National Library of Energy BETA

Sample records for aerosol intensive properties

  1. The seasonality of aerosol properties in Big Bend National Park 

    E-Print Network [OSTI]

    Allen, Christopher Lee

    2007-04-25

    ), to characterize the seasonal variability of the Big Bend regions aerosol optical properties. Mass extinction efficiencies and relative humidity scattering enhancement factors were calculated for both externally and internally mixed aerosol populations for all size...

  2. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  3. Optimal Estimation Retrieval Aerosol Microphysical Properties

    E-Print Network [OSTI]

    Oxford, University of

    ) the validation of this algorithm on the basis of synthetic extinction data, and (3) application of the new algorithm to SAGE II measurements of stratospheric background aerosol. The validation results indicate that the new method is able to retrieve the particle size of typical background aerosols reasonably well

  4. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  5. Group Report: Connections between Aerosol Properties

    E-Print Network [OSTI]

    effect and causes surface warming. Absorption of solar or thermal radiation within the atmospheric column-influencing constituents (such as green- house gases) by this process, anthropogenic aerosols can contribute to climate

  6. Cloud-Driven Changes in Aerosol Optical Properties - Final Technical Report

    SciTech Connect (OSTI)

    Ogren, John A.; Sheridan, Patrick S.; Andrews, Elisabeth

    2007-09-30

    The optical properties of aerosol particles are the controlling factors in determining direct aerosol radiative forcing. These optical properties depend on the chemical composition and size distribution of the aerosol particles, which can change due to various processes during the particles’ lifetime in the atmosphere. Over the course of this project we have studied how cloud processing of atmospheric aerosol changes the aerosol optical properties. A counterflow virtual impactor was used to separate cloud drops from interstitial aerosol and parallel aerosol systems were used to measure the optical properties of the interstitial and cloud-scavenged aerosol. Specifically, aerosol light scattering, back-scattering and absorption were measured and used to derive radiatively significant parameters such as aerosol single scattering albedo and backscatter fraction for cloud-scavenged and interstitial aerosol. This data allows us to demonstrate that the radiative properties of cloud-processed aerosol can be quite different than pre-cloud aerosol. These differences can be used to improve the parameterization of aerosol forcing in climate models.

  7. Cloud Scavenging Effects on Aerosol Radiative and Cloud-nucleating Properties - Final Technical Report

    SciTech Connect (OSTI)

    Ogren, John A.; Sheridan, Patrick S.; Andrews, Elisabeth

    2009-03-05

    The optical properties of aerosol particles are the controlling factors in determining direct aerosol radiative forcing. These optical properties depend on the chemical composition and size distribution of the aerosol particles, which can change due to various processes during the particles’ lifetime in the atmosphere. Over the course of this project we have studied how cloud processing of atmospheric aerosol changes the aerosol optical properties. A counterflow virtual impactor was used to separate cloud drops from interstitial aerosol and parallel aerosol systems were used to measure the optical properties of the interstitial and cloud-scavenged aerosol. Specifically, aerosol light scattering, back-scattering and absorption were measured and used to derive radiatively significant parameters such as aerosol single scattering albedo and backscatter fraction for cloud-scavenged and interstitial aerosol. This data allows us to demonstrate that the radiative properties of cloud-processed aerosol can be quite different than pre-cloud aerosol. These differences can be used to improve the parameterization of aerosol forcing in climate models.

  8. Trends in aerosol optical properties over the Bohai Rim in Northeast China from 2004 to 2010

    E-Print Network [OSTI]

    Zeng, Ning

    Trends in aerosol optical properties over the Bohai Rim in Northeast China from 2004 to 2010 al., 2004). However, the spatial and temporal contributions of aerosol optical properties and aerosol of this growth is driven by new industry that consumes substantially more coal and fossil fuel in the region

  9. Mixtures of pollution, dust, sea salt, and volcanic aerosol during ACE-Asia: Radiative properties

    E-Print Network [OSTI]

    was dominated by marine, polluted, volcanic, and dust aerosols. Average total light scattering coefficients (sspMixtures of pollution, dust, sea salt, and volcanic aerosol during ACE-Asia: Radiative properties). Aerosol hygroscopicity ranged from deliquescent with hysteresis (marine frequently and polluted variably

  10. ARM AOS Processing Status and Aerosol Intensive Properties VAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation Data Management Facility PlotsProducts (VAP) VAP Update1 ARMAOS

  11. Optical Properties of Mixed Black Carbon, Inorganic and Secondary Organic Aerosols

    SciTech Connect (OSTI)

    Paulson, S E

    2012-05-30

    Summarizes the achievements of the project, which are divided into four areas: 1) Optical properties of secondary organic aerosols; 2) Development and of a polar nephelometer to measure aerosol optical properties and theoretical approaches to several optical analysis problems, 3) Studies on the accuracy of measurements of absorbing carbon by several methods, and 4) Environmental impacts of biodiesel.

  12. Evolution of biomass burning aerosol properties from an agricultural fire in southern Africa

    E-Print Network [OSTI]

    Highwood, Ellie

    Evolution of biomass burning aerosol properties from an agricultural fire in southern Africa Steven Met Office C-130 within a distinct biomass burning plume during the Southern AFricAn Regional science, and P. R. Buseck, Evolution of biomass burning aerosol properties from an agricultural fire in southern

  13. Radiative Effects of Dust Aerosols, Natural Cirrus Clouds and Contrails: Broadband Optical Properties and Sensitivity Studies 

    E-Print Network [OSTI]

    Yi, Bingqi

    2013-07-09

    This dissertation aims to study the broadband optical properties and radiative effects of dust aerosols and ice clouds. It covers three main topics: the uncertainty of dust optical properties and radiative effects from the dust particle shape...

  14. CARES: Carbonaceous Aerosol and Radiative Effects Study Science Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-05-27

    Carbonaceous aerosol components, which include black carbon (BC), urban primary organic aerosols (POA), biomass burning aerosols, and secondary organic aerosols (SOA) from both urban and biogenic precursors, have been previously shown to play a major role in the direct and indirect radiative forcing of climate. The primary objective of the CARES 2010 intensive field study is to investigate the evolution of carbonaceous aerosols of different types and their effects on optical and cloud formation properties.

  15. Multi-grid-cell validation of satellite aerosol property retrievals in INTEX/ITCT/ICARTT 2004

    E-Print Network [OSTI]

    Multi-grid-cell validation of satellite aerosol property retrievals in INTEX/ITCT/ICARTT 2004 P. B 5 December 2006; published 8 May 2007. [1] Aerosol transport off the US Northeast coast during) provided comparisons of AATS AOD spectra to retrievals for 90 grid cells of the satellite radiometers MODIS

  16. Chemical and Physical Properties of Atmospheric Aerosols (a) A Case Study in the Unique Properties of Agricultural Aerosols (b) The Role of Chemical Composition in Ice Nucleation during the Arctic Spring 

    E-Print Network [OSTI]

    Moon, Seong-Gi

    2011-08-08

    dataset is reported for these physical and chemical properties of agricultural aerosols appropriate for use in a site-specific emission inventory. The emission rate and transport of the aerosols are also discussed. In addition, mixing ratios of total...

  17. The influence of meteorology on the organic and inorganic properties of aerosols in Hong Kong

    E-Print Network [OSTI]

    Zheng, Mei

    The influence of meteorology on the organic and inorganic properties of aerosols in Hong Kong Mei, Fe) could be from coal flyash, the estimate of crustal material in the Dry-N period may include some

  18. Measurements of aerosol vertical profiles and optical properties during INDOEX

    E-Print Network [OSTI]

    , and the Kaashidhoo Climate Observatory (KCO) in the Maldives. Sun photometers were used to provide aerosol optical depths (AOD) needed to calibrate the MPL. This study focuses on the height distribution and optical trajectories, radiosonde profiles of temperature and humidity, and aerosol concentration and optical

  19. DISSERTATION THE OPTICAL, CHEMICAL, AND PHYSICAL PROPERTIES OF AEROSOLS AND

    E-Print Network [OSTI]

    Pierce, Jeffrey

    AND GASES EMITTED BY THE LABORATORY COMBUSTION OF WILDLAND FUELS Biomass burning is a major source of trace Laboratory at Missoula Experiment. Emission factors are presented as a function of modified combustion efficiency (MCE), a measure of the fire combustion conditions. The emissions of many trace gas and aerosol

  20. Variability of Aerosol Optical Properties from Long-term

    E-Print Network [OSTI]

    Delene, David J.

    aerosols and overestimates absorption due to suspended particles by about 20-30%. Green L E D Opal Glas s O Photometer · Principle of operation is to measure the change in light transmission through a filter on which light extinction and light scattering. · Instrument exhibits a significant response to nonabsorbing

  1. CLOUD DROPLET NUCLEATION AND ITS CONNECTION TO AEROSOL PROPERTIES

    E-Print Network [OSTI]

    influence the earth's radiation balance and climate directly, by scanering shortwave (solar) radiation in the earth radiation budget over the industrial period. exerting a radiative forcing that is of comparable. Keywords - Climate. aerosols. clouds, radiation INTRODUcnON In recent years awareness has increased

  2. Production Mechanism, Number Concentration, Size Distribution, Chemical Composition, and Optical Properties of Sea Spray Aerosols Workshop, Summer 2012

    SciTech Connect (OSTI)

    Meskhidze, Nicholas [NCSU] [NCSU

    2013-10-21

    The objective of this workshop was to address the most urgent open science questions for improved quantification of sea spray aerosol-radiation-climate interactions. Sea spray emission and its influence on global climate remains one of the most uncertain components of the aerosol-radiation-climate problem, but has received less attention than other aerosol processes (e.g. production of terrestrial secondary organic aerosols). Thus, the special emphasis was placed on the production flux of sea spray aerosol particles, their number concentration and chemical composition and properties.

  3. Characterizing Aerosol Distributions and Optical Properties Using the NASA Langley High Spectral Resolution Lidar

    SciTech Connect (OSTI)

    Hostetler, Chris; Ferrare, Richard

    2013-02-14

    The objective of this project was to provide vertically and horizontally resolved data on aerosol optical properties to assess and ultimately improve how models represent these aerosol properties and their impacts on atmospheric radiation. The approach was to deploy the NASA Langley Airborne High Spectral Resolution Lidar (HSRL) and other synergistic remote sensors on DOE Atmospheric Science Research (ASR) sponsored airborne field campaigns and synergistic field campaigns sponsored by other agencies to remotely measure aerosol backscattering, extinction, and optical thickness profiles. Synergistic sensors included a nadir-viewing digital camera for context imagery, and, later in the project, the NASA Goddard Institute for Space Studies (GISS) Research Scanning Polarimeter (RSP). The information from the remote sensing instruments was used to map the horizontal and vertical distribution of aerosol properties and type. The retrieved lidar parameters include profiles of aerosol extinction, backscatter, depolarization, and optical depth. Products produced in subsequent analyses included aerosol mixed layer height, aerosol type, and the partition of aerosol optical depth by type. The lidar products provided vertical context for in situ and remote sensing measurements from other airborne and ground-based platforms employed in the field campaigns and was used to assess the predictions of transport models. Also, the measurements provide a data base for future evaluation of techniques to combine active (lidar) and passive (polarimeter) measurements in advanced retrieval schemes to remotely characterize aerosol microphysical properties. The project was initiated as a 3-year project starting 1 January 2005. It was later awarded continuation funding for another 3 years (i.e., through 31 December 2010) followed by a 1-year no-cost extension (through 31 December 2011). This project supported logistical and flight costs of the NASA sensors on a dedicated aircraft, the subsequent analysis and archival of the data, and the presentation of results in conferences, workshops, and publications. DOE ASR field campaigns supported under this project included - MAX-Mex /MILAGRO (2006) - TexAQS 2006/GoMACCS (2006) - CHAPS (2007) - RACORO (2009) - CARE/CalNex (2010) In addition, data acquired on HSRL airborne field campaigns sponsored by other agencies were used extensively to fulfill the science objectives of this project and the data acquired have been made available to other DOE ASR investigators upon request.

  4. EVALUATING TREATMENTS OF AEROSOL OPTICAL PROPERTIES AND THEIR EFFECT ON RADIATIVE FORCING USING MILAGRO MEASUREMENTS

    E-Print Network [OSTI]

    at the American Geophysical Union Fall Meeting San Francisco, CA December 10-14, 2007 Environmental Sciences-chemistry-aerosol model, WRF-chem, to evaluate the predicted optical properties and downwind of Mexico City using both-averaging", "shell-core" and other approaches that employ Mie theory. The impact of the various approaches

  5. FY 2010 Fourth Quarter Report: Evaluation of the Dependency of Drizzle Formation on Aerosol Properties

    SciTech Connect (OSTI)

    Lin, W; McGraw, R; Liu, Y; Wang, J; Vogelmann, A; Daum, PH

    2010-10-01

    Metric for Quarter 4: Report results of implementation of composite parameterization in single-column model (SCM) to explore the dependency of drizzle formation on aerosol properties. To better represent VOCALS conditions during a test flight, the Liu-Duam-McGraw (LDM) drizzle parameterization is implemented in the high-resolution Weather Research and Forecasting (WRF) model, as well as in the single-column Community Atmosphere Model (CAM), to explore this dependency.

  6. Lidar Measurements of the Vertical Distribution of Aerosol Optical and Physical Properties over Central Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Boris B.; Sverdlik, Leonid G.; Imashev, Sanjar A.; Solomon, Paul A.; Lantz, Jeffrey; Schauer, James J.; Shafer, Martin M.; Artamonova, Maria S.; Carmichael, Gregory R.

