National Library of Energy BETA

Sample records for aerosols solvents adhesives

  1. Solvent for urethane adhesives and coatings and method of use

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Holt, Jerrid S. (Knoxville, TN)

    2010-08-03

    A solvent for urethane adhesives and coatings, the solvent having a carbaldehyde and a cyclic amide as constituents. In some embodiments the solvent consists only of miscible constituents. In some embodiments the carbaldehyde is benzaldehyde and in some embodiments the cyclic amide is N-methylpyrrolidone (M-pyrole). An extender may be added to the solvent. In some embodiments the extender is miscible with the other ingredients, and in some embodiments the extender is non-aqueous. For example, the extender may include isopropanol, ethanol, tetrahydro furfuryl alcohol, benzyl alcohol, Gamma-butyrolactone or a caprolactone. In some embodiments a carbaldehyde and a cyclic amide are heated and used to separate a urethane bonded to a component.

  2. Guo et al., Aerosol and Air Quality, Vol. 4, No. 1, pp. 1-16, 2004 An Upwind/Downwind Comparative Study of the Solvent

    E-Print Network [OSTI]

    Zheng, Mei

    Study of the Solvent Extractable Organic Compounds in PM2.5 in Hong Kong Zhigang Guo1 , K.L. To, Mei. The solvent extractable organic compounds (SEOC) were separated into four major fractions (n-alkanes, fatty-distance (within Hong Kong) plumes. Keywords: aerosol, PM2.5, solvent-extractable organic compounds, transport

  3. Understanding the Mechanism of Solvent-Mediated Adhesion of Vacuum Deposited Au and Pt Thin Films onto PMMA Substrates

    SciTech Connect (OSTI)

    Mo, Alan K [ORNL; Brown, Victoria L. [James Madison University; Rugg, Brandon K. [James Madison University; Devore, Prof. Thomas C. [James Madison University; Meyer III, Harry M [ORNL; Hu, Dr. Xiaofeng [James Madison University; Hughes, Prof. W. Christopher [James Madison University; Augustine, Prof. Brian H. [James Madison University

    2012-01-01

    The adhesion of 100 nm thick electron-beam deposited Au and Pt and magnetron sputtered Au thin films onto poly(methyl methacrylate) (PMMA) substrates can be significantly enhanced to over 90% adhesion by either spin-casting or vapor-exposure to hydrohalocarbon solvents prior to metal deposition compared to samples that are either cleaned in isopropyl alcohol or pre-treated with a remote O2 plasma. X-ray photoelectron spectroscopy (XPS) and evolved gas Fourier transform infrared spectroscopy (EGA-FTIR) reveal the presence of residual halogenated solvent molecules at the PMMA surface which chemically activates the surface to produce a stable chemical interaction between the noble metal film and the PMMA. Density functional theory (DFT) calculations show that the halogenated solvent molecules preferentially form a Lewis acid-base adduct with the oxygen atoms in the ester group in PMMA which is consistent with the measured enthalpy of desorption of chloroform (CHCl3) on PMMA determined by EGA-FTIR to be 36 kJ mol-1. The DFT model also supports the experimentally observed change in the high resolution XPS O 1s peak at 533.77 eV after metallization attributed to a change in the local bonding environment of the bridging O in the PMMA ester group. DFT also predicts that the deposited metal atom (M) inserts into the C-X bond where X is the halogen atom on either CHCl3 or bromoform (CHBr3) to form a O M X interaction that is observed by a M-X bond in the high resolution XPS Cl 2p3/2 peak at 198.03 eV and Br 3p3/2 peak at 182.06 eV. A range of solvents with differing polarities for PMMA pre-treatment have been used and it is proposed that non-complexing solvents result in significant metal adhesion improvement. The Gutmann acceptor number can be used to predict the effectiveness of solvent treatment for noble metal adhesion. A model is proposed in which the bond energy of the C-X bond of the solvent must be sufficiently low so that the C-X bond can be cleaved to form the M-X bond. Supporting this model, a negative control of vapor phase exposure to fluoroform (CHF3) is shown to have no effect on noble metal adhesion due to the higher bond dissociation energy of the C-F bond compared to the C-Cl and C-Br bond energy. The surface activation of vapor-phase exposed PMMA surfaces is technologically significant for the fabrication of polymer microdevices requiring Au or Pt metallization.

  4. Vapor Transport of a Volatile Solvent for a Multicomponent Aerosol Droplet

    E-Print Network [OSTI]

    Feng, James Q

    2015-01-01

    This work presents analytical formulas derived for evaluating vapor transport of a volatile solvent for an isolated multicomponent droplet in a quiescent environment, based on quasi-steady-state approximation. Among multiple solvent components, only one component is considered to be much more volatile than the rest such that other components are assumed to be nonvolatile remaining unchanged in the droplet during the process of (single-component) volatile solvent evaporation or condensation. For evaporating droplet, the droplet size often initially decreases following the familiar "d^2 law" at an accelerated rate. But toward the end, the rate of droplet size change diminishes due to the presence of nonvolatile cosolvent. Such an acceleration-deceleration reversal behavior is unique for evaporating multicomponent droplet, while the droplet of pure solvent has an accelerated rate of size change all the way through the end. This reversal behavior is also reflected in the droplet surface temperature evolution as "...

  5. Vapor Transport of a Volatile Solvent for a Multicomponent Aerosol Droplet

    E-Print Network [OSTI]

    James Q. Feng

    2015-07-19

    This work presents analytical formulas derived for evaluating vapor transport of a volatile solvent for an isolated multicomponent droplet in a quiescent environment, based on quasi-steady-state approximation. Among multiple solvent components, only one component is considered to be much more volatile than the rest such that other components are assumed to be nonvolatile remaining unchanged in the droplet during the process of (single-component) volatile solvent evaporation or condensation. For evaporating droplet, the droplet size often initially decreases following the familiar "d^2 law" at an accelerated rate. But toward the end, the rate of droplet size change diminishes due to the presence of nonvolatile cosolvent. Such an acceleration-deceleration reversal behavior is unique for evaporating multicomponent droplet, while the droplet of pure solvent has an accelerated rate of size change all the way through the end. This reversal behavior is also reflected in the droplet surface temperature evolution as "S-shaped" curves. However, a closer mathematical examination of conditions for acceleration-deceleration reversal indicates that the acceleration phase may disappear when the amount of nonvolatile cosolvent is relatively small and ambient vapor pressure is relatively high. Because the net effect of adding nonvolatile cosolvent is to reduce the mole fraction of the volatile solvent such that the saturation vapor pressure is lowered, vapor condensation onto the multicomponent droplet is predicted to occur when the ambient vapor pressure is subsaturated with respect to that for the pure volatile solvent. In this case, the droplet will grow asymptotically toward a finite size. But when the ambient vapor pressure becomes supersaturated with respect to that for the pure volatile solvent, the condensation growth of droplet can continue indefinitely without bound.

  6. Solvents: Theory and Application

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Solvents: Theory and Application Revised: 2007-03-02 Source: www.microchemicals.eu/technical-information Photoresists, developers, remover, adhesion promoters, etchants, and solvents ... Phone: +49 731 36080-409 Fax of solvents can be explained, and which solvent is (un)suited for your purpose. Interaction Between Molecules

  7. Hazardous particle binder, coagulant and re-aerosolization inhibitor

    DOE Patents [OSTI]

    Krauter, Paula (Livermore, CA); Zalk, David (San Jose, CA); Hoffman, D. Mark (Livermore, CA)

    2011-04-12

    A copolymer and water/ethanol solvent solution capable of binding with airborne contaminants or potential airborne contaminants, such as biological weapon agents or toxic particulates, coagulating as the solvent evaporates, and adhering the contaminants to a surface so as to inhibit the re-suspension of such contaminants. The solution uses a water or ethanol/water mixture for the solvent, and a copolymer having one of several functional group sets so as to have physical and chemical characteristics of high adhesion, low viscosity, low surface tension, negative electrostatic charge, substantially neutral pH, and a low pKa. Use of the copolymer solution prevents re-aerosolization and transport of unwanted, reactive species thus increasing health and safety for personnel charged with decontamination of contaminated buildings and areas.

  8. Hazardous particle binder, coagulant and re-aerosolization inhibitor

    DOE Patents [OSTI]

    Krauter, Paula; Zalk, David; Hoffman, D. Mark

    2012-07-10

    A copolymer and water/ethanol solvent solution capable of binding with airborne contaminants or potential airborne contaminants, such as biological weapon agents or toxic particulates, coagulating as the solvent evaporates, and adhering the contaminants to a surface so as to inhibit the re-suspension of such contaminants. The solution uses a water or ethanol/water mixture for the solvent, and a copolymer having one of several functional group sets so as to have physical and chemical characteristics of high adhesion, low viscosity, low surface tension, negative electrostatic charge, substantially neutral pH, and a low pKa. Use of the copolymer solution prevents re-aerosolization and transport of unwanted, reactive species thus increasing health and safety for personnel charged with decontamination of contaminated buildings and areas.

  9. Solvent substitution

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The DOE Environmental Restoration and Waste Management Office of Technology Development and the Air Force Engineering and Services Center convened the First Annual International Workshop on Solvent Substitution on December 4--7, 1990. The primary objectives of this joint effort were to share information and ideas among attendees in order to enhance the development and implementation of required new technologies for the elimination of pollutants associated with industrial use of hazardous and toxic solvents; and to aid in accelerating collaborative efforts and technology transfer between government and industry for solvent substitution. There were workshop sessions focusing on Alternative Technologies, Alternative Solvents, Recovery/Recycling, Low VOC Materials and Treatment for Environmentally Safe Disposal. The 35 invited papers presented covered a wide range of solvent substitution activities including: hardware and weapons production and maintenance, paint stripping, coating applications, printed circuit boards, metal cleaning, metal finishing, manufacturing, compliance monitoring and process control monitoring. This publication includes the majority of these presentations. In addition, in order to further facilitate information exchange and technology transfer, the US Air Force and DOE solicited additional papers under a general Call for Papers.'' These papers, which underwent review and final selection by a peer review committee, are also included in this combined Proceedings/Compendium. For those involved in handling, using or managing hazardous and toxic solvents, this document should prove to be a valuable resource, providing the most up-to-date information on current technologies and practices in solvent substitution. Individual papers are abstracted separated.

  10. Marine aerosols

    E-Print Network [OSTI]

    Saltzman, ES

    2009-01-01

    proper- ties found in the marine boundary layer over theand R. E. Larson (1994), Marine boundary layer measurementsand T. Hoffmann (2002), Marine aerosol formation from

  11. Solvent wash solution

    DOE Patents [OSTI]

    Neace, James C. (Blackville, SC)

    1986-01-01

    Process for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 volume percent of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  12. Solvent wash solution

    DOE Patents [OSTI]

    Neace, J.C.

    1984-03-13

    A process is claimed for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 vol % of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  13. Solvent recovery targeting

    SciTech Connect (OSTI)

    Ahmad, B.S.; Barton, P.I.

    1999-02-01

    One of the environmental challenges faced by the pharmaceutical and specialty chemical industries is the widespread use of organic solvents. With a solvent-based chemistry, the solvent necessarily has to be separated from the product. Chemical species in waste-solvent streams typically form multicomponent azeotropic mixtures, and this often complicates separation and, hence, recovery of solvents. A design approach is presented whereby process modifications proposed by the engineer to reduce the formation of waste-solvent streams can be evaluated systematically. This approach, called solvent recovery targeting, exploits a recently developed algorithm for elucidating the separation alternatives achievable when applying batch distillation to homogeneous multicomponent mixtures. The approach places the composition of the waste-solvent mixture correctly in the relevant residue curve map and computes the maximum amount of pure material that can be recovered via batch distillation. Solvent recovery targeting is applied to two case studies derived from real industrial processes.

  14. PH dependent adhesive peptides

    DOE Patents [OSTI]

    Tomich, John; Iwamoto, Takeo; Shen, Xinchun; Sun, Xiuzhi Susan

    2010-06-29

    A novel peptide adhesive motif is described that requires no receptor or cross-links to achieve maximal adhesive strength. Several peptides with different degrees of adhesive strength have been designed and synthesized using solid phase chemistries. All peptides contain a common hydrophobic core sequence flanked by positively or negatively charged amino acids sequences.

  15. Adhesion Enhancement through Micropatterning at Polydimethylsiloxane-Acrylic Adhesive Interfaces

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    Adhesion Enhancement through Micropatterning at Polydimethylsiloxane-Acrylic Adhesive Interfaces M Adhesion at polydimethylsiloxane (PDMS)-acrylic adhesive interfaces is shown to be enhanced through features on the level of adhesion have been analyzed. For cylindrical pillars, two regimes are clearly

  16. Wetting and phase separation in soft adhesion

    E-Print Network [OSTI]

    K. E. Jensen; R. Sarfati; R. W. Style; R. Boltyanskiy; A. Chakrabarti; M. K. Chaudhury; E. R. Dufresne

    2015-07-22

    In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of soft materials. This suggests that the contact line in soft adhesion should mimic that of a liquid droplet, with a contact angle determined by surface tensions. Consistent with this hypothesis, we observe a contact angle of a soft silicone substrate on rigid silica spheres that depends on the surface functionalization but not the sphere size. However, to satisfy this wetting condition without a divergent elastic stress, the gel separates from its solvent near the contact line. This creates a four-phase contact zone with two additional contact lines hidden below the surface of the substrate. While the geometries of these contact lines are independent of the size of the sphere, the volume of the phase-separated region is not, but rather depends on the indentation volume. These results indicate that theories of adhesion of soft gels need to account for both the compressibility of the gel network and a non-zero surface stress between the gel and its solvent.

  17. Mixed Solvent Electrolyte Model

    Broader source: Energy.gov [DOE]

    With assistance from AMO, OLI Systems, Inc., developed the mixed-solvent electrolyte model, a comprehensive physical property package that can predict the properties of electrolyte systems ranging...

  18. Experiments related to the resuspension of aerosols during hydrogen burns

    SciTech Connect (OSTI)

    Nelson, L.S.; Guay, K.P.

    1987-01-01

    We have performed seven ''add-on'' experiments in two large combustion facilities to investigate the capability of hydrogen burns to remove simulated structural and fission product aerosols previously deposited on small metal discs that have surfaces prototypical of those found in nuclear reactor containments. Our results suggest that hydrogen combustion provides an especially effective mechanism for removal (and, presumably, resuspension) of sedimented aerosols produced in a hypothetical nuclear reactor core-degradation or core-melting accident. The presence of condensing steam does not seem to assure adhesion of sedimented aerosols during hydrogen burns. Differences are exhibited between different surfaces as well as between types of aerosol. In-depth studies will be required to assess the impact exposure of sedimented aerosols to hydrogen burns might have on the radiological source term.

  19. Continuous countercurrent membrane column for the separation of solute/solvent and solvent/solvent systems

    DOE Patents [OSTI]

    Nerad, Bruce A. (Longmont, CO); Krantz, William B. (Boulder, CO)

    1988-01-01

    A reverse osmosis membrane process or hybrid membrane - complementary separator process for producing enriched product or waste streams from concentrated and dilute feed streams for both solvent/solvent and solute/solvent systems is described.

  20. Adhesive Gravitational Clustering

    E-Print Network [OSTI]

    Thomas Buchert; Alvaro Dominguez

    2005-06-21

    The notion of `adhesion' has been advanced for the phenomenon of stabilization of large-scale structure emerging from gravitational instability of a cold medium. Recently, the physical origin of adhesion has been identified: a systematic derivation of the equations of motion for the density and the velocity fields leads naturally to the key equation of the `adhesion approximation' - however, under a set of strongly simplifying assumptions. In this work, we provide an evaluation of the current status of adhesive gravitational clustering and a clear explanation of the assumptions involved. Furthermore, we propose systematic generalizations with the aim to relax some of the simplifying assumptions. We start from the general Newtonian evolution equations for self-gravitating particles on an expanding Friedmann background and recover the popular `dust model' (pressureless fluid), which breaks down after the formation of density singularities; then we investigate, in a unified framework, two other models which, under the restrictions referred to above, lead to the `adhesion approximation'. We apply the Eulerian and Lagrangian perturbative expansions to these new models and, finally, we discuss some non-perturbative results that may serve as starting points for workable approximations of non-linear structure formation in the multi-stream regime. In particular, we propose a new approximation that includes, in limiting cases, the standard `adhesion model' and the Eulerian as well as Lagrangian first-order approximations.

  1. Method for recovering and using lignin in adhesive resins by extracting demethylated lignin

    DOE Patents [OSTI]

    Schroeder, Herbert A. (Ft. Collins, CO)

    1991-01-01

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is preferably dried and stored until it is used (along with an alkali, an aldehyde and an adhesive filler) in compounding an adhesive of the type generally used in the manufacture of plywood.

  2. Halogenated solvent remediation

    DOE Patents [OSTI]

    Sorenson, Jr., Kent S. (Windsor, CO)

    2008-11-11

    Methods for enhancing bioremediation of ground water contaminated with nonaqueous halogenated solvents are disclosed. An illustrative method includes adding an electron donor for microbe-mediated anaerobic reductive dehalogenation of the halogenated solvents, which electron donor enhances mass transfer of the halogenated solvents from residual source areas into the aqueous phase of the ground water. Illustrative electron donors include C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, salts thereof, esters of C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, and mixtures thereof, of which lactic acid, salts of lactic acid--such as sodium lactate, lactate esters, and mixtures thereof are particularly illustrative. The microbes are either indigenous to the ground water, or such microbes can be added to the ground water in addition to the electron donor.

  3. Halogenated solvent remediation

    DOE Patents [OSTI]

    Sorenson, Kent S.

    2004-08-31

    Methods for enhancing bioremediation of ground water contaminated with nonaqueous halogenated solvents are disclosed. A preferred method includes adding a composition to the ground water wherein the composition is an electron donor for microbe-mediated reductive dehalogenation of the halogenated solvents and enhances mass transfer of the halogenated solvents from residual source areas into the aqueous phase of the ground water. Illustrative compositions effective in these methods include surfactants such as C.sub.2 -C.sub.4 carboxylic acids and hydroxy acids, salts thereof, esters of C.sub.2 -C.sub.4 carboxylic acids and hydroxy acids, and mixtures thereof. Especially preferred compositions for use in these methods include lactic acid, salts of lactic acid, such as sodium lactate, lactate esters, and mixtures thereof. The microbes are either indigenous to the ground water, or such microbes can be added to the ground water in addition to the composition.

  4. Safe battery solvents

    DOE Patents [OSTI]

    Harrup, Mason K. (Idaho Falls, ID); Delmastro, Joseph R. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID)

    2007-10-23

    An ion transporting solvent maintains very low vapor pressure, contains flame retarding elements, and is nontoxic. The solvent in combination with common battery electrolyte salts can be used to replace the current carbonate electrolyte solution, creating a safer battery. It can also be used in combination with polymer gels or solid polymer electrolytes to produce polymer batteries with enhanced conductivity characteristics. The solvents may comprise a class of cyclic and acyclic low molecular weight phosphazenes compounds, comprising repeating phosphorus and nitrogen units forming a core backbone and ion-carrying pendent groups bound to the phosphorus. In preferred embodiments, the cyclic phosphazene comprises at least 3 phosphorus and nitrogen units, and the pendent groups are polyethers, polythioethers, polyether/polythioethers or any combination thereof, and/or other groups preferably comprising other atoms from Group 6B of the periodic table of elements.

  5. Adhesive particle shielding

    DOE Patents [OSTI]

    Klebanoff, Leonard Elliott (Dublin, CA); Rader, Daniel John (Albuquerque, NM); Walton, Christopher (Berkeley, CA); Folta, James (Livermore, CA)

    2009-01-06

    An efficient device for capturing fast moving particles has an adhesive particle shield that includes (i) a mounting panel and (ii) a film that is attached to the mounting panel wherein the outer surface of the film has an adhesive coating disposed thereon to capture particles contacting the outer surface. The shield can be employed to maintain a substantially particle free environment such as in photolithographic systems having critical surfaces, such as wafers, masks, and optics and in the tools used to make these components, that are sensitive to particle contamination. The shield can be portable to be positioned in hard-to-reach areas of a photolithography machine. The adhesive particle shield can incorporate cooling means to attract particles via the thermophoresis effect.

  6. A batch fabricated biomimetic dry adhesive

    E-Print Network [OSTI]

    Northen, Michael T; Turner, K L

    2005-01-01

    nano-structures as dry adhesives J. Adhesion Sci. Technol.al 2003 Microfabricated adhesive mimicking gecko foot-hairfabricated biomimetic dry adhesive Michael T Northen 1,3 and

  7. Membrane adhesion and domain formation

    E-Print Network [OSTI]

    Thomas R. Weikl; Reinhard Lipowsky

    2007-09-23

    We review theoretical results for the adhesion-induced phase behavior of biomembranes. The focus is on models in which the membranes are represented as discretized elastic sheets with embedded adhesion molecules. We present several mechanism that lead to the formation of domains during adhesion, and discuss the time-dependent evolution of domain patterns obtained in Monte-Carlo simulations. The simulated pattern dynamics has striking similarities to the pattern evolution observed during T cell adhesion.

  8. Adhesion of microcapsules

    E-Print Network [OSTI]

    Peter Graf; Reimar Finken; Udo Seifert

    2006-06-14

    The adhesion of microcapsules to an attractive contact potential is studied theoretically. The axisymmetric shape equations are solved numerically. Beyond a universal threshold strength of the potential, the contact radius increases like a square root of the strength. Scaling functions for the corresponding amplitudes are derived as a function of the elastic parameters.

  9. Adhesivity, Bigraphs and Bisimulation Congruences

    E-Print Network [OSTI]

    Sobocinski, Pawel

    Adhesivity, Bigraphs and Bisimulation Congruences Pawel Soboci´nski1 IT University Copenhagen] and the author [7]. The general areas include adhesive categories and generalisations, contextual labelled for Modeling Distributed and Mobile Systems". We shall concentrate on the notions of adhesivity and reactive

  10. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian (Port Jefferson, NY); Kulkarni, Pramod (Port Jefferson Station, NY)

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  11. High temperature adhesive silicone foam composition, foam generating system and method of generating foam

    DOE Patents [OSTI]

    Mead, Judith W. (Peralta, NM); Montoya, Orelio J. (Albuquerque, NM); Rand, Peter B. (Albuquerque, NM); Willan, Vernon O. (Albuquerque, NM)

    1984-01-01

    Access to a space is impeded by generation of a sticky foam from a silicone polymer and a low boiling solvent such as a halogenated hydrocarbon. In a preferred aspect, the formulation is polydimethylsiloxane gel mixed with F502 Freon as a solvent and blowing agent, and pressurized with CO.sub.2 in a vessel to about 250 PSI, whereby when the vessel is opened, a sticky and solvent resistant foam is deployed. The foam is deployable, over a wide range of temperatures, adhering to wet surfaces as well as dry, is stable over long periods of time and does not propagate flame or lose adhesive properties during an externally supported burn.

  12. Solvent Immersion Imprint Lithography

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Wilkins, Michael J.; Grate, Jay W.; Kelly, Ryan T.; Konopka, Allan; Xantheas, Sotiris S.; Chang, M. T.

    2014-06-21

    The mechanism of polymer disolution was explored for polymer microsystem prototyping, including microfluidics and optofluidics. Polymer films are immersed in a solvent, imprinted and finally brought into contact with a non-modified surface to permanently bond. The underlying polymer-solvent interactions were experimentally and theoretically investigated, and enabled rapid polymer microsystem prototyping. During imprinting, small molecule integration in the molded surfaces was feasible, a principle applied to oxygen sensing. Polystyrene (PS) was employed for microbiological studies at extreme environmental conditions. The thermophile anaerobe Clostridium Thermocellum was grown in PS pore-scale micromodels, revealing a double mean generation lifetime than under ideal culture conditions. Microsystem prototyping through directed polymer dissolution is simple and accessible, while simultaneous patterning, bonding, and surface/volume functionalization are possible in less than one minute.

  13. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  14. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  15. Screenable Pressure-Sensitive Adhesives

    Broader source: Energy.gov [DOE]

    Pressure-sensitive adhesives (PSAs) in recycled paper create a number of problems for the recycling process, including lost production and diminished product quality. Unlike conventional PSAs, a...

  16. Solvent Blending Strategy to Upgrade MCU CSSX Solvent to Equivalent Next-Generation CSSX Solvent

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Moyer, Bruce A

    2012-12-01

    The results of the present study have validated an equal-volume blending strategy for upgrading freshly prepared CSSX solvent to a blended solvent functionally equivalent to NG-CSSX solvent. It is shown that blending fresh CSSX solvent as currently used in MCU with an equal volume of an NG-CSSX solvent concentrate of appropriate composition yields a blended solvent composition (46.5 mM of MaxCalix, 3.5 mM of BOBCalixC6, 0.5 M of Cs-7SB, 3 mM of guanidine suppressor, and 1.5 mM of TOA in Isopar L) that exhibits equivalent batch ESS performance to that of the NG-CSSX solvent containing 50 mM of MaxCalix, 0.5 M of Cs-7SB, and 3 mM of guanidine suppressor in Isopar L. The solvent blend composition is robust to third-phase formation. Results also show that a blend containing up to 60% v/v of CSSX solvent could be accommodated with minimal risk. Extraction and density data for the effect of solvent concentration mimicking diluent evaporation or over-dilution of the equal-volume blended solvent are also given, providing input for setting operational limits. Given that the experiments employed all pristine chemicals, the results do not qualify a blended solvent starting with actual used MCU solvent, which can be expected to have undergone some degree of degradation. Consequently, further work should be considered to evaluate this risk and implement appropriate remediation if needed.

  17. Adhesion gene regulation in mammary cell proliferation

    E-Print Network [OSTI]

    Lau, Eric HonYui

    2011-01-01

    A. , et al. , Nectin: an adhesion molecule involved in OF CALIFORNIA, MERCED Adhesion Gene Regulation in Mammary1 1.2 Role of Adhesion Molecules in Development and

  18. Adhesion mediates the initiation of epidermal differentiation

    E-Print Network [OSTI]

    Lasse, Samuel Hersh

    2011-01-01

    and integrin-mediated adhesions." Proc Natl Acad Sci U S Akeratinocyte cell-cell adhesion." J Cell Biol 141(6): 1449-et al. (2005). "Cell-adhesion assays: fabrication of an E-

  19. Caspr2 : possible synaptogenic cell adhesion molecule

    E-Print Network [OSTI]

    Do, Trinh Thuy

    2011-01-01

    T. 2002. SynCAM, a Synaptic Adhesion Molecule That DrivesPSD-95-interacting adhesion molecules regulate excitatorycode for trans-synaptic cell adhesion mediated by binding of

  20. Discrete-element modeling of particulate aerosol flows

    SciTech Connect (OSTI)

    Marshall, J.S. [School of Engineering, University of Vermont, 33 Colchecter Avenue, Burlington, Vermont 05405 (United States)], E-mail: jeffm@cems.uvm.edu

    2009-03-20

    A multiple-time step computational approach is presented for efficient discrete-element modeling of aerosol flows containing adhesive solid particles. Adhesive aerosol particulates are found in numerous dust and smoke contamination problems, including smoke particle transport in the lungs, particle clogging of heat exchangers in construction vehicles, industrial nanoparticle transport and filtration systems, and dust fouling of electronic systems and MEMS components. Dust fouling of equipment is of particular concern for potential human occupation on dusty planets, such as Mars. The discrete-element method presented in this paper can be used for prediction of aggregate structure and breakup, for prediction of the effect of aggregate formation on the bulk fluid flow, and for prediction of the effects of small-scale flow features (e.g., due to surface roughness or MEMS patterning) on the aggregate formation. After presentation of the overall computational structure, the forces and torques acting on the particles resulting from fluid motion, particle-particle collision, and adhesion under van der Waals forces are reviewed. The effect of various parameters of normal collision and adhesion of two particles are examined in detail. The method is then used to examine aggregate formation and particle clogging in pipe and channel flow.

  1. Corrugated pipe adhesive applicator apparatus

    DOE Patents [OSTI]

    Shirey, R.A.

    1983-06-14

    Apparatus for coating selected portions of the troughs of a corrugated pipe with an adhesive includes a support disposed within the pipe with a reservoir containing the adhesive disposed on the support. A pump, including a spout, is utilized for supplying the adhesive from the reservoir to a trough of the pipe. A rotatable applicator is supported on the support and contacts the trough of the pipe. The applicator itself is sized so as to fit within the trough, and contacts the adhesive in the trough and spreads the adhesive in the trough upon rotation. A trough shield, supported by the support and disposed in the path of rotation of the applicator, is utilized to prevent the applicator from contacting selected portions of the trough. A locator head is also disposed on the support and provides a way for aligning the spout, the applicator, and the trough shield with the trough. 4 figs.

  2. Adhesion Transition of Flexible Sheets

    E-Print Network [OSTI]

    Arthur A. Evans; Eric Lauga

    2009-05-31

    Intermolecular forces are known to precipitate adhesion events between solid bodies. Inspired by a macro-scale experiment showing the hysteretic adhesion of a piece of flexible tape over a plastic substrate, we develop here a model of far-field dry adhesion between two flexible sheets interacting via a power-law potential. We show that phase transitions from unadhered to adhered states occur as dictated by a dimensionless bending parameter representing the ratio of interaction strength to bending stiffness. The order of the adhesion transitions, as well as their hysteretic nature, is shown to depend on the form of the interaction potential between the flexible sheets. When three or more sheets interact, additional geometrical considerations determine the hierarchical or sequential nature of the adhesion transitions.

  3. Corrugated pipe adhesive applicator apparatus

    DOE Patents [OSTI]

    Shirey, Ray A. (North Grafton, MA)

    1983-06-14

    Apparatus for coating selected portions of the troughs of a corrugated pipe within an adhesive includes a support disposed within the pipe with a reservoir containing the adhesive disposed on the support. A pump, including a spout, is utilized for supplying the adhesive from the reservoir to a trough of the pipe. A rotatable applicator is supported on the support and contacts the trough of the pipe. The applicator itself is sized so as to fit within the trough, and contacts the adhesive in the trough and spreads the adhesive in the trough upon rotation. A trough shield, supported by the support and disposed in the path of rotation of the applicator, is utilized to prevent the applicator from contacting selected portions of the trough. A locator head is also disposed on the support and provides a way for aligning the spout, the applicator, and the trough shield with the trough.

  4. Adhesion Impact of Silicone Contamination during Encapsulation...

    Office of Scientific and Technical Information (OSTI)

    Adhesion Impact of Silicone Contamination during Encapsulation. Citation Details In-Document Search Title: Adhesion Impact of Silicone Contamination during Encapsulation. Abstract...

  5. Physical properties of ambient and laboratory-generated secondary organic aerosol

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    the rebound energy, then the particle will remain on the surface. The viscosity, including both elastic of viscosity values appropriate for SOA models. When an aerosol particle impacts a surface, some kinetic energy is dissipated in deformation. If the kinetic energy loss is large enough that the adhesion energy exceeds

  6. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  7. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    2008-01-15

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  8. International Journal of Adhesion & Adhesives 26 (2006) 314324 Dynamic response of a repaired composite beam with an adhesively

    E-Print Network [OSTI]

    Vaziri, Ashkan

    2006-01-01

    International Journal of Adhesion & Adhesives 26 (2006) 314­324 Dynamic response of a repaired composite beam with an adhesively bonded patch under a harmonic peeling load A. Vaziri1 , H. Nayeb with adhesive. In the theoretical part, the equations of motion in the axial and transverse directions were

  9. Solvent reorganization energy of electron-transfer reactions in polar solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent reorganization energy of electron-transfer reactions in polar solvents Dmitry V. Matyushova theory of solvent reorganization energy in polar molecular solvents is developed. The theory represents the solvent response as a combination of the density and polarization fluctuations of the solvent given

  10. Photovoltaic module with adhesion promoter

    DOE Patents [OSTI]

    2013-10-08

    Photovoltaic modules with adhesion promoters and methods for fabricating photovoltaic modules with adhesion promoters are described. A photovoltaic module includes a solar cell including a first surface and a second surface, the second surface including a plurality of interspaced back-side contacts. A first glass layer is coupled to the first surface by a first encapsulating layer. A second glass layer is coupled to the second surface by a second encapsulating layer. At least a portion of the second encapsulating layer is bonded directly to the plurality of interspaced back-side contacts by an adhesion promoter.

