National Library of Energy BETA

Sample records for airborne particulates pm10

  1. Airborne particulate discriminator

    DOE Patents [OSTI]

    Creek, Kathryn Louise; Castro, Alonso; Gray, Perry Clayton

    2009-08-11

    A method and apparatus for rapid and accurate detection and discrimination of biological, radiological, and chemical particles in air. A suspect aerosol of the target particulates is treated with a taggant aerosol of ultrafine particulates. Coagulation of the taggant and target particles causes a change in fluorescent properties of the cloud, providing an indication of the presence of the target.

  2. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  3. Tonopah Test Range Air Monitoring: CY2012 Meteorological, Radiological, and Airborne Particulate Observations

    SciTech Connect (OSTI)

    Mizell, Steve A; Nikolich, George; Shadel, Craig; McCurdy, Greg; Miller, Julianne J

    2013-07-01

    In 1963, the Atomic Energy Commission (AEC), predecessor to the US Department of Energy (DOE), implemented Operation Roller Coaster on the Tonopah Test Range (TTR) and an adjacent area of the Nevada Test and Training Range (NTTR) (formerly the Nellis Air Force Range (NAFR)). Operation Roller Coaster consisted of four tests in which chemical explosions were detonated in the presence of nuclear devices to assess the dispersal of radionuclides and evaluate the effectiveness of storage structures to contain the ejected radionuclides. These tests resulted in dispersal of plutonium over the ground surface downwind of the test ground zero. Three tests, Clean Slate 1, 2, and 3, were conducted on the TTR in Cactus Flat; the fourth, Double Tracks, was conducted in Stonewall Flat on the NTTR. DOE is working to clean up and close all four sites. Substantial cleaned up has been accomplished at Double Tracks and Clean Slate 1. Cleanup of Clean Slate 2 and 3 is on the DOE planning horizon for some time in the next several years. The Desert Research Institute installed two monitoring stations, number 400 at the Sandia National Laboratories Range Operations Center and number 401 at Clean Slate 3, in 2008 and a third monitoring station, number 402 at Clean Slate 1, in 2011 to measure radiological, meteorological, and dust conditions. The primary objectives of the data collection and analysis effort are to (1) monitor the concentration of radiological parameters in dust particles suspended in air, (2) determine whether winds are re-distributing radionuclides or contaminated soil material, (3) evaluate the controlling meteorological conditions if wind transport is occurring, and (4) measure ancillary radiological, meteorological, and environmental parameters that might provide insight to the above assessments. The following observations are based on data collected during CY2012. The mean annual concentration of gross alpha and gross beta is highest at Station 400 and lowest at Station 401. This difference may be the result of using filter media at Station 400 with a smaller pore size than the media used at the other two stations. Average annual gamma exposure at Station 401 is slightly greater than at Station 400 and 402. Average annual gamma exposure at all three TTR stations are in the upper range to slightly higher than values reported for the CEMP stations surrounding the TTR. At higher wind speeds, the saltation counts are greater at Station 401 than at Station 402 while the suspended particulate concentrations are greater at Station 402 than at Statin 401. Although these observations seem counterintuitive, they are likely the result of differences in the soil material present at the two sites. Station 401 is located on an interfluve elevated above two adjacent drainage channels where the soil surface is likely to be composed of coarser material. Station 402 is located in finer sediments at the playa edge and is also subject to dust from a dirt road only 500 m to the north. During prolonged high wind events, suspended dust concentrations at Station 401 peaked with the initial winds then decreased whereas dust concentrations at Station 402 peaked with each peak in the wind speed. This likely reflects a limited PM10 source that is quickly expended at Station 401 relative to an abundant PM10 source at Station 402. In CY2013, to facilitate comparisons between radiological analyses of collected dust, the filter media at all three stations will be standardized. In addition, a sequence of samples will be collected at Station 400 using both types of filter media to enable development of a mathematical relationship between the results derived from the two filter types. Additionally, having acquired approximately four years of observations at Stations 400 and 401 and a year of observations at Station 402, a period-of-record analysis of the radiological and airborne dust conditions will be undertaken.

  4. Acute health effects of PM10 pollution on symptomatic and asymptomatic children

    SciTech Connect (OSTI)

    Pope, C.A. 3d.; Dockery, D.W. )

    1992-05-01

    This study assessed the association between daily changes in respiratory health and respirable particulate pollution (PM10) in Utah Valley during the winter of 1990-1991. During the study period, 24-h PM10 concentrations ranged from 7 to 251 micrograms/m3. Participants included symptomatic and asymptomatic samples of fifth- and sixth-grade students. Relatively small but statistically significant (p less than 0.01) negative associations between peak expiratory flow (PEF) and PM10 were observed for both the symptomatic and asymptomatic samples. The association was strongest for the symptomatic children. Large associations between the incidence of respiratory symptoms, especially cough, and PM10 pollution were also observed for both samples. Again the association was strongest for the symptomatic sample. Immediate and delayed PM10 effects were observed. Respiratory symptoms and PEF changes were more closely associated with 5-day moving-average PM10 levels than with concurrent-day levels. These associations were also observed at PM10 levels below the 24-h standard of 150 micrograms/m3. This study indicates that both symptomatic and asymptomatic children may suffer acute health effects of respirable particulate pollution, with symptomatic children suffering the most.

  5. Apparatus for real-time airborne particulate radionuclide collection and analysis

    DOE Patents [OSTI]

    Smart, John E. (West Richland, WA); Perkins, Richard W. (Richland, WA)

    2001-01-01

    An improved apparatus for collecting and analyzing an airborne particulate radionuclide having a filter mounted in a housing, the housing having an air inlet upstream of the filter and an air outlet downstream of the filter, wherein an air stream flows therethrough. The air inlet receives the air stream, the filter collects the airborne particulate radionuclide and permits a filtered air stream to pass through the air outlet. The improvement which permits real time counting is a gamma detecting germanium diode mounted downstream of the filter in the filtered air stream. The gamma detecting germanium diode is spaced apart from a downstream side of the filter a minimum distance for a substantially maximum counting detection while permitting substantially free air flow through the filter and uniform particulate radionuclide deposition on the filter.

  6. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from condensation of vaporized material and subsequent rapid formation of aggregates. Particles of larger size, resulting from ejection of melted material or fragments from the cutting zone, were also observed. This study presents data regarding the metal cutting rate, particle size distribution, and their generation rate, while using different cutting tools and metals. The study shows that respirable particles constitute only a small fraction of the released kerf.

  7. Mutagenic activity and chemical analysis of airborne particulates collected in Pisa (Italy)

    SciTech Connect (OSTI)

    Vellosi, R.; Fiorio, R.; Rosellini, D.; Bronzetti, G. ); Vannucchi, C.; Ciacchini, G.; Giaconi, V. ); Bianchi, F. )

    1994-03-01

    In the last few years there has been much concern about the problem connected to the exposure to mutagens present in the environment of industrialized countries. Particularly, the mutagenic activity of airborne particulate matter has been studied by many investigators and correlated with elevated lung cancer mortality rates. In most cases the Salmonella typhimurium/microsome test has been used for these studies. This short-term test, which is the most validated among the short-term genotoxicity tests, provides an important indication on the carcinogenic potential of environmental pollutants. That are complex mixtures containing a wide variety of compounds potentially capable of causing additive, antagonistic or synergistic genotoxic response in living organisms. Several studies have suggested that diverse factors, such as traffic and meteorological conditions, could affect the levels of pollutants in the air. In our work, we have investigated three different areas in Pisa, where the intensity and the kind of the road traffic were different. Airborne particles have been collected during a year and the genotoxic activity has been studied using TA98 and TA100 strains of Salmonella typhimurium. 20 refs., 1 fig., 3 tabs.

  8. Evaluation of static pressure drops and PM10 and TSP emissions for modified 1D-3D cyclones

    SciTech Connect (OSTI)

    Holt, G.A.; Baker, R.V.; Hughs, S.E.

    1999-12-01

    Five modifications of a standard 1D3D cyclone were tested and compared against the standard 1D3D design in the areas of particulate emissions and static pressure drop across the cyclone. The modifications to the 1D3D design included a 2D2D inlet, a 2D2D air outlet, a D/3 trash exit, an expansion chamber with a D/3 trash exit, and a tapered air outlet duct. The 1D3D modifications that exhibited a significant improvement in reducing both PM10 and total suspended particulate (TSP) emissions were the designs with the 2D2D inlet and air exhaust combined with either the conical D/3 tail cone or the expansion chamber. In reference to the standard 1D3D cyclone, the average reduction in PM10 emissions was 24 to 29% with a 29 to 35% reduction observed in TSP emissions. The modifications with the tapered air outlets did not show any significant improvements in controlling PM10 emissions. However, the modification with the tapered air outlet/expansion chamber combination exhibited statistical significance in reducing TSP emissions by 18% compared to the 1D3D cyclone. All modifications tested exhibited lower static pressure drops than the standard 1D3D.

  9. Tonopah Test Range Air Monitoring. CY2014 Meteorological, Radiological, and Airborne Particulate Observations

    SciTech Connect (OSTI)

    Nikoloch, George; Shadel, Craig; Chapman, Jenny; Mizell, Steve A.; McCurdy, Greg; Etyemezian, Vicken; Miller, Julianne J.

    2015-10-01

    In 1963, the U.S. Department of Energy (DOE) (formerly the Atomic Energy Commission [AEC]), implemented Operation Roller Coaster on the Tonopah Test Range (TTR) and an adjacent area of the Nevada Test and Training Range (NTTR) (formerly the Nellis Air Force Range). This test resulted in radionuclide-contaminated soils at Clean Slate I, II, and III. This report documents observations made during ongoing monitoring of radiological, meteorological, and dust conditions at stations installed adjacent to Clean Slate I and Clean Slate III and at the TTR Range Operations Control center. The primary objective of the monitoring effort is to determine if winds blowing across the Clean Slate sites are transporting particles of radionuclide-contaminated soils beyond both the physical and administrative boundaries of the sites. Results for the calendar year (CY) 2014 monitoring are: (1) the gross alpha and gross beta values from the monitoring stations are approximately equivalent to the highest values observed during the CY2014 reporting at the surrounding Community Environmental Monitoring Program (CEMP) stations; (2) only naturally occurring radionuclides were identified in the gamma spectral analyses; (3) the ambient gamma radiation measurements indicate that the average annual gamma exposure is similar at all three monitoring stations and periodic intervals of increased gamma values appear to be associated with storm fronts passing through the area; and (4) the concentrations of both resuspended dust and saltated sand particles generally increase with increasing wind speed. Differences in the observed dust concentrations are likely the result of differences in the soil characteristics immediately adjacent to the monitoring stations. Neither the resuspended particulate radiological analyses nor the ambient gamma radiation measurements suggest wind transport of radionuclide-contaminated soils.

  10. Tonopah Test Range Air Monitoring: CY2013 Meteorological, Radiological, and Airborne Particulate Observations

    SciTech Connect (OSTI)

    Mizell, Steve A; Nikolich, George; Shadel, Craig; McCurdy, Greg; Etyemezian, Vicken; Miller, Julianne J

    2014-10-01

    In 1963, the U.S. Department of Energy (DOE) (formerly the Atomic Energy Commission [AEC]), implemented Operation Roller Coaster on the Tonopah Test Range (TTR) and an adjacent area of the Nevada Test and Training Range (NTTR) (formerly the Nellis Air Force Range). This test resulted in radionuclide-contaminated soils at Clean Slate I, II, and III. This report documents observations made during on-going monitoring of radiological, meteorological, and dust conditions at stations installed adjacent to Clean Slate I and Clean Slate III and at the TTR Range Operations Control center. The primary objective of the monitoring effort is to determine if winds blowing across the Clean Slate sites are transporting particles of radionuclide-contaminated soils beyond both the physical and administrative boundaries of the sites. Results for the calendar year (CY) 2013 monitoring include: (1) the gross alpha and gross beta values from the monitoring stations are approximately equivalent to the highest values observed during the CY2012 reporting at the surrounding Community Environmental Monitoring Program (CEMP) stations (this was the latest documented data available at the time of this writing); (2) only naturally occurring radionuclides were identified in the gamma spectral analyses; (3) the ambient gamma radiation measurements indicate that the average annual gamma exposure is similar at all three monitoring stations and periodic intervals of increased gamma values appear to be associated with storm fronts passing through the area; and (4) the concentrations of both resuspended dust and saltated sand particles generally increase with increasing wind speed. However, differences in the observed dust concentrations are likely due to differences in the soil characteristics immediately adjacent to the monitoring stations. Neither the resuspended particulate radiological analyses nor the ambient gamma radiation measurements suggest wind transport of radionuclide-contaminated soils.

  11. Particulate matter pollution in Mexico City

    SciTech Connect (OSTI)

    Vega R, E.; Mora P, V.; Mugica A, V.

    1998-12-31

    The levels of particulate matter are of concern since they may induce severe effects on public health and is the second atmospheric pollution problem in Mexico City. Another noticeable effect in large cities attributable to particulate matter, is the deterioration of visibility. In this paper the analysis of the data of TSP and PM10 during 1988 to 1996 is presented. The seasonal variation of particulate matter, the typical ratios of PM10/TSP and relationships of the two variables were determined. It was found that PM10 concentrations show an important tendency to decrease during this period, due to some control strategies, although this is not the case for TSP. The monthly trend exhibits a clear relationship with the dry (October through April) and wet (May through September) seasons. The particulate matter concentrations are lower during the wet season. The hourly behavior shows that the highest concentrations are correlated with the traffic rush hours. The most TSP polluted area was the northeast, meanwhile the southeast is the most PM10 polluted area. There is a clear evidence of the particulate matter transportation from these areas to other sites of the City.

  12. PM-10 exhaust samples collected during IM-240 dyanamometer tests of in-service vehicles in Nevada

    SciTech Connect (OSTI)

    Sagebiel, J.C.; Zielinska, B.; Walsh, P.A.; Chow, J.C.; Cadle, S.H.; Mulawa, P.A.; Knapp, K.T.; Zweidinger, R.B.; Snow, R.

    1997-01-01

    Twenty-three vehicles that were recruited by remote sensing and roadside inspection and maintenance (I/M) checks during the 1994 Clark and Washoe Remote Sensing Study (CAWRSS) were tested on the IM240 cycle using a transportable dynamometer. Six of these vehicles emitted visible smoke. Total gas-phase hydrocarbon (HC), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) exhaust concentrations were continuously measured in the diluted exhaust stream from the constant volume sampler (CVS) during IM240 testing. Two isokinetic PM-10 samples were collected simultaneously using cyclones and filter holders connected to a dilution tube. Teflon filters were collected for total mass and then extracted for chloride, nitrate, and sulfate ions. Quartz filters were analyzed by the thermal/optical reflectance method for organic and elemental carbon. The quartz filters and backup vapor traps were then extracted and analyzed by GC/MS for 28 separate polynuclear aromatic hydrocarbons. Mass emission rates of PM-10 per vehicle ranged from 5.6 to over 1300 mg/mi, with most of the mass attributable to carbon. Except for one vehicle with high sulfate emissions, the ion emissions were relatively low. Total PAH emissions were in the range of 10-200 mg/mi. 10 refs., 8 figs., 5 tabs.

  13. The Source of Airborne Lead: Recycling Pb-Contaminated Soils

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Source of Airborne Lead: Recycling Pb-Contaminated Soils Starting in the 1970s, federal regulatory control and eventual elimination of lead-based "anti-knock" additives in gasoline decreased the level of airborne Pb in the USA by two orders-of-magnitude [1]. Blood lead levels of the USA figure 1 Figure 1. The good, the bad, and the ugly. Ambient airborne particulate matter captured on filters of woven silica fiber (large strips) and TeflonTM (round). Clean fiber filter at bottom

  14. Active airborne contamination control using electrophoresis

    SciTech Connect (OSTI)

    Veatch, B.D.

    1994-06-01

    In spite of our best efforts, radioactive airborne contamination continues to be a formidable problem at many of the Department of Energy (DOE) weapons complex sites. For workers that must enter areas with high levels of airborne contamination, personnel protective equipment (PPE) can become highly restrictive, greatly diminishing productivity. Rather than require even more restrictive PPE for personnel in some situations, the Rocky Flats Plant (RFP) is actively researching and developing methods to aggressively combat airborne contamination hazards using electrophoretic technology. With appropriate equipment, airborne particulates can be effectively removed and collected for disposal in one simple process. The equipment needed to implement electrophoresis is relatively inexpensive, highly reliable, and very compact. Once airborne contamination levels are reduced, less PPE is required and a significant cost savings may be realized through decreased waste and maximized productivity. Preliminary ``cold,`` or non-radioactive, testing results at the RFP have shown the technology to be effective on a reasonable scale, with several potential benefits and an abundance of applications.

  15. Considerations for modeling small-particulate impacts from surface coal-mining operations based on wind-tunnel simulations

    SciTech Connect (OSTI)

    Perry, S.G.; Petersen, W.B.; Thompson, R.S.

    1994-12-31

    The Clean Air Act Amendments of 1990 provide for a reexamination of the current Environmental Protection Agency`s (USEPA) methods for modeling fugitive particulate (PM10) from open-pit, surface coal mines. The Industrial Source Complex Model (ISCST2) is specifically named as the method that needs further study. Title II, Part B, Section 234 of the Amendments states that {open_quotes}...the Administrator shall analyze the accuracy of such model and emission factors and make revisions as may be necessary to eliminate any significant over-predictions of air quality effect of fugitive particulate emissions from such sources.{close_quotes}

  16. Asthmatic responses to airborne acid aerosols

    SciTech Connect (OSTI)

    Ostro, B.D.; Lipsett, M.J.; Wiener, M.B.; Selner, J.C. )

    1991-06-01

    Controlled exposure studies suggest that asthmatics may be more sensitive to the respiratory effects of acidic aerosols than individuals without asthma. This study investigates whether acidic aerosols and other air pollutants are associated with respiratory symptoms in free-living asthmatics. Daily concentrations of hydrogen ion (H+), nitric acid, fine particulates, sulfates and nitrates were obtained during an intensive air monitoring effort in Denver, Colorado, in the winter of 1987-88. A panel of 207 asthmatics recorded respiratory symptoms, frequency of medication use, and related information in daily diaries. We used a multiple regression time-series model to analyze which air pollutants, if any, were associated with health outcomes reported by study participants. Airborne H+ was found to be significantly associated with several indicators of asthma status, including moderate or severe cough and shortness of breath. Cough was also associated with fine particulates, and shortness of breath with sulfates. Incorporating the participants' time spent outside and exercise intensity into the daily measure of exposure strengthened the association between these pollutants and asthmatic symptoms. Nitric acid and nitrates were not significantly associated with any respiratory symptom analyzed. In this population of asthmatics, several outdoor air pollutants, particularly airborne acidity, were associated with daily respiratory symptoms.

  17. Mutagenicity of airborne particles from a nonindustrial town in Italy

    SciTech Connect (OSTI)

    Barale, R.; Zucconi, D.; Giorgelli, F.; Carducci, A.L.; Tonelli, M.; Loprieno, N.

    1989-01-01

    The mutagenic activity of airborne particulate matter collected in Pisa, a small nonindustrial town located in Italy, has been monitored over 1 year using the Ames Salmonella Test. Airborne particulate was collected on fiberglass filters using a Hi-Vol sampler and extracted by sonication and Soxhlet acetone extraction in sequence. TA 98 and TA 100 salmonella strains gave positive results with the great majority of samples. The mutagenicity trend fits with a harmonic regression with a peak during December/January and inversely correlates with the temperature. No correlations were observed with other meteorological conditions such as wind, cloud, rainfall, atmospheric pressure, and humidity. The ratio between mutagenicity/microgram of particulate matter with S9 and that without S9 remains more or less constant regardless of seasonal fluctuations, suggesting that during cold months quantitative increases of mutagens onto particulate matter have probably occurred. The comparison of air mutagenicity in different sites suggests that motor vehicle exhaust fumes are the major source of air pollution. Finally, because of high-traffic volume, air mutagenicity at street level is comparable to that observed in several metropolitan areas all over the world.

  18. Pitch based foam with particulate

    DOE Patents [OSTI]

    Klett, James W. (Knoxville, TN)

    2001-01-01

    A thermally conductive, pitch based foam composite having a particulate content. The particulate alters the mechanical characteristics of the foam without severely degrading the foam thermal conductivity. The composite is formed by mixing the particulate with pitch prior to foaming.

  19. Airborne wireless communication systems, airborne communication methods, and communication methods

    DOE Patents [OSTI]

    Deaton, Juan D. (Menan, ID); Schmitt, Michael J. (Idaho Falls, ID); Jones, Warren F. (Idaho Falls, ID)

    2011-12-13

    An airborne wireless communication system includes circuitry configured to access information describing a configuration of a terrestrial wireless communication base station that has become disabled. The terrestrial base station is configured to implement wireless communication between wireless devices located within a geographical area and a network when the terrestrial base station is not disabled. The circuitry is further configured, based on the information, to configure the airborne station to have the configuration of the terrestrial base station. An airborne communication method includes answering a 911 call from a terrestrial cellular wireless phone using an airborne wireless communication system.

  20. Investigation of Direct Injection Vehicle Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass ...

  1. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Golden, CO)

    1986-01-01

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  2. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    1984-06-27

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  3. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration...

  4. Advanced Particulate Filter Technologies for Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific ...

  5. Design characteristics for facilities which process hazardous particulate

    SciTech Connect (OSTI)

    Abeln, S.P.; Creek, K.; Salisbury, S.

    1998-12-01

    Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

  6. Sampling airborne microorganisms. Summary report, 1 October 1985-30 September 1986

    SciTech Connect (OSTI)

    Chatigny, M.A.

    1986-09-01

    In response to a rapidly increasing awarness of problems in air pollution and air hygiene, considerable emphasis has been placed on sampling of gaseous and particulate contaminants. Although included in the latter category, airborne microbes have not been considered major air pollutants as have chemical aerosols. They have been of some concern in extramural environments (plant diseases) and of considerable interest in intramural (hospital surgical theaters) environments. The intrinsic characteristics of microbes make them difficult to collect and assay quantitatively. The collection instrumentation available tends to be less sophisticated, though no less diverse, than that for other particulates and to require more processing after collection.

  7. Airborne agent concentration analysis

    DOE Patents [OSTI]

    Gelbard, Fred

    2004-02-03

    A method and system for inferring airborne contaminant concentrations in rooms without contaminant sensors, based on data collected by contaminant sensors in other rooms of a building, using known airflow interconnectivity data. The method solves a least squares problem that minimizes the difference between measured and predicted contaminant sensor concentrations with respect to an unknown contaminant release time. Solutions are constrained to providing non-negative initial contaminant concentrations in all rooms. The method can be used to identify a near-optimal distribution of sensors within the building, when then number of available sensors is less than the total number of rooms. This is achieved by having a system-sensor matrix that is non-singular, and by selecting that distribution which yields the lowest condition number of all the distributions considered. The method can predict one or more contaminant initial release points from the collected data.

  8. Airborne Wind Turbine

    SciTech Connect (OSTI)

    2010-09-01

    Broad Funding Opportunity Announcement Project: Makani Power is developing an Airborne Wind Turbine (AWT) that eliminates 90% of the mass of a conventional wind turbine and accesses a stronger, more consistent wind at altitudes of near 1,000 feet. At these altitudes, 85% of the country can offer viable wind resources compared to only 15% accessible with current technology. Additionally, the Makani Power wing can be economically deployed in deep offshore waters, opening up a resource which is 4 times greater than the entire U.S. electrical generation capacity. Makani Power has demonstrated the core technology, including autonomous launch, land, and power generation with an 8 meter wingspan, 20 kW prototype. At commercial scale, Makani Power aims to develop a 600 kW, 28 meter wingspan product capable of delivering energy at an unsubsidized cost competitive with coal, the current benchmark for low-cost power.

  9. Void/particulate detector

    DOE Patents [OSTI]

    Claytor, T.N.; Karplus, H.B.

    1983-09-26

    Apparatus for detecting voids and particulates in a flowing stream of fluid contained in a pipe may comprise: (a) a transducer for transmitting an ultrasonic signal into the stream, coupled to the pipe at a first location; (b) a second transducer for detecting the through-transmission of said signal, coupled to the pipe at a second location; (c) a third transducer for detecting the back-scattering of said signal, coupled to the pipe at a third location, said third location being upstream from said first location; (d) circuit means for normalizing the back-scattered signal from said third transducer to the through-transmitted signal from said second transducer; which normalized signal provides a measure of the voids and particulates flowing past said first location.

  10. Rigid particulate matter sensor

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-02-22

    A sensor to detect particulate matter. The sensor includes a first rigid tube, a second rigid tube, a detection surface electrode, and a bias surface electrode. The second rigid tube is mounted substantially parallel to the first rigid tube. The detection surface electrode is disposed on an outer surface of the first rigid tube. The detection surface electrode is disposed to face the second rigid tube. The bias surface electrode is disposed on an outer surface of the second rigid tube. The bias surface electrode is disposed to face the detection surface electrode on the first rigid tube. An air gap exists between the detection surface electrode and the bias surface electrode to allow particulate matter within an exhaust stream to flow between the detection and bias surface electrodes.

  11. Regenerable particulate filter

    DOE Patents [OSTI]

    Stuecker, John N. (Albuquerque, NM); Cesarano, III, Joseph (Albuquerque, NM); Miller, James E. (Albuquerque, NM)

    2009-05-05

    A method of making a three-dimensional lattice structure, such as a filter used to remove particulates from a gas stream, where the physical lattice structure is designed utilizing software simulation from pre-defined mass transfer and flow characteristics and the designed lattice structure is fabricated using a free-form fabrication manufacturing technique, where the periodic lattice structure is comprised of individual geometric elements.

  12. Particulate and gaseous organic receptor modeling for the southern California Air Quality Study. Final report

    SciTech Connect (OSTI)

    Watson, J.G.; Chow, J.G.; Lu, Z.; Gertler, A.W.

    1993-11-01

    The Chemical Mass Balance (CMB) receptor model was applied to the chemically-speciated diurnal particulate matter samples and volatile organic compound (VOC) acquired during the summer and fall campaigns of the Southern California Air Quality Study (SCAQS). Source profiles applicable to the Los Angeles area were used to apportion PM[sub (2.5)] and PM[sub (10)] to primary paved road dust, primary construction dust, primary motor vehicle exhaust, primary marine aerosol, secondary ammonium nitrate, and secondary ammonium sulfate. Nonmethane hydrocarbon was apportioned to motor vehicle exhaust, liquid fuel, gasoline vapor, gas leaks, architectural and industrial coatings, and biogenic emissions. Suspended dust was the major contributor to PM(10) during the summer, while secondary ammonium nitrate and primary motor vehicle exhaust contributions were high in the fall. Motor vehicle exhaust was the major contributor to nonmethane hydrocarbons, ranging from 30% to 70% of the total.

  13. Introduction to Airborne Tritium Tritides

    Office of Environmental Management (EM)

    ... Microscopic Metal Dust Tritium Tritides in airborne dust particles can be inhaled. 10CFR835 lists STCs (Special Tritium Compounds) with DAC factors that the are 2 to 5 times more ...

  14. Apparatus for particulate matter analysis

    DOE Patents [OSTI]

    Gundel, Lara A.; Apte, Michael G.; Hansen, Anthony D.; Black, Douglas R.

    2007-01-30

    The apparatus described herein is a miniaturized system for particle exposure assessment (MSPEA) for the quantitative measurement and qualitative identification of particulate content in gases. The present invention utilizes a quartz crystal microbalance (QCM) or other mass-sensitive temperature compensated acoustic wave resonator for mass measurement. Detectors and probes and light sources are used in combination for the qualitative determination of particulate matter.

  15. ccpi1-airborne | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Demonstration of the Airborne Process [pdf-580kb] (withdrawn) Mustang Clean Energy, LLC, A Subsidiary of the Peabody Energy, St. Louis, Missouri Project Fact Sheet Commercial Demonstration of the Airborne Process (Withdrawn) [PDF-675KB] (Oct

  16. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pathfinder Airborne ISR Systems Areas of Expertise Capabilities Capabilities Sandia's Intelligence, Surveillance and Reconnaissance (ISR) breadth of capabilities include everything...

  17. Introduction Airborne Tritium Tritides | Department of Energy

    Office of Environmental Management (EM)

    Introduction Airborne Tritium Tritides Introduction Airborne Tritium Tritides Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Introduction Airborne Tritium Tritides More Documents & Publications DOE-HDBK-1129-2008 DOE-HDBK-1129-2007 DOE-HDBK-1129-99

  18. ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Ye Zhuang; Stanley J. Miller; Michelle R. Olderbak; Rich Gebert

    2001-12-01

    A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the U.S. Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in an entirely novel manner. The AHPC concept combines fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two methods, both in the particulate collection step and in transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and solves the problem of reentrainment and re-collection of dust in conventional baghouses. Phase I of the development effort consisted of design, construction, and testing of a 5.7-m{sup 3}/min (200-acfm) working AHPC model. Results from both 8-hr parametric tests and 100-hr proof-of-concept tests with two different coals demonstrated excellent operability and greater than 99.99% fine-particle collection efficiency. Since all of the developmental goals of Phase I were met, the approach was scaled up in Phase II to a size of 255 m{sup 3}/min (9000 acfm) (equivalent in size to 2.5 MW) and was installed on a slipstream at the Big Stone Power Plant. For Phase II, the AHPC at Big Stone Power Plant was operated continuously from late July 1999 until mid-December 1999. The Phase II results were highly successful in that ultrahigh particle collection efficiency was achieved, pressure drop was well controlled, and system operability was excellent. For Phase III, the AHPC was modified into a more compact configuration, and components were installed that were closer to what would be used in a full-scale commercial design. The modified AHPC was operated from April to July 2000. While operational results were acceptable during this time, inspection of bags in the summer of 2000 revealed some membrane damage to the fabric that appeared to be caused by electrical effects. Subsequently, extensive theoretical, bench-scale, and pilot-scale investigations were completed to find an approach to prevent bag damage without compromising AHPC performance. Results showed that the best bag protection and AHPC performance were achieved by using a perforated plate installed between the discharge electrodes and bags. This perforated-plate design was then installed in the 2.5-MW AHPC at Big Stone Power Plant in Big Stone City, South Dakota, and the AHPC was operated from March to June 2001. Results showed that the perforated-plate design solved the bag damage problem and offered even better AHPC performance than the previous design. All of the AHPC performance goals were met, including ultrahigh collection efficiency, high air-to-cloth ratio, reasonable pressure drop, and long bag-cleaning interval.

  19. Airborne Imagery Collections Barrow 2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cherry, Jessica; Crowder, Kerri

    2015-07-20

    The data here are orthomosaics, digital surface models (DSMs), and individual frames captured during low altitude airborne flights in 2013 at the Barrow Environmental Observatory. The orthomosaics, thermal IR mosaics, and DSMs were generated from the individual frames using Structure from Motion techniques.

  20. Electrically heated particulate filter restart strategy

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-07-12

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a propagation module that estimates a propagation status of combustion of particulate matter in the particulate filter. A regeneration module controls current to the particulate filter to re-initiate regeneration based on the propagation status.

  1. Electrical diesel particulate filter (DPF) regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-12-31

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  2. Introduction to Airborne Tritium Tritides

    Office of Environmental Management (EM)

    OVER 65 YEARS OF RADIATION DETECTION & MEASURMENT SOLUTIONS US NUCLEAR CORP INTRODUCTION AIRBORNE TRITIUM TRITIDES HYDRIDES - An Anion of Hydrogen Compounds containing hydrogen bonded to metals or metalloid may be referred to as hydrides A hydride is a compound formed by hydrogen and another, usually more electropositive, element or group. Almost all of the elements form binary compounds with hydrogen (exceptions being He, Ne, Ar, Kr, Pm, Os, Ir, Rn, Fr, and Ra). There are three main types

  3. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  4. ccpi1-airborne | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Demonstration of the Airborne Process pdf-580kb (withdrawn) Mustang Clean Energy, LLC, A Subsidiary of the Peabody Energy, St. Louis, Missouri Project Fact Sheet...

  5. Ceramic Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Particulate Filters Ceramic Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_yonushonis.pdf More Documents & Publications Durability of Diesel Engine Particulate Filters Durability of Diesel Engine Particulate Filters Durability of Diesel Engine

  6. Category:Airborne Gravity Survey | Open Energy Information

    Open Energy Info (EERE)

    Category Edit History Category:Airborne Gravity Survey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Airborne Gravity Survey...

  7. The Effect of Airborne Contaminants on Fuel Cell Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Effect of Airborne Contaminants on Fuel Cell Performance & Durability The Effect of Airborne Contaminants on Fuel Cell Performance & Durability Presented at the Department of...

  8. ARM - Field Campaign - ARM Airborne Carbon Measurements (ARM...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Airborne Carbon Measurements (ARM-ACME V) Campaign Links Science Plan Images ARM Data Discovery Browse Data Related Campaigns ARM Airborne Carbon Measurements (ARM-ACME)...