    2013-01-01

    The vertical structure of aerosol optical and physical properties was measured by Lidar in Eastern Kyrgyzstan, Central Asia, from June 2008 to May 2009. Lidar measurements were supplemented with surface-based measurements of PM 2.5 and PM 10 mass and chemical composition in both size fractions. Dust transported into the region is common, being detected 33% of the time. The maximum frequency occurred in the spring of 2009. Dust transported to Central Asia comes from regional sources, for example, Taklimakan desert and Aral Sea basin, and from long-range transport, for example, deserts of Arabia, Northeast Africa, Iran, and Pakistan. Regionalmore »sources are characterized by pollution transport with maximum values of coarse particles within the planetary boundary layer, aerosol optical thickness, extinction coefficient, integral coefficient of aerosol backscatter, and minimum values of the Ĺngström exponent. Pollution associated with air masses transported over long distances has different characteristics during autumn, winter, and spring. During winter, dust emissions were low resulting in high values of the Ĺngström exponent (about 0.51) and the fine particle mass fraction (64%). Dust storms were more frequent during spring with an increase in coarse dust particles in comparison to winter. The aerosol vertical profiles can be used to lower uncertainty in estimating radiative forcing. « less

  7. Global Distribution and Climate Forcing of Marine Organic Aerosol - Part 2: Effects on Cloud Properties and Radiative Forcing

    SciTech Connect (OSTI)

    Gantt, Brett; Xu, Jun; Meskhidze, N.; Zhang, Yang; Nenes, Athanasios; Ghan, Steven J.; Liu, Xiaohong; Easter, Richard C.; Zaveri, Rahul A.

    2012-07-25

    A series of simulations with the Community Atmosphere Model version 5 (CAM5) with a 7-mode Modal Aerosol Model were conducted to assess the changes in cloud microphysical properties and radiative forcing resulting from marine organic aerosols. Model simulations show that the anthropogenic aerosol indirect forcing (AIF) predicted by CAM5 is decreased in absolute magnitude by up to 0.09 Wm{sup -2} (7 %) when marine organic aerosols are included. Changes in the AIF from marine organic aerosols are associated with small global increases in low-level incloud droplet number concentration and liquid water path of 1.3 cm{sup -3} (1.5 %) and 0.22 gm{sup -2} (0.5 %), respectively. Areas especially sensitive to changes in cloud properties due to marine organic aerosol include the Southern Ocean, North Pacific Ocean, and North Atlantic Ocean, all of which are characterized by high marine organic emission rates. As climate models are particularly sensitive to the background aerosol concentration, this small but non-negligible change in the AIF due to marine organic aerosols provides a notable link for ocean-ecosystem marine low-level cloud interactions and may be a candidate for consideration in future earth system models.

  8. ARM - Field Campaign - Cirrus Clouds and Aerosol Properties Campaign

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See22,Microphysical Properties ofgovCampaignsCirrus Clouds

  9. The application of size- resolved hygroscopicity measurements to understand the physical and chemical properties of ambient aerosol 

    E-Print Network [OSTI]

    Santarpia, Joshua Lee

    2005-08-29

    -1 THE APPLICATION OF SIZE-RESOLVED HYGROSCOPICITY MEASUREMENTS TO UNDERSTANDING THE PHYSICAL AND CHEMICAL PROPERTIES OF AMBIENT AEROSOL A Dissertation by JOSHUA L. SANTARPIA Submitted to the Office of Graduate Studies of Texas A&M University in partial... OF AMBIENT AEROSOL A Dissertation by JOSHUA L. SANTARPIA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content...

  10. Aerosol Characterization Data from the Asian Pacific Regional Aerosol Characterization Project (ACE-Asia)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Aerosol Characterization Experiments (ACE) were designed to increase understanding of how atmospheric aerosol particles affect the Earth's climate system. These experiments integrated in-situ measurements, satellite observations, and models to reduce the uncertainty in calculations of the climate forcing due to aerosol particles and improve the ability of models to predict the influences of aerosols on the Earth's radiation balance. ACE-Asia was the fourth in a series of experiments organized by the International Global Atmospheric Chemistry (IGAC) Program (A Core Project of the International Geosphere Biosphere Program). The Intensive Field Phase for ACE-Asia took place during the spring of 2001 (mid-March through early May) off the coast of China, Japan and Korea. ACE-Asia pursued three specific objectives: 1) Determine the physical, chemical, and radiative properties of the major aerosol types in the Eastern Asia and Northwest Pacific region and investigate the relationships among these properties. 2) Quantify the physical and chemical processes controlling the evolution of the major aerosol types and in particular their physical, chemical, and radiative properties. 3) Develop procedures to extrapolate aerosol properties and processes from local to regional and global scales, and assess the regional direct and indirect radiative forcing by aerosols in the Eastern Asia and Northwest Pacific region [Edited and shortened version of summary at http://data.eol.ucar.edu/codiac/projs?ACE-ASIA]. The Ace-Asia collection contains 174 datasets.

  11. Aerosol Properties from Multi-spectral and Multi-angular Aircraft 4STAR Observations: Expected Advantages and Challenges

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Flynn, Connor J.; Redemann, Jens; Schmid, Beat; Russell, P. B.; Sinyuk, Alexander

    2012-11-01

    The airborne Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) is developed to retrieve aerosol microphysical and optical properties from multi-angular and multi-spectral measurements of sky radiance and direct-beam sun transmittance. The necessarily compact design of the 4STAR may cause noticeable apparent enhancement of sky radiance at small scattering angles. We assess the sensitivity of expected 4STAR-based aerosol retrieval to such enhancement by applying the operational AERONET retrieval code and constructed synthetic 4STARlike data. Also, we assess the sensitivity of the broadband fluxes and the direct aerosol radiative forcing to uncertainties in aerosol retrievals associated with the sky radiance enhancement. Our sensitivity study results suggest that the 4STARbased aerosol retrieval has limitations in obtaining detailed information on particle size distribution and scattering phase function. However, these limitations have small impact on the retrieved bulk optical parameters, such as the asymmetry factor (up to 4%, or ±0.02) and single-scattering albedo (up to 2%, or ±0.02), and the calculated direct aerosol radiative forcing (up to 6%, or 2 Wm-2).

  12. Investigation of the optical and cloud forming properties of pollution, biomass burning, and mineral dust aerosols 

    E-Print Network [OSTI]

    Lee, Yong Seob

    2006-08-16

    that were observed during this period. The predicted cloud condensation nuclei concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction...

  13. Retrieval of Non-Spherical Dust Aerosol Properties from Satellite Observations 

    E-Print Network [OSTI]

    Huang, Xin

    2013-08-01

    of the refractive index, which may lead to misinterpretation of the measurements and substantial errors in the retrieved aerosol parameters; (e) Depending signi cantly on the selection of the limited num- ber of xed dust aerosol models, the retrieval quality may...

  14. Intercomparison and Evaluation of Global Aerosol Microphysical Properties among AeroCom Models of a Range of Complexity

    SciTech Connect (OSTI)

    Mann, G. W.; Carslaw, K. S.; Reddington, C. L.; Pringle, K. J.; Schulz, M.; Asmi, A.; Spracklen, D. V.; Ridley, D. A.; Woodhouse, M. T.; Lee, L. A.; Zhang, Kai; Ghan, Steven J.; Easter, Richard C.; Liu, Xiaohong; Stier, P.; Lee, Y. H.; Adams, P. J.; Tost, H.; Lelieveld, J.; Bauer, S.; Tsigaridis, Kostas; van Noije, T.; Strunk, A.; Vignati, E.; Bellouin, N.; Dalvi, M.; Johnson, C. E.; Bergman, T.; Kokkola, H.; Von Salzen, Knut; Yu, Fangqun; Luo, Gan; Petzold, A.; Heintzenberg, J.; Clarke, A. D.; Ogren, J. A.; Gras, J.; Baltensperger, Urs; Kaminski, U.; Jennings, S. G.; O'Dowd, C. D.; Harrison, R. M.; Beddows, D. C.; Kulmala, M.; Viisanen, Y.; Ulevicius, V.; Mihalopoulos, Nikos; Zdimal, V.; Fiebig, M.; Hansson, H. C.; Swietlicki, E.; Henzing, J. S.

    2014-05-13

    Many of the next generation of global climate models will include aerosol schemes which explicitly simulate the microphysical processes that determine the particle size distribution. These models enable aerosol optical properties and cloud condensation nuclei (CCN) concentrations to be determined by fundamental aerosol processes, which should lead to a more physically based simulation of aerosol direct and indirect radiative forcings. This study examines the global variation in particle size distribution simulated by twelve global aerosol microphysics models to quantify model diversity and to identify any common biases against observations. Evaluation against size distribution measurements from a new European network of aerosol supersites shows that the mean model agrees quite well with the observations at many sites on the annual mean, but there are some seasonal biases common to many sites. In particular, at many of these European sites, the accumulation mode number concentration is biased low during winter and Aitken mode concentrations tend to be overestimated in winter and underestimated in summer. At high northern latitudes, the models strongly underpredict Aitken and accumulation particle concentrations compared to the measurements, consistent with previous studies that have highlighted the poor performance of global aerosol models in the Arctic. In the marine boundary layer, the models capture the observed meridional variation in the size distribution, which is dominated by the Aitken mode at high latitudes, with an increasing concentration of accumulation particles with decreasing latitude. Considering vertical profiles, the models reproduce the observed peak in total particle concentrations in the upper troposphere due to new particle formation, although modelled peak concentrations tend to be biased high over Europe. Overall, the results suggest that most global aerosol microphysics models simulate the global variation of the particle size distribution with a good degree of skill, but some models are in poor agreement with the observations. Further work is required to better constrain size-resolved primary and secondary particle number sources, and an improved understanding of nucleation and growth (e.g. the role of nitrate and secondary organics) will improve the fidelity of simulated particle size distributions.

  15. Simulated aerosol key optical properties over global scale using an aerosol transport model coupled with a new type of dynamic core

    E-Print Network [OSTI]

    Dong, Xiquan

    effects: (a) a direct effect in which aerosol particles scatter and absorb the solar and thermal radiation Atmospheric aerosols greatly impact the Earth's climate in many ways, and to date, not all of them are well

  16. Atmospheric Aerosols Aging Involving Organic Compounds and Impacts on Particle Properties 

    E-Print Network [OSTI]

    Qiu, Chong

    2013-02-01

    In the first part of this dissertation, we study the aging of soot, a representative type of primary aerosols, in the presence of OH-initiated oxidation products of toluene. Monodisperse soot particles are introduced into an environmental chamber...

  17. Variations in organic aerosol optical and hygroscopic properties upon heterogeneous OH oxidation

    E-Print Network [OSTI]

    Cappa, Christopher D.

    Measurements of the evolution of organic aerosol extinction cross sections (?[subscript ext]) and subsaturated hygroscopicity upon heterogeneous OH oxidation are reported for two model compounds, squalane (a C30 saturated ...

  18. Aircraft Observations of Sub-cloud Aerosol and Convective Cloud Physical Properties 

    E-Print Network [OSTI]

    Axisa, Duncan

    2011-02-22

    This research focuses on aircraft observational studies of aerosol-cloud interactions in cumulus clouds. The data were collected in the summer of 2004, the spring of 2007 and the mid-winter and spring of 2008 in Texas, ...

  19. The Two-Column Aerosol Project (TCAP) Science Plan

    SciTech Connect (OSTI)

    Berkowitz, CM; Berg, LK; Cziczo, DJ; Flynn, CJ; Kassianov, EI; Fast, JD; Rasch, PJ; Shilling, JE; Zaveri, RA; Zelenyuk, A; Ferrare, RA; Hostetler, CA; Cairns, B; Russell, PB; Ervens, B

    2011-07-27

    The Two-Column Aerosol Project (TCAP) field campaign will provide a detailed set of observations with which to (1) perform radiative and cloud condensation nuclei (CCN) closure studies, (2) evaluate a new retrieval algorithm for aerosol optical depth (AOD) in the presence of clouds using passive remote sensing, (3) extend a previously developed technique to investigate aerosol indirect effects, and (4) evaluate the performance of a detailed regional-scale model and a more parameterized global-scale model in simulating particle activation and AOD associated with the aging of anthropogenic aerosols. To meet these science objectives, the Atmospheric Radiation Measurement (ARM) Climate Research Facility will deploy the ARM Mobile Facility (AMF) and the Mobile Aerosol Observing System (MAOS) on Cape Cod, Massachusetts, for a 12-month period starting in the summer of 2012 in order to quantify aerosol properties, radiation, and cloud characteristics at a location subject to both clear and cloudy conditions, and clean and polluted conditions. These observations will be supplemented by two aircraft intensive observation periods (IOPs), one in the summer and a second in the winter. Each IOP will deploy one, and possibly two, aircraft depending on available resources. The first aircraft will be equipped with a suite of in situ instrumentation to provide measurements of aerosol optical properties, particle composition and direct-beam irradiance. The second aircraft will fly directly over the first and use a multi-wavelength high spectral resolution lidar (HSRL) and scanning polarimeter to provide continuous optical and cloud properties in the column below.

  20. Physical properties of ambient and laboratory-generated secondary organic aerosol

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    the rebound energy, then the particle will remain on the surface. The viscosity, including both elastic of viscosity values appropriate for SOA models. When an aerosol particle impacts a surface, some kinetic energy is dissipated in deformation. If the kinetic energy loss is large enough that the adhesion energy exceeds

  1. Laboratory investigation of chemical and physical properties of soot-containing aerosols 

    E-Print Network [OSTI]

    Zhang, Dan

    2006-08-16

    are conducted using a threewavelength Nephelometer and a multi-path extinction cell. Coating of H2SO4 is found to increase the single scattering albedo (SSA) of soot particles which has impact on the aerosol direct radiative effect. Other laboratory techniques...