  11. Adhesives from modified soy protein

    DOE Patents [OSTI]

    Sun, Susan (Manhattan, KS); Wang, Donghai (Manhattan, KS); Zhong, Zhikai (Manhattan, KS); Yang, Guang (Shanghai, CN)

    2008-08-26

    The, present invention provides useful adhesive compositions having similar adhesive properties to conventional UF and PPF resins. The compositions generally include a protein portion and modifying ingredient portion selected from the group consisting of carboxyl-containing compounds, aldehyde-containing compounds, epoxy group-containing compounds, and mixtures thereof. The composition is preferably prepared at a pH level at or near the isoelectric point of the protein. In other preferred forms, the adhesive composition includes a protein portion and a carboxyl-containing group portion.

  12. High temperature adhesive silicone foam composition, foam generating system and method of generating foam. [For access denial

    DOE Patents [OSTI]

    Mead, J.W.; Montoya, O.J.; Rand, P.B.; Willan, V.O.

    1983-12-21

    Access to a space is impeded by generation of a sticky foam from a silicone polymer and a low boiling solvent such as a halogenated hydrocarbon. In a preferred aspect, the formulation is polydimethylsiloxane gel mixed with F502 Freon as a solvent and blowing agent, and pressurized with CO/sub 2/ in a vessel to about 250 PSI, whereby when the vessel is opened, a sticky and solvent resistant foam is deployed. The foam is deployable, over a wide range of temperatures, adhering to wet surfaces as well as dry, is stable over long periods of time and does not propagate flame or lose adhesive properties during an externally supported burn.

  13. Specific Adhesion of Peptides on Semiconductor Surfaces in Experiment and Simulation

    E-Print Network [OSTI]

    Karsten Goede; Michael Bachmann; Wolfhard Janke; Marius Grundmann

    2007-10-24

    We report on self-assembly, clustering, and conformational phases of peptides on inorganic semiconductor surfaces. The peptide-covered surface fraction can differ by a factor of 25, depending mainly on surface and peptide polarity. Low adhesion induces large and soft clusters, which also have high contact angles to the surface. Direct surface adhesion of a peptide molecule competes with forming molecular aggregates which offer an overall reduced surface contact. Simulating a simple hybrid model yields a pseudophase diagram with a rich, temperature and solvent-quality dependent variety of subphases which are specific to the hydrophobicity and polarity of the considered substrates.

  14. Module: Material Structure Focus: Adhesion & Cohesion

    E-Print Network [OSTI]

    Rowley, Clarence W.

    Module: Material Structure Focus: Adhesion & Cohesion Duration: 43 minute period Contact: Daniel will develop a working understanding of adhesion and cohesion. Materials: Water Pipette (or Dropper) Plastic and illustrate the terms "adhesion" and "cohesion." 3. Students will complete a lab on adhesion and cohesion

  15. APPLIED PHYSICS REVIEWSFOCUSED REVIEW Adhesive wafer bonding

    E-Print Network [OSTI]

    Lü, James Jian-Qiang

    APPLIED PHYSICS REVIEWS­FOCUSED REVIEW Adhesive wafer bonding F. Niklausa Microsystem Technology 9 February 2006 Wafer bonding with intermediate polymer adhesives is an important fabrication-dimensional integrated circuits, advanced packaging, and microfluidics. In adhesive wafer bonding, the polymer adhesive

  16. Seafood delicacy makes great adhesive

    ScienceCinema (OSTI)

    Idaho National Laboratory - Frank Roberto, Heather Silverman

    2010-01-08

    Technology from Mother Nature is often hard to beat, so Idaho National Laboratory scientistsgenetically analyzed the adhesive proteins produced by blue mussels, a seafood delicacy. Afterobtaining full-length DNA sequences encoding these proteins, reprod

  17. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  18. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  19. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  20. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  1. Coal liquefaction process with enhanced process solvent

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Dohee (Macungie, PA)

    1984-01-01

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  2. RACORO aerosol data processing

    SciTech Connect (OSTI)

    Elisabeth Andrews

    2011-10-31

    The RACORO aerosol data (cloud condensation nuclei (CCN), condensation nuclei (CN) and aerosol size distributions) need further processing to be useful for model evaluation (e.g., GCM droplet nucleation parameterizations) and other investigations. These tasks include: (1) Identification and flagging of 'splash' contaminated Twin Otter aerosol data. (2) Calculation of actual supersaturation (SS) values in the two CCN columns flown on the Twin Otter. (3) Interpolation of CCN spectra from SGP and Twin Otter to 0.2% SS. (4) Process data for spatial variability studies. (5) Provide calculated light scattering from measured aerosol size distributions. Below we first briefly describe the measurements and then describe the results of several data processing tasks that which have been completed, paving the way for the scientific analyses for which the campaign was designed. The end result of this research will be several aerosol data sets which can be used to achieve some of the goals of the RACORO mission including the enhanced understanding of cloud-aerosol interactions and improved cloud simulations in climate models.

  3. Mussel adhesive protein provides cohesive matrix for collagen type-1?

    E-Print Network [OSTI]

    2015-01-01

    M. Zinc-doped dentin adhesive for collagen protection at theWaite JH. Mussel-inspired adhesives and coatings. Annu Revderived one component adhesive coacervate. Acta Biomater

  4. A mussel-derived one component adhesive coacervate

    E-Print Network [OSTI]

    2014-01-01

    in a mussel-inspired adhesive coacervate. Soft Matter 2010;RJ. Biomimetic underwater adhesives with environmentallySA, Waite JH. Probing the adhesive footprints of Mytilus

  5. Interfacial pH during mussel adhesive plaque formation

    E-Print Network [OSTI]

    Rodriguez, NRM; Das, S; Kaufman, Y; Israelachvili, JN; Waite, JH

    2015-01-01

    JH. 2011. Mussel-inspired adhesives and coatings. Annu Rev1987. Nature’s underwater adhesive specialist. Int J Adhesderived one component adhesive coacervate. Acta Biomater.

  6. Adhesion Between Surfaces Separated by Molecularly Thin Perfluoropolyether Films

    E-Print Network [OSTI]

    Brunner, R.; Tyndall, G. W.; Waltman, R. J.; Talke, F. E.

    2010-01-01

    results indicate that the adhesive force between macroscopicThe presence of these adhesive interactions, which arePFPE) ?lms, the adhesive interaction strength, and hence the

  7. Adhesive contact of elastomers: effective adhesion energy and creep function

    E-Print Network [OSTI]

    Etienne Barthel; Christian Frétigny

    2009-06-11

    For the adhesive contact of elastomers, we propose expressions to quantify the impact of viscoelastic response on effective adhesion energy as a function of contact edge velocity. The expressions we propose are simple analytical functionals of the creep response and should be suitable for experimental data analysis in terms of measured rheologies. We also emphasize the role of the coupling between local stress field at the contact edge and the macroscopic remote loading (far field). We show that the contrast between growing and receding contact originates from the impact of viscoelastic response on coupling, while the separation process at the contact edge is similarly affected by viscoelasticity in both cases.

  8. An evaluation of adhesive sample holders for advanced crystallographic experiments

    SciTech Connect (OSTI)

    Mazzorana, Marco; Sanchez-Weatherby, Juan Sandy, James; Lobley, Carina M. C.; Sorensen, Thomas

    2014-09-01

    Commercially available adhesives have been evaluated for crystal mounting when undertaking complex macromolecular crystallography experiments. Here, their use as tools for advanced sample mounting and cryoprotection is assessed and their suitability for room-temperature data-collection and humidity-controlled studies is investigated. The hydration state of macromolecular crystals often affects their overall order and, ultimately, the quality of the X-ray diffraction pattern that they produce. Post-crystallization techniques that alter the solvent content of a crystal may induce rearrangement within the three-dimensional array making up the crystal, possibly resulting in more ordered packing. The hydration state of a crystal can be manipulated by exposing it to a stream of air at controlled relative humidity in which the crystal can equilibrate. This approach provides a way of exploring crystal hydration space to assess the diffraction capabilities of existing crystals. A key requirement of these experiments is to expose the crystal directly to the dehydrating environment by having the minimum amount of residual mother liquor around it. This is usually achieved by placing the crystal on a flat porous support (Kapton mesh) and removing excess liquid by wicking. Here, an alternative approach is considered whereby crystals are harvested using adhesives that capture naked crystals directly from their crystallization drop, reducing the process to a one-step procedure. The impact of using adhesives to ease the harvesting of different types of crystals is presented together with their contribution to background scattering and their usefulness in dehydration experiments. It is concluded that adhesive supports represent a valuable tool for mounting macromolecular crystals to be used in humidity-controlled experiments and to improve signal-to-noise ratios in diffraction experiments, and how they can protect crystals from modifications in the sample environment is discussed.

  9. Adhesive, elastomeric gel impregnating composition

    DOE Patents [OSTI]

    Shaw, David Glenn (Tucson, AZ); Pollard, John Randolph (Tucson, AZ); Brooks, Robert Aubrey (Tijeras, NM)

    2002-01-01

    An improved capacitor roll with alternating film and foil layers is impregnated with an adhesive, elastomeric gel composition. The gel composition is a blend of a plasticizer, a polyol, a maleic anhydride that reacts with the polyol to form a polyester, and a catalyst for the reaction. The impregnant composition is introduced to the film and foil layers while still in a liquid form and then pressure is applied to aid with impregnation. The impregnant composition is cured to form the adhesive, elastomeric gel. Pressure is maintained during curing.

  10. 1/6TH SCALE STRIP EFFLUENT FEED TANK-MIXING RESULTS USING MCU SOLVENT

    SciTech Connect (OSTI)

    Hansen, E

    2006-02-01

    The purpose of this task was to determine if mixing was an issue for the entrainment and dispersion of the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) solvent in the Defense Waste Processing Facility (DWPF) Strip Effluent Feed Tank (SEFT). The MCU strip effluent stream containing the Cs removed during salt processing will be transferred to the DWPF for immobilization in HLW glass. In lab-scale DWPF chemical process cell testing, mixing of the solvent in the dilute nitric acid solution proved problematic, and the Savannah River National Laboratory (SRNL) was requested to perform scaled SEFT mixing tests to evaluate whether the problem was symptomatic of the lab-scale set-up or of the solvent. The solvent levels tested were 228 and 235 ppm, which represented levels near the estimated DWPF solvent limit of 239 ppm in 0.001M HNO{sub 3} solution. The 239 ppm limit was calculated by Norato in X-CLC-S-00141. The general approach for the mixing investigation was to: (1) Investigate the use of fluorescent dyes to aid in observing the mixing behavior. Evaluate and compare the physical properties of the fluorescent dyed MCU solvents to the baseline Oak Ridge CSSX solvent. Based on the data, use the dyed MCU solvent that best approximates the physical properties. (2) Use approximately a 1/6th linear scale of the SEFT to replicate the internal configuration for DWPF mixing. (3) Determine agitator speed(s) for scaled testing based on the DWPF SEFT mixing speed. (4) Perform mixing tests using the 1/6th SEFT and determine any mixing issues (entrainment/dispersion, accumulation, adhesion) through visual observations and by pulling samples to assess uniformity. The mixing tests used MCU solvent fabricated at SRNL blended with Risk Reactor DFSB-K43 fluorescent dye. This dyed SRNL MCU solvent had equivalent physical properties important to mixing as compared to the Oak Ridge baseline solvent, blended easily with the MCU solvent, and provided an excellent visual aid.

  11. Controllable adhesion using field-activated fluids Randy H. Ewoldt

    E-Print Network [OSTI]

    Controllable adhesion using field-activated fluids Randy H. Ewoldt Institute for Mathematics for variable- strength controllable adhesion. The adhesive performance is measured experimentally in tensile magnet. Increasing the magnetic field strength induces higher peak adhesive forces. We hypothesize

  12. Bistability of Cell Adhesion in Shear Flow

    E-Print Network [OSTI]

    Efremov, Artem K.

    Cell adhesion plays a central role in multicellular organisms helping to maintain their integrity and homeostasis. This complex process involves many different types of adhesion proteins, and synergetic behavior of these ...

  13. Controllable adhesion using field-activated fluids

    E-Print Network [OSTI]

    Ewoldt, Randy H.

    We demonstrate that field-responsive magnetorheological fluids can be used for variable-strength controllable adhesion. The adhesive performance is measured experimentally in tensile tests (a.k.a. probe-tack experiments) ...

  14. The state diagram for cell adhesion under flow: Leukocyte rolling and firm adhesion

    E-Print Network [OSTI]

    Tees, David F.J.

    The state diagram for cell adhesion under flow: Leukocyte rolling and firm adhesion Kai-Chien Chang, Philadelphia, PA, and approved July 31, 2000 (received for review May 24, 2000) Leukocyte adhesion under flow mediated by selectins) followed by firm adhesion (primarily me- diated by integrins). Using a computational

  15. Cell Adhesion Strength Is Controlled by Intermolecular Spacing of Adhesion Receptors

    E-Print Network [OSTI]

    Schwarz, Ulrich

    Cell Adhesion Strength Is Controlled by Intermolecular Spacing of Adhesion Receptors C. Selhuber numerous cellular processes such as spreading, adhesion, migration, and proliferation. Using force the strength of cell adhesion. For spacings R90 nm, focal contact formation was inhibited and the detachment

  16. Replacement solvents for use in chemical synthesis

    DOE Patents [OSTI]

    Molnar, Linda K. (Philadelphia, PA); Hatton, T. Alan (Sudbury, MA); Buchwald, Stephen L. (Newton, MA)

    2001-05-15

    Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.

  17. Photoresist substrate having robust adhesion

    DOE Patents [OSTI]

    Dentinger, Paul M. (Sunol, CA)

    2005-07-26

    A substrate material for LIGA applications w hose general composition is Ti/Cu/Ti/SiO.sub.2. The SiO.sub.2 is preferably applied to the Ti/Cu/Ti wafer as a sputtered coating, typically about 100 nm thick. This substrate composition provides improved adhesion for epoxy-based photoresist materials, and particularly the photoresist material SU-8.

  18. INTERFACE ADHESION: EFFECTS OF PLASTICITY AND SEGREGATION

    E-Print Network [OSTI]

    Hutchinson, John W.

    INTERFACE ADHESION: EFFECTS OF PLASTICITY AND SEGREGATION A. G. EVANS, J. W. HUTCHINSON{ and Y. WEIÐThe adhesion at interfaces between dissimilar materials is strongly aected by both segregation and the extent either by alloying with elements that ``getter'' the contaminants or by using an ``adhesion layer

  19. EFFECT OF MECHANICAL STRESS ON BACTERIAL ADHESION

    E-Print Network [OSTI]

    Ribot, Magali

    EFFECT OF MECHANICAL STRESS ON BACTERIAL ADHESION AND EARLY BIOFILM GROWTH Sigolène LECUYER-4. growth and maturation (h-days) 5. dispersion (days-months) #12;MECHANICAL STRESS DURING ADHESION stress can be transmitted: ·by the underlying substrate (adhesion, friction) time PART I PART II #12

  20. The Nanoscale Biophysics of Microscale Cell Adhesion

    E-Print Network [OSTI]

    Tees, David F.J.

    The Nanoscale Biophysics of Microscale Cell Adhesion David F. J. Tees, Ph.D. Department of Physics://www.phy.ohiou.edu/~tees/current_research.html #12;Outline 1) Adhesion molecules and review of cell-scale phenomena 2) Force dependence of reaction Appendix 2--Bell model Appendix 3--Reliability theory #12;Cell Adhesion: Microscale to Nanoscale Cell 1

  1. Adhesion of multicomponent vesicle membranes Yanxiang Zhao*

    E-Print Network [OSTI]

    Du, Qiang

    Adhesion of multicomponent vesicle membranes Yanxiang Zhao* Department of Mathematics, Pennsylvania 2010 In this work, we study the adhesion of multicomponent vesicle membrane to both flat and curved substrates, based on the conventional Helfrich bending energy for multicomponent vesicles and adhesion

  2. M, N -Adhesive Transformation Systems (Long Version)

    E-Print Network [OSTI]

    Habel, Annegret

    M, N -Adhesive Transformation Systems (Long Version) Annegret Habel1 and Detlef Plump2 1 Carl von.plump@york.ac.uk Draft: October 1, 2012 Abstract. The categorical framework of M-adhesive transformation systems does with graphs, however, and are commonly used in graph transformation languages. In this paper, we generalise M-adhesive

  3. Toposes are adhesive Stephen Lack1

    E-Print Network [OSTI]

    Sobocinski, Pawel

    Toposes are adhesive Stephen Lack1 and Pawel Soboci´nski2 1 School of Computing and Mathematics Abstract. Adhesive categories have recently been proposed as a cate- gorical foundation for facets for reason- ing about concurrency. Here we continue our study of adhesive categories by showing that toposes

  4. Cellulose Graft Copolymers for Potential Adhesive Applications

    E-Print Network [OSTI]

    Narayan, Ramani

    Chapter 24 Cellulose Graft Copolymers for Potential Adhesive Applications Bonding of Plastics interfacial adhesion between the wood and polystyrene components because of their inherent incompatibility, Corvallis, OR 97331 0097-6156/89/0385-0337$06.00/0 Q 1989 American Chemical Society #12;338 ADHESIVES FROM

  5. Multi-Amalgamation in Adhesive Categories

    E-Print Network [OSTI]

    Habel, Annegret

    Multi-Amalgamation in Adhesive Categories Ulrike Golas1 , Hartmut Ehrig1 , and Annegret Habel2 1 of amalgamation in this paper in the framework of adhesive categories for a bundle of rules with (nested) application conditions. In fact, it is also valid for weak adhesive HLR categories. The main result

  6. Aerosol collection characteristics of ambient aerosol samplers 

    E-Print Network [OSTI]

    Ortiz, Carlos A

    1978-01-01

    when the sampler is not in operation, both as functions of particle size and wind speed. Wind velocity was a major cause of bias for the four samplers when collecting aerosol particles & 10 um. Characteristic curves were very similar for the 0. 38 m... x 0. 38 m ( 15" x 15") Hi-Vol and the 0. 29 m x 0. 36 m (11&" x 14") Hi-Vol. At 28 um and wind speeds of 2, 8, and 24 km/hr, sampling effectiveness values respectively were 70, 43, and 43 percent for the 0. 38 m x 0. 38 m Hi-Vol and 81, 56, and 43...

  7. Requirements for a Dynamic Solvent Extraction Module to Support...

    Office of Scientific and Technical Information (OSTI)

    FUELS; PERFORMANCE; SAFEGUARDS; SAFETY; SECURITY; SIMULATION; SOLVENT EXTRACTION; SOLVENTS; WASTE FORMS dynamic; model; solvent extraction Word Cloud More Like This Full Text...

  8. SOLVENT EXTRACTION OF PHENOLS FROM WATER

    E-Print Network [OSTI]

    Greminger, Douglas C.

    2012-01-01

    Waste Water Treatment by Solvent Extraction," Canadian J.A.F. Preuss, "Extraction of Phenol from Water with a Liquid1980 SOLVENT EXTRACTION OF PHENOLS FROM WATER LP,WRENCE BERv

  9. Dipolar correlations in structured solvents under nanoconfinement

    E-Print Network [OSTI]

    Sahin Buyukdagli; Ralf Blossey

    2014-05-26

    We study electrostatic correlations in structured solvents confined to nanoscale systems. We derive variational equations of Netz-Orland type for a model liquid composed of finite size dipoles. These equations are solved for both dilute solvents and solvents at physiological concentrations in a slit nanopore geometry. Correlation effects are of major importance for the dielectric reduction and anisotropy of the solvent resulting from dipole image interactions and also lead to a reduction of van der Waals attractions between low dielectric bodies. Finally, by comparison with other recently developed self-consistent theories and experiments, we scrutinize the effect of solvent-membrane interactions on the differential capacitance of the charged liquid in contact with low dielectric substrates. The interfacial solvent depletion driven by solvent-image interactions plays the major role in the observed low values of the experimental capacitance data, while non-locality associated with the extended charge structure of solvent molecules only brings a minor contribution.

  10. Wash solvent reuse in paint production

    SciTech Connect (OSTI)

    Parsons, A.B.; Heater, K.J.; Olfenbuttel, R.F.

    1994-04-01

    The project evaluated solvent used to clean paint manufacture equipment for its utility in production of subsequent batches of solvent-borne paint. Reusing wash solvent would reduce the amount of solvent disposed of as waste. The evaluation of this wash-solvent recovery technology was conducted by Battelle Memorial Institute for the Pollution Prevention Research Branch of the U.S. Environmental Protection Agency. The evaluation was conducted with the cooperation and assistance of Vanex Color, Inc. The product quality, waste reduction/pollution prevention, and economic impacts of this technology change, as it has been implemented by Vanex, were examined. Two batches of a solvent-borne alkyd house paint were prepared at Vanex--one batch made with 100%-new solvent and the other with 30%-wash solvent--and sampled for laboratory analysis at Battelle.

  11. Solvent-induced forces in protein folding

    SciTech Connect (OSTI)

    Ben-Naim, A. (Hebrew Univ., Jerusalem (Israel))

    1990-08-23

    The solvent-induced forces between various groups on the protein are examined. It is found that the intramolecular hydrophilic forces are likely to be the strongest forces mediated through the solvent. It is argued that these are probably the most important solvent-induced driving forces in the process of protein folding.

  12. Solvent dramatically affects protein structure refinement

    E-Print Network [OSTI]

    Summa, Christopher M.

    Solvent dramatically affects protein structure refinement Gaurav Chopraa , Christopher M. Summab, fold and function in aqueous solution in vivo and in vitro. In this work, we study the role of solvent explicit and implicit solvent were performed on a set of 75 native proteins to test the various energy

  13. COMMUNICATION Phosphorylation Causes Subtle Changes in Solvent

    E-Print Network [OSTI]

    Komives, Elizabeth A.

    COMMUNICATION Phosphorylation Causes Subtle Changes in Solvent Accessibility at the Interdomain transiently phosphorylated enzyme with a lifetime of approximately two seconds. Solvent accessibility changes. No changes in solvent accessibility were seen in the regulatory domain upon phosphorylation of Asp56, but two

  14. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  15. Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V Form: February 2, 2006 We report the results of molecular dynamics simulations of the solvent of a positive reorganization entropy in polar solvents. The results of simulations are analyzed in terms

  16. sition from a localized solvent-bound ground state to the continuum of the solvent conduc-

    E-Print Network [OSTI]

    Wong, Joyce

    sition from a localized solvent-bound ground state to the continuum of the solvent conduc- tion species account for es in the immediate and solvent-separated contact pairs. The ET reaction being of two well-defined configurations, an immediate or solvent-separated contact pair. Both configura- tions

  17. Preferential Solvent Partitioning within Asphaltenic Aggregates Dissolved in Binary Solvent Mixtures

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Preferential Solvent Partitioning within Asphaltenic Aggregates Dissolved in Binary Solvent on asphaltenes from Hondo crude oil dissolved in binary solvent mixtures of toluene with n-heptane, decalin, or 1 data, and subsequent calculations of minimum error were performed to ascertain the entrained solvent

  18. Solvent cleaning system and method for removing contaminants from solvent used in resin recycling

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06

    A two step solvent and carbon dioxide based system that produces essentially contaminant-free synthetic resin material and which further includes a solvent cleaning system for periodically removing the contaminants from the solvent so that the solvent can be reused and the contaminants can be collected and safely discarded in an environmentally safe manner.

  19. Reciprocal-space solvent flattening

    SciTech Connect (OSTI)

    Terwilliger, Thomas C., E-mail: terwilliger@lanl.gov [Structural Biology Group, Mail Stop M888, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    1999-11-01

    A procedure is described for improvement of crystallographic phases by reciprocal-space maximization of a likelihood function including experimental phases and characteristics of the electron-density map. Solvent flattening is a powerful tool for improving crystallographic phases for macromolecular structures obtained at moderate resolution, but uncertainties in the optimal weighting of experimental phases and modified phases make it difficult to extract all the phase information possible. Solvent flattening is essentially an iterative method for maximizing a likelihood function which consists of (i) experimental phase information and (ii) information on the likelihood of various arrangements of electron density in a map, but the likelihood function is generally not explicitly defined. In this work, a procedure is described for reciprocal-space maximization of a likelihood function based on experimental phases and characteristics of the electron-density map. The procedure can readily be applied to phase improvement based on solvent flattening and can potentially incorporate information on a wide variety of other characteristics of the electron-density map.

  20. Maritime Aerosol Network as a component of Aerosol Robotic A. Smirnov,1,2

    E-Print Network [OSTI]

    Maritime Aerosol Network as a component of Aerosol Robotic Network A. Smirnov,1,2 B. N. Holben,2 I of the Maritime Aerosol Network (MAN), which has been developed as a component of the Aerosol Robotic Network), Maritime Aerosol Network as a component of Aerosol Robotic Network, J. Geophys. Res., 114, D06204, doi:10

  1. Batch extracting process using magneticparticle held solvents

    DOE Patents [OSTI]

    Nunez, Luis (Elmhurst, IL); Vandergrift, George F. (Bolingbrook, IL)

    1995-01-01

    A process for selectively removing metal values which may include catalytic values from a mixture containing same, wherein a magnetic particle is contacted with a liquid solvent which selectively dissolves the metal values to absorb the liquid solvent onto the magnetic particle. Thereafter the solvent-containing magnetic particles are contacted with a mixture containing the heavy metal values to transfer metal values into the solvent carried by the magnetic particles, and then magnetically separating the magnetic particles. Ion exchange resins may be used for selective solvents.

  2. SOLVENT DISPERSION AND FLOW METER CALCULATION RESULTS

    SciTech Connect (OSTI)

    Nash, C.; Fondeur, F.; Peters, T.

    2013-06-21

    Savannah River National Laboratory (SRNL) found that the dispersion numbers for the six combinations of CSSX:Next Generation Solvent (NGS) “blend” and pure NGS versus salt solution, caustic wash, and strip aqueous solutions are all good. The dispersion numbers are indications of processability with centrifugal contactors. A comparison of solvent physical and thermal properties shows that the Intek™ solvent flow meter in the plant has a reading biased high versus calibrated flow when NGS is used, versus the standard CSSX solvent. The flow meter, calibrated for CSSX solvent, is predicted to read 2.8 gpm of NGS in a case where the true flow of NGS is 2.16 gpm.

  3. J. Aerosol Sci. Vol. 31, No. 11, pp. 1283}1298, 2000 2000 Elsevier Science Ltd. All rights reserved

    E-Print Network [OSTI]

    methods are adapted for the production of aerosols of hematite ( -Fe O ), corundum ( -Al O ), mullite, which is the precursor solvent for mullite and silica, thermally decomposes to yield several gases-insoluble mineral dust. Common electrolytes are (NH ) SO and NH NO , which originate from anthropogenic energy

  4. Aerosol Observing System (AOS) Handbook

    SciTech Connect (OSTI)

    Jefferson, A

    2011-01-17

    The Aerosol Observing System (AOS) is a suite of in situ surface measurements of aerosol optical and cloud-forming properties. The instruments measure aerosol properties that influence the earth’s radiative balance. The primary optical measurements are those of the aerosol scattering and absorption coefficients as a function of particle size and radiation wavelength and cloud condensation nuclei (CCN) measurements as a function of percent supersaturation. Additional measurements include those of the particle number concentration and scattering hygroscopic growth. Aerosol optical measurements are useful for calculating parameters used in radiative forcing calculations such as the aerosol single-scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. CCN measurements are important in cloud microphysical models to predict droplet formation.

  5. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  6. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  7. VISCOELASTIC AND FATIGUE PROPERTIES OF DENTAL ADHESIVES AND THEIR IMPACT ON DENTIN-ADHESIVE INTERFACE DURABILITY

    E-Print Network [OSTI]

    Singh, Viraj

    2009-12-22

    The clinical performance of composite tooth restoration under cyclic loading is impacted by the behavior of the dentin-adhesive (d-a) interface, which is a complex construct of different material components. Dentin adhesive ...

  8. Electrostatic interactions in critical solvents

    E-Print Network [OSTI]

    Markus Bier; Andrea Gambassi; Martin Oettel; S. Dietrich

    2011-04-29

    The subtle interplay between critical phenomena and electrostatics is investigated by considering the effective force acting on two parallel walls confining a near-critical binary liquid mixture with added salt. The ion-solvent coupling can turn a non-critical repulsive electrostatic force into an attractive one upon approaching the critical point. However, the effective force is eventually dominated by the critical Casimir effect, the universal properties of which are not altered by the presence of salt. This observation allows a consistent interpretation of recent experimental data.

  9. Roles of discontinuities in bio-inspired adhesive pads

    E-Print Network [OSTI]

    Chaudhury, Manoj K.

    Roles of discontinuities in bio-inspired adhesive pads Jun Young Chung and Manoj K. Chaudhury adhesion to various surfaces. Motivated by the adhesive microstructures of insects, we examine the behaviour of adhesion and crack propagation in patterned adhesive films. These films are made of silicone

  10. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion...

  11. The Quaternary Structure of Amalgam, a Drosophila Neuronal Adhesion Protein, Explains Its Dual Adhesion Properties

    E-Print Network [OSTI]

    Sussman, Joel L.

    The Quaternary Structure of Amalgam, a Drosophila Neuronal Adhesion Protein, Explains Its Dual Adhesion Properties Tzviya Zeev-Ben-Mordehai, Efstratios Mylonas,{ Aviv Paz, Yoav Peleg,§ Lilly Toker) is a secreted neuronal adhesion protein that contains three tandem immunoglobulin domains. It has both

  12. A computational model for nanoscale adhesion between deformable solids and its application to gecko adhesion

    E-Print Network [OSTI]

    A computational model for nanoscale adhesion between deformable solids and its application to gecko adhesion Roger A. Sauer 1 Aachen Institute for Advanced Study in Computational Engineering Science (AICES), RWTH Aachen University, Templergaben 55, 52056 Aachen, Germany Published2 in the Journal of Adhesion

  13. P-8 / D. R. Cairns P-8: Conductive and Adhesive Properties of Z-axis Adhesives for Tail

    E-Print Network [OSTI]

    Cairns, Darran

    P-8 / D. R. Cairns P-8: Conductive and Adhesive Properties of Z-axis Adhesives for Tail Bonding Abstract The change in resistance of an anisotropic conducting adhesive (Z-axis adhesive) solderless joint ageing at 85° C and 85 % Relative humidity for six days. The anisotropic conducting adhesive performs

  14. Aerosol chemical vapor deposition of metal oxide films

    DOE Patents [OSTI]

    Ott, K.C.; Kodas, T.T.

    1994-01-11

    A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

  15. Adhesion Between Surfaces Separated by Molecularly Thin Perfluoropolyether Films

    E-Print Network [OSTI]

    Brunner, R.; Tyndall, G. W.; Waltman, R. J.; Talke, F. E.

    2010-01-01

    Etsion, I. , Bogy, D.B. : Adhesion of contacting roughof contact deformations on adhesion of particles. J. ColloidA 324, 301 7. Maugis, D. : Adhesion of spheres: the JKR-DMT

  16. Strong adhesion and cohesion of chitosan in aqueous solutions

    E-Print Network [OSTI]

    2013-01-01

    J. ; Waite, J. H. Adhesion mechanism in a DOPA-deficientof surface-roughness on adhesion of elastic solids. Proc. R.Zeng, H. B. ; Hwang, D. S. Adhesion of mussel foot proteins

  17. Cell–Matrix De-Adhesion Dynamics Reflect Contractile Mechanics

    E-Print Network [OSTI]

    Sen, Shamik; Kumar, Sanjay

    2009-01-01

    Sweeney, and D. E. Discher. Adhesion-contractile balance in1794–1806, 2004. Trypsin De-Adhesion and Cell Contractilityvinculin staining at focal adhesions was more intense and

  18. Interaction and Deformation of Viscoelastic Particles. 2. Adhesive Particles

    E-Print Network [OSTI]

    Attard, Phil

    Interaction and Deformation of Viscoelastic Particles. 2. Adhesive Particles Phil Attard Ian Wark, 2001. In Final Form: April 30, 2001 Analyzed is the mutual deformation of adhesive particles the particles' adhesion. An analytic

  19. Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Zhang, Sheng-Shui (Tucson, AZ); Xu, Kang (Tempe, AZ)

    1998-01-01

    The present invention relates to electrolyte solvents for use in liquid or rubbery electrolyte solutions. Specifically, this invention is directed to boron-containing electrolyte solvents and boron-containing electrolyte solutions.

