National Library of Energy BETA

Sample records for air oxidation wao

  1. Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for

    Energy Savers [EERE]

    Tank 48H Treatment Project (TTP) | Department of Energy Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Wet Air Oxidation. PDF icon Technology Maturation Plan (TMP) Wet Air Oxidation (WAO)

  2. Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology...

    Office of Environmental Management (EM)

    Westinghouse Savannah River Company LLC Savannah River Site Aiken, SC 29808 ... Waste Treatment and Immobilization Plant. 1 The proposed testing, costs and ...

  3. DESTRUCTION OF TETRAPHENYLBORATE IN TANK 48H USING WET AIR OXIDATION BATCH BENCH SCALE AUTOCLAVE TESTING WITH ACTUAL RADIOACTIVE TANK 48H WASTE

    SciTech Connect (OSTI)

    Adu-Wusu, K; Paul Burket, P

    2009-03-31

    Wet Air Oxidation (WAO) is one of the two technologies being considered for the destruction of Tetraphenylborate (TPB) in Tank 48H. Batch bench-scale autoclave testing with radioactive (actual) Tank 48H waste is among the tests required in the WAO Technology Maturation Plan. The goal of the autoclave testing is to validate that the simulant being used for extensive WAO vendor testing adequately represents the Tank 48H waste. The test objective was to demonstrate comparable test results when running simulated waste and real waste under similar test conditions. Specifically: (1) Confirm the TPB destruction efficiency and rate (same reaction times) obtained from comparable simulant tests, (2) Determine the destruction efficiency of other organics including biphenyl, (3) Identify and quantify the reaction byproducts, and (4) Determine off-gas composition. Batch bench-scale stirred autoclave tests were conducted with simulated and actual Tank 48H wastes at SRNL. Experimental conditions were chosen based on continuous-flow pilot-scale simulant testing performed at Siemens Water Technologies Corporation (SWT) in Rothschild, Wisconsin. The following items were demonstrated as a result of this testing. (1) Tetraphenylborate was destroyed to below detection limits during the 1-hour reaction time at 280 C. Destruction efficiency of TPB was > 99.997%. (2) Other organics (TPB associated compounds), except biphenyl, were destroyed to below their respective detection limits. Biphenyl was partially destroyed in the process, mainly due to its propensity to reside in the vapor phase during the WAO reaction. Biphenyl is expected to be removed in the gas phase during the actual process, which is a continuous-flow system. (3) Reaction byproducts, remnants of MST, and the PUREX sludge, were characterized in this work. Radioactive species, such as Pu, Sr-90 and Cs-137 were quantified in the filtrate and slurry samples. Notably, Cs-137, boron and potassium were shown as soluble as a result of the WAO reaction. (4) Off-gas composition was measured in the resulting gas phase from the reaction. Benzene and hydrogen were formed during the reaction, but they were reasonably low in the off-gas at 0.096 and 0.0063 vol% respectively. Considering the consistency in replicating similar test results with simulated waste and Tank 48H waste under similar test conditions, the results confirm the validity of the simulant for other WAO test conditions.

  4. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Print Organic aerosols (nanometer-sized liquid or solid particles suspended in air) are important constituents of the troposphere, and ...

  5. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Aerosol Oxidation Speeds Up in Smoggy Air Print Wednesday, 17 February 2016 11:37 Organic aerosols (nanometer-sized liquid or solid ...

  6. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Aerosol Oxidation Speeds Up in Smoggy Air Print Wednesday, 17 February 2016 11:37 Organic aerosols (nanometer-sized liquid or solid particles suspended in air) are important constituents of the troposphere, and their chemistry has large-scale impacts on climate, pollution, and health. Accurate predictions of these aerosol impacts require a robust microphysical understanding of all relevant chemical reaction mechanisms and time scales, including those

  7. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Print Organic aerosols (nanometer-sized liquid or solid particles suspended in air) are important constituents of the troposphere, and their chemistry has large-scale impacts on climate, pollution, and health. Accurate predictions of these aerosol impacts require a robust microphysical understanding of all relevant chemical reaction mechanisms and time scales, including those involving highly reactive free-radical molecules. However, detailed modeling is

  8. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Print Organic aerosols (nanometer-sized liquid or solid particles suspended in air) are important constituents of the troposphere, and their chemistry has large-scale impacts on climate, pollution, and health. Accurate predictions of these aerosol impacts require a robust microphysical understanding of all relevant chemical reaction mechanisms and time scales, including those involving highly reactive free-radical molecules. However, detailed modeling is

  9. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Oxidation Speeds Up in Smoggy Air Print Organic aerosols (nanometer-sized liquid or solid particles suspended in air) are important constituents of the troposphere, and their chemistry has large-scale impacts on climate, pollution, and health. Accurate predictions of these aerosol impacts require a robust microphysical understanding of all relevant chemical reaction mechanisms and time scales, including those involving highly reactive free-radical molecules. However, detailed modeling is

  10. Oxide modified air electrode surface for high temperature electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar; Ruka, Roswell J.

    1992-01-01

    An electrochemical cell is made having a porous cermet electrode (16) and a porous lanthanum manganite electrode (14), with solid oxide electrolyte (15) between them, where the lanthanum manganite surface next to the electrolyte contains a thin discontinuous layer of high surface area cerium oxide and/or praseodymium oxide, preferably as discrete particles (30) in contact with the air electrode and electrolyte.

  11. Aerosol Oxidation Speeds Up in Smoggy Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Management Aerial Measuring System AMS Logo NNSA's Aerial Measuring System (AMS) provides specialized airborne radiation detection systems to provide real-time measurements of low levels of air and ground contamination. The AMS team consists of scientists, technicians, pilots, and ground support personnel. These trained experts are in charge of maintaining a state of readiness to respond to a radiological emergency at any time. The team is based out of Nellis Air Force Base in Las Vegas, Nevada,

  12. Biodegradation of air-oxidized Illinois No. 6 coal

    SciTech Connect (OSTI)

    Linehan, J.C.; Fredrickson, J.K.; Wilson, B.W.; Bean, R.M.; Stewart, D.L.; Thomas, B.L.; Campbell, J.A.; Franz, J.A.

    1988-09-01

    We have found that Illinois No. 6 coal, after an air-oxidation pretreatment, can be substantially biodegraded by Penicillium sp. to a product largely soluble in dilute base. It is the purpose of this paper to describe the chemical nature of the biotreated Illinois No. 6 coal and to compare it with the corresponding material from leonardite biosolubilization. 12 refs., 7 figs., 3 tabs.

  13. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, Lewis; Ruka, Roswell J.; Singhal, Subhash C.

    1999-01-01

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell.

  14. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, L.; Ruka, R.J.; Singhal, S.C.

    1999-08-03

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO{sub 3}. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell. 3 figs.

  15. Air feed tube support system for a solid oxide fuel cell generator

    DOE Patents [OSTI]

    Doshi, Vinod B. (Monroeville, PA); Ruka, Roswell J. (Pittsburgh, PA); Hager, Charles A. (Zelienople, PA)

    2002-01-01

    A solid oxide fuel cell generator (12), containing tubular fuel cells (36) with interior air electrodes (18), where a supporting member (82) containing a plurality of holes (26) supports oxidant feed tubes (51), which pass from an oxidant plenum (52") into the center of the fuel cells, through the holes (26) in the supporting member (82), where a compliant gasket (86) around the top of the oxidant feed tubes and on top (28) of the supporting member (82) helps support the oxidant feed tubes and center them within the fuel cells, and loosen the tolerance for centering the air feed tubes.

  16. Laboratory flammability studies of mixtures of hydrogen, nitrous oxide, and air

    SciTech Connect (OSTI)

    Cashdollar, K L; Hertzberg, M; Zlochower, I A; Lucci, C E; Green, G M; Thomas, R A

    1992-06-26

    At the request of the Department of Energy and the Westinghouse Hanford Company, the Bureau of Mines has investigated the flammability of mixtures of hydrogen, nitrous oxide, and air. This work is relevant to the possible hazards of flammable gas generation from nuclear waste tanks at Hanford, WA. The tests were performed in a 120-L spherical chamber under both quiescent and turbulent conditions using both electric spark and pyrotechnic ignition sources. The data reported here for binary mixtures of hydrogen in air generally confirm the data of previous investigators, but they are more comprehensive than those reported previously. The results clarify to a greater extent the complications associated with buoyancy, turbulence, and selective diffusion. The data reported here for ternary mixtures of hydrogen and nitrous oxide in air indicate that small additions of nitrous oxide (relative to the amount of air) have little effect, but that higher concentrations of nitrous oxide (relative to air) significantly increase the explosion hazard.

  17. Pressurized solid oxide fuel cell integral air accumular containment

    DOE Patents [OSTI]

    Gillett, James E.; Zafred, Paolo R.; Basel, Richard A.

    2004-02-10

    A fuel cell generator apparatus contains at least one fuel cell subassembly module in a module housing, where the housing is surrounded by a pressure vessel such that there is an air accumulator space, where the apparatus is associated with an air compressor of a turbine/generator/air compressor system, where pressurized air from the compressor passes into the space and occupies the space and then flows to the fuel cells in the subassembly module, where the air accumulation space provides an accumulator to control any unreacted fuel gas that might flow from the module.

  18. Experimental Validation of Stratified Flow Phenomena, Graphite Oxidation, and Mitigation Strategies of Air Ingress Accidents

    SciTech Connect (OSTI)

    Chang Ho Oh; Eung Soo Kim; Hee Cheon No; Nam Zin Cho

    2008-12-01

    The US Department of Energy is performing research and development (R&D) that focuses on key phenomena that are important during challenging scenarios that may occur in the Next Generation Nuclear Plant (NGNP) Program / GEN-IV Very High Temperature Reactor (VHTR). Phenomena identification and ranking studies (PIRT) to date have identified the air ingress event, following on the heels of a VHTR depressurization, as very important (Schultz et al., 2006). Consequently, the development of advanced air ingress-related models and verification and validation (V&V) are very high priority for the NGNP program. Following a loss of coolant and system depressurization, air will enter the core through the break. Air ingress leads to oxidation of the in-core graphite structure and fuel. The oxidation will accelerate heat-up of the bottom reflector and the reactor core and will cause the release of fission products eventually. The potential collapse of the bottom reflector because of burn-off and the release of CO lead to serious safety problems. For estimation of the proper safety margin we need experimental data and tools, including accurate multi-dimensional thermal-hydraulic and reactor physics models, a burn-off model, and a fracture model. We also need to develop effective strategies to mitigate the effects of oxidation. The results from this research will provide crucial inputs to the INL NGNP/VHTR Methods R&D project. This project is focused on (a) analytical and experimental study of air ingress caused by density-driven, stratified, countercurrent flow, (b) advanced graphite oxidation experiments, (c) experimental study of burn-off in the bottom reflector, (d) structural tests of the burnt-off bottom reflector, (e) implementation of advanced models developed during the previous tasks into the GAMMA code, (f) full air ingress and oxidation mitigation analyses, (g) development of core neutronic models, (h) coupling of the core neutronic and thermal hydraulic models, and (i) verification and validation of the coupled models.

  19. Solid oxide fuel cell power plant having a fixed contact oxidation catalyzed section of a multi-section cathode air heat exchanger

    DOE Patents [OSTI]

    Saito, Kazuo; Lin, Yao

    2015-02-17

    The multi-section cathode air heat exchanger (102) includes at least a first heat exchanger section (104), and a fixed contact oxidation catalyzed section (126) secured adjacent each other in a stack association. Cool cathode inlet air flows through cool air channels (110) of the at least first (104) and oxidation catalyzed sections (126). Hot anode exhaust flows through hot air channels (124) of the oxidation catalyzed section (126) and is combusted therein. The combusted anode exhaust then flows through hot air channels (112) of the first section (104) of the cathode air heat exchanger (102). The cool and hot air channels (110, 112) are secured in direct heat exchange relationship with each other so that temperatures of the heat exchanger (102) do not exceed 800.degree. C. to minimize requirements for using expensive, high-temperature alloys.

  20. Solid oxide fuel cells, and air electrode and electrical interconnection materials therefor

    DOE Patents [OSTI]

    Bates, J.L.

    1992-09-01

    In one aspect of the invention, an air electrode material for a solid oxide fuel cell comprises Y[sub 1[minus]a]Q[sub a]MnO[sub 3], where Q is selected from the group consisting of Ca and Sr or mixtures thereof and a' is from 0.1 to 0.8. Preferably, a' is from 0.4 to 0.7. In another aspect of the invention, an electrical interconnection material for a solid oxide fuel cell comprises Y[sub 1[minus]b]Ca[sub b]Cr[sub 1[minus]c]Al[sub c]O[sub 3], where b' is from 0.1 to 0.6 and c' is from 0 to 9.3. Preferably, b' is from 0.3 to 0.5 and c' is from 0.05 to 0.1. A composite solid oxide electrochemical fuel cell incorporating these materials comprises: a solid oxide air electrode and an adjacent solid oxide electrical interconnection which commonly include the cation Y, the air electrode comprising Y[sub 1[minus]a]Q[sub a]MnO[sub 3], where Q is selected from the group consisting of Ca and Sr or mixtures thereof and a' is from 0.1 to 0.8, the electrical interconnection comprising Y[sub 1[minus]b]Ca[sub b]Cr[sub 1[minus]c]Al[sub c]O[sub 3], where b' is from 0.1 to 0.6 and c' is from 0.0 to 0.3; a yttrium stabilized solid electrolyte comprising (1[minus]d)ZrO[sub 2]-(d)Y[sub 2]O[sub 3] where d' is from 0.06 to 0.5; and a solid fuel electrode comprising X-ZrO[sub 2], where X' is an elemental metal. 5 figs.

  1. Solid oxide fuel cells, and air electrode and electrical interconnection materials therefor

    DOE Patents [OSTI]

    Bates, J. Lambert

    1992-01-01

    In one aspect of the invention, an air electrode material for a solid oxide fuel cell comprises Y.sub.1-a Q.sub.a MnO.sub.3, where "Q" is selected from the group consisting of Ca and Sr or mixtures thereof and "a" is from 0.1 to 0.8. Preferably, "a" is from 0.4 to 0.7. In another aspect of the invention, an electrical interconnection material for a solid oxide fuel cell comprises Y.sub.1-b Ca.sub.b Cr.sub.1-c Al.sub.c O.sub.3, where "b" is from 0.1 to 0.6 and "c" is from 0 to 9.3. Preferably, "b" is from 0.3 to 0.5 and "c" is from 0.05 to 0.1. A composite solid oxide electrochemical fuel cell incorporating these materials comprises: a solid oxide air electrode and an adjacent solid oxide electrical interconnection which commonly include the cation Y, the air electrode comprising Y.sub.1-a Q.sub.a MnO.sub.3, where "Q" is selected from the group consisting of Ca and Sr or mixtures thereof and "a" is from 0.1 to 0.8, the electrical interconnection comprising Y.sub.1-b Ca.sub.b Cr.sub.1-c Al.sub.c O.sub.3, where "b" is from 0.1 to 0.6 and "c" is from 0.0 to 0.3; a yttrium stabilized solid electrolyte comprising (1-d)ZrO.sub.2 -(d)Y.sub.2 O.sub.3 where "d" is from 0.06 to 0.5; and a solid fuel electrode comprising X-ZrO.sub.2, where "X" is an elemental metal.

  2. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, Lewis J. H.; Singh, Prabhakar; Ruka, Roswell J.; Vasilow, Theodore R.; Bratton, Raymond J.

    1997-01-01

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators.

  3. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, L.J.H.; Singh, P.; Ruka, R.J.; Vasilow, T.R.; Bratton, R.J.

    1997-11-11

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators. 4 figs.

  4. In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palm, B. B.; Campuzano-Jost, P.; Ortega, A. M.; Day, D. A.; Kaser, L.; Jud, W.; Karl, T.; Hansel, A.; Hunter, J. F.; Cross, E. S.; et al

    2015-11-04

    Ambient air was oxidized by OH radicals in an oxidation flow reactor (OFR) located in a montane pine forest during the BEACHON-RoMBAS campaign to study biogenic secondary organic aerosol (SOA) formation and aging. High OH concentrations and short residence times allowed for semi-continuous cycling through a large range of OH exposures ranging from hours to weeks of equivalent (eq.) atmospheric aging. A simple model is derived and used to account for the relative time scales of condensation of low volatility organic compounds (LVOCs) onto particles, condensational loss to the walls, and further reaction to produce volatile, non-condensing fragmentation products. MoremoreSOA production was observed in the OFR at nighttime (average 4 ?g m-3 when LVOC fate corrected) compared to daytime (average 1 ?g m-3 when LVOC fate corrected), with maximum formation observed at 0.41.5 eq. days of photochemical aging. SOA formation followed a similar diurnal pattern to monoterpenes, sesquiterpenes, and toluene + p-cymene concentrations, including a substantial increase just after sunrise at 07:00 LT. Higher photochemical aging (> 10 eq. days) led to a decrease in new SOA formation and a loss of preexisting OA due to heterogeneous oxidation followed by fragmentation and volatilization. When comparing two different commonly used methods of OH production in OFRs (OFR185 and OFR254), similar amounts of SOA formation were observed. We recommend the OFR185 mode for future forest studies. Concurrent gas-phase measurements of air after OH oxidation illustrate the decay of primary VOCs, production of small oxidized organic compounds, and net production at lower ages followed by net consumption of terpenoid oxidation products as photochemical age increased. New particle formation was observed in the reactor after oxidation, especially during times when precursor gas concentrations and SOA formation were largest. Approximately 6 times more SOA was formed in the reactor from OH oxidation than could be explained by the VOCs measured in ambient air. Several recently-developed instruments quantified ambient semi- and intermediate-volatility organic compounds (S/IVOCs) that were not detected by a PTR-TOF-MS. An SOA yield of 2480 % from those compounds can explain the observed SOA, suggesting that these typically unmeasured S/IVOCs play a substantial role in ambient SOA formation. Our results allow ruling out condensation sticking coefficients much lower than 1. Our measurements help clarify the magnitude of SOA formation in forested environments, and demonstrate methods for interpretation of ambient OFR measurements.less

  5. Cast Stone Oxidation Front Evaluation: Preliminary Results For Samples Exposed To Moist Air

    SciTech Connect (OSTI)

    Langton, C. A.; Almond, P. M.

    2013-11-26

    The rate of oxidation is important to the long-term performance of reducing salt waste forms because the solubility of some contaminants, e.g., technetium, is a function of oxidation state. TcO{sub 4}{sup −} in the salt solution is reduced to Tc(IV) and has been shown to react with ingredients in the waste form to precipitate low solubility sulfide and/or oxide phases. Upon exposure to oxygen, the compounds containing Tc(IV) oxidize to the pertechnetate ion, Tc(VII)O{sub 4}{sup −}, which is very soluble. Consequently the rate of technetium oxidation front advancement into a monolith and the technetium leaching profile as a function of depth from an exposed surface are important to waste form performance and ground water concentration predictions. An approach for measuring contaminant oxidation rate (effective contaminant specific oxidation rate) based on leaching of select contaminants of concern is described in this report. In addition, the relationship between reduction capacity and contaminant oxidation is addressed. Chromate (Cr(VI) was used as a non-radioactive surrogate for pertechnetate, Tc(VII), in Cast Stone samples prepared with 5 M Simulant. Cast Stone spiked with pertechnetate was also prepared and tested. Depth discrete subsamples spiked with Cr were cut from Cast Stone exposed to Savannah River Site (SRS) outdoor ambient temperature fluctuations and moist air. Depth discrete subsamples spiked with Tc-99 were cut from Cast Stone exposed to laboratory ambient temperature fluctuations and moist air. Similar conditions are expected to be encountered in the Cast Stone curing container. The leachability of Cr and Tc-99 and the reduction capacities, measured by the Angus-Glasser method, were determined for each subsample as a function of depth from the exposed surface. The results obtained to date were focused on continued method development and are preliminary and apply to the sample composition and curing / exposure conditions described in this report. The Cr oxidation front (depth to which soluble Cr was detected) for the Cast Stone sample exposed for 68 days to ambient outdoor temperatures and humid air (total age of sample was 131 days) was determined to be about 35 mm below the top sample surface exposed. The Tc oxidation front, depth at which Tc was insoluble, was not determined. Interpretation of the results indicates that the oxidation front is at least 38 mm below the exposed surface. The sample used for this measurement was exposed to ambient laboratory conditions and humid air for 50 days. The total age of the sample was 98 days. Technetium appears to be more easily oxidized than Cr in the Cast Stone matrix. The oxidized forms of Tc and Cr are soluble and therefore leachable. Longer exposure times are required for both the Cr and Tc spiked samples to better interpret the rate of oxidation. Tc spiked subsamples need to be taken further from the exposed surface to better define and interpret the leachable Tc profile. Finally Tc(VII) reduction to Tc(IV) appears to occur relatively fast. Results demonstrated that about 95 percent of the Tc(VII) was reduced to Tc(IV) during the setting and very early stage setting for a Cast Stone sample cured 10 days. Additional testing at longer curing times is required to determine whether additional time is required to reduce 100 % of the Tc(VII) in Cast Stone or whether the Tc loading exceeded the ability of the waste form to reduce 100 % of the Tc(VII). Additional testing is required for samples cured for longer times. Depth discrete subsampling in a nitrogen glove box is also required to determine whether the 5 percent Tc extracted from the subsamples was the result of the sampling process which took place in air. Reduction capacity measurements (per the Angus-Glasser method) performed on depth discrete samples could not be correlated with the amount of chromium or technetium leached from the depth discrete subsamples or with the oxidation front inferred from soluble chromium and technetium (i.e., effective Cr and Tc oxidation fronts). Residual reduction capacity in the oxidized region of the test samples indicates that the remaining reduction capacity is not effective in re-reducing Cr(VI) or Tc(VII) in the presence of oxygen. Depth discrete sampling and leaching is a useful for evaluating Cast Stone and other chemically reducing waste forms containing ground granulated blast furnace slag (GGBFS) or other reduction / sequestration reagents to control redox sensitive contaminant chemistry and leachability in the near surface disposal environment. Based on results presented in this report, reduction capacity measured by the Angus-Glasser Ce(IV) method is not an appropriate or meaningful parameter for determining or predicting Tc and Cr oxidation / retentions, speciation, or solubilities in cementitious materials such as Cast Stone. A model for predicting Tc(IV) oxidation to soluble Tc(VII) should consider the waste form porosity (pathway for oxygen ingress), oxygen source, and the contaminant specific oxidation rates and oxidation fronts. Depth discrete sampling of materials exposed to realistic conditions in combination with short term leaching of crushed samples has potential for advancing the understanding of factors influencing performance. This information can be used to support conceptual model development.

  6. Planar solid oxide fuel cell with staged indirect-internal air and fuel preheating and reformation

    DOE Patents [OSTI]

    2003-10-21

    A solid oxide fuel cell arrangement and method of use that provides internal preheating of both fuel and air in order to maintain the optimum operating temperature for the production of energy. The internal preheat passes are created by the addition of two plates, one on either side of the bipolar plate, such that these plates create additional passes through the fuel cell. This internal preheat fuel cell configuration and method reduce the requirements for external heat exchanger units and air compressors. Air or fuel may be added to the fuel cell as required to maintain the optimum operating temperature through a cathode control valve or an anode control valve, respectively. A control loop comprises a temperature sensing means within the preheat air and fuel passes, a means to compare the measured temperature to a set point temperature and a determination based on the comparison as to whether the control valves should allow additional air or fuel into the preheat or bypass manifolds of the fuel cell.

  7. OXIDATION OF INCONEL 718 IN AIR AT TEMPERATURES FROM 973K TO 1620K.

    SciTech Connect (OSTI)

    GREENE,G.A.; FINFROCK,C.C.

    2000-10-01

    As part of the APT project, it was necessary to quantify the release of tungsten from the APT spallation target during postulated accident conditions in order to develop accident source terms for accident consequence characterization. Experiments with tungsten rods at high temperatures in a flowing steam environment characteristic of postulated accidents revealed that considerable vaporization of the tungsten occurred as a result of reactions with the steam and that the aerosols which formed were readily transported away from the tungsten surfaces, thus exposing fresh tungsten to react with more steam. The resulting tungsten release fractions and source terms were undesirable and it was decided to clad the tungsten target with Inconel 718 in order to protect it from contact with steam during an accident and mitigate the accident source term and the consequences. As part of the material selection criteria, experiments were conducted with Inconel 718 at high temperatures to evaluate the rate of oxidation of the proposed clad material over as wide a temperature range as possible, as well as to determine the high-temperature failure limit of the material. Samples of Inconel 718 were inserted into a preheated furnace at temperatures ranging from 973 K to 1620 K and oxidized in air for varying periods of time. After oxidizing in air at a constant temperature for the prescribed time and then being allowed to cool, the samples would be reweighed to determine their weight gain due to the uptake of oxygen. From these weight gain measurements, it was possible to identify three regimes of oxidation for Inconel 718: a low-temperature regime in which the samples became passivated after the initial oxidation, an intermediate-temperature regime in which the rate of oxidation was limited by diffusion and exhibited a constant parabolic rate dependence, and a high-temperature regime in which material deformation and damage accompanied an accelerated oxidation rate above the parabolic regime. At temperatures below 1173 K, the rate of oxidation of the Inconel 718 surface was found to decrease markedly with time; the parabolic oxidation rate coefficient was not a constant but decreased with time. This was taken to indicate that the oxide film on the surface was having a passivating effect on oxygen transport through the oxide to the underlying metal. For temperatures in the range 1173 K to 1573 K, the time-dependent rate of oxidation as determined once again by weight-gain measurements was found to display the classical parabolic rate behavior, indicating that the rate of transport of reactants through the oxide was controlled by diffusion through the growing oxide layer. Parabolic rate coefficients were determined by least-squares analysis of time-dependent mass-gain data at 1173 K, 1273 K, 1373 K, 1473 K and 1573 K. At temperatures above 1540 K, post test examination of the oxidized samples revealed that the Inconel 718 began to lose strength and to deform. At 1540 K, samples which were suspended from their ends during testing began to demonstrate axial curvature as they lost strength and bowed under their own weight. As the temperatures of the tests were increased, rivulets were seen to appear on the surfaces of the test specimens; damage became severe at 1560 K. Although melting was never observed in any of these tests even up to. 1620 K, it was concluded from these data that the Inconel 718 clad should not be expected to protect the underlying tungsten at temperatures above 1540 K.

  8. Advanced regenerative thermal oxidation (RTO) technology for air toxics control - selected case histories

    SciTech Connect (OSTI)

    Seiwert, J.J. Jr.

    1997-12-31

    Advanced design regenerative thermal oxidation (RTO) systems have been developed and are in commercial scale use for control of process emissions containing air toxics (HAPs) and VOCs. High operating temperatures coupled with high thermal energy recovery efficiencies inherent with RTO technology provide for high destruction efficiencies while minimizing formation of objectionable combustion byproducts. These results are achieved with low system operating costs. This paper covers development of advanced design commercial RTO systems for control of air emissions from several important commercial processes: total reduced sulfur (TRS) and other HAPs/VOC emissions from pulp mill processes. Chlorinated organics and other HAPs/VOC emissions from pharmaceutical manufacturing operations. The data presented represent the first commercial scale application of RTO technology to abate emissions from these processes. Particular design features required for each specific process, in order to provide reliable, safe and effective systems, are reviewed. Emissions abatement performance, as well as operational data, are presented for the systems.

  9. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J.; Kuo, Lewis; Li, Baozhen

    1999-01-01

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La.sub.w Ca.sub.x Ln.sub.y Ce.sub.z MnO.sub.3, wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics.

  10. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Kuo, L.; Li, B.

    1999-06-29

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO[sub 3]. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La[sub w]Ca[sub x]Ln[sub y]Ce[sub z]MnO[sub 3], wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics. 10 figs.

  11. SPONTANEOUS CATALYTIC WET AIR OXIDATION DURING PRE-TREATMENT OF HIGH-LEVEL RADIOACTIVE WASTE SLUDGE

    SciTech Connect (OSTI)

    Koopman, D.; Herman, C.; Pareizs, J.; Bannochie, C.; Best, D.; Bibler, N.; Fellinger, T.

    2009-10-01

    Savannah River Remediation, LLC (SRR) operates the Defense Waste Processing Facility for the U.S. Department of Energy at the Savannah River Site. This facility immobilizes high-level radioactive waste through vitrification following chemical pretreatment. Catalytic destruction of formate and oxalate ions to carbon dioxide has been observed during qualification testing of non-radioactive analog systems. Carbon dioxide production greatly exceeded hydrogen production, indicating the occurrence of a process other than the catalytic decomposition of formic acid. Statistical modeling was used to relate the new reaction chemistry to partial catalytic wet air oxidation of both formate and oxalate ions driven by the low concentrations of palladium, rhodium, and/or ruthenium in the waste. Variations in process conditions led to increases or decreases in the total oxidative destruction, as well as partially shifting the preferred species undergoing destruction from oxalate ion to formate ion.

  12. FINAL REPORT on Experimental Validation of Stratified Flow Phenomena, Graphite Oxidation, and Mitigation Strategies of Air Ingress Accidents

    SciTech Connect (OSTI)

    Chang H. Oh; Eung S. Kim; Hee C. NO; Nam Z. Cho

    2011-01-01

    The U.S. Department of Energy is performing research and development that focuses on key phenomena that are important during challenging scenarios that may occur in the Next Generation Nuclear Plant (NGNP)/Generation IV very high temperature reactor (VHTR). Phenomena Identification and Ranking studies to date have identified the air ingress event, following on the heels of a VHTR depressurization, as very important. Consequently, the development of advanced air ingress-related models and verification & validation are of very high priority for the NGNP Project. Following a loss of coolant and system depressurization incident, air ingress will occur through the break, leading to oxidation of the in-core graphite structure and fuel. This study indicates that depending on the location and the size of the pipe break, the air ingress phenomena are different. In an effort to estimate the proper safety margin, experimental data and tools, including accurate multidimensional thermal-hydraulic and reactor physics models, a burn-off model, and a fracture model are required. It will also require effective strategies to mitigate the effects of oxidation, eventually. This 3-year project (FY 2008–FY 2010) is focused on various issues related to the VHTR air-ingress accident, including (a) analytical and experimental study of air ingress caused by density-driven, stratified, countercurrent flow, (b) advanced graphite oxidation experiments, (c) experimental study of burn-off in the core bottom structures, (d) structural tests of the oxidized core bottom structures, (e) implementation of advanced models developed during the previous tasks into the GAMMA code, (f) full air ingress and oxidation mitigation analyses, (g) development of core neutronic models, (h) coupling of the core neutronic and thermal hydraulic models, and (i) verification and validation of the coupled models.

  13. GENERATION, TRANSPORT AND DEPOSITION OF TUNGSTEN-OXIDE AEROSOLS AT 1000 C IN FLOWING AIR-STEAM MIXTURES.

    SciTech Connect (OSTI)

    GREENE,G.A.; FINFROCK,C.C.

    2001-10-01

    Experiments were conducted to measure the rates of oxidation and vaporization of pure tungsten rods in flowing air, steam and air-steam mixtures in laminar flow. Also measured were the downstream transport of tungsten-oxide condensation aerosols and their region of deposition, including plateout in the superheated flow tube, rainout in the condenser and ambient discharge which was collected on an array of sub-micron aerosol filters. The nominal conditions of the tests, with the exception of the first two tests, were tungsten temperatures of 1000 C, gas mixture temperatures of 200 C and wall temperatures of 150 C to 200 C. It was observed that the tungsten oxidation rates were greatest in all air and least in all steam, generally decreasing non-linearly with increasing steam mole fraction. The tungsten oxidation rates in all air were more than five times greater than the tungsten oxidation rates in all steam. The tungsten vaporization rate was zero in all air and increased with increasing steam mole fraction. The vaporization rate became maximum at a steam mole fraction of 0.85 and decreased thereafter as the steam mole fraction was increased to unity. The tungsten-oxide was transported downstream as condensation aerosols, initially flowing upwards from the tungsten rod through an 18-inch long, one-inch diameter quartz tube, around a 3.5-inch radius, 90{sup o} bend and laterally through a 24-inch horizontal run. The entire length of the quartz glass flow path was heated by electrical resistance clamshell heaters whose temperatures were individually controlled and measured. The tungsten-oxide plateout in the quartz tube was collected, nearly all of which was deposited at the end of the heated zone near the entrance to the condenser which was cold. The tungsten-oxide which rained out in the condenser as the steam condensed was collected with the condensate and weighed after being dried. The aerosol smoke which escaped the condenser was collected on the sub-micron filter assemblies. There was no aerosol generation for the case of all air, so the plateout, condensate and smoke were all zero. For the case of all steam, there was very little plateout in the superheated regions (several percent) and the rest of the aerosol was collected in the condensate from the condenser. There was no smoke discharge into the filters. For the experiments with intermediate air-steam fractions, there was some aerosol plateout, considerable aerosol in the condensate and aerosol smoke discharged from the condenser with the escaping air.

  14. Storage of LWR spent fuel in air: Volume 1: Design and operation of a spent fuel oxidation test facility

    SciTech Connect (OSTI)

    Thornhill, C.K.; Campbell, T.K.; Thornhill, R.E.