  2. Aerosol properties and their influences on marine boundary layer cloud condensation nuclei

    E-Print Network [OSTI]

    Dong, Xiquan

    and early spring months had the highest mean surface wind speed (> 5 m sŔ1 ) and greatest contribution of aerosols found in the atmosphere such as mineral dust, urban/industrial pollution, biomass burning, and sea by using observations and model simulations [Rosenfeld et al., 2008; Li et al., 2011; Feingold et al., 2006

  3. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  4. Direct Aerosol Forcing Uncertainty

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mccomiskey, Allison

    2008-01-15

    Understanding sources of uncertainty in aerosol direct radiative forcing (DRF), the difference in a given radiative flux component with and without aerosol, is essential to quantifying changes in Earth's radiation budget. We examine the uncertainty in DRF due to measurement uncertainty in the quantities on which it depends: aerosol optical depth, single scattering albedo, asymmetry parameter, solar geometry, and surface albedo. Direct radiative forcing at the top of the atmosphere and at the surface as well as sensitivities, the changes in DRF in response to unit changes in individual aerosol or surface properties, are calculated at three locations representing distinct aerosol types and radiative environments. The uncertainty in DRF associated with a given property is computed as the product of the sensitivity and typical measurement uncertainty in the respective aerosol or surface property. Sensitivity and uncertainty values permit estimation of total uncertainty in calculated DRF and identification of properties that most limit accuracy in estimating forcing. Total uncertainties in modeled local diurnally averaged forcing range from 0.2 to 1.3 W m-2 (42 to 20%) depending on location (from tropical to polar sites), solar zenith angle, surface reflectance, aerosol type, and aerosol optical depth. The largest contributor to total uncertainty in DRF is usually single scattering albedo; however decreasing measurement uncertainties for any property would increase accuracy in DRF. Comparison of two radiative transfer models suggests the contribution of modeling error is small compared to the total uncertainty although comparable to uncertainty arising from some individual properties.

  5. Universal and nonuniversal statistical properties of levels and intensities for chaotic Rydberg molecules

    SciTech Connect (OSTI)

    Lombardi, M.; Seligman, T.H. (Laboratoire de Spectrometrie Physique-Universite Joseph Fourier de Grenoble, Boite Postale No. 87, 38402 Saint Martin d'Heres, CEDEX (France))

    1993-05-01

    We study Rydberg molecules taking into account the interaction between the rotational motion of the nuclei and the radial motion of the electron. This situation can be treated to a good approximation in quantum mechanics by the multichannel quantum-defect method which in turn has a well-defined classical limit. We are able to calculate very long sequences of levels and the corresponding amplitudes of wave packets. This allows us to study the statistical properties of both in detail. Our interest focuses on aspects of quantum chaos'' that can be particularly well understood in this case. Our main result is that, in a completely chaotic classical situation, where statistics of quantum-level spacings follow the expected universal Gaussian-orthogonal-ensemble behavior, and statistics of line intensities display the expected universal Porter-Thomas behavior, nonuniversal properties are explicitly contained in correlations between intensities and spacings, determined by the time needed for the classical system to mix on a length scale given by the quantum wavelength.

  6. Intercomparison and evaluation of global aerosol microphysical properties among AeroCom models of a range of complexity

    E-Print Network [OSTI]

    Ridley, David Andrew

    Many of the next generation of global climate models will include aerosol schemes which explicitly simulate the microphysical processes that determine the particle size distribution. These models enable aerosol optical ...

  7. Table S1: (a) Aircraft, ground and satellite based instruments, the aerosol properties used from these instruments and their availability on the two case study days.

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    properties used from these instruments and their availability on the two case studyTable S1: (a) Aircraft, ground and satellite based instruments, the aerosol de Monterrey + Y/N=> Yes/No => AOD observation is/is not available

  8. Relative humidity and its effect on aerosol optical depth in the vicinity of convective clouds

    E-Print Network [OSTI]

    Altaratz, O

    The hygroscopic growth of aerosols is controlled by the relative humidity (RH) and changes the aerosols' physical and hence optical properties. Observational studies of aerosol–cloud interactions evaluate the aerosol ...

  9. Aerosol properties, in-canopy gradients, turbulent fluxes and VOC concentrations at a pristine forest site in Amazonia

    E-Print Network [OSTI]

    Rizzo, LV; Artaxo, P; Karl, T; Guenther, AB; Greenberg, J

    2010-01-01

    wet season. Atmospheric Chemistry and Physics Discussions 9,carbonaceous aerosols. Atmospheric Chemistry and Physics 6,of the EU project OSOA. Atmospheric Chemistry and Physics 4,

  10. Biomass burning and pollution aerosol over North America: Organic components and their influence on spectral optical properties and

    E-Print Network [OSTI]

    Clarke, Antony

    Biomass burning and pollution aerosol over North America: Organic components and their influence Received 11 July 2006; revised 5 April 2007; accepted 19 April 2007; published 9 June 2007. [1] Thermal and pollution plumes identified from trace gas measurements were evaluated for their aerosol physiochemical

  11. Laboratory Studies of the Reactive Chemistry and Changing CCN Properties of Secondary Organic Aerosol, Including Model Development

    SciTech Connect (OSTI)

    Scot Martin

    2013-01-31

    The chemical evolution of secondary-organic-aerosol (SOA) particles and how this evolution alters their cloud-nucleating properties were studied. Simplified forms of full Koehler theory were targeted, specifically forms that contain only those aspects essential to describing the laboratory observations, because of the requirement to minimize computational burden for use in integrated climate and chemistry models. The associated data analysis and interpretation have therefore focused on model development in the framework of modified kappa-Koehler theory. Kappa is a single parameter describing effective hygroscopicity, grouping together several separate physicochemical parameters (e.g., molar volume, surface tension, and van't Hoff factor) that otherwise must be tracked and evaluated in an iterative full-Koehler equation in a large-scale model. A major finding of the project was that secondary organic materials produced by the oxidation of a range of biogenic volatile organic compounds for diverse conditions have kappa values bracketed in the range of 0.10 +/- 0.05. In these same experiments, somewhat incongruently there was significant chemical variation in the secondary organic material, especially oxidation state, as was indicated by changes in the particle mass spectra. Taken together, these findings then support the use of kappa as a simplified yet accurate general parameter to represent the CCN activation of secondary organic material in large-scale atmospheric and climate models, thereby greatly reducing the computational burden while simultaneously including the most recent mechanistic findings of laboratory studies.

  12. Science Overview Document Indirect and Semi-Direct Aerosol Campaign (ISDAC) April 2008

    SciTech Connect (OSTI)

    SJ Ghan; B Schmid; JM Hubbe; CJ Flynn; A Laskin; AA Zelenyuk; DJ Czizco; CN Long; G McFarquhar; J Verlinde; J Harrington; JW Strapp; P Liu; A Korolev; A McDonald; M Wolde; A Fridlind; T Garrett; G Mace; G Kok; S Brooks; D Collins; D Lubin; P Lawson; M Dubey; C Mazzoleni; M Shupe; S Xie; DD Turner; Q Min; EJ Mlawer; D Mitchell

    2007-11-01

    The ARM Climate Research Facility’s (ACRF) Aerial Vehicle Program (AVP) will deploy an intensive cloud and aerosol observing system to the ARM North Slope of Alaska (NSA) locale for a five week Indirect and Semi-Direct Aerosol Campaign (ISDAC) during period 29 March through 30 April 2008. The deployment period is within the International Polar Year, thus contributing to and benefiting from the many ancillary observing systems collecting data synergistically. We will deploy the Canadian National Research Council Convair 580 aircraft to measure temperature, humidity, total particle number, aerosol size distribution, single particle composition, concentrations of cloud condensation nuclei and ice nuclei, optical scattering and absorption, updraft velocity, cloud liquid water and ice contents, cloud droplet and crystal size distributions, cloud particle shape, and cloud extinction. In addition to these aircraft measurements, ISDAC will deploy two instruments at the ARM site in Barrow: a spectroradiometer to retrieve cloud optical depth and effective radius, and a tandem differential mobility analyzer to measure the aerosol size distribution and hygroscopicity. By using many of the same instruments used during Mixed-Phase Arctic Cloud Experiment (M-PACE), conducted in October 2004, we will be able to contrast the arctic aerosol and cloud properties during the fall and spring transitions. The aerosol measurements can be used in cloud models driven by objectively analyzed boundary conditions to test whether the cloud models can simulate the aerosol influence on the clouds. The influence of aerosol and boundary conditions on the simulated clouds can be separated by running the cloud models with all four combinations of M-PACE and ISDAC aerosol and boundary conditions: M-PACE aerosol and boundary conditions, M-PACE aerosol and ISDAC boundary conditions, ISDAC aerosol and M-PACE boundary conditions, and ISDAC aerosol and boundary conditions. ISDAC and M-PACE boundary conditions are likely to be very different because of the much more extensive ocean water during M-PACE. The uniformity of the surface conditions during ISDAC greatly simplifies the objective analysis (surface fluxes and precipitation are very weak), so that it can largely rely on the European Centre for Medium-Range Weather Forecasts analysis. The aerosol measurements can also be used as input to the cloud models and to evaluate the aerosol retrievals. By running the cloud models with and without solar absorption by the aerosols, we can determine the semidirect effect of the aerosol on the clouds.

  13. Inverse modelling of cloud-aerosol interactions - Part 2: Sensitivity tests on liquid phase clouds using a Markov chain Monte Carlo based simulation approach

    E-Print Network [OSTI]

    Partridge, D. G; Vrugt, J. A; Tunved, P.; Ekman, A. M. L; Struthers, H.; Sorooshian, A.

    2012-01-01

    Seinfeld, J. H. : Aerosol, cloud drop concentration closureof aerosol composition on cloud droplet size distribution –aerosol properties on warm cloud droplet activation, At-

  14. Aerosol Observing System (AOS) Handbook

    SciTech Connect (OSTI)

    Jefferson, A

    2011-01-17

    The Aerosol Observing System (AOS) is a suite of in situ surface measurements of aerosol optical and cloud-forming properties. The instruments measure aerosol properties that influence the earth’s radiative balance. The primary optical measurements are those of the aerosol scattering and absorption coefficients as a function of particle size and radiation wavelength and cloud condensation nuclei (CCN) measurements as a function of percent supersaturation. Additional measurements include those of the particle number concentration and scattering hygroscopic growth. Aerosol optical measurements are useful for calculating parameters used in radiative forcing calculations such as the aerosol single-scattering albedo, asymmetry parameter, mass scattering efficiency, and hygroscopic growth. CCN measurements are important in cloud microphysical models to predict droplet formation.

  15. Effects on precipitation, clouds, and temperature from long-range transport of idealized aerosol plumes in WRF-Chem simulations

    E-Print Network [OSTI]

    Zhao, Zhan; Pritchard, Michael S; Russell, Lynn M

    2012-01-01

    on intense convective precipitation in the northeastern US,aerosols on regional precipitation over East Asia, J.of aerosols on surface precipitation from clouds: An attempt

  16. A new aerosol collector for quasi on-line analysis of particulate organic matter: the Aerosol Collection Module (ACM) and first applications with a GC/MS-FID

    E-Print Network [OSTI]

    Hohaus, T.

    In many environments organic matter significantly contributes to the composition of atmospheric aerosol particles influencing its properties. Detailed chemical characterization of ambient aerosols is critical in order to ...

  17. Marine aerosols

    E-Print Network [OSTI]

    Saltzman, ES

    2009-01-01

    proper- ties found in the marine boundary layer over theand R. E. Larson (1994), Marine boundary layer measurementsand T. Hoffmann (2002), Marine aerosol formation from

  18. Shortwave aerosol radiative forcing over cloud-free oceans from Terra: 1. Angular models for aerosols

    E-Print Network [OSTI]

    Christopher, Sundar A.

    Sensor Microwave Imager (SSM/I) data to obtain near surface wind speed. The new aerosol ADMs are built to obtain aerosol properties within a Clouds and Earth Radiant Energy System (CERES) footprint and Special as functions of near-surface ocean wind speed and MODIS aerosol optical depth at 0.55 mm (t0.55). Among the new

  19. Challenge the future 1 Observations of aerosol-cloud-radiation

    E-Print Network [OSTI]

    Graaf, Martin de

    -road Industrial coal Residential solid fuel Biofuel cooking Biofuel heating Coal Open Burning Agricultural fields causes Differences in: · cloud properties · cloud fraction and location · aerosol properties · smoke

  20. Final Technical Report for "Ice nuclei relation to aerosol properties: Data analysis and model parameterization for IN in mixed-phase clouds"Ă?Âť (DOE/SC00002354)

    SciTech Connect (OSTI)

    Paul J. DeMott, Anthony J. Prenni; Sonia M. Kreidenweis

    2012-09-28

    Clouds play an important role in weather and climate. In addition to their key role in the hydrologic cycle, clouds scatter incoming solar radiation and trap infrared radiation from the surface and lower atmosphere. Despite their importance, feedbacks involving clouds remain as one of the largest sources of uncertainty in climate models. To better simulate cloud processes requires better characterization of cloud microphysical processes, which can affect the spatial extent, optical depth and lifetime of clouds. To this end, we developed a new parameterization to be used in numerical models that describes the variation of ice nuclei (IN) number concentrations active to form ice crystals in mixed-phase (water droplets and ice crystals co-existing) cloud conditions as these depend on existing aerosol properties and temperature. The parameterization is based on data collected using the Colorado State University continuous flow diffusion chamber in aircraft and ground-based campaigns over a 14-year period, including data from the DOE-supported Mixed-Phase Arctic Cloud Experiment. The resulting relationship is shown to more accurately represent the variability of ice nuclei distributions in the atmosphere compared to currently used parameterizations based on temperature alone. When implemented in one global climate model, the new parameterization predicted more realistic annually averaged cloud water and ice distributions, and cloud radiative properties, especially for sensitive higher latitude mixed-phase cloud regions. As a test of the new global IN scheme, it was compared to independent data collected during the 2008 DOE-sponsored Indirect and Semi-Direct Aerosol Campaign (ISDAC). Good agreement with this new data set suggests the broad applicability of the new scheme for describing general (non-chemically specific) aerosol influences on IN number concentrations feeding mixed-phase Arctic stratus clouds. Finally, the parameterization was implemented into a regional cloud-resolving model to compare predictions of ice crystal concentrations and other cloud properties to those observed in two intensive case studies of Arctic stratus during ISDAC. Our implementation included development of a prognostic scheme of ice activation using the IN parameterization so that the most realistic treatment of ice nuclei, including their budget (gains and losses), was achieved. Many cloud microphysical properties and cloud persistence were faithfully reproduced, despite a tendency to under-predict (by a few to several times) ice crystal number concentrations and cloud ice mass, in agreement with some other studies. This work serves generally as the basis for improving predictive schemes for cloud ice crystal activation in cloud and climate models, and more specifically as the basis for such a scheme to be used in a Multi-scale Modeling Format (MMF) that utilizes a connected system of cloud-resolving models on a global grid in an effort to better resolve cloud processes and their influence on climate.

