Sample records for airshares eu carbon

  1. AirShares EU Carbon Allowances Fund | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlinPapersWindeySanta2004) |Agawam,Ahmeek,Wisconsin: EnergyAirAirShares EU

  2. De-Carbonizing California and the EU

    E-Print Network [OSTI]

    Berck, Peter; Brannlund, Runar

    2008-01-01T23:59:59.000Z

    the EU has set a biofuels transport target for each country,for 10% of transport fuels to be biofuels. This is about the

  3. Carbon leakage and competitiveness of cement and steel industries under the EU

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    No 53-2013 Carbon leakage and competitiveness of cement and steel industries under the EU ETS: much2014 #12;Carbon leakage and competitiveness of cement and steel industries under the EU ETS: much ado about nothing Abstract In a world of uneven climate policies, concerns about carbon leakage

  4. Carbon Leakage in the Primary Aluminium Sector: What evidence after 6 years of the EU ETS?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the European Union Emissions Trading Scheme (EU ETS). The findings suggest that while rising electricity prices. Keywords: carbon leakage, European Union Emissions Trading Scheme (EU ETS), CO2 pricing 1 1 #12;32 2 1 - Introduction Since the European Union Emissions Trading Scheme (EU ETS) began pricing CO2 emissions within

  5. Preparation of polypyrrole-incorporated mesoporous carbon-based composites for confinement of Eu(III) within mesopores

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    e Mesoporous polymer-carbon composite (CMPEI/CMK-3) materials were successfully preparedPreparation of polypyrrole-incorporated mesoporous carbon-based composites for confinement of Eu processes. 1. Introduction A number of organic-inorganic or organic-organic composite materials have been

  6. Imaging the oxygen-rich disk toward the silicate carbon star EU And

    E-Print Network [OSTI]

    Keiichi Ohnaka; David A. Boboltz

    2007-12-14T23:59:59.000Z

    We present multi-epoch high-angular resolution observations of 22 GHz H2O masers toward the silicate carbon star EU And to probe the spatio-kinematic distribution of oxygen-rich material. EU And was observed at three epochs (maximum time interval of 14 months) with the Very Long Baseline Array (VLBA). Our VLBA observations of the 22 GHz H2O masers have revealed that the maser spots are distributed along a straight line across ~20 mas, with a slight hint of an S-shaped structure. The observed spectra show three prominent velocity components at V_LSR = -42, -38, and -34 km s^-1, with the masers in SW redshifted and those in NE blueshifted. The maser spots located in the middle of the overall distribution correspond to the component at V_LSR = -38 km s^-1, which approximately coincides with the systemic velocity. These observations can be interpreted as either an emerging helical jet or a disk viewed almost edge-on (a circumbinary or circum-companion disk). However, the outward motion measured in the VLBA images taken 14 months apart is much smaller than that expected from the jet scenario. Furthermore, the mid-infrared spectrum obtained with the Spitzer Space Telescope indicates that the 10 micron silicate emission is optically thin and the silicate grains are of sub-micron size. This lends support to the presence of a circum-companion disk, because an optically thin circumbinary disk consisting of such small grains would be blown away by the intense radiation pressure of the primary (carbon-rich) star. If we assume Keplerian rotation for the circum-companion disk, the mass of the companion is estimated to be 0.5--0.8 M_sun. We also identify CO2 emission features at 13--16 micron in the Spitzer spectrum of EU And--the first unambiguous detection of CO2 in silicate carbon stars.

  7. CARBON LEAKAGE AND CAPACITY-BASED ALLOCATIONS. IS THE EU RIGHT?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , California, China, India, New Zealand...). The EU implemented its ETS in 2005 and has signicantly revised Organization (Wooders and Cosbey, 2010). The main approach to circumvent this political constraint relies in Australia if the new majority does not repeal the Clean Energy Future legislation). The EU has followed

  8. Carbon Prices during the EU ETS Phase II: Dynamics and Volume Analysis

    E-Print Network [OSTI]

    Boyer, Edmond

    Université Paris Dauphine Abstract The European Union Emissions Trading Scheme (EU ETS) is the largest emissions trading scheme to date. This article summarizes the principle elements behind the trading system of reducing CO2 emissions and achieving the Kyoto Protocol target. The European Union Emissions Trading Scheme

  9. CARBON LEAKAGE AND CAPACITY-BASED ALLOCATIONS. IS THE EU RIGHT?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    petroleum...). Three main approaches have been proposed: output based allocation (Aus- tralia, California makes the dierence. A calibration of the model is used to evaluate the EU scheme for the cement sec- tor and Business Economics (Guy Meunier and Jean-Pierre Ponssard). 1 hal-00672907,version1-22Feb2012 #12

  10. JOURNAL DE PHYSIQUE Colloque C5, supplement aun 5, Tome 40, Mai 1979, page C5-393 Effects of carbon on the magnetism of EuB6

    E-Print Network [OSTI]

    Boyer, Edmond

    of carbon on the magnetism of EuB6 M. Kasaya (*), J. M. Tarascon, J. Etourneau and P. Hagenmuller antiferromagnétique. Pour des compositions intermédiaires, ils sont mictomagnétiques. Abstract. -- Magnetization has been measured as function of temperature and magnetic field for compounds of composition EuB6_xCx (0

  11. Les dterminants du prix du carbone sur le march europen des quotas Carbon price drivers in the EU Emissions Trading Scheme

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the EU Emissions Trading Scheme Emilie Alberola1 et Julien Chevallier2 Résumé: L'article examine le prix des quotas durant la première période (2005-2007) de l'European Union Emissions Trading Scheme (EU

  12. Impact of European Emissions Trading System (EU-ETS) on carbon emissions and investment decisions in the power sector

    E-Print Network [OSTI]

    Feilhauer, Stephan M. (Stephan Marvin)

    2009-01-01T23:59:59.000Z

    This masters thesis assesses the impact of a emissions trading on short-term carbon abatement and investment decisions in the power sector. Environmental benefits from carbon abatement due to emissions trading are quantified ...

  13. Research Summary The EU Emissions Trading System: Opportunities for Forests?

    E-Print Network [OSTI]

    is currently the world's largest carbon market. It does not cover carbon sequestration by forests at present. Although the EU ETS does not currently cover forestry carbon sequestration and there is no indication. o Consider potential opportunities associated with the EU ETS and carbon sequestration that may

  14. Contraction & Convergence: UK carbon emissions and the

    E-Print Network [OSTI]

    Watson, Andrew

    the EU's emissions trading scheme will do little to mitigate carbon emissions 4) Aviation growth must emissions. Keywords Contraction & Convergence; aviation; emissions trading; passengers; carbon dioxide #12

  15. activated carbon preparation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mesoporous carbon-based composites for confinement of Eue Mesoporous polymer-carbon composite (CMPEICMK-3) materials were successfully prepared. After Eu(III) ions were loaded...

  16. activated carbon prepared: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mesoporous carbon-based composites for confinement of Eue Mesoporous polymer-carbon composite (CMPEICMK-3) materials were successfully prepared. After Eu(III) ions were loaded...

  17. activated carbons prepared: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mesoporous carbon-based composites for confinement of Eue Mesoporous polymer-carbon composite (CMPEICMK-3) materials were successfully prepared. After Eu(III) ions were loaded...

  18. De-Carbonizing California and the EU

    E-Print Network [OSTI]

    Berck, Peter; Brannlund, Runar

    2008-01-01T23:59:59.000Z

    first example is the ethanol and hydrogen fuel cell vehiclein cellulosic fuels (either ethanol or a liquid ,) the useto the use of fuel will likely keep most ethanol in the

  19. De-Carbonizing California and the EU

    E-Print Network [OSTI]

    Berck, Peter; Brannlund, Runar

    2008-01-01T23:59:59.000Z

    was a stabilization of CO2 emissions orginating from fossila stabilization by 2010 of CO2 emissions from transports toDifferentiated with respect to CO2 emissions SEK 10 000 (€ 1

  20. The European carbon market (2005-2007): banking, pricing and risk-hedging strategies

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Keywords: Climate Change Policy; Emissions Trading; EU ETS; European carbon market; Banking Borrowing2010 #12;2 1 Introduction The European Union Emissions Trading Scheme (EU ETS) has been created

  1. Template synthesis and luminescence properties of TiO{sub 2}:Eu{sup 3+} nanotubes

    SciTech Connect (OSTI)

    Zhao, Huan; Zheng, Keyan; Sheng, Ye; Li, Hongbo; Zhang, Hongguang; Qi, Xiaofei [College of Chemistry, Jilin University, Changchun 130012 (China); Shi, Zhan [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zou, Haifeng, E-mail: zouhf@jlu.edu.cn [College of Chemistry, Jilin University, Changchun 130012 (China)

    2014-02-15T23:59:59.000Z

    Uniform TiO{sub 2}:Eu{sup 3+} nanotubes have been successfully synthesized through a simple solvothermal process with carbon nanotubes (CNTs) as templates, free of any surfactant or catalyst. X-ray diffraction (XRD) results demonstrate that the product is a pure anatase phase of TiO{sub 2}. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images indicate that the as-obtained TiO{sub 2}:Eu{sup 3+} nanotubes are uniform in size and distribution, and the thickness of the wall is about 8 nm. The possible formation mechanism has also been proposed. The luminescent spectrum shows that TiO{sub 2}:Eu{sup 3+} nanotubes exhibit a red emission at 612 nm due to the {sup 5}D{sub 0}?{sup 7}F{sub 2} transition. Furthermore, this synthetic route is promising for the preparation of other one-dimensional inorganic nanomaterials because of its simplicity and the low cost of the starting reagents. - Graphical abstract: This picture is the illustration for the formation process of TiO{sub 2}:Eu{sup 3+} nanotubes. Display Omitted - Highlights: • TiO{sub 2}:Eu{sup 3+} nanotubes have been prepared through a simple solvothermal process. • The TiO{sub 2}:Eu{sup 3+} nanotubes are uniform in size and distribution. • Under UV light excitation, the TiO{sub 2}:Eu{sup 3+} nanotubes show strong red emission.

  2. Modelling Correlation in Carbon and Energy Markets

    E-Print Network [OSTI]

    Koenig, Philipp

    2011-02-10T23:59:59.000Z

    The paper examines correlations between daily returns of month-ahead baseload electricity, fuel input and carbon emission allowance (EU-ETS) prices for Great Britain. The perspective of a CCGT plant operator is assumed, producing baseload...

  3. Supported by GreenNet-EU27

    E-Print Network [OSTI]

    Figueiredo Integration costs of wind due to changed system operation and investment decisions in GermanySupported by GreenNet-EU27 EIE/04/049/S07.38561 GreenNet-EU27 GUIDING A LEAST COST GRID INTEGRATION cost and grid extension cost caused by intermittent RES-E grid integration Derk Jan Swider (Ed

  4. Discovery of the $^{151}$Eu $\\alpha$ decay

    E-Print Network [OSTI]

    Casali, N; Orio, F; Pattavina, L; Beeman, J W; Bellini, F; Cardani, L; Dafinei, I; Di Domizio, S; Di Vacri, M L; Gironi, L; Kosmyna, M B; Nazarenko, B P; Nisi, S; Pessina, G; Piperno, G; Pirro, S; Rusconi, C; Shekhovtsov, A N; Tomei, C; Vignati, M

    2013-01-01T23:59:59.000Z

    We report on the observation of the $^{151}$Eu $\\alpha$ decay to the ground state of $^{147}$Pm. We measured a half-life of T_{1/2}=(4.62$\\pm$0.95(stat.)$\\pm$0.68(syst.))$\\times 10^{18}$ y and a Q-value of 1948.9$\\pm$6.9 keV, using a 6.15 g Li$_6$Eu(BO$_3$)$_3$ crystal operated as scintillating bolometer.

  5. Facebook and its EU users Applicability of the EU data protection law

    E-Print Network [OSTI]

    Boyer, Edmond

    Facebook and its EU users ­ Applicability of the EU data protection law to US based SNS* Aleksandra (SNS). The analysis will be conducted on the example of Facebook, which is one of the most popular SNS. The goal of the paper is to examine whether European users of Facebook can rely on their national data

  6. Social Actors in the Implementation of EU Agri-Environmental Policy

    E-Print Network [OSTI]

    Moyano, Eduardo

    2005-01-01T23:59:59.000Z

    of EU Agri- Environmental Policy Eduardo Moyano Institute ofof EU Agri- Environmental Policy Eduardo Moyano and Fernandoof EU Agri-Environmental Policy”. Unfortunately, neither

  7. Optically active centers in Eu implanted, Eu in situ doped GaN, and Eu doped GaN quantum dots

    SciTech Connect (OSTI)

    Bodiou, L.; Braud, A.; Doualan, J.-L.; Moncorge, R. [Centre de Recherche sur les Ions, les Materiaux et la Photonique (CIMAP), CNRS-CEA-ENSICAEN, Universite de Caen, UMR 6252, 14050 Caen (France); Park, J. H.; Munasinghe, C.; Steckl, A. J. [University of Cincinnati, Cincinnati, Ohio 45221-0030 (United States); Lorenz, K.; Alves, E. [Instituto Tecnologico e Nuclear, Estrada Nacional 10, PT-2685-953 Sacavem (Portugal); Daudin, B. [INAC SP2M/PSC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France)

    2009-02-15T23:59:59.000Z

    A comparison is presented between Eu implanted and Eu in situ doped GaN thin films showing that two predominant Eu sites are optically active around 620 nm in both types of samples with below and above bandgap excitation. One of these sites, identified as a Ga substitutional site, is common to both types of Eu doped GaN samples despite the difference in the GaN film growth method and in the doping technique. High-resolution photoluminescence (PL) spectra under resonant excitation reveal that in all samples these two host-sensitized sites are in small amount compared to the majority of Eu ions which occupy isolated Ga substitutional sites and thus cannot be excited through the GaN host. The relative concentrations of the two predominant host-sensitized Eu sites are strongly affected by the annealing temperature for Eu implanted samples and by the group III element time opening in the molecular beam epitaxy growth. Red luminescence decay characteristics for the two Eu sites reveal different excitation paths. PL dynamics under above bandgap excitation indicate that Eu ions occupying a Ga substitutional site are either excited directly into the {sup 5}D{sub 0} level or into higher excited levels such as {sup 5}D{sub 1}, while Eu ions sitting in the other site are only directly excited into the {sup 5}D{sub 0} level. These differences are discussed in terms of the spectral overlap between the emission band of a nearby bound exciton and the absorption bands of Eu ions. The study of Eu doped GaN quantum dots reveals the existence of only one type of Eu site under above bandgap excitation, with Eu PL dynamics features similar to Eu ions in Ga substitutional sites.

  8. Universitt Wien European Studies Vienna Romania's Way into the EU

    E-Print Network [OSTI]

    Müller, Ralf R.

    1 Universität Wien European Studies Vienna Romania's Way into the EU Author: Liana Müller Supervisor: Prof. Dr. Peter Fischer Index terms Romania, European Union, Enlargement, Accession, Acquis............................................................................. 8 3 EU ­ Romania relations

  9. act infringes eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Main Mall Vancouver, B.C. Canada Pauly, Daniel 44 This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground affecting corporate climate...

  10. Energy Department Partners with EU on Electric Vehicle and Smart...

    Office of Environmental Management (EM)

    Partners with EU on Electric Vehicle and Smart Grid Coordination Energy Department Partners with EU on Electric Vehicle and Smart Grid Coordination July 19, 2013 - 5:17pm Addthis...

  11. ag cu eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  12. aquilo mas eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  13. augu eu degvielu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  14. Edinburgh Research Explorer The Structure of Eu-III

    E-Print Network [OSTI]

    Millar, Andrew J.

    ]. Very recently, Eu has been found to be superconducting at a pressure of approximately 80 GPa, with Tc

  15. Japan, EU reach basic agreement over ITER The Yomiuri Shimbun

    E-Print Network [OSTI]

    Japan, EU reach basic agreement over ITER The Yomiuri Shimbun The government and the European Union to the unsuccessful candidate country. Japan and France, the EU's candidate, have been bidding to host the facility bidder's country. The ITER project participants--Japan, China, the EU, Russia, South Korea and the United

  16. This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground affecting corporate climate strategies.

    E-Print Network [OSTI]

    This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground@bookpoint.co.uk May 2013 322 pages Hardback 978-1-4094-6078-7 £60.00 Corporate Responses to EU Emissions Trading at The Fridtjof Nansen Institute, Norway `With greenhouse gas emissions trading schemes emerging worldwide

  17. Optimal Production Policy under the Carbon Emission Market

    E-Print Network [OSTI]

    Touzi, Nizar

    with the reduction of the green- house gases including CO2 and is accepted by several countries e.g. Euro- pean Union Scheme (EU ETS) which provides a way to control the emission of CO2 within carbon polluters throughOptimal Production Policy under the Carbon Emission Market Redouane Belaouar Arash Fahim Nizar

  18. Induced spin-polarization of EuS at room temperature in Ni/EuS multilayers

    SciTech Connect (OSTI)

    Poulopoulos, P., E-mail: poulop@upatras.gr [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Materials Science Department, University of Patras, 26504 Patras (Greece); Goschew, A.; Straub, A.; Fumagalli, P. [Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Kapaklis, V.; Wolff, M. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (ESRF), B.P.220, 38043 Grenoble (France); Pappas, S. D. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

    2014-03-17T23:59:59.000Z

    Ni/EuS multilayers with excellent multilayer sequencing are deposited via e-beam evaporation on the native oxide of Si(100) wafers at 4?×?10{sup ?9} millibars. The samples have very small surface and interface roughness and show sharp interfaces. Ni layers are nanocrystalline 4–8?nm thick and EuS layers are 2–4?nm thick and are either amorphous or nanocrystalline. Unlike for Co/EuS multilayers, all Eu ions are in divalent (ferromagnetic) state. We show a direct antiferromagnetic coupling between EuS and Ni layers. At room temperature, the EuS layers are spin-polarized due to the proximity of Ni. Therefore, Ni/EuS is a candidate for room-temperature spintronics applications.

  19. CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite

    E-Print Network [OSTI]

    Rollins, Andrew M.

    materials. MATERIALS AND DESIRED DATA Carbon-Carbon Composites(T300 & SWB): Crush Resistance, Bend StrengthCARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

  20. Evidence of Eu{sup 2+} 4f electrons in the valence band spectra of EuTiO{sub 3} and EuZrO{sub 3}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T. [National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Valant, M. [Materials Research Laboratory, University of Nova Gorica, Vipavska 13, 5000 Nova Gorica (Slovenia); Williams, J. R. [International Center for Young Scientists (ICYS), MANA, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Bugnet, M.; Botton, G. A. [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Ohashi, N. [International Center for Materials Nanoarchitectonics, MANA, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Sakka, Y. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2012-10-15T23:59:59.000Z

    We report on optical band gap and valence electronic structure of two Eu{sup 2+}-based perovskites, EuTiO{sub 3} and EuZrO{sub 3} as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f{sup 7} electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO{sub 3} perovskites except that it is shifted to higher binding energies. Appearance of the Eu{sup 2+} 4f{sup 7} band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  1. Optical properties of Eu{sup 2+}/Eu{sup 3+} mixed valence, silicon nitride based materials

    SciTech Connect (OSTI)

    Kate, Otmar M. ten, E-mail: o.m.tenkate@tudelft.nl [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Vranken, Thomas [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Kolk, Erik van der [Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Jansen, Antonius P.J.; Hintzen, Hubertus T. [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands)

    2014-05-01T23:59:59.000Z

    Eu{sub 2}SiN{sub 3}, a mixed valence europium nitridosilicate, has been prepared via solid-state reaction synthesis and its oxidation behavior and optical properties have been determined. Furthermore, the stability of several isostructural compounds of the type M{sup 2+}L{sup 3+}SiN{sub 3} has been predicted by using the density functional theory calculations, and verified by the actual synthesis of CaLaSiN{sub 3}, CaEuSiN{sub 3} and EuLaSiN{sub 3}. The band gap of CaLaSiN{sub 3} was found around 3.2 eV giving the material its yellow color. Eu{sub 2}SiN{sub 3} on the other hand is black due to a combination of the 4f–5d absorption band of Eu{sup 2+} and the charge transfer band of Eu{sup 3+}. Thermogravimetric analysis and Raman spectroscopic study of Eu{sub 2}SiN{sub 3} revealed that oxidation of this compound in dry air takes place via a nitrogen retention complex. - Graphical abstract: Energy level scheme of Eu{sub 2}SiN{sub 3} showing the occupied N{sup 3?} 2p band (blue rectangle), unoccupied Eu{sup 2+} 5d band (white rectangle), occupied Eu{sup 2+} 4f ground states (filled red circles) and unoccupied Eu{sup 2+} ground states (open red circles). - Highlights: • Density functional theory calculations on the stability of M{sup 2+}L{sup 3+}SiN{sub 3} compounds. • Solid-state reaction synthesis of Eu{sub 2}SiN{sub 3}, CaLaSiN{sub 3}, EuLaSiN{sub 3} and CaEuSiN{sub 3}. • Determination of the Eu{sup 2+} 4f–5d and Eu{sup 3+} CT transitions in M{sup 2+}L{sup 3+}SiN{sub 3} compounds. • Oxidation of Eu{sub 2}SiN{sub 3} in dry air takes place via a nitrogen retention complex.

  2. Syntheses, crystal structures, and properties of EuRhIn, EuIr{sub 2}, and EuIrSn{sub 2}

    SciTech Connect (OSTI)

    Poettgen, R.; Hoffmann, R.D.; Moeller, M.H.; Kotzyba, G.; Kuennen, B.; Rosenhahn, C.; Mosel, B.D. [Univ. Muenster (Germany)] [Univ. Muenster (Germany)

    1999-06-01T23:59:59.000Z

    The title compounds were prepared from the elements by reactions in sealed tantalum tubes in a high-frequency furnace. Their structures were refined from single crystal X-ray diffractometer data: Pnma, a = 744.4(1) pm, b = 434.15(9) pm, c = 845.5(1) pm, wR2 = 0.0433, 658 F{sup 2} values, 20 variables for EuRhIn, Rd3m, a = 756.5(1) pm, wR2 = 0.0349, 94 F{sup 2} values, 5 variables for EuIr{sub 2}, and Cmcm, a = 434.78(3) pm, b = 1124.0(1) pm, c = 751.20(5) pm, wR2 = 0.0561, 565 F{sup 2} values, 16 variables for EuIrSn{sub 2}. EuRhIn crystallizes with a TiNiSi type structure that consists of strongly puckered Rh{sub 3}In{sub 3} hexagons. The europium atoms fill the channels within the three-dimensional [RhIn] polyanion. EuRhIn orders ferromagnetically at 22.0(5) K with a saturation magnetic moment of 6.7(1) {mu}{sub B}/Eu at 4 k and 5.5 T. The divalent character of the europium atoms in EuRhIn was determined from temperature dependent susceptibility (7.9 {mu}{sub B}/Eu in the high-temperature part) and {sup 151}Eu Moessbauer spectroscopic experiments. The latter show an isomer shift of {delta} = {minus}8.30(2) mm/s at 78 K. At 4.2 K full magnetic hyperfine field splitting subjected to significant quadrupole splitting of {Delta}E{sub Q} = 8 mm/s is observed. EuRhIn is a metallic conductor with a room temperature value of 58 {micro}{Omega}cm for the specific resistivity. The structure of the Laves phase EuIr{sub 2} is confirmed on the basis of single crystal X-ray data. The iridium atoms form a tetrahedral network with Ir-Ir distances of 268 pm. EuIrSn{sub 2} adopts a MgCuAl{sub 2} type structure that may be described as an iridium-filled variant of a distorted CaIn{sub 2}-like sublattice of composition EuSn{sub 2}. The tin atoms in the distorted and puckered hexagonal network have shorter (303 and 322 pm) and longer (343 pm) tin-tin contacts. 40 refs., 9 figs., 5 tabs.

  3. A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+

    E-Print Network [OSTI]

    McKittrick, Joanna

    A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+ Luminescent Powders G. A. Hirata1 between the precursors. The preparation of Eu-doped Ga2O3 powders was achieved using a new combustion)3 and Ga(NO3)3 as the precursors and hydrazine as (non-carbonaceous) fuel. A spontaneous combustion

  4. Chemical bonding in EuTGe (T=Ni, Pd, Pt) and physical properties of EuPdGe

    SciTech Connect (OSTI)

    Rocquefelte, Xavier [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France); Gautier, Regis [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France); Halet, Jean-Francois [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France)], E-mail: halet@univ-rennes1.fr; Muellmann, Ralf [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Rosenhahn, Carsten [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Mosel, Bernd D. [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany)], E-mail: pottgen@uni-muenster.de

    2007-02-15T23:59:59.000Z

    EuPdGe was prepared from the elements by reaction in a sealed tantalum tube in a high-frequency furnace. Magnetic susceptibility measurements show Curie-Weiss behavior above 60 K with an experimental magnetic moment of 8.0(1){mu} {sub B}/Eu indicating divalent europium. At low external fields antiferromagnetic ordering is observed at T {sub N}=8.5(5) K. Magnetization measurements indicate a metamagnetic transition at a critical field of 1.5(2) T and a saturation magnetization of 6.4(1){mu} {sub B}/Eu at 5 K and 5.5 T. EuPdGe is a metallic conductor with a room-temperature value of 5000{+-}500 {mu}{omega} cm for the specific resistivity. {sup 151}Eu Moessbauer spectroscopic experiments show a single europium site with an isomer shift of {delta}=-9.7(1) mm/s at 78 K. At 4.2 K full magnetic hyperfine field splitting with a hyperfine field of B=20.7(5) T is observed. Density functional calculations show the similarity of the electronic structures of EuPdGe and EuPtGe. T-Ge interactions (T=Pd, Pt) exist in both compounds. An ionic formula splitting Eu{sup 2+} T {sup 0}Ge{sup 2-} seems more appropriate than Eu{sup 2+} T {sup 2+}Ge{sup 4-} accounting for the bonding in both compounds. Geometry optimizations of EuTGe (T=Ni, Pt, Pd) show weak energy differences between the two structural types. - Graphical abstract: Cutouts of the [PdGe] and [PtGe] polyanions in the structures of EuPdGe and EuPtGe. Atom designations and some relevant interatomic distances are given.

  5. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01T23:59:59.000Z

    fluctuations. Electricity generation [TWh/year] EU-25 USA4 . Electricity generation [TWh/year] Japan EU-25 USA EU-25USA Japan Wind Waste Solar Biomass Geothermal Figure 2 Historical pattern of electricity

  6. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Haak, Hein

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe on Internet. A cooperative Rain 8 Danger from river flooding 8 Thunderstorms 10 Lightning tips 11 Snow and ice 12 Mist and fog 13

  7. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Stoffelen, Ad

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe dangers 16 Forest and bush fires 17 Avalanches 18 #12;33 www.meteoalarm.eu The weather knows no boundaries dangerous, both nationally and on a local scale of over 650 regions. Not only are gales, torrential rain

  8. EU Guide v 2d January 20141 Finance Division

    E-Print Network [OSTI]

    de Gispert, Adrià

    EU Guide v 2d January 20141 Finance Division Procurement Services The EU Directives on Public purchasing practice and especially where funders require it as part of their grant conditions. In exceptional Andrew Reid (goods and services) or the Director of Estate Management and Building Services (property

  9. What (Economic) Constitution Does the EU Need ? Janvier 2007

    E-Print Network [OSTI]

    Boyer, Edmond

    of the structurally different economic performances and incentives of small and large countries under the EuropeanWhat (Economic) Constitution Does the EU Need ? N° 2007-04 Janvier 2007 Eloi Laurent OFCE-FNSP eloi2014 #12;2 What (Economic) Constitution Does the EU Need? * Éloi Laurent (OFCE/FNSP)1 Jacques Le

  10. Japan rejects EU ITER deal 02 February 2005

    E-Print Network [OSTI]

    billion (euro 422 million) worth of orders to EU companies and to fund around half the costs this year. The joint project between Japan, the EU, the US, Russia, China and South Korea will see, supported by Russia and China proposes the French town of Cadarache for the development. Meanwhile

  11. Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal logging > Printer-friendly

    E-Print Network [OSTI]

    Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal logging > Printer-friendly Cameroon axes illegal logging 14/05/2010 Cameroon axes illegal logging Illegal and trade of illegal logging. The latest country to sign up to the programme is Cameroon, which completed

  12. Antiferromagnetism of perovskite EuZrO{sub 3}

    SciTech Connect (OSTI)

    Zong Yanhua [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan); Fujita, Koji, E-mail: fujita@dipole7.kuic.kyoto-u.ac.j [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan); Akamatsu, Hirofumi; Murai, Shunsuke; Tanaka, Katsuhisa [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)

    2010-01-15T23:59:59.000Z

    Polycrystalline EuZrO{sub 3} has been synthesized by the solid-state reaction between EuO and ZrO{sub 2}, and its structural and magnetic properties have been investigated. Rietveld analysis of the X-ray diffraction pattern indicates that EuZrO{sub 3} crystallizes in an orthorhombic perovskite structure. {sup 151}Eu Moessbauer effect measurement reveals that almost all the europium ions are present as the divalent state and occupy distorted sites with non-axial electric field gradients, in agreement with the orthorhombic structure. In contrast to previous reports, an antiferromagnetic transition was observed around 4.1 K. The magnetic structure below the Neel temperature has been discussed. - Graphical abstract: Perovskite EuZrO{sub 3} with almost all Eu ions present as Eu{sup 2+} has been synthesized and its structure and magnetic properties have been studied. An antiferromagnetic transition was observed around 4.1 K for the first time. The mechanism of the magnetic transition has been discussed.

  13. Optical Probing of metamagnetic phases in epitaxial EuSe

    SciTech Connect (OSTI)

    Galgano, G. D.; Henriques, A. B. [Instituto de Fisica, Universidade de Sao Paulo, Caixa Postal 66318, 05315-970 Sao Paulo (Brazil); Bauer, G.; Springholz, G. [Institut fuer Halbleiter und Festkoerperphysik, Johannes Kepler Universitaet Linz, 4040 Linz (Austria)

    2011-12-23T23:59:59.000Z

    EuSe is a wide gap magnetic semiconductors with a potential for applications in proof-of-concept spintronic devices. When the temperature is lowered, EuSe goes through sharp transitions between a variety of magnetic phases and is thus described as metamagnetic. The purpose of the present investigation is to correlate the magnetic order to the sharp dichroic doublet, discovered recently in high quality thin epitaxial layers of EuSe, grown by molecular beam epitaxy. We report detailed measurements of the doublet positions and intensities as a function of magnetic field in low temperatures, covering several magnetic phases.

  14. Stringency and distribution in the EU ETS: first evidence 41 CLIMATE POLICY

    E-Print Network [OSTI]

    Steininger, Karl W.

    Stringency and distribution in the EU Emissions Trading Scheme: first evidence CLAUDIA KETTNER1,2 , ANGELA covered by the EU Emissions Trading Scheme (EU ETS) were compared. Based on data available for 24 Member: climate policy; emissions trading; EU Emissions Trading Scheme A partir des émissions vérifiées pour les

  15. Plug-in electric vehicle introduction in the EU

    E-Print Network [OSTI]

    Sisternes, Fernando J. de $q (Fernando José Sisternes Jiménez)

    2010-01-01T23:59:59.000Z

    Plug-in electric vehicles (PEVs) could significantly reduce gasoline consumption and greenhouse gas (GHG) emissions in the EU's transport sector. However, PEV well-towheel (WTW) emissions depend on improvements in vehicle ...

  16. Agricultural policies in France: from EU regulation to national design

    E-Print Network [OSTI]

    Boyer, Edmond

    Agricultural policies in France: from EU regulation to national design Yann Desjeux, Hervé Guyomard.................................................................................2 I.2. Short characteristics of the French agriculture and its strategic problems ...............8.......................................................................................................................13 II. Agricultural market policy (Pillar I

  17. Forschung und EU-Hochschulbro, Technologietransfer Februar 2012

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    .7. Forschungsinfrastrukturen 8 2.7.1. Arbeitsprogramm 2013 ­ Geplante Ausschreibungen 8 2.8. Euratom 9 2.8.1. Nuclear Fission.1.1. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-NET ICT-AGRI) ­ Vorankündigung 16 6 ­ Entwurf Arbeitsprogramm 2012 19 8.1.2. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-NET ICT

  18. Metastable states in InGaN/GaN MQW structures doped with Sm, Eu, and Eu + Sm

    SciTech Connect (OSTI)

    Mezdrogina, M. M., E-mail: Margaret.M@mail.ioffe.ru [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Kozhanova, Yu. V. [St. Petersburg State Polytechnical University (Russian Federation)

    2013-04-15T23:59:59.000Z

    Measurements of the microphotoluminescence (microPL) spectra of InGaN/GaN:Sm and InGaN/GaN:Eu quantum well (QW) structures show that the action of a magnetic field gives rise to Van Vleck paramagnetism for Eu{sup 3+} and Sm{sup 3+}. The macrophotoluminescence (macroPL) spectra recorded after measuring the microPL spectra of InGaN/GaN QW structures doped with Sm or Eu + Sm at a high excitation level (>10{sup 23} photons cm{sup -2} s{sup -1}) in magnetic fields contain no QW emission lines which are present in the macroPL spectra recorded before these microPL measurements. This is indicative of the presence of photoinduced defects. Annealing of the InGaN/GaN:Sm and InGaN/GaN:(Eu + Sm) structures reduces the concentration of photoinduced defects.

  19. Report on the EU-US Environmental Biotechnology Workshop on Microbial Community Dynamics: Cooperation and Competition

    SciTech Connect (OSTI)

    Wall, Judy D. [University of Missouri-Columbia

    2013-07-01T23:59:59.000Z

    The Workshop on Microbial Community Dynamics: Cooperation and Competition to be held in the fall of 2012 in St. Louis, Missouri, USA, is an initiative of the Environmental Biotechnology Working Group of the EU-US Taskforce on Biotechnology Research, a cooperative program between the European Commission and the United States of America. The activities of the Environmental Biotechnology Working Group have as their goals to provide a forum for early career scientists from the US and EU to meet, to learn cutting edge research in the area of microbial biotechnology from world experts and to set the groundwork for future cooperation and collaboration. Workshop topics will address fundamental physiology and genetics of microbial communities that will contribute to advances in bioremediation, bioenergy conversion and carbon sequestration. Senior scientist participants will be world renowned experts who will present the current status of their fields and forecast research challenges and opportunities. It is a goal of the Environmental Biotechnology Working Group to facilitate the formation of direct collaborations among US and European scientists in programs of mutual interest and benefit. Therefore, the workshop will also provide an opportunity for members of the Working Group and attendees to identify areas where advancement is necessary and plan the steps necessary for realizing future research collaborations. In addition, time will be provided for mentoring of the early career scientists by the senior scientists on an individual basis.