  20. Adhesive Loose Packings of Small Particles

    E-Print Network [OSTI]

    Wenwei Liu; Shuiqing Li; Adrian Baule; Hernán A. Makse

    2014-10-08

    We explore adhesive loose packings of dry small spherical particles of micrometer size using 3D discrete-element simulations with adhesive contact mechanics. A dimensionless adhesion parameter ($Ad$) successfully combines the effects of particle velocities, sizes and the work of adhesion, identifying a universal regime of adhesive packings for $Ad>1$. The structural properties of the packings in this regime are well described by an ensemble approach based on a coarse-grained volume function that includes correlations between bulk and contact spheres. Our theoretical and numerical results predict: (i) An equation of state for adhesive loose packings that appears as a continuation from the frictionless random close packing (RCP) point in the jamming phase diagram; (ii) The existence of a maximal loose packing point at the coordination number $Z=2$ and packing fraction $\\phi=1/2^{3}$. Our results highlight that adhesion leads to a universal packing regime at packing fractions much smaller than the random loose packing, which can be described within a statistical mechanical framework. We present a general phase diagram of jammed matter comprising frictionless, frictional, adhesive as well as non-spherical particles, providing a classification of packings in terms of their continuation from the spherical frictionless RCP.

  1. Aerosol Observing System Upgraded

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TA I N P A T T E R N A NA LY S IDOE Office2 Aerosol

  2. Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness...

    Office of Scientific and Technical Information (OSTI)

    Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness of Carbon Based Biomaterials Citation Details In-Document Search Title: Enhanced Tissue Adhesion by Increased...

  3. Dynamics around solutes and solutesolvent complexes in mixed solvents

    E-Print Network [OSTI]

    Fayer, Michael D.

    Dynamics around solutes and solute­solvent complexes in mixed solvents Kyungwon Kwak, Sungnam Park-IR spectroscopy of the hydroxyl stretch of phenol-OD in three solvents, CCl4, mesitylene (1, 3, 5 trimethyl- benzene), and the mixed solvent of mesitylene and CCl4 (0.83 mole fraction CCl4), are used to study solute-solvent

  4. AERONET: The Aerosol Robotic Network

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    AERONET collaboration provides globally distributed observations of spectral aerosol optical Depth (AOD), inversion products, and precipitable water in diverse aerosol regimes. Aerosol optical depth data are computed for three data quality levels: Level 1.0 (unscreened), Level 1.5 (cloud-screened), and Level 2.0 (cloud screened and quality-assured). Inversions, precipitable water, and other AOD-dependent products are derived from these levels and may implement additional quality checks.[Copied from http://aeronet.gsfc.nasa.gov/new_web/system_descriptions.html

  5. eDPS Aerosol Collection

    SciTech Connect (OSTI)

    Venzie, J.

    2015-10-13

    The eDPS Aerosol Collection project studies the fundamental physics of electrostatic aerosol collection for national security applications. The interpretation of aerosol data requires understanding and correcting for biases introduced from particle genesis through collection and analysis. The research and development undertaken in this project provides the basis for both the statistical correction of existing equipment and techniques; as well as, the development of new collectors and analytical techniques designed to minimize unwanted biases while improving the efficiency of locating and measuring individual particles of interest.

  6. Adhesion of membranes via actively switched receptors

    E-Print Network [OSTI]

    Bartosz Rozycki; Reinhard Lipowsky; Thomas R. Weikl

    2005-12-20

    We consider a theoretical model for membranes with adhesive receptors, or stickers, that are actively switched between two conformational states. In their 'on'-state, the stickers bind to ligands in an apposing membrane, whereas they do not interact with the ligands in their 'off'-state. We show that the adhesiveness of the membranes depends sensitively on the rates of the conformational switching process. This dependence is reflected in a resonance at intermediate switching rates, which can lead to large membrane separations and unbinding. Our results may provide insights into novel mechanisms for the controlled adhesion of biological or biomimetic membranes.

  7. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-08-25

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  8. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-09-08

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  9. Method of making thermally removable adhesives

    DOE Patents [OSTI]

    Aubert, James H.

    2004-11-30

    A method of making a thermally-removable adhesive is provided where a bismaleimide compound, a monomeric furan compound, containing an oxirane group an amine curative are mixed together at an elevated temperature of greater than approximately 90.degree. C. to form a homogeneous solution, which, when cooled to less than approximately 70.degree. C., simultaneously initiates a Diels-Alder reaction between the furan and the bismaleimide and a epoxy curing reaction between the amine curative and the oxirane group to form a thermally-removable adhesive. Subsequent heating to a temperature greater than approximately 100.degree. C. causes the adhesive to melt and allows separation of adhered pieces.

  10. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

    1998-01-01

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

  11. CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION MODELING IN GROUNDWATER

    E-Print Network [OSTI]

    Boyer, Edmond

    CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION MODELING IN GROUNDWATER F. QUIOT1 , C.Goblet@ensmp.fr Keywords : numerical model, groundwater contamination, chlorinated solvents, natural atténuation atténuation models to predict transport and fate of chlorinated solvents in saturated groundwater Systems

  12. Biobriefcase electrostatic aerosol collector

    DOE Patents [OSTI]

    Bell, Perry M. (Tracy, CA); Christian, Allen T. (Madison, WI); Bailey, Christopher G. (Pleasanton, CA); Willis, Ladona (Manteca, CA); Masquelier, Donald A. (Tracy, CA); Nasarabadi, Shanavaz L. (Livermore, CA)

    2009-03-17

    A system for sampling air and collecting particles entrained in the air comprising a receiving surface, a liquid input that directs liquid to the receiving surface and produces a liquid surface, an air input that directs the air so that the air with particles entrained in the air impact the liquid surface, and an electrostatic contact connected to the liquid that imparts an electric charge to the liquid. The particles potentially including bioagents become captured in the liquid by the air with particles entrained in the air impacting the liquid surface. Collection efficiency is improved by the electrostatic contact electrically charging the liquid. The effects of impaction and adhesion due to electrically charging the liquid allows a unique combination in a particle capture medium that has a low fluid consumption rate while maintaining high efficiency.

  13. Stability of Adhesion Clusters under Constant Force T. Erdmann1

    E-Print Network [OSTI]

    Schwarz, Ulrich

    Stability of Adhesion Clusters under Constant Force T. Erdmann1 and U. S. Schwarz1,2 1 Max Planck. This effect might be used by cell-matrix adhesions to induce signaling events through cytoskeletal loading matrix and to each other through clusters of adhesion molecules. The number of receptors in adhesion

  14. Friction and Adhesion Hysteresis between Surfactant Monolayers in Water

    E-Print Network [OSTI]

    Klein, Jacob

    Friction and Adhesion Hysteresis between Surfactant Monolayers in Water Wuge H. Briscoe Physical friction between two surfaces in adhesive contact with the loading­unloading adhesion hysteresis between with a double-chained quaternary ammonium surfactant in intimate adhesive contact in water. This enables us

  15. Sliding induced adhesion of stiff polymer microfiber arrays

    E-Print Network [OSTI]

    Fearing, Ron

    Sliding induced adhesion of stiff polymer microfiber arrays: 2. Microscale behaviour By Bryan The adhesive pads of geckos provide control of normal adhesive force by con- trolling the applied shear force. This frictional adhesion effect is one of the key principles used for rapid detachment in animals running up

  16. A Lattice-Theoretical Perspective on Adhesive Categories

    E-Print Network [OSTI]

    Baldan, Paolo

    A Lattice-Theoretical Perspective on Adhesive Categories Paolo Baldan Dipartimento di Matematica Abstract It is a known fact that the subobjects of an object in an adhesive category form a distributive in an adhesive category, and we prove that any finite object of an adhesive category can be obtained

  17. Aerosol penetration through transport lines 

    E-Print Network [OSTI]

    Dileep, V.R.

    1996-01-01

    It is very important to minimize the losses in aerosol transport systems for the Continuous Air Monitors (CAM) to have a prompt and a meaningful alarm and the U.S. Environmental Protection Agency (EPA) also Currently mandates continuous emissions...

  18. Selective light sintering of Aerosol-Jet printed silver nanoparticle inks on polymer substrates

    SciTech Connect (OSTI)

    Schuetz, K., E-mail: klaus.schuetz1@gmx.de, E-mail: hoerber@faps.uni-erlangen.de, E-mail: franke@faps.uni-erlangen.de; Hoerber, J., E-mail: klaus.schuetz1@gmx.de, E-mail: hoerber@faps.uni-erlangen.de, E-mail: franke@faps.uni-erlangen.de; Franke, J., E-mail: klaus.schuetz1@gmx.de, E-mail: hoerber@faps.uni-erlangen.de, E-mail: franke@faps.uni-erlangen.de [Institute for Factory Automation and Production Systems, University of Erlangen-Nuremberg (Germany)

    2014-05-15

    Printing silver nanoparticle inks to generate conductive structures for electronics on polymer substrates has gained increasing relevance in recent years. In this context, the Aerosol-Jet Technology is well suited to print silver ink on 3D-Molded Interconnect Devices (MID). The deposited ink requires thermal post-treatment to obtain sufficient electrical conductivity and adhesion. However, commonly used oven sintering cannot be applied for many thermoplastic substrates due to low melting temperatures. In this study a new sintering technology, selective light sintering, is presented, based on the focused, continuous light beam of a xenon lamp. Sintering experiments were conducted with Aerosol-Jet printed structures on various polycarbonate (PC) substrates. Especially on neat, light transparent PC, silver tracks were evenly sintered with marginal impact to the substrate. Electrical conductivities significantly exceed the values obtained with conventional oven sintering. Adhesive strength is sufficient for conductive tracks. Experiments with non-transparent PC substrates led to substrate damage due to increased light absorption. Therefore a concept for a variation of light sintering was developed, using optical filters. First experiments showed significant reduction of substrate damage and good sintering qualities. The highly promising results of the conducted experiments provide a base for further investigations to increase adhesion and qualifying the technology for MID applications and a broad spectrum of thermoplastic substrates.

  19. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  20. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G; Eckert, Charles A; Liotta, Charles L; Heldebrant, David J

    2014-04-29

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  1. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G. (Kingston, CA); Eckert, Charles A. (Atlanta, GA); Liotta, Charles L. (Atlanta, GA); Heldebrant, David J. (Richland, WA)

    2011-07-19

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  2. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G.; Eckert, Charles A.; Liotta, Charles L.; Heldebrant, David J.

    2013-08-20

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  3. Mechanism of paint removing by organic solvents

    SciTech Connect (OSTI)

    Del Nero, V.; Siat, C.; Marti, M.J.; Aubry, J.M.; Lallier, J.P.; Dupuy, N.; Huvenne, J.P.

    1996-01-01

    The mechanism of paint removing has been studied by comparing the stripping efficiency of a given solvent with its ability to swell the film. The most effective solvents have a Hildebrand{close_quote}s parameter, {delta}{sub H}, ranging from 10.5 to 12 and a Dimroth parameter, ET{sub (30)}, ranging from 0.25 to 0.4. The synergy observed with the mixtures DMSO/non polar solvent is explained by a dissociation of the DMSO clusters into individual molecules which diffuse more easily. {copyright} {ital 1996 American Institute of Physics.}

  4. Test Plan for Solvent Extraction Data Acquisition to Support...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Test Plan for Solvent Extraction Data Acquisition to Support Modeling Efforts Citation Details In-Document Search Title: Test Plan for Solvent Extraction Data...

  5. Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Breakout Session 1-D: The Pitch Renewable,...

  6. A fresh look at the adhesion approximation

    E-Print Network [OSTI]

    Thomas Buchert

    1997-11-04

    I report on a systematic derivation of the phenomenological ``adhesion approximation'' from gravitational instability together with a brief evaluation of the related status of analytical modeling of large-scale structure.

  7. Molecular Adhesion between Cartilage Extracellular Matrix Macromolecules

    E-Print Network [OSTI]

    Rojas, Fredrick P.

    In this study, we investigated the molecular adhesion between the major constituents of cartilage extracellular matrix, namely, the highly negatively charged proteoglycan aggrecan and the type II/IX/XI fibrillar collagen ...

  8. Generic failure mechanisms in adhesive bonds

    E-Print Network [OSTI]

    Hass, Philipp; Niemz, Peter

    2015-01-01

    The failure of adhesive bondlines has been studied at the microscopic level via tensile tests. Stable crack propagation could be generated by means of samples with improved geometry, which made in-situ observations possible. The interaction of cracks with adhesive bondlines under various angles to the crack propagation was the focus of this study as well as the respective loading situations for the adhesives UF, PUR, and PVAc, which have distinctly different mechanical behaviors. It is shown how adhesive properties influence the occurrence of certain failure mechanisms and determine their appearance and order of magnitude. With the observed failure mechanisms, it becomes possible to predict the propagation path of a crack through the specimen.

  9. Nanomaterials from Aerosols Aerosols are suspensions of liquid or solid particles in a gas. Aerosol particles

    E-Print Network [OSTI]

    Beaucage, Gregory

    changes which are evidenced by changes in the temperature of the oceans and rapid melting of the polar and glacial ice packs. Of pollution sources, aerosols represent the least understood and could potentially

  10. Optimizing injected solvent fraction in stratified reservoirs 

    E-Print Network [OSTI]

    Moon, Gary Michael

    1993-01-01

    Waterflooding has become standard practice for extending the productive life of many solution gas drive reservoirs, but has the disadvantage of leaving a substantial residual oil volume in the reservoir. Solvent flooding has been offered as a...

  11. Brayton Solvent Recovery Heat Pump Technology Update 

    E-Print Network [OSTI]

    Enneking, J. C.

    1993-01-01

    The Brayton cycle technology was developed to reduce the temperature of gas streams containing solvents in order to condense and recover them. While the use of turbo compressor/expander machinery in conjunction with an energy recuperator...

  12. Accelerated solvent extraction of petroleum contaminated sediments 

    E-Print Network [OSTI]

    Bauguss, Jeffery Lynn

    1997-01-01

    Attempts have been made in recent years to find acceptable alternatives to classical soxhlet extraction of petroleum contaminated sediments. One such method that is very promising is accelerated solvent extraction also ...

  13. Advanced Water Removal via Membrane Solvent Extraction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Removal via Membrane Solvent Extraction Reduction in energy and water use for the ethanol industry Ethanol is the leading biofuel in the U.S. with 13 Billion gallons produced...

  14. Process for solvent refining of coal using a denitrogenated and dephenolated solvent

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1984-01-01

    A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

  15. Chemical and Physical Characteristics of Diesel Aerosol | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Physical Characteristics of Diesel Aerosol Chemical and Physical Characteristics of Diesel Aerosol 2002 DEER Conference Presentation: University of Minnesota...

  16. Optimization of a Solvent Extraction Desalination Plant 

    E-Print Network [OSTI]

    Beighle, Phillip Lew

    1969-01-01

    , a dynamic mathematical model was developed embodying the solvent extraction principles to find a set of flow rates and temper- atures consistent. with the specifications. The model was subjected to the physical restrictions normally associated... temperature, feed temperature, and feed rate, a set of feasible solutions was calculated. Another set of feasible solutions was then calculated using t. he previous set by allowing the solvent recycle temperature, product temperature, and steam rate...

  17. Method of stripping metals from organic solvents

    DOE Patents [OSTI]

    Todd, Terry A. (Aberdeen, ID); Law, Jack D. (Pocatello, ID); Herbst, R. Scott (Idaho Falls, ID); Romanovskiy, Valeriy N. (St. Petersburg, RU); Smirnov, Igor V. (St.-Petersburg, RU); Babain, Vasily A. (St-Petersburg, RU); Esimantovski, Vyatcheslav M. (St-Petersburg, RU)

    2009-02-24

    A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

  18. CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION

    SciTech Connect (OSTI)

    Fondeur, F.; Fink, S.

    2011-12-08

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

  19. Adhesive rough contacts near complete contact

    E-Print Network [OSTI]

    M. Ciavarella

    2015-05-01

    Recently, there has been some debate over the effect of adhesion on the contact of rough surfaces. Classical asperity theories predict, in agreement with experimental observations, that adhesion is always destroyed by roughness except if the amplitude of the same is extremely small, and the materials are particularly soft. This happens for all fractal dimensions. However, these theories are limited due to the geometrical simplification, which may be particularly strong in conditions near full contact. We introduce therefore a simple model for adhesion, which aims at being rigorous near full contact, where we postulate there are only small isolated gaps between the two bodies. The gaps can be considered as "pressurized cracks" by using Ken Johnson's idea of searching a corrective solution to the full contact solution. The solution is an extension of the adhesive-less solution proposed recently by Xu, Jackson, and Marghitu (XJM model) (2014). This process seems to confirm recent theories using the JKR theory, namely that the effect of adhesion depends critically on the fractal dimension. For D2.5, seems for large enough magnifications that a full fractal roughness completely destroys adhesion. These results are partly paradoxical since strong adhesion is not observed in nature except in special cases. A possible way out of the paradox may be that the conclusion is relevant for the near full contact regime, where the strong role of flaws at the interfaces, and of gaps full of contaminant, trapped air or liquid in pressure, needs to be further explored. If conditions near full contact are not achieved on loading, probably the conclusions of classical asperity theories may be confirmed.

  20. Junction adhesion molecule expression influences hematopoietic and endothelial commitment of murine embryonic stem cells

    E-Print Network [OSTI]

    Stankovich, Basha Lorraine

    2009-01-01

    OF CALIFORNIA, MERCED Junction Adhesion Molecule Expressionstem cells. Junction adhesion molecules influence cell fateBirchmeier W. Balancing cell adhesion and Wnt signaling, the

  1. Intercellular adhesion and pathfinding molecule T-cadherin in the development of the nervous system

    E-Print Network [OSTI]

    VanSteenhouse, Harper C.

    2007-01-01

    of homophilic cadherin adhesion. Biophys J 84:4033-4042.endocytosis terminates adhesion allowing contact mediatedDISSERTATION Intercellular Adhesion and Pathfinding Molecule

  2. Endothelial adhesion receptors are recruited to adherent leukocytes by inclusion in preformed tetraspanin nanoplatforms.

    E-Print Network [OSTI]

    2008-01-01

    PTPmu expression and cell-cell adhesion. J. Cell Biol. 163 :LFA- 1 – dependent adhesion. Proc. Natl. Acad. Sci. USA .1995 . Intercellular adhesion molecule-1 dimerization and

  3. Structural and functional biological materials : abalone nacre, sharp materials, and abalone foot adhesion

    E-Print Network [OSTI]

    Lin, Albert Yu-Min

    2008-01-01

    Abalone foot, underwater adhesion. Submitted Meyers MA, LinAbalone foot, underwater adhesion. Submitted 5) Meyers MA,to provide molecular adhesion. This is a mechanism which

  4. Integration of single-crystal devices with flexible substrates using conductive adhesive layers

    E-Print Network [OSTI]

    Doran, Christopher Kyle Gregory

    2011-01-01

    using conductive adhesives. ” Submitted for publication,mobility transistors using adhesive bonding. ” ElectronicSubstrates using Conductive Adhesive Layers by Christopher

  5. Adhesive activity of Lu glycoproteins is regulated by interaction with spectrin

    E-Print Network [OSTI]

    An, Xiuli

    2010-01-01

    and thereby generate a large adhesive force. Future proof ofAdhesive Activity of Lu Glycoproteins is Regulated bythe cytoskeleton regulates its adhesive receptor function.

  6. Asperity-scale surface mechanics - Implications to adhesive contacts and microscale deformation behavior of rough surfaces

    E-Print Network [OSTI]

    Xu, Huaming

    2012-01-01

    tip-sample wear under adhesive contact,” Tribol. Int. , 33,Kramer, E. J. , 1996, “Adhesive contact of cylindrical lensof an Elastic–Plastic Adhesive Spherical Microcontact,” J.

  7. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01

    address: Center for Atmospheric Chemistry Study, Departmenttween phytoplankton, atmospheric chemistry, and climate areno. 12 ? 4601– 4605 CHEMISTRY Atmospheric aerosol deposition

  8. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  9. Real time infrared aerosol analyzer

    DOE Patents [OSTI]

    Johnson, Stanley A. (Countryside, IL); Reedy, Gerald T. (Bourbonnais, IL); Kumar, Romesh (Naperville, IL)

    1990-01-01

    Apparatus for analyzing aerosols in essentially real time includes a virtual impactor which separates coarse particles from fine and ultrafine particles in an aerosol sample. The coarse and ultrafine particles are captured in PTFE filters, and the fine particles impact onto an internal light reflection element. The composition and quantity of the particles on the PTFE filter and on the internal reflection element are measured by alternately passing infrared light through the filter and the internal light reflection element, and analyzing the light through infrared spectrophotometry to identify the particles in the sample.

  10. Simple Model of Membrane Proteins Including Solvent

    E-Print Network [OSTI]

    D. L. Pagan; A. Shiryayev; T. P. Connor; J. D. Gunton

    2006-03-04

    We report a numerical simulation for the phase diagram of a simple two dimensional model, similar to one proposed by Noro and Frenkel [J. Chem. Phys. \\textbf{114}, 2477 (2001)] for membrane proteins, but one that includes the role of the solvent. We first use Gibbs ensemble Monte Caro simulations to determine the phase behavior of particles interacting via a square-well potential in two dimensions for various values of the interaction range. A phenomenological model for the solute-solvent interactions is then studied to understand how the fluid-fluid coexistence curve is modified by solute-solvent interactions. It is shown that such a model can yield systems with liquid-liquid phase separation curves that have both upper and lower critical points, as well as closed loop phase diagrams, as is the case with the corresponding three dimensional model.

  11. Method of measuring metal coating adhesion

    DOE Patents [OSTI]

    Roper, John R. (Northglenn, CO)

    1985-01-01

    A method for measuring metal coating adhesion to a substrate material comprising the steps of preparing a test coupon of substrate material having the metal coating applied to one surface thereof, applying a second metal coating of gold or silver to opposite surfaces of the test coupon by hot hollow cathode process, applying a coating to one end of each of two pulling rod members, joining the coated ends of the pulling rod members to said opposite coated surfaces of the test coupon by a solid state bonding technique and finally applying instrumented static tensile loading to the pulling rod members until fracture of the metal coating adhesion to the substrate material occurs.

  12. Wrapping an adhesive sphere with a sheet

    E-Print Network [OSTI]

    J. Hure; B. Roman; J. Bico

    2011-03-25

    We study the adhesion of an elastic sheet on a rigid spherical substrate. Gauss'Theorema Egregium shows that this operation necessarily generates metric distortions (i.e. stretching) as well as bending. As a result, a large variety of contact patterns ranging from simple disks to complex branched shapes are observed as a function of both geometrical and material properties. We describe these different morphologies as a function of two non-dimensional parameters comparing respectively bending and stretching energies to adhesion. A complete configuration diagram is finally proposed.

  13. Solvent-resistant microporous polymide membranes

    DOE Patents [OSTI]

    Miller, Warren K. (Bend, OR); McCray, Scott B. (Bend, OR); Friesen, Dwayne T. (Bend, OR)

    1998-01-01

    An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

  14. Solvent-resistant microporous polymide membranes

    DOE Patents [OSTI]

    Miller, W.K.; McCray, S.B.; Friesen, D.T.

    1998-03-10

    An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

  15. Catalog solvent extraction: anticipate process adjustments

    SciTech Connect (OSTI)

    Campbell, S.G.; Brass, E.A.; Brown, S.J.; Geeting, M.W.

    2008-07-01

    The Modular Caustic-Side Solvent Extraction Unit (MCU) utilizes commercially available centrifugal contactors to facilitate removal of radioactive cesium from highly alkaline salt solutions. During the fabrication of the contactor assembly, demonstrations revealed a higher propensity for foaming than was initially expected. A task team performed a series of single-phase experiments that revealed that the shape of the bottom vanes and the outer diameter of those vanes are key to the successful deployment of commercial contactors in the Caustic-Side Solvent Extraction Process. (authors)

  16. Computational optimization of adhesive microstructures based on a nonlinear beam formulation

    E-Print Network [OSTI]

    Computational optimization of adhesive microstructures based on a nonlinear beam formulation Janine computational shape optimization of adhesive microstructures. Adhesion is described by van der Waals the shape of gecko spatulae. Keywords: shape optimization, peeling strips, gecko adhesion, computational

  17. A controllably adhesive climbing robot using magnetorheological fluid

    E-Print Network [OSTI]

    Wiltsie, Nicholas Eric

    2012-01-01

    In this thesis, the novel adhesive effects of magnetorheological fluid for use in climbing robotics were experimentally measured and compared to existing cohesive failure fluid models of yield stress adhesion. These models ...

  18. Stratospheric Albedo Modification by Aerosol Injection

    E-Print Network [OSTI]

    Katz, J I

    2009-01-01

    This paper reviews and develops the proposal, widely discussed but not examined in detail, to use stratospheric aerosols to increase the Earth's albedo to Solar radiation in order to control climate change. The potential of this method has been demonstrated by the "natural experiments" of volcanic injection of sulfate aerosols into the stratosphere that led to subsequent observed global cooling. I consider several hygroscopic oxides as possible aerosol materials in addition to oxides of sulfur. Aerosol chemistry, dispersion and transport have been the subject of little study and are not understood, representing a significant scientific risk. Even the optimal altitude of injection and aerosol size distribution are poorly known. Past attention focused on guns and airplanes as means of lofting aerosols or their chemical precursors, but large sounding rockets are cheap, energetically efficient, can be designed to inject aerosols at any required altitude, and involve little technical risk. Sophisticated, mass-opti...

  19. Stratospheric Aerosol Geoengineering ALAN ROBOCK

    E-Print Network [OSTI]

    Robock, Alan

    hydrologic responses, whitening of the skies, reduction of solar power, and impacts of diffuse radiation Project, conducting climate model experiments with standard stratospheric aerosol in- jection scenarios, which stated that ``It is extremely likely that human in- fluence has been the dominant cause

  20. How do liquids confined at the nanoscale influence adhesion?

    E-Print Network [OSTI]

    C. Yang; U. Tartaglino; B. N. J. Persson

    2006-12-06

    Liquids play an important role in adhesion and sliding friction. They behave as lubricants in human bodies especially in the joints. However, in many biological attachment systems they acts like adhesives, e.g. facilitating insects to move on ceilings or vertical walls. Here we use molecular dynamics to study how liquids confined at the nanoscale influence the adhesion between solid bodies with smooth and rough surfaces. We show that a monolayer of liquid may strongly affect the adhesion.

  1. Method for making adhesive from biomass

    DOE Patents [OSTI]

    Russell, J.A.; Riemath, W.F.

    1984-03-30

    A method is described for making adhesive from biomass. A liquefaction oil is prepared from lignin-bearing plant material and a phenolic fraction is extracted therefrom. The phenolic fraction is reacted with formaldehyde to yield a phenol-formaldehyde resin. 2 figures.

  2. Cell adhesion receptors in C. elegans

    E-Print Network [OSTI]

    Hardin, Jeff

    EAT-20 (H30A04.1) N P I E V; CB NLR-1 (F20B10.1) PDZ BD 1722 aa 810 aa 1560 aa 1620 aa 1193 aa Crumbs-1 cytoplasmic domain binds catenins and promotes the formation of adherens-junction-like adhesions

  3. An Adhesion Model for the Drag Force

    E-Print Network [OSTI]

    Dan Comanescu

    2008-01-28

    The paper present a model for the drag force between a resistive medium and a solid body using the hypothesis that the drag force is created by the adhesion of some particles of the resistive medium on the solid body's surface. The study focus on the mass evolution of the solid body.

  4. Method for making adhesive from biomass

    DOE Patents [OSTI]

    Russell, Janet A. (Richland, WA); Riemath, William F. (Pasco, WA)

    1985-01-01

    A method is described for making adhesive from biomass. A liquefaction oil is prepared from lignin-bearing plant material and a phenolic fraction is extracted therefrom. The phenolic fraction is reacted with formaldehyde to yield a phenol-formaldehyde resin.

  5. Cell Adhesion Mechanisms and Elasto-Viscoplastic Mechanics of Tumours

    E-Print Network [OSTI]

    Preziosi, Luigi

    Cell Adhesion Mechanisms and Elasto-Viscoplastic Mechanics of Tumours D. Ambrosi, L. Preziosi and deform while binding each other thanks to adhesion molecules exerting forces of measurable strength. In this paper it is illus- trated a macroscopic mechanical model of solid tumour which takes such adhesion

  6. Adhesion Science: Recent Developments and Prospects Wednesday September 15, 2010

    E-Print Network [OSTI]

    Fisher, Frank

    Adhesion Science: Recent Developments and Prospects Wednesday September 15, 2010 Babbio 122, NOON Dr. Kash Mittal Editor-in-Chief, Journal of Adhesion Science and Technology The phenomenon of adhesion is of crucial importance in many nanotechnology areas (e.g., MEMS/NEMS devices, microfluidics, Lab

  7. Introduction Adhesion complexes play key roles in many events, including

    E-Print Network [OSTI]

    Hardin, Jeff

    Introduction Adhesion complexes play key roles in many events, including cell migration cell adhesion are remarkably similar in Caenorhabditis elegans, Drosophila and humans (Hynes and Zhao to reveal much about the basic, conserved molecular mechanisms that mediate and regulate cell adhesion

  8. Adhesion and cohesion in structures containing suspended microscopic polymeric films

    E-Print Network [OSTI]

    Shan, Wanliang

    Adhesion and cohesion in structures containing suspended microscopic polymeric films W.L. Shan a 2011 Accepted 12 December 2011 Available online 16 December 2011 Keywords: Adhesive strength Cohesive presents a novel technique for the characterization of adhesion and cohesion in suspended micro

  9. How Focal Adhesion Size Depends on Integrin Affinity Tong Zhao,,

    E-Print Network [OSTI]

    Dinner, Aaron

    How Focal Adhesion Size Depends on Integrin Affinity Tong Zhao,, Ying Li,, and Aaron R. Dinner the thermodynamics and kinetics of integrin receptor binding and clustering impact the formation of focal adhesions in their environment. Cells on chemically well-defined surfaces were observed to have distributions of focal adhesions

  10. Adhesion at Poly(Butylacrylate)Poly(Dimethylsiloxane) Nicolas Amouroux

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    Adhesion at Poly(Butylacrylate)­Poly(Dimethylsiloxane) Interfaces Nicolas Amouroux ARKEMA K. K of the adhesion modulation mechanisms of silica-like nanoparticles (MQ resins) incorporated in polydimethylsiloxane (PDMS) elasto- mers and acrylic adhesives. The Johnson-Kendall-Roberts (JKR) test has been used

  11. Introduction Cell adhesion to the extracellular matrix (ECM) plays multiple

    E-Print Network [OSTI]

    Zaidel-Bar, Ronen

    Introduction Cell adhesion to the extracellular matrix (ECM) plays multiple roles in the regulation of cell behavior and fate. In most adhesion sites, integrin receptors mediate the binding to the ECM via; Martin et al., 2002). The intracellular domain of integrin- mediated adhesions contains a large number

  12. Sliding induced adhesion of stiff polymer microfiber arrays

    E-Print Network [OSTI]

    Fearing, Ron

    Sliding induced adhesion of stiff polymer microfiber arrays: 1. Macroscale behaviour By Jongho Lee1 favorable conformations. Keywords: bio-inspired adhesion, gecko, friction, shear, sliding 1. Introduction structures. The gecko's keratin fiber arrays form a unique attach- ment mechanism which is non-adhesive

  13. Metallic adhesion and tunnelling at the atomic A Schirmeisen1

    E-Print Network [OSTI]

    Grütter, Peter

    Metallic adhesion and tunnelling at the atomic scale A Schirmeisen1 , G Cross1 , A Stalder1 , P Gr scaling parameter of = 0.2 nm. We conclude that not only the apex atoms contribute to the adhesion forces are discussed. The study of metallic adhesion on the atomic scale lays the foundation for the understanding

  14. Adhesion and reinforcement in carbon nanotube polymer composite Chenyu Weia

    E-Print Network [OSTI]

    Wei, Chenyu

    Adhesion and reinforcement in carbon nanotube polymer composite Chenyu Weia NASA Ames Research; published online 28 February 2006 Temperature dependent adhesion behavior and reinforcement in carbon investigated as multifunctional materials for electric and thermal applications.6­8 The adhesion behavior

  15. Thermal effects in adhesive contact: modelling and analysis Elena Bonetti

    E-Print Network [OSTI]

    Rossi, Riccarda

    Thermal effects in adhesive contact: modelling and analysis Elena Bonetti , Giovanna Bonfanti , Riccarda Rossi Abstract In this paper, we consider a contact problem with adhesion between a viscoelastic equations, describing the evolution of the temperatures of the body and of the adhesive material. Our main

  16. M, N -Adhesive Transformation Systems Annegret Habel1

    E-Print Network [OSTI]

    Habel, Annegret

    M, N -Adhesive Transformation Systems Annegret Habel1 and Detlef Plump2 1 Carl von Ossietzky.plump@york.ac.uk Abstract. The categorical framework of M-adhesive transformation systems does not cover graph, and are commonly used in graph transformation languages. In this paper, we gen- eralise M-adhesive transformation

  17. Neutrophil and endothelial adhesive function during human fetal ontogeny

    E-Print Network [OSTI]

    von Andrian, Ulrich H.