  1. Non-intrusive characterization of heat transfer fluid aerosol formation 

    E-Print Network [OSTI]

    Krishna, Kiran

    2001-01-01

    in process equipment. Predictive models relating the aerosol formation distances, aerosol droplet size, and volume concentrations to bulk liquid pressure, temperature, fluid properties, leak size and ambient conditions are developed. These models will be used...

  2. BIOMASS BURNING IN THE AMAZON: LINKS BETWEEN BURNING, SCIAMACHY TRACE GASES, AND AEROSOL AND SURFACE PROPERTIES FROM THE ORAC-AATSR RETRIEVAL

    E-Print Network [OSTI]

    Oxford, University of

    BIOMASS BURNING IN THE AMAZON: LINKS BETWEEN BURNING, SCIAMACHY TRACE GASES, AND AEROSOL@atm.ox.ac.uk AEROSOL AND GAS PROPERTIESSEASONALITY OF BURNING Biomass burning in the Amazon shows strong seasonal in aerosol optical depth (AOD) and effective radius, linked to biomass burning through detected fires. Use

  3. Chemical composition, microstructure, and hygroscopic properties of aerosol particles at the Zotino Tall Tower Observatory (ZOTTO), Siberia, during a summer campaign

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mikhailov, E. F.; Mironov, G. N.; Pöhlker, C.; Chi, X.; Krüger, M. L.; Shiraiwa, M.; Förster, J. -D.; Pöschl, U.; Vlasenko, S. S.; Ryshkevich, T. I.; et al

    2015-03-16

    In this study we describe the hygroscopic properties of accumulation- and coarse-mode aerosol particles sampled at the Zotino Tall Tower Observatory (ZOTTO) in Central Siberia (61° N; 89° E) from 16 to 21 June 2013. The hygroscopic growth measurements were supplemented with chemical analyses of the samples, including inorganic ions and organic/elemental carbon. In addition, the microstructure and chemical composition of aerosol particles were analyzed by X-ray micro-spectroscopy (STXM-NEXAFS) and transmission electron microscopy (TEM). A mass closure analysis indicates that organic carbon accounted for 61 and 38% of PM in the accumulation mode and coarse mode, respectively. The water solublemore »fraction of organic matter was estimated to be 52 and 8% of PM in these modes. Sulfate, predominantly in the form of ammoniated sulfate, was the dominant inorganic component in both size modes: ~ 34% in the accumulation vs. ~ 47% in the coarse mode. The hygroscopic growth measurements were conducted with a filter-based differential hygroscopicity analyzer (FDHA) over the range of 5–99.4% RH in the hydration and dehydration operation modes. The FDHA study indicates that both accumulation and coarse modes exhibit pronounced water uptake approximately at the same RH, starting at ~ 70%, while efflorescence occurred at different humidities, i.e., at ~ 35% RH for submicron particles vs. ~ 50% RH for supermicron particles. This ~ 15% RH difference was attributed to higher content of organic material in the submicron particles, which suppresses water release in the dehydration experiments. The kappa mass interaction model (KIM) was applied to characterize and parameterize non-ideal solution behavior and concentration-dependent water uptake by atmospheric aerosol samples in the 5–99.4% RH range. Based on KIM, the volume-based hygroscopicity parameter, ?v, was calculated. The ?v, ws value related to the water soluble (ws) fraction was estimated to be ~ 0.15 for the accumulation mode and ~ 0.36 for the coarse mode, respectively. The obtained ?v, ws for the accumulation mode is in good agreement with earlier data reported for remote sites in the Amazon rain forest (?v ≈ 0.15) and a Colorado boreal forest (?v ≈ 0.16). We used the Zdanovskii–Stokes–Robinson (ZSR) mixing rule to predict the chemical composition dependent hygroscopicity, ?v, p. The obtained ?v, p values overestimate the experimental FDHA-KIM-derived ?v, ws by factors of 1.8 and 1.5 for the accumulation and coarse modes, respectively. This divergence can be partly explained by incomplete dissolution of the hygroscopic inorganic compounds resulting from kinetic limitations due to a sparingly soluble organic coating. The TEM and STXM-NEXAFS results indicate that aged submicron (>300 nm) and supermicron aerosol particles possess core-shell structures with an inorganic core, and are enriched in organic carbon at the mixed particle surface. The direct FDHA kinetic studies provide a bulk diffusion coefficient of water of ~ 10?12 cm2 s?1 indicating a semi-solid state of the organic-rich phase leading to kinetic limitations of water uptake and release during hydration and dehydration cycles. Overall the present ZOTTO data set, obtained in the growing season, has revealed a strong influence of organic carbon on the hygroscopic properties of the ambient aerosols. The sparingly soluble organic coating controls hygroscopic growth, phase transitions, and microstructural rearrangement processes. The observed kinetic limitations can strongly influence the outcome of experiments performed on multi-second time scales, such as the commonly applied HTDMA (Hygroscopicity Tandem Differential Mobility Analyzer) and CCNC (Cloud Condensation Nuclei Counter) measurements.« less

  4. Clouds of short-circuited thermionic nanobatteries and promising prospects for development of nanobattery-based aerosol fusion reactors. The preliminary report

    E-Print Network [OSTI]

    Meshcheryakov, Oleg

    2012-01-01

    The physical mechanisms of periodic separation and relaxation of electric charges within aerosol particles possessing the properties the short-circuited batteries can be extremely diverse. With use of appropriate materials and dispersing methods, the electrochemical, thermoelectric, thermionic, pyroelectric, photoelectric, photo electronic emission, or even radionuclide-based emission micro and nano-batteries can be synthesized and be dispersed in the air as clouds self-assembed of the short-circuited aerosol batteries due to the inter-particle electromagnetic dipole-dipole attraction. Intense thermionic emission from ionized hot spots migrating on the relatively cold surface of charged explosive particles, can convert these particles into short-circuited thermionic batteries, turning an aerosol cloud consisting of such unipolar charged, gradually decomposing explosive particles into ball lightning. The slow exothermic decomposition of the highly sensitive explosive aerosol particles, catalyzed by excess ions...

  5. Method and apparatus for measuring the intensity and phase of one or more ultrashort light pulses and for measuring optical properties of materials

    DOE Patents [OSTI]

    Trebino, Rick P. (Livermore, CA); DeLong, Kenneth W. (Livermore, CA)

    1996-01-01

    The intensity and phase of one or more ultrashort light pulses are obtained using a non-linear optical medium. Information derived from the light pulses is also used to measure optical properties of materials. Various retrieval techniques are employed. Both "instantaneously" and "non-instantaneously" responding optical mediums may be used.

  6. Developing models of aerosol representation to investigate composition, evolution, optical properties, and CCN spectra using measurements of size-resolved hygroscopicity 

    E-Print Network [OSTI]

    Gasparini, Roberto

    2006-08-16

    , size and hygroscopicity information were combined to model the aerosol as a population of multi-component particles. With this model, the aerosol hygroscopic growth factor f(RH), relating the submicron scattering at high RH to that at low RH...

  7. Clouds of short-circuited thermionic nanobatteries and promising prospects for development of nanobattery-based aerosol fusion reactors. The preliminary report

    E-Print Network [OSTI]

    Oleg Meshcheryakov

    2012-04-13

    The physical mechanisms of periodic separation and relaxation of electric charges within aerosol particles possessing the properties the short-circuited batteries can be extremely diverse. With use of appropriate materials and dispersing methods, the electrochemical, thermoelectric, thermionic, pyroelectric, photoelectric, photo electronic emission, or even radionuclide-based emission micro and nano-batteries can be synthesized and be dispersed in the air as clouds self-assembed of the short-circuited aerosol batteries due to the inter-particle electromagnetic dipole-dipole attraction. Intense thermionic emission from ionized hot spots migrating on the relatively cold surface of charged explosive particles, can convert these particles into short-circuited thermionic batteries, turning an aerosol cloud consisting of such unipolar charged, gradually decomposing explosive particles into ball lightning. The slow exothermic decomposition of the highly sensitive explosive aerosol particles, catalyzed by excess ions on their surface, and also ion-catalyzed reactions of slow water vapor induced oxidation of charged combustible aerosol particles underlie two main classes of natural ball lightning. At the same time, the artificially generated clouds consisting of such unipolar charged aerosol nanobatteries, probably, can have some useful applications, not only military ones. In particular, it seems that high-performance pyroelectric fusion reactors could be created on the basis of such ball-shaped aerosol clouds self-assembled of pyroelectric nanocrystals - short-circuited pyroelectric nanobatteries.

  8. Aerosol Science and Technology, 48:803812, 2014 Copyright C American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 48:803­812, 2014 Copyright C American Association for Aerosol of particle growth in the atmosphere, and many properties of the resulting mixed particles depend on organic. In this article, analytic equations are derived p(;d) for condensational growth in a continuously mixed flow

  9. Project Overview: Cumulus Humilis Aerosol Processing Study (CHAPS): Proposed Summer 2007 ASP Field Campaign

    SciTech Connect (OSTI)

    Berkowitz, Carl M.; Berg, Larry K.; Ogren, J. A.; Hostetler, Chris A.; Ferrare, Richard

    2006-05-18

    This white paper presents the scientific motivation and preliminary logistical plans for a proposed ASP field campaign to be carried out in the summer of 2007. The primary objective of this campaign is to use the DOE Gulfstream-1 aircraft to make measurements characterizing the chemical, physical and optical properties of aerosols below, within and above large fields of fair weather cumulus and to use the NASA Langley Research Center’s High Spectral Resolution Lidar (HSRL) to make independent measurements of aerosol backscatter and extinction profiles in the vicinity of these fields. Separate from the science questions to be addressed by these observations will be information to add in the development of a parameterized cumulus scheme capable of including multiple cloud fields within a regional or global scale model. We will also be able to compare and contrast the cloud and aerosol properties within and outside the Oklahoma City plume to study aerosol processes within individual clouds. Preliminary discussions with the Cloud and Land Surface Interaction Campaign (CLASIC) science team have identified overlap between the science questions posed for the CLASIC Intensive Operation Period (IOP) and the proposed ASP campaign, suggesting collaboration would benefit both teams.

  10. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian (Port Jefferson, NY); Kulkarni, Pramod (Port Jefferson Station, NY)

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  11. ARM - Measurement - Aerosol optical properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach Home Room NewsgovMeasurementsAdvectiveeffectiveproperties

  12. ARM - AOS Aerosol Properties Plots

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers'Organization and Contact

  13. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  14. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  15. Effects of aerosols on deep convective cumulus clouds 

    E-Print Network [OSTI]

    Fan, Jiwen

    2009-05-15

    in the droplet size. Ice processes are more sensitive to the changes of aerosol chemical properties than the warm rain processes. The most noticeable effect of increasing aerosol number concentrations is an increase of CDNC and cloud water content but a decrease...

  16. Aerodynamic Focusing Of High-Density Aerosols

    SciTech Connect (OSTI)

    Ruiz, D. E.; Fisch, Nathaniel

    2014-02-24

    High-density micron-sized particle aerosols might form the basis for a number of applications in which a material target with a particular shape might be quickly ionized to form a cylindrical or sheet shaped plasma. A simple experimental device was built in order to study the properties of high-density aerosol focusing for 1#22; m silica spheres. Preliminary results recover previous findings on aerodynamic focusing at low densities. At higher densities, it is demonstrated that the focusing properties change in a way which is consistent with a density dependent Stokes number.

  17. The role of precipitation size distributions in km-scale NWP simulations of intense precipitation: Evaluation of cloud properties and surface precipitation

    SciTech Connect (OSTI)

    Van Weverberg K.; Vogelmann A.; van Lipzig, N. P. M.; Delobbec, L.