  20. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01T23:59:59.000Z

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  1. Optically induced magnetic polarons in EuTe

    SciTech Connect (OSTI)

    Henriques, A. B.; Galgano, G. D. [Instituto de Física, Universidade de São Paulo, Caixa Postal 66318, 05315-970, São Paulo (Brazil); Abramof, E.; Rappl, P. H. O. [LAS - INPE, Av. Dos Astronautas, 1758, 12227-010, São José dos Campos (Brazil)

    2013-12-04T23:59:59.000Z

    Direct measurements of the photoinduced magnetization in EuTe, using a two color pump-and-probe technique, are presented. The photoinduced effect was pumped using photons of above-the-bandgap energy, and detected by the Faraday rotation of a probe beam of energy below-the-bandgap. The photoinduced Faraday rotation changes sign, as expected from our model for the optically induced magnetic polaron. The EuTe spin-flop transition at low fields is also detected as a sharp step in the photoinduced Faraday rotation, and its observation provides additional supports for the photoinduced polaron model.

  2. Reforming the EU: The Future of European Law and Policy IV CONFERENCE PROGRAMME

    E-Print Network [OSTI]

    Birmingham, University of

    Reforming the EU: The Future of European Law and Policy IV CONFERENCE session "Reforming the EU" Chair: Dr Luca Rubini, Deputy Director Institute Rubini Reforming European competition law: should the European Commission have

  3. The EU ETS: CO2 prices drivers during the learning experience (2005-2007)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Union Allowances (EUAs), valid for compliance under the European Union Emissions Trading Scheme (EU ETS of the European Union Emissions Trading Scheme (EU ETS) is to regulate CO2 emissions from the most energy

  4. EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry in Gabon

    E-Print Network [OSTI]

    1 EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry: .....................................................................................................................................................2 Part I: The EU, China and the external environmental dimension....................................................................3 1.1 China as a competitor normative power in the environmental sector

  5. Enlargement and the EU Periphery: The Impact of Changing Market Potential

    E-Print Network [OSTI]

    Boyer, Edmond

    proximate to the new accession countries than in "interior" EU regions. We also find that a future Balkans through which EU enlargement may affect the economies of Western Europe: increased specialisation

  6. ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS...

    Office of Environmental Management (EM)

    ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS FOR A CLEAN ENERGY FUTURE, SEPTEMBER 8-9, 2014 ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL...

  7. The Political Economy of Agri-Environmental Policies in the EU

    E-Print Network [OSTI]

    Swinnen, Johan

    2005-01-01T23:59:59.000Z

    Economy of Agri-Environmental Policies in the EU JohanEconomy of Agri-Environmental Policies in the EU Johan F.M.changes” Agri-environmental policies are only fraction of

  8. How EU Agri-Environmental Policy Might Have Differed Under Various WTO Scenarios

    E-Print Network [OSTI]

    Swinbank, Alan

    2005-01-01T23:59:59.000Z

    No. 12 How EU Agri-Environmental Policy Might Have DifferedEconomy of Agri-environmental Policies in the U.S. and the2005 How EU agri-environmental policy might have differed

  9. The EU Emission Trading Scheme Insights from the First Trading Years

    E-Print Network [OSTI]

    Steininger, Karl W.

    observed in the Kyoto period. Price development in the EU ETS is mainly driven by the perceived stringency

  10. Forschung und EU-Hochschulbro, Technologietransfer September 2014

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    Nachwuchswissenschaftler/innen 4 1.2. LEIT: Information and communication technologies 4 1.2.1. Öffentliche Konsultation zu Programme Chemical Biology of Native Nucleic Acid Modifications (SPP 1784) 13 4.1.4. Volkswagen.1.8. NIH: Research Grants 16 5. Umweltwissenschaften und Energie 16 5.1.1. EU/KIC InnoEnergy: Call

  11. Limited Sectoral Trading between the EU ETS and China

    E-Print Network [OSTI]

    Limited Sectoral Trading between the EU ETS and China Claire Gavard, Niven Winchester and Sergey established research centers at MIT: the Center for Global Change Science (CGCS) and the Center for Energy analysis need to be related to the economic, technological, and political forces that drive emissions

  12. EU signs ITER deal Negotiations on the ITER international nuclear

    E-Print Network [OSTI]

    Korea and the US, the agreement aims to develop a project that will test the feasibility of nuclearEU signs ITER deal Negotiations on the ITER international nuclear fusion project have been on Wednesday reached a final agreement on the ITER project after years of talks. "The completion

  13. Transitioning Applications to Ontologies http://www.tao-project.eu/

    E-Print Network [OSTI]

    Bontcheva, Kalina

    Transitioning Applications to Ontologies http://www.tao-project.eu/ GOAL Define a low-cost route) in aerospace and automotive industries òSoftware applications maintenance and user support ñOther areas existing application documentation (specifications, UML diagrams, code documentation, software manuals

  14. Transitioning Applications to Ontologies http://www.tao-project.eu

    E-Print Network [OSTI]

    Bontcheva, Kalina

    Transitioning Applications to Ontologies http://www.tao-project.eu TAO Transitioning Applications to Ontologies The goal of the TAO project is to define a low-cost route to transitioning legacy systems will be validated in two high-profile case studies: a comprehensive open source platform (with thousands of users

  15. Mossbauer studies of 151 Eu in europium oxalate,

    E-Print Network [OSTI]

    Ryan, Dominic

    Mo¨ssbauer studies of 151 Eu in europium oxalate, europium bissalen ammonium and europium benzoate of europium water insoluble chelates have been prepared for several decades, the covalent nature temperatures (qD) of three europium chelates: namely europium oxalate, europium bissalen ammonium (recently

  16. Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques

    E-Print Network [OSTI]

    Boyer, Edmond

    , the sorption of Eu(III) at the solid-water interface is important for the performance assessment of nuclear and absence of fulvic acid (FA) and humic acid (HA). The results indicated that the sorption of Eu. The extended X-ray absorption fine structure (EXAFS) analysis of Eu-HA complexes indicated that the distances

  17. Call for expression of interest EU-Brazil Technology and Innovation Forum

    E-Print Network [OSTI]

    Call for expression of interest EU-Brazil Technology and Innovation Forum Participation to B2B targeting research and innovation actors. Among them, this year the EU-Brazil Technology and Innovation and Innovation Forum The EU-Brazil Technology and Innovation Forum is organized by the B.BICE+ consortium

  18. Copyright reform on the EU level European Network for Copyright in support of

    E-Print Network [OSTI]

    Kuhlen, Rainer

    Copyright reform on the EU level European Network for Copyright in support of Education and Budapest Business School #12;Copyright reform on the EU level What can science and education expect from a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR

  19. EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE

    E-Print Network [OSTI]

    EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE Report prepared: Kretschmer, B, Bowyer, C and Buckwell, A (2012) EU Biofuel Use and Agricultural Commodity Prices: A Review............................................................................................................. 8 2 EU POLICY DRIVING BIOFUELS DEMAND AND OUTLOOK FOR THIS DEMAND TO 2020. 9 2.1 What is the current

  20. Issue No. 13 of 2 July 2010 The EU bans illegal timber and timber products

    E-Print Network [OSTI]

    Issue No. 13 of 2 July 2010 The EU bans illegal timber and timber products On 16 June 2010, the EU Parliament and the EU Council reached an agreement on the ban of illegally-logged or illegally-sourced timber in October 2008. Illegal logging is defined as the harvest, processing or trading of timber in violation

  1. Oxygen off-stoichiometry and phase separation in EuO thin films

    SciTech Connect (OSTI)

    Altendorf, S. G.; Efimenko, A.; Oliana, V. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany); Kierspel, H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany)

    2011-10-15T23:59:59.000Z

    We report on our study on the influence of the growth conditions on the europium/oxygen stoichiometry, morphology, magnetic properties, and electrical conductivity of EuO thin films. SQUID magnetometry and x-ray photoelectron spectroscopy were utilized as complementary techniques to determine the oxygen content of EuO{sub 1{+-}x} thin films grown by molecular beam epitaxy with and without the employment of the so-called Eu distillation process. We found indications for phase separation to occur in Eu-rich as well as in over-oxidized EuO for films grown at substrate temperatures below the Eu distillation temperature. Only a fraction of the excess Eu contributes to the metal-insulator transition in Eu-rich films grown under these conditions. We also observed that the surfaces of these films were ill defined and may even contain more Eu excess than the film average. Only EuO films grown under distillation conditions are guaranteed to have the same magnetic and electrical properties as stoichiometric bulk EuO, and to have surfaces with the proper Eu/O stoichiometry and electronic structure.

  2. ITER: Japan to assign 20 percent of construction work to EU firms; Proposal for EU official to assume chief executive

    E-Print Network [OSTI]

    Experimental Reactor (ITER). Japan yesterday revealed the details of a proposal to host the project. Tokyo has, Japan bears half price even with construction inside the EU limits of the accessory structures prospect. The experimental device in order ITER generates electricity, reproducing the fusion reaction

  3. Seeking the optimal LaTaO{sub 4}:Eu phosphor

    SciTech Connect (OSTI)

    Bleier, Grant C. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Nyman, May, E-mail: mdnyman@sandia.gov [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Rohwer, Lauren E.S.; Rodriguez, Mark A. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States)

    2011-12-15T23:59:59.000Z

    Lanthanum orthotantalate, LaTaO{sub 4}, is an excellent host lattice for rare-earth luminescent ions such as Eu{sup 3+} for red emission. However, there are multiple RETaO{sub 4} (RE=rare earth) polymorphs, and the stability of these is controlled predominantly by the RE-radius. Thus it is difficult to obtain a pure phase of LaTaO{sub 4}:Eu as Eu concentration and consequently the RE radius is varied. We recently reported a 'soft-chemical' route that allows crystallization of pure-phase LaTaO{sub 4}:Eu at temperatures as low as 800 Degree-Sign C. In the current report, we investigate polymorph evolution and Eu emission as a function of Eu concentration and annealing temperature. We obtain a maximum quantum yield (QY) of 83% at the highest Eu substitution (25%) for which the low temperature orthorhombic (Pbca) polymorph is stable. Therefore, QY is not limited necessarily by concentration quenching; rather it is limited by polymorph stability as the RE-radius decreases with increasing Eu substitution. - Graphical Abstract: Eu-substituted lanthanum orthotantalates, LaTaO{sub 4}:Eu, are excellent red phosphors. They exhibit up to 83% quantum-yield emission under blue light excitation, optimized through both 'soft chemical processing' and polymorph purity. Highlights: Black-Right-Pointing-Pointer LaTaO{sub 4}:Eu phosphors were synthesized via 'soft-chemical' and solid-state routes. Black-Right-Pointing-Pointer Quantum-yield of Eu emission depends on host polymorph, which changes with La:Eu ratio. Black-Right-Pointing-Pointer Polymorph with optimal Eu-emission is only obtained by 'soft-chemistry'.

  4. EuTZn (T=Pd, Pt, Au) with TiNiSi-type structure-Magnetic properties and {sup 151}Eu Moessbauer spectroscopy

    SciTech Connect (OSTI)

    Mishra, Trinath; Hermes, Wilfried; Harmening, Thomas; Eul, Matthias [Institut fuer Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany)

    2009-09-15T23:59:59.000Z

    The europium compounds EuTZn (T=Pd, Pt, Au) were synthesized from the elements in sealed tantalum tubes in an induction furnace. These intermetallics crystallize with the orthorhombic TiNiSi-type structure, space group Pnma. The structures were investigated by X-ray diffraction on powders and single crystals: a=732.3(2), b=448.5(2), c=787.7(2) pm, R{sub 1}/wR{sub 2}=0.0400/0.0594, 565 F{sup 2} values for EuPdZn, a=727.8(3), b=443.7(1), c=781.7(3) pm, R{sub 1}/wR{sub 2}=0.0605/0.0866, 573 F{sup 2} values for EuPtZn, and a=747.4(2), b=465.8(2), c=789.1(4) pm, R{sub 1}/wR{sub 2}=0.0351/0.0590, 658 F{sup 2} values for EuAuZn, with 20 variables per refinement. Together the T and zinc atoms build up three-dimensional [TZn] networks with short T-Zn distances. The EuTZn compounds show Curie-Weiss behavior in the temperature range from 75 to 300 K with mu{sub eff}=7.97(1), 7.70(1), and 7.94(1) mu{sub B}/Eu atom and theta{sub P}=18.6(1), 34.9(1), and 55.5(1) K for T=Pd, Pt, and Au, respectively, indicating divalent europium. Antiferromagntic ordering was detected at 15.1(3) K for EuPdZn and canted ferromagnetic ordering at 21.2(3) and 51.1(3) K for EuPtZn and EuAuZn. {sup 151}Eu Moessbauer spectroscopic measurements confirm the divalent nature of the europium atoms by isomer shift values ranging from -8.22(8) (EuPtZn) to -9.23(2) mm/s (EuAuZn). At 4.2 K full magnetic hyperfine field splitting is observed in all three compounds due to magnetic ordering of the europium magnetic moments. - Graphical abstract: Europium coordination in EuPdZn, EuPtZn, and EuAuZn.

  5. Radioactive contamination of SrI2(Eu) crystal scintillator

    E-Print Network [OSTI]

    Belli, P; Cerulli, R; Danevich, F A; Galenin, E; Gektin, A; Incicchitti, A; Isaienko, V; Kobychev, V V; Laubenstein, M; Nagorny, S S; Podviyanuk, R B; Tkachenko, S; Tretyak, V I

    2011-01-01T23:59:59.000Z

    A strontium iodide crystal doped by europium (SrI2(Eu)) was produced by using the Stockbarger growth technique. The crystal was subjected to characterisation that included relative photoelectron output and energy resolution for gamma quanta. The intrinsic radioactivity of SrI2(Eu) crystal scintillator was tested both in scintillation mode and by using ultra-low background HPGe gamma spectrometry deep underground. The response of the SrI2(Eu) detector to alpha particles (alpha/beta ratio and pulse shape) was estimated by analysing the 226Ra trace contamination internal to the crystal. We have found alpha/beta=0.55 and no difference in scintillation decay for alpha particles and gamma quanta. The application of the obtained results in the search for the double electron capture and electron capture with positron emission in 84Sr has been investigated at a level of sensitivity T_1/2 \\sim 10^15-10^16 yr. The results of these studies demonstrate the potentiality of this material for a variety of scintillation appli...

  6. Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}

    SciTech Connect (OSTI)

    Grossholz, Hagen; Hartenbach, Ingo [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Trill, Henning; Mosel, Bernd D. [Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Schleid, Thomas, E-mail: schleid@iac.uni-stuttgart.d [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)

    2009-11-15T23:59:59.000Z

    Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent magnetic moments. {sup 151}Eu-Moessbauer spectroscopic experiments at 4.2 K show one signal at an isomer shift of -12.4(1) mm/s and a second one at 0.42(4) mm/s. These signals occur in a ratio of 1:2 and correspond to Eu{sup 2+} and Eu{sup 3+}, respectively. The spectra at 78 and 298 K are similar, thus no change in the Eu{sup 2+}/Eu{sup 3+} fraction can be detected. - Graphical abstract: Crystal structure and {sup 151}Eu-Moessbauer spectra of mixed-valent Eu{sub 3}F{sub 4}S{sub 2}.

  7. Development of Eu{sup 3+} activated monoclinic, perovskite, and garnet compounds in the Gd{sub 2}O{sub 3}–Al{sub 2}O{sub 3} phase diagram as efficient red-emitting phosphors

    SciTech Connect (OSTI)

    Li, Jinkai [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Li, Ji-Guang, E-mail: LI.Jiguang@nims.go.jp [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan); Li, Jing [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan); Liu, Shaohong; Li, Xiaodong; Sun, Xudong [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Sakka, Yoshio [Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan)

    2013-10-15T23:59:59.000Z

    Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9} (GdAM), GdAlO{sub 3} (GdAP), and Gd{sub 3}Al{sub 5}O{sub 12} (GdAG, containing 10 at% of Lu{sup 3+} for lattice stabilization) have been developed in this work as efficient red-emitting phosphors. With coprecipitated carbonate precursors, phase evolution studies found minimum processing temperatures of ?1000, 1100, and 1300 °C for the three phosphors to crystallize as pure phases, respectively. Compared with their yttrium aluminate counterparts, the gadolinium-based phosphors exhibit red-shifted O{sup 2?}–Eu{sup 3+} charge transfer excitation band (CTB) centers due to the lower electronegativity of Gd{sup 3+} and appreciably higher quantum yields of photoluminescence owing to the occurrence of efficient Gd{sup 3+}?Eu{sup 3+}energy transfer. The optimal Eu{sup 3+} contents were determined to be ?7.5 at% for GdAM and 5.0 at% for both GdAP and GdAG, and concentration quenching of luminescence was suggested to be due to exchange interactions. Fluorescence decay analysis found a shorter lifetime for the phosphor powder processed at a higher temperature or with a higher Eu{sup 3+} content, and the underlying mechanism was discussed. Fluorescence lifetimes were also compared between the yttrium and gadolinium phosphor systems for the dominant emissions. - Graphical abstract: Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9} (GdAM), GdAlO{sub 3} (GdAP), and Gd{sub 3}Al{sub 5}O{sub 12} (GdAG, containing 10 at% of Lu{sup 3+} for lattice stabilization) have been developed as efficient red-emitting phosphors. Owing to the Gd{sup 3+} to Eu{sup 3+} energy transfer, improved luminescence is observed for the compounds than their yttrium-based counterparts. Display Omitted - Highlights: • Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9}, GdAlO{sub 3} and (Gd{sub 0.9}Lu{sub 0.1}){sub 3}Al{sub 5}O{sub 12} developed as red phosphors. • Improved red-emissions than their yttrium-based counterparts confirmed. • Efficient Gd{sup 3+}?Eu{sup 3+}energy transfer observed. • Applications in various lighting, display, and scintillation areas expected.

  8. Growth and characterization of Sc-doped EuO thin films

    SciTech Connect (OSTI)

    Altendorf, S. G.; Reisner, A.; Chang, C. F.; Hollmann, N.; Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, 01187 Dresden (Germany)

    2014-02-03T23:59:59.000Z

    The preparation of 3d-transition metal-doped EuO thin films by molecular beam epitaxy is investigated using the example of Sc doping. The Sc-doped EuO samples display a good crystalline structure, despite the relatively small ionic radius of the dopant. The Sc doping leads to an enhancement of the Curie temperature to up to 125?K, remarkably similar to previous observations on lanthanide-doped EuO.

  9. Optical and structural stability of blue SrO:Eu{sup 2+} phosphor

    SciTech Connect (OSTI)

    Komatsu, Keiji, E-mail: Keiji_Komatsu@mst.nagaokaut.ac.jp [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nakamura, Atsushi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Chubu Chelest Co. Ltd., 3-3-3 Hinagahigashi, Yokkaichi, Mie 510-0886 (Japan); Ohshio, Shigeo; Toda, Ikumi; Muramatsu, Hiroyuki; Saitoh, Hidetoshi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan)

    2013-08-15T23:59:59.000Z

    Chemical stability of 6-coodinated SrO is a fundamental problem when this is used for various applications. In this study, optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor were investigated. SrO:Eu{sup 2+} phosphor was synthesized from thermal treatment of SrO:Eu powder located on a single crystalline MgO at 1500° C under reduction atmosphere. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. Our findings prove that obtained 8-coordinated SrO:Eu{sup 2+} possesses relative optical and chemical stabilities in water. - Graphical abstract: Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence in distilled water. Highlights: • We investigated optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor in water. • Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. • We found that the 8-coodrodinated SrO crystal structure changed to SrCO{sub 3} crystal structure after the 5 days immersion. • The obtained SrO:Eu{sup 2+} phosphor possesses high chemical stability under water, compared with commercial (6-coordinated) SrO.

  10. A facile method for the preparation of Eu{sup 2+}-doped nanocrystalline BaFCl

    SciTech Connect (OSTI)

    Wang, Xianglei; Liu, Zhiqiang [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia); Stevens-Kalceff, Marion A. [School of Physics and Electron Microscope Unit, Mark Wainwright Analytical Centre, The University of New South Wales, Sydney, NSW 2052 (Australia); Riesen, Hans, E-mail: h.riesen@adfa.edu.au [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • A facile co-precipitation method for the preparation of Eu{sup 2+}-doped BaFCl. • Reduction of Eu{sup 3+} to Eu{sup 2+} by zinc granular under nitrogen flow. • Photoluminescence and cathodoluminescence spectroscopy of the as-prepared BaFCl:Eu{sup 2+}. • Temperature dependent photoluminescence properties of Eu{sup 2+} ions in BaFCl. - Abstract: A facile method for the preparation of Eu{sup 2+}-doped BaFCl is reported. The method is based on the co-precipitation of aqueous solutions of BaCl{sub 2} and NH{sub 4}F to yield BaFCl. The doping by europium in the 2+ oxidation state is realized by the reduction of Eu{sup 3+} to Eu{sup 2+} employing granular zinc in the BaCl{sub 2} solution under nitrogen. Powder X-ray diffraction and electron microscopy have been used to confirm the BaFCl phase and photoluminescence, in the temperature range of 2.5–290 K, and room-temperature cathodoluminescence spectra have been measured to characterize the Eu{sup 2+} ions in the sample.

  11. Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones: Stability and Improved Photophysical Performance

    E-Print Network [OSTI]

    Moore, Evan G.

    2010-01-01T23:59:59.000Z

    1,2-HOPO) 2 ] ? , which lack a water molecule in the innerEu(III) complexes that lack a water molecule in their inner

  12. OUT OF EGYPT: Globalisation, marginalisation and illegal Muslim migration to the EU

    E-Print Network [OSTI]

    Talani, Leila Simona

    2005-01-01T23:59:59.000Z

    marginalisation and illegal Muslim migration to the EU: Drbased in Cairo working on illegal migration from the Middleunderstand the problem of illegal migration in the context

  13. US-EU-Japan Working Group on Critical Materials

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently20,000 Russian Nuclear Warheads into Fuel forShale_Gas.pdfUS-EU-Japan Working Group on

  14. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23T23:59:59.000Z

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  15. Carbon Sequestration

    SciTech Connect (OSTI)

    None

    2013-05-06T23:59:59.000Z

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  16. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17T23:59:59.000Z

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  17. Europium location in the AlN: Eu green phosphor prepared by a gas-reduction-nitridation route

    SciTech Connect (OSTI)

    Yin Liangjun; Zhu Qiangqiang; Yu Wei; Hao Luyuan; Xu Xin [Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Hu Fengchun [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Hefei 230026 (China); Lee, Ming-Hsien [Department of Physics, Tamkang University, Tamsui, Taipei 251, Taiwan (China)

    2012-03-01T23:59:59.000Z

    Eu doped aluminum nitride phosphors were successfully synthesized by a novel gas-reduction-nitridation route with a reaction temperature of 1400 deg. C and a soaking time of 3 h. The obtained AlN:Eu phosphors were analyzed to elucidate the location of the Eu luminescent center. High-resolution transmission electron microscopy and transmission electron microscopy-energy dispersive spectra proved that Eu was located in the crystal lattice of AlN, then EXAFS revealed that Eu occupied a highly distorted Al site coordinated by four nitrogen at about 2.30-2.40 Angst , and the second nearest neighbors of Eu were 12 Al. This could be confirmed by the first-principles calculations based on the obtained local structure around the Eu luminescence center, where the theoretical absorption spectrum was similar to the experimental excitation spectrum. X-ray appearance near edge structure showed that Eu existed in terms of both Eu{sup 3+} and Eu{sup 2+} ions, which could be related to the limited location space of Eu. High temperature treatment could significantly increase the amount of Eu{sup 2+} by the expansion of the crystal lattice, leading to an increased green luminescence of the obtained AlN:Eu phosphors.

  18. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer, E-mail: pottgen@uni-muenster.de

    2013-07-15T23:59:59.000Z

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with ?{sub eff}=7.87(1) ?{sub B}/Eu atom and ?{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of ?9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  19. Cross Border Trading and Borrowing in the EU ETS A. Denny Ellerman* and Raphael Trotignon**

    E-Print Network [OSTI]

    multi- national trading system, the European Union's CO2 Emissions Trading Scheme (EU ETS) provides** This paper exploits a little used data resource within the central registry of the European Union's Emissions Trading System (EU ETS) to analyze cross border trading and inter-year borrowing during the first trading

  20. building science into EU policy The current status of biofuels in the

    E-Print Network [OSTI]

    easac building science into EU policy The current status of biofuels in the European Union the EASAC Secretariat at secretariat@easac.eu #12;The current status of biofuels in the European Union, their environmental impacts and future prospects easac #12;ii | December 2012 | Sustainable Biofuels EASAC ISBN 978

  1. Price relationships in the EU emissions trading system Julien Chevallier1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Price relationships in the EU emissions trading system Julien Chevallier1 Université Paris Dauphine Abstract The Emissions Trading Scheme (ETS) constrains industrial polluters to buy/sell CO2 the price relationships in the EU emissions trading system. The United Nations Framework Convention

  2. A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme

    E-Print Network [OSTI]

    Watson, Andrew

    A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme Alice Bows-up analysis of including aviation within the EU's Emissions Trading Scheme Alice Bows & Kevin Anderson Tyndall's emissions trading scheme. Results indicate that unless the scheme adopts both an early baseline year

  3. Detailed search S&T key figures reveal China breathing down EU's neck

    E-Print Network [OSTI]

    , revealing stagnation in research and development (R&D) investment in the EU, which Science and Research in the proportion of GDP that it spends on research) was around 0.7 per cent between 2000 and 2003. 'If this trend at the Barcelona European Council to raise R&D spending to 3 per cent of EU GDP by 2010. Yet according

  4. Ris DTU Dec.3 2009WindScanner.eu 1 Ris DTU, Technical University of Denmark

    E-Print Network [OSTI]

    % to the average Danish electricity consumption · Today DK is leading worldwide regarding research and development market · By year 2020 EU's goal is to cover ~20% of the Unions electricity consumption via sustainable of wind power technology · EU Governments wish to maintain the lead Internationally on the wind power

  5. THE EU-AFRICA ENERGY COOPERATION: CHALLENGES AND OPPORTUNITIES FOR PUBLIC AND PRIVATE BUSINESSES

    E-Print Network [OSTI]

    Boyer, Edmond

    multilateral and bilateral energy relationships with Africa. There are three EU-Africa energy initiativesTHE EU-AFRICA ENERGY COOPERATION: CHALLENGES AND OPPORTUNITIES FOR PUBLIC AND PRIVATE BUSINESSESD Candidate Energy security, sustainable development and mutual benefits are the three keywords

  6. Volume 1, Issue 2 2009 Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive

    E-Print Network [OSTI]

    Galis, Frietson

    Volume 1, Issue 2 · 2009 · Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive Organization Caminada, Koen and Goudswaard, Kees (2009) "Effectiveness of Poverty Reduction in the EU: A Descriptive Analysis," Poverty & Public Policy: Vol. 1: Iss. 2, Article 5. Available at: http

  7. NO-assisted molecular-beam epitaxial growth of nitrogen substituted EuO

    SciTech Connect (OSTI)

    Wicks, R. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Altendorf, S. G.; Caspers, C.; Kierspel, H.; Sutarto, R. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Tjeng, L. H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, 01187 Dresden (Germany); Damascelli, A. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Quantum Matter Institute, University of British Columbia, Vancouver, British Columbia V6T 1Z4 (Canada)

    2012-04-16T23:59:59.000Z

    We have investigated a method for substituting oxygen with nitrogen in EuO thin films, which is based on molecular beam epitaxy distillation with NO gas as the oxidizer. By varying the NO gas pressure, we produce crystalline, epitaxial EuO{sub 1-x}N{sub x} films with good control over the films' nitrogen concentration. In situ x-ray photoemission spectroscopy reveals that nitrogen substitution is connected to the formation Eu{sup 3+}4f{sup 6} and a corresponding decrease in the number of Eu{sup 2+}4f{sup 7}, indicating that nitrogen is being incorporated in its 3{sup -} oxidation state. While small amounts of Eu{sup 3+} in over-oxidized Eu{sub 1-{delta}}O thin films lead to a drastic suppression of the ferromagnetism, the formation of Eu{sup 3+} in EuO{sub 1-x}N{sub x} still allows the ferromagnetic phase to exist with an unaffected T{sub c}, thus providing an ideal model system to study the interplay between the magnetic f{sup 7} (J = 7/2) and the non-magnetic f{sup 6} (J = 0) states close to the Fermi level.

  8. Growth and optical properties of partially transparent Eu doped CaF{sub 2} ceramic

    SciTech Connect (OSTI)

    Ghosh, Manoranjan, E-mail: mghosh@barc.gov.in; Sen, Shashwati, E-mail: mghosh@barc.gov.in; Pitale, S. S., E-mail: mghosh@barc.gov.in; Goutam, U. K., E-mail: mghosh@barc.gov.in; Shinde, Seema, E-mail: mghosh@barc.gov.in; Patra, G. D., E-mail: mghosh@barc.gov.in; Gadkari, S. C., E-mail: mghosh@barc.gov.in [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai - 400085 (India)

    2014-04-24T23:59:59.000Z

    Partially transparent ceramic of 2 at.% Eu doped CaF{sub 2} have been grown preferentially towards [111] direction. For this purpose, Eu doped CaF{sub 2} nanoparticles (size?12 nm) obtained by a low temperature solution growth method has been pressed at 1000°C under vacuum. The preferentially grown ceramic shows 15% transparency within the visible range of spectrum. As confirmed by the X-ray diffraction result, the hot pressed ceramic exhibits reduced lattice volume than the nanopowder. It indicates Eu{sup 3+} as the dominant substituting ions at the Ca{sup 2+} sites of CaF{sub 2} lattice in the hot pressed ceramic material. It is corroborated by the photoluminescence results of hot pressed ceramic which shows strong red emission corresponding to Eu{sup 3+} sites. However, photoluminescence of nanopowder exhibits intense peak in the blue region of the spectrum which is characteristics of Eu2+ sites.

  9. Multi-level governance revisited: comparing the strategies of interest representation of legislative regions in EU environmental policy- making. 

    E-Print Network [OSTI]

    Högenauer, Anna-Lena

    2011-07-04T23:59:59.000Z

    Since the 1980s, regions have taken a strong interest in EU policy-making and increasingly demanded representation in the process. This has given rise to the concept of multi-level governance (MLG) in EU policy-making, ...

  10. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. Forenergy and could capture and sequester carbon emissions.

  11. Capturing carbon | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon Released: October 02, 2011 New technology enables molecular-level insight into carbon sequestration Carbon sequestration is a potential solution for reducing greenhouse...

  12. Limited Sectoral Trading between the EU ETS and China

    E-Print Network [OSTI]

    Gavard, Claire

    2013-08-21T23:59:59.000Z

    In the negotiations of the United Nations Framework Convention on Climate Change (UNFCCC), new market mechanisms are proposed to involve Non-Annex I countries in the carbon markets developed by Annex I countries, beyond ...

  13. School of Animal, Rural and Environmental Sciences Management of carbon budgets for severely eroded upland blanket peat bogs impacts

    E-Print Network [OSTI]

    Evans, Paul

    upland blanket peat bogs ­ impacts of restoration Blanket bog is an important carbon sink and an Annex 1 Habitat priority under the EU Habitats Directive, but in the Peak District National Park much suffers peat by Natural England as an important site for studies of vegetation history and peat erosion in the Pennines

  14. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01T23:59:59.000Z

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  15. The Role of Domestic Factors in the Formation of Trade Unions: A Look at Turkey/EU Relations

    E-Print Network [OSTI]

    Youngblood, Kristina Lynne

    2008-08-19T23:59:59.000Z

    studied Turkey and the European Union (EU). Turkey was officially admitted as a candidate country to the EU in 1997. Despite efforts to meet EU demands, Turkey’s admittance has been blocked. As recently as 2007 Turkey was denied membership, while...

  16. EU could go it alone on nuclear fusion plant 29.11.2004 -10:02 CET | By Richard Carter

    E-Print Network [OSTI]

    EU could go it alone on nuclear fusion plant 29.11.2004 - 10:02 CET | By Richard Carter The EU if no agreement can be reached with Japan by the end of the year over where to build the plant, according to EU research ministers. Talks over the world's first nuclear fusion reactor have stalled because Japan

  17. Carbon microtubes

    DOE Patents [OSTI]

    Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2011-06-14T23:59:59.000Z

    A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

  18. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Sequestration Partnership MSU . . . . . . . . . . . . . . . . . . . . . . . Montana State University MVA . . . . . . . . . . . . . . . . . . . . . . . Monitoring,...

  19. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. For

  20. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    cycle plants, possibly with carbon capture and storage (CCS)natural gas plant with carbon capture and storage technology

  1. Methanation of Carbon Dioxide

    E-Print Network [OSTI]

    Goodman, Daniel Jacob

    2013-01-01T23:59:59.000Z

    gas plant with carbon capture and storage technology werewith carbon capture and storage (CCS) technology, to replace

  2. Carbon Additionality: Discussion Paper

    E-Print Network [OSTI]

    Carbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 CarbonFix Standard (CFS) 28 Climate, Community and Biodiversity Standard (CCBS) 28 Forest Carbon Standard (FCS) 28

  3. Preparation and fluorescence property of red-emitting Eu{sup 3+}-activated amorphous calcium silicate phosphor

    SciTech Connect (OSTI)

    Kojima, Yoshiyuki, E-mail: ykojima@chem.cst.nihon-u.ac.jp [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)] [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan); Kamei, Shinnosuke; Nishimiya, Nobuyuki [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)] [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)

    2010-02-15T23:59:59.000Z

    This paper describes the energy efficient synthesis of a red-emitting Eu{sup 3+}-activated amorphous calcium silicate phosphor produced by heating a Eu{sup 3+}-activated calcium silicate hydrate phosphor. Concentration quenching of the Eu{sup 3+}-activated calcium silicate hydrate phosphor was not observed and the emission intensity did not decrease up to a Eu/(Ca+Eu) atomic ratio of 0.46. Heating of the Eu{sup 3+}-activated calcium silicate hydrate (Eu/(Ca+Eu) atomic ratio = 0.32) phosphor produced an amorphous Eu{sup 3+}-activated calcium silicate phosphor, which had a maximum emission intensity at 870 {sup o}C and emitted in the red under near-ultraviolet irradiation (395 nm). The emission intensity of the Eu{sup 3+}-activated amorphous calcium silicate phosphor was about half that of a commercial BaMgAl{sub 10}O{sub 17}:Eu{sup 2+} phosphor, and shows great potential for application in white light-emitting diodes.

