean, VA; Palo Alto level patent analysts/agents for our Los Angeles, Palo Alto, San Diego and San Francisco offices of business strategies. Patent analysts/agents participate in domestic and foreign patent prosecution

  17. 2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008

    E-Print Network [OSTI]

    Havens, Timothy

    2008 IEEE Swarm Intelligence Symposium St. Louis MO USA, September 21-23, 2008 Roach Infestation of the PSO algorithm, entitled Roach Infestation Optimization (RIO), that is inspired by recent discoveries discoveries in the behavior of cockroaches are the inspiration for our proposed algorithm, Roach Infestation

  18. Safety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha

    E-Print Network [OSTI]

    as an example. 1. Introduction Software control in safety-critical systems such as aerospace, military, nuclearSafety Analysis Using Coloured Petri Nets Seung Mo Cho, Hyoung Seok Hong, and Sung Deok Cha Department of Computer Science Korea Advanced Institute of Science and Technology (KAIST) 373-1, Kusong

  19. A Network Model and Computational Approach Mo Supply Chain for Nuclear Medicine

    E-Print Network [OSTI]

    Nagurney, Anna

    A Network Model and Computational Approach for the 99 Mo Supply Chain for Nuclear Medicine Ladimer S. Nagurney1 and Anna Nagurney2 1Department of Electrical and Computer Engineering University University of Massachusetts - Amherst, Massachusetts 01003 Fall 2011 Joint Meeting Of The New England

  20. ZnMoO4: a promising bolometer for neutrinoless double beta decay searches

    E-Print Network [OSTI]

    J. W. Beeman; F. Bellini; S. Capelli; L. Cardani; N. Casali; I. Dafinei; S. Di Domizio; F. Ferroni; E. N. Galashov; L. Gironi; F. Orio; L. Pattavina; G. Pessina; G. Piperno; S. Pirro; V. N. Shlegel; Ya. V. Vasilyev; C. Tomei; M. Vignati

    2012-02-01T23:59:59.000Z

    We investigate the performances of two ZnMoO4 scintillating crystals operated as bolometers, in view of a next generation experiment to search the neutrinoless double beta decay of Mo-100. We present the results of the alpha vs beta/gamma discrimination, obtained through the scintillation light as well as through the study of the shape of the thermal signal alone. The discrimination capability obtained at the 2615 keV line of Tl-208 is 8 sigma, using the heat-light scatter plot, while it exceeds 20 sigma using the shape of the thermal pulse alone. The achieved FWHM energy resolution ranges from 2.4 keV (at 238 keV) to 5.7 keV (at 2615 keV). The internal radioactive contaminations of the ZnMoO4 crystals were evaluated through a 407 hours background measurement. The obtained limit is < 32 microBq/kg for Th-228 and Ra-226. These values were used for a Monte Carlo simulation aimed at evaluating the achievable background level of a possible, future array of enriched ZnMoO4 crystals.

  1. Interlayer growth in Mo/B{sub 4}C multilayered structures upon thermal annealing

    SciTech Connect (OSTI)

    Nyabero, S. L.; Kruijs, R. W. E. van de; Yakshin, A. E.; Zoethout, E.; Bosgra, J.; Loch, R. A. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Blanckenhagen, G. von [Carl Zeiss SMT GmbH, Rudolf-Eber-Strasse 2, 73447 Oberkochen (Germany); Bijkerk, F. [FOM Dutch Institute for Fundamental Energy Research (DIFFER), P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2013-04-14T23:59:59.000Z

    Both multilayer period thickness expansion and compaction were observed in Mo/B{sub 4}C multilayers upon annealing, and the physical causes for this were explored in detail. Using in situ time-dependent grazing incidence X-ray reflectometry, period changes down to picometer-scale were resolved. It was shown that the changes depend on the thickness of the B{sub 4}C layers, annealing temperature, and annealing time. Although strong stress relaxation during annealing was observed, it was excluded as a cause for period expansion. Auger electron spectroscopy and wide angle X-ray diffraction measurements revealed the growth of interlayers, with associated period changes influenced by the supply of B and C atoms to the growing compound interlayers. For multilayers with a Mo thickness of 3 nm, two regimes were recognized, depending on the deposited B{sub 4}C thickness: in multilayers with B{sub 4}C {<=} 1.5 nm, the supply of additional Mo into the already formed MoB{sub x}C{sub y} interlayer was dominant and led to densification, resulting in period compaction. For multilayers with B{sub 4}C {>=} 2 nm, the B and C enrichment of interlayers formed low density compounds and yielded period expansion.

  2. TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211

    E-Print Network [OSTI]

    Noble, James S.

    TheElectronMicroscopyCore(EMC) UniversityofMissouriColumbia,MO65211 The. The EMC houses two field emission SEM's, a Hitachi cold-field SEM (S-4700) and a FEI thermal FE SEM imaging and chemical analysis from their SEM/EDS systems. AdditionalSupportby: FormoreInformationortoregistergoto:http://www.emc

  3. RobeRt & LauRie bean taishoff inciting a MoRe incLusive

    E-Print Network [OSTI]

    McConnell, Terry

    RobeRt & LauRie bean taishoff inciting a MoRe incLusive coLLege caMpus syRacuse univeRsity scho. Thanks to her expertise--and the generosity of Robert Taishoff '86 and Laurie Bean Taishoff '84--the

  4. Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1

    E-Print Network [OSTI]

    Braun, Peter

    Incremental Development for Automotive Software in AutoMoDe Andreas Bauer1 Jan Romberg1 Bernhard Validas AG 3 ETAS GmbH 4 PMSF IT Consulting 5 Robert Bosch GmbH Abstract Automotive software development. To facilitate the design and evolution of heterogeneous automotive software, suitable views for each level

  5. Core-level satellites and outer core-level multiplet splitting in Mn model compounds

    SciTech Connect (OSTI)

    Nelson, A. J. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Reynolds, John G. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Roos, Joseph W. [Ethyl Corporation, Richmond, Virginia 23217 (United States)] [Ethyl Corporation, Richmond, Virginia 23217 (United States)

    2000-07-01T23:59:59.000Z

    We report a systematic study of the Mn 2p, 3s, and 3p core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the 3d metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn 3s multiplet splitting becomes smaller as the Mn oxidation state increases, and that 3s-3d electron correlation reduces the branching ratio of the {sup 7}S:{sup 5}S states in the Mn 3s spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the 3s spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration-interaction model including intrashell electron correlation, charge transfer, and final-state screening. (c) 2000 American Vacuum Society.

  6. Neutron diffraction study of MnNiGa{sub 2}—Structural and magnetic behaviour

    SciTech Connect (OSTI)

    Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Ma, L.; Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China); Hofmann, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Avdeev, M.; Kennedy, S. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Md Din, M. F.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Hoelzel, M. [FRM-II, Technische Universität München, 85747 Garching (Germany); Fachbereich Materialwissenschaften, Technische Universität Darmstadt, 64287 Darmstadt (Germany)

    2014-05-07T23:59:59.000Z

    MnNiGa{sub 2} crystallizes in the L21 (Heusler) structure and has a ferromagnetic ordering temperature T{sub C}???192?K. Rietveld refinement of the neutron diffraction patterns indicates that the Ga atoms occupy the equivalent 8c position, while Mn and Ni share the 4a (0, 0, 0) and 4b (0.5, 0.5, 0.5) sites with a mixed occupancy of Mn and Ni atoms. It is found that that ?83% of Mn and ?17% Ni are located at the 4a site while ?83% of Ni and ?17% Mn occupy the 4b site. There is no evidence of a magneto-volume effect around T{sub C}. In agreement with this finding, our detailed critical exponent analyses of isothermal magnetization curves and the related Arrott plots confirm that the magnetic phase transition at T{sub C} is second order.

  7. First-principles study of the interfacial adhesion between SiO2 and MoSi2 D. E. Jiang1 and Emily A. Carter2

    E-Print Network [OSTI]

    Carter, Emily A.

    the energy efficiency and per- formance of gas turbine engines requires structural materials able to operate on MoSi2, a potential high-temperature coating material for metals. This silica scale protects MoSi2 the potential of MoSi2 as a high-temperature structural material and coating. DOI: 10.1103/PhysRevB.72

  8. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highlymore »active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).« less

  9. METALS AND MATERIALS International, Vol. 13, No. 6 (2007), pp. 463~468 Comparative Study on Mechanical Properties of MoSiN Multilayer Films

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    2007-01-01T23:59:59.000Z

    -grown MoSiN thin films, argon and nitrogen plasmas ignited by RF and pulse DC under vacuum conditions were) and Ti-covered Si(100) substrates, as well as silicon nitride substrates. Titanium and its alloy have of a MoSi2 source in the presence of nitrogen plasma and MoSiN films have shown good thermal stability

  10. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Ramirez, Pedro J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. Central De Venezuela, Caracas (Venesuela); Stachiola, Dario [Brookhaven National Lab. (BNL), Upton, NY (United States); Brito, Joaquin L. [Inst. Venezolano de Investigaciones Cientificas, Caracas (Venezuela)

    2015-05-06T23:59:59.000Z

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?•nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²?, Ni²? and Co²? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highly active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).

  11. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

    E-Print Network [OSTI]

    Cui, Yi

    Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

  12. Control of the Magnetic and Magnetotransport Properties of La0.67Sr0.33MnO3 Thin Films Through Epitaxial Strain

    SciTech Connect (OSTI)

    Arenholz, Elke; Takamura, Y.; Chopdekar, R.V.; Arenholz, E.; Suzuki, Y.

    2007-12-20T23:59:59.000Z

    The influence of epitaxial strain, in the form of tetragonal distortions, on the magnetic and magnetotransport properties of La{sub 0.67}Sr{sub 0.33}MnO{sub 3} thin films was studied. The tetragonal distortion (c/a ratio) was modulated through the choice of the substrate, ranging from c/a=1.007 on (001)-oriented (LaAlO{sub 3}){sub 0.3}(Sr{sub 2}AlTaO{sub 6}){sub 0.7} substrates to 0.952 on (110)-oriented GdScO{sub 3} substrates. In agreement with previous theoretical predictions, these large values of tensile strain cause the Curie temperature and the saturation magnetization to decrease, alter the temperature dependence of the resistivity and magnetoresistance, and increase the resistivity several orders of magnitude.

  13. Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations

    E-Print Network [OSTI]

    Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

    2007-01-01T23:59:59.000Z

    J. Inoue, S. Nonoyama, and H. Itoh, Phys. Rev. Lett. 85, 4610 #1;2000#2;. 10 V. I. Litvinov and V. K. Dugaev, Phys. Rev. Lett. 86, 5593 #1;2001#2;. 11 A. C. Durst, R. N. Bhatt, and P. A. Wolff, Phys. Rev. B 65, 235205 #1;2002#2;. 12 A. L.... Chudnovskiy and D. Pfannkuche, Phys. Rev. B 65, 165216 #1;2002#2;. 13 A. Kaminski and S. Das Sarma, Phys. Rev. Lett. 88, 247202 #1;2002#2;. 14 M. Berciu and R. N. Bhatt, Phys. Rev. Lett. 87, 107203 #1;2001#2;. 15 R. N. Bhatt, M. Berciu, M. P. Kennett...

  14. Synthesis of NiCoMnX (X = In, Al) Heusler-type Magnetic Shape Memory Alloy Thin Films 

    E-Print Network [OSTI]

    Rios, Steven Eli

    2014-08-13T23:59:59.000Z

    transformations that showed a grain size dependence. An analytical model that uses a thermodynamic framework was developed to explain the suppression of the martensitic transformations for films with submicron-sized grains. Hence, in addition to chemical...

  15. Synthesis of NiCoMnX (X = In, Al) Heusler-type Magnetic Shape Memory Alloy Thin Films

    E-Print Network [OSTI]

    Rios, Steven Eli

    2014-08-13T23:59:59.000Z

    deposition, and details the challenges associated with controlling film composition, precipitation, microstructure, residual stress, and mechanical properties. As-deposited films were found to contain a mixture of amorphous and nanocrystalline...