    2012-04-01

    We investigate the sensitivity of simulated cloud properties and surface precipitation to assumptions regarding the size distributions of the precipitating hydrometeors in a one-moment bulk microphysics scheme. Three sensitivity experiments were applied to two composites of 15 convective and 15 frontal stratiform intense precipitation events observed in a coastal midlatitude region (Belgium), which were evaluated against satellite-retrieved cloud properties and radar-rain-gauge derived surface precipitation. It is found that the cloud optical thickness distribution was well captured by all experiments, although a significant underestimation of cloudiness occurred in the convective composite. The cloud-top-pressure distribution was improved most by more realistic snow size distributions (including a temperature-dependent intercept parameter and non-spherical snow for the calculation of the slope parameter), due to increased snow depositional growth at high altitudes. Surface precipitation was far less sensitive to whether graupel or hail was chosen as the rimed ice species, as compared to previous idealized experiments. This smaller difference in sensitivity could be explained by the stronger updraught velocities and higher freezing levels in the idealized experiments compared to typical coastal midlatitude environmental conditions.

  18. Development and Characterization of a Thermodenuder for Aerosol Volatility Measurements

    SciTech Connect (OSTI)

    Dr. Timothy Onasch

    2009-09-09

    This SBIR Phase I project addressed the critical need for improved characterization of carbonaceous aerosol species in the atmosphere. The proposed work focused on the development of a thermodenuder (TD) system capable of systematically measuring volatility profiles of primary and secondary organic aerosol species and providing insight into the effects of absorbing and nonabsorbing organic coatings on particle absorption properties. This work provided the fundamental framework for the generation of essential information needed for improved predictions of ambient aerosol loadings and radiative properties by atmospheric chemistry models. As part of this work, Aerodyne Research, Inc. (ARI) continued to develop and test, with the final objective of commercialization, an improved thermodenuder system that can be used in series with any aerosol instrument or suite of instruments (e.g., aerosol mass spectrometers-AMS, scanning mobility particle sizers-SMPS, photoacoustic absorption spectrometers-PAS, etc.) to obtain aerosol chemical, physical, and optical properties as a function of particle volatility. In particular, we provided the proof of concept for the direct coupling of our improved TD design with a full microphysical model to obtain volatility profiles for different organic aerosol components and to allow for meaningful comparisons between different TD-derived aerosol measurements. In a TD, particles are passed through a heated zone and a denuding (activated charcoal) zone to remove semi-volatile material. Changes in particle size, number concentration, optical absorption, and chemical composition are subsequently detected with aerosol instrumentation. The aerosol volatility profiles provided by the TD will strengthen organic aerosol emission inventories, provide further insight into secondary aerosol formation mechanisms, and provide an important measure of particle absorption (including brown carbon contributions and identification, and absorption enhancements due to coatings on soot particles). The successfully completed Phase I project included construction of a prototype design for the TD with detailed physical modeling, testing with laboratory and ambient aerosol particles, and the initiation of a detailed microphysical model of the aerosol particles passing through the TD to extract vapor pressure distributions. The objective of the microphysical model is to derive vapor pressure distributions (i.e. vapor pressure ranges, including single chemical compounds, mixtures of known compounds, and complex ‘real-world’ aerosols, such as SOA, and soot particles with absorbing and nonabsorbing coatings) from TD measurements of changes in particle size, mass, and chemical composition for known TD temperatures and flow rates (i.e. residence times). The proposed Phase II project was designed to optimize several TD systems for different instrument applications and to combine the hardware and modeling into a robust package for commercial sales.

  19. INTRODUCTION Atmospheric aerosol particles influence the Earth's

    E-Print Network [OSTI]

    Wunderle, Stefan

    , scattering, and absorbing solar electromagnetic radiation and by modifying cloud properties due to their roleINTRODUCTION Atmospheric aerosol particles influence the Earth's radiation budget by reflecting to maximum cover a region once in the daytime. In contrary, up-to-date geostationary instruments like

  20. Light intensity compressor

    DOE Patents [OSTI]

    Rushford, Michael C. (Livermore, CA)

    1990-01-01

    In a system for recording images having vastly differing light intensities over the face of the image, a light intensity compressor is provided that utilizes the properties of twisted nematic liquid crystals to compress the image intensity. A photoconductor or photodiode material that is responsive to the wavelength of radiation being recorded is placed adjacent a layer of twisted nematic liquid crystal material. An electric potential applied to a pair of electrodes that are disposed outside of the liquid crystal/photoconductor arrangement to provide an electric field in the vicinity of the liquid crystal material. The electrodes are substantially transparent to the form of radiation being recorded. A pair of crossed polarizers are provided on opposite sides of the liquid crystal. The front polarizer linearly polarizes the light, while the back polarizer cooperates with the front polarizer and the liquid crystal material to compress the intensity of a viewed scene. Light incident upon the intensity compressor activates the photoconductor in proportion to the intensity of the light, thereby varying the field applied to the liquid crystal. The increased field causes the liquid crystal to have less of a twisting effect on the incident linearly polarized light, which will cause an increased percentage of the light to be absorbed by the back polarizer. The intensity of an image may be compressed by forming an image on the light intensity compressor.

  1. Climate implications of carbonaceous aerosols: An aerosol microphysical study using the GISS/MATRIX climate model

    SciTech Connect (OSTI)

    Bauer, Susanne E.; Menon, Surabi; Koch, Dorothy; Bond, Tami; Tsigaridis, Kostas

    2010-04-09

    Recently, attention has been drawn towards black carbon aerosols as a likely short-term climate warming mitigation candidate. However the global and regional impacts of the direct, cloud-indirect and semi-direct forcing effects are highly uncertain, due to the complex nature of aerosol evolution and its climate interactions. Black carbon is directly released as particle into the atmosphere, but then interacts with other gases and particles through condensation and coagulation processes leading to further aerosol growth, aging and internal mixing. A detailed aerosol microphysical scheme, MATRIX, embedded within the global GISS modelE includes the above processes that determine the lifecycle and climate impact of aerosols. This study presents a quantitative assessment of the impact of microphysical processes involving black carbon, such as emission size distributions and optical properties on aerosol cloud activation and radiative forcing. Our best estimate for net direct and indirect aerosol radiative forcing change is -0.56 W/m{sup 2} between 1750 and 2000. However, the direct and indirect aerosol effects are very sensitive to the black and organic carbon size distribution and consequential mixing state. The net radiative forcing change can vary between -0.32 to -0.75 W/m{sup 2} depending on these carbonaceous particle properties. Assuming that sulfates, nitrates and secondary organics form a coating shell around a black carbon core, rather than forming a uniformly mixed particles, changes the overall net radiative forcing from a negative to a positive number. Black carbon mitigation scenarios showed generally a benefit when mainly black carbon sources such as diesel emissions are reduced, reducing organic and black carbon sources such as bio-fuels, does not lead to reduced warming.

  2. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  3. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  4. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  5. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  6. SPATIO-TEMPORAL CHARACTERIZATION OF AEROSOLS THROUGH ACTIVE USE OF DATA FROM MULTIPLE SENSORS

    E-Print Network [OSTI]

    Obradovic, Zoran

    climate change related studies. In recent years remote sensing instruments of various properties have been. Aerosol concentration and chemical properties are important parameters in climate change modelsSPATIO-TEMPORAL CHARACTERIZATION OF AEROSOLS THROUGH ACTIVE USE OF DATA FROM MULTIPLE SENSORS Z

  7. Method and apparatus for aerosol particle absorption spectroscopy

    DOE Patents [OSTI]

    Campillo, Anthony J. (Nesconset, NY); Lin, Horn-Bond (Manorville, NY)

    1983-11-15

    A method and apparatus for determining the absorption spectra, and other properties, of aerosol particles. A heating beam source provides a beam of electromagnetic energy which is scanned through the region of the spectrum which is of interest. Particles exposed to the heating beam which have absorption bands within the band width of the heating beam absorb energy from the beam. The particles are also illuminated by light of a wave length such that the light is scattered by the particles. The absorption spectra of the particles can thus be determined from an analysis of the scattered light since the absorption of energy by the particles will affect the way the light is scattered. Preferably the heating beam is modulated to simplify the analysis of the scattered light. In one embodiment the heating beam is intensity modulated so that the scattered light will also be intensity modulated when the particles absorb energy. In another embodiment the heating beam passes through an interferometer and the scattered light reflects the Fourier Transform of the absorption spectra.

  8. RACORO aerosol data processing

    SciTech Connect (OSTI)

    Elisabeth Andrews

    2011-10-31

    The RACORO aerosol data (cloud condensation nuclei (CCN), condensation nuclei (CN) and aerosol size distributions) need further processing to be useful for model evaluation (e.g., GCM droplet nucleation parameterizations) and other investigations. These tasks include: (1) Identification and flagging of 'splash' contaminated Twin Otter aerosol data. (2) Calculation of actual supersaturation (SS) values in the two CCN columns flown on the Twin Otter. (3) Interpolation of CCN spectra from SGP and Twin Otter to 0.2% SS. (4) Process data for spatial variability studies. (5) Provide calculated light scattering from measured aerosol size distributions. Below we first briefly describe the measurements and then describe the results of several data processing tasks that which have been completed, paving the way for the scientific analyses for which the campaign was designed. The end result of this research will be several aerosol data sets which can be used to achieve some of the goals of the RACORO mission including the enhanced understanding of cloud-aerosol interactions and improved cloud simulations in climate models.

  9. Aerosol Science and Technology, 39:6883, 2005 Copyright c American Association for Aerosol Research

    E-Print Network [OSTI]

    . Coffman5 1 Finnish Meteorological Institute, Air Quality Research, Sahaajankatu, Helsinki, Finland 2¨ais¨al¨a Foundation (Finland), and the 100th Anniversary Foundation of Helsingin Sanomat (Finland). Address, 00880 Helsinki, Finland. E-mail: aki.virkkula@fmi.fi properties of aerosols depend on the wavelength

  10. Organic Aerosol Component (OACOMP) Value-Added Product Report

    SciTech Connect (OSTI)

    Fast, J; Zhang, Q; Tilp, A; Shippert, T; Parworth, C; Mei, F

    2013-08-23

    Significantly improved returns in their aerosol chemistry data can be achieved via the development of a value-added product (VAP) of deriving OA components, called Organic Aerosol Components (OACOMP). OACOMP is primarily based on multivariate analysis of the measured organic mass spectral matrix. The key outputs of OACOMP are the concentration time series and the mass spectra of OA factors that are associated with distinct sources, formation and evolution processes, and physicochemical properties.

  11. Modeling aerosols and their interactions with shallow cumuli during the 2007 CHAPS field study

    SciTech Connect (OSTI)

    Shrivastava, ManishKumar B.; Berg, Larry K.; Fast, Jerome D.; Easter, Richard C.; Laskin, Alexander; Chapman, Elaine G.; Gustafson, William I.; Liu, Ying; Berkowitz, Carl M.

    2013-02-07

    The Weather Research and Forecasting model coupled with chemistry (WRF-Chem) is used to simulate relationships between aerosols and clouds in the vicinity of Oklahoma City during the June 2007 Cumulus Humilis Aerosol Processing Study (CHAPS). The regional scale simulation completed using 2 km horizontal grid spacing evaluates four important relationships between aerosols and shallow cumulus clouds observed during CHAPS. First, the model reproduces the trends of higher nitrate volume fractions in cloud droplet residuals compared to interstitial non-activated aerosols, as measured using the Aerosol Mass Spectrometer. Comparing simulations with cloud chemistry turned on and off, we show that nitric acid vapor uptake by cloud droplets explains the higher nitrate content of cloud droplet residuals. Second, as documented using an offline code, both aerosol water and other inorganics (OIN), which are related to dust and crustal emissions, significantly affect predicted aerosol optical properties. Reducing the OIN content of wet aerosols by 50% significantly improves agreement of model predictions with measurements of aerosol optical properties. Third, the simulated hygroscopicity of aerosols is too high as compared to their hygroscopicity derived from cloud condensation nuclei and particle size distribution measurements, indicating uncertainties associated with simulating size-dependent chemical composition and treatment of aerosol mixing state within the model. Fourth, the model reasonably represents the observations of the first aerosol indirect effect where pollutants in the vicinity of Oklahoma City increase cloud droplet number concentrations and decrease the droplet effective radius. While previous studies have often focused on cloud-aerosol interactions in stratiform and deep convective clouds, this study highlights the ability of regional-scale models to represent some of the important aspects of cloud-aerosol interactions associated with fields of short-lived shallow cumuli.

  12. Implementing marine organic aerosols into the GEOS-Chem model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gantt, B.; Johnson, M. S.; Crippa, M.; Prévôt, A. S. H.; Meskhidze, N.

    2015-03-17

    Marine-sourced organic aerosols (MOAs) have been shown to play an important role in tropospheric chemistry by impacting surface mass, cloud condensation nuclei, and ice nuclei concentrations over remote marine and coastal regions. In this work, an online marine primary organic aerosol emission parameterization, designed to be used for both global and regional models, was implemented into the GEOS-Chem (Global Earth Observing System Chemistry) model. The implemented emission scheme improved the large underprediction of organic aerosol concentrations in clean marine regions (normalized mean bias decreases from -79% when using the default settings to -12% when marine organic aerosols are added). Modelmore »predictions were also in good agreement (correlation coefficient of 0.62 and normalized mean bias of -36%) with hourly surface concentrations of MOAs observed during the summertime at an inland site near Paris, France. Our study shows that MOAs have weaker coastal-to-inland concentration gradients than sea-salt aerosols, leading to several inland European cities having >10% of their surface submicron organic aerosol mass concentration with a marine source. The addition of MOA tracers to GEOS-Chem enabled us to identify the regions with large contributions of freshly emitted or aged aerosol having distinct physicochemical properties, potentially indicating optimal locations for future field studies.« less

  13. Implementing marine organic aerosols into the GEOS-Chem model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gantt, B.; Johnson, M. S.; Crippa, M.; Prévôt, A. S. H.; Meskhidze, N.