    Neutrophil and endothelial adhesive function during human fetal ontogeny Claudia Nussbaum,* Anna of gesta- tion with respect to rolling and adhesive functions. With the use of microflow chambers, we. These adhesion-related abil- ities are very rare in extremely premature infants ( 30 weeks of gestation), which

  18. Adhesive contact delaminating at mixed mode, its thermodynamics and analysis

    E-Print Network [OSTI]

    Rossi, Riccarda

    Adhesive contact delaminating at mixed mode, its thermodynamics and analysis Riccarda Rossi.roubicek@mff.cuni.cz Abstract An adhesive unilateral contact problem between visco-elastic heat-conductive bodies in lin- ear Kelvin-Voigt rheology is scrutinised. The flow-rule for debonding the adhesive is considered rate

  19. Processes for Adhesive Rewriting Systems Paolo Baldan1

    E-Print Network [OSTI]

    Sobocinski, Pawel

    Processes for Adhesive Rewriting Systems Paolo Baldan1 , Andrea Corradini2 , Tobias Heindel3 Abstract. Rewriting systems over adhesive categories have been re- cently introduced as a general framework semantics for adhesive rewriting sys- tems by defining the fundamental notion of process, well-known from

  20. Unfolding Grammars in Adhesive Categories Paolo Baldan1

    E-Print Network [OSTI]

    Baldan, Paolo

    Unfolding Grammars in Adhesive Categories Paolo Baldan1 , Andrea Corradini2 , Tobias Heindel3 adhesive categories. The unfolding construction is characterized as a coreflection, i.e. the unfolding in adhesive categories with "well-behaved" colimits of -chains of monomorphisms. Compared to previous work

  1. Tearing Graphene Sheets From Adhesive Substrates Produces Tapered Nanoribbons

    E-Print Network [OSTI]

    Reis, Pedro Miguel

    Thin films Tearing Graphene Sheets From Adhesive Substrates Produces Tapered Nanoribbons Dipanjan from adhesive substrates is reported, including the discovery of the formation of tapered graphene that the resulting nanoribbon geometry is controlled by both the graphene­substrate adhesion energy and by the number

  2. Short Communication Similarity considerations in adhesive contact problems

    E-Print Network [OSTI]

    Awtar, Shorya

    Short Communication Similarity considerations in adhesive contact problems J.R. Barber n Department online 4 July 2013 Keywords: Adhesion van der Waal's forces Similarity JKR theory a b s t r a c of the adhesive force law. & 2013 Elsevier Ltd. All rights reserved. 1. Introduction Contact problems involving

  3. Abstract True Concurrency: Adhesive Processes Paolo Baldan1

    E-Print Network [OSTI]

    Baldan, Paolo

    Abstract True Concurrency: Adhesive Processes Paolo Baldan1 , Andrea Corradini2 , Tobias Heindel3 Abstract. Rewriting systems over adhesive categories have been re- cently introduced as a general framework semantics for adhesive rewriting sys- tems by defining the fundamental notion of process, well-known from

  4. Adhesive Categories Stephen Lack1 and Pawel Sobocinski2

    E-Print Network [OSTI]

    Sobocinski, Pawel

    Adhesive Categories Stephen Lack1 and Pawel Soboci´nski2 1 School of Quantitative Methods. We introduce adhesive categories, which are categories with structure ensuring that pushouts along on arbitrary adhesive categories. Introduction Recently there has been renewed interest in reasoning using

  5. Adhesivity is not enough: Local Church-Rosser revisited

    E-Print Network [OSTI]

    Baldan, Paolo

    Adhesivity is not enough: Local Church-Rosser revisited Paolo Baldan1 , Fabio Gadducci2 , and Pawel Abstract. Adhesive categories provide an abstract setting for the double- pushout approach to rewriting, including the local Church-Rosser theorem, can be proven in adhesive categories, provided that one restricts

  6. Adhesive High-Level Replacement Categories and Systems

    E-Print Network [OSTI]

    Habel, Annegret

    Adhesive High-Level Replacement Categories and Systems Hartmut Ehrig1 , Annegret Habel2 , Julia.habel@informatik.uni-oldenburg.de Abstract. Adhesive high-level replacement (HLR) categories and sys- tems are introduced as a new of HLR systems with the new concept of adhesive categories introduced by Lack and Soboci

  7. Development of methods to quantify bitumen-aggregate adhesion and loss of adhesion due to water 

    E-Print Network [OSTI]

    Bhasin, Amit

    2007-09-17

    reasons. The objective of this research is to develop experimental and analytical tools to characterize important material properties that influence the moisture sensitivity of asphalt mixes. Quality of adhesion between the aggregate and bitumen binder...

  8. Yielding and flow in adhesive and non-adhesive concentrated emulsions

    E-Print Network [OSTI]

    L. Becu; S. Manneville; A. Colin

    2006-03-07

    The nonlinear rheological response of soft glassy materials is addressed experimentally by focusing on concentrated emulsions where interdroplet attraction is tuned through varying the surfactant content. Velocity profiles are recorded using ultrasonic velocimetry simultaneously to global rheological data in the Couette geometry. Our data show that non-adhesive and adhesive emulsions have radically different flow behaviors in the vicinity of yielding: while the flow remains homogeneous in the non-adhesive emulsion and the Herschel-Bulkley model for a yield stress fluid describes the data very accurately, the adhesive system displays shear localization and does not follow a simple constitutive equation, suggesting that the mechanisms involved in yielding transitions are not universal.

  9. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

    1989-01-01

    There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

  10. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1989-04-25

    There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

  11. Solvent treatment of coal for improved liquefaction

    DOE Patents [OSTI]

    Appell, Herbert R. (Pitcairn, PA); Narain, Nand K. (Bethel Park, PA); Utz, Bruce R. (Pittsburgh, PA)

    1986-05-06

    Increased liquefaction yield is obtained by pretreating a slurry of solid carbonaceous material and a liquid hydrocarbonaceous solvent at a temperature above 200.degree. C. but below 350.degree. C. for a period of 10 minutes to four hours prior to exposure to liquefaction temperatures.

  12. DO AEROSOLS CHANGE CLOUD COVER AND AFFECT CLIMATE?

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    IN MEXICO CITY BASIN Light scattering by aerosols decreases absorption of solar radiation. #12;AEROSOLS;AEROSOL INFLUENCES ON CLIMATE AND CLIMATE CHANGE #12;DMS #12;AEROSOL IN MEXICO CITY BASIN #12;AEROSOL AS SEEN FROM SPACE Fire plumes from southern Mexico transported north into Gulf of Mexico. #12;CLOUD

  13. ROSE Process Offers Energy Savings for Solvent Extraction 

    E-Print Network [OSTI]

    Gearheart, J. A.; Nelson, S. R.

    1983-01-01

    Kerr-McGee has developed and commercialized an energy-efficient solvent extraction process known as ROSE (Residuum Oil Supercritical Extraction) in which the extraction solvent is recovered as a supercritical fluid. The energy requirement...

  14. Construction of prototype system for directional solvent extraction desalination

    E-Print Network [OSTI]

    Fowler, Michael James

    2012-01-01

    Directional solvent extraction has been demonstrated as a low temperature, membrane free desalination process. This method dissolves the water into an inexpensive, benign directional solvent, rejects the contaminants, then ...

  15. Integrating Safety Issues in Optimizing Solvent Selection and Process Design 

    E-Print Network [OSTI]

    Patel, Suhani Jitendra

    2011-10-21

    Incorporating consideration for safety issues while designing solvent processes has become crucial in light of the chemical process incidents involving solvents that have taken place in recent years. The implementation of inherently safer design...

  16. The Role of Solvent Heterogeneity in Determining the Dispersion...

    Office of Scientific and Technical Information (OSTI)

    density resonse of a solvent to a surface in conjunction with the Clausius-Mossotti equation, we present a simple theory relating the discrete nature of solvent to dispersion...

  17. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06

    of this research is to examine sea salt aerosols and their impact on polluted environments. Sea salt aerosols act as Cloud Condensation Nuclei (CCN) as well as providing a surface for heterogeneous reactions. Such reactions have implications for trace gases...

  18. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1986-01-01

    A process for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal.

  19. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, D.; Givens, E.N.; Schweighardt, F.K.

    1986-12-09

    A process is described for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal. 2 figs.

  20. How to use Solvent Purification System A brief manual

    E-Print Network [OSTI]

    d'Alarcao, Marc

    1 How to use Solvent Purification System A brief manual By V. Azev. SPS (Figure 1) can be used to collect dry oxygen free solvents into two different types of containers. One of them is a syringe. Syringes are filled with a solvent in a usual manner using a septum port on the flask (Figure 2

  1. Solvent structure and hydrodynamic effects in photoinduced electron transfer

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent structure and hydrodynamic effects in photoinduced electron transfer S. F. Swallen, Kristin to account for realistic finite-volume solvent effects. This work introduces physically important effects caused by the solvent which fundamentally affect the rates and spatial distribution of charge transfer

  2. Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems

    E-Print Network [OSTI]

    Tisseur, Francoise

    Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems Peter Lancaster and Fran ISSN 1749-9097 #12;Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems$ Peter with prescribed spectral data (eigenvalues and eigenvectors) it is natural to prescribe a right solvent

  3. PROCEEDINGS Open Access Building Markov state models with solvent

    E-Print Network [OSTI]

    Guibas, Leonidas J.

    PROCEEDINGS Open Access Building Markov state models with solvent dynamics Chen Gu1 , Huang timescale dynamics. However, the solvent information in molecular simulations are often ignored in current methods, because of the large number of solvent molecules in a system and the indistinguishability

  4. Solvent Accessibility of the Thrombin-thrombomodulin Interface

    E-Print Network [OSTI]

    Komives, Elizabeth A.

    Solvent Accessibility of the Thrombin- thrombomodulin Interface Jeffrey G. Mandell1 , Abel Baerga Characterization RIKEN 2-1 Hirosawa, Wako, Saitama 351-01, Japan The kinetics of solvent accessibility exchange due to solvent accessibility at the interface from H/2 H exchange due to complex dissociation

  5. Aerosol Science and Technology, 43:641652, 2009 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 43:641­652, 2009 Copyright © American Association for Aerosol Differential Mobility Analyzer for Measurement of the Irreversibility of the Hygroscopic Growth Factor T is the irreversibility of the hygroscopic growth fac- tor of aerosol particles. The instrument uses the hysteresis

  6. Shortwave aerosol radiative forcing over cloud-free oceans from Terra: 1. Angular models for aerosols

    E-Print Network [OSTI]

    Christopher, Sundar A.

    Sensor Microwave Imager (SSM/I) data to obtain near surface wind speed. The new aerosol ADMs are built to obtain aerosol properties within a Clouds and Earth Radiant Energy System (CERES) footprint and Special as functions of near-surface ocean wind speed and MODIS aerosol optical depth at 0.55 mm (t0.55). Among the new

  7. Adhesive joint and composites modeling in SIERRA.

    SciTech Connect (OSTI)

    Ohashi, Yuki; Brown, Arthur A.; Hammerand, Daniel Carl; Adolf, Douglas Brian; Chambers, Robert S.; Foulk, James W., III

    2005-11-01

    Polymers and fiber-reinforced polymer matrix composites play an important role in many Defense Program applications. Recently an advanced nonlinear viscoelastic model for polymers has been developed and incorporated into ADAGIO, Sandia's SIERRA-based quasi-static analysis code. Standard linear elastic shell and continuum models for fiber-reinforced polymer-matrix composites have also been added to ADAGIO. This report details the use of these models for advanced adhesive joint and composites simulations carried out as part of an Advanced Simulation and Computing Advanced Deployment (ASC AD) project. More specifically, the thermo-mechanical response of an adhesive joint when loaded during repeated thermal cycling is simulated, the response of some composite rings under internal pressurization is calculated, and the performance of a composite container subjected to internal pressurization, thermal loading, and distributed mechanical loading is determined. Finally, general comparisons between the continuum and shell element approaches for modeling composites using ADAGIO are given.

  8. Production of biodiesel using expanded gas solvents

    SciTech Connect (OSTI)

    Ginosar, Daniel M; Fox, Robert V; Petkovic, Lucia M

    2009-04-07

    A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

  9. Alternative solvents/technologies for paint stripping

    SciTech Connect (OSTI)

    Tsang, M.N.; Harris, T.L.

    1990-01-01

    Paint stripping is a necessary part of maintenance at US Air Force Air Logistics Centers. The Waste from Air Force paint stripping operations contains toxic chemicals that require special handling and disposal at considerable cost. Solvent emissions of volatile organic compounds (VOCs) into the atmosphere are another source of pollution. These wastes are hazardous to the environment and to operating personnel, and are now regulated by the US Environmental Protection Agency, which can impose fines for discharges that exceed the established limits. This report describes the research project titled Alternative Solvents/Technologies for Paint Stripping being conducted by the Idaho National Engineering Laboratory for the Engineering and Services Center at Tyndall Air Force Base. This report also includes the results obtained in Phase 1. 8 refs., 3 tabs.

  10. Researchers Model Impact of Aerosols Over California

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Aerosols Over California Research may clarify the effectiveness of regional pollution controls May 28, 2013 | Tags: Climate Research, Hopper Contact: Linda Vu,...

  11. Aerosol Retrieval Using Remote-sensed Observations

    E-Print Network [OSTI]

    Wang, Yueqing

    2012-01-01

    4.1.2 Baltimore and the DRAGONaround Baltimore . . . . . . . . . . . . . . . . . . . 4.1.4component aerosol 1 for Baltimore-Washington region on June

  12. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    they can have either cooling or warming effects. Lighter-colored organic carbon particles cool regions of the planet by scattering sunlight back into space. Other aerosol particles...

  13. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth...

  14. Contact electrification and the work of adhesion

    E-Print Network [OSTI]

    B. N. J. Persson; M. Scaraggi; A. I. Volokitin

    2013-05-13

    We present a general theory for the contribution from contact electrification to the work necessary to separate two solid bodies. The theory depends on the surface charge density correlation function, which we deduce from Kelvin Force Microscopy (KFM) maps of the surface electrostatic potential. For silicon rubber (polydimethylsiloxane, PDMS) we discuss in detail the relative importance of the different contributions to the observed work of adhesion.

  15. Solvent extraction of Southern US tar sands

    SciTech Connect (OSTI)

    Penney, W.R.

    1990-01-01

    The Department of Chemical Engineering at the University of Arkansas, in association with Diversified Petroleum Recovery, Inc. (DPR) of Little Rock, Arkansas, has been developing a solvent extraction process for the recovery of bitumen from tar sands for the past five years. The unique feature of the process is that the bitumen is recovered from the solvent by contacting with a co-solvent, which causes the bitumen to precipitate. The overall purpose of this project is to study both the technical and economic feasibility of applying this technology for recovery of bitumen from tar sands by (1) investigating the socioeconmic factors which affect (a) plant siting and (b) the market value of recovered bitumen; (2) operating a process demonstration unit at the rate of 1 lb/hr recovered bitumen while producing clean sand and recyclable solvents; and (3) determine the economic conditions which will make a bitumen recovery project economical. DPR has analyzed the historical trends of domestic production, consumption, discoveries and reserves of crude oil. They have started an investigation of the volatility in the price of crude oil and of gasoline prices and of the differential between gasoline and crude oil. DPR continues to analyze the geographical movement and demand for asphalt products. Utah does not appear economically attractive as a site for a bitumen from tar sands asphalt plant. Oklahoma sites are now being studied. This report also contains the quarterly progress report from a University of Nevada study to determine bitumen composition, oxygen uptake rates, and viscosities of Alabama and Utah bitumens. Both reports have been indexed separately for inclusion on the data base.

  16. Contact lines for fluid surface adhesion

    E-Print Network [OSTI]

    Markus Deserno; Martin M. Mueller; Jemal Guven

    2007-03-01

    When a fluid surface adheres to a substrate, the location of the contact line adjusts in order to minimize the overall energy. This adhesion balance implies boundary conditions which depend on the characteristic surface deformation energies. We develop a general geometrical framework within which these conditions can be systematically derived. We treat both adhesion to a rigid substrate as well as adhesion between two fluid surfaces, and illustrate our general results for several important Hamiltonians involving both curvature and curvature gradients. Some of these have previously been studied using very different techniques, others are to our knowledge new. What becomes clear in our approach is that, except for capillary phenomena, these boundary conditions are not the manifestation of a local force balance, even if the concept of surface stress is properly generalized. Hamiltonians containing higher order surface derivatives are not just sensitive to boundary translations but also notice changes in slope or even curvature. Both the necessity and the functional form of the corresponding additional contributions follow readily from our treatment.

  17. A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents Peter Vath and Matthew B. Zimmt* Department of Chemistry, Brown ReceiVed: February 9, 1999; In Final Form: April 26, 1999 The temperature dependence of the solvent

  18. Extending the physicochemical characterization of aerosol particles in California

    E-Print Network [OSTI]

    Zauscher, Melanie Dorothy

    2012-01-01

    Combustion Aerosol, Atmospheric Chemistry and Physics, 11 (Based Receptor Modeling, Atmospheric Chemistry and Physics,Aerosols, Journal of Atmospheric Chemistry, 22 (1-2), 19-39.

  19. Building America Webinar: Sealing of Home Enclosures with Aerosol...

    Energy Savers [EERE]

    Sealing of Home Enclosures with Aerosol Particles Building America Webinar: Sealing of Home Enclosures with Aerosol Particles This webinar was presented by research team Building...

  20. The Indirect and Semi-Direct Aerosol Campaign

    SciTech Connect (OSTI)

    Ghan, Steve

    2014-03-24

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  1. ARM - Field Campaign - Aerosol and Cloud Experiments in the Eastern...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    horizontal variabilities of aerosol, trace gases, cloud, drizzle, and atmospheric thermodynamics are critically needed for understanding and quantifying the budget of MBL aerosol,...

  2. The Indirect and Semi-Direct Aerosol Campaign

    ScienceCinema (OSTI)

    Ghan, Steve

    2014-06-12

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  3. High performance low cost interconnections for flip chip attachment with electrically conductive adhesive. Final report

    SciTech Connect (OSTI)

    NONE

    1998-05-01

    This final report is a compilation of final reports from each of the groups participating in the program. The main three groups involved in this effort are the Thomas J. Watson Research Center of IBM Corporation in Yorktown Heights, New York, Assembly Process Design of IBM Corporation in Endicott, New York, and SMT Laboratory of Universal Instruments Corporation in Binghamton, New York. The group at the research center focused on the conductive adhesive materials development and characterization. The group in process development focused on processing of the Polymer-Metal-Solvent Paste (PMSP) to form conductive adhesive bumps, formation of the Polymer-Metal Composite (PMC) on semiconductor devices and study of the bonding process to circuitized organic carriers, and the long term durability and reliability of joints formed using the process. The group at Universal Instruments focused on development of an equipment set and bonding parameters for the equipment to produce bond assembly tooling. Reports of each of these individual groups are presented here reviewing their technical efforts and achievements.

  4. Batch extracting process using magnetic particle held solvents

    DOE Patents [OSTI]

    Nunez, L.; Vandergrift, G.F.

    1995-11-21

    A process is described for selectively removing metal values which may include catalytic values from a mixture containing same, wherein a magnetic particle is contacted with a liquid solvent which selectively dissolves the metal values to absorb the liquid solvent onto the magnetic particle. Thereafter the solvent-containing magnetic particles are contacted with a mixture containing the heavy metal values to transfer metal values into the solvent carried by the magnetic particles, and then magnetically separating the magnetic particles. Ion exchange resins may be used for selective solvents. 5 figs.

  5. An Effective Solvent Theory Connecting the Underlying Mechanisms of Osmolytes and Denaturants for Protein Stability

    E-Print Network [OSTI]

    Plotkin, Steven S.

    An Effective Solvent Theory Connecting the Underlying Mechanisms of Osmolytes and Denaturants solvent, using a single, contact-based interaction energy between protein and solvent particles or repulsive. A statistical mechanical equiv- alence is demonstrated between this effective solvent model

  6. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, J.M.; Simandl, R.F.; Thompson, L.M.

    1993-05-04

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140 F and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140 F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  7. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, John M. (Oak Ridge, TN); Simandl, Ronald F. (Farragut, TN); Thompson, Lisa M. (Knoxville, TN)

    1993-01-01

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140.degree. F. and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140.degree. F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  8. Demixing of colloid-polymer mixtures in poor solvents

    E-Print Network [OSTI]

    Matthias Schmidt; Alan R. Denton

    2002-04-15

    The influence of poor solvent quality on fluid demixing of a model mixture of colloids and nonadsorbing polymers is investigated using density functional theory. The colloidal particles are modelled as hard spheres and the polymer coils as effective interpenetrating spheres that have hard interactions with the colloids. The solvent is modelled as a two-component mixture of a primary solvent, regarded as a background theta-solvent for the polymer, and a cosolvent of point particles that are excluded from both colloids and polymers. Cosolvent exclusion favors overlap of polymers, mimicking the effect of a poor solvent by inducing an effective attraction between polymers. For this model, a geometry-based density functional theory is derived and applied to bulk fluid phase behavior. With increasing cosolvent concentration (worsening solvent quality), the predicted colloid-polymer binodal shifts to lower colloid concentrations, promoting demixing. For sufficiently poor solvent, a reentrant demixing transition is predicted at low colloid concentrations.

  9. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  10. THE INFLUENCE OF CURRENT ON THE ADHESIVE POTENTIAL, DENSITY AND ABUNDANCE OF THE MAGNIFICENT SEA ANEMONE (HETERACTIS MAGNIFICA) IN MO’OREA, FRENCH POLYNESIA

    E-Print Network [OSTI]

    Lewis, Caroline A Ms.

    2012-01-01

    INFLUENCE OF CURRENT ON THE ADHESIVE POTENTIAL, DENSITY ANDeffects of current on the adhesive potential were observed,adhesiveness To estimate the adhesive force of the anemones,

  11. Carbonaceous Aerosol Study Using Advanced Particle Instrumentation

    E-Print Network [OSTI]

    Qi, Li

    2010-01-01

    6 6.1 Introduction Biomass combustion emissions contributeEmissions of trace gases and aerosols during the open combustion of biomassbiomass burning work explored the evolution of organic aerosol emissions as a function of modified combustion efficiency with correlations drawn between levoglucosan emissions

  12. Optimal Estimation Retrieval Aerosol Microphysical Properties

    E-Print Network [OSTI]

    Oxford, University of

    ) the validation of this algorithm on the basis of synthetic extinction data, and (3) application of the new algorithm to SAGE II measurements of stratospheric background aerosol. The validation results indicate that the new method is able to retrieve the particle size of typical background aerosols reasonably well

  13. Atmospheric aerosol light scattering and polarization peculiarities

    E-Print Network [OSTI]

    Patlashenko, Zh I

    2015-01-01

    This paper considers environmental problems of natural and anthropogenic atmospheric aerosol pollution and its global and regional monitoring. Efficient aerosol investigations may be achieved by spectropolarimetric measurements. Specifically second and fourth Stokes parameters spectral dependencies carry information on averaged refraction and absorption indexes and on particles size distribution functions characteristics.

  14. Adhesive flexible barrier film, method of forming same, and organic electronic device including same

    DOE Patents [OSTI]

    Blizzard, John Donald; Weidner, William Kenneth

    2013-02-05

    An adhesive flexible barrier film comprises a substrate and a barrier layer disposed on the substrate. The barrier layer is formed from a barrier composition comprising an organosilicon compound. The adhesive flexible barrier film also comprises an adhesive layer disposed on the barrier layer and formed from an adhesive composition. A method of forming the adhesive flexible barrier film comprises the steps of disposing the barrier composition on the substrate to form the barrier layer, disposing the adhesive composition on the barrier layer to form the adhesive layer, and curing the barrier layer and the adhesive layer. The adhesive flexible barrier film may be utilized in organic electronic devices.

  15. AEROSOL PARTICLE COLLECTOR DESIGN STUDY

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2007-09-27

    A computational evaluation of a particle collector design was performed to evaluate the behavior of aerosol particles in a fast flowing gas stream. The objective of the work was to improve the collection efficiency of the device while maintaining a minimum specified air throughput, nominal collector size, and minimal power requirements. The impact of a range of parameters was considered subject to constraints on gas flow rate, overall collector dimensions, and power limitations. Potential improvements were identified, some of which have already been implemented. Other more complex changes were identified and are described here for further consideration. In addition, fruitful areas for further study are proposed.

  16. ARM Cloud Aerosol Precipitation Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation Data Management Facility PlotsProducts (VAP) VAP38 ARM6Aerosol

  17. A thermally responsive, rigid, and reversible adhesive Xiaofan Luo, Kathryn E. Lauber 1

    E-Print Network [OSTI]

    Mather, Patrick T.

    A thermally responsive, rigid, and reversible adhesive Xiaofan Luo, Kathryn E. Lauber 1 , Patrick T: Reversible adhesive Solid adhesive Thermally responsive polymer a b s t r a c t In this paper we present the development of a unique self-adhesive material that, unlike conventional adhesives, maintains a high degree

  18. Polymer Translocation Induced by a Bad Solvent

    E-Print Network [OSTI]

    Christopher Lorscher; Tapio Ala-Nissila; Aniket Bhattacharya

    2010-06-08

    We employ 3D Langevin Dynamics simulations to study the dynamics of polymer chains translocating through a nanopore in presence of asymmetric solvent conditions. Initially a large fraction ($>$ 50%) of the chain is placed at the \\textit{cis} side in a good solvent while the $trans$ segments are placed in a bad solvent that causes the chain to collapse and promotes translocation from the $cis$ to the $trans$ side. In particular, we study the ratcheting effect of a globule formed at the \\textit{trans} side created by the translocated segment, and how this ratchet drives the system towards faster translocation. Unlike in the case of unbiased or externally forced translocation where the mean first passage time $\\langle \\tau \\rangle $ is often characterized by algebraic scaling as a function of the chain length $N$ with a single scaling exponent $\\alpha$, and the histogram of the mean first passage time $P(\\tau/\\langle\\tau \\rangle)$ exhibits scaling, we find that scaling is not well obeyed. For relatively long chains we find $\\langle \\tau \\rangle \\sim N^\\alpha$ where $\\alpha \\approx 1$ for $\\varepsilon/k_{B}T > 1$. In this limit, we also find that translocation proceeds with a nearly constant velocity of the individual beads(monomers), which is attributed to the coiling of the globule. We provide an approximate theory assuming rotat ional motion restricted on a 2D disc to demonstrate that there is a crossover from diffusive behavior of the center of mass for short chains to a single file translocation for long chains, where the average translocation time scales linearly with the chain length $N$.

  19. Scenarios Evaluation Tool for Chlorinated Solvent MNA

    SciTech Connect (OSTI)

    Vangelas, Karen; Michael J. Truex; Charles J. Newell; Brian Looney

    2007-02-28

    Over the past three decades, much progress has been made in the remediation of chlorinated solvents from the subsurface. Yet these pervasive contaminants continue to present a significant challenge to the U.S. Department of Energy (DOE), other federal agencies, and other public and private organizations. The physical and chemical properties of chlorinated solvents make it difficult to rapidly reach the low concentrations typically set as regulatory limits. These technical challenges often result in high costs and long remediation time frames. In 2003, the DOE through the Office of Environmental Management funded a science-based technical project that uses the U.S. Environmental Protection Agency's technical protocol (EPA, 1998) and directives (EPA, 1999) on Monitored Natural Attenuation (MNA) as the foundation on which to introduce supporting concepts and new scientific developments that will support remediation of chlorinated solvents based on natural attenuation processes. This project supports the direction in which many site owners want to move to complete the remediation of their site(s), that being to complete the active treatment portion of the remedial effort and transition into MNA. The overarching objective of the effort was to examine environmental remedies that are based on natural processes--remedies such as Monitored Natural Attenuation (MNA) or Enhanced Attenuation (EA). The research program did identify several specific opportunities for advances based on: (1) mass balance as the central framework for attenuation based remedies, (2) scientific advancements and achievements during the past ten years, (3) regulatory and policy development and real-world experience using MNA, and (4) exploration of various ideas for integrating attenuation remedies into a systematic set of ''combined remedies'' for contaminated sites. These opportunities are summarized herein and are addressed in more detail in referenced project documents and journal articles, as well as in the technical and regulatory documents being developed within the ITRC.

  20. Inverse determination of effective mechanical properties of adhesive bondlines

    E-Print Network [OSTI]

    Hass, Philipp; Mendoza, Miller; Herrmann, Hans J; Niemz, Peter

    2015-01-01

    A new approach for determining effective mechanical bondline properties using a combined experimental-numerical modal analysis technique is proposed. After characterizing clear spruce wood boards, an adhesive layer is applied to the boards surfaces. The shift of the eigenfrequencies resulting from the adhesive layer together with information on the bondline geometry can then be used to inversely determine the mechanical properties of the adhesive layer using Finite Element Models. The calculated values for clear wood as well as for the adhesive layer lie within reasonable ranges, thus demonstrating the methods potential.

  1. NELL-1 regulates BMSC osteogenic and adipogenic differentiation by interacting with Integrin and regulating cell focal adhesion

    E-Print Network [OSTI]

    Chung, Jong Uk

    2012-01-01

    D, Schlaepfer D. Focal adhesion kinase: in command andTamura Y, et al. Focal adhesion kinase activity is requiredmotility and enhanced focal adhesion contact formation in

  2. Myosin II activity dependent and independent vinculin recruitment to the sites of E-cadherin mediated cell-cell adhesion

    E-Print Network [OSTI]

    Sumida, Grant M; Tomita, Tyler M; Shih, Wenting; Yamada, Soichiro

    2011-01-01

    site and the C-terminal focal adhesion targeting sequence inactivation at sites of cell adhesion. Nature 2004, 430(C: Vinculin controls focal adhesion formation by direct

  3. The inflammatory response in transgastric surgery: gastric content leak leads to localized inflammatory response and higher adhesive disease

    E-Print Network [OSTI]

    2010-01-01

    response and higher adhesive disease Sonia L. Ramamoorthy Æin?ammatory markers, adhesive disease, and morbidity.cantly higher rate of adhesive disease in the SG compared

  4. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  5. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  6. Stability of adhesion clusters under constant force

    E-Print Network [OSTI]

    T. Erdmann; U. S. Schwarz

    2004-01-27

    We solve the stochastic equations for a cluster of parallel bonds with shared constant loading, rebinding and the completely dissociated state as an absorbing boundary. In the small force regime, cluster lifetime grows only logarithmically with bond number for weak rebinding, but exponentially for strong rebinding. Therefore rebinding is essential to ensure physiological lifetimes. The number of bonds decays exponentially with time for most cases, but in the intermediate force regime, a small increase in loading can lead to much faster decay. This effect might be used by cell-matrix adhesions to induce signaling events through cytoskeletal loading.

  7. AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS

    E-Print Network [OSTI]

    Graaf, Martin de

    AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS M. de Graaf, L.G. Tilstra information has become available from active space-based sensors and some dedicated field campaigns on aerosol-absorption, is the Absorbing Aerosol Index (AAI), which can indicate absorbing aerosols overlying clouds. The AAI is available

  8. INVESTIGATION OF PLUTONIUM AND URANIUM UPTAKE INTO MCU SOLVENT AND NEXT GENERATION SOLVENT

    SciTech Connect (OSTI)

    Peters, T.; Fink, S.