  16. Processing, Microstructure and Creep Behavior of Mo-Si-B-Based Intermetallic Alloys for Very High Temperature Structural Applications

    SciTech Connect (OSTI)

    Vijay Vasudevan

    2008-03-31T23:59:59.000Z

    This research project is concerned with developing a fundamental understanding of the effects of processing and microstructure on the creep behavior of refractory intermetallic alloys based on the Mo-Si-B system. In the first part of this project, the compression creep behavior of a Mo-8.9Si-7.71B (in at.%) alloy, at 1100 and 1200 C was studied, whereas in the second part of the project, the constant strain rate compression behavior at 1200, 1300 and 1400 C of a nominally Mo-20Si-10B (in at.%) alloy, processed such as to yield five different {alpha}-Mo volume fractions ranging from 5 to 46%, was studied. In order to determine the deformation and damage mechanisms and rationalize the creep/high temperature deformation data and parameters, the microstructure of both undeformed and deformed samples was characterized in detail using x-ray diffraction, scanning electron microscopy (SEM) with back scattered electron imaging (BSE) and energy dispersive x-ray spectroscopy (EDS), electron back scattered diffraction (EBSD)/orientation electron microscopy in the SEM and transmission electron microscopy (TEM). The microstructure of both alloys was three-phase, being composed of {alpha}-Mo, Mo{sub 3}Si and T2-Mo{sub 5}SiB{sub 2} phases. The values of stress exponents and activation energies, and their dependence on microstructure were determined. The data suggested the operation of both dislocation as well as diffusional mechanisms, depending on alloy, test temperature, stress level and microstructure. Microstructural observations of post-crept/deformed samples indicated the presence of many voids in the {alpha}-Mo grains and few cracks in the intermetallic particles and along their interfaces with the {alpha}-Mo matrix. TEM observations revealed the presence of recrystallized {alpha}-Mo grains and sub-grain boundaries composed of dislocation arrays within the grains (in Mo-8.9Si-7.71B) or fine sub-grains with a high density of b = 1/2<111> dislocations (in Mo-20Si-10B), which are consistent with the values of the respective stress exponents and activation energies that were obtained and provide confirmatory evidence for the operation of diffusional (former alloy) or dislocation (latter alloy) creep mechanisms. In contrast, the intermetallic phases contained very few dislocations, but many cracks. The relative contributions of the {alpha}-Mo and the intermetallic particles to the overall deformation process, including their individual and collective dependence on temperature and strain rate are discussed in light of the present results and those from previous reports.

  17. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

    SciTech Connect (OSTI)

    M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

    2004-09-30T23:59:59.000Z

    Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

  18. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Evidence Confirms Combustion Theory Print Researchers recently uncovered the first step in the process that transforms gas-phase molecules into solid particles like soot and...

  19. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

    SciTech Connect (OSTI)

    Tan, Ying-Hua; Yu, Ke, E-mail: yk5188@263.net; Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang [Key Laboratory of Polar Materials and Devices (Ministry of Education of China), Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)

    2014-08-14T23:59:59.000Z

    The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

  20. Chemical interaction of B{sub 4}C, B, and C with Mo/Si layered structures

    SciTech Connect (OSTI)

    Rooij-Lohmann, V. I. T. A. de; Veldhuizen, L. W.; Zoethout, E.; Yakshin, A. E.; Kruijs, R. W. E. van de [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Thijsse, B. J. [Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft (Netherlands); Gorgoi, M.; Schaefers, F. [Helmholtz-Zentrum Berlin fuer Materialien und Energie GmbH, BESSY II, Albert-Einstein Strasse 15, 12489 Berlin (Germany); Bijkerk, F. [FOM Institute for Plasma Physics Rijnhuizen, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2010-11-15T23:59:59.000Z

    To enhance the thermal stability, B{sub 4}C diffusion barrier layers are often added to Mo/Si multilayer structures for extreme ultraviolet optics. Knowledge about the chemical interaction between B{sub 4}C and Mo or Si, however is largely lacking. Therefore, the chemical processes during annealing up to 600 deg. C of a Mo/B{sub 4}C/Si layered structure have been investigated in situ with hard x-ray photoelectron spectroscopy and ex situ with depth profiling x-ray photoelectron spectroscopy. Mo/B/Si and Mo/C/Si structures have also been analyzed as reference systems. The chemical processes in these systems have been identified, with two stages being distinguished. In the first stage, B and C diffuse and react predominantly with Mo. MoSi{sub x} forms in the second stage. If the diffusion barrier consists of C or B{sub 4}C, a compound forms that is stable up to the maximum probed temperature and annealing time. We suggest that the diffusion barrier function of B{sub 4}C interlayers as reported in literature can be caused by the stability of the formed compound, rather than by the stability of B{sub 4}C itself.

  1. Investigations of segregation phenomena in highly strained Mn-doped Ge wetting layers and Ge quantum dots embedded in silicon

    SciTech Connect (OSTI)

    Prestat, E., E-mail: eric.prestat@gmail.com; Porret, C.; Favre-Nicolin, V.; Tainoff, D.; Boukhari, M.; Bayle-Guillemaud, P.; Jamet, M.; Barski, A., E-mail: andre.barski@cea.com [INAC, SP2M, CEA and Université Joseph Fourier, 17 rue des Martyrs, 38054 Grenoble (France)

    2014-03-10T23:59:59.000Z

    In this Letter, we investigate manganese diffusion and the formation of Mn precipitates in highly strained, few monolayer thick, Mn-doped Ge wetting layers and nanometric size Ge quantum dot heterostructures embedded in silicon. We show that in this Ge(Mn)/Si system manganese always precipitates and that the size and the position of Mn clusters (precipitates) depend on the growth temperature. At high growth temperature, manganese strongly diffuses from germanium to silicon, whereas decreasing the growth temperature reduces the manganese diffusion. In the germanium quantum dots layers, Mn precipitates are detected, not only in partially relaxed quantum dots but also in fully strained germanium wetting layers between the dots.

  2. Epitaxial growth of few-layer MoS2(0001) on FeS2{100}

    E-Print Network [OSTI]

    Liu, T.; Temprano, I.; King, D. A.; Driver, S. M.; Jenkins, S. J.

    2014-11-13T23:59:59.000Z

    ) or self-assembled monolayers have already shown promise in delivering high quality graphene.8 Few-layer MoS2 is most commonly obtained by top-down methods such as lithium intercalation, micro mechanical exfoliation, or liquid-phase exfoliation.2 Attempts... trilayers may be terminated by complete S layers, leading to S–Fe–S–S–Mo–S layering; in this scenario, the epitaxy is driven simply by van der Waals interactions between the layers. In principle, sourcing the S atoms in the MoS2 layer from the bulk FeS2...

  3. Photoresponse properties of large-area MoS{sub 2} atomic layer synthesized by vapor phase deposition

    SciTech Connect (OSTI)

    Luo, Siwei; Qi, Xiang, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn; Ren, Long; Hao, Guolin; Fan, Yinping; Liu, Yundan; Han, Weijia; Zang, Chen; Li, Jun; Zhong, Jianxin, E-mail: xqi@xtu.edu.cn, E-mail: jxzhong@xtu.edu.cn [Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, People's Republic of China Laboratory for Quantum Engineering and Micro-Nano Energy Technology, and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan 411105 (China)

    2014-10-28T23:59:59.000Z

    Photoresponse properties of a large area MoS{sub 2} atomic layer synthesized by vapor phase deposition method without any catalyst are studied. Scanning electron microscopy, atomic force microscopy, Raman spectrum, and photoluminescence spectrum characterizations confirm that the two-dimensional microstructures of MoS{sub 2} atomic layer are of high quality. Photoelectrical results indicate that the as-prepared MoS{sub 2} devices have an excellent sensitivity and a good reproducibility as a photodetector, which is proposed to be ascribed to the potential-assisted charge separation mechanism.

  4. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

    SciTech Connect (OSTI)

    Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

    2008-03-19T23:59:59.000Z

    The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

  5. Mn Occupations in Ga1-xMnxN Dilute Magnetic Semiconductors Probed by X-Ray Absorption Near-Edge Structure Spectroscopy

    SciTech Connect (OSTI)

    Wei Shiqiang; Yan Wensheng; Sun Zhihu; Liu Qinghua; Zhong Wenjie [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Zhang Xinyi [Department of Physics, Surface Physics Laboratory (National Key Laboratory), Fudan University, 220 Handan Road, Shanghai 200433 (China); Synchrotron Radiation Research Center, Fudan University, 220 Handan Road, Shanghai 200433 (China); Oyanagi, H. [Photonics Research Institute, National Institute of Advanced Industrial Science and Technology 1-1-1 Umezono Tsukuba, Ibaraki 305-8568 (Japan); Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China)

    2007-02-02T23:59:59.000Z

    X-ray absorption near-edge structure (XANES) is used to study the characteristics of different sites of Mn in the Ga1-xMnxN dilute magnetic semiconductor (DMS) with zinc-blende structure. The XANES spectra of representative Mn occupation sites (substitutional MnGa, interstitial MnI, MnGa-MnI dimer and Mn cluster) in GaN lattice are theoretically calculated and compared with experimental results. The substitutional Mn in GaN is characterized by a pre-edge peak at 2.0 eV and a post-edge multiple-scattering peak at 29.1 eV. The peaks shift in position and drop in intensity dramatically for the interstitial MnI and MnGa-MnI dimmer, and disappear completely for Mn clusters. We propose that the distinct characteristics of Mn K-edge XANES spectra for different Mn sites favor to discriminate Mn occupations in GaMnN DMS.

  6. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

    SciTech Connect (OSTI)

    Liu, Chao-Xing; /Tsinghua U., Beijing /Stanford U., Phys. Dept.; Qi, Xiao-Liang; /Stanford U., Phys. Dept.; Dai, Xi; Fang, Zhong; /Beijing, Inst. Phys.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-03-19T23:59:59.000Z

    The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

  7. Tailoring interlayer coupling and coercivity in Co/Mn/Co trilayers by controlling the interface roughness

    SciTech Connect (OSTI)

    Zhang, Bin; Wu, Chii-Bin; Kuch, Wolfgang, E-mail: kuch@physik.fu-berlin.de [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin (Germany)

    2014-06-21T23:59:59.000Z

    Epitaxial Co/Mn/Co trilayers with a wedged Mn layer were grown on Cu(001) and studied by magneto-optical Kerr effect measurements. The bottom Co film as well as the Mn film exhibits a layer-by-layer growth mode, which allows to modify both interface roughnesses on the atomic scale by tuning the thicknesses of the films to achieve a certain filling of their topmost atomic layers. The onset of antiferromagnetic order in the Mn layer at room temperature was found at thicknesses of 4.1 (4.8) and 3.4 (4.0) atomic monolayers (ML) for a filled (half-filled) topmost atomic layer of the bottom Co film in Mn/Co bilayers and Co/Mn/Co trilayers, respectively. Magnetization loops with only one step were found for a trilayer with half-filled topmost atomic layer of the bottom Co film, while loops with two separate steps have been observed in trilayers with an integer number of atomic layers in the bottom Co film. The coercivity of the top Co film shows an oscillation with 1 ML period as a function of the Mn thickness above 10 ML, which is interpreted as the influence of the atomic-scale control of the interface roughness on the interface exchange coupling between the antiferromagnetic Mn and the top ferromagnetic (FM) Co layer. The strength of the magnetic interlayer coupling between the top and bottom Co layers through the Mn layer for an integer number of atomic layers in the bottom Co layer, deduced from minor-loop measurements, exhibits an oscillation with a period of 2 ML Mn thickness, indicative of direct exchange coupling through the antiferromagnetic Mn layer. In addition, a long-period interlayer coupling of the two FM layers with antiparallel coupling maxima at Mn thicknesses of 2.5, 8.2, and 13.7 ML is observed and attributed to indirect exchange coupling of the Rudermann-Kittel-Kasuya-Yosida type.