  9. ccpi-airborne_r2 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 AIRBORNE PROCESS(tm) COMMERCIAL SCALE DEMONSTRATION PROGRAM MUSTANG CLEAN ENERGY, LLC, a subsidiary of PEABODY ENERGY ST. LOUIS, MISSOURI PROJECT FACT SHEET Airborne Process(tm)...

  10. Accident Generated Particulate Materials and Their Characteristics -- A Review of Background Information

    SciTech Connect (OSTI)

    Sutter, S. L.

    1982-05-01

    Safety assessments and environmental impact statements for nuclear fuel cycle facilities require an estimate of the amount of radioactive particulate material initially airborne (source term) during accidents. Pacific Northwest Laboratory (PNL) has surveyed the literature, gathering information on the amount and size of these particles that has been developed from limited experimental work, measurements made from operational accidents, and known aerosol behavior. Information useful for calculating both liquid and powder source terms is compiled in this report. Potential aerosol generating events discussed are spills, resuspension, aerodynamic entrainment, explosions and pressurized releases, comminution, and airborne chemical reactions. A discussion of liquid behavior in sprays, sparging, evaporation, and condensation as applied to accident situations is also included.

  11. Geophex Airborne Unmanned Survey System

    SciTech Connect (OSTI)

    Won, I.L.; Keiswetter, D.

    1995-12-31

    Ground-based surveys place personnel at risk due to the proximity of buried unexploded ordnance (UXO) items or by exposure to radioactive materials and hazardous chemicals. The purpose of this effort is to design, construct, and evaluate a portable, remotely-piloted, airborne, geophysical survey system. This non-intrusive system will provide stand-off capability to conduct surveys and detect buried objects, structures, and conditions of interest at hazardous locations. During a survey, the operators remain remote from, but within visual distance of, the site. The sensor system never contacts the Earth, but can be positioned near the ground so that weak geophysical anomalies can be detected. The Geophex Airborne Unmanned Survey System (GAUSS) is designed to detect and locate small-scale anomalies at hazardous sites using magnetic and electromagnetic survey techniques. The system consists of a remotely-piloted, radio-controlled, model helicopter (RCH) with flight computer, light-weight geophysical sensors, an electronic positioning system, a data telemetry system, and a computer base-station. The report describes GAUSS and its test results.

  12. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for LIght-Duty Diesel Vehicles | Department of Energy Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles PDF icon 2005_deer_anderson.pdf More Documents & Publications Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency

  13. Fogging formulations for fixation of particulate contamination in ductwork and enclosures

    DOE Patents [OSTI]

    Maresca, Jr., Joseph W.; Kostelnik, Lori M.; Kriskivich, James R.; Demmer, Rick L.; Tripp, Julia L.

    2015-09-08

    A method and an apparatus using aqueous fixatives for fogging of ventilation ductwork, enclosures, or buildings containing dust, lint, and particulates that may be contaminated by radionuclides and other dangerous or unsafe particulate contaminants, which method and apparatus are capable of (1) obtaining full coverage within the ductwork and (2) penetrating and fixing the lint, dust and large particles present in the ductwork so that no airborne particles are released during or after the application of the fixative. New aqueous fogging solutions outperform conventional glycerin-based solutions. These aqueous solutions will fog using conventional methods of application and contain a surfactant to aid wetting and penetration of the lint and dust, a binder to stabilize loose or respirable particles, and an agent to aid in fogging and enhance adhesiveness. The solutions are safe and easy to use.

  14. Particulate Generation in Tritium Systems

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Paul Cloessner, PhD Laboratory Fellow Tritium Focus Group February 22, 2014 Outline * Description of Events * Analysis of Material * Sources of material contamination * System Restoration/Modifications * Contaminant Minimization and Control * Lessons Learned 2 An Unpleasant Surprise * Let down filter on compressor became plugged after 10 years of operation. * Tritium processing interrupted when other filters (flow orifices) became plugged approximately

  15. PIA - Radioactive Airborne Contamination Survey | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Radioactive Airborne Contamination Survey PIA - Radioactive Airborne Contamination Survey PIA - Radioactive Airborne Contamination Survey PDF icon PIA - Radioactive Airborne Contamination Survey More Documents & Publications Integrated Safety Management Workshop Registration, PIA, Idaho National Laboratory PIA - Bonneville Power Adminstration Ethics Helpline PIA - Advanced Test Reactor National Scientific User Facility Users Week 2009

  16. Principles for Sampling Airborne Radioactivity from Stacks

    SciTech Connect (OSTI)

    Glissmeyer, John A.

    2010-10-18

    This book chapter describes the special processes involved in sampling the airborne effluents from nuclear faciities. The title of the book is Radioactive Air Sampling Methods. The abstract for this chapter was cleared as PNNL-SA-45941.

  17. Diesel particulate filter with zoned resistive heater

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-03-08

    A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

  18. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-03-30

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  19. Trends in Particulate Nanostructure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Nanostructure Trends in Particulate Nanostructure This work attempts to explain the differences in the physical characteristics (nanostructure) of the soot across platforms, heavy-duty and light-duty, and biodiesel blend level. PDF icon p-10_strzelec.pdf More Documents & Publications Investigation of NO2 Oxidation Kinetics and Burning Mode for Medium Duty Diesel Particulate: Contrasting O2 and NO2 Oxidation Load Expansion with Diesel/Gasoline RCCI for Improved Engine Efficiency

  20. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Durability of Diesel Engine Particulate Filters High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the...

  1. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon pm041lance2011p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel...

  2. Electrically heated particulate filter embedded heater design

    DOE Patents [OSTI]

    Gonze, Eugene V.; Chapman, Mark R.

    2014-07-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  3. Electrically heated particulate filter using catalyst striping

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

    2013-07-16

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

  4. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  5. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  6. Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Dispersion in a Phospholipid Lung Surfactant In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials

  7. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  8. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  9. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  10. Pleated Ceramic Fiber Diesel Particulate Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pleated Ceramic Fiber Diesel Particulate Filter Pleated Ceramic Fiber Diesel Particulate Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_nixdorf.pdf More Documents & Publications Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Expanded Capacity Microwave-Cleaned Diesel Particulate Filter

  11. Apparatus and methods for monitoring the concentrations of hazardous airborne substances, especially lead

    DOE Patents [OSTI]

    Zaromb, Solomon

    2004-07-13

    Air is sampled at a rate in excess of 100 L/min, preferably at 200-300 L/min, so as to collect therefrom a substantial fraction, i.e., at least 20%, preferably 60-100%, of airborne particulates. A substance of interest (analyte), such as lead, is rapidly solubilized from the the collected particulates into a sample of liquid extractant, and the concentration of the analyte in the extractant sample is determined. The high-rate air sampling and particulate collection may be effected with a high-throughput filter cartridge or with a recently developed portable high-throughput liquid-absorption air sampler. Rapid solubilization of lead is achieved by a liquid extractant comprising 0.1-1 M of acetic acid or acetate, preferably at a pH of 5 or less and preferably with inclusion of 1-10% of hydrogen peroxide. Rapid determination of the lead content in the liquid extractant may be effected with a colorimetric or an electroanalytical analyzer.

  12. ARM - Field Campaign - ARM Airborne Carbon Measurements (ARM-ACME)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsARM Airborne Carbon Measurements (ARM-ACME) Campaign Links Final Campaign Report ARM Data Discovery Browse Data Related Campaigns ARM Airborne Carbon Measurements (ARM-ACME VI) 2015.10.01, Biraud, AAF ARM Airborne Carbon Measurements (ARM-ACME V) 2015.06.01, Biraud, AAF ARM Airborne Carbon Measurements IV (ARM-ACME IV) 2013.10.01, Biraud, AAF ARM Airborne Carbon Measurements (ARM-ACME III) 2012.10.01, Biraud, AAF ARM Airborne Carbon Measurements (ARM-ACME 2.5) 2012.01.01, Biraud, AAF

  13. Advanced particulate matter control apparatus and methods

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND); Zhuang, Ye (Grand Forks, ND); Almlie, Jay C. (East Grand Forks, MN)

    2012-01-10

    Apparatus and methods for collection and removal of particulate matter, including fine particulate matter, from a gas stream, comprising a unique combination of high collection efficiency and ultralow pressure drop across the filter. The apparatus and method utilize simultaneous electrostatic precipitation and membrane filtration of a particular pore size, wherein electrostatic collection and filtration occur on the same surface.

  14. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  15. Electrically heated particulate filter propagation support methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-06-07

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate combustion of particulate matter in the particulate filter. A propagation module estimates a propagation status of the combustion of the particulate matter based on a combustion temperature. A temperature adjustment module controls the combustion temperature by selectively increasing a temperature of exhaust that passes through the particulate filter.

  16. Radiant zone heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-12-27

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  17. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) PDF icon ace22lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration...

  18. Mesoscale Simulations of Particulate Flows with Parallel Distributed...

    Office of Scientific and Technical Information (OSTI)

    Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. ...

  19. A New CFD Model for understanding and Managing Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon...

  20. New Cordierite Diesel Particulate Filters for Catalyzed and Non...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER...

  1. Durability of Diesel Particulate Filters - Bench Studies on Cordierite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August...

  2. Emissions and Durability of Underground Mining Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Ceramic Particulate Filters Development of an Accelerated Ash-Loading Protocol ...

  3. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine...

  4. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis ...

  5. 2007 Diesel Particulate Measurement Research (E-66 Project) ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Measurement Research (E-66 Project) 2007 Diesel Particulate Measurement Research (E-66 Project) 2004 Diesel Engine Emissions Reduction (DEER) Conference:...

  6. Reduction of Transient Particulate Matter Spikes with Decision...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric ...

  7. Predicting Thermal Stress in Diesel Particulate Filters | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Stress in Diesel Particulate Filters Predicting Thermal Stress in Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Corning...

  8. Failure Stress and Apparent Elastic Modulus of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three...

  9. Evaluation of a Partial Flow Dilution System for Transient Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially...

  10. Characterization of Pre-Commercial Gasoline Engine Particulates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods...

  11. Local Soot Loading Distribution in Cordierite Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by...

  12. ccpi-airborne_r2 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 AIRBORNE PROCESS(tm) COMMERCIAL SCALE DEMONSTRATION PROGRAM MUSTANG CLEAN ENERGY, LLC, a subsidiary of PEABODY ENERGY ST. LOUIS, MISSOURI PROJECT FACT SHEET Airborne Process(tm) Commercial Scale Demonstration Program (Withdrawn) [PDF-675KB] (Oct 2008

  13. ARM - Field Campaign - ARM Airborne Carbon Measurements IV (ARM...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    first for airborne measurements. We continued our long-term airborne study of atmospheric composition and carbon cycling in the Southern Great Plains by flying total of 600 flight...

  14. Sandia Multispectral Airborne Lidar for UAV Deployment

    SciTech Connect (OSTI)

    Daniels, J.W.; Hargis,Jr. P.J.; Henson, T.D.; Jordan, J.D.; Lang, A.R.; Schmitt, R.L.

    1998-10-23

    Sandia National Laboratories has initiated the development of an airborne system for W laser remote sensing measurements. System applications include the detection of effluents associated with the proliferation of weapons of mass destruction and the detection of biological weapon aerosols. This paper discusses the status of the conceptual design development and plans for both the airborne payload (pointing and tracking, laser transmitter, and telescope receiver) and the Altus unmanned aerospace vehicle platform. Hardware design constraints necessary to maintain system weight, power, and volume limitations of the flight platform are identified.

  15. Micro-Electron Spin Resonance for Airborne Soot Measurement

    Broader source: Energy.gov [DOE]

    A real-time method for airborne soot concentration measurement using a miniaturized electron spin resonance sensor is presented.

  16. Electrically heated particulate filter enhanced ignition strategy

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  17. Neutron Imaging of Diesel Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Filters Neutron Imaging of Diesel Particulate Filters Neutron computed tomography shows soot and ash loading in a cordierite diesel particulate filter PDF icon deer09_bilheux.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters

  18. Effects of Advanced Combustion Technologies on Particulate Matter Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characteristics | Department of Energy Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Findings of important implications for aftertreatment devices such as EGR coolers and diesel particulate filters, of physico-chemical changes observed in particulate matter during advanced combustion. PDF icon deer08_storey.pdf More Documents & Publications Measurement and

  19. Requirements from Particulate Filter Technology for Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions ...

  20. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP ...

  1. Requirements from Particulate Filter Technology for Commercial Vehicles:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sintered Metal Particulate Filter Opens a New Dimension of Performance | Department of Energy from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance Requirements from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_biddinger.pdf More

  2. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Expanded Capacity Microwave-Cleaned Diesel Particulate Filter Expanded Capacity Microwave-Cleaned Diesel Particulate Filter 2002 DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon 2002_deer_nixdorf.pdf More Documents & Publications Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape

  3. Advanced Hybrid Particulate Collector Project Management Plan

    SciTech Connect (OSTI)

    Miller, S.J.

    1995-11-01

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  4. Analyzing Options for Airborne Emergency Wireless Communications

    SciTech Connect (OSTI)

    Michael Schmitt; Juan Deaton; Curt Papke; Shane Cherry

    2008-03-01

    In the event of large-scale natural or manmade catastrophic events, access to reliable and enduring commercial communication systems is critical. Hurricane Katrina provided a recent example of the need to ensure communications during a national emergency. To ensure that communication demands are met during these critical times, Idaho National Laboratory (INL) under the guidance of United States Strategic Command has studied infrastructure issues, concerns, and vulnerabilities associated with an airborne wireless communications capability. Such a capability could provide emergency wireless communications until public/commercial nodes can be systematically restored. This report focuses on the airborne cellular restoration concept; analyzing basic infrastructure requirements; identifying related infrastructure issues, concerns, and vulnerabilities and offers recommended solutions.

  5. Airborne Tactical Free-Electron Laser

    SciTech Connect (OSTI)

    Roy Whitney; George Neil

    2007-02-01

    The goal of 100 kilowatts (kW) of directed energy from an airborne tactical platform has proved challenging due to the size and weight of most of the options that have been considered. However, recent advances in Free-Electron Lasers appear to offer a solution along with significant tactical advantages: a nearly unlimited magazine, time structures for periods from milliseconds to hours, radar like functionality, and the choice of the wavelength of light that best meets mission requirements. For an Airborne Tactical Free-Electron Laser (ATFEL) on a platforms such as a Lockheed C-130J-30 and airships, the two most challenging requirements, weight and size, can be met by generating the light at a higher harmonic, aggressively managing magnet weights, managing cryogenic heat loads using recent SRF R&D results, and using FEL super compact design concepts that greatly reduce the number of components. The initial R&D roadmap for achieving an ATFEL is provided in this paper. Performing this R&D is expected to further reduce the weight, size and power requirements for the FELs the Navy is currently developing for shipboard applications, as well as providing performance enhancements for the strategic airborne MW class FELs. The 100 kW ATFEL with its tactical advantages may prove sufficiently attractive for early advancement in the queue of deployed FELs.

  6. Method for dispersing catalyst onto particulate material

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  7. Sandia National Laboratories: Pathfinder Airborne ISR and Synthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aperture Radar (SAR) Systems Pathfinder Airborne ISR Systems What is SAR? Areas of Expertise Images VideoSAR Publications Facebook Twitter YouTube Flickr RSS Pathfinder Airborne ISR Systems Pathfinder Airborne ISR and Synthetic Aperture Radar (SAR) Systems Tactical Eyes for the Warfighter Tactical Eyes for the Warfighter Actionable Intelligence for the Decision Maker Actionable Intelligence for the Decision Maker All Weather, Persistent, Optical Like All Weather, Persistent, Optical Like

  8. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  9. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  10. Particulate matter sensor with a heater

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-08-16

    An apparatus to detect particulate matter. The apparatus includes a sensor electrode, a shroud, and a heater. The electrode measures a chemical composition within an exhaust stream. The shroud surrounds at least a portion of the sensor electrode, exclusive of a distal end of the sensor electrode exposed to the exhaust stream. The shroud defines an air gap between the sensor electrode and the shroud and an opening toward the distal end of the sensor electrode. The heater is mounted relative to the sensor electrode. The heater burns off particulate matter in the air gap between the sensor electrode and the shroud.

  11. Airborne Electromagnetic Survey At Chena Geothermal Area (Kolker...

    Open Energy Info (EERE)

    Phase I) Notes Fugro, Inc. performed an airborne geophysical survey using the DIGHEM (Digital Helicopter ElectroMagnetics) aircraft over a 937 km2 survey grid. An coplanar...

  12. Airborne Electromagnetic Survey At Raft River Geothermal Area...

    Open Energy Info (EERE)

    Raft River Geothermal Area (1979) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Airborne Electromagnetic Survey At Raft River Geothermal Area...

  13. ARM Airborne Carbon Measurements VI (ACME VI) Science Plan (Program...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM Airborne Carbon Measurements VI (ACME VI) Science Plan From October 1 through September 30, 2016, the Atmospheric RadiationMeasurement (ARM) Aerial Facility will deploy ...

  14. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions ...

  15. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon ... Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile ...

  16. Investigation of Direct Injection Vehicle Particulate Matter Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass analysis of a gasoline direct injection engine in a test cell with a chassis dynamometer. PDF icon p-10_gibbs.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Reducing the

  17. Advanced Particulate Filter Technologies for Direct Injection Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Applications | Department of Energy Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific designs and material properties have to be developed for gasoline particulate filters based on the different engine and exhaust gas characteristic of gasoline engines compared to diesel engines, e.g., generally lower levels of engine-out particulate emissions or higher

  18. Characterization of Pre-Commercial Gasoline Engine Particulates Through

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Aerosol Methods | Department of Energy Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Advanced aerosol analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends. PDF icon deer12_zelenyuk.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  19. Development of Advanced Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters Development of Advanced Particulate Filters 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace024_lee_2012_o.pdf More Documents & Publications Particulate Emissions Control by Advanced Filtration Systems or GDI Engines Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF

  20. Update on 2007 Diesel Particulate Measurement Research | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2007 Diesel Particulate Measurement Research Update on 2007 Diesel Particulate Measurement Research 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_shimpi.pdf More Documents & Publications Real-Time Measurement of Diesel Trap Efficiency Mass Correlation of Engine Emissions with Spectral Instruments Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles

  1. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Ultra-Lite Diesel Particulate Filter Cartridge for Reduced

  2. Clean Coal Technology Demonstration Program | Department of Energy

    Energy Savers [EERE]

    Clean Coal Technology Demonstration Program Clean Coal Technology Demonstration Program The Office of Fossil Energy's Clean Coal Technology Demonstration Program (1986-1993) laid the foundation for effective technologies now in use that have helped significantly lower emissions of sulfur dioxide (SO2), nitrogen oxides (NOx) and airborne particulates (PM10). PDF icon Clean Coal Technology Demonstration Program More Documents & Publications Return on Investment Sustainable Coal Use Clean Coal

  3. The Office of Fossil Energy's (FE) Clean

    Energy Savers [EERE]

    Office of Fossil Energy's (FE) Clean Coal Technology Demonstration Program (1986-1993) laid the foundation for effective technologies now in use that have helped significantly lower emissions of sulfur dioxide (SO 2 ), nitrogen oxides (NO x ) and airborne particulates (PM 10 ). The program forged cost-sharing partnerships between the U.S. Department of Energy, industry, universities and technology suppliers and users. The U.S. General Accounting Office said the program demonstrated "how the

  4. Particulate Generation in a Tritium System | Department of Energy

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Particulate Generation in a Tritium System Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Particulate Generation in a Tritium System More Documents & Publications Fuel Injector Holes Fuel Injector Holes Fuel injector Holes (Fabrication of Micro-Orifices for Fuel Injectors)

  5. Electrically heated particulate filter preparation methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a fuel control module that controls injection of fuel into exhaust that passes through the particulate filter. A regeneration module controls current to the particulate filter to initiate regeneration after the fuel has been injected into the exhaust.

  6. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANL/Corning/Caterpillar CRADA) | Department of Energy (ANL/Corning/Caterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) PDF icon ace_22_lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems

  7. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024_lee_2011_o.pdf More Documents & Publications Development of Advanced Particulate Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA)

  8. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm041_lance_2012_o.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration Durability of Diesel Engine Particulate Filters (Agreement ID:10461)

  9. Apparatus for measuring surface particulate contamination

    DOE Patents [OSTI]

    Woodmansee, Donald E. (Simpsonville, SC)

    2002-01-01

    An apparatus for measuring surface particulate contamination includes a tool for collecting a contamination sample from a target surface, a mask having an opening of known area formed therein for defining the target surface, and a flexible connector connecting the tool to the mask. The tool includes a body portion having a large diameter section defining a surface and a small diameter section extending from the large diameter section. A particulate collector is removably mounted on the surface of the large diameter section for collecting the contaminants. The tool further includes a spindle extending from the small diameter section and a spool slidingly mounted on the spindle. A spring is disposed between the small diameter section and the spool for biasing the spool away from the small diameter section. An indicator is provided on the spindle so as to be revealed when the spool is pressed downward to compress the spring.

  10. Face crack reduction strategy for particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion. A control module initiates combustion of PM in the PM filter using a heater and selectively adjusts oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter. A method comprises providing a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion; initiating combustion of PM in the PM filter using a heater; selectively adjusting oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter.

  11. Generator powered electrically heated diesel particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2014-03-18

    A control circuit for a vehicle powertrain includes a switch that selectivity interrupts current flow between a first terminal and a second terminal. A first power source provides power to the first terminal and a second power source provides power to the second terminal and to a heater of a heated diesel particulate filter (DPF). The switch is opened during a DPF regeneration cycle to prevent the first power source from being loaded by the heater while the heater is energized.

  12. CALIOPE and TAISIR airborne experiment platform

    SciTech Connect (OSTI)

    Chocol, C.J.

    1994-07-01

    Between 1950 and 1970, scientific ballooning achieved many new objectives and made a substantial contribution to understanding near-earth and space environments. In 1986, the Lawrence Livermore National Laboratory (LLNL) began development of ballooning technology capable of addressing issues associated with precision tracking of ballistic missiles. In 1993, the Radar Ocean Imaging Project identified the need for a low altitude (1 km) airborne platform for its Radar system. These two technologies and experience base have been merged with the acquisition of government surplus Aerostats by Lawrence Livermore National Laboratory. The CALIOPE and TAISIR Programs can benefit directly from this technology by using the Aerostat as an experiment platform for measurements of the spill facility at NTS.

  13. Development of a Low-Cost Particulate Matter Monitor

    SciTech Connect (OSTI)

    White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

    2008-08-01

    We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic collection efficiency using an increased temperature gradient, and shielding the resonator electronics from deposition of ultrafine particles.

  14. Assessment of Contribution of Contemporary Carbon Sources to Size-Fractionated Particulate Matter and Time-Resolved Bulk Particulate Matter Using the Measurement of Radiocarbon

    SciTech Connect (OSTI)

    Hwang, H M; Young, T M; Buchholz, B A

    2009-04-16

    This study was motivated by a desire to improve understanding of the sources contributing to the carbon that is an important component of airborne particulate matter (PM). The ultimate goal of this project was to lay a ground work for future tools that might be easily implemented with archived or routinely collected samples. A key feature of this study was application of radiocarbon measurement that can be interpreted to indicate the relative contributions from fossil and non-fossil carbon sources of atmospheric PM. Size-resolved PM and time-resolved PM{sub 10} collected from a site in Sacramento, CA in November 2007 (Phase I) and March 2008 (Phase II) were analyzed for radiocarbon and source markers such as levoglucosan, cholesterol, and elemental carbon. Radiocarbon data indicates that the contributions of non-fossil carbon sources were much greater than that from fossil carbon sources in all samples. Radiocarbon and source marker measurements confirm that a greater contribution of non-fossil carbon sources in Phase I samples was highly likely due to residential wood combustion. The present study proves that measurement of radiocarbon and source markers can be readily applied to archived or routinely collected samples for better characterization of PM sources. More accurate source apportionment will support ARB in developing more efficient control strategies.

  15. Estimates of Particulate Mass in Multi Canister Overpacks (MCO)

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    2000-02-16

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulates that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  16. Estimates of particulate mass in multi-canister overpacks

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    1999-02-25

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulate that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  17. ARM - Field Campaign - ARM Airborne Carbon Measurements (ARM...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 submitted) in the past four years. We will continue our airborne study of atmospheric composition and carbon cycling in the SGP. The goals of this measurement program are to...

  18. ARM - Field Campaign - NASA Coordinated Airborne CO2 Lidar Flight...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsNASA Coordinated Airborne CO2 Lidar Flight Test Campaign ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at...

  19. ARM - Field Campaign - Two-Column Aerosol Project (TCAP): Airborne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Two-Column Aerosol Project (TCAP): Airborne HSRL and RSP Measurements 2012.07.01 -...

  20. Shielded regeneration heating element for a particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  1. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  2. Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamic Neutron Radiography | Department of Energy Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Quantitative analysis of the soot loading and soot distribution for Cordierite type DPFs are studied under controlled conditions. PDF icon deer10_harvel.pdf More Documents & Publications Neutron Imaging of Diesel Particulate Filters

  3. Final Report: Particulate Emissions Testing, Unit 1, Potomac River

    Energy Savers [EERE]

    Generating Station, Alexandria, Virginia | Department of Energy Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Docket No. EO-05-01: TRC Environmental Corporation (TRC) of Lowell, Massachusetts was retained by Mirant Potomac River, LLC (Mirant) to provide sampling and analytical support in completing a Particulate Emission

  4. High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) |

    Energy Savers [EERE]

    Department of Energy High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) DOE-STD-3020-2015 Specification for HEPA Filters Used by DOE Contractors The purpose of this standard is to establish specifications and quality assurance (QA) requirements for the procurement, packaging, shipping and storage of high efficiency particulate air (HEPA) filters. DOE-STD-3025-2007 Quality Assurance Inspection and Testing of HEPA

  5. Non-Destructive Neutron Imaging to Analyze Particulate Filters | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Neutron Imaging to Analyze Particulate Filters Non-Destructive Neutron Imaging to Analyze Particulate Filters Non-destructive, non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon p-27_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Vehicle Technologies Office Merit Review 2014:

  6. Reliability and Design Strength Limit Calculations on Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy and Design Strength Limit Calculations on Diesel Particulate Filters Reliability and Design Strength Limit Calculations on Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Confererence Presentation: Corning PDF icon 2004_deer_webb.pdf More Documents & Publications Predicting Thermal Stress in Diesel Particulate Filters Environmental Effects on Power Electronic Devices Effect of Machining Procedures on the Strength of Ceramics for

  7. Requirements-Driven Diesel Catalyzed Particulate Trap Design and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_harris.pdf More Documents & Publications Diesel Emission Control Technology Review Investigation of Aging Mechanisms in Lean NOx Traps Diesel Particulate Filters: Market Introducution

  8. Characterization of Particulate Emissions from GDI Engine Combustion with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alcohol-blended Fuels | Department of Energy Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures PDF icon p-19_seong.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Fuel and Lubricant

  9. Detailed Assessment of Particulate Characteristics from Low-Temperature

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Engines | Department of Energy Assessment of Particulate Characteristics from Low-Temperature Combustion Engines Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace083_lee_2012_p.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol

  10. Development and Applications of Catalyzed Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Applications of Catalyzed Diesel Particulate Filter Development and Applications of Catalyzed Diesel Particulate Filter 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sud Chemie Prototech Inc. PDF icon 2004_deer_huang.pdf More Documents & Publications CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ Optical Analysis of Ash Formation and

  11. Development of Acicular Mullite Materials for Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Acicular Mullite Materials for Diesel Particulate Filters Application Development of Acicular Mullite Materials for Diesel Particulate Filters Application 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_pyzik.pdf More Documents & Publications Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFƒSCR On-Filter (SCRF) fundamental Modeling and

  12. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024_lee_2010_o.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) Development of Advanced Particulate Filters

  13. Development of an Active Regeneration Diesel Particulate Filter System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Regeneration Diesel Particulate Filter System Development of an Active Regeneration Diesel Particulate Filter System PDF icon 2004_deer_anderson.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration

  14. Diesel Particulate Filter: A Success for Faurecia Exhaust Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Filter: A Success for Faurecia Exhaust Systems Diesel Particulate Filter: A Success for Faurecia Exhaust Systems 2003 DEER Conference Presentation: Faurecia Exhaust Systems PDF icon 2003_deer_parmann.pdf More Documents & Publications Combination of Diesel fuel system architectures and Ceria-based fuel-borne catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications Improvement and Simplification of Diesel Particulate

  15. Durability of Diesel Particulate Filters - Bench Studies on Cordierite

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_dacosta.pdf More Documents & Publications Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Development of

  16. Emissions and Durability of Underground Mining Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Durability of Underground Mining Diesel Particulate Filter Applications Emissions and Durability of Underground Mining Diesel Particulate Filter Applications Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_rubeli.pdf More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine

  17. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  18. Blowers for Air Assisted Diesel Particulate Filter Regeneration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Blowers for Air Assisted Diesel Particulate Filter Regeneration Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM and manufacturing cost studies are well advanced. PDF icon p-14_milburn.pdf More Documents & Publications Development of a Non Air-assisted Thermal Regenerator Development of an Active Regeneration Diesel Particulate Filter

  19. CARB Verification of Catalyzed Diesel Particulate Filters for Emergency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Sets | Department of Energy CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_huang.pdf More Documents & Publications Development and Applications of Catalyzed Diesel Particulate Filter California ARB Verification Testing of the CBSTM Soot Filter for

  20. Substrate Studies of an Electrically-Assisted Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on both electrically assisted and conventional fuel-only DPF regeneration cycles PDF icon deer12_parks.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration

  1. Diesel particulate filter regeneration via resistive surface heating

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-10-08

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine; and a grid of electrically resistive material that is applied to an exterior upstream surface of the PF and that selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  2. ARM Airborne Carbon Measurement on the North Slope

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Airborne Carbon Measurement on the North Slope During the summer of 2015, a research campaign gave scientists insight into trends and variability of trace gases in the atmosphere over the Atmospheric Radiation Measurement (ARM) Climate Research Facility's North Slope of Alaska site to improve Arctic climate models. The ARM Airborne Carbon Measurements (ARM-ACME) campaign-finalizing the fifth phase in the Arctic-is providing a new observational perspective on the Earth's carbon cycle, and how

  3. Indoor air quality & airborne disease control in healthcare facilities

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Indoor air quality & airborne disease control in healthcare facilities Citation Details In-Document Search Title: Indoor air quality & airborne disease control in healthcare facilities This article is concerned with indoor air quality (IAQ) in the context of healthcare facilities. It defines what is meant by IAQ, lists health outcomes of poor IAQ, addresses specific healthcare IAQ issues, discusses solutions by means of HVAC systems, and

  4. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024lee2011o.pdf More Documents & Publications Development of Advanced Particulate Filters...

  5. Development of an Active Regeneration Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration...

  6. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  7. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster ... More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Expanded ...

  8. Final Report: Particulate Emissions Testing, Unit 1, Potomac...

    Broader source: Energy.gov (indexed) [DOE]

    analytical support in completing a Particulate Emission Test of Unit 1 of the Potomac River generating facility. The Test Program at the Potomac facility involved the completion ...

  9. Non-Destructive Neutron Imaging to Analyze Particulate Filters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon...

  10. Detailed Assessment of Particulate Characteristics from Low-Temperatur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines ... Program Annual Merit Review and Peer Evaluation Meeting PDF icon ...

  11. Development of Acicular Mullite Materials for Diesel Particulate...

    Broader source: Energy.gov (indexed) [DOE]

    Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFSCR On-Filter (SCRF) fundamental Modeling and Experimental Studies of ...

  12. Substrate Studies of an Electrically-Assisted Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on...

  13. Value Analysis of Alternative Diesel Particulate Filter (DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel ... Provide higher soot mass limits and durability than other materials at the same porosity. ...

  14. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions ...

  15. Mesoscale simulations of particulate flows with parallel distributed...

    Office of Scientific and Technical Information (OSTI)

    distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier ...

  16. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  17. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056stewart2011o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter ...

  18. Development and Demonstration of an Electronic Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and...

  19. Neutron Imaging of Diesel Particulate Filters

    SciTech Connect (OSTI)

    Strzelec, Andrea; Bilheux, Hassina Z; FINNEY, Charles E A; Daw, C Stuart; Foster, Prof. Dave; Rutland, Prof. Christopher J.; Schillinger, Burkhard; Schulz, Michael

    2009-01-01

    This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

  20. Electrically heated particulate filter with reduced stress

    DOE Patents [OSTI]

    Gonze, Eugene V.

    2013-03-05

    A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.

  1. Method of forming particulate materials for thin-film solar cells

    DOE Patents [OSTI]

    Eberspacher, Chris; Pauls, Karen Lea

    2004-11-23

    A method for preparing particulate materials useful in fabricating thin-film solar cells is disclosed. Particulate materials is prepared by the method include for example materials comprising copper and indium and/or gallium in the form of single-phase, mixed-metal oxide particulates; multi-phase, mixed-metal particulates comprising a metal oxide; and multinary metal particulates.