    1988-12-01

    This report describes the design and operation and technical accomplishments of a spent-fuel oxidation test facility at the Pacific Northwest Laboratory. The objective of the experiments conducted in this facility was to develop a data base for determining spent-fuel dry storage temperature limits by characterizing the oxidation behavior of light-water reactor (LWR) spent fuels in air. These data are needed to support licensing of dry storage in air as an alternative to spent-fuel storage in water pools. They are to be used to develop and validate predictive models of spent-fuel behavior during dry air storage in an Independent Spent Fuel Storage Installation (ISFSI). The present licensed alternative to pool storage of spent fuel is dry storage in an inert gas environment, which is called inerted dry storage (IDS). Licensed air storage, however, would not require monitoring for maintenance of an inert-gas environment (which IDS requires) but does require the development of allowable temperature limits below which UO/sub 2/ oxidation in breached fuel rods would not become a problem. Scoping tests at PNL with nonirradiated UO/sub 2/ pellets and spent-fuel fragment specimens identified the need for a statistically designed test matrix with test temperatures bounding anticipated maximum acceptable air-storage temperatures. This facility was designed and operated to satisfy that need. 7 refs.

  15. Short-Term Oxidation Studies on Nicrofer- 6025HT in Air at Elevated Temperatures for Advanced Coal Based Power Plants

    SciTech Connect (OSTI)

    Joshi, Vineet V.; Meier, Alan; Darsell, Jens T.; Nachimuthu, Ponnusamy; Bowden, Mark E.; Weil, K. Scott

    2013-04-01

    Several advanced air separation unit (ASU) designs being considered for use in coal gasification rely on the use of solid state mixed ionic and electronic conductors. Nicrofer-6025HT, a nickel-based alloy, has been identified as a potential manifold material to transport the hot gases into the ASUs. In the current study, isothermal oxidation tests were conducted on Nicrofer-6025HT in the temperature range of 700900 C for up to 24 h. The evolution of oxide scale was evaluated using SEM, XRD, and XPS. The composite surface oxide layer that formed consisted of an outer chromia-rich scale and an inner alumina scale. For the longer times at the higher temperatures evaluated, a NiCr2O4 spinel phase was located at the interface between the alumina and chromia. Based on the experimental results a four-step oxidation model was proposed.

  16. FY-09 Report: Experimental Validation of Stratified Flow Phenomena, Graphite Oxidation, and Mitigation Strategies of Air Ingress Accidents

    SciTech Connect (OSTI)

    Chang H. Oh; Eung S. Kim

    2009-12-01

    The Idaho National Laboratory (INL), under the auspices of the U.S. Department of Energy, is performing research and development that focuses on key phenomena important during potential scenarios that may occur in the Next Generation Nuclear Plant (NGNP)/Gen-IV very high temperature reactor (VHTR). Phenomena Identification and Ranking Studies to date have identified that an air ingress event following on the heels of a VHTR depressurization is a very important incident. Consequently, the development of advanced air ingress-related models and verification and validation data are a very high priority for the NGNP Project. Following a loss of coolant and system depressurization incident, air will enter the core through the break, leading to oxidation of the in-core graphite structure and fuel. If this accident occurs, the oxidation will accelerate heat-up of the bottom reflector and the reactor core and will eventually cause the release of fission products. The potential collapse of the core bottom structures causing the release of CO and fission products is one of the concerns. Therefore, experimental validation with the analytical model and computational fluid dynamic (CFD) model developed in this study is very important. Estimating the proper safety margin will require experimental data and tools, including accurate multidimensional thermal-hydraulic and reactor physics models, a burn-off model, and a fracture model. It will also require effective strategies to mitigate the effects of oxidation. The results from this research will provide crucial inputs to the INL NGNP/VHTR Methods Research and Development project. The second year of this three-year project (FY-08 to FY-10) was focused on (a) the analytical, CFD, and experimental study of air ingress caused by density-driven, stratified, countercurrent flow; (b) advanced graphite oxidation experiments and modeling; (c) experimental study of burn-off in the core bottom structures, (d) implementation of advanced graphite oxidation models into the GAMMA code, and (f) air ingress and oxidation mitigation analyses of the whole air-ingress scenario.

  17. Carvedilol alleviates adjuvant-induced arthritis and subcutaneous air pouch edema: Modulation of oxidative stress and inflammatory mediators

    SciTech Connect (OSTI)

    Arab, Hany H.; El-Sawalhi, Maha M.

    2013-04-15

    Rheumatoid arthritis (RA) is a systemic inflammatory disease with cardiovascular complications as the leading cause of morbidity. Carvedilol is an adrenergic antagonist which has been safely used in treatment of several cardiovascular disorders. Given that carvedilol has powerful antioxidant/anti-inflammatory properties, we aimed to investigate its protective potential against arthritis that may add further benefits for its clinical usefulness especially in RA patients with concomitant cardiovascular disorders. Two models were studied in the same rat; adjuvant arthritis and subcutaneous air pouch edema. Carvedilol (10 mg/kg/day p.o. for 21 days) effectively suppressed inflammation in both models with comparable efficacy to the standard anti-inflammatory diclofenac (5 mg/kg/day p.o.). Notably, carvedilol inhibited paw edema and abrogated the leukocyte invasion to air pouch exudates. The latter observation was confirmed by the histopathological assessment of the pouch lining that revealed mitigation of immuno-inflammatory cell influx. Carvedilol reduced/normalized oxidative stress markers (lipid peroxides, nitric oxide and protein thiols) and lowered the release of inflammatory cytokines (TNF-? and IL-6), and eicosanoids (PGE{sub 2} and LTB{sub 4}) in sera and exudates of arthritic rats. Interestingly, carvedilol, per se, didn't present any effect on assessed biochemical parameters in normal rats. Together, the current study highlights evidences for the promising anti-arthritic effects of carvedilol that could be mediated through attenuation of leukocyte migration, alleviation of oxidative stress and suppression of proinflammatory cytokines and eicosanoids. - Highlights: ? Carvedilol possesses promising anti-arthritic properties. ? It markedly suppressed inflammation in adjuvant arthritis and air pouch edema. ? It abrogated the leukocyte invasion to air pouch exudates and linings. ? It reduced/normalized oxidative stress markers in sera and exudates of arthritic rats. ? It also mitigated the release of proinflammatory cytokines and eicosanoids.

  18. Surface analysis of Zircaloy-2 implanted with carbon before and after oxidation in air at 500 deg. C

    SciTech Connect (OSTI)

    Peng, D.Q. . E-mail: pdq01@mails.tsinghua.edu.cn; Bai, X.D.; Pan, F.; Sun, H.; Chen, B.S.

    2006-03-15

    Zircaloy-2 specimens were implanted with carbon ions in the fluence range from 1 x 10{sup 16} to 1 x 10{sup 18} ions/cm{sup 2}, using a MEVVA source at an extraction voltage of 40 kV at a maximum temperature of 380 deg. C. The valences and depth profiles of elements in the implanted surface of Zircaloy-2 were analyzed by X-ray photoelectron spectroscopy and Auger electron spectroscopy, respectively. Scanning electron microscopy was used to examine the micro-morphology of samples. The color of the oxidized samples was checked with an optical scanner. Glancing-angle X-ray diffraction at 0.3{sup o} incident angles was employed to examine the phase transformations of implanted samples before and after oxidation in the air at 500 deg. C for 2 h. Before oxidation, at fluences less than 5 x 10{sup 16} ions/cm{sup 2}, hexagonal zirconia (H-ZrO{sub 0.35}) was present. At a fluence of 1 x 10{sup 17} ions/cm{sup 2}, rhombohedral zirconia (R-Zr{sub 3}O) appeared. When the fluence reached 1 x 10{sup 18} ions/cm{sup 2}, cubic zirconium carbide was produced. There are many pits, both deep and shallow, in the sample surfaces, both prior to oxidation and after oxidation. Oxidation in the air at 500 deg. C gave rise to black surfaces on all samples. The X-ray diffraction results showed that monoclinic and tetragonal zirconia were present in the surface of as-received sample. For implanted samples, monoclinic and tetragonal zirconia are still present, while cubic zirconium carbide is produced at all fluences. The presence of ZrC is attributed to the high-temperature, long-time (2 h) exposure.

  19. Stabilized three-stage oxidation of DME/air mixture in a micro flow reactor with a controlled temperature profile

    SciTech Connect (OSTI)

    Oshibe, Hiroshi; Nakamura, Hisashi; Tezuka, Takuya; Hasegawa, Susumu; Maruta, Kaoru

    2010-08-15

    Ignition and combustion characteristics of a stoichiometric dimethyl ether (DME)/air mixture in a micro flow reactor with a controlled temperature profile which was smoothly ramped from room temperature to ignition temperature were investigated. Special attention was paid to the multi-stage oxidation in low temperature condition. Normal stable flames in a mixture flow in the high velocity region, and non-stationary pulsating flames and/or repetitive extinction and ignition (FREI) in the medium velocity region were experimentally confirmed as expected from our previous study on a methane/air mixture. In addition, stable double weak flames were observed in the low velocity region for the present DME/air mixture case. It is the first observation of stable double flames by the present methodology. Gas sampling was conducted to obtain major species distributions in the flow reactor. The results indicated that existence of low-temperature oxidation was conjectured by the production of CH{sub 2}O occured in the upstream side of the experimental first luminous flame, while no chemiluminescence from it was seen. One-dimensional computation with detailed chemistry and transport was conducted. At low mixture velocities, three-stage oxidation was confirmed from profiles of the heat release rate and major chemical species, which was broadly in agreement with the experimental results. Since the present micro flow reactor with a controlled temperature profile successfully presented the multi-stage oxidations as spatially separated flames, it is shown that this flow reactor can be utilized as a methodology to separate sets of reactions, even for other practical fuels, at different temperature. (author)

  20. Final report on the oxidation of energetic materials in supercritical water. Final Air Force report

    SciTech Connect (OSTI)

    Buelow, S.J.; Allen, D.; Anderson, G.K.

    1995-04-03

    The objective of this project was to determine the suitability of oxidation in supercritical fluids (SCO), particularly water (SCWO), for disposal of propellants, explosives, and pyrotechnics (PEPs). The SCO studies of PEPs addressed the following issues: The efficiency of destruction of the substrate. The products of destruction contained in the effluents. Whether the process can be conducted safely on a large scale. Whether energy recovery from the process is economically practicable. The information essential for process development and equipment design was also investigated, including issues such as practical throughput of explosives through a SCWO reactor, reactor materials and corrosion, and models for process design and optimization.

  1. Oxide

    Energy Science and Technology Software Center (OSTI)

    2014-07-15

    Oxide is a modular framework for feature extraction and analysis of executable files. Oxide is useful in a variety of reverse engineering and categorization tasks relating to executable content.

  2. Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air

    DOE Patents [OSTI]

    Hanson, Susan Kloek; Silks, Louis A; Wu, Ruilian

    2013-08-27

    The invention concerns processes for oxidizing an alcohol to produce a carbonyl compound. The processes comprise contacting the alcohol with (i) a gaseous mixture comprising oxygen; and (ii) an amine compound in the presence of a catalyst, having the formula: ##STR00001## where each of R.sup.1-R.sup.12 are independently H, alkyl, aryl, CF.sub.3, halogen, OR.sup.13, SO.sub.3R.sup.14, C(O)R.sup.15, CONR.sup.16R.sup.17 or CO.sub.2R.sup.18; each of R.sup.13-R.sup.18 is independently alkyl or aryl; and Z is alkl or aryl.

  3. Long-Term Oxidation of Candidate Cast Iron and Advanced Austenitic Stainless Steel Exhaust System Alloys from 650-800 C in Air with Water Vapor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, Michael P; Muralidharan, Govindarajan; Leonard, Donovan N; Haynes, James A

    2014-01-01

    The oxidation behavior of SiMo cast iron, Ni-resist D5S cast iron, cast chromia-forming austenitic stainless steels of varying Cr/Ni content based on CF8C plus, HK, and HP, and a developmental cast alumina-forming austenitic (AFA) stainless steel of interest for diesel exhaust system components were studied for up to 5000 h at 650-800 C in air with 10% H2O. At 650 C, the Ni-resist D5S exhibited moderately better oxidation resistance than did the SiMo cast iron. However, the D5S suffered from oxide scale spallation issues at 700 C and higher, whereas the oxide scales formed on SiMo cast iron remained adherentmore » from 700-800 C despite oxide scales hundreds of microns thick. The oxidation of the SiMo cast iron exhibited unusual temperature dependence, with periods of slower oxidation kinetics at 750-800 C compared to 650-700 C due to continuous silica-rich scale formation at the higher temperatures. The oxidation of the cast chromia-forming austenitics trended with the level of Cr and Ni additions, with small mass losses consistent with Cr oxy-hydroxide volatilization processes for the higher 25Cr/25-35Ni HK and HP type alloys, and transition to rapid Fe-base oxide formation and scale spallation in the lower 19Cr/12Ni CF8C plus type alloy. In contrast, small positive mass changes consistent with protective alumina scale formation were observed for the cast AFA alloy under all conditions studied. Implications of these findings for diesel exhaust system components are discussed.« less

  4. Long-Term Oxidation of Candidate Cast Iron and Advanced Austenitic Stainless Steel Exhaust System Alloys from 650-800 C in Air with Water Vapor

    SciTech Connect (OSTI)

    Brady, Michael P; Muralidharan, Govindarajan; Leonard, Donovan N; Haynes, James A

    2014-01-01

    The oxidation behavior of SiMo cast iron, Ni-resist D5S cast iron, cast chromia-forming austenitic stainless steels of varying Cr/Ni content based on CF8C plus, HK, and HP, and a developmental cast alumina-forming austenitic (AFA) stainless steel of interest for diesel exhaust system components were studied for up to 5000 h at 650-800 C in air with 10% H2O. At 650 C, the Ni-resist D5S exhibited moderately better oxidation resistance than did the SiMo cast iron. However, the D5S suffered from oxide scale spallation issues at 700 C and higher, whereas the oxide scales formed on SiMo cast iron remained adherent from 700-800 C despite oxide scales hundreds of microns thick. The oxidation of the SiMo cast iron exhibited unusual temperature dependence, with periods of slower oxidation kinetics at 750-800 C compared to 650-700 C due to continuous silica-rich scale formation at the higher temperatures. The oxidation of the cast chromia-forming austenitics trended with the level of Cr and Ni additions, with small mass losses consistent with Cr oxy-hydroxide volatilization processes for the higher 25Cr/25-35Ni HK and HP type alloys, and transition to rapid Fe-base oxide formation and scale spallation in the lower 19Cr/12Ni CF8C plus type alloy. In contrast, small positive mass changes consistent with protective alumina scale formation were observed for the cast AFA alloy under all conditions studied. Implications of these findings for diesel exhaust system components are discussed.

  5. Synthesis of free-standing carbon nanohybrid by directly growing carbon nanotubes on air-sprayed graphene oxide paper and its application in supercapacitor

    SciTech Connect (OSTI)

    Wei, Li; Jiang, Wenchao; Yuan, Yang; Goh, Kunli; Yu, Dingshan; Wang, Liang; Chen, Yuan

    2015-04-15

    We report the synthesis of a free-standing two dimensional carbon nanotube (CNT)-reduced graphene oxide (rGO) hybrid by directly growing CNTs on air-sprayed GO paper. As a result of the good integration between CNTs and thermally reduced GO film during chemical vapor deposition, excellent electrical conductivity (2.6×10{sup 4} S/m), mechanical flexibility (electrical resistance only increases 1.1% after bent to 90° for 500 times) and a relatively large surface area (335.3 m{sup 2}/g) are achieved. Two-electrode supercapacitor assembled using the CNT–rGO hybrids in ionic liquid electrolyte (1-ethyl-3-methylimidazolium tetrafluoroborate) shows excellent stability upon 500 bending cycles with the gravimetric energy density measuring 23.7 Wh/kg and a power density of 2.0 kW/kg. Furthermore, it shows an impedance phase angle of −64.4° at a frequency of 120 Hz, suggesting good potentials for 120 Hz alternating current line filtering applications. - Graphical abstract: Flexible and highly conductive carbon nanotube-reduced graphene oxide nanohybrid. - Highlights: • Direct growth of carbon nanotubes by chemical vapor deposition on air-sprayed graphene oxide paper. • Two-dimensional carbon nanohybrid with excellent conductivity and mechanical flexibility. • Supercapacitor with excellent performance stability upon mechanical deformation for flexible electronics applications. • Supercapacitor with high impedance phase angle for 120 Hz alternating current line filtering applications.

  6. EGG-EP-9842 D

    Office of Scientific and Technical Information (OSTI)

    (WAO) at subcritical conditions for destruction of hazardous waste, and supercritical water oxidation (SCWO) also for the destruction of hazardous waste. The scientific...

  7. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery part I: Bridging mass transport and charge transfer with redox cycle kinetics

    SciTech Connect (OSTI)

    Jin, XF; Zhao, X; Huang, K

    2015-04-15

    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JIVIAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H-2/H2O-concentration across various components of the battery are also systematically investigated. (C) 2015 Elsevier B.V. All rights reserved.

  8. Life cycle inventory analysis of regenerative thermal oxidation of air emissions from oriented strand board facilities in Minnesota - a perspective of global climate change

    SciTech Connect (OSTI)

    Nicholson, W.J.

    1997-12-31

    Life cycle inventory analysis has been applied to the prospective operation of regenerative thermal oxidation (RTO) technology at oriented strand board plants at Bemidji (Line 1) and Cook, Minnesota. The net system destruction of VOC`s and carbon monoxide, and at Cook a small quantity of particulate, has a very high environmental price in terms of energy and water use, global warming potential, sulfur and nitrogen oxide emissions, solids discharged to water, and solid waste deposited in landfills. The benefit of VOC destruction is identified as minor in terms of ground level ozone at best and possibly slightly detrimental. Recognition of environmental tradeoffs associated with proposed system changes is critical to sound decision-making. There are more conventional ways to address carbon monoxide emissions than combustion in RTO`s. In an environment in which global warming is a concern, fuel supplemental combustion for environmental control does not appear warranted. Consideration of non-combustion approaches to address air emission issues at the two operations is recommended. 1 ref., 5 tabs.

  9. Passivation of Zn{sub 3}P{sub 2} substrates by aqueous chemical etching and air oxidation

    SciTech Connect (OSTI)

    Kimball, Gregory M.; Bosco, Jeffrey P.; Mueller, Astrid M.; Tajdar, Syed F.; Brunschwig, Bruce S.; Atwater, Harry A.; Lewis, Nathan S.

    2012-11-15

    Surface recombination velocities measured by time-resolved photoluminescence and compositions of Zn{sub 3}P{sub 2} surfaces measured by x-ray photoelectron spectroscopy (XPS) have been correlated for a series of wet chemical etches of Zn{sub 3}P{sub 2} substrates. Zn{sub 3}P{sub 2} substrates that were etched with Br{sub 2} in methanol exhibited surface recombination velocity values of 2.8 Multiplication-Sign 10{sup 4} cm s{sup -1}, whereas substrates that were further treated by aqueous HF-H{sub 2}O{sub 2} exhibited surface recombination velocity values of 1.0 Multiplication-Sign 10{sup 4} cm s{sup -1}. Zn{sub 3}P{sub 2} substrates that were etched with Br{sub 2} in methanol and exposed to air for 1 week exhibited surface recombination velocity values of 1.8 Multiplication-Sign 10{sup 3} cm s{sup -1}, as well as improved ideality in metal/insulator/semiconductor devices.

  10. Compressed Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lighting Compressed Air ESUE Motors Federal Agriculture Compressed Air Compressed Air Roadmap The Bonneville Power Administration created the roadmap to help utilities find energy...

  11. Reactive Air Brazing: Method of Joining Ceramic and Metal Parts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactive Air Brazing: Method of Joining Ceramic and Metal Parts in Solid Oxide Fuel Cells Pacific Northwest National Laboratory Contact PNNL About This Technology The use of air ...

  12. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  13. Air Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Quality Air Quality To preserve our existing wilderness-area air quality, LANL implements a conscientious program of air monitoring. March 17, 2015 Real-time data monitoring ...

  14. Superconductive ceramic oxide combination

    SciTech Connect (OSTI)

    Chatterjee, D.K.; Mehrotra, A.K.; Mir, J.M.

    1991-03-05

    This patent describes the combination of a superconductive ceramic oxide which degrades in conductivity upon contact of ambient air with its surface and, interposed between the ceramic oxide surface and ambient air in the amount of at least 1 mg per square meter of surface area of the superconductive ceramic oxide, a passivant polymer selected from the group consisting of a polyester ionomer and an alkyl cellulose.

  15. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  16. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  17. Air Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Quality Air Quality Tour The Laboratory calculates the dose to the maximally exposed individual (MEI) to determine effects of Laboratory operations on the public. Open full...

  18. Air Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Quality Air Quality Tour The Laboratory calculates the dose to the maximally exposed individual (MEI) to determine effects of Laboratory operations on the public.

  19. Air Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Quality Air Quality Tour The Laboratory calculates the dose to the maximally exposed individual (MEI) to determine effects of Laboratory operations on the public.

  20. Air Sealing

    SciTech Connect (OSTI)

    2000-02-01

    This fact sheet describes ventilation and the importance of sealing air leaks and providing controlled ventilation.

  1. Energy Efficient Removal of Volatile Organic Compounds (VOCs) and Organic Hazardous Air Pollutants (o-HAPs) from Industrial Waste Streams by Direct Electron Oxidation

    SciTech Connect (OSTI)

    Testoni, A. L.

    2011-10-19

    This research program investigated and quantified the capability of direct electron beam destruction of volatile organic compounds and organic hazardous air pollutants in model industrial waste streams and calculated the energy savings that would be realized by the widespread adoption of the technology over traditional pollution control methods. Specifically, this research determined the quantity of electron beam dose required to remove 19 of the most important non-halogenated air pollutants from waste streams and constructed a technical and economic model for the implementation of the technology in key industries including petroleum refining, organic & solvent chemical production, food & beverage production, and forest & paper products manufacturing. Energy savings of 75 - 90% and green house gas reductions of 66 - 95% were calculated for the target market segments.

  2. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, Mark A.; Hoch, Martin M.

    1997-01-01

    Method for controlling the supply of air to a PROX reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference therebetween correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference.

  3. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  4. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L.; Nyaiesh, Ali R.

    1988-01-01

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  5. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Phase 2, Overfire air tests

    SciTech Connect (OSTI)

    Smith, L.L.; Hooper, M.P.

    1992-07-13

    This Phase 2 Test Report summarizes the testing activities and results for the second testing phase of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The second phase demonstrates the Advanced Overfire Air (AOFA) retrofit with existing Foster Wheeler (FWEC) burners. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data supported by short-term characterization data. Ultimately a fifty percent NO{sub x} reduction target using combinations of combustion modifications has been established for this project.

  6. Partial oxidation power plant with reheating and method thereof

    DOE Patents [OSTI]

    Newby, Richard A. (Pittsburgh, PA); Yang, Wen-Ching (Export, PA); Bannister, Ronald L. (Winter Springs, FL)

    1999-01-01

    A system and method for generating power having an air compression/partial oxidation system, a turbine, and a primary combustion system. The air compression/partial oxidation system receives a first air stream and a fuel stream and produces a first partially oxidized fuel stream and a first compressed air stream therefrom. The turbine expands the first partially oxidized fuel stream while being cooled by the first compressed air stream to produce a heated air stream. The heated air stream is injected into the expanding first partially oxidized fuel stream, thereby reheating it in the turbine. A second partially oxidized fuel stream is emitted from the turbine. The primary combustion system receives said second partially oxidized fuel stream and a second air stream, combusts said second partially oxidized fuel stream, and produces rotating shaft power and an emission stream therefrom.

  7. Partial oxidation power plant with reheating and method thereof

    DOE Patents [OSTI]

    Newby, R.A.; Yang, W.C.; Bannister, R.L.

    1999-08-10

    A system and method are disclosed for generating power having an air compression/partial oxidation system, a turbine, and a primary combustion system. The air compression/partial oxidation system receives a first air stream and a fuel stream and produces a first partially oxidized fuel stream and a first compressed air stream therefrom. The turbine expands the first partially oxidized fuel stream while being cooled by the first compressed air stream to produce a heated air stream. The heated air stream is injected into the expanding first partially oxidized fuel stream, thereby reheating it in the turbine. A second partially oxidized fuel stream is emitted from the turbine. The primary combustion system receives said second partially oxidized fuel stream and a second air stream, combusts said second partially oxidized fuel stream, and produces rotating shaft power and an emission stream therefrom. 2 figs.

  8. Air filter

    SciTech Connect (OSTI)

    Jackson, R.E.; Sparks, J.E.

    1981-03-03

    An air filter is described that has a counter rotating drum, i.e., the rotation of the drum is opposite the tangential intake of air. The intake air has about 1 lb of rock wool fibers per 107 cu. ft. of air sometimes at about 100% relative humidity. The fibers are doffed from the drum by suction nozzle which are adjacent to the drum at the bottom of the filter housing. The drum screen is cleaned by periodically jetting hot dry air at 120 psig through the screen into the suction nozzles.

  9. Electrode electrolyte interlayers containing cerium oxide for electrochemical fuel cells

    DOE Patents [OSTI]

    Borglum, Brian P.; Bessette, Norman F.

    2000-01-01

    An electrochemical cell is made having a porous fuel electrode (16) and a porous air electrode (13), with solid oxide electrolyte (15) therebetween, where the air electrode surface opposing the electrolyte has a separate, attached, dense, continuous layer (14) of a material containing cerium oxide, and where electrolyte (16) contacts the continuous oxide layer (14), without contacting the air electrode (13).

  10. Air-to-air turbocharged air cooling versus air-to-water turbocharged air cooling

    SciTech Connect (OSTI)

    Moranne, J.-P.; Lukas, J.J.

    1984-01-01

    In Europe, turbocharged air in diesel engines used in on-road vehicles is cooled only by air. It is expected that by 1990, ten to twelve percent of European heavy trucks with diesel engines will cool turbocharged air by water. Air-to-air turbocharges air cooling is reviewed and the evolution of air-to-water turbocharged air cooling presented before the two systems are compared.

  11. air force

    National Nuclear Security Administration (NNSA)

    en NNSA, Air Force Complete Successful B61-12 Life Extension Program Development Flight Test at Tonopah Test Range http:nnsa.energy.govmediaroompressreleases...

  12. The Clean Air Interstate Rule

    SciTech Connect (OSTI)

    Debra Jezouit; Frank Rambo

    2005-07-01

    On May 12, 2005, EPA promulgated the Clean Air Interstate Rule, which overhauls and expands the scope of air emissions trading programs in the eastern United States. The rule imposes statewide caps on emissions of nitrogen oxides and sulfur dioxide to be introduced in two phases, beginning in 2009. This article briefly explains the background leading up to the rule and summarizes its key findings and requirements. 2 refs., 1 fig., 1 tab.

  13. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  14. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir; Kumar, Romesh; Krumpelt, Michael

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  15. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  16. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir; Kumar, Romesh; Krumpelt, Michael

    2001-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  17. Air transport of plutonium metal: content expansion initiative for the plutonium air transportable (PAT01) packaging

    SciTech Connect (OSTI)

    Caviness, Michael L; Mann, Paul T

    2010-01-01

    The National Nuclear Security Administration (NNSA) has submitted an application to the Nuclear Regulatory Commission (NRC) for the air shipment of plutonium metal within the Plutonium Air Transportable (PAT-1) packaging. The PAT-1 packaging is currently authorized for the air transport of plutonium oxide in solid form only. The INMM presentation will provide a limited overview of the scope of the plutonium metal initiative and provide a status of the NNSA application to the NRC.

  18. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  19. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E.; Lyons, James E.; Myers, Jr., Harry K.; Shaikh, Shahid N.

    1998-01-01

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  20. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z (n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  1. Reactive Air Aluminization

    SciTech Connect (OSTI)

    Choi, Jung-Pyung; Chou, Y. S.; Stevenson, Jeffry W.

    2011-10-28

    Ferritic stainless steels and other alloys are of great interest to SOFC developers for applications such as interconnects, cell frames, and balance of plant components. While these alloys offer significant advantages (e.g., low material and manufacturing cost, high thermal conductivity, and high temperature oxidation resistance), there are challenges which can hinder their utilization in SOFC systems; these challenges include Cr volatility and reactivity with glass seals. To overcome these challenges, protective coatings and surface treatments for the alloys are under development. In particular, aluminization of alloy surfaces offers the potential for mitigating both evaporation of Cr from the alloy surface and reaction of alloy constituents with glass seals. Commercial aluminization processes are available to SOFC developers, but they tend to be costly due to their use of exotic raw materials and/or processing conditions. As an alternative, PNNL has developed Reactive Air Aluminization (RAA), which offers a low-cost, simpler alternative to conventional aluminization methods.

  2. Effects of Oxidation on Oxidation-Resistant Graphite

    SciTech Connect (OSTI)

    Windes, William; Smith, Rebecca; Carroll, Mark

    2015-05-01

    The Advanced Reactor Technology (ART) Graphite Research and Development Program is investigating doped nuclear graphite grades that exhibit oxidation resistance through the formation of protective oxides on the surface of the graphite material. In the unlikely event of an oxygen ingress accident, graphite components within the VHTR core region are anticipated to oxidize so long as the oxygen continues to enter the hot core region and the core temperatures remain above 400C. For the most serious air-ingress accident which persists over several hours or days the continued oxidation can result in significant structural damage to the core. Reducing the oxidation rate of the graphite core material during any air-ingress accident would mitigate the structural effects and keep the core intact. Previous air oxidation testing of nuclear-grade graphite doped with varying levels of boron-carbide (B4C) at a nominal 739C was conducted for a limited number of doped specimens demonstrating a dramatic reduction in oxidation rate for the boronated graphite grade. This report summarizes the conclusions from this small scoping study by determining the effects of oxidation on the mechanical strength resulting from oxidation of boronated and unboronated graphite to a 10% mass loss level. While the B4C additive did reduce mechanical strength loss during oxidation, adding B4C dopants to a level of 3.5% or more reduced the as-fabricated compressive strength nearly 50%. This effectively minimized any benefits realized from the protective film formed on the boronated grades. Future work to infuse different graphite grades with silicon- and boron-doped material as a post-machining conditioning step for nuclear components is discussed as a potential solution for these challenges in this report.

  3. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  4. Savannah River Site Tank 48H Waste Treatment Project Technology Readiness Assessment

    SciTech Connect (OSTI)

    Harmon, H.D.; Young, J.K.; Berkowitz, J.B.; DeVine, Jr.J.C.; Sutter, H.G.

    2008-07-01

    One of U.S. Department of Energy's (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F and H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents - approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes - are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRC's ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates - WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Desk-book. The TRA consists of three parts: - Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. - Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. - Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy. (authors)

  5. SAVANNAH RIVER SITE TANK 48H WASTE TREATMENT PROJECT TECHNOLOGY READINESS ASSESSMENT

    SciTech Connect (OSTI)

    Harmon, Harry D.; Young, Joan K.; Berkowitz, Joan B.; Devine, John C.; Sutter, Herbert G.

    2008-10-25

    ABSTRACT One of U.S. Department of Energys (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F&H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRCs ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Deskbook. The TRA consists of three parts: Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy.

  6. SAVANNAH RIVER SITE TANK 48H WASTE TREATMENT PROJECT TECHNOLOGY READINESS ASSESSMENT

    SciTech Connect (OSTI)

    Harmon, Harry D.; Young, Joan K.; Berkowitz, Joan B.; Devine, John C.; Sutter, Herbert G.

    2008-03-18

    One of U.S. Department of Energy's (DOE) primary missions at Savannah River Site (SRS) is to retrieve and treat the high level waste (HLW) remaining in SRS tanks and close the F&H tank farms. At present, a significant impediment to timely completion of this mission is the presence of significant organic chemical contamination in Tank 48H. Tank 48H is a 1.3 million gallon tank with full secondary containment, located and interconnected within the SRS tank system. However, the tank has been isolated from the system and unavailable for use since 1983, because its contents - approximately 250,000 gallons of salt solution containing Cs-137 and other radioisotopes - are contaminated with nearly 22,000 Kg of tetraphenylborate, a material which can release benzene vapor to the tank head space in potentially flammable concentrations. An important element of the DOE SRS mission is to remove, process, and dispose of the contents of Tank 48H, both to eliminate the hazard it presents to the SRS H-Tank Farm and to return Tank 48H to service. Tank 48H must be returned to service to support operation of the Salt Waste Processing Facility, to free up HLW tank space, and to allow orderly tank closures per Federal Facility Agreement commitments. The Washington Savannah River Company (WSRC), the SRS prime contractor, has evaluated alternatives and selected two processes, Wet Air Oxidation (WAO) and Fluidized Steam Bed Reforming (FBSR) as candidates for Tank 48H processing. Over the past year, WSRC has been testing and evaluating these two processes, and DOE is nearing a final technology selection in late 2007. In parallel with WSRC's ongoing work, DOE convened a team of independent qualified experts to conduct a Technology Readiness Assessment (TRA). The purpose of the TRA was to determine the maturity level of the Tank 48H treatment technology candidates - WAO and FBSR. The methodology used for this TRA is based on detailed guidance for conducting TRAs contained in the Department of Defense (DoD), Technology Readiness Assessment Deskbook. The TRA consists of three parts: (1) Determination of the Critical Technology Elements (CTEs) for each of the candidate processes. (2) Evaluation of the Technology Readiness Levels (TRLs) of each CTE for each process. (3) Defining of the technology testing or engineering work necessary to bring immature technologies to the appropriate maturity levels. The TRA methodology assigns a TRL to a technology based on the lowest TRL assigned to any CTE of that technology. Based on the assessment, the overall TRL for WAO was 2 and the TRL for FBSR was 3. WAO was limited by the current lack of definition for the off-gas treatment system (TRL of 2). The FBSR Product Handling had little or no test work and therefore received the lowest score (TRL of 3) for the FBSR CTEs. In summary, both FBSR and WAO appear to be viable technologies for treatment of Tank 48H legacy waste. FBSR has a higher degree of maturity than WAO, but additional technology development will be required for both technologies. However, the Assessment Team believes that sufficient information is available for DOE to select the preferred or primary technology. Limited testing of the backup technology should be conducted as a risk mitigation strategy.