  8. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15T23:59:59.000Z

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  9. Microstructure, microstructural stability and mechanical properties of sand-cast Mg–4Al–4RE alloy

    SciTech Connect (OSTI)

    Rzycho?, Tomasz, E-mail: tomasz.rzychon@polsl.pl [Silesian University of Technology, Faculty of Materials Science and Metallurgy, Krasi?skiego 8, 40 019 Katowice (Poland); Kie?bus, Andrzej [Silesian University of Technology, Faculty of Materials Science and Metallurgy, Krasi?skiego 8, 40 019 Katowice (Poland); Lity?ska-Dobrzy?ska, Lidia [Polish Academy of Sciences, Institute of Metallurgy and Materials Science, 25 Reymonta Street, 30-059 Kraków (Poland)

    2013-09-15T23:59:59.000Z

    This paper presents a methodology for assessing the phase composition and the results of structural stability tests of the sand-cast Mg–4Al–4RE alloy after annealing it at 175 and 250 °C for 3000 h. The microstructure was analyzed with optical, scanning electron, and transmission electron microscopy. The phase composition was determined with X-ray diffraction. The structure of the Mg–4Al–4RE (AE44) alloy is composed of large grains of ?-Mg solid solution, needle-shaped precipitates of the Al{sub 11}RE{sub 3}phase, polyhedral precipitates of the Al{sub 2}RE phase and Al{sub 10}RE{sub 2}Mn{sub 7} phase. After annealing at 175 °C for 3000 h, no changes in the alloy structure are observed, whereas after annealing at 250 °C the precipitates of the Al{sub 11}RE{sub 3} phase are found to be in the initial stages of spheroidization. The coarse-grained structure and unfavorable morphology of the intermetallic phases in the sand-cast AE44 alloy, which are caused by low solidification rates, result in low creep resistance up to 200 °C and low mechanical properties at ambient temperature and at 175 °C. - Highlights: • Complement the knowledge about the microstructure of Mg-Al-RE alloys. • Clarify the mechanism of formation of Mg17Al12 phase above 180 °C. • Applying a chemical dissolution of the ?-Mg in order to phase identification. • Applying a statistical test to assess the spheroidization of precipitates. • Quantitative description of microstructure of Mg-Al-RE alloys.

  10. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW (TUM & AUI Alumni) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für

  11. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM School

  12. Al Akhawayn University Al Akhawayn partner of TUM since 2002

    E-Print Network [OSTI]

    Cengarle, María Victoria

    Haddouti · Dissertation at Chair for Databases (Prof. Bayer), Professor at Al Akhawayn, now working at BMW Alumni) · BMW, Hachim.haddouti@bmw.de #12;Double Degree TUM - Georgia Tech Fakultät für Informatik TUM

  13. An experimental study of the solubility of MoO3 in aqueous vapour and low to intermediate density

    E-Print Network [OSTI]

    (Zajacz et al., 2008; Lerchbaumer and Audetat, 2012; Seo et al., 2012). In view of this, it is important., 1999; Audetat and Pettke, 2003; Rusk et al., 2004; Klemm et al., 2007, 2008; Zajacz et al., 2008; Seo et al., 2009; Audetat, 2010; Landtwing et al., 2010; Lerchbaumer and Audetat, 2012; Seo et al., 2012

  14. Brittle Fracture in a 50Mo-50Re alloy in static tensile testing

    SciTech Connect (OSTI)

    Xu, Jianhui [University of Kentucky, Lexington; Kenik, Edward A [ORNL; Zhai, Tongguang [University of Kentucky, Lexington

    2008-01-01T23:59:59.000Z

    Tensile tests were conducted on 50Mo-50Re alloys, in fully-recrystallized and recovery heat-treated conditions respectively, at a very low strain rate of 10-6 s-1 and room temperature in air. It was found that both these alloys exhibited predominantly cleavage fracture with significant intergranular secondary cracking, compared to the predominantly ductile fracture found in the alloys at a higher strain rate. Cracks were often initiated at grain boundary triple junctions at the low strain rate. Electron back scatter diffraction (EBSD) measurements revealed significantly high misorientation gradients at grain boundaries, especially in the vicinity of some grain boundary triple junctions in the deformed alloys. Transmission electron microscopic (TEM) results verified the existence of significant misorientation taking place at grain boundaries in these alloys. Stress-assisted dynamic embrittlement, possibly due to trace interstitials, was the possible cause for the occurrence of brittle fracture in the 50Mo-50Re alloys at the low strain rate.

  15. Spectroscopy of Double-Beta and Inverse-Beta Decays from 100Mo for Neutrinos

    E-Print Network [OSTI]

    H. Ejiri; J. Engel; R. Hazama; P. Krastev; N. Kudomi; R. G. H. Robertson

    2000-05-15T23:59:59.000Z

    Spectroscopic studies of two beta-rays from 100Mo are shown to be of potential interest for investigating both the Majorana neutrino mass by neutrinoless double beta-decay and low energy solar neutrino's by inverse beta-decay. With a multi-ton 100Mo detector, coincidence studies of correlated beta-beta from neutrinoless double beta-decay, together with the large Q value, permit identification of the neutrino-mass term with a sensitivity of ~ 0.03 eV. Correlation studies of the inverse beta and the successive beta-decay of 100Tc, together with the large capture rates for low energy solar neutrino's, make it possible to detect in realtime individual low energy solar neutrino in the same detector.

  16. Air damping of atomically thin MoS{sub 2} nanomechanical resonators

    SciTech Connect (OSTI)

    Lee, Jaesung; Wang, Zenghui; Feng, Philip X.-L., E-mail: philip.feng@case.edu [Department of Electrical Engineering and Computer Science, Case School of Engineering, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States); He, Keliang; Shan, Jie [Department of Physics, College of Arts and Sciences, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, Ohio 44106 (United States)

    2014-07-14T23:59:59.000Z

    We report on experimental measurement of air damping effects in high frequency nanomembrane resonators made of atomically thin molybdenum disulfide (MoS{sub 2}) drumhead structures. Circular MoS{sub 2} nanomembranes with thickness of monolayer, few-layer, and multi-layer up to ?70?nm (?100 layers) exhibit intriguing pressure dependence of resonance characteristics. In completely covered drumheads, where there is no immediate equilibrium between the drum cavity and environment, resonance frequencies and quality (Q) factors strongly depend on environmental pressure due to bulging of the nanomembranes. In incompletely covered drumheads, strong frequency shifts due to compressing-cavity stiffening occur above ?200?Torr. The pressure-dependent Q factors are limited by free molecule flow (FMF) damping, and all the mono-, bi-, and tri-layer devices exhibit lower FMF damping than thicker, conventional devices do.

  17. Oxidation Behavior and Chlorination Treatment to Improve Oxidation Resistance of Nb-Mo-Si-B Alloys

    SciTech Connect (OSTI)

    Vikas Behrani

    2004-12-19T23:59:59.000Z

    This thesis is written in an alternate format. The thesis is composed of a general introduction, two original manuscripts, and a general conclusion. References cited within each chapter are given at the end of each chapter. The general introduction starts with the driving force behind this research, and gives an overview of previous work on boron doped molybdenum silicides, Nb/Nb{sub 5}Si{sub 3} composites, boron modified niobium silicides and molybdenum niobium silicides. Chapter 2 focuses on the oxidation behavior of Nb-Mo-Si-B alloys. Chapter 3 contains studies on a novel chlorination technique to improve the oxidation resistance of Nb-Mo-Si-B alloys. Chapter 4 summarizes the important results in this study.

  18. Fission induced swelling and creep of U–Mo alloy fuel

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; J. S. Cheon; A. B. Robinson; D. M. Wachs

    2013-06-01T23:59:59.000Z

    Tapering of U–Mo alloy fuel at the end of plates is attributed to lateral mass transfer by fission induced creep, by which fuel mass is relocated away from the fuel end region where fission product induced fuel swelling is in fact the highest. This mechanism permits U–Mo fuel to achieve high burnup by effectively relieving stresses at the fuel end region, where peak stresses are otherwise expected because peak fission product induced fuel swelling occurs there. ABAQUS FEA was employed to examine whether the observed phenomenon can be simulated using physical–mechanical data available in the literature. The simulation results obtained for several plates with different fuel fabrication and loading scheme showed that the measured data were able to be simulated with a reasonable creep rate coefficient. The obtained creep rate constant lies between values for pure uranium and MOX, and is greater than all other ceramic uranium fuels.

  19. Induced codeposition. 1: An experimental investigation of Ni-Mo alloys

    SciTech Connect (OSTI)

    Podlaha, E.J.; Landolt, D. [Ecole Polytechnique Federale de Lausanne (Switzerland)

    1996-03-01T23:59:59.000Z

    The electrodeposition of nickel-molybdenum alloys was studied on rotating cylinder electrodes. The current density, electrode rotation rate, electrolyte temperature, and species concentrations were shown to influence alloy composition. The mass-transport limiting species were identified for different operating conditions and electrolyte compositions in order to study the rate-limiting steps of induced codeposition. If the concentration of nickel in the electrolyte was much larger than that of molybdate the molybdenum content in the alloy increased with rotation rate. On the other hand, if the concentration of molybdate in the electrolyte was larger than that of nickel the alloy composition was found to be independent of rotation rate. These results were applied to the deposition of compositionally modulated Ni-Mo alloys exhibiting larger periodic variations in Mo concentration than hitherto reported.

  20. Phase transitions in K-doped MoO{sub 2}

    SciTech Connect (OSTI)

    Alves, L. M. S., E-mail: leandro-fisico@hotmail.com; Lima, B. S. de; Santos, C. A. M. dos [Departamento de Engenharia de Materiais, Escola de Engenharia de Lorena-USP, Lorena, São Paulo 12602-810 (Brazil); Rebello, A.; Masunaga, S. H.; Neumeier, J. J. [Department of Physics, Montana State University, P.O. Box 173840, Bozeman, Montana 59717-3840 (United States); Leão, J. B. [NIST Center for Neutron Research, National Institute of Standards and Technology, 100 Bureau Dr. MS 6102, Gaithersburg, Maryland 20899-6102 (United States)

    2014-05-28T23:59:59.000Z

    K{sub 0.05}MoO{sub 2} has been studied by x-ray and neutron diffractometry, electrical resistivity, magnetization, heat capacity, and thermal expansion measurements. The compound displays two phase transitions, a first-order phase transition near room temperature and a second-order transition near 54?K. Below the transition at 54?K, a weak magnetic anomaly is observed and the electrical resistivity is well described by a power-law temperature dependence with exponent near 0.5. The phase transitions in the K-doped MoO{sub 2} compound have been discussed for the first time using neutron diffraction, high resolution thermal expansion, and heat capacity measurements as a function of temperature.

  1. LEXICAL DECISION IN A PHONOLOGICALLY SHALLOW ORTHOGRAPHY* G Lukatela+, Do Popadic+, P. Ognjenovic+, and Mo To Turvey++

    E-Print Network [OSTI]

    +, and Mo To Turvey++ Abstracto The Serbo-Croatian language is written in two alphabets, Roman and Cyrillic shallow writing systems of Serbo-Croatian, lex ical decision proceeds with reference to the phonology

  2. Performance of ZnMoO4 crystal as cryogenic scintillating bolometer to search for double beta decay of molybdenum

    E-Print Network [OSTI]

    L. Gironi; C. Arnaboldi; J. W. Beeman; O. Cremonesi; F. A. Danevich; V. Ya. Degoda; L. I. Ivleva; L. L. Nagornaya; M. Pavan; G. Pessina; S. Pirro; V. I. Tretyak; I. A. Tupitsyna

    2010-10-01T23:59:59.000Z

    Zinc molybdate (ZnMoO4) single crystals were grown for the first time by the Czochralski method and their luminescence was measured under X ray excitation in the temperature range 85-400 K. Properties of ZnMoO4 crystal as cryogenic low temperature scintillator were checked for the first time. Radioactive contamination of the ZnMoO4 crystal was estimated as <0.3 mBq/kg (228-Th) and 8 mBq/kg (226-Ra). Thanks to the simultaneous measurement of the scintillation light and the phonon signal, the alpha particles can be discriminated from the gamma/beta interactions, making this compound extremely promising for the search of neutrinoless Double Beta Decay of 100-Mo. We also report on the ability to discriminate the alpha-induced background without the light measurement, thanks to a different shape of the thermal signal that characterizes gamma/beta and alpha particle interactions.

  3. High yield production of inorganic graphene-like materials (MoS?, WS?, BN) through liquid exfoliation testing key parameters

    E-Print Network [OSTI]

    Pu, Fei, S.B. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Inorganic graphene-like materials such as molybdenum disulfide (MoS?), tungsten sulfide (WS?), and boron nitride (BN) are known to have electronic properties. When exfoliated into layers and casted onto carbon nanofilms, ...