    2014-09-09

    Marine organic aerosols (MOA) have been shown to play an important role in tropospheric chemistry by impacting surface mass, cloud condensation nuclei, and ice nuclei concentrations over remote marine and coastal regions. In this work, an online marine primary organic aerosol emission parameterization, designed to be used for both global and regional models, was implemented into the GEOS-Chem model. The implemented emission scheme improved the large underprediction of organic aerosol concentrations in clean marine regions (normalized mean bias decreases from -79% when using the default settings to -12% when marine organic aerosols are added). Model predictions were also in goodmore »agreement (correlation coefficient of 0.62 and normalized mean bias of -36%) with hourly surface concentrations of MOA observed during the summertime at an inland site near Paris, France. Our study shows that MOA have weaker coastal-to-inland concentration gradients than sea-salt aerosols, leading to several inland European cities having > 10% of their surface submicron organic aerosol mass concentration with a marine source. The addition of MOA tracers to GEOS-Chem enabled us to identify the regions with large contributions of freshly-emitted or aged aerosol having distinct physicochemical properties, potentially indicating optimal locations for future field studies.« less

  14. Aerosol collection characteristics of ambient aerosol samplers 

    E-Print Network [OSTI]

    Ortiz, Carlos A

    1978-01-01

    when the sampler is not in operation, both as functions of particle size and wind speed. Wind velocity was a major cause of bias for the four samplers when collecting aerosol particles & 10 um. Characteristic curves were very similar for the 0. 38 m... x 0. 38 m ( 15" x 15") Hi-Vol and the 0. 29 m x 0. 36 m (11&" x 14") Hi-Vol. At 28 um and wind speeds of 2, 8, and 24 km/hr, sampling effectiveness values respectively were 70, 43, and 43 percent for the 0. 38 m x 0. 38 m Hi-Vol and 81, 56, and 43...

  15. ARM - Field Campaign - Shortwave Radiation and Aerosol Intensive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD:govCampaignsReplicator Sonde CampaignBlackObservation

  16. Intensive Observation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLANIs gravityIntellectual PropertyEnergyAdvisor XESpring

  17. Carbonaceous Aerosols and Radiative Effects Study (CARES), g1-aircraft, sedlacek sp2

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sedlacek, Art

    The primary objective of the Carbonaceous Aerosol and Radiative Effects Study (CARES) in 2010 was to investigate the evolution of carbonaceous aerosols of different types and their optical and hygroscopic properties in central California, with a focus on the Sacramento urban plume.

  18. Mars aerosol studies with the MGS TES emission phase function observations: Optical depths, particle

    E-Print Network [OSTI]

    Whitney, Barbara A.

    aerosol properties to date. TES solar band and infrared (IR) spectral EPF sequences are analyzed to obtain and scattering of radiation; 6225 Planetology: Solar System Objects: Mars; KEYWORDS: Martian atmosphere, aerosols, radiative forcing from atmo- spheric dust solar absorption and thermal emission was recognized as a primary

  19. Carbonaceous Aerosols and Radiative Effects Study (CARES), g1-aircraft, sedlacek sp2

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sedlacek, Art

    2011-08-30

    The primary objective of the Carbonaceous Aerosol and Radiative Effects Study (CARES) in 2010 was to investigate the evolution of carbonaceous aerosols of different types and their optical and hygroscopic properties in central California, with a focus on the Sacramento urban plume.

  20. Long-term impacts of aerosols on vertical development of cloud and precipitation

    SciTech Connect (OSTI)

    Li Z.; Liu Y.; Niu, F.; Fan, J.; Rosenfeld, D.; Ding, Y.

    2011-11-13

    Aerosols alter cloud density and the radiative balance of the atmosphere. This leads to changes in cloud microphysics and atmospheric stability, which can either suppress or foster the development of clouds and precipitation. The net effect is largely unknown, but depends on meteorological conditions and aerosol properties. Here, we examine the long-term impact of aerosols on the vertical development of clouds and rainfall frequencies, using a 10-year dataset of aerosol, cloud and meteorological variables collected in the Southern Great Plains in the United States. We show that cloud-top height and thickness increase with aerosol concentration measured near the ground in mixed-phase clouds-which contain both liquid water and ice-that have a warm, low base. We attribute the effect, which is most significant in summer, to an aerosol-induced invigoration of upward winds. In contrast, we find no change in cloud-top height and precipitation with aerosol concentration in clouds with no ice or cool bases. We further show that precipitation frequency and rain rate are altered by aerosols. Rain increases with aerosol concentration in deep clouds that have a high liquid-water content, but declines in clouds that have a low liquid-water content. Simulations using a cloud-resolving model confirm these observations. Our findings provide unprecedented insights of the long-term net impacts of aerosols on clouds and precipitation.

  1. Maritime Aerosol Network as a component of Aerosol Robotic A. Smirnov,1,2

    E-Print Network [OSTI]

    Maritime Aerosol Network as a component of Aerosol Robotic Network A. Smirnov,1,2 B. N. Holben,2 I of the Maritime Aerosol Network (MAN), which has been developed as a component of the Aerosol Robotic Network), Maritime Aerosol Network as a component of Aerosol Robotic Network, J. Geophys. Res., 114, D06204, doi:10

  2. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometermore »(UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.« less

  3. Asthmatic responses to airborne acid aerosols

    SciTech Connect (OSTI)

    Ostro, B.D.; Lipsett, M.J.; Wiener, M.B.; Selner, J.C. )

    1991-06-01

    Controlled exposure studies suggest that asthmatics may be more sensitive to the respiratory effects of acidic aerosols than individuals without asthma. This study investigates whether acidic aerosols and other air pollutants are associated with respiratory symptoms in free-living asthmatics. Daily concentrations of hydrogen ion (H+), nitric acid, fine particulates, sulfates and nitrates were obtained during an intensive air monitoring effort in Denver, Colorado, in the winter of 1987-88. A panel of 207 asthmatics recorded respiratory symptoms, frequency of medication use, and related information in daily diaries. We used a multiple regression time-series model to analyze which air pollutants, if any, were associated with health outcomes reported by study participants. Airborne H+ was found to be significantly associated with several indicators of asthma status, including moderate or severe cough and shortness of breath. Cough was also associated with fine particulates, and shortness of breath with sulfates. Incorporating the participants' time spent outside and exercise intensity into the daily measure of exposure strengthened the association between these pollutants and asthmatic symptoms. Nitric acid and nitrates were not significantly associated with any respiratory symptom analyzed. In this population of asthmatics, several outdoor air pollutants, particularly airborne acidity, were associated with daily respiratory symptoms.

  4. Parameters of Distribution of the Primary Gamma-Transition Intensities Following Resonance Neutron Capture and Some Properties of Compound Nuclei $^{157,159}$Gd

    E-Print Network [OSTI]

    A. M. Sukhovoj; V. A. Khitrov

    2009-06-16

    The re-analysis of the published experimental data on the primary gamma-transition intensities following neutron capture in different groups of neutron resonances in $^{156,158}$Gd has been performed. There are determined the most probable values of sum of E1 and M1 primary transitions, numbers of excited by them levels of both parities, ratios of radiative strength functions k(M1)/k(E1), dispersions of deviations of random values of intensities from the average and ratios of mean intensities of primary transitions to levels J=5/2 with respect to analogous data for J=1/2 and 3/2 (capture of the 24 keV neutrons) in narrow excitation energy intervals. All the data on level density and sums of radiative strength functions confirm the presence of clearly expressed step-like structure in level density below 3 MeV and general trend in change in strength functions as changing primary gamma-transition energy. Variations of distribution dispersions and, especially, ratio k(M1)/k(E1) (or $k(E1)/k(M1)$) at changing excitation energy point to strong change in structure of these nuclei above 1.0-1.5 MeV.

  5. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  6. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  7. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Composition and Reactions of Atmospheric Aerosol Particles Print Microscopic aerosol particles in the atmosphere contain carbonaceous components from mineral dust and combustion...

  8. Aerodynamic focusing of high-density aerosols D.E. Ruiz a,n

    E-Print Network [OSTI]

    be modeled by a simple drag force within a prescribed background flowing gas. The particle-to-gas feedback to study the properties of high-density aerosol focusing for 1 m silica spheres. Preliminary results

  9. Light Scattering by Ice Crystals and Mineral Dust Aerosols in the Atmosphere 

    E-Print Network [OSTI]

    Bi, Lei

    2012-07-16

    Modeling the single-scattering properties of nonspherical particles in the atmo¬sphere (in particular, ice crystals and dust aerosols) has important applications to climate and remote sensing studies. The ?rst part of the dissertation (Chapters II...

  10. CARES: Carbonaceous Aerosol and Radiative Effects Study Operations Plan

    SciTech Connect (OSTI)

    Zaveri, RA; Shaw, WJ; Cziczo, DJ

    2010-07-12

    The CARES field campaign is motivated by the scientific issues described in the CARES Science Plan. The primary objectives of this field campaign are to investigate the evolution and aging of carbonaceous aerosols and their climate-affecting properties in the urban plume of Sacramento, California, a mid-size, mid-latitude city that is located upwind of a biogenic volatile organic compound (VOC) emission region. Our basic observational strategy is to make comprehensive gas, aerosol, and meteorological measurements upwind, within, and downwind of the urban area with the DOE G-1 aircraft and at strategically located ground sites so as to study the evolution of urban aerosols as they age and mix with biogenic SOA precursors. The NASA B-200 aircraft, equipped with the High Spectral Resolution Lidar (HSRL), digital camera, and the Research Scanning Polarimeter (RSP), will be flown in coordination with the G-1 to characterize the vertical and horizontal distribution of aerosols and aerosol optical properties, and to provide the vertical context for the G-1 and ground in situ measurements.

  11. COLLABORATIVE RESEARCH: Study of Aerosol Sources and Processing at the GVAX Pantnagar Supersite

    SciTech Connect (OSTI)

    Worsnop, Douglas R.

    2014-07-28

    This project funded the participation of scientists from seven research groups, running more than thirty instruments, in the Winter Intensive Operating Period (January-February 2012) of the Clean Air for London (ClearfLo) campaign at a rural site in Detling, UK, 45 km southeast of central London. The primary science questions for the ClearfLo Winter IOP were, 1) what is the urban increment of particulate matter (PM) and other pollutants in the greater London area, and, 2) what is the contribution of solid fuel use for home heating to wintertime PM? An additional motivation for the Detling measurements was the question of whether coatings on black carbon particles enhance absorption. The following four key accomplishments have been identified so far: 1) Chemical, physical and optical characterization of PM from local and regional sources (Figures 2, 4, 5 and 6). 2) Measurement of urban increment in particulate matter and gases in London (Figure 3). 3) Measurement of optical properties and chemical composition of coatings on black carbon containing particles indicates absorption enhancement. 4) First deployment of chemical ionization instrument (MOVI-CI-TOFMS) to measure both particle-phase and gas-phase organic acids. (See final report from Joel Thornton, University of Washington, for details.) Analysis of the large dataset acquired in Detling is ongoing and will yield further key accomplishments. These measurements of urban and rural aerosol properties will contribute to improved modeling of regional aerosol emissions, and of atmospheric aging and removal. The measurement of absorption enhancement by coatings on black carbon will contribute to improved modeling of the direct radiative properties of PM.

  12. CLouds and Aerosol Radiative Interaction and Forcing Investigation

    E-Print Network [OSTI]

    Graaf, Martin de

    Radiative Interaction and Forcing Investigation Version 1.0 Date March 2012 Status Final #12;#12;CLARIFI, by absorbing and scattering solar radiation, and more importantly, by modifying cloud propertiesCLARIFI CLouds and Aerosol Radiative Interaction and Forcing Investigation M. de Graaf, L

  13. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for assessing aerosol effects on cold season precipitation in California.

  14. Influences of emission sources and meteorology on aerosol chemistry in a polluted urban environment: results from DISCOVER-AQ California

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Young, D. E.; Kim, H.; Parworth, C.; Zhou, S.; Zhang, X.; Cappa, C. D.; Seco, R.; Kim, S.; Zhang, Q.