  4. Synthesis and determination of the structural and optical characteristics of cBN micropowder with Eu{sup 3+} ions

    SciTech Connect (OSTI)

    Leonchik, S. V., E-mail: Leonchik@physics.by; Karotki, A. V. [National Academy of Sciences of Belarus, Scientific-Practical Materials Research Center (Belarus)] [National Academy of Sciences of Belarus, Scientific-Practical Materials Research Center (Belarus)

    2013-10-15T23:59:59.000Z

    Cubic boron-nitride micropowder with Eu{sup 3+} ions (cBN:Eu) is synthesized under conditions of high pressures and temperatures. The structural, morphological, chemical, and optical characteristics of the cBN:Eu micropowder are studied using X-ray diffraction, energy-dispersive X-ray spectral microanalysis, photoluminescence, and optical transmission methods. It is found that the cBN:Eu lattice parameter is {approx}3.615 A. The intense red luminescence of the cBN:Eu micropowder (red glow), measured in the visible region of the spectrum in the range from 550 to 750 nm, is attributed to intracenter 4f-electron transitions of the Eu{sup 3+} ions. The possible nature of the cBN:Eu micropowder luminescence is discussed.

  5. Carbon Trading, Carbon Taxes and Social Discounting

    E-Print Network [OSTI]

    Weiblen, George D

    Carbon Trading, Carbon Taxes and Social Discounting Elisa Belfiori belf0018@umn.edu University of Minnesota Abstract This paper considers the optimal design of policies to carbon emissions in an economy, such as price or quantity controls on the net emissions of carbon, are insufficient to achieve the social

  6. Occupancy and site distribution of europium in barium magnesium aluminate Eu Mossbauer spectroscopy

    E-Print Network [OSTI]

    Boolchand, Punit

    Occupancy and site distribution of europium in barium magnesium aluminate by 151 Eu Mo¨ssbauer Mo¨ssbauer spectroscopy. Analysis of the Mo¨ssbauer line shapes reveals a pentamodal or higher site

  7. The EU’s Emissions Trading Scheme: A Proto-Type Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  8. The EU’s Emissions Trading Scheme: A Prototype Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  9. Allocation and competitiveness in the EU emissions trading scheme: policy overview

    E-Print Network [OSTI]

    Grubb, Michael; Neuhoff, Karsten

    The European emissions trading scheme (EU ETS) has an efficient and effective market design that risks being undermined by three interrelated problems: the approach to allocation; the absence of a credible commitment to post-2012 continuation...

  10. The EU’s CAP, the Doha Round and Developing Countries

    E-Print Network [OSTI]

    Halderman, Michael; Nelson, Michael

    2004-01-01T23:59:59.000Z

    Development IFPRI IGC ILRI IPSA LDC LEI LFA LLPs MGQ MS MTRDev.ing - America Dev.ing LDC EU Candidate Accession Becauseparticularly important to LDC trade including bananas,

  11. CO2 Abatement in the UK Power Sector: Evidence from the EU ETS Trial Period

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    This paper provides an empirical assessment of CO2 emissions abatement in the UK power sector during the trial period of the EU ETS. Using an econometrically estimated model of fuel switching, it separates the impacts of ...

  12. Manufacturing industry challenges and responses to EU, California, and other product-targeted environmental regulations

    E-Print Network [OSTI]

    Kirschner, Michael

    2008-01-01T23:59:59.000Z

    directive (2002/96/EC, “WEEE” ) the EU expanded its scope ofe-waste”) regulation like WEEE, decided to take matters intake its cues from RoHS and WEEE. While industry lobbying

  13. Compliance Behavior in the EU-ETS: Cross Border Trading, Banking and Borrowing

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    This paper exploits a little used data resource within the central registry of the European Union’s Emissions Trading System (EU ETS) to analyze cross border flows of allowances for compliance purposes during the first ...

  14. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    the treatment of waste from industries by biomethanation), to in- crease the price for the electricity (the of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment

  15. STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu BER DIE STYRIAN ACADEMY

    E-Print Network [OSTI]

    STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu #12;ÜBER DIE STYRIAN ACADEMY Die STYRIAN ACADEMY ist eine europäische Aus- und Weiterbildungsplattform mit Standort Steiermark. Die STYRIAN ACADEMY 2010/2011 ist dem europäischen Zukunftsthema nachhaltige Energiesysteme gewidmet. Die

  16. -News Home Help EU reiterates warning to Japan over nuclear project

    E-Print Network [OSTI]

    reactor without Japanese support, to end a standoff with Tokyo about who will host the project. news web and Russia back France's bid for it to be based in Cadarache, southern France. news web sites EU science

  17. Print this article Close This Window EU OKs India joining ITER nuclear reactor project

    E-Print Network [OSTI]

    Print this article Close This Window EU OKs India joining ITER nuclear reactor project Fri Dec 2 trademarks and trademarks of the Reuters group of companies around the world. Close This Window 12/2/05 4

  18. EU Agri-Environmental Payments: Appropriate Policy or Protectionism in Disguise?

    E-Print Network [OSTI]

    Glebe, Thilo

    2005-01-01T23:59:59.000Z

    1 Theory of agri-environmental policy Dr. Thilo Glebe EUto look at the agri-environmental policy from a theoreticalto the EU agri- environmental policy I want to ask therefore

  19. Photoluminescence properties of Tb-Eu-Mn-codoped fluoroborate glasses under ?-irradiation

    SciTech Connect (OSTI)

    Hari Babu, B.; Ravi Kanth Kumar, V. V. [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)] [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)

    2013-09-28T23:59:59.000Z

    We report here an energy transfer from Tb{sup 3+} to Eu{sup 3+}, Mn{sup 2+} and Eu{sup 2+} to Tb{sup 3+} and Mn{sup 2+} for an un-irradiated and ?-irradiated B{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-Na{sub 2}O-SrF{sub 2} glass samples, respectively. The blue emission from Eu{sup 2+} ions as well as green and red emission from Tb{sup 3+}, Eu{sup 3+}, and Mn{sup 2+} ions will contribute to the generation of white light while excited at 339 nm using a xenon lamp. Furthermore, the chromaticity color coordinates, correlated color temperature, and quantum efficiency parameters are calculated for all the glass samples, and their relative variations with respect to ?-irradiation dose are presented.

  20. Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones: Stability and Improved Photophysical Performance

    E-Print Network [OSTI]

    Moore, Evan G.

    2010-01-01T23:59:59.000Z

    In particular, terbium and europium are of primary interestand similar size as the europium cation (4f 6 ), but with anof ? Eu , the overall europium quantum yield, will also

  1. EU Blanket Design Activities and Neutronics Support Efforts

    SciTech Connect (OSTI)

    Fischer, U. [Forschungszentrum Karlsruhe (Germany); Batistoni, P. [ENEA Fusion Division (Italy); Boccaccini, L.V. [Forschungszentrum Karlsruhe (Germany); Giancarli, L. [CEA Saclay (France); Hermsmeyer, S. [Forschungszentrum Karlsruhe (Germany); Poitevin, Y. [CEA Saclay (France)

    2005-05-15T23:59:59.000Z

    An overview is provided of the design activities and the related neutronics support efforts conducted in the European Union for the development of breeder blankets for future fusion power reactors. The EU fusion programme considers two blanket lines, the Helium-Cooled Pebble Bed (HCPB) blanket with Lithium ceramics pebbles (Li{sub 4}SiO{sub 4} or Li{sub 2}TiO{sub 3}) as breeder and beryllium pebbles as neutron multiplier, and the Helium-Cooled Lithium-Lead (HCLL) blanket with the Pb-Li eutectic alloy as breeder and neutron multiplier. The blanket design and the related R and D efforts are based on the use of the same coolant and the same modular blanket structure to minimise the development costs as much as possible. The neutronic support efforts include design analyses for the layout and optimization of the modular HCPB/HCLL blankets based on detailed three-dimensional Monte Carlo calculations as well as underlying neutronics activities conducted in the frame of the European Fusion and Activation File (EFF/EAF) projects to develop qualified nuclear data and computational tools for reliable neutronics design calculations.

  2. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  3. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Li, M. Daskin. 2009. Carbon Footprint and the Management ofThe Importance of Carbon Footprint Estimation Boundaries.Carbon accounting and carbon footprint - more than just

  4. Management of waste electrical and electronic equipment in two EU countries: A comparison

    SciTech Connect (OSTI)

    Torretta, Vincenzo, E-mail: vincenzo.torretta@uninsubria.it [Department of Science and High Technology, Insubria University of Varese, Via G.B. Vico 46, I-21100 Varese (Italy); Ragazzi, Marco [Department of Civil and Environmental Engineering, University of Trento, Via Mesiano 77, I-38123 Trento (Italy); Istrate, Irina Aura [Department of Energy Production and Use, Politehnica University of Bucharest, Splaiul Independentei 313, 060042 Bucharest (Romania); Rada, Elena Cristina [Department of Civil and Environmental Engineering, University of Trento, Via Mesiano 77, I-38123 Trento (Italy)

    2013-01-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Review on data regarding WEEE management in Italy and in Romania. Black-Right-Pointing-Pointer Problems that countries that will enter in the EU will have to solve facing with the WEEE management. Black-Right-Pointing-Pointer Pilot experiences useful for the awareness campaign of the population. - Abstract: The paper presents some data regarding waste electrical and electronic (WEEE) management in one of the founding countries of the EU, Italy, and in a recent entry into the EU, Romania. The aim of this research was to analyze some problems that countries entering the EU will have to solve with respect to WEEE management. The experiences of Italy and Romania could provide an interesting reference point. The strengths and weaknesses that the two EU countries have encountered can be used in order to give a more rational plan for other countries. In Italy the increase of WEEE collection was achieved in parallel with the increase of the efficiency of selective Municipal Solid Waste collection. In Romania, pilot experiences were useful to increase the awareness of the population. The different interests of the two populations towards recyclable waste led to a different scenario: in Romania all types of WEEE have been collected since its entrance into the EU; in Italy the 'interest' in recycling is typically related to large household appliances, with a secondary role of lighting equipment.

  5. Illegal Logging Gives EU Massive Eco-Headache With tropical rainforests continuing to disappear at an alarming rate, the EU is partially to

    E-Print Network [OSTI]

    17.04.2008 Illegal Logging Gives EU Massive Eco-Headache With tropical rainforests continuing. The problem of illegal logging is particularly acute in Indonesia, allegedly the world's third largest gases and global warming, rising demand for palm oil has resulted in local companies burning woods

  6. CALIFORNIA CARBON SEQUESTRATION THROUGH

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION CARBON SEQUESTRATION THROUGH CHANGES IN LAND USE IN WASHINGTON. Carbon Sequestration Through Changes in Land Use in Washington: Costs and Opportunities. California for Terrestrial Carbon Sequestration in Oregon. Report to Winrock International. #12;ii #12;iii Preface

  7. Photophysics of carbon nanotubes

    E-Print Network [OSTI]

    Samsonidze, Georgii G

    2007-01-01T23:59:59.000Z

    This thesis reviews the recent advances made in optical studies of single-wall carbon nanotubes. Studying the electronic and vibrational properties of carbon nanotubes, we find that carbon nanotubes less than 1 nm in ...

  8. Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production

    E-Print Network [OSTI]

    Narasayya, Vivek

    #12;Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward Zero Carbon Energy Production Toward

  9. Carbon Code Requirements for voluntary carbon sequestration projects

    E-Print Network [OSTI]

    Woodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July trademark 10 3. Carbon sequestration 11 3.1 Units of carbon calculation 11 3.2 Carbon baseline 11 3.3 Carbon leakage 12 3.4 Project carbon sequestration 12 3.5 Net carbon sequestration 13 4. Environmental quality 14

  10. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B. (16716 Martincoit Rd., Poway, CA 92064)

    1993-01-01T23:59:59.000Z

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  11. Carbon Fiber Technology Facility

    Broader source: Energy.gov (indexed) [DOE]

    The Carbon Fiber Technology Facility is relevant in proving the scale- up of low-cost carbon fiber precursor materials and advanced manufacturing technologies * Significant...

  12. Motivating carbon dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Motivating carbon dioxide Motivating carbon dioxide Released: April 17, 2013 Scientists show what it takes to get the potential fuel feedstock to a reactive spot on a model...

  13. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08T23:59:59.000Z

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  14. Aryl Bridged 1-Hydroxypyridin-2-one: Effect of the Bridge on the Eu(III) Sensitization Process

    E-Print Network [OSTI]

    D'Aleo, Anthony

    2010-01-01T23:59:59.000Z

    kinetic parameters for the europium emission were completed.water molecule bound to the europium cation while for [Eu(Lsensitization of the europium ion. Keywords: europium,

  15. EuCuOSe: Crystal structure refinement, electrical and magnetic properties

    SciTech Connect (OSTI)

    Llanos, Jaime [Departamento de Quimica, Universidad Catolica del Norte, Avda. Angamos 0610, Casilla 1280, Antofagasta (Chile)], E-mail: jllanos@ucn.cl; Cortes, Rodrigo; Sanchez, Victor [Departamento de Quimica, Universidad Catolica del Norte, Avda. Angamos 0610, Casilla 1280, Antofagasta (Chile)

    2008-02-05T23:59:59.000Z

    The europium copper oxyselenide EuCuOSe has been prepared by reacting Eu, CuO and Se in the ratio 1:1:1 at 1123 K for a period of 10 days in sealed quartz ampoule. The structure has been determined by single-crystal X-ray methods. The compound crystallizes tetragonal in the space group P4/nmm (no. 129) with two formula units in the cell with dimensions a = 393.65(8) pm and c = 871.80(17) pm. The structure is composed of {sup 2}{sub {infinity}}{l_brace}[(Eu{sup 3+})(O{sup 2-}){sub 4/4}(Se{sup 2-}){sub 4/4}]{sup -}{r_brace} double layers separated by copper atoms, which are tetrahedrally coordinated to Se{sup 2-} anions. According to the resistivity measurements, EuCuOSe is a semiconductor. The magnetic susceptibility data shows the typical non-Curie-Weiss behavior of the {sup 7}F{sub J} states of Eu in the 4f{sup 6} configuration.

  16. Chemical Feature of Eu abundance in the Draco dwarf spheroidal galaxy

    E-Print Network [OSTI]

    Tsujimoto, Takuji; Shigeyama, Toshikazu; Aoki, Wako

    2015-01-01T23:59:59.000Z

    Chemical abundance of r-process elements in nearby dwarf spheroidal (dSph) galaxies is a powerful tool to probe the site of r-process since their small-mass scale can sort out individual events producing r-process elements. A merger of binary neutron stars is a promising candidate of this site. In faint, or less massive dSph galaxies such as the Draco, a few binary neutron star mergers are expected to have occurred at most over the whole past. We have measured chemical abundances including Eu and Ba of three red giants in the Draco dSph by Subaru/HDS observation. The Eu detection for one star with [Fe/H]=-1.45 confirms a broadly constant [Eu/H] of ~-1.3 for stars with [Fe/H]>-2. This feature is shared by other dSphs with similar masses, i.e., the Sculptor and the Carina, and suggests that neutron star merger is the origin of r-process elements in terms of its rarity. In addition, two very metal-poor stars with [Fe/H]=-2.12 and -2.51 are found to exhibit very low Eu abundances such as [Eu/H]<-2 with an impl...

  17. A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection

    SciTech Connect (OSTI)

    Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

    2014-03-14T23:59:59.000Z

    We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

  18. Optical studies on Eu{sup 3+} doped boro-tellurite glasses

    SciTech Connect (OSTI)

    Maheshvaran, K.; Marimuthu, K. [Department of Physics, Gandhigram Rural Institute - Deemed University, Gandhigram - 624 302 (India)

    2012-06-05T23:59:59.000Z

    Eu{sup 3+} doped boro-tellurite glasses with the chemical composition (39-x)B{sub 2}O{sub 3}+30TeO{sub 2}+15MgO+15K{sub 2}O +xEu{sub 2}O{sub 3} (where x = 0.01, 0.1, 1, 2 and 3 wt%) have been prepared by following conventional melt quenching technique. Spectroscopic properties of the Eu{sup 3+} doped boro-tellurite glasses have been studied by recording the optical absorption and luminescence measurements. Through the optical absorption spectra, bonding parameters ({beta}-bar, {delta}) have been calculated to identify the ionic/covalent nature of the glasses. Judd-Ofelt (JO) analysis have been carried out using the luminescence spectra. The JO parameters ({Omega}{sub {lambda}}= 2, 4 and 6) were used to calculate the radiative properties for the {sup 5}D{sub 0}{yields}{sup 7}F{sub J} (J = 1, 2, 3 and 4) emission transitions of the Eu{sup 3+} ions. The change in optical properties with the variation of Eu{sup 3+} ion concentration have been studied and discussed with similar studies.

  19. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06T23:59:59.000Z

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  20. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1997-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  1. New ternary phosphides and arsenides. Syntheses, crystal structures, physical properties of Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}

    SciTech Connect (OSTI)

    Wang, Jian [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Xia, Sheng-Qing, E-mail: shqxia@sdu.edu.cn [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Tao, Xu-Tang [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Schäfer, Marion C. [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bobev, Svilen, E-mail: bobev@udel.edu [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States)

    2013-09-15T23:59:59.000Z

    Three new europium pnictides Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3} have been synthesized and their structures were determined by single-crystal X-ray diffraction. Eu{sub 2}ZnP{sub 2} is isotypic with Yb{sub 2}CdSb{sub 2} (Cmc2{sub 1} (No. 36); cell parameters a=4.1777(7) Å, b=15.925(3) Å, c=7.3008(12) Å), while the latter two compounds crystallize with the Ba{sub 2}Cd{sub 2}Sb{sub 3} structure type (C2/m (No. 12); cell parameters a=15.653(5)/16.402(1) Å, b=4.127(1)/4.445(4) Å, c=11.552(4)/12.311(1) Å and ?=126.647(4)/126.515(7)° for Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}, respectively). Magnetic susceptibility measurements in the interval 5–300 K confirm paramagnetic behavior and effective magnetic moments characteristic of Eu{sup 2+} ([Xe] 4f{sup 7}) ground states. Temperature-dependent electrical conductivity measurements also prove that Eu{sub 2}Cd{sub 2}As{sub 3} is a semiconducting compound with a narrow band gap of 0.059 eV below 100 K. According to TG/DSC analyses, Eu{sub 2}Cd{sub 2}As{sub 3} starts to decompose at about 950 K. - Graphical abstract: A polyhedral view of the crystal structure of new pnictides Eu{sub 2}T{sub 2}Pn{sub 3} (T=Zn or Cd; Pn=P or As). Display Omitted - Highlights: • Three new ternary pnictide Zintl compounds, Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}, have been synthesized and characterized. • The europium cations are divalent and ferromagnetically coupled in both Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}. • Eu{sub 2}Cd{sub 2}As{sub 3} has a very small band gap of 0.06 eV and starts to decompose over 950 K.

  2. Climate for Collaboration: Analysis of US and EU Lessons and Opportunities in Energy and Climate Policy

    SciTech Connect (OSTI)

    De Vita, A.; de Connick, H.; McLaren, J.; Cochran, J.

    2009-11-01T23:59:59.000Z

    A deepening of cooperation between the United States and the European Union requires mutual trust, and understanding of current policies, challenges and successes. Through providing such understanding among policymakers, industry and other stakeholders in both economies, opportunities for transatlantic cooperation on climate change and energy policy emerge. This paper sets out by discussing the environmental, legislative, and economic contexts of the EU and US as related to climate. This context is essential to understanding how cap-and-trade, renewable energy and sustainable transportation policies have taken shape in the EU and the US, as described in Chapter 3.1. For each of these policies, a barrier analysis and discussion is provided. Chapter 4 builds off this improved understanding to listobservations and possible lessons learned. The paper concludes with recommendations on topics where EU and US interests align, and where further cooperation could prove beneficial.

  3. Hetero-epitaxial EuO interfaces studied by analytic electron microscopy

    SciTech Connect (OSTI)

    Mundy, Julia A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Hodash, Daniel; Melville, Alexander; Held, Rainer [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Mairoser, Thomas; Schmehl, Andreas [Zentrum für Elektronische Korrelationen und Magnetismus, Universität Augsburg, Universitätsstraße 1, D-86159 Augsburg (Germany); Muller, David A.; Kourkoutis, Lena F. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

    2014-03-03T23:59:59.000Z

    With nearly complete spin polarization, the ferromagnetic semiconductor europium monoxide could enable next-generation spintronic devices by providing efficient ohmic spin injection into silicon. Spin injection is greatly affected by the quality of the interface between the injector and silicon. Here, we use atomic-resolution scanning transmission electron microscopy in conjunction with electron energy loss spectroscopy to directly image and chemically characterize a series of EuO|Si and EuO|YAlO{sub 3} interfaces fabricated using different growth conditions. We identify the presence of europium silicides and regions of disorder at the EuO|Si interfaces, imperfections that could significantly reduce spin injection efficiencies via spin-flip scattering.

  4. Optical properties of Eu{sup 2+} doped antipervoskite fluoride single crystals

    SciTech Connect (OSTI)

    Daniel, D. Joseph; Ramasamy, P. [Centre for Crystal Growth, SSN College of Engineering, kalavakkam, Tamilnadu- 603 110 (India); Nithya, R. [Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamilnadu - 603 102 (India); Madhusoodanan, U. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamilnadu - 603 102 (India)

    2013-02-05T23:59:59.000Z

    Single crystals of pure and Eu{sup 2+} doped LiBaF{sub 3} have been grown from melt by using a vertical Bridgman-Stockbarger method. Absorption and luminescence spectra for pure and rare-earth-doped LiBaF{sub 3} were studied. At ambient conditions the photoluminescence spectra consisted of sharp lines peaked at {approx}359 nm attributed to the {sup 6}P7/2{yields}{sup 8}S7/2 transitions in the 4f{sub 7} electronic configuration of Eu{sup 2+} and a broad band extending between 370 and 450 nm attributed to Eu{sup 2+} trapped exciton recombination. The effect of {sup 60}Co gamma irradiation has also been investigated.

  5. Research Summary Carbon Additionality

    E-Print Network [OSTI]

    of the quality assurance of emissions reduction and carbon sequestration activities, but remains a source of muchResearch Summary Carbon Additionality Additionality is widely considered to be a core aspect controversy in national carbon accounting, international regulatory frameworks and carbon markets. A review

  6. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10T23:59:59.000Z

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  7. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  8. The Woodland Carbon Code

    E-Print Network [OSTI]

    The Woodland Carbon Code While society must continue to make every effort to reduce greenhouse gas a role by removing carbon dioxide from the atmosphere. The potential of woodlands to soak up carbon to help compensate for their carbon emissions. But before investing in such projects, people want to know

  9. Mesoporous carbon materials

    SciTech Connect (OSTI)

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09T23:59:59.000Z

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  10. EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel-rules-won-t-r385258.htm 1 of 2 1/16/2008 12:32 PM

    E-Print Network [OSTI]

    EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel promises new biofuel rules won't harm the environment © AP 2008-01-14 16:21:49 - BRUSSELS, Belgium (AP) - The European Union promised Monday that its new push to promote biofuels will try to prevent harming

  11. Trapping processes in CaS:Eu{sup 2+},Tm{sup 3+}

    SciTech Connect (OSTI)

    Jia, Dongdong [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China)] [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China); Jia, Weiyi [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico)] [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico); Evans, D. R. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States); Dennis, W. M. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States); Liu, Huimin [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico)] [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico); Zhu, Jing [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China)] [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China); Yen, W. M. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)

    2000-09-15T23:59:59.000Z

    CaS:Eu{sup 2+},Tm{sup 3+} is a persistent red phosphor. Thermoluminescence was measured under different excitation and thermal treatment conditions. The results reveal that the charge defects, created by substituting Tm{sup 3+} for Ca{sup 2+}, serve as hole traps for the afterglow at room temperature. Tm{sup 3+} plays the role of deep electron trapping centers, capturing electrons either through the conduction band or directly from the excited Eu{sup 2+} ions. These two processes, in which two different sites of Tm{sup 3+} are involved, correspond to two traps with different depths. (c) 2000 American Institute of Physics.

  12. Temperature dependent band offsets in PbSe/PbEuSe quantum well heterostructures

    SciTech Connect (OSTI)

    Simma, M.; Bauer, G.; Springholz, G. [Institut fuer Halbleiter und Festkoerperphysik, Johannes Kepler Universitaet, A-4040 Linz (Austria)

    2012-10-22T23:59:59.000Z

    The band offsets of PbSe/Pb{sub 1-x}Eu{sub x}Se multi-quantum wells grown by molecular beam epitaxy are determined as a function of temperature and europium content using temperature-modulated differential transmission spectroscopy. The confined quantum well states in the valence and conduction bands are analyzed using a k{center_dot}p model with envelope function approximation. From the fit of the experimental data, the normalized conduction band offset is determined as 0.45{+-}0.15 of the band gap difference, independently of Eu content up to 14% and temperature from 20 to 300 K.

  13. If it's Broken, Don't Fix it: The Government of the Euro area in the EU "Reform Treaty"

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    If it's Broken, Don't Fix it: The Government of the Euro area in the EU "Reform Treaty" N° 2007: The Government of the Euro area in the EU "Reform Treaty" Éloi Laurent OFCE (Sciences-po Center for Economic failure. This paper examines the reforms of the "economic governance" of the euro area proposed

  14. Japan, EU adamant about their proposals to host ITER, put off negotiations to next year; Joint construction plan involving Japan,

    E-Print Network [OSTI]

    Japan, EU adamant about their proposals to host ITER, put off negotiations to next year; Joint construction plan involving Japan, U.S. South Korea also emerging NIHON KEIZAI, December 20, 2004 Japan are likely to enter a crucial stage early in the next year. In addition to Japan and the EU, the United

  15. Soil metagenomics and carbon cycling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and carbon cycling Establishing a foundational understanding of the microbial and ecosystem factors that control carbon cycling to improve climate modeling and carbon...

  16. Carbon Nanostructure-Based Sensors

    E-Print Network [OSTI]

    Sarkar, Tapan

    2012-01-01T23:59:59.000Z

    Control of Single-Walled Carbon Nanotube Functionalization.M. S. Characterizing carbon nanotube samples with resonancewith a Single-Walled Carbon Nanotube Capacitor. Science

  17. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  18. The Australian terrestrial carbon budget

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    Australian terrestrial carbon budget Open Access 3 , G. P.The Australian terrestrial carbon budget Luo, C. , Mahowald,terrestrial carbon budget Richards, G. P. , Borough, C. ,

  19. Forschung und EU-Hochschulbro, Technologietransfer Anschrift: Brhlstr. 27 30169 Hannover Tel.: (0511) 762 4091 Fax: 3009 dezernat4@zuv.uni-hannover.de

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    for a Greener Agriculture (ERA-Net ICT-AGRI) 12 6.1.2. EU/BMELV: Transnationale Projekte im Bereich Bioenergie 10. Agrarwissenschaften 17 10.1.1. EU/BMELV: Transnationale Projekte im Bereich "Agricultural Umweltschutzprojekten 17 11.1.2. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-Net ICT-AGRI) 18 11.1.3. EU

  20. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    2012-04-10T23:59:59.000Z

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  1. Fact sheet EU poll illegal timber trade Illegal logging and related timber trade

    E-Print Network [OSTI]

    March 2009 Fact sheet EU poll illegal timber trade Illegal logging and related timber trade Illegal level is needed to halt the trade in illegal timber and timber products on the European market trade. It has clarified obligations for all companies in the supply chain to prove the legality

  2. Water Research 39 (2005) 239247 Biosorption of La, Eu and Yb using Sargassum biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Water Research 39 (2005) 239­247 Biosorption of La, Eu and Yb using Sargassum biomass Vivian Diniz-loaded biomass was studied. The ion exchange sorption mechanism was confirmed by the release of calcium ions from the biomass that matched the total number of metal and protons removed from the solution. The metal binding

  3. Influence of high magnetic field on the luminescence of Eu{sup 3+}-doped glass ceramics

    SciTech Connect (OSTI)

    Jiang, Wei; Chen, Weibo; Chen, Ping; Xu, Beibei; Zheng, Shuhong; Guo, Qiangbing; Liu, Xiaofeng, E-mail: xfliu@zju.edu.cn, E-mail: qjr@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China); Zhang, Junpei; Han, Junbo [Wuhan National High Magnetic field Center, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Qiu, Jianrong, E-mail: xfliu@zju.edu.cn, E-mail: qjr@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China); State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, Guangdong 510640 (China)

    2014-09-28T23:59:59.000Z

    Rare earth (RE) doped materials have been widely exploited as the intriguing electronic configuration of RE ions offers diverse functionalities from optics to magnetism. However, the coupling of magnetism with photoluminescence (PL) in such materials has been rarely reported in spite of its fundamental significance. In the present paper, the effect of high pulsed magnetic field on the photoluminescence intensity of Eu{sup 3+}-doped nano-glass-ceramics has been investigated. In our experiment, Eu-doped oxyfluoride glass and glass ceramic were prepared by the conventional melt-quenching process and controlled heat treatment. The results demonstrate that the integrated PL intensity of Eu{sup 3+} decreases with the enhancement of magnetic field, which can be interpreted in terms of cooperation effect of Zeeman splitting and magnetic field induced change in site symmetry. Furthermore, as a result of Zeeman splitting, both blue and red shift in the emission peaks of Eu{sup 3+} can be observed, and this effect becomes more prominent with the increase of magnetic field. Possible mechanisms associated with the observed magneto-optical behaviors are suggested. The results of the present paper may open a new gate for modulation of luminescence by magnetic field and remote optical detection of magnetic field.

  4. GEE Workshop, Mnchen, 6 Juni 2008 The EU Policy Framework for the Promotion

    E-Print Network [OSTI]

    production but also distribution and end-use pose enormous challenges ­ Hydrogen and fuel cells are still to hydrogen and fuel cell development ­ Regional dimension/cluster policy We therefore address the following questions ­ To what extent is the current EU policy framework conducive to hydrogen and fuel cell

  5. Eos,Vol. 85, No. 46, 16 November 2004 use among European Union (EU) member

    E-Print Network [OSTI]

    Wang, Chunzai

    Eos,Vol. 85, No. 46, 16 November 2004 use among European Union (EU) member states applications of the atlas contents should have no problem doing so. The price of the atlas is a hefty $310 the substantial amount of information contained within the atlas,the price represents a good value,and university

  6. TRANSFORMING THE EUROPEAN ENERGY SYSTEM: MEMBER STATES' PROSPECTS WITHIN THE EU FRAMEWORK

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and energy policy; National Renewable Action Plans (NREAPs); environmental federalism; mitigation scenarios energies in the official National Renewable Energy Action Plans (NREAPs) (EEA, 2012). In 2011, the EuropeanTRANSFORMING THE EUROPEAN ENERGY SYSTEM: MEMBER STATES' PROSPECTS WITHIN THE EU FRAMEWORK BRIGITTE

  7. HEAT ROADMAP EUROPE 2050 SECOND PRE-STUDY FOR THE EU27

    E-Print Network [OSTI]

    Kolaei, Alireza Rezania

    HEAT ROADMAP EUROPE 2050 SECOND PRE-STUDY FOR THE EU27 By Aalborg University David Connolly Brian in various reports and studies, i.e. in the Energy Efficiency of the Energy Roadmap 2050 published) of the Energy Roadmap are over-ambitious as regards the reduction of final heat demands in buildings (72

  8. The knowledge economy in Europe A report prepared for the 2007 EU Spring Council

    E-Print Network [OSTI]

    Chen-Burger, Yun-Heh (Jessica)

    The knowledge economy in Europe A report prepared for the 2007 EU Spring Council Prepared by Ian. Knowledge industry employment in Europe 6 4. Moving towards a knowledge based economy in Europe 7 5 10 8. Investing in knowledge 11 9. Next steps 23 Sponsors for the knowledge economy programme include

  9. EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006

    E-Print Network [OSTI]

    EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006 European Union nations on Monday endorsed a pact to build an experimental fusion reactor with the aim, China, Japan, South Korea and Russia - also aim to ratify the International Thermonuclear Experimental

  10. -News Home Help Chirac defends planned EU arms sales to China to nervous Japan

    E-Print Network [OSTI]

    -News Home Help Chirac defends planned EU arms sales to China to nervous Japan Sun Mar 27,11:33 AM Union ( - ) arms embargo on China, telling a nervous Japan the move would not entail transfers ban, acknowledged that Japan was worried about arms sales to its neighbor and growing rival but said

  11. ASTRONOMY TO INSPIRE AND EDUCATE YOUNG CHILDREN EU-UNAWE Lorentz Center Workshop

    E-Print Network [OSTI]

    Galis, Frietson

    Africa (provisional title) (10 min) Right Honorable Dr. E. N. N. Ngcobo MP, Chair, South African between Europe and Africa Prof. T Riera, MEP, EU Parliamentary Committee: Industry, Research and Energy: Astronomy for Development, South Africa Reaching disadvantaged children using astronomy and space (5 min

  12. Summary of the 1st EuCAN Workshop "Universities meet laboratories (ULA2014)"

    E-Print Network [OSTI]

    Aleksan, R; Appleby, R; Arduini, G; Assmann, R; Aulenbacher, K; Bambade, P; Barletta, W; Boine-Frankenheim, O; Burrows, P; Faus-Golfe, A; Guiducci, S; Herr, W; Pavlovi?, M; Podlech, H; Rinolfi, L; Rivkin, L; Russenschuck, S; Schleiff, E; Seidel, M; Stoecker, H; Stroth, J; Valloni, A; Ziemann, V

    2014-01-01T23:59:59.000Z

    The 1st EuCAN workshop ULA2014 illuminated the interplay of universities and laboratories. The workshop took place at the Faculty of Applied Physics of the Goethe-University Frankfurt from 30 September to 1 October 2014. The 40 participants (see Fig. 1) mainly came from European countries.