    2012-01-06

    At the request of the Savannah River Remediation (SRR) customer, the Savannah River National Laboratory (SRNL) examined the plutonium (Pu) and uranium (U) uptake into the Next Generation Solvent (NGS) that will be used at the Salt Waste Processing Facility (SWPF). SRNL examined archived samples of solvent used in Extraction-Scrub-Strip (ESS) tests, as well as samples from new tests designed explicitly to examine the Pu and U uptake. Direct radiocounting for Pu and U provided the best results. Using the radiocounting results, we found that in all cases there were <3.41E-12 g Pu/g of NGS and <1.17E-05 g U/g of NGS in multiple samples, even after extended contact times and high aqueous:organic volume phase ratios. These values are conservative as they do not allow for release or removal of the actinides by scrub, strip, or solvent wash processes. The values do not account for extended use or any increase that may occur due to radiolytic damage of the solvent.

  9. NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2011-09-29

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

  10. Non-Ideal Behavior in Solvent Extraction

    SciTech Connect (OSTI)

    Peter Zalupski

    2011-09-01

    This report presents a summary of the work performed to meet FCR&D level 3 milestone M31SW050801, 'Complete the year-end report summarizing FY11 experimental and modeling activities.' This work was carried out under the auspices of the Non-Ideality in Solvent Extraction Systems FCR&D work package. The report summarizes our initial considerations of potential influences that non-ideal chemistry may impose on computational prediction of outcomes in solvent extraction systems. The report is packaged into three separate test cases where a robustness of the prediction by SXFIT program is under scrutiny. The computational exercises presented here emphasize the importance of accurate representation of both an aqueous and organic mixtures when modeling liquid-liquid distribution systems. Case No.1 demonstrates that non-ideal behavior of HDEHP in aliphatic diluents, such as n-dodecane, interferes with the computation. Cases No.2 and No.3 focus on the chemical complexity of aqueous electrolyte mixtures. Both exercises stress the need for an improved thermodynamic model of an aqueous environment present in the europium distribution experiments. Our efforts for year 2 of this project will focus on the improvements of aqueous and non-aqueous solution models using fundamental physical properties of mixtures acquired experimentally in our laboratories.

  11. Solvent-extraction purification of neptunium

    SciTech Connect (OSTI)

    Kyser, E.A.; Hudlow, S.L.

    2008-07-01

    The Savannah River Site (SRS) has recovered {sup 237}Np from reactor fuel that is currently being processed into NpO{sub 2} for future production of {sup 238}Pu. Several purification flowsheets have been utilized. An oxidizing solvent-extraction (SX) flowsheet was used to remove Fe, sulfate ion, and Th while simultaneously {sup 237}Np, {sup 238}Pu, u, and nonradioactive Ce(IV) was extracted into the tributyl phosphate (TBP) based organic solvent. A reducing SX flowsheet (second pass) removed the Ce and Pu and recovered both Np and U. The oxidizing flowsheet was necessary for solutions that contained excessive amounts of sulfate ion. Anion exchange was used to perform final purification of Np from Pu, U, and various non-actinide impurities. The Np(IV) in the purified solution was then oxalate-precipitated and calcined to an oxide for shipment to other facilities for storage and future target fabrication. Performance details of the SX purification and process difficulties are discussed. (authors)

  12. Acid gas scrubbing by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1988-04-12

    A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorus and sulfur, and having a boiling point of at least 100 C and a solubility parameter of from about 7.5 to about 13.5 (cal/cm[sup 3]-atm)[sup 1/2]. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes. 3 figs.

  13. Method for destroying halocarbon compositions using a critical solvent

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Janikowski, Stuart K.

    2006-01-10

    A method for destroying halocarbons. Halocarbon materials are reacted in a dehalogenation process wherein they are combined with a solvent in the presence of a catalyst. A hydrogen-containing solvent is preferred which functions as both a solvating agent and hydrogen donor. To augment the hydrogen donation capacity of the solvent if needed (or when non-hydrogen-containing solvents are used), a supplemental hydrogen donor composition may be employed. In operation, at least one of the temperature and pressure of the solvent is maintained near, at, or above a critical level. For example, the solvent may be in (1) a supercritical state; (2) a state where one of the temperature or pressure thereof is at or above critical; or (3) a state where at least one of the temperature and pressure thereof is near-critical. This system provides numerous benefits including improved reaction rates, efficiency, and versatility.

  14. Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME, SCIAMACHY, and GOME-2

    E-Print Network [OSTI]

    Tilstra, Gijsbert

    Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME the resulting time series, we use tropospheric NO2 data as a reference in the regions dominated by biomass sensitive to desert dust aerosols (DDA) and biomass burning aerosols (BBA). See Figure 1. The AAI

  15. Adhesives and method for making the same

    DOE Patents [OSTI]

    Dorsey, George F. (Farragut, TN)

    1991-01-01

    A thermosetting mixture for use as an adhesive, as well as other applications, that is substantially nonmutagenic. This mixture is based upon a thermosetting resin selected from polyurethane and epoxy resins, using an improved curing agent that does not contain mutagenic components. Specifically, the curing agent is a multi-mixture of substituted alkylanilines produced by an improved process. These alkylanilines are formed by condensation of at least two 2,6-dialkylanilines with a formaldehyde in an acid solution. Upon purification, at least three aromatic diamines are formed that are used for the curing agent with the polyurethane and epoxy resisn. Pot life, green strength and ultimate strength are comparable to adhesives of the prior art that contain mutagenic constituents. Although several dianilines are described, the preferred curing agents are formed using 2,6-diethylaniline (DEA) and 2,6-diisopropylaniline (DIPA), where the mole % of DEA and DIPA is 38-48 and 62-52, respectively. Curing agents within the preferred range have been designated as "Asilamine 4852" and "Asilamine 4555".

  16. Alcohols as hydrogen-donor solvents for treatment of coal

    DOE Patents [OSTI]

    Ross, David S. (Palo Alto, CA); Blessing, James E. (Menlo Park, CA)

    1981-01-01

    A method for the hydroconversion of coal by solvent treatment at elevated temperatures and pressure wherein an alcohol having an .alpha.-hydrogen atom, particularly a secondary alcohol such as isopropanol, is utilized as a hydrogen donor solvent. In a particular embodiment, a base capable of providing a catalytically effective amount of the corresponding alcoholate anion under the solvent treatment conditions is added to catalyze the alcohol-coal reaction.

  17. Solvent and Process for Recovery of Hydroxide from Aqueous Mixtures

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Chambliss, C. Kevin; Bonnesen, Peter V.; Keever, Tamara J.

    1999-09-13

    Hydroxide values and associated alkali metal may be recovered from alkaline aqueous solutions using classes of fluorinated alcohols in a water immiscible solvent. The alcohols are characterized by fluorine substituents which are proximal to the acidic alcohol protons and are located to adjust the acidity of the extractant and the solubility of the extractant in the solvent. A method for stripping the extractant and solvent to regenerate the extractant and purified aqueous hydroxide solution is described.

  18. Solvent and process for recovery of hydroxide from aqueous mixtures

    DOE Patents [OSTI]

    Moyer, Bruce A. (Oak Ridge, TN); Chambliss, C. Kevin (Macon, GA); Bonnesen, Peter V. (Knoxville, TN); Keever, Tamara J. (Oak Ridge, TN)

    2001-01-01

    Hydroxide values and associated alkali metal may be recovered from alkaline aqueous solutions using classes of fluorinated alcohols in a water immiscible solvent. The alcohols are characterized by fluorine substituents which are proximal to the acidic alcohol protons and are located to adjust the acidity of the extractant and the solubility of the extractant in the solvent. A method for stripping the extractant and solvent to regenerate the extractant and purified aqueous hydroxide solution is described.

  19. Bridging adhesion of mussel-inspired peptides: Role of charge, chain length, and surface type

    E-Print Network [OSTI]

    2015-01-01

    J. N. ; Waite, J. H. Adhesion of mussel foot protein Mefp-5Waite, J. H. Mussel protein adhesion depends on interproteinDOPA to substrate-peptide adhesion and internal cohesion of

  20. Cell Adhesion on Polyelectrolyte Multilayer Coated Polydimethylsiloxane Surfaces with Varying Topographies

    E-Print Network [OSTI]

    Lee, Ilsoon

    Cell Adhesion on Polyelectrolyte Multilayer Coated Polydimethylsiloxane Surfaces with Varying to the pattern size and pitch influences cell adhesion and proliferation. Extensive research has shown substrate for cell ad- hesion. To improve adhesion, we built polyelectrolyte multilayers (PEMs) on PDMS

  1. Contact Mechanics Modeling of Homogeneous and Layered Elastic-Plastic Media: Surface Roughness and Adhesion Effects

    E-Print Network [OSTI]

    Song, Zhichao

    2012-01-01

    Greenwood, J.A. , 1997. Adhesion of elastic spheres. Proc.to the Maugis model of adhesion between elastic spheres. J.determination of interfacial adhesion properties by wedge

  2. Ultrastructure and Histochemistry of the Adhesive Breeding Glands in Male Gastrophryne carolinensis

    E-Print Network [OSTI]

    Sever, David M.

    Ultrastructure and Histochemistry of the Adhesive Breeding Glands in Male Gastrophryne carolinensis. Chabarria2 The histology, histochemistry, and ultrastructure of the adhesive breeding glands of male Gastrophryne carolinensis are described. Adhesive glands are mutlicellular exocrine glands in the dermis

  3. Biomechanical Testing Of An Adhesive Polymer Intended For The Treatment Of Retinal Detachment

    E-Print Network [OSTI]

    Kerr, Mayuri

    2014-01-01

    of cyanoacrylate tissue adhesive in the rabbit. ,” Retina,and M. F. Marmor, “Retinal adhesive force in living rabbit,effects of retinal adhesive force in vivo. ,” Retina, vol.

  4. Bridging adhesion of mussel-inspired peptides: Role of charge, chain length, and surface type

    E-Print Network [OSTI]

    2015-01-01

    immobilization of cell adhesive peptide onto TiO 2 substrateMessersmith, P. B. Mussel adhesive protein mimetic polymersJ. H. Mussel-inspired adhesives and coatings. Annu. Rev.

  5. CARES: Carbonaceous Aerosol and Radiative Effects Study Science Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-05-27

    Carbonaceous aerosol components, which include black carbon (BC), urban primary organic aerosols (POA), biomass burning aerosols, and secondary organic aerosols (SOA) from both urban and biogenic precursors, have been previously shown to play a major role in the direct and indirect radiative forcing of climate. The primary objective of the CARES 2010 intensive field study is to investigate the evolution of carbonaceous aerosols of different types and their effects on optical and cloud formation properties.

  6. Vacuum pyrolyzed tire oil as a coal solvent

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Y.; Ji, Q.

    1995-12-31

    Coal liquefaction is highly dependent upon the type of coal liquefaction solvent used. The solvent must readily solubilize the coal and must act as an effective hydrogen donor or shuttler. Oil derived from the vacuum pyrolysis of used rubber tires has recently been used as a coal solvent with good conversion of coal to liquids in a hydrogen atmosphere. All experiments were completed in shaken tubing reactors at 450{degrees}C utilizing a bituminous coal. Results show the effectiveness of the pyrolyzed tire oil as a coal liquefaction solvent depends upon hydrogen pressure. Electron probe microanalysis data reveal good dispersion of the molybdenum catalyst in coal particles taken from liquefaction experiments.

  7. Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers

    Broader source: Energy.gov [DOE]

    Breakout Session 1-D: The Pitch Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Len Rand, Chief Executive Officer, Chairman, xF Technologies

  8. The Air or Brayton Cycle Solvent Recovery System 

    E-Print Network [OSTI]

    Fox, B. J.

    1986-01-01

    it suitable for solvent recovery. Thi s unit util i zes ai r foil beari ngs. to recover the heat for useful purposes. It is easy Over the past several years they have sold. these for the air cycle system to return the solvent lean uni ts to condense... CYCLE SOLVENT RECOVERY SYSTEM Bryce J. Fox 3M Company St. Paul, ABSTRACT The required temperature and technique for condensing common industrial solvents from the exhaust air of drying ovens is explained. ?:The benefits of the Air Cycle...

  9. Recovery of sugars from ionic liquid biomass liquor by solvent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Recovery of sugars from ionic liquid biomass liquor by solvent extraction Citation Details In-Document Search Title: Recovery of sugars from ionic liquid biomass liquor by...

  10. Substrata Mechanical Stiffness Can Regulate Adhesion of Viable Bacteria

    E-Print Network [OSTI]

    Van Vliet, Krystyn J.

    Substrata Mechanical Stiffness Can Regulate Adhesion of Viable Bacteria Jenny A. Lichter,, M. Todd, 2008 The competing mechanisms that regulate adhesion of bacteria to surfaces and subsequent biofilm and hospital-acquired infections due to bacteria, there is considerable interest in better understanding

  11. Effects of Surface Properties on Adhesion of Protein to Biomaterials 

    E-Print Network [OSTI]

    Feng, Fangzhou

    2011-10-21

    of implants. The present research evaluates and analyzes the adhesive strength of proteins on pure High Density Polyethylene (HDPE), Single Wall Carbon Nanotube (SWCNT) enhanced HDPE composites, Ti-C:H coating and Ti6Al4V alloys (grade 2). The adhesive...

  12. Adhesion of benzocyclobutene-passivated silicon in epoxy layered structures

    E-Print Network [OSTI]

    Hutchinson, John W.

    to interface surface energies using contact angle and contact mechanics measurements may produce adhesion as a function of applied G. Adhesion and subcritical debonding were affected by changes in interfacial chemistry different epoxy underfill resins. The effects of environmental variables were studied with temperature

  13. Adhesion layer for etching of tracks in nuclear trackable materials

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Contolini, Robert J. (Lake Oswego, OR)

    2001-01-01

    A method for forming nuclear tracks having a width on the order of 100-200 nm in nuclear trackable materials, such as polycarbonate (LEXAN) without causing delamination of the LEXAN. The method utilizes an adhesion film having a inert oxide which allows the track to be sufficiently widened to >200 nm without delamination of the nuclear trackable materials. The adhesion film may be composed of a metal such as Cr, Ni, Au, Pt, or Ti, or composed of a dielectric having a stable surface, such as silicon dioxide (SiO.sub.2), silicon nitride (SiN.sub.x), and aluminum oxide (AlO). The adhesion film can either be deposited on top of the gate metal layer, or if the properties of the adhesion film are adequate, it can be used as the gate layer. Deposition of the adhesion film is achieved by standard techniques, such as sputtering or evaporation.

  14. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  15. Asimetrias de Informacion y Analisis Economico de los Contratos de Adhesion

    E-Print Network [OSTI]

    Salazar, Diego F.

    2006-01-01

    1983). Contracts of Adhesion: An Essay in Reconstruction.1985). Los contratos por adhesión: problemas y soluciones.Rakoff. Contracts of Adhesion: An Essay in Reconstruction.

  16. Lipid Membrane Adhesion and Fusion Driven by Designed, Minimally Multivalent Hydrogen-Bonding Lipids

    E-Print Network [OSTI]

    Bong, Dennis

    Lipid Membrane Adhesion and Fusion Driven by Designed, Minimally Multivalent Hydrogen spatially selective as judged by vesicular adhesion to surface patterned supported lipid bilayers (SLBs

  17. Group Report: Connections between Aerosol Properties

    E-Print Network [OSTI]

    effect and causes surface warming. Absorption of solar or thermal radiation within the atmospheric column-influencing constituents (such as green- house gases) by this process, anthropogenic aerosols can contribute to climate

  18. Aerosol Condensational Growth in Cloud Formation 

    E-Print Network [OSTI]

    Geng, Jun

    2010-10-12

    A code for the quasi-stationary solution of the coupled heat and mass transport equations for aerosols in a finite volume was developed. Both mass and heat are conserved effectively in the volume, which results in a ...

  19. Aerosol remote sensing in polar regions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Wehrli, Christoph; et al

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i)more »a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.« less

  20. Aerosol remote sensing in polar regions

    SciTech Connect (OSTI)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Mazzola, Mauro; Lanconelli, Christian; Vitale, Vito; Stebel, Kerstin; Aaltonen, Veijo; de Leeuw, Gerrit; Rodriguez, Edith; Herber, Andreas B.; Radionov, Vladimir F.; Zielinski, Tymon; Petelski, Tomasz; Sakerin, Sergey M.; Kabanov, Dmitry M.; Xue, Yong; Mei, Linlu; Istomina, Larysa; Wagener, Richard; McArthur, Bruce; Sobolewski, Piotr S.; Kivi, Rigel; Courcoux, Yann; Larouche, Pierre; Broccardo, Stephen; Piketh, Stuart J.

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i) a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.

  1. Sticky Surfaces: Sphere-Sphere Adhesion Dynamics

    E-Print Network [OSTI]

    Sarthok Sircar; John G. Younger; David M. Bortz

    2013-09-08

    We present a multi-scale model to study the attachment of spherical particles with a rigid core, coated with binding ligands and in equilibrium with the surrounding, quiescent fluid medium. This class of fluid-immersed adhesion is widespread in many natural and engineering settings. Our theory highlights how the micro-scale binding kinetics of these ligands, as well as the attractive / repulsive surface potential in an ionic medium effects the eventual macro-scale size distribution of the particle aggregates (flocs). The results suggest that the presence of elastic ligands on the particle surface allow large floc aggregates by inducing efficient inter-floc collisions (i.e., a large, non-zero collision factor). Strong electrolytic composition of the surrounding fluid favors large floc formation as well.

  2. Aerosol fabrication methods for monodisperse nanoparticles

    DOE Patents [OSTI]

    Jiang, Xingmao; Brinker, C Jeffrey

    2014-10-21

    Exemplary embodiments provide materials and methods for forming monodisperse particles. In one embodiment, the monodisperse particles can be formed by first spraying a nanoparticle-containing dispersion into aerosol droplets and then heating the aerosol droplets in the presence of a shell precursor to form core-shell particles. By removing either the shell layer or the nanoparticle core of the core-shell particles, monodisperse nanoparticles can be formed.

  3. Electrically Driven Technologies for Radioactive Aerosol Abatement

    SciTech Connect (OSTI)

    David W. DePaoli; Ofodike A. Ezekoye; Costas Tsouris; Valmor F. de Almeida

    2003-01-28

    The purpose of this research project was to develop an improved understanding of how electriexecy driven processes, including electrocoalescence, acoustic agglomeration, and electric filtration, may be employed to efficiently treat problems caused by the formation of aerosols during DOE waste treatment operations. The production of aerosols during treatment and retrieval operations in radioactive waste tanks and during thermal treatment operations such as calcination presents a significant problem of cost, worker exposure, potential for release, and increased waste volume.

  4. Development of plutonium aerosol fractionation system 

    E-Print Network [OSTI]

    Mekala, Malla R.

    1993-01-01

    DEVELOPMENT OF A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1993 Major Subject: Mechanical Engineering DEVELOPMENT OP A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Approved as to style and content by: A. R. McFarland (Chair of Committee) N. K. Anand (Mer toer) (', & C. B...

  5. Proceedings of ISEC 2008, International Solvent Extraction Conference - Solvent Extraction: Fundamentals to Industrial Applications

    SciTech Connect (OSTI)

    Moyer, Bruce A.

    2008-07-01

    The North American industry has employed major solvent-extraction processes to support a wide range of separations including but not limited to chemical, metallurgical, nuclear, biochemical, pharmaceutical, and petroleum applications. The knowledge enabling these separations has been obtained through fundamental studies in academe, government and industry. The International Solvent Extraction Conferences have been and continue to be a major gathering of scientists, engineers, operators, and vendors from around the world, who present new findings since the last meeting, exchange ideas, make business contacts, and conduct collegial discussions. The ISEC 2008 program emphasizes fundamentals to industrial applications of solvent extraction, particularly how this broad spectrum of activities is interconnected and has led to the implementation of novel processes. The oral and poster sessions have been organized into seven topics: Fundamentals; Novel Reagents, Materials and Techniques; Nuclear Fuel Reprocessing; Hydrometallurgy and Metals Extraction; Analytical and Preparative Applications; Biotechnology, Pharmaceuticals, Life-Science Products, and Organic Products; and Process Chemistry and Engineering. Over 350 abstracts were received, resulting in more than 260 manuscripts published in these proceedings. Five outstanding plenary presentations have been identified, with five parallel sessions for oral presentations and posters. In recognition of the major role solvent extraction (SX) plays in the hydrometallurgical and nuclear industries, these proceedings begin with sections focusing on hydrometallurgy, process chemistry, and engineering. More fundamental topics follow, including sections on novel reagents, materials, and techniques, featuring novel applications in analytical and biotechnology areas. Despite the diversity of topics and ideas represented, however, the primary focus of the ISEC community continues to be metals extraction. Four papers from these proceedings have been entered already in INIS in the form of individual reports. Among the remaining papers, 60 have been selected from the following sessions: Plenary Lectures, Hydrometallurgy and Metals Extraction, Nuclear Fuel Reprocessing, Analytical and Preparative Applications, Fundamentals, and Novel Reagents, Materials, and Techniques.

  6. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, Robert N. (Allentown, PA)

    1986-01-01

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  7. Electrostatic Free Energy and its Variations in Implicit Solvent Models

    E-Print Network [OSTI]

    Li, Bo

    Electrostatic Free Energy and its Variations in Implicit Solvent Models Jianwei Che , Joachim. The unique set of such concentrations that minimize this free energy are given by the usual Boltzmann. The variation of the electrostatic free energy with respect to the location change of solute-solvent interfaces

  8. WRF-Chem Simulations of Aerosols and Anthropogenic Aerosol Radiative Forcing in East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhao, Chun; Liu, Xiaohong; Zhang, Meigen; Leung, Lai-Yung R.

    2014-08-01

    This study aims to provide a first comprehensive evaluation of WRF-Chem for modeling aerosols and anthropogenic aerosol radiative forcing (RF) over East Asia. Several numerical experiments were conducted from November 2007 to December 2008. Comparison between model results and observations shows that the model can generally reproduce the observed spatial distributions of aerosol concentration, aerosol optical depth (AOD) and single scattering albedo (SSA) from measurements at different sites, including the relatively higher aerosol concentration and AOD over East China and the relatively lower AOD over Southeast Asia, Korean, and Japan. The model also depicts the seasonal variation and transport of pollutions over East Asia. Particulate matter of 10 um or less in the aerodynamic diameter (PM10), black carbon (BC), sulfate (SO42-), nitrate (NO3-) and ammonium (NH4+) concentrations are higher in spring than other seasons in Japan due to the pollutant transport from polluted area of East Asia. AOD is high over Southwest and Central China in winter, spring and autumn and over North China in summer while is low over South China in summer due to monsoon precipitation. SSA is lowest in winter and highest in summer. The model also captures the dust events at the Zhangye site in the semi-arid region of China. Anthropogenic aerosol RF is estimated to range from -5 to -20 W m-2 over land and -20 to -40 W m-2 over ocean at the top of atmosphere (TOA), 5 to 30 W m-2 in the atmosphere (ATM) and -15 to -40 W m-2 at the bottom (BOT). The warming effect of anthropogenic aerosol in ATM results from BC aerosol while the negative aerosol RF at TOA is caused by scattering aerosols such as SO4 2-, NO3 - and NH4+. Positive BC RF at TOA compensates 40~50% of the TOA cooling associated with anthropogenic aerosol.

  9. CO-SOLVENT SELECTION AND RECOVERY Angelo Lucia* and Erik J. Finger

    E-Print Network [OSTI]

    Lucia, Angelo

    1 CO-SOLVENT SELECTION AND RECOVERY Angelo Lucia* and Erik J. Finger Department of Chemical and recovery of two or more solvents (i.e., co-solvents) are studied because of their importance present difficulties in solvent selection while the volatile components give rise to solvent recovery

  10. Solvent Selection For Enhanced Bioproduction of 3-methylcatechol in a Two-Phase

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    ARTICLE Solvent Selection For Enhanced Bioproduction of 3-methylcatechol in a Two for the identification of an appro- priate organic solvent and they included solvent toxicity, bioavailability of the solvent as well as solvent affinity for 3MC. The critical log P (log Pcrit) of the biocatalyst was found

  11. Aerosol-cloud radiative effects from passive satellite instruments Mar%n de Graaf

    E-Print Network [OSTI]

    Graaf, Martin de

    Satellite measurements of absorbing aerosols Reflectance Difference Method Cloud modelling Results Outlook Aerosol-Radiation Interac. Aerosol-Cloud Interac. Total anthropogenic Solar irradiance #12;Absorbing aerosols: SCIAMACHY Results Outlook #12;SCIAMACHY on ESA's Environmetal Satellite: ENVISAT Polar orbi

  12. Relative humidity and its effect on aerosol optical depth in the vicinity of convective clouds

    E-Print Network [OSTI]

    Altaratz, O

    The hygroscopic growth of aerosols is controlled by the relative humidity (RH) and changes the aerosols' physical and hence optical properties. Observational studies of aerosol–cloud interactions evaluate the aerosol ...

  13. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  14. Aerosol Science and Technology, 48:803812, 2014 Copyright C American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 48:803­812, 2014 Copyright C American Association for Aerosol of particle growth in the atmosphere, and many properties of the resulting mixed particles depend on organic. In this article, analytic equations are derived p(;d) for condensational growth in a continuously mixed flow

  15. Aerosol Science and Technology, 45:244261, 2011 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 45:244­261, 2011 Copyright © American Association for Aerosol University, Cambridge, Massachusetts, USA The hygroscopic phase transitions and growth factors of mixed chemical composition on phase transitions. The hygroscopic growth factors of the mixed particles were

  16. Aerosol Science and Technology, 38:12061222, 2004 Copyright c American Association for Aerosol Research

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    to Combustion-Generated Soot Aerosols as a Function of Fuel Equivalence Ratio Jay G. Slowik,1 K. Stainken,1 Paul factor, size, and fractal dimension of soot aerosol particles generated in a propane/O2 flame were on the fuel equivalence ratio. Type 1: for propane/O2), dva was nearly constant and independent

  17. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  18. Aerosol Characterization Data from the Asian Pacific Regional Aerosol Characterization Project (ACE-Asia)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Aerosol Characterization Experiments (ACE) were designed to increase understanding of how atmospheric aerosol particles affect the Earth's climate system. These experiments integrated in-situ measurements, satellite observations, and models to reduce the uncertainty in calculations of the climate forcing due to aerosol particles and improve the ability of models to predict the influences of aerosols on the Earth's radiation balance. ACE-Asia was the fourth in a series of experiments organized by the International Global Atmospheric Chemistry (IGAC) Program (A Core Project of the International Geosphere Biosphere Program). The Intensive Field Phase for ACE-Asia took place during the spring of 2001 (mid-March through early May) off the coast of China, Japan and Korea. ACE-Asia pursued three specific objectives: 1) Determine the physical, chemical, and radiative properties of the major aerosol types in the Eastern Asia and Northwest Pacific region and investigate the relationships among these properties. 2) Quantify the physical and chemical processes controlling the evolution of the major aerosol types and in particular their physical, chemical, and radiative properties. 3) Develop procedures to extrapolate aerosol properties and processes from local to regional and global scales, and assess the regional direct and indirect radiative forcing by aerosols in the Eastern Asia and Northwest Pacific region [Edited and shortened version of summary at http://data.eol.ucar.edu/codiac/projs?ACE-ASIA]. The Ace-Asia collection contains 174 datasets.

  19. SCENARIOS EVALUATION TOOL FOR CHLORINATED SOLVENT MNA

    SciTech Connect (OSTI)

    Vangelas, K; Brian02 Looney, B; Michael J. Truex; Charles J. Newell

    2006-08-16

    Over the past three decades, much progress has been made in the remediation of chlorinated solvents from the subsurface. Yet these pervasive contaminants continue to present a significant challenge to the U.S. Department of Energy (DOE), other federal agencies, and other public and private organizations. The physical and chemical properties of chlorinated solvents make it difficult to rapidly reach the low concentrations typically set as regulatory limits. These technical challenges often result in high costs and long remediation time frames. In 2003, the DOE through the Office of Environmental Management funded a science-based technical project that uses the U.S. Environmental Protection Agency's technical protocol (EPA, 1998) and directives (EPA, 1999) on Monitored Natural Attenuation (MNA) as the foundation on which to introduce supporting concepts and new scientific developments that will support remediation of chlorinated solvents based on natural attenuation processes. This project supports the direction in which many site owners want to move to complete the remediation of their site(s), that being to complete the active treatment portion of the remedial effort and transition into MNA. The overarching objective of the effort was to examine environmental remedies that are based on natural processes--remedies such as Monitored Natural Attenuation (MNA) or Enhanced Attenuation (EA). The research program did identify several specific opportunities for advances based on: (1) mass balance as the central framework for attenuation based remedies, (2) scientific advancements and achievements during the past ten years, (3) regulatory and policy development and real-world experience using MNA, and (4) exploration of various ideas for integrating attenuation remedies into a systematic set of ''combined remedies'' for contaminated sites. These opportunities are summarized herein and are addressed in more detail in referenced project documents and journal articles, as well as in the technical and regulatory documents being developed within the ITRC. Three topic areas were identified for development during this project. These areas are: mass balance, Enhanced Attenuation (EA), and new characterization and monitoring tools and approaches to support MNA and EA. Each of these topics is documented in stand alone reports, WSRC-STI-2006-00082, WSRC-STI-2006-00083, and WSRC-STI-2006-00084, respectively. In brief, the mass balance efforts are examining methods and tools to allow a site to be evaluated in terms of a system where the inputs and processes within the system are compared to the outputs from the system, as well as understanding what attenuation processes may be occurring and how likely they are to occur within a system. Enhanced Attenuation is a new concept that is a transition step between primary treatments and MNA, when the natural attenuation processes are not sufficient to allow direct transition from the primary treatment to MNA. EA technologies are designed to either boost the level of the natural attenuation processes or decrease the loading of contaminants to the system for a period of time sufficient to allow the remedial goals to be met over the long-term. For characterization and monitoring, a phased approach based on documenting the site specific mass balance was developed. Tools and techniques to support the approach included direct measures of the biological processes and various tools to support cost-effective long-term monitoring of systems where the natural attenuation processes are the main treatment remedies. The effort revealed opportunities for integrating attenuation mechanisms into a systematic set of ''combined remedies'' for contaminated sites.

  20. Stabilization of Large Scale Structure by Adhesive Gravitational Clustering

    E-Print Network [OSTI]

    Thomas Buchert

    1999-08-13

    The interplay between gravitational and dispersive forces in a multi-streamed medium leads to an effect which is exposed in the present note as the genuine driving force of stabilization of large-scale structure. The conception of `adhesive gravitational clustering' is advanced to interlock the fairly well-understood epoch of formation of large-scale structure and the onset of virialization into objects that are dynamically in equilibrium with their large-scale structure environment. The classical `adhesion model' is opposed to a class of more general models traced from the physical origin of adhesion in kinetic theory.

  1. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, L.A.; Allred, R.E.; Wilson, K.V. Jr.

    1992-02-18

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  2. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, Larry A. (Albuquerque, NM); Allred, Ronald E. (Albuquerque, NM); Wilson, Jr., Kennard V. (Albuquerque, NM)

    1992-01-01

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  3. Friction, Adhesion, and Deformation: Dynamic Measurements with the Atomic Force Phil Attard

    E-Print Network [OSTI]

    Attard, Phil

    Friction, Adhesion, and Deformation: Dynamic Measurements with the Atomic Force Microscope Phil. Adhesion Sci. Technol. 16, 753­791 (2002).) Running title: Friction, Adhesion, and Deformation Abstract for the friction force microscope, quantitative measurements of friction and the ef- fect of adhesion, measurement

  4. High-Affinity DNA Base Analogs as Supramolecular, Nanoscale Promoters of Macroscopic Adhesion

    E-Print Network [OSTI]

    Sottos, Nancy R.