  2. Quality assurance project plan for the radionuclide airborne emissions for the Plutonium Finishing Plant

    SciTech Connect (OSTI)

    Kristofzski, J.G.; Alison, D.

    1992-04-01

    The information provided in this document meets the quality assurance (QA) requirements for the National Emission Standards for Hazardous Air Pollutants'' (NESHAP) (EPA 1989a) radionuclide airborne emissions control program in accordance with the regulation's referenced stack monitoring method (i.e. Method 114) for the Plutonium Finishing Plant (PFP). At the Hanford Site, the operations personnel have primary responsibility for implementing the continuous radionuclide emission measurements in conformance with NESHAP. Continuous measurement is used to describe continuous sampling of the effluent stream withdrawn and subjected to radiochemical analysis, and monitoring of radionuclide particulate emissions for administrative control. This Quality Assurance Project Plan (QAPjP) fully describes these PFP- implemented activities and the associated QA program as required by the NESHAP. The information is provided in the format specified in QAMS/005, Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans (EPA 1983a). This QAPjP describes the QA program for only those activities that are the responsibility of the PFP: operation, calibration, and maintenance of the sampling systems. The QA requirements for laboratory services, data compilation, and data reporting are beyond the scope of this QAPjP.

  3. Quality assurance project plan for the radionuclide airborne emissions for the Plutonium Finishing Plant

    SciTech Connect (OSTI)

    Kristofzski, J.G.; Alison, D.

    1992-04-01

    The information provided in this document meets the quality assurance (QA) requirements for the ``National Emission Standards for Hazardous Air Pollutants`` (NESHAP) (EPA 1989a) radionuclide airborne emissions control program in accordance with the regulation`s referenced stack monitoring method (i.e. Method 114) for the Plutonium Finishing Plant (PFP). At the Hanford Site, the operations personnel have primary responsibility for implementing the continuous radionuclide emission measurements in conformance with NESHAP. Continuous measurement is used to describe continuous sampling of the effluent stream withdrawn and subjected to radiochemical analysis, and monitoring of radionuclide particulate emissions for administrative control. This Quality Assurance Project Plan (QAPjP) fully describes these PFP- implemented activities and the associated QA program as required by the NESHAP. The information is provided in the format specified in QAMS/005, Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans (EPA 1983a). This QAPjP describes the QA program for only those activities that are the responsibility of the PFP: operation, calibration, and maintenance of the sampling systems. The QA requirements for laboratory services, data compilation, and data reporting are beyond the scope of this QAPjP.

  4. Airborne measured analytic signal for UXO detection

    SciTech Connect (OSTI)

    Gamey, T.J.; Holladay, J.S. [Aerodat Inc., Mississauga, Ontario (Canada); Mahler, R. [Industrieanlagen Betriebsgesellschaft, Deutschland (Australia)

    1997-10-01

    The Altmark Tank Training Range north of Haldensleben, Germany has been in operation since WWI. Weapons training and testing has included cavalry, cannon, small arms, rail guns, and tank battalions. Current plans are to convert the area to a fully digital combat training facility. Instead of using blank or dummy ordnance, hits will be registered with lasers and computers. Before this can happen, the 25,000 ha must be cleared of old debris. In support of this cleanup operation, Aerodat Inc., in conjunction with IABG of Germany, demonstrated a new high resolution magnetic survey technique involving the measurement of 3-component magnetic gradient data. The survey was conducted in May 1996, and covered 500 ha in two blocks. The nominal line spacing was 10 m, and the average sensor altitude was 7 m. The geologic column consisted of sands over a sedimentary basin. Topographic relief was generally flat with approximately 3 m rolling dunes and occasional man-made features such as fox holes, bunkers, tank traps and reviewing stands. Trees were sparse and short (2-3 metres) due to frequent burn off and tank activity. As such, this site was nearly ideal for low altitude airborne surveying.

  5. ARM Airborne Continuous carbon dioxide measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Biraud, Sebastien

    2013-03-26

    The heart of the AOS CO2 Airborne Rack Mounted Analyzer System is the AOS Manifold. The AOS Manifold is a nickel coated aluminum analyzer and gas processor designed around two identical nickel-plated gas cells, one for reference gas and one for sample gas. The sample and reference cells are uniquely designed to provide optimal flushing efficiency. These cells are situated between a black-body radiation source and a photo-diode detection system. The AOS manifold also houses flow meters, pressure sensors and control valves. The exhaust from the analyzer flows into a buffer volume which allows for precise pressure control of the analyzer. The final piece of the analyzer is the demodulator board which is used to convert the DC signal generated by the analyzer into an AC response. The resulting output from the demodulator board is an averaged count of CO2 over a specified hertz cycle reported in volts and a corresponding temperature reading. The system computer is responsible for the input of commands and therefore works to control the unit functions such as flow rate, pressure, and valve control.The remainder of the system consists of compressors, reference gases, air drier, electrical cables, and the necessary connecting plumbing to provide a dry sample air stream and reference air streams to the AOS manifold.

  6. ARM Airborne Continuous carbon dioxide measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Biraud, Sebastien

    The heart of the AOS CO2 Airborne Rack Mounted Analyzer System is the AOS Manifold. The AOS Manifold is a nickel coated aluminum analyzer and gas processor designed around two identical nickel-plated gas cells, one for reference gas and one for sample gas. The sample and reference cells are uniquely designed to provide optimal flushing efficiency. These cells are situated between a black-body radiation source and a photo-diode detection system. The AOS manifold also houses flow meters, pressure sensors and control valves. The exhaust from the analyzer flows into a buffer volume which allows for precise pressure control of the analyzer. The final piece of the analyzer is the demodulator board which is used to convert the DC signal generated by the analyzer into an AC response. The resulting output from the demodulator board is an averaged count of CO2 over a specified hertz cycle reported in volts and a corresponding temperature reading. The system computer is responsible for the input of commands and therefore works to control the unit functions such as flow rate, pressure, and valve control.The remainder of the system consists of compressors, reference gases, air drier, electrical cables, and the necessary connecting plumbing to provide a dry sample air stream and reference air streams to the AOS manifold.

  7. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, W.R. Jr.; Guthrie, S.E.; Raber, T.N.; Wally, K.; Whinnery, L.L.; Zifer, T.

    1999-02-02

    The present invention pertains generally to immobilizing particulate matter contained in a packed bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that (a) the particulate retains its essential chemical nature, (b) the local movement of the particulate particles is not unduly restricted, (c) bulk powder migration and is prevented, (d) physical and chemical access to the particulate is unchanged over time, and (e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of an individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport. 4 figs.

  8. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, Jr., William R.; Guthrie, Stephen E.; Raber, Thomas N.; Wally, Karl; Whinnery, LeRoy L.; Zifer, Thomas

    1999-01-01

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  9. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  10. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm041_lance_2011_p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Biofuels Impact on DPF Durability

  11. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  12. Method for removing particulate matter from a gas stream

    DOE Patents [OSTI]

    Postma, Arlin K. (Benton City, WA)

    1984-01-01

    Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

  13. Process for producing dispersed particulate composite materials

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Richland, WA); Hirth, John P. (Viola, ID)

    1995-01-01

    This invention is directed to a process for forming noninterwoven dispersed particulate composite products. In one case a composite multi-layer film product comprises a substantially noninterwoven multi-layer film having a plurality of discrete layers. This noninterwoven film comprises at least one discrete layer of a first material and at least one discrete layer of a second material. In another case the first and second materials are blended together with each other. In either case, the first material comprises a metalloid and the second material a metal compound. At least one component of a first material in one discrete layer undergoes a solid state displacement reaction with at least one component of a second material thereby producing the requisite noninterwoven composite film product. Preferably, the first material comprises silicon, the second material comprises Mo.sub.2 C, the third material comprises SiC and the fourth material comprises MoSi.sub.2.

  14. Overlap zoned electrically heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

    2011-07-19

    A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  15. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for ... Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency ...

  16. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009...

  17. ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope...

    Office of Scientific and Technical Information (OSTI)

    ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska Science and Implementation Plan Citation Details In-Document Search Title: ARM-ACME V: ARM Airborne ...

  18. Ground-Based and Airborne (PMS 2-D Probe Canister-Mounted) 183...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from -45 to +10 C (airborne has not been tested) This poster will describe details of the ground-based and airborne GVR designs and calibration, and will present examples of...

  19. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, G.S.

    1998-12-15

    Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

  20. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1998-01-01

    Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

  1. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024lee2010o.pdf More Documents & Publications Development of Advanced Diesel Particulate...

  2. Diesel Particulate Filter Technology for Low-Temperature and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Technology for Low-Temperature and Low-NOxPM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOxPM Applications 2004 DEER Conference...

  3. Blowers for Air Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM ...

  4. Mechanical Properties of Particulate Reinforced Aluminium Alloy Matrix Composite

    SciTech Connect (OSTI)

    Sayuti, M. [Faculty of Engineering, Malikussaleh University of Lhokseumawe, 24300 Aceh (Indonesia); Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Sulaiman, S.; Baharudin, B. T. H. T.; Arifin, M. K. A. [Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Suraya, S.; Vijayaram, T. R.

    2011-01-17

    This paper discusses the mechanical properties of Titanium Carbide (TiC) particulate reinforced aluminium-silicon alloy matrix composite. TiC particulate reinforced LM6 alloy matrix composites were fabricated by carbon dioxide sand molding process with different particulate weight fraction. Tensile strength, hardness and microstructure studies were conducted to determine the maximum load, tensile strength, modulus of elasticity and fracture surface analysis have been performed to characterize the morphological aspects of the test samples after tensile testing. Hardness values are measured for the TiC reinforced LM6 alloy composites and it has been found that it gradually increases with increased addition of the reinforcement phase. The tensile strength of the composites increased with the increase percentage of TiC particulate.

  5. ARM - Field Campaign - Semi-Continuous OCEC Particulate Measurement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send Campaign : Semi-Continuous OCEC Particulate Measurement 2013.06.01 - 2013.11.27 Lead Scientist : Robert Cary For data sets, see below. Abstract The Sunset Laboratory...

  6. ARM - Field Campaign - 1999 Northeast Corridor Ozone & Particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 1999 Northeast Corridor Ozone & Particulate Study 1999.07.23 - 1999.08.11 Lead...

  7. Zone heated inlet ignited diesel particulate filter regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  8. A Standard Soot Generator for Diesel Particulate Filter Testing |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Standard Soot Generator for Diesel Particulate Filter Testing A Standard Soot Generator for Diesel Particulate Filter Testing Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_nickolaus.pdf More Documents & Publications XP-SiC: An Innovative Substrate

  9. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Authors: Kanarska, Y ; Lomov, I ; Antoun, T Publication Date: 2010-09-10 OSTI Identifier: 1120915 Report Number(s): LLNL-JRNL-455392 DOE Contract Number: W-7405-ENG-48

  10. Improvement and Simplification of Diesel Particulate Filter System using a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceria-Based Fuel-Borne Catalyst in Serial Applications | Department of Energy Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis PDF icon 2004_deer_macaudiere.pdf More Documents &

  11. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  12. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a

  13. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI)

  14. Accelerated Extraction of Diesel Particulate Matter SOF | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Extraction of Diesel Particulate Matter SOF Accelerated Extraction of Diesel Particulate Matter SOF Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_lewis.pdf More Documents & Publications Chemical Analysis of Soot Using Thermal Desorption/Pyrolysis Gas

  15. Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Loading and Regeneration | Department of Energy Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_sappok.pdf More Documents & Publications Vehicle Technologies Office Merit

  16. Reducing the Particulate Emission Numbers in DI Gasoline Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Particulate Emission Numbers in DI Gasoline Engines Reducing the Particulate Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding air/fuel zones richer than stoichiometric and temperatures that promote particle formation PDF icon deer10_klindt.pdf More Documents & Publications Bosch Powertrain Technologies Vehicle Emissions Review - 2012 Ethanol Effects on Lean-Burn and

  17. Reduction of Transient Particulate Matter Spikes with Decision Tree Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control | Department of Energy Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric decision tree to measure transient PM could correctly identify 94% of high opacity spikes and used to take targeted action to reduce PM without affecting NOx. PDF icon deer12_brahma.pdf More Documents & Publications New Demands on Heavy Duty Engine Management Systems An Enabling Study

  18. Evaluation of a Partial Flow Dilution System for Transient Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Matter Emissions | Department of Energy a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially available partial flow dilution system was evaluated against a constant volume sampling system over a suite of transient engine dynamometer tests. PDF icon deer08_shade.pdf More Documents & Publications Evaluation of the European PMP Methodologies Using Chassis Dynamometer

  19. Experimental Diesel Particulate Filter Capabilities at PNNL | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Diesel Particulate Filter Capabilities at PNNL Experimental Diesel Particulate Filter Capabilities at PNNL Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_gallant.pdf More Documents & Publications Diesel Soot Filter Characterization and Modeling for Advanced Substrates fundamental Modeling and Experimental Studies of Acicular Mullite Diesel

  20. Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramics | Department of Energy Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three established mechanical test specimen geometries and test methods for brittle materials are adapted to DPF architecture to evaluate failure initiation stress and apparent elastic modulus of the ceramics. PDF icon p-15_wereszczak.pdf More Documents & Publications Durability of Diesel Engine

  1. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Time and Fuel Consumption | Department of Energy Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster regeneration time, improved heat transfer, and reduction in manufacturing steps PDF icon deer09_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber

  2. Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Future Diesel Aftertreatment Systems | Department of Energy Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems DPF products like Acicular Mullite meet multiple needs Provide higher soot mass limits and durability than other materials at the same porosity. PDF icon deer09_majkowski.pdf More Documents &

  3. Diesel Particulate Filters: Market Introducution in Europe | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Filters: Market Introducution in Europe Diesel Particulate Filters: Market Introducution in Europe 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Aaqius and Aaqius PDF icon 2004_deer_seguelong2.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles French perspective on diesel engines & emissions Diesel Particulate Filter: A Success for Faurecia Exhaust Systems

  4. Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters SEM analysis showed that ACM DPF can be coated with relatively high catalyst washcoat without significantly affecting the porosity or pore size Therefore, it maintains a low back pressure performance at very high catalyst PDF icon deer09_malanga.pdf More Documents & Publications Future Trends for

  5. Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of Sanitation, the Radio Frequency Diesel

  6. Diesel particulate filter (DPF) regeneration by electrical heating of resistive coatings

    DOE Patents [OSTI]

    Williamson, Weldon S. (Malibu, CA); Gonze, Eugene V. (Pinckney, MI)

    2008-12-30

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is integrally formed in an upstream end of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  7. Alternatives to Diesel Fuel in California - Fuel Cycle Energy and Emission Effects of Possible Replacements Due to the TAC Diesel Particulate Decision

    SciTech Connect (OSTI)

    Christopher L. Saraicks; Donald M. Rote; Frank Stodolsky; James J. Eberhardt

    2000-05-01

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression ignition by spark ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7 percent above projected (total) consumption level. In the second case, ressionignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOx emissions, though all scenarios bring about PM10 reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  8. Real-Time Airborne Particle Analyzer - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Real-Time Airborne Particle Analyzer Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary Particle analysis is useful for determining chemical compositions in a wide range of disciplines, from ascertaining the source of a petroleum sample to duplicating a fragrance. The technique is appealing to a broad cross section of analytical sciences, but its applications are limited because, for existing equipment, sample size

  9. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  10. Method for dispersing catalyst onto particulate material and product thereof

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  11. Method and apparatus for injecting particulate media into the ground

    DOE Patents [OSTI]

    Dwyer, Brian P.; Dwyer, Stephen F.; Vigil, Francine S.; Stewart, Willis E.

    2004-12-28

    An improved method and apparatus for injecting particulate media into the ground for constructing underground permeable reactive barriers, which are used for environmental remediation of subsurface contaminated soil and water. A media injector sub-assembly attached to a triple wall drill string pipe sprays a mixture of active particulate media suspended in a carrier fluid radially outwards from the sub-assembly, at the same time that a mixing fluid is sprayed radially outwards. The media spray intersects the mixing spray at a relatively close distance from the point of injection, which entrains the particulate media into the mixing spray and ensures a uniform and deep dispersion of the active media in the surrounding soil. The media injector sub-assembly can optionally include channels for supplying compressed air to an attached down-the-hole hammer drive assembly for use during drilling.

  12. EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduces Fuel Consumption, Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of

  13. Concentrations and Size Distributions of Particulate Matter Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel | Department of Energy Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel 2002 DEER Conference Presentation: West Virginia

  14. Imaging of Diesel Particulate Filters using a High-Flux Neutron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified...

  15. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, ...

  16. A New CFD Model for understanding and Managing Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration | Department of Energy CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon 2004_deer_hou.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Vehicle Evaluation of Downsized Dow ACM DPF

  17. The State of the Science in Diesel Particulate Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The State of the Science in Diesel Particulate Control The State of the Science in Diesel Particulate Control 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_muntean.pdf More Documents & Publications Method Development: Identification of the Soluble Organic Fraction of Particulate Matter on DPF Soot Aftertreatment Research Prioritization: A CLEERS Industrial Survey Development of a Sub-Grid Model of a Diesel Particulate Filter:

  18. Electrically heated particulate matter filter with recessed inlet end plugs

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Ament, Frank (Troy, MI)

    2012-02-21

    A particulate matter (PM) filter includes filter walls having inlet ends and outlet ends. First adjacent pairs of the filter walls define inlet channels. Second adjacent pairs of the filter walls define outlet channels. Outlet end plugs are arranged in the inlet channels adjacent to the output ends. Inlet end plugs arranged in the outlet channels spaced from the inlet ends.

  19. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  20. Electrically heated particulate filter diagnostic systems and methods

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2009-09-29

    A system that diagnoses regeneration of an electrically heated particulate filter is provided. The system generally includes a grid module that diagnoses a fault of the grid based on at least one of a current signal and a voltage signal. A diagnostic module at least one of sets a fault status and generates a warning signal based on the fault of the grid.

  1. Comparison of Particulate Collection in Probes and on Filters

    SciTech Connect (OSTI)

    Eaton, J.M.; Humphreys, M.P.

    2001-06-14

    Major radionuclide emissions from the Department of Energy's Y-12 National Security Complex are nuclides of uranium which are emitted as a particulate. The radionuclide NESHAP regulation requires stack sampling to be conducted in accordance with ANST Standard N13.1, 1969. Appendix B of this standard requires in every case where sampling delivery lines are used that an evaluation should be made of deposition in these lines. A number of Y-12 Complex stacks are fitted with continuous samplers which draw particulate laden air through a probe and across a sample filter. One approach to evaluate line loss as required by the ANSI standard is to establish a representative factor that is used for all subsequent sampling efforts. Another approach is to conduct a routine probe wash procedure on an ongoing basis to account for line losses. In 1991, Y-12 National Security Complex personnel began routine probe washes as part of their sample collection procedure. Since then, 50-80 stacks have been sampled on a near continuous basis and probe washes have been conducted quarterly. Particulate collection in probes versus particulate collection on filters is recorded as a probe factor and probe factor trends for a 10-year period are available.

  2. Inductively heated particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore Jr., Michael J; Kirby, Kevin W; Phelps, Amanda; Gregoire, Daniel J

    2012-10-23

    A system includes a particulate matter (PM) filter with an upstream end for receiving exhaust gas, a downstream end and zones. The system also includes a heating element. A control module selectively activates the heating element to inductively heat one of the zones.

  3. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace056_stewart_2012_o.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods

  4. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056_stewart_2011_o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  5. Electrically heated particulate filter regeneration methods and systems for hybrid vehicles

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-10-12

    A control system for controlling regeneration of a particulate filter for a hybrid vehicle is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate regeneration. An engine control module controls operation of an engine of the hybrid vehicle based on the control of the current to the particulate filter.

  6. Airborne Instrumentation Needs for Climate and Atmospheric Research

    SciTech Connect (OSTI)

    McFarquhar, Greg; Schmid, Beat; Korolev, Alexei; Ogren, John A.; Russell, P. B.; Tomlinson, Jason M.; Turner, David D.; Wiscombe, Warren J.

    2011-10-06

    Observational data are of fundamental importance for advances in climate and atmospheric research. Advances in atmospheric science are being made not only through the use of ground-based and space-based observations, but also through the use of in-situ and remote sensing observations acquired on instrumented aircraft. In order for us to enhance our knowledge of atmospheric processes, it is imperative that efforts be made to improve our understanding of the operating characteristics of current instrumentation and of the caveats and uncertainties in data acquired by current probes, as well as to develop improved observing methodologies for acquisition of airborne data.

  7. Quality assurance program plan for radionuclide airborne emissions monitoring

    SciTech Connect (OSTI)

    Boom, R.J.

    1995-03-01

    This Quality Assurance Program Plan identifies quality assurance program requirements and addresses the various Westinghouse Hanford Company organizations and their particular responsibilities in regards to sample and data handling of airborne emissions. The Hanford Site radioactive airborne emissions requirements are defined in National Emissions Standards for Hazardous Air Pollutants (NESHAP), Code of Federal Regulations, Title 40, Part 61, Subpart H (EPA 1991a). Reporting of the emissions to the US Department of Energy is performed in compliance with requirements of US Department of Energy, Richland Operations Office Order 5400.1, General Environmental Protection Program (DOE-RL 1988). This Quality Assurance Program Plan is prepared in accordance with and to the requirements of QAMS-004/80, Guidelines and Specifications for Preparing Quality Assurance Program Plans (EPA 1983). Title 40 CFR Part 61, Appendix B, Method 114, Quality Assurance Methods (EPA 1991b) specifies the quality assurance requirements and that a program plan should be prepared to meet the requirements of this regulation. This Quality Assurance Program Plan identifies NESHAP responsibilities and how the Westinghouse Hanford Company Environmental, Safety, Health, and Quality Assurance Division will verify that the methods are properly implemented.

  8. Multi-center airborne coherent atmospheric wind sensor (MACAWS)

    SciTech Connect (OSTI)

    Rothermel, J.; Menzies, R.T.; Tratt, D.M.

    1996-11-01

    The Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) is an airborne scanning coherent Doppler lidar designed to acquire remote multi-dimensional measurements of winds and absolute aerosol backscatter in the troposphere and lower stratosphere. These measurements enable study of atmospheric dynamic processes and features at scales of motion that may be undersampled by, or may be beyond the capability of, existing or planned sensors. MACAWS capabilities enable more realistic assessments of concepts in global tropospheric wind measurement with satellite Doppler lidar, as well as a unique capability to validate the NASA Scatterometer currently scheduled for launch in late 1996. MACAWS consists of a Joule-class CO{sub 2} coherent Doppler lidar on a ruggedized optical table, a programmable scanner to direct the lidar beam in the desired direction, and a dedicated inertial navigation system to account for variable aircraft attitude and speed. MACAWS was flown for the first time in September 1995, over the eastern Pacific Ocean and western US. 33 refs., 2 figs.

  9. Environmental continuous air monitor for ambient transuranic particulates

    SciTech Connect (OSTI)

    Rodgers, J.C.; Moore, M.E. [Los Alamos National Lab., NM (United States)

    1995-12-31

    We have constructed a working prototype of an environmental continuous air monitor (ECAM) for outdoor applications. The ECAM device is designed to continuously monitor the presence of transuranic contaminant aerosol below a size of 10 mm aerodynamic diameter. In remote operation, the ECAM can transmit radiological and meteorological data to a central processing location, where we have implemented geographical mapping and GPS capabilities into an integrated software package. The Canberra Alpha Sentry Monitor, a commercially available continuous air monitor (CAM) for indoor room applications, was used as the basic building block for the prototype. We increased the sample air flow to 4 cubic feet per minute (CFM) compared to the design air flow rate of 2 CFM. We also added a spread-spectrum radio data link between the CAM RS-232 serial port and a distant radio receiver that enables remote monitoring. In order to avoid collecting the large diameter particle fraction containing most of the inert mass that causes sample burial and alpha spectrum degradation, a Model 254 PM10 size-fractionating Wet from Graseby-Andersen was fitted to the Alpha Sentry Monitor. We removed the top cover of the CAM unit, and routed openings in the top surface of the CAM inlet. This allows air to flow into the inlet, down a collection tube, and then vertically into the CAM without the elbow and horizontal transition piece of the present in-line adapter. The air flows through a 47 mm filter, and the transuranic contamination is counted by a solid state alpha radiation detector, which is placed at a distance of 5 mm above the filter. The increased air flow significantly improves CAM alarm sensitivity and response time to an estimated level of 3.8x10-12 mCi/ml for an integration period 30 minutes. At the same time, the fractionating inlet removes a substantial amount of inert dust and thus enables extended monitoring without frequent maintenance.

  10. Fluidizable particulate materials and methods of making same

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC)

    1999-01-01

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  11. Fluidizable particulate materials and methods of making same

    SciTech Connect (OSTI)

    Gupta, R.P.

    1999-10-26

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  12. Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Operations | Department of Energy Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations The overall goal of this study is to help identify which conditions and potential mechanisms impede soot formation in GDI operations. PDF icon p-24_storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion

  13. Stabilization void-fill encapsulation high-efficiency particulate filters

    SciTech Connect (OSTI)

    Alexander, R.G.; Stewart, W.E.; Phillips, S.J.; Serkowski, M.M.; England, J.L.; Boynton, H.C.

    1994-05-01

    This report discusses high-efficiency particulate air (HEPA) filter systems that which are contaminated with radionuclides are part of the nuclear fuel processing systems conducted by the US Department of Energy (DOE) and require replacement and safe and efficient disposal for plant safety. Two K-3 HEPA filters were removed from service, placed burial boxes, buried, and safely and efficiently stabilized remotely which reduced radiation exposure to personnel and the environment.

  14. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    2003-04-08

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between the rows of filter elements are rows of high voltage discharge electrodes. Between the rows of discharge electrodes and the rows of filter elements are grounded perforated plates for creating electrostatic precipitation zones.

  15. Microwave mode shifting antenna system for regenerating particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA; Gregoire, Daniel J [Thousand Oaks, CA

    2011-04-26

    A regeneration system comprises a particulate matter (PM) filter including a microwave energy absorbing surface, and an antenna system comprising N antennas and an antenna driver module that sequentially drives the antenna system in a plurality of transverse modes of the antenna system to heat selected portions of the microwave absorbing surface to regenerate the PM filter, where N is an integer greater than one. The transverse modes may include transverse electric (TE) and/or transverse magnetic (TM) modes.

  16. Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon | Department of Energy Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-14_strzelec.pdf More Documents & Publications Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Vehicle Technologies Office: 2010 Fuel

  17. Initial assessment of an airborne Ku-band polarimetric SAR.

    SciTech Connect (OSTI)

    Raynal, Ann Marie; Doerry, Armin Walter

    2013-02-01

    Polarimetric synthetic aperture radar (SAR) has been used for a variety of dual-use research applications since the 1940's. By measuring the direction of the electric field vector from radar echoes, polarimetry may enhance an analyst's understanding of scattering effects for both earth monitoring and tactical surveillance missions. Polarimetry may provide insight into surface types, materials, or orientations for natural and man-made targets. Polarimetric measurements may also be used to enhance the contrast between scattering surfaces such as man-made objects and their surroundings. This report represents an initial assessment of the utility of, and applications for, polarimetric SAR at Ku-band for airborne or unmanned aerial systems.

  18. Method for measuring the size distribution of airborne rhinovirus

    SciTech Connect (OSTI)

    Russell, M.L.; Goth-Goldstein, R.; Apte, M.G.; Fisk, W.J.

    2002-01-01

    About 50% of viral-induced respiratory illnesses are caused by the human rhinovirus (HRV). Measurements of the concentrations and sizes of bioaerosols are critical for research on building characteristics, aerosol transport, and mitigation measures. We developed a quantitative reverse transcription-coupled polymerase chain reaction (RT-PCR) assay for HRV and verified that this assay detects HRV in nasal lavage samples. A quantitation standard was used to determine a detection limit of 5 fg of HRV RNA with a linear range over 1000-fold. To measure the size distribution of HRV aerosols, volunteers with a head cold spent two hours in a ventilated research chamber. Airborne particles from the chamber were collected using an Andersen Six-Stage Cascade Impactor. Each stage of the impactor was analyzed by quantitative RT-PCR for HRV. For the first two volunteers with confirmed HRV infection, but with mild symptoms, we were unable to detect HRV on any stage of the impactor.

  19. Airborne and ground-based measurements of the trace gases and particles emitted from prescribed fires in the United States

    SciTech Connect (OSTI)

    Burling, Ian; Yokelson, Robert J.; Akagi, Sheryl; Urbanski, Shawn; Wold, Cyle E.; Griffith, David WT; Johnson, Timothy J.; Reardon, James; Weise, David

    2011-12-07

    We measured the emission factors for 19 trace gas species and particulate matter (PM2.5) from 14 prescribed fires in chaparral and oak savanna in the southwestern US, as well as pine forest understory in the southeastern US and Sierra Nevada mountains of California. These are likely the most extensive emission factor field measurements for temperate biomass burning to date and the only published emission factors for temperate oak savanna fuels. This study helps close the gap in emissions data available for temperate zone fires relative to tropical biomass burning. We present the first field measurements of the biomass burning emissions of glycolaldehyde, a possible precursor for aqueous phase secondary organic aerosol formation. We also measured the emissions of phenol, another aqueous phase secondary organic aerosol precursor. Our data confirm previous suggestions that urban deposition can impact the NOx emission factors and thus subsequent plume chemistry. For two fires, we measured the emissions in the convective smoke plume from our airborne platform at the same time the unlofted residual smoldering combustion emissions were measured with our ground-based platform after the flame front passed through. The smoke from residual smoldering combustion was characterized by emission factors for hydrocarbon and oxygenated organic species that were up to ten times higher than in the lofted plume, including significant 1,3-butadiene and isoprene concentrations which were not observed in the lofted plume. This should be considered in modeling the air quality impacts of smoke that disperses at ground level, and we show that the normally-ignored unlofted emissions can also significantly impact estimates of total emissions. Preliminary evidence of large emissions of monoterpenes was seen in the residual smoldering spectra, but we have not yet quantified these emissions. These data should lead to an improved capacity to model the impacts of biomass burning in similar ecosystems.

  20. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_44_hall.pdf More Documents & Publications Development and Demonstration of an Electronic Particulate Matter Sensor for Both

  1. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-05_lu.pdf More Documents & Publications Advanced Metal Fiber Wall-Flow DPF For Diesel Emission Control Requirements from Particulate Filter Technology for Commercial Vehicles:

  2. Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction | Department of Energy the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-15_wei.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Investigation of Direct Injection Vehicle Particulate Matter

  3. New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER Conference Presentation: Corning Incorporated PDF icon 2003_deer_merkel.pdf More Documents & Publications 12TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE (DEER 2006) PRESENTATIONS Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by

  4. Development of a Sub-Grid Model of a Diesel Particulate Filter: application

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique | Department of Energy a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2002_deer_muntean.pdf More Documents & Publications The State of the Science in Diesel Particulate Control fundamental Modeling and Experimental

  5. Chemopreventive activity of compounds extracted from Casearia sylvestris (Salicaceae) Sw against DNA damage induced by particulate matter emitted by sugarcane burning near Araraquara, Brazil

    SciTech Connect (OSTI)

    Prieto, A.M.; Santos, A.G.; Csipak, A.R.; Caliri, C.M.; Silva, I.C.; Arbex, M.A.; Silva, F.S.; Marchi, M.R.R.

    2012-12-15

    Ethanolic extract of Casearia sylvestris is thought to be antimutagenic. In this study, we attempted to determine whether this extract and casearin X (a clerodane diterpene from C. sylvestris) are protective against the harmful effects of airborne pollutants from sugarcane burning. To that end, we used the Tradescantia micronucleus test in meiotic pollen cells of Tradescantia pallida, the micronucleus test in mouse bone marrow cells, and the comet assay in mouse blood cells. The mutagenic compound was total suspended particulate (TSP) from air. For the Tradescantia micronucleus test, T. pallida cuttings were treated with the extract at 0.13, 0.25, or 0.50 mg/ml. Subsequently, TSP was added at 0.3 mg/ml, and tetrads from the inflorescences were examined for micronuclei. For the micronucleus test in mouse bone marrow cells and the comet assay in mouse blood cells, Balb/c mice were treated for 15 days with the extract3.9, 7.5, or 15.0 mg/kg body weight (BW)or with casearin X0.3, 0.25, or 1.2 mg/kg BWafter which they received TSP (3.75 mg/kg BW). In T. pallida and mouse bone marrow cells, the extract was antimutagenic at all concentrations tested. In mouse blood cells, the extract was antigenotoxic at all concentrations, whereas casearin X was not antimutagenic but was antigenotoxic at all concentrations. We conclude that C. sylvestris ethanolic extract and casearin X protect DNA from damage induced by airborne pollutants from sugarcane burning. -- Highlights: ? We assessed DNA protection of C. sylvestris ethanolic extract. ? We assessed DNA protection of casearin X. ? We used Tradescantia pallida micronucleus test as screening. ? We used comet assay and micronucleus test in mice. ? The compounds protected DNA against sugar cane burning pollutants.