  13. EU Gives Japan Until End-June to Accept Nuclear-Project Offer

    E-Print Network [OSTI]

    must begin this year. The EU made the partnership offer in November to break a deadlock in which China of negotiations.'' ITER, which would generate ``clean'' energy by fusing together light atoms such as hydrogen reach an agreement. ``Only on a political level is it possible to get a solution quickly,'' he said

  14. EU in push for support on nuclear fusion reactor September 26, 2004

    E-Print Network [OSTI]

    to obtain power through nuclear fusion, a clean energy source. But views are split on where the ITER reactor, estimated to cost around $10 billion over 30 years, should be based. While the EU, backed by China yesterday. Diplomats said the US resistance seemed to be political rather than based on scientific grounds

  15. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries-technical barriers for the implementation and development of biogas from centralised co-digestion in the studied Assessment of a Centralised co-digestion Plant hypothetically sited in Aveyron, Midi Pyrenees France June

  16. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    is to assess the economic, environmental and energy aspects of the biogas production by centralised co-digestion and processed in digesting tanks for 15 days. During this period the biogas emerges and is collected. After of Biogas for Electricity and Heat Production in EU countries. Economic and Environmental Benefits of Biogas

  17. Call title: ENERGY -EU India Call Call identifier: FP7-ENERGY-2010-INDIA

    E-Print Network [OSTI]

    Milano-Bicocca, Università

    Collaborative ProjectAREA ENERGY.2.1: PHOTOVOLTAICS ENERGY.2010.2.1-3: Development of new concentrator modules and field performance evaluation of Concentrated PV systems - EU-India Call Collaborative Project AREA will be constituted if there is a sufficient number of good quality proposals. It will be used if extra budget becomes

  18. EU Informal Competitiveness Council (Ian Lucas, Parliamentary Under-Secretary (Business and Regulatory

    E-Print Network [OSTI]

    prioritised recovery from the economic crisis and financial stability, focusing on external (i.e. outside EU-efficient economy. There was general support among member states that economic growth and environmental protection to be strengthened and that the mandate of the Centre for Renewable Energy Systems Technology (CREST) advisory

  19. Options introduction and volatility in the EU ETS1 Julien Chevallier 2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of derivatives instruments on the underlying crude oil market and derived products. Thus, detecting whether identify a potential destabilizing effect of the introduction of options on the underlying market (EU ETS either decrease (due to more market depth) or increase (due to more speculation) volatility

  20. STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology

    E-Print Network [OSTI]

    STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology #12;ABOUT THE STYRIAN ACADEMY The STYRIAN ACADEMY is a unique international European life. The STYRIAN ACADEMY addresses business, science and politics as well as excellent students and an interested

  1. Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS

    E-Print Network [OSTI]

    Junk, Michael

    Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS cell from electroluminescence (EL) is introduced. A two-dimensional model of the solar cell screen printed monocrystalline silicon solar cell are shown and the influence of lateral diffusion

  2. International Internship at EuCham For students participating in LLP-ERASMUS programme

    E-Print Network [OSTI]

    Schüler, Axel

    International Internship at EuCham For students participating in LLP-ERASMUS programme We coordination. We offer an internship in an international environment, in which you can both gain knowledge Minimum duration of 6 months Internship takes place in Budapest Internship is unpaid Official language

  3. -News Home Help EU again warns could mount nuclear project without Japan

    E-Print Network [OSTI]

    revealed. news web sites The European Commission ( - ) is set to propose that negotiating strategy next the International Thermonuclear Experimental Reactor (ITER). news web sites Talks in Vienna on Tuesday made some support the Japanese bid -- and Russia and China, which back the EU bid. news web sites Ambassadors from

  4. -News Home Help EU offers 'sweetener' to Japan to let France host nuclear project

    E-Print Network [OSTI]

    to host a revolutionary nuclear fusion project. news web sites "I cannot elaborate on the sweetener, but I Wednesday after talks in Vienna on the International Thermonuclear Experimental Reactor (ITER). news web ( - ) -- which have supported the Japanese bid -- plus Russia and China, which back the EU bid.news web sites

  5. A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics

    E-Print Network [OSTI]

    Chi, Ji

    2009-05-15T23:59:59.000Z

    Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

  6. pEtrolEuM EnginEEring College of Engineering and Mines

    E-Print Network [OSTI]

    Hartman, Chris

    pEtrolEuM EnginEEring College of Engineering and Mines Department of Petroleum Engineering 907 engineering offers a unique look at the challenging problems confronting the petroleum industry. This program and engineering science. Courses in petroleum engineering deal with drilling, formation evaluation, production

  7. DeclanButler,Paris Japan and the European Union (EU) will this

    E-Print Network [OSTI]

    been withdrawnfromthecompetition. The ITER partners -- the EU, Japan, Russia, Canada, China, South." Adealwillinvolveconsensusonengineer- ing, costs, culture and politics, though per- haps not in that order. On paper, the French partners Korea and China. The amount of money each party is prepared to put on the table this week could

  8. EU warns of breakaway plans on nuclear project 24 September 2004

    E-Print Network [OSTI]

    . He argued the project could be launched with Russia paying 10 percent of the costs and China -- which is backed by South Korea, China, the United States and Russia as well as the EU. But the European support from China and Russia. South Korea and the United States appear to prefer the Japanese site

  9. UKERC ENERGY RESEARCH ATLAS: CARBON CAPTURE AND STORAGE (version 10 February 2008) Section 1: An overview which includes a broad characterisation of research activity in the sector and the key research challenges

    E-Print Network [OSTI]

    Haszeldine, Stuart

    UKERC ENERGY RESEARCH ATLAS: CARBON CAPTURE AND STORAGE (version 10 February 2008) Section 1 Research and Technology Development (RTD) Programmes. Section 8: UK participation in energy-related EU international initiatives, including those supported by the International Energy Agency. Version 1.2 published

  10. The EU Approach for Responsible and Safe Management of Spent Fuel and Radioactive Waste - 12118

    SciTech Connect (OSTI)

    Blohm-Hieber, Ute; Necheva, Christina [European Commission, Directorate-General for Energy, Luxembourg L-2920 (Luxembourg)

    2012-07-01T23:59:59.000Z

    In July 2011 legislation on responsible and safe management of spent fuel and radioactive waste was adopted in the European Union (EU). It aims at ensuring a high level of safety, avoiding undue burdens on future generations and enhancing transparency. EU Member States are responsible for the management of their spent fuel and/or radioactive waste. Each Member State remains free to define its fuel cycle policy. The spent fuel can be regarded either as a valuable resource that may be reprocessed or as radioactive waste that is destined for direct disposal. Whatever option is chosen, the disposal of high level waste, separated at reprocessing, or of spent fuel regarded as waste should be considered. The storage of radioactive waste, including long-term storage, is an interim solution, but not an alternative to disposal. To this end, each Member State has to establish, maintain and implement national policy, framework and programme for management of spent fuel and/or radioactive waste in the long term. Member States will invite international peer reviews to ensure that high safety standards are achieved. The EU approach is anchored in internationally endorsed principles and requirements of the IAEA safety standards and the Joint Convention and in this context makes them legally binding and enforceable in the EU. The EU approach of regulating the management of spent fuel and radioactive waste is anchored in the competence of the national regulatory authorities and in the internationally endorsed principles and requirements of the IAEA Safety Standards and the Joint Convention. Member States have to report to the Commission on the implementation of Directive 2011/70/Euratom for the first time by 23 August 2015, and every 3 years thereafter, taking advantage of the review and reporting under the Joint Convention. On the basis of the Member States' reports, the Commission will submit to the European Parliament and the Council a report on progress made and an inventory of radioactive waste and spent fuel present in the EU territory and the future prospects. Directive 2011/70/Euratom is a logical next step after the Council Directive 2009/71/Euratom on the nuclear safety of nuclear installations. The EU is the first major regional actor providing a binding legal framework on nuclear safety and on responsible and safe management of spent fuel and radioactive waste, and thus is a real model to progress spent fuel and waste management in a safe and responsible manner. (authors)

  11. THE EFFECTS OF FLAME TEMPERATURE, PARTICLE SIZE AND EUROPIUM DOPING CONCENTRATION ON THE PROPERTIES OF Y2O3:EU PARTICLES FORMED IN A FLAME AEROSOL PROCESS

    E-Print Network [OSTI]

    Yim, Hoon

    2010-07-14T23:59:59.000Z

    Y2O3:Eu particles are phosphors that have found wide applications. Flamesynthesized Y2O3:Eu particles may have either the cubic or the monoclinic structure. The effects of particle size and Eu doping concentration on crystal structure...

  12. Structural Properties of Eu-Doped GaN Investigated by Raman Spectroscopy

    SciTech Connect (OSTI)

    Senawiratne, J; Xia, Y; Detchprohm, T; Tringe, J W; Stevens, C G; Wetzel, C

    2006-06-20T23:59:59.000Z

    Rare-earth (RE) impurities doped GaN are highly promising candidates for light emitting device applications due to their efficient electroluminescence properties at room temperature. Among those, Eu doped GaN has been identified as an excellent material for the red spectral region due to its strong emission at 620 nm. As a transition internal to the Eu doping atom (4f-4f), light emission originates in a much smaller complex than the more flexibly controllable quantum structures of wells, wires, and dots. This is thought to make the center less susceptible to structural defects and in particular radiation damage in the lattice host. Nevertheless, the lattice host is crucial for providing the excitation in from of free electrons and holes. In this respect, the actual lattice site Eu occupies in the host lattice, i.e. in GaN, is important. A large fraction of Eu atoms are typically inactive which must be attributed to their lattice site and local environment. GaN films implanted with Eu to concentrations of {approx}10{sup 18} cm{sup -3} were subjected to a highly directed beam of 500 keV He{sup +} at a dose of 5 x 10{sup 14} cm{sup -2}. By means of a shadow mask, irradiated and unexposed regions lie very close to each other on the same sample. We used optical and structural analysis to identify the exerted radiation damage. At the full radiation dose, photoluminescence intensity has decayed to {approx}0.01 of its initial value. From the dose dependence of the radiation decay we previously concluded, that this decay is in part due to the destruction of radiative Eu sites [J.W. Tringe, unpublished (2006)]. Along the transition from virgin to irradiated material we analyze the accumulated damage in terms of surface morphology (atomic force microscopy), crystallinity (x-ray diffraction), and phonon dispersion using micro-Raman spectroscopy. In addition to the well-studied E{sub 2}(high) mode, two new vibrational modes at 659 cm{sup -1} and 201 cm{sup -1} were observed in the Eu implanted and annealed sample, prior to He{sup +} irradiation. These modes are either remnants of the implantation damage or related to the Eu impurity. As such they can be indicative of the actual lattice site the Eu atom resides on. After irradiation, broad Raman modes at 300 cm-1 are being observed. This band indicates disorder activated Raman scattering (DARS) due to the radiation damage. An additional narrow mode appears at 672 cm{sup -1}, which can possibly be due to a nitrogen vacancy related vibrational mode. The continuous transition from irradiated to un-irradiated sample allows the direct evolution of radiation damage and its coordinated effects in structural, optical and vibrational properties. By its systematic correlation we anticipate to be able to elucidate the Eu lattice interaction and the processes of radiation damage.

  13. Carbon Monoxide Safety Tips

    E-Print Network [OSTI]

    Shaw, Bryan W.; Garcia, Monica L.

    1999-07-26T23:59:59.000Z

    Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

  14. SCALE-UP OF CARBON /CARBON BIPOLAR PLATES

    E-Print Network [OSTI]

    Scale-up of Carbon/Carbon Bipolar Plates · Project Objectives ­ Build and demonstrate a pilot facility#12;SCALE-UP OF CARBON /CARBON BIPOLAR PLATES Quarterly Report to the Department of Energy, May 19 #12;DOE PROGRAM OBJECTIVES Scale-up of Carbon/Carbon Bipolar Plates · Phase I ­ Technology Development

  15. ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    1 ESM 271 Carbon Footprints and Carbon Accounting Instructor: Sangwon Suh Bren hall 3422, suh: Homework (1 for each week @10%): 40% Personal carbon account (report): 30% Final exam: 30% Course schedule Week 1: Introduction to carbon footprint and carbon account - Background: carbon awareness, major

  16. Structure and physical properties of EuTa{sub 2}O{sub 6} tungsten bronze polymorph

    SciTech Connect (OSTI)

    Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Forbes, S.; Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

    2014-08-11T23:59:59.000Z

    A tetragonal tungsten bronze (TTB) polymorph of EuTa{sub 2}O{sub 6} was prepared and analyzed. EuTa{sub 2}O{sub 6} crystallizes in the centrosymmetric Pnam space group (with unit cell: a?=?12.3693, b?=?12.4254, and c?=?7.7228?Å) isomorphous with orthorhombic ?-SrTa{sub 2}O{sub 6}. In contrast to early reports, we see no evidence of deviation from paramagnetic Curie-Weiss behavior among the Eu{sup 2+} 4f{sup 7}spins in EuTa{sub 2}O{sub 6} down to 2?K. Dielectric constant shows a broad peak at ca. 50?K with dielectric dispersion resembling diffuse phase transition. The relaxation time, however, follows a simple (non-freezing) thermally activated process with an activation energy of 92?meV and an attempt frequency of f{sub 0}?=?5.79?×?10{sup 12?}Hz. A thermal conductivity of EuTa{sub 2}O{sub 6} shows a low-temperature (T???30?K) “plateau” region reminiscent of a glass-like behaviour in Nb-based TTB compounds. This behaviour can be attributed to the loosely bound Eu{sup 2+} ions occupying large tricapped trigonal prismatic sites in the EuTa{sub 2}O{sub 6} structure.

  17. Synthesis, Crystal and Electronic Structure of the Quaternary Magnetic EuTAl4Si2 (T = Rh and Ir) Compounds

    SciTech Connect (OSTI)

    Maurya, Arvind [Tata Institute of Fundamental Research; Thamizhavel, Arumugam [Tata Institute of Fundamental Research; Provino, Alessia [University of Genova; Pani, Marcella [University of Genova; Manfrinetti, Pietro [University of Genova; Paudyal, Durga [Ames Laboratory; Dhar, Sudesh Kumar [Tata Institute of Fundamental Research

    2014-01-22T23:59:59.000Z

    Single crystals of the quaternary europium compounds EuRhAl4Si2 and EuIrAl4Si2 were synthesized by using the Al–Si binary eutectic as a flux. The structure of the two quaternary compounds has been refined by single crystal X-ray diffraction. Both compounds are stoichiometric and adopt an ordered derivative of the ternary KCu4S3 structure type (tetragonal tP8, P4/mmm). The two compounds reported here represent the first example of a quaternary and truly stoichiometric 1:1:4:2 phase crystallizing with this structure type. In light of our present results, the structure of the BaMg4Si3 compound given in literature as representing a new prototype is actually isotypic with the KCu4S3 structure. Local spin density approximation including the Hubbard U parameter (LSDA + U) calculations show that Eu ions are in the divalent state, with a significant hybridization between the Eu 5d, Rh (Ir) 4d (5d), Si 3p and Al 3p states. Magnetic susceptibility measured along the [001] direction confirms the divalent nature of the Eu ions in EuRhAl4Si2 and EuIrAl4Si2, which order magnetically near 11 and 15 K, respectively.

  18. Light-induced structural changes in Eu-doped (Pb,La)(Zr,Ti)O{sub 3} ceramics

    SciTech Connect (OSTI)

    Myint, Thandar; Gunawidjaja, Ray; Eilers, Hergen [Applied Sciences Laboratory, Institute for Shock Physics, Washington State University, Spokane, Washington 99210-1495 (United States)

    2011-04-25T23:59:59.000Z

    Fluorescence spectra of poled and unpoled Eu-doped (Pb,La)(Zr,Ti)O{sub 3} ceramics with various compositions were measured using 580 nm excitation. The ratio of the intensities of the Eu{sup 3+} {sup 5}D{sub 0}{yields}{sup 7}F{sub 2}/{sup 5}D{sub 0}{yields}{sup 7}F{sub 1} fluorescence transitions was used as an indicator for the symmetry of the Eu{sup 3+} site. As the symmetry decreases, the ratio increases. Increasing the Zr content in (Pb,La)(Zr,Ti)O{sub 3} increases the ratio, indicating that the symmetry of the Eu{sup 3+} site decreases. Exposure of the Eu-doped (Pb,La)(Zr,Ti)O{sub 3} samples to UV light also increases the intensity ratio, indicating that UV light exposure leads to structural distortions in Eu-doped (Pb,La)(Zr,Ti)O{sub 3} samples, lowering the Eu{sup 3+} site symmetry.

  19. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  20. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  1. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06T23:59:59.000Z

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  2. Carbon Footprint Towson University

    E-Print Network [OSTI]

    Fath, Brian D.

    Carbon Footprint Towson University GHG Inventory for Educational Institutes Getting Starting.TM The Carbon Footprint 8 The Constellation Experience A Broad Inventory 1. Scope I-Direct Emissions works.TM The Carbon Footprint 10 The Constellation Experience A Broad Inventory 3. Scope III

  3. Manufacture of finely divided carbon

    SciTech Connect (OSTI)

    Walker, D.G.

    1980-01-22T23:59:59.000Z

    Finely divided carbon is manufactured by a process producing a gaseous stream containing carbon monoxide by reacting coal and air in a slagging ash gasifier, separating carbon monoxide from the gaseous mixture, and disproportionating the carbon monoxide to produce finely divided carbon and carbon dioxide, the latter of which is recycled to the gasifier.

  4. SmallholderSmallholder CarbonCarbon AgroforestryAgroforestry && Carbon for Poverty ReductionCarbon for Poverty Reduction

    E-Print Network [OSTI]

    SmallholderSmallholder CarbonCarbon AgroforestryAgroforestry && Carbon for Poverty ReductionCarbon for Poverty Reduction Roundtable (CAPR)Roundtable (CAPR) GEO Forest Monitoring SymposiumGEO Forest Monitoring)Amazon Initiative Consortium (IA) #12;Carbon for Poverty Reduction Roundtable (CAPR)Carbon for Poverty Reduction

  5. Thermal neutron diffraction determination of the magnetic structure of EuCu{sub 2}Ge{sub 2}

    SciTech Connect (OSTI)

    Rowan-Weetaluktuk, W. N.; Ryan, D. H., E-mail: dhryan@physics.mcgill.ca [Department of Physics, and Centre for the Physics of Materials, McGill University, 3600 University Street, Montreal, Quebec H3A 2T8 (Canada); Lemoine, P. [Laboratoire CRISMAT, ENSICAEN, UMR 6508 CNRS, 6 Boulevard du Maréchal Juin, 14050 Caen Cedex 4 (France); Cadogan, J. M. [School of Physical, Environmental and Mathematical Sciences, UNSW Canberra at the Australian Defence Force Academy, Canberra BC 2610 (Australia)

    2014-05-07T23:59:59.000Z

    The magnetic structure of EuCu{sub 2}Ge{sub 2} has been determined by flat-plate neutron powder diffraction. Two magnetic phases are present in the neutron diffraction pattern at 3.5?K. They have the same moment, within error, and a common transition temperature. Both {sup 151}Eu and {sup 153}Eu Mössbauer spectroscopy show that the two magnetic phases belong to the same crystallographic phase. Both phases can be modelled by planar helimagnetic structures: one with a propagation vector of [0.654(1), 0, 0], the other with a propagation vector of [0.410(1), 0.225(1), 0].

  6. Magnetic ordering of divalent europium in double perovskites Eu{sub 2}LnTaO{sub 6} (Ln=rare earths)

    SciTech Connect (OSTI)

    Misawa, Yoshitaka; Doi, Yoshihiro [Division of Chemistry, Hokkaido University, Sapporo 060-0810 (Japan); Hinatsu, Yukio, E-mail: hinatsu@sci.hokudai.ac.jp [Division of Chemistry, Hokkaido University, Sapporo 060-0810 (Japan)

    2011-06-15T23:59:59.000Z

    Structures and magnetic properties of double perovskite-type oxides Eu{sub 2}LnTaO{sub 6} (Ln=Eu, Dy-Lu) were investigated. These compounds adopt a distorted double perovskite structure with space group P2{sub 1}/n. Magnetic susceptibility, specific heat, and {sup 151}Eu Moessbauer spectrum measurements show that the Eu{sup 2+} ions at the 12-coordinate sites of the perovskite structure are antiferromagnetically ordered at {approx}4 K, and that Ln{sup 3+} ions at the 6-coordinate site are in the paramagnetic state down to 1.8 K. - Graphical abstract: Magnetic properties of double perovskite-type oxides Eu{sub 2}LnTaO{sub 6} (Ln=Eu, Dy-Lu) were investigated. Magnetic susceptibility, specific heat, and {sup 151}Eu Moessbauer spectrum measurements show that the Eu{sup 2+} ions at the 12-coordinate sites of the perovskite structure are antiferromagnetically ordered at {approx}4 K. Highlights: > Crystal structures of double perovskites Eu{sub 2}LnTaO{sub 6} (Ln=rare earth) were determined. > We found that these compounds show an antiferromagnetic ordering at {approx}4 K. > The magnetic ordering is due to the interactions of Eu{sup 2+} ions. > It was elucidated by specific heat and {sup 151}Eu Moessbauer spectrum measurements.

  7. Formation of Carbon Dwarfs

    E-Print Network [OSTI]

    Charles L. Steinhardt; Dimitar D. Sasselov

    2012-01-27T23:59:59.000Z

    We consider the formation of dwarf carbon stars via accretion from a carbon AGB companion in light of the new 107 object sample of Downes et al. (2004). This sample is now large enough to allow good mass determination via comparison of a composite spectrum to theoretical atmospheric models. Carbon dwarfs of spectral type M are indeed main sequence M dwarfs with enhanced metallicity and carbon abundance. We also calculate the predicted abundance of both M and of F/G carbon dwarfs, and show that the latter should be falsifiable in the near future.

  8. Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon fiber

    E-Print Network [OSTI]

    Das, Suman

    Study of fire retardant behavior of carbon nanotube membranes and carbon nanofiber paper in carbon Accepted 14 January 2010 Available online 20 January 2010 A B S T R A C T Single-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) membranes (buckypaper) and carbon nanofiber (CNF) paper

  9. 4/6/2014 EU Drafts Hydraulic Fracturing Guidelines to Mitigate Conflicting Laws | The DailyEnergyReport http://www.dailyenergyreport.com/eu-drafts-hydraulic-fracturing-guidelines-to-mitigate-conflicting-laws-2/ 1/7

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    /eu-drafts-hydraulic-fracturing-guidelines-to-mitigate-conflicting-laws-2/ 1/7 Tweet 1 April 6, 2014 Search for a topic... GO Home Efficiency Renewables Buildings because of its durable nickel allow material and smart aerodynamic design. Post to Facebook Add to Linked The Maryland Electricity Market Americans Hop on Trains as Gas Prices Hit the Roof 1 #12;4/6/2014 EU Drafts

  10. Synthesis, crystal structure and magnetic properties of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}

    SciTech Connect (OSTI)

    Kokal, I. [Koç University, Rumelifeneri Yolu, Sariyer, Istanbul 34450 (Turkey); Aydemir, U., E-mail: uaydemir@ku.edu.tr [Koç University, Rumelifeneri Yolu, Sariyer, Istanbul 34450 (Turkey); Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str.40, Dresden 01187 (Germany); Prots, Yu.; Förster, T.; Sichelschmidt, J. [Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str.40, Dresden 01187 (Germany); Yahyaoglu, M. [Koç University, Rumelifeneri Yolu, Sariyer, Istanbul 34450 (Turkey); Auffermann, G.; Schnelle, W. [Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str.40, Dresden 01187 (Germany); Schappacher, F.; Pöttgen, R. [Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstraße 30, Münster 48149 (Germany); Somer, M., E-mail: msomer@ku.edu.tr [Koç University, Rumelifeneri Yolu, Sariyer, Istanbul 34450 (Turkey)

    2014-02-15T23:59:59.000Z

    Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was synthesized from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3} at 850 °C. Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] crystallizes in the trigonal space group R3{sup ¯}c (No. 167) with a=12.0225(2) Å, c=6.8556(2) Å and Z=6. In the crystal structure, isolated, planar cyclic [B{sub 3}N{sub 6}]{sup 9?} units are charge-balanced by the mixed-valence Eu{sup 3+}/Eu{sup 2+} and Li{sup +} cations. Li{sup +} occupies partially (44%) the Wyckoff site 6b and is sandwiched between the [B{sub 3}N{sub 6}]{sup 9?} anions. Mössbauer spectroscopy results show the resonance lines of Eu{sup 2+} and Eu{sup 3+}, respectively, indicating the heterogeneous mixed valency of the Eu atoms. X-Band ESR investigations between 5 and 300 K reveal an intense signal over the whole temperature range originating from Eu{sup 2+}. Magnetic susceptibility measurements indicate a Curie–Weiss behavior with an experimental effective magnetic moment of ?{sub eff}=8.28 ?{sub B} per formula unit. - Graphical abstract: Single crystals of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was obtained from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3.}{sup 151}Eu Mössbauer, ESR and magnetic susceptibility measurements reveal the heterogeneous mixed valency of the Eu atoms. Display Omitted - Highlights: • Single crystals of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was obtained from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3} at 850 °C. • Crystal structure is built up by isolated, planar cyclic [B{sub 3}N{sub 6}]{sup 9?} units which are surrounded by mixed valence Eu{sup 3+}/Eu{sup 2+}. • Li{sup +} occupies partially (44%) the site 6b and is sandwiched between the [B{sub 3}N{sub 6}]{sup 9?} anions. • The {sup 151}Eu Mössbauer spectroscopy, electron spin resonance spectroscopy and magnetic susceptibility measurements confirm the heterogeneous mixed valency of Eu.

  11. Studies of the N=90 region: The decay of 154Eu to 154Gd

    SciTech Connect (OSTI)

    Kulp, W.D.; Wood, J.L.; Krane, K.S.; Loats, J.; Schmelzenbach, P.; Stapels, C.J.; Larimer, R.-M.; Norman, E.B.

    2003-12-05T23:59:59.000Z

    The decay of {sup 154}Eu {yields} {sup 154}Gd has been studied by {gamma}-ray singles and {gamma}-{gamma} coincidence spectroscopy using an array of 20 Compton-suppressed Ge detectors. The primary goal of the work was to confirm or refute a large number of questionable features in the decay scheme: the outcome is the removal of 8 levels from the previously adopted scheme, with the result that a new type of collective band is revealed. Many weak decay branches for the decay are clarified. These results are critical for understanding the structure of {sup 154}Gd and the N = 90 isotones; and the improved completeness of the decay scheme contributes to the use of {sup 154}Eu as a metrological standard.

  12. Photon Physics and Plasma Research, WILGA 2012; EuCARD Sessions

    E-Print Network [OSTI]

    Romaniuk, R S

    2012-01-01T23:59:59.000Z

    Wilga Sessions on HEP experiments, astroparticle physica and accelerator technology were organized under the umbrella of the EU FP7 Project EuCARD – European Coordination for Accelerator Research and Development. This paper is the third part (out of five) of the research survey of WILGA Symposium work, May 2012 Edition, concerned with Photon Physics and Plasma Research. It presents a digest of chosen technical work results shown by young researchers from different technical universities from this country during the Jubilee XXXth SPIE-IEEE Wilga 2012, May Edition, symposium on Photonics and Web Engineering. Topical tracks of the symposium embraced, among others, nanomaterials and nanotechnologies for photonics, sensory and nonlinear optical fibers, object oriented design of hardware, photonic metrology, optoelectronics and photonics applications, photonics-electronics co-design, optoelectronic and electronic systems for astronomy and high energy physics experiments, JET tokamak and pi-of-the sky experiments ...

  13. Enhancement of the electron electric dipole moment in Eu{sup 2+}

    SciTech Connect (OSTI)

    Skripnikov, L.V.; Titov, A.V.; Petrov, A. N.; Mosyagin, N. S. [Petersburg Nuclear Physics Institute, Gatchina, Leningrad District 188300 (Russian Federation); Sushkov, O. P. [School of Physics, University of New South Wales, Sydney 2052 (Australia)

    2011-08-15T23:59:59.000Z

    Recently, the ferroelectric Eu{sub 0.5}Ba{sub 0.5}TiO{sub 3} was suggested for experimental searches of the electron electric dipole moment. To analyze results of the experiment and interpret them in terms of fundamental constants, the effective electric field E{sub eff} acting on unpaired electrons of the europium cation should be calculated. In the present paper we consider Eu{sup 2+} cation in the uniform external electric field E{sub ext} as the first step and important starting point toward the calculation of E{sub eff} in the real solid. We have performed high-level electronic structure correlation calculations using the coupled clusters theory compared to other approaches. The calculated value of the field enhancement coefficient is K=E{sub eff}/E{sub ext}=-4.6.

  14. Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe

    E-Print Network [OSTI]

    Bastin, Mariah Margareta

    2013-02-04T23:59:59.000Z

    ABSTRACT Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe Out of the current sovereign debt crisis, the continuing debate over the proper role and responsibility...

  15. First evidence of asymmetric cost pass-through of Eu emissions allowances : examining wholesale electricity prices in Germany

    E-Print Network [OSTI]

    Zachmann, Georg

    2007-01-01T23:59:59.000Z

    This paper applies the literature on asymmetric price transmission to the emerging commodity market for EU emissions allowances (EUA). We utilize an error correction model and an autoregressive distributed lag model to ...

  16. Full-Color Emission From In2S3 and In2S3:Eu3+ Nanoparticles....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoparticles. Full-Color Emission From In2S3 and In2S3:Eu3+ Nanoparticles. Abstract: Blue (425 nm) and green (510 nm) emission is observed from In2S3 nanoparticles which are...

  17. Over-Allocation or Abatement? A Preliminary Analysis of the EU Emissions Trading Scheme Based on the 2005 Emissions Data

    E-Print Network [OSTI]

    Ellerman, A. Denny.

    This paper provides an initial analysis of the European Union Emissions Trading Scheme (EU ETS) based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, ...

  18. Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe 

    E-Print Network [OSTI]

    Bastin, Mariah Margareta

    2013-02-04T23:59:59.000Z

    ABSTRACT Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe Out of the current sovereign debt crisis, the continuing debate over the proper role and responsibility...

  19. Comparison of the Evolution of Energy Intensity in Spain and in the EU15. Why is Spain Different?

    E-Print Network [OSTI]

    Ocaña, Carlos

    Energy intensity in Spain has increased since 1990, while the opposite has happened in the EU15. Decomposition analysis of primary energy intensity ratios has been used to identify which are the key sectors driving the ...

  20. Over-allocation or abatement? : a preliminary analysis of the EU ETS based on the 2005 emission data

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2006-01-01T23:59:59.000Z

    This paper provides an initial analysis of the EU ETS based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, released on May 15, 2006, and subsequent ...

  1. Red emission from Eu-doped GaN luminescent films grown by metalorganic chemical vapor deposition

    E-Print Network [OSTI]

    Steckl, Andrew J.

    chemical vapor deposition on GaN/Al2O3 substrates. Trimethylgallium TMGa , ammonia (NH3), and europium 2 europium doping was performed utilizing a europium beta-diketonate, eu- ropium 2,2,4,4-tetramethyl-3

  2. Tuning cationic composition of La:EuTiO{sub 3??} films

    SciTech Connect (OSTI)

    Shkabko, Andrey, E-mail: shkabko@gmail.com [Forschungszentrum Jülich, Peter Grünberg Institut (PGI-7), D-52425 Jülich (Germany); Empa, Solid State Chemistry and Catalysis, CH-8600 Dübendorf (Switzerland); Xu, Chencheng; Meuffels, Paul; Gunkel, Felix; Dittmann, Regina; Waser, Rainer [Forschungszentrum Jülich, Peter Grünberg Institut (PGI-7), D-52425 Jülich (Germany); Weidenkaff, Anke [Empa, Solid State Chemistry and Catalysis, CH-8600 Dübendorf (Switzerland)

    2013-11-01T23:59:59.000Z

    Eu{sub 1?x}La{sub x}TiO{sub 3??} (x = 0, 0.3, 0.5) films were deposited in a p(Ar(96%)/H{sub 2}(4%)) = 4 × 10{sup ?4} mbar atmosphere on (LaAlO{sub 3}){sub 0.3}-(Sr{sub 2}AlTaO{sub 6}){sub 0.7} vicinal substrates (0.1°). Reflection high-energy electron diffraction oscillation characteristics of a layer-by-layer growth mode were observed for stoichiometric and Ti-rich films and the laser fluence suited to deposit stoichiometric films was identified to be 1.25 J/cm{sup 2} independent of the La content. The variety of resulting film compositions follows the general trend of Eu-enrichment for low laser and Ti-enrichment for high laser fluence. X-ray diffraction confirms that all the films are compressively strained with a general trend of an increase of c-axis elongation for non-stoichiometric films. The surfaces of non-stoichiometric films have an increased roughness, the highest sheet resistances, exhibit the presence of islands, and are Eu{sup 3+} rich for films deposited at low laser fluence.

  3. Enhanced magnetization and improved insulating character in Eu substituted BiFeO{sub 3}

    SciTech Connect (OSTI)

    Durga Rao, T.; Asthana, Saket, E-mail: asthanas@iith.ac.in [Advanced Functional Materials Laboratory, Department of Physics, Indian Institute of Technology Hyderabad, Andhra Pradesh–502205 (India); Ranjith, R. [Department of Materials Science and Metallurgical Engineering, Indian Institute of Technology Hyderabad, Andhra Pradesh–502205 (India)

    2014-03-28T23:59:59.000Z

    The polycrystalline Bi{sub 1?x}Eu{sub x}FeO{sub 3} (x?=?0, 0.05, and 0.1) ceramics were synthesized by conventional solid-state route. X-ray diffraction studies and Raman measurements revealed that the compounds crystallized in rhombohedral structure with R3c space group. In addition, a nominal percentage of orthorhombic phase was observed in 10 mol.?% Eu substituted BiFeO{sub 3}. Appearance of weak ferromagnetism and significant increase in Néel temperature T{sub N} in the substituted compounds were discussed on the basis of structural distortions. Enhanced remnant magnetization of 75 memu/g and large coercive field of 6.4?kÖe were observed in 10 mol.?% Eu substituted BiFeO{sub 3}. Equivalent circuit model was employed to estimate the grain and grain boundary contributions towards the electrical parameters such as resistance and conductivity. Non-Debye type of relaxation was confirmed from impedance and electric modulus studies. The obtained frequency variation of ac conductivity at different temperature obeys Jonscher's power law and is consistent with the correlated barrier hopping model. Temperature variations of ac conductivity explained that electronic hopping, oxygen vacancies movement, and/or creation of defects contribute to conduction in all the compounds.