  4. Two photon absorption and its saturation of WS2 and MoS2 monolayer and few-layer films

    E-Print Network [OSTI]

    Zhang, Saifeng; McEvoy, Niall; O'Brien, Maria; Winters, Sinéad; Berner, Nina C; Yim, Chanyoung; Zhang, Xiaoyan; Chen, Zhanghai; Zhang, Long; Duesberg, Georg S; Wang, Jun

    2015-01-01T23:59:59.000Z

    The optical nonlinearity of WS2, MoS2 monolayer and few-layer films was investigated using the Z-scan technique with femtosecond pulses from the visible to the near infrared. The dependence of nonlinear absorption of the WS2 and MoS2 films on layer number and excitation wavelength was studied systematically. WS2 with 1~3 layers exhibits a giant two-photon absorption (TPA) coefficient. Saturation of TPA for WS2 with 1~3 layers and MoS2 with 25~27 layers was observed. The giant nonlinearity of WS2 and MoS2 is attributed to two dimensional confinement, a giant exciton effect and the band edge resonance of TPA.

  5. Quantitative Prediction of Surface Segregation in Bimetallic Pt-MAlloy Nanoparticles (M=Ni, Re, Mo)

    SciTech Connect (OSTI)

    Wang, Guofeng; Van Hove, Michel A.; Ross, Phil N.; Baskes,Michael I.

    2005-06-20T23:59:59.000Z

    This review addresses the issue of surface segregation inbimetallic alloy nanoparticles, which are relevant to heterogeneouscatalysis, in particular for electro-catalysts of fuel cells. We describeand discuss a theoretical approach to predicting surface segregation insuch nanoparticles by using the Modified Embedded Atom Method and MonteCarlo simulations. In this manner it is possible to systematicallyexplore the behavior of such nanoparticles as a function of componentmetals, composition, and particle size, among other variables. We choseto compare Pt75Ni25, Pt75Re25, and Pt80Mo20 alloys as example systems forthis discussion, due to the importance of Pt in catalytic processes andits high-cost. It is assumed that the equilibrium nanoparticles of thesealloys have a cubo-octahedral shape, the face-centered cubic lattice, andsizes ranging from 2.5 nm to 5.0 nm. By investigating the segregation ofPt atoms to the surfaces of the nanoparticles, we draw the followingconclusions from our simulations at T= 600 K. (1) Pt75Ni25 nanoparticlesform a surface-sandwich structure in which the Pt atoms are stronglyenriched in the outermost and third layers while the Ni atoms areenriched in the second layer. In particular, a nearly pure Pt outermostsurface layer can be achieved in those nanoparticles. (2) EquilibriumPt75Re25 nanoparticles adopt a core-shell structure: a nearly pure Ptshell surrounding a more uniform Pt-Re core. (3) In Pt80Mo20nanoparticles, the facets are fully occupied by Pt atoms, the Mo atomsonly appear at the edges and vertices, and the Pt and Mo atoms arrangethemselves in an alternating sequence along the edges and vertices. Oursimulations quantitatively agree with previous experimental andtheoretical results for the extended surfaces of Pt-Ni, Pt-Re, and Pt-Moalloys. We further discuss the reasons for the different types of surfacesegregation found in the different alloys, and some of theirimplications.

  6. An internship with San Tomas hunting camp Freeport-McMoRan, Inc. 

    E-Print Network [OSTI]

    Huggins, J. Grant

    1986-01-01T23:59:59.000Z

    An Internship with San Tomas Hunting Camp Freeport~NoRan, Inc. : A PRCFESSIQRAL PAPER by J. Grant Huggine Submitted to the College of Agriculture of Texas AN University in Rmrtial fulfillment of the requirements for the degree of NASTER GF... AGRICULTURE December 1986 Najor Subject: Wildlife Science Department of Wildife and Fisheries Sciences An Internship with San Tomas Hunting Camp Fr eeport-McMoRan, Inc. by J. Grant Huggins Approved as to style and content by: Wallace G. Klussmann...

  7. Continuing investigations for technology assessment of /sup 99/Mo production from LEU (low enriched Uranium) targets

    SciTech Connect (OSTI)

    Vandergrift, G.F.; Kwok, J.D.; Marshall, S.L.; Vissers, D.R.; Matos, J.E.

    1987-01-01T23:59:59.000Z

    Currently much of the world's supply of /sup 99m/Tc for medical purposes is produced from /sup 99/Mo derived from the fissioning of high enriched uranium (HEU). The need for /sup 99m/Tc is continuing to grow, especially in developing countries, where needs and national priorities call for internal production of /sup 99/Mo. This paper presents the results of our continuing studies on the effects of substituting low enriched Uranium (LEU) for HEU in targets for the production of fission product /sup 99/Mo. Improvements in the electrodeposition of thin films of uranium metal are reported. These improvements continue to increase the appeal for the substitution of LEU metal for HEU oxide films in cylindrical targets. The process is effective for targets fabricated from stainless steel or hastaloy. A cost estimate for setting up the necessary equipment to electrodeposit uranium metal on cylindrical targets is reported. Further investigations on the effect of LEU substitution on processing of these targets are also reported. Substitution of uranium silicides for the uranium-aluminum alloy or uranium aluminide dispersed fuel used in other current target designs will allow the substitution of LEU for HEU in these targets with equivalent /sup 99/Mo-yield per target and no change in target geometries. However, this substitution will require modifications in current processing steps due to (1) the insolubility of uranium silicides in alkaline solutions and (2) the presence of significant quantities of silicate in solution. Results to date suggest that both concerns can be handled and that substitution of LEU for HEU can be achieved.

  8. AutoMoDe - Model-Based Development of Automotive Software

    E-Print Network [OSTI]

    Ziegenbein, Dirk; Freund, Ulrich; Bauer, Andreas; Romberg, Jan; Schatz, Bernhard

    2011-01-01T23:59:59.000Z

    This paper describes first results from the AutoMoDe (Automotive Model-Based Development) project. The overall goal of the project is to develop an integrated methodology for model-based development of automotive control software, based on problem-specific design notations with an explicit formal foundation. Based on the existing AutoFOCUS framework, a tool prototype is being developed in order to illustrate and validate the key elements of our approach.

  9. Effect of heat treatment on the mechanical properties of modified 9Cr-1Mo steel

    SciTech Connect (OSTI)

    Sultan F. Alsagabi; Triratna Shrestha; Indrajit Charit; Gabriel P. Potirniche; Michael V. Glazoff

    2014-09-01T23:59:59.000Z

    The modified 9Cr-1Mo steel (Grade 91) is a material of choice in fossil-fuel-fired power plants with increased efficiency, service life, and reduction in emission of greenhouse gases. It is also considered a prospective material for the Next Generation Nuclear Power Plant for application in reactor pressure vessels at temperatures up to 650°C. In this paper, heat treatment of the modified 9Cr-1Mo steel was studied by normalizing and tempering the steel at various temperatures and times, with the ultimate goal of improving its creep resistance and optimizing material hardness. The microstructural evolution of the heat treated steels was correlated with the differential scanning calorimetric results. Optical microscopy, scanning and transmission electron microscopy in conjunction with microhardness profiles and calorimetric plots were used to understand the evolution of microstructure including precipitate structures in modified 9Cr-1Mo steel and relate it to the mechanical behavior of the steel. Thermo- CalcTM calculations were used to support experimental work and provide guidance in terms of the precipitate stability and microstructural evolution. Furthermore, the carbon isopleth and temperature dependencies of the volume fraction of different precipitates were constructed. The predicted and experimentally observed results were found to be in good agreement.

  10. Evolution of collectivity along the N=Z line: The {sup 84}Mo nucleus

    SciTech Connect (OSTI)

    Bucurescu, D.; Ur, C.A.; Marginean, N.; Ionescu-Bujor, M.; Iordachescu, A.; Petrache, C.M. [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania)] [Horia Hulubei National Institute of Physics and Nuclear Engineering, Bucharest (Romania); Ur, C.A; Bazzacco, D.; Lunardi, S.; Petrache, C.M.; Brandolini, F.; Falconi, G.; Lenzi, S.M.; Venturelli, R. [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy)] [Dipartimento di Fisica dellUniversita and INFN, Sezione di Padova, Padova (Italy); Napoli, D.R.; de Angelis, G.; Gadea, A.; Foltescu, D.; Farnea, E.; Podolyak, Zs.; De Poli, M. [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy)] [INFN, Laboratori Nazionali di Legnaro, Legnaro (Italy); Rao, M.N. [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)] [Universidade de Sao Paolo, Sao Paolo, Brasil (Brazil)

    1997-11-01T23:59:59.000Z

    The reaction {sup 58}Ni({sup 28}Si,2n{gamma}) at 90 MeV incident energy has been used to populate the N=Z nucleus {sup 84}Mo. The GASP array was used together with the ISIS Silicon ball, which allowed a subtraction of the charged particle channels in the {gamma}-{gamma} coincidences. The only known transition 2{sub 1}{sup +}{r_arrow}0{sub 1}{sup +} of 443.8 keV in {sup 84}Mo has been found in coincidence with a {gamma} ray of 673.5{plus_minus}0.4 keV which was assigned as the second (4{sub 1}{sup +}{r_arrow}2{sub 1}{sup +}) yrast transition. The behavior of the resulting yrast line indicates that {sup 84}Mo is a transitional nucleus. The correlation between the excitation energies of the 2{sub 1}{sup +} and 4{sub 1}{sup +} levels of the N=Z nuclei reveals a systematic deviation from the average behavior defined by all collective even-even nuclei. {copyright} {ital 1997} {ital The American Physical Society}

  11. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

    SciTech Connect (OSTI)

    Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2012-12-15T23:59:59.000Z

    The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

  12. Robust ferroelectric state in multiferroic Mn 1 ? x Zn x WO 4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chaudhury, R. P.; Ye, F.; Fernandez-Baca, J. A.; Lorenz, B.; Wang, Y. Q.; Sun, Y. Y.; Mook, H. A.; Chu, C. W.

    2011-01-01T23:59:59.000Z

    We report on the remarkably robust ferroelectric state in the multiferroic compound Mn1-xZnxWO?. Substitution of the magnetic Mn²? with nonmagnetic Zn²? reduces the magnetic exchange and provides control of the various magnetic and multiferroic states of MnWO?. Only 5% of Zn substitution results in complete suppression of the frustrated collinear (paraelectric) low-temperature phase. The helical magnetic and ferroelectric phase develops as the ground state. The multiferroic state is stable up to a high level of substitution of more than 50%. The magnetic, thermodynamic, and dielectric properties, as well as the ferroelectric polarization of single crystals of Mn1-xZnxWO?, are studied for different substitutions up to x=0.5. The magnetic phases have been identified in single-crystal neutron-scattering experiments. The ferroelectric polarization scales with the neutron intensity of the incommensurate peak of the helical phase.

  13. Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1

    E-Print Network [OSTI]

    Sparks, Donald L.

    Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano

  14. Mn solid solutions in self-assembled Ge/Si (001) quantum dot heterostructures

    SciTech Connect (OSTI)

    Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

    2012-12-10T23:59:59.000Z

    Heteroepitaxial Ge{sub 0.98}Mn{sub 0.02} quantum dots (QDs) on Si (001) were grown by molecular beam epitaxy. The standard Ge wetting layer-hut-dome-superdome sequence was observed, with no indicators of second phase formation in the surface morphology. We show that Mn forms a dilute solid solution in the Ge quantum dot layer, and a significant fraction of the Mn partitions into a sparse array of buried, Mn-enriched silicide precipitates directly underneath a fraction of the Ge superdomes. The magnetic response from the ultra-thin film indicates the absence of robust room temperature ferromagnetism, perhaps due to anomalous intermixing of Si into the Ge quantum dots.