  6. Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  7. Development of a Sub-Grid Model of a Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference ...

  8. Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  9. Active DPF for Off-Road Particulate Matter (PM) Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy DPF for Off-Road Particulate Matter (PM) Control Active DPF for Off-Road Particulate Matter (PM) Control This presentation details how a possibly catalyzed active diesel particulate filter can be used to control off-road particulate matter. PDF icon deer08_servati.pdf More Documents & Publications DPF for a Tractor Auxiliary Power Unit A Low-Cost Continuous Emissions Monitoring System for Mobile and Stationary Engine SCR/DPF Applications/Data-Logger for Vehicle Data Acquisition

  10. Measuring PM Distribution in a Catalyzed Particulate Filter using a Terahertz Wave Scanner

    Broader source: Energy.gov [DOE]

    Terahertz scanning system produced 3-dimensional image of local PM density in catatalyzed particulate filters tested under loading and oxidizing conditions

  11. Apparatus for removal of particulate matter from gas streams

    DOE Patents [OSTI]

    Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

    2000-01-01

    An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

  12. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  13. Low exhaust temperature electrically heated particulate matter filter system

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI); Bhatia, Garima (Bangalore, IN)

    2012-02-14

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  14. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, S.J.

    1999-08-17

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements. 12 figs.

  15. Controlled laser production of elongated articles from particulates

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Lewis, Gary K. (Los Alamos, NM); Milewski, John O. (Santa Fe, NM)

    2002-01-01

    It has been discovered that wires and small diameter rods can be produced using laser deposition technology in a novel way. An elongated article such as a wire or rod is constructed by melting and depositing particulate material into a deposition zone which has been designed to yield the desired article shape and dimensions. The article is withdrawn from the deposition zone as it is formed, thus enabling formation of the article in a continuous process. Alternatively, the deposition zone is moved along any of numerous deposition paths away from the article being formed.

  16. Electrically heated particulate filter with zoned exhaust flow control

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-06-26

    A system includes a particulate matter (PM) filter that includes X zones. An electrical heater includes Y heater segments that are associated with respective ones of the X zones. The electrical heater is arranged upstream from and proximate with the PM filter. A valve assembly includes Z sections that are associated with respective ones of the X zones. A control module adjusts flow through each of the Z sections during regeneration of the PM filter via control of the valve assembly. X, Y and Z are integers.

  17. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  18. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    1999-01-01

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements.

  19. Wireless zoned particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA

    2011-10-04

    An assembly includes a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and multiple zones. An absorbing layer absorbs microwave energy in one of N frequency ranges and is arranged with the upstream end. N is an integer. A frequency selective filter has M frequency selective segments and receives microwave energy in the N frequency ranges. M is an integer. One of the M frequency selective segments permits passage of the microwave energy in one of the N frequency ranges and does not permit passage of microwave energy in the other of the N frequency ranges.

  20. Zoned electrical heater arranged in spaced relationship from particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-11-15

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  1. Overview of the first Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) experiment: Conversion of a ground-based lidar for airborne applications

    SciTech Connect (OSTI)

    Howell, J.N.; Hardesty, R.M.; Rothermel, J.; Menzies, R.T.

    1996-12-31

    The first Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) field experiment demonstrated an airborne high energy TEA CO{sub 2} Doppler lidar system for measurement of atmospheric wind fields and aerosol structure. The system was deployed on the NASA DC-8 during September 1995 in a series of checkout flights to observe several important atmospheric phenomena, including upper level winds in a Pacific hurricane, marine boundary layer winds, cirrus cloud properties, and land-sea breeze structure. The instrument, with its capability to measure three-dimensional winds and backscatter fields, promises to be a valuable tool for climate and global change, severe weather, and air quality research. In this paper, the authors describe the airborne instrument, assess its performance, discuss future improvements, and show some preliminary results from September experiments.

  2. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  3. Airborne release fractions/rates and respirable fractions for nonreactor nuclear facilities. Volume 2, Appendices

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    This document contains compiled data from the DOE Handbook on Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear facilities. Source data and example facilities utilized, such as the Plutonium Recovery Facility, are included.

  4. ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska

    Office of Scientific and Technical Information (OSTI)

    Science and Implementation Plan (Program Document) | SciTech Connect ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska Science and Implementation Plan Citation Details In-Document Search Title: ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska Science and Implementation Plan Atmospheric temperatures are warming faster in the Arctic than predicted by climate models. The impact of this warming on permafrost degradation is not well understood,

  5. The Effect of Airborne Contaminants on Fuel Cell Performance & Durability |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy The Effect of Airborne Contaminants on Fuel Cell Performance & Durability The Effect of Airborne Contaminants on Fuel Cell Performance & Durability Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 PDF icon rocheleau_uhawaii_kickoff.pdf More Documents & Publications Supporting a Hawaii Hydrogen Economy Effects of Impurities of Fuel Cell Performance and Durability Effect of System and Air Contaminants on

  6. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, George T. (15 Cherry Hills Dr., Aiken, SC 29803)

    1992-01-01

    An off-gas stack for a melter comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes pervents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  7. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, G.T.

    1991-04-08

    This report describes an off-gas stack for a melter, furnace or reaction vessel comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes prevents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  8. Airborne spread of foot-and-mouth disease - model intercomparison

    SciTech Connect (OSTI)

    Gloster, J; Jones, A; Redington, A; Burgin, L; Sorensen, J H; Turner, R; Dillon, M; Hullinger, P; Simpson, M; Astrup, P; Garner, G; Stewart, P; D'Amours, R; Sellers, R; Paton, D

    2008-09-04

    Foot-and-mouth disease is a highly infectious vesicular disease of cloven-hoofed animals caused by foot-and-mouth disease virus. It spreads by direct contact between animals, by animal products (milk, meat and semen), by mechanical transfer on people or fomites and by the airborne route - with the relative importance of each mechanism depending on the particular outbreak characteristics. Over the years a number of workers have developed or adapted atmospheric dispersion models to assess the risk of foot-and-mouth disease virus spread through the air. Six of these models were compared at a workshop hosted by the Institute for Animal Health/Met Office during 2008. A number of key issues emerged from the workshop and subsequent modelling work: (1) in general all of the models predicted similar directions for 'at risk' livestock with much of the remaining differences strongly related to differences in the meteorological data used; (2) determination of an accurate sequence of events is highly important, especially if the meteorological conditions vary substantially during the virus emission period; and (3) differences in assumptions made about virus release, environmental fate, and subsequent infection can substantially modify the size and location of the downwind risk area. Close relationships have now been established between participants, which in the event of an outbreak of disease could be readily activated to supply advice or modelling support.

  9. Resistive heater geometry and regeneration method for a diesel particulate filter

    DOE Patents [OSTI]

    Phelps, Amanda; Kirby, Kevin W.; Gregoir, Daniel J.

    2011-10-25

    One embodiment of the invention includes a diesel particulate filter comprising a first face and a second face; a bottom electrode layer formed over the first face of the diesel particulate filter; a middle resistive layer formed over a portion of the bottom electrode layer; and a top electrode layer formed over a portion of the middle resistive layer.

  10. High exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  11. Integrated exhaust and electrically heated particulate filter regeneration systems

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2013-01-08

    A system includes a particulate matter (PM) filter that includes multiple zones. An electrical heater includes heater segments that are associated with respective ones of the zones. The electrical heater is arranged upstream from and proximate with the PM filter. A post-fuel injection system injects fuel into at least one of a cylinder of an engine and an exhaust system. A control module is configured to operate in a first mode that includes activating the electrical heater to heat exhaust of the engine. The control module is also configured to operate in a second mode that includes activating the post-injection system to heat the exhaust. The control module selectively operates in at least one of the first mode and the second mode.

  12. Dry scrubbing oxides and particulate contaminants from hot gases

    SciTech Connect (OSTI)

    Quee, J. A.; Haak, M. P.

    1985-03-12

    Sulfur dioxides are dry scrubbed from a flue gas by introducing minute droplets containing a liquid, such as water, and an alkali or alkaline reactant, such as lime, into the spray zone in the primary spray drying chamber of a spray dryer and concurrently contacting these droplets with the hot flue gas. The droplets are partially dried to a tacky condition before reaching a foraminous collecting member extending through the primary spray drying chamber and collect on the collecting member as a moist, porous mat. As the flue gas continues to flow through the mat, the mat serves as a filter for removing fly ash and other particulate matter and remaining sulfur oxides react with unreacted particles of the reactant and reactive ingredients of the fly ash particles in the mat.

  13. Pb Isotopes as an Indicator of the Asian Contribution to Particulate Air Pollution in Urban California

    SciTech Connect (OSTI)

    Ewing, Stephanie A.; Christensen, John N.; Brown, Shaun T.; Vancuren, Richard A.; Cliff, Steven S.; DePaolo, Donald J.

    2010-10-25

    During the last two decades, expanding industrial activity in east Asia has led to increased production of airborne pollutants that can be transported to North America. Previous efforts to detect this trans-Pacific pollution have relied upon remote sensing and remote sample locations. We tested whether Pb isotope ratios in airborne particles can be used to directly evaluate the Asian contribution to airborne particles of anthropogenic origin in western North America, using a time series of samples from a pair of sites upwind and downwind of the San Francisco Bay Area. Our results for airborne Pb at these sites indicate a median value of 29 Asian origin, based on mixing relations between distinct regional sample groups. This trans-Pacific Pb is present in small quantities but serves as a tracer for airborne particles within the growing Asian industrial plume. We then applied this analysis to archived samples from urban sites in central California. Taken together, our results suggest that the analysis of Pb isotopes can reveal the distribution of airborne particles affected by Asian industrial pollution at urban sites in northern California. Under suitable circumstances, this analysis can improve understanding of the global transport of pollution, independent of transport models.

  14. 3D model generation using an airborne swarm

    SciTech Connect (OSTI)

    Clark, R. A.; Punzo, G.; Macdonald, M.; Dobie, G.; MacLeod, C. N.; Summan, R.; Pierce, G.; Bolton, G.

    2015-03-31

    Using an artificial kinematic field to provide co-ordination between multiple inspection UAVs, the authors herein demonstrate full 3D modelling capability based on a photogrammetric system. The operation of the system is demonstrated by generating a full 3D surface model of an intermediate level nuclear waste storage drum. Such drums require periodic inspection to ensure that drum distortion or corrosion is carefully monitored. Performing this inspection with multiple airborne platforms enables rapid inspection of structures that are inaccessible to on-surface remote vehicles and are in human-hazardous environments. A three-dimensional surface-meshed model of the target can then be constructed in post-processing through photogrammetry analysis of the visual inspection data. The inspection environment uses a tracking system to precisely monitor the position of each aerial vehicle within the enclosure. The vehicles used are commercially available Parrot AR. Drone quadcopters, controlled through a computer interface connected over an IEEE 802.11n (WiFi) network, implementing a distributed controller for each vehicle. This enables the autonomous and distributed elements of the control scheme to be retained, while alleviating the vehicles of the control algorithms computational load. The control scheme relies on a kinematic field defined with the target at its centre. This field defines the trajectory for all the drones in the volume relative to the central target, enabling the drones to circle the target at a set radius while avoiding drone collisions. This function enables complete coverage along the height of the object, which is assured by transitioning to another inspection band only after completing circumferential coverage. Using a swarm of vehicles, the time until complete coverage can be significantly reduced.

  15. Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Heavy Duty and NRMM According to Annex XXVII StVZO | Department of Energy Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO This presentation discusses how a diesel particulate filter can be integrated in the exhaust piping of a heavy-duty engine. PDF icon deer08_rembor.pdf More

  16. affects on the transport of airborne emissions. This information is needed durin

    National Nuclear Security Administration (NNSA)

    affects on the transport of airborne emissions. This information is needed during the period of repository operation and closure to "estimate the potential effects on the transport of airborne emissions." 1.3.3 Environmental Quality Further federal regulations 10 CFR 960.5-2-5 include the need for information on existing air quality and trends in order to estimate potential impacts on public health and welfare and on environmental quality. 1.3.4 National Ambient Air Quality Standards

  17. Effluent monitoring Quality Assurance Project Plan for radioactive airborne emissions data. Revision 2

    SciTech Connect (OSTI)

    Frazier, T.P.

    1995-12-01

    This Quality Assurance Project Plan addresses the quality assurance requirements for compiling Hanford Site radioactive airborne emissions data. These data will be reported to the U.S. Environmental Protection Agency, the US Department of Energy, and the Washington State Department of Health. Effluent Monitoring performs compliance assessments on radioactive airborne sampling and monitoring systems. This Quality Assurance Project Plan is prepared in compliance with interim guidelines and specifications. Topics include: project description; project organization and management; quality assurance objectives; sampling procedures; sample custody; calibration procedures; analytical procedures; monitoring and reporting criteria; data reduction, verification, and reporting; internal quality control; performance and system audits; corrective actions; and quality assurance reports.

  18. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines

    SciTech Connect (OSTI)

    Hall, Matt; Matthews, Ron

    2011-09-30

    The goal of the research was to refine and complete development of an on-board particulate matter (PM) sensor for diesel, DISI, and HCCI engines, bringing it to a point where it could be commercialized and marketed.

  19. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

    1994-08-01

    The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

  20. Engine-External HC-Dosing for Regeneration of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to ...

  1. Monitoring and Control of Alkali Volatilization and Batch Carryover for Minimization of Particulates and Crown Corrosion

    SciTech Connect (OSTI)

    2001-01-01

    New Technology will Allow Glass Manufacturers to Optimize Furnace Conditions. Laser-induced breakdown spectroscopy is a continuous monitoring technique that glass manufacturers can use to reduce particulate matter emissions and extend furnace life.

  2. Optical backscatter probe for sensing particulate in a combustion gas stream

    DOE Patents [OSTI]

    Parks, James E; Partridge, William P

    2013-05-28

    A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

  3. Imaging of Diesel Particulate Filters using a High-Flux Neutron Source |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified inside automotive DPFs using neutrons show how the deposits of soot, ash, and washcoat occurs within the filter. PDF icon p-14_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Non-Destructive Neutron

  4. Evaluation of Passive and Active Soot Filters for Removal of Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Diesel Engines | Department of Energy Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines 2002 DEER Conference Presentation: Cummins, Inc. PDF icon 2002_deer_bunting.pdf More Documents & Publications Exhaust Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Active Soot Filter Regeneration Development and Field

  5. Development of SCR on Diesel Particulate Filter System for Heavy Duty

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy SCR on Diesel Particulate Filter System for Heavy Duty Applications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Evaluation of a system consisting of SCRDPF in comparison to a commercial 2010 CDPF system on an engine under high and low engine-out NOx conditions PDF icon deer12_naseri.pdf More Documents & Publications Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF SCR-DPF Integrations

  6. Development of an Accelerated Ash-Loading Protocol for Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_bunting_2.pdf More Documents & Publications

  7. Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Traps | Department of Energy Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_vanderwal.pdf More Documents &

  8. Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.

    SciTech Connect (OSTI)

    Lee, K. O.; Zhu, J.; Ciatti, S.; Choi, M. Y.; Energy Systems; Drexel Univ.

    2003-01-01

    The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes significantly. Bigger primary particles were measured at higher EGR rates, higher equivalence ratios (fuel-rich), and lower exhaust temperatures. Fractal dimensions (D{sup f}) were measured at a range of 1.5 - 1.7, which are smaller than those measured for heavy-duty direct-injection diesel engine particulates in our previous study. This finding implies that the light-duty diesel engine used in this study produces more stretched chain-like shape particles, while the heavy-duty diesel engine emits more spherical particles. The microstructures of diesel particulates were observed at high TEM magnifications and further analyzed by a Raman spectroscope. Raman spectra revealed an atomic structure of the particulates produced at high engine loads, which is similar to that of typical graphite.

  9. Advances in controlling particulate emissions from fossil-fired power plants

    SciTech Connect (OSTI)

    Chang, R.

    1995-12-31

    Present and possible future Federal, state, and local air pollutant emission regulations coupled with an increasingly competitive business environment and the aging of existing particulate control equipment are motivating utilities to improve particulate control system effectiveness and reduce control cost. To these ends, several cost-effective means of improving particulate control are being developed and tested. Three fossil plant retrofit technologies of note include two flue gas conditioning systems--one ``agentless`` arrangement that uses the SO{sub 2} in the flue gas as the raw material for an SO{sub 3} conditioning system, and a promising new additive that has performed well in laboratory and pilot-scale tests. A second retrofit technology supplements all or most of the existing electrostatic precipitator with a pulse-jet baghouse. A third approach described in this paper is one example of a new class of advanced filtration systems, some of which can remove NO{sub x} and particulate in the same vessel. Technologies like these will enable utilities to boost particulate removal effectiveness after switching to lower-sulfur coal for Clean Air Act compliance, minimize compliance costs, and optimally position themselves for possible further emission regulations.

  10. Plasma regenerated particulate trap and NO.sub.x reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01

    A non-catalytic two-stage process for removal of NO.sub.x and particulates from engine exhaust comprises a first stage that plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, and a second stage, which preferably occurs simultaneously with the first stage, that converts NO.sub.2 and carbon soot particles to respective environmentally benign gases that include N.sub.2 and CO.sub.2. By preconverting NO to NO.sub.2 in the first stage, the efficiency of the second stage for NO.sub.x reduction is enhanced while carbon soot from trapped particulates is simultaneously converted to CO.sub.2 when reacting with the NO.sub.2 (that converts to N.sub.2). For example, an internal combustion engine exhaust is connected by a pipe to a chamber where carbon-containing particulates are electrostatically trapped or filtered and a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. Volatile hydrocarbons (C.sub.x H.sub.y) from the trapped particulates are oxidized in the plasma and the remaining soot from the particulates reacts with the NO.sub.2 to convert NO.sub.2 to N.sub.2, and the soot to CO.sub.2. The nitrogen exhaust components remain in the gas phase throughout the process, with no accompanying adsorption.

  11. Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate

    SciTech Connect (OSTI)

    Strzelec, Andrea; Toops, Todd J; Daw, C Stuart

    2011-01-01

    We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

  12. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  13. Device and method for accurately measuring concentrations of airborne transuranic isotopes

    DOE Patents [OSTI]

    McIsaac, C.V.; Killian, E.W.; Grafwallner, E.G.; Kynaston, R.L.; Johnson, L.O.; Randolph, P.D.

    1996-09-03

    An alpha continuous air monitor (CAM) with two silicon alpha detectors and three sample collection filters is described. This alpha CAM design provides continuous sampling and also measures the cumulative transuranic (TRU), i.e., plutonium and americium, activity on the filter, and thus provides a more accurate measurement of airborne TRU concentrations than can be accomplished using a single fixed sample collection filter and a single silicon alpha detector. 7 figs.

  14. DOE/SC-ARM-15-032 ARM-ACME V: ARM Airborne Carbon

    Office of Scientific and Technical Information (OSTI)

    32 ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska Science and Implementation Plan S Biraud May 2015 CLIMATE RESEARCH FACILITY DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product,

  15. ARM Airborne Carbon Measurements VI (ARM-ACME V) Science Plan

    Office of Scientific and Technical Information (OSTI)

    s. DEPARTMENT OF CD ENERGY Office of Science DOE/SC-ARM-15-047 ARM Airborne Carbon Measurements VI (ACME VI) Science Plan S Biraud December 2015 CLIMATE RESEARCH FACILITY DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information,

  16. Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities, Volume 1

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TS NOT MEASUREMENT SENSITIVE DOE-HDBK-3010-94 December 1994 Reaffirmed 2013 DOE HANDBOOK AIRBORNE RELEASE FRACTIONS/RATES AND RESPIRABLE FRACTIONS FOR NONREACTOR NUCLEAR FACILITIES Volume I - Analysis of Experimental Data U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of

  17. Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities, Volume II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TS NOT MEASUREMENT SENSITIVE DOE-HDBK-3010-94 December 1994 Reaffirmed 2013 DOE HANDBOOK AIRBORNE RELEASE FRACTIONS/RATES AND RESPIRABLE FRACTIONS FOR NONREACTOR NUCLEAR FACILITIES Volume II - Appendices U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical

  18. ARM Airborne Carbon Measurements VI (ARM-ACME V) Science Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 ARM Airborne Carbon Measurements VI (ACME VI) Science Plan S Biraud December 2015 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe

  19. Device and method for accurately measuring concentrations of airborne transuranic isotopes

    DOE Patents [OSTI]

    McIsaac, Charles V. (Idaho Falls, ID); Killian, E. Wayne (Idaho Falls, ID); Grafwallner, Ervin G. (Arco, ID); Kynaston, Ronnie L. (Blackfoot, ID); Johnson, Larry O. (Pocatello, ID); Randolph, Peter D. (Idaho Falls, ID)

    1996-01-01

    An alpha continuous air monitor (CAM) with two silicon alpha detectors and three sample collection filters is described. This alpha CAM design provides continuous sampling and also measures the cumulative transuranic (TRU), i.e., plutonium and americium, activity on the filter, and thus provides a more accurate measurement of airborne TRU concentrations than can be accomplished using a single fixed sample collection filter and a single silicon alpha detector.

  20. Geophex Airborne Unmanned Survey System (GAUSS). Topical report, October 1993--March 1995

    SciTech Connect (OSTI)

    1995-03-01

    The objectives of the project are to construct a geophysical sensor system based on a remotely operated model helicopter (ROH) and to evaluate the efficacy of the system for characterization of hazardous environmental sites. Geophex Airborne Unmanned Survey System (GAUSS) is a geophysical survey system that uses a ROH as the survey vehicle. We have selected the ROH because of its advantages over fixed wing and ground based vehicles. Lower air speed and superior maneuverability of the ROH make it better suited for geophysical surveys than a fixed wing model aircraft. The ROH can fly close to the ground, allowing detection of weak or subtle anomalies. Unlike ground based vehicles, the ROH can traverse difficult terrain while providing a stable sensor platform. ROH does not touch the ground during the course of a survey and is capable of functioning over water and surf zones. The ROH has been successfully used in the motion picture industry and by geology companies for payload bearing applications. The only constraint to use of the airborne system is that the ROH must remain visible to the pilot. Obstructed areas within a site can be characterized by relocating the base station to alternate positions. GAUSS consists of a ROH with radio controller, a data acquisition and processing (DAP) system, and lightweight digital sensor systems. The objective of our Phase I research was to develop a DAP and sensors suitable for ROH operation. We have constructed these subsystems and integrated them to produce an automated, hand-held geophysical surveying system, referred to as the ``pre-prototype``. We have performed test surveys with the pre-prototype to determine the functionality of the and DAP and sensor subsystems and their suitability for airborne application. The objective of the Phase II effort will be to modify the existing subsystems and integrate them into an airborne prototype. Efficacy of the prototype for geophysical survey of hazardous sites will then be determined.

  1. Airborne megawatt class free-electron laser for defense and security

    SciTech Connect (OSTI)

    Roy Whitney; David Douglas; George Neil

    2005-03-01

    An airborne megawatt (MW) average power Free-Electron Laser (FEL) is now a possibility. In the process of shrinking the FEL parameters to fit on ship, a surprisingly lightweight and compact design has been achieved. There are multiple motivations for using a FEL for a high-power airborne system for Defense and Security: Diverse mission requirements can be met by a single system. The MW of light can be made available with any time structure for time periods from microseconds to hours, i.e. there is a nearly unlimited magazine. The wavelength of the light can be chosen to be from the far infrared (IR) to the near ultraviolet (UV) thereby best meeting mission requirements. The FEL light can be modulated for detecting the same pattern in the small fraction of light reflected from the target resulting in greatly enhanced targeting control. The entire MW class FEL including all of its subsystems can be carried by large commercial size airplanes or on an airship. Adequate electrical power can be generated on the plane or airship to run the FEL as long as the plane or airship has fuel to fly. The light from the FEL will work well with relay mirror systems. The required R&D to achieve the MW level is well understood. The coupling of the capabilities of an airborne FEL to diverse mission requirements provides unique opportunities.

  2. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  3. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  4. Method for the Removal of Ultrafine Particulates from an Aqueous Suspension

    SciTech Connect (OSTI)

    Chaiko, David J.; Kopasz, John P.; Ellison, Adam J.G.

    1999-03-05

    A method of separating ultra-fine particulate from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel-containing the particulate, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  5. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F | Department of Energy Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F 2003 DEER Conference Presentation: Centers for Disease Control and

  6. Method for the removal of ultrafine particulates from an aqueous suspension

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL); Kopasz, John P. (Bolingbrook, IL); Ellison, Adam J. G. (Corning, NY)

    2000-01-01

    A method of separating ultra-fine particulates from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel containing the particulates, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  7. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_depetrillo.pdf More Documents & Publications Active Diesel Emission Control Technology for Sub-50 HP Engines with Low Exhaust Temperature Profiles

  8. MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY

    National Nuclear Security Administration (NNSA)

    MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY DATA REPORT FOR 1989 AND 1990 WBS No. 1.2.5.4.2 Contract No. DE-AC08-87NVl0576 March 1992 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services Las Vegas, Nevada 1.0 MECUTIVE SUMMARY Routine particulate matter ambient air quality monitoring has been performed at two stations in the Yucca Mountain air monitoring network since the spring

  9. NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991

    National Nuclear Security Administration (NNSA)

    NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991 WBS No. 1.2.13.4.2 Contract No. DE-ACO8-87NV10576 Oc tobe r 199 2 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services L a s Vegas, Nevada TABLE OF CONTENTS m Section 1. Executive Summary 2. 3. Results Particulate Matter Ambient Air Quality Monitoring Methods List of Tables 1-1 3-1 3-2 3-3 3-4 3-5 3-6 Page 1-1 2-1 3-1

  10. Controlling particulates, temperature, and tritium in an inert glovebox for a weapons program

    SciTech Connect (OSTI)

    Purson, J.D.; Powers, D.; Walthers, C.; Navarro, C.; Newman, E.; Romero, J.; Jenkins, R.

    1996-07-01

    A glovebox is described in which several environmental parameters are controlled and monitored. Included in these are particulate, tritium, water vapor, oxygen and temperature. The paper details the design rationale and process and describes the glovebox, presently in use for neutron generator production.

  11. Methods of hydrolyzing pretreated densified biomass particulates and systems related thereto

    DOE Patents [OSTI]

    Bals, Bryan; Teymouri, Farzaneh; Campbell, Tim; Dale, Bruce

    2015-02-03

    A method is provided in which pretreated and densified cellulosic biomass particulates can be hydrolyzed at a high solids loading rate as compared with the solids loading rate of loose hydrolysable cellulosic biomass fibers. The resulting high concentration sugar-containing stream can be easily converted to biofuels or an entire suite of other useful bioproducts.

  12. Diesel Particulate Filters and NO2 Emission Limits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters and NO2 Emission Limits Diesel Particulate Filters and NO2 Emission Limits EPAs New air quality standards for NO2 will impact future DPF designs PDF icon deer09_ibrahim.pdf More Documents & Publications RYPOS - An Actively Regenerated DPF that Demonstrates Significant NO2 Reduction Emission Controls for Heavy-Duty Trucks RYPOS Trap Field Demonstrations Part 1

  13. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  14. INTERPRETATION OF AIRBORNE ELECTROMAGNETIC AND MAGNETIC DATA IN THE 600 AREA

    SciTech Connect (OSTI)

    CUMMINS GD

    2010-11-11

    As part of the 200-PO-1 Phase I geophysical surveys, Fugro Airborne Surveys was contracted to collect airborne electromagnetic (EM) and magnetic surveys of the Hanford Site 600 Area. Two helicopter survey systems were used with the HeliGEOTEM{reg_sign} time domain portion flown between June 19th and June 20th, 2008, and the RESOLVE{reg_sign} frequency domain portion was flown from June 29th to July 1st, 2008. Magnetic data were acquired contemporaneously with the electromagnetic surveys using a total-field cesium vapor magnetometer. Approximately 925 line kilometers (km) were flown using the HeliGEOTEM{reg_sign} II system and 412 line kilometers were flown using the RESOLVE{reg_sign} system. The HeliGEOTEM system has an effective penetration of roughly 250 meters into the ground and the RESOLVE system has an effective penetration of roughly 60 meters. Acquisition parameters and preliminary results are provided in SGW-39674, Airborne Electromagnetic Survey Report, 200-PO-1 Groundwater Operable Unit, 600 Area, Hanford Site. Airborne data are interpreted in this report in an attempt to identify areas of likely preferential groundwater flow within the aquifer system based on the presence of paleochannels or fault zones. The premise for the interpretation is that coarser-grained intervals have filled in scour channels created by episodic catastrophic flood events during the late Pleistocene. The interpretation strategy used the magnetic field anomaly data and existing bedrock maps to identify likely fault or lineament zones. Combined analysis of the magnetic, 60-Hz noise monitor, and flight-altitude (radar) data were used to identify zones where EM response is more likely due to cultural interference and or bedrock structures. Cross-sectional and map view presentations of the EM data were used to identify more electrically resistive zones that likely correlate with coarser-grained intervals. The resulting interpretation identifies one major northwest-southeast trending preferential flowpath with several minor units running along a similar trend. This presumed path of preferential flow is compared with the tritium concentration levels observed for the 600 Area. Analysis of the magnetic field data shows the location of potential bedrock faults and lineaments which may influence the horizontal and vertical flow of water. Faults lying within, or in the vicinity of preferential groundwater flow paths may allow flow into or out of the otherwise confined basalt layers.

  15. DOE/SC-ARM-15-032 ARM-ACME V: ARM Airborne Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SC-ARM-15-032 ARM-ACME V: ARM Airborne Carbon Measurements V on the North Slope of Alaska Science and Implementation Plan S Biraud May 2015 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process

  16. "Airborne Wind Energy - Harnessing a Vast, Untapped Renewable Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Source" | Princeton Plasma Physics Lab November 14, 2012, 4:15pm Colloquia MBG Auditorium "Airborne Wind Energy - Harnessing a Vast, Untapped Renewable Energy Source" Dr. Kenneth Jensen Makani Power Inc. At just 500 m above the ground, the average power density of the wind is double that at 100 m where wind turbines typically reside. This makes high-altitude wind one of the most concentrated forms of renewable energy after hydro-power. Building conventional wind turbines at

  17. INSIGHTS FROM LABORATORY AND AIRBORNE BRDF MEASUREMENTS FOR SATELLITE REMOTE SENSING

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosols and Surface Optical Properties from Airborne Spectral Measurements of Directional Reflectance C.K.Gatebe 1,2 & M.D. King, 2,3 Collaborators: O. Dubovik, 4 A.Sinyuk, 2,5 P. Russell, 6 J. Redemann 6 Acknowledgements: G.T. Arnold (SSAI & GSFC) Gala Wind (SSAI & GSFC) Rajesh Poudyal (SSAI & GSFC) Hal Maring & Andy Roberts (NASA HQ) 1 University of Maryland, Baltimore County 2 NASA Goddard Space Flight Center 3 University of Colorado 4 Laboratoire d'Optique Atmosphérique

  18. Method of making polymer powders and whiskers as well as particulate products of the method and atomizing apparatus

    DOE Patents [OSTI]

    Otaigbe, Joshua U.; McAvoy, Jon M.; Anderson, Iver E.; Ting, Jason; Mi, Jia; Terpstra, Robert

    2001-01-09

    Method for making polymer particulates, such as spherical powder and whiskers, by melting a polymer material under conditions to avoid thermal degradation of the polymer material, atomizing the melt using gas jet means in a manner to form atomized droplets, and cooling the droplets to form polymer particulates, which are collected for further processing. Atomization parameters can be controlled to produce polymer particulates with controlled particle shape, particle size, and particle size distribution. For example, atomization parameters can be controlled to produce spherical polymer powders, polymer whiskers, and combinations of spherical powders and whiskers. Atomizing apparatus also is provided for atoomizing polymer and metallic materials.

  19. Airborne release fractions/rates and respirable fractions for nonreactor nuclear facilities. Volume 1, Analysis of experimental data

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    This handbook contains (1) a systematic compilation of airborne release and respirable fraction experimental data for nonreactor nuclear facilities, (2) assessments of the data, and (3) values derived from assessing the data that may be used in safety analyses when the data are applicable. To assist in consistent and effective use of this information, the handbook provides: identification of a consequence determination methodology in which the information can be used; discussion of the applicability of the information and its general technical limits; identification of specific accident phenomena of interest for which the information is applicable; and examples of use of the consequence determination methodology and airborne release and respirable fraction information.

  20. Emergency Response Equipment and Related Training: Airborne Radiological Computer System (Model II)

    SciTech Connect (OSTI)

    David P. Colton

    2007-02-28

    The materials included in the Airborne Radiological Computer System, Model-II (ARCS-II) were assembled with several considerations in mind. First, the system was designed to measure and record the airborne gamma radiation levels and the corresponding latitude and longitude coordinates, and to provide a first overview look of the extent and severity of an accident's impact. Second, the portable system had to be light enough and durable enough that it could be mounted in an aircraft, ground vehicle, or watercraft. Third, the system must control the collection and storage of the data, as well as provide a real-time display of the data collection results to the operator. The notebook computer and color graphics printer components of the system would only be used for analyzing and plotting the data. In essence, the provided equipment is composed of an acquisition system and an analysis system. The data can be transferred from the acquisition system to the analysis system at the end of the data collection or at some other agreeable time.