  4. Microstructural and photocatatlytic properties of Eu-doped mesporous titanium dioxide nanopaticles by sol–gel method

    SciTech Connect (OSTI)

    Chen, Daimei, E-mail: chendaimei@cugb.edu.cn [National Laboratory of Mineral Materials, School of Materials Sciences and Technology, University of Geosciences, Beijing 100083 (China)] [National Laboratory of Mineral Materials, School of Materials Sciences and Technology, University of Geosciences, Beijing 100083 (China); Zhu, Qian; Lv, Zhijin; Deng, Xutao; Zhou, Fengsan; Deng, Yanxi [National Laboratory of Mineral Materials, School of Materials Sciences and Technology, University of Geosciences, Beijing 100083 (China)] [National Laboratory of Mineral Materials, School of Materials Sciences and Technology, University of Geosciences, Beijing 100083 (China)

    2012-11-15T23:59:59.000Z

    Highlights: ? Eu-doped TiO{sub 2} was prepared using sol–gel method in the presence of pluronic P123. ? Eu atoms were doped into the lattice of anatase TiO{sub 2}. ? Eu doping can increase the band gap of TiO{sub 2}. ? Eu-doped TiO{sub 2} exhibited much higher photocatalytic activity than undoped TiO{sub 2}. -- Abstract: The europium-doped mesoporous titanium dioxide nanoparticles (Eu-doped TiO{sub 2}) with the different Eu/Ti rations were prepared using sol–gel method in the presence of tir-block copolymer pluronic P123. The as-prepared catalysts were characterized by low-angle and wide-angle X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N{sub 2} absorption–desorption, ultraviolet visible light spectroscopy (UV–vis) and X-ray photoelectron spectroscopy (XPS), respectively. The XRD analysis indicated that all as-prepared TiO{sub 2} samples were mainly anatase phase and mesoporous. The crystallite sizes were in the range 6–11 nm, in consistent with the results obtained form TEM images. HRTEM and XPS showed that the europium atoms were doped into the lattice of anatase TiO{sub 2}. Eu doping can not only increase the stability of mesoporous TiO{sub 2}, but also make the absorption edge position move toward shorter wavelength. The photodecomposition experiments showed that the photodegradation activity of Eu-doped TiO{sub 2} was higher than that of undoped TiO{sub 2}.

  5. Carbon dioxide sensor

    DOE Patents [OSTI]

    Dutta, Prabir K. (Worthington, OH); Lee, Inhee (Columbus, OH); Akbar, Sheikh A. (Hilliard, OH)

    2011-11-15T23:59:59.000Z

    The present invention generally relates to carbon dioxide (CO.sub.2) sensors. In one embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor that incorporates lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3). In another embodiment, the present invention relates to a carbon dioxide (CO.sub.2) sensor has a reduced sensitivity to humidity due to a sensing electrode with a layered structure of lithium carbonate and barium carbonate. In still another embodiment, the present invention relates to a method of producing carbon dioxide (CO.sub.2) sensors having lithium phosphate (Li.sub.3PO.sub.4) as an electrolyte and sensing electrode comprising a combination of lithium carbonate (Li.sub.2CO.sub.3) and barium carbonate (BaCO.sub.3).

  6. Ag-catalyzed synthesis of europium borate Eu(BO{sub 2}){sub 3} nanowires, growth mechanism and luminescent properties

    SciTech Connect (OSTI)

    Yang, Lan, E-mail: yanglan1116@126.com [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China)] [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China); Zhou, Liqun, E-mail: zlq@hubu.edu.cn [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China)] [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China); Huang, Ying; Tang, Ziwei [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China)] [Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062 (China)

    2011-02-15T23:59:59.000Z

    Eu(BO{sub 2}){sub 3} nanowires with diameters of 10-20 nm were fabricated through direct sintering Eu(NO{sub 3}){sub 3}.6H{sub 2}O and H{sub 3}BO{sub 3} with Ag as catalyst. The result of X-ray diffraction (XRD) indicated that the nanowire was single-crystalline with body-centered monoclinic structure. Based on the fact that Ag nanoparticles attached to the tips and middles of nanowires, a vapor-liquid-solid (VLS) growth mechanism of the Eu(BO{sub 2}){sub 3} nanowires is proposed. Three well-defined stages have been clearly identified during the process: Ag-Eu-B-O cluster process, crystal nucleation, and axial growth. The photoluminescence characteristics under UV excitation were investigated. The dominated Eu{sup 3+} orange-red emission corresponding to the magnetic dipole transition {sup 5}D{sub 0} {yields} {sup 7}F{sub 1} is centered at 591 nm, indicating that Eu{sup 3+} is located at high symmetry crystal field with inversion center.

  7. Multiphase Sequestration Geochemistry: Model for Mineral Carbonation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiphase Sequestration Geochemistry: Model for Mineral Carbonation. Multiphase Sequestration Geochemistry: Model for Mineral Carbonation. Abstract: Carbonation of formation...

  8. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  9. Would Border Carbon Adjustments prevent carbon leakage and heavy industry

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    No 52-2013 Would Border Carbon Adjustments prevent carbon leakage and heavy industry halshs-00870689,version1-7Oct2013 #12;Would Border Carbon Adjustments prevent carbon leakage and heavy The efficiency of unilateral climate policies may be hampered by carbon leakage and competitiveness losses

  10. Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions

    E-Print Network [OSTI]

    Balser, Dana S.

    Carbon RRLs Carbon RRLs towards Ultra-compact HII Regions Dana S. Balser D. Anish Roshi (Raman (Agnes Scott College) #12;Carbon RRLs Carbon Radio Recombination Lines (RRLs) NGC 2024 (Orion B) IC 1795 (W3) Palmer et al. (1967) #12;Carbon RRLs Photodissociation Regions (PDRs) Hollenbach & Tielens (1997

  11. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    Pierrehumbert, Raymond

    Cumulative Carbon and Just Allocation of the Global Carbon Commons R.T. Pierrehumbert1 on climate can be characterized by a single statistic, called Cumulative Carbon. This is the aggregate amount of carbon emitted in the form of carbon dioxide by activities such as fossil fuel burning and deforestation

  12. Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes**

    E-Print Network [OSTI]

    New Mexico, University of

    Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes** D. Bruce Burckel Polsky* The special nature of the CÀC bond can lead to various polymorphic forms of carbon such as graphite, glassy-carbon, fullerenes (such as buckyballs), carbon nanotubes, and diamond. Electrodes made

  13. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  14. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  15. Purposes, paradigms and pressure groups: Accountability and sustainability in EU environmental assessment, 1985-2010

    SciTech Connect (OSTI)

    Sheate, William R., E-mail: w.sheate@imperial.ac.uk

    2012-02-15T23:59:59.000Z

    Twenty five years since the introduction of the European Union (EU) environmental impact assessment (EIA) Directive in 1985 this paper reflects on the extent to which environmental assessment (EA) processes, over the course of their evolution over the last 25 years in the EU, have provided a platform for enhancing accountability and sustainability. Surprisingly-in the context of legal mandates for EA-there is little reference in the EA literature explicitly to the literature on accountability and the role EA may play in this increasingly important aspect of governance. The paper explores EA implementation principally from an environmentalist perspective and particularly the way in which NGOs and other advocates for the environment in the UK and EU have used the EA legislation as a lever for increasing democratic, corporate and professional accountability of proponents and decision-makers alike. From an a historical analysis, including two historical EIA case studies and two contemporary SEA case studies, it becomes clear that EA has had an important role to play-at the legislative level in providing the requirements for accountability, and at the implementation level as the lever that can be used to hold individuals, organisations and authorities to account for their actions. The relationship with the shift to sustainability is a close one, since sustainable development demands greater public involvement in decision-making and greater accountability of executive decisions to the public. The lessons from this analysis allow the development of a nascent policy-oriented theory regarding EA's role in accountability, which provides a framework for a distinctive new area of EA research and policy analysis. Moreover, an accountability perspective on EA could help re-frame EA for policy makers from being purely an informational and procedural instrument to one which promotes better accountability and sustainability simultaneously. - Highlights: Black-Right-Pointing-Pointer Little attention in the literature to environmental assessment (EA) and accountability. Black-Right-Pointing-Pointer Evolution of EA in the EU influenced by shifting policy paradigms and demands for accountability. Black-Right-Pointing-Pointer EIA and SEA, as formal procedures, can provide platforms for accountability. Black-Right-Pointing-Pointer Four case studies illustrate how NGOs and others have used EA to further accountability. Black-Right-Pointing-Pointer A policy-oriented theory provides a basis for considering future evolution of EA in the EU.

  16. Activated Carbon Injection

    ScienceCinema (OSTI)

    None

    2014-07-22T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  17. Carbon Fiber SMC

    Broader source: Energy.gov (indexed) [DOE]

    confidential, or otherwise restricted information. ACC932 Materials and Processes Technology Development Carbon Fiber SMC 5-20-09 Charles Knakal USCAR C. S. Wang General Motors...

  18. Activated Carbon Injection

    SciTech Connect (OSTI)

    None

    2014-07-16T23:59:59.000Z

    History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

  19. Reinforced Carbon Nanotubes.

    DOE Patents [OSTI]

    Ren, Zhifen (Newton, MA); Wen, Jian Guo (Newton, MA); Lao, Jing Y. (Chestnut Hill, MA); Li, Wenzhi (Brookline, MA)

    2005-06-28T23:59:59.000Z

    The present invention relates generally to reinforced carbon nanotubes, and more particularly to reinforced carbon nanotubes having a plurality of microparticulate carbide or oxide materials formed substantially on the surface of such reinforced carbon nanotubes composite materials. In particular, the present invention provides reinforced carbon nanotubes (CNTs) having a plurality of boron carbide nanolumps formed substantially on a surface of the reinforced CNTs that provide a reinforcing effect on CNTs, enabling their use as effective reinforcing fillers for matrix materials to give high-strength composites. The present invention also provides methods for producing such carbide reinforced CNTs.

  20. Carbon Fiber Technology Facility

    Broader source: Energy.gov (indexed) [DOE]

    conventional and alternative precursors to carbon fiber Advance high-volume composite design and manufacturing capabilities Transition technology to industry partners...

  1. EMBODIED CARBON TARIFFS Christoph Bhringer

    E-Print Network [OSTI]

    EMBODIED CARBON TARIFFS Christoph Böhringer Jared C. Carbone Thomas F. Rutherford Revised: August 2013 Abstract Embodied carbon tariffs tax the direct and indirect carbon emissions embodied in trade -- an idea popularized by countries seeking to extend the reach of domestic carbon regu- lations. We

  2. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Y. Li, M. Daskin. 2009. Carbon Footprint and the ManagementJ. van Houtum. 2011. E?ect of carbon emission regulations onStreamlined Enterprise Carbon Footprinting. Environmental

  3. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01T23:59:59.000Z

    EU ETS: European Union Emissions Trading System GHG: Greenstarts operating an emissions trading scheme (ETS) similarGovernments operating emissions trading systems face the

  4. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    Pearce, D. 2003. The Social Cost Of Carbon And Its PolicyR.S.J. 2008. The Social Cost of Carbon: Trends, Outliers and

  5. Combined experimental and theoretical study of the low temperature dielectric and magnetic properties of trivalent Eu ion doped SrTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Yu Jiangzhou; Fang Liang; Cai Tianyi; Ju Sheng; Dong Wen; Zheng Fengang; Shen Mingrong [Jiangsu Key Laboratory of Thin Films and Department of Physics, Soochow University, Suzhou, 215006 (China)

    2012-03-15T23:59:59.000Z

    Single-phase Sr{sub 1-3x/2}Eu{sub x}TiO{sub 3} (SETO{sub x}) (x = 0-0.075) ceramics were prepared to study the effects of Eu substitution on their crystal structure, low temperature dielectric, and magnetic behaviors. Rietveld refinement of X-ray diffraction data yields direct evidence that the Eu ion substitutes Sr site at the perovskite. The measured dielectric properties can be well explained by the mean-field model. It has been found that the anomaly dielectric enhancement behavior exists in the SETO{sub x=0.005} sample, while more stable quantum paraelectric states are obtained in other doped samples. On the other hand, all the Eu doped samples exhibit doping concentration dependence of paramagnetism. Developing the linear response model, we conclude that a molecular field is acting on Eu ions possibly via the spin polarized Eu-O-Ti hybridization.

  6. Aryl Bridged 1-Hydroxypyridin-2-one: Effect of the Bridge on the Eu(III) Sensitization Process

    SciTech Connect (OSTI)

    D'Aleo, Anthony; Moore, Evan G.; Szigethy, Geza; Xu, Jide; Raymond, Kenneth N.

    2009-06-17T23:59:59.000Z

    The efficiency of Eu3+ luminescence by energy transfer from an antenna ligand can be strongly dependent on the metal ion coordination geometry. The geometric component of the Eu(III) sensitization has been probed using series of tetradentate 1,2-HOPO derivatives that are connected by bridges of varying length and geometry. The ligands are N,N'-(1,2-phenylene)bis(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamide) for the ligand (L{sup 1}), 1-hydroxy-N-(2-(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamido)benzyl)-6-oxo-1,6-dihydropyridine-2-carboxamide (L{sup 2}) and N,N'-(1,2-phenylenebis(methylene))bis(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamide) (L{sup 3}). Spectroscopic characterization of both the Gd(III) and Eu(III) metal complexes, TD-DFT analysis of model compounds and evaluation of the kinetic parameters for the europium emission were completed. Some striking differences were observed in the luminescence quantum yield by altering the bridging unit. The [Eu(L{sup 2}){sub 2}]{sup -} derivative shows efficient sensitization coupled with good metal centered emission. For [Eu(L{sup 3}){sub 2}]{sup -}, the large quenching of the luminescence quantum yield compared to [Eu(L{sup 2}){sub 2}]{sup -} is primarily a result of one inner sphere water molecule bound to the europium cation while for [Eu(L{sup 1}){sub 2}]{sup -}, the low luminescence quantum yield can be attributed to inefficient sensitization of the europium ion.

  7. Carbon Park Environmental Impact Assessment

    E-Print Network [OSTI]

    of offsetting the University's carbon footprint, promoting biodiversity and establishing easily maintained Carbon Park Environmental Impact Assessment A B.E.S.T. Project By, Adam Bond 2011 #12; Bishop's University Carbon Park

  8. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon First Proof of Ferromagnetic Carbon Print Wednesday, 25 July 2007 00:00 Although it has long been suspected that carbon belongs on the short list of...

  9. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E. (Pinole, CA); Moses, William W. (Berkeley, CA)

    1991-01-01T23:59:59.000Z

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  10. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14T23:59:59.000Z

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  11. The role of activator concentration and precipitate formation on optical and dosimetric properties of KCl:Eu{sup 2+} storage phosphor detectors

    SciTech Connect (OSTI)

    Hansel, Rachael A.; Xiao, Zhiyan; Hu, Yanle; Green, Olga; Yang, Deshan; Harold Li, H. [Department of Radiation Oncology, Washington University School of Medicine, 4921 Parkview Place, Campus Box 8224, St. Louis, Missouri 63110 (United States)] [Department of Radiation Oncology, Washington University School of Medicine, 4921 Parkview Place, Campus Box 8224, St. Louis, Missouri 63110 (United States)

    2013-09-15T23:59:59.000Z

    Purpose: The activator ion (Eu{sup 2+} in KCl:Eu{sup 2+}) plays an important role in the photostimulated luminescence (PSL) mechanism of storage phosphor radiation detectors. In order to design an accurate, effective, and robust detector, it is important to understand how the activator ion concentration affects the structure and, consequently, radiation detection properties of KCl:Eu{sup 2+}.Methods: Potassium chloride pellets were fabricated with various amounts of europium dopant (0.01–5.0 mol.% Eu{sup 2+}). Clinical radiation doses were given with a 6 MV linear accelerator. Radiation doses larger than 100 Gy were given with a {sup 137}Cs irradiator. Dose response curves, radiation hardness, and temporal signal stability were measured using a laboratory PSL readout system. The crystal structure of the material was studied using x ray diffraction and luminescence spectroscopy.Results: The most intense PSL signal was from samples with 1.0 mol.% Eu. However, samples with concentrations higher than 0.05 mol.% Eu exhibited significant degradation in PSL intensity for cumulated doses larger than 3000 Gy. Structural and luminescence spectroscopy showed clear evidence of precipitate phases within the KCl lattice, especially for high activator concentrations. Analysis of PL emission spectra showed that interactions between Eu-V{sub c} dipoles and Eu-V{sub c} trimers could explain trends in PSL sensitivity and radiation hardness observations.Conclusions: The concentration of the activator ion (Eu{sup 2+}) significantly affects radiation detection properties of the storage phosphor KCl:Eu{sup 2+}. An activator concentration between 0.01 and 0.05 mol.% Eu in KCl:Eu{sup 2+} storage phosphor detectors is recommended for linear dose response, good PSL sensitivity, predictable temporal stability, and high reusability for megavoltage radiation detection.

  12. CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA: REPORT TO THE LEGISLATURE Regional Carbon Sequestration Partnership (WESTCARB) studies that we used, including Cameron Downey

  13. Analysis of alpha-induced reactions on $^{151}$Eu below the Coulomb barrier

    E-Print Network [OSTI]

    V. Avrigeanu; M. Avrigeanu

    2010-12-05T23:59:59.000Z

    Novel measurements of $(\\alpha,\\gamma)$ and $(\\alpha$,n) reaction cross sections on the target nucleus $^{151}$Eu, close to the reaction thresholds, support the setting up of recent parameters of the $\\alpha$-particle optical model potential below the Coulomb barrier. A better understanding of the $\\alpha$-particle optical potential at these energies leads to a statistical model analysis of additional partial cross sections that were formerly measured but not considered within the model analysis. On this basis we have tentatively assigned a modified $J^{\\pi}$=9$^-$ spin and parity to the 22.7-h isomer in $^{154}$Tb.

  14. The EU's Human Rights Obligations in Relation to Policies with Extraterritorial Effects

    E-Print Network [OSTI]

    Bartels, Lorand

    2014-04-09T23:59:59.000Z

    in their territory to cause harm to other states. This obligation is usually dated to the 1941 Trail Smelter arbitration, in which it was said that ‘no State has the right to use or permit the use of its territory in such a manner as to cause injury by fumes... and equipment [2008] OJ L335/99 requires EU Member States to ‘exercise special caution and vigilance in issuing licences … to countries where serious violations of human rights have been established …’. 49 Trail Smelter (US/Canada) (1941) 3 RIAA 1905...

  15. advanced carbon-carbon composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite Biology and Medicine Websites Summary: CARBON-CARBON...

  16. Trading Water for Carbon with Biological Carbon Sequestration

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    Trading Water for Carbon with Biological Carbon Sequestration Robert B. Jackson,1 * Esteban G. Farley,1 David C. le Maitre,5 Bruce A. McCarl,6 Brian C. Murray7 Carbon sequestration strategies plantations feature prominently among tools for carbon sequestration (1­8). Plantations typi- cally combine

  17. Cumulative Carbon and Just Allocation of the Global Carbon Commons

    E-Print Network [OSTI]

    Pierrehumbert, Raymond

    Cumulative Carbon and Just Allocation of the Global Carbon Commons R.T. Pierrehumbert* Abstract statistic, called cumulative carbon. This statistic is the aggregate amount ofcarbon emitted in theform such activitiespersist.In thispaper the conceptis usedto addressthe question offair allocation of carbon emissions

  18. International Conference on Carbon Nanotechnology: Potential and Challenges (Carbon 10)

    E-Print Network [OSTI]

    Srivastava, Kumar Vaibhav

    International Conference on Carbon Nanotechnology: Potential and Challenges (Carbon 10) 15 - 17th Since the discovery of the carbon nanotube (CNT) about two decades ago, research related to its of Materials and Process Engineering Kanpur Chapter hosted the `International Conference on Carbon

  19. IMPACCT: Carbon Capture Technology

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    IMPACCT Project: IMPACCT’s 15 projects seek to develop technologies for existing coal-fired power plants that will lower the cost of carbon capture. Short for “Innovative Materials and Processes for Advanced Carbon Capture Technologies,” the IMPACCT Project is geared toward minimizing the cost of removing carbon dioxide (CO2) from coal-fired power plant exhaust by developing materials and processes that have never before been considered for this application. Retrofitting coal-fired power plants to capture the CO2 they produce would enable greenhouse gas reductions without forcing these plants to close, shifting away from the inexpensive and abundant U.S. coal supply.

  20. Giant magnetocaloric effect in magnetoelectric Eu{sub 1-x}Ba{sub x}TiO{sub 3}

    SciTech Connect (OSTI)

    Rubi, Km; Kumar, Pawan; Maheswar Repaka, D. V.; Chen, Ruofan; Wang, Jian-Sheng; Mahendiran, R., E-mail: phyrm@nus.edu.sg [Department of Physics, 2 Science Drive 3, Faculty of Science, National University of Singapore, Singapore 117551 (Singapore)

    2014-01-20T23:59:59.000Z

    We report the magnetic entropy change (?S{sub m}) in magnetoelectric Eu{sub 1-x}Ba{sub x}TiO{sub 3} for 0.1???x???0.9. We find ??S{sub m}?=?11 (40) J/kg·K in x?=?0.1 for a field change of 1 (5) T, respectively, which is the largest value among all Eu-based oxides. ?S{sub m} arises from the field-induced suppression of the spin entropy of Eu{sup 2+}:4f{sup 7} localized moments. While ???S{sub m}? decreases with increasing x, ???S{sub m}??=?6.58?J/kg·K observed in the high spin diluted composition x?=?0.9 is larger than that in many manganites. Our results indicate that these magnetoelectrics are potential candidates for cryogenic magnetic refrigeration.

  1. Effect of Mg codoping on Eu{sup 3+} luminescence in GaN grown by ammonia molecular beam epitaxy

    SciTech Connect (OSTI)

    Takagi, Yasufumi [Central Research Laboratory, Hamamatsu Photonics K. K., Hamamatsu, Shizuoka 434-8601 (Japan); Suwa, Takanobu; Sekiguchi, Hiroto; Wakahara, Akihiro [Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580 (Japan); Okada, Hiroshi [Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580 (Japan); Electronics-Inspired Interdisciplinary Research Institute (EIIRIS), Toyohashi University of Technology, Toyohashi, Aichi 441-8580 (Japan)

    2011-10-24T23:59:59.000Z

    The effect of Mg codoping on the Eu{sup 3+} luminescence in GaN was investigated by photoluminescence measurements. Two notable emission peaks associated with the {sup 5}D{sub 0}{yields}{sup 7}F{sub 2} transition in the Eu{sup 3+} ions were governed by Mg codopants, which corresponded to the change of the dominant peak wavelength from 622.3 to 620.3 nm with an increase in Mg concentration. An optimal amount of Mg also led to enhancement of approximately 20 times of the Eu{sup 3+} luminescence. These results indicated that the Mg codopants selectively activated the optical site of 620.3 nm emission due to the elimination of nonradiative deexcitation paths from the {sup 5}D{sub 0} state.

  2. Photoluminescence studies of Y{sub 2}O{sub 3}:Eu{sup 3+} under high pressure

    SciTech Connect (OSTI)

    Zhang, Jian; Cui, Hang; Ma, Chunli; Wu, Xiaoxin; Cui, Qiliang [State Key Laboratory of Superhard Materials, Jilin University, Changchun, Jilin 130012 (China); Zhu, Peifen [Department of Electrical and Computer Engineering, Lehigh University, Bethlehem, Pennsylvania 18015 (United States); Zhu, Hongyang, E-mail: hongyangzhu@jlu.edu.cn [State Key Laboratory of Superhard Materials, Jilin University, Changchun, Jilin 130012 (China); College of Materials Science and Engineering, Jilin University, Changchun, Jilin 130012 (China); Ma, Yanzhang [Department of Mechanical Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)

    2014-01-14T23:59:59.000Z

    The Eu-doped yttria (Y{sub 2}O{sub 3}:Eu{sup 3+}) has been investigated by the in situ high-pressure angle dispersive synchrotron X-ray diffraction (XRD) and the photoluminescence (PL) spectroscopy. The red shift and intensity ratio variation of emissions with increasing pressure were observed and elucidated. It was found that the red shift of emissions is related to the expansion of the f orbit of the Eu{sup 3+} and the intensity ratio variation of emissions is ascribed to the change of the crystal field under high pressure. The pressure-induced changes in spectrum are related to the phase transition, which was confirmed by XRD pattern. The two high pressure phases were identified as the monoclinic (C2/m) phase and hexagonal (P-3m1) phase by the Rietveld refinement.

  3. {sup 152}Eu depths profiles granite and concrete cores exposed to the Hiroshima atomic bomb

    SciTech Connect (OSTI)

    Shizuma, Kiyoshi; Iwatani, Kazuo [Hiroshima Univ. (Japan); Oka, Takamitsu [Kure Univ. (Japan)] [and others

    1997-06-01T23:59:59.000Z

    Two granite and two concrete core samples were obtained within 500 m from the hypocenter of the Hiroshima atomic bomb, and the depth profile of {sup 152}Eu was measured to evaluate the incident neutron spectrum. The granite cores were obtained from a pillar of the Motoyasu Bridge located 101 m from the hypocenter and from a granite rock in the Shirakami Shrine (379 m); the concrete cores were obtained from a gate in the Gokoku Shrine (398 m) and from top of the Hiroshima bank (250 m). The profiles of the specific activities of the cores were measured to a depth of 40 cm from the surface using low background germanium (Ge) spectrometers. According to the measured depth profiles, relaxation lengths of incident neutrons were derived as 13.6 cm for Motoyasu Bridge pillar (granite), 12.2 cm for Shirakami Shrine core (granite), and 9.6 cm for concrete cores of Gokoku Shrine and Hiroshima Bank. In addition, a comparison of the granite cores in Hiroshima showed good agreement with Nagasaki data. Present results indicates that the depth profile of {sup 152}Eu reflects incident neutrons not so high but in the epithermal region. 19 refs., 7 figs., 8 tabs.

  4. High-pressure powder x-ray diffraction study of EuVO4

    E-Print Network [OSTI]

    Garg, Alka B

    2015-01-01T23:59:59.000Z

    The high-pressure structural behavior of europium orthovanadate has been studied using in-situ, synchrotron based, high-pressure x-ray powder diffraction technique. Angle-dispersive x-ray diffraction measurements were carried out at room temperature up to 34.7 GPa using a diamond-anvil cell, extending the pressure range reported in previous experiments. We confirmed the occurrence of zircon-scheelite phase transition at 6.8 GPa and the coexistence of low- and high-pressure phases up to 10.1 GPa. In addition, clear evidence of a scheelite-fregusonite transition is found at 23.4 GPa. The fergusonite structure remains stable up to 34.7 GPa, the highest pressure reached in the present measurements. A partial decomposition of EuVO4 was also observed from 8.1 to 12.8 GPa, however, this fact did not preclude the identification of the different crystal structures of EuVO4. The crystal structures of the different phases have been Rietveld refined and their equations of state (EOS) have been determined. The results are...

  5. The Characterization of Eu2+-Doped Mixed Alkaline-Earth Iodide Scintillator Crystals

    SciTech Connect (OSTI)

    Neal, John S [ORNL; Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Wisniewski, D. [Institute of Physics, Nicolaus Copernicus University, Toru?, Poland; Kolopus, James A [ORNL; Cherepy, Nerine [Lawrence Livermore National Laboratory (LLNL); Payne, Stephen A. [Lawrence Livermore National Laboratory (LLNL)

    2011-01-01T23:59:59.000Z

    The high-performance inorganic scintillator, SrI2:Eu2+, when activated with divalent europium in the concentration range of 3 to 6%, has shown great promise for use in applications that require high-energy-resolution gamma-ray detection. We have recently grown and tested crystals in which other alkaline-earth ions have been partially substituted for Sr ions. Specifically, europium-doped single crystals have been grown in which up to 30 at % of the strontium ions have been substituted for either by barium, magnesium, or calcium ions. In the case of the strontium iodide scintillator host, a material that is characterized by an orthorhombic crystal structure, there are three other column IIA elements that are obvious choices for investigations whose purpose is to realize potential improvements in the performance of SrI2:Eu2+-based scintillators via the replacement of strontium ions with either Mg2+, Ca2+, or Ba2+. Light yields of up to 81,400 photons/MeV with an associated energy resolution of 3.7% (fwhm for 662 keV gamma-rays) have been observed in the case of a partial substitution of Ba2+ for Sr2+. The measured decay times ranged from 1.1 to 2.0 s, while the peak emission wavelengths ranged from 432 to 438 nm.

  6. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01T23:59:59.000Z

    carbon has a high carbon sequestration potential due to itsin soil can lead to sustainable carbon sequestration.process takes carbon sequestration from afforestation a step

  7. Method for synthesizing carbon nanotubes

    DOE Patents [OSTI]

    Fan, Hongyou

    2012-09-04T23:59:59.000Z

    A method for preparing a precursor solution for synthesis of carbon nanomaterials, where a polar solvent is added to at least one block copolymer and at least one carbohydrate compound, and the precursor solution is processed using a self-assembly process and subsequent heating to form nanoporous carbon films, porous carbon nanotubes, and porous carbon nanoparticles.

  8. GETTING CARBON CAPTURE AND STORAGE

    E-Print Network [OSTI]

    Haszeldine, Stuart

    GETTING CARBON CAPTURE AND STORAGE TECHNOLOGIES TO MARKET BREAKING THE DEADLOCK Report of a Science: Carbon Capture and Storage © OECD/IEA 2009, fig. 1, p. 6 Figures 2 and 3 reprinted with permission from `UK Carbon storage and capture, where is it?' by Stuart Haszeldine, Professor of Carbon Capture

  9. Research Report Forests and carbon

    E-Print Network [OSTI]

    , baseline, carbon, climate change mitigation, forestry, quality assurance, sequestration. FCRP013/FCResearch Report Forests and carbon: a review of additionality #12;#12;Forests and carbon: a review. ISBN 978-0-85538-816-4 Valatin, G. (2011). Forests and carbon: a review of additionality. Forestry

  10. 4, 1367, 2007 Modelling carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 13­67, 2007 Modelling carbon overconsumption and extracellular POC formation M. Schartau et carbon overconsumption and the formation of extracellular particulate organic carbon M. Schartau1 , A Correspondence to: M. Schartau (markus.schartau@gkss.de) 13 #12;BGD 4, 13­67, 2007 Modelling carbon

  11. ATK - Supersonic Carbon Capture

    ScienceCinema (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO); Calayag, Bon (ATK, Program Manager)

    2014-04-11T23:59:59.000Z

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  12. Carbon Capture Pilots (Kentucky)

    Broader source: Energy.gov [DOE]

    Support for the Carbon Management Research Group (CMRG), a public/private partnership consisting of most of the Commonwealth’s utilities, the Electric Power Research Institute, the Center for...

  13. Extrasolar Carbon Planets

    E-Print Network [OSTI]

    Marc J. Kuchner; S. Seager

    2005-05-02T23:59:59.000Z

    We suggest that some extrasolar planets planets and low-mass white dwarf planets are especially good candidate members of this new class of planets, but these objects could also conceivably form around stars like the Sun. This planet-formation pathway requires only a factor of two local enhancement of the protoplanetary disk's C/O ratio above solar, a condition that pileups of carbonaceous grains may create in ordinary protoplanetary disks. Hot, Neptune-mass carbon planets should show a significant paucity of water vapor in their spectra compared to hot planets with solar abundances. Cooler, less massive carbon planets may show hydrocarbon-rich spectra and tar-covered surfaces. The high sublimation temperatures of diamond, SiC, and other carbon compounds could protect these planets from carbon depletion at high temperatures.

  14. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  15. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01T23:59:59.000Z

    S O N I A YE H Low Carbon Fuel Standards The most direct andalternative transportation fuels is to spur innovation withstandard for upstream fuel producers. hen it comes to energy

  16. Activated carbon aerogels

    SciTech Connect (OSTI)

    Hanzawa, Y.; Kaneko, K. [Chiba Univ. (Japan)] [Chiba Univ. (Japan); Pekala, R.W. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Dresselhaus, M.S. [Massachusetts Inst. of Technology, Cambridge, MA (United States)] [Massachusetts Inst. of Technology, Cambridge, MA (United States)

    1996-12-25T23:59:59.000Z

    Activated carbon aerogels were obtained from the CO{sub 2} activation of the carbon aerogels. The adsorption isotherms of nitrogen on activated carbon aerogels at 77 K were measured and analyzed by the high-resolution {alpha}{sub s} plot to evaluate their porosities. The {alpha}{sub s} plot showed an upward deviation from linearity below {alpha}{sub s} = 0.5, suggesting that the presence of micropores becomes more predominant with the extent of the activation. Activation increased noticeably the pore volume and the surface area (the maximum value: 2600 m{sup 2}.g{sup -1}) without change of the basic network structure of primary particles. Activated carbon aerogels had a bimodal pore size distribution of uniform micropores and mesopores. 16 refs., 2 figs., 1 tab.

  17. ATK - Supersonic Carbon Capture

    SciTech Connect (OSTI)

    Castrogiovanni, Anthony (ACEnT Laboratories, President and CEO) [ACEnT Laboratories, President and CEO; Calayag, Bon (ATK, Program Manager) [ATK, Program Manager

    2014-03-05T23:59:59.000Z

    ATK and ACEnt Laboratories, with the help of ARPA-E funding, have taken an aerospace problem, supersonic condensation, and turned it into a viable clean energy solution for carbon capture.

  18. Quantum size effects and transport phenomena in PbSe quantum wells and PbSe/EuS superlattices

    SciTech Connect (OSTI)

    Rogacheva, E. I.; Nashchekina, O. N.; Ol'khovskaya, S. I.; Sipatov, A. Yu. [National technical university Kharkov polytechnic institute, 21 Frunze St., Kharkov, 61002 (Ukraine); Dresselhaus, M. S. [Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge MA 02139 (United States)

    2013-12-04T23:59:59.000Z

    It is established that the room-temperature dependences of transport properties on the total thickness of PbSe layers d in PbSe/EuS superlattices exhibit an oscillatory behavior. It is shown that the oscillation period ?d practically coincides with the period of the thickness oscillations observed earlier in single PbSe/EuS quantum well. The non-monotonic character of these dependences is attributed to quantum size effects. The theoretically estimated and experimentally determined ?d values are in good agreement.

  19. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14T23:59:59.000Z

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  20. Carbon dioxide removal process

    DOE Patents [OSTI]

    Baker, Richard W.; Da Costa, Andre R.; Lokhandwala, Kaaeid A.

    2003-11-18T23:59:59.000Z

    A process and apparatus for separating carbon dioxide from gas, especially natural gas, that also contains C.sub.3+ hydrocarbons. The invention uses two or three membrane separation steps, optionally in conjunction with cooling/condensation under pressure, to yield a lighter, sweeter product natural gas stream, and/or a carbon dioxide stream of reinjection quality and/or a natural gas liquids (NGL) stream.