  15. Growth of GaMnAs under near-stoichiometric conditions

    SciTech Connect (OSTI)

    Avrutin, V.; Humienik, D.; Frank, S.; Koeder, A.; Schoch, W.; Limmer, W.; Sauer, R.; Waag, A. [Abteilung Halbleiterphysik, Universitaet Ulm, D-89069 Ulm (Germany); Institut fuer Halbleitertechnik, Technische Universitaet (TU) Braunschweig, Hans-Sommer-Strasse 66, D38103 Braunschweig (Germany)

    2005-07-15T23:59:59.000Z

    We studied the effect of the V/III flux ratio and substrate temperature on magnetotransport properties and lattice parameters of Ga{sub 0.96}Mn{sub 0.04}As grown by molecular-beam epitaxy. For all the substrate temperatures, the conductivities and Curie temperatures of the layers were found to increase as the V/III flux ratio approaches 1. A Curie temperature as high as 95 K was achieved for the Ga{sub 0.96}Mn{sub 0.04}As samples grown at 240 deg. C and a V/III ratio of about 1.5. The lattice parameter of Ga{sub 0.96}Mn{sub 0.04}As increased with decreasing V/III ratio and/or increasing growth temperature. Possible reasons for the effect of the V/III ratio on the magnetotransport properties and lattice parameter of GaMnAs are discussed.

  16. Fabrication and Luminescence of ZnS:Mn2+ Nanoflowers. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of ZnS:Mn2+ nanoparticles are prepared and characterized. The configurations of these fractal structures are very sensitive to both the pH values of the particle solutions from...

  17. Synthesis and Luminescence of ZnMgS:Mn2+ Nanoparticles. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    followed by a post-annealing process, thus showing the features of less complexity, low cost, and easy incorporation of dopants. In comparison with the emission of ZnS:Mn2+...

  18. Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee, 1979-

    2007-01-01T23:59:59.000Z

    Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

  19. Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition

    E-Print Network [OSTI]

    Xia, Hui

    LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

  20. Response of Citrus volkameriana (L.) plants to different Mn concentrations under hydroponic conditions.

    E-Print Network [OSTI]

    Papadakis, Ioannis; Sotiropoulos, Thomas; Giannakoula, Anastasia; Antonopoulou, Chrysovalantou; Therios, Ioannis

    2009-01-01T23:59:59.000Z

    and Mn +2 stress conditions. Plant Sci. 165, 769-776. Heuer,and glycinebetaine on growth of salt-stressed tomato plants.Plant Sci. 165, 693-699. Hoagland, D. R. , Arnon, D. I. (

  1. Frequency Response of Acoustic-Assisted Ni–Mn–Ga Ferromagnetic- Shape-Memory-Alloy Actuator

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee

    A prototype of Ni–Mn–Ga based ferromagnetic-shape-memory-alloy (FSMA) actuator was designed and built; an acoustic-assist technique was applied to the actuator to enhance its performance. A piezoelectric stack actuator was ...

  2. Synthesis and characterization of MnPS{sub 3} for hydrogen sorption

    SciTech Connect (OSTI)

    Ismail, N., E-mail: nahlaismail24@yahoo.co [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Temerk, Y.M. [Assiut University, Faculty of Science, Chemistry Department, Assuit (Egypt); El-Meligi, A.A. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt); Badr, M.A. [Mechanical Engineering Department, Cairo (Egypt); Madian, M. [Physical Chemistry Department, National Research Center, Center of Excellence for Advanced Science, Renewable Energy Group, Cairo (Egypt)

    2010-05-15T23:59:59.000Z

    Single phase MnPS{sub 3} powder was prepared by solid state reaction between Mn, S and P carried out at 650 deg. C in evacuated silica tube. The structure, morphology and sorption characteristics of the prepared solid were investigated. The results revealed that the obtained MnPS{sub 3} compound was capable of adsorbing 3.5 wt% hydrogen at -193 deg. C and a pressure of 30 bar. Little amount of hydrogen (0.07 wt%) was adsorbed at room temperature. The hydrogen adsorption/desorption cycles at various temperatures did not result in irreversible chemical structural changes of the MnPS{sub 3} compound, but the microstructure after hydrogen cycling diminished and became finer. - Graphical abstract: Atomic building of MPS{sub 3}

  3. Mn Monolayer Modified Rh for Syngas-to-Ethanol Conversion: A First-Principles Study

    SciTech Connect (OSTI)

    Li, Fengyu [University of Puerto Rico; Jiang, Deen [ORNL; Zeng, X.C. [University of Nebraska, Lincoln; Chen, Zhongfang [University of Puerto Rico

    2012-01-01T23:59:59.000Z

    Rh is unique in its ability to convert syngas to ethanol with the help of promoters. We performed systematic first-principles computations to examine the catalytic performance of pure and Mn modified Rh(100) surfaces for ethanol formation from syngas. CO dissociation on the surface as well as CO insertion between the chemisorbed CH{sub 3} and the surface are the two key steps. The CO dissociation barrier on the Mn monolayer modified Rh(100) surface is remarkably lowered by {approx}1.5 eV compared to that on Rh(100). Moreover, the reaction barrier of CO insertion into the chemisorbed CH{sub 3} group on the Mn monolayer modified Rh(100) surface is 0.34 eV lower than that of methane formation. Thus the present work provides new mechanistic insight into the role of Mn promoters in improving Rh's selectivity to convert syngas to ethanol.

  4. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    E-Print Network [OSTI]

    Nelson-Cheeseman, B. B.

    2007-01-01T23:59:59.000Z

    Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

  5. Modeling and Characterization of the Magnetocaloric Effect in Ni2MnGa Materials

    SciTech Connect (OSTI)

    Nicholson, Don M [ORNL; Odbadrakh, Khorgolkhuu [ORNL; Rios, Orlando [ORNL; Hodges, Jason P [ORNL; Ludtka, Gerard Michael [ORNL; Porter, Wallace D [ORNL; Sefat, A. S. [Oak Ridge National Laboratory (ORNL); Rusanu, Aurelian [ORNL; Evans III, Boyd Mccutchen [ORNL

    2012-01-01T23:59:59.000Z

    Magnetic shape memory alloys have great promise as magneto-caloric effect refrigerant materials due to their combined magnetic and structural transitions. Computational and experimental research is reported on the Ni2MnGa material system. The magnetic states of this system have been explored using the Wang-Landau statistical approach in conjunction with the Locally Self-consistent Multiple-Scattering (LSMS) method to explore the magnetic states responsible for the magnet-caloric effect in this material. The effects of alloying agents on the transition temperatures of the Ni2MnGa alloy were investigated using differential scanning calorimetry (DSC) and superconducting quantum interference device (SQUID). Neutron scattering experiments were performed to observe the structural and magnetic phase transformations at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on alloys of Ni-Mn-Ga and Ni-Mn-Ga-Cu-Fe. Data from the observations are discussed in comparison with the computational studies.

  6. DOI: 10.1002/ejic.200700164 Chlorido-Bridged MnII

    E-Print Network [OSTI]

    Gao, Song

    geometry sharing an equatorial-to-axial edge with parallel equatorial planes. The hydrogen bonds be,[3] dicyanamide,[4] and car- boxylate.[5] Ferromagnetic exchange coupling among these MnII compounds

  7. Above room-temperature ferromagnetism of Mn delta-doped GaN nanorods

    SciTech Connect (OSTI)

    Lin, Y. T.; Wadekar, P. V.; Kao, H. S.; Chen, T. H.; Chen, Q. Y.; Tu, L. W., E-mail: lwtu@faculty.nsysu.edu.tw [Department of Physics and Center for Nanoscience and Nanotechnology, National Sun Yat-Sen University, Kaohsiung 80424, Taiwan (China); Huang, H. C.; Ho, N. J. [Department of Materials and Optoelectronic Science and Center for Nanoscience and Nanotechnology, National Sun Yat-Sen University, Kaohsiung 80424, Taiwan (China)

    2014-02-10T23:59:59.000Z

    One-dimensional nitride based diluted magnetic semiconductors were grown by plasma-assisted molecular beam epitaxy. Delta-doping technique was adopted to dope GaN nanorods with Mn. The structural and magnetic properties were investigated. The GaMnN nanorods with a single crystalline structure and with Ga sites substituted by Mn atoms were verified by high-resolution x-ray diffraction and Raman scattering, respectively. Secondary phases were not observed by high-resolution x-ray diffraction and high-resolution transmission electron microscopy. In addition, the magnetic hysteresis curves show that the Mn delta-doped GaN nanorods are ferromagnetic above room temperature. The magnetization with magnetic field perpendicular to GaN c-axis saturates easier than the one with field parallel to GaN c-axis.

  8. Perpendicular exchange bias effect in sputter-deposited CoFe/IrMn bilayers

    SciTech Connect (OSTI)

    Chen, J. Y., E-mail: chenjy02@gmail.com; Thiyagarajah, Naganivetha; Xu, H. J.; Coey, J. M. D. [School of Physics and CRANN, Trinity College, Dublin 2 (Ireland)

    2014-04-14T23:59:59.000Z

    CoFe/IrMn bilayers with perpendicular magnetization for various IrMn layer thicknesses exhibit unusual two-step hysteresis loops with both positive and negative loop shifts. Observed at room temperature in the as-grown state, they provide direct evidence of large antiferromagnetic domain formation at the IrMn interface. The exchange bias field reaches 100?mT with an IrMn layer thickness of 4?nm after field annealing at 200?°C–300?°C in 800?mT, which is at least three times as large as the coercivity, and may be useful for reference layers of spin-valves or magnetic tunnel junctions with perpendicular magnetic anisotropy.

  9. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C. [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Samnakay, R. [Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Rumyantsev, S. L. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Ioffe Physical-Technical Institute, St. Petersburg 194021 (Russian Federation); Goli, P.; Balandin, A. A., E-mail: balandin@ee.ucr.edu [Nano-Device Laboratory, Department of Electrical Engineering, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Materials Science and Engineering Program, Bourns College of Engineering, University of California – Riverside, Riverside, California 92521 (United States); Shur, M. S. [Department of Electrical, Computer, and Systems Engineering, Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)

    2014-04-14T23:59:59.000Z

    We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2?×?10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5?×?10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

  10. Neutron Resonance Parameters of 55Mn from Reich-Moore Analysis of Recent Experimental Neutron Transmission and Capture Cross Sections

    SciTech Connect (OSTI)

    Derrien, Herve [ORNL] [ORNL; Leal, Luiz C [ORNL] [ORNL; Larson, Nancy M [ORNL] [ORNL; Guber, Klaus H [ORNL] [ORNL; Wiarda, Dorothea [ORNL] [ORNL; Arbanas, Goran [ORNL] [ORNL

    2008-01-01T23:59:59.000Z

    High-resolution neutron capture cross section measurements of 55Mn were recently performed at GELINA by Schillebeeckx et al. (2005) and at ORELA by Guber et al. (2007). The analysis of the experimental data was performed with the computer code SAMMY using the Bayesian approach in the resonance parameters representation of the cross sections. The neutron transmission data taken in 1988 by Harvey et al. (2007) and not analyzed before were added to the SAMMY experimental data base. More than 95% of the s-wave resonances and more than 85% of the p-wave resonances were identified in the energy range up to 125 keV, leading to the neutron strength functions S0 = (3.90 0.78) x 10-4 and S1 = (0.45 0.08) x 10-4. About 25% of the d-wave resonances were identified with a possible strength function of S2 = 1.0 x 10-4. The capture cross section calculated at 0.0253 eV is 13.27 b, and the capture resonance integral is 13.52 0.30 b. In the energy range 15 to 120 keV, the average capture cross section is 12% lower than Lerigoleur value and 25% smaller than Macklin value. GELINA and ORELA experimental capture cross sections show a background cross section not described by the Reich-Moore resonance parameters. Part of this background could be due to a direct capture component and/or to the missing d-wave resonances. The uncertainty of 10% on the average capture cross section above 20 keV is mainly due to the inaccuracy in the calculation of the background components.