  7. Hickam Air Force Base

    Broader source: Energy.gov [DOE]

    Hickam Air Force Base spans 2,850 acres in Honolulu, Hawaii. The military base is home to the 15th Airlift Wing, the Hawaii Air National Guard, and the Pacific Air Forces headquarters.

  8. Geothermal Power Plants — Meeting Clean Air Standards

    Broader source: Energy.gov [DOE]

    Geothermal power plants can meet the most stringent clean air standards. They emit little carbon dioxide, very low amounts of sulfur dioxide, and no nitrogen oxides. See Charts 1, 2, and 3 below.

  9. air_water.cdr

    Office of Legacy Management (LM)

    122011 Air Monitoring Groundwater Monitoring Surface Water Monitoring A continuously operating air monitoring network was in place from 1986 through 2000 for the Weldon Spring ...

  10. Primary zone air proportioner

    DOE Patents [OSTI]

    Cleary, Edward N. G.

    1982-10-12

    An air proportioner is provided for a liquid hydrocarbon fueled gas turbine of the type which is convertible to oil gas fuel and to coal gas fuel. The turbine includes a shell for enclosing the turbine, an air duct for venting air in said shell to a gasifier, and a fuel injector for injecting gasified fuel into the turbine. The air proportioner comprises a second air duct for venting air from the air duct for mixing with fuel from the gasifier. The air can be directly injected into the gas combustion basket along with the fuel from the injector or premixed with fuel from the gasifier prior to injection by the fuel injector.

  11. Cromer Cycle Air Conditioner

    Broader source: Energy.gov [DOE]

    New Air Conditioning System Uses Desiccant to Transfer Moisture and Increase Efficiency and Capacity

  12. Nox control for high nitric oxide concentration flows through combustion-driven reduction

    DOE Patents [OSTI]

    Yeh, James T.; Ekmann, James M.; Pennline, Henry W.; Drummond, Charles J.

    1989-01-01

    An improved method for removing nitrogen oxides from concentrated waste gas streams, in which nitrogen oxides are ignited with a carbonaceous material in the presence of substoichiometric quantities of a primary oxidant, such as air. Additionally, reductants may be ignited along with the nitrogen oxides, carbonaceous material and primary oxidant to achieve greater reduction of nitrogen oxides. A scrubber and regeneration system may also be included to generate a concentrated stream of nitrogen oxides from flue gases for reduction using this method.

  13. Air-pollutant emissions from kerosene space heaters

    SciTech Connect (OSTI)

    Leaderer, B.P.

    1982-12-10

    Air pollutant emissions from portable convective and radiant kerosene space heaters were measured in an environmental chamber. Emission factors for nitrogen oxides, sulfur dioxide, carbon monoxide, carbon dioxide, and oxygen depletion are presented. The data suggest that the use of such heaters in residences can result in exposures to air pollutants in excess of ambient air quality standards and in some cases in excess of occupational health standards.

  14. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  15. Determining the Right Air Quality for Your Compressed Air System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Right Air Quality for Your Compressed Air System Determining the Right Air Quality for Your Compressed Air System This tip sheet outlines the main factors for determining the right air quality for compressed air systems. COMPRESSED AIR TIP SHEET #5 PDF icon Determining the Right Air Quality for Your Compressed Air System (August 2004) More Documents & Publications Effect of Intake on Compressor Performance Improving Compressed Air System Performance: A Sourcebook

  16. Isokinetic air sampler

    DOE Patents [OSTI]

    Sehmel, George A.

    1979-01-01

    An isokinetic air sampler includes a filter, a holder for the filter, an air pump for drawing air through the filter at a fixed, predetermined rate, an inlet assembly for the sampler having an inlet opening therein of a size such that isokinetic air sampling is obtained at a particular wind speed, a closure for the inlet opening and means for simultaneously opening the closure and turning on the air pump when the wind speed is such that isokinetic air sampling is obtained. A system incorporating a plurality of such samplers provided with air pumps set to draw air through the filter at the same fixed, predetermined rate and having different inlet opening sizes for use at different wind speeds is included within the ambit of the present invention as is a method of sampling air to measure airborne concentrations of particulate pollutants as a function of wind speed.

  17. Detection of Amorphous Silica in Air-Oxidized Ti3SiC2 at 500-1000°C by NMR and SIMS

    SciTech Connect (OSTI)

    Pang, Wei Kong; Low, I M; Hanna, J V

    2010-11-12

    The use of secondary-ion mass spectrometry (SIMS), nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) to detect the existence of amorphous silica in Ti3SiC2 oxidised at 500-1000 ºC is described. The formation of an amorphous SiO2 layer and its growth in thickness with temperature was monitored using dynamic SIMS. Results of NMR and TEM verify for the first time the direct evidence of amorphous silica formation during the oxidation of Ti3SiC2 at 1000 ºC.

  18. Hanford Site air operating permit application

    SciTech Connect (OSTI)

    1995-05-01

    The Clean Air Act Amendments of 1990, which amended the Federal Clean Air Act of 1977, required that the US Environmental Protection Agency develop a national Air Operating Permit Program, which in turn would require each state to develop an Air Operating Permit Program to identify all sources of ``regulated`` pollutants. Regulated pollutants include ``criteria`` pollutants (oxides of nitrogen, sulfur oxides, total suspended particulates, carbon monoxide, particulate matter greater than 10 micron, lead) plus 189 other ``Hazardous`` Air Pollutants. The Hanford Site, owned by the US Government and operated by the US Department of Energy, Richland Operations Office, is located in southcentral Washington State and covers 560 square miles of semi-arid shrub and grasslands located just north of the confluence of the Snake and Yakima Rivers with the Columbia River. This land, with restricted public access, provides a buffer for the smaller areas historically used for the production of nuclear materials, waste storage, and waste disposal. About 6 percent of the land area has been disturbed and is actively used. The Hanford Site Air Operating Permit Application consists of more than 1,100 sources and in excess of 300 emission points. Before January 1995, the maintenance and operations contractor and the environmental restoration contractor for the US Department of Energy completed an air emission inventory on the Hanford Site. The inventory has been entered into a database so that the sources and emission points can be tracked and updated information readily can be retrieved. The Hanford Site Air Operating Permit Application contains information current as of April 19, 1995.

  19. Detecting Air Leaks

    Broader source: Energy.gov [DOE]

    You may already know where some air leakage occurs in your home, such as an under-the-door draft, but you'll need to find the less obvious gaps to properly air seal your home.

  20. Determining the Right Air Quality for Your Compressed Air System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    coating, climate control Process Air Food and pharmaceutical process air, ... Contaminants can enter a compressed air system at the compressor intake, or can be ...

  1. Simple Interactive Models for better air quality (SIM-air) |...

    Open Energy Info (EERE)

    Interactive Models for better air quality (SIM-air) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Simple Interactive Models (SIM-air) AgencyCompany Organization:...

  2. Surface and interfacial reaction study of InAs(100)-crystalline oxide interface

    SciTech Connect (OSTI)

    Zhernokletov, D. M.; Laukkanen, P.; Dong, H.; Brennan, B.; Kim, J.; Galatage, R. V.; Yakimov, M.; Tokranov, V.; Oktyabrsky, S.; Wallace, R. M.; Department of Materials Science and Engineering, University of Texas at Dallas, Richardson, Texas 75080

    2013-05-27

    A crystalline oxide film on InAs(100) is investigated with in situ monochromatic x-ray photoelectron spectroscopy and low energy electron diffraction before and after in situ deposition of Al{sub 2}O{sub 3} by atomic layer deposition (ALD) as well as upon air exposure. The oxidation process leads to arsenic and indium trivalent oxidation state formation. The grown epitaxial oxide-InAs interface is stable upon ALD reactor exposure; however, trimethyl aluminum decreases oxidation states resulting in an unreconstructed surface. An increase in oxide concentration is also observed upon air exposure suggesting the crystalline oxide surface is unstable.

  3. Air Sparging Decision Tool

    Energy Science and Technology Software Center (OSTI)

    1996-06-10

    The Air Sparging Decision Tool is a computer decision aid to help environmental managers and field practitioners in evaluating the applicability of air sparging to a wide range of sites and for refining the operation of air sparging systems. The program provides tools for the practitioner to develop the conceptual design for an air sparging system suitable for the identified site. The Tool provides a model of the decision making process, not a detailed designmore » of air sparging systems. The Tool will quickly and cost effectively assist the practitioner in screening for applicability of the technology at a proposed site.« less

  4. Aluminum-based metal-air batteries

    DOE Patents [OSTI]

    Friesen, Cody A.; Martinez, Jose Antonio Bautista

    2016-01-12

    Provided in one embodiment is an electrochemical cell, comprising: (i) a plurality of electrodes, comprising a fuel electrode that comprises aluminum and an air electrode that absorbs gaseous oxygen, the electrodes being operable in a discharge mode wherein the aluminum is oxidized at the fuel electrode and oxygen is reduced at the air electrode, and (ii) an ionically conductive medium, comprising an organic solvent; wherein during non-use of the cell, the organic solvent promotes formation of a protective interface between the aluminum of the fuel electrode and the ionically conductive medium, and wherein at an onset of the discharge mode, at least some of the protective interface is removed from the aluminum to thereafter permit oxidation of the aluminum during the discharge mode.

  5. An Innovative Reactor Technology to Improve Indoor Air Quality

    SciTech Connect (OSTI)

    Rempel, Jane

    2013-03-30

    As residential buildings achieve tighter envelopes in order to minimize energy used for space heating and cooling, accumulation of indoor air pollutants such as volatile organic compounds (VOCs), becomes a major concern causing poor air quality and increased health risks. Current VOC removal methods include sorbents, ultraviolet photocatalytic oxidation (UVPCO), and increased ventilation, but these methods do not capture or destroy all VOCs or are prohibitively expensive to implement. TIAX's objective in this program was to develop a new VOC removal technology for residential buildings. This novel air purification technology is based on an innovative reactor and light source design along with UVPCO properties of the chosen catalyst to purify indoor air and enhance indoor air quality (IAQ). During the program we designed, fabricated and tested a prototype air purifier to demonstrate its feasibility and effectiveness. We also measured kinetics of VOC destruction on photocatalysts, providing deep insight into reactor design.

  6. Baseline air quality study at Fermilab

    SciTech Connect (OSTI)

    Dave, M.J.; Charboneau, R.

    1980-10-01

    Air quality and meteorological data collected at Fermi National Accelerator Laboratory are presented. The data represent baseline values for the pre-construction phase of a proposed coal-gasification test facility. Air quality data were characterized through continuous monitoring of gaseous pollutants, collection of meteorological data, data acquisition and reduction, and collection and analysis of discrete atmospheric samples. Seven air quality parameters were monitored and recorded on a continuous real-time basis: sulfur dioxide, ozone, total hydrocarbons, nonreactive hydrocarbons, nitric oxide, nitrogen oxides, and carbon monoxide. A 20.9-m tower was erected near Argonne's mobile air monitoring laboratory, which was located immediately downwind of the proposed facility. The tower was instrumented at three levels to collect continuous meteorological data. Wind speed was monitored at three levels; wind direction, horizontal and vertical, at the top level; ambient temperature at the top level; and differential temperature between all three levels. All continuously-monitored parameters were digitized and recorded on magnetic tape. Appropriate software was prepared to reduce the data. Statistical summaries, grphical displays, and correlation studies also are presented.

  7. Determining the Right Air Quality for Your Compressed Air System - Compressed Air Tip Sheet #5

    SciTech Connect (OSTI)

    2004-08-01

    BestPractices Program tip sheet discussing how to determine the right air quality for compressed air systems.

  8. Indium oxide/n-silicon heterojunction solar cells

    DOE Patents [OSTI]

    Feng, Tom; Ghosh, Amal K.

    1982-12-28

    A high photo-conversion efficiency indium oxide/n-silicon heterojunction solar cell is spray deposited from a solution containing indium trichloride. The solar cell exhibits an Air Mass One solar conversion efficiency in excess of about 10%.

  9. Personal continuous air monitor

    DOE Patents [OSTI]

    Morgan, Ronald G.; Salazar, Samuel A.

    2000-01-01

    A personal continuous air monitor capable of giving immediate warning of the presence of radioactivity has a filter/detector head to be worn in the breathing zone of a user, containing a filter mounted adjacent to radiation detectors, and a preamplifier. The filter/detector head is connected to a belt pack to be worn at the waist or on the back of a user. The belt pack contains a signal processor, batteries, a multichannel analyzer, a logic circuit, and an alarm. An air pump also is provided in the belt pack for pulling air through the filter/detector head by way of an air tube.

  10. Adsorption air conditioner

    DOE Patents [OSTI]

    Rousseau, Jean L. I.

    1979-01-01

    A solar powered air conditioner using the adsorption process is constructed with its components in a nested cylindrical array for compactness and ease of operation.

  11. Steam Oxidation of Advanced Steam Turbine Alloys

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2008-01-01

    Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650C to 800C) to steam at 34.5 MPa (650C to 760C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

  12. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T.; Lahr, David L.

    2010-11-09

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  13. Combined fuel and air staged power generation system

    SciTech Connect (OSTI)

    Rabovitser, Iosif K; Pratapas, John M; Boulanov, Dmitri

    2014-05-27

    A method and apparatus for generation of electric power employing fuel and air staging in which a first stage gas turbine and a second stage partial oxidation gas turbine power operated in parallel. A first portion of fuel and oxidant are provided to the first stage gas turbine which generates a first portion of electric power and a hot oxidant. A second portion of fuel and oxidant are provided to the second stage partial oxidation gas turbine which generates a second portion of electric power and a hot syngas. The hot oxidant and the hot syngas are provided to a bottoming cycle employing a fuel-fired boiler by which a third portion of electric power is generated.

  14. History of Air Conditioning

    Broader source: Energy.gov [DOE]

    We take it for granted but what would life be like without the air conditioner? Once considered a luxury, this invention is now an essential, allowing us to cool everything from homes, businesses, businesses, data centers, laboratories and other buildings vital to our daily lives. Explore this timeline to learn some of the key dates in the history of air conditioning.

  15. AIR RADIOACTIVITY MONITOR

    DOE Patents [OSTI]

    Bradshaw, R.L.; Thomas, J.W.

    1961-04-11

    The monitor is designed to minimize undesirable background buildup. It consists of an elongated column containing peripheral electrodes in a central portion of the column, and conduits directing an axial flow of radioactively contaminated air through the center of the column and pure air through the annular portion of the column about the electrodes. (AEC)

  16. Portable oven air circulator

    DOE Patents [OSTI]

    Jorgensen, Jorgen A.; Nygren, Donald W.

    1983-01-01

    A portable air circulating apparatus for use in cooking ovens which is used to create air currents in the oven which transfer heat to cooking foodstuffs to promote more rapid and more uniform cooking or baking, the apparatus including a motor, fan blade and housing of metallic materials selected from a class of heat resistant materials.

  17. Recirculating electric air filter

    DOE Patents [OSTI]

    Bergman, Werner

    1986-01-01

    An electric air filter cartridge has a cylindrical inner high voltage eleode, a layer of filter material, and an outer ground electrode formed of a plurality of segments moveably connected together. The outer electrode can be easily opened to remove or insert filter material. Air flows through the two electrodes and the filter material and is exhausted from the center of the inner electrode.

  18. Protective air lock

    DOE Patents [OSTI]

    Evans, Herbert W.

    1976-03-30

    A device suitable for preventing escape and subsequent circulation of toxic gases comprising an enclosure which is sealed by a surrounding air lock, automatic means for partially evacuating said enclosure and said air lock and for ventilating said enclosure and means for disconnecting said enclosure ventilating means, whereby a relatively undisturbed atmosphere is created in said enclosure.

  19. Recirculating electric air filter

    DOE Patents [OSTI]

    Bergman, W.

    1985-01-09

    An electric air filter cartridge has a cylindrical inner high voltage electrode, a layer of filter material, and an outer ground electrode formed of a plurality of segments moveably connected together. The outer electrode can be easily opened to remove or insert filter material. Air flows through the two electrodes and the filter material and is exhausted from the center of the inner electrode.

  20. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  1. Investigation of key parameters influencing the efficient photocatalytic oxidation of indoor volatile organic compounds (VOCs)

    SciTech Connect (OSTI)

    Quici, Natalia; Kibanova, Daria; Vera, Maria Laura; Choi, Hyeok; Dionysiou, Dionysios D.; Litter, Marta I.; Cervini-Silva, Javiera; Hodgson, Alfred T.; Destaillats, Hugo; Destaillats, Hugo

    2008-06-01

    Photocatalytic oxidation of indoor VOCs has the potential to eliminate pollutants from indoor environments, thus effectively improving and/or maintaining indoor air quality while reducing ventilation energy costs. Design and operation of UV photocatalytic oxidation (UVPCO) air cleaners requires optimization of various parameters to achieve highest pollutant removal efficiencies while avoiding the formation of harmful secondary byproducts and maximizing catalyst lifetime.

  2. Renewables and air quality

    SciTech Connect (OSTI)

    Wooley, D.R.

    2000-08-01

    The US heavy reliance on fossil fuels is a central obstacle to improving air quality and preventing catastrophic climate change. To solve this problem will require a combination of financial incentives and market rules that strongly encourage development of renewable energy resources to meet electric power demand. One promising policy option is to allow renewable energy resources to directly participate in air pollution emission trading mechanisms. Currently, the clean air benefits of renewable energy generally go unrecognized by regulators, under-appreciated by consumers and uncompensated by markets. Renewable energy is a key clean air alternative to conventional electricity generation, and the development of renewables could be stimulated by changes to the Clean Air Act's emissions trading programs. As Congress revisits clean air issues over the next several years, renewable energy representatives could push for statutory changes that reward the renewable energy industry for the air quality benefits it provides. By also becoming involved in key US Environmental Protection Agency (EPA) and state rule-making cases, the renewables industry could influence the structure of emissions trading programs and strengthen one of the most persuasive arguments for wind, solar and biomass energy development.

  3. High-Temperature Oxide Regrowth on Mechanically-Damaged Surfaces

    SciTech Connect (OSTI)

    Blau, Peter Julian; Lowe, Tracie M

    2008-01-01

    Here we report the effects of mechanical damage from a sharp stylus on the regrowth of oxide layers on a Ni-based superalloy known as Pyromet 80A . It was found that the oxide that reformed on the damaged portion of a pre-oxidized surface differed from that which formed on undamaged areas after the equal exposures to elevated temperature in air. These findings have broad implications for modeling the processes of material degradation in applications such as exhaust valves in internal combustion engines because they imply that static oxidation data for candidate materials may not adequately reflect their reaction to operating environments that involve both mechanical contact and oxidation.

  4. Electro-deposition of superconductor oxide films

    DOE Patents [OSTI]

    Bhattacharya, Raghu N.

    2001-01-01

    Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.

  5. Air Shower Simulations

    SciTech Connect (OSTI)

    Alania, Marco; Gomez, Adolfo V. Chamorro; Araya, Ignacio J.; Huerta, Humberto Martinez; Flores, Alejandra Parra; Knapp, Johannes

    2009-04-30

    Air shower simulations are a vital part of the design of air shower experiments and the analysis of their data. We describe the basic features of air showers and explain why numerical simulations are the appropriate approach to model the shower simulation. The CORSIKA program, the standard simulation program in this field, is introduced and its features, performance and limitations are discussed. The basic principles of hadronic interaction models and some gerneral simulation techniques are explained. Also a brief introduction to the installation and use of CORSIKA is given.

  6. Air heating system

    DOE Patents [OSTI]

    Primeau, John J.

    1983-03-01

    A self-starting, fuel-fired, air heating system including a vapor generator, a turbine, and a condenser connected in a closed circuit such that the vapor output from the vapor generator is conducted to the turbine and then to the condenser where it is condensed for return to the vapor generator. The turbine drives an air blower which passes air over the condenser for cooling the condenser. Also, a condensate pump is driven by the turbine. The disclosure is particularly concerned with the provision of heat exchanger and circuitry for cooling the condensed fluid output from the pump prior to its return to the vapor generator.

  7. Air ejector augmented compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, F.W.; Kartsounes, G.T.

    Energy is stored in slack demand periods by charging a plurality of underground reservoirs with air to the same peak storage pressure, during peak demand periods throttling the air from one storage reservoir into a gas turbine system at a constant inlet pressure until the air presure in the reservoir falls to said constant inlet pressure, thereupon permitting air in a second reservoir to flow into said gas turbine system while drawing air from the first reservoir through a variable geometry air ejector and adjusting said variable geometry air ejector, said air flow being essentially at the constant inlet pressure of the gas turbine system.

  8. Recent Progress in Retrieving Air Temperature Profiles and Air...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recent Progress in Retrieving Air Temperature Profiles and Air-Sea Temperature Differences from Infrared and Microwave Scanning Radiometer Data D. Cimini University of L'Aquila ...

  9. Air ejector augmented compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, Frederick W.; Kartsounes, George T.

    1980-01-01

    Energy is stored in slack demand periods by charging a plurality of underground reservoirs with air to the same peak storage pressure, during peak demand periods throttling the air from one storage reservoir into a gas turbine system at a constant inlet pressure until the air pressure in the reservoir falls to said constant inlet pressure, thereupon permitting air in a second reservoir to flow into said gas turbine system while drawing air from the first reservoir through a variable geometry air ejector and adjusting said variable geometry air ejector, said air flow being essentially at the constant inlet pressure of the gas turbine system.

  10. Building America Case Study: Air Leakage and Air Transfer Between...

    Energy Savers [EERE]

    Air Leakage and Air Transfer Between Garage and Living Space Waldorf, Maryland PROJECT INFORMATION Project Name: Ventilation Effectiveness Location: Waldorf, MD Partners: Building ...

  11. Guide to Air Sealing

    SciTech Connect (OSTI)

    2011-02-01

    Air sealing is one of the most cost-effective ways to improve the comfort and energy efficiency of your home. Hire a certified professional contractor for best results.

  12. Air bag restraint device

    DOE Patents [OSTI]

    Marts, Donna J.; Richardson, John G.

    1995-01-01

    A rear-seat air bag restraint device is disclosed that prevents an individual, or individuals, from continuing violent actions while being transported in a patrol vehicle's rear seat without requiring immediate physical contact by the law enforcement officer. The air bag is activated by a control switch in the front seat and inflates to independently restrict the amount of physical activity occurring in the rear seat of the vehicle while allowing the officer to safely stop the vehicle. The air bag can also provide the officer additional time to get backup personnel to aid him if the situation warrants it. The bag is inflated and maintains a constant pressure by an air pump.

  13. Air bag restraint device

    DOE Patents [OSTI]

    Marts, D.J.; Richardson, J.G.

    1995-10-17

    A rear-seat air bag restraint device is disclosed that prevents an individual, or individuals, from continuing violent actions while being transported in a patrol vehicle`s rear seat without requiring immediate physical contact by the law enforcement officer. The air bag is activated by a control switch in the front seat and inflates to independently restrict the amount of physical activity occurring in the rear seat of the vehicle while allowing the officer to safely stop the vehicle. The air bag can also provide the officer additional time to get backup personnel to aid him if the situation warrants it. The bag is inflated and maintains a constant pressure by an air pump. 8 figs.

  14. Air Sealing Windows

    SciTech Connect (OSTI)

    2009-05-14

    This information sheet addresses windows and may also be applied to doors and other pre-assembled elements installed in building enclosures that also perform an air barrier function.

  15. Compressed Air Systems

    Broader source: Energy.gov [DOE]

    There are incentives for variable frequency drive screw compressors (10-40 HP), air receivers/tanks for load/no-load compressors, cycling refrigerated dryers (up to 200 CFM capacity), no-loss...

  16. Air conditioning system

    DOE Patents [OSTI]

    Lowenstein, Andrew; Miller, Jeffrey; Gruendeman, Peter; DaSilva, Michael

    2005-02-01

    An air conditioner comprises a plurality of plates arranged in a successively stacked configuration with portions thereof having a spaced apart arrangement, and defining between successive adjacent pairs of plates at the spaced apart portions a first and second series of discrete alternating passages wherein a first air stream is passed through the first series of passages and a second air stream is passed through the second series of passages; and said stacked configuration of plates forming integrally therewith a liquid delivery means for delivering from a source a sufficient quantity of a liquid to the inside surfaces of the first series of fluid passages in a manner which provides a continuous flow of the liquid from a first end to a second end of the plurality of plates while in contact with the first air stream.

  17. Breathing zone air sampler

    DOE Patents [OSTI]

    Tobin, John

    1989-01-01

    A sampling apparatus is provided which comprises a sampler for sampling air in the breathing zone of a wearer of the apparatus and a support for the sampler preferably in the form of a pair of eyeglasses. The sampler comprises a sampling assembly supported on the frame of the eyeglasses and including a pair of sample transport tubes which are suspended, in use, centrally of the frame so as to be disposed on opposite sides of the nose of the wearer and which each include an inlet therein that, in use, is disposed adjacent to a respective nostril of the nose of the wearer. A filter holder connected to sample transport tubes supports a removable filter for filtering out particulate material in the air sampled by the apparatus. The sample apparatus is connected to a pump for drawing air into the apparatus through the tube inlets so that the air passes through the filter.

  18. Air Products & Chemicals, Inc.

    Office of Energy Efficiency and Renewable Energy (EERE)

    Air Products is partnering with Denbury Green Pipeline – Texas, LLC to capture and sequester one million tons of carbon dioxide per year from two existing steam-methane reformers at Air Products’ hydrogen-production facility in Port Arthur, Texas. The captured CO2 is transported by pipeline to oil fields in eastern Texas for enhanced oil recovery. The total award value of the project is $431 million, with $284 million comprising DOE’s 66 percent share.

  19. Air Quality | Open Energy Information

    Open Energy Info (EERE)

    Air Quality Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleAirQuality&oldid612070" Feedback Contact needs updating Image needs updating...

  20. ARM - Lesson Plans: Air Pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Teachers' Toolbox Lesson Plans Lesson Plans: Air Pressure Objective The objective of this ... Important Points to Understand Air has weight and exerts pressure on everything with which ...

  1. Coating of porous carbon for use in lithium air batteries

    DOE Patents [OSTI]

    Amine, Khalil; Lu, Jun; Du, Peng; Lei, Yu; Elam, Jeffrey W

    2015-04-14

    A cathode includes a carbon material having a surface, the surface having a first thin layer of an inert material and a first catalyst overlaying the first thin layer, the first catalyst including metal or metal oxide nanoparticles, wherein the cathode is configured for use as the cathode of a lithium-air battery.

  2. Solid oxide fuel cell operable over wide temperature range

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    2001-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  3. AIR COOLED NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Fermi, E.; Szilard, L.

    1958-05-27

    A nuclear reactor of the air-cooled, graphite moderated type is described. The active core consists of a cubicle mass of graphite, approximately 25 feet in each dimension, having horizontal channels of square cross section extending between two of the opposite faces, a plurality of cylindrical uranium slugs disposed in end to end abutting relationship within said channels providing a space in the channels through which air may be circulated, and a cadmium control rod extending within a channel provided in the moderator. Suitable shielding is provlded around the core, as are also provided a fuel element loading and discharge means, and a means to circulate air through the coolant channels through the fuel charels to cool the reactor.

  4. AIR PASSIVATION OF METAL HYDRIDE BEDS FOR WASTE DISPOSAL

    SciTech Connect (OSTI)

    Klein, J; R. H. Hsu, R

    2007-07-02

    Metal hydride beds offer compact, safe storage of tritium. After metal hydride beds have reached the end of their useful life, the beds will replaced with new beds and the old beds prepared for disposal. One acceptance criteria for hydride bed waste disposal is that the material inside the bed not be pyrophoric. To determine the pyrophoric nature of spent metal hydride beds, controlled air ingress tests were performed. A simple gas handling manifold fitted with pressure transducers and a calibrated volume were used to introduce controlled quantities of air into a metal hydride bed and the bed temperature rise monitored for reactivity with the air. A desorbed, 4.4 kg titanium prototype hydride storage vessel (HSV) produced a 4.4 C internal temperature rise upon the first air exposure cycle and a 0.1 C temperature rise upon a second air exposure. A total of 346 scc air was consumed by the bed (0.08 scc per gram Ti). A desorbed, 9.66 kg LaNi{sub 4.25}Al{sub 0.75} prototype storage bed experienced larger temperature rises over successive cycles of air ingress and evacuation. The cycles were performed over a period of days with the bed effectively passivated after the 12th cycle. Nine to ten STP-L of air reacted with the bed producing both oxidized metal and water.

  5. Compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, Frederick W.; Kartsounes, George T.

    1981-01-01

    An internal combustion reciprocating engine is operable as a compressor during slack demand periods utilizing excess power from a power grid to charge air into an air storage reservoir and as an expander during peak demand periods to feed power into the power grid utilizing air obtained from the air storage reservoir together with combustible fuel. Preferably the internal combustion reciprocating engine is operated at high pressure and a low pressure turbine and compressor are also employed for air compression and power generation.

  6. Compressed air energy storage system

    DOE Patents [OSTI]

    Ahrens, F.W.; Kartsounes, G.T.

    An internal combustion reciprocating engine is operable as a compressor during slack demand periods utilizing excess power from a power grid to charge air into an air storage reservoir and as an expander during peak demand periods to feed power into the power grid utilizing air obtained from the air storage reservoir together with combustion reciprocating engine is operated at high pressure and a low pressure turbine and compressor are also employed for air compression and power generation.

  7. UV/oxidation providers shed technical problems, fight cost perceptions

    SciTech Connect (OSTI)

    Rapaport, D. )

    1993-05-01

    Systems combining ultraviolet light and oxidation (UV/oxidation) to remove contaminants from water were introduced in the early 1980s. Since then, improvements in the technology, a wide array of applications, educational efforts by companies offering the systems and changes in environmental regulations have accelerated acceptance of UV/oxidation technology. From the standpoint of regulatory officials, the major advantage of UV/oxidation is that it creates no secondary pollutants to treat or haul away. It is a self-contained, in situ treatment technology. This benefit has gained importance as regulations have become more stringent regarding disposal of secondary pollutants, such as saturated carbon, and concentration levels of air emissions created by air stripping. Such regulations have increased the costs of monitoring and disposal, while the costs of using UV/oxidation were decreasing.

  8. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J.

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  9. Minimize Compressed Air Leaks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compressed Air Leaks Minimize Compressed Air Leaks This tip sheet outlines a strategy for compressed air leak detection and provides a formula for cost savings calculations. COMPRESSED AIR TIP SHEET #3 PDF icon Minimize Compressed Air Leaks (August 2004) More Documents & Publications Eliminate Inappropriate Uses of Compressed Air Determine the Cost of Compressed Air for Your Plant Analyzing Your Compressed Air System

  10. Air Proportional Counter

    DOE Patents [OSTI]

    Simpson, J.A. Jr.

    1950-12-05

    A multiple wire counter utilizing air at atmospheric pressure as the ionizing medium and having a window of a nylon sheet of less than 0.5 mil thickness coated with graphite. The window is permeable to alpha particles so that the counter is well adapted to surveying sources of alpha radiation.

  11. AIR M A IL

    Office of Legacy Management (LM)

    MEMORlAL DRIVE AIR M A IL . AtFxb.-zf .7.-i- M r. s. .II. Gown - Gentlemen: Re: A.E.C. Contract No. We assume the weight of the 9-l2" biscuits will:be 107'poutids ...

  12. Automatic electrochemical ambient air monitor for chloride and chlorine

    DOE Patents [OSTI]

    Mueller, Theodore R.

    1976-07-13

    An electrochemical monitoring system has been provided for determining chloride and chlorine in air at levels of from about 10-1000 parts per billion. The chloride is determined by oxidation to chlorine followed by reduction to chloride in a closed system. Chlorine is determined by direct reduction at a platinum electrode in 6 M H.sub.2 SO.sub.4 electrolyte. A fully automated system is utilized to (1) acquire and store a value corresponding to electrolyte-containing impurities, (2) subtract this value from that obtained in the presence of air, (3) generate coulometrically a standard sample of chlorine mixed with air sample, and determine it as chlorine and/or chloride, and (4) calculate, display, and store for permanent record the ratio of the signal obtained from the air sample and that obtained with the standard.

  13. lithium cobalt oxide cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lithium cobalt oxide cathode - Sandia Energy Energy Search Icon Sandia Home Locations ... SunShot Grand Challenge: Regional Test Centers lithium cobalt oxide cathode Home...

  14. Air Conditioning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat & Cool » Home Cooling Systems » Air Conditioning Air Conditioning Air conditioners cost U.S. homeowners more than $11 billion each year, and regular maintenance can keep your air conditioner running efficiently. | Photo courtesy of ©iStockphoto/JaniceRichard Air conditioners cost U.S. homeowners more than $11 billion each year, and regular maintenance can keep your air conditioner running efficiently. | Photo courtesy of ©iStockphoto/JaniceRichard Two-thirds of all homes in the

  15. Air ingression calculations for selected plant transients using MELCOR

    SciTech Connect (OSTI)

    Kmetyk, L.N.