  1. Energy Risk Management with Carbon Assets Julien Chevallier*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the EU Emissions Trading Scheme. In a stylized exercise, we compute returns, standard deviations as part of the European Union Emissions Trading Scheme (EU ETS)1 , present very peculiar characteristics

  2. Carbon based prosthetic devices

    SciTech Connect (OSTI)

    Devlin, D.J.; Carroll, D.W.; Barbero, R.S.; Archuleta, T. [Los Alamos National Lab., NM (US); Klawitter, J.J.; Ogilvie, W.; Strzepa, P. [Ascension Orthopedics (US); Cook, S.D. [Tulane Univ., New Orleans, LA (US). School of Medicine

    1998-12-31T23:59:59.000Z

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The project objective was to evaluate the use of carbon/carbon-fiber-reinforced composites for use in endoprosthetic devices. The application of these materials for the metacarpophalangeal (MP) joints of the hand was investigated. Issues concerning mechanical properties, bone fixation, biocompatibility, and wear are discussed. A system consisting of fiber reinforced materials with a pyrolytic carbon matrix and diamond-like, carbon-coated wear surfaces was developed. Processes were developed for the chemical vapor infiltration (CVI) of pyrolytic carbon into porous fiber preforms with the ability to tailor the outer porosity of the device to provide a surface for bone in-growth. A method for coating diamond-like carbon (DLC) on the articulating surface by plasma-assisted chemical vapor deposition (CVD) was developed. Preliminary results on mechanical properties of the composite system are discussed and initial biocompatibility studies were performed.

  3. Carbon Characterization Laboratory Report

    SciTech Connect (OSTI)

    David Swank; William Windes; D.C. Haggard; David Rohrbaugh; Karen Moore

    2009-03-01T23:59:59.000Z

    The newly completed Idaho National Laboratory (INL) Carbon Characterization Laboratory (CCL) is located in Lab-C20 of the Idaho National Laboratory Research Center. This laboratory was established under the Next Generation Nuclear Plant (NGNP) Project to support graphite research and development activities. The CCL is designed to characterize and test carbon-based materials such as graphite, carbon-carbon composites, and silicon-carbide composite materials. The laboratory is fully prepared to measure material properties for nonirradiated carbon-based materials. Plans to establish the laboratory as a radiological facility within the next year are definitive. This laboratory will be modified to accommodate irradiated materials, after which it can be used to perform material property measurements on both irradiated and nonirradiated carbon-based material. Instruments, fixtures, and methods are in place for preirradiation measurements of bulk density, thermal diffusivity, coefficient of thermal expansion, elastic modulus, Young’s modulus, Shear modulus, Poisson ratio, and electrical resistivity. The measurement protocol consists of functional validation, calibration, and automated data acquisition.

  4. The European Forest Institute and the Finnish Forest Research Institute: The supply of woody biomass from the forests in the EU can be

    E-Print Network [OSTI]

    biomass from the forests in the EU can be significantly increased The supply of woody biomass from and recycled wood) for the 27 EU member states. As with woody biomass from forests, the supply of woody biomassThe European Forest Institute and the Finnish Forest Research Institute: The supply of woody

  5. Japan hopes for rapid accord with EU on nuclear reactor Japanese Prime Minister Junichiro Koizumi said Monday that he hopes to resolve a dispute with the

    E-Print Network [OSTI]

    Japan hopes for rapid accord with EU on nuclear reactor 02/05/2005 Japanese Prime Minister nuclear reactor as soon as possible. Koizumi discussed the row over plans for the International Terms and Conditions 5/2/05 8:59 AMEUbusiness - Japan hopes for rapid accord with EU on nuclear reactor

  6. On the Stochastic Properties of Carbon Futures Prices Julien Chevallier

    E-Print Network [OSTI]

    , in the wider context of the European Union Emissions Trading Scheme (EU ETS) and the price formation

  7. Measurement of carbon capture efficiency and stored carbon leakage

    DOE Patents [OSTI]

    Keeling, Ralph F.; Dubey, Manvendra K.

    2013-01-29T23:59:59.000Z

    Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon capture and storage process. Optionally, the data can be used to quantify a carbon dioxide concentration increase at the first location that is attributable to escape of carbon dioxide from the source and to calculate a rate of escape of carbon dioxide from the source by executing a model of gas-phase transport using at least the first carbon dioxide concentration increase. Related systems, methods, and articles of manufacture are also described.

  8. High-pressure x-ray diffraction study of YBO{sub 3}/Eu{sup 3+}, GdBO{sub 3}, and EuBO{sub 3}: Pressure-induced amorphization in GdBO{sub 3}

    SciTech Connect (OSTI)

    Wang, Pei; Xu, Chao; Ren, Xiangting; Lei, Li; Wang, Shanmin; Peng, Fang; Yan, Xiaozhi; Liu, Dongqiong; Wang, Qiming [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); He, Duanwei, E-mail: duanweihe@scu.edu.cn [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Institute of Fluid Physics and National Key Laboratory of Shockwave and Detonation Physics, China Academy of Engineering Physics, Mianyang 621900 (China); Xiong, Lun; Liu, Jing [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

    2014-01-28T23:59:59.000Z

    Angle-dispersive synchrotron X-ray diffraction measurements were performed on vaterite-type YBO{sub 3}/Eu{sup 3+}, GdBO{sub 3}, and EuBO{sub 3}, respectively, up to 41?GPa at room temperature using a diamond-anvil cell. Pressure-induced amorphization was observed in hexagonal GdBO{sub 3} with a significant compression along the c-axis. Compared to the ions of the distorted GdBO{sub 3} phase, its anions may lose their long-range order prior to the cations at high pressures. Based on the experimental pressure-volume data, the obtained bulk moduli of YBO{sub 3}/Eu{sup 3+} and GdBO{sub 3} are 329 and 321?GPa, respectively, which are more than 90% larger than that of EuBO{sub 3} (167?GPa) and are presumably attributed to Gd{sup 3+} and Y{sup 3+} with a high density of d valence electrons.

  9. WESTCARB Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The West Coast Regional Carbon Sequestration Partnership (known as WESTCARB) was established in Fall 2003. It is one of seven research partnerships co-funded by DOE to characterize regional carbon sequestration opportunities and conduct pilot-scale validation tests. The California Energy Commission manages WESTCARB and is a major co-funder. WESTCARB is characterizing the extent and capacity of geologic formations capable of storing CO2, known as sinks. Results are entered into a geographic information system (GIS) database, along with the location of major CO2-emitting point sources in each of the six WESTCARB states, enabling researchers and the public to gauge the proximity of candidate CO2 storage sites to emission sources and the feasibility of linking them via pipelines. Specifically, the WESTCARB GIS database (also known as the carbon atlas) stores layers of geologic information about potential underground storage sites, such as porosity and nearby fault-lines and aquifers. Researchers use these data, along with interpreted geophysical data and available oil and gas well logs to estimate the region's potential geologic storage capacity. The database also depicts existing pipeline routes and rights-of-way and lands that could be off-limits, which can aid the development of a regional carbon management strategy. The WESTCARB Carbon Atlas, which is accessible to the public, provides a resource for public discourse on practical solutions for regional CO2 management. A key WESTCARB partner, the Utah Automated Geographic Reference Center, has developed data serving procedures to enable the WESTCARB Carbon Atlas to be integrated with those from other regional partnerships, thereby supporting the U.S. Department of Energy's national carbon atlas, NATCARB

  10. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2008-10-21T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  11. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2012-01-24T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  12. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  13. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2011-08-16T23:59:59.000Z

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  14. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott J; Alvizo, Oscar

    2013-10-29T23:59:59.000Z

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  15. Chemically modified carbonic anhydrases useful in carbon capture systems

    DOE Patents [OSTI]

    Novick, Scott; Alvizo, Oscar

    2013-01-15T23:59:59.000Z

    The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

  16. activated carbon composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  17. ammonium carbonates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  18. a537 carbon steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  19. americium carbonates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  20. affecting carbon tetrachloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  1. Carbon contamination topography analysis of EUV masks

    E-Print Network [OSTI]

    Fan, Y.-J.

    2010-01-01T23:59:59.000Z

    induced carbon contamination of extreme ultraviolet optics,"and A. Izumi. "Carbon contamination of EL'V mask: filmEffect of Carbon Contamination on the Printing Performance

  2. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01T23:59:59.000Z

    H. , 2005, IPCC: Carbon Capture and Storage: Technical05CH11231. INTRODUCTION Carbon capture and storage (CCS)Development Mechanism CCS: Carbon Capture and Storage C02e:

  3. Sandia National Laboratories: Carbon Capture & Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture & Storage High-Pressure and High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies On February 21, 2013, in Carbon Capture, Carbon Capture &...

  4. ASSESSMENT OF HOUSEHOLD CARBON FOOTPRINT REDUCTION POTENTIALS

    E-Print Network [OSTI]

    Masanet, Eric

    2010-01-01T23:59:59.000Z

    of  American household carbon footprint. ” Ecological and  limitations) of carbon footprint estimates toward of the art in carbon footprint analyses for California, 

  5. On carbon footprints and growing energy use

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01T23:59:59.000Z

    On carbon footprints and growing energy use Curtis M.reductions in the carbon footprint of a growing organizationhis own organization's carbon footprint and answers this

  6. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01T23:59:59.000Z

    around Surface-Attached Carbon Nanotubes. Ind. Eng. Chem.the flexural rigidity of carbon nanotube ensembles. AppliedNanotechnology in Carbon Materials. Acta Metallurgica, 1997.

  7. Participatory Carbon Monitoring: Operational Guidance for National...

    Open Energy Info (EERE)

    Participatory Carbon Monitoring: Operational Guidance for National REDD+ Carbon Accounting Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Participatory Carbon...

  8. A Top-down and Bottom-up look at Emissions Abatement in Germany in response to the EU ETS

    E-Print Network [OSTI]

    Feilhauer, Stephan M. (Stephan Marvin)

    2008-01-01T23:59:59.000Z

    This paper uses top-down trend analysis and a bottom-up power sector model to define upper and lower boundaries on abatement in Germany in the first phase of the EU Emissions Trading Scheme (2005-2007). Long-term trend ...

  9. Abstract--This paper describes Nice Grid, a demonstration project part of the European initiative Grid4EU. The project

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Grid4EU. The project aims at developing a smart solar neighbourhood in the urban area of the city with forecasts of solar power production and load in a local energy management system. The paper, which demonstration projects on Smart Grid. Index Terms-- Energy storage, Forecasting, Photovoltaic systems, Smart

  10. Role of Bioenergy in the Kyoto Protocol, in the EU-ETS and in future Climate Agreements

    E-Print Network [OSTI]

    of bioenergy use through: Internal emission reductions within the Greenhouse Gas capped sectors Offsetting/CDM CDM project pipeline: > 1000 projects of which: Registered projects: 334 Expected CERs (from RISOE Distribution of projects Bioenergy #12;The EU-ETS and biomass (1) In January 2005 the European

  11. "Japan and the EU in the global economy -challenges and opportunities" Graduate School of Economics, Kobe University

    E-Print Network [OSTI]

    Banbara, Mutsunori

    "Japan and the EU in the global economy - challenges and opportunities" Bruegel Graduate School and financial linkages between Europe and Japan: new evidence and scope for improvement André Sapir, Senior of Economics, Kobe University; Senior Research Fellow, Policy Research Institute, Ministry of Finance, Japan

  12. From October 10, 2007 Report of E.U. Environmental Agency on Europe's environment: Recycling and WTE are complementary

    E-Print Network [OSTI]

    Columbia University

    From October 10, 2007 Report of E.U. Environmental Agency on Europe's environment: Recycling detrimental effects on public health and the environment. When comparing waste disposal options recycling and incineration with energy recovery. In contrast, countries with a medium level of landfill (25

  13. Effect of fluoride in NTS groundwaters on the aqueous speciation of U, Np, Pu, Am and Eu

    SciTech Connect (OSTI)

    Bruton, C J; Nimz, G J

    2005-03-22T23:59:59.000Z

    To address SNJV concerns that fluoride in Nevada Test site (NTS) groundwaters may impact radionuclide speciation and transport, NTS water quality databases were obtained and scanned for analyses with high fluoride concentrations (> 10 mg/L). The aqueous speciation of nine representative samples of these groundwaters with added trace amounts of uranium (U), neptunium (Np), plutonium (Pu), americium (Am) and europium (Eu) was then calculated with the computer code EQ3NR assuming a temperature of 25 C, using currently available thermodynamic data for these species. Under conditions where U(VI), Np(V), Pu(IV), Am(III) and Eu(III) dominate, F complexes are insignificant (<1 mole %) for U, Np, Pu and Am. Eu-F complexes may be significant in groundwaters that lack bicarbonate, possess pH values less than about 7 at ambient temperatures, or contain F in extremely high concentrations (e.g. > 50 mg/L). The objective is to evaluate the extent to which fluoride in NTS groundwaters complex U(VI), Np(V), Pu(IV), Am(III) and Eu(III). The approach used is to screen existing databases of groundwater chemistry at NTS for waters with high fluoride concentrations and calculate the extent to which fluoride complexes with the nuclides of interest in these waters.

  14. REFUEL: an EU road map for biofuels , E. Deurwaarder and S. Lensink, ECN policy Studies, the Netherlands

    E-Print Network [OSTI]

    REFUEL: an EU road map for biofuels M. Londo1 , E. Deurwaarder and S. Lensink, ECN policy Studies), Poland K. Könighofer, Joanneum Research, Austria Abstract A successful mid-term development of biofuels calls for a robust road map. REFUEL assesses inter alia least-cost biofuel chain options, their benefits

  15. On the peculiar properties of triangular-chain EuCr{sub 3}(BO{sub 3}){sub 4} antiferromagnet

    SciTech Connect (OSTI)

    Gondek, ?., E-mail: lgondek@agh.edu.pl [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, al. Mickiewicza 30, 30-059 Kraków (Poland); Szytu?a, A. [M. Smoluchowski Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków (Poland); Przewo?nik, J.; ?ukrowski, J. [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, al. Mickiewicza 30, 30-059 Kraków (Poland); Prokhorov, A.; Chernush, L.; Zubov, E. [A.A. Galkin Donetsk Physico-Technical Institute, NANU, 83114 Donetsk, R. Luxembourg str. 72 (Ukraine); Dyakonov, V. [A.A. Galkin Donetsk Physico-Technical Institute, NANU, 83114 Donetsk, R. Luxembourg str. 72 (Ukraine); Institute of Physics, PAS, 02-668 Warsaw, Al. Lotników 32/46 (Poland); Duraj, R. [Institute of Physics Technical University of Cracow, Podchorazych 1, 30-084 Krakow (Poland); Tyvanchuk, Yu. [Analytical Chemistry Department, Ivan Franko National University of Lviv, Kyryla and Mephodiya 6, 79005 Lviv (Ukraine)

    2014-02-15T23:59:59.000Z

    In this paper we report studies on EuCr{sub 3}(BO{sub 3}){sub 4} compound, that is a member of newly discovered family of huntite-related specimens for non-linear optics. For the first time, the uncommon temperature dependence of the EuCr{sub 3}(BO{sub 3}){sub 4} lattice parameters is reported. Additionally, the magnetism of this compound is extremely interesting. Namely, a possible interplay in between potentially magnetic rare-earth ions and 3d metal stacked within quasi-1D chain that can lead to a great variety of magnetic behaviour. Indeed, in our studies we have found 3D-long range ordering with metamagnetic behaviour, while at higher temperature the magnetic chains become uncoupled. - Graphical abstract: Torsion-like vibrations are the key to understand negative thermal expansion along the a-axis. Display Omitted - Highlights: • EuCr{sub 3}(BO{sub 3}){sub 4} is a peculiar triangular-chain antiferromagnet. • Rare earth sublattice is non-magnetic with Eu{sup 3+} configuration. • Cr{sup 3+} magnetic moments show 1-D behaviour along with spin fluctuations. • Torsion vibrations of Cr triangular tubes lead to anomalous expansion of unit cell.

  16. Comparative analysis of the life cycle impact assessment of available cement inventories in the EU

    SciTech Connect (OSTI)

    Josa, Alejandro [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain)]. E-mail: alejandro.josa@upc.edu; Aguado, Antonio [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain); Cardim, Arnaldo [Civil Engineering Department, Polytechnic School of Penambuco University, Rua Benfica, 455-Madalena, CEP 50.750-410 (Brazil); Byars, Ewan [Centre for Cement and Concrete, Department of Civil and Structural Engineering, University of Sheffield, Sir Frederick Mappin Building, Mappin Street, Sheffield S1 3JD (United Kingdom)

    2007-05-15T23:59:59.000Z

    Life cycle impact assessment (LCIA) is one of basic steps in life cycle assessment methodology (LCA). This paper presents a comparative study of the LCIA of different life cycle inventories (LCI) for EU cements. The analysis unit used is the manufacture of 1 kg of cement, from 'cradle to gate'. The impact categories considered are those resulting from the manufacture of cement and include greenhouse effects, acidification, eutrophication and summer and winter smog, amongst others. The results of the study highlighted some inconsistencies in existing inventories. As for the LCIA, the main environmental interventions related to cement manufacture were classified and characterised and their effect on different impact categories analysed. Differences observed in evaluation of the impact of cement type were essentially related to their clinker content.

  17. Antimagnetic rotation and sudden change of electric quadrupole transition strength in 143Eu

    E-Print Network [OSTI]

    S. Rajbanshi; S. Roy; Somnath Nag; Abhijit Bisoi; S. Saha; J. Sethi; T. Trivedi; T. Bhattacharjee; S. Bhattacharyya; S. Chattopadhyay; G. Gangopadhyay; G. Mukherjee; R. Palit; R. Raut; M. Saha Sarkar; A. K. Singh; A. Goswami

    2015-05-22T23:59:59.000Z

    Lifetimes of the states in the quadrupole structure in 143Eu have been measured using the Doppler shift attenuation method as well as parity of the states in the sequence has been firmly identified from polarization measurement using the Indian National Gamma Array. The decreasing trends of the deduced quadrupole transition strength B(E2) with spin, along with increasing J (2) /B(E2) values before band crossing, conclusively establish the origin of these states as arising out of antimagnetic rotation. The abrupt increase in the B(E2) values after the band crossing in the quadrupole band, a novel feature observed in the present experiment, may indicates the crossing of different shears configurations resulting in re-opening of shears structure. The results are well reproduced by numerical calculation within the framework of semi-classical geometric model.

  18. Pulsed laser deposition of high-quality thin films of the insulating ferromagnet EuS

    SciTech Connect (OSTI)

    Yang, Qi I., E-mail: qiyang@stanford.edu [Department of Physics, Stanford University, Stanford, California 94305 (United States); Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305 (United States); Zhao, Jinfeng; Risbud, Subhash H. [Department of Chemical Engineering and Materials Science, University of California, Davis, California 95616 (United States); Zhang, Li; Dolev, Merav [Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305 (United States); Department of Applied Physics, Stanford University, Stanford, California 94305 (United States); Fried, Alexander D. [Department of Physics, Stanford University, Stanford, California 94305 (United States); Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305 (United States); Marshall, Ann F. [Stanford Nanocharacterization Laboratory, Stanford University, Stanford, California 94305 (United States); Kapitulnik, Aharon [Department of Physics, Stanford University, Stanford, California 94305 (United States); Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305 (United States); Department of Applied Physics, Stanford University, Stanford, California 94305 (United States)

    2014-02-24T23:59:59.000Z

    High-quality thin films of the ferromagnetic insulator europium(II) sulfide (EuS) were fabricated by pulsed laser deposition on Al{sub 2}O{sub 3} (0001) and Si (100) substrates. A single orientation was obtained with the [100] planes parallel to the substrates, with atomic-scale smoothness indicates a near-ideal surface topography. The films exhibit uniform ferromagnetism below 15.9?K, with a substantial component of the magnetization perpendicular to the plane of the films. Optimization of the growth condition also yielded truly insulating films with immeasurably large resistance. This combination of magnetic and electric properties opens the gate for future devices that require a true ferromagnetic insulator.

  19. EU Framework 6 Project: Predictive Toxicology (PredTox)-overview and outcome

    SciTech Connect (OSTI)

    Suter, Laura, E-mail: Laura.suter-dick@roche.com [Hoffmann-La Roche AG, Basel (Switzerland); Schroeder, Susanne [Nycomed GmbH, Barsbuettel (Germany); Meyer, Kirstin [Bayer Schering Pharma AG, Berlin (Germany); Gautier, Jean-Charles [Sanofi aventis R and D, Disposition, Safety and Animal Research, Vitry sur Seine (France); Amberg, Alexander [Sanofi aventis R and D, Disposition, Safety and Animal Research, Frankfurt (Germany); Wendt, Maria; Gmuender, Hans [Genedata AG, Basel (Switzerland); Mally, Angela [University of Wuerzburg, Institut fuer Toxikologie, Wuerzburg (Germany); Boitier, Eric [Sanofi aventis R and D, Disposition, Safety and Animal Research, Vitry sur Seine (France); Ellinger-Ziegelbauer, Heidrun [Bayer Schering Pharma AG, Wuppertal (Germany); Matheis, Katja [Boehringer Ingelheim Pharma GmbH and Co. KG, Biberach (Germany); Pfannkuch, Friedlieb [Hoffmann-La Roche AG, Basel (Switzerland)

    2011-04-15T23:59:59.000Z

    In this publication, we report the outcome of the integrated EU Framework 6 Project: Predictive Toxicology (PredTox), including methodological aspects and overall conclusions. Specific details including data analysis and interpretation are reported in separate articles in this issue. The project, partly funded by the EU, was carried out by a consortium of 15 pharmaceutical companies, 2 SMEs, and 3 universities. The effects of 16 test compounds were characterized using conventional toxicological parameters and 'omics' technologies. The three major observed toxicities, liver hypertrophy, bile duct necrosis and/or cholestasis, and kidney proximal tubular damage were analyzed in detail. The combined approach of 'omics' and conventional toxicology proved a useful tool for mechanistic investigations and the identification of putative biomarkers. In our hands and in combination with histopathological assessment, target organ transcriptomics was the most prolific approach for the generation of mechanistic hypotheses. Proteomics approaches were relatively time-consuming and required careful standardization. NMR-based metabolomics detected metabolite changes accompanying histopathological findings, providing limited additional mechanistic information. Conversely, targeted metabolite profiling with LC/GC-MS was very useful for the investigation of bile duct necrosis/cholestasis. In general, both proteomics and metabolomics were supportive of other findings. Thus, the outcome of this program indicates that 'omics' technologies can help toxicologists to make better informed decisions during exploratory toxicological studies. The data support that hypothesis on mode of action and discovery of putative biomarkers are tangible outcomes of integrated 'omics' analysis. Qualification of biomarkers remains challenging, in particular in terms of identification, mechanistic anchoring, appropriate specificity, and sensitivity.

  20. Carbon Chemistry in interstellar clouds

    E-Print Network [OSTI]

    Maryvonne Gerin; David Fosse; Evelyne Roueff

    2002-12-03T23:59:59.000Z

    We discuss new developments of interstellar chemistry, with particular emphasis on the carbon chemistry. We confirm that carbon chains and cycles are ubiquitous in the ISM and closely chemically related to ea ch other, and to carbon. Investigation of the carbon budget in shielded and UV illuminated gas shows that the inventory of interstellar molecules is not complete and more complex molecules with 4 or more carbon atoms must be present. Finally we discuss the consequences for the evolution of clouds and conclude that the ubiquitous presence of carbon chains and cycles is not a necessary consequence of a very young age for interstellar clouds.

  1. Formation of rare earth carbonates using supercritical carbon dioxide

    DOE Patents [OSTI]

    Fernando, Quintus (Tucson, AZ); Yanagihara, Naohisa (Zacopan, MX); Dyke, James T. (Santa Fe, NM); Vemulapalli, Krishna (Tuscon, AZ)

    1991-09-03T23:59:59.000Z

    The invention relates to a process for the rapid, high yield conversion of select rare earth oxides or hydroxides, to their corresponding carbonates by contact with supercritical carbon dioxide.

  2. Carbon-particle generator

    DOE Patents [OSTI]

    Hunt, A.J.

    1982-09-29T23:59:59.000Z

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  3. ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION EFFORTS

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION examines biological carbon sequestration using a grassland restoration as a model system. Chapter 1 for biological carbon sequestration. In this analysis, we found that significantly greater soil carbon

  4. Ultrahard carbon nanocomposite films

    SciTech Connect (OSTI)

    SIEGAL,MICHAEL P.; TALLANT,DAVID R.; PROVENCIO,PAULA P.; OVERMYER,DONALD L.; SIMPSON,REGINA L.; MARTINEZ-MIRANDA,L.J.

    2000-01-27T23:59:59.000Z

    Modest thermal annealing to 600 C of diamondlike amorphous-carbon (a-C) films grown at room temperature results in the formation of carbon nanocomposites with hardness similar to diamond. These nanocomposite films consist of nanometer-sized regions of high density a-C embedded in an a-C matrix with a reduced density of 5--10%. The authors report on the evolution of density and bonding topologies as a function of annealing temperature. Despite a decrease in density, film hardness actually increases {approximately} 15% due to the development of the nanocomposite structure.

  5. Low Cost Carbon Fiber Production Carbon Fiber Manufacturing Cost Modeling

    E-Print Network [OSTI]

    to bond with composite matrix material. It is important that a carbon fiber manufacturing cost model manufactured with carbon fiber as opposed to traditional materials such as steel, automotive parts are able associated with both the manufacture of carbon fibers themselves as well as their composites. Traditional

  6. Irradiation Stability of Carbon Nanotubes 

    E-Print Network [OSTI]

    Aitkaliyeva, Assel

    2010-01-14T23:59:59.000Z

    Ion irradiation of carbon nanotubes is a tool that can be used to achieve modification of the structure. Irradiation stability of carbon nanotubes was studied by ion and electron bombardment of the samples. Different ion ...

  7. Sensor applications of carbon nanotubes

    E-Print Network [OSTI]

    Rushfeldt, Scott I

    2005-01-01T23:59:59.000Z

    A search of published research on sensing mechanisms of carbon nanotubes was performed to identify applications in which carbon nanotubes might improve on current sensor technologies, in either offering improved performance, ...

  8. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts to...

  9. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  10. Carbon nanotubes: synthesis and functionalization 

    E-Print Network [OSTI]

    Andrews, Robert

    2007-01-01T23:59:59.000Z

    conditions were then used as the basis of several comparative CVD experiments showing that the quality of nanotubes and the yield of carbon depended on the availability of carbon to react. The availability could be controlled by the varying concentration...

  11. First Proof of Ferromagnetic Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Proof of Ferromagnetic Carbon Print Although it has long been suspected that carbon belongs on the short list of materials that can be magnetic at room temperature, attempts...

  12. Photo-induced charge state conversion of Eu{sup 2+} in Ca{sub 2}ZnSi{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Kamioka, Hayato [Graduate School of Pure and Applied Sciences, University of Tsukuba, Ten-noudai 1-1-1, Tsukuba, Ibaraki 305-8571 (Japan); Hirano, Masahiro [Transparent Electro-Active Materials Project, ERATO-SORST, Japan Science and Technology, Bldg. S2-6F East, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan); Hosono, Hideo [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan)

    2009-09-01T23:59:59.000Z

    Eu{sup 2+} doped sorosilicate Ca{sub 2}ZnSi{sub 2}O{sub 7} (melilite) exhibits a broad band emission peaking at approx600 nm(approx2 eV) due to the electric dipole allowed transition of 4f{sup 6}5d{sup 1} to 4f{sup 7} of Eu{sup 2+} by an excitation with blue light (460 nm). Strong O{sup 2-} ligand field with low symmetry due to the layered tetragonal crystallographic structure of the melilite may play a dominant role in lowering the emission band energy to approx2 eV. In addition, line emissions attributable to the transitions from {sup 5}D{sub 0} to {sup 7}F{sub J} of Eu{sup 3+} ions are detected by an excitation with deep UV light with sub-360 nm wavelengths. This is due to the formation of transient Eu{sup 3+} ions via charge transfer from Eu{sup 2+} to the matrix. The lifetime of the transient Eu{sup 3+} ion is found to be 58 ms by a pump-probe measurement, in which UV pulse laser and green continuous wave laser are employed as pump and probe lights, respectively. Based on these results, the energy diagram of Eu{sup 2+} in Ca{sub 2}ZnSi{sub 2}O{sub 7} is proposed.

  13. 14 April 2001 tmospheric carbon dioxide

    E-Print Network [OSTI]

    Teskey, Robert O.

    emissions is through increased carbon sequestration into forests. In a large-scale assessment, Birdsey- ing carbon sequestration in southern forests. Carbon sequestration via southern pine forests may policy commitments. Keywords: carbon sequestration; southern pine forests ABSTRACT MEETING GLOBAL POLICY

  14. Relationship between Eu{sup 3+} reduction and glass polymeric structure in Al{sub 2}O{sub 3}-modified borate glasses under air atmosphere

    SciTech Connect (OSTI)

    Jiao, Qing; Yu, Xue; Xu, Xuhui; Zhou, Dacheng; Qiu, Jianbei, E-mail: qiu@kmust.edu.cn

    2013-06-15T23:59:59.000Z

    The reduction of Eu{sup 3+} to Eu{sup 2+} is realized efficiently in Eu{sub 2}O{sub 3}-doped borate glasses prepared under air condition by melting-quenching method. Luminescent spectra show an increasing tendency of Eu{sup 2+} emission with increasing Al{sub 2}O{sub 3} concentration in B{sub 2}O{sub 3}–Na{sub 2}O glasses. It is interesting that significant enhancement appeared of Eu{sup 2+} luminescence in the Al{sub 2}O{sub 3}-rich sample comparing to the samples of Al{sub 2}O{sub 3} less than 6 mol%. FTIR and Raman scattering measurements indicated that some new vibration modes assigned to the low-polymerized structure groups decomposed from the slight Al{sub 2}O{sub 3} dopant samples. These results demonstrated that the polymerization of the glass structure decreased with increasing incorporation of Al{sub 2}O{sub 3} into the borate glasses, linking to the efficiency of Eu{sup 3+} self-reduction in air at high temperature. - graphical abstract: A novel europium valence reduction phenomenon occurred in Al{sub 2}O{sub 3} modified borate glasses, FTIR and Raman measurements revealed that high polymeric groups were destroyed to low polymery structures with Al{sub 2}O{sub 3} addition. - Highlights: • The efficient reduction of Eu{sup 3+} to Eu{sup 2+} is observed in the B{sub 2}O{sub 3}–Na{sub 2}O glasses. • Eu{sup 2+} luminescence is significant enhanced in the Al{sub 2}O{sub 3}-rich glasses. • The introduction of Al{sub 2}O{sub 3} changed the network structure of the borate glasses. • High polymeric borate groups in the glass matrix may be destroyed to the lower ones.

  15. Distributed Energy Resources for Carbon Emissions Mitigation

    E-Print Network [OSTI]

    Firestone, Ryan; Marnay, Chris

    2008-01-01T23:59:59.000Z

    Distributed Energy Resource Technology Characterizations. ”ABORATORY Distributed Energy Resources for Carbon Emissions5128 Distributed Energy Resources for Carbon Emissions

  16. Project Profile: Direct Supercritical Carbon Dioxide Receiver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Supercritical Carbon Dioxide Receiver Development Project Profile: Direct Supercritical Carbon Dioxide Receiver Development National Renewable Energy Laboratory logo The...

  17. Electrobiocommodities from Carbon Dioxide: Enhancing Microbial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrobiocommodities from Carbon Dioxide: Enhancing Microbial Electrosynthesis with Synthetic Electromicrobiology and System Design Electrobiocommodities from Carbon Dioxide:...

  18. Carbon-Fuelled Future

    SciTech Connect (OSTI)

    Appel, Aaron M.

    2014-09-12T23:59:59.000Z

    Whether due to changes in policy or consumption of available fossil fuels, alternative sources of energy will be required, especially given the rising global energy demand. However, one of the main factors limiting the widespread utilization of renewable energy, such as wind, solar, wave or geothermal, is our ability to store energy. Storage of energy from carbon-neutral sources, such as electricity from solar or wind, can be accomplished through many routes. One approach is to store energy in the form of chemical bonds, as fuels. The conversion of low-energy compounds, such as water and carbon dioxide, to higher energy molecules, such as hydrogen or carbon-based fuels, enables the storage of carbon-neutral energy on a very large scale. The author¹s work in this area is supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. Carbon Footprint Calculator

    Broader source: Energy.gov [DOE]

    This calculator estimates the amount of carbon emissions you and members of your household are responsible for. It does not include emissions associated with your work or getting to work if you commute by public transportation. It was developed by IEEE Spectrum magazine.

  20. Carbon smackdown: smart windows

    ScienceCinema (OSTI)

    Delia Milliron

    2010-09-01T23:59:59.000Z

    August 3, 2010 Berkeley Lab talk: In the fourth of five Carbon Smackdown matches, Berkeley Lab researchers Delia Milliron of the Materials Sciences Division and Stephen Selkowitz of the Environmental Energy Technologies Division talk about their work on energy-saving smart windows.

  1. Carbon smackdown: wind warriors

    SciTech Connect (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-07-21T23:59:59.000Z

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  2. CARBON -14 PHYSICAL DATA

    E-Print Network [OSTI]

    Vallino, Joseph J.

    CARBON - 14 [14C] PHYSICAL DATA · Beta Energy: 156 keV (maximum) 49 keV (average) (100% abundance on wipes. #12;RADIATION MONITORING DOSIMETERS · Not needed (beta energy too low). · 14C Beta Dose Rate: 6) · Effective Half-Life: 40 days (unbound) · Specific Activity: 4460 mCi/gram · Maximum Beta Range in Air: 24

  3. Carbon smackdown: wind warriors

    ScienceCinema (OSTI)

    Glen Dahlbacka of the Accelerator & Fusion Research Division and Ryan Wiser of the Environmental Energy Technologies Division are the speakers.

    2010-09-01T23:59:59.000Z

    July 16. 2010 carbon smackdown summer lecture: learn how Berkeley Lab scientists are developing wind turbines to be used in an urban setting, as well as analyzing what it will take to increase the adoption of wind energy in the U.S.