  1. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  2. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

    1995-01-01

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  3. Apparatus and method for removing particulate deposits from high temperature filters

    DOE Patents [OSTI]

    Nakaishi, Curtis V.; Holcombe, Norman T.; Micheli, Paul L.

    1992-01-01

    A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

  4. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  5. Method of producing particulate-reinforced composites and composties produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intenisty acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaciton products comprise a solide particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particles-reinforced composite materials produced by such a process.

  6. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, R.F.; Brown, J.D.; Andriulli, J.B.; Strain, P.D.

    1998-09-08

    A method is described for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector. 1 fig.

  7. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Andriulli, John B. (Kingston, TN); Strain, Paul D. (Eads, TN)

    1998-01-01

    A method for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector.

  8. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2015-12-29

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  9. Operating Experience Level 3, Update to Requalification Test Failure of Certain High Efficiency Particulate Air (HEPA) Filters

    Broader source: Energy.gov [DOE]

    Operating Experience Level 3 (OE-3) document provides information regarding the previous requalification test failure and subsequent successful requalification, of certain high efficiency particulate air (HEPA) Filters models manufactured by Flanders Corporation.

  10. Engine gaseous, aerosol precursor and particulate at simulated flight altitude conditions. Technical memo

    SciTech Connect (OSTI)

    Wey, C.C.

    1998-10-01

    The overall objective of the NASA Atmospheric Effects of Aviation Project (AEAP) is to develop scientific bases for assessing atmospheric impacts of the exhaust emissions by both current and future fleets of subsonic and supersonic aircraft. Among the six primary elements of the AEAP is Emissions Characterization. The objective of the Emission Characterization effort is to determine the exhaust emission constituents and concentrations at the engine exit plane. The specific objective of this engine test is to obtain a database of gaseous and particulate emissions as a function of fuel sulfur and engine operating conditions. The database of the particulate emission properties is to be used as a comparative baseline with subsequent flight measurement. The engine used in this test was a Pratt and Whitney F100-200E turbofan engine. Aviation fuel (Jet A) with a range of fuel sulfur was used. Low and high sulfur values are limited by commercially available fuels and by fuel specification limits of 0.3% by weight. Test matrix was set by parametrically varying the combustor inlet temperature (T3) between idle and maximum power setting at simulated SLS and up to five other altitudes for each fuel. Four diagnostic systems, extractive and non-intrusive, were assembled for the gaseous and particulate emissions characterization measurements study. NASA extractive system includes smoke meter and analyzers for measurement of CO, CO{sub 2}, NO, NOx, O{sub 2}, total unburnt hydrocarbons (THC), and SO{sub 2}. Particulate emissions were characterized by University of Missouri-Rolla Mobile Aerosol Sampling System.

  11. Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Filter Technology for Low-Temperature and Low-NOx/PM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM Applications 2004 DEER Conference Presentation: Johnson-Matthey Catalysts PDF icon 2004_deer_chatterjee.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 Aftertreatment Modeling Status, Futur Potential, and

  12. Development of Optical Technologies for Monitoring Moisture and Particulate in Geothermal Steam

    SciTech Connect (OSTI)

    J. K. Partin

    2006-08-01

    The results of an investigation directed at evaluating the feasibility of using optical measurements for the real-time monitoring moisture and particulate in geothermal steam is described. The measurements exploit new technologies that have been developed for the telecommunications industry and includes new solid state laser devices, large-bandwidth, high-sensitivity detectors and low loss optical fiber compo-nents. In particular, the design, fabrication, and in-plant testing of an optical steam monitor for the detection of moisture is presented. The measurement principle is based upon the selective absorption of infrared energy in response to the presence of moisture. Typically, two wavelengths are used in the measurements: a wavelength that is strongly absorbed by water and a reference wavelength that is minimally influenced by water and steam which serves as a reference to correct for particulate or droplet scattering. The two wavelengths are chosen to be as close as possible in order to more effectively correct for scattering effects. The basic instrumentation platform developed for the in-situ monitoring of steam moisture can be modified and used to perform other measurements of interest to plant operators. An upgrade that will allow the instrument to be used for the sensitive detection of particulate in process streams has been investigated. The new monitor design involves the use of laser diodes that are much less sensitive to water and water vapor and more sensitive to scattering phenomena, as well as new processing techniques to recover these signals. The design reduces the averaging time and sampling volume, while increasing the laser probe power, enhancing particulate detection sensitivity. The design concept and initial laboratory experiments with this system are also reported.

  13. Light absorption from particulate impurities in snow and ice determined by spectrophotometric analysis of filters

    SciTech Connect (OSTI)

    Grenfell, Thomas C.; Doherty, Sarah J.; Clarke, Antony D.; Warren, Stephen G.

    2011-05-10

    Light absorption by particulate impurities in snow and ice can affect the surface albedo and is important for the climate. The absorption properties of these particles can be determined by collecting and melting snow samples and extracting the particulate material by filtration of the meltwater. This paper describes the optical design and testing of a new instrument to measure the absorption spectrum from 400 to 750 nm wavelength of the particles collected on filters using an ''integrating-sandwich'' configuration. The measured absorption is shown to be unaffected by scattering of light from the deposited particulates. A set of calibration standards is used to derive an upper limit for the concentration of black carbon (BC) in the snow. The wavelength dependence of the absorption spectra from 450 to 600 nm is used to calculate an absorption Angstrom exponent for the aerosol. This exponent is used to estimate the actual BC concentration in the snow samples as well as the relative contributions of BC and non-BC constituents to the absorption of solar radiation integrated over the wavelength band 300 to 750 nm.

  14. The use of a receptor model for fine particulate in Mexico City

    SciTech Connect (OSTI)

    Vega, E.; Garcia, I.; Ruiz, M.E.

    1997-12-31

    Mexico City Metropolitan Area (MCMA) faces severe pollution problems typical of large urban areas all over the world. The city is in an elevated basin (2,240 m) at a subtropical latitude (19.5N), with a high mountain chain at the West and South. This basin setting inhibits dispersion of pollution and contributes to the frequent wintertime thermal inversions which further trap pollutants near the surface. The study of atmospheric pollution and its control have been carried out using physico-chemical dispersion models, and the type known as receptor models often finds favor. The main objective of this paper is to present the results of a chemical mass balance receptor model applied to two different data sets of particulate matter. The twelve-hour samples were collected during day and night periods in the winter of 1989, previous to the introduction of catalytic converters in automobiles, and the other after 1991, since the catalytic converters are compulsory in all the new model vehicles. Samples of particulate matter were collected using a denuder and a Hi-Vol systems for the fine fraction (aerosols with diameter less than 2.5 {micro}m) and total suspended particles respectively. The results show that the major source contributions to the inhalable particulate matter for the first period are: automobiles (44%); secondary aerosols (19%); dust (10%).

  15. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I.; Kontaksakis, M.; Glytsos, T.; Kalogerakis, N.; Lazaridis, M.

    2010-11-15

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  16. Quality Assurance Project Plan for radioactive airborne emissions data compilation and reporting

    SciTech Connect (OSTI)

    Burris, S.A.; Thomas, S.P.

    1994-02-01

    This Quality Assurance Project Plan addresses the quality assurance requirements for compiling data from radioactie aiborne emissions. These data will be reported to the US Environmental Protection Agency, the US Department of Energy, and the Washington State Department of Health. Hanford Site radioactive airborne emissions are reported to the US Environmental Protection Agency in compliance with Title 40, Protection of the Environment, Code of Federal Regulations, Part 61, ``National Emissions Standards for Hazardous Air Pollutants , ``Subpart H, ``National Emissions Standards for Emissions of Radionuclides Other Than Radon From Department of Energy Facilities`` (EPA 1989a). Reporting to US Department of Energy is performed in compliance with requirements of US Department of Energy Order 5400.1, General Environmental Protection Program (DOE 1988a).

  17. Geophex Airborne Unmanned Survey System (GAUSS). Topical report, October 1993--September 1996

    SciTech Connect (OSTI)

    1998-12-31

    This document is a Final Technical Report that describes the results of the Geophex Airborne Unmanned Survey System (GAUSS) research project. The objectives were to construct a geophysical data acquisition system that uses a remotely operated unmanned aerial vehicle (UAV) and to evaluate its effectiveness for characterization of hazardous environmental sites. The GAUSS is a data acquisition system that mitigates the potential risk to personnel during geophysical characterization of hazardous or radioactive sites. The fundamental basis of the GAUSS is as follows: (1) an unmanned survey vehicle carries geophysical sensors into a hazardous location, (2) the pilot remains outside the hazardous site and operates the vehicle using radio control, (3) geophysical measurements and their spatial locations are processed by an automated data-acquisition system which displays data on an off-site monitor in real-time, and (4) the pilot uses the display to direct the survey vehicle for complete site coverage. The objective of our Phase I research was to develop a data acquisition and processing (DAP) subsystem and geophysical sensors suitable for UAV deployment. We integrated these two subsystems to produce an automated, hand-held geophysical surveying system. The objective of the Phase II effort was to modify the subsystems and integrate them into an airborne prototype. The completed GAUSS DAP system consists of a UAV platform, a laser tracking and ranging subsystem, a telemetry subsystem, light-weight geophysical sensors, a base-station computer (BC), and custom-written survey control software (SCS). We have utilized off-the-shelf commercial products, where possible, to reduce cost and design time.

  18. Acute changes in pulse pressure in relation to constituents of particulate air pollution in elderly persons

    SciTech Connect (OSTI)

    Jacobs, Lotte; Buczynska, Anna; Walgraeve, Christophe; Delcloo, Andy; Potgieter-Vermaak, Sanja; Molecular Science Institute, School of Chemistry, University of Witwatersrand, Johannesburg; Division of Chemistry and Environmental Science, Manchester Metropolitan University, Manchester ; Van Grieken, Rene; Demeestere, Kristof; Dewulf, Jo; Van Langenhove, Herman; De Backer, Hugo; Nemery, Benoit; Nawrot, Tim S.; Centre for Environmental Sciences, Hasselt University, Diepenbeek

    2012-08-15

    An increased pulse pressure (difference between systolic and diastolic blood pressure) suggests aortic stiffening. The objective of this study was to examine the acute effects of both particulate matter (PM) mass and composition on blood pressure, among elderly persons. We carried out a panel study in persons living in elderly homes in Antwerp, Belgium. We recruited 88 non-smoking persons, 70% women with a mean age of 83 years (standard deviation: 5.2). Blood pressure was measured and a blood sample was collected on two time points, which were chosen so that there was an exposure contrast in ambient PM exposure. The elemental content of the collected indoor and outdoor PM{sub 2.5} (particulate matter with an aerodynamic diameter <2.5 {mu}m) mass concentration was measured. Oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) on outdoor PM{sub 10} (particulate matter with an aerodynamic diameter <10 {mu}m) were measured. Each interquartile range increase of 20.8 {mu}g/m Superscript-Three in 24-h mean outdoor PM{sub 2.5} was associated with an increase in pulse pressure of 4.0 mmHg (95% confidence interval: 1.8-6.2), in persons taking antihypertensive medication (n=57), but not in persons not using antihypertensive medication (n=31) (p for interaction: 0.02). Vanadium, iron and nickel contents of PM{sub 2.5} were significantly associated with systolic blood pressure and pulse pressure, among persons on antihypertensive medication. Similar results were found for indoor concentrations. Of the oxy-PAHs, chrysene-5,6-dione and benzo[a]pyrene-3,6-dione were significantly associated with increases in systolic blood pressure and pulse pressure. In elderly, pulse pressure was positively associated with acute increases in outdoor and indoor air pollution, among persons taking antihypertensive medication. These results might form a mechanistic pathway linking air pollution as a trigger of cardiovascular events.

  19. Particulate emissions from residential wood combustion: Final report: Norteast regional Biomass Program

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The objective of this study was to provide a resource document for the Northeastern states when pursuing the analysis of localized problems resulting from residential wood combustion. Specific tasks performed include assigning emission rates for total suspended particulates (TSP) and benzo(a)pyrene (BaP) from wood burning stoves, estimating the impact on ambient air quality from residential wood combustion and elucidating the policy options available to Northeastern states in their effort to limit any detrimental effects resulting from residential wood combustion. Ancillary tasks included providing a comprehensive review on the relevant health effects, indoor air pollution and toxic air pollutant studies. 77 refs., 11 figs., 25 tabs.

  20. Solid Phase Characterization of Tank 241-AY-102 Annulus Space Particulate

    SciTech Connect (OSTI)

    Cooke, G. A.

    2013-01-30

    The Special Analytical Studies Group at the 222-S Laboratory (222-S) examined the particulate recovered from a series of samples from the annular space of tank 241-AY-102 (AY-102) using solid phase characterization (SPC) methods. These include scanning electron microscopy (SEM) using the ASPEX?1 scanning electron microscope, X-ray diffraction (XRD) using the Rigaku?2 MiniFlex X-ray diffractometer, and polarized light microscopy (PLM) using the Nikon?3 Eclipse Pol optical microscope. The SEM is equipped with an energy dispersive X-ray spectrometer (EDS) to provide chemical information.

  1. Electrically resistive coating for remediation (regeneration) of a diesel particulate filter and method

    DOE Patents [OSTI]

    Phelps, Amanda C.; Kirby, Kevin K.; Gregoire, Daniel J.

    2012-02-14

    A resistively heated diesel particulate filter (DPF). The resistively heated DPF includes a DPF having an inlet surface and at least one resistive coating on the inlet surface. The at least one resistive coating is configured to substantially maintain its resistance in an operating range of the DPF. The at least one resistive coating has a first terminal and a second terminal for applying electrical power to resistively heat up the at least one resistive coating in order to increase the temperature of the DPF to a regeneration temperature. The at least one resistive coating includes metal and semiconductor constituents.

  2. Total Particulate Matter Air Sampling Data (TEOM) from Los Alamos National Laboratory

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    LANL measures the total particulate mass concentration in the air on a routine basis as well as during incidents that may affect ambient air. The collected data is added to the Air Quality Index (AQI). AQI is an index for reporting daily air quality. It tells you how clean or polluted your air is, and what associated health effects might be a concern for you. The AQI focuses on health effects you may experience within a few hours or days after breathing polluted air. EPA calculates the AQI for five major air pollutants regulated by the Clean Air Act.

  3. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications National Solar Thermal Test Facility ... Hydrogen Production Market Transformation Fuel Cells Predictive Simulation of Engines Transportation Energy Consortiums ...

  4. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  5. Loading and Regeneration Analysis of a Diesel Particulate Filter with a Radio Frequency-Based Sensor

    SciTech Connect (OSTI)

    Sappok, Alex; Prikhodko, Vitaly Y; Parks, II, James E

    2010-01-01

    Accurate knowledge of diesel particulate filter (DPF) loading is critical for robust and efficient operation of the combined engine-exhaust aftertreatment system. Furthermore, upcoming on-board diagnostics regulations require on-board technologies to evaluate the status of the DPF. This work describes the application of radio frequency (RF) based sensing techniques to accurately measure DPF soot levels and the spatial distribution of the accumulated material. A 1.9L GM turbo diesel engine and a DPF with an RF-sensor were studied. Direct comparisons between the RF measurement and conventional pressure-based methods were made. Further analysis of the particulate matter loading rates was obtained with a mass-based soot emission measurement instrument (TEOM). Comparison with pressure drop measurements show the RF technique is unaffected by exhaust flow variations and exhibits a high degree of sensitivity to DPF soot loading and good dynamic response. Additional computational and experimental work further illustrates the spatial resolution of the RF measurements. Based on the experimental results, the RF technique shows significant promise for improving DPF control enabling optimization of the combined engine-aftertreatment system for improved fuel economy and extended DPF service life.

  6. Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Parks, II, James E; Prikhodko, Vitaly Y

    2009-01-01

    Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOX and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associated with DPF regeneration. In this study, a SiC DPF was loaded and regenerated on a 1.7-liter 4-cylinder diesel engine operated in conventional and advanced combustion modes at different speed and load conditions. A diesel oxidation catalyst (DOC) and a lean NOX trap (LNT) were also installed in the exhaust stream. Five steady-state speed and load conditions were weighted to estimate Federal Test Procedure (FTP) fuel efficiency. The DPF was loaded using lean-rich cycling with frequencies that resulted in similar levels of NOX emissions downstream of the LNT. The pressure drop across the DPF was measured at a standard point (1500 rpm, 5.0 bar) before and after loading, and a P rise rate was determined for comparison between conventional and advanced combustion modes. Higher PM emissions in conventional combustion resulted in a higher rate of backpressure rise across the DPF at all of the load points leading to more frequent DPF regenerations and higher fuel penalty. The fuel penalty during conventional combustion was 4.2% compared with 3.1% for a mixture of conventional and advanced modes.

  7. Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 1999

    SciTech Connect (OSTI)

    DL Edwards; KD Shields; MJ Sula; MY Ballinger

    1999-09-28

    Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants (NESHAP--US Code of Federal Regulations, Title 40 Part 61, Subpart H). In these assessments, potential unabated offsite doses were evaluated for emission locations at facilities owned by the US Department of Energy and operated by Pacific Northwest National Laboratory (Pacific Northwest) on the Hanford Site. Two of the facilities evaluated, 325 Building Radiochemical Processing Laboratory, and 331 Building Life Sciences Laboratory met state and federal criteria for continuous sampling of airborne radionuclide emissions. One other building, the 3720 Environmental Sciences Laboratory, was recognized as being in transition with the potential for meeting the continuous sampling criteria.

  8. Optimized Field Sampling and Monitoring of Airborne Hazardous Transport Plumes; A Geostatistical Simulation Approach

    SciTech Connect (OSTI)

    Chen, DI-WEN

    2001-11-21

    Airborne hazardous plumes inadvertently released during nuclear/chemical/biological incidents are mostly of unknown composition and concentration until measurements are taken of post-accident ground concentrations from plume-ground deposition of constituents. Unfortunately, measurements often are days post-incident and rely on hazardous manned air-vehicle measurements. Before this happens, computational plume migration models are the only source of information on the plume characteristics, constituents, concentrations, directions of travel, ground deposition, etc. A mobile ''lighter than air'' (LTA) system is being developed at Oak Ridge National Laboratory that will be part of the first response in emergency conditions. These interactive and remote unmanned air vehicles will carry light-weight detectors and weather instrumentation to measure the conditions during and after plume release. This requires a cooperative computationally organized, GPS-controlled set of LTA's that self-coordinate around the objectives in an emergency situation in restricted time frames. A critical step before an optimum and cost-effective field sampling and monitoring program proceeds is the collection of data that provides statistically significant information, collected in a reliable and expeditious manner. Efficient aerial arrangements of the detectors taking the data (for active airborne release conditions) are necessary for plume identification, computational 3-dimensional reconstruction, and source distribution functions. This report describes the application of stochastic or geostatistical simulations to delineate the plume for guiding subsequent sampling and monitoring designs. A case study is presented of building digital plume images, based on existing ''hard'' experimental data and ''soft'' preliminary transport modeling results of Prairie Grass Trials Site. Markov Bayes Simulation, a coupled Bayesian/geostatistical methodology, quantitatively combines soft information regarding contaminant location with hard experimental results. Soft information is used to build an initial conceptual image of where contamination is likely to be. As experimental data are collected and analyzed, indicator kriging is used to update the initial conceptual image. The sequential Gaussian simulation is then practiced to make a comparison between the two simulations. Simulated annealing is served as a postprocessor to improve the result of Markov Bayes simulation or sequential Gaussian simulation.

  9. ARM Airborne Carbon Measurements (ARM-ACME) and ARM-ACME 2.5 Final Campaign Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 ARM Airborne Carbon Measurements (ARM-ACME) and ARM-ACME 2.5 Final Campaign Reports SC Biraud MS Torn January 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents

  10. DOE-HDBK-3010-94; Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities, Volume II

    Office of Environmental Management (EM)

    3010-94 December 1994 DOE HANDBOOK AIRBORNE RELEASE FRACTIONS/RATES AND RESPIRABLE FRACTIONS FOR NONREACTOR NUCLEAR FACILITIES Volume II - Appendices U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O. Box 62, Oak Ridge, TN 37831; (615)

  11. DOE-HDBK-3010-94; Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities

    National Nuclear Security Administration (NNSA)

    SENSITIVE DOE-HDBK-3010-94 December 1994 DOE HANDBOOK AIRBORNE RELEASE FRACTIONS/RATES AND RESPIRABLE FRACTIONS FOR NONREACTOR NUCLEAR FACILITIES Volume I - Analysis of Experimental Data U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information, P.O.

  12. Results of Self-Absorption Study on the Versapor 3000 Filters for Radioactive Particulate Air Sampling

    SciTech Connect (OSTI)

    Barnett, J. M.; Cullinan, Valerie I.; Barnett, Debra S.; Trang-Le, Truc LT; Bliss, Mary; Greenwood, Lawrence R.; Ballinger, Marcel Y.

    2009-02-17

    Since the mid-1980s, Pacific Northwest National Laboratory (PNNL) has used a value of 0.85 as the correction factor for self absorption of activity for particulate radioactive air samples collected from building exhaust for environmental monitoring. This value accounts for activity that cannot be detected by direct counting of alpha and beta particles. Emissions can be degraded or blocked by filter fibers for particles buried in the filter material or by inactive dust particles collected with the radioactive particles. These filters are used for monitoring air emissions from PNNL stacks for radioactive particles. This paper describes an effort to re-evaluate self-absorption effects in particulate radioactive air sample filters (Versapor 3000, 47 mm diameter) used at PNNL. There were two methods used to characterize the samples. Sixty samples were selected from the archive for acid digestion to compare the radioactivity measured by direct gas-flow proportional counting of filters to the results obtained after acid digestion of the filter and counting again by gas-flow proportional detection. Thirty different sample filters were selected for visible light microscopy to evaluate filter loading and particulate characteristics. Mass-loading effects were also considered. Filter ratios were calculated by dividing the initial counts by the post-digestion counts with the expectation that post-digestion counts would be higher because digestion would expose radioactivity embedded in the filter in addition to that on top of the filter. Contrary to expectations, the post digestion readings were almost always lower than initial readings and averaged approximately half the initial readings for both alpha and beta activity. Before and after digestion readings appeared to be related to each other, but with a low coefficient of determination (R^2) value. The ratios had a wide range of values indicating that this method did not provide sufficient precision to quantify self-absorption effects. The microscopy analysis compares different filter loadings and shows that smaller particle sizes (under 10 micron) can readily be seen on the more lightly loaded filters. At higher loadings, however, the particle size is harder to differentiate. This study provides data on actual stack emission samples showing a range of mass loading conditions and visual evidence of particle size and distribution and also presents the difficulties in quantifying self-absorption effects using actual samples.

  13. Cross-flow, filter-sorbent catalyst for particulate, SO sub 2 and NO sub x control

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    This synopsis describes a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particulate filter, an SO{sub 2} sorbent, and a NO{sub x} reduction catalyst.

  14. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

    1988-01-01

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

  15. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, D.O.; Alexeff, I.; Sikka, V.K.

    1987-08-10

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

  16. Variable power distribution for zoned regeneration of an electrically heated particulate filter

    DOE Patents [OSTI]

    Bhatia, Garima [Bangalore, IN; Gonze, Eugene V [Pinckney, MI

    2012-04-03

    A system includes a particulate matter (PM) filter with multiple zones, an electric heater and a control module. The electrical heater includes heater segments, which each correspond with a respective one of the zones. The electrical heater is arranged upstream from and is proximate with the PM filter. The control module selectively applies a first energy level to a first one of the zones via a first one of the heater segments to initiate regeneration in the first zone. The control module also selectively applies a second energy level that is less than the first energy level to a second one of the zones via a second one of the heater segments to initiate regeneration in the second zone.

  17. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D; Lewis Sr, Samuel Arthur; Lee, Doh-Won; Huff, Shean P; Storey, John Morse; Swartz, Matthew M; Wagner, Robert M

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  18. Real-Time Airborne Gamma-Ray Background Estimation Using NASVD with MLE and Radiation Transport for Calibration

    SciTech Connect (OSTI)

    Kulisek, Jonathan A.; Schweppe, John E.; Stave, Sean C.; Bernacki, Bruce E.; Jordan, David V.; Stewart, Trevor N.; Seifert, Carolyn E.; Kernan, Warnick J.

    2015-06-01

    Helicopter-mounted gamma-ray detectors can provide law enforcement officials the means to quickly and accurately detect, identify, and locate radiological threats over a wide geographical area. The ability to accurately distinguish radiological threat-generated gamma-ray signatures from background gamma radiation in real time is essential in order to realize this potential. This problem is non-trivial, especially in urban environments for which the background may change very rapidly during flight. This exacerbates the challenge of estimating background due to the poor counting statistics inherent in real-time airborne gamma-ray spectroscopy measurements. To address this, we have developed a new technique for real-time estimation of background gamma radiation from aerial measurements. This method is built upon on the noise-adjusted singular value decomposition (NASVD) technique that was previously developed for estimating the potassium (K), uranium (U), and thorium (T) concentrations in soil post-flight. The method can be calibrated using K, U, and T spectra determined from radiation transport simulations along with basis functions, which may be determined empirically by applying maximum likelihood estimation (MLE) to previously measured airborne gamma-ray spectra. The method was applied to both measured and simulated airborne gamma-ray spectra, with and without man-made radiological source injections. Compared to schemes based on simple averaging, this technique was less sensitive to background contamination from the injected man-made sources and may be particularly useful when the gamma-ray background frequently changes during the course of the flight.

  19. Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2010

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.; Gervais, Todd L.; Barnett, J. M.

    2011-05-13

    Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants ([NESHAP]; U.S. Code of Federal Regulations, Title 40, Part 61, Subpart H) and Washington Administrative Code 246-247: Radiation Protection - Air Emissions. In these NESHAP assessments, potential unabated off-site doses were evaluated for emission locations at buildings that are part of the consolidated laboratory campus of the Pacific Northwest National Laboratory. This report describes the inventory-based methods and provides the results for the NESHAP assessment performed in 2010.

  20. Calculation of aerosol backscatter from airborne continuous wave focused CO sub 2 Doppler lidar measurements. 1. Algorithm description

    SciTech Connect (OSTI)

    Rothermel, J. ); Bowdle, D.A. ); Vaughan, J.M.; Brown, D.W. ); Woodfield, A.A. )

    1991-03-20

    Since 1981 the Royal Signals and Radar Establishment and the Royal Aircraft Establishment, United Kingdom, have made vertical and horizontal sounding measurements of aerosol backscatter coefficients at 10.6 {mu}m using an airborne continuous wave focused CO{sub 2} Doppler lidar, the Laser True Airspeed System (LATAS). The heterodyne signal from the LATAS detector is spectrally analyzed. Then, in conjunction with aircraft flight parameters, the data are processed in a six-stage computer algorithm: Set search window, search for peak signal, test peak signal, measure total signal, calculate signal-to-noise ratio (SNR), and calculate backscatter coefficient.

  1. Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2007

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.; Barfuss, Brad C.; Gervais, Todd L.

    2008-01-01

    Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants (NESHAP U.S. Code of Federal Regulations, Title 40, Part 61, Subpart H) and Washington Administrative Code (WAC) 246-247: Radiation Protection Air Emissions. In these NESHAP assessments, potential unabated offsite doses were evaluated for emission locations at buildings that are part of the consolidated laboratory campus of the Pacific Northwest National Laboratory. This report describes the inventory-based methods and provides the results for the NESHAP assessment performed in 2007.

  2. Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2001

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.; Sula, Monte J.; Gervais, Todd L.; Shields, Keith D.; Edwards, Daniel R.

    2001-09-28

    Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants (NESHAP - U.S. Code of Federal Regulations, Title 40 Part 61, Subpart H) and Washington Administrative Code (WAC) 246-247: Radiation Protection - Air Emissions. In these assessments, potential unabated offsite doses were evaluated for emission locations at facilities owned by the U.S. Department of Energy and operated by Pacific Northwest National Laboratory (PNNL) on the Hanford Site. This report describes the inventory-based methods, and provides the results, for the assessment performed in 2001.

  3. Assessment of Unabated Facility Emission Potentials for Evaluating Airborne Radionuclide Monitoring Requirements at Pacific Northwest National Laboratory - 2003

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.; Sula, Monte J.; Gervais, Todd L.; Edwards, Daniel L.

    2003-12-05

    Assessments were performed to evaluate compliance with the airborne radionuclide emission monitoring requirements in the National Emission Standards for Hazardous Air Pollutants (NESHAP - U.S. Code of Federal Regulations, Title 40, Part 61, Subpart H) and Washington Administrative Code (WAC) 246-247: Radiation Protection - Air Emissions. In these assessments, potential unabated offsite doses were evaluated for emission locations at facilities owned by the U.S. Department of Energy and operated by Pacific Northwest National Laboratory (PNNL) on the Hanford Site. This report describes the inventory-based methods and provides the results for the assessment performed in 2003.

  4. Final Report DE-EE0005380 Assessment of Offshore Wind Farm Effects on Sea Surface, Subsurface and Airborne Electronic Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    UNIVERSITY OF TEXAS AT AUSTIN Final Report DE-EE0005380 Assessment of Offshore Wind Farm Effects on Sea Surface, Subsurface and Airborne Electronic Systems Prepared for: U.S. Department of Energy Prepared by: Hao Ling (UT) Mark F. Hamilton (ARL:UT) Rajan Bhalla (SAIC) Walter E. Brown (ARL:UT) Todd A. Hay (ARL:UT) Nicholas J. Whitelonis (UT) Shang-Te Yang (UT) Aale R. Naqvi (UT) 9/30/2013 DE-EE0005380 The University of Texas at Austin ii Notice and Disclaimer This report is being disseminated by

  5. Processing and Protection of Rare Earth Permanent Magnet Particulate for Bonded Magnet Applications

    SciTech Connect (OSTI)

    Peter Kelly Sokolowski

    2007-12-01

    Rapid solidification of novel mixed rare earth-iron-boron, MRE{sub 2}Fe{sub 14}B (MRE = Nd, Y, Dy; currently), magnet alloys via high pressure gas atomization (HPGA) have produced similar properties and structures as closely related alloys produced by melt spinning (MS) at low wheel speeds. Recent additions of titanium carbide and zirconium to the permanent magnet (PM) alloy design in HPGA powder (using He atomization gas) have made it possible to achieve highly refined microstructures with magnetic properties approaching melt spun particulate at cooling rates of 10{sup 5}-10{sup 6}K/s. By producing HPGA powders with the desirable qualities of melt spun ribbon, the need for crushing ribbon was eliminated in bonded magnet fabrication. The spherical geometry of HPGA powders is more ideal for processing of bonded permanent magnets since higher loading fractions can be obtained during compression and injection molding. This increased volume loading of spherical PM powder can be predicted to yield a higher maximum energy product (BH){sub max} for bonded magnets in high performance applications. Passivation of RE-containing powder is warranted for the large-scale manufacturing of bonded magnets in applications with increased temperature and exposure to humidity. Irreversible magnetic losses due to oxidation and corrosion of particulates is a known drawback of RE-Fe-B based alloys during further processing, e.g. injection molding, as well as during use as a bonded magnet. To counteract these effects, a modified gas atomization chamber allowed for a novel approach to in situ passivation of solidified particle surfaces through injection of a reactive gas, nitrogen trifluoride (NF{sub 3}). The ability to control surface chemistry during atomization processing of fine spherical RE-Fe-B powders produced advantages over current processing methodologies. In particular, the capability to coat particles while 'in flight' may eliminate the need for post atomization treatment, otherwise a necessary step for oxidation and corrosion resistance. Stability of these thin films was attributed to the reduction of each RE's respective oxide during processing; recognizing that fluoride compounds exhibit a slightly higher (negative) free energy driving force for formation. Formation of RE-type fluorides on the surface was evidenced through x-ray photoelectron spectroscopy (XPS). Concurrent research with auger electron spectroscopy has been attempted to accurately quantify the depth of fluoride formation in order to grasp the extent of fluorination reactions with spherical and flake particulate. Gas fusion analysis on coated powders (dia. <45 {micro}m) from an optimized experiment indicated an as-atomized oxygen concentration of 343ppm, where typical, nonpassivated RE atomized alloys exhibit an average of 1800ppm oxygen. Thermogravimetric analysis (TGA) on the same powder revealed a decreased rate of oxidation at elevated temperatures up to 300 C, compared to similar uncoated powder.