  11. Reactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    , the reactivity of lead (Pb(II)) on naturally occurring Mn(III,IV) (oxyhydr)oxide minerals was evaluated using to suggest oxidation as an operative sorption mechanism. Lead appeared to coordinate to vacancy sitesReactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface C H R I S T O P H E R J . M

  12. Effect of MnAs/GaAs(001) film accommodations on the phase-transition temperature

    SciTech Connect (OSTI)

    Iikawa, F.; Brasil, M.J.S.P.; Couto, O.D.D.; Adriano, C.; Giles, C.; Daeweritz, L. [Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970 (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, Campinas-SP, C.P. 6165, 13083-970, Brazil and Laboratorio Nacional de Luz Sincrotron, CP-6192, 13084-971 Campinas-SP (Brazil); Paul-Drude-Institut fuer Festkoerperelektronik, Hausvogteiplatz 5-7, 10117 Berlin (Germany)

    2004-09-20T23:59:59.000Z

    The phase-transition temperature of MnAs epitaxial films grown by molecular-beam epitaxy on GaAs(001) with different crystalline accommodations was studied by specular and grazing incidence x-ray diffraction. The transition temperature of MnAs films with tilted hexagonal c-axis orientations with respect to the GaAs substrate is higher than the most investigated nontilted films and reaches a value above room temperature, which is more suitable for device applications.

  13. (In,Mn)As quantum dots: Molecular-beam epitaxy and optical properties

    SciTech Connect (OSTI)

    Bouravleuv, A. D., E-mail: bour@mail.ioffe.ru; Nevedomskii, V. N. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Ubyivovk, E. V. [St. Petersburg State University (Russian Federation)] [St. Petersburg State University (Russian Federation); Sapega, V. F. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Khrebtov, A. I. [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation)] [St. Petersburg Academic University, Nanotechnology Research and Education Centre (Russian Federation); Samsonenko, Yu. B.; Cirlin, G. E.; Ustinov, V. M. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

    2013-08-15T23:59:59.000Z

    Self-assembled (In,Mn)As quantum dots are synthesized by molecular-beam epitaxy on GaAs (001) substrates. The experimental results obtained by transmission electron microscopy show that doping of the central part of the quantum dots with Mn does not bring about the formation of structural defects. The optical properties of the samples, including those in external magnetic fields, are studied.

  14. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect (OSTI)

    Pei, L.Z., E-mail: lzpei@ahut.edu.cn; Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  15. Magneto acoustical emission in nanocrystalline Mn–Zn ferrites

    SciTech Connect (OSTI)

    Praveena, K., E-mail: praveenaou@gmail.com [Materials Research Centre, Indian Institute of Science, Bangalore 560012 (India); Department of Physics, Osmania University, Hyderabad 500007 (India); Murthty, S.R. [Department of Physics, Osmania University, Hyderabad 500007 (India)

    2013-11-15T23:59:59.000Z

    Graphical abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE. - Highlights: • The AE been measured along the hysteresis loops from 80 K to Curie temperature. • The MAE activity along hysteresis loop is proportional to P{sub h} during the same loop. • It is found that the domain wall creation/or annihilation processes are the origin of the MAE. - Abstract: Mn{sub 0.4}Zn{sub 0.6}Fe{sub 2}O{sub 4} powders were prepared by microwave hydrothermal method. The powders were characterized by X-ray diffraction, transmission electron microscope. The powders were sintered at different temperatures 400, 500, 600, 700, 800 and 900 °C/30 min using microwave sintering method. The grain size was estimated by scanning electron microscope. The room temperature dielectric and magnetic properties were studied in the frequency range (100 kHz–1.8 GHz). The magnetization properties were measured upto 1.5 T. The acoustic emission has been measured along the hysteresis loops from 80 K to Curie temperature. It is found that the magneto-acoustic emission (MAE) activity along hysteresis loop is proportional to the hysteresis losses during the same loop. This law has been verified on series of polycrystalline ferrites and found that the law is valid whatever the composition, the grain size and temperature. It is also found that the domain wall creation/or annihilation processes are the origin of the MAE.

  16. Magnetic Order and Ferroelectricity in RMnO3 Multiferroic Manganites: Coupline Between R- and Mn-spins

    SciTech Connect (OSTI)

    Aliouane, N.; Prokhnenko, O; Feyerherm, R; Mostovoy, M; Strempfer, J; Habicht, K; Rule, K; Dudzik, E; Wolter, A; et. al.

    2008-01-01T23:59:59.000Z

    Combining polarized and unpolarized neutron scattering techniques with x-ray resonant magnetic scattering we have studied the coupling between the Mn- and R-spin-ordering in the multiferroic RMnO3, R = Tb and Dy. Polarized neutron diffraction reveals the moment orientation associated with the various modes describing the complex magnetic ordering observed in TbMnO3, while neutron diffraction in high magnetic fields allows the identification of the origin (Mn versus Tb) of the various modes. In this way we identify significant Cx and Fz contributions from Tb arising from the coupling of Tb moments to the Mn cycloidal ordering. The x-ray studies give further insight into this coupling. In the ferroelectric phase, both TbMnO3 and DyMnO3 show an induced ordering of the R-ion with a propagation vector clamped to the Mn ordering. While in TbMnO3 this clamping leads to a ground state in which the two propagation vectors tTb and tMn obey the relation 3tTb-tMn = 1, in DyMnO3 the ferroelectric polarization is effectively enhanced. The theoretical analysis of these effects not only explains the observed behavior for R = Tb and Dy but can also be applied to understand the Mn-R interaction in the related compounds with R = Gd and Ho. Finally we show both experimentally and theoretically how the Mn-R coupling can enhance the ferroelectric polarization in this manganite's multiferroics.

  17. Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites

    SciTech Connect (OSTI)

    Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

    2013-12-16T23:59:59.000Z

    This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

  18. Synthesis and characterization of nanoparticulate MnS within the pores of mesoporous silica

    SciTech Connect (OSTI)

    Barry, Louse; Copley, Mark [Department of Chemistry, University College Cork, Cork (Ireland); Holmes, Justin D. [Department of Chemistry, University College Cork, Cork (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland); Otway, David J. [Department of Chemistry, University College Cork, Cork (Ireland); Kazakova, Olga [National Physical Laboratory, Teddington (United Kingdom); Morris, Michael A. [Department of Chemistry, University College Cork, Cork (Ireland); Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland)], E-mail: m.morris@ucc.ie

    2007-12-15T23:59:59.000Z

    Mesoporous silica was loaded with nanoparticulate MnS via a simple post-synthesis treatment. The mesoporous material that still contained surfactant was passivated to prevent MnS formation at the surface. The surfactant was extracted and a novel manganese ethylxanthate was used to impregnate the pore network. This precursor thermally decomposes to yield MnS particles that are smaller or equal to the pore size. The particles exhibit all three common polymorphs. The passivation treatment is most effective at lower loadings because at the highest loadings (SiO{sub 2}:MnS molar ratio of 6:1) large particles (>50 nm) form at the exterior of the mesoporous particles. The integrity of the mesoporous network is maintained through the preparation and high order is maintained. The MnS particles exhibit unexpected ferromagnetism at low temperatures. Strong luminescence of these samples is observed and this suggests that they may have a range of important application areas. - Graphical abstract: A novel manganese ethylxanthate precursor was used to impregnate the pore network of mesoporous silica and was decomposed to yield MnS particles smaller or equal to the pore size. The particles exhibit all three common polymorphs, demonstrate unexpected ferromagnetism at low temperatures and display a strong luminescence.

  19. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  20. Inverse magnetocaloric effect in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys

    SciTech Connect (OSTI)

    Singh, Sanjay, E-mail: sanju8419@gmail.com; Barman, S. R. [UGC-DAE Consortium for Scientific Research, Khandwa Road, Indore 452001 (India); Esakki Muthu, S.; Arumugam, S. [Centre for High Pressure Research, School of Physics, Bharathidasan University, Tiruchirappalli 620024 (India); Senyshyn, A. [Forschungsneutronenquelle Heinz Maier-Leibnitz FRM-II, Technische Universität München, Lichtenbergstrasse 1, 85747 Garching b. München (Germany); Rajput, P. [European Synchrotron Radiation Facility, 6 rue Jules Horowitz, F-38000 Grenoble (France); Suard, E. [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)

    2014-02-03T23:59:59.000Z

    Inverse magnetocaloric effect is demonstrated in Mn{sub 2}NiGa and Mn{sub 1.75}Ni{sub 1.25}Ga magnetic shape memory alloys. The entropy change at the martensite transition is larger in Mn{sub 1.75}Ni{sub 1.25}Ga, and it increases linearly with magnetic field in both the specimens. Existence of inverse magnetocaloric effect is consistent with the observation that magnetization in the martensite phase is smaller than the austenite phase. Although the Mn content is smaller in Mn{sub 1.75}Ni{sub 1.25}Ga, from neutron diffraction, we show that the origin of inverse magnetocaloric effect is the antiferromagnetic interaction between the Mn atoms occupying inequivalent sites.

  1. Beta-decay of Mn-65 to Fe-65

    E-Print Network [OSTI]

    Olaizola, B; Mach, H; Aprahamian, A; Briz, J A; Cal-Gonzalez, J; Ghita, D; Koster, U; Kurcewicz, W; Lesher, S R; Pauwels, D; Picado, E; Poves, A; Radulov, D; Simpson, G S; Udias, J M

    2013-01-01T23:59:59.000Z

    The low energy structure of Fe-65 has been studied by means of gamma- and fast-timing spectroscopy. A level scheme of Fe-65 populated following the beta-decay of Mn-65 was established for the first time. It includes 41 levels and 85 transitions. The excitation energy of the beta-decaying isomer in Fe-65 has been precisely determined at 393.7(2) keV. The beta delayed neutron emission branch was measured as Pn = 7.9(12)%, which cannot be reconciled with the previously reported value of 21.0(5)%. Four gamma-rays and four excited states in Fe-64 were identified as being populated following the beta-n decay. Four lifetimes and five lifetime limits in the subnanosecond range have been measured using the Advanced Time-Delayed Method. The level scheme is compared with shell-model calculations. Tentative spin and parity assignments are proposed based on the observed transition rates, the calculations and the systematics of the region.

  2. Course Syllabus: Chemistry 3AL Course Information

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Course Syllabus: Chemistry 3AL Course Information Course Name Chemistry 3AL Course Instructor are online. Chemistry 3AL Syllabus https://elearning.berkeley.edu/AngelUploads/Content/2013SUC... 1 of 5 5

  3. Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions

    SciTech Connect (OSTI)

    Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

    2009-03-15T23:59:59.000Z

    Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

  4. Effects of Potassium Doping on CO Hydrogenation Over MoS2 Catalysts: A First-Principles Investigation

    SciTech Connect (OSTI)

    Andersen, Amity; Kathmann, Shawn M.; Lilga, Michael A.; Albrecht, Karl O.; Hallen, Richard T.; Mei, Donghai

    2014-07-01T23:59:59.000Z

    Periodic density functional theory calculations were performed to explore the effects of doping potassium (K) on the reactivity of CO hydrogenation to mixed higher alcohols over MoS2 catalysts. We found that the doped K species over the model MoS2(100) catalyst surface acts as a unique site for CO adsorption where either the K-C or the K-O bonding is allowed. The charge transfer from the K 4s electron to the conduction band of the MoS2(100) surface slightly enhances CO adsorption at the edge Mo sites. Due to the large electropositive nature, the presence of the surface K species, however, will hinder the dissociative adsorption of hydrogen. As a result, the doping K species drive CO hydrogenation selectivity toward the C2+ alcohols instead of hydrocarbons by increasing CO and decreasing hydrogen coverages on the MoS2 catalysts. To further elucidate the effect of doping K on the shifting of the selectivity toward CO hydrogenation, we calculated several key reaction steps leading to the H2CCO precursor formation, i.e., CO hydrogenation, the C-O bond scission and the C-C coupling (CH2+CO). The C-C coupling step is favorable for both the Mo and S edges. However, the undoped S edge has an overall more thermodynamically favorable reaction profile up to C-O scission compared with the Mo edge. This work was funded by a CRADA project (No. PNNL/297) with Range Fuels. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. The work involving the results analysis and mansucript writing was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences.

  5. Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5

    E-Print Network [OSTI]

    Li, Jing

    Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5 Tan Yuena and C Jersey 08854 Presented on 2 November 2005; published online 18 April 2006 Mn hfipbb py H2O 0.5 H2hfipbb=4 as on powder samples of Mn hfipbb py H2O 0.5. Antiferromagnetic ordering was observed below a transition

  6. ALS Ceramics Materials Research Advances Engine Performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Ceramics Materials Research Advances Engine Performance ALS Ceramics Materials Research Advances Engine Performance Print Thursday, 27 September 2012 00:00 ritchie ceramics...