    1994-01-01

    Two sets of MELCOR calculations have been completed studying the effects of air ingression on the consequences of various severe accident scenarios. One set of calculations analyzed a station blackout with surge line failure prior to vessel breach, starting from nominal operating conditions; the other set of calculations analyzed a station blackout occurring during shutdown (refueling) conditions. Both sets of analyses were for the Surry plant, a three-loop Westinghouse PWR. For both accident scenarios, a basecase calculation was done, and then repeated with air ingression from containment into the core region following core degradation and vessel failure. In addition to the two sets of analyses done for this program, a similar air-ingression sensitivity study was done as part of a low-power/shutdown PRA, with results summarized here; that PRA study also analyzed a station blackout occurring during shutdown (refueling) conditions, but for the Grand Gulf plant, a BWR/6 with Mark III containment. These studies help quantify the amount of air that would have to enter the core region to have a significant impact on the severe accident scenario, and demonstrate that one effect, of air ingression is substantial enhancement of ruthenium release. These calculations also show that, while the core clad temperatures rise more quickly due to oxidation with air rather than steam, the core also degrades and relocates more quickly, so that no sustained, enhanced core heatup is predicted to occur with air ingression.

  16. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  17. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  18. Air cathode structure manufacture

    DOE Patents [OSTI]

    Momyer, William R.; Littauer, Ernest L.

    1985-01-01

    An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

  19. Capture and Use of Coal Mine Ventilation Air Methane

    SciTech Connect (OSTI)

    Deborah Kosmack

    2008-10-31

    CONSOL Energy Inc., in conjunction with MEGTEC Systems, Inc., and the U.S. Department of Energy with the U.S. Environmental Protection Agency, designed, built, and operated a commercial-size thermal flow reversal reactor (TFRR) to evaluate its suitability to oxidize coal mine ventilation air methane (VAM). Coal mining, and particularly coal mine ventilation air, is a major source of anthropogenic methane emissions, a greenhouse gas. Ventilation air volumes are large and the concentration of methane in the ventilation air is low; thus making it difficult to use or abate these emissions. This test program was conducted with simulated coal mine VAM in advance of deploying the technology on active coal mine ventilation fans. The demonstration project team installed and operated a 30,000 cfm MEGTEC VOCSIDIZER oxidation system on an inactive coal mine in West Liberty, WV. The performance of the unit was monitored and evaluated during months of unmanned operation at mostly constant conditions. The operating and maintenance history and how it impacts the implementation of the technology on mine fans were investigated. Emission tests showed very low levels of all criteria pollutants at the stack. Parametric studies showed that the equipment can successfully operate at the design specification limits. The results verified the ability of the TFRR to oxidize {ge}95% of the low and variable concentration of methane in the ventilation air. This technology provides new opportunities to reduce greenhouse gas emissions by the reduction of methane emissions from coal mine ventilation air. A large commercial-size installation (180,000 cfm) on a single typical mine ventilation bleeder fan would reduce methane emissions by 11,000 to 22,100 short tons per year (the equivalent of 183,000 to 366,000 metric tonnes carbon dioxide).

  20. Fresh air indoors

    SciTech Connect (OSTI)

    Kull, K.

    1988-09-01

    This article describes and compares ventilation systems for the control of indoor air pollution in residential housing. These include: local exhaust fans, whole-house fans, central exhaust with wall ports, and heat-recovery central ventilation (HRV). HRV's have a higher initial cost than the other systems but they are the only ones that save energy. Homeowners are given guidelines for choosing the system best suited for their homes in terms of efficiency and payback period.

  1. Air conditioning apparatus

    SciTech Connect (OSTI)

    Ouchi, Y.; Otoshi, Sh.

    1985-04-09

    The air conditioning apparatus according to the invention comprises an absorption type heat pump comprising a system including an absorber, a regenerator, a condenser and an evaporator. A mixture of lithium bromide and zinc chloride is used as an absorbent which is dissolved to form an absorbent solution into a mixed solvent having a ratio by weight of methanol to water, the ratio falling in a range between 0.1 and 0.3. Said solution is circulated through the system.

  2. Fundamentals of Compressed Air Systems

    Broader source: Energy.gov [DOE]

    Find out how a compressed air system works and the benefits of optimal compressed air system performance. This initial class demonstrates how to compute the current cost of your plant's compressed...

  3. ARM - Instrument - ccn-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsccn-air Documentation Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Error occurred. Instrument "ccn-air" does not exist.

  4. ARM - Instrument - cpc-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentscpc-air Documentation Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Error occurred. Instrument "cpc-air" does not exist.

  5. ARM - Instrument - hk-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentshk-air Documentation Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Error occurred. Instrument "hk-air" does not exist.

  6. Combustion air preheating

    SciTech Connect (OSTI)

    Wells, T.A.; Petterson, W.C.

    1986-10-14

    This patent describes a process for steam cracking hydrocarbons to cracked gases in a tubular furnace heated by burning a mixture of fuel and combustion air and subsequently quenching the cracked gases. Waste heat is recovered in the form of high pressure steam and the combustion air is preheated prior to introduction into the furnace. The improvement described here comprises: (a) superheating the high pressure steam and expanding at least a portion of the superheated high pressure steam through a first turbine to produce shaft work and superheated medium pressure steam at a temperature between 260/sup 0/ and 465/sup 0/ C.; (b) expanding at least a portion of the superheated medium pressure steam through a second turbine to produce shaft work and low pressure steam at a temperature between 120/sup 0/ and 325/sup 0/ C.; and (c) preheating the combustion air by indirect heat exchange with at least a portion of the superheated medium pressure stream and at least a portion of the low pressure steam.

  7. Air transparent soundproof window

    SciTech Connect (OSTI)

    Kim, Sang-Hoon; Lee, Seong-Hyun

    2014-11-15

    A soundproof window or wall which is transparent to airflow is presented. The design is based on two wave theories: the theory of diffraction and the theory of acoustic metamaterials. It consists of a three-dimensional array of strong diffraction-type resonators with many holes centered on each individual resonator. The negative effective bulk modulus of the resonators produces evanescent wave, and at the same time the air holes with subwavelength diameter existed on the surfaces of the window for macroscopic air ventilation. The acoustic performance levels of two soundproof windows with air holes of 20mm and 50mm diameters were measured. The sound level was reduced by about 30 - 35dB in the frequency range of 400 - 5,000Hz with the 20mm window, and by about 20 - 35dB in the frequency range of 700 - 2,200Hz with the 50mm window. Multi stop-band was created by the multi-layers of the window. The attenuation length or the thickness of the window was limited by background noise. The effectiveness of the soundproof window with airflow was demonstrated by a real installation.

  8. Air quality committee

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Committees on air quality, coal, forest resources, and public lands and land use report on legislative, judicial, and administrative developments in 1979. There was no new significant air quality legislation, but a number of lawsuits raised questions about State Implementation Plans, prevention of significant deterioration, the Clean Air Act Amendments, new source performance standards, and motor vehicle emissions. Efforts to increase coal utilization emphasized implementation of the Power Plant and Industrial Fuel Use Act of 1978 and the Surface Mining Program. New legislation protects certain forest products from exploitation and exportation. Forest-related lawsuits focused on the RARE II process. Land-use legislation modified credit assistance to coastal zones and the language of interstate land sales, established a new agency to consolidate flood-insurance programs, and added protection to archaeological resources. Land-use-related lawsuits covered coastal zone management, interstate land sales, Indian reservations, and land-use planning in the context of civil rights, antitrust action, exclusionary zoning, comprehensive planning, and regional general welfare. Other suits addressed grants, leasing, claims, grazing rights, surveys, and other matters of public lands concern. Administrative actions centered on implementing the Coastal Zone Management Act, establishing the Council of Energy Resource Tribes, and developing guidelines for energy development. 147 references. (DCK)

  9. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  10. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  11. Maintaining System Air Quality | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Maintaining System Air Quality Maintaining System Air Quality This tip sheet discusses how to maintain air quality in compressed air systems through proper use of equipment. COMPRESSED AIR TIP SHEET #12 PDF icon Maintaining System Air Quality (August 2004) More Documents & Publications Remove Condensate with Minimal Air Loss Engineer End Uses for Maximum Efficiency Stabilizing System Pressure

  12. Effect of air-staging on anthracite combustion and NOx formation

    SciTech Connect (OSTI)

    Weidong Fan; Zhengchun Lin; Youyi Li; Jinguo Kuang; Mingchuan Zhang

    2009-01-15

    Experiments were carried out in a multipath air inlet one-dimensional furnace to assess NOx emission characteristics of the staged combustion of anthracite coal. These experiments allowed us to study the impact of pulverized coal fineness and burnout air position on emission under both deep and shallow air-staged combustion conditions. We also studied the impact of char-nitrogen release on both the burning-out process of the pulverized coal and the corresponding carbon content in fly ash. We found that air-staged combustion affects a pronounced reduction in NOx emissions from the combustion of anthracite coal. The more the air is staged, the more NOx emission is reduced. In shallow air-staged combustion (f{sub M} = 0.85), the fineness of the pulverized coal strongly influences emissions, and finer coals result in lower emissions. Meanwhile, the burnout air position has only a weak effect. In the deep air-staged combustion (f{sub M} = 0.6), the effect of coal fineness is smaller, and the burnout air position has a stronger effect. When the primary combustion air is stable, NOx emissions increase with increasing burnout air. This proves that, in the burnout zone, coal char is responsible for the discharge of fuel-nitrogen that is oxidized to NOx. The measurement of secondary air staging in a burnout zone can help inhibit the oxidization of NO caused by nitrogen release. Air-staged combustion has little effect on the burnout of anthracite coal, which proves to be suitable for air-staged combustion. 31 refs., 11 figs., 1 tab.

  13. Clean Air Interstate Rule (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    Clean Air Interstate Rule (CAIR) is a cap-and-trade program promulgated by the Environmental Protection Agency in 2005, covering 28 eastern U.S. states and the District of Columbia. It was designed to reduce sulfur dioxide (SO2) and nitrogen oxide (NOx) emissions in order to help states meet their National Ambient Air Quality Standards (NAAQS) for ozone and particulate matter (PM2.5) and to further emissions reductions already achieved through the Acid Rain Program and the NOx State Implementation Plan call program. The rule was set to commence in 2009 for seasonal and annual NOx emissions and in 2010 for SO2 emissions.

  14. Hybrid and Advanced Air Cooling

    Broader source: Energy.gov [DOE]

    DOE Geothermal Program Peer Review 2010 - Presentation. This project will identify and analyze advanced air cooling strategies thatallow air-cooled geothermal power plants to maintain a high electric power output during periods of high air dry bulb temperatures while minimizing water consumption.

  15. Aire Valley Environmental | Open Energy Information

    Open Energy Info (EERE)

    Aire Valley Environmental Jump to: navigation, search Name: Aire Valley Environmental Place: United Kingdom Product: Leeds-based waste-to-energy project developer. References: Aire...

  16. Common Air Conditioner Problems | Department of Energy

    Office of Environmental Management (EM)

    Common Air Conditioner Problems Common Air Conditioner Problems A refrigerant leak is one common air conditioning problem. | Photo courtesy of iStockphotoBanksPhotos. A...

  17. Analyzing Your Compressed Air System; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industry Training * Fundamentals of Compressed Air ... Compressed air needs are defned by the air quality and ... Plants with a fatter load profle can use simpler control ...

  18. ARM - Field Campaign - AIRS Validation Sonde Support

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The AIRS instrument was intended to make highly accurate measurements of air temperature, humidity, clouds, and surface temperature. The data collected by AIRS was...

  19. ARM - Field Campaign - AIRS Validation Sonde Support

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The AIRS instrument is intended to make highly accurate measurements of air temperature, humidity, clouds, and surface temperature. The data collected by AIRS will be...

  20. California Air Resources Board | Open Energy Information

    Open Energy Info (EERE)

    Air Resources Board Jump to: navigation, search Logo: California Air Resources Board Name: California Air Resources Board Place: Sacramento, California Website: www.arb.ca.gov...

  1. Tips: Air Conditioners | Department of Energy

    Energy Savers [EERE]

    Air Conditioners Tips: Air Conditioners Bigger isn't always better for an air conditioner. Learn effective ways to stay cool while saving energy. | Photo courtesy of ...

  2. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland; Liu, Ping; Smith, R. Davis

    2009-07-14

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  3. Air Risk Information Support Center

    SciTech Connect (OSTI)

    Shoaf, C.R.; Guth, D.J.

    1990-12-31

    The Air Risk Information Support Center (Air RISC) was initiated in early 1988 by the US Environmental Protection Agency`s (EPA) Office of Health and Environmental Assessment (OHEA) and the Office of Air Quality Planning and Standards (OAQPS) as a technology transfer effort that would focus on providing information to state and local environmental agencies and to EPA Regional Offices in the areas of health, risk, and exposure assessment for toxic air pollutants. Technical information is fostered and disseminated by Air RISCs three primary activities: (1) a {open_quotes}hotline{close_quotes}, (2) quick turn-around technical assistance projects, and (3) general technical guidance projects. 1 ref., 2 figs.

  4. Simplified air change effectiveness modeling

    SciTech Connect (OSTI)

    Rock, B.A.; Anderson, R.; Brandemuehl, M.J.

    1992-06-01

    This paper describes recent progress in developing practical air change effectiveness modeling techniques for the design and analysis of air diffusion in occupied rooms. The ultimate goal of this continuing work is to develop a simple and reliable method for determining heating, ventilating, and air-conditioning (HVAC) system compliance with ventilation standards. In the current work, simplified two-region models of rooms are used with six occupancy patterns to find the air change effectiveness. A new measure, the apparent ACH effectiveness, yields the relative ventilation performance of an air diffusion system. This measure can be used for the prediction or evaluation of outside air delivery to the occupants. The required outside air can be greater or less than that specified by ventilation standards such as ASHRAE Standard 62-89.

  5. Hot air drum evaporator

    DOE Patents [OSTI]

    Black, Roger L.

    1981-01-01

    An evaporation system for aqueous radioactive waste uses standard 30 and 55 gallon drums. Waste solutions form cascading water sprays as they pass over a number of trays arranged in a vertical stack within a drum. Hot dry air is circulated radially of the drum through the water sprays thereby removing water vapor. The system is encased in concrete to prevent exposure to radioactivity. The use of standard 30 and 55 gallon drums permits an inexpensive compact modular design that is readily disposable, thus eliminating maintenance and radiation build-up problems encountered with conventional evaporation systems.

  6. Regenerative air heater

    DOE Patents [OSTI]

    Hasselquist, P.B.; Baldner, R.

    1980-11-26

    A gas-cooled steel skirt is used to support a refractory cored brick matrix and dome structure in a high temperature regenerative air heater useful in magnetohydrodynamic power generation. The steel skirt thermally expands to accommodate the thermal expansion of the dome structure despite substantial temperature differential thereby reducing relative movement between the dome bricks. Gas cooling of the steel skirt allows the structure to operate above its normal temperature during clean-out cycles and also allows for the control of the thermal expansion of the steel skirt.

  7. Regenerative air heater

    DOE Patents [OSTI]

    Hasselquist, Paul B.; Baldner, Richard

    1982-01-01

    A gas-cooled steel skirt is used to support a refractory cored brick matrix and dome structure in a high temperature regenerative air heater useful in magnetohydrodynamic power generation. The steel skirt thermally expands to accommodate the thermal expansion of the dome structure despite substantial temperature differential thereby reducing relative movement between the dome bricks. Gas cooling of the steel skirt allows the structure to operate above its normal temperature during clean-out cycles and also allows for the control of the thermal expansion of the steel skirt.

  8. Method for forming indium oxide/n-silicon heterojunction solar cells

    DOE Patents [OSTI]

    Feng, Tom; Ghosh, Amal K.

    1984-03-13

    A high photo-conversion efficiency indium oxide/n-silicon heterojunction solar cell is spray deposited from a solution containing indium trichloride. The solar cell exhibits an Air Mass One solar conversion efficiency in excess of about 10%.

  9. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  10. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, Charles C.; Mrazek, Franklin C.

    1988-01-01

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  11. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  12. Central Air Conditioning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Central Air Conditioning Central Air Conditioning Central air conditioners circulate cool air through a system of supply and return ducts. | Photo courtesy of ©iStockphoto/DonNichols. Central air conditioners circulate cool air through a system of supply and return ducts. | Photo courtesy of ©iStockphoto/DonNichols. Central air conditioners circulate cool air through a system of supply and return ducts. Supply ducts and registers (i.e., openings in the walls, floors, or ceilings covered by

  13. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    SciTech Connect (OSTI)

    Carerras-Sospedra, Marc; Brouwer, Jack; Dabdub, Donald; Lunden, Melissa; Singer, Brett

    2011-07-01

    The effects of liquefied natural gas (LNG) on pollutant emission inventories and air quality in the South Coast Air Basin of California were evaluated using recent LNG emission measurements by Lawrence Berkeley National Laboratory and the Southern California Gas Company (SoCalGas), and with a state-of-the-art air quality model. Pollutant emissions can be affected by LNG owing to differences in composition and physical properties, including the Wobbe index, a measure of energy delivery rate. This analysis uses LNG distribution scenarios developed by modeling Southern California gas flows, including supplies from the LNG receiving terminal in Baja California, Mexico. Based on these scenarios, the projected penetratino of LNG in the South Coast Air Basin is expected to be limited. In addition, the increased Wobbe index of delivered gas (resulting from mixtures of LNG and conventional gas supplies) is expected to cause increases smaller than 0.05 percent in overall (area-wide) emissions of nitrogen oxides (NOx). BAsed on the photochemical state of the South Coast Air Basin, any increase in NOx is expected to cause an increase in the highest local ozone concentrations, and this is reflected in model results. However, the magnitude of the increase is well below the generally accepted accuracy of the model and would not be discernible with the existing monitoring network. Modeling of hypothetical scenarios indicates that discernible changes to ambient ozone and particulate matter concentrations would occur only at LNG distribution rates that are not achievable with current or planned infrastructure and with Wobbe index vlaues that exceed current gas quality tariffs. Results of these hypothetical scenarios are presented for consideration of any proposed substantial expansion of LNG supply infrastructure in Southern California.

  14. Dynamic Modeling in Solid-Oxide Fuel Cells Controller Design

    SciTech Connect (OSTI)

    Lu, Ning; Li, Qinghe; Sun, Xin; Khaleel, Mohammad A.

    2007-06-28

    In this paper, a dynamic model of the solid-oxide fuel cell (SOFC) power unit is developed for the purpose of designing a controller to regulate fuel flow rate, fuel temperature, air flow rate, and air temperature to maintain the SOFC stack temperature, fuel utilization rate, and voltage within operation limits. A lumped model is used to consider the thermal dynamics and the electro-chemial dynamics inside an SOFC power unit. The fluid dynamics at the fuel and air inlets are considered by using the in-flow ramp-rates.

  15. Mixed Acid Oxidation

    SciTech Connect (OSTI)

    Pierce, R.A.

    1999-10-26

    Several non-thermal processes have been developed to destroy organic waste compounds using chemicals with high oxidation potentials. These efforts have focused on developing technologies that work at low temperatures, relative to incineration, to overcome many of the regulatory issues associated with obtaining permits for waste incinerators. One such technique with great flexibility is mixed acid oxidation. Mixed acid oxidation, developed at the Savannah River Site, uses a mixture of an oxidant (nitric acid) and a carrier acid (phosphoric acid). The carrier acid acts as a non-volatile holding medium for the somewhat volatile oxidant. The combination of acids allows appreciable amounts of the concentrated oxidant to remain in the carrier acid well above the oxidant''s normal boiling point.

  16. Oxidation catalyst systems for emission control of LPG-powered forklift trucks

    SciTech Connect (OSTI)

    Majewski, W.A.; Martin, E.P.; Pietrasz, E.

    1994-10-01

    An oxidation catalyst was installed on an industrial LPG-powered forklift truck. For high conversion efficiency in an oxidation system on a rich burning engine a secondary air supply to the catalyst is necessary. Two simple and cost-effective ways of secondary air supply were tested: an air valve and a venturi type injector. The amount of secondary air supplied by both devices was measured under a variety of conditions - different engine speed, load and exhaust system pressure. Carbon monoxide emissions and the catalyst performance were measured and evaluated in terms of the secondary air flow. Advantages and drawbacks of the air valve and venturi injector systems are discussed and compared. 1 refs., 11 figs., 3 tabs.

  17. Air Force Renewable Energy Programs

    Broader source: Energy.gov [DOE]

    Presentation covers Air Force Renewable Energy Programs and is given at the Spring 2011 Federal Utility Partnership Working Group (FUPWG) meeting.

  18. Cold air systems: Sleeping giant

    SciTech Connect (OSTI)

    MacCracken, C.D. )

    1994-04-01

    This article describes how cold air systems help owners increase the profits from their buildings by reducing electric costs and improving indoor air quality through lower relative humidity levels. Cold air distribution involves energy savings, cost savings, space savings, greater comfort, cleaner air, thermal storage, tighter ducting, coil redesign, lower relative humidities, retrofitting, and improved indoor air quality (IAQ). It opens a door for architects, engineers, owners, builders, environmentalists, retrofitters, designers, occupants, and manufacturers. Three things have held up cold air's usage: multiple fan-powered boxes that ate up the energy savings of primary fans. Cold air room diffusers that provided inadequate comfort. Condensation from ducts, boxes, and diffusers. Such problems have been largely eliminated through research and development by utilities and manufacturers. New cold air diffusers no longer need fan powered boxes. It has also been found that condensation is not a concern so long as the ducts are located in air conditioned space, such as drop ceilings or central risers, where relative humidity falls quickly during morning startup.

  19. Air Cooling | Open Energy Information

    Open Energy Info (EERE)

    Air cooling is limited on ambient temperatures and typically require a larger footprint than Water Cooling, but when water restrictions are great enough to prevent the...

  20. Air bearing vacuum seal assembly

    DOE Patents [OSTI]

    Booth, Rex

    1978-01-01

    An air bearing vacuum seal assembly capable of rotating at the speed of several thousand revolutions per minute using an air cushion to prevent the rotating and stationary parts from touching, and a two stage differential pumping arrangement to maintain the pressure gradient between the air cushion and the vacuum so that the leak rate into the vacuum is, for example, less than 1 .times. 10.sup.-4 Pa m.sup.3 /s. The air bearing vacuum seal has particular application for mounting rotating targets to an evacuated accelerator beam tube for bombardment of the targets with high-power charged particle beams in vacuum.

  1. Clean Air Act, Section 309

    Energy Savers [EERE]

    CLEAN AIR ACT 309* 7609. Policy review (a) The Administrator shall review and comment in writing on the environmental impact of any matter relating to duties and ...

  2. Growth control of the oxidation state in vanadium oxide thin...

    Office of Scientific and Technical Information (OSTI)

    Growth control of the oxidation state in vanadium oxide thin films Citation Details In-Document Search Title: Growth control of the oxidation state in vanadium oxide thin films ...

  3. Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Films | ANSER Center | Argonne-Northwestern National Laboratory Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films

  4. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA's Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  5. Air toxics provisions of the Clean Air Act: Potential impacts on energy

    SciTech Connect (OSTI)

    Hootman, H.A.; Vernet, J.E.

    1991-11-01

    This report provides an overview of the provisions of the Clean Air Act and its Amendments of 1990 that identify hazardous air pollutant (HAP) emissions and addresses their regulation by the US Environmental Protection Agency (EPA). It defines the major energy sector sources of these HAPs that would be affected by the regulations. Attention is focused on regulations that would cover coke oven emissions; chromium emission from industrial cooling towers and the electroplating process; HAP emissions from tank vessels, asbestos-related activities, organic solvent use, and ethylene oxide sterilization; and emissions of air toxics from municipal waste combustors. The possible implications of Title III regulations for the coal, natural gas, petroleum, uranium, and electric utility industries are examined. The report discusses five major databases of HAP emissions: (1) TRI (EPA`s Toxic Release Inventory); (2) PISCES (Power Plant Integrated Systems: Chemical Emissions Studies developed by the Electric Power Research Institute); (3) 1985 Emissions Inventory on volatile organic compounds (used for the National Acid Precipitation Assessment Program); (4) Particulate Matter Species Manual (EPA); and (5) Toxics Emission Inventory (National Aeronautics and Space Administration). It also offers information on emission control technologies for municipal waste combustors.

  6. U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus

    Office of Scientific and Technical Information (OSTI)

    improved observations from the Ozone Monitoring Instrument (OMI) (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) Citation Details In-Document Search Title: U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) Emissions of nitrogen oxides

  7. U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus

    Office of Scientific and Technical Information (OSTI)

    improved observations from the Ozone Monitoring Instrument (OMI) (Journal Article) | DOE PAGES Accepted Manuscript: U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) Title: U.S. NO₂ trends (2005-2013): EPA air quality system (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) Emissions of nitrogen oxides (NOx) and, subsequently, atmospheric levels of nitrogen dioxide

  8. Common Air Conditioner Problems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Common Air Conditioner Problems Common Air Conditioner Problems A refrigerant leak is one common air conditioning problem. | Photo courtesy of ©iStockphoto/BanksPhotos. A refrigerant leak is one common air conditioning problem. | Photo courtesy of ©iStockphoto/BanksPhotos. One of the most common air conditioning problems is improper operation. If your air conditioner is on, be sure to close your home's windows and outside doors. For room air conditioners, isolate the room or a group of

  9. Why does LANL sample the air?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Why does LANL sample the air? Why does LANL sample the air? As the most significant pathway, air is monitored to ensure that any possible release is quickly detected. Diagram of air quality monitors within an exhaust stack. Nuclear facilities have three additional air sampling systems. LANL samples and analyzes air to assess effects on workers, the public, animals, and plants. As the most significant pathway, air is monitored to ensure that any possible release is quickly detected. How we do it

  10. The Clean Air Mercury Rule

    SciTech Connect (OSTI)

    Michael Rossler

    2005-07-01

    Coming into force on July 15, 2005, the US Clean Air Mercury Rule will use a market-based cap-and-trade approach under Section 111 of the Clean Air Act to reduce mercury emissions from the electric power sector. This article provides a comprehensive summary of the new rule. 14 refs., 2 tabs.

  11. Title III hazardous air pollutants

    SciTech Connect (OSTI)

    Todd, R.

    1995-12-31

    The author presents an overview of the key provisions of Title III of the Clean Air Act Amendments of 1990. The key provisions include the following: 112(b) -- 189 Hazardous Air Pollutants (HAP); 112(a) -- Major Source: 10 TPY/25 TPY; 112(d) -- Application of MACT; 112(g) -- Modifications; 112(I) -- State Program; 112(j) -- The Hammer; and 112(r) -- Accidental Release Provisions.

  12. Protective supplied breathing air garment

    DOE Patents [OSTI]

    Childers, Edward L.; von Hortenau, Erik F.

    1984-07-10

    A breathing air garment for isolating a wearer from hostile environments containing toxins or irritants includes a suit and a separate head protective enclosure or hood engaging a suit collar in sealing attachment. The hood and suit collar are cylindrically shaped and dimensioned to enable the wearer to withdraw his hands from the suit sleeves to perform manual tasks within the hood interior. Breathing air is supplied from an external air line with an air delivery hose attached to the hood interior. The hose feeds air into an annular halo-like fiber-filled plenum having spaced discharge orifices attached to the hood top wall. A plurality of air exhaust/check valves located at the suit extremities cooperate with the hood air delivery system to provide a cooling flow of circulating air from the hood throughout the suit interior. A suit entry seal provided on the suit rear torso panel permits access into the suit and is sealed with an adhesive sealing flap.

  13. Protective supplied breathing air garment

    DOE Patents [OSTI]

    Childers, E.L.; Hortenau, E.F. von.

    1984-07-10

    A breathing air garment is disclosed for isolating a wearer from hostile environments containing toxins or irritants includes a suit and a separate head protective enclosure or hood engaging a suit collar in sealing attachment. The hood and suit collar are cylindrically shaped and dimensioned to enable the wearer to withdraw his hands from the suit sleeves to perform manual tasks within the hood interior. Breathing air is supplied from an external air line with an air delivery hose attached to the hood interior. The hose feeds air into an annular halo-like fiber-filled plenum having spaced discharge orifices attached to the hood top wall. A plurality of air exhaust/check valves located at the suit extremities cooperate with the hood air delivery system to provide a cooling flow of circulating air from the hood throughout the suit interior. A suit entry seal provided on the suit rear torso panel permits access into the suit and is sealed with an adhesive sealing flap. 17 figs.

  14. ARM - Instrument - co-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsco-air Documentation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Carbon Monoxide- Airborne (CO-AIR) Instrument Categories Airborne Observations, Atmospheric Carbon Contact(s) Stephen Springston Brookhaven National Laboratory (631) 344-4477 srs@bnl.gov

  15. ARM - Instrument - gustprobe-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsgustprobe-air Documentation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Aircraft Gust Probe (GUSTPROBE-AIR) Instrument Categories Airborne Observations Contact(s) Annette Koontz Pacific Northwest National Laboratory Developer (509) 375-3609 annette.koontz@pnnl

  16. Partial oxidation catalyst

    DOE Patents [OSTI]

    Krumpelt, Michael; Ahmed, Shabbir; Kumar, Romesh; Doshi, Rajiv

    2000-01-01

    A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  17. AIR FORCE SPECIAL WEAPONS CENTER

    Office of Legacy Management (LM)

    HEADQUARTERS aII?y 9 AIR FORCE SPECIAL WEAPONS CENTER 1 AIR FORCE SYSTEMS COMMAND . - KlRTlAND AIR FORCE BASE, NEW MEXICO - k FINAL REPORT O N AIR FORCE PARTICIPATION PROJECT RULISON .1 O c t o b e r 1969 P r e p a r e d by : CONT INENTAL TEST D I V I S ION DIRECTORATE OF NUCLEAR FIELD OPERATIONS This page intentionally left blank INDEX AIR FORCE PARTICIPATION I N PROJECT RULISON FINAL REPORT PARAGRAPH BASIC REPORT SUBJECT R e f e r e n c e s PAGE 2 G e n e r a l 1 3 P l a n n i n g 3 4 Command

  18. Graphite Oxidation Simulation in HTR Accident Conditions

    SciTech Connect (OSTI)

    El-Genk, Mohamed

    2012-10-19

    Massive air and water ingress, following a pipe break or leak in steam-generator tubes, is a design-basis accident for high-temperature reactors (HTRs). Analysis of these accidents in both prismatic and pebble bed HTRs requires state-of-the-art capability for predictions of: 1) oxidation kinetics, 2) air “helium gas mixture stratification and diffusion into the core following the depressurization, 3) transport of multi-species gas mixture, and 4) graphite corrosion. This project will develop a multi-dimensional, comprehensive oxidation kinetics model of graphite in HTRs, with diverse capabilities for handling different flow regimes. The chemical kinetics/multi-species transport model for graphite burning and oxidation will account for temperature-related changes in the properties of graphite, oxidants (O2, H2O, CO), reaction products (CO, CO2, H2, CH4) and other gases in the mixture (He and N2). The model will treat the oxidation and corrosion of graphite in geometries representative of HTR core component at temperatures of 900°C or higher. The developed chemical reaction kinetics model will be user-friendly for coupling to full core analysis codes such as MELCOR and RELAP, as well as computational fluid dynamics (CFD) codes such as CD-adapco. The research team will solve governing equations for the multi-dimensional flow and the chemical reactions and kinetics using Simulink, an extension of the MATLAB solver, and will validate and benchmark the model's predictions using reported experimental data. Researchers will develop an interface to couple the validated model to a commercially available CFD fluid flow and thermal-hydraulic model of the reactor , and will perform a simulation of a pipe break in a prismatic core HTR, with the potential for future application to a pebble-bed type HTR.

  19. In-situ formation of multiphase air plasma sprayed barrier coatings for turbine components

    DOE Patents [OSTI]

    Subramanian, Ramesh

    2001-01-01

    A turbine component (10), such as a turbine blade, is provided which is made of a metal alloy (22) and a base, planar-grained thermal barrier layer (28) applied by air plasma spraying on the alloy surface, where a heat resistant ceramic oxide overlay material (32') covers the bottom thermal barrier coating (28), and the overlay material is the reaction product of the precursor ceramic oxide overlay material (32) and the base thermal barrier coating material (28).

  20. ZIRCONIUM OXIDE NANOSTRUCTURES PREPARED BY ANODIC OXIDATION

    SciTech Connect (OSTI)

    Dang, Y. Y.; Bhuiyan, M.S.; Paranthaman, M. P.

    2008-01-01

    Zirconium oxide is an advanced ceramic material highly useful for structural and electrical applications because of its high strength, fracture toughness, chemical and thermal stability, and biocompatibility. If highly-ordered porous zirconium oxide membranes can be successfully formed, this will expand its real-world applications, such as further enhancing solid-oxide fuel cell technology. Recent studies have achieved various morphologies of porous zirconium oxide via anodization, but they have yet to create a porous layer where nanoholes are formed in a highly ordered array. In this study, electrochemical methods were used for zirconium oxide synthesis due to its advantages over other coating techniques, and because the thickness and morphology of the ceramic fi lms can be easily tuned by the electrochemical parameters, such as electrolyte solutions and processing conditions, such as pH, voltage, and duration. The effects of additional steps such as pre-annealing and post-annealing were also examined. Results demonstrate the formation of anodic porous zirconium oxide with diverse morphologies, such as sponge-like layers, porous arrays with nanoholes ranging from 40 to 75 nm, and nanotube layers. X-ray powder diffraction analysis indicates a cubic crystallographic structure in the zirconium oxide. It was noted that increased voltage improved the ability of the membrane to stay adhered to the zirconium substrate, whereas lower voltages caused a propensity for the oxide fi lm to fl ake off. Further studies are needed to defi ne the parameters windows that create these morphologies and to investigate other important characteristics such as ionic conductivity.