  6. Use of micro-XANES to speciate chromium in airborne fine particles in the Sacramento Valley

    SciTech Connect (OSTI)

    Michelle L. Werner; Peter S. Nico; Matthew A. Marcus; Cort Anastasio

    2007-07-15

    While particulate matter (PM) in the atmosphere can lead to a wide array of negative health effects, the cause of toxicity is largely unknown. One aspect of PM that likely affects health is the chemical composition, in particular the transition metals within the particles. Chromium is one transition metal of interest due to its two major oxidation states, with Cr(III) being much less toxic compared to Cr(VI). Using microfocused X-ray absorption near edge structure (micro-XANES), we analyzed the Cr speciation in fine particles (diameters {le} 2.5 {mu}m) collected at three sites in the Sacramento Valley of northern California: Sacramento, a large urban area, Davis, a small city, and Placerville, a rural area. These are several major stationary sources of Cr within 24 km of the site including chrome-plating plants, power plants and incinerators. The microfocused X-ray beam enables us to look at very small areas on the filter with a resolution of typically 5-7 micrometers. With XANES we are able to not only distinguish between Cr(VI) and Cr(III), but also to identify different types of Cr(III) and more reduced Cr species. At all of our sampling sites the main Cr species were Cr(III), with Cr(OH){sub 3} or a Cr-Fe, chromite-like, phase being the dominant species. Cr(VI)-containing particles were found only in the most urban site. All three sites contained some reduced Cr species, either Cr(0) or Cr{sub 3}C{sub 2}, although these were minor components. This work demonstrates that micro-XANES can be used as a minimally invasive analytical tool to investigate the composition of ambient PM. 32 refs., 6 figs.

  7. Emissions of Volatile Particulate Components from Turboshaft Engines running JP-8 and Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Landgraf, Bradley J

    2009-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military and also a wide range of commercial applications around the world, but emissions data for this class of engines are limited. In this study, we focus on emissions from T700-GE-700 and T700-GE-701C engines; T700 engine was run with military JP-8 and T701C run with both JP-8 and Fischer-Tropsch (FT) fuels. Each engine was run at three engine power settings from the idle to maximum power in sequence. Exhaust particles measured at the engine exhaust plane (EEP) have a peak mobility diameter less than 50nm in all engine power settings. At a 4-m downstream location, sulfate/sulfur measurements indicate all particulate sulfur exists practically as sulfate, and the particulate sulfur and sulfate contents increased as the engine power increased. The conversion of sulfur to sulfate was found not to be dependent on engine power setting. Analysis also showed that conversion of sulfur to sulfate was not by the adsorption of sulfur dioxide gas on the soot particles and then subsequently oxidized to form sulfate, but by gas-phase conversion of SO2 via OH or O then subsequently forming H2SO4 and condensing on soot particles. Without the sulfur and aromatic components, use of the FT fuel led to significant reduction of soot emissions as compared to that of the JP-8 fuel producing less number of particles than that of the JP-8 fuel; however, the FT fuel produced much higher number concentrations of particles smaller than 7nm than that of JP-8 in all engine power settings. This indicates non-aromatics components in the FT fuel could have contributed to the enhancement of emissions of particles smaller than 7nm. These small particles are volatile, not observed at the EEP, and may be important in playing a role for the formation of secondary particles in the atmosphere or serving as a site for effective cloud nuclei condensation to occur.

  8. SOURCE SIGNATURES OF FINE PARTICULATE MATTER FROM PETROLEUM REFINING AND FUEL USE

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Artur Braun; Yuanzhi Chen; J. David Robertson; Joseph Kyger; Adel F. Sarofim; Ronald J. Pugmire; Henk L.C. Meuzelaar; JoAnn Lighty

    2003-07-31

    The molecular structure and microstructure of a suite of fine particulate matter (PM) samples produced by the combustion of residual fuel oil and diesel fuel were investigated by an array of analytical techniques. Some of the more important results are summarized below. Diesel PM (DPM): A small diesel engine test facility was used to generate a suite of diesel PM samples from different fuels under engine load and idle conditions. C XANES, {sup 13}C NMR, XRD, and TGA were in accord that the samples produced under engine load conditions contained more graphitic material than those produced under idle conditions, which contained a larger amount of unburned diesel fuel and lubricating oil. The difference was enhanced by the addition of 5% of oxygenated compounds to the reference fuel. Scanning transmission x-ray micro-spectroscopy (STXM) was able to distinguish particulate regions rich in C=C bonds from regions rich in C-H bonds with a resolution of {approx}50 nm. The former are representative of more graphitic regions and the latter of regions rich in unburned fuel and oil. The dominant microstructure observed by SEM and TEM consisted of complex chain-like structures of PM globules {approx}20-100 nm in mean diameter, with a high fractal dimension. High resolution TEM revealed that the graphitic part of the diesel soot consisted of onion-like structures made up of graphene layers. Typically 3-10 graphene layers make up the ''onion rings'', with the layer spacing decreasing as the number of layers increases. ROFA PM: Residual oil fly ash (ROFA) PM has been analyzed by a new approach that combines XAFS spectroscopy with selective leaching procedures. ROFA PM{sub 2.5} and PM{sub 2.5+} produced in combustion facilities at the U.S. EPA National Risk Management Research Laboratory (NRML) were analyzed by XAFS before and after leaching with water, acid (1N HCl), and pentane. Both water and acid leaching removed most of the metal sulfates, which were the dominant phase present for most metals (V, Ni, Zn, etc.). This allowed conclusive identification in the leaching residue of important secondary sulfide and oxide phases, including Ni sulfide, a toxic and carcinogenic phase observed in the leached PM{sub 2.5+} samples. Other significant secondary phases identified included V{sub 2}O{sub 4}, V sulfide, and NiFe{sub 2}O{sub 4}.

  9. A comparison between satellite and airborne multispectral data for the assessment of Mangrove areas in the eastern Caribbean

    SciTech Connect (OSTI)

    Green, E.P.; Edwards, A.J.; Mumby, P.J.

    1997-06-01

    Satellite (SPOT XS and Landsat TM) and airborne multispectral (CASI) imagery was acquired from the Turks and Caicos Islands, British West Indies. The descriptive resolution and accuracy of each image type is compared for two applications: mangrove habitat mapping and the measurement of mangrove canopy characteristics (leaf area index and canopy closure). Mangroves could be separated from non-mangrove vegetation to an accuracy of only 57% with SPOT XS data but better discrimination could be achieved with either Landsat TM or CASI (in both cases accuracy was >90%). CASI data permitted a more accurate classification of different mangrove habitats than was possible using Landsat TM. Nine mangrove habitats could be mapped to an accuracy of 85% with the high-resolution airborne data compared to 31% obtained with TM. A maximum of three mangrove habitats were separable with Landsat TM: the accuracy of this classification was 83%. Measurement of mangrove canopy characteristics is achieved more accurately with CASI than with either satellite sensor, but high costs probably make it a less cost-effective option. The cost-effectiveness of each sensor is discussed for each application.

  10. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching (Murrysville, PA); Newby, Richard A. (Pittsburgh, PA); Lippert, Thomas E. (Murrysville, PA)

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  11. Assessment of particulate concentrations from domestic biomass combustion in rural Mexico

    SciTech Connect (OSTI)

    Brauer, M.; Bartlett, K.; Regalado-Pineda, J.; Perez-Padilla, R.

    1996-01-01

    Recent evidence has suggested that woodsmoke exposure in developed countries is associated with acute and chronic health impacts. Particulate concentrations were measured in rural Mexican kitchens using biomass combustion for cooking. To investigate differences in indoor particle concentrations between kitchens using different fuels and stove types, measurements were made in eight kitchens using only biomass, six using only liquefied petroleum gas (LPG), six using a combination of biomass and LPG, and three using biomass in ventilated stoves. Outdoor samples were collected at the same time as the indoor samples. PM{sub 10} and PM{sub 2.5} measurements were made with inertial impactors, and particle light scattering was measured continuously with an integrating nephelometer. PM{sub 10} and PM{sub 2.5} concentrations (mean concentrations of 768 and 555 {mu}g m{sup -3}, respectively) in the kitchens burning only biomass were greater than in all other types (biomass > biomass + LPG > ventilated > LPG > outdoor). A similar trend was evident for the indoor/outdoor concentration ratio. Based on the short-term measurements estimated from the nephelometer data, PM{sub 10} and PM{sub 2.5} cooking period average and 5-min peak concentrations were significantly higher (p < 0.05) in kitchens using only biomass than in those using LPG, a combination of LPG and biomass, or a ventilated biomass stove. 20 refs., 3 figs., 3 tabs.

  12. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    SciTech Connect (OSTI)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels that have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.

  13. CRADA opportunities in removal of particulates from hot-gas streams by filtration

    SciTech Connect (OSTI)

    Smith, D.H.

    1995-06-01

    Our analyses of samples and operating data from the Pressurized Fluidized Bed Combustion (PFBC), cyclone, and filtration units of the Tidd Clean Coal demonstration facility show that calcined dolomitic sorbent reacted with SO{sub 2} (and O{sub 2}) to form Sulfates (CaSO{sub 4} and CaMgn [SO{sub 4}]n+1) not only in the PFBC bed, but also in the filtration vessel. Analyses of limited data from the journal literature suggest that the filter-vessel reactions may have produced sulfate {open_quotes}necks,{close_quotes} which bonded the particles together, thus substantially increasing the critical angle of repose and shear tensile strengths of the filtered powders. This proposed mechanism rationalizes the {open_quotes}bridging{close_quotes} and other particle-accumulation problems that caused filter breakage. Engineering services potentially available to resolve these problems include elucidation and modeling of ex-situ and in-situ filter-vessel chemistry, measurement and modeling of particulate materials properties, and measurement and modeling of cleaning back-pulse aerodynamics and cleaning efficiencies.

  14. Sub-micrometre Particulate Matter is Primarily in Liquid Form over Amazon Rainforests

    SciTech Connect (OSTI)

    Bateman, Adam P.; Gong, Z. H.; Liu, Pengfei; Sato, Bruno; Cirino, Glauber; Zhang, Yue; Artaxo, Paulo; Bertram, Allan K.; Manzi, A.; Rizzo, L. V.; Souza, Rodrigo A.; Zaveri, Rahul A.; Martin, Scot T.

    2016-01-01

    Particulate matter (PM) occurs in the Earth’s atmosphere both in liquid and non-liquid forms. The physical state affects the available physical and chemical mechanisms of growth and reactivity, ultimately affecting the number, size, and composition of the atmospheric particle population. Herein, the physical state, including the response to relative humidity (RH), was investigated on-line and in real time for PM (< 1 μm) over the tropical rain forest of central Amazonia during both the wet and dry seasons of 2013. The results show that the PM was liquid for RH > 80% across 296 to 300 K. These results, in conjunction with the distributions of RH and temperature in Amazonia, imply that near-surface submicron PM in Amazonia is liquid most of the time. The observations are consistent with laboratory experiments showing that PM produced by isoprene photo-oxidation is liquid across these meteorological conditions. The findings have implications for the mechanisms of new particle production in Amazonia, the growth of submicron particles and hence dynamics of the cloud life cycle, and the sensitivity of these processes to anthropogenic activities. An approach for inclusion of particle physical state in chemical transport models is presented.

  15. Cytotoxicity of settling particulate matter and sediments of the Neckar River (Germany) during a winter flood

    SciTech Connect (OSTI)

    Hollert, H.; Duerr, M.; Erdinger, L.; Braunbeck, T.

    2000-03-01

    To investigate the cytotoxic and genotoxic potentials of settling particulate matter (SPM) carried by the Neckar River, a well-studied model for a lock-regulated river in central Europe, during a flood, acute cytotoxicity was investigated using the fibroblast-like fish cell line RTG-2 with the neutral red retention, the succinic acid dehydrogenase (MTT), and the lactatedehydrogenase (LDH) release assays as well as microscopic inspection as endpoints. Genotoxicity of water, pore water, sediments, and SPM were assessed using the Ames test. Different extraction methods (Soxhlet extraction with solvents of variable polarity as well as a fluid/fluid extraction according to pH) in addition to a supplementation of biotests with 59 fractions from the liver of {beta}-naphthoflavone/phenobarbital-induced rats allowed a further characterization of the biological damage. Both sediments and SPM extracts caused cytotoxic effects in RTG-2 cells. Cytotoxicity was found to increase significantly with polarity of extracting solvents. Following extraction according to pH, cytotoxicity could be attributed mainly to neutral substances, whereas the slightly acid and basic fractions already showed little or no cytotoxicity. Samples taken during the period of flood rise showed the highest cytotoxic activities. Cytotoxicity was significantly enhanced by the addition of S9 preparations. In contrast, no genotoxic activity was found in native surface waters, pore waters, and SPM.

  16. Detailed Characterization of Particulates Emitted by Pre-Commercial Single-Cylinder Gasoline Compression Ignition Engine

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Reitz, Paul; Stewart, Mark L.; Imre, D.; Loeper, Paul; Adams, Cory; Andrie, Michael; Rothamer, David; Foster, David E.; Narayanaswamy, Kushal; Najt, Paul M.; Solomon, Arun S.

    2014-08-01

    Gasoline Compression Ignition (GCI) engines have the potential to achieve high fuel efficiency and to significantly reduce both NOx and particulate matter (PM) emissions by operating under dilute partially-premixed conditions. This low temperature combustion strategy is dependent upon direct-injection of gasoline during the compression stroke and potentially near top dead center (TDC). The timing and duration of the in-cylinder injections can be tailored based on speed and load to create optimized conditions that result in a stable combustion. We present the results of advanced aerosol analysis methods that have been used for detailed real-time characterization of PM emitted from a single-cylinder GCI engine operated at different speed, load, timing, and number and duration of near-TDC fuel injections. PM characterization included 28 measurements of size and composition of individual particles sampled directly from the exhaust and after mass and/or mobility classification. We use these data to calculate particle effective density, fractal dimension, dynamic shape factors in free-molecular and transition flow regimes, average diameter of primary spherules, number of spherules, and void fraction of soot agglomerates.

  17. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  18. Source Contribution Analysis of Surface Particulate Polycyclic Aromatic Hydrocarbon Concentrations in Northeastern Asia by Source-receptor Relationships

    SciTech Connect (OSTI)

    Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Ohara, Toshimasa; Kurokawa, Jun-Ichi; Ueda, Hiromasa; Tang, Ning; Hayakawa, Kazuichi; Ohizumi, Tsuyoshi; Akimoto, Hajime

    2013-11-01

    We analyzed the sourceereceptor relationships for particulate polycyclic aromatic hydrocarbon (PAH) concentrations in northeastern Asia using an aerosol chemical transport model. The model successfully simulated the observed concentrations. In Beijing (China) benzo[a]pyren (BaP) concentrations are due to emissions from its own domain. In Noto, Oki and Tsushima (Japan), transboundary transport from northern China (>40N, 40-60%) and central China (30-40N, 10-40%) largely influences BaP concentrations from winter to spring, whereas the relative contribution from central China is dominant (90%) in Hedo. In the summer, the contribution from Japanese domestic sources increases (40-80%) at the 4 sites. Contributions from Japan and Russia are additional source of BaP over the northwestern Pacific Ocean in summer. The contribution rates for the concentrations from each domain are different among PAH species depending on their particulate phase oxidation rates. Reaction with O3 on particulate surfaces may be an important component of the PAH oxidation processes.

  19. Progression of soot cake layer properties during the systematic regeneration of diesel particulate filters measured with neutron tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Toops, Todd J.; Pihl, Josh A.; Finney, Charles E. A.; Gregor, Jens; Bilheux, Hassina

    2015-01-16

    Although particulate filters (PFs) have been a key component of the emission control system for modern diesel engines, there remain significant questions about the basic regeneration behavior of the filters and how it changes with accumulation of increasing soot layers. This effort describes a systematic deposition and regeneration of particulate matter in 25-mm diameter 76-mm long wall-flow PFs composed of silicon carbide (SiC) material. The initial soot distributions were analyzed for soot cake thickness using a nondestructive neutron imaging technique. With the PFs intact, it was then possible to sequentially regenerate the samples and reanalyze them, which was performedmoreafter nominal 20, 50, and 70 % regenerations. The loaded samples show a relatively uniform distribution of particulate with an increasing soot cake thickness and nearly identical initial density of 70 mg/cm3. Throughout regeneration, the soot cake thickness initially decreases significantly while the density increases to 8090 mg/cm3. After ~50 % regeneration, the soot cake thickness stays relatively constant, but instead, the density decreases as pores open up in the layer (~35 mg/cm3 at 70 % regeneration). Complete regeneration initially occurs at the rear of the PF channels. With this information, a conceptual model of the regeneration is proposed.less

  20. The probability of laser caused ocular injury to the aircrew of undetected aircraft violating the exclusion zone about the airborne aura LIDAR.

    SciTech Connect (OSTI)

    Augustoni, Arnold L.

    2006-12-01

    The probability of a laser caused ocular injury, to the aircrew of an undetected aircraft entering the exclusion zone about the AURA LIDAR airborne platform with the possible violation of the Laser Hazard Zone boundary, was investigated and quantified for risk analysis and management.

  1. Cashew nut roasting: Chemical characterization of particulate matter and genotocixity analysis

    SciTech Connect (OSTI)

    Oliveira Galvo, Marcos Felipe de; Melo Cabral, Thiago de; Andr, Paulo Afonso de; Ftima Andrade, Maria de; Miranda, Regina Maura de; Saldiva, Paulo Hilrio Nascimento; Castro Vasconcellos, Prola de; Batistuzzo de Medeiros, Silvia Regina

    2014-05-01

    Background: Particulate matter (PM) is potentially harmful to health and related to genotoxic events, an increase in the number of hospitalizations and mortality from respiratory and cardiovascular diseases. The present study conducted the first characterization of elemental composition and polycyclic aromatic hydrocarbon (PAH) analysis of PM, as well as the biomonitoring of genotoxic activity associated to artisanal cashew nut roasting, an important economic and social activity worldwide. Methods: The levels of PM{sub 2.5} and black carbon were also measured by gravimetric analysis and light reflectance. The elemental composition was determined using X-ray fluorescence spectrometry and PAH analysis was carried out by gas chromatographymass spectrometry. Genotoxic activity was measured by the Tradescantia pallida micronucleus bioassay (Trad-MCN). Other biomarkers of DNA damage, such as nucleoplasmic bridges and nuclear fragments, were also quantified. Results: The mean amount of PM{sub 2.5} accumulated in the filters (January 2124.2 g/m{sup 3}; May 1022.2 g/m{sup 3}; September 1291.9 g/m{sup 3}), black carbon (January 363.6 g/m{sup 3}; May 70 g/m{sup 3}; September 69.4 g/m{sup 3}) and concentrations of Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Se, Br and Pb were significantly higher than the non-exposed area. Biomass burning tracers K, Cl, and S were the major inorganic compounds found. Benzo[k]fluoranthene, indene[1,2,3-c,d]pyrene, benzo[ghi]perylene, phenanthrene and benzo[b]fluoranthene were the most abundant PAHs. Mean benzo[a]pyrene-equivalent carcinogenic power values showed a significant cancer risk. The Trad-MCN bioassay revealed an increase in micronucleus frequency, 27 times higher than the negative control and significantly higher in all the months analyzed, possibly related to the mutagenic PAHs found. Conclusions: This study demonstrated that artisanal cashew nut roasting is a serious occupational problem, with harmful effects on workers' health. Those involved in this activity are exposed to higher PM{sub 2.5} concentrations and to 12 PAHs considered potentially mutagenic and/or carcinogenic. The Trad-MCN with T. pallida was sensitive and efficient in evaluating the genotoxicity of the components and other nuclear alterations may be used as effective biomarkers of DNA damage. - Highlights: The cashew nut roasting generated high concentrations of particulate matter fine. The biomass burning tracers K, Cl, S were the major inorganic compounds found. It was identified 12 PAHs considered to be potentially mutagenic and/or carcinogenic. The genotoxic potential of this activity was confirmed by the Trad MCN assay. This activity is a serious occupational problem with harmful effects to health workers.

  2. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect (OSTI)

    Rizzo, Jeffrey J.

    2010-04-30

    The Wabash gasification facility, owned and operated by sgSolutions LLC, is one of the largest single train solid fuel gasification facilities in the world capable of transforming 2,000 tons per day of petroleum coke or 2,600 tons per day of bituminous coal into synthetic gas for electrical power generation. The Wabash plant utilizes Phillips66 proprietary E-Gas (TM) Gasification Process to convert solid fuels such as petroleum coke or coal into synthetic gas that is fed to a combined cycle combustion turbine power generation facility. During plant startup in 1995, reliability issues were realized in the gas filtration portion of the gasification process. To address these issues, a slipstream test unit was constructed at the Wabash facility to test various filter designs, materials and process conditions for potential reliability improvement. The char filtration slipstream unit provided a way of testing new materials, maintenance procedures, and process changes without the risk of stopping commercial production in the facility. It also greatly reduced maintenance expenditures associated with full scale testing in the commercial plant. This char filtration slipstream unit was installed with assistance from the United States Department of Energy (built under DOE Contract No. DE-FC26-97FT34158) and began initial testing in November of 1997. It has proven to be extremely beneficial in the advancement of the E-Gas (TM) char removal technology by accurately predicting filter behavior and potential failure mechanisms that would occur in the commercial process. After completing four (4) years of testing various filter types and configurations on numerous gasification feed stocks, a decision was made to investigate the economic and reliability effects of using a particulate removal gas cyclone upstream of the current gas filtration unit. A paper study had indicated that there was a real potential to lower both installed capital and operating costs by implementing a char cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  3. Alternatives to conventional diesel fuel-some potential implications of California's TAC decision on diesel particulate.

    SciTech Connect (OSTI)

    Eberhardt, J. J.; Rote, D. M.; Saricks, C. L.; Stodolsky, F.

    1999-08-10

    Limitations on the use of petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to provisions of the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies. (1) Increased penetration of natural gas and greater gasoline use in the transportation fuels market, to the extent that some compression-ignition (CI) applications revert to spark-ignition (SI) engines. (2) New specifications requiring diesel fuel reformulation based on exhaust products of individual diesel fuel constituents. Each of these alternatives results in some degree of (conventional) diesel displacement. In the first case, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles, and gasoline demand in California increases by 32.2 million liters per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter equivalents per day, about 7 percent above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Economic implications of vehicle and engine replacement were not evaluated.

  4. The innate and adaptive immune response induced by alveolar macrophages exposed to ambient particulate matter

    SciTech Connect (OSTI)

    Miyata, Ryohei; Eeden, Stephan F. van

    2011-12-15

    Emerging epidemiological evidence suggests that exposure to particulate matter (PM) air pollution increases the risk of cardiovascular events but the exact mechanism by which PM has adverse effects is still unclear. Alveolar macrophages (AM) play a major role in clearing and processing inhaled PM. This comprehensive review of research findings on immunological interactions between AM and PM provides potential pathophysiological pathways that interconnect PM exposure with adverse cardiovascular effects. Coarse particles (10 {mu}m or less, PM{sub 10}) induce innate immune responses via endotoxin-toll-like receptor (TLR) 4 pathway while fine (2.5 {mu}m or less, PM{sub 2.5}) and ultrafine particles (0.1 {mu}m or less, UFP) induce via reactive oxygen species generation by transition metals and/or polyaromatic hydrocarbons. The innate immune responses are characterized by activation of transcription factors [nuclear factor (NF)-{kappa}B and activator protein-1] and the downstream proinflammatory cytokine [interleukin (IL)-1{beta}, IL-6, and tumor necrosis factor-{alpha}] production. In addition to the conventional opsonin-dependent phagocytosis by AM, PM can also be endocytosed by an opsonin-independent pathway via scavenger receptors. Activation of scavenger receptors negatively regulates the TLR4-NF-{kappa}B pathway. Internalized particles are subsequently subjected to adaptive immunity involving major histocompatibility complex class II (MHC II) expression, recruitment of costimulatory molecules, and the modulation of the T helper (Th) responses. AM show atypical antigen presenting cell maturation in which phagocytic activity decreases while both MHC II and costimulatory molecules remain unaltered. PM drives AM towards a Th1 profile but secondary responses in a Th1- or Th-2 up-regulated milieu drive the response in favor of a Th2 profile.

  5. Source apportionment of particulate matter in the US and associations with lung inflammatory markers

    SciTech Connect (OSTI)

    Duvall, R.M.; Norris, G.A.; Dailey, L.A.; Burke, J.M.; McGee, J.K.; Gilmour, M.I.; Gordon, T.; Devlin, R.B.

    2008-07-01

    Size-fractionated particulate matter (PM) samples were collected from six U.S. cities and chemically analyzed as part of the Multiple Air Pollutant Study. Particles were administered to cultured lung cells and the production of three different proinflammatory markers was measured to explore the association between the health effect markers and PM. Ultrafine, fine, and coarse PM samples were collected between December 2003 and May 2004 over a 4-wk period in each city. Filters were pooled for each city and the PM samples were extracted then analyzed for trace metals, ions, and elemental carbon. Particle extracts were applied to cultured human primary airway epithelial cells, and the secreted levels of interleukin-8 (IL-8), heme oxygenase-1, and cyclooxygenase-2 were measured 1 and 24 h following exposure. Fine PM sources were quantified by the chemical mass balance (CMB) model. The relationship between toxicological measures, PM sources, and individual species were evaluated using linear regression. Ultrafine and fine PM mass were associated with increases in IL-8 (r{sup 2} = .80 for ultrafine and r{sup 2} = .52 for fine). Sources of fine PM and their relative contributions varied across the sampling sites and a strong linear association was observed between IL-8 and secondary sulfate from coal combustion (r{sup 2} = .79). Ultrafine vanadium, lead, copper, and sulfate were also associated with increases in IL-8. Increases in inflammatory markers were not observed for coarse PM mass and source markers. These findings suggest that certain PM size fractions and sources are associated with markers of lung injury or inflammation.

  6. Exposure assessment approaches to evaluate respiratory health effects of particulate matter and nitrogen dioxide

    SciTech Connect (OSTI)

    Quackenboss, J.J.; Krzyzanowski, M.; Lebowitz, M.D. )

    1991-01-01

    Several approaches can be taken to estimate or classify total personal exposures to air pollutants. While personal exposure monitoring (PEM) provides the most direct measurements, it is usually not practical for extended time periods or large populations. This paper describes the use of indirect approaches to estimate total personal exposure for NO2 and particulate matter (PM), summarizes the distributions of these estimates, and compares the effectiveness of these estimates with microenvironmental concentrations for evaluating effects on respiratory function and symptoms. Pollutant concentrations were measured at several indoor and outdoor locations for over 400 households participating in an epidemiological study in Tucson, Arizona. Central site monitoring data were significantly correlated with samples collected directly outside homes, but the former usually had higher pollutant concentrations. Integrated indices of daily total personal exposure were calculated using micro-environmental (ME) measurements or estimates and time-budget diary information. Peak expiratory flow rates (PEFR) were measured for up to four times a day during two-week study periods. In thirty children (ages 6-15 years) with current diagnosed asthma, a significant reduction in PEFR was associated with NO2 levels measured outside of their homes. Additional decrements of morning PEFR were found in those children sleeping in bedrooms with higher measured NO2 levels. Morning and noon PEFR decrements were also linked to higher morning NO2 levels that were measured at central monitoring stations. Effects of PM were also found, but were limited to morning PEFR. No effects were found in non-asthmatic children. The relationship of PEFR to the calculated indices of daily average total exposure were weaker than to the microenvironment concentrations.

  7. ARM Airborne Carbon Measurements (ARM-ACME) and ARM-ACME 2.5 Final Campaign Reports

    SciTech Connect (OSTI)

    Biraud, S. C.; Tom, M. S.; Sweeney, C.

    2016-01-01

    We report on a 5-year multi-institution and multi-agency airborne study of atmospheric composition and carbon cycling at the Atmospheric Radiation Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site, with scientific objectives that are central to the carbon-cycle and radiative-forcing goals of the U.S. Global Change Research Program and the North American Carbon Program (NACP). The goal of these measurements is to improve understanding of 1) the carbon exchange of the Atmospheric Radiation Measurement (ARM) SGP region; 2) how CO2 and associated water and energy fluxes influence radiative-forcing, convective processes, and CO2 concentrations over the ARM SGP region, and 3) how greenhouse gases are transported on continental scales.

  8. Unmanned airborne vehicle (UAV): Flight testing and evaluation of two-channel E-field very low frequency (VLF) instrument

    SciTech Connect (OSTI)

    1998-12-01

    Using VLF frequencies, transmitted by the Navy`s network, for airborne remote sensing of the earth`s electrical, magnetic characteristics was first considered by the United States Geological Survey (USGS) around the mid 1970s. The first VLF system was designed and developed by the USGS for installation and operation on a single engine, fixed wing aircraft used by the Branch of Geophysics for geophysical surveying. The system consisted of five channels. Two E-field channels with sensors consisting of a fixed vertical loaded dipole antenna with pre-amp mounted on top of the fuselage and a gyro stabilized horizontal loaded dipole antenna with pre-amp mounted on a tail boom. The three channel magnetic sensor consisted of three orthogonal coils mounted on the same gyro stabilized platform as the horizontal E-field antenna. The main features of the VLF receiver were: narrow band-width frequency selection using crystal filters, phase shifters for zeroing out system phase variances, phase-lock loops for generating real and quadrature gates, and synchronous detectors for generating real and quadrature outputs. In the mid 1990s the Branch of Geophysics designed and developed a two-channel E-field ground portable VLF system. The system was built using state-of-the-art circuit components and new concepts in circuit architecture. Small size, light weight, low power, durability, and reliability were key considerations in the design of the instrument. The primary purpose of the instrument was for collecting VLF data during ground surveys over small grid areas. Later the system was modified for installation on a Unmanned Airborne Vehicle (UAV). A series of three field trips were made to Easton, Maryland for testing and evaluating the system performance.

  9. Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

    SciTech Connect (OSTI)

    Strzelec, Andrea

    2009-12-01

    The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

  10. Cell-specific oxidative stress and cytotoxicity after wildfire coarse particulate matter instillation into mouse lung

    SciTech Connect (OSTI)

    Williams, Keisha M.; Franzi, Lisa M.; Last, Jerold A.

    2013-01-01

    Our previous work has shown that coarse particulate matter (PM{sub 10-2.5}) from wildfire smoke is more toxic to lung macrophages on an equal dose (by mass) basis than coarse PM isolated from normal ambient air, as evidenced by decreased numbers of macrophages in lung lavage fluid 6 and 24 hours after PM instillation into mouse lungs in vivo and by cytotoxicity to a macrophage cell line observed directly in vitro. We hypothesized that pulmonary macrophages from mice instilled with wildfire coarse PM would undergo more cytotoxicity than macrophages from controls, and that there would be an increase in oxidative stress in their lungs. Cytotoxicity was quantified as decreased viable macrophages and increased percentages of dead macrophages in the bronchoalveolar lavage fluid (BALF) of mice instilled with wildfire coarse PM. At 1 hour after PM instillation, we observed both decreased numbers of viable macrophages and increased dead macrophage percentages as compared to controls. An increase in free isoprostanes, an indicator of oxidative stress, from control values of 28.1 3.2 pg/mL to 83.9 12.2 pg/mL was observed a half-hour after PM instillation. By 1 hour after PM instillation, isoprostane values had returned to 30.4 7.6 pg/mL, not significantly different from control concentrations. Lung sections from mice instilled with wildfire coarse PM showed rapid Clara cell responses, with decreased intracellular staining for the Clara cell secretory protein CCSP 1 hour after wildfire PM instillation. In conclusion, very rapid cytotoxicity occurs in pulmonary macrophages and oxidative stress responses are seen 0.51 hour after wildfire coarse PM instillation. These results define early cellular and biochemical events occurring in vivo and support the hypothesis that oxidative stress-mediated macrophage toxicity plays a key role in the initial response of the mouse lung to wildfire PM exposure. -- Highlights: ? We studied very early events (0.51 hour) after giving wildfire PM{sub 10-2.5} to mice. ? Wildfire PM{sub 10-2.5} rapidly kills lung macrophages in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits oxidative stress in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits Clara cell CCSP secretion in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits TNF-? secretion into BALF in mice.

  11. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  12. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    SciTech Connect (OSTI)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and mediumhigh (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEM imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.

  13. Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; Toops, Todd J.; Daw, C. Stuart; Sun, Chenxi; Lapuerta, Magin; Agudelo, John

    2014-12-26

    The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEMmore » imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.« less

  14. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, Paul A. (Idaho Falls, ID)

    1998-01-01

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

  15. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, P.A.

    1998-02-24

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated barrier material, preferably in the form of a flexible sheet, and one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention. 3 figs.

  16. Mechanisms of particulate matter formation in spark-ignition engines. 2: Effect of fuel, oil, and catalyst parameters

    SciTech Connect (OSTI)

    Kayes, D.; Hochgreb, S.