  4. 4, 99123, 2007 Amazon carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    , suggested much larger estimates for tropical forest carbon sequestration in the Ama- zon BasinBGD 4, 99­123, 2007 Amazon carbon balanc J. Lloyd et al. Title Page Abstract Introduction Discussions is the access reviewed discussion forum of Biogeosciences An airborne regional carbon balance

  5. 3, 409447, 2006 Modeling carbon

    E-Print Network [OSTI]

    Boyer, Edmond

    BGD 3, 409­447, 2006 Modeling carbon dynamics in farmland of China F. Zhang et al. Title Page impacts of management alternatives on soil carbon storage of farmland in Northwest China F. Zhang1,3 , C-term losses of soil organic carbon (SOC) have been observed in many agricul- ture lands in Northwest China

  6. 7, 405428, 2007 SCIAMACHY carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    with an increasing energy demand and inherent fuel consump- tion such as China. Carbon monoxide (CO) contributesACPD 7, 405­428, 2007 SCIAMACHY carbon monoxide M. Buchwitz et al. Title Page Abstract Introduction Discussions Three years of global carbon monoxide from SCIAMACHY: comparison with MOPITT and first results

  7. 4, 21112145, 2007 Enhanced carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    are generally low in productivity and carbon (C) storage. We report, however, large increases in C sequestration . Carbon sequestration following afforestation was associated with increased N use efficiency as reflected of terrestrial ecosystems that leads to increased carbon (C) sequestration. One of those means is afforestation

  8. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01T23:59:59.000Z

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  9. Research Report Forests and carbon

    E-Print Network [OSTI]

    Research Report Forests and carbon: valuation, discounting and risk management #12;#12;Forests and carbon: valuation, discounting and risk management Gregory Valatin Forestry Commission: Edinburgh-0-85538-815-7 Valatin, G. (2010). Forests and carbon: valuation, discounting and risk management. Forestry Commission

  10. 1, 167193, 2004 Terrestrial carbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 1, 167­193, 2004 Terrestrial carbon budget at country-scale I. A. Janssens et al. Title Page Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences The carbon budget.janssens@ua.ac.be) 167 #12;BGD 1, 167­193, 2004 Terrestrial carbon budget at country-scale I. A. Janssens et al. Title

  11. Vibrationally induced center reconfiguration in co-doped GaN:Eu, Mg epitaxial layers: Local hydrogen migration vs. activation of non-radiative channels

    SciTech Connect (OSTI)

    Mitchell, B.; Dierolf, V. [Lehigh University, 16 Memorial Dr. E, Bethlehem, Pennsylvania 18015 (United States)] [Lehigh University, 16 Memorial Dr. E, Bethlehem, Pennsylvania 18015 (United States); Lee, D. [Lawrence Livermore National Laboratory, 7000 East Ave L-413, California 94550 (United States)] [Lawrence Livermore National Laboratory, 7000 East Ave L-413, California 94550 (United States); Lee, D.; Fujiwara, Y. [Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)] [Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)

    2013-12-09T23:59:59.000Z

    Europium doped gallium nitride (GaN:Eu) is a promising candidate as a material for red light emitting diodes. When Mg was co-doped into GaN:Eu, additional incorporation environments were discovered that show high excitation efficiency at room temperature and have been attributed to the coupling of Mg-H complexes to the majority Eu site. Electron beam irradiation, indirect and resonant (direct) laser excitation were found to modify these complexes, indicating that vibrational energy alone can trigger the migration of the H while the presence of additional charges and excess energy controls the type of reconfiguration and the activation of non-radiative decay channels.

  12. Multifunctional Superhydrophobic Polymer/Carbon Nanocomposites: Graphene, Carbon Nanotubes, or Carbon Black?

    E-Print Network [OSTI]

    Daraio, Chiara

    Multifunctional Superhydrophobic Polymer/Carbon Nanocomposites: Graphene, Carbon Nanotubes, Switzerland *S Supporting Information ABSTRACT: Superhydrophobic surfaces resisting water penetration fabrication of highly electrically conductive, polymer-based superhydrophobic coatings, with impressive

  13. CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR

    E-Print Network [OSTI]

    Su, Xiao

    CALCULATING THE CARBON FOOTPRINT SUPPLY CHAIN FOR THE SEMICONDUCTOR INDUSTRY By: Yasser Dessouky #12;Carbon Footprint Supply Chain Carbon Trust defines carbon footprint of a supply chain as follows: "The carbon footprint of a product is the carbon dioxide emitted across the supply chain for a single

  14. 6, 34193463, 2006 Black carbon or

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 3419­3463, 2006 Black carbon or brown carbon M. O. Andreae and A. Gelencs´er Title Page Chemistry and Physics Discussions Black carbon or brown carbon? The nature of light-absorbing carbonaceous;ACPD 6, 3419­3463, 2006 Black carbon or brown carbon M. O. Andreae and A. Gelencs´er Title Page

  15. Catalytic Carbon-Carbon and Carbon-Silicon Bond Activation and Functionalization by Nickel Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Catalytic Carbon-Carbon and Carbon-Silicon Bond Activation and Functionalization by Nickel of Rochester, Rochester, New York 14627 Received June 11, 1999 The nickel alkyne complexes (dippe)Ni(Me3Si, and nickel phosphine complexes.3 Milstein and co-workers reported the cata- lytic hydrogenolysis

  16. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  17. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19T23:59:59.000Z

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  18. EB2012-MS-43 ADVANCES IN THE MODELLING OF CARBON/CARBON

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , the Carbon-Carbon composites (C/C) are materials frequently used in industrial applications such as planeEB2012-MS-43 ADVANCES IN THE MODELLING OF CARBON/CARBON COMPOSITE UNDER TRIBOLOGICAL CONSTRAINTS 1, homogenization, carbon ABSTRACT Thermo mechanical properties of Carbon-Carbon composite (C/C) allow them

  19. Carbon Cycle Discussion After the warm-up quiz, discuss the carbon cycle.

    E-Print Network [OSTI]

    Carrington, Emily

    Carbon Cycle Discussion After the warm-up quiz, discuss the carbon cycle. Carbon is one is without carbon. Where else is carbon on our Earth? In rocks, living organisms, the atmosphere, oceans Does carbon stay in one place? What processes include moving carbon? Introduce residence time: How long does

  20. Lithium in LMC carbon stars

    E-Print Network [OSTI]

    D. Hatzidimitriou; D. H. Morgan; R. D. Cannon; B. F. W. Croke

    2003-04-16T23:59:59.000Z

    Nineteen carbon stars that show lithium enrichment in their atmospheres have been discovered among a sample of 674 carbon stars in the Large Magellanic Cloud. Six of the Li-rich carbon stars are of J-type, i.e. with strong 13C isotopic features. No super-Li-rich carbon stars were found. The incidence of lithium enrichment among carbon stars in the LMC is much rarer than in the Galaxy, and about five times more frequent among J-type than among N-type carbon stars. The bolometric magnitudes of the Li-rich carbon stars range between -3.3 and -5.7. Existing models of Li-enrichment via the hot bottom burning process fail to account for all of the observed properties of the Li-enriched stars studied here.

  1. Theoretical studies of strongly correlated rare-earth intermetallics RIn? and RSn? (R=Sm, Eu, and Gd)

    SciTech Connect (OSTI)

    Shafiq, M.; Ahmad, Iftikhar, E-mail: ahma5532@gmail.com, E-mail: dr.iftikhar@uom.edu.pk [Center for Computational Materials Science, University of Malakand, Chakdara (Pakistan); Department of Physics, University of Malakand, Chakdara (Pakistan); Jalali Asadabadi, S. [Department of Physics, Faculty of Science, University of Isfahan, Hezar Gerib Avenue, Isfahan 81744 (Iran, Islamic Republic of)

    2014-09-14T23:59:59.000Z

    In this paper, the structural, elastic, and electronic properties of RIn? and RSn? (R = Sm, Eu, Gd) compounds have been investigated using the full potential linearized augmented plane wave plus local orbital method within the density functional theory. The structural properties are investigated using the LDA, GGA, and the band correlated LDA+U and GGA+U schemes. The lattice parameters are in good agreement with the available experimental results and the divalent state of Eu is also verified. The spin-orbit coupling is included in order to predict the correct electronic properties and splitting of 4f states of the rare earth elements is also incorporated. We calculated Bulk modulus, shear modulus, Young's modulus, anisotropic ratio, Kleinman parameters, Poisson's ratio, Lame's co-efficient, sound velocities for shear and longitudinal waves, and Debye temperature. We also predict the Cauchy pressure and B/G ratio in order to explore the ductile and brittle behaviors of these compounds.

  2. Luminescence Spectroscopy of Eu-doped (Ca,Sr)TiO{sub 3} Nanocrystals Prepared by Using Sonochemical Method

    SciTech Connect (OSTI)

    Kurniawan, C. [Chemistry Department of Semarang State University, Jl. Raya Sekaran Semarang (Indonesia); Prijamboedi, B. [Chemistry Department of Bandung Institute of Technology, Jl. Ganesha 10 Bandung (Indonesia)

    2010-10-24T23:59:59.000Z

    Perovskite-type compounds (ABO{sub 3}) of (Ca,Sr)TiO{sub 3} doped with trivalent europium (Eu{sup 3+}) were synthesized by sonochemical techniques. Powder X-ray diffraction measurement on (Ca,Sr)TiO{sub 3} were used to identify the perovskite crystal structure. The photoluminescence property in (Ca,Sr)TiO{sub 3} with europium substitution several atoms in the host lattice was also studied. Further, the photoluminescence spectra were taken at room temperature. The structural difference between fourth kinds of doped samples with different heating temperatures accounts for the intensification of the luminescence intensity. The presented measurements monitor the emission wavelengths of the Eu{sup 3+} with emission peaks at 593, 615 and 700 nm. The obtained results were discussed with respect to developed preparation method.

  3. TL and PL studies on cubic fluoroperovskite single crystal (KMgF{sub 3}: Eu{sup 2+}, Ce{sup 3+})

    SciTech Connect (OSTI)

    Daniel, D. Joseph, E-mail: josephd@ssn.edu.in; Ramasamy, P. [Centre for Crystal Growth, SSN College of Engineering, Kalavakkam, Tamilnadu-603110 (India); Madhusoodanan, U.; Annalakshmi, O. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamilnadu - 603102 (India)

    2014-04-24T23:59:59.000Z

    The perovskite-like KMgF{sub 3} polycrystalline compounds were synthesized by standard solid state reaction technique. Phase purity of the synthesized compounds was analyzed by powder X-ray diffraction technique. Single crystals of (0.2 mol% of EuF{sub 3} and CeF{sub 3}) Co-doped KMgF{sub 3} have been grown from melt by using a vertical Bridgman-Stockbarger method. Thermoluminescence (TL) characteristics of KMgF{sub 3} samples doped with Eu{sub 2+} and Ce{sub 3+} have been studied after ?-ray irradiation. At ambient conditions the photoluminescence spectra consisted of sharp line peaked of Eu{sub 2+} at 360 nm attributed to the f ? f transition ({sup 6}P{sub 7/2}?{sup 8}S{sub 7/2}) could only be observed due to the energy transfer from Ce{sub 3+} to Eu{sub 2+}.

  4. Effect of Eu–Ni substitution on electrical and dielectric properties of Co–Sr–Y-type hexagonal ferrite

    SciTech Connect (OSTI)

    Ali, Irshad, E-mail: irshadalibzu@gmail.com [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Islam, M.U. [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Ashiq, Muhammad Naeem, E-mail: naeemashiqqau@yahoo.com [Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 60800 (Pakistan); Khan, Hasan M. [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Iqbal, M. Asif [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Nust College of Electrical and Mechanical Engineering, Islamabad (Pakistan); Najam-Ul-Haq, Muhammad [Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 60800 (Pakistan)

    2014-01-01T23:59:59.000Z

    Graphical abstract: - Highlights: • Single phase nanostructured Sr{sub 2}Co{sub 2?x}Ni{sub x} Eu{sub y}Fe{sub 12?y}O{sub 22} were synthesized by the microemulsion method. • The materials show semiconducting behavior. • The high resistivity makes these materials useful for high frequency applications. • The Curie temperature decreases with the substituents. - Abstract: Single phase nanostructured Eu–Ni substituted Y-type hexaferrites with nominal composition Sr{sub 2}Co{sub 2?x}Ni{sub x} Eu{sub y}Fe{sub 12?y}O{sub 22} (x = 0.0–1, y = 0.0–0.1) were synthesized by the normal microemulsion method. X-ray diffraction (XRD) technique was employed for phase analysis and indexing of each pattern corroborates that well defined Y-type crystalline phase is formed. It is observed that DC resistivity enhanced which is accredited to room temperature resistivity differences of dopant and host ions. The hopping of electrons and jumping of holes are responsible for conduction below Curie temperature (T{sub C}), whereas above Curie temperature is due to polaron hopping. The decrease in T{sub C} may be due to the fact that Eu–Fe interactions on the B sites are weaker than Fe–Fe interaction. The dispersion in the dielectric constant ??(f) favor the occurrence of peaks in the tan ?(f). The extraordinary values of resistivity and small dielectric loss make these materials pre-eminent contestant for high frequency applications.

  5. Reforming TSOs: using the 'third package' Legislation to promote efficiency and accelerate regional integration in EU wholesale power markets

    SciTech Connect (OSTI)

    Moselle, Boaz

    2008-10-15T23:59:59.000Z

    The EU is developing new legislation - the so-called ''Third Package'' - to foster competition in its electric power markets. These proposals could be improved by adding more focus on regional integration of wholesale power markets, allowing more leeway for arrangements that fit the diverse existing patterns of transmission ownership and control, and addressing upfront new regulatory concerns that arise when transmission is divested as an independent, for-profit business. (author)

  6. CARBON DIOXIDE FIXATION.

    SciTech Connect (OSTI)

    FUJITA,E.

    2000-01-12T23:59:59.000Z

    Solar carbon dioxide fixation offers the possibility of a renewable source of chemicals and fuels in the future. Its realization rests on future advances in the efficiency of solar energy collection and development of suitable catalysts for CO{sub 2} conversion. Recent achievements in the efficiency of solar energy conversion and in catalysis suggest that this approach holds a great deal of promise for contributing to future needs for fuels and chemicals.

  7. A facile preparation and the luminescent properties of Eu{sup 3+}-doped Y{sub 2}O{sub 2}SO{sub 4} nanopieces

    SciTech Connect (OSTI)

    Song, Lixin; Shao, Xiaoli; Du, Pingfan; Cao, Houbao; Hui, Quan; Xing, Tonghai; Xiong, Jie, E-mail: jxiong@zstu.edu.cn

    2013-11-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} nanopieces were prepared via electrospinning followed by calcination. • The photoluminescence of Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} nanopieces were investigated. • The Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} was compared to nanoribbons and commercial Y{sub 2}O{sub 3}:Eu{sup 3+}. • The potential applications of the nanopieces and the facile method are suggested. - Abstract: The europium(III)-doped yttrium oxysulfate (Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+}) nanopieces have been prepared via electrospinning followed by calcination at 1000 °C in mixed gas of sulfur dioxide and air. Based on the experimental results, a possible formation mechanism for the nanopieces is that the nanopieces are determined by the directing template of electrospun nanoribbons and the multilayer crystal structure of Y{sub 2}O{sub 2}SO{sub 4}. Besides, the nanopieces show excellent luminescent properties with emissions at 581, 589, 597, 653, 619, and 697 nm resulting from the {sup 5}D{sub 0} ? {sup 7}F{sub J} (J = 0, 1, 2, 3, 4) transition of Eu{sup 3+}. The peaks of charge transfer and {sup 5}D{sub 0} ? {sup 7}F{sub 2} transition of Eu{sup 3+} obviously have red shifts comparing to those of both Y{sub 2}O{sub 3}:Eu{sup 3+} nanoribbons and commercial Y{sub 2}O{sub 3}:Eu{sup 3+}. Moreover, the nanopieces exhibit stronger intensities than the Y{sub 2}O{sub 3}:Eu{sup 3+} in excitation and emission spectra. Concentration quenching in the nanopieces occurs when Eu{sup 3+} concentration is 11 mol%, indicating that the nanopieces have an optimum luminescent intensity under this doping concentration.

  8. Carbon Capital: The Political Ecology of Carbon Forestry and Development in Chiapas, Mexico

    E-Print Network [OSTI]

    Osborne, Tracey Muttoo

    2010-01-01T23:59:59.000Z

    B v + B d ) C T = Total carbon B v = biomass contained indevelopment through carbon sequestration: experiences in2000) Rural livelihoods and carbon management, IIED Natural

  9. Carbon taxes and India

    SciTech Connect (OSTI)

    Fisher-Vanden, K.A.; Pitcher, H.M.; Edmonds, J.A.; Kim, S.H. [Pacific Northwest Lab., Richland, WA (United States); Shukla, P.R. [Indian Institute of Management, Ahmedabad (India)

    1994-07-01T23:59:59.000Z

    Using the Indian module of the Second Generation Model 9SGM, we explore a reference case and three scenarios in which greenhouse gas emissions were controlled. Two alternative policy instruments (carbon taxes and tradable permits) were analyzed to determine comparative costs of stabilizing emissions at (1) 1990 levels (the 1 X case), (2) two times the 1990 levels (the 2X case), and (3) three times the 1990 levels (the 3X case). The analysis takes into account India`s rapidly growing population and the abundance of coal and biomass relative to other fuels. We also explore the impacts of a global tradable permits market to stabilize global carbon emissions on the Indian economy under the following two emissions allowance allocation methods: (1) {open_quotes}Grandfathered emissions{close_quotes}: emissions allowances are allocated based on 1990 emissions. (2) {open_quotes}Equal per capita emissions{close_quotes}: emissions allowances are allocated based on share of global population. Tradable permits represent a lower cost method to stabilize Indian emissions than carbon taxes, i.e., global action would benefit India more than independent actions.

  10. Electron nuclear double resonance study of photostimulated luminescence active centers in CsBr:Eu{sup 2+} medical imaging plates

    SciTech Connect (OSTI)

    Vrielinck, H.; Loncke, F.; Matthys, P.; Callens, F. [Department of Solid State Sciences, Ghent University, Krijgslaan 281-S1, B-9000 Gent (Belgium); Tahon, J.-P.; Leblans, P. [Agfa HealthCare NV, Septestraat 27, B-2640 Mortsel (Belgium)

    2011-02-01T23:59:59.000Z

    CsBr:Eu{sup 2+} needle image plates exhibit an electron-paramagnetic-resonance (EPR) spectrum at room temperature (RT), whose intensity is correlated with the photostimulated luminescence sensitivity of the plate. This EPR spectrum shows a strong temperature dependence: At RT it is owing to a single Eu{sup 2+} (S =7/2) center with axial symmetry, whereas at T<35 K the spectra can only be explained when two distinct centers are assumed to be present, a minority axial center and a majority center with nearly extremely rhombic symmetry. In this paper these low-temperature centers are studied with electron nuclear double resonance (ENDOR) spectroscopy, which reveals the presence of {sup 1}H nuclei close to the central Eu{sup 2+} ions in the centers. Analysis of the angular dependence of the ENDOR spectra allows to propose models for these centers, providing an explanation for the observed difference in intensity between the spectral components and for their temperature dependence.

  11. Luminescence properties of Eu-activated alkaline and alkaline-earth silicate Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}

    SciTech Connect (OSTI)

    Wang, Jing [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Huang, Yanlin, E-mail: huang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Wang, Xigang, E-mail: wangxigang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Qin, Lin [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Seo, Hyo Jin, E-mail: hjseo@pknu.ac.kr [Department of Physics and Center for Marine-Integrated Biomedical Technology, Pukyong National University, Busan 608-737 (Korea, Republic of)

    2014-07-01T23:59:59.000Z

    Highlights: • A novel yellow-emitting alkaline and alkaline-earth silicate Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} was first developed. • Under excitation with UV or near UV light the silicate presents broad emission band centered at 580 nm. - Abstract: Yellow-emitting phosphors of Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} was prepared by wet chemistry sol–gel method. X-ray powder diffraction and SEM measurements were applied to characterize the structure and morphology, respectively. The luminescence properties were investigated by the photoluminescence excitation and emission spectra, decay curve (lifetimes), CIE coordinates and the internal quantum efficiencies. The excitation spectra can match well with the emission light of near UV-LED chips (360–400 nm). Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} presents a symmetric emission band from 4f{sup 6}5d{sup 1} ? 4f{sup 7}({sup 8}S{sub 7/2}) transitions of Eu{sup 2+} ions on doping below 3.0 mol%. On increasing Eu-doping levels, the sample contains two kinds of emission centers, i.e., Eu{sup 2+} and Eu{sup 3+} ions, which present the characteristic broad band (5d ? 4f) and narrower (4f ? 4f) luminescence lines, respectively. The energy transfer, the luminescence thermal stability (activation energy ?E for thermal quenching) and luminescence mechanism of Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} phosphors were discussed by analyzing the relationship between the luminescence characteristics and the crystal structure.

  12. Effect of optical excitation energy on the red luminescence of Eu3+ H. Y. Peng, C. W. Lee, and H. O. Everitta

    E-Print Network [OSTI]

    Steckl, Andrew J.

    and carrier relaxation dynamics. A Eu-doped GaN film was deposited on a p-Si 111 substrate by solid-source MBE. A thin GaN buffer layer was first deposited at a substrate temperature of 600 °C before the main growthEffect of optical excitation energy on the red luminescence of Eu3+ in GaN H. Y. Peng, C. W. Lee

  13. Bifunctional Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+}nanocomposites obtained by the homogeneous precipitation method

    SciTech Connect (OSTI)

    Peng, Hongxia [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shanxi Key Laboratory of Physico-Inorganic Chemistry, School of Chemistry and Materials Science, Northwest University, Xi’an, Shanxi 710069 (China); Cui, Bin, E-mail: cuibin@nwu.edu.cn [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shanxi Key Laboratory of Physico-Inorganic Chemistry, School of Chemistry and Materials Science, Northwest University, Xi’an, Shanxi 710069 (China); Wang, Yingsai [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shanxi Key Laboratory of Physico-Inorganic Chemistry, School of Chemistry and Materials Science, Northwest University, Xi’an, Shanxi 710069 (China)

    2013-05-15T23:59:59.000Z

    Graphical abstract: The TEM images reveal clearly the core–shell structures because of the obvious difference in contrast between the central part and the fringe, which indicates the Gd{sub 2}O{sub 3}:Eu{sup 3+} layer had successfully deposited on the magnetite Fe{sub 3}O{sub 4} cores. And Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles keep the spherical morphology, non-aggregation and rough surface. The images reveal that the average diameters of the Fe{sub 3}O{sub 4} and Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanoparticles are ?200 nm and ?250 nm, respectively. The thickness of Gd{sub 2}O{sub 3}:Eu{sup 3+} layer is ?25 nm. Highlights: ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites were synthesized by homogeneous precipitation method. ? Formation of core–shell nanostructure revealed by transmission electron microscopy. ? Fe{sub 3}O{sub 4}@Gd{sub 2}O{sub 3}:Eu{sup 3+} nanocomposites showed magnetic behavior and fluorescence properties. ? Possible applications including bioseparation, drug delivery system, bio-labels, etc. - Abstract: An easy homogeneous precipitation method was developed for the synthesis of bifunctional magnetic-fluorescent nanocomposites with Fe{sub 3}O{sub 4} nanoparticles as the core and europium-doped gadolinium oxide (Gd{sub 2}O{sub 3}:Eu{sup 3+}) as the shell. The nanocomposites showed both strong magnetic behavior and unique Eu-related fluorescence properties with a high emission intensity, which may lead to development of nanocomposites with great potential for applications in drug targeting, biosensors, and diagnostic analysis.

  14. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01T23:59:59.000Z

    for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

  15. activated carbon electrodes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes** Materials Science Websites Summary: Pyrolytic carbon electrodes Lithographically Defined...

  16. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Moorhead, Arthur J. (Knoxville, TN)

    1997-01-01T23:59:59.000Z

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to "wick" into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy.

  17. Method for joining carbon-carbon composites to metals

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Moorhead, A.J.

    1997-07-15T23:59:59.000Z

    A method for joining carbon-carbon composites to metals by brazing. Conventional brazing of recently developed carbon-bonded carbon fiber (CBCF) material to a metal substrate is limited by the tendency of the braze alloy to ``wick`` into the CBCF composite rather than to form a strong bond. The surface of the CBCF composite that is to be bonded is first sealed with a fairly dense carbonaceous layer achieved by any of several methods. The sealed surface is then brazed to the metal substrate by vacuum brazing with a Ti-Cu-Be alloy. 1 fig.

  18. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Task 3: Mechanical behaviors of carbonated minerals. - Task 4: Modeling of CO2- reservoir rock interactions. - Task 5: Preparation of report covering the four tasks previous task,...

  19. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08T23:59:59.000Z

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  20. Howell, R.A., 2012 Living with a carbon allowance 1 Living with a carbon allowance: the experiences of Carbon

    E-Print Network [OSTI]

    Howell, R.A., 2012 Living with a carbon allowance 1 Living with a carbon allowance: the experiences of Carbon Rationing Action Groups and implications for policy Rachel A. Howell Environmental Change with a carbon allowance: the experiences of Carbon Rationing Action Groups and implications for policy. Energy

  1. Luminescent properties of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} and its potential application in white light emitting diodes

    SciTech Connect (OSTI)

    Wang, Zhijun, E-mail: wangzhijunmail@yahoo.com.cn [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Li, Panlai; Li, Ting; Zhang, Xing; Li, Qingxuan; Yang, Zhiping; Guo, Qinglin [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2013-06-01T23:59:59.000Z

    Graphical abstract: Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} phosphor can be effectively excited by an ultraviolet and near-ultraviolet light, and produce a bright blue emission centered at 436 nm. The CIE chromaticity coordinations (x, y) of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+}(NSCE)/Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}(LSSE) vary with the molar ratio of the two constituents. When NSCE/LSSE is 1:3, the CIE chromaticity coordination is (0.332, 0.346), which is close to that of the natural sunlight (0.33, 0.33). The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a promising blue phosphor for UV chip-based multi-phosphor converted white light emitting diodes. Highlights: ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} shows the blue emission with a peak at 436 nm and broad excitation band in the UV/n-UV range. ? White light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor with the Li{sub 2}SrSiO{sub 4}:Eu{sup 2+} yellow phosphor. ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} would be a promising blue phosphor candidate for UV chip-based multi-phosphor converted white LEDs. - Abstract: A novel blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is synthesized by a high temperature solid-state reaction, and its luminescent properties are systematically studied. Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} can be effectively excited by the 354 nm radiation, and create blue emission (436 nm). The emission intensity of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is influenced by the Eu{sup 2+} doping content, and the optimal doping content is 1.5%, and the concentration quenching mechanism of Eu{sup 2+} in Na{sub 2}CaSiO{sub 4} can be attributed to the multipolar interaction. The white light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} with the yellow phosphor Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}. The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a potential blue emitting phosphor for UV chip-based multi-phosphor converted white light emitting diodes.

  2. MISSION CLIMAT WORKING PAPER N 2010 6

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    between EU emissions allowances (EUAs) ­ valid under the EU Emissions Trading Scheme (EU ETS in the European Carbon Market 4 1. Introduction The European Union Emissions Trading Scheme (EU ETS) is the EU

  3. Carbon/Ternary Alloy/Carbon Optical Stack on Mylar as an Optical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CarbonTernary AlloyCarbon Optical Stack on Mylar as an Optical Data Storage Medium to Potentially Replace Magnetic Tape. CarbonTernary AlloyCarbon Optical Stack on Mylar as an...

  4. Geologic Carbon Storage Archived Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corporation 9302005 Enhanced Microbial Pathways for Methane Production from Oil Shale Western Research Institute 1012005 Carbon Sequestration for Existing Power Plants...

  5. Carbon-assisted flyer plates

    DOE Patents [OSTI]

    Stahl, David B. (Los Alamos, NM); Paisley, Dennis L. (Santa Fe, NM)

    1994-01-01T23:59:59.000Z

    A laser driven flyer plate utilizing an optical fiber connected to a laser. The end of the optical fiber has a layer of carbon and a metal layer deposited onto it. The carbon layer provides the laser induced plasma which is superior to the plasma produced from most metals. The carbon layer plasma is capable of providing a flatter flyer plate, converting more of the laser energy to driving plasma, promoting a higher flyer plate acceleration, and providing a more uniform pulse behind the plate. In another embodiment, the laser is in optical communication with a substrate onto which a layer of carbon and a layer of metal have been deposited.

  6. Carbon nanotube IR detectors (SV)

    SciTech Connect (OSTI)

    Leonard, F. L.

    2012-03-01T23:59:59.000Z

    Sandia National Laboratories (Sandia) and Lockheed Martin Corporation (LMC) collaborated to (1) evaluate the potential of carbon nanotubes as channels in infrared (IR) photodetectors; (2) assemble and characterize carbon nanotube electronic devices and measure the photocurrent generated when exposed to infrared light;(3) compare the performance of the carbon nanotube devices with that of traditional devices; and (4) develop and numerically implement models of electronic transport and opto-electronic behavior of carbon nanotube infrared detectors. This work established a new paradigm for photodetectors.

  7. Carbon Sequestration Atlas IV Video

    ScienceCinema (OSTI)

    Rodosta, Traci

    2014-06-27T23:59:59.000Z

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  8. Carbon Sequestration Advisory Committee (Nebraska)

    Broader source: Energy.gov [DOE]

    Under this statute, the Director of Natural Resources will document and quantify carbon sequestration and greenhouse emissions reductions associated with agricultural practices, management systems,...

  9. Low Cost Carbon Fiber Overview

    Broader source: Energy.gov (indexed) [DOE]

    and Processing (IT) Lignin-Based Low-Cost Carbon Fiber Precursors * Structural Materials for Vehicles (VT) * Graphite Electrodes for Arc Furnaces (IT) * Nanoporous CF for...

  10. Carbon Fiber Consortium | Partnerships | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in 2011 to accelerate the development and deployment of new, lower cost carbon fiber composite materials. The Consortium draws on the broad experience that the Oak Ridge National...

  11. Sandia National Laboratories: Carbon Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SO2), nitrous oxides (NOx), mercury, and fine particulate matter. Carbon dioxide (CO2) is always a byproduct of combustion. ... Geomechanics Laboratory On April 7, 2011,...

  12. Carbon Sequestration Atlas IV Video

    SciTech Connect (OSTI)

    Rodosta, Traci

    2013-04-19T23:59:59.000Z

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  13. University of Dundee Carbon Management Plan

    E-Print Network [OSTI]

    Davidson, Fordyce A.

    Carbon Management Strategy 2.1 Our low carbon vision 6 2.2 Context and drivers for Carbon Management 6 2 and sources of funding 18 6 Actions to Embed Carbon Management in Your Organisation 19 6.1 Corporate Strategy Appendix A: Carbon Management Matrix - Embedding 23 Appendix B: Energy Prices 24 #12;3 FOREWORD FROM

  14. University of Aberdeen Carbon Management Plan

    E-Print Network [OSTI]

    Levi, Ran

    of Aberdeen is committed to reducing its carbon footprint and to playing its part in limiting the worstUniversity of Aberdeen Carbon Management Plan Higher Education Carbon Management Programme working with Page 1 The University of Aberdeen Carbon Management Programme Carbon Management Plan (CMP

  15. Carbon Management Plan 1. Executive summary 5

    E-Print Network [OSTI]

    Haase, Markus

    Carbon Management Plan June 2011 #12;2 #12;3 CONTENTS 1. Executive summary 5 2. Introduction 15 3. Background and context 16 4. Carbon management strategy 18 5. Carbon emissions baseline and projections 22 6. Past actions and achievements 30 7. Carbon Management Plan implementation 33 8. Carbon Management Plan

  16. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01T23:59:59.000Z

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  17. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27T23:59:59.000Z

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  18. ARM - Carbon Dioxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would love to heargovInstrumentstdma Comments? WeairgovInstrumentswsiCampaignCarbon

  19. Sandia Energy - Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand RequirementsCoatings Initiated at PNNL's Sequim BayCapture Home Carbon Capture The

  20. Sandia Energy - Carbon Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand RequirementsCoatings Initiated at PNNL's Sequim BayCapture Home Carbon

  1. Carbon Capture FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r8.05CarBen Version 3 Prototype:carbon

  2. Carbon Storage Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l aNanocomposites, and DevicesCarbonProgram

  3. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries BatteriesCAESMissionMetal-OrganicCarbon Bearing

  4. Carbon Fiber Technology Facility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy Change RequestFirst Report to the PrimePilot Plant andCarbon

  5. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

  6. Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao

    E-Print Network [OSTI]

    Barthelat, Francois

    Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao promising carbon uptake results and is a viable option for carbonation curing. Carbon sequestration increase in Carbon dioxide (CO2) emissions over the past five decades, specific ways to reduce

  7. Intermediate Temperature Carbon - Carbon Composite Structures. CRADA Final Report

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar [ORNL

    2007-06-01T23:59:59.000Z

    The objective of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC (the "Contractor") and Synterials, Inc. (the "Participant") was to demonstrate promising processing methods, which can lead to producing Carbon-Carbon Composites (CCC), with tensile and interlaminar properties comparable to those of organic matrix composites and environmental stability at 1200 F for long periods of time. The participant synthesized carbon-carbon composites with two different fiber coatings and three different matrices. Both parties evaluated the tensile and interlaminar properties of these materials and characterized the microstructure of the matrices and interfaces. It was found that fiber coatings of carbon and boron carbide provided the best environmental protection and resulted in composites with high tensile strength.

  8. Research Summary Carbon valuation, discounting and risk management

    E-Print Network [OSTI]

    covered by the EU Emissions Trading Scheme (ETS) and £51/tCO2e (£183/tC) for non-ETS sectors, both rising

  9. Carbon dioxide and climate

    SciTech Connect (OSTI)

    Not Available

    1990-10-01T23:59:59.000Z

    Scientific and public interest in greenhouse gases, climate warming, and global change virtually exploded in 1988. The Department's focused research on atmospheric CO{sub 2} contributed sound and timely scientific information to the many questions produced by the groundswell of interest and concern. Research projects summarized in this document provided the data base that made timely responses possible, and the contributions from participating scientists are genuinely appreciated. In the past year, the core CO{sub 2} research has continued to improve the scientific knowledge needed to project future atmospheric CO{sub 2} concentrations, to estimate climate sensitivity, and to assess the responses of vegetation to rising concentrations of CO{sub 2} and to climate change. The Carbon Dioxide Research Program's goal is to develop sound scientific information for policy formulation and governmental action in response to changes of atmospheric CO{sub 2}. The Program Summary describes projects funded by the Carbon Dioxide Research Program during FY 1990 and gives a brief overview of objectives, organization, and accomplishments.