  1. Air Leakage and Air Transfer Between Garage and Living Space

    SciTech Connect (OSTI)

    Rudd, A.

    2014-09-01

    This research project focused on evaluation of air transfer between the garage and living space in a single-family detached home constructed by a production homebuilder in compliance with the 2009 International Residential Code and the 2009 International Energy Conservation Code. The project gathered important information about the performance of whole-building ventilation systems and garage ventilation systems as they relate to minimizing flow of contaminated air from garage to living space. A series of 25 multi-point fan pressurization tests and additional zone pressure diagnostic testing characterized the garage and house air leakage, the garage-to-house air leakage, and garage and house pressure relationships to each other and to outdoors using automated fan pressurization and pressure monitoring techniques. While the relative characteristics of this house may not represent the entire population of new construction configurations and air tightness levels (house and garage) throughout the country, the technical approach was conservative and should reasonably extend the usefulness of the results to a large spectrum of house configurations from this set of parametric tests in this one house. Based on the results of this testing, the two-step garage-to-house air leakage test protocol described above is recommended where whole-house exhaust ventilation is employed. For houses employing whole-house supply ventilation (positive pressure) or balanced ventilation (same pressure effect as the Baseline condition), adherence to the EPA Indoor airPLUS house-to-garage air sealing requirements should be sufficient to expect little to no garage-to-house air transfer.

  2. Effect of pre-oxidation and environmental aging on the seal strength of a novel high-temperature solid oxide fuel cell (SOFC) sealing glass with metallic interconnect

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

    2008-09-15

    A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two ferritic stainless steel coupons for strength evaluation. The steel coupons were pre-oxidized at elevated temperatures to promote thick oxide layers to simulate long-term exposure conditions. In addition, seals to as-received metal coupons were also tested after aging in oxidizing or reducing environments to simulate the actual SOFC environment. Room temperature tensile testing showed strength degradation when using pre-oxidized coupons, and more extensive degradation after aging in air. Fracture surface and microstructural analysis confirmed that the cause of degradation was formation of SrCrO4 at the outer sealing edges exposed to air.

  3. Effect of nitrogen doping on wetting and photoactive properties of laser processed zinc oxide-graphene oxide nanocomposite layers

    SciTech Connect (OSTI)

    György, E.; Pérez del Pino, A.; Logofatu, C.; Duta, A.; Isac, L.

    2014-07-14

    Zinc oxide-graphene oxide nanocomposite layers were submitted to laser irradiation in air or controlled nitrogen atmosphere using a frequency quadrupled Nd:YAG (λ = 266 nm, τ{sub FWHM} ≅ 3 ns, ν = 10 Hz) laser source. The experiments were performed in air at atmospheric pressure or in nitrogen at a pressure of 2 × 10{sup 4} Pa. The effect of the irradiation conditions, incident laser fluence value, and number of subsequent laser pulses on the surface morphology of the composite material was systematically investigated. The obtained results reveal that nitrogen incorporation improves significantly the wetting and photoactive properties of the laser processed layers. The kinetics of water contact angle variation when the samples are submitted to laser irradiation in nitrogen are faster than that of the samples irradiated in air, the surfaces becoming super-hydrophilic under UV light irradiation.

  4. INEEL AIR MODELING PROTOCOL ext

    SciTech Connect (OSTI)

    C. S. Staley; M. L. Abbott; P. D. Ritter

    2004-12-01

    Various laws stemming from the Clean Air Act of 1970 and the Clean Air Act amendments of 1990 require air emissions modeling. Modeling is used to ensure that air emissions from new projects and from modifications to existing facilities do not exceed certain standards. For radionuclides, any new airborne release must be modeled to show that downwind receptors do not receive exposures exceeding the dose limits and to determine the requirements for emissions monitoring. For criteria and toxic pollutants, emissions usually must first exceed threshold values before modeling of downwind concentrations is required. This document was prepared to provide guidance for performing environmental compliance-driven air modeling of emissions from Idaho National Engineering and Environmental Laboratory facilities. This document assumes that the user has experience in air modeling and dose and risk assessment. It is not intended to be a "cookbook," nor should all recommendations herein be construed as requirements. However, there are certain procedures that are required by law, and these are pointed out. It is also important to understand that air emissions modeling is a constantly evolving process. This document should, therefore, be reviewed periodically and revised as needed. The document is divided into two parts. Part A is the protocol for radiological assessments, and Part B is for nonradiological assessments. This document is an update of and supersedes document INEEL/INT-98-00236, Rev. 0, INEEL Air Modeling Protocol. This updated document incorporates changes in some of the rules, procedures, and air modeling codes that have occurred since the protocol was first published in 1998.

  5. Inertial impaction air sampling device

    DOE Patents [OSTI]

    Dewhurst, Katharine H.

    1990-01-01

    An inertial impactor to be used in an air sampling device for collection of respirable size particles in ambient air which may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry.

  6. CSP Tower Air Brayton Combustor

    Broader source: Energy.gov [DOE]

    This fact sheet describes a concentrating solar power tower air Brayton combustor project awarded under the DOE's 2012 SunShot CSP R&D award program. The team, led by the Southwest Research Institute, is working to develop an external combustor that allows for the mixing of CSP-heated air with natural gas in hybridized power plants. This project aims to increase the temperature capabilities of the CSP tower air receiver and gas turbine to 1,000ºC and achieve energy conversion efficiencies greater than 50%.

  7. Inertial impaction air sampling device

    DOE Patents [OSTI]

    Dewhurst, K.H.

    1990-05-22

    An inertial impactor is designed which is to be used in an air sampling device for collection of respirable size particles in ambient air. The device may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

  8. Inertial impaction air sampling device

    DOE Patents [OSTI]

    Dewhurst, K.H.

    1987-12-10

    An inertial impactor to be used in an air sampling device for collection of respirable size particles in ambient air which may include a graphite furnace as the impaction substrate in a small-size, portable, direct analysis structure that gives immediate results and is totally self-contained allowing for remote and/or personal sampling. The graphite furnace collects suspended particles transported through the housing by means of the air flow system, and these particles may be analyzed for elements, quantitatively and qualitatively, by atomic absorption spectrophotometry. 3 figs.

  9. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  10. EPA Air Pollution and the Clean Air Act Webpage | Open Energy...

    Open Energy Info (EERE)

    Air Pollution and the Clean Air Act Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: EPA Air Pollution and the Clean Air Act Webpage Abstract...

  11. Air Leakage and Air Transfer Between Garage and Living Space

    SciTech Connect (OSTI)

    Rudd, Armin

    2014-09-01

    This research project focused on evaluation of air transfer between the garage and living space in a single-family detached home constructed by a production homebuilder in compliance with the 2009 International Residential Code and the 2009 International Energy Conservation Code. The project gathered important information about the performance of whole-building ventilation systems and garage ventilation systems as they relate to minimizing flow of contaminated air from garage to living space. A series of 25 multi-point fan pressurization tests and additional zone pressure diagnostic testing characterized the garage and house air leakage, the garage-to-house air leakage, and garage and house pressure relationships to each other and to outdoors using automated fan pressurization and pressure monitoring techniques. While the relative characteristics of this house may not represent the entire population of new construction configurations and air tightness levels (house and garage) throughout the country, the technical approach was conservative and should reasonably extend the usefulness of the results to a large spectrum of house configurations from this set of parametric tests in this one house. Based on the results of this testing, the two-step garage-to-house air leakage test protocol described above is recommended where whole-house exhaust ventilation is employed.

  12. OXIDATION OF TRANSURANIC ELEMENTS

    DOE Patents [OSTI]

    Moore, R.L.

    1959-02-17

    A method is reported for oxidizing neptunium or plutonium in the presence of cerous values without also oxidizing the cerous values. The method consists in treating an aqueous 1N nitric acid solution, containing such cerous values together with the trivalent transuranic elements, with a quantity of hydrogen peroxide stoichiometrically sufficient to oxidize the transuranic values to the hexavalent state, and digesting the solution at room temperature.

  13. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  14. DunoAir | Open Energy Information

    Open Energy Info (EERE)

    DunoAir Jump to: navigation, search Name: DunoAir Place: Hessen, Germany Zip: 6865 VX Sector: Wind energy Product: Doorwerth-based wind project developer. References: DunoAir1...

  15. Is there something in the air?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control the Present Is there something in the air? Is there something in the air? LANL implements a conscientious program of sampling to ensure air quality. August 1, 2013 ...

  16. Metal-Air Battery - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Metal-Air Battery Battelle Memorial Institute Contact ... The open electrochemical cells may function as metal-air batteries.Benefits Metal-air ...

  17. Why does LANL sample the air?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Why does LANL sample the air? Why does LANL sample the air? As the most significant pathway, air is monitored to ensure that any possible release is quickly detected. Diagram of ...

  18. Heating, Ventilation and Air Conditioning Efficiency

    Energy Savers [EERE]

    Functions of HVAC Systems The purpose of a Heating, Ventilation and Air Conditioning ... energy efficiency as one of the design factors 3 Air Air is the major conductor of heat. ...

  19. Final Report on the Clean Energy/Air Quality Integration Initiative Pilot Project of the U.S. Department of Energy's Mid-Atlantic Regional Office

    SciTech Connect (OSTI)

    Jacobson, D.; O'Connor, P.; High, C.; Brown, J.

    2006-08-01

    The MARO pilot project represents the first effort in the country to seek to obtain credit under a Clean Air Act (CAA) State Implementation Plan (SIP) for nitrogen oxide (NOx) emission reductions.

  20. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott; Wang, Ruiping; Derouane, Eric

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  1. Commercial Compressed Air Systems Program

    Broader source: Energy.gov [DOE]

    There are incentives for variable frequency drive screw compressors (10-40 HP), air receivers/tanks for load/no-load screw and vane compressors, cycling refrigerated thermal mass dryers (up to 30...

  2. ARM - Instrument - inletcvi-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsinletcvi-air Documentation Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Error occurred. Instrument "inletcvi

  3. ARM - Instrument - inletisok-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsinletisok-air Documentation Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Error occurred. Instrument "inletisok

  4. Clean Air Act | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services » Environment » Environmental Policy and Assistance » Clean Air Act Clean Air Act The primary law governing the Department of Energy (DOE) air pollution control activities is the Clean Air Act (CAA). This law defines the role of the U.S. Environmental Protection Agency (EPA) and state, local and tribal air programs in protecting and improving the nation's air quality and stratospheric ozone layer by regulating emissions from mobile and stationary sources. The CAA contains titles

  5. Air-Conditioning Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air-Conditioning Basics Air-Conditioning Basics August 16, 2013 - 1:59pm Addthis Air conditioning is one of the most common ways to cool homes and buildings. How Air Conditioners Work Air conditioners employ the same operating principles and basic components as refrigerators. Refrigerators use energy (usually electricity) to transfer heat from the cool interior of the refrigerator to the relatively warm surroundings; likewise, an air conditioner uses energy to transfer heat from the interior

  6. Tubular solid oxide fuel cell current collector

    DOE Patents [OSTI]

    Bischoff, Brian L.; Sutton, Theodore G.; Armstrong, Timothy R.

    2010-07-20

    An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

  7. Solid oxide electrochemical cell fabrication process

    DOE Patents [OSTI]

    Dollard, Walter J.; Folser, George R.; Pal, Uday B.; Singhal, Subhash C.

    1992-01-01

    A method to form an electrochemical cell (12) is characterized by the steps of thermal spraying stabilized zirconia over a doped lanthanum manganite air electrode tube (14) to provide an electrolyte layer (15), coating conductive particles over the electrolyte, pressurizing the outside of the electrolyte layer, feeding halide vapors of yttrium and zirconium to the outside of the electrolyte layer and feeding a source of oxygen to the inside of the electrolyte layer, heating to cause oxygen reaction with the halide vapors to close electrolyte pores if there are any and to form a metal oxide coating on and between the particles and provide a fuel electrode (16).

  8. Ductless Mini-Split Air Conditioners

    Broader source: Energy.gov [DOE]

    Ductless mini-split air conditioners are a good choice if you want a zoned air conditioning system but have no ducts in your house.

  9. Preheated Combustion Air | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preheated Combustion Air This tip sheet describes how to improve process heating efficiency by preheating combustion air for burners. PROCESS HEATING TIP SHEET 1 PDF icon ...

  10. Compressed Air Storage Strategies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Compressed Air Storage Strategies (August 2004) More Documents & Publications Compressed Air System Control Strategies Stabilizing System Pressure Effect of Intake on ...

  11. Save the World Air | Open Energy Information

    Open Energy Info (EERE)

    the World Air Jump to: navigation, search Name: Save the World Air Place: Santa Barbara, California Zip: 93101 Product: California-based, device manufacturer for better fuel...

  12. Room Air Conditioners | Department of Energy

    Office of Environmental Management (EM)

    frequently. Based on size alone, an air conditioner generally needs 20 Btu for each square foot of living space. Other important factors to consider when selecting an air...

  13. Central Air Conditioning | Department of Energy

    Office of Environmental Management (EM)

    Air supply and return ducts come from indoors through the home's exterior wall or roof to connect with the packaged air conditioner, which is usually located outdoors....

  14. Maintaining System Air Quality | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Maintaining System Air Quality (August 2004) More Documents & Publications Remove Condensate with Minimal Air Loss Engineer End Uses for Maximum Efficiency Stabilizing System...

  15. Property:AirMeasurement | Open Energy Information

    Open Energy Info (EERE)

    String Description MHK Axial Load Measurement Categories Used in FormTemplate MHKSensor & MHKInstrument Allows Values Barometric Pressure (Air);Precipitation (Air);Relative...

  16. Reactive Air Aluminizing - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Reactive Air Aluminizing Pacific Northwest National Laboratory Contact PNNL About This Technology Reactive Air Aluminizing process diagram ...

  17. Heating Ventilation and Air Conditioning Efficiency | Department...

    Energy Savers [EERE]

    Heating Ventilation and Air Conditioning Efficiency Heating Ventilation and Air Conditioning Efficiency This presentation covers common pitfalls that lead to wasted energy in ...

  18. ARM - Lesson Plans: Air Density and Temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Teachers' Toolbox Lesson Plans Lesson Plans: Air Density and Temperature Objective The objective of this activity is to investigate the effect of temperature on the density of air. ...

  19. Lithium Air Electrodes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Air Electrodes Pacific Northwest National Laboratory Contact PNNL About This Technology A comparison chart illustrates that Li-Air electrodes offer the highest energy ...

  20. Hopi Tribe Clean Air Partnership Project

    Energy Savers [EERE]

    HOPI TRIBE CLEAN AIR PARTNERSHIP PROJECT Roger Tungovia, Project Manager Ken Lomayestewa, ... Change the name from Hopi Clean Air Partnership Project to Hopi Renewable Energy Office ...

  1. Air Liquide Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    Hydrogen Energy Jump to: navigation, search Logo: Air Liquide Hydrogen Energy Name: Air Liquide Hydrogen Energy Address: 6, Rue Cognacq-Jay Place: Paris, France Zip: 75321 Sector:...

  2. The Effects of Oxy-firing Conditions on Gas-phase Mercury Oxidation by Chlorine and Bromine

    SciTech Connect (OSTI)

    Buitrago, Paula; Silcox, Geoffrey

    2010-06-30

    Bench-scale experiments were conducted in a quartz-lined, natural gas-fired reactor with the combustion air replaced with a blend of 27 mole percent oxygen, with the balance carbon dioxide. Quench rates of 210 and 440 K/s were tested. In the absence of sulfur dioxide, the oxy-firing environment caused a remarkable increase in oxidation of mercury by chlorine. At 400 ppm chlorine (as HCl equivalent), air-firing results in roughly 5 percent oxidation. At the same conditions with oxy-firing, oxidation levels are roughly 80 percent. Oxidation levels with bromine at 25 and 50 ppm (as HBr equivalent) ranged from 80 to 95 percent and were roughly the same for oxy- and air-firing conditions. Kinetic calculations of levels of oxidation at air- and oxy-conditions captured the essential features of the experimental results but have not revealed a mechanistic basis for the oxidative benefits of oxy-firing conditions. Mixtures of 25 ppm bromine and 100 and 400 ppm chlorine gave more than 90 percent oxidation. At all conditions, the effects of quench rate were not significant. The presence of 500 ppm SO2 caused a dramatic decline in the levels of oxidation at all oxy-fired conditions examined. This effect suggests that SO2 may be preventing oxidation in the gas phase or preventing oxidation in the wetconditioning system that was used in quantifying oxidized and elemental mercury concentrations. Similar effects of SO2 have been noted with air-firing. The addition of sodium thiosulfate to the hydroxide impingers that are part of wet conditioning systems may prevent liquid-phase oxidation from occurring.

  3. Remove Condensate with Minimal Air Loss | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remove Condensate with Minimal Air Loss This tip sheet outlines several condensate removal methods as part of maintaining compressed air system air quality. COMPRESSED AIR TIP ...

  4. Air quality implications associated with the selection of power plants in the Pacific Northwest

    SciTech Connect (OSTI)

    Baechler, M.C.; Glantz, C.S.; Edelmen, P.C.

    1993-11-01

    This assessment models emission inventories and pollutant emission rates for fossil fuel power plants. Ground-level air concentration of nitrogen oxides, sulfur dioxide and TSP are predicted. Pollutant deposition, non-acidic deposition, acidic deposition, ozone impacts, and visibility attenuation are considered. Human health effects, wildlife effects, effects on plants and crops, and residual environmental impacts are estimated from predicted emissions.

  5. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  6. Computational studies of polysiloxanes : oxidation potentials and decomposition reactions.

    SciTech Connect (OSTI)

    Assary, R. S.; Curtiss, L. A.; Redfern, P. C.; Zhang, Z.; Amine, K.

    2011-06-23

    Silicon-containing solvents have tremendous potential for application as electrolytes for electrical energy storage devices such as lithium-ion (air) batteries and supercapacitors. Quantum chemical methods were employed to investigate trends in oxidation potentials and decomposition reactions of a series of polysiloxanes. Various electron-donating and -withdrawing substituents can be used to tune the oxidation potential in shorter chain siloxanes but not in longer ones. Decomposition reactions of siloxanes in their oxidized states were investigated and compared against their carbon analogues. These studies suggest that the Si-O group provides added stability for siloxanes over their carbon analogues. Computational studies have also been performed for various disiloxanes and siloxanes with spacer groups to understand their thermochemical stability and oxidation potentials.

  7. Navajo Generating Station and Air Visibility Regulations: Alternatives and Impacts

    SciTech Connect (OSTI)

    Hurlbut, D. J.; Haase, S.; Brinkman, G.; Funk, K.; Gelman, R.; Lantz, E.; Larney, C.; Peterson, D.; Worley, C.; Liebsch, E.

    2012-01-01

    Pursuant to the Clean Air Act, the U.S. Environmental Protection Agency (EPA) announced in 2009 its intent to issue rules for controlling emissions from Navajo Generating Station that could affect visibility at the Grand Canyon and at several other national parks and wilderness areas. The final rule will conform to what EPA determines is the best available retrofit technology (BART) for the control of haze-causing air pollutants, especially nitrogen oxides. While EPA is ultimately responsible for setting Navajo Generating Station's BART standards in its final rule, it will be the U.S. Department of the Interior's responsibility to manage compliance and the related impacts. This study aims to assist both Interior and EPA by providing an objective assessment of issues relating to the power sector.

  8. Reduce Air Infiltration in Furnaces (English/Chinese) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    Chinese translation of the Reduce Air Infiltration in Furnaces fact sheet. Provides suggestions on how to improve furnace energy efficiency. Fuel-fired furnaces discharge combustion products through a stack or a chimney. Hot furnace gases are less dense and more buoyant than ambient air, so they rise, creating a differential pressure between the top and the bottom of the furnace. This differential, known as thermal head, is the source of a natural draft or negative pressure in furnaces and boilers. A well-designed furnace (or boiler) is built to avoid air leakage into the furnace or leakage of flue gases from the furnace to the ambient. However, with time, most furnaces develop cracks or openings around doors, joints, and hearth seals. These openings (leaks) usually appear small compared with the overall dimensions of the furnace, so they are often ignored. The negative pressure created by the natural draft (or use of an induced-draft fan) in a furnace draws cold air through the openings (leaks) and into the furnace. The cold air becomes heated to the furnace exhaust gas temperature and then exits through the flue system, wasting valuable fuel. It might also cause excessive oxidation of metals or other materials in the furnaces. The heat loss due to cold air leakage resulting from the natural draft can be estimated if you know four major parameters: (1) The furnace or flue gas temperature; (2) The vertical distance H between the opening (leak) and the point where the exhaust gases leave the furnace and its flue system (if the leak is along a vertical surface, H will be an average value); (3) The area of the leak, in square inches; and (4) The amount of operating time the furnace spends at negative pressure. Secondary parameters that affect the amount of air leakage include these: (1) The furnace firing rate; (2) The flue gas velocity through the stack or the stack cross-section area; (3) The burner operating conditions (e.g., excess air, combustion air temperature, and so on). For furnaces or boilers using an induced-draft (ID) fan, the furnace negative pressure depends on the fan performance and frictional losses between the fan inlet and the point of air leakage. In most cases, it would be necessary to measure or estimate negative pressure at the opening. The amount of air leakage, the heat lost in flue gases, and their effects on increased furnace or boiler fuel consumption can be calculated by using the equations and graphs given in Industrial Furnaces (see W. Trinks et al., below). Note that the actual heat input required to compensate for the heat loss in flue gases due to air leakage would be greater than the heat contained in the air leakage because of the effect of available heat in the furnace. For a high-temperature furnace that is not maintained properly, the fuel consumption increase due to air leakage can be as high as 10% of the fuel input.

  9. NEPTUNIUM OXIDE PROCESSING

    SciTech Connect (OSTI)

    Jordan, J; Watkins, R; Hensel, S

    2009-05-27

    The Savannah River Site's HB-Line Facility completed a campaign in which fifty nine cans of neptunium oxide were produced and shipped to the Idaho National Laboratory in the 9975 shipping container. The neptunium campaign was divided into two parts: Part 1 which consisted of oxide made from H-Canyon neptunium solution which did not require any processing prior to conversion into an oxide, and Part 2 which consisted of oxide made from additional H-Canyon neptunium solutions which required processing to purify the solution prior to conversion into an oxide. The neptunium was received as a nitrate solution and converted to oxide through ion-exchange column extraction, precipitation, and calcination. Numerous processing challenges were encountered in order make a final neptunium oxide product that could be shipped in a 9975 shipping container. Among the challenges overcome was the issue of scale: translating lab scale production into full facility production. The balance between processing efficiency and product quality assurance was addressed during this campaign. Lessons learned from these challenges are applicable to other processing projects.

  10. Tips: Air Ducts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tips: Air Ducts Tips: Air Ducts Air ducts: out of sight, out of mind. The unsealed ducts in your attic and crawlspaces lose air, and uninsulated ducts lose heat -- wasting energy and money. Air ducts: out of sight, out of mind. The unsealed ducts in your attic and crawlspaces lose air, and uninsulated ducts lose heat -- wasting energy and money. Your air ducts are one of the most important systems in your home, and if the ducts are poorly sealed or insulated they are likely contributing to

  11. Fuel cell stack with passive air supply

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2006-01-17

    A fuel cell stack has a plurality of polymer electrolyte fuel cells (PEFCs) where each PEFC includes a rectangular membrane electrode assembly (MEA) having a fuel flow field along a first axis and an air flow field along a second axis perpendicular to the first axis, where the fuel flow field is long relative to the air flow field. A cathode air flow field in each PEFC has air flow channels for air flow parallel to the second axis and that directly open to atmospheric air for air diffusion within the channels into contact with the MEA.

  12. Precombustion control of air toxics

    SciTech Connect (OSTI)

    Akers, D.J.; Harrison, C.; Nowak, M.; Toole-O`Neil, B.

    1996-12-31

    If regulation of hazardous air pollutant emissions from utility boilers occurs in the next few years, the least-cost, lowest-risk control method for many utilities is likely to be some form of coal cleaning. Approximately 75 percent of coal mined east of the Mississippi River is already cleaned before it is used by the electric utility industry. Current methods of coal cleaning reduce ash and sulfur content by removing ash-forming and sulfur-bearing minerals; these same methods have the capability to remove large amounts of most of the 14 elements named as hazardous air pollutants (HAPs) in Title III of the 1990 Amendments to the Clean Air Act.

  13. High Energy Efficiency Air Conditioning

    SciTech Connect (OSTI)

    Edward McCullough; Patrick Dhooge; Jonathan Nimitz

    2003-12-31

    This project determined the performance of a new high efficiency refrigerant, Ikon B, in a residential air conditioner designed to use R-22. The refrigerant R-22, used in residential and small commercial air conditioners, is being phased out of production in developed countries beginning this year because of concerns regarding its ozone depletion potential. Although a replacement refrigerant, R-410A, is available, it operates at much higher pressure than R-22 and requires new equipment. R-22 air conditioners will continue to be in use for many years to come. Air conditioning is a large part of expensive summer peak power use in many parts of the U.S. Previous testing and computer simulations of Ikon B indicated that it would have 20 - 25% higher coefficient of performance (COP, the amount of cooling obtained per energy used) than R-22 in an air-cooled air conditioner. In this project, a typical new R-22 residential air conditioner was obtained, installed in a large environmental chamber, instrumented, and run both with its original charge of R-22 and then with Ikon B. In the environmental chamber, controlled temperature and humidity could be maintained to obtain repeatable and comparable energy use results. Tests with Ikon B included runs with and without a power controller, and an extended run for several months with subsequent analyses to check compatibility of Ikon B with the air conditioner materials and lubricant. Baseline energy use of the air conditioner with its original R-22 charge was measured at 90 deg F and 100 deg F. After changeover to Ikon B and a larger expansion orifice, energy use was measured at 90 deg F and 100 deg F. Ikon B proved to have about 19% higher COP at 90 deg F and about 26% higher COP at 100 deg F versus R-22. Ikon B had about 20% lower cooling capacity at 90 deg F and about 17% lower cooling capacity at 100 deg F versus R-22 in this system. All results over multiple runs were within 1% relative standard deviation (RSD). All of these values agree well with previous results and computer simulations of Ikon B performance versus R-22. The lower cooling capacity of Ikon B is not a concern unless a particular air conditioner is near its maximum cooling capacity in application. Typically, oversized A/C systems are installed by contractors to cover contingencies. In the extended run with Ikon B, which lasted about 4.5 months at 100 deg F ambient temperature and 68% compressor on time, the air conditioner performed well with no significant loss of energy efficiency. Post-run analysis of the refrigerant, compressor lubricant oil, compressor, compressor outlet tubing, and the filter/dryer showed minor effects but nothing that was considered significant. The project was very successful. All objectives were achieved, and the performance of Ikon B indicates that it can easily be retrofitted into R-22 air conditioners to give 15 - 20% energy savings and a 1 - 3 year payback of retrofit costs depending on location and use. Ikon B has the potential to be a successful commercial product.

  14. Mixed Oxide Fuel Fabrication Facility

    National Nuclear Security Administration (NNSA)

    0%2A en Mixed Oxide (MOX) Fuel Fabrication Facility http:nnsa.energy.govfieldofficessavannah-river-field-officemixed-oxide-mox-fuel-fabrication-facility

  15. Chapter 22: Compressed Air Evaluation Protocol

    SciTech Connect (OSTI)

    Benton, N.

    2014-11-01

    Compressed-air systems are used widely throughout industry for many operations, including pneumatic tools, packaging and automation equipment, conveyors, and other industrial process operations. Compressed-air systems are defined as a group of subsystems composed of air compressors, air treatment equipment, controls, piping, pneumatic tools, pneumatically powered machinery, and process applications using compressed air. A compressed-air system has three primary functional subsystems: supply, distribution, and demand. Air compressors are the primary energy consumers in a compressed-air system and are the primary focus of this protocol. The two compressed-air energy efficiency measures specifically addressed in this protocol are: high-efficiency/variable speed drive (VSD) compressor replacing modulating compressor; compressed-air leak survey and repairs. This protocol provides direction on how to reliably verify savings from these two measures using a consistent approach for each.

  16. Device for staged carbon monoxide oxidation

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Nguyen, Trung V.; Guante, Jr., Joseph

    1993-01-01

    A method and apparatus for selectively oxidizing carbon monoxide in a hydrogen rich feed stream. The method comprises mixing a feed stream consisting essentially of hydrogen, carbon dioxide, water and carbon monoxide with a first predetermined quantity of oxygen (air). The temperature of the mixed feed/oxygen stream is adjusted in a first the heat exchanger assembly (20) to a first temperature. The mixed feed/oxygen stream is sent to reaction chambers (30,32) having an oxidation catalyst contained therein. The carbon monoxide of the feed stream preferentially absorbs on the catalyst at the first temperature to react with the oxygen in the chambers (30,32) with minimal simultaneous reaction of the hydrogen to form an intermediate hydrogen rich process stream having a lower carbon monoxide content than the feed stream. The elevated outlet temperature of the process stream is carefully controlled in a second heat exchanger assembly (42) to a second temperature above the first temperature. The process stream is then mixed with a second predetermined quantity of oxygen (air). The carbon monoxide of the process stream preferentially reacts with the second quantity of oxygen in a second stage reaction chamber (56) with minimal simultaneous reaction of the hydrogen in the process stream. The reaction produces a hydrogen rich product stream having a lower carbon monoxide content than the process stream. The product stream is then cooled in a third heat exchanger assembly (72) to a third predetermined temperature. Three or more stages may be desirable, each with metered oxygen injection.

  17. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. , Guttadora, Gregory L. , Parker, John J.

    2006-02-07

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  18. Long-term, low-temperature oxidation of PWR spent fuel: Interim transition report

    SciTech Connect (OSTI)

    Einziger, R.E.; Buchanan, H.C.

    1988-05-01

    Since some of the fuel rods will be breached and eventually most of the cladding will corrode, exposing fuel, one factor influencing the ability of spent fuel to retain radionuclides is its oxidation state in the expected moist air atmosphere. Oxidation of the fuel could split the cladding, exposing additional fuel and changing the leaching characteristics. Thermodynamically, there is no reason why UO{sub 2} should not oxidize completely to UO{sub 3} at repository temperatures. The underlying uncertainty is the rate of oxidation. Extrapolation of higher temperature data indicates that insufficient oxidation to convert all of the fuel to U{sub 3}O{sub 8} will occur during the first 10,000 years. However, lower oxidation states, such as U{sub 4}O{sub 9} and U{sub 3}O{sub 7}, might form. To date, the tests have run between 3200 and 4100 hours out of a planned 16,000-hour duration. Some preliminary conclusions can be drawn: (1) Moisture content of the air has no significant effect on oxidation rate, (2) the data have an uncertainty of 15 to 20%, which must be accounted for in the interpretation of single sample tests, and (3) below 175{degree}C, the oxidation rate is dependent on the particle size in the sample. The smaller particles oxidize more rapidly. 19 refs., 23 figs., 7 tabs.

  19. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

  20. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

  1. The Effects of Water Vapor and Hydrogen on the High-Temperature Oxidation of Alloys

    SciTech Connect (OSTI)

    Mu, N.; Jung, K.; Yanar, N. M.; Pettit, F. S; Holcomb, G. R.; Howard, B. H.; Meier, G. H.

    2013-06-01

    Essentially all alloys and coatings that are resistant to corrosion at high temperature require the formation of a protective (slowly-growing and adherent) oxide layer by a process known as selective oxidation. The fundamental understanding of this process has been developed over the years for exposure in pure oxygen or air. However, the atmospheres in most applications contain significant amounts of water vapor which can greatly modify the behavior of protective oxides. The development of oxy-fuel combustion systems in which fossil fuels are burned in a mixture of recirculated flue gas and oxygen, rather than in air, has caused renewed interest in the effects of water vapor and steam on alloy oxidation. The focus of this paper is on the ways the presence of water vapor can directly alter the selective oxidation process. The paper begins with a brief review of the fundamentals of selective oxidation followed by a description of recent experimental results regarding the effect of water vapor on the oxidation of a variety of chromia-forming alloys (Fe- and Ni-base) in the temperature range 600 to 700 °C. The atmospheres include air, air-H{sub 2}O, Ar-H{sub 2}O and Ar-H{sub 2}O-O{sub 2}. Then the behavior of alumina-forming alloys in H{sub 2}O-containing atmospheres is briefly described. As hydrogen is produced during oxidation of alloys in H{sub 2}O, it can be released back into the gas phase or injected into the metal (where it can diffuse through to the other side). Experiments in which hydrogen concentrations have been measured on both sides of thin specimens during oxidation by H{sub 2}O on only one side are described. Finally, it is attempted to catalogue the various experimental observations under a few general principles.