    1999-11-15

    A combined experimental and modeling effort was performed in order to understand how particulate matter (PM) is formed in spark-ignition (SI) internal combustion engines. Fuel type and fuel/air ratio strongly affect particle concentrations. PM emissions vary by up to 6 orders of magnitude between fuels at the same fuel/air ratio. Minimum PM concentrations are emitted at a global fuel/air ratio within 10% of stoichiometric, with the exact value depending on the particular fuel. Concentrations can increase by more than 3 orders of magnitude when the fuel/air ratio is either increased or decreased 30% from stoichiometric. Particles derived from oil consumption were found to be between 0 and 40% of the PM concentration for the oils used in the present experiments. Differences in PM emissions with and without the catalytic converter are not statistically significant. Particulate number and mass concentrations plus particle sizes are addressed in this paper, as is the correlation between PM and hydrocarbon (HC) emissions.

  17. Carcinogenic effects in A/J mice of particulate of a coal-tar paint used in potable water systems

    SciTech Connect (OSTI)

    Robinson, M.; Laurie, R.D.; Bull, R.J.; Stober, J.A.

    1987-01-01

    Coal-tar paints are among the products used as inside coatings for water pipes and storage tanks to retard corrosion in potable water-supply systems. Four different formulations of these paints were tested in earlier work by this laboratory in the Ames mutagenesis and the mouse skin carcinogenesis bioassays(6). The paint most active in these assays was then tested in a particulate form in the lung adenoma assay with A/J mice. The paint was applied to clean glass plates, cured, collected and homogenized in 2% Emulphor. Doses of this coal-tar suspension were administered by gavage at 1.0, 10.0, and 55.0 mg in 0.2 ml per mouse 3 x weekly for 8 weeks. The total doses of coal-tar paint were 24, 240, and 1320 mg/mouse. Benzo(a)pyrene, administered in a parallel schedule to a total dose of 6 mg/mouse, served as positive control. A negative control group received an equivalent volume of 2% Emulphor. Animals were sacrificed at 9 months of age (8 months after first dose) and lung adenomas counted. A dose-related response, in the average number of lung tumors per mouse, was observed with the coal-tar particulate. There were also squamous-cell tumors of the forestomach in 42% of the mice receiving 55.0 mg coal tar paint per application.

  18. Stratification of particulate and VOC pollutants in horizontal-flow-paint spray booths. Report for September 1988-October 1989

    SciTech Connect (OSTI)

    Darvin, C.H.

    1990-01-01

    The paper discusses stratification of particulate and volatile organic compound (VOC) pollutants in horizontal flow paint spray booths, as part of a joint U.S. Air Force/EPA research and development program on emissions from paint spray booths. The test program discussed in the paper was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control strategies are being developed. The results of one series of tests indicate that the pollutants, both particulate and VOC, fall to the lower level of the booth or stratify at the level at which they were generated. This might be expected since the densities of typical pollutants found in spray booths are greater than air. The results showed, however, that the concentration of pollutants in the lower level prior to exiting the booth was significantly greater than expected. Data indicated that, for the 16 ft (4.9 m) high booth tested, the concentration at the exit of the booth below the 8 ft (2.4 m) level was 5-25 times greater than the concentration above that level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The concentrated zone could be directed to a proportionally smaller VOC control system of significantly less capital and operating cost.

  19. Origin of particulate organic carbon in the marine atmosphere as indicated by it stable carbon isotopic composition

    SciTech Connect (OSTI)

    Chesselet, R.; Fontugne, M.; Buat-Menard, P.; Ezat, U.; Lambert, C.E.

    1981-04-01

    Organic carbon concentration and isotopic composition were determined in samples of atmospheric particulate matter collected in 1979 at remote marine locations (Enewetak atoll, Sargasso Sea) during the SEAREX (Sea-Air Exchange) program field experiments. Atmospheric Particulate Organic Carbon (POC) concentrations were found to be in the range of 0.3 to 1.2 mg. m/sup -3/, in agreement with previous literature data. The major mass of POC was found on the smallest particles (r<0.5 mm). The /sup 13/C//sup 12/C of the small particles is close to the one expected (d/sup 13/C = 26 +- 2/sup 0///sub infinity/) for atmospheric POC of continental origin. For all the samples analysed so far, it appears that more than 80% of atmospheric POC over remote marine areas is of continental origin. This can be explained either by long-range transport of small sized continental organic aserosols or by the production of POC in the marine atmosphere from a vapor phase organic carbon pool of continental origin. The POC in the large size fraction of marine aerosols (<20% of the total concentration) is likely to have a direct marine origin since its carbon isotopic composition is close to the expected value (d/sup 13/C = -21 +- 2/sup 0///sub 00/) for POC associated with sea-salt droplets transported to the marine atmosphere.

  20. Analyzing source apportioned methane in northern California during Discover-AQ-CA using airborne measurements and model simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Matthew S.; Yates, Emma L.; Iraci, Laura T.; Loewenstein, Max; Tadić, Jovan M.; Wecht, Kevin J.; Jeong, Seongeun; Fischer, Marc L.

    2014-12-01

    This study analyzes source apportioned methane (CH4) emissions and atmospheric mixing ratios in northern California during the Discover-AQ-CA field campaign using airborne measurement data and model simulations. Source apportioned CH4 emissions from the Emissions Database for Global Atmospheric Research (EDGAR) version 4.2 were applied in the 3-D chemical transport model GEOS-Chem and analyzed using airborne measurements taken as part of the Alpha Jet Atmospheric eXperiment over the San Francisco Bay Area (SFBA) and northern San Joaquin Valley (SJV). During the time period of the Discover-AQ-CA field campaign EDGAR inventory CH4 emissions were ~5.30 Gg day –1 (Gg = 1.0 ×more » 109 g) (equating to ~1.90 × 103 Gg yr–1) for all of California. According to EDGAR, the SFBA and northern SJV region contributes ~30% of total CH4 emissions from California. Source apportionment analysis during this study shows that CH4 mixing ratios over this area of northern California are largely influenced by global emissions from wetlands and local/global emissions from gas and oil production and distribution, waste treatment processes, and livestock management. Model simulations, using EDGAR emissions, suggest that the model under-estimates CH4 mixing ratios in northern California (average normalized mean bias (NMB) = –5.2% and linear regression slope = 0.20). The largest negative biases in the model were calculated on days when large amounts of CH4 were measured over local emission sources and atmospheric CH4 mixing ratios reached values >2.5 parts per million. Sensitivity emission studies conducted during this research suggest that local emissions of CH4 from livestock management processes are likely the primary source of the negative model bias. These results indicate that a variety, and larger quantity, of measurement data needs to be obtained and additional research is necessary to better quantify source apportioned CH4 emissions in California.« less

  1. Analyzing source apportioned methane in northern California during Discover-AQ-CA using airborne measurements and model simulations

    SciTech Connect (OSTI)

    Johnson, Matthew S.; Yates, Emma L.; Iraci, Laura T.; Loewenstein, Max; Tadić, Jovan M.; Wecht, Kevin J.; Jeong, Seongeun; Fischer, Marc L.

    2014-12-01

    This study analyzes source apportioned methane (CH4) emissions and atmospheric mixing ratios in northern California during the Discover-AQ-CA field campaign using airborne measurement data and model simulations. Source apportioned CH4 emissions from the Emissions Database for Global Atmospheric Research (EDGAR) version 4.2 were applied in the 3-D chemical transport model GEOS-Chem and analyzed using airborne measurements taken as part of the Alpha Jet Atmospheric eXperiment over the San Francisco Bay Area (SFBA) and northern San Joaquin Valley (SJV). During the time period of the Discover-AQ-CA field campaign EDGAR inventory CH4 emissions were ~5.30 Gg day –1 (Gg = 1.0 × 109 g) (equating to ~1.90 × 103 Gg yr–1) for all of California. According to EDGAR, the SFBA and northern SJV region contributes ~30% of total CH4 emissions from California. Source apportionment analysis during this study shows that CH4 mixing ratios over this area of northern California are largely influenced by global emissions from wetlands and local/global emissions from gas and oil production and distribution, waste treatment processes, and livestock management. Model simulations, using EDGAR emissions, suggest that the model under-estimates CH4 mixing ratios in northern California (average normalized mean bias (NMB) = –5.2% and linear regression slope = 0.20). The largest negative biases in the model were calculated on days when large amounts of CH4 were measured over local emission sources and atmospheric CH4 mixing ratios reached values >2.5 parts per million. Sensitivity emission studies conducted during this research suggest that local emissions of CH4 from livestock management processes are likely the primary source of the negative model bias. These results indicate that a variety, and larger quantity, of measurement data needs to be obtained and additional research is necessary to better quantify source apportioned CH4 emissions in California.

  2. DOE-HDBK-3010-94; DOE Handbook Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities, Volume 1

    Office of Environmental Management (EM)

    10-94 December 1994 CHANGE NOTICE NO. 1 March 2000 DOE HANDBOOK AIRBORNE RELEASE FRACTIONS/RATES AND RESPIRABLE FRACTIONS FOR NONREACTOR NUCLEAR FACILITIES Volume I - Analysis of Experimental Data U.S. Department of Energy AREA SAFT Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document has been reproduced from the best available copy. Available to DOE and DOE contractors from ES&H Technical Information Services, U.S. Department

  3. The development and application of the chemical mixture methodology in analysis of potential health impacts from airborne release in emergencies

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Petrocchi, Achille J.; Craig, Douglas K.; Glantz, Clifford S.; Trott, Donna M.; Ciolek, John T.; Lu, Po-Yung; Bond, Jayne-Anne; Tuccinardi, Thomas E.; Bouslaugh, Philip R.

    2010-07-15

    The Chemical Mixture Methodology (CMM) is used for emergency response and safety planning by the U.S. Department of Energy, its contractors, and other private and public sector organizations. The CMM estimates potential health impacts on individuals and their ability to take protective actions as a result of exposure to airborne chemical mixtures. They are based on the concentration of each chemical in the mixture at a designated receptor location, the protective action criteria (PAC) providing chemical-specific exposure limit values, and the health code numbers (HCNs) that identify the target organ groupings that may be impacted by exposure to each chemical in a mixture. The CMM has been significantly improved since its introduction more than 10 years ago. Major enhancements involve the expansion of the number of HCNs from 44 to 60 and inclusion of updated PAC values based on an improved development methodology and updates in the data used to derive the PAC values. Comparisons between the 1999 and 2009 versions of the CMM show potentially substantial changes in the assessment results for selected sets of chemical mixtures. In particular, the toxic mode hazard indices (HIs) and target organ HIs are based on more refined acute HCNs, thereby improving the quality of chemical consequence assessment, emergency planning, and emergency response decision making. Seven hypothetical chemical storage and processing scenarios are used to demonstrate how the CMM is applied in emergency planning and hazard assessment.

  4. Final Report DE-EE0005380: Assessment of Offshore Wind Farm Effects on Sea Surface, Subsurface and Airborne Electronic Systems

    SciTech Connect (OSTI)

    Ling, Hao; Hamilton, Mark F.; Bhalla, Rajan; Brown, Walter E.; Hay, Todd A.; Whitelonis, Nicholas J.; Yang, Shang-Te; Naqvi, Aale R.

    2013-09-30

    Offshore wind energy is a valuable resource that can provide a significant boost to the US renewable energy portfolio. A current constraint to the development of offshore wind farms is the potential for interference to be caused by large wind farms on existing electronic and acoustical equipment such as radar and sonar systems for surveillance, navigation and communications. The US Department of Energy funded this study as an objective assessment of possible interference to various types of equipment operating in the marine environment where offshore wind farms could be installed. The objective of this project was to conduct a baseline evaluation of electromagnetic and acoustical challenges to sea surface, subsurface and airborne electronic systems presented by offshore wind farms. To accomplish this goal, the following tasks were carried out: (1) survey electronic systems that can potentially be impacted by large offshore wind farms, and identify impact assessment studies and research and development activities both within and outside the US, (2) engage key stakeholders to identify their possible concerns and operating requirements, (3) conduct first-principle modeling on the interactions of electromagnetic signals with, and the radiation of underwater acoustic signals from, offshore wind farms to evaluate the effect of such interactions on electronic systems, and (4) provide impact assessments, recommend mitigation methods, prioritize future research directions, and disseminate project findings. This report provides a detailed description of the methodologies used to carry out the study, key findings of the study, and a list of recommendations derived based the findings.

  5. Buildings Energy Data Book: 1.4 Environmental Data

    Buildings Energy Data Book [EERE]

    0 2010 Emissions Summary Table for U.S. Buildings Energy Consumption (Thousand Short Tons) (1) Buildings Buildings Percent Wood/SiteFossil Electricity Total U.S. Total of U.S. Total SO2 (2) 54% NOx 17% CO 5% VOCs 2% PM-2.5 15% PM-10 7% Note(s): Source(s): 1) VOCs = volatile organic compounds; PM-10 = particulate matter less than 10 micrometers in aerodynamic diameter. PM-2.5 = particulate matter less than 2.5 micrometers in aerodynamic diameter. CO and VOCs site fossil emissions mostly from wood

  6. Cross-flow, filter-sorbent catalyst for particulate, SO{sub 2} and NO{sub x} control. First quarterly technical progress report, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    This synopsis describes a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particulate filter, an SO{sub 2} sorbent, and a NO{sub x} reduction catalyst.

  7. In-mine evaluation of catalyzed diesel particulate filters at two underground metal mines. Report of investigations/1995

    SciTech Connect (OSTI)

    Watts, W.F.; Cantrell, B.K.; Bickel, K.L.; Olson, K.S.; Rubow, K.L.

    1995-11-01

    The U.S. Bureau of Mines evaluated the performance of a catalyzed diesel particulate filter (CDPF) and a CDPF combined with a diesel oxidation catalyst (DOC) at two metal mines. This paper describes the results from the two field evaluations. The CDPF/DOC was installed on an Elphinstone load-haul-dump (LHD) powered by a Caterpillar 3306 prechambered, turbocharged engine. The CDPF was installed on a Tamrock diesel-hydraulic roof-bolting jumbo, powered by a Deutz F6L912W engine. The underground evaluation at this mine was more difficult because of frequent movement by the roof-bolting jumbo, variation in the daily workload, tremendous fluctuation in ventilation air flow rate and the use of a high sulfur diesel fuel, which promotes the formation of sulfate particles, decreases filtration efficiency, and hastens the deterioration of the catalyst.

  8. Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study)

    SciTech Connect (OSTI)

    Annette Rohr; James Wagner Masako Morishita; Gerald Keeler; Jack Harkema

    2010-06-30

    Alterations in heart rate variability (HRV) have been reported in rodents exposed to concentrated ambient particles (CAPs) from different regions of the United States. The goal of this study was to compare alterations in cardiac function induced by CAPs in two distinct regional atmospheres. AirCARE 1, a mobile laboratory with an EPA/Harvard fine particle (particulate matter <2.5 {micro}m; PM{sub 2.5}) concentrator was located in urban Detroit, MI, where the PM mixture is heavily influenced by motor vehicles, and in Steubenville, OH, where PM is derived primarily from long-range transport and transformation of power plant emissions, as well as from local industrial operations. Each city was studied during both winter and summer months, for a total of four sampling periods. Spontaneously hypertensive rats instrumented for electrocardiogram (ECG) telemetry were exposed to CAPs 8 h/day for 13 consecutive days during each sampling period. Heart rate (HR), and indices of HRV (standard deviation of the average normal-to-normal intervals [SDNN]; square root of the mean squared difference of successive normal-to-normal intervals [rMSSD]), were calculated for 30-minute intervals during exposures. A large suite of PM components, including nitrate, sulfate, elemental and organic carbon, and trace elements, were monitored in CAPs and ambient air. In addition, a unique sampler, the Semi-Continuous Elements in Air Sampler (SEAS) was employed to obtain every-30-minute measurements of trace elements. Positive matrix factorization (PMF) methods were applied to estimate source contributions to PM{sub 2.5}. Mixed modeling techniques were employed to determine associations between pollutants/CAPs components and HR and HRV metrics. Mean CAPs concentrations in Detroit were 518 and 357 {micro}g/m{sup 3} (summer and winter, respectively) and 487 and 252 {micro}g/m{sup 3} in Steubenville. In Detroit, significant reductions in SDNN were observed in the summer in association with cement/lime, iron/steel, and gasoline/diesel factors, while associations with the sludge incineration factor and components were less consistent. In winter, increases in HR were associated with a refinery factor and its components. CAPs-associated HR decreases in winter were linked to sludge incineration, cement/lime, and coal/secondary factors and the majority of their associated components. Specific relationships for increased rMSSD in winter were difficult to determine due to lack of consistency between factors and associated constituents. In Steubenville, we observed significant changes in HR (both increases and decreases), SDNN, and rMSSD in the summer, but not in the winter. We examined associations between individual source factors/PM components and HRV metrics segregated by predominant wind direction (NE or SW). Changes in HR (both increases and decreases) were linked with metal processing, waste incineration, and iron/steel factors along with most of their associated elemental constituents. Reductions in SDNN were associated with metal processing, waste incineration, and mobile source factors and the majority of elements loading onto these factors. There were no consistent associations between changes in rMSSD and source factors/components. Despite the large number of coal-fired power plants in the region, and therefore the large contribution of secondary sulfate to overall PM mass, we did not observe any associations with the coal/secondary factor or with the majority of its associated components. There were several inconsistencies in our results which make definitive conclusions difficult. For example, we observed opposing signs of effect estimates with some components depending on season, and with others depending on wind direction. In addition, our extensive dataset clearly would be subject to issues of multiple comparisons, and the 'true' significant results are unknown. Overall, however, our results suggest that acute changes in cardiac function were most strongly associated with local industrial sources. Results for coal-fired power plant-derived PM were

  9. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  10. Allergy arising from exposure to airborne contaminants in an insect rearing facility: Health effects and exposure control

    SciTech Connect (OSTI)

    Wolff, D.

    1994-06-01

    In agricultural crop improvement, yield under various stress conditions and limiting factors is assessed experimentally. Of the stresses on plants which affect yield are those due to insects. Ostrinia nubilalis, the European corn borer (corn borer) is a major pest in sweet and field corn in the U.S. There are many ways to fight crop pests such as the corn borer, including (1) application of chemical insecticides, (2) application of natural predators and, (3) improving crop resistance through plant genetics programs. Randomized field trials are used to determine the effectiveness of pest management programs. These trials frequently consist of randomly selected crop plots to which well-defined input regimes are instituted. For example, corn borers might be released onto crop plots in several densities at various stages of crop development, then sprayed with different levels of pesticide. These experiments are duplicated across regions and, in some cases across the country, to determine, in this instance for example, the best pesticide application rate for a given pest density and crop development stage. In order to release these pests onto crop plots, one must have an adequate supply of the insect pest. In winter months studies are carried out in the laboratory to examine chemical and natural pesticide effectiveness, as well as such things as the role of pheromones in moth behavior. The advantage in field trials is that yield data can be garnered directly. In this country, insects are raised for crop research primarily through the US Department of Agriculture, in cooperation with public Land Grant Universities and, by the private sector agricultural concerns - seed companies and others. This study quantifies the airborne allergen exposure of persons working in a Land Grant University entomology lab were allergy to European corn borer was suspected.

  11. J

    National Nuclear Security Administration (NNSA)

    16,1997 Prepared for: U.S. Department of Energy Yucca Mountain Site Characterization ... of the Nevada Test Site, where typical wind patterns could carry airborne particulate ...

  12. Microsoft Word - DOE-ID-INL-14-022.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    precautions would be taken to prevent particulate from becoming airborne. If dust control methods are required, the method used and frequency applied must be recorded in...

  13. Microsoft Word - DOE-ID-INL-15-017.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    precautions would be taken to prevent particulate from becoming airborne. If dust control methods are required, the method used and frequency applied must be recorded in...

  14. Microsoft Word - DOE-ID-14-007.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reasonable precautions would be taken to prevent particulate from becoming airborne. This is in accordance with the methods specified in the Rules for the Control of Air Pollution ...

  15. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England

    2004-10-20

    In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

  16. Collection efficiency of the Soot-Particle Aerosol Mass Spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-05-26

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of two. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  17. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-18

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  18. Advances in exposure and toxicity assessment of particulate matter: An overview of presentations at the 2009 Toxicology and Risk Assessment Conference

    SciTech Connect (OSTI)

    Gunasekar, Palur G.; Stanek, Lindsay W.

    2011-07-15

    The 2009 Toxicology and Risk Assessment Conference (TRAC) session on 'Advances in Exposure and Toxicity Assessment of Particulate Matter' was held in April 2009 in West Chester, OH. The goal of this session was to bring together toxicology, geology and risk assessment experts from the Department of Defense and academia to examine issues in exposure assessment and report on recent epidemiological findings of health effects associated with particulate matter (PM) exposure. Important aspects of PM exposure research are to detect and monitor low levels of PM with various chemical compositions and to assess the health risks associated with these exposures. As part of the overall theme, some presenters discussed collection methods for sand and dust from Iraqi and Afghanistan regions, health issues among deployed personnel, and future directions for risk assessment research among these populations. The remaining speakers focused on the toxicity of ultrafine PM and the characterization of aerosols generated during ballistic impacts of tungsten heavy alloys.

  19. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  20. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  1. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  2. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  3. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  4. Stratification of particulate and VOC pollutants in paint spray booths, June 1990. Report for April 1988-April 1989

    SciTech Connect (OSTI)

    Darvin, C.H.; Ayer, J.

    1990-01-01

    The paper discusses flow management as part of a joint EPA/U.S. Air Force program on emissions from paint spray booths. The goal of the program is to identify and develop efficient and economical emissions control concepts for this source. Flow management is one potential solution that reduces the volume of gases that must be processed in a control system. Although it will not itself control pollution, it can influence the economic and technical viability of subsequent control systems. The test program discussed here was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control and flow management strategies are being developed. Study results indicate that both particulate and volatile organic compounds (VOCs) fall to the lower level of the booth or, at most, stratify at the level at which they were generated. Results indicate that the concentration at the lower level of the booth near the exhaust was from 5 to 25 times greater than that at the upper level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The enriched lower zone could then be directed to a proportionately smaller VOC control system, of lower capital and operating costs.

  5. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    DOE R&D Accomplishments [OSTI]

    Molina, Luisa T.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavala, Miguel; Velasco, Erik; Molina; Mario J.

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation.

  6. The use of CETANER{trademark} for the reduction of particulate matter emissions in a turbocharged direct injection (TDI) diesel engine

    SciTech Connect (OSTI)

    Hess, H.S.; Chiodo, J.A.; Boehman, A.L.; Tijim, P.J.A.; Waller, F.J.

    1999-07-01

    In this experimental study, the effects of the addition of CETANER{trademark} to a premium diesel fuel at various blend levels (5%, 10% and 15% by weight) were evaluated using a 1.9 liter turbocharged direct injection diesel engine. CETANER{trademark}, a product developed by Air Products and Chemicals, Inc., can be manufactured from coal-derived syngas through a two-stage process: (i) Liquid Phase DiMethyl Ether synthesis (LPDME); and (ii) oxidative coupling of DiMethyl Ether (DME) to form long chain linear ethers. When compared to other oxygenated components currently being researched, CETANER has several key advantages: (1) it is derived from a non-petroleum feedstock; (2) it has a cetane number greater than 100; and (3) it will have a cost comparable to diesel fuel. Particulate matter emissions and exhaust gas composition (NOx and CO), were determined at six steady-state engine operating conditions. In addition, fuel properties (viscosity, cloud point, pour point, density, flash point and calorific value) of the various blends were also determined. Engine test results indicate that CETANER is effective in reducing particulate matter emissions at all blend levels tested, without any modifications to engine operating parameters. At the highest blend level (15% CETANER by weight), particulate matter emissions were reduced by greater than 20% when compared to premium diesel fuel.

  7. Correlation between Asian Dust and Specific Radioactivities of Fission Products Included in Airborne Samples in Tokushima, Shikoku Island, Japan, Due to the Fukushima Nuclear Accident

    SciTech Connect (OSTI)

    Sakama, M.; Nagano, Y.; Kitade, T.; Shikino, O.; Nakayama, S.

    2014-06-15

    Radioactive fission product {sup 131}I released from the Fukushima Daiichi Nuclear Power Plants (FD-NPP) was first detected on March 23, 2011 in an airborne aerosol sample collected at Tokushima, Shikoku Island, located in western Japan. Two other radioactive fission products, {sup 134}Cs and {sup 137}Cs were also observed in a sample collected from April 2 to 4, 2011. The maximum specific radioactivities observed in this work were about 2.5 to 3.5 mBq×m{sup -3} in a airborne aerosol sample collected on April 6. During the course of the continuous monitoring, we also made our first observation of seasonal Asian Dust and those fission products associated with the FDNPP accident concurrently from May 2 to 5, 2011. We found that the specific radioactivities of {sup 134}Cs and {sup 137}Cs decreased drastically only during the period of Asian Dust. And also, it was found that this trend was very similar to the atmospheric elemental concentration (ng×m{sup -3}) variation of stable cesium ({sup 133}Cs) quantified by elemental analyses using our developed ICP-DRC-MS instrument.

  8. Persistent activation of DNA damage signaling in response to complex mixtures of PAHs in air particulate matter

    SciTech Connect (OSTI)

    Jarvis, Ian W.H.; Bergvall, Christoffer; Bottai, Matteo; Westerholm, Roger; Stenius, Ulla; Dreij, Kristian

    2013-02-01

    Complex mixtures of polycyclic aromatic hydrocarbons (PAHs) are present in air particulate matter (PM) and have been associated with many adverse human health effects including cancer and respiratory disease. However, due to their complexity, the risk of exposure to mixtures is difficult to estimate. In the present study the effects of binary mixtures of benzo[a]pyrene (BP) and dibenzo[a,l]pyrene (DBP) and complex mixtures of PAHs in urban air PM extracts on DNA damage signaling was investigated. Applying a statistical model to the data we observed a more than additive response for binary mixtures of BP and DBP on activation of DNA damage signaling. Persistent activation of checkpoint kinase 1 (Chk1) was observed at significantly lower BP equivalent concentrations in air PM extracts than BP alone. Activation of DNA damage signaling was also more persistent in air PM fractions containing PAHs with more than four aromatic rings suggesting larger PAHs contribute a greater risk to human health. Altogether our data suggests that human health risk assessment based on additivity such as toxicity equivalency factor scales may significantly underestimate the risk of exposure to complex mixtures of PAHs. The data confirms our previous findings with PAH-contaminated soil (Niziolek-Kierecka et al., 2012) and suggests a possible role for Chk1 Ser317 phosphorylation as a biological marker for future analyses of complex mixtures of PAHs. -- Highlights: ? Benzo[a]pyrene (BP), dibenzo[a,l]pyrene (DBP) and air PM PAH extracts were compared. ? Binary mixture of BP and DBP induced a more than additive DNA damage response. ? Air PM PAH extracts were more potent than toxicity equivalency factor estimates. ? Larger PAHs (> 4 rings) contribute more to the genotoxicity of PAHs in air PM. ? Chk1 is a sensitive marker for persistent activation of DNA damage signaling from PAH mixtures.

  9. Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-Out and Tailpipe Particulate Matter Emissions: Preprint

    SciTech Connect (OSTI)

    He, X.; Ireland, J. C.; Zigler, B. T.; Ratcliff, M. A.; Knoll, K. E.; Alleman, T. L.; Tester, J. T.

    2011-02-01

    The influences of ethanol and iso-butanol blended with gasoline on engine-out and post Three-Way Catalyst (TWC) particle size distribution and number concentration were studied using a GM 2.0L turbocharged Spark Ignition Direct Injection (SIDI) engine. The engine was operated using the production ECU with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. US federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at ten selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm. Idle and low speed / low load conditions emitted higher total particle numbers than other operating conditions. At idle, the engine-out Particulate Matter (PM) emissions were dominated by nucleation mode particles, and the production TWC reduced these nucleation mode particles by more than 50%, while leaving the accumulation mode particle distribution unchanged. At engine load higher than 6 bar NMEP, accumulation mode particles dominated the engine-out particle emissions and the TWC had little effect. Compared to the baseline gasoline (E0), E10 does not significantly change PM emissions, while E20 and BU12 both reduce PM emissions under the conditions studied. Iso-butanol was observed to impact PM emissions more than ethanol, with up to 50% reductions at some conditions. In this paper, the issues related to PM measurement using FMPS are also discussed. While some uncertainties are due to engine variation, the FMPS must be operated under careful maintenance procedures in order to achieve repeatable measurement results.

  10. Mathematical model for predicting the probability of acute mortality in a human population exposed to accidentally released airborne radionuclides. Final report for Phase I

    SciTech Connect (OSTI)

    Filipy, R.E.; Borst, F.J.; Cross, F.T.; Park, J.F.; Moss, O.R.; Roswell, R.L.; Stevens, D.L.

    1980-05-01

    A mathematical model was constructed for the purpose of predicting the fraction of human population which would die within 1 year of an accidental exposure to airborne radionuclides. The model is based on data from laboratory experiments with rats, dogs and baboons, and from human epidemiological data. Doses from external, whole-body irradiation and from inhaled, alpha- and beta-emitting radionuclides are calculated for several organs. The probabilities of death from radiation pneumonitis and from bone marrow irradiation are predicted from doses accumulated within 30 days of exposure to the radioactive aerosol. The model is compared with existing similar models under hypothetical exposure conditions. Suggestions for further experiments with inhaled radionuclides are included. 25 refs., 16 figs., 13 tabs.

  11. Development of pollutant release estimates due to abrasive blasting for lead paint removal from New York City Department of Transportation steel bridges

    SciTech Connect (OSTI)

    Lee, M.; Domanski, J.

    1999-07-01

    The use of abrasive blasting techniques in the removal of lead paint from steel bridges is a subject of public health and environmental concerns. This process creates airborne dust that must be appropriately contained to prevent inhalation or ingestion exposure during the removal activity, since some of that dust contains lead and other metals. Lead particles, if not appropriately contained, can also settle in local soils or on and within buildings, and can ultimately be inhaled or ingested. Potential worst case release scenarios for the release of dust and pollutants from paint removal operations were developed as part of the analysis framework for the Environmental Impact Statement for Lead Paint Removal Operations on New York City Department of Transportation Bridges. A multi-step analytical framework was developed for the Environmental Impact Statement (EIS), aimed at characterizing and quantifying a series of worst case scenarios for the release of contaminated material into the environment. The pollutants that the analysis focused on were lead, respirable particulates (PM10), Total Suspended Particulates (TSP) and other metals. Samples of existing paint obtained from various surfaces of representative bridges were analyzed to determine average paint dry film thickness and the concentration of metals in the paint for each of the representative bridges. Samples of expendable abrasives were analyzed to determine the concentration of metals within the abrasives. Six scenarios were developed to encompass the range of potential releases that can occur during blasting operations. Two subcategories of hypothetical release events were developed for each scenario-- reasonable worst case events and maximum worst case events. Air quality dispersion modeling with the Environmental Protection Agency's ISC3ST model was employed with the predicted release rates.

  12. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD reduced this by 7% while the EvCh reduced it by 13%. For other operating conditions, PM treated for volatile removal actually exhibited an increase in organic fraction on the order of 5%. This addition appears to be sensitive to the gaseous hydrocarbon concentrations in the exhaust although a precise correlation has not yet been derived. It has been concluded that VOCs are tightly bound to the PM carbon core and thus are not effectively removed by either treatment method.

  13. High strength particulate ceramics

    DOE Patents [OSTI]

    Liles, Kenneth J.; Hoyer, Jesse L.; Mlynarski, Kenneth W.

    1991-01-01

    This invention relates to new and useful hard, dense, composite materials made from metallic nitrides such as titanium nitride when combined with aluminum oxide and aluminum nitride and a process comprising the steps of: (1) mixing constituent materials using kerosene as a mixing medium; (2) screening, settling, filtering, and washing the mixture in acetone; (3) filling and sealing said materials in a latex mold; (4) isostatically pressing the material into a compacted powder; and (5) sintering the compacted powder in a gas atmosphere at 1,850.degree. C. for two hours.

  14. Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gaseous Emissions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  15. Particulate Matter Aerosols

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The study of atmospheric aerosols is important because of its adverse effects on health, air quality, visibility, cultural heritage, and Earth's radiation balance. Techniques that...

  16. Epidemiological-environmental study of diesel bus garage workers: acute effects of NO/sub 2/ and respirable particulate on the respiratory system

    SciTech Connect (OSTI)

    Gamble, J.; Jones, W.; Minshall, S.

    1987-02-01

    Personal samples of nitrogen dioxide (NO/sub 2/) and respirable particulate (RP) were collected over the shift on 232 workers in four diesel bus garages. Response was assessed by an acute respiratory questionnaire and before and after shift spirometry. Measures of exposure to NO/sub 2/ and RP were associated with work-related symptoms of cough; itching, burning, or watering eyes; difficult or labored breathing; chest tightness; and wheeze. The prevalence of burning eyes, headaches, difficult or labored breathing, nausea, and wheeze experienced at work were higher in the diesel bus garage workers than in a comparison population of battery workers, while the prevalence of headaches was reduced. Mean reductions in forced vital capacity (FVC), forced expiratory volume in 1 sec (FEV1), peak flow, and flows at 50 and 75% of FVC were not obviously different from zero. There was no detectable association of exposure to NO/sub 2/ or respirable particulate and acute reductions in pulmonary function. Workers who often had respiratory work-related symptoms generally had a slightly greater mean acute reduction in FEV1 and FEF50 than did those who did not have these symptoms, but these differences were not statistically significant.