    High-Affinity DNA Base Analogs as Supramolecular, Nanoscale Promoters of Macroscopic Adhesion Cyrus Information ABSTRACT: Adhesion phenomena are essential to many biological processes and to synthetic adhesives adhesion mechanisms. Recently, supramolecular building blocks, such as synthetic DNA base- pair mimics

  5. Under consideration for publication in Math. Struct. in Comp. Science M-Adhesive Transformation Systems with

    E-Print Network [OSTI]

    Habel, Annegret

    Under consideration for publication in Math. Struct. in Comp. Science M-Adhesive Transformation application conditions in the framework of M-adhesive categories, where M-adhesive categories are slightly more general than weak adhesive high-level replacement categories. Most of the proofs are based

  6. An Atomic Interaction based Continuum Model for Adhesive Contact Roger A. Sauer , Shaofan Li

    E-Print Network [OSTI]

    An Atomic Interaction based Continuum Model for Adhesive Contact Mechanics Roger A. Sauer , Shaofan the adhesive contact between deformable bodies. To model adhesive contact, an interatomic interaction potential of the model with respect to its geometrical size and the strength of adhesion is investigated. The proposed

  7. On the optimum shape of thin adhesive strips for various peeling directions

    E-Print Network [OSTI]

    On the optimum shape of thin adhesive strips for various peeling directions Janine C. Mergel, Roger Published2 in The Journal of Adhesion, DOI: 10.1080/00218464.2013.840538 Submitted on 23 July 2013, Revised: computational shape optimization, adhesive tapes, cohesive zone models, peeling angle, gecko adhesion 1

  8. How to Care for Your Wound After It's Treated With DERMABOND* Topical Skin Adhesive

    E-Print Network [OSTI]

    Kay, Mark A.

    How to Care for Your Wound After It's Treated With DERMABOND* Topical Skin Adhesive DERMABOND* Topical Skin Adhesive (2-octyl cyanoacrylate) is a sterile, liquid skin adhesive that holds wound edges · If your wound is bandaged, keep the bandage dry. · Replace the dressing daily until the adhesive film has

  9. P l e a s e P o s t Instant Adhesive Eye Injury

    E-Print Network [OSTI]

    P l e a s e P o s t Instant Adhesive Eye Injury Lawrence Berkeley National Laboratory Lessons Learned LL-2006-01 Concern Statement: While attempting to apply instant adhesive to a piece with cyanoacrylate instant adhesives. Trade names include 495 Super Bonder® Instant Adhesive, Superglue® , and Krazy

  10. Hydrogen donor solvent coal liquefaction process

    DOE Patents [OSTI]

    Plumlee, Karl W. (Baytown, TX)

    1978-01-01

    An indigenous hydrocarbon product stream boiling within a range of from about C.sub.1 -700.degree. F., preferably C.sub.1 -400.degree. F., is treated to produce an upgraded hydrocarbon fuel component and a component which can be recycled, with a suitable donor solvent, to a coal liquefaction zone to catalyze the reaction. In accordance therewith, a liquid hydrocarbon fraction with a high end boiling point range up to about 700.degree. F., preferably up to about 400.degree. F., is separated from a coal liquefaction zone effluent, the separated fraction is contacted with an alkaline medium to provide a hydrocarbon phase and an aqueous extract phase, the aqueous phase is neutralized, and contacted with a peroxygen compound to convert indigenous components of the aqueous phase of said hydrocarbon fraction into catalytic components, such that the aqueous stream is suitable for recycle to the coal liquefaction zone. Naturally occurring phenols and alkyl substituted phenols, found in the aqueous phase, are converted, by the addition of hydroxyl constituents to phenols, to dihydroxy benzenes which, as disclosed in copending Application Ser. Nos. 686,813 now U.S. Pat. No. 4,049,536; 686,814 now U.S. Pat. No. 4,049,537; 686,827 now U.S. Pat. No. 4,051,012 and 686,828, K. W. Plumlee et al, filed May 17, 1976, are suitable hydrogen transfer catalysts.

  11. Solvent Mediated Assembly of Nanoparticles Confined in Mesoporous Alumina

    E-Print Network [OSTI]

    Kyle J. Alvine; Diego Pontoni; Oleg G. Shpyrko; Peter S. Pershan; David J. Cookson; Kyusoon Shin; Thomas P. Russell; Markus Brunnbauer; Francesco Stellacci; Oleg Gang

    2006-03-24

    The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.

  12. Optimization of cell adhesion environments for a liver cell bioreactor

    E-Print Network [OSTI]

    Wongchaowart, Michael B

    2006-01-01

    The MilliF bioreactor offers great potential for the formation of i vivo-like liver tissue outside the body, making it a valuable tool for applications such as drug toxicity models and biosensors. Cell adhesion is an ...

  13. Geckobot: A Gecko Inspired Climbing Robot Using Elastomer Adhesives

    E-Print Network [OSTI]

    Sitti, Metin

    ], and painting [5]. Other applications include building repair and maintenance, search and rescue, and toys adhesion, where the robot carries an on-board pump to create a vacuum inside cups which are pressed against

  14. Determining graphene adhesion via substrate-regulated morphology of graphene

    E-Print Network [OSTI]

    Li, Teng

    Determining graphene adhesion via substrate-regulated morphology of graphene Zhao Zhang and Teng Li Institute of Physics. Related Articles Identification of graphene crystallographic orientation by atomic two-dimensional, epitaxially-grown, nanostructured graphene for study of single molecule

  15. Tuning adhesion failure strength for tissue-specific applications

    E-Print Network [OSTI]

    Artzi, Natalie

    Soft tissue adhesives are employed to repair and seal many different organs, which range in both tissue surface chemistry and mechanical challenges during organ function. This complexity motivates the development of tunable ...

  16. Bacterial flagella explore microscale hummocks and hollows to increase adhesion

    E-Print Network [OSTI]

    Friedlander, Ronn Samuel

    Biofilms, surface-bound communities of microbes, are economically and medically important due to their pathogenic and obstructive properties. Among the numerous strategies to prevent bacterial adhesion and subsequent biofilm ...

  17. Development of sodium silicate adhesives for electrical steel bonding

    E-Print Network [OSTI]

    Marks, Jordan (Jordan Christine)

    2014-01-01

    Inorganic adhesives have several benefits over traditional joining methods for joining electrical steels used in magnetic cores of numerous industrial applications. As insulators with very high melting temperatures, the ...

  18. Adsorbed Polymer and NOM Limits Adhesion and Toxicity of Nano

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Adsorbed Polymer and NOM Limits Adhesion and Toxicity of Nano Scale Zerovalent Iron to E. coli Z H. Here we assess the effect that adsorbed synthetic polymers and natural organic matter

  19. Non-intrusive characterization of heat transfer fluid aerosol formation 

    E-Print Network [OSTI]

    Krishna, Kiran

    2001-01-01

    in process equipment. Predictive models relating the aerosol formation distances, aerosol droplet size, and volume concentrations to bulk liquid pressure, temperature, fluid properties, leak size and ambient conditions are developed. These models will be used...

  20. The seasonality of aerosol properties in Big Bend National Park 

    E-Print Network [OSTI]

    Allen, Christopher Lee

    2007-04-25

    ), to characterize the seasonal variability of the Big Bend regions aerosol optical properties. Mass extinction efficiencies and relative humidity scattering enhancement factors were calculated for both externally and internally mixed aerosol populations for all size...

  1. Apparatus for rapid measurement of aerosol bulk chemical composition

    DOE Patents [OSTI]

    Lee, Yin-Nan E.; Weber, Rodney J.; Orsini, Douglas

    2006-04-18

    An apparatus for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution is provided. The apparatus includes an enhanced particle size magnifier for producing activated aerosol particles and an enhanced collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical means. Methods for on-line measurement of chemical composition of aerosol particles are also provided, the method including exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; and flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

  2. Apparatus for rapid measurement of aerosol bulk chemical composition

    DOE Patents [OSTI]

    Lee, Yin-Nan E. (East Setauket, NY); Weber, Rodney J. (Atlanta, GA)

    2003-01-01

    An apparatus and method for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution are provided. The apparatus includes a modified particle size magnifier for producing activated aerosol particles and a collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical methods. The method provided for on-line measurement of chemical composition of aerosol particles includes exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

  3. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, F.K.

    1986-07-29

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process. 4 figs.

  4. Integrated process for the solvent refining of coal

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1983-01-01

    A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the solid product in a second stage to produce additional liquid product. A fresh inexpensive, throw-away catalyst is utilized in the second stage hydrogenation of the solid product and this catalyst is recovered and recycled for catalyst duty in the solvent refining stage without any activation steps performed on the used catalyst prior to its use in the solvent refining of feed coal.

  5. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1986-01-01

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  6. Acetone as a solvent for extraction of cottonseed oil 

    E-Print Network [OSTI]

    Hui, In-Wai

    1950-01-01

    ACETONE AS A SOLVENT FOR EXTRACTION GP COTTONSEED OIL A Thesis In-Wai Hui June 1950 Approval as to style and content recommended c t Head oi' the Department of Chemical Engineering ACETONE AS A SOLVENT FOR EXT "ACTION OF COTTONSEED OIL A... Thesis In-Nai Hui June 1950 ACETONE AS A SOLVENT FOR EXTRACTION QF COTTONSEED OIL A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas Partis1 Fulfillment of the Recuirements for the Degree of Master of Science...

  7. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  8. Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass

    E-Print Network [OSTI]

    Cai, Charles Miao-Zi

    2014-01-01

    THF is a promising green solvent that is relatively non-is a biomass-sourced green solvent with catalytic qualities

  9. Serum complement and platelet adhesiveness in acute canine ehrlichiosis 

    E-Print Network [OSTI]

    Lovering, Sandra Lorraine

    1977-01-01

    SERUM COMPLEMENT AND PLATELET ADHESIVENESS IN ACUTE CANINE EHRLICHIOSIS A Thesis by Sandra Lorraine Lovering Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1977 Ma]or Sub] ect: VETERINARY PATHOLOGY SERUM COMPLEMENT AND PLATELET ADHESIVENESS IN ACUTE CANINE EHRLICHIOSIS A Thesis by Sandra Lorraine Lovering Approved as to style and content by: (Chairman of ommittee) (Head...

  10. Advanced Low Energy Enzyme Catalyzed Solvent for CO{sub 2} Capture

    SciTech Connect (OSTI)

    Zaks, Alex; Reardon, John

    2013-09-30

    A proof-of-concept biocatalyst enhanced solvent process was developed and demonstrated in an integrated bench-scale system using coal post combustion flue gas. The biocatalyst was deployed as a coating on M500X structured packing. Rate enhancement was evaluated using a non-volatile and non- toxic 20 wt% potassium carbonate solution. Greater than 500-fold volumetric scale-up from laboratory to bench scale was demonstrated in this project. Key technical achievements included: 10-fold mass transfer enhancement demonstrated in laboratory testing relative to blank potassium carbonate at 45°C; ~ 7-fold enhancement over blank in bench-scale field testing at National Carbon Capture Center; aerosol emissions were below detection limits (< 0.8 ppm); 90% capture was demonstrated at ~19.5 Nm{sup 3}/hr (dry basis); and ~ 80% CO{sub 2} capture was demonstrated at ~ 30 Nm{sup 3}/hr (dry basis) for more than 2800-hrs on flue gas with minimal detectible decline in activity. The regeneration energy requirement was 3.5 GJ/t CO{sub 2} for this solvent, which was below the target of <2.1 GJ/t CO{sub 2}. Bench unit testing revealed kinetic limitations in the un-catalyzed stripper at around 85°C, but process modeling based on bench unit data showed that equivalent work of less than 300 kWh/t CO{sub 2} including all CO{sub 2} compression can be achieved at lower temperature stripping conditions. Cost analysis showed that 20% potassium carbonate in a basic solvent flow sheet with biocatalyst coated packing has economic performance comparable to the reference NETL Case-12, 30% MEA. A detailed techno-economic analysis indicated that addition of catalyst in the stripper could reduce the cost of capture by ~6% and cost of avoided CO{sub 2} by ~10% below reference NETL Case-12. Based on these results, a directional plan was identified to reduce the cost of CO{sub 2} capture in future work.

  11. Wave-mechanics and the adhesion approximation

    E-Print Network [OSTI]

    C. J. Short; P. Coles

    2006-11-22

    The dynamical equations describing the evolution of a self-gravitating fluid of cold dark matter (CDM) can be written in the form of a Schrodinger equation coupled to a Poisson equation describing Newtonian gravity. It has recently been shown that, in the quasi-linear regime, the Schrodinger equation can be reduced to the exactly solvable free-particle Schrodinger equation. The free-particle Schrodinger equation forms the basis of a new approximation scheme -the free-particle approximation - that is capable of evolving cosmological density perturbations into the quasi-linear regime. The free-particle approximation is essentially an alternative to the adhesion model in which the artificial viscosity term in Burgers' equation is replaced by a non-linear term known as the quantum pressure. Simple one-dimensional tests of the free-particle method have yielded encouraging results. In this paper we comprehensively test the free-particle approximation in a more cosmologically relevant scenario by appealing to an N-body simulation. We compare our results with those obtained from two established methods: the linearized fluid approach and the Zeldovich approximation. We find that the free-particle approximation comprehensively out-performs both of these approximation schemes in all tests carried out and thus provides another useful analytical tool for studying structure formation on cosmological scales.

  12. Similarity and singularity in adhesive elastohydrodynamic touchdown

    E-Print Network [OSTI]

    Carlson, Andreas

    2015-01-01

    We consider the touchdown of an elastic sheet as it adheres to a wall, which has a dynamics that is limited by the viscous resistance provided by the squeeze flow of the intervening liquid trapped between the two solid surfaces. The dynamics of the sheet is described mathematically by elastohydrodynamic lubrication theory, coupling the elastic deformation of the sheet, the microscopic van der Waals adhesion and the viscous thin film flow. We use a combination of numerical simulations of the governing partial differential equation and a scaling analysis to describe the self-similar solution of the touchdown of the sheet as it approaches the wall. An analysis of the equation satisfied by the similarity variables in the vicinity of the touchdown event shows that an entire sequence of solutions are allowed. However, a comparison of these shows that only the fundamental similarity solution is observed in the time-dependent numerical simulations, consistent with the fact that it alone is stable. Our analysis genera...

  13. Micro-Raman spectroscopic studies on the adhesive-dentine interface and the degree of conversion of dental adhesives 

    E-Print Network [OSTI]

    Miletic, Vesna

    2010-01-01

    A series of studies on monomer to polymer conversion in adhesive systems was undertaken using micro-Raman spectroscopy. A database of micro-Raman spectra was compiled for identification of tooth tissues and materials. ...

  14. Observations of Secondary Organic Aerosol Production and Soot Aging under Atmospheric Conditions Using a Novel Environmental Aerosol Chamber 

    E-Print Network [OSTI]

    Glen, Crystal

    2012-02-14

    of the processes leading to SOA production under ambient gaseous and particulate concentrations as well as the impact these aerosol types have on climate is poorly understood. Although the majority of atmospheric aerosols scatter radiation either directly...

  15. AEROSOL-PRECIPITATION INTERACTIONS IN THE SOUTHERN APPALACHIAN MOUNTAINS

    E-Print Network [OSTI]

    AEROSOL-PRECIPITATION INTERACTIONS IN THE SOUTHERN APPALACHIAN MOUNTAINS A Thesis by GINGER MARIE of the requirements for the degree of MASTER OF ARTS May 2011 Department of Geography and Planning #12;AEROSOL-PRECIPITATION and Graduate Studies #12;Copyright by Ginger Marie Kelly 2011 All Rights Reserved #12;iv ABSTRACT AEROSOL-PRECIPITATION

  16. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    I. Solvent Refined Coal II. Catalysts III. Purpose andSondreal, E.A. , "Viscosity of Coal Liquids - The Effect ofAnthraxylon - Kinetics of Coal Hydrogenation," Ind. and Eng.

  17. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  18. A Monte Carlo study of spectroscopy in nanoconfined solvents

    E-Print Network [OSTI]

    Thompson, Ward H.

    2002-09-26

    The absorption and fluorescence spectra of a model diatomic molecule with a charge-transfer electronic transition are simulated. The effect of confining the solvent in which the diatomic molecule is dissolved is examined by comparing results...

  19. Solvent-mediated interactions between nanoparticles at fluid interfaces

    E-Print Network [OSTI]

    F. Bresme; H. Lehle; M. Oettel

    2009-04-03

    We investigate the solvent mediated interactions between nanoparticles adsorbed at a liquid-vapor interface in comparison to the solvent mediated interactions in the bulk liquid and vapor phases of a Lennard-Jones solvent. Molecular dynamics simulation data for the latter are in good agreement with results from integral equations in the reference functional approximation and a simple geometric approximation. Simulation results for the solvent mediated interactions at the interface differ markedly from the interactions of the particles in the corresponding bulk phases. We find that at short interparticle distances the interactions are considerably more repulsive than those in either bulk phase. At long interparticle distances we find evidence for a long-ranged attraction. We discuss these observations in terms of interfacial interactions, namely, the three-phase line tension that would operate at short distances, and capillary wave interactions for longer interparticle distances.

  20. Nuclear Magnetic Resonance Quantum Computing Using Liquid Crystal Solvents

    E-Print Network [OSTI]

    Costantino S. Yannoni; Mark H. Sherwood; Lieven M. K. Vandersypen; Dolores C. Miller; Mark G. Kubinec; Isaac L. Chuang

    1999-12-12

    Liquid crystals offer several advantages as solvents for molecules used for nuclear magnetic resonance quantum computing (NMRQC). The dipolar coupling between nuclear spins manifest in the NMR spectra of molecules oriented by a liquid crystal permits a significant increase in clock frequency, while short spin-lattice relaxation times permit fast recycling of algorithms, and save time in calibration and signal-enhancement experiments. Furthermore, the use of liquid crystal solvents offers scalability in the form of an expanded library of spin-bearing molecules suitable for NMRQC. These ideas are demonstrated with the successful execution of a 2-qubit Grover search using a molecule ($^{13}$C$^{1}$HCl$_3$) oriented in a liquid crystal and a clock speed eight times greater than in an isotropic solvent. Perhaps more importantly, five times as many logic operations can be executed within the coherence time using the liquid crystal solvent.

  1. Proteins in Mixed Solvents: A Molecular-level Perspective

    E-Print Network [OSTI]

    Baynes, Brian M.

    We present a statistical mechanical approach for quantifying thermodynamic properties of proteins in mixed solvents. This approach, based on molecular dynamics simulations which incorporate all atom models and the theory ...

  2. Arsenic Speciation of Solvent-Extracted Leachate from

    E-Print Network [OSTI]

    Florida, University of

    and quantify arsenic species leaching from new and weathered CCA-treated wood and CCA-treated wood ash. Solvent process. CCA-treated wood ash leached more arsenic than unburned wood using the SPLP and TCLP, and ash

  3. Renewable, Nontoxic, and Cost-Competitive Solvents and Plasticizers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Befer than leading "green" candidates TURI Test xF solvents Compared s olvents Paint Stripping MF and EF DCM, NMP, Green AlternaKve Degreasing MF and EF TCE, NPB, Green...

  4. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    E.A. , "Viscosity of Coal Liquids - The Effect of CharacterOF SOLVENT REFINED COAL TO LIQUID PRODUCTS Kylan I. Tanner*for Conversion of Coal to Liquid Fuels: Basic and Ex-

  5. Apparatus and method for removing solvent from carbon dioxide in resin recycling system

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06

    A two-step resin recycling system and method solvent that produces essentially contaminant-free synthetic resin material. The system and method includes one or more solvent wash vessels to expose resin particles to a solvent, the solvent contacting the resin particles in the one or more solvent wash vessels to substantially remove contaminants on the resin particles. A separator is provided to separate the solvent from the resin particles after removal from the one or more solvent wash vessels. The resin particles are next exposed to carbon dioxide in a closed loop carbon dioxide system. The closed loop system includes a carbon dioxide vessel where the carbon dioxide is exposed to the resin, substantially removing any residual solvent remaining on the resin particles after separation. A separation vessel is also provided to separate the solvent from the solvent laden carbon dioxide. Both the carbon dioxide and the solvent are reused after separation in the separation vessel.

  6. Homophilic Adhesion Mechanism of Neurofascin, a Member of the L1 Family of Neural Cell Adhesion Molecules

    SciTech Connect (OSTI)

    Liu, Heli; Focia, Pamela J.; He, Xiaolin (NWU, MED)

    2012-02-13

    The L1 family neural cell adhesion molecules play key roles in specifying the formation and remodeling of the neural network, but their homophilic interaction that mediates adhesion is not well understood. We report two crystal structures of a dimeric form of the headpiece of neurofascin, an L1 family member. The four N-terminal Ig-like domains of neurofascin form a horseshoe shape, akin to several other immunoglobulin superfamily cell adhesion molecules such as hemolin, axonin, and Dscam. The neurofascin dimer, captured in two crystal forms with independent packing patterns, reveals a pair of horseshoes in trans-synaptic adhesion mode. The adhesion interaction is mediated mostly by the second Ig-like domain, which features an intermolecular {beta}-sheet formed by the joining of two individual GFC {beta}-sheets and a large but loosely packed hydrophobic cluster. Mutagenesis combined with gel filtration assays suggested that the side chain hydrogen bonds at the intermolecular {beta}-sheet are essential for the homophilic interaction and that the residues at the hydrophobic cluster play supplementary roles. Our structures reveal a conserved homophilic adhesion mode for the L1 family and also shed light on how the pathological mutations of L1 affect its structure and function.

  7. A study of a solvent extraction desalination process 

    E-Print Network [OSTI]

    McFerrin, Arthur Ransom

    1969-01-01

    to separate salt from water has been known for decades, it was not investigated for use in desalination until 1953 (21). Since 1953, the Office of Saline Water, Department of Interior has supported an exhaustive study of the solvent extractjon desalinat... water to produce a solvent phase containing considerable water but little salt, and a water phase of increased salt content. The amine has a lower consolute temperature with water, and the fresh ~ster is recovered by heating the extract to a higher...

  8. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, R.N.

    1986-10-14

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  9. Aerodynamic Focusing Of High-Density Aerosols

    SciTech Connect (OSTI)

    Ruiz, D. E.; Fisch, Nathaniel

    2014-02-24

    High-density micron-sized particle aerosols might form the basis for a number of applications in which a material target with a particular shape might be quickly ionized to form a cylindrical or sheet shaped plasma. A simple experimental device was built in order to study the properties of high-density aerosol focusing for 1#22; m silica spheres. Preliminary results recover previous findings on aerodynamic focusing at low densities. At higher densities, it is demonstrated that the focusing properties change in a way which is consistent with a density dependent Stokes number.

  10. Journal of Medical and Biological Engineering, 32(1): 70-7670 Effects of Various Adhesive Substrates on the Adhesion Forces

    E-Print Network [OSTI]

    Lee, James

    Journal of Medical and Biological Engineering, 32(1): 70-7670 Effects of Various Adhesive Substrates on the Adhesion Forces of Endothelial Progenitor Cells Guixue Wang1,* Li Xiao1 Xue Wu1 Xiang Xie1.855 Abstract This study evaluates the effects of various substrates on the adhesion forces

  11. Initiate test loop irradiations of ALSEP process solvent

    SciTech Connect (OSTI)

    Peterman, Dean R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Olson, Lonnie G. [Idaho National Lab. (INL), Idaho Falls, ID (United States); McDowell, Rocklan G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-09-01

    This report describes the initial results of the study of the impacts of gamma radiolysis upon the efficacy of the ALSEP process and is written in completion of milestone M3FT-14IN030202. Initial irradiations, up to 100 kGy absorbed dose, of the extraction section of the ALSEP process have been completed. The organic solvent used for these experiments contained 0.05 M TODGA and 0.75 M HEH[EHP] dissolved in n-dodecane. The ALSEP solvent was irradiated while in contact with 3 M nitric acid and the solutions were sparged with compressed air in order to maintain aerated conditions. The irradiated phases were used for the determination of americium and europium distribution ratios as a function of absorbed dose for the extraction and stripping conditions. Analysis of the irradiated phases in order to determine solvent composition as a function of absorbed dose is ongoing. Unfortunately, the failure of analytical equipment necessary for the analysis of the irradiated samples has made the consistent interpretation of the analytical results difficult. Continuing work will include study of the impacts of gamma radiolysis upon the extraction of actinides and lanthanides by the ALSEP solvent and the stripping of the extracted metals from the loaded solvent. The irradiated aqueous and organic phases will be analyzed in order to determine the variation in concentration of solvent components with absorbed gamma dose. Where possible, radiolysis degradation product will be identified.

  12. Flattening coefficient of aerosols collected on treated slides 

    E-Print Network [OSTI]

    Olan-Figueroa, Excel

    1981-01-01

    was found to be 1. 338, and for DOP, 1. 354. There is no apparent variation of F with particle diameter for aerosols in the 2. 7-29. 1 um range. The slightly lower value of F for oleic acid suggests that the contact angle of oleic acid with respect... monodisoerse aerosols in the 1. 5 to 50 um diameter range, the vibratino j et monodisperse aerosol generator has been used. The monodisperse aerosols generated by this device can be considered as an "aerosol standard" since the size and concentration...

  13. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  14. Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry

    E-Print Network [OSTI]

    Kroll, Jesse

    In this study we compile and present results from the factor analysis of 43 Aerosol Mass Spectrometer (AMS) datasets (27 of the datasets are reanalyzed in this work). The components from all sites, when taken together, ...

  15. Effect of Hydrophobic Primary Organic Aerosols on Secondary Organic Aerosol Formation from Ozonolysis of ?-Pinene

    SciTech Connect (OSTI)

    Song, Chen; Zaveri, Rahul A.; Alexander, M. Lizabeth; Thornton, Joel A.; Madronich, Sasha; Ortega, John V.; Zelenyuk, Alla; Yu, Xiao-Ying; Laskin, Alexander; Maughan, A. D.

    2007-10-16

    Semi-empirical secondary organic aerosol (SOA) models typically assume a well-mixed organic aerosol phase even in the presence of hydrophobic primary organic aerosols (POA). This assumption significantly enhances the modeled SOA yields as additional organic mass is made available to absorb greater amounts of oxidized secondary organic gases than otherwise. We investigate the applicability of this critical assumption by measuring SOA yields from ozonolysis of ?-pinene (a major biogenic SOA precursor) in a smog chamber in the absence and in the presence of dioctyl phthalate (DOP) and lubricating oil seed aerosol. These particles serve as surrogates for urban hydrophobic POA. The results show that these POA did not enhance the SOA yields. If these results are found to apply to other biogenic SOA precursors, then the semi-empirical models used in many global models would predict significantly less biogenic SOA mass and display reduced sensitivity to anthropogenic POA emissions than previously thought.

  16. Two Hundred Fifty Years of Aerosols and Climate: The End of the Age of Aerosols

    SciTech Connect (OSTI)

    Smith, Steven J.; Bond, Tami C.

    2014-01-20

    Carbonaceous and sulfur aerosols have a substantial global and regional influence on climate in addition to their impact on health and ecosystems. The magnitude of this influence has changed substantially over the past and is expected to continue to change into the future. An integrated picture of the changing climatic influence of black carbon, organic carbon and sulfate over the period 1850 through 2100, focusing on uncertainty, is presented using updated historical inventories and a coordinated set of emission projections. While aerosols have had a substantial impact on climate over the past century, by the end of the 21st century aerosols will likely be only a minor contributor to radiative forcing due to increases in greenhouse gas forcing and a global decrease in pollutant emissions. This outcome is even more certain under a successful implementation of a policy to limit greenhouse gas emissions as low-carbon energy technologies that do not emit appreciable aerosol or SO2 are deployed.

  17. Climate implications of carbonaceous aerosols: An aerosol microphysical study using the GISS/MATRIX climate model

    SciTech Connect (OSTI)

    Bauer, Susanne E.; Menon, Surabi; Koch, Dorothy; Bond, Tami; Tsigaridis, Kostas

    2010-04-09

    Recently, attention has been drawn towards black carbon aerosols as a likely short-term climate warming mitigation candidate. However the global and regional impacts of the direct, cloud-indirect and semi-direct forcing effects are highly uncertain, due to the complex nature of aerosol evolution and its climate interactions. Black carbon is directly released as particle into the atmosphere, but then interacts with other gases and particles through condensation and coagulation processes leading to further aerosol growth, aging and internal mixing. A detailed aerosol microphysical scheme, MATRIX, embedded within the global GISS modelE includes the above processes that determine the lifecycle and climate impact of aerosols. This study presents a quantitative assessment of the impact of microphysical processes involving black carbon, such as emission size distributions and optical properties on aerosol cloud activation and radiative forcing. Our best estimate for net direct and indirect aerosol radiative forcing change is -0.56 W/m{sup 2} between 1750 and 2000. However, the direct and indirect aerosol effects are very sensitive to the black and organic carbon size distribution and consequential mixing state. The net radiative forcing change can vary between -0.32 to -0.75 W/m{sup 2} depending on these carbonaceous particle properties. Assuming that sulfates, nitrates and secondary organics form a coating shell around a black carbon core, rather than forming a uniformly mixed particles, changes the overall net radiative forcing from a negative to a positive number. Black carbon mitigation scenarios showed generally a benefit when mainly black carbon sources such as diesel emissions are reduced, reducing organic and black carbon sources such as bio-fuels, does not lead to reduced warming.

  18. Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata European Synchrotron, the solute-solvent cross term, and the solvent-only term. The last term is very sensitive to the thermodynamic state of the bulk solvent, which may change during a chemical reaction due to energy transfer from

  19. Mechanistic Origins of Hierarchical Order in Organic Monolayers Deposited From Liquid Crystal Solvents

    E-Print Network [OSTI]

    Patrick, David L.

    Solvents Nick E. Gislason, Calvin Murphy, and David L. Patrick* Department of Chemistry, Western Washington two oriented liquid crystal solvents and one isotropic solvent using a sacrificial template method in which a solvent film applied in a first deposition step is displaced by BOC in a second deposition step

  20. WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other

    E-Print Network [OSTI]

    Haimovich, Alexander

    WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other solvents indicates that these solvents can be customized with the chemical muscle to dissolve almost any material are a groundbreaking green alternative to highly toxic solvents capable of causing signifi- cant environmental harm

  1. Solvent-Promoted Self-Healing Epoxy Materials Mary M. Caruso, David A. Delafuente, Victor Ho,

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Solvent-Promoted Self-Healing Epoxy Materials Mary M. Caruso, David A. Delafuente, Victor Ho, Nancy of a solvent to a polymer matrix. Solvents such as ethanol and methanol were used to seal the cracks.15-17 Raman and Palmese found that solvent molecules can influence the epoxy-amine reaction chemistry

  2. Solvent Quality Changes the Structure of G8 PAMAM Dendrimer, a Disagreement with Some Experimental Interpretations

    E-Print Network [OSTI]

    Goddard III, William A.

    Solvent Quality Changes the Structure of G8 PAMAM Dendrimer, a Disagreement with Some Experimental on the solvent quality, but recently a disagreement concerning the magnitude and sign has arisen.7,8 Small that with decreasing solvent quality (decrease of the polarity of the solvent) the radius of gyration of PAMAM

  3. Solvent Entrainment in and Flocculation of Asphaltenic Aggregates Probed by Small-Angle Neutron Scattering

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Articles Solvent Entrainment in and Flocculation of Asphaltenic Aggregates Probed by Small solvents in which a broad spectrum of solute and solvent chemical compositions was represented. Fits of solvent entrainment from 30 to 50% (v/v) within the aggregates that were consistent with previous

  4. Corpus Callosum Volume in Railroad Workers With Chronic Exposure to Solvents

    E-Print Network [OSTI]

    Corpus Callosum Volume in Railroad Workers With Chronic Exposure to Solvents Marc W. Haut, Ph reported after long-term exposure to solvents. Solvents are hypothesized to affect brain white matter to solvents. Methods: We manually traced (blind to group membership) the volume of the corpus callosum in 31

  5. CHBE 484 Solvent Recovery Project Group Department of Chemical and Biological Engineering

    E-Print Network [OSTI]

    CHBE 484 Solvent Recovery Project Group Department of Chemical and Biological Engineering Vancouver, B.C. Canada V6T 1Z1 Dear Mr. Craig Smith: RE: Solvent Recovery Report for CHBE 484 Green Engineering The UBC solvent recovery program has been successful in recovering solvents such as acetone

  6. Effect of Solvent Evaporation on Fiber Morphology in Rotary Jet Holly McIlwee Golecki,,

    E-Print Network [OSTI]

    Parker, Kevin Kit

    and solvent evaporation enables production of nanoscale polymer fibers. RJS surpasses the electrospinning

  7. Method for recovering and using lignin in adhesive resins

    DOE Patents [OSTI]

    Schroeder, Herbert A. (Ft. Collins, CO)

    1993-01-01

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

  8. Results from simulated upper-plenum aerosol transport and aerosol resuspension experiments

    SciTech Connect (OSTI)

    Wright, A.L.; Pattison, W.L.