    2015-12-15

    The San Joaquin Valley (SJV) in California experiences persistent air quality problems associated with elevated particulate matter (PM) concentrations due to anthropogenic emissions, topography, and meteorological conditions. Thus it is important to unravel the various sources and processes that affect the physico-chemical properties of PM in order to better inform pollution abatement strategies and improve parameterizations in air quality models. more »Aerosol Mass Spectrometer (HR-ToF-AMS) and an Ionicon Proton Transfer Reaction Time-of-Flight Mass Spectrometer (PTR-TOF-MS) as part of the NASA Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) campaign. The average submicron aerosol (PM1) concentration was 31.0 ?g m?3 and the total mass was dominated by organic aerosols (OA, 55 %), followed by ammonium nitrate (35 %). High PM pollution events were commonly associated with elevated OA concentrations, mostly from primary sources. Organic aerosols had average atomic oxygen-to-carbon (O / C), hydrogen-to-carbon (H / C), and nitrogen-to-carbon (N / C) ratios of 0.42, 1.70, and 0.017, respectively. Six distinct sources of organic aerosol were identified from positive matrix factorization (PMF) analysis of the AMS data: hydrocarbon-like OA (HOA; 9 % of total OA; O / C = 0.09) associated with local traffic, cooking OA (COA; 28 % of total OA; O / C = 0.19) associated with food cooking activities, two biomass burning OAs (BBOA1; 13 % of total OA; O / C = 0.33 and BBOA2; 20 % of total OA; O / C = 0.60) most likely associated with residential space heating from wood combustion, and semi-volatile oxygenated OA (SV-OOA; 16 % of total OA; O / C = 0.63) and low volatility oxygenated OA (LV-OOA; 24 % of total OA; O / C = 0.90) formed via chemical reactions in the atmosphere. Large differences in aerosol chemistry at Fresno were observed between the current campaign (winter 2013) and a~previous wintertime campaign (winter 2010), most notably that PM1 concentrations were nearly three times higher in 2013 than in 2010. These variations were attributed to differences in the meteorological conditions, which influenced primary emissions and secondary aerosol formation. In particular, COA and BBOA concentrations were greater in 2013 than 2010, where colder temperatures in 2013 likely resulted in increased biomass burning activities. The influence from a nighttime formed residual layer that mixed down in the morning was found to be much more intense in 2013 than 2010, leading to sharp increases in ground-level concentrations of secondary aerosol species including nitrate, sulfate, and OOA, in the morning between 08:00 to 12:00 PST. This is an indication that nighttime chemistry might also be higher in 2013. As solar radiation was stronger in 2013 the higher nitrate and OOA concentrations in 2013 could also be partly due to greater photochemical production of secondary aerosol species. The greater solar radiation and larger range in temperature in 2013 also likely led to both SV-OOA and LV-OOA being observed in 2013 whereas only a single OOA factor was identified in 2010.« less

  15. Sources and properties of Amazonian aerosol particles

    E-Print Network [OSTI]

    2010-01-01

    of Emissions of Gases and Aero- sols from Nature), Atmos.nonprecipitating clouds on the aero- sol size distribution,2000), Development of an aero- sol mass spectrometer for

  16. Optical Properties of Secondary Organic Aerosols

    E-Print Network [OSTI]

    Kim, Hwajin

    2012-01-01

    J. H. Journal of Atmospheric Chemistry 1997 , 26, 189-193. (induced ageing, Atmospheric Chemistry and Physics, 11(21),emerging issues, Atmospheric Chemistry and Physics, 9(14),

  17. Optical Properties of Secondary Organic Aerosols

    E-Print Network [OSTI]

    Kim, Hwajin

    2012-01-01

    two SOA precursor hydrocarbon measurements within 2% of onetwo SOA precursor hydrocarbon measurements within 2% of onetwo SOA precursor hydrocarbon measurements within 2% of one

  18. Sources and properties of Amazonian aerosol particles

    E-Print Network [OSTI]

    2010-01-01

    using autonomous unmanned aerial vehicles, Atmos. Chem.derived. Autonomous, unmanned aerial vehicles have recently

  19. ARM - Field Campaign - MASRAD - Aerosol Optical Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01)govCampaignsFIRE-Arctic-govCampaignsLower

  20. ARM - Field Campaign - MASRAD: Marine Aerosol Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to

  1. Emerging Technology for Measuring Atmospheric Aerosol Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansas NuclearElectronic StructureEly M. Gelbard,SevenEconomic Methodologyfor

  2. Aerosol Observing System Upgraded

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TA I N P A T T E R N A NA LY S IDOE Office2 Aerosol

  3. Development of Aerosol Models for Radiative Flux Calculations at ARM Sites

    SciTech Connect (OSTI)

    Ogren, John A.; Dutton, Ellsworth G.; McComiskey, Allison C.

    2006-09-30

    The direct radiative forcing (DRF) of aerosols, the change in net radiative flux due to aerosols in non-cloudy conditions, is an essential quantity for understanding the human impact on climate change. Our work has addressed several key issues that determine the accuracy, and identify the uncertainty, with which aerosol DRF can be modeled. These issues include the accuracy of several radiative transfer models when compared to measurements and to each other in a highly controlled closure study using data from the ARM 2003 Aerosol IOP. The primary focus of our work has been to determine an accurate approach to assigning aerosol properties appropriate for modeling over averaged periods of time and space that represent the observed regional variability of these properties. We have also undertaken a comprehensive analysis of the aerosol properties that contribute most to uncertainty in modeling aerosol DRF, and under what conditions they contribute the most uncertainty. Quantification of these issues enables the community to better state accuracies of radiative forcing calculations and to concentrate efforts in areas that will decrease uncertainties in these calculations in the future.

  4. Optical properties of boreal forest fire smoke derived from Sun photometry

    E-Print Network [OSTI]

    Zeng, Ning

    Optical properties of boreal forest fire smoke derived from Sun photometry N. T. O'Neill,1 T. F 2001; published 13 June 2002. [1] Aerosol optical properties derived from Sun photometry were: Aerosols (0305); KEYWORDS: aerosols, forest fire smoke, Sun photometry, optics 1. Introduction [2] Smoke

  5. AERONET: The Aerosol Robotic Network

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    AERONET collaboration provides globally distributed observations of spectral aerosol optical Depth (AOD), inversion products, and precipitable water in diverse aerosol regimes. Aerosol optical depth data are computed for three data quality levels: Level 1.0 (unscreened), Level 1.5 (cloud-screened), and Level 2.0 (cloud screened and quality-assured). Inversions, precipitable water, and other AOD-dependent products are derived from these levels and may implement additional quality checks.[Copied from http://aeronet.gsfc.nasa.gov/new_web/system_descriptions.html

  6. eDPS Aerosol Collection

    SciTech Connect (OSTI)

    Venzie, J.

    2015-10-13

    The eDPS Aerosol Collection project studies the fundamental physics of electrostatic aerosol collection for national security applications. The interpretation of aerosol data requires understanding and correcting for biases introduced from particle genesis through collection and analysis. The research and development undertaken in this project provides the basis for both the statistical correction of existing equipment and techniques; as well as, the development of new collectors and analytical techniques designed to minimize unwanted biases while improving the efficiency of locating and measuring individual particles of interest.

  7. Chapter 3: Evaluating the impacts of carbonaceous aerosols on clouds and climate

    SciTech Connect (OSTI)

    Menon, Surabi; Del Genio, Anthony D.

    2007-09-03

    Any attempt to reconcile observed surface temperature changes within the last 150 years to changes simulated by climate models that include various atmospheric forcings is sensitive to the changes attributed to aerosols and aerosol-cloud-climate interactions, which are the main contributors that may well balance the positive forcings associated with greenhouse gases, absorbing aerosols, ozone related changes, etc. These aerosol effects on climate, from various modeling studies discussed in Menon (2004), range from +0.8 to -2.4 W m{sup -2}, with an implied value of -1.0 W m{sup -2} (range from -0.5 to -4.5 W m{sup -2}) for the aerosol indirect effects. Quantifying the contribution of aerosols and aerosol-cloud interactions remain complicated for several reasons some of which are related to aerosol distributions and some to the processes used to represent their effects on clouds. Aerosol effects on low lying marine stratocumulus clouds that cover much of the Earth's surface (about 70%) have been the focus of most of prior aerosol-cloud interaction effect simulations. Since cumulus clouds (shallow and deep convective) are short lived and cover about 15 to 20% of the Earth's surface, they are not usually considered as radiatively important. However, the large amount of latent heat released from convective towers, and corresponding changes in precipitation, especially in biomass regions due to convective heating effects (Graf et al. 2004), suggest that these cloud systems and aerosol effects on them, must be examined more closely. The radiative heating effects for mature deep convective systems can account for 10-30% of maximum latent heating effects and thus cannot be ignored (Jensen and Del Genio 2003). The first study that isolated the sensitivity of cumulus clouds to aerosols was from Nober et al. (2003) who found a reduction in precipitation in biomass burning regions and shifts in circulation patterns. Aerosol effects on convection have been included in other models as well (cf. Jacobson, 2002) but the relative impacts on convective and stratiform processes were not separated. Other changes to atmospheric stability and thermodynamical quantities due to aerosol absorption are also known to be important in modifying cloud macro/micro properties. Linkages between convection and boreal biomass burning can also impact the upper troposphere and lower stratosphere, radiation and cloud microphysical properties via transport of tropospheric aerosols to the lower stratosphere during extreme convection (Fromm and Servranckx 2003). Relevant questions regarding the impact of biomass aerosols on convective cloud properties include the effects of vertical transport of aerosols, spatial and temporal distribution of rainfall, vertical shift in latent heat release, phase shift of precipitation, circulation and their impacts on radiation. Over land surfaces, a decrease in surface shortwave radiation ({approx} 3-6 W m{sup -2} per decade) has been observed between 1960 to 1990, whereas, increases of 0.4 K in land temperature during the same period that occurred have resulted in speculations that evaporation and precipitation should also have decreased (Wild et al. 2004). However, precipitation records for the same period over land do not indicate any significant trend (Beck et al. 2005). The changes in precipitation are thought to be related to increased moisture advection from the oceans (Wild et al. 2004), which may well have some contributions from aerosol-radiation-convection coupling that could modify circulation patterns and hence moisture advection in specific regions. Other important aspects of aerosol effects, besides the direct, semi-direct, microphysical and thermodynamical impacts include alteration of surface albedos, especially snow and ice covered surfaces, due to absorbing aerosols. These effects are uncertain (Jacobson, 2004) but may produce as much as 0.3 W m{sup -2} forcing in the Northern hemisphere that could contribute to melting of ice and permafrost and change in the length of the season (e.g. early arrival of Spring

  8. Aerosol penetration through transport lines 

    E-Print Network [OSTI]

    Dileep, V.R.

    1996-01-01

    It is very important to minimize the losses in aerosol transport systems for the Continuous Air Monitors (CAM) to have a prompt and a meaningful alarm and the U.S. Environmental Protection Agency (EPA) also Currently mandates continuous emissions...

  9. Overview of the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES)

    SciTech Connect (OSTI)

    Zaveri, Rahul A.; Shaw, William J.; Cziczo, D. J.; Schmid, Beat; Ferrare, R.; Alexander, M. L.; Alexandrov, Mikhail; Alvarez, R. J.; Arnott, W. P.; Atkinson, D.; Baidar, Sunil; Banta, Robert M.; Barnard, James C.; Beranek, Josef; Berg, Larry K.; Brechtel, Fred J.; Brewer, W. A.; Cahill, John F.; Cairns, Brian; Cappa, Christopher D.; Chand, Duli; China, Swarup; Comstock, Jennifer M.; Dubey, Manvendra K.; Easter, Richard C.; Erickson, Matthew H.; Fast, Jerome D.; Floerchinger, Cody; Flowers, B. A.; Fortner, Edward; Gaffney, Jeffrey S.; Gilles, Mary K.; Gorkowski, K.; Gustafson, William I.; Gyawali, Madhu S.; Hair, John; Hardesty, Michael; Harworth, J. W.; Herndon, Scott C.; Hiranuma, Naruki; Hostetler, Chris A.; Hubbe, John M.; Jayne, J. T.; Jeong, H.; Jobson, Bertram T.; Kassianov, Evgueni I.; Kleinman, L. I.; Kluzek, Celine D.; Knighton, B.; Kolesar, K. R.; Kuang, Chongai; Kubatova, A.; Langford, A. O.; Laskin, Alexander; Laulainen, Nels S.; Marchbanks, R. D.; Mazzoleni, Claudio; Mei, F.; Moffet, Ryan C.; Nelson, Danny A.; Obland, Michael; Oetjen, Hilke; Onasch, Timothy B.; Ortega, Ivan; Ottaviani, M.; Pekour, Mikhail S.; Prather, Kimberly A.; Radney, J. G.; Rogers, Ray; Sandberg, S. P.; Sedlacek, Art; Senff, Christoph; Senum, Gunar; Setyan, Ari; Shilling, John E.; Shrivastava, ManishKumar B.; Song, Chen; Springston, S. R.; Subramanian, R.; Suski, Kaitlyn; Tomlinson, Jason M.; Volkamer, Rainer M.; Wallace, Hoyt A.; Wang, J.; Weickmann, A. M.; Worsnop, Douglas R.; Yu, Xiao-Ying; Zelenyuk, Alla; Zhang, Qi

    2012-08-22

    Substantial uncertainties still exist in the scientific understanding of the possible interactions between urban and natural (biogenic) emissions in the production and transformation of atmospheric aerosol and the resulting impact on climate change. The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program's Carbonaceous Aerosol and Radiative Effects Study (CARES) carried out in June 2010 in Central Valley, California, was a comprehensive effort designed to improve this understanding. The primary objective of the field study was to investigate the evolution of secondary organic and black carbon aerosols and their climate-related properties in the Sacramento urban plume as it was routinely transported into the forested Sierra Nevada foothills area. Urban aerosols and trace gases experienced significant physical and chemical transformations as they mixed with the reactive biogenic hydrocarbons emitted from the forest. Two heavily-instrumented ground sites - one within the Sacramento urban area and another about 40 km to the northeast in the foothills area - were set up to characterize the evolution of meteorological variables, trace gases, aerosol precursors, aerosol size, composition, and climate-related properties in freshly polluted and 'aged' urban air. On selected days, the DOE G-1 aircraft was deployed to make similar measurements upwind and across the evolving Sacramento plume in the morning and again in the afternoon. The NASA B-200 aircraft, carrying remote sensing instruments, was also deployed to characterize the vertical and horizontal distribution of aerosols and aerosol optical properties within and around the plume. This overview provides: a) the scientific background and motivation for the study, b) the operational and logistical information pertinent to the execution of the study, c) an overview of key observations and initial results from the aircraft and ground-based sampling platforms, and d) a roadmap of planned data analyses and focused modeling efforts that will facilitate the integration of new knowledge into improved representations of key aerosol processes in climate models.

  10. Building dependability arguments for software intensive systems

    E-Print Network [OSTI]

    Seater, Robert Morrison

    2009-01-01

    A method is introduced for structuring and guiding the development of end-to-end dependability arguments. The goal is to establish high-level requirements of complex software-intensive systems, especially properties that ...