  17. Particulate, colloidal, and solution phase associations of plutonium, americium, and uranium in surface and groundwater at the Rocky Flats Plant, Colorado

    SciTech Connect (OSTI)

    Harnish, R.A.; McKnight, D.M.; Ranville, J.F.; Stephens, V.C.; Honeyman, B.D.

    1993-12-31

    With the cessation of plutonium processing at the D.O.E.-administered Rocky Flats Plant near Denver, CO, the focus of activities at the facility has switched to contaminant assessment and potential remediation strategies. In this context the authors began a study in 1991 to determine the potential for colloid-facilitated transport of the actinides Pu, Am, and in surface- and groundwater at this site. Using the technique of tangential flow ultrafiltration, the authors isolated particles from four size fractions at one groundwater well and two surface water seeps to determine the distribution of Pu, Am, and U among particulate, colloidal, and dissolved aqueous phases. Analysis of particle isolates and filtrate fractions showed significant associations of Am and Pu with colloidal and particulate size particles; uranium isotopes were associated mainly with low molecular weight organic species. The results indicate a potential for colloidal-facilitated transport of the actinides Pu and Am and a significant contribution by low molecular weight natural organic matter to uranium transport.

  18. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Molina, Luisa T.; Molina, Mario J.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavaka, Miguel; Velasco, Erik

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a com

  19. Effects of Hot Streak and Phantom Cooling on Heat Transfer in a Cooled Turbine Stage Including Particulate Deposition

    SciTech Connect (OSTI)

    Bons, Jeffrey; Ameri, Ali

    2015-09-30

    The objective of this research effort was to develop a validated computational modeling capability for the characterization of the effects of hot streaks and particulate deposition on the heat load of modern gas turbines. This was accomplished with a multi-faceted approach including analytical, experimental, and computational components. A 1-year no cost extension request was approved for this effort, so the total duration was 4 years. The research effort succeeded in its ultimate objective by leveraging extensive experimental deposition studies complemented by computational modeling. Experiments were conducted with hot streaks, vane cooling, and combinations of hot streaks with vane cooling. These studies contributed to a significant body of corporate knowledge of deposition, in combination with particle rebound and deposition studies funded by other agencies, to provide suitable conditions for the development of a new model. The model includes the following physical phenomena: elastic deformation, plastic deformation, adhesion, and shear removal. It also incorporates material property sensitivity to temperature and tangential-normal velocity rebound cross-dependencies observed in experiments. The model is well-suited for incorporation in CFD simulations of complex gas turbine flows due to its algebraic (explicit) formulation. This report contains model predictions compared to coefficient of restitution data available in the open literature as well as deposition results from two different high temperature turbine deposition facilities. While the model comparisons with experiments are in many cases promising, several key aspects of particle deposition remain elusive. The simple phenomenological nature of the model allows for parametric dependencies to be evaluated in a straightforward manner. This effort also included the first-ever full turbine stage deposition model published in the open literature. The simulations included hot streaks and simulated vane cooling. The new deposition model was implemented into the CFD model as a wall boundary condition, with various particle sizes investigated in the simulation. Simulations utilizing a steady mixing plane formulation and an unsteady sliding mesh were conducted and the flow solution of each was validated against experimental data. Results from each of these simulations, including impact and capture distributions and efficiencies, were compared and potential reasons for differences discussed in detail. The inclusion of a large range of particle sizes allowed investigation of trends with particle size, such as increased radial migration and reduced sticking efficiency at the larger particle sizes. The unsteady simulation predicted lower sticking efficiencies on the rotor blades than the mixing plane simulation for the majority of particle sizes. This is postulated to be due to the preservation of the hot streak and cool vane wake through the vane-rotor interface (which are smeared out circumferentially in the mixing-plane simulation). The results reported here represent the successful implementation of a novel deposition model into validated vane-rotor flow solutions that include a non-uniform inlet temperature profile and simulated vane cooling.

  20. Effects of overburden, biomass and atmospheric inversions on energy and angular distributions of gamma rays from U, K, Th, and airborne radon sources. Final report

    SciTech Connect (OSTI)

    Rubin, R.M.; Leggett, D.; Wells, M.B.

    1980-12-01

    This report describes a set of radiation transport calculations that were run with the AHISN S/sub n/ discrete ordinates code and a point kernel code to determine the energy, polar angle and height in air distributions of the total and direct gamma-ray flux densities from: (1) uranium sources of 3.2, 200 and 800 ppM in a sandstone orebody covered with biomass densities of 0, 10.2, 20.4, 51.0 and 102.0 kg/m/sup 2/; (2) thorium sources of 12, 25 and 80 ppM in a sandstone ore body covered with biomass densities of 0, 10.2, 20.4, 51.0 and 102.0 kg/m/sup 2/; (3) potassium source (2.5 wt %) in a sandstone ore body covered with biomass densities of 0, 10.2, 20.4, 51.0 and 102.0 kg/m/sup 2/; (4) constant airborne source with height for no inversion and for inversion layer heights of 65.22, 260.32 and 458.43 m; (5) exponentially decreasing airborne source for no inversion and inversion layer heights of 65.22, 260.32 and 458.43 m; (6) 3.2 ppM uranium source in overburden layers of 10.266, 17.110, 26.399 and 32.509 cm thick; (7) 12 ppM thorium source in overburden layers of 10.266, 17.110, 26.399 and 32.509 cm; (8) 2.5 wt % of potassium in overburden layers of 10.266, 17.110, 26.399 and 32.509 cm thick; and (9) 3.2 ppM, 200 ppM, and 800 ppM uranium source in sandstone orebody covered with overburden thicknesses of 10.266, 17.110, 26.399 and 32.509 cm. Gamma-ray emission from the decay of natural uranium, thorium, radon, and potassium are given in a 45-energy group structure applicable to the energy windows used to map the potential uranium ore reserves.

  1. Aerosol backscatter measurements at 10. 6 micrometers with airborne and ground-based CO sub 2 Doppler lidars over the Colorado high plains. 1. Lidar intercomparison

    SciTech Connect (OSTI)

    Bowdle, D.A. ); Rothermel, J. ); Vaughan, J.M.; Brown, D.W. ); Post, M.J. )

    1991-03-20

    An airborne continuous wave (CW) focused CO{sub 2} Doppler lidar and a ground-based pulsed CO{sub 2} Doppler lidar were used to obtain seven pairs of comparative measurements of tropospheric aerosol backscatter profiles at 10.6 {mu}m wavelength, near Denver, Colorado, during a 20-day period in July 1982. In regions of uniform backscatter the two lidars show good agreement, with differences usually less than {approximately}50% near 8-km altitude and less than a factor of 2 or 3 elsewhere but with the pulsed lidar often lower than the CW lidar. Near sharp backscatter gradients the two lidars show poorer agreement, with the pulsed lidar usually higher than the CW lidar. Most discrepancies arise from a combination of atmospheric factors and instrument factors, particularly small-scale areal and temporal backscatter heterogeneity above the planetary boundary layer, unusual large-scale vertical backscatter structure in the upper troposphere and lower stratosphere, and differences in the spatial resolution, detection threshold, and noise estimation for the two lidars.

  2. Laser ablation-inductively coupled plasma-mass spectrometry: Examinations of the origins of polyatomic ions and advances in the sampling of particulates

    SciTech Connect (OSTI)

    Witte, Travis

    2011-11-30

    This dissertation provides a general introduction to Inductively coupled plasma-mass spectrometry (ICP-MS) and laser ablation (LA) sampling, with an examination of analytical challenges in the employment of this technique. It discusses the origin of metal oxide ions (MO+) in LA-ICP-MS, as well as the effect of introducing helium and nitrogen to the aerosol gas flow on the formation of these polyatomic interferences. It extends the study of polyatomic ions in LA-ICP-MS to metal argide (MAr+) species, an additional source of possible significant interferences in the spectrum. It describes the application of fs-LA-ICP-MS to the determination of uranium isotope ratios in particulate samples.

  3. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  4. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratorys monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  5. Users guide for the conversion of Navy paint-spray-booth particulate emission-control systems from wet to dry operation. Final report, January-September 1989

    SciTech Connect (OSTI)

    Ayer, J.; Tate, D.

    1990-03-01

    The report is a guide for converting U.S. Navy paint-spray-booth particulate emission control systems from wet to dry operation. The use of water curtains for air-pollution-control of paint-spray booths is considered a major source of water and solid-waste pollution from industrial painting operations. It is possible, however, to eliminate this water-pollution problem and significantly reduce the solid-waste load by converting the booth to utilize a dry-filter pollution-control system. The conversion, however, requires extensive planning prior to actual facility modification. The report describes requirements to facilitate the planning and preparation for conversion of typical spray booths. Although the report addresses modifications of Navy spray booths, the basic engineering requirements discussed apply also to other Department of Defense installations and to commercial industrial facilities.

  6. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  7. Barrow Black Carbon Source and Impact Study Final Campaign Report

    SciTech Connect (OSTI)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact (BBCSI) Study was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement site in Barrow, AK. The carbonaceous component was characterized via measurement of the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the particulate matter, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine (PM2.5) and 49 coarse (PM10) particulate matter fractions were collected at weekly and bi-monthly intervals. The PM2.5 sampler operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the BBCSI used standard Tisch hi-vol motors which have a known lifetime of ~1 month under constant use; this necessitated monthly maintenance and it is suggested that the motors be upgraded to industrial blowers for future deployment in the Arctic. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric particulate matter samples from Barrow, AK from July 2012 to June 2013. Preliminary analysis of the organic and black carbon concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer.

  8. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  9. Volatile organic compound and particulate emission studies of AF (Air Force) paint-booth facilities. Phase 1. Final report, February-December 1987

    SciTech Connect (OSTI)

    Ayer, J.; Wolbach, D.

    1988-07-01

    This study presents the results of volatile organic compound (VOC) and particulate emission surveys performed at three Air Force painting facilities. The three facilities -- one in McClellan AFB buildings 655 and two at Travis AFB in buildings 550 and 1014 -- did not meet local VOC emission standards. The possibility of reducing these emissions with recirculation modifications and various VOC reduction and control strategies is discussed. Although VOC emissions from paint spray booths can be controlled by add-on control systems, control is expensive for present air flow rates. The use of air recirculation within the spray booth can reduce the cost of VOC emission controls by reducing the quantity of air that requires processing. Recirculation systems were designed for two of the painting facilities included in this study. In designing the systems, various criteria such as paint booth VOC concentrations and health and safety standards were considered. Add-on VOC emission-control systems that can be used in conjunction with the recirculation system are evaluated. The devices of interest are a solvent incineration system and an activated-carbon adsorption bed. The VOC removal efficiency, initial capital investment and operating costs for both of these technologies are discussed.

  10. WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lowe, Douglas; Archer-Nicholls, Scott; Morgan, Will; Allan, James D.; Utembe, Steve; Ouyang, Bin; Aruffo, Eleonora; Le Breton, Michael; Zaveri, Rahul A.; di Carlo, Piero; et al

    2015-02-09

    Chemical modelling studies have been conducted over north-western Europe in summer conditions, showing that night-time dinitrogen pentoxide (N2O5) heterogeneous reactive uptake is important regionally in modulating particulate nitrate and has a~modest influence on oxidative chemistry. Results from Weather Research and Forecasting model with Chemistry (WRF-Chem) model simulations, run with a detailed volatile organic compound (VOC) gas-phase chemistry scheme and the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) sectional aerosol scheme, were compared with a series of airborne gas and particulate measurements made over the UK in July 2010. Modelled mixing ratios of key gas-phase species were reasonably accurate (correlationsmore » with measurements of 0.7–0.9 for NO2 and O3). However modelled loadings of particulate species were less accurate (correlation with measurements for particulate sulfate and ammonium were between 0.0 and 0.6). Sulfate mass loadings were particularly low (modelled means of 0.5–0.7 μg kg−1air, compared with measurements of 1.0–1.5 μg kg−1air). Two flights from the campaign were used as test cases – one with low relative humidity (RH) (60–70%), the other with high RH (80–90%). N2O5 heterogeneous chemistry was found to not be important in the low-RH test case; but in the high-RH test case it had a strong effect and significantly improved the agreement between modelled and measured NO3 and N2O5. When the model failed to capture atmospheric RH correctly, the modelled NO3 and N2O5 mixing ratios for these flights differed significantly from the measurements. This demonstrates that, for regional modelling which involves heterogeneous processes, it is essential to capture the ambient temperature and water vapour profiles. The night-time NO3 oxidation of VOCs across the whole region was found to be 100–300 times slower than the daytime OH oxidation of these compounds. The difference in contribution was less for alkenes (× 80) and comparable for dimethylsulfide (DMS). However the suppression of NO3 mixing ratios across the domain by N2O5 heterogeneous chemistry has only a very slight, negative, influence on this oxidative capacity. The influence on regional particulate nitrate mass loadings is stronger. Night-time N2O5 heterogeneous chemistry maintains the production of particulate nitrate within polluted regions: when this process is taken into consideration, the daytime peak (for the 95th percentile) of PM10 nitrate mass loadings remains around 5.6 μg kg−1air, but the night-time minimum increases from 3.5 to 4.6 μg kg−1air. The sustaining of higher particulate mass loadings through the night by this process improves model skill at matching measured aerosol nitrate diurnal cycles and will negatively impact on regional air quality, requiring this process to be included in regional models.« less

  11. Shape-selective catalysts for Fischer-Tropsch chemistry : iron-containing particulate catalysts. Activity report : January 1, 2001 - December 31, 2004.

    SciTech Connect (OSTI)

    Cronauer, D.; Chemical Engineering

    2006-05-12

    Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry--specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. It is desired that selectivity be directed toward producing diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. The goal is to produce shape-selective catalysts that have the potential to limit the formation of longchain products and yet retain the active metal sites in a protected 'cage'. This cage also restricts their loss by attrition during use in slurry-bed reactors. The first stage of this program was to prepare and evaluate iron-containing particulate catalysts. This activity report centers upon this first stage of experimentation with particulate FT catalysts. (For reference, a second experimental stage is under way to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes.) To date, experimentation has centered upon the evaluation of a sample of iron-based, spray-dried catalyst prepared by B.H. Davis of the Center of Applied Energy Research (CAER) and samples of his catalyst onto which inorganic 'shells' were deposited. The reference CAER catalyst contained a high level of dispersed fine particles, a portion of which was removed by differential settling. Reaction conditions have been established using a FT laboratory unit such that reasonable levels of CO conversion can be achieved, where therefore a valid catalyst comparison can be made. A wide range of catalytic activities was observed with SiO{sub 2}-coated FT catalysts. Two techniques were used for SiO{sub 2}coating. The first involved a caustic precipitation of SiO{sub 2} from an organo-silicate onto the CAER catalyst. The second was the acidic precipitation of an organo-silicate with aging to form fractal particles that were then deposited onto the CAER catalyst. Several resulting FT catalysts were as active as the coarse catalyst on which they were prepared. The most active ones were those with the least amount of coating, namely about 2.2 wt% SiO{sub 2}. In the case of the latter acid technique, the use of HCl and HNO{sub 3} was much more effective than that of H{sub 2}SO{sub 4}. Scanning electron microscopy (SEM) was used to observe and analyze as-received and treated FT catalysts. It was observed that (1) spherical particles of CAER FT catalyst were made up of agglomerates of particles that were, in turn, also agglomerates; (2) the spray drying process of CAER apparently concentrated the Si precursor at the surface during drying; (3) while SEM pointed out broad differences in the appearance of the prepared catalyst particles, there was little indication that the catalysts were being uniformly coated with a cage-like protective surface, with perhaps the exception of HNO{sub 3}-precipitated catalyst; and (4) there was only a limited penetration of carbon (i.e., CO) into the FT catalyst during the conditioning and FT reaction steps.

  12. Real-time measurements of particulate matter and polycyclic aromatic hydrocarbon emissions from stationary combustion sources used in oil and gas production

    SciTech Connect (OSTI)

    D. w. Hahn; K. r. Hencken; H. A. Johnsen; J. R. Ross; P. M. Walsh

    1998-12-10

    Particulate matter emissions and some components of the particles were measured in the exhaust from combustion equipment used in oil and gas production operations near Bakersfield, California. The combustion sources included a 22.5 MW (electric) turbine generator, a 342-Bhp rich-burn spark ignition engine, and a 50 million Btu/h steam generator, all fired using natural gas. The particle components and measurement techniques were as follows: (1) Calcium, magnesium, sodium, silicon, and iron were measured using laser-induced breakdown spectroscopy (LIBS), (2) particle-bound polycyclic aromatic hydrocarbons (PAH) were detected using the charge produced by photoionization, (3) particles having sizes between 0.1 and 7.5 {micro}m were counted using an instrument based on light scattering, and (4) total particulate matter was measured according to US EPA Method 5. Not all of the methods were applied to all of the sources. Measurements were also made in the ambient air near the combustion air inlets to the units, for comparison with the concentrations in the exhaust, but the inlet and outlet measurements were not done simultaneously. Calcium, sodium, and silicon were found in the exhaust from the steam generator at concentrations similar to those in the ambient air near the inlet to the burner. Sodium and silicon were observed in the engine exhaust at levels a factor of four higher than their concentrations in the air. The principal metal observed in the engine exhaust was calcium, a component of the lubricating oil, at a concentration of 11.6 {micro}g/m{sup 3}. The air entering the gas turbine is filtered, so the average concentrations of metals in the turbine exhaust under steady operating conditions were even lower than in the air. During start-up following a shut-down to wash the turbine, silicon and iron were the major species in the stack, at concentrations of 6.4 and 16.2 {micro}g/m{sup 3}, respectively. A possible source of silicon is the water injected into the turbine for NO{sub x} control. Iron-containing particles are expected to be scale from ferrous metals. A commercial photoelectric aerosol sensor was used to measure PAH adsorbed on particles in the exhaust from the steam generator and the rich-burn engine. The conversion of the instrument readings to PAH concentrations is dependent upon the specific distribution of PAH species present. Using the typical calibration factor recommended by the instrument manufacturer, the estimated average concentration of particle-bound PAH was below the instrument detection limit (3--10 ng/m{sup 3}) in the stack gas from the steam generator, and was estimated to be 0.045--0.15 {micro}g/m{sup 3} in the exhaust from the rich-burn engine. Particle mass concentrations estimated from number concentrations determined using the particle counting and sizing instrument were only small fractions of the concentrations measured using Method 5. This is thought to be due primarily to the limited range over which size was quantified (0.1 to 7.5 {micro}m) and the poor efficiency with which the sampling system transferred large particles.

  13. Alternatives to diesel fuel in California - fuel cycle energy and emission effects of possible replacements due to the TAC diesel particulate decision.

    SciTech Connect (OSTI)

    Saricks, C. L.; Rote, D. M.; Stodolsky, F.; Eberhardt, J. J.

    1999-12-03

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible mid-course strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression-ignition by spark-ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21% above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7% above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case the authors estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOX emissions, though all scenarios bring about PM{sub 10} reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  14. Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler

    SciTech Connect (OSTI)

    Sen Li; Chin-Min Cheng; Bobby Chen; Yan Cao; Jacob Vervynckt; Amanda Adebambo; Wei-Ping Pan

    2007-12-15

    The properties of fly ash in coal-fired boilers influence the emission of mercury from power plants into the environment. In this study, seven different bituminous coals were burned in a full-scale 100 MWe pulverized coal combustion boiler and the derived fly ash samples were collected from a mechanical hopper (MH) and an electrostatic precipitator hopper (ESP). The mercury content, specific surface area (SSA), unburned carbon, and elemental composition of the fly ash samples were analyzed to evaluate the correlation between the concentration of particulate-bound mercury and the properties of coal and fly ash. For a given coal, it was found that the mercury content in the fly ash collected from the ESP was greater than in the fly ash samples collected from the MHP. This phenomenon may be due to a lower temperature of flue gas at the ESP (about 135{sup o}C) compared to the temperature at the air preheater (about 350{sup o}C). Also, a significantly lower SSA observed in MH ash might also contribute to the observation. A comparison of the fly ash samples generated from seven different coals using statistical methods indicates that the mercury adsorbed on ESP fly ashes has a highly positive correlation with the unburned carbon content, manganese content, and SSA of the fly ash. Sulfur content in coal showed a significant negative correlation with the Hg adsorption. Manganese in fly ash is believed to participate in oxidizing volatile elemental mercury (Hg{sup 0}) to ionic mercury (Hg{sup 2+}). The oxidized mercury in flue gas can form a complex with the fly ash and then get removed before the flue gas leaves the stack of the boiler.

  15. Documenting the Effectiveness of Cosorption of Airborne Contaminants by a Field-Installed Active Desiccant System: Final Report - Phase 2D

    SciTech Connect (OSTI)

    Fischer, J

    2003-01-23

    The final report for Phase 1 of this research effort (ORNL/SUB/94-SV004/1) concluded that a significant market opportunity would exist for active desiccant systems if it could be demonstrated that they can remove a significant proportion of common airborne contaminants while simultaneously performing the primary function of dehumidifying a stream of outdoor air or recirculated building air. If the engineering community begins to follow the intent of ASHRAE Standard 62, now part of all major building codes, the outdoor air in many major cities may need to be pre-cleaned before it is introduced into occupied spaces. Common air contaminant cosorption capability would provide a solution to three important aspects of the ASHRAE 62-89 standard that have yet to be effectively addressed by heating, ventilation, and air-conditioning (HVAC) equipment manufacturers: (1) The ASHRAE standard defines acceptable outdoor air quality. If the outdoor air contains unacceptable levels of certain common outdoor air contaminants (e.g., sulfur dioxide, ozone), then the standard requires that these contaminants be removed from the outdoor air stream to reach compliance with the acceptable outdoor air quality guidelines. (2) Some engineers prefer to apply a filtration or prescriptive approach rather than a ventilation approach to solving indoor air quality problems. The ASHRAE standard recognizes this approach provided that the filtration technology exists to remove the gaseous contaminants encountered. The performance of current gaseous filtration technologies is not well documented, and they can be costly to maintain because the life of the filter is limited and the cost is high. Moreover, it is not easy to determine when the filters need changing. In such applications, an additional advantage provided by the active desiccant system would be that the same piece of equipment could control space humidity and provide filtration, even during unoccupied periods, if the active desiccant system were operated in a recirculation mode. (3) Almost all major medical, university, and research facilities face the dilemma that the air exhausted from a building exits near the intake of another building. As a result, contaminants exhausted outdoors are pulled back into the same or an adjacent building. The removal of contaminants from outdoor air that an active desiccant system offers would be attractive to applications in such cases. The primary objective of this research project was to quantify the ability of the SEMCO composite desiccant dehumidification wheel to purify outdoor and recirculated air streams by removing gaseous contaminants commonly encountered in actual applications. This contaminant removal is provided simultaneously with dehumidification (removing the latent load) of these air streams at conditions encountered in HVAC applications. This research builds upon initial seed work completed by the Georgia Tech Research Institute (GTRI) during 1993 (Bayer and Downing 1993).

  16. Particulate Generation in Tritium Systems

    Office of Environmental Management (EM)

    3.1 wt% Fluoride 24 wt% Ammonium 11 wt% Chloride 0.1 wt% SubTotal 41.7 wt % Dirtcorrosion 3 wt % Degraded Teflon 55.7% Total 100% Analytical Methods: ICP-ES on an aqua-regia...

  17. Photocatalytic hydrogen production using visible-light-responsive Ta{sub 3}N{sub 5} photocatalyst supported on monodisperse spherical SiO{sub 2} particulates

    SciTech Connect (OSTI)

    Liu, Xiaoming; Zhao, Lan; Domen, Kazunari; Takanabe, Kazuhiro

    2014-01-01

    Graphical abstract: A simple and effective solgel process followed by nitridation in an NH{sub 3} flow has been developed to deposit Ta{sub 3}N{sub 5} semiconductor photocatalyst layers onto monodisperse spherical SiO{sub 2} particles. The obtained Ta{sub 3}N{sub 5}/SiO{sub 2} particles maintain an original spherical morphology of SiO{sub 2} and a sub-micrometer size with a narrow size distribution and without aggregation. The presence of SiO{sub 2} support shows at least no detrimental effects on photocatalytic activity, but tunes the secondary particle size to control dispersibility of the photocatalyst in the solution. - Highlights: Fine nanoparticles of Ta{sub 3}N{sub 5} were immobilized on the surfaces of SiO{sub 2} giving SiO{sub 2}@Ta{sub 3}N{sub 5} coreshell spheres successfully produced H{sub 2} from methanol solution under visible light. The presence of support (SiO{sub 2}) ensures the dispersion of the particulate in solution maintaining high photocatalytic activity of Ta{sub 3}N{sub 5}. The obtained supported photocatalyst gives uniform size distribution and control the degree of dispersibility in the solution, which may control nature of light absorption and reflection of the photoreactor. - Abstract: Fine nanoparticles of Ta{sub 3}N{sub 5} (1020 nm) were synthesized on the surfaces of SiO{sub 2} spheres with a diameter of ?550 nm. A solgel method was used to modify the surface of SiO{sub 2} with Ta{sub 2}O{sub 5} from TaCl{sub 5} dissolved in ethanol in the presence of citric acid and polyethylene glycol. The resulting oxide composites were treated in an NH{sub 3} flow at 1123 K to form coreshell structured Ta{sub 3}N{sub 5}/SiO{sub 2} sub-microspheres. The obtained samples were characterized using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDX), transmission electron microscopy (TEM), and photocatalytic activity measurements for H{sub 2} evolution from an aqueous methanol solution. The XRD results demonstrate the expected sequential formation of Ta{sub 2}O{sub 5} layers, followed by Ta{sub 3}N{sub 5} after nitridation on the Ta{sub 2}O{sub 5}/SiO{sub 2} composite. SEM and TEM observations indicate that the obtained Ta{sub 3}N{sub 5}/SiO{sub 2} sub-microspheres have a uniform size distribution with high crystallinity and an obvious coreshell structure. The presence of support maintained the intrinsic photocatalytic activity of Ta{sub 3}N{sub 5} nanoparticles, but it did drastically improve the dispersion of the photocatalysts in the solution. This study proposes the use of an inert support in photocatalytic reactors to improve ease of handling the powder photocatalyst for gas-phase photocatalysis and the suspension of the solution, controlling nature of light harvesting and degree of scattering of the photoreactor.

  18. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    receives and preprocesses Radio Frequency (RF) echo returns, and produces the raw phase history data for the radar. It includes processors which control and service all real-time...

  19. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platforms Sky Spirit Mini Unmanned Aerial Vehicle (UAV) Sky Spirit Mini Unmanned Aerial Vehicle (UAV) TigerShark Unmanned Aerial Vehicle (UAV) TigerShark Unmanned Aerial Vehicle...

  20. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    raise image quality, and advance real-time on-board processing, Sandia has been ... Key Products RADARs (Multimode, Real-Time, High Resolution) Sandia delivers pathfinder ...

  1. Real-time airborne particle analyzer

    DOE Patents [OSTI]

    Reilly, Peter T.A.

    2012-10-16

    An aerosol particle analyzer includes a laser ablation chamber, a gas-filled conduit, and a mass spectrometer. The laser ablation chamber can be operated at a low pressure, which can be from 0.1 mTorr to 30 mTorr. The ablated ions are transferred into a gas-filled conduit. The gas-filled conduit reduces the electrical charge and the speed of ablated ions as they collide and mix with buffer gases in the gas-filled conduit. Preferably, the gas filled-conduit includes an electromagnetic multipole structure that collimates the nascent ions into a beam, which is guided into the mass spectrometer. Because the gas-filled conduit allows storage of vast quantities of the ions from the ablated particles, the ions from a single ablated particle can be analyzed multiple times and by a variety of techniques to supply statistically meaningful analysis of composition and isotope ratios.

  2. RADIOACTIVE-AIRBORNE-CONTAMINATION-SURVEY.pdf

    Energy Savers [EERE]

  3. Airborne Gravity Survey | Open Energy Information

    Open Energy Info (EERE)

    Gravity Techniques Information Provided by Technique Lithology: Distribution of density in the subsurface enables inference of rock type. StratigraphicStructural:...

  4. Airborne Electromagnetic Survey | Open Energy Information

    Open Energy Info (EERE)

    content StratigraphicStructural: Hydrological: can be used to detect changes in density of fluids and indicate if there is salt water intrusion Thermal: Cost Information...

  5. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the exponentially growing magnitude of Intelligence, Surveillance and Reconnaissance (ISR) data volumes. Sandia's expertise enables predictive rather than reactive Intelligence,...

  6. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aperture Radar (SAR)? What is Synthetic Aperture Radar? Environmental monitoring, earth-resource mapping, and military systems require broad-area imaging at high...

  7. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for facilities and border protection missions, including the ability to identify security threats along the border. Crevasse Detection Using Sandia's MiniSAR technology,...

  8. High-performance computing for airborne applications

    SciTech Connect (OSTI)

    Quinn, Heather M; Manuzzato, Andrea; Fairbanks, Tom; Dallmann, Nicholas; Desgeorges, Rose

    2010-06-28

    Recently, there has been attempts to move common satellite tasks to unmanned aerial vehicles (UAVs). UAVs are significantly cheaper to buy than satellites and easier to deploy on an as-needed basis. The more benign radiation environment also allows for an aggressive adoption of state-of-the-art commercial computational devices, which increases the amount of data that can be collected. There are a number of commercial computing devices currently available that are well-suited to high-performance computing. These devices range from specialized computational devices, such as field-programmable gate arrays (FPGAs) and digital signal processors (DSPs), to traditional computing platforms, such as microprocessors. Even though the radiation environment is relatively benign, these devices could be susceptible to single-event effects. In this paper, we will present radiation data for high-performance computing devices in a accelerated neutron environment. These devices include a multi-core digital signal processor, two field-programmable gate arrays, and a microprocessor. From these results, we found that all of these devices are suitable for many airplane environments without reliability problems.

  9. Sandia National Laboratories: Pathfinder Airborne ISR Systems...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    antenna broadside to the platform track. A stripmap is an image typically formed parallel to the aircraft ground track that can be as long as the user desires. Stripmap...

  10. Airborne electromagnetic surveys as a reconnaissance technique...

    Open Energy Info (EERE)

    it was thought that a shallow exploration technique would not be effective. Extensive audio-magnetotelluric (AMT) work by the USGS in KGRA's showed that many geothermal systems...

  11. Particulate Matter Characteristics for Highly Dilute Stoichiometric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon p-24storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion Technologies on...

  12. Particulate and droplet diagnostics in spray combustion

    SciTech Connect (OSTI)

    Semerjian, H.G.

    1986-07-01

    There is a critical need for detailed data on the structure of spray flames, including information on the particle field, droplets, velocity and temperature fields, as well as gaseous species concentrations. The objective of this project is to obtain such a comprehensive data base, as a complementary effort to the spray modelling work being carried out at JPL and LANL. In addition, this study will provide data on the effect of fuel properties and flow field characteristics on the spray combustion processes. Finally, this research effort will focus on identification of the most important sub-processes, such as droplet vaporization, droplet-droplet interactions, droplet-air interactions, radiative energy transfer, etc., which have the greatest impact on the overall characteristics of spray flames. 57 refs., 18 figs., 2 tabs.

  13. Sandia Energy - Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of solid fuels such as coal and biomass. Recent research in the MFC has focused on char-NOx formation and reburn (Figure 2), NOx formation during oxy-fuel combustion of pulverized...

  14. Emission abatement system utilizing particulate traps

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2004-04-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  15. Development and Applications of Catalyzed Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ Optical Analysis of Ash Formation and Transport Controlled Experiments on the Effects of LubricantAdditive (Low-Ash, Ashless) Characteristics on DPF Degradation

  16. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, E.L.; Scharff, R.P.; Bauman, B.D.; Williams, M.A.

    1995-01-17

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figures.

  17. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    Bauman, Bernard D.; Williams, Mark A.; Bagheri, Reza

    1997-12-02

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

  18. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    Bauman, Bernard D.; Williams, Mark A.

    1999-01-01

    A plastic article having a number of surfaces with at least one surface being modified by contacting that surface with a reactive gas atmosphere containing F.sub.2, Cl.sub.2, O.sub.2, Ozone, SO.sub.3, oxidative acids, or mixtures thereof, at a temperature and gas partial pressure sufficient to increase the surface energy of the at least one surface being modified to at least 40 dynes/cm at a temperature of 20.degree. C., to enhance bonding of non-slip polymer coatings to the modified surface, to which coatings elastomeric or rigid particles may be admixed for imparting a surface profile and increasing the coefficient of friction between the coated surface and the counter-surface.

  19. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    Bauman, B.D.; Williams, M.A.; Bagheri, R.

    1997-12-02

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.

  20. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, E.L.; Bauman, B.D.; Williams, M.A.

    1996-04-09

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.