    1984-01-01

    Recent calculational results published as part of the Battelle-Columbus BMI-2104 source term study indicate that, for some LWR accident sequences, aerosol deposition in the reactor primary coolant system (PCS) can lead to significant reductions in the radionuclide source term. Aerosol transport and deposition in the PCS have been calculated in this study using the TRAP-MELT 2 computer code, which was developed at Battelle-Columbus; the status of validation of the TRAP-MELT 2 code has been described in an Oak Ridge National Laboratory (ORNL) report. The objective of the ORNL TRAP-MELT Validation Project, which is sponsored by the Fuel Systems Behavior Research Branch of the US Nuclear Regulatory Commission, is to conduct simulated reactor-vessel upper-plenum aerosol deposition and transport tests. The results from these tests will be used in the ongoing effort to validate TRAP-MELT 2. The TRAP-MELT Validation Project includes two experimental subtasks. In the Aerosol Transport Tests, aerosol transport in a vertical pipe is being studied; this geometry was chosen to simulate aerosol deposition and transport in the reactor-vessel upper-plenum. To date, four experiments have been performed; the results from these tests are presented in this paper. 7 refs., 4 figs., 4 tabs.

  9. INTRODUCTION Atmospheric aerosol particles influence the Earth's

    E-Print Network [OSTI]

    Wunderle, Stefan

    , scattering, and absorbing solar electromagnetic radiation and by modifying cloud properties due to their roleINTRODUCTION Atmospheric aerosol particles influence the Earth's radiation budget by reflecting to maximum cover a region once in the daytime. In contrary, up-to-date geostationary instruments like

  10. Experimental study of nuclear workplace aerosol samplers 

    E-Print Network [OSTI]

    Parulian, Antony

    1995-01-01

    consists of an inlet-elbow, a transport line, and a EL-900 CAM prototype manufactured by EG&G. Results show that only 12% of 10 []m aerodynamic diameter (AD) aerosol particles penetrate through the complete sampling system when it is operated at flow rate...

  11. A new aerosol collector for quasi on-line analysis of particulate organic matter: the Aerosol Collection Module (ACM) and first applications with a GC/MS-FID

    E-Print Network [OSTI]

    Hohaus, T.

    In many environments organic matter significantly contributes to the composition of atmospheric aerosol particles influencing its properties. Detailed chemical characterization of ambient aerosols is critical in order to ...

  12. Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent

    SciTech Connect (OSTI)

    Ginosar, Daniel M.; Wendt, Daniel S.; Petkovic, Lucia M.

    2014-06-10

    A method of removing a nonpolar solvent from a fluid volume that includes at least one nonpolar compound, such as a fat, an oil or a triglyceride, is provided. The method comprises contacting a fluid volume with an expanding gas to expand the nonpolar solvent and form a gas-expanded solvent. The gas-expanded solvent may have a substantially reduced density in comparison to the at least one nonpolar compound and/or a substantially reduced capacity to solubilize the nonpolar compound, causing the nonpolar compounds to separate from the gas-expanded nonpolar solvent into a separate liquid phase. The liquid phase including the at least one nonpolar compound may be separated from the gas-expanded solvent using conventional techniques. After separation of the liquid phase, at least one of the temperature and pressure may be reduced to separate the nonpolar solvent from the expanding gas such that the nonpolar solvent may be recovered and reused.

  13. Direct and semidirect aerosol effects of Southern African biomass burning aerosol

    SciTech Connect (OSTI)

    Sakaeda, Naoko; Wood, Robert; Rasch, Philip J.

    2011-06-21

    The direct and semi-direct radiative effects of biomass burning aerosols from Southern African fires during July-October are investigated using 20 year runs of the Community Atmospheric Model (CAM) coupled to a slab ocean model. The aerosol optical depth is constrained using observations in clear skies from MODIS and for aerosol layers above clouds from CALIPSO. Over the ocean, where the absorbing biomass burning aerosol layers are primarily located above cloud, negative top of atmosphere (TOA) semi-direct radiative effects associated with increased low cloud cover dominate over a weaker positive all-sky direct radiative effect (DRE). In contrast, over the land where the aerosols are often below or within cloud layers, reductions in cloud liquid water path (LWP) lead to a positive semi-direct radiative effect that dominates over a near-zero DRE. Over the ocean, the cloud response can be understood as a response to increased lower tropospheric stability (LTS) which is caused both by aerosol absorptive warming in overlying layers and surface cooling in response to direct aerosol forcing. The ocean cloud changes are robust to changes in the cloud parameterization (removal of the hard-wired dependence of clouds on LTS), suggesting that they are physically realistic. Over land where cloud cover changes are minimal, decreased LWP is consistent with weaker convection driven by increased static stability. Over the entire region the overall TOA radiative effect from the biomass burning aerosols is almost zero due to opposing effects over the land and ocean. However, the surface forcing is strongly negative requiring a reduction in precipitation. This is primarily realized through reductions in convective precipitation on both the southern and northern flanks of the convective precipitation region spanning the equatorial rainforest and the ITCZ in the southern Sahel. The changes are consistent with the low-level aerosol forced cooling pattern. The results highlight the importance of semi-direct radiative effects and precipitation responses for determining the climatic effects of aerosols in the African region.

  14. Wall Adhesion and Constitutive Modelling of Strong Colloidal Gels

    E-Print Network [OSTI]

    Daniel R. Lester; Richard Buscall; Anthony D. Stickland; Peter J. Scales

    2014-06-24

    Wall adhesion effects during batch sedimentation of strongly flocculated colloidal gels are commonly assumed to be negligible. In this study in-situ measurements of colloidal gel rheology and solids volume fraction distribution suggest the contrary, where significant wall adhesion effects are observed in a 110mm diameter settling column. We develop and validate a mathematical model for the equilibrium stress state in the presence of wall adhesion under both viscoplastic and viscoelastic constitutive models. These formulations highlight fundamental issues regarding the constitutive modeling of colloidal gels, specifically the relative utility and validity of viscoplastic and viscoelastic rheological models under arbitrary tensorial loadings. The developed model is validated against experimental data, which points toward a novel method to estimate the shear and compressive yield strength of strongly flocculated colloidal gels from a series of equilibrium solids volume fraction profiles over various column widths.

  15. A physical description of the adhesion and aggregation of platelets

    E-Print Network [OSTI]

    Chopard, Bastien; Latt, Jonas; Dubois, Frank; Yourassowsky, Catherine; Van Antwerpen, Pierre; Eker, Omer; Vanhamme, Luc; Perez-Morga, David; Courbebaisse, Guy; Boudjeltia, Karim Zouaoui

    2015-01-01

    The early stages of clot formation in blood vessels involve platelets adhesion-aggregation. Although these mechanisms have been extensively studied, gaps in their understanding still persist. We have performed detailed in-vitro experiments and developed a numerical model to better describe and understand this phenomenon. Unlike previous studies, we took into account both activated and non-activated platelets, as well as the 3D nature of the aggregation process. Our investigation reveals that blood albumin is a major parameter limiting platelet adhesion and aggregation. Our results also show that the well accepted Zydney-Colton shear-induced diffusivity is much too low to explain the observed deposition rate. Simulations are in very good agreement with observations and provide quantitative estimates of the adhesion and aggregation rates that are hard to measure experimentally.

  16. Surface Tension regularizes the Crack Singularity of Adhesive Contacts

    E-Print Network [OSTI]

    Stefan Karpitschka; Leen van Wijngaarden; Jacco H. Snoeijer

    2015-08-14

    The elastic and adhesive properties of a solid surface can be quantified by indenting it with a rigid sphere. Indentation tests are classically described by the JKR-law when the solid is very stiff, while recent work highlights the importance of surface tension for exceedingly soft materials. Here we show that surface tension plays a crucial role even for stiff solids: it regularizes the crack-like singularity at the edge of the contact. We find that the edge region exhibits a universal, self-similar structure that emerges from the balance of surface tension and elasticity. The similarity theory provides a complete description for adhesive contacts, reconciling the global adhesion laws and local contact mechanics.

  17. Development of Effective Solvent Modifiers for the Solvent Extraction of Cesium from Alkaline High-Level Tank Waste.

    SciTech Connect (OSTI)

    Bonnesen, Peter V.; Delmau, Laetitia H.; Moyer, Bruce A.; Lumetta, Gregg J. )

    2003-01-01

    A series of novel alkylphenoxy fluorinated alcohols were prepared and investigated for their effectiveness as modifiers in solvents containing calix[4]arene-bis-(tert-octylbenzo)-crown-6 for extracting cesium from alkaline nitrate media. A modifier that contained a terminal 1,1,2,2-tetrafluoroethoxy group was found to decompose following long-term exposure to warm alkaline solutions. However, replacement of the tetrafluoroethoxy group with a 2,2,3,3-tetrafluoropropoxy group led to a series of modifiers that possessed the alkaline stability required for a solvent extraction process. Within this series of modifiers, the structure of the alkyl substituent (tert-octyl, tert-butyl, tert-amyl, and sec-butyl) of the alkylphenoxy moiety was found to have a profound impact on the phase behavior of the solvent in liquid-liquid contacting experiments, and hence on the overall suitability of the modifier for a solvent extraction process. The sec-butyl derivative[1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol] (Cs-7SB) was found to possess the best overall balance of properties with respect to third phase and coalescence behavior, cleanup following degradation, resistance to solids formation, and cesium distribution behavior. Accordingly, this modifier was selected for use as a component of the solvent employed in the Caustic-Side Solvent Extraction (CSSX) process for removing cesium from high level nuclear waste (HLW) at the U.S. Department of Energy?s (DOE) Savannah River Site. In batch equilibrium experiments, this solvent has also been successfully shown to extract cesium from both simulated and actual solutions generated from caustic leaching of HLW tank sludge stored in tank B-110 at the DOE?s Hanford Site.

  18. Regulation of cell adhesion and cell death : the roles of the Abl tyrosine kinase and the retinoblastoma protein

    E-Print Network [OSTI]

    Huang, X.

    2007-01-01

    CD31-induced integrin adhesion. J Cell Biol, 2000. 148(6):stress fibers and focal adhesions. J Cell Biol, 1996. 133(Rap1 activation for cell adhesion and embryogenesis. Embo J,

  19. Contact time- and pH-dependent adhesion and cohesion of low molecular weight chitosan coated surfaces

    E-Print Network [OSTI]

    2015-01-01

    J. , & Waite, J. H. (2012). Adhesion mech- anism in a DOPA-D. S. (2013). Strong adhesion and cohesion of chitosan inMolecular weight effects in adhesion. Langmuir, 15(24),

  20. Contact mechanics with adhesion: Interfacial separation and contact area

    E-Print Network [OSTI]

    C. Yang; B. N. J. Persson; J. Israelachvili; K. Rosenberg

    2008-08-26

    We study the adhesive contact between elastic solids with randomly rough, self affine fractal surfaces. We present molecular dynamics (MD) simulation results for the interfacial stress distribution and the wall-wall separation. We compare the MD results for the relative contact area and the average interfacial separation, with the prediction of the contact mechanics theory of Persson. We find good agreement between theory and the simulation results. We apply the theory to the system studied by Benz et al. involving polymer in contact with polymer, but in this case the adhesion gives only a small modification of the interfacial separation as a function of the squeezing pressure.

  1. Collapse transition of flexible homopolymers with adhesive contacts

    E-Print Network [OSTI]

    Sid Ahmed Sabeur; Mounira Bouarkat; Friederike Schmid

    2011-06-26

    The presence of ordered structures such as helices in collapsed states of polymer chains is still an open question challenging physics and biology. In this work, we present a potential model for polymer chains with monomers that are not strictly attractive, but that can make adhesive contacts with other monomers. We find that the chain develop helical order during the process of collapsing from an initially stretched conformation. It seems in this case that the adhesive contacts help the polymer chain to stay trapped in the helix state.

  2. Strong dynamical effects during stick-slip adhesive peeling

    E-Print Network [OSTI]

    Marie-Julie Dalbe; Stéphane Santucci; Pierre-Philippe Cortet; Loïc Vanel

    2013-11-14

    We consider the classical problem of the stick-slip dynamics observed when peeling a roller adhesive tape at a constant velocity. From fast imaging recordings, we extract the dependencies of the stick and slip phases durations with the imposed peeling velocity and peeled ribbon length. Predictions of Maugis and Barquins [in Adhesion 12, edited by K.W. Allen, Elsevier ASP, London, 1988, pp. 205--222] based on a quasistatic assumption succeed to describe quantitatively our measurements of the stick phase duration. Such model however fails to predict the full stick-slip cycle duration, revealing strong dynamical effects during the slip phase.

  3. Ion Exchange and Solvent Extraction: Supramolecular Aspects of Solvent Exchange Volume 21

    SciTech Connect (OSTI)

    Gloe, Karsten [Technischen Universität Dresden] [Technischen Universität Dresden; Tasker, Peter A [ORNL] [ORNL; Oshima, Tatsuya [University of Miyazaki] [University of Miyazaki; Watarai, Hitoshi [Institute for NanoScience Design at Osaka University] [Institute for NanoScience Design at Osaka University; Nilsson, Mikael [University of California, Irvine] [University of California, Irvine

    2013-01-01

    Preface The theme of supramolecular chemistry (SC), entailing the organization of multiple species through noncovalent interactions, has permeated virtually all aspects of chemical endeavor over the past several decades. Given that the observed behavior of discrete molecular species depends upon their weak interactions with one another and with matrix components, one would have to conclude that SC must indeed form part of the fabric of chemistry itself. A vast literature now serves to categorize SC phenomena within a body of consistent terminology. The word supramolecular itself appears in the titles of dozens of books, several journals, and a dedicated encyclopedia. Not surprisingly, the theme of SC also permeates the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. It is attempted in the six chapters of this volume to identify both how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the current direction of SX. Researchers and practitioners have long dealt with supramolecular interactions in SX. Indeed, the use of polar extractant molecules in nonpolar media virtually assures that aggregative interactions will dominate the solution behavior of SX. Analytical chemists working in the 1930s to the 1950s with simple mono- and bidentate chelating ligands as extractants noted that extraction of metal ions obeyed complicated mass-action equilibria involving complex stoichiometries. As chemists and engineers developed processes for nuclear and hydrometallurgical applications in the 1950s and 1960s, the preference for aliphatic diluents only enhanced the complexity and supramolecular nature of extraction chemistry. Use of physical techniques such as light scattering and vapor-pressure measurements together with various spectroscopic methods revealed organic-phase aggregates from well-defined dimers to small aggregates containing a few extractant molecules to large inverse micelles swollen with water molecules. Extraction systems involving long-chain cations such as alkylammonium species or long-chain anions such as sulfonates or carboxylates proved especially prone to extensive aggregate formation. The related phenomenon of third-phase formation in SX systems, long misunderstood, is now yielding to spectroscopic and scattering techniques showing extensive long-range organization. Over the last 50 years, tools for studying the structure and thermodynamics of aggregation have grown increasingly sophisticated, leading to a rich and detailed understanding of what we can now recognize as SC phenomena in SX. In the 1970s and 1980s, the rapid growth of SC elicited a paradigm shift in SX. The influence of SC principles had two major effects on the course of SX research. First, it provided a framework for understanding the supramolecular behavior that was already well appreciated in the field of SX, though earlier without the SC terminology. Second, it provided the conceptual tools to control supramolecular behavior in SX, direct it for intended functionality, and to simplify it. Extraction by designed reagents has been steadily progressing ever since, with commercial applications emerging to successfully validate this approach. With the discovery of crown ethers in the late 1960s, the advancement of extractant design has fruitfully employed the concept of inclusion. While considerable initial progress occurred with such molecules, especially because of their affinity and selectivity for alkali and alkaline earth metals, other molecular platforms such as calixarenes have proven more versatile. Multidentate receptors for partial to full inclusion of cations, anions, ion pairs, as well as neutral species, have now become commonplace for selective extraction. This volume of Ion Exchange and Solvent Extraction examines how the principles of SC are being employed both in advancing the design of new highly selective SX systems and in understanding aggregation phenomena in SX systems. Chapter 1 discusses the nature and definition of SC

  4. Development of novel contactor for nuclear solvent extraction

    SciTech Connect (OSTI)

    Kumar, Shekhar; Kumar, Rajnish; Sivakumar, D.; Balamurugan, M.; Koganti, S.B.

    2008-07-01

    For current designs of radiochemical plants, solvent-extraction contactors with no periodic maintenance like pulse column are the first choice. In addition, as costs of specialty solvents for nuclear extraction are quite high, there is a demand for operation at extreme phase ratios. Recently a novel mixer-settler was visualized and developed for this kind of service. The mixer of the novel contactor is based on rotated helical tubes and does not involve any mechanical moving part. Mass-transfer runs were carried out with aqueous nitric acid and 30% TBP solvent at A/O of 0.25-200 (in extraction) and A/O of 0.25-10 (in back-extraction mode). The developed contactor exhibited nearly 100% efficiency for all the cases. (authors)

  5. Substrate adhesion of a nongrafted flexible polymer in a cavity Michael Bachmann* and Wolfhard Janke

    E-Print Network [OSTI]

    Janke, Wolfhard

    Substrate adhesion of a nongrafted flexible polymer in a cavity Michael Bachmann* and Wolfhard adhesive surface. An example for the cavity model is shown in Fig. 1. The polymer can move between the two

  6. Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inspection of Adhesive Bonds in Metal-Metal Joints Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  7. Biomaterials 24 (2003) 37573764 Cell adhesion on gaseous plasma modified poly-(l-lactide) surface

    E-Print Network [OSTI]

    Yang, Jian

    2003-01-01

    Biomaterials 24 (2003) 3757­3764 Cell adhesion on gaseous plasma modified poly-(l-lactide) surface properties of biomaterials. It is commonly accepted that the adhesion of cells to solid substrata

  8. Rate Effects for Mixed-Mode Fracture of Plastically Deforming, Adhesively-Bonded Structures

    E-Print Network [OSTI]

    Thouless, Michael

    from a commercial adhesive and a dual-phase steel has been studied under different rates. Since mixed- mode fracture occurs along the interface between the steel and adhesive, the cohesive- parameters

  9. Production of polystyrene particles via aerosolization 

    E-Print Network [OSTI]

    Norasetthekul, Somchintana

    1995-01-01

    at high temperature studied by Chiang and Prud'homme, a uniform PS concentration within droplets was likely in our case. As solvent evaporates, van der Waals forces and subsequent entanglement of polymer chains causes solidification. The PS-benzene phase...

  10. Industrial application of GNEP solvent-extraction processes

    SciTech Connect (OSTI)

    Arm, S.T.; Phillips, C.; Dobson, A.

    2008-07-01

    EnergySolutions is currently studying the feasibility of commercially recycling spent nuclear fuel in the USA as part of the Global Nuclear Energy Partnership. Uranium, plutonium, and neptunium recycling are accomplished by employing well-established solvent-extraction technology based on the tributylphosphate extractant and acetohydroxamic complexant stripping in a commercially demonstrated configuration. Americium and curium recycling is best achieved by employing the TRUEX and TALSPEAK solvent-extraction processes or a simplified variant of them. Facility design is not predicated on performing any research and development a priori. Process development and demonstration will proceed in parallel with design by proven design-management techniques. (authors)

  11. Degradation problems with the solvent extraction organic at Roessing uranium

    SciTech Connect (OSTI)

    Munyungano, Brodrick; Feather, Angus; Virnig, Michael

    2008-07-01

    Roessing Uranium Ltd recovers uranium from a low-grade ore in Namibia. Uranium is recovered and purified from an ion-exchange eluate in a solvent-extraction plant. The solvent-extraction plant uses Alamine 336 as the extractant for uranium, with isodecanol used as a phase modifier in Sasol SSX 210, an aliphatic hydrocarbon diluent. Since the plant started in the mid 1970's, there have been a few episodes where the tertiary amine has been quickly and severely degraded when the plant was operated outside certain operating parameters. The Rossing experience is discussed in more detail in this paper. (authors)

  12. Laminin isoforms differentially regulate adhesion, spreading, proliferation, and ERK activation of h1 integrin-null cells

    E-Print Network [OSTI]

    Campbell, Kevin P.

    Laminin isoforms differentially regulate adhesion, spreading, proliferation, and ERK activation signal-regulated kinase (ERK) activation, whereas all these responses occurred in response to adhesion

  13. Contact Mechanics Modeling of Homogeneous and Layered Elastic-Plastic Media: Surface Roughness and Adhesion Effects

    E-Print Network [OSTI]

    Song, Zhichao

    2012-01-01

    adhesion in microelectromechanical systems. ASME J. Tribol.microtribology for microelectromechanical systems. Wear 200,forces in microelectromechanical systems: mechanisms,

  14. Contact Mechanics Modeling of Homogeneous and Layered Elastic-Plastic Media: Surface Roughness and Adhesion Effects

    E-Print Network [OSTI]

    Song, Zhichao

    2012-01-01

    surface adhesion in microelectromechanical systems. ASME J.microtribology for microelectromechanical systems. Wear 200,forces in microelectromechanical systems: mechanisms,

  15. Total aerosol effect: forcing or radiative flux perturbation?

    SciTech Connect (OSTI)

    Lohmann, Ulrike; Storelvmo, Trude; Jones, Andy; Rotstayn, Leon; Menon, Surabi; Quaas, Johannes; Ekman, Annica; Koch, Dorothy; Ruedy, Reto

    2009-09-25

    Uncertainties in aerosol forcings, especially those associated with clouds, contribute to a large extent to uncertainties in the total anthropogenic forcing. The interaction of aerosols with clouds and radiation introduces feedbacks which can affect the rate of rain formation. Traditionally these feedbacks were not included in estimates of total aerosol forcing. Here we argue that they should be included because these feedbacks act quickly compared with the time scale of global warming. We show that for different forcing agents (aerosols and greenhouse gases) the radiative forcings as traditionally defined agree rather well with estimates from a method, here referred to as radiative flux perturbations (RFP), that takes these fast feedbacks and interactions into account. Thus we propose replacing the direct and indirect aerosol forcing in the IPCC forcing chart with RFP estimates. This implies that it is better to evaluate the total anthropogenic aerosol effect as a whole.

  16. Climate Engineering with Stratospheric Aerosols and Associated Engineering Parameters

    SciTech Connect (OSTI)

    Kravitz, Benjamin S.

    2013-02-12

    Climate engineering with stratospheric aerosols, an idea inspired by large volcaniceruptions, could cool the Earth’s surface and thus alleviate some of the predicted dangerous impacts of anthropogenic climate change. However, the effectiveness of climate engineering to achieve a particular climate goal, and any associated side effects, depend on certain aerosol parameters and how the aerosols are deployed in the stratosphere. Through the examples of sulfate and black carbon aerosols, this paper examines "engineering" parameters-aerosol composition, aerosol size, and spatial and temporal variations in deployment-for stratospheric climate engineering. The effects of climate engineering are sensitive to these parameters, suggesting that a particle could be found ordesigned to achieve specific desired climate outcomes. This prospect opens the possibility for discussion of societal goals for climate engineering.

  17. Aerosol Retrievals from ARM SGP MFRSR Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Alexandrov, Mikhail

    2008-01-15

    The Multi-Filter Rotating Shadowband Radiometer (MFRSR) makes precise simultaneous measurements of the solar direct normal and diffuse horizontal irradiances at six wavelengths (nominally 415, 500, 615, 673, 870, and 940 nm) at short intervals (20 sec for ARM instruments) throughout the day. Time series of spectral optical depth are derived from these measurements. Besides water vapor at 940 nm, the other gaseous absorbers within the MFRSR channels are NO2 (at 415, 500, and 615 nm) and ozone (at 500, 615, and 670 nm). Aerosols and Rayleigh scattering contribute atmospheric extinction in all MFRSR channels. Our recently updated MFRSR data analysis algorithm allows us to partition the spectral aerosol optical depth into fine and coarse modes and to retrieve the fine mode effective radius. In this approach we rely on climatological amounts of NO2 from SCIAMACHY satellite retrievals and use daily ozone columns from TOMS.

  18. Aerosol Retrievals from ARM SGP MFRSR Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Alexandrov, Mikhail

    The Multi-Filter Rotating Shadowband Radiometer (MFRSR) makes precise simultaneous measurements of the solar direct normal and diffuse horizontal irradiances at six wavelengths (nominally 415, 500, 615, 673, 870, and 940 nm) at short intervals (20 sec for ARM instruments) throughout the day. Time series of spectral optical depth are derived from these measurements. Besides water vapor at 940 nm, the other gaseous absorbers within the MFRSR channels are NO2 (at 415, 500, and 615 nm) and ozone (at 500, 615, and 670 nm). Aerosols and Rayleigh scattering contribute atmospheric extinction in all MFRSR channels. Our recently updated MFRSR data analysis algorithm allows us to partition the spectral aerosol optical depth into fine and coarse modes and to retrieve the fine mode effective radius. In this approach we rely on climatological amounts of NO2 from SCIAMACHY satellite retrievals and use daily ozone columns from TOMS.

  19. Design of Aerosol Face Masks for Children Using Computerized 3D Face Analysis

    E-Print Network [OSTI]

    Kimmel, Ron

    seal to the child's face, and thus may minimize aerosol leakage and dead space. Key words: inhaled supplied with valved aerosol hold- ing chambers used for aerosol therapy. (Adapted with per- mission from

  20. Coordination of Contractility, Adhesion and Flow in Migrating Physarum Amoebae

    E-Print Network [OSTI]

    Guy, Bob

    by contracting and pushing-off the surrounding environment. This versatility has also spurred the exploratory, substrate adhesion and cytoplasmic flow in migrating amoebae of the slime mold Physarum polycephalum network. This flow is driven by pressure gradients created by contraction of the actomyosin network within

  1. Fine tuning of graphene-metal adhesion by surface alloying

    E-Print Network [OSTI]

    Alfè, Dario

    Fine tuning of graphene-metal adhesion by surface alloying D. Alfe`1,2 , M. Pozzo1 , E. Miniussi3 route for governing the interaction between graphene and metal through the selective choice characterization of the properties of graphene on a model PtRu surface alloy on Ru(0001), with a concentration

  2. Adhesion-Induced Instability Patterns in Thin Confined Elastic Film

    E-Print Network [OSTI]

    Chaudhury, Manoj K.

    the instability while not determining its wavelength. The instability also throws light on cavitation phenomena in confined adhesive layers. Introduction Hydrodynamic-force-driven nonequilibrium systems give rise to many Deborah numbers (De , 1), the hydrodynamic forces dominate pattern formation, whereas at high Deborah

  3. Slippery or sticky ! Control of wrinkling patterns by selective adhesion

    E-Print Network [OSTI]

    Hugues Vandeparre; Julien Léopoldès; Christophe Poulard; Sylvain Desprez; Gwennaelle Derue; Cyprien Gay; Pascal Damman

    2007-06-28

    Wrinkling patterns at the metallized surface of thin polymer films are shown to be sensitive to the sticky or slippery character of the polymer/substrate interface (titanium coating, polystyrene film and coated silicon substrate). Selective prefered wrinkle orientation and amplitude are achieved. Existing theoretical models are expanded to specific boundary conditions (adhesive vs slippery) and rationalize these observations.

  4. Molecular assemblies as protective barriers and adhesion promotion interlayer

    DOE Patents [OSTI]

    King, David E. (Lakewood, CO); Czanderna, Alvin W. (Denver, CO); Kennedy, Cheryl E. (Lafayette, CO)

    1996-01-01

    A protective diffusion barrier having adhesive qualifies for metalized surfaces is provided by a passivating agent having the formula HS--(CH.sub.2).sub.11 --COOH Which forms a very dense, transparent organized molecular assembly or layer that is impervious to water, alkali, and other impurities and corrosive substances that typically attack metal surfaces.

  5. Molecular assemblies as protective barriers and adhesion promotion interlayer

    DOE Patents [OSTI]

    King, D.E.; Czanderna, A.W.; Kennedy, C.E.

    1996-01-30

    A protective diffusion barrier having adhesive qualities for metalized surfaces is provided by a passivating agent having the formula HS--(CH{sub 2}){sub 11}--COOH which forms a very dense, transparent organized molecular assembly or layer that is impervious to water, alkali, and other impurities and corrosive substances that typically attack metal surfaces. 8 figs.

  6. Adhesion and the Geometry of the Cosmic Web

    E-Print Network [OSTI]

    Johan Hidding; Rien van de Weygaert; Gert Vegter; Bernard J. T. Jones

    2012-11-22

    We present a new way to formulate the geometry of the Cosmic Web in terms of Lagrangian space. The Adhesion model has an ingenious geometric interpretation out of which the spine of the Cosmic Web emerges naturally. Within this context we demonstrate a deep connection of the relation between Eulerian and Lagrangian space with that between Voronoi and Delaunay tessellations.

  7. ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS

    E-Print Network [OSTI]

    Matsuoka, Hiroshige

    ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS H. MATSUOKA1 , T] or meniscus force [3], which have been neglected in the conventional and relatively large mechani- cal systems forces between mica surfaces in under- saturated vapors of several kind of hydrocarbon liquids are mea

  8. RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES

    E-Print Network [OSTI]

    Nairn, John A.

    RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES JOHN A. NAIRN ABSTRACT Because by including residual stresses in fracture mechanics models of failure. This chapter gives general results examples of including residual stresses in fracture mechanics interpretation of experimental results

  9. Slide diamond burnishing of tool steels with adhesive coatings and diffusion layers

    E-Print Network [OSTI]

    North Texas, University of

    Slide diamond burnishing of tool steels with adhesive coatings and diffusion layers W. Brostow*1 modification of selected tool steels. The steels were covered with adhesive coatings of the hard chrome type was determined by a profilometer before and after burnishing. Adhesion of coatings to steel was determined

  10. Wet and Dry Adhesion Properties of Self-Selective Nanowire Connectors

    E-Print Network [OSTI]

    Javey, Ali

    Wet and Dry Adhesion Properties of Self-Selective Nanowire Connectors By Hyunhyub Ko, Zhenxing,for example, the amazing adhesion abilities of gecko feet,[3­8] the self- cleaning superhydrophobic surface that enable efficient binding with self-similar surfaces but weak adhesion towards other surfaces

  11. Engineering cell adhesion for applications in biotechnology Celeste M. Nelson and Christopher S. Chen*

    E-Print Network [OSTI]

    Chen, Christopher S.

    1 Engineering cell adhesion for applications in biotechnology Celeste M. Nelson and Christopher S underlying adhesion between cells and their underlying substratum. We describe the current model of cell adhesion and the use of micropatterned surfaces to control cell behavior. #12;3 1. Introduction Living

  12. Adhesion through Single Peptide Aptamers Marie-Eve Aubin-Tam,,

    E-Print Network [OSTI]

    Lang, Matthew

    Adhesion through Single Peptide Aptamers Marie-Eve Aubin-Tam,,§ David C. Appleyard,,| Enrico Aptamer and antibody mediated adhesion is central to biological function and is valuable Noncovalent interactions drive a myriad of biological pro- cesses such as association, adhesion, motility

  13. Underwater adhesion of abalone: The role of van der Waals and capillary forces

    E-Print Network [OSTI]

    Meyers, Marc A.

    Underwater adhesion of abalone: The role of van der Waals and capillary forces A.Y.M. Lin d,*, R reserved. Keywords: Abalone foot; Underwater adhesion; Van der Waals forces 1. Introduction Numerous and capillary forces gen- erated by nanoscaled fibrils on their feet [1­4]. Addition- ally, similar adhesive

  14. Interaction of laser-generated surface acoustic pulses with fine particles: Surface cleaning and adhesion studies

    E-Print Network [OSTI]

    Schuessler, Hans

    and adhesion studies Al. A. Kolomenskiia) and H. A. Schuessler Department of Physics, Texas A&M University of the adhesion force. © 1998 American Institute of Physics. S0021-8979 98 02317-2 I. INTRODUCTION of the adhesive forces. In the present work a novel cleaning technique with laser-generated surface acoustic waves

  15. Measurement of the adhesion of a brittle film on a ductile substrate by indentation

    E-Print Network [OSTI]

    Hutchinson, John W.