  7. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral Fellowship in ResidenceALS EvidenceALS

  8. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALS Communications GroupALS

  9. Synthesis of spherical LiMnPO{sub 4}/C composite microparticles

    SciTech Connect (OSTI)

    Bakenov, Zhumabay [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)] [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan); Taniguchi, Izumi, E-mail: taniguchi.i.aa@m.titech.ac.jp [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)] [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2011-08-15T23:59:59.000Z

    Highlights: {yields} We could prepare LiMnPO{sub 4}/C composites by a novel preparation method. {yields} The LiMnPO{sub 4}/C composites were spherical particles with a mean diameter of 3.65 {mu}m. {yields} The LiMnPO{sub 4}/C composite cathode exhibited 112 mAh g{sup -1} at 0.05 C. {yields} It also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C. -- Abstract: Spherical LiMnPO{sub 4}/C composite microparticles were prepared by a combination of spray pyrolysis and spray drying followed by heat treatment and examined as a cathode material for lithium batteries. The structure, morphology and electrochemical performance of the resulting spherical LiMnPO{sub 4}/C microparticles were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electronic microscopy and standard electrochemical techniques. The final sample was identified as a single phase orthorhombic structure of LiMnPO{sub 4} and spherical powders with a geometric mean diameter of 3.65 {mu}m and a geometric standard deviation of 1.34. The electrochemical cells contained the spherical LiMnPO{sub 4}/C microparticles exhibited first discharge capacities of 112 and 130 mAh g{sup -1} at 0.05 C at room temperature and 55 {sup o}C, respectively. These also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C.

  10. Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.550 DATABASE 1-600 MB/MO

    E-Print Network [OSTI]

    Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.550 DATABASE 1-600 MB/MO Database Administration (601 to 950 MB) MB/Month 0.290 DATABASE 601-950 MB/MO Database Administration (951 to 3,000 MB) MB/Month 0.200 DATABASE 951-3,000 MB/MO Database

  11. Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.500 DATABASE 1-600 MB/MO

    E-Print Network [OSTI]

    Service Description Unit Rate in $ Invoice Description Database Administration (1 to 600 MB) MB/Month 0.500 DATABASE 1-600 MB/MO Database Administration (601 to 950 MB) MB/Month 0.265 DATABASE 601-950 MB/MO Database Administration (951 to 3,000 MB) MB/Month 0.175 DATABASE 951-3,000 MB/MO Database

  12. A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics

    E-Print Network [OSTI]

    Chi, Ji

    2009-05-15T23:59:59.000Z

    Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

  13. Dopant-Free GaN/AlN/AlGaN Radial Nanowire Heterostructures as High

    E-Print Network [OSTI]

    Li, Yat

    Dopant-Free GaN/AlN/AlGaN Radial Nanowire Heterostructures as High Electron Mobility Transistors, 2006 ABSTRACT We report the rational synthesis of dopant-free GaN/AlN/AlGaN radial nanowire-organic chemical vapor deposition (MOCVD). Transmission electron microscopy (TEM) studies reveal that the GaN/ AlN/AlGaN

  14. Martensitic transformation behaviors of rapidly solidified Ti–Ni–Mo powders

    SciTech Connect (OSTI)

    Kim, Yeon-wook, E-mail: ywk@kmu.ac.kr [Department of Advanced Materials, Keimyung University, 1000 Shindang-dong, Dalseo-gu, Daegu 704-701 (Korea, Republic of)] [Department of Advanced Materials, Keimyung University, 1000 Shindang-dong, Dalseo-gu, Daegu 704-701 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    For the fabrication of bulk near-net-shape shape memory alloys and porous metallic biomaterials, consolidation of Ti–Ni–Mo alloy powders is more useful than that of elemental powders of Ti, Ni and Mo. Ti{sub 50}Ni{sub 49.9}Mo{sub 0.1} shape memory alloy powders were prepared by gas atomization, and transformation temperatures and microstructures of those powders were investigated as a function of powder size. XRD analysis showed that the B2–R–B19 martensitic transformation occurred in powders smaller than 150 ?m. According to DSC analysis of the as-atomized powders, the B2–R transformation temperature (T{sub R}) of the 25–50 ?m powders was 18.4 °C. The T{sub R} decreased with increasing powder size, however, the difference in T{sub R} between 25–50 ?m powders and 100–150 ?m powders is only 1 °C. Evaluation of powder microstructures was based on SEM examination of the surface and the polished and etched powder cross sections and the typical images of the rapidly solidified powders showed cellular morphology. Porous cylindrical foams of 10 mm diameter and 1.5 mm length were fabricated by spark plasma sintering (SPS) at 800 °C and 5 MPa. Finally these porous TiNi alloy samples are heat-treated for 1 h at 850 °C, and then quenched in ice water. The bulk samples have 23% porosity and 4.6 g/cm{sup 3} density and their T{sub R} is 17.8 °C.

  15. Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO

    E-Print Network [OSTI]

    Zimring, Mark

    2012-01-01T23:59:59.000Z

    2011 Using Qualified Energy Conservation Bonds (QECBs) toCounty, MO Qualified Energy Conservation Bonds (QECBs) arerange of qualified energy conservation projects. QECBs offer

  16. COMBATING THE PURPLE BOTANICAL PLAGUE: EVALUATION OF COLLETOTRICHUM GLOEOSPORIOIDES F. SP. MICONIAE FOR BIOLOGICAL CONTROL OF MICONIA CALVESCENS IN MO’OREA, FRENCH POLYNESIA

    E-Print Network [OSTI]

    Chen, Irene Y

    2009-01-01T23:59:59.000Z

    gloeosporioides, elevation, endophyte community, Mo’orea,occur upon contact: the endophyte fungus outcompeted theelevation gradient having 25 endophyte competition plates.

  17. Exchange bias induced by the fully strained La{sub 2/3}Ca{sub 1/3}MnO{sub 3} dead layers

    SciTech Connect (OSTI)

    Xie, Q. Y. [National Lab of Solid State Microstructures, Department of Physics, Nanjing University, Nanijng 210093 (China); College of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210046 (China); Wu, X. S., E-mail: xswu@nju.edu.cn [National Lab of Solid State Microstructures, Department of Physics, Nanjing University, Nanijng 210093 (China); Gao, J. [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); Jia, Q. J. [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China)

    2014-05-07T23:59:59.000Z

    A pure compressively strained La{sub 2/3}Ca{sub 1/3}MnO{sub 3} (LCMO) dead layer grown on (001)-oriented LaAlO{sub 3} substrate can show all the rich phenomenon of large bias field shift, coercive field enhancement, and high blocking temperature. The obtained exchange bias field (?350?Oe) and the enhanced coercivity of about 1160?Oe at 5?K under 500?Oe cooling field are superior to that have been reported in LCMO-based ferromagnetic/antiferromagnetic superlattices or nanoscale systems. Our results clearly demonstrate that the inhomogeneous magnetic dead layer of LCMO can induce a strong exchange bias effect, which may be exploited as a very simple structure for spin-valve device application.

  18. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect (OSTI)

    West, J. Palmer; Sulejmanovic, Dino [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States); Becht, Gregory [E. I. du Pont, Wilmington, DE 19880-0500 (United States); He, Jian; Hitchcock, Dale [Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Yan, Yonggao [Wuhan University of Technology, Wuhan 430070 (China); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634 (United States)

    2013-10-15T23:59:59.000Z

    Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

  19. Beta-decay properties of Zr and Mo neutron-rich isotopes

    E-Print Network [OSTI]

    P. Sarriguren; J. Pereira

    2010-06-08T23:59:59.000Z

    Gamow-Teller strength distributions, beta-decay half-lives, and beta-delayed neutron emission are investigated in neutron-rich Zr and Mo isotopes within a deformed quasiparticle random-phase approximation. The approach is based on a self-consistent Skyrme Hartree-Fock mean field with pairing correlations and residual separable particle-hole and particle-particle forces. Comparison with recent measurements of half-lives stresses the important role that nuclear deformation plays in the description of beta-decay properties in this mass region.

  20. Electronic structure of CdMoO{sub 4} using Compton scattering technique

    SciTech Connect (OSTI)

    Sharma, Khushboo, E-mail: khushboo.phy@gmail.com; Ahuja, B. L. [Department of Physics, University College of Science, M.L. Sukhadia University, Udaipur-313001 (India); Sahariya, Jagrati [Department of Physics, Manipal University, Jaipur-303007 (India)

    2014-04-24T23:59:59.000Z

    The first ever Compton profile of polycrystalline CdMoO{sub 4} has been measured using {sup 137}Cs spectrometer. The results are compared with theoretical Compton profiles deduced from free atom and linear combination of atomic orbitals (LCAO) methods. We have also computed the energy bands using density functional theory (DFT) within LCAO. The computed bands confirm the semiconducting behaviour of this compound. It is seen that the DFT theoretical profile (with local density approximation) gives a better agreement with the experimental Compton data than free atom Compton profile.

  1. FULL SIZE U-10MO MONOLITHIC FUEL FOIL AND FUEL PLATE FABRICATION-TECHNOLOGY DEVELOPMENT

    SciTech Connect (OSTI)

    G. A. Moore; J-F Jue; B. H. Rabin; M. J. Nilles

    2010-03-01T23:59:59.000Z

    Full-size U10Mo foils are being developed for use in high density LEU monolithic fuel plates. The application of a zirconium barrier layer too the foil is applied using a hot co-rolling process. Aluminum clad fuel plates are fabricated using Hot Isostatic Pressing (HIP) or a Friction Bonding (FB) process. An overview is provided of ongoing technology development activities, including: the co-rolling process, foil shearing/slitting and polishing, cladding bonding processes, plate forming, plate-assembly swaging, and fuel plate characterization. Characterization techniques being employed include, Ultrasonic Testing (UT), radiography, and microscopy.

  2. DOE - Office of Legacy Management -- St Louis Downtown Site - MO 02

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntown Site - MO 02 FUSRAP

  3. DOE - Office of Legacy Management -- St Louis University - MO 0-02

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntown Site - MO 02 FUSRAPSt Louis

  4. DOE - Office of Legacy Management -- United Nuclear Corp - MO 0-03

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -K LeDowntownUnited Nuclear Corp - MO 0-03

  5. File:USDA-CE-Production-GIFmaps-MO.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdf Jump to:Originalfaq.pdfFinal.pdf JumpIN.pdfMO.pdf Jump to:

  6. Single-crystal structure of vanadium-doped La{sub 2}Mo{sub 2}O{sub 9}

    SciTech Connect (OSTI)

    Alekseeva, O. A., E-mail: olalex@ns.crys.ras.ru; Antipin, A. M. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Gagor, A.; Pietraszko, A. [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland)] [Polish Academy of Sciences, Trzebiatowski Institute of Low Temperature and Structure Research (Poland); Novikova, N. E.; Sorokina, N. I. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Kharitonova, E. P.; Voronkova, V. I. [Moscow State University (Russian Federation)] [Moscow State University (Russian Federation)

    2013-11-15T23:59:59.000Z

    A high-precision X-ray diffraction study of single crystals of two compositions-La{sub 2}Mo{sub 1.78}V{sub 0.22}O{sub 8.89} and La{sub 2}Mo{sub 1.64}V{sub 0.36}O{sub 8.82}-was performed. In the vanadium-doped compounds, as in the structure of the metastable {beta}{sub ms} phase of pure La{sub 2}Mo{sub 2}O{sub 9}, the La and Mo atoms and one of the three oxygen atoms are displaced from the threefold axis, on which they are located in the high-temperature {beta} phase. The structure contains two partially occupied oxygen sites. It was shown that molybdenum atoms are partially replaced by vanadium atoms, which are not involved in the disordering, are located on the threefold axis, and are shifted toward one of the oxygen atoms. This is consistent with the temperature-induced changes in the structure of La{sub 2}Mo{sub 2}O{sub 9} and the changes in the properties of these crystals caused by the introduction of vanadium atoms into the structure.