  2. ISOTHERMAL AIR INGRESS VALIDATION EXPERIMENTS

    SciTech Connect (OSTI)

    Chang H Oh; Eung S Kim

    2011-09-01

    Idaho National Laboratory carried out air ingress experiments as part of validating computational fluid dynamics (CFD) calculations. An isothermal test loop was designed and set to understand the stratified-flow phenomenon, which is important as the initial air flow into the lower plenum of the very high temperature gas cooled reactor (VHTR) when a large break loss-of-coolant accident occurs. The unique flow characteristics were focused on the VHTR air-ingress accident, in particular, the flow visualization of the stratified flow in the inlet pipe to the vessel lower plenum of the General Atomic’s Gas Turbine-Modular Helium Reactor (GT-MHR). Brine and sucrose were used as heavy fluids, and water was used to represent a light fluid, which mimics a counter current flow due to the density difference between the stimulant fluids. The density ratios were changed between 0.87 and 0.98. This experiment clearly showed that a stratified flow between simulant fluids was established even for very small density differences. The CFD calculations were compared with experimental data. A grid sensitivity study on CFD models was also performed using the Richardson extrapolation and the grid convergence index method for the numerical accuracy of CFD calculations . As a result, the calculated current speed showed very good agreement with the experimental data, indicating that the current CFD methods are suitable for predicting density gradient stratified flow phenomena in the air-ingress accident.

  3. Strong interactions in air showers

    SciTech Connect (OSTI)

    Dietrich, Dennis D.

    2015-03-02

    We study the role new gauge interactions in extensions of the standard model play in air showers initiated by ultrahigh-energy cosmic rays. Hadron-hadron events remain dominated by quantum chromodynamics, while projectiles and/or targets from beyond the standard model permit us to see qualitative differences arising due to the new interactions.

  4. Bipolar plating of metal contacts onto oxide interconnection for solid oxide electrochemical cell

    DOE Patents [OSTI]

    Isenberg, A.O.

    1987-03-10

    Disclosed is a method of forming an adherent metal deposit on a conducting layer of a tube sealed at one end. The tube is immersed with the sealed end down into an aqueous solution containing ions of the metal to be deposited. An ionically conducting aqueous fluid is placed inside the tube and a direct current is passed from a cathode inside the tube to an anode outside the tube. Also disclosed is a multi-layered solid oxide fuel cell tube which consists of an inner porous ceramic support tube, a porous air electrode covering the support tube, a non-porous electrolyte covering a portion of the air electrode, a non-porous conducting interconnection covering the remaining portion of the electrode, and a metal deposit on the interconnection. 1 fig.

  5. Bipolar plating of metal contacts onto oxide interconnection for solid oxide electrochemical cell

    DOE Patents [OSTI]

    Isenberg, Arnold O.

    1987-01-01

    Disclosed is a method of forming an adherent metal deposit on a conducting layer of a tube sealed at one end. The tube is immersed with the sealed end down into an aqueous solution containing ions of the metal to be deposited. An ionically conducting aqueous fluid is placed inside the tube and a direct current is passed from a cathode inside the tube to an anode outside the tube. Also disclosed is a multi-layered solid oxide fuel cell tube which consists of an inner porous ceramic support tube, a porous air electrode covering the support tube, a non-porous electrolyte covering a portion of the air electrode, a non-porous conducting interconnection covering the remaining portion of the electrode, and a metal deposit on the interconnection.

  6. ISSUANCE 2015-05-01: Commercial Package Air Conditioners and Commercial Warm Air Furnaces Working Group; Notice of Open Meetings

    Broader source: Energy.gov [DOE]

    Commercial Package Air Conditioners and Commercial Warm Air Furnaces Working Group; Notice of Open Meetings

  7. DOE Requires Air-Con International to Cease Sales of Inefficient Air Conditioners and Proposes Penalties

    Broader source: Energy.gov [DOE]

    The Department has issued a Notice of Noncompliance Determination and Proposed Civil Penalty to Air-Con, International, requiring Air-Con to cease the sale of certain air-conditioning systems in...

  8. Multi-stage, isothermal CO preferential oxidation reactor

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Brundage, Mark A. (Pittsford, NY); Borup, Rodney Lynn (East Rochester, NY); Pettit, William Henry (Rochester, NY); Stukey, Kevin (W. Henrietta, NY); Hart-Predmore, David James (Rochester, NY); Fairchok, Joel (Alexander, NY)

    2000-01-01

    A multi-stage, isothermal, carbon monoxide preferential oxidation (PrOx) reactor comprising a plurality of serially arranged, catalyzed heat exchangers, each separated from the next by a mixing chamber for homogenizing the gases exiting one heat exchanger and entering the next. In a preferred embodiment, at least some of the air used in the PrOx reaction is injected directly into the mixing chamber between the catalyzed heat exchangers.

  9. Open end protection for solid oxide fuel cells

    DOE Patents [OSTI]

    Zafred, Paolo R.; Dederer, Jeffrey T.; Tomlins, Gregory W.; Toms, James M.; Folser, George R.; Schmidt, Douglas S.; Singh, Prabhakar; Hager, Charles A.

    2001-01-01

    A solid oxide fuel cell (40) having a closed end (44) and an open end (42) operates in a fuel cell generator (10) where the fuel cell open end (42) of each fuel cell contains a sleeve (60, 64) fitted over the open end (42), where the sleeve (60, 64) extends beyond the open end (42) of the fuel cell (40) to prevent degradation of the interior air electrode of the fuel cell by fuel gas during operation of the generator (10).

  10. Electrocatalytic Activity of Transition Metal Oxide-Carbon Composites for Oxygen Reduction in Alkaline Batteries and Fuel Cells

    SciTech Connect (OSTI)

    Malkhandi, S; Trinh, P; Manohar, AK; Jayachandrababu, KC; Kindler, A; Prakash, GKS; Narayanan, SR

    2013-06-07

    Conductive transition metal oxides (perovskites, spinels and pyrochlores) are attractive as catalysts for the air electrode in alkaline rechargeable metal-air batteries and fuel cells. We have found that conductive carbon materials when added to transition metal oxides such as calcium-doped lanthanum cobalt oxide, nickel cobalt oxide and calcium-doped lanthanum manganese cobalt oxide increase the electrocatalytic activity of the oxide for oxygen reduction by a factor of five to ten. We have studied rotating ring-disk electrodes coated with (a) various mass ratios of carbon and transition metal oxide, (b) different types of carbon additives and (c) different types of transition metal oxides. Our experiments and analysis establish that in such composite catalysts, carbon is the primary electro- catalyst for the two-electron electro-reduction of oxygen to hydroperoxide while the transition metal oxide decomposes the hydroperoxide to generate additional oxygen that enhances the observed current resulting in an apparent four-electron process. These findings are significant in that they change the way we interpret previous reports in the scientific literature on the electrocatalytic activity of various transition metal oxide- carbon composites for oxygen reduction, especially where carbon is assumed to be an additive that just enhances the electronic conductivity of the oxide catalyst. (C) 2013 The Electrochemical Society. All rights reserved.

  11. History of Air Conditioning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    History of Air Conditioning History of Air Conditioning July 20, 2015 - 3:15pm Addthis Paul Lester Paul Lester Digital Content Specialist, Office of Public Affairs MORE ON AIR CONDITIONING Check out our Energy Saver 101 infographic to learn how air conditioners work. Go to Energy Saver for more tips and advice on home cooling. Stay up-to-date on how the Energy Department is working to improve air conditioning technology. We take the air conditioner for granted, but imagine what life would be

  12. Room Air Conditioners | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Room Air Conditioners Room Air Conditioners A room air conditioner is one solution to cooling part of a house. | Photo courtesy of ©iStockphoto/kschulze. A room air conditioner is one solution to cooling part of a house. | Photo courtesy of ©iStockphoto/kschulze. Room or window air conditioners cool rooms rather than the entire home or business. If they provide cooling only where they're needed, room air conditioners are less expensive to operate than central units, even though their

  13. Incorporation of oxidized uranium into Fe (hydr)oxides during Fe(II) catalyzed remineralization

    SciTech Connect (OSTI)

    Nico, Peter S.; Stewart, Brandy D.; Fendorf, Scott

    2009-07-01

    The form of solid phase U after Fe(II) induced anaerobic remineralization of ferrihydrite in the presence of aqueous and absorbed U(VI) was investigated under both abiotic batch and biotic flow conditions. Experiments were conducted with synthetic ground waters containing 0.168 mM U(VI), 3.8 mM carbonate, and 3.0 mM Ca{sup 2+}. In spite of the high solubility of U(VI) under these conditions, appreciable removal of U(VI) from solution was observed in both the abiotic and biotic systems. The majority of the removed U was determined to be substituted as oxidized U (U(VI) or U(V)) into the octahedral position of the goethite and magnetite formed during ferrihydrite remineralization. It is estimated that between 3% and 6% of octahedral Fe(III) centers in the new Fe minerals were occupied by U(VI). This site specific substitution is distinct from the non-specific U co-precipitation processes in which uranyl compounds, e.g. uranyl hydroxide or carbonate, are entrapped with newly formed Fe oxides. The prevalence of site specific U incorporation under both abiotic and biotic conditions and the fact that the produced solids were shown to be resistant to both extraction (30 mM KHCO{sub 3}) and oxidation (air for 5 days) suggest the potential importance of sequestration in Fe oxides as a stable and immobile form of U in the environment.

  14. Long-Term Cyclic Oxidation Behavior of Wrought Commercial Alloys at High Temperatures

    SciTech Connect (OSTI)

    Bingtao Li

    2003-08-05

    The oxidation resistance of a high-temperature alloy is dependent upon sustaining the formation of a protective scale, which is strongly related to the alloying composition and the oxidation condition. The protective oxide scale only provides a finite period of oxidation resistance owing to its eventual breakdown, which is especially accelerated under thermal cycling conditions. This current study focuses on the long-term cyclic oxidation behavior of a number of commercial wrought alloys. The alloys studied were Fe- and Ni-based, containing different levels of minor elements, such as Si, Al, Mn, and Ti. Oxidation testing was conducted at 1000 and 1100 C in still air under both isothermal and thermal cycling conditions (1-day and 7-days). The specific aspects studied were the oxidation behavior of chromia-forming alloys that are used extensively in industry. The current study analyzed the effects of alloying elements, especially the effect of minor element Si, on cyclic oxidation resistance. The behavior of oxide scale growth, scale spallation, subsurface changes, and chromium interdiffusion in the alloy were analyzed in detail. A novel model was developed in the current study to predict the life-time during cyclic oxidation by simulating oxidation kinetics and chromium interdiffusion in the subsurface of chromia-forming alloys.

  15. Air sampling in the workplace. Final report

    SciTech Connect (OSTI)

    Hickey, E.E.; Stoetzel, G.A.; Strom, D.J.; Cicotte, G.R.; Wiblin, C.M.; McGuire, S.A.

    1993-09-01

    This report provides technical information on air sampling that will be useful for facilities following the recommendations in the NRC`s Regulatory Guide 8.25, Revision 1, ``Air sampling in the Workplace.`` That guide addresses air sampling to meet the requirements in NRC`s regulations on radiation protection, 10 CFR Part 20. This report describes how to determine the need for air sampling based on the amount of material in process modified by the type of material, release potential, and confinement of the material. The purposes of air sampling and how the purposes affect the types of air sampling provided are discussed. The report discusses how to locate air samplers to accurately determine the concentrations of airborne radioactive materials that workers will be exposed to. The need for and the methods of performing airflow pattern studies to improve the accuracy of air sampling results are included. The report presents and gives examples of several techniques that can be used to evaluate whether the airborne concentrations of material are representative of the air inhaled by workers. Methods to adjust derived air concentrations for particle size are described. Methods to calibrate for volume of air sampled and estimate the uncertainty in the volume of air sampled are described. Statistical tests for determining minimum detectable concentrations are presented. How to perform an annual evaluation of the adequacy of the air sampling is also discussed.

  16. Generic air sampler probe tests

    SciTech Connect (OSTI)

    Glissmeyer, J.A.; Ligotke, M.W.

    1995-11-01

    Tests were conducted to determine the best nozzle and probe designs for new air sampling systems to be installed in the ventilation systems of some of the waste tanks at the Hanford Site in Richland, Washington. Isokinetic nozzle probes and shrouded probes were tested. The test aerosol was sodium-fluorescein-tagged oleic acid. The test parameters involved particle sizes from 1 to 15 {mu}m, air velocities from 3 to 15 m/s. The results of the tests show that shrouded probes can deliver samples with significantly less particle-size bias then the isokinetic nozzle probes tested. Tests were also conducted on two sample flow splitters to determine particle loss as a function of aerodynamic particle size. The particle size range covered in these tests was 5 to 15 {mu}m. The results showed little particle loss, but did show a bias in particle concentration between the two outlets of each splitter for the larger particle sizes.

  17. Clean Air Act. Revision 5

    SciTech Connect (OSTI)

    Not Available

    1994-02-15

    This Reference Book contains a current copy of the Clean Air Act, as amended, and those regulations that implement the statute and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. This Reference Book has been completely revised and is current through February 15, 1994.

  18. ARM - Campaign Instrument - sp2-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -air Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Single Particle Soot Photometer - Airborne (SP2-AIR)...

  19. ARM - Campaign Instrument - mmcr94-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -air Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : 94 GHz, W-band Airborne Cloud Radar (MMCR94-AIR)...

  20. Protective supplied-breathing-air garment

    DOE Patents [OSTI]

    Childers, E.L.; von Hortenau, E.F.

    1982-05-28

    A breathing-air garment for isolating a wearer from hostile environments containing toxins or irritants is disclosed. The garment includes a suit and a separate head-protective enclosure or hood engaging a suit collar in sealing attachment. The hood and suit collar are cylindrically shaped and dimensioned to enable the wearer to withdraw his hands from the suit sleeves to perform manual tasks within the hood interior. Breathing air is supplied from an external air line with an air-delivery hose attached to the hood interior. The hose feeds air into an annular halo-like fiber-filled plenum having spaced discharge orifices attached to the hood top wall. A plurality of air exhaust/check valves located at the suit extremities cooperate with the hood air-delivery system to provide a cooling flow of circulating air from the hood throughout the suit interior. A suit entry seal provided on the suit sealed with an adhesive sealing flap.

  1. Advanced Management of Compressed Air Systems

    Broader source: Energy.gov [DOE]

    Find out how a compressed air system works and the benefits of optimal compressed air system performance. This training is designed to help end users as well as industry solution providers learn...

  2. ESPC Success Story - Dyess Air Force Base

    Energy Savers [EERE]

    DYESS AIR FORCE BASE DYESS, TEXAS Water Conservation and Green Energy ESPC SUCCESS STORY Dyess Air Force Base and surrounding west Texas has been under extreme-drought water ...

  3. Seneca Compressed Air Energy Storage (CAES) Project

    SciTech Connect (OSTI)

    2012-11-30

    This document provides specifications for the process air compressor for a compressed air storage project, requests a budgetary quote, and provides supporting information, including compressor data, site specific data, water analysis, and Seneca CAES value drivers.

  4. Is there something in the air?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    there something in the air? LANL implements a conscientious program of sampling to ensure air quality. August 1, 2013 Clouds over Los Alamos Clouds over Los Alamos Why does LANL...

  5. SolarAire LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Place: Folsom, California Sector: Solar Product: Developing a solar thermal air conditioning unit. References: SolarAire LLC1 This article is a stub. You can help OpenEI by...

  6. Hill Air Force Base | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Energy savings performance contracting at Hill Air Force Base generated much interest ... There was a need to reduce energy and water use at Hill Air Force Base, which is subjected ...

  7. Air Traffic Operations | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the Air Traffic Cloud Click to email this to a friend (Opens in new window) Share on ... In the Air Traffic Cloud Researchers Mike Durling and Liling Ren discuss new technology to ...

  8. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-09-29

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase is dispersed.

  9. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-03-17

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

  10. Perform Tests and Document Results and Analysis of Oxide Layer Effects and Comparisons

    SciTech Connect (OSTI)

    Collins, E. D.; DelCul, G. D.; Spencer, B. B.; Hunt, R. D.; Ausmus, C.

    2014-08-30

    During the initial feasibility test using actual used nuclear fuel (UNF) cladding in FY 2012, an incubation period of 30–45 minutes was observed in the initial dry chlorination. The cladding hull used in the test had been previously oxidized in a dry air oxidation pretreatment prior to removal of the fuel. The cause of this incubation period was attributed to the resistance to chlorination of an oxide layer imparted by the dry oxidation pretreatment on the cladding. Subsequently in 2013, researchers at the Korea Atomic Energy Institute (KAERI) reported on their chlorination study [R1] on ~9-gram samples of unirradiated ZirloTM cladding tubes that had been previously oxidized in air at 500oC for various time periods to impart oxide layers of varying thickness. In early 2014, discussions with Indefinite Delivery, Indefinite Quantity (IDIQ) contracted technical consultants from Westinghouse described their previous development (and patents) [R2] on methods of chemical washing to remove some or all of the hydrous oxide layer imparted on UNF cladding during irradiation in light water reactors (LWRs) . Thus, the Oak Ridge National Laboratory (ORNL) study, described herein, was planned to extend the KAERI study on the effects of anhydrous oxide layers, but on larger ~100-gram samples of unirradiated zirconium alloy cladding tubes, and to investigate the effects of various methods of chemical pretreatment prior to chlorination with 100% chlorine on the average reaction rates and Cl2 usage efficiencies.

  11. Hill Air Force Base | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hill Air Force Base Hill Air Force Base Hill Air Force Base Overview Energy savings performance contracting at Hill Air Force Base generated much interest during a recent training session on energy management that downlinked 12 Department of Defense sites. Energy systems in 940 buildings on the Base will be upgraded under an 18-year ESPC between the Government and the energy service company, CES/Way. Improvements are distributed over five task orders that will be completed in five years, with

  12. Preventive Maintenance Strategies for Compressed Air Systems

    Broader source: Energy.gov [DOE]

    This tip sheet discusses preventive maintenance strategies for compressed air systems to avoid high equipment repair and replacement costs.

  13. Compressed Air Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Assistance » Compressed Air Systems Compressed Air Systems Applying best energy management practices and purchasing energy-efficient equipment can lead to significant savings in compressed air systems. Use the software tools, training, and publications listed below to improve performance and save energy. Compressed Air Tools Tools to Assess Your Energy System AIRMaster+ Tool AIRMaster+ LogTool Qualified Specialists Qualified Specialists have passed a rigorous competency examination on

  14. FAA Air Traffic Organization Safety Management

    Broader source: Energy.gov [DOE]

    Presenter: Mark DeNicuolo, Manager Performance and Analyses Air Traffic Organization Safety and Technical Training Federal Aviation Administration

  15. Biological Air Emissions Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Air Emissions Control Biological Air Emissions Control Innovative Technology Enables Low-Cost, Energy-Efficient Treatment of Industrial Exhaust Streams Air quality standards are becoming more stringent for the U.S. wood products industry. Emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) (including methanol, formaldehyde, acetylaldehyde, and acrolein) during production of wood products must be tightly controlled. Conventional VOCs and HAPs emission

  16. Thermally Oxidized Silicon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the

  17. Molecular water oxidation catalyst

    DOE Patents [OSTI]

    Gratzel, Michael; Munavalli, Shekhar; Pern, Fu-Jann; Frank, Arthur J.

    1993-01-01

    A dimeric composition of the formula: ##STR1## wherein L', L", L'", and L"" are each a bidentate ligand having at least one functional substituent, the ligand selected from bipyridine, phenanthroline, 2-phenylpyridine, bipyrimidine, and bipyrazyl and the functional substituent selected from carboxylic acid, ester, amide, halogenide, anhydride, acyl ketone, alkyl ketone, acid chloride, sulfonic acid, phosphonic acid, and nitro and nitroso groups. An electrochemical oxidation process for the production of the above functionally substituted bidentate ligand diaqua oxo-bridged ruthenium dimers and their use as water oxidation catalysts is described.

  18. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  19. Workshop on indoor air quality research needs

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Workshop participants report on indoor air quality research needs including the monitoring of indoor air quality, report of the instrumentation subgroup of indoor air quality, health effects, and the report of the control technology session. Risk analysis studies addressing indoor environments were also summarized. (DLS)

  20. A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Authors: Sherman, B. D., Pillai, S., Kodis, G., Bergkamp, J., Mallouk, T. E., Gust, D., Moore, T. A., and Moore, A. L. Title: A Porphyrin-Stabilized Iridium Oxide Water Oxidation...

  1. Assessment of the Market for Compressed Air Efficiency Services

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    14 Characteristics of Compressed Air Systems 14 Compressed Air System Management 17 Customer Knowledge of Compressed Air System Energy Use and Efficiency Opportunities 18 ...

  2. High-Efficiency Window Air Conditioners - Building America Top...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Efficiency Window Air Conditioners - Building America Top Innovation High-Efficiency Window Air Conditioners - Building America Top Innovation This photo shows a window air ...

  3. Reduce Air Infiltration in Furnaces | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Infiltration in Furnaces Reduce Air Infiltration in Furnaces This tip sheet describes ... PROCESS HEATING TIP SHEET 5 PDF icon Reduce Air Infiltration in Furnaces (January 2006) ...

  4. New Air and Water-Resistive Barrier Technologies for Commercial...

    Energy Savers [EERE]

    New Air and Water-Resistive Barrier Technologies for Commercial Buildings New Air and Water-Resistive Barrier Technologies for Commercial Buildings New Air and Water-Resistive ...

  5. ARM - Field Campaign - AIRS Validation Soundings Phase IV and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The AIRS instrument was intended to make highly accurate measurements of air temperature, humidity, clouds, and surface temperature. The data collected by AIRS was...

  6. 2011 Air Quality Regulations Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Quality Regulations Report 2011 Air Quality Regulations Report PDF icon 2011 Air Quality Regulations Report120111.pdf More Documents & Publications 2011:...

  7. 2011: Air Quality Regulations Report | Department of Energy

    Office of Environmental Management (EM)

    : Air Quality Regulations Report 2011: Air Quality Regulations Report PDF icon 2011 Air Quality Regulations ReportA120911.pdf More Documents & Publications 2011...

  8. RAPID/Geothermal/Air Quality/Alaska | Open Energy Information

    Open Energy Info (EERE)

    RAPIDGeothermalAir QualityAlaska < RAPID | Geothermal | Air Quality(Redirected from RAPIDOverviewGeothermalAir QualityAlaska) Jump to: navigation, search RAPID...

  9. Attic Air Sealing Guide - Building America Top Innovation | Department...

    Energy Savers [EERE]

    Attic Air Sealing Guide - Building America Top Innovation Attic Air Sealing Guide - Building America Top Innovation Image showing step-by-step instructions for air sealing. One of ...

  10. Improving Compressed Air System Performance Third Edition | Department...

    Energy Savers [EERE]

    Compressed Air System Performance Third Edition Improving Compressed Air System Performance Third Edition PDF icon Improving Compressed Air Sourcebook version 3.pdf More Documents ...

  11. Energy Savings with Acceptable Indoor Air Quality Through Improved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Flow Control in Residential Retrofit Energy Savings with Acceptable Indoor Air Quality Through Improved Air Flow Control in Residential Retrofit Sealed duct penetrations. ...

  12. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  13. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1993-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  14. Conformations of organophosphine oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    De Silva, Nuwan; Zahariev, Federico; Hay, Benjamin P.; Gordon, Mark S.; Windus, Theresa L.

    2015-07-17

    The conformations of a series of organophosphine oxides, OP(CH3)2R, where R = methyl, ethyl, isopropyl, tert-butyl, vinyl, and phenyl, are predicted using the MP2/cc-pVTZ level of theory. Comparison of potential energy surfaces for rotation about P–C bonds with crystal structure data reveals a strong correlation between predicted location and energetics of minima and histograms of dihedral angle distributions observed in the solid state. In addition, the most stable conformers are those that minimize the extent of steric repulsion between adjacent rotor substituents, and the torsional barriers tend to increase with the steric bulk of the rotating alkyl group. MM3 forcemore » field parameters were adjusted to fit the MP2 results, providing a fast and accurate model for predicting organophosphine oxides shapes—an essential part of understanding the chemistry of these compounds. As a result, the predictive power of the modified MM3 model was tested against MP2/cc-pVTZ conformations for triethylphosphine oxide, OP(CH2CH3)3, and triphenylphosphine oxide, OP(Ph)3.« less

  15. Conformations of organophosphine oxides

    SciTech Connect (OSTI)

    De Silva, Nuwan; Zahariev, Federico; Hay, Benjamin P.; Gordon, Mark S.; Windus, Theresa L.

    2015-07-17

    The conformations of a series of organophosphine oxides, OP(CH3)2R, where R = methyl, ethyl, isopropyl, tert-butyl, vinyl, and phenyl, are predicted using the MP2/cc-pVTZ level of theory. Comparison of potential energy surfaces for rotation about P–C bonds with crystal structure data reveals a strong correlation between predicted location and energetics of minima and histograms of dihedral angle distributions observed in the solid state. In addition, the most stable conformers are those that minimize the extent of steric repulsion between adjacent rotor substituents, and the torsional barriers tend to increase with the steric bulk of the rotating alkyl group. MM3 force field parameters were adjusted to fit the MP2 results, providing a fast and accurate model for predicting organophosphine oxides shapes—an essential part of understanding the chemistry of these compounds. As a result, the predictive power of the modified MM3 model was tested against MP2/cc-pVTZ conformations for triethylphosphine oxide, OP(CH2CH3)3, and triphenylphosphine oxide, OP(Ph)3.

  16. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, Donald E.

    1994-01-01

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

  17. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, D.E.

    1994-09-20

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

  18. Air Sealing Your Home | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Your Home Air Sealing Your Home Save on heating and cooling costs by checking for air leaks in common trouble spots in your home. Save on heating and cooling costs by checking for air leaks in common trouble spots in your home. Reducing the amount of air that leaks in and out of your home is a cost-effective way to cut heating and cooling costs, improve durability, increase comfort, and create a healthier indoor environment. Caulking and weatherstripping are two simple and effective air-sealing

  19. Strategy Guideline. Compact Air Distribution Systems

    SciTech Connect (OSTI)

    Burdick, Arlan

    2013-06-01

    This guideline discusses the benefits and challenges of using a compact air distribution system to handle the reduced loads and reduced air volume needed to condition the space within an energy efficient home. The decision criteria for a compact air distribution system must be determined early in the whole-house design process, considering both supply and return air design. However, careful installation of a compact air distribution system can result in lower material costs from smaller equipment, shorter duct runs, and fewer outlets; increased installation efficiencies, including ease of fitting the system into conditioned space; lower loads on a better balanced HVAC system, and overall improved energy efficiency of the home.

  20. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  1. Alpha-environmental continuous air monitor inlet

    DOE Patents [OSTI]

    Rodgers, John C.

    2003-01-01

    A wind deceleration and protective shroud that provides representative samples of ambient aerosols to an environmental continuous air monitor (ECAM) has a cylindrical enclosure mounted to an input on the continuous air monitor, the cylindrical enclosure having shrouded nozzles located radially about its periphery. Ambient air flows, often along with rainwater flows into the nozzles in a sampling flow generated by a pump in the continuous air monitor. The sampling flow of air creates a cyclonic flow in the enclosure that flows up through the cylindrical enclosure until the flow of air reaches the top of the cylindrical enclosure and then is directed downward to the continuous air monitor. A sloped platform located inside the cylindrical enclosure supports the nozzles and causes any moisture entering through the nozzle to drain out through the nozzles.

  2. DOE Takes Action to Stop the Sales of Air-Con Air Conditioner Models Shown

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Violate Federal Energy Efficiency Appliance Standards | Department of Energy Action to Stop the Sales of Air-Con Air Conditioner Models Shown to Violate Federal Energy Efficiency Appliance Standards DOE Takes Action to Stop the Sales of Air-Con Air Conditioner Models Shown to Violate Federal Energy Efficiency Appliance Standards September 23, 2010 - 12:00am Addthis Washington, DC - The Department of Energy announced today that it has taken action against Air-Con, International, requiring

  3. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  4. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  5. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  6. Solid oxide fuel cell matrix and modules

    DOE Patents [OSTI]

    Riley, B.

    1988-04-22

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs. 11 figs.

  7. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  8. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  9. Photochemical air pollution. Part I

    SciTech Connect (OSTI)

    Goldstein E.; Hackney, J.D.; Rokaw, S.N.

    1985-03-01

    In this paper, epidemiologic studies are reported which indicate that high photochemical oxidant exposures: do not cause mortality or serious illness; may increase the risk of asthmatic attacks in a small percentage of asthmatic patients; appear to reduce pulmonary function in smokers and nonsmokers after long-term exposure; cause acute discomfort of eye and throat, chest irritation and cough; and interfere with athletic performance. Exposure to high ambient levels of NO/sub 2/ is not associated with mortality, serious disease or respiratory dysfunction, but self-limiting symptoms of respiratory irritation or illness may develop in children. 106 references, 2 figures, 1 table.

  10. Air and water cooled modulator

    DOE Patents [OSTI]

    Birx, D.L.; Arnold, P.A.; Ball, D.G.; Cook, E.G.

    1995-09-05

    A compact high power magnetic compression apparatus and method are disclosed for delivering high voltage pulses of short duration at a high repetition rate and high peak power output which does not require the use of environmentally unacceptable fluids such as chlorofluorocarbons either as a dielectric or as a coolant, and which discharges very little waste heat into the surrounding air. A first magnetic switch has cooling channels formed therethrough to facilitate the removal of excess heat. The first magnetic switch is mounted on a printed circuit board. A pulse transformer comprised of a plurality of discrete electrically insulated and magnetically coupled units is also mounted on said printed board and is electrically coupled to the first magnetic switch. The pulse transformer also has cooling means attached thereto for removing heat from the pulse transformer. A second magnetic switch also having cooling means for removing excess heat is electrically coupled to the pulse transformer. Thus, the present invention is able to provide high voltage pulses of short duration at a high repetition rate and high peak power output without the use of environmentally unacceptable fluids and without discharging significant waste heat into the surrounding air. 9 figs.

  11. Air and water cooled modulator

    DOE Patents [OSTI]

    Birx, Daniel L.; Arnold, Phillip A.; Ball, Don G.; Cook, Edward G.

    1995-01-01

    A compact high power magnetic compression apparatus and method for delivering high voltage pulses of short duration at a high repetition rate and high peak power output which does not require the use of environmentally unacceptable fluids such as chlorofluorocarbons either as a dielectric or as a coolant, and which discharges very little waste heat into the surrounding air. A first magnetic switch has cooling channels formed therethrough to facilitate the removal of excess heat. The first magnetic switch is mounted on a printed circuit board. A pulse transformer comprised of a plurality of discrete electrically insulated and magnetically coupled units is also mounted on said printed board and is electrically coupled to the first magnetic switch. The pulse transformer also has cooling means attached thereto for removing heat from the pulse transformer. A second magnetic switch also having cooling means for removing excess heat is electrically coupled to the pulse transformer. Thus, the present invention is able to provide high voltage pulses of short duration at a high repetition rate and high peak power output without the use of environmentally unacceptable fluids and without discharging significant waste heat into the surrounding air.

  12. Monitor of the concentration of particles of dense radioactive materials in a stream of air

    DOE Patents [OSTI]

    Yule, Thomas J.

    1979-01-01

    A monitor of the concentration of particles of radioactive materials such as plutonium oxide in diameters as small as 1/2 micron includes in combination a first stage comprising a plurality of virtual impactors, a second stage comprising a further plurality of virtual impactors, a collector for concentrating particulate material, a radiation detector disposed near the collector to respond to radiation from collected material and means for moving a stream of air, possibly containing particulate contaminants, through the apparatus.

  13. Bibliography of work on the photocatalytic removal of hazardous compounds from water and air

    SciTech Connect (OSTI)

    Blake, D.M.

    1994-05-01

    This is a bibliography of information in the open literature on work that has been done to date on the photocatalytic oxidation of compounds, principally organic compounds. The goal of the listing is removing hazardous oompounds from water or air. It contains lists of substances and literature citations. The bibliography includes information obtained through the middle of 1993 and some selected references for the balance of that year.

  14. A model for residual stress evolution in air-plasma-sprayed zirconia thermal barrier coatings

    SciTech Connect (OSTI)

    Nair, B. G.; Singh, J. P.; Grimsditch, M.

    2000-02-28

    Ruby fluorescence spectroscopy indicates that residual stress in air-plasma-sprayed zirconia thermal barrier coatings is a function of the local interface geometry. The stress profile of a simulated rough interface characterized by ``peaks'' and ``valleys'' was modeled with a finite-element approach that accounted for thermal mismatch, oxide scale growth, and top coat sintering. Dependence of the stress profile on interface geometry and microstructure was investigated, and the results were compared with measured stresses.

  15. Air-Source Heat Pump Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Basics Air-Source Heat Pump Basics August 19, 2013 - 11:03am Addthis Air-source heat pumps transfer heat between the inside of a building and the outside air. How Air-Source...

  16. Enzymatic Oxidation of Methane

    SciTech Connect (OSTI)

    Sirajuddin, S; Rosenzweig, AC

    2015-04-14

    Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane bioconversion processes, MMOs have attracted intense attention in recent years. There are two distinct types of MMO, a soluble, cytoplasmic MMO (sMMO) and a membrane-bound, particulate MMO (pMMO). Both oxidize methane at metal centers within a complex, multisubunit scaffold, but the structures, active sites, and chemical mechanisms are completely different. This Current Topic review article focuses on the overall architectures, active site structures, substrate reactivities, proteinprotein interactions, and chemical mechanisms of both MMOs, with an emphasis on fundamental aspects. In addition, recent advances, including new details of interactions between the sMMO components, characterization of sMMO intermediates, and progress toward understanding the pMMO metal centers are highlighted. The work summarized here provides a guide for those interested in exploiting MMOs for biotechnological applications.