    Measurement of the adhesion of a brittle film on a ductile substrate by indentation BY M. D. DRORY1 is analysed for obtaining the interfacetoughness. This measurementmethod of adhesion provides a simple be present. The aspect of film reliability explored here is the measurementof adhesion for brittle coatings

  16. A Thermoplastic/Thermoset Blend Exhibiting Thermal Mending and Reversible Adhesion

    E-Print Network [OSTI]

    Mather, Patrick T.

    A Thermoplastic/Thermoset Blend Exhibiting Thermal Mending and Reversible Adhesion Xiaofan Luo that the DEB phenomenon enables strong and facile adhesion of the same material to itself and to a variety separation · epoxy · self-healing · fracture · adhesion INTRODUCTION P olymeric materials, such as high

  17. Adhesion transition of flexible sheets Arthur A. Evans1,* and Eric Lauga2,

    E-Print Network [OSTI]

    Lauga, Eric

    Adhesion transition of flexible sheets Arthur A. Evans1,* and Eric Lauga2, 1 Department of Physics to precipitate adhesion events between solid bodies. Inspired by a macro- scale experiment showing the hysteretic adhesion of a piece of flexible tape over a plastic substrate, we develop here a model of far-field dry

  18. DOI: 10.1002/cbic.200900425 Potent Fluoro-oligosaccharide Probes of Adhesion in

    E-Print Network [OSTI]

    Davis, Ben G.

    DOI: 10.1002/cbic.200900425 Potent Fluoro-oligosaccharide Probes of Adhesion in Toxoplasmosis Sarah-called micronemal proteins (MICs) that mediate this first-phase adhesion not only by direct binding to host cell sur), as putative ligands and shown that these are recognised by the microneme adhesive repeat (MAR) domains of Tg

  19. Adhesion G Protein-Coupled Receptors: Signaling, Pharmacology, and Mechanisms of Activation

    E-Print Network [OSTI]

    Hall, Randy A

    MINIREVIEW Adhesion G Protein-Coupled Receptors: Signaling, Pharmacology, and Mechanisms, Atlanta, Georgia Received May 30, 2012; accepted July 20, 2012 ABSTRACT The adhesion G protein by extremely large N termini featuring various adhesion domains capable of mediating cell-cell and cell

  20. Accepted Manuscript Adhesion and collisional release of particles in dense planetary rings

    E-Print Network [OSTI]

    Potsdam, Universität

    Accepted Manuscript Adhesion and collisional release of particles in dense planetary rings Anna, F., Brilliantov, N., Adhesion and collisional release of particles in dense planetary rings, Icarus could affect the content, and all legal disclaimers that apply to the journal pertain. #12;Adhesion

  1. The cadherincatenin complex as a focal point of cell adhesion and

    E-Print Network [OSTI]

    Ikura, Mitsuhiko

    The cadherin­catenin complex as a focal point of cell adhesion and signalling: new insights from cell adhesion. The cadherin molecules com- prise three domains, the intracellular domain, the trans, cadherin enhances its adhesive properties binding the cytoskeleton via cytoplasmic associated factors a

  2. Adhesion strength measurement of polymer dielectric interfaces using laser spallation technique

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Adhesion strength measurement of polymer dielectric interfaces using laser spallation technique on the interface adhesion strength is investigated. The interface strength values correlate strongly with the PBO formulation and surface roughness of the substrate. Effect of autoclaving on the interface adhesion strength

  3. The Two-Pathway Model for the Catch-Slip Transition in Biological Adhesion

    E-Print Network [OSTI]

    The Two-Pathway Model for the Catch-Slip Transition in Biological Adhesion Yuriy V. Pereverzev. (1) in a mathematical description of membrane-to- surface adhesion and detachment. In this work adhesion protein FimH was shown to undergo a force-induced conformational change that led to stronger

  4. Simulation of Cell Adhesion to Bioreactive Surfaces in Shear: The Effect of Cell Size

    E-Print Network [OSTI]

    Tees, David F.J.

    Simulation of Cell Adhesion to Bioreactive Surfaces in Shear: The Effect of Cell Size David F. J Engineering, Cornell University, Ithaca, New York 14853 Leukocyte adhesion under flow in the microvasculature is a multistep process in which rolling adhesion is followed by firm arrest. These interactions are mediated

  5. Adhesion of Bacterial Exopolymers to r-FeOOH: Inner-Sphere Complexation of Phosphodiester Groups

    E-Print Network [OSTI]

    Chorover, Jon

    Adhesion of Bacterial Exopolymers to r-FeOOH: Inner-Sphere Complexation of Phosphodiester Groups of polyelectrolytes that mediate biomineralization and bacterial adhesion and stabilize biofilm matrixes in natural-FeOOH) surface, providing an energetically stable bond for further EPS or cell adhesion. 1. Introduction

  6. Adhesion energy in nanogap InP/InGaAs microcantilevers Jan D. Makowski,a

    E-Print Network [OSTI]

    Talghader, Joseph J.

    Adhesion energy in nanogap InP/InGaAs microcantilevers Jan D. Makowski,a Anand S. Gawarikar 2006 The adhesion energy is measured between InGaAs quantum wells that have collapsed across a 125 nm and shape of collapsed microcantilevers with optical interferometry. The adhesion energy is found to be 72

  7. THEORETICAL & APPLIED MECHANICS LETTERS 1, 011001 (2011) Contact radius of stamps in reversible adhesion

    E-Print Network [OSTI]

    Rogers, John A.

    2011-01-01

    adhesion Jian Wu,1 Seok Kim,2 Andrew Carlson,2 Chaofeng Lu,1, 3 Keh-Chih Hwang,4 Yonggang Huang,1, a. This is important to the realization of reversible control of adhesion, which has many important applications linearly with the work of adhesion between the stamp and the contacting surface, and inversely

  8. Mechanical switching and coupling between two dissociation pathways in a P-selectin adhesion bond

    E-Print Network [OSTI]

    Heinrich, Volkmar

    Mechanical switching and coupling between two dissociation pathways in a P-selectin adhesion bond energy barrier. Using a sensitive force probe to test the leukocyte adhesion bond P-selectin glycoprotein interactions among large multidomain proteins underlie most adhesive functions in biology. Well known

  9. Adhesion-Induced DNA Naturation A. E. Allahverdyan,1,2

    E-Print Network [OSTI]

    Adhesion-Induced DNA Naturation A. E. Allahverdyan,1,2 Zh. S. Gevorkian,1,3,4 Chin-Kun Hu,4 and Th of the genetic information. We shall study the adsorption and surface (adhesion) induced naturation of a double some features of DNA (see below), our model predicts two mechanisms of adhesion-induced naturation

  10. Linking molecular affinity and cellular specificity in cadherin-mediated adhesion

    E-Print Network [OSTI]

    Ben-Shaul, Avinoam

    Linking molecular affinity and cellular specificity in cadherin-mediated adhesion P. Katsambaa,b,1 Kingdom Contributed by Barry H. Honig, May 15, 2009 (sent for review May 4, 2009) Many cell­cell adhesive is poorly understood, in part because the relationship between cellular adhesive specificity and intermolec

  11. Dynamic response of adhesion complexes: Beyond the single-path picture Denis Bartolo,1,

    E-Print Network [OSTI]

    Derényi, Imre

    Dynamic response of adhesion complexes: Beyond the single-path picture Denis Bartolo,1, * Imre Dere, France Received 25 June 2001; published 10 May 2002 We analyze the response of molecular adhesion put forward to probe the unfolding of proteins and to quantify the strength of adhesion structures 1

  12. NOVEL ADHESION TEST FOR ENVIRONMENTALLY ASSISTED FRACTURE IN THIN Alex A. Volinsky and Patrick Waters

    E-Print Network [OSTI]

    Volinsky, Alex A.

    NOVEL ADHESION TEST FOR ENVIRONMENTALLY ASSISTED FRACTURE IN THIN FILMS Alex A. Volinsky coating adhesion quantitatively, taking into account environmental effects. This paper describes general films (DLC) used in the hard drive industry as an example. DLC film adhesion has been measured to drop

  13. Adhesion energy in carbon nanotube-polyethylene composite: Effect of chirality

    E-Print Network [OSTI]

    Garmestani, Hamid

    Adhesion energy in carbon nanotube-polyethylene composite: Effect of chirality M. Al-Haik and M. Y 2005 This work presents a study of the adhesion energy between carbon nanotube-polyethylene matrix nanotube chirality on adhesion energy. It is observed that composites that utilize nanotubes with smaller

  14. Specific adhesion of peptides on semiconductor surfaces in experiment and simulation

    E-Print Network [OSTI]

    Janke, Wolfhard

    Specific adhesion of peptides on semiconductor surfaces in experiment and simulation Karsten Goede by a factor of 25, depending mainly on surface and peptide polarity. Low adhesion induces large and soft clusters, which also have high contact angles to the surface. Direct surface adhesion of a peptide molecule

  15. Directional adhesion of gecko-inspired angled microfiber arrays Jongho Lee,1

    E-Print Network [OSTI]

    Fearing, Ron

    Directional adhesion of gecko-inspired angled microfiber arrays Jongho Lee,1 Ronald S. Fearing,2. Friction experiments demonstrated that this fibrillar polymer surface exhibits directional adhesion adhesion is interpreted in the context of a nonlinear elastic bending model of an angled beam. Shearing

  16. Simulating Anti-adhesive and Antibacterial Bifunctional Polymers for Surface Coating using BioScape

    E-Print Network [OSTI]

    Compagnoni, Adriana

    Simulating Anti-adhesive and Antibacterial Bifunctional Polymers for Surface Coating using Bio a computational model of anti-adhesive and antibacterial bifunctional polymers for sur- face coating developed by Henk Busscher's Group in Gronin- gen, The Netherlands. The bifunctional brushes act as anti- adhesive

  17. About contacts of adhesive, elasto-plastic, frictional powders Stefan Luding

    E-Print Network [OSTI]

    Luding, Stefan

    About contacts of adhesive, elasto-plastic, frictional powders Stefan Luding Multi Scale Mechanics with peculiar pressure dependence, for adhesive powders ­ due to the nonlinear dependence of the contact adhesion on the confining forces. Introduction Granular materials have various applications, involving geo

  18. Physics/Mathematics double degree BSc project: Adhesive Force of Droplets with Increasingly Realistic

    E-Print Network [OSTI]

    Vuik, Kees

    Physics/Mathematics double degree BSc project: Adhesive Force of Droplets with Increasingly to predict how the adhesive force depends on the droplet properties. What is this project about? In this project you theoretically and numerically investigate how the adhesive force depends on two key parameters

  19. Molecular Dynamics modelling of the adhesive interaction between fine F. A. Gilabert

    E-Print Network [OSTI]

    Krivtsov, Anton M.

    Molecular Dynamics modelling of the adhesive interaction between fine particles F. A. Gilabert the frictionless adhesive interaction force between two fine cohesive polymer grains. The model consists of three a higher resolution near the contact area. Secondly, the cohesion strength (i.e., the work of adhesion

  20. Role of Interfacial Resistance to Shear Stress on Adhesive Peel Strength

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    Role of Interfacial Resistance to Shear Stress on Adhesive Peel Strength Nicolas Amouroux, Je,13,1805-1809;Langmuir1998,14,4865-4872),whichgavethefirstevidenceofinterfacial slip when a pressure-sensitive adhesive and result in weak shear deformations in the adhesive. Thus, depending on the composition of the elastomer

  1. Tearing as a test for mechanical characterization of thin adhesive films

    E-Print Network [OSTI]

    Reis, Pedro Miguel

    ARTICLES Tearing as a test for mechanical characterization of thin adhesive films EUGENIO HAMM1 adhesive films have become increasingly important in applications involving packaging, coating of the conversion of bending energy into surface energy of fracture and adhesion. In particular, this triangular

  2. An energy-momentum-conserving temporal discretization scheme for adhesive contact problems

    E-Print Network [OSTI]

    An energy-momentum-conserving temporal discretization scheme for adhesive contact problems Sachin S' knowledge, none have been proposed for adhesive contact problems. In this work, an energy-momentum-conserving temporal discretization scheme for adhesive contact problems is proposed. A contact criterion is also

  3. Available online at www.sciencedirect.com Visualizing and quantifying adhesive signals

    E-Print Network [OSTI]

    Available online at www.sciencedirect.com Visualizing and quantifying adhesive signals Mohsen and signaling of adhesion sites in response to mechanical stimuli requires in situ characterization of the dynamic activation of a large number of adhesion components. Here, we review high-resolution live cell

  4. EFFECT OF HEATING ON THE STRUCTURE OF AN ADHESIVE JOINT, AS INDICATED BY ELECTRICAL

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    NOTE EFFECT OF HEATING ON THE STRUCTURE OF AN ADHESIVE JOINT, AS INDICATED BY ELECTRICAL RESISTANCE was found to cause a partly reversible effect on the structure of an adhesive (epoxy) joint involving steel expansion of the adhesive. The ir- reversible portion was due to an irreversible microstructural change

  5. Analysis of a temperature-dependent model for adhesive contact with Elena Bonetti

    E-Print Network [OSTI]

    Rossi, Riccarda

    Analysis of a temperature-dependent model for adhesive contact with friction Elena Bonetti , Giovanna Bonfanti , and Riccarda Rossi Abstract We propose a model for (unilateral) contact with adhesion´emond's approach, adhesion is described in terms of a surface damage parameter . The related equations

  6. Mixed-mode interfacial adhesive strength of a thin film on an anisotropic substrate

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Mixed-mode interfacial adhesive strength of a thin film on an anisotropic substrate Rajesh Kiteya adhesion strength between a gold (Au) thin film and an anisotropic passivated silicon (Si) substrate delamination remain a major reliability concern as interfacial properties, in particular interfacial adhesion

  7. From an adhesive to a brittle delamination model in thermo-visco-elasticity

    E-Print Network [OSTI]

    Rossi, Riccarda

    From an adhesive to a brittle delamination model in thermo-visco-elasticity Riccarda Rossi Marita words and phrases: Rate-independent evolution of adhesive contact, brittle delamination, Kelvin- Voigt of generalized standard materials [HN75]. More precisely, the adhesiveness of the bonding is modeled with the aid

  8. Attribution of Graphs by Composition of M, N -adhesive Categories: Long Version

    E-Print Network [OSTI]

    Habel, Annegret

    Attribution of Graphs by Composition of M, N -adhesive Categories: Long Version Christoph Peuser,habel}@informatik.uni-oldenburg.de Abstract. This paper continues the work on M, N-adhesive categories and shows some important constructions on these categories. We use these constructions for an alternative, short proof for the M, N-adhesive- ness

  9. Biomimetic soy protein nanocomposites with calcium carbonate crystalline arrays for use as wood adhesive

    E-Print Network [OSTI]

    adhesive Dagang Liu a,b,*, Huihuang Chen a , Peter R. Chang c , Qinglin Wu b , Kaifu Li a , Litao Guan 2010 Available online 21 March 2010 Keywords: Wood glue Calcium carbonate Gecko adhesion Soy protein soy protein-based adhesives still have not been widely adopted by industry, partially due

  10. Adhesively bonded lap joints with extreme interface geometry Babak Haghpanah, Shihung Chiu, Ashkan Vaziri n

    E-Print Network [OSTI]

    Vaziri, Ashkan

    Adhesively bonded lap joints with extreme interface geometry Babak Haghpanah, Shihung Chiu, Ashkan 2013 Keywords: Adhesively bonded joint Interface profile Failure Finite element a b s t r a c t The role of adhesive­adherend interface morphology (through intentional deviation from a flat joint plane

  11. Construction of microfluidic chips using polydimethylsiloxane for adhesive Hongkai Wu, Bo Huang and Richard N. Zare*

    E-Print Network [OSTI]

    Zare, Richard N.

    Construction of microfluidic chips using polydimethylsiloxane for adhesive bonding{ Hongkai Wu, Bo plate). The effects of the adhesive layer on the electroosmotic flow (EOF) in glass channels of approximately 10 to 500 mm, a y200­500 nm thick adhesive layer creates a bond without voids or excess material

  12. Supplementary Information for "Tearing as a Test for Mechanical Characterization of Thin Adhesive Films"

    E-Print Network [OSTI]

    Reis, Pedro Miguel

    Supplementary Information for "Tearing as a Test for Mechanical Characterization of Thin Adhesive a better estimation of the fracture force, we extract the adhesion from the slopes in Fig. 3 and plot that adhesion energy is com- parable to the fracture force. This happens when W 2 t cos in equation (7), or L

  13. PERSPECTIVES Nano-to-Microscale Mechanical Switches and Fuses Mediate Adhesive Contacts between

    E-Print Network [OSTI]

    Heinrich, Volkmar

    PERSPECTIVES Nano-to-Microscale Mechanical Switches and Fuses Mediate Adhesive Contacts between, the leukocyte adhesion cascade involves the capture of white blood cells at the vascular endothelium, a progressively slowing, "roll- ing" motion of cells along the vessel walls, firm cell adhesion at target sites

  14. Role of Internal Chain Dynamics on the Rupture Kinetic of Adhesive Contacts V. Barsegov,1

    E-Print Network [OSTI]

    Barsegov, Valeri

    Role of Internal Chain Dynamics on the Rupture Kinetic of Adhesive Contacts V. Barsegov,1 G rupture of adhesive contacts between monomers that are not covalently linked in a Rouse chain. When such as the force-extension curves, lifetime distribution of adhesive contacts, and un- binding force distributions

  15. Fundamenta Informaticae 72 (2006) 129 1 Adhesive High-Level Replacement Systems

    E-Print Network [OSTI]

    Habel, Annegret

    2006-01-01

    Fundamenta Informaticae 72 (2006) 1­29 1 IOS Press Adhesive High-Level Replacement Systems: A New. Adhesive high-level replacement (HLR) systems are introduced as a new categorical framework for graph with the new concept of adhesive categories introduced by Lack and Soboci´nski. In this paper we show that most

  16. Tearing as a test for mechanical characterization of thin adhesive films

    E-Print Network [OSTI]

    Roman, Benoît

    ARTICLES Tearing as a test for mechanical characterization of thin adhesive films EUGENIO HAMM1 Thin adhesive films have become increasingly important in applications involving packaging, coating of the conversion of bending energy into surface energy of fracture and adhesion. In particular, this triangular

  17. A FLUID-CELL INTERACTION AND ADHESION ALGORITHM FOR TISSUE-COATING OF CARDIOVASCULAR IMPLANTS

    E-Print Network [OSTI]

    Canic, Suncica

    A FLUID-CELL INTERACTION AND ADHESION ALGORITHM FOR TISSUE-COATING OF CARDIOVASCULAR IMPLANTS JIAN. In this manuscript we develop a fluid-cell interaction and adhesion algorithm applied to modeling the cell coating parameters and adhesion parameters on the generation of a stable and strong tissue coating of artificial

  18. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    and J. Viidanoja, Atmospheric chemistry of c 3 -c 6organic nitrates, Atmospheric Chemistry and Physics, 9 (4),organic aerosol yields, Atmospheric Chemistry and Physics

  19. Challenge the future 1 Observations of aerosol-cloud-radiation

    E-Print Network [OSTI]

    Graaf, Martin de

    -road Industrial coal Residential solid fuel Biofuel cooking Biofuel heating Coal Open Burning Agricultural fields causes Differences in: · cloud properties · cloud fraction and location · aerosol properties · smoke

  20. Extending the physicochemical characterization of aerosol particles in California

    E-Print Network [OSTI]

    Zauscher, Melanie Dorothy

    2012-01-01

    W. T. (1997).Emissions from Smoldering Combustion of BiomassCombustion generated aerosols, including emissions from diesel and gasoline engines, biomass and

  1. Climatic effects of different aerosol types in China simulated

    E-Print Network [OSTI]

    Y. GU

    2006-01-01

    P. Shettle (1991), Atmospheric Aero- sols—Global ClimatologyEffects of stratospheric aero- sols and preliminarytypes, such as volcanic aero- sols, desert aerosols, or

  2. Relating Secondary Organic Aerosol Characteristics with Cloud Condensation Nuclei Activity

    E-Print Network [OSTI]

    Tang, Xiaochen

    2013-01-01

    by V and Ni from heavy oil combustion: Anthropogenic sourcesgeneration from heavy fuel oil (HFO) as an alternative toengines operating with heavy fuel oils. Journal of Aerosol

  3. The Radiative Role of Free Tropospheric Aerosols and Marine Clouds...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: The Radiative Role of Free Tropospheric Aerosols and Marine Clouds over the Central North Atlantic Citation Details In-Document Search Title: The Radiative Role...

  4. A contact model for sticking of adhesive mesoscopic particles

    E-Print Network [OSTI]

    A. Singh; V. Magnanimo; S. Luding

    2015-03-12

    The interaction between realistic visco-elasto-plastic and adhesive meso-particles is the subject of this study. The final goal is to define a simple, flexible and useful interaction model that allows to describe the multi-contact bulk behavior of assemblies of non-homogeneous/non-spherical particles, e.g. with internal structures of the scale of their contact deformation. We attempt to categorize previous approaches and propose a simplified mesoscale normal contact model that contains the essential ingredients to describe an ensemble of particles, while it is not aimed to include all details of every single contact, i.e. the mechanics of constituent elementary, primary particles is not explicitly taken into account. The model combines short-ranged, non-contact adhesive interactions with an elaborate, piece-wise linear visco-elasto-plastic adhesive contact law. Using energy conservation arguments, the special case of binary collisions is studied and an analytical expression for the coefficient of restitution in terms of impact velocity is derived. The assemblies (particles or meso-particles) stick to each other at very low impact velocity, while they rebound less dissipatively with increasing velocity, in agreement with experimental/theoretical/numerical findings for elasto-plastic spherical particles. For larger impact velocities we observe an interesting second sticking regime. While the first sticking is attributed to dominating non-contact adhesive forces, while the high velocity sticking is due to a balance between the non-linearly increasing history dependent adhesion and plastic dissipation. The model allows for a stiff, elastic core material, which produces a new rebound regime at even higher velocities.

  5. Treatment of Chlorinated Solvents by Nitrogen-Fixing and

    E-Print Network [OSTI]

    Chu, Kung-Hui "Bella"

    ). Therefore, effective contaminant destruction approaches such as in-situ vadose zone bioremediation or above of ground- water contaminants including aliphatic, aromatic, and halogenated hydrocarbons (3 bioremediation for the treatment of chlorinated solvents at Savannah River (6, 7). At this site, nitrogen

  6. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    of the requirements of the Degree of Doctor of Philosophy in Chemical Engineering Practice Abstract In the light1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman B. Chem. Eng. Institute of Chemical Technology, University of Mumbai, 2005 M.S. Chemical Engineering

  7. Solvent Size vs Cohesive Energy as the Origin of Hydrophobicity

    E-Print Network [OSTI]

    Lazaridis, Themis

    of Chemistry, City College of CUNY, Convent Avenue & 138th Street, New York, New York 10031 Received March 22Solvent Size vs Cohesive Energy as the Origin of Hydrophobicity THEMIS LAZARIDIS* Department of water's properties and report a detailed decomposition of the solvation free energy, enthalpy, entropy

  8. Photolysis of RDX and HMX in aqueous and organic solvents 

    E-Print Network [OSTI]

    Choi, Jihyun

    2000-01-01

    the model had a significant amount of lack-of-fit when it was applied to empirical data. Using the selected kinetic model, solvent parameters and the initial concentration of HEs were studied to see their effects on the photolysis rate. Solution pH, buffers...

  9. Electrostatic interactions in charged nanoslits within an explicit solvent theory

    E-Print Network [OSTI]

    Sahin Buyukdagli

    2015-07-23

    Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution of this highly non-linear integro-differential equation for the electrostatic potential. The scheme is an extension of the approach previously introduced for simple planes (S. Buyukdagli and Ralf Blossey, J. Chem. Phys. 140, 234903 (2014)) to nanoslit geometry. We show that the reduced dielectric response of solvent molecules at the membrane walls gives rise to an electric field significantly stronger than the field of the classical Poisson-Boltzmann equation. This peculiarity associated with non-local electrostatic interactions results in turn in an interfacial counterion adsorption layer absent in continuum theories. The observation of this enhanced counterion affinity in the very close vicinity of the interface may have important impacts on nanofludic transport through charged nanopores. Our results indicate the quantitative inaccuracy of solvent implicit nanofiltration theories in predicting the ionic selectivity of membrane nanopores.

  10. Filming the Birth of Molecules and Accompanying Solvent Rearrangement

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    the products. As a result, the properties of the solvent significantly affect the energy landscape, rates of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby, Denmark # Synchrotron Soleil Supporting Information ABSTRACT: Molecules are often born with high energy and large-amplitude vibrations

  11. MODELING OF CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION IN GROUNDWATER

    E-Print Network [OSTI]

    Boyer, Edmond

    1 MODELING OF CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION IN GROUNDWATER QUIOT Fabrice1 performed by 4 teams (ANTEA, ENSMP, ENVIROS and INERIS) to simulate a contamination of groundwater is the evaluation of the fate of pollutants in groundwaters and soils. This knowledge is based on the result

  12. Quantifying Aerosol Direct Effects from Broadband Irradiance and Spectral Aerosol Optical Depth Observations

    SciTech Connect (OSTI)

    Creekmore, Torreon N.; Joseph, Everette; Long, Charles N.; Li, Siwei

    2014-05-16

    We outline a methodology using broadband and spectral irradiances to quantify aerosol direct effects on the surface diffuse shortwave (SW) irradiance. Best Estimate Flux data span a 13 year timeframe at the Department of Energy Atmospheric Radiation Measurement Program’s Southern Great Plains (SGP) site. Screened clear-sky irradiances and aerosol optical depth (AOD), for solar zenith angles ? 65°, are used to estimate clear-sky diffuse irradiances. We validate against detected clear-sky observations from SGP’s Basic Radiation System (BRS). BRS diffuse irradiances were in accordance with estimates, producing a root-mean-square error and mean bias errors of 4.0 W/m2 and -1.4 W/m2, respectively. Absolute differences show 99% of estimates within ±10 W/m2 (10%) of the mean BRS observations. Clear-sky diffuse estimates are used to derive quantitative estimates of aerosol radiative effects, represented as the aerosol diffuse irradiance (ADI). ADI is the contribution of diffuse SW to global SW, attributable to scattering of atmospheric transmission by natural plus anthropogenic aerosols. Estimated slope for the ADI as a function of AOD indicates an increase of ~22 W/m2 in diffuse SW for every 0.1 increase in AOD. Such significant increases in the diffuse fraction could possibly increase photosynthesis. Annual mean ADI is 28.2 W/m2, and heavy aerosol loading at SGP provides up to a maximum increase of 120 W/m2 in diffuse SW over background conditions. With regard to seasonal variation, the mean diffuse forcings are 17.2, 33.3, 39.0, and 23.6 W/m2 for winter, spring, summer, and fall, respectively.

  13. NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2012-01-17

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and with the exception of CPVC, no leachate was observed in the NGS from any of the polymers studied. The testing shows no major concerns for compatibility over the short duration of these tests but does indicate that longer duration exposure studies are warranted, especially for Tefzel. However, the physical changes experienced by Tefzel in the improved solvent were comparable to the physical changes obtained when Tefzel is placed in CSSX baseline solvent. Therefore, there is no effect of the improved solvent beyond those observed in CSSX baseline solvent.

  14. Aerosol cluster impact and break-up : II. Atomic and Cluster Scale Models.

    SciTech Connect (OSTI)

    Lechman, Jeremy B.; Takato, Yoichi

    2010-09-01

    Understanding the interaction of aerosol particle clusters/flocs with surfaces is an area of interest for a number of processes in chemical, pharmaceutical, and powder manufacturing as well as in steam-tube rupture in nuclear power plants. Developing predictive capabilities for these applications involves coupled phenomena on multiple length and timescales from the process macroscopic scale ({approx}1m) to the multi-cluster interaction scale (1mm-0.1m) to the single cluster scale ({approx}1000 - 10000 particles) to the particle scale (10nm-10{micro}m) interactions, and on down to the sub-particle, atomic scale interactions. The focus of this report is on the single cluster scale; although work directed toward developing better models of particle-particle interactions by considering sub-particle scale interactions and phenomena is also described. In particular, results of mesoscale (i.e., particle to single cluster scale) discrete element method (DEM) simulations for aerosol cluster impact with rigid walls are presented. The particle-particle interaction model is based on JKR adhesion theory and is implemented as an enhancement to the granular package in the LAMMPS code. The theory behind the model is outlined and preliminary results are shown. Additionally, as mentioned, results from atomistic classical molecular dynamics simulations are also described as a means of developing higher fidelity models of particle-particle interactions. Ultimately, the results from these and other studies at various scales must be collated to provide systems level models with accurate 'sub-grid' information for design, analysis and control of the underlying systems processes.

  15. Development and Characterization of a Thermodenuder for Aerosol Volatility Measurements

    SciTech Connect (OSTI)

    Dr. Timothy Onasch

    2009-09-09

    This SBIR Phase I project addressed the critical need for improved characterization of carbonaceous aerosol species in the atmosphere. The proposed work focused on the development of a thermodenuder (TD) system capable of systematically measuring volatility profiles of primary and secondary organic aerosol species and providing insight into the effects of absorbing and nonabsorbing organic coatings on particle absorption properties. This work provided the fundamental framework for the generation of essential information needed for improved predictions of ambient aerosol loadings and radiative properties by atmospheric chemistry models. As part of this work, Aerodyne Research, Inc. (ARI) continued to develop and test, with the final objective of commercialization, an improved thermodenuder system that can be used in series with any aerosol instrument or suite of instruments (e.g., aerosol mass spectrometers-AMS, scanning mobility particle sizers-SMPS, photoacoustic absorption spectrometers-PAS, etc.) to obtain aerosol chemical, physical, and optical properties as a function of particle volatility. In particular, we provided the proof of concept for the direct coupling of our improved TD design with a full microphysical model to obtain volatility profiles for different organic aerosol components and to allow for meaningful comparisons between different TD-derived aerosol measurements. In a TD, particles are passed through a heated zone and a denuding (activated charcoal) zone to remove semi-volatile material. Changes in particle size, number concentration, optical absorption, and chemical composition are subsequently detected with aerosol instrumentation. The aerosol volatility profiles provided by the TD will strengthen organic aerosol emission inventories, provide further insight into secondary aerosol formation mechanisms, and provide an important measure of particle absorption (including brown carbon contributions and identification, and absorption enhancements due to coatings on soot particles). The successfully completed Phase I project included construction of a prototype design for the TD with detailed physical modeling, testing with laboratory and ambient aerosol particles, and the initiation of a detailed microphysical model of the aerosol particles passing through the TD to extract vapor pressure distributions. The objective of the microphysical model is to derive vapor pressure distributions (i.e. vapor pressure ranges, including single chemical compounds, mixtures of known compounds, and complex ‘real-world’ aerosols, such as SOA, and soot particles with absorbing and nonabsorbing coatings) from TD measurements of changes in particle size, mass, and chemical composition for known TD temperatures and flow rates (i.e. residence times). The proposed Phase II project was designed to optimize several TD systems for different instrument applications and to combine the hardware and modeling into a robust package for commercial sales.

  16. THE COMBUSTION OF SOLVENT REPINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME

    E-Print Network [OSTI]

    Chin, W.K.

    2011-01-01

    R.F. (1977). Combustion of coal in an opposed flow diffusionpulverized, solvent-refined coal. ASME Paper No. 76-WA/FU-6.OF SOLVENT REFINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME*

  17. Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control January 13, 2015 - 11:20am...

  18. Strategies for the aerobic co-metabolism of chlorinated solvents CURRENT OPINION IN BIOTECHNOLOGY

    E-Print Network [OSTI]

    Semprini, Lewis

    Strategies for the aerobic co-metabolism of chlorinated solvents Semprini L CURRENT OPINION for aerobic co- metabolism of chlorinated solvents. Different co-metabolic substrates and different methods

  19. Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from

    E-Print Network [OSTI]

    California at Riverside, University of

    Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from limits potential sugar yields.[7] Thus, it is desirable We introduce a new pretreatment called co-solvent

  20. Simulations of time-dependent fluorescence in nano-confined solvents

    E-Print Network [OSTI]

    Thompson, Ward H.

    2004-04-13

    The time-dependent fluorescence of a model diatomic molecule with a charge-transfer electronic transition in confined solvents has been simulated. The effect of confining the solvent is examined by comparing results for solutions contained within...