  7. MO: ZL

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ,"^ I ThisS11220Grand

  8. Carbon/lambda-MnO{sub 2} composites for supercapacitor electrodes

    SciTech Connect (OSTI)

    Malak-Polaczyk, A., E-mail: agnieszka-malak@wp.p [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland); Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Matei-Ghimbeu, C.; Vix-Guterl, C. [Institut de Sciences des Materiaux de Mulhouse, CNRS LRC 7228, 15 Rue Starcky, 68057 Mulhouse (France); Frackowiak, E. [Institute of Chemistry and Technical Electrochemistry, Poznan University of Technology, Piotrowo 3, 60-695 Poznan (Poland)

    2010-04-15T23:59:59.000Z

    In the present work a composite of carbon with lambda-MnO{sub 2} have been synthesized by a simple two-step route. In the first step, to obtain LiMn{sub 2}O{sub 4}/carbon material, mesoporous activated carbon was impregnated with the solution of precursor metal salts and heated subsequently. As-prepared materials were acid treated which resulted in the formation of lambda-MnO{sub 2}/carbon. Physical properties, structure and specific surface area of electrode materials were studied by TEM, X-ray diffraction and nitrogen sorption measurements. Voltammetry cycling, galvanostatic charge/discharge and impedance spectroscopy measurements performed in two- and three-electrode cells have been applied in order to measure electrochemical parameters. TEM images confirmed well dispersed lambda-MnO{sub 2} particles on the surface of carbon material. The carbon in the composite plays an important role as the surface area enhancing component and a support of pseudocapacitive material. Furthermore, the through-connected porosity serves as a continuous pathway for electrolyte transport. A synergetic effect of the porous carbon framework and of the redox properties of the lambda-MnO{sub 2} is at the origin of improvement of specific capacitance values which has been observed for composites after delithiation. - Comparison of capacitance characteristics for initial carbon and synthesised composites for CB in 1 mol L{sup -1} Na{sub 2}SO{sub 4} solution.

  9. Thickness Effect of Al-Doped ZnO Window Layer on Damp Heat Stability of CuInGaSe2 Solar Cells: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Mansfield, L.; DeHart, C.; Glick, S. H.; Yan, F.; Noufi, R.

    2011-07-01T23:59:59.000Z

    We investigated the damp heat (DH) stability of CuInGaSe2 (CIGS) solar cells as a function of thickness of the Al-doped ZnO (AZO) window layer from the 'standard' 0.12 ?m to a modest 0.50 ?m over an underlying 0.10-?m intrinsic ZnO buffer layer. The CIGS cells were prepared with external electrical contact using fine Au wire to the tiny 'standard' Ni/Al (0.05 ?m/3 ?m) metal grid contact pads. Bare cell coupons and sample sets encapsulated in a specially designed, Al-frame test structure with an opening for moisture ingress control using a TPT backsheet were exposed to DH at 85oC and 85% relative humidity, and characterized by current-voltage (I-V), quantum efficiency (QE), and (electrochemical) impedance spectroscopy (ECIS). The results show that bare cells exhibited rapid degradation within 50-100 h, accompanied by film wrinkling and delamination and corrosion of Mo and AlNi grid, regardless of AZO thickness. In contrast, the encapsulated cells did not show film wrinkling, delamination, and Mo corrosion after 168 h DH exposure; but the trend of efficiency degradation rate showed a weak correlation to the AZO thickness.

  10. Manganese containing layer for magnetic recording media

    DOE Patents [OSTI]

    Lambeth, David N. (Pittsburgh, PA); Lee, Li-Lien (Santa Clara, CA); Laughlin, David E. (Pittsburgh, PA)

    1999-01-01T23:59:59.000Z

    The present invention provides for a magnetic recording media incorporating Mn-containing layers between a substrate and a magnetic layer to provide media having increased coercivity and lower noise. The Mn-containing layer can be incorporated in a rotating, translating or stationary recording media to operate in conjunction with magnetic transducing heads for recording and reading of magnetic data, as well as other applications. The magnetic recording medium of the invention preferably includes a Co or Co alloy film magnetic layer, and Mn-containing layer, preferably comprised of VMn, TiMn, MnZn, CrMnMo, CrMnW, CrMnV, and CrMnTi, and most preferably a CrMn alloy, disposed between the substrate and the magnetic layer to promote an epitaxial crystalline structure in the magnetic layer. The medium can further include seed layers, preferably polycrystalline MgO for longitudinal media, underlayers, and intermediate layers. Underlayers and intermediate layers are comprised of materials having either an A2 structure or a B2-ordered crystalline structure disposed between the seed layer and the magnetic layer. Materials having an A2 structure are preferably Cr or Cr alloys, such as CrV, CrMo, CrW and CrTi. Materials having a B2-ordered structure having a lattice constant that is substantially comparable to that of Cr, such as those preferably selected from the group consisting of NiAl, AILCo, FeAl, FeTi, CoFe, CoTi, CoHf, CoZr, NiTi, CuBe, CuZn, A-LMn, AlRe, AgMg, and Al.sub.2 FeMn.sub.2, and is most preferably FeAl or NiAl.

  11. /sup 238/PuO/sub 2//Mo-50 wt% Re compatibility at 800 and 1000/sup 0/C

    SciTech Connect (OSTI)

    Schaeffer, D.R.; Teaney, P.E.

    1980-07-18T23:59:59.000Z

    The compatibility of Mo-50 wt % Re with /sup 238/PuO/sub 2/ was investigated after heat treatments of up to 720 days at 800/sup 0/C and 180 days at 1000/sup 0/C. At 800/sup 0/C, a 1-..mu..m thick, continuous layer of molybdenum oxide resulted. At 1000/sup 0/C, the oxide reaction product contained some plutonium and did not appear continuous. At 1000/sup 0/C, a layer of intermetallic formed at the Mo-Re edge, beneath the oxide layer, creating a barrier between the Mo-50 wt % Re and the /sup 238/PuO/sub 2/. The intermetallic layer was promoted by the iron impurity in the /sup 238/PuO/sub 2/.

  12. 4 al 6 de septiembre COMPUTACIN

    E-Print Network [OSTI]

    Figueira, Santiago

    . Esteban Lanzarotti ¿cóMO se hace un rObOt? Lic. Sol Pedre 13.30 aplicaciOnes Móviles: ¿el futurO viene enO Dr. Diego Fernández Slezak MOdelOs y cOMputadOras (nada que ver cOn las fOtOs de paMpita) Dr. Ing

  13. LASER TRIGGERED GAS SWITCHES UTILIZING BEAM TRANSPORT THROUGH 1 MO-cm DEIONIZED WATER.

    SciTech Connect (OSTI)

    Woodworth, Joseph Ray; Lehr, Jane [Sandia National Laboratories, Albuquerque, NM; Blickem, James R.; Wallace, Zachariah R.; Anaya, Victor Jr; Corley, John P; Lott, John; Hodge, Keith; Zameroski, Nathan D. [Sandia National Laboratories, Albuquerque, NM

    2005-11-01T23:59:59.000Z

    We report on the successful attempts to trigger high voltage pressurized gas switches by utilizing beam transport through 1 MO-cm deionized water. The wavelength of the laser radiation was 532 nm. We have investigated Nd: YAG laser triggering of a 6 MV, SF6 insulated gas switch for a range of laser and switch parameters. Laser wavelength of 532 nm with nominal pulse lengths of 10 ns full width half maximum (FWHM) were used to trigger the switch. The laser beam was transported through 67 cm-long cell of 1 MO-cm deionized water constructed with anti reflection UV grade fused silica windows. The laser beam was then focused to form a breakdown arc in the gas between switch electrodes. Less than 10 ns jitter in the operation of the switch was obtained for laser pulse energies of between 80-110 mJ. Breakdown arcs more than 35 mm-long were produced by using a 70 cm focusing optic.

  14. Shape controlled synthesis of CaMoO{sub 4} thin films and their photoluminescence property

    SciTech Connect (OSTI)

    Marques, Ana Paula de Azevedo [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil)], E-mail: apamarques@liec.ufscar.br; Longo, Valeria M. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Melo, Dulce M.A. de [Laboratorio de Analise Termica e Materiais, Departamento de Quimica, Universidade Federal do Rio Grande do Norte, 59072-970 Natal, RN (Brazil); Pizani, Paulo S. [Laboratorio de Semicondutores, Departamento de Fisica, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Leite, Edson R. [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); Varela, Jose Arana [CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil); Longo, Elson [Laboratorio Interdisciplinar de Eletroquimica e Ceramica, Departamento de Quimica, Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos, Universidade Federal de Sao Carlos, C. Postal 676, 13565-905 Sao Carlos, SP (Brazil); CMDMC, LIEC, Instituto de Quimica, Universidade Estadual Paulista, 14801-907 Araraquara, SP (Brazil)

    2008-05-15T23:59:59.000Z

    CaMoO{sub 4} (CMO) disordered and ordered thin films were prepared by the complex polymerization method (CPM). The films were annealed at different temperatures and time in a conventional resistive furnace (RF) and in a microwave (MW) oven. The microstructure and surface morphology of the structure were monitored by atomic force microscopy (AFM) and high-resolution scanning electron microscopy (HRSEM). Order and disorder were characterized by X-ray diffraction (XRD) and optical reflectance. A strong photoluminescence (PL) emission was observed in the disordered thin films and was attributed to complex cluster vacancies. The experimental results were compared with density functional and Hartree-Fock calculations. - Graphical abstract: CaMoO{sub 4} thin films were prepared by the complex polymerization method (CPM). The films were annealed at different temperatures and time in a conventional resistive furnace and in a microwave oven. A strong photoluminescence emission was observed in the disordered thin films and was attributed to complex cluster vacancies. The experimental results were confirmed by high level first principle calculations.

  15. On the bonding nature of electron states for the Fe-Mo double perovskite

    SciTech Connect (OSTI)

    Carvajal, E.; Cruz-Irisson, M. [ESIME-Culhuacán, Instituto Politécnico Nacional, Av. Santa Ana 1000, C.P. 04430, México, D.F. (Mexico); Oviedo-Roa, R. [Programa de Investigación en Ingeniería Molecular, Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, C.P. 07730, México, D.F. (Mexico); Navarro, O. [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, A.P. 70-360, 04510, México, D.F. (Mexico)

    2014-05-15T23:59:59.000Z

    The electronic transport as well as the effect of an external magnetic field has been investigated on manganese-based materials, spinels and perovskites. Potential applications of double perovskites go from magnetic sensors to electrodes in solid-oxide fuel cells; besides the practical interests, it is known that small changes in composition modify radically the physical properties of double perovskites. We have studied the Sr{sub 2}FeMoO{sub 6} double perovskite compound (SFMO) using first-principles density functional theory. The calculations were done within the generalized gradient approximation (GGA) scheme with the Perdew-Burke-Ernzerhof (PBE) functional. We have made a detailed analysis of each electronic state and the charge density maps around the Fermi level. For the electronic properties of SFMO it was used a primitive cell, for which we found the characteristic half-metallic behavior density of states composed by e{sub g} and t{sub 2g} electrons from Fe and Mo atoms. Those peaks were tagged as bonding or antibonding around the Fermi level at both, valence and conduction bands.

  16. Determination of the direct double- ? -decay Q value of Zr 96 and atomic masses of Zr 90 - 92 , 94 , 96 and Mo 92 , 94 - 98 , 100

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Valverde, A. A.

    2015-05-01T23:59:59.000Z

    Experimental searches for neutrinoless double-? decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-? decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ??Zr double-? decay Q value: Q??=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M. Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-? shift is primarily due to a more accurate measurement of the ??Zr atomic mass: m(??Zr)=95.90827735(17) u. Using the new Q value, the 2???-decay matrix element, |M2?|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C? and ??Rb as references are also reported.

  17. Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers

    SciTech Connect (OSTI)

    Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

    2014-08-18T23:59:59.000Z

    Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

  18. al tratamiento local: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and MEG data (Vigario et al., 1998; Tang et al., 2000a; Vigario et al., 1999, 2000; Wubbeler et al Pearlmutter, Barak 39 Independent Components of...

  19. Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

    2014-10-23T23:59:59.000Z

    Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

  20. Scott Taylor, ALS Safety Manager

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearchPhysics LabwildfiresScott Taylor, ALS Safety