  17. Millisecond Oxidation of Alkanes

    Broader source: Energy.gov [DOE]

    This factsheet describes a project whose goal is to commercialize a production process for propylene and acrylic acid from propane using a catalytic auto-thermal oxydehydrogenation process operating at short contact times. Auto-thermal oxidation for conversion of propane to propylene and acrylic acid promises energy savings of 20 trillion Btu per year by 2020. In addition to reducing energy consumption, this technology can reduce manufacturing costs by up to 25 percent, and reduce a variety of greenhouse gas emissions.

  18. Solid oxide fuel cell matrix and modules

    DOE Patents [OSTI]

    Riley, Brian (Willimantic, CT)

    1990-01-01

    Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

  19. Lithium-Air Battery: High Performance Cathodes for Lithium-Air Batteries

    SciTech Connect (OSTI)

    2010-08-01

    BEEST Project: Researchers at Missouri S&T are developing an affordable lithium-air (Li-Air) battery that could enable an EV to travel up to 350 miles on a single charge. Todays EVs run on Li-Ion batteries, which are expensive and suffer from low energy density compared with gasoline. This new Li-Air battery could perform as well as gasoline and store 3 times more energy than current Li-Ion batteries. A Li-Air battery uses an air cathode to breathe oxygen into the battery from the surrounding air, like a human lung. The oxygen and lithium react in the battery to produce electricity. Current Li-Air batteries are limited by the rate at which they can draw oxygen from the air. The team is designing a battery using hierarchical electrode structures to enhance air breathing and effective catalysts to accelerate electricity production.

  20. Cold Climate and Retrofit Applications for Air-to-Air Heat Pumps

    SciTech Connect (OSTI)

    Baxter, Van D

    2015-01-01

    Air source heat pumps (ASHP) including air-to-air ASHPs are easily applied to buildings almost anywhere for new construction as well as retrofits or renovations. They are widespread in milder climate regions but their use in cold regions is hampered due to low heating efficiency and capacity at cold outdoor temperatures. Retrofitting air-to-air ASHPs to existing buildings is relatively easy if the building already has an air distribution system. For buildings without such systems alternative approaches are necessary. Examples are ductless, minisplit heat pumps or central heat pumps coupled to small diameter, high velocity (SDHV) air distribution systems. This article presents two subjects: 1) a summary of R&D investigations aimed at improving the cold weather performance of ASHPs, and 2) a brief discussion of building retrofit options using air-to-air ASHP systems.

  1. Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test

    Broader source: Energy.gov [DOE]

    In a test sponsored by the U.S. Department of Energy, a Delphi auxiliary power unit employing a solid oxide fuel cell (SOFC) successfully operated the electrical system and air conditioning of a Peterbilt Model 386 truck under conditions simulating idling conditions for 10 hours.

  2. Solid oxide fuel cell systems with hot zones having improved reactant distribution

    DOE Patents [OSTI]

    Poshusta, Joseph C.; Booten, Charles W.; Martin, Jerry L.

    2012-11-06

    A Solid Oxide Fuel Cell (SOFC) system having a hot zone with a center cathode air feed tube for improved reactant distribution, a CPOX reactor attached at the anode feed end of the hot zone with a tail gas combustor at the opposing end for more uniform heat distribution, and a counter-flow heat exchanger for efficient heat retention.

  3. Solid oxide fuel cell systems with hot zones having improved reactant distribution

    DOE Patents [OSTI]

    Poshusta, Joseph C; Booten, Charles W; Martin, Jerry L

    2013-12-24

    A Solid Oxide Fuel Cell (SOFC) system having a hot zone with a center cathode air feed tube for improved reactant distribution, a CPOX reactor attached at the anode feed end of the hot zone with a tail gas combustor at the opposing end for more uniform heat distribution, and a counter-flow heat exchanger for efficient heat retention.

  4. Nonisostructural complex oxide heteroepitaxy

    SciTech Connect (OSTI)

    Wong, Franklin J. Ramanathan, Shriram

    2014-07-01

    The authors present an overview of the fundamentals and representative examples of the growth of epitaxial complex oxide thin films on structurally dissimilar substrates. The authors will delineate how the details of particular crystal structures and symmetry of different oxide surfaces can be employed for a rational approach to the synthesis of nonisostructural epitaxial heterostructures. The concept of oxygen eutaxy can be widely applied. Materials combinations will be split into three categories, and in all cases the films and substrates occur in different crystal structures: (1) common translational and rotational symmetry between the film and substrate planes; (2) translational symmetry mismatch between the substrates and films that is distinct from a simple mismatch in lattice parameters; and (3) rotational symmetry mismatch. In case (1), in principle single-crystalline thin films can be attained despite the films and substrates possessing different crystal structures. In case (2), antiphase boundaries will be prevalent in the thin films. In case (3), thin-film rotational variants that are joined by tilt boundaries will be present. Diffraction techniques to determine crystallographic alignment and epitaxial variants are discussed, and transmission electron microscopy studies to investigate extended defects in the thin films will also be reviewed. The authors end with open problems in this field regarding the structure of oxide interfaces that can be topics for future research.

  5. The role of probe oxide in local surface conductivity measurements

    SciTech Connect (OSTI)

    Barnett, C. J.; Kryvchenkova, O.; Wilson, L. S. J.; Maffeis, T. G. G.; Cobley, R. J.; Kalna, K.

    2015-05-07

    Local probe methods can be used to measure nanoscale surface conductivity, but some techniques including nanoscale four point probe rely on at least two of the probes forming the same low resistivity non-rectifying contact to the sample. Here, the role of probe shank oxide has been examined by carrying out contact and non-contact I V measurements on GaAs when the probe oxide has been controllably reduced, both experimentally and in simulation. In contact, the barrier height is pinned but the barrier shape changes with probe shank oxide dimensions. In non-contact measurements, the oxide modifies the electrostatic interaction inducing a quantum dot that alters the tunneling behavior. For both, the contact resistance change is dependent on polarity, which violates the assumption required for four point probe to remove probe contact resistance from the measured conductivity. This has implications for all nanoscale surface probe measurements and macroscopic four point probe, both in air and vacuum, where the role of probe oxide contamination is not well understood.

  6. Downhole steam generator having a downhole oxidant compressor

    DOE Patents [OSTI]

    Fox, Ronald L.

    1983-01-01

    Apparatus and method for generation of steam in a borehole for penetration into an earth formation wherein a downhole oxidant compressor is used to compress relatively low pressure (atmospheric) oxidant, such as air, to a relatively high pressure prior to mixing with fuel for combustion. The multi-stage compressor receives motive power through a shaft driven by a gas turbine powered by the hot expanding combustion gases. The main flow of compressed oxidant passes through a velocity increasing nozzle formed by a reduced central section of the compressor housing. An oxidant bypass feedpipe leading to peripheral oxidant injection nozzles of the combustion chamber are also provided. The downhole compressor allows effective steam generation in deep wells without need for high pressure surface compressors. Feedback preheater means are provided for preheating fuel in a preheat chamber. Preheating of the water occurs in both a water feed line running from aboveground and in a countercurrent water flow channel surrounding the combustor assembly. The countercurrent water flow channels advantageously serve to cool the combustion chamber wall. The water is injected through slotted inlets along the combustion chamber wall to provide an unstable boundary layer and stripping of the water from the wall for efficient steam generation. Pressure responsive doors are provided at the steam outlet for closing and sealing the combustion chamber from entry of reservoir fluids in the event of a flameout.

  7. Air-core grid for scattered x-ray rejection

    DOE Patents [OSTI]

    Logan, C.M.; Lane, S.M.

    1995-10-03

    The invention is directed to a grid used in x-ray imaging applications to block scattered radiation while allowing the desired imaging radiation to pass through, and to process for making the grid. The grid is composed of glass containing lead oxide, and eliminates the spacer material used in prior known grids, and is therefore, an air-core grid. The glass is arranged in a pattern so that a large fraction of the area is open allowing the imaging radiation to pass through. A small pore size is used and the grid has a thickness chosen to provide high scatter rejection. For example, the grid may be produced with a 200 {micro}m pore size, 80% open area, and 4 mm thickness. 2 figs.

  8. Air-core grid for scattered x-ray rejection

    DOE Patents [OSTI]

    Logan, Clinton M.; Lane, Stephen M.

    1995-01-01

    The invention is directed to a grid used in x-ray imaging applications to block scattered radiation while allowing the desired imaging radiation to pass through, and to process for making the grid. The grid is composed of glass containing lead oxide, and eliminates the spacer material used in prior known grids, and is therefore, an air-core grid. The glass is arranged in a pattern so that a large fraction of the area is open allowing the imaging radiation to pass through. A small pore size is used and the grid has a thickness chosen to provide high scatter rejection. For example, the grid may be produced with a 200 .mu.m pore size, 80% open area, and 4 mm thickness.

  9. Room air monitor for radioactive aerosols

    DOE Patents [OSTI]

    Balmer, D.K.; Tyree, W.H.

    1987-03-23

    A housing assembly for use with a room air monitor for simultaneous collection and counting of suspended particles includes a casing containing a combination detector-preamplifier system at one end, a filter system at the other end, and an air flow system consisting of an air inlet formed in the casing between the detector-preamplifier system and the filter system and an air passageway extending from the air inlet through the casing and out the end opposite the detector-preamplifier combination. The filter system collects suspended particles transported directly through the housing by means of the air flow system, and these particles are detected and examined for radioactivity by the detector-preamplifier combination. 2 figs.

  10. Room air monitor for radioactive aerosols

    DOE Patents [OSTI]

    Balmer, David K.; Tyree, William H.

    1989-04-11

    A housing assembly for use with a room air monitor for simultaneous collection and counting of suspended particles includes a casing containing a combination detector-preamplifier system at one end, a filter system at the other end, and an air flow system consisting of an air inlet formed in the casing between the detector-preamplifier system and the filter system and an air passageway extending from the air inlet through the casing and out the end opposite the detector-preamplifier combination. The filter system collects suspended particles transported directly through the housing by means of the air flow system, and these particles are detected and examined for radioactivity by the detector-pre The U.S. Government has rights in this invention pursuant to Contract No. DE-AC04-76DP03533 between the Department of Energy and Rockwell International Corporation.

  11. Air Sampling System Evaluation Template

    Energy Science and Technology Software Center (OSTI)

    2000-05-09

    The ASSET1.0 software provides a template with which a user can evaluate an Air Sampling System against the latest version of ANSI N13.1 "Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stacks and Ducts of Nuclear Facilities". The software uses the ANSI N13.1 PIC levels to establish basic design criteria for the existing or proposed sampling system. The software looks at such criteria as PIC level, type of radionuclide emissions, physical state ofmore » the radionuclide, nozzle entrance effects, particulate transmission effects, system and component accuracy and precision evaluations, and basic system operations to provide a detailed look at the subsystems of a monitoring and sampling system/program. A GAP evaluation can then be completed which leads to identification of design and operational flaws in the proposed systems. Corrective measures can then be limited to the GAPs.« less

  12. Enclosed rotary disc air pulser

    DOE Patents [OSTI]

    Olson, A. L.; Batcheller, Tom A.; Rindfleisch, J. A.; Morgan, John M.

    1989-01-01

    An enclosed rotary disc air pulser for use with a solvent extraction pulse olumn includes a housing having inlet, exhaust and pulse leg ports, a shaft mounted in the housing and adapted for axial rotation therein, first and second disc members secured to the shaft within the housing in spaced relation to each other to define a chamber therebetween, the chamber being in communication with the pulse leg port, the first disc member located adjacent the inlet port, the second disc member being located adjacent the exhaust port, each disc member having a milled out portion, the disc members positioned on the shaft so that as the shaft rotates, the milled out portions permit alternative cyclical communication between the inlet port and the chamber and the exhaust port and the chamber.

  13. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  14. Fluid-bed air-supply system

    DOE Patents [OSTI]

    Zielinski, Edward A.; Comparato, Joseph R.

    1979-01-01

    The air-supply system for a fluidized-bed furnace includes two air conduits for the same combustion zone. The conduits feed separate sets of holes in a distributor plate through which fluidizing air flows to reach the bed. During normal operation, only one conduit and set of holes is used, but the second conduit and set of holes is employed during start-up.

  15. Diffusion-flame burning of fuel-vapor pockets in air

    SciTech Connect (OSTI)

    Fendell, F.E.; Bush, W.B.; Mitchell, J.A.; Fink, S.F. IV . Center for Propulsion Technology and Fluid Mechanics)

    1994-08-01

    The authors examine analytically, with numerical assistance, the unsteady, diffusively limited burnup of initially unmixed fuel vapor and gaseous oxidizer. They study three simple spherical geometries: (1) an initially uniform sphere of fuel vapor immersed in an unbounded expanse of oxidizer; (2) a variant on case 1 in which only a finite concentric annulus of enveloping oxidizer is available for the burning of the initially uniform sphere of fuel vapor; and (3) an impervious sphere, consisting initially of one uniform hemisphere of fuel vapor and one uniform hemisphere of oxidizer. Of particular interest is the time interval for the exhaustion of the lean reactant, as a function of the fuel-to-oxidizer stoichiometry and the sphere radius. The motivation for these studies is to ascertain the fate of inhomogeneous blobs that arise as a consequence of imperfect fuel/air mixing, e.g., in the context of a supersonic combustor. In such a context, an inhomogeneous blob of gaseous mixture, idealized to have the geometry of a sphere, is examined as a Lagrangian element, as it is convected downstream, without slip, by the surrounding gaseous flow. The longest time for diffusional burnup, for the spherically enclosed geometries, arises for the case in which the fuel vapor and oxidizer are present in stoichiometric proportion.

  16. Study of Air Ingress Across the Duct During the Accident Conditions

    SciTech Connect (OSTI)

    Hassan, Yassin

    2013-05-06

    The goal of this project is to study the fundamental physical phenomena associated with air ingress in very high temperature reactors (VHTRs). Air ingress may occur due to a rupture of primary piping and a subsequent breach in the primary pressure boundary in helium-cooled and graphite-moderated VHTRs. Significant air ingress is a concern because it introduces potential to expose the fuel, graphite support rods, and core to a risk of severe graphite oxidation. Two of the most probable air ingress scenarios involve rupture of a control rod or fuel access standpipe, and rupture in the main coolant pipe on the lower part of the reactor pressure vessel. Therefore, establishing a fundamental understanding of air ingress phenomena is critical in order to rationally evaluate safety of existing VHTRs and develop new designs that minimize these risks. But despite this importance, progress toward development these predictive capabilities has been slowed by the complex nature of the underlying phenomena. The combination of inter-diffusion among multiple species, molecular diffusion, natural convection, and complex geometries, as well as the multiple chemical reactions involved, impose significant roadblocks to both modeling and experiment design. The project team will employ a coordinated experimental and computational effort that will help gain a deeper understanding of multiphased air ingress phenomena. This project will enhance advanced modeling and simulation methods, enabling calculation of nuclear power plant transients and accident scenarios with a high degree of confidence. The following are the project tasks: Perform particle image velocimetry measurement of multiphase air ingresses; and, Perform computational fluid dynamics analysis of air ingress phenomena.

  17. Sandia Energy - Air Force Research Laboratory Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the Air Force Research Laboratory in Albuquerque utilized the site at the National Solar Thermal Test Facility to evaluate seismic and optical activity from explosives set...

  18. Sandia Energy - Air Force Research Laboratory Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Air Force Research Laboratory (AFRL) in Albuquerque utilized the site at the National Solar Thermal Test Facility (NSTTF) to evaluate seismic and optical activity from...

  19. air force | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    NNSA, Air Force Complete Successful B61-12 Life Extension Program Development Flight Test at Tonopah Test Range WASHINGTON - The National Nuclear Security Administration (NNSA) and ...

  20. PNNL: About: Air Emissions (Radioactive) Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from unacceptable risks resulting from its operations. These reports document PNNL Campus and Marine Science Laboratory (MSL) radionuclide air emissions that result in the...

  1. Liquid phase thermal swing chemical air separation

    DOE Patents [OSTI]

    Erickson, D.C.

    1988-05-24

    A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

  2. Training: Compressed Air Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... This training includes classroom instruction, a practical exam testing hands-on ... previously completed the CAC Advanced Management of Compressed Air Systems course as a ...

  3. Heating, Ventilation, and Air Conditioning Projects | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Lead Performer: Mechanical Solutions Inc. - Whippany, NJ Partners: Lennox International Inc. - Richardson, Membrane Based Air Conditioning Lead Performer: Dais Analytic Corporation ...

  4. Lab Breakthrough: Desiccant Enhanced Evaporative Air Conditioning

    Broader source: Energy.gov [DOE]

    Researchers at the National Renewable Energy Laboratory (NREL) invented a breakthrough technology that improves air conditioning in a novel way — with heat.

  5. Breakthrough Video: Desiccant Enhanced Evaporative Air Conditioning

    SciTech Connect (OSTI)

    2012-01-01

    Researchers at the National Renewable Energy Laboratory (NREL) invented a breakthrough technology that improves air conditioning in a novel waywith heat. NREL combined desiccant materials, which remove moisture from the air using heat, and advanced evaporative technologies to develop a cooling unit that uses 90% less electricity and up to 80% less total energy than traditional air conditioning (AC). This solution, called the desiccant enhanced evaporative air conditioner (DEVAP), also controls humidity more effectively to improve the comfort of people in buildings.

  6. International Air Transport Association (IATA) | Open Energy...

    Open Energy Info (EERE)

    Name: International Air Transport Association (IATA) Address: 800 Place Victoria PO Box 113 Place: Montreal, Quebec Phone Number: 1 514 874 0202 Website: www.iata.org...

  7. Washington Environmental Permit Handbook - Air Operating Permit...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: Washington Environmental Permit Handbook - Air Operating PermitPermitting...

  8. Compressed Air System Control Strategies; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using controls, storage, and demand management to ... at part-load is key to a high performance compressed air system. ... A STRONG ENERGY PORTFOLIO FOR A STRONG AMERICA ...

  9. Colorado Air Pollution Control Division - Construction Permits...

    Open Energy Info (EERE)

    Pollution Control Division - Construction Permits Forms and Air Pollutant Emission Notices (APENs) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site:...

  10. Central Air Conditioning | Department of Energy

    Energy Savers [EERE]

    that the newly installed air conditioner has the exact refrigerant charge and airflow rate specified by the manufacturer Locates the thermostat away from heat sources, such as...

  11. Covered Product Category: Room Air Conditioners | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... This calculator allows the user to input a location, cooling capacity of the room air conditioners, efficiency (i.e., EER) and rate for electricity. The output section ...

  12. History of Air Conditioning | Department of Energy

    Energy Savers [EERE]

    Efficiency Standards Drive Improvements As air conditioning use soared in the 1970s, the energy crisis hit. In response, lawmakers passed laws to reduce energy consumption across...

  13. Sabdia's Radial Flow Air Bearing Heat Exchanger

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sandia's Radial Flow ir Bearing Heat Exchanger 2014 Building Technologies Office Peer Review Sandia's TRL 5 Air Bearing Heat exchanger technology (a. k. a. The Sandia Cooler) ...

  14. Liquid phase thermal swing chemical air separation

    DOE Patents [OSTI]

    Erickson, Donald C.

    1988-01-01

    A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

  15. Air Liquide Group | Open Energy Information

    Open Energy Info (EERE)

    search Name: Air Liquide Group Place: Paris, France Zip: 75321 Sector: Hydro, Hydrogen Product: Paris-based manufacturer of industrial and medical gases. The company is...

  16. Air Products Chemicals Inc | Open Energy Information

    Open Energy Info (EERE)

    Air Products & Chemicals Inc Place: Allentown, Pennsylvania Zip: 18195 Sector: Hydro, Hydrogen, Services Product: A global supplier of merchant hydrogen with a portfolio of...

  17. Air Conditioning Heating and Refrigeration Institute Comment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon DOE Reg Burden RFI 7-18-14 More Documents & Publications Regulatory Burden RFI from AHRI Regulatory Burden RFI Air-Conditioning, Heating, and Refrigeration Institute ...

  18. Development of a Zirconia-Based Electrochemical Sensor for the Detection of Hydrogen in Air

    SciTech Connect (OSTI)

    Brosha, E; Mukundan, R; Lujan, R; Garzon, F; Woo, L; Worsley, M; Glass, B

    2008-07-16

    Mixed potential sensors utilizing a machined, dense indium-tin oxide working electrode (In{sub 2}O{sub 3}:SnO{sub 2}; 90%:10%), a Pt wire counter electrode, and porous YSZ electrolyte were prepared using ceramic tape casting methods. The response of these devices to hydrogen concentrations up to 2% in air were studied from 600 to 740 C. The sensor response exhibited a reversible behavior and a fast response time with sensitivity increasing with decreasing temperature. GC analysis confirmed significant heterogeneous oxidation of the H{sub 2} on heated furnace tube wall surfaces thus driving sensor response at H{sub 2} concentrations greater than a few hundred ppm. The transition to a cold wall, miniature platform heater significantly reduced hydrogen oxidation although some flow rate dependence remains.

  19. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Srhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sren; Nyberg, Tomas [Department of Solid State Electronics, The ngstrm Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.510 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  20. Indoor air quality study of forty east Tennessee homes

    SciTech Connect (OSTI)

    Hawthorne, A.R.; Gammage, R.B.; Dudney, C.S.; Hingerty, B.E.; Schuresko, D.D.; Parzyck, D.C.; Womack, D.R.; Morris, S.A.; Westley, R.R.; White, D.A.

    1984-12-01

    Over a one-year period, measurements of indoor air pollutants (CO/sub x/, NO/sub x/, formaldehyde, volatile organics, particulates, and radon) were made in 40 homes in East Tennessee. The houses were of various ages with different types of insulation and heating. Over one-half of the houses exceeded the ASHRAE indoor ceiling guideline of 0.1 ppM for formaldehyde on at least one occasion. Over the duration of the study, older houses averaged 0.04 ppM of formaldehyde while houses less than 5 years old averaged 0.08 ppM (P < 0.01). The highest concentration of formaldehyde measured was 0.4 ppM in a new home. Diurnal and seasonal fluctuations in levels of formaldehyde in some homes were as much as twofold and tenfold, respectively. The highest levels of formaldehyde were usually recorded during summer months. The concentration in indoor air of various organics was at least tenfold higher than in outdoor air. Carbon monoxide and nitrgen oxides were usually <2 and <0.02 ppM, respectively, except when gas stoves or kerosene space heaters were operating, or when a car was running in the garage. In 30% of the houses, the annual indoor guideline for radon, 4 pCi/L, was exceeded. The mean radon level in houses built on the ridgelines was 4.4 pCi/L, while houses located in the valleys had a mean level of 1.7 pCi/L (P < 0.01). The factor having the most impact on infiltration was operation of the central duct fan of the heating, ventilation, and air conditioning system. The mean rate of air exchange increased from 0.39 to 0.74 h/sup -1/ when the duct fan was operated (measurements prior to December 1982). This report presents the study design and implementation, describes the monitoring protocols, and provides a complete set of the data collected during the project. 25 references, 29 figures, 42 tables.

  1. Electrolytic oxide reduction system

    DOE Patents [OSTI]

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L; Berger, John F

    2015-04-28

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies, a plurality of cathode assemblies, and a lift system configured to engage the anode and cathode assemblies. The cathode assemblies may be alternately arranged with the anode assemblies such that each cathode assembly is flanked by two anode assemblies. The lift system may be configured to selectively engage the anode and cathode assemblies so as to allow the simultaneous lifting of any combination of the anode and cathode assemblies (whether adjacent or non-adjacent).

  2. PLATES WITH OXIDE INSERTS

    DOE Patents [OSTI]

    West, J.M.; Schumar, J.F.

    1958-06-10

    Planar-type fuel assemblies for nuclear reactors are described, particularly those comprising fuel in the oxide form such as thoria and urania. The fuel assembly consists of a plurality of parallel spaced fuel plate mennbers having their longitudinal side edges attached to two parallel supporting side plates, thereby providing coolant flow channels between the opposite faces of adjacent fuel plates. The fuel plates are comprised of a plurality of longitudinally extending tubular sections connected by web portions, the tubular sections being filled with a plurality of pellets of the fuel material and the pellets being thermally bonded to the inside of the tubular section by lead.

  3. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

  4. Selective Oxidation of Organic Substrates to Partially Oxidized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Brief (243 KB) Technology Marketing Summary Rapid and controlled rate of catalysis, utilizing ozone for oxidation of alcohols to ketones or aldehydes, is made possible...

  5. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

  6. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect (OSTI)

    Rachor, Ingke; Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria

    2011-05-15

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of atmospheric air. For one material with elevated levels of fine particles and high organic matter content, methane production impeded the quantification of methane oxidation potentials. Regarding the design of landfill cover layers it was concluded that the magnitude of the expected methane load, the texture and expected compaction of the cover material are key variables that need to be known. Based on these, a column study can serve as an appropriate testing system to determine the methane oxidation capacity of a soil intended as landfill cover material.

  7. PREPARATION OF REFRACTORY OXIDE MICROSPHERE

    DOE Patents [OSTI]

    Haws, C.C. Jr.

    1963-09-24

    A method is described of preparing thorium oxide in the form of fused spherical particles about 1 to 2 microns in diameter. A combustible organic solution of thorium nitrate containing additive metal values is dispersed into a reflected, oxygen-fed flame at a temperature above the melting point of the resulting oxide. The metal additive is aluminum at a proportion such as to provide 1 to 10 weight per cent aluminum oxide in the product, silicon at the same proportion, or beryllium at a proportion of 12 to 25 weight per cent beryllium oxide in the product. A minor proportion of uranium values may also be provided in the solution. The metal additive lowers the oxide melting point and allows fusion and sphere formation in conventional equipment. The product particles are suitable for use in thorium oxide slurries for nuclear reactors. (AEC)

  8. HVAC Cabinet Air Leakage Test Method - Building America Top Innovation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Cabinet Air Leakage Test Method - Building America Top Innovation HVAC Cabinet Air Leakage Test Method - Building America Top Innovation While HVAC installers have improved their air sealing practices to reduce the amount of air leaking at ducts and duct boots, testing showed that distribution systems still leaked at air handlers and furnace HVAC Air Leakage Fig 1 Air handler furnace cabinet with pressure taps.jpg cabinets. This has hampered the ability of HVAC

  9. NETL: Solid Oxide Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solid Oxide Fuel Cells Solid oxide fuel cells (SOFC) are electrochemical devices that convert chemical energy of a fuel and oxidant directly into electrical energy. Since SOFCs produce electricity through an electrochemical reaction and not through a combustion process, they are much more efficient and environmentally benign than conventional electric power generation processes. Their inherent characteristics make them uniquely suitable to address the environmental, climate change, and water

  10. Evolution of soot size distribution in premixed ethylene/air and ethylene/benzene/air flames: Experimental and modeling study

    SciTech Connect (OSTI)

    Echavarria, Carlos A.; Sarofim, Adel F.; Lighty, JoAnn S.; D'Anna, Andrea

    2011-01-15

    The effect of benzene concentration in the initial fuel on the evolution of soot size distribution in ethylene/air and ethylene/benzene/air flat flames was characterized by experimental measurements and model predictions of size and number concentration within the flames. Experimentally, a scanning mobility particle sizer was used to allow spatially resolved and online measurements of particle concentration and sizes in the nanometer-size range. The model couples a detailed kinetic scheme with a discrete-sectional approach to follow the transition from gas-phase to nascent particles and their coagulation to larger soot particles. The evolution of soot size distribution (experimental and modeled) in pure ethylene and ethylene flames doped with benzene showed a typical nucleation-sized (since particles do not actually nucleate in the classical sense particle inception is often used in place of nucleation) mode close to the burner surface, and a bimodal behavior at greater height above burner (HAB). However, major features were distinguished between the data sets. The growth of nucleation and agglomeration-sized particles was faster for ethylene/benzene/air flames, evidenced by the earlier presence of bimodality in these flames. The most significant changes in size distribution were attributed to an increase in benzene concentration in the initial fuel. However, these changes were more evident for high temperature flames. In agreement with the experimental data, the model also predicted the decrease of nucleation-sized particles in the postflame region for ethylene flames doped with benzene. This behavior was associated with the decrease of soot precursors after the main oxidation zone of the flames. (author)

  11. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  12. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1993-01-01

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  13. Continuous lengths of oxide superconductors

    DOE Patents [OSTI]

    Kroeger, Donald M.; List, III, Frederick A.

    2000-01-01

    A layered oxide superconductor prepared by depositing a superconductor precursor powder on a continuous length of a first substrate ribbon. A continuous length of a second substrate ribbon is overlaid on the first substrate ribbon. Sufficient pressure is applied to form a bound layered superconductor precursor powder between the first substrate ribbon and the second substrate ribbon. The layered superconductor precursor is then heat treated to establish the oxide superconducting phase. The layered oxide superconductor has a smooth interface between the substrate and the oxide superconductor.

  14. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar; Holland, Orin Wayne

    2001-01-01

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  15. Influence of uranium hydride oxidation on uranium metal behaviour

    SciTech Connect (OSTI)

    Patel, N.; Hambley, D.; Clarke, S.A.; Simpson, K.

    2013-07-01

    This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

  16. Study of using oxygen-enriched combustion air for locomotive diesel engines

    SciTech Connect (OSTI)

    Poola, R.B.; Sekar, R.; Assanis, D.N.; Cataldi, G.R.

    1996-12-31

    A thermodynamic simulation is used to study the effects of oxygen-enriched intake air on the performance and nitrogen oxide (NO) emissions of a locomotive diesel engine. The parasitic power of the air separation membrane required to supply the oxygen-enriched air is also estimated. For a given constraint on peak cylinder pressure, the gross and net power output of an engine operating under different levels of oxygen enrichment are compared with those obtained when a high-boost turbocharged engine is used. A 4% increase in peak cylinder pressure can result in an increase in net engine power of approximately 13% when intake air with an oxygen content of 28% by volume is used and fuel injection timing is retarded by 4 degrees. When the engine is turbocharged to a higher inlet boost, the same increase in peak cylinder pressure can improve power by only 4%. If part of the significantly higher exhaust enthalpies available as a result of oxygen enrichment are recovered, the power requirements of the air separator membrane can be met, resulting in substantial net power improvements. Oxygen enrichment with its attendant higher combustion temperatures, reduces emissions of particulates and visible smoke but increases NO emissions (by up to three times at 26% oxygen content). Therefore, exhaust gas after-treatment and heat recovery would be required if the full potential of oxygen enrichment for improving the performance of locomotive diesel engines is to be realized.

  17. Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li–O2 battery charging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gittleson, Forrest S.; Ryu, Won-Hee; Schwab, Mark; Tong, Xiao; Taylor, André D.

    2016-01-01

    Rechargeable Li-O2 and Li-air batteries require electrode and electrolyte materials that synergistcally promote long-term cell operation. We investigate the role of noble metals Pt and Pd as catalysts for the Li-O2 oxidation process and their compatibility with a dimethyl sulfoxide (DMSO) based electrolyte. Lastly, we identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products.

  18. Solid oxide fuel cell with transitioned cross-section for improved anode gas management at the open end

    DOE Patents [OSTI]

    Zafred, Paolo R.; Draper, Robert

    2012-01-17

    A solid oxide fuel cell (400) is made having a tubular, elongated, hollow, active section (445) which has a cross-section containing an air electrode (452) a fuel electrode (454) and solid oxide electrolyte (456) between them, where the fuel cell transitions into at least one inactive section (460) with a flattened parallel sided cross-section (462, 468) each cross-section having channels (472, 474, 476) in them which smoothly communicate with each other at an interface section (458).

  19. Oxidation Behavior of In-Flight Molten Aluminum Droplets in the Twin-Wire Electric Arc Thermal Spray Process

    SciTech Connect (OSTI)

    Donna Post Guillen; Brian G. Williams

    2005-05-01

    This paper examines the in-flight oxidation of molten aluminum sprayed in air using the twin-wire electric arc (TWEA) thermal spray process. The oxidation reaction of aluminum in air is highly exothermic and is represented by a heat generation term in the energy balance. Aerodynamic shear at the droplet surface enhances the amount of in-flight oxidation by: (1) promoting entrainment and mixing of the surface oxides within the droplet, and (2) causing a continuous heat generation effect that increases droplet temperature over that of a droplet without internal circulation. This continual source of heat input keeps the droplets in a liquid state during flight. A linear rate law based on the Mott-Cabrera theory was used to estimate the growth of the surface oxide layer formed during droplet flight. The calculated oxide volume fraction of an average droplet at impact agrees well with the experimentally determined oxide content for a typical TWEA-sprayed aluminum coating, which ranges from 3.3 to 12.7%. An explanation is provided for the elevated, nearly constant surface temperature (~ 2000 oC) of the droplets during flight to the substrate and shows that the majority of oxide content in the coating is produced during flight, rather than after deposition.

  20. Magnetic Transparent Conducting Oxide Film And Method Of Making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F. (Richland, WA); Exarhos, Gregory J. (Richland, WA); Sharma, Shiv K. (Honolulu, HI)

    2006-03-14

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 Ocm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450 C. in air. An increase in film resistivity was found upon substitution of other cations (e.g., Zn2+, Al3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo2O4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity.

  1. Magnetic Transparent Conducting Oxide Film And Method Of Making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F.; Exarhos, Gregory J.; Sharma, Shiv K.

    2006-03-14

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 O·cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450° C. in air. An increase in film resistivity was found upon substitution of other cations (e.g., Zn2+, Al3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo2O4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity.