  10. Bridgman Growth of Large SrI2:Eu2+ Single Crystals: A High-performance Scintillator for Radiation Detection Applications

    SciTech Connect (OSTI)

    Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Kolopus, James A [ORNL; Hawrami, Rastgo [Radiation Monitoring Devices, Watertown, MA; Higgins, William [Radiation Monitoring Devices, Watertown, MA; Van Loef, Edgar [Radiation Monitoring Devices, Watertown, MA; Glodo, J. [Radiation Monitoring Devices, Watertown, MA; Shah, Kanai [Radiation Monitoring Devices, Watertown, MA; Bhattacharya, P. [Fisk University, Nashville, TN; Tupitsyn, E [Fisk University, Nashville, TN; Groza, Michael [Fisk University, Nashville, TN; Burger, Arnold [Fisk University, Nashville, TN

    2013-01-01T23:59:59.000Z

    Single-crystal strontium iodide (SrI2) doped with relatively high levels (e.g., 3 - 6 %) of Eu2+ exhibits characteristics that make this material superior, in a number of respects, to other scintillators that are currently used for radiation detection. Specifically, SrI2:Eu2+ has a light yield that is significantly higher than LaBr3:Ce3+ -a currently employed commercial high-performance scintillator. Additionally, SrI2:Eu2+ is characterized by an energy resolution as high as 2.6% at the 137Cs gamma-ray energy of 662 keV, and there is no radioactive component in SrI2:Eu2+ - unlike LaBr3:Ce3+ that contains 138La. The Ce3+-doped LaBr3 decay time is, however, faster (30 nsec) than the 1.2 sec decay time of SrI2:Eu2+. Due to the relatively low melting point of strontium iodide (~515 oC), crystal growth can be carried out in quartz crucibles by the vertical Bridgman technique. Materials-processing and crystal-growth techniques that are specific to the Bridgman growth of europium-doped strontium iodide scintillators are described here. These techniques include the use of a porous quartz frit to physically filter the molten salt from a quartz antechamber into the Bridgman growth crucible and the use of a bent or bulb grain selector design to suppress multiple grain growth. Single crystals of SrI2:Eu2+ scintillators with good optical quality and scintillation characteristics have been grown in sizes up to 5.0 cm in diameter by applying these techniques. Other aspects of the SrI2:Eu2+ crystal-growth methods and of the still unresolved crystal-growth issues are described here.

  11. Carbon Dioxide Reduction Through Urban Forestry

    E-Print Network [OSTI]

    Standiford, Richard B.

    . Retrieval Terms: urban forestry, carbon dioxide, sequestration, avoided energy The Authors E. Gregory McCarbon Dioxide Reduction Through Urban Forestry: Guidelines for Professional and Volunteer Tree; Simpson, James R. 1999. Carbon dioxide reduction through urban forestry

  12. Carbon Fiber Composite Cellular A Dissertation

    E-Print Network [OSTI]

    Wadley, Haydn

    Carbon Fiber Composite Cellular Structures ____________________________________ A Dissertation and honeycombs. However, for weight sensitive, ambient temperature applications, carbon fiber composites have emerged as a promising material due to its high specific strength and low density. Carbon fiber reinforced

  13. A synthesis of carbon in international trade

    E-Print Network [OSTI]

    Peters, G. P; Davis, S. J; Andrew, R.

    2012-01-01T23:59:59.000Z

    and Peters, G. P. : Carbon Footprint of Nations: A Global,analysis for na- tional carbon footprint accounting, Eco.study of the UK’s carbon footprint, Eco. Syst. Res. , 22,

  14. Carbon Nanotubes: Bearing Stress Like Never Before

    E-Print Network [OSTI]

    Limaye, Aditya

    2013-01-01T23:59:59.000Z

    of the mechanical properties of carbon nanotube– polymercomposites. Carbon, 44. 1624 – 1652 doi: 10.1016/j.R.H. , & Hart, A.J. (2013). Carbon Nanotubes: Present and

  15. CARBON MARKETS AROUND THE WORLD Ashley Lawson

    E-Print Network [OSTI]

    California at Davis, University of

    CARBON MARKETS AROUND THE WORLD Ashley Lawson Senior Analyst, Thomson Reuters Point Carbon only pilot trading carbon 6 #12;Shenzhen · Policy ­ Intensity-based ETS started June 18, 2013

  16. Who Pays a Price on Carbon?

    E-Print Network [OSTI]

    Grainger, Corbett A.; Kolstad, Charles D.

    2010-01-01T23:59:59.000Z

    on a per-capita basis a carbon price is much more regressiveadverse distributional effects of a carbon emissions policy.Distributional incidence · Carbon tax · Tradable permits Q52

  17. Link between optical spectra, crystal-field parameters, and local environments of Eu{sup 3+} ions in Eu{sub 2}O{sub 3}-doped sodium disilicate glass

    SciTech Connect (OSTI)

    Qin, T.; Mountjoy, G.; Afify, N. D. [School of Physical Sciences, University of Kent, Canterbury CT2 7NH (United Kingdom); Reid, M. F. [Department of Physics and Astronomy and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Christchurch 8140 (New Zealand); Yeung, Y. Y. [Department of Science and Environmental Studies, Hong Kong Institute of Education, 10 Lo Ping Road, Tai Po, New Territories, Hong Kong (Hong Kong); Speghini, A.; Bettinelli, M. [Laboratorio di Chimica dello Stato Solido, DB, Universita di Verona, INSTM, UdR Verona, I-37134 Verona (Italy)

    2011-09-01T23:59:59.000Z

    Rare-earth-doped glasses are key materials for optical technology due to the luminescent properties of 4f{sup n} ions. The crystal-field model describes the effect of local environment on transitions between 4f electrons. We present a detailed modeling study of the optical spectra of sodium disilicate glass, 33Na{sub 2}O{center_dot}67SiO{sub 2}, doped with 0.2% and 1.0 mol%Eu{sub 2}O{sub 3}. This study uses very large molecular dynamics models with up to 100 Eu{sup 3+} ions, the superposition model for covalent and overlap effects on crystal-field parameters, and realistic values for homogeneous linewidth broadening. The simulated spectra are in reasonable agreement with experiment. The trends in {sup 7} F{sub J} energy levels across different Eu{sup 3+} ion sites have been examined and a very detailed analysis is presented that looks at how features of the spectra are related to features of the local environment of Eu{sup 3+} ions. Increasing the crystal-field strength S{sub total} causes the {sup 7} F{sub 0} energy level to decrease and causes the splitting of {sup 7} F{sub J} manifolds to increase, and this is due to increasing mixing of 4f wave functions. To a reasonable approximation the crystal-field strength components S{sub k} depend on angular positions of ligands independently of distances to ligands. The former are seen to be more significant in determining S{sub k}, which are closely related to the rotationally invariant bond-orientational order parameters Q{sub k}. The values of S{sub 2} are approximately linear in Q{sub 2}, and the values of Q{sub 2} are higher for fivefold than sixfold coordinated rare-earth ions. These results can be of importance for efforts to enhance the local environment of rare-earth ions in oxide glasses for optical applications.

  18. 2013 Carbon Management Research Symposium

    E-Print Network [OSTI]

    . BACKGROUND · As a first step towards developing risk assessment strategies for carbon sequestration projects2013 Carbon Management Research Symposium Effects of Formation Heterogeneity on CO2 Gas Phase Attenuation in the Shallow Subsurface During Possible Leakage from Geologic Sequestration Sites Michael

  19. Permafrost soils and carbon cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ping, C. L.; Jastrow, J. D.; Jorgenson, M. T.; Michaelson, G. J.; Shur, Y. L.

    2015-01-01T23:59:59.000Z

    Knowledge of soils in the permafrost region has advanced immensely in recent decades, despite the remoteness and inaccessibility of most of the region and the sampling limitations posed by the severe environment. These efforts significantly increased estimates of the amount of organic carbon stored in permafrost-region soils and improved understanding of how pedogenic processes unique to permafrost environments built enormous organic carbon stocks during the Quaternary. This knowledge has also called attention to the importance of permafrost-affected soils to the global carbon cycle and the potential vulnerability of the region's soil organic carbon (SOC) stocks to changing climatic conditions. Inmore »this review, we briefly introduce the permafrost characteristics, ice structures, and cryopedogenic processes that shape the development of permafrost-affected soils, and discuss their effects on soil structures and on organic matter distributions within the soil profile. We then examine the quantity of organic carbon stored in permafrost-region soils, as well as the characteristics, intrinsic decomposability, and potential vulnerability of this organic carbon to permafrost thaw under a warming climate. Overall, frozen conditions and cryopedogenic processes, such as cryoturbation, have slowed decomposition and enhanced the sequestration of organic carbon in permafrost-affected soils over millennial timescales. Due to the low temperatures, the organic matter in permafrost soils is often less humified than in more temperate soils, making some portion of this stored organic carbon relatively vulnerable to mineralization upon thawing of permafrost.« less

  20. LOW CARBON & 570 million GVA

    E-Print Network [OSTI]

    Wrigley, Stuart

    LOW CARBON & RENEWABLES #12;£570 million GVA THE SECTOR COMPRISES 326 COMPANIES EMPLOYING 12- tor comprises 326 companies, employing approximately 12,240 people and contributing £570 million nuclear, wind, solar, geo-thermal and tidal power. The total market value of the low carbon environmental

  1. Process for making hollow carbon spheres

    DOE Patents [OSTI]

    Luhrs, Claudia C.; Phillips, Jonathan; Richard, Monique N.; Knapp, Angela Michelle

    2013-04-16T23:59:59.000Z

    A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

  2. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Perry, William L. (Jemez Springs, NM); Chen, Chun-Ku (Albuquerque, NM)

    2006-02-14T23:59:59.000Z

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  3. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M. (National Energy Technology Laboratory, Pittsburgh, PA); Romanov, Vyacheslav N. (National Energy Technology Laboratory, Pittsburgh, PA); Cygan, Randall Timothy

    2010-11-01T23:59:59.000Z

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  4. RE/ZrO{sub 2} (RE = Sm, Eu) composite oxide nano-materials: Synthesis and applications in photocatalysis

    SciTech Connect (OSTI)

    Du, Weimin, E-mail: duweimin75@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); Zhu, Zhaoqiang [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450001 (China); Zhang, Xiaofen; Wang, Dacheng; Liu, Donghe [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); Qian, Xuefeng [School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240 (China); Du, Jimin, E-mail: djm@aynu.edu.cn [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • RE/ZrO{sub 2} (RE = Sm, Eu) nano-materials have been successfully synthesized. • Defect and electron structures determine the absorption properties on visible light. • Nano-sized Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} has good visible-light-responsive photocatalytic activities. • In the future, it can be used in wastewater treatment and environmental protection. - Abstract: Zirconia modified by Samarium/Europium, RE/ZrO{sub 2} (RE = Sm, Eu), composite oxide nano-materials have been successfully synthesized by improved sol–gel method. Characterization results show that X-ray diffraction (XRD) peaks of products gradually shift to the lower angle with the increase of rare earth which implies that the lattice distances of RE/ZrO{sub 2} nano-materials are gradually enlarged. Moreover, the molar ratios between zirconium and rare earth are consistent with the chemical formula and both of them are uniformly distributed in samples. Optical properties indicate that defect structures and electron configurations of RE/ZrO{sub 2} (RE = Sm, Eu) with single phase determine their absorption properties on visible light. Photocatalytic experiments indicate Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} nano-crystals have excellent visible-light-responsive photocatalytic activities on Methylene blue and Rhodamine B which results from the special defect structure, suitable electronic configuration, and larger specific surface area. It follows that Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} nano-crystals are new visible-light-responsive photocatalysts which can be applied in dye wastewater treatment and environmental protection in the future.

  5. atomics international aqueous carbonate procelladonna: Topics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PROGRAM ON ENERGY AND Geosciences Websites Summary: and storage, 6) adaptation of wholesale electricity markets to support a low-carbon future, 7) global power carbon policy...

  6. Carbon Storage Atlas, Employee Newsletter Earn International...

    Broader source: Energy.gov (indexed) [DOE]

    NETL's Carbon Storage Atlas IV and FE's internal employee newsletter, inTouch, earned 2013 National Association of Government Communicators awards. NETL's Carbon Storage Atlas IV...

  7. Who Pays a Price on Carbon?

    E-Print Network [OSTI]

    Grainger, Corbett A.; Kolstad, Charles D.

    2010-01-01T23:59:59.000Z

    that a fully auctioned emissions trading program (with aof a carbon tax or emissions trading system (Fullertona carbon tax or emissions trading system may have exemptions

  8. New Zealand Joins International Carbon Storage Group

    Broader source: Energy.gov [DOE]

    The Carbon Sequestration Leadership Forum today announced that New Zealand has become the newest member of the international carbon storage body.

  9. Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

  10. Energy-Related Carbon Emissions in Manufacturing

    Reports and Publications (EIA)

    2000-01-01T23:59:59.000Z

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  11. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  12. GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA to extend our thanks to the authors of various West Coast Regional Carbon Sequestration Partnership

  13. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:May 2015 All Issues submit Greening up fossil fuels with carbon...

  14. Carbonic Acid Shows Promise in Geology, Biology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprising Secrets of Carbonic Acid Probing the Surprising Secrets of Carbonic Acid Berkeley Lab Study Holds Implications for Geological and Biological Processes October 23,...

  15. Electrical Transport in Carbon Nanotubes and Graphene

    E-Print Network [OSTI]

    Liu, Gang

    2010-01-01T23:59:59.000Z

    Introduction to Carbon Nanotubes and Graphene Single wallCarbon nanotubes and graphene are the most popular Carbonin the Normal Metal – Graphene – Superconductor Junctions

  16. Carbon Fiber Pilot Plant and Research Facilities

    Broader source: Energy.gov (indexed) [DOE]

    for the U.S. Department of Energy Presentationname Carbon Fiber Facilities Materials Carbon Fiber Research Facility Type Production Fiber Types Tow Size Tensioning Line...

  17. Structure and Transformation of Amorphous Calcium Carbonate:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformation of Amorphous Calcium Carbonate: A Solid-State 43Ca NMR and Computational Molecular Dynamics Structure and Transformation of Amorphous Calcium Carbonate: A...

  18. Prospects for Enhancing Carbon Sequestration and Reclamation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prospects for Enhancing Carbon Sequestration and Reclamation of Degraded Lands with Fossil-fuel Combustion By-products. Prospects for Enhancing Carbon Sequestration and Reclamation...

  19. Putting the pressure on carbon dioxide | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on carbon dioxide Released: March 26, 2014 Improving the chances for fuel recovery and carbon sequestration Artwork from this research graces the cover of Environmental Science...

  20. UCSF Sustainability Baseline Assessment: Carbon Footprint Analysis

    E-Print Network [OSTI]

    Yamamoto, Keith

    UCSF Sustainability Baseline Assessment: Carbon Footprint Analysis Final Issue Date: March 21, 2010 #12;Carbon Footprint Analysis Background This chapter of the Sustainability Assessment focuses on UCSF

  1. A chemistry tale of two carbons | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A chemistry tale of two carbons A chemistry tale of two carbons Released: September 03, 2012 Comprehensive field study of urban, natural emissions interacting to affect climate...

  2. Electrochemical implications of defects in carbon nanotubes

    E-Print Network [OSTI]

    Hoefer, Mark

    2012-01-01T23:59:59.000Z

    conducting polymer hybrid supercapacitors. Journal of Thestudies of carbon-carbon supercapacitors. Journal of TheHigh-voltage asymmetric supercapacitors operating in aqueous

  3. Noncovalently functionalized graphitic mesoporous carbon as a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    functionalized graphitic mesoporous carbon as a stable support of Pt nanoparticles for oxygen reduction. Noncovalently functionalized graphitic mesoporous carbon as a stable...

  4. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration Systems This case study documents one...

  5. Functionalized carbon nanotubes and nanofibers for biosensing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon nanotubes and nanofibers for biosensing applications. Functionalized carbon nanotubes and nanofibers for biosensing applications. Abstract: This review summarizes the recent...

  6. CFTF | Carbon Fiber Technology Facility | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BTRIC CNMS CSMB CFTF Working with CFTF HFIR MDF NTRC OLCF SNS Carbon Fiber Technology Facility Home | User Facilities | CFTF CFTF | Carbon Fiber Technology Facility SHARE Oak...

  7. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiohon, Georges A; Liang, Chengdu

    2013-02-05T23:59:59.000Z

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  8. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiochon, Georges A; Liang, Chengdu

    2014-01-14T23:59:59.000Z

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  9. California Low Carbon Fuels Infrastructure Investment Initiative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Carbon Fuels Infrastructure Investment Initiative California Low Carbon Fuels Infrastructure Investment Initiative 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  10. Synthesis and photoluminescence properties of NaLaMgWO{sub 6}:RE{sup 3+} (RE = Eu, Sm, Tb) phosphor for white LED application

    SciTech Connect (OSTI)

    Hou, Jingshan [College of Materials Science and Engineering, Dong Hua University, Shanghai 200051 (China) [College of Materials Science and Engineering, Dong Hua University, Shanghai 200051 (China); CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Yin, Xin [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China) [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Huang, Fuqiang, E-mail: huangfq@mail.sic.ac.cn [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China) [CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Jiang, Weizhong, E-mail: jwzh@dhu.edu.cn [College of Materials Science and Engineering, Dong Hua University, Shanghai 200051 (China)] [College of Materials Science and Engineering, Dong Hua University, Shanghai 200051 (China)

    2012-06-15T23:59:59.000Z

    Highlights: ? NaLa{sub 1?x}MgWO{sub 6}:xRE{sup 3+} phosphors were synthesized by solid-state reaction method. ? Compared with Y{sub 2}O{sub 3}:Eu{sup 3+}, NaLaMgWO{sub 6}:Eu{sup 3+} performed better luminescence properties. ? The results demonstrated NaLaMgWO{sub 6} as a suitable host for RE{sup 3+}-doping. -- Abstract: Single phase of NaLa{sub 1?x}MgWO{sub 6}:xRE{sup 3+} (0 < x ?1) (RE = Eu, Sm, Tb) phosphors were prepared by solid-state reaction method. X-ray diffraction, scanning electron microscopy, the morphology energy-dispersive X-ray spectroscopy, UV–vis diffuse reflectance spectra and photoluminescence were used to characterize the samples. Under the light excitation, NaLaMgWO{sub 6}:Eu{sup 3+}, NaLaMgWO{sub 6}:Sm{sup 3+} and NaLaMgWO{sub 6}:Tb{sup 3+}, phosphors showed the characteristic emissions of Eu{sup 3+} ({sup 5}D{sub 0} ? {sup 7}F{sub 4,3,2,1}), Sm{sup 3+} ({sup 4}G{sub 5/2} ? {sup 6}H{sub 5/2,7/2,9/2}), and Tb{sup 3+} ({sup 5}D{sub 4} ? {sup 7}F{sub 6,5,4,3}), respectively. The intensity of the red emission for Na(La{sub 0.6}Eu{sub 0.4})MgWO{sub 6} is 2.5 times higher than that of (Y{sub 0.95}Eu{sub 0.05}){sub 2}O{sub 3} under blue light irradiation. The quantum efficiencies of the entitled phosphors excited under 394 nm and 464 nm are also investigated and compared with commercial phosphors Y{sub 2}O{sub 3}:Eu{sup 3+}, Sr{sub 2}Si{sub 5}N{sub 8}:Eu{sup 2+} and Y{sub 3}A{sub 5}G{sub 12}:Ce{sup 3+}. The results demonstrated NaLaMgWO{sub 6}:RE{sup 3+} phosphors as potential candidates for white light emitting diode pumped by UV or blue chip.

  11. Electrodynamics of single-crystal Eu/sub 2/CuO/sub 4/: A boson excitation spectrum

    SciTech Connect (OSTI)

    Reagor, D.W.; Cheong, S.; Brown, S.E.; Migliori, A.; Fisk, Z.; Thompson, J.D.

    1988-01-01T23:59:59.000Z

    Static and microwave measurements of the electronic response of the planar cuprate Eu/sub 2/CuO/sub 4/ provide evidence for thermally activated collective excitations. These observations together with microwave and other measurements on superconductors suggest that paired charge--carrying objects may exist both above and below T/sub c/ in the superconductors. If these objects, which can be related to solitons of a spin density wave ground state, play a role in superconductivity, certain conclusions may be drawn. We discuss here the evidence for such objects and their implications. 19 refs., 5 figs.

  12. Superconducting and magnetic properties of a new EuAsFeO0.85F0.15 superconductor

    E-Print Network [OSTI]

    V. M. Dmitriev; I. E. Kostyleva; E. P. Khlybov; A. J. Zaleski; A. V. Terekhov; L. F. Rybaltchenko; E. V. Khristenko; L. A. Ishchenko

    2009-01-16T23:59:59.000Z

    Polycrystalline samples of a new superconducting EuAsFeO0.85F0.15 compound with critical temperature Tc=11K were prepared by solid state synthesis. Its electric and magnetic properties have been investigated in magnetic fields from 0.1 to 140000 Oe. Critical magnetic fields Hc1, and Hc2 were measured and hence the magnetic penetration depths and the coherence length have been estimated. The temperature dependence Hc2 (T) exhibits clear hyperbolic - type behavior starting with the lowest fields. The data derived were used to estimate probable high Tc and Hc2 in compounds doped with rare-earths having small atomic radii.

  13. Analysis of Beta-Decay Rates for Ag108, Ba133, Eu152, Eu154, Kr85, Ra226 And Sr90, Measured at the Physikalisch-Technische Bundesanstalt from 1990 to 1996

    E-Print Network [OSTI]

    Peter A. Sturrock; Ephraim Fischbach; Jere Jenkins

    2014-10-10T23:59:59.000Z

    We present the results of an analysis of measurements of the beta-decay rates of Ag108, Ba133, Eu152, Eu154, Kr85, Ra226, and Sr90 acquired at the Physikalisch-Technische Bundesanstalt from 1990 through 1995. Although the decay rates vary over a range of 165 to 1 and the measured detector current varies over a range of 19 to 1, the detrended and normalized current measurements exhibit a sinusoidal annual variation with amplitude in the small range 0.068% to 0.088% (mean 0.081%, standard deviation 0.0072%, an 11{\\sigma} rejection of the zero-amplitude hypothesis) and phase-of-maximum in the small range 0.062 to 0.083 (January 23 to January 30). In comparing these results with those of other related experiments that yield different results, it may be significant that this experiment, at a standards laboratory, seems to be unique in using a 4{\\pi} detector. These results are compatible with a solar influence, and appear not to be compatible with an experimental or environmental influence. It is possible that Ba133 measurements are subject also to a non-solar (possibly cosmic) influence.

  14. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    1999-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  15. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1999-04-27T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  16. Method for fabricating composite carbon foam

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Pekala, Richard W. (Pleasant Hill, CA); Kaschmitter, James L. (Pleasanton, CA)

    2001-01-01T23:59:59.000Z

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  17. Gas permeability of carbon aerogels

    SciTech Connect (OSTI)

    Kong, F.; LeMay, J.D.; Hulsey, S.S.; Alviso, C.T.; Pekala, R.W. (Chemistry and Materials Science Department, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States))

    1993-12-01T23:59:59.000Z

    Carbon aerogels are synthesized via the aqueous polycondensation of resorcinol with formaldehyde, followed by supercritical drying and subsequent pyrolysis at 1050 [degree]C. As a result of their interconnected porosity, ultrafine cell/pore size, and high surface area, carbon aerogels have many potential applications such as supercapacitors, battery electrodes, catalyst supports, and gas filters. The performance of carbon aerogels in the latter two applications depends on the permeability or gas flow conductance in these materials. By measuring the pressure differential across a thin specimen and the nitrogen gas flow rate in the viscous regime, the permeability of carbon aerogels was calculated from equations based upon Darcy's law. Our measurements show that carbon aerogels have permeabilities on the order of 10[sup [minus]12] to 10[sup [minus]10] cm[sup 2] over the density range from 0.05--0.44 g/cm[sup 3]. Like many other aerogel properties, the permeability of carbon aerogels follows a power law relationship with density, reflecting differences in the average mesopore size. Comparing the results from this study with the permeability of silica aerogels reported by other workers, we found that the permeability of aerogels is governed by a simple universal flow equation. This paper discusses the relationship between permeability, pore size, and density in carbon aerogels.

  18. Carbon foam characterization tensile evaluation of carbon foam ligaments 

    E-Print Network [OSTI]

    Verdugo Rodriguez, Rogelio Alberto

    2004-09-30T23:59:59.000Z

    A methodology for ligament isolation and specimen preparation for tensile testing of single ligaments from the unit cell of open-cell carbon foams has been successfully developed and implemented. Results are presented for ...

  19. Carbon dioxide hydrate particles for ocean carbon sequestration

    E-Print Network [OSTI]

    Chow, A.C.

    This paper presents strategies for producing negatively buoyant CO[subscript 2] hydrate composite particles for ocean carbon sequestration. Our study is based on recent field observations showing that a continuous-jet ...

  20. Atmospheric carbon dioxide and the global carbon cycle

    SciTech Connect (OSTI)

    Trabalka, J R [ed.

    1985-12-01T23:59:59.000Z

    This state-of-the-art volume presents discussions on the global cycle of carbon, the dynamic balance among global atmospheric CO2 sources and sinks. Separate abstracts have been prepared for the individual papers. (ACR)

  1. Carbon-Optimal and Carbon-Neutral Supply Chains

    E-Print Network [OSTI]

    Caro, F.; Corbett, C. J.; Tan, T.; Zuidwijk, R.

    2011-01-01T23:59:59.000Z

    that the focus in the life-cycle assessment (LCA) and carbonclosely related to life-cycle assessment (LCA). The existingsupply chains, and on life-cycle assessment (LCA) and carbon

  2. Measuring supply chain carbon efficiency : a carbon label framework

    E-Print Network [OSTI]

    Craig, Anthony (Anthony J.)

    2012-01-01T23:59:59.000Z

    In the near term, efficiency improvements represent a key option for reducing the impacts of climate change. The growing awareness of climate change has increased the attention regarding the carbon emissions "embedded" in ...

  3. Carbon films produced from ionic liquid carbon precursors

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Lee, Je Seung

    2013-11-05T23:59:59.000Z

    The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

  4. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07T23:59:59.000Z

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  5. Carbon Markets and Technological Innovation

    E-Print Network [OSTI]

    Weber, T A; Neuhoff, Karsten

    www.eprg.group.cam.ac.uk E P R G W O R K IN G P A P E R N O N -T E C H N IC A L S U M M A R Y Carbon Markets and Technological Innovation EPRG Working Paper 0917 Cambridge Working Paper in Economics 0932 Thomas A. Weber... and Karsten Neuhoff This paper examines how considering firm-level innovation in carbon-abatement technologies influences the optimal design choice for carbon pricing. It builds on Weitzman’s model (1974) that shows in what instances cap and trade...

  6. Magnetization-induced enhancement of photoluminescence in core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite

    SciTech Connect (OSTI)

    Jia, Yanmin, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Zhou, Zhihua; Wei, Yongbin [Department of Physics, Zhejiang Normal University, Jinhua 321004 (China); Wu, Zheng, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Chen, Jianrong [College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004 (China); Zhang, Yihe [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Liu, Yongsheng [Department of Physics, Shanghai University of Electric Power, Shanghai 200090 (China)

    2013-12-07T23:59:59.000Z

    After the core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite synthesized through a facile sol-gel method was magnetized under an external magnetic field of 0.25?T for 4?h, an enhancement of ?56% in photoluminescence intensity was observed. The remanent magnetization of the CoFe{sub 2}O{sub 4} core increases the intensity of the excited charge transfer transition of VO{sub 4}{sup 3?} group in YVO{sub 4}:Eu{sup 3+} shell, which may enhance the probability related to the Eu{sup 3+} radiative transition {sup 5}D{sub 0}-{sup 7}F{sub 2}, yielding to a high photoluminescence. The obvious remanent-magnetization-induced enhancement in photoluminescence is helpful in developing excellent magnetic/luminescent material for the practical display devices.

  7. Eu3+ as a dual probe for the determination of IL anion donor power: A combined luminescence spectroscopic and electrochemical approach

    SciTech Connect (OSTI)

    Babai, Arash; Kopiec, Gabriel; Lackmann, Anastasia; Mallick, Bert; Pitula, Slawomir; Tang, Sifu; Mudring, Anja-Verena

    2014-04-01T23:59:59.000Z

    This work is aimed at giving proof that Eu(Tf2N)(3) (Tf2N = bis(trifluoromethanesulfonyl)amide) can act as both an optical and electrochemical probe for the determination of the Lewis acidity of an ionic liquid anion. For that reason the luminescence spectra and cyclic voltammograms of dilute solutions of Eu(Tf2N)(3) in various ionic liquids were investigated. The Eu2+/3+ redox potential in the investigated ILs can be related to the Lewis basicity of the IL anion. The IL cation had little influence. The lower the determined halfwave potential, the higher the IL anion basicity. The obtained ranking can be confirmed by luminescence spectroscopy where a bathochromic shift of the D-5(0) -> F-7(4) transition indicates a stronger Lewis basicity of the IL anion. (C) 2014 Published by Elsevier B.V.

  8. Photoluminescence spectroscopy of YVO$_{4}$:Eu$^{3+}$ nanoparticles with aromatic linker molecules: a precursor to biomedical functionalization

    E-Print Network [OSTI]

    Senty, T R; Zhang, Y; Cushing, S K; Seehra, M S; Shi, X; Bristow, A D

    2014-01-01T23:59:59.000Z

    Here, photoluminescence spectra of YVO$_{4}$:Eu$^{3+}$ nanoparticles are presented,with and without the attachment of of organic linker molecules that are proposed for linking to biomolecules. YVO$_{4}$:Eu$^{3+}$ nanoparticles with 5% dopant concentration were synthesized by wet chemical synthesis. X-ray diffraction and transmission electron microscopy show the expected wakefieldite structure of tetragonal particles with an average size of 17 nm. Fourier-transform infrared spectroscopy determines that metal-carboxylate coordination is successful in replacing the native metal-hydroxyl bonds with three organic linkers, namely benzoic acid, 3-nitro 4-chloro-benzoic acid and 3,4-dihydroxybenzoic acid, in separate treatments. UV-excitation photoluminescence spectra show that the position and intensity of dominant $^{5}D_{0}-^{7}F_{2}$ electric-dipole transition at 619 nm is unaffected by the benzoic acid and 3-nitro 4-chloro-benzoic acid treatments. Attachment of the 3,4-dihydroxybenzoic acid produces an order-of-...

  9. Rapid oxidation/stabilization technique for carbon foams, carbon fibers and C/C composites

    DOE Patents [OSTI]

    Tan, Seng; Tan, Cher-Dip

    2004-05-11T23:59:59.000Z

    An enhanced method for the post processing, i.e. oxidation or stabilization, of carbon materials including, but not limited to, carbon foams, carbon fibers, dense carbon-carbon composites, carbon/ceramic and carbon/metal composites, which method requires relatively very short and more effective such processing steps. The introduction of an "oxygen spill over catalyst" into the carbon precursor by blending with the carbon starting material or exposure of the carbon precursor to such a material supplies required oxygen at the atomic level and permits oxidation/stabilization of carbon materials in a fraction of the time and with a fraction of the energy normally required to accomplish such carbon processing steps. Carbon based foams, solids, composites and fiber products made utilizing this method are also described.

  10. Purification and Processing of Graphitic Carbons

    E-Print Network [OSTI]

    Worsley, Kimberly Anne

    2010-01-01T23:59:59.000Z

    Oxidation of Petroleum Asphaltenes. Liq. Fuels Tech. 1985,fibers, 2, petroleum asphaltenes, 4 carbon xerogels, 5

  11. Ultimate Isotope Precision for Carbonates Thermo Scientific

    E-Print Network [OSTI]

    Lachniet, Matthew S.

    Ultimate Isotope Precision for Carbonates Thermo Scientific KIEL IV Carbonate Device Part of Thermo integration cycle Ultimate Isotope Precision for Carbonates The Thermo Scientific KIEL IV Carbonate DeviceV Thermo Scientific MAT 253 or the 3-kV DELTA V isotope ratio mass spectrometer meets the requirements

  12. March 2005 Number 238 CARBON CAPTURE AND

    E-Print Network [OSTI]

    Mather, Tamsin A.

    March 2005 Number 238 CARBON CAPTURE AND STORAGE (CCS) As part of the government's global strategy. This POSTnote discusses the potential of carbon capture and storage (CCS), a method of carbon sequestration2 and will be included in the forthcoming Department of Trade and Industry (DTI) Carbon Abatement Technology Strategy

  13. Biochar and Carbon Sequestration: A Regional Perspective

    E-Print Network [OSTI]

    Everest, Graham R

    Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East of England #12;Low Carbon Innovation Centre Report for EEDA Biochar and Carbon Sequestration: A Regional Perspective 20/04/2009 ii Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East

  14. CARBON DIOXIDE AND OUR OCEAN LEGACY

    E-Print Network [OSTI]

    is a biologist at the California State Univer- sity San Marcos, with expertise in the effects of carbon dioxideCARBON DIOXIDE AND OUR OCEAN LEGACY G Carbon Dioxide: Our Role The United States is the single. Every day the average American adds about 118 pounds of carbon dioxide to the atmos- phere, due largely

  15. Mesoporous carbonates and method of making

    DOE Patents [OSTI]

    Fryxell, Glen; Liu, Jun; Zemanian, Thomas S.

    2004-06-15T23:59:59.000Z

    Mesoporous metal carbonate structures are formed by providing a solution containing a non-ionic surfactant and a calcium acetate salt, adding sufficient base to react with the acidic byproducts to be formed by the addition of carbon dioxide, and adding carbon dioxide, thereby forming a mesoporous metal carbonate structure containing the metal from said metal salt.

  16. INTRODUCTION Pedogenic (secondary) calcium carbonate is,

    E-Print Network [OSTI]

    Ahmad, Sajjad

    INTRODUCTION Pedogenic (secondary) calcium carbonate is, by definition, a product of soil processes of calcium for pe- dogenic calcium carbonate (Gile et al., 1979). In regard to the source of the carbonate; Cerling et al., 1989; Quade et al., 1989). Because pedogenic calcium carbonate is read- ily soluble, its

  17. 6 Monthly Report on MMU Carbon

    E-Print Network [OSTI]

    Monthly Report on MMU Carbon Management Plan #12;2009/10 Emissions MMU Carbon Footprint Trajectory Project Footprint MMU Actual Carbon Footprint Projects that Reduced the 2009/10 CO2 Footprint #12;2010/11 Emissions6 Monthly Report on MMU Carbon Management Plan June 2011 let's make a sustainable planet #12

  18. Carbon nanotubes : synthesis, characterization, and applications

    E-Print Network [OSTI]

    Deck, Christian Peter

    2009-01-01T23:59:59.000Z

    in carbon nanotube ceramic matrix composites. Actapolymeric, metallic, or ceramic matrix material. These fiber

  19. Carbon Capture and Storage Realising the potential?

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Carbon Capture and Storage Realising the potential? UKERC Research Project #12;Carbon Capture Winskel University of Edinburgh Peter Pearson and Stathis Arapostathis Low Carbon Research Institute @UKERKHQ #12;UKERC Research Project: Carbon Capture and Storage: Realising the potential? 01 It is the hub

  20. Carbon dioxide storage professor Martin Blunt

    E-Print Network [OSTI]

    Carbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS) referS to the Set of technologies developed to capture carbon dioxide (Co2) gas from the exhausts raises new issues of liability and risk. the focus of this briefing paper is on the storage of carbon