  2. Manifold, bus support and coupling arrangement for solid oxide fuel cells

    DOE Patents [OSTI]

    Parry, G.W.

    1988-04-21

    Individual, tubular solid oxide fuel cells (SOFCs) are assembled into bundles called a module within a housing, with a plurality of modules arranged end-to-end in a linear, stacked configuration called a string. A common set of piping comprised of a suitable high temperature resistant material (1) provides fuel and air to each module housing, (2) serves as electrically conducting buses, and (3) provides structural support for a string of SOFC modules. Ceramic collars are used to connect fuel and air inlet piping to each of the electrodes in an SOFC module and provide (1) electrical insulation for the current carrying bus bars and gas manifolds, (2) damping for the fuel and air inlet piping, and (3) proper spacing between the fuel and air inlet piping to prevent contact between these tubes and possible damage to the SOFC. 11 figs.

  3. Isothermal oxidation behavior and microstructure of plasma surface Ta coating on ?-TiAl

    SciTech Connect (OSTI)

    Song, Jian; Zhang, Ping-Ze Wei, Dong-Bo; Wei, Xiang-Fei; Wang, Ya

    2014-12-15

    The oxidation behavior of ?-TiAl with Ta surface coating fabricated by double glow plasma surface alloying technology was investigated by thermogravimetric method. Oxidation experiments were carried out at 750 C and 850 C in air for 100 h. The modification layer was comprised of deposition layer and diffusion layer, which metallurgically adhered to the substrate. Tantalum element decreased with the case depth. The oxidation morphology was studied by a scanning electron microscope and X-ray diffraction. The results highlighted that in the oxidizing process of the oxidation, the phase containing Ta-richer may restrain diffusing outward of the element Al in the matrix. Ti diffused outward, and formed the TiO{sub 2} scales, while the middle layer was rich in Al, and formed the continuous Al{sub 2}O{sub 3} scales after oxidation, which was effective to prevent further infiltration of oxygen atoms, and as a result the oxidation resistance increased immensely. - Highlights: A Ta modified coating was prepared on ?-TiAl using DGP surface alloying technology. The modification layer metallurgically adhered to the substrate. The bonding force is about 60 N, satisfying the demands of practical use. The oxidation resistance increased immensely at 750 C and 850 C.

  4. A REVIEW OF THE OXIDATION BEHAVIOR OF STRUCTURAL ALLOYS IN STEAM

    SciTech Connect (OSTI)

    Wright, Ian G; Dooley, Barry

    2010-01-01

    The focus of this review is the state of knowledge of the oxidation behavior in steam of alloys with potential for use as pressure parts in steam boilers. Growth of steam-side oxides has implications for scale exfoliation, tube blockage and overheating, and turbine erosion. Mitigation of such problems requires mechanistic understanding of the influences of alloy composition and microstructure as well as time, temperature, and boiler operating parameters on the evolution of specific scale structures. The oxidation behavior in steam of three classes of alloys is addressed: ferritic steels (particularly the 9-12 wt% Cr alloys), austenitic steels, and high-temperature nickel-based alloys. Understanding the interplay among compositional and microstructural requirements for strengthening and oxidation resistance, and their influence on the rate and mode of scale evolution is key to the most effective application of these alloy classes. Underlying these interests is the apparently different mode of oxide growth in steam than in air, especially contributions from inward transport of oxidant species. The particular species involved and their roles in the oxidation process are expected to exert a large influence on the oxide morphologies developed, while the fate of any hydrogen released in the alloy is a further topic of particular interest.

  5. Reporting central tendencies of chamber measured surface emission and oxidation

    SciTech Connect (OSTI)

    Abichou, Tarek; Clark, Jeremy; Chanton, Jeffery

    2011-05-15

    Methane emissions, concentrations, and oxidation were measured on eleven MSW landfills in eleven states spanning from California to Pennsylvania during the three year study. The flux measurements were performed using a static chamber technique. Initial concentration samples were collected immediately after placement of the flux chamber. Oxidation of the emitted methane was evaluated using stable isotope techniques. When reporting overall surface emissions and percent oxidation for a landfill cover, central tendencies are typically used to report 'averages' of the collected data. The objective of this study was to determine the best way to determine and report central tendencies. Results showed that 89% of the data sets of collected surface flux have lognormal distributions, 83% of the surface concentration data sets are also lognormal. Sixty seven percent (67%) of the isotope measured percent oxidation data sets are normally distributed. The distribution of data for all eleven landfills provides insight of the central tendencies of emissions, concentrations, and percent oxidation. When reporting the 'average' measurement for both flux and concentration data collected at the surface of a landfill, statistical analyses provided insight supporting the use of the geometric mean. But the arithmetic mean can accurately represent the percent oxidation, as measured with the stable isotope technique. We examined correlations between surface CH{sub 4} emissions and surface air CH{sub 4} concentrations. Correlation of the concentration and flux values using the geometric mean proved to be a good fit (R{sup 2} = 0.86), indicating that surface scans are a good way of identifying locations of high emissions.

  6. Oxidation behaviour of uranium and neptunium in stabilised zirconia

    SciTech Connect (OSTI)

    Walter, Marcus; Somers, Joseph; Bouexiere, Daniel; Gaczynski, Piotr; Brendebach, Boris

    2009-12-15

    Yttria stabilised zirconia (YSZ) based (Zr,Y,U)O{sub 2-x} and (Zr,Y,Np)O{sub 2-x} solid solutions with 6 and 20 mol% actinide were prepared with Y/Zr ratios ranging from 0.2 to 2.0 to investigate uranium and neptunium oxidation behaviour depending on the oxygen vacancies in the defect fluorite lattice. Sintering at 1600 deg. C in Ar/H{sub 2} yields a cubic, fluorite-type structure with U(IV) and Np(IV). Annealing (Zr,Y,U)O{sub 2-x} with Y/Zr=0.2 at 800 deg. C in air results in a tetragonal phase, whereas (Zr,Y,U)O{sub 2-x} with higher Y/Zr ratios and (Zr,Y,Np)O{sub 2-x} retain the cubic structure. XANES and O/M measurements indicate mixed U(V)-U(VI) and Np(IV)-Np(V) oxidation states after oxidation. Based on X-ray diffraction, O/M and EXAFS measurements, different oxidation mechanisms are identified for U- and Np-doped stabilised zirconia. In contrast to U, excess oxygen vacancies are needed to oxidise Np in (Zr,Y,Np)O{sub 2-x} as the oxidation process competes with Zr for oxygen vacancies. As a consequence, U(VI) and Np(V) can only be obtained in stabilised zirconia with Y/Zr=1 but not in YSZ with Y/Zr=0.2. - Graphical abstract: The O/U ratio in oxidised (Zr,Y,U)O{sub 2-x} depends on the Y/U ratio, whereas O/Np in (Zr,Y,Np)O{sub 2-x} correlates with the Y/(Zr+Np) ratio. This indicates that both Zr and Np compete for oxygen vacancies, which hinders the Np oxidation at low Y/Zr ratios. Display Omitted

  7. High Efficiency Room Air Conditioner

    SciTech Connect (OSTI)

    Bansal, Pradeep

    2015-01-01

    This project was undertaken as a CRADA project between UT-Battelle and Geberal Electric Company and was funded by Department of Energy to design and develop of a high efficiency room air conditioner. A number of novel elements were investigated to improve the energy efficiency of a state-of-the-art WAC with base capacity of 10,000 BTU/h. One of the major modifications was made by downgrading its capacity from 10,000 BTU/hr to 8,000 BTU/hr by replacing the original compressor with a lower capacity (8,000 BTU/hr) but high efficiency compressor having an EER of 9.7 as compared with 9.3 of the original compressor. However, all heat exchangers from the original unit were retained to provide higher EER. The other subsequent major modifications included- (i) the AC fan motor was replaced by a brushless high efficiency ECM motor along with its fan housing, (ii) the capillary tube was replaced with a needle valve to better control the refrigerant flow and refrigerant set points, and (iii) the unit was tested with a drop-in environmentally friendly binary mixture of R32 (90% molar concentration)/R125 (10% molar concentration). The WAC was tested in the environmental chambers at ORNL as per the design rating conditions of AHAM/ASHRAE (Outdoor- 95F and 40%RH, Indoor- 80F, 51.5%RH). All these modifications resulted in enhancing the EER of the WAC by up to 25%.

  8. Gradient porous electrode architectures for rechargeable metal-air batteries

    DOE Patents [OSTI]

    Dudney, Nancy J.; Klett, James W.; Nanda, Jagjit; Narula, Chaitanya Kumar; Pannala, Sreekanth

    2016-03-22

    A cathode for a metal air battery includes a cathode structure having pores. The cathode structure has a metal side and an air side. The porosity decreases from the air side to the metal side. A metal air battery and a method of making a cathode for a metal air battery are also disclosed.

  9. Technology Solutions Case Study: Sealed Air-Return Plenum Retrofit

    SciTech Connect (OSTI)

    none,

    2012-08-01

    In this project, Pacific Northwest National Laboratory researchers greatly improved indoor air quality and HVAC performance by replacing an old, leaky air handler with a new air handler with an air-sealed return plenum with filter; they also sealed the ducts, and added a fresh air intake.

  10. Operation of staged membrane oxidation reactor systems

    DOE Patents [OSTI]

    Repasky, John Michael

    2012-10-16

    A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

  11. Ultra Supercritical Steamside Oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

    2005-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  12. Preparing for the clean air act amendments

    SciTech Connect (OSTI)

    Boomer, B.; Bensinger, D. Midwest Research Inst., Cary, NC )

    1993-09-09

    The U.S. Environmental Protection Agency (EPA) and state air quality control agencies are in the midst of developing regulations and programs to meet the ambitious goals of the Clean Air Act Amendment (CAAA) of 1990. The CAAA--which call for stricter air quality standards, a greater number of pollutants and sources to be regulated, new operating permits, and more stringent enforcement of air quality violations--are expected to have a significant impact on virtually every facility in the country. An important deadline in the implementation of the CAAA is November 1993. That is when individual states must submit their proposed operating permit programs to the EPA, as mandated by Title 5 of the Amendments. The EPA then has one year after receiving a state program to accept or reject it. Once a state's program is accepted, all major sources of air pollution in that state have one year to apply for an operating air permit. Although the initial deadlines for business and industry are up to two years away, sufficient information is now available to take the first steps toward compliance with the new air quality regulations. Even while the details of the new rules are being hammered out, plant engineering can and should begin laying the groundwork for their own permit applications. Time and effort spent preparing now for the provisions of the CAAA will pay off in the long run.

  13. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, Joseph L.; Hung, Cheng-Hung

    1993-01-01

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions.

  14. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, J.L.; Chenghung Hung.

    1993-12-07

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions. 14 figures.

  15. Catalysts for low temperature oxidation

    DOE Patents [OSTI]

    Toops, Todd J.; Parks, III, James E.; Bauer, John C.

    2016-03-01

    The invention provides a composite catalyst containing a first component and a second component. The first component contains nanosized gold particles. The second component contains nanosized platinum group metals. The composite catalyst is useful for catalyzing the oxidation of carbon monoxide, hydrocarbons, oxides of nitrogen, and other pollutants at low temperatures.

  16. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  17. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, R.G.

    1984-08-31

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  18. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, Ramkrishna G.

    1986-01-01

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  19. Engine piston having an insulating air gap

    DOE Patents [OSTI]

    Jarrett, Mark Wayne; Hunold,Brent Michael

    2010-02-02

    A piston for an internal combustion engine has an upper crown with a top and a bottom surface, and a lower crown with a top and a bottom surface. The upper crown and the lower crown are fixedly attached to each other using welds, with the bottom surface of the upper crown and the top surface of the lower crown forming a mating surface. The piston also has at least one centrally located air gap formed on the mating surface. The air gap is sealed to prevent substantial airflow into or out of the air gap.

  20. Performance of Blackglas{trademark} composites in 4000-hour oxidation study

    SciTech Connect (OSTI)

    Campbell, S.; Gonczy, S.; McNallan, M.; Cox, A.

    1996-12-31

    The effect of long term (4000 hour) oxidation on the mechanical properties of Blackglas{trademark}-Nitrided Nextel{trademark}312 Ceramic Matrix Composites in the temperature range of 500{degrees} - 700{degrees}C was investigated. Flexure specimens of the title composites prepared using three different pyrolysis processes were subjected to oxidation in flowing dry air at 500{degrees}, 600{degrees}C, and 700{degrees}C. Samples were removed at several different time intervals for 3-point flexure analysis. Results indicate that processing conditions had very little effect on the oxidation resistance of this system. At 600{degrees} and 700{degrees}C the mechanical properties degrade continuously to a steady value about half the original flexure strength. At 500{degrees}C, material properties initially improve then begin to slowly degrade. Optical microscopy indicates that oxidation of the matrix begins at the matrix/fiber interface and microcracks and proceeds into the bulk of the matrix.

  1. Thermal and Physical Properties of Plutonium Dioxide Produced from the Oxidation of Metal: a Data Summary

    SciTech Connect (OSTI)

    Wayne, David M.

    2014-01-13

    The ARIES Program at the Los Alamos National Laboratory removes plutonium metal from decommissioned nuclear weapons, and converts it to plutonium dioxide in a specially-designed Direct Metal Oxidation furnace. The plutonium dioxide is analyzed for specific surface area, particle size distribution, and moisture content. The purpose of these analyses is to certify that the plutonium dioxide powder meets or exceeds the specifications of the end-user, and the specifications for the packaging and transport of nuclear materials. Analytical results from plutonium dioxide from ARIES development activities, from ARIES production activities, from muffle furnace oxidation of metal, and from metal that was oxidized over a lengthy time interval in air at room temperature, are presented. The processes studied produce plutonium dioxide powder with distinct differences in measured properties, indicating the significant influence of oxidation conditions on physical properties.

  2. Penetration and air-emission-reduction benefits of solar technologies in the electric utilities

    SciTech Connect (OSTI)

    Sutherland, R.J.

    1981-01-01

    The results of a study of four solar energy technologies and the electric utility industry are reported. The purpose of the study was to estimate the penetration by federal region of four solar technologies - wind, biomass, phtovoltaics, and solar thermal - in terms of installed capacity and power generated. The penetration by these technologies occurs at the expense of coal and nuclear power. The displacement of coal plants implies a displacement of their air emissions, such as sulfur dioxide, oxides of nitrogen, and particulate matter. The main conclusion of this study is that solar thermal, photovoltaics, and biomass fail to penetrate significantly by the end of this century in any federal region. Wind energy penetrates the electric utility industry in several regions during the 1990s. Displaced coal and nuclear generation are also estimated by region, as are the corresponding reductions in air emissions. The small-scale penetration by the solar technologies necessarily limits the amount of conventional fuels displaced and the reduction in air emissions. A moderate displacement of sulfur dioxide and the oxides of nitrogen is estimated to occur by the end of this century, and significant lowering of these emissions should occur in the early part of the next century.

  3. Air-Source Heat Pumps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air-Source Heat Pumps Air-Source Heat Pumps April 23, 2015 - 3:35pm Addthis When properly installed, an air-source heat pump can deliver one-and-a-half to three times more heat...

  4. Shale Gas Development Challenges: Air | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Shale Gas Development Challenges: Air PDF icon Shale Gas Development Challenges: Air More Documents & Publications Natural Gas from Shale: Questions and Answers Challenges associated with shale gas production How is shale gas produced?

  5. Air-Con International: Order (2010-SE-0301)

    Broader source: Energy.gov [DOE]

    DOE ordered Air-Con International, Inc. to pay a $10,000 civil penalty after finding Air-Con had imported and distributed in commerce in the U.S. various models of air-conditioning units.

  6. Property:AirQualityPermitProcess | Open Energy Information

    Open Energy Info (EERE)

    property "AirQualityPermitProcess" Showing 1 page using this property. R RAPIDGeothermalAir QualityAlaska + The Air Permit process in Alaska is divided into two divisions: Title...

  7. MCA 75-2 - Air Quality | Open Energy Information

    Open Energy Info (EERE)

    2 - Air Quality Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: MCA 75-2 - Air QualityLegal Abstract Clean Air Act of Montana...

  8. AirShares EU Carbon Allowances Fund | Open Energy Information

    Open Energy Info (EERE)

    AirShares EU Carbon Allowances Fund Jump to: navigation, search Name: AirShares EU Carbon Allowances Fund Place: New York, New York Zip: 10170 Product: AirShares is a commodity...

  9. MHK Technologies/Ocean Powered Compressed Air Stations | Open...

    Open Energy Info (EERE)

    Description The Ocean Powered Compressed Air Station is a point absorber that uses an air pump to force air to a landbased generator The device only needs 4m water depth and...

  10. Los Alamos achieves 20-year low on radioactive air emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL achieves 20-year low on radioactive air emissions Los Alamos achieves 20-year low on radioactive air emissions The Lab measures air emissions through a comprehensive system of ...

  11. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of stoves that burn ethanol molecules and their partially oxidized derivatives to the final products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of stoves that burn ethanol molecules and their partially oxidized derivatives to the final products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  12. Tips: Air Conditioners | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Bigger isn't always better for an air conditioner. Learn effective ways to stay cool while saving energy. | Photo courtesy of iStockphotogalinast. Bigger isn't always better...

  13. ARM - Campaign Instrument - dri-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    air Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Desert Research Institute Airborne Aerosol Instruments...

  14. Central Air Conditioner Enforcement Policy Statement | Department...

    Broader source: Energy.gov (indexed) [DOE]

    April 24, 2014 DOE will not seek civil penalties for violations of the regional standards applicable to central air conditioners that occur prior to July 1, 2016, provided that the...

  15. 2012 National Tribal Forum on Air Quality

    Broader source: Energy.gov [DOE]

    This forum on improving air quality will take place May 22-24, 2012, in Tulsa, Oklahoma. It is co-sponsored by the Institute for Tribal Environmental Professionals (ITEP) and the National Tribal...

  16. Michael Thackery on Lithium-air Batteries

    ScienceCinema (OSTI)

    Michael Thackery

    2010-01-08

    Michael Thackery, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  17. Tips: Sealing Air Leaks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Seal air leaks around fireplace chimneys, furnaces, and gas-fired water heater vents with fire-resistant materials such as sheet metal or sheetrock and furnace cement caulk. ...

  18. Residential Air-Source Heat Pump Program

    Broader source: Energy.gov [DOE]

    Massachusetts offers rebates of up to $2,500 for the installation of high-efficiency, cold-climate air-source heat pumps (ASHPs) in residential buildings of one to four units. 

  19. Tips: Air Conditioners | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    cool while saving energy. | Photo courtesy of iStockphotogalinast. Buying a bigger room air conditioner won't necessarily make you feel more comfortable during the hot summer...

  20. Large panel design for containment air baffle

    DOE Patents [OSTI]

    Orr, R.S.

    1992-12-08

    The movable air baffle shield means in accordance with the present invention provides an efficient method of cooling the space surrounding the containment vessel while also providing the capability of being moved away from the containment vessel during inspection. The containment apparatus comprises a generally cylindrical sealed containment vessel for containing at least a portion of a nuclear power generation plant, a disparate shield building surrounding and housing the containment vessel therein and spaced outwardly thereof so as to form an air annulus in the space between the shield building and the containment vessel, a shield baffle means positioned in the air annulus around at least a portion of the sides of the containment vessel providing a coolant path between the baffle means and the containment vessel to permit cooling of the containment vessel by air, the shield baffle means being movable to afford access to the containment vessel. 9 figs.

  1. Michael Thackeray on Lithium-air Batteries

    ScienceCinema (OSTI)

    Thackeray, Michael

    2013-04-19

    Michael Thackeray, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  2. Khalil Amine on Lithium-air Batteries

    SciTech Connect (OSTI)

    Khalil Amine

    2009-09-14

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  3. ARM - Campaign Instrument - tdma-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Tandem Differential Mobility Analyzer- Airborne (TDMA-AIR) Instrument Categories Aerosols,...

  4. ARM - Field Campaign - AIRS validation IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the purpose of providing in situ validation data for development and testing of AIRS water vapor retrievals. This was a user support activity with funding provided by the user...

  5. ARM - Field Campaign - AIRS Validation Sonde Support

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the purpose of providing in situ validation data for development and testing of AIRS water vapor retrievals. This is a user support activity with funding provided by the user....

  6. Tips: Sealing Air Leaks | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    leak out. Cover your kitchen exhaust fan to stop air leaks when not in use. Check your dryer vent to be sure it is not blocked. This will save energy and may prevent a fire....

  7. Clean Air Act | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Clean Air ActLegal Abstract A primary goal of this chapter is to encourage or otherwise promote...

  8. Khalil Amine on Lithium-air Batteries

    ScienceCinema (OSTI)

    Khalil Amine

    2010-01-08

    Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

  9. Large panel design for containment air baffle

    DOE Patents [OSTI]

    Orr, Richard S.

    1992-01-01

    The movable air baffle shield means in accordance with the present invention provides an efficient method of cooling the space surrounding the containment vessel while also providing the capability of being moved away from the containment vessel during inspection. The containment apparatus comprises a generally cylindrical sealed containment vessel for containing at least a portion of a nuclear power generation plant, a disparate shield building surrounding and housing the containment vessel therein and spaced outwardly thereof so as to form an air annulus in the space between the shield building and the containment vessel, a shield baffle means positioned in the air annulus around at least a portion of the sides of the containment vessel providing a coolant path between the baffle means and the containment vessel to permit cooling of the containment vessel by air, the shield baffle means being movable to afford access to the containment vessel.

  10. AltAir Fuels | Open Energy Information

    Open Energy Info (EERE)

    Renewable Energy Product: Seattle-based developer of projects for the production of jet fuel from renewable and sustainable oils. References: AltAir Fuels1 This article is a...

  11. Detecting Air Leaks | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    a thorough and accurate measurement of air leakage in your home, hire a qualified technician to conduct an energy assessment, particularly a blower door test. For a thorough and...

  12. High-energy metal air batteries

    SciTech Connect (OSTI)

    Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

    2014-07-01

    Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

  13. High-energy metal air batteries

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

    2013-07-09

    Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

  14. Clean Air Trade Inc | Open Energy Information

    Open Energy Info (EERE)

    a company specialising in CER purchase as well as project development and investment in clean energy. References: Clean Air Trade Inc1 This article is a stub. You can help OpenEI...

  15. Reduce Air Infiltration in Furnaces; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secondary parameters that affect the amount of air leakage include these: * The furnace firing rate * The flue gas velocity through the stack or the stack cross-section area * The ...

  16. Air separation with temperature and pressure swing

    DOE Patents [OSTI]

    Cassano, Anthony A.

    1986-01-01

    A chemical absorbent air separation process is set forth which uses a temperature swing absorption-desorption cycle in combination with a pressure swing wherein the pressure is elevated in the desorption stage of the process.

  17. Evaluation of Foaming and Antifoam Effectiveness During the WTP Oxidative Leaching Process

    SciTech Connect (OSTI)

    Burket, P. R.; Jones, T. M.; White, T. L.; Crawford, C. L.; Calloway, T. B

    2005-10-11

    The River Protection Project-Waste Treatment Plant (RPP-WTP) requested Savannah River National Laboratory (SRNL) to conduct small-scale foaming and antifoam testing using a Hanford waste simulant subjected to air sparging during oxidative leaching. The foaminess of Hanford tank waste solutions was previously demonstrated by SRNL during WTP evaporator foaming studies and in small scale air sparger studies. The commercial antifoam, Dow Corning Q2-3183A was recommended to mitigate the foam in the evaporators and in vessel equipped with pulse jet mixers and air spargers. Currently, WTP is planning to use air spargers in the HLW Lag Storage Vessels (HLP-VSL-00027A/B), the Ultrafiltration Vessels (UFP-VSL-00002A&B), and the HLW Feed Blend Vessel (HLPVSL-00028) to assist the performance of the Pulse Jet Mixers (PJM). The previous air sparger antifoam studies conducted by SRNL researchers did not evaluate the hydrogen generation rate expected from antifoam additions or the effectiveness of the antifoam during caustic leaching or oxidative leaching. The fate of the various antifoam components and breakdown products in the WTP process under prototypic process conditions (temperature & radiation) was also not investigated. The effectiveness of the antifoam during caustic leaching, expected hydrogen generation rate associated with antifoam addition, and the fate of various antifoam components are being conducted under separate SRNL research tasks.

  18. Generator module architecture for a large solid oxide fuel cell power plant

    DOE Patents [OSTI]

    Gillett, James E.; Zafred, Paolo R.; Riggle, Matthew W.; Litzinger, Kevin P.

    2013-06-11

    A solid oxide fuel cell module contains a plurality of integral bundle assemblies, the module containing a top portion with an inlet fuel plenum and a bottom portion receiving air inlet feed and containing a base support, the base supports dense, ceramic exhaust manifolds which are below and connect to air feed tubes located in a recuperator zone, the air feed tubes passing into the center of inverted, tubular, elongated, hollow electrically connected solid oxide fuel cells having an open end above a combustion zone into which the air feed tubes pass and a closed end near the inlet fuel plenum, where the fuel cells comprise a fuel cell stack bundle all surrounded within an outer module enclosure having top power leads to provide electrical output from the stack bundle, where the fuel cells operate in the fuel cell mode and where the base support and bottom ceramic air exhaust manifolds carry from 85% to all 100% of the weight of the stack, and each bundle assembly has its own control for vertical and horizontal thermal expansion control.

  19. High-Efficiency Window Air Conditioners - Building America Top Innovation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy High-Efficiency Window Air Conditioners - Building America Top Innovation High-Efficiency Window Air Conditioners - Building America Top Innovation This photo shows a window air conditioning unit in place in a window frame. Window air conditioners are inexpensive, portable, and can be installed by home occupants, making them a good solution for spot cooling and for installing air conditioning into homes that lack ductwork. However, window air conditioners have low

  20. Air Sealing for New Home Construction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    » Air Sealing for New Home Construction Air Sealing for New Home Construction Air Sealing for New Home Construction Minimizing air movement in and out of a house is key to building an energy-efficient home. Controlling air leakage is also critical to moisture control. It's always best to use techniques and materials identified as best practices for your site and climate. Climate-specific construction details are available through Building America. Here are some general air sealing techniques

  1. Air-Con International: Noncompliance Determination and Proposed Penalty

    Energy Savers [EERE]

    (2010-SE-0301) | Department of Energy Air-Con International: Noncompliance Determination and Proposed Penalty (2010-SE-0301) Air-Con International: Noncompliance Determination and Proposed Penalty (2010-SE-0301) September 20, 2010 DOE issued a Notice of Noncompliance Determination to Air-Con International finding that a variety of central air conditioners and air conditioning heat pumps distributed under the Air-Con private label do not comport with the energy conservation standards. DOE

  2. Air-Source Heat Pumps | Department of Energy

    Energy Savers [EERE]

    Air-Conditioning Basics Air-Conditioning Basics August 16, 2013 - 1:59pm Addthis Air conditioning is one of the most common ways to cool homes and buildings. How Air Conditioners Work Air conditioners employ the same operating principles and basic components as refrigerators. Refrigerators use energy (usually electricity) to transfer heat from the cool interior of the refrigerator to the relatively warm surroundings; likewise, an air conditioner uses energy to transfer heat from the interior

  3. ARM - Campaign Instrument - co-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsco-air Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Monoxide- Airborne (CO-AIR) Instrument Categories Airborne Observations, Atmospheric Carbon Campaigns Cloud LAnd Surface Interaction Campaign (CLASIC) [ Download Data ] Southern Great Plains, 2007.06.01 - 2007.06.30 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf)

  4. ARM - Campaign Instrument - irt-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsirt-air Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Infrared Thermometer - Airborne (IRT-AIR) Instrument Categories Radiometric Campaigns 1999 Northeast Corridor Ozone & Particulate Study [ Download Data ] Off Site Campaign : various, including non-ARM sites, 1999.07.23 - 1999.08.11 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the

  5. ARM - Campaign Instrument - lmwrr-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentslmwrr-air Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Airborne L-band Microwave Radiometer and Radar (LMWRR-AIR) Instrument Categories Airborne Observations, Cloud Properties, Radiometric Campaigns Cloud LAnd Surface Interaction Campaign (CLASIC) [ Download Data ] Southern Great Plains, 2007.06.01 - 2007.06.30 Primary Measurements Taken The following measurements are those considered scientifically

  6. ARM - Campaign Instrument - pass-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentspass-air Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Photoacoustic Soot Spectrometer- Airborne (PASS-AIR) Instrument Categories Aerosols, Airborne Observations Campaigns Carbonaceous Aerosol and Radiative Effects Study (CARES) [ Download Data ] McClellan AFB, Sacramento, CA, 2010.06.02 - 2010.06.28 Indirect and Semi-Direct Aerosol Campaign (ISDAC) [ Download Data ] North Slope Alaska, 2008.04.01 -

  7. ARM - Campaign Instrument - uw-air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    air Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : University of Washington Airborne Aerosol Instruments (UW-AIR) Instrument Categories Aerosols, Airborne Observations Campaigns Aerosol IOP [ Download Data ] Southern Great Plains, 2003.05.01 - 2003.05.31 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf) file headers for the list of all

  8. Air Activation Following an Atmospheric Explosion

    SciTech Connect (OSTI)

    Lowrey, Justin D.; McIntyre, Justin I.; Prichard, Andrew W.; Gesh, Christopher J.

    2013-03-13

    In addition to thermal radiation and fission products, nuclear explosions result in a very high flux of unfissioned neutrons. Within an atmospheric nuclear explosion, these neutrons can activate the various elemental components of natural air, potentially adding to the radioactive signature of the event as a whole. The goal of this work is to make an order-of-magnitude estimate of the total amount of air activation products that can result from an atmospheric nuclear explosion.

  9. Linear air-fuel sensor development

    SciTech Connect (OSTI)

    Garzon, F.; Miller, C.

    1996-12-14

    The electrochemical zirconia solid electrolyte oxygen sensor, is extensively used for monitoring oxygen concentrations in various fields. They are currently utilized in automobiles to monitor the exhaust gas composition and control the air-to-fuel ratio, thus reducing harmful emission components and improving fuel economy. Zirconia oxygen sensors, are divided into two classes of devices: (1) potentiometric or logarithmic air/fuel sensors; and (2) amperometric or linear air/fuel sensors. The potentiometric sensors are ideally suited to monitor the air-to-fuel ratio close to the complete combustion stoichiometry; a value of about 14.8 to 1 parts by volume. This occurs because the oxygen concentration changes by many orders of magnitude as the air/fuel ratio is varied through the stoichiometric value. However, the potentiometric sensor is not very sensitive to changes in oxygen partial pressure away from the stoichiometric point due to the logarithmic dependence of the output voltage signal on the oxygen partial pressure. It is often advantageous to operate gasoline power piston engines with excess combustion air; this improves fuel economy and reduces hydrocarbon emissions. To maintain stable combustion away from stoichiometry, and enable engines to operate in the excess oxygen (lean burn) region several limiting-current amperometric sensors have been reported. These sensors are based on the electrochemical oxygen ion pumping of a zirconia electrolyte. They typically show reproducible limiting current plateaus with an applied voltage caused by the gas diffusion overpotential at the cathode.

  10. National Air & Space Intelligence Center Holds Program About...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Air & Space Intelligence Center Holds Program About Empowering Women in the Workplace National Air & Space Intelligence Center Holds Program About Empowering Women in the...

  11. Air Quality/Emissions Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air QualityEmissions Resources Air QualityEmissions Resources Federal agencies and certain state governments are required to acquire alternative fuel vehicles as part of the ...

  12. The Next Generation Air Particle Detectors for the United States...

    Office of Scientific and Technical Information (OSTI)

    The Next Generation Air Particle Detectors for the United States Navy Citation Details In-Document Search Title: The Next Generation Air Particle Detectors for the United States ...

  13. Product Standards for Air Conditioners (Japan) | Open Energy...

    Open Energy Info (EERE)

    Air Conditioners (Japan) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Product Standards for Air Conditioners (Japan) Focus Area: Appliances & Equipment Topics: Policy...

  14. American Society of Heating, Refrigeration, and Air Condition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    American Society of Heating, Refrigeration, and Air Condition Engineers (ASHRAE) 2016 Annual Conference American Society of Heating, Refrigeration, and Air Condition Engineers ...

  15. Evaluation of the Compressed Air Challenge Training Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... and compressed air system vendors with knowledge and tools required to effect ... Systems and 925 individuals had attended Advanced Management of Compressed Air Systems. ...

  16. Analyzing Your Compressed Air System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This tip sheet outlines the process to analyze industrial compressed air systems and ... More Documents & Publications Compressed Air System Control Strategies Determining the ...

  17. Determine the Cost of Compressed Air for Your Plant | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This tip sheet discusses a method for determining the cost of compressed air at industrial ... More Documents & Publications Compressed Air System Control Strategies Select an ...

  18. Guidelines for Selecting a Compressed Air System Service Provider...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guidelines for Selecting a Compressed Air System Service Provider Guidelines for Selecting a Compressed Air System Service Provider This publication is meant to help industrial ...

  19. Building America Top Innovations 2014 Profile: HVAC Cabinet Air...

    Energy Savers [EERE]

    HVAC Cabinet Air Leakage Test Method (top left) Building America teams evaluated several testing methods to identify a robust, repeatable test to recommend for air leakage ...

  20. Outside Air Ventilation Controller - Building America Top Innovation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Outside Air Ventilation Controller - Building America Top Innovation Outside Air Ventilation Controller - Building America Top Innovation This photo shows a two-story house with ...