  11. Constraining the atmospheric composition of the day-night terminators of HD 189733b: Atmospheric retrieval with aerosols

    SciTech Connect (OSTI)

    Lee, Jae-Min; Irwin, Patrick G. J.; Fletcher, Leigh N.; Barstow, Joanna K.; Heng, Kevin

    2014-07-01

    A number of observations have shown that Rayleigh scattering by aerosols dominates the transmission spectrum of HD 189733b at wavelengths shortward of 1 ?m. In this study, we retrieve a range of aerosol distributions consistent with transmission spectroscopy between 0.3-24 ?m that were recently re-analyzed by Pont et al. To constrain the particle size and the optical depth of the aerosol layer, we investigate the degeneracies between aerosol composition, temperature, planetary radius, and molecular abundances that prevent unique solutions for transit spectroscopy. Assuming that the aerosol is composed of MgSiO{sub 3}, we suggest that a vertically uniform aerosol layer over all pressures with a monodisperse particle size smaller than about 0.1 ?m and an optical depth in the range 0.002-0.02 at 1 ?m provides statistically meaningful solutions for the day/night terminator regions of HD 189733b. Generally, we find that a uniform aerosol layer provide adequate fits to the data if the optical depth is less than 0.1 and the particle size is smaller than 0.1 ?m, irrespective of the atmospheric temperature, planetary radius, aerosol composition, and gaseous molecules. Strong constraints on the aerosol properties are provided by spectra at wavelengths shortward of 1 ?m as well as longward of 8 ?m, if the aerosol material has absorption features in this region. We show that these are the optimal wavelengths for quantifying the effects of aerosols, which may guide the design of future space observations. The present investigation indicates that the current data offer sufficient information to constrain some of the aerosol properties of HD189733b, but the chemistry in the terminator regions remains uncertain.

  12. Effects of Ocean Ecosystem on Marine Aerosol-Cloud Interaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meskhidze, Nicholas; Nenes, Athanasios

    2010-01-01

    Using satellite data for the surface ocean, aerosol optical depth (AOD), and cloud microphysical parameters, we show that statistically significant positive correlations exist between ocean ecosystem productivity, the abundance of submicron aerosols, and cloud microphysical properties over different parts of the remote oceans. The correlation coefficient for remotely sensed surface chlorophyll a concentration ([Chl- a ]) and liquid cloud effective radii over productive areas of the oceans varies between ? 0.2 and ? 0.6 . Special attention is given to identifying (and addressing) problems from correlation analysis used in the previousmore »studies that can lead to erroneous conclusions. A new approach (using the difference between retrieved AOD and predicted sea salt aerosol optical depth, AOD diff ) is developed to explore causal links between ocean physical and biological systems and the abundance of cloud condensation nuclei (CCN) in the remote marine atmosphere. We have found that over multiple time periods, 550?nm AOD diff (sensitive to accumulation mode aerosol, which is the prime contributor to CCN) correlates well with [Chl- a ] over the productive waters of the Southern Ocean. Since [Chl- a ] can be used as a proxy of ocean biological productivity, our analysis demonstrates the role of ocean ecology in contributing CCN, thus shaping the microphysical properties of low-level marine clouds. « less

  13. Nanomaterials from Aerosols Aerosols are suspensions of liquid or solid particles in a gas. Aerosol particles

    E-Print Network [OSTI]

    Beaucage, Gregory

    changes which are evidenced by changes in the temperature of the oceans and rapid melting of the polar and glacial ice packs. Of pollution sources, aerosols represent the least understood and could potentially

  14. Chemical and Physical Characteristics of Diesel Aerosol | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Physical Characteristics of Diesel Aerosol Chemical and Physical Characteristics of Diesel Aerosol 2002 DEER Conference Presentation: University of Minnesota...

  15. Parameterizations of Cloud Microphysics and Indirect Aerosol Effects

    SciTech Connect (OSTI)

    Tao, Wei-Kuo

    2014-05-19

    1. OVERVIEW Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A recent report published by the National Academy of Science states "The greatest uncertainty about the aerosol climate forcing - indeed, the largest of all the uncertainties about global climate forcing - is probably the indirect effect of aerosols on clouds [NRC, 2001]." The aerosol effect on clouds is often categorized into the traditional "first indirect (i.e., Twomey)" effect on the cloud droplet sizes for a constant liquid water path [Twomey, 1977] and the "semi-direct" effect on cloud coverage [e.g., Ackerman et al., 2000]. Enhanced aerosol concentrations can also suppress warm rain processes by producing a narrow droplet spectrum that inhibits collision and coalescence processes [e.g., Squires and Twomey, 1961; Warner and Twomey, 1967; Warner, 1968; Rosenfeld, 1999]. The aerosol effect on precipitation processes, also known as the second type of aerosol indirect effect [Albrecht, 1989], is even more complex, especially for mixed-phase convective clouds. Table 1 summarizes the key observational studies identifying the microphysical properties, cloud characteristics, thermodynamics and dynamics associated with cloud systems from high-aerosol continental environments. For example, atmospheric aerosol concentrations can influence cloud droplet size distributions, warm-rain process, cold-rain process, cloud-top height, the depth of the mixed phase region, and occurrence of lightning. In addition, high aerosol concentrations in urban environments could affect precipitation variability by providing an enhanced source of cloud condensation nuclei (CCN). Hypotheses have been developed to explain the effect of urban regions on convection and precipitation [van den Heever and Cotton, 2007 and Shepherd, 2005]. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (GCE) model. Atmospheric aerosols are also described using number density size-distribution functions. A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region and summertime convection over a mid-latitude continent with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. The impact of atmospheric aerosol concentration on cloud and precipitation will be investigated. 2. MODEL DESCRIPTION AND CASE STUDIES 2.1 GCE MODEL The model used in this study is the 2D version of the GCE model. Modeled flow is anelastic. Second- or higher-order advection schemes can produce negative values in the solution. Thus, a Multi-dimensional Positive Definite Advection Transport Algorithm (MPDATA) has been implemented into the model. All scalar variables (potential temperature, water vapor, turbulent coefficient and all five hydrometeor classes) use forward time differencing and the MPDATA for advection. Dynamic variables, u, v and w, use a second-order accurate advection scheme and a leapfrog time integration (kinetic energy semi-conserving method). Short-wave (solar) and long-wave radiation as well as a subgrid-scale TKE turbulence scheme are also included in the model. Details of the model can be found in Tao and Simpson (1993) and Tao et al. (2003). 2.2 Microphysics (Bin Model) The formulation of the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (cloud droplets and raindrops), and six types of ice particles: pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail. Each type is described by a special size distribution function containing 33 categories (bin

  16. Assessing regional scale predictions of aerosols, marine stratocumulus, and their interactions during VOCALS-REx using WRF-Chem

    SciTech Connect (OSTI)

    Yang Q.; Lee Y.; Gustafson Jr., W. I.; Fast, J. D.; Wang, H.; Easter, R. C.; Morrison, H.; Chapman, E. G.; Spak, S. N.; Mena-Carrasco, M. A.

    2011-12-02

    This study assesses the ability of the recent chemistry version (v3.3) of the Weather Research and Forecasting (WRF-Chem) model to simulate boundary layer structure, aerosols, stratocumulus clouds, and energy fluxes over the Southeast Pacific Ocean. Measurements from the VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) and satellite retrievals (i.e., products from the MODerate resolution Imaging Spectroradiometer (MODIS), Clouds and Earth's Radiant Energy System (CERES), and GOES-10) are used for this assessment. The Morrison double-moment microphysics scheme is newly coupled with interactive aerosols in the model. The 31-day (15 October-16 November 2008) WRF-Chem simulation with aerosol-cloud interactions (AERO hereafter) is also compared to a simulation (MET hereafter) with fixed cloud droplet number concentrations in the microphysics scheme and simplified cloud and aerosol treatments in the radiation scheme. The well-simulated aerosol quantities (aerosol number, mass composition and optical properties), and the inclusion of full aerosol-cloud couplings lead to significant improvements in many features of the simulated stratocumulus clouds: cloud optical properties and microphysical properties such as cloud top effective radius, cloud water path, and cloud optical thickness. In addition to accounting for the aerosol direct and semi-direct effects, these improvements feed back to the simulation of boundary-layer characteristics and energy budgets. Particularly, inclusion of interactive aerosols in AERO strengthens the temperature and humidity gradients within the capping inversion layer and lowers the marine boundary layer (MBL) depth by 130 m from that of the MET simulation. These differences are associated with weaker entrainment and stronger mean subsidence at the top of the MBL in AERO. Mean top-of-atmosphere outgoing shortwave fluxes, surface latent heat, and surface downwelling longwave fluxes are in better agreement with observations in AERO, compared to the MET simulation. Nevertheless, biases in some of the simulated meteorological quantities (e.g., MBL temperature and humidity) and aerosol quantities (e.g., underestimations of accumulation mode aerosol number) might affect simulated stratocumulus and energy fluxes over the Southeastern Pacific, and require further investigation. The well-simulated timing and outflow patterns of polluted and clean episodes demonstrate the model's ability to capture daily/synoptic scale variations of aerosol and cloud properties, and suggest that the model is suitable for studying atmospheric processes associated with pollution outflow over the ocean. The overall performance of the regional model in simulating mesoscale clouds and boundary layer properties is encouraging and suggests that reproducing gradients of aerosol and cloud droplet concentrations and coupling cloud-aerosol-radiation processes are important when simulating marine stratocumulus over the Southeast Pacific.

  17. Aerosol Lifecycle IOP at BNL A. J. Sedlacek, L. Kleinmen, E. Lewis,Y. -N. Lee,

    E-Print Network [OSTI]

    of `research grade' instruments (MAOS) · Maiden foreign deployment of MAOS will be GVAX, requiring the training to the GVAX Aerosol Lifecycle IOP: Infrastructure Motivation #12;· MAOS will be deployed at Lucknow (India (pollution alerts) can be expected · Good chance of catching an intense but distant biomass burning event

  18. Evolution of organic aerosol mass spectra upon heating: implications for OA phase and partitioning behavior

    SciTech Connect (OSTI)

    UC Davis; Cappa, Christopher D.; Wilson, Kevin R.

    2010-10-28

    Vacuum Ultraviolet (VUV) photoionization mass spectrometry has been used to measure the evolution of chemical composition for two distinct organic aerosol types as they are passed through a thermodenuder at different temperatures. The two organic aerosol types considered are primary lubricating oil (LO) aerosol and secondary aerosol from the alpha-pinene + O3 reaction (alphaP). The evolution of the VUV mass spectra for the two aerosol types with temperature are observed to differ dramatically. For LO particles, the spectra exhibit distinct changes with temperature in which the lower m/z peaks, corresponding to compounds with higher vapor pressures, disappear more rapidly than the high m/z peaks. In contrast, the alphaP aerosol spectrum is essentially unchanged by temperature even though the particles experience significant mass loss due to evaporation. The variations in the LO spectra are found to be quantitatively in agreement with expectations from absorptive partitioning theory whereas the alphaP spectra suggest that the evaporation of alphaP derived aerosol appears to not be governed by partitioning theory. We postulate that this difference arises from the alphaP particles existing as in a glassy state instead of having the expected liquid-like behavior. To reconcile these observations with decades of aerosol growth measurements, which indicate that OA formation is described by equilibrium partitioning, we present a conceptual model wherein the secondary OA is formed and then rapidly converted from an absorbing form to a non-absorbing form. The results suggest that although OA growth may be describable by equilibrium partitioning theory, the properties of organic aerosol once formed may differ significantly from the properties determined in the equilibrium framework.

  19. Smoke over haze: Comparative analysis of satellite, surface radiometer, and airborne in situ measurements of aerosol optical

    E-Print Network [OSTI]

    Zeng, Ning

    measurements of aerosol optical properties and radiative forcing over the eastern United States Brian Vant column closure between narrow and broadband measurements and calculations. Citation: Vant-Hull, B., Z. Li

  20. Toxicity of atmospheric aerosols on marine phytoplankton

    E-Print Network [OSTI]

    2009-01-01

    address: Center for Atmospheric Chemistry Study, Departmenttween phytoplankton, atmospheric chemistry, and climate areno. 12 ? 4601– 4605 CHEMISTRY Atmospheric aerosol deposition

  1. Observations of the first aerosol indirect effect in shallow cumuli

    SciTech Connect (OSTI)

    Berg, Larry K.; Berkowitz, Carl M.; Barnard, James C.; Senum, Gunar; Springston, Stephen R.

    2011-02-08

    Data from the Cumulus Humilis Aerosol Processing Study (CHAPS) are used to estimate the impact of both aerosol indirect effects and cloud dynamics on the microphysical and optical properties of shallow cumuli observed in the vicinity of Oklahoma City, Oklahoma. Not surprisingly, we find that the amount of light scattered by the clouds is dominated by their liquid water content (LWC), which in turn is driven by cloud dynamics. However, removing the effect of cloud dynamics by examining the scattering normalized by LWC shows a strong sensitivity of scattering to pollutant loading. These results suggest that even moderately sized cities, like Oklahoma City, can have a measureable impact on the optical properties of shallow cumuli.

  2. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  3. Real time infrared aerosol analyzer

    DOE Patents [OSTI]

    Johnson, Stanley A. (Countryside, IL); Reedy, Gerald T. (Bourbonnais, IL); Kumar, Romesh (Naperville, IL)

    1990-01-01

    Apparatus for analyzing aerosols in essentially real time includes a virtual impactor which separates coarse particles from fine and ultrafine particles in an aerosol sample. The coarse and ultrafine particles are captured in PTFE filters, and the fine particles impact onto an internal light reflection element. The composition and quantity of the particles on the PTFE filter and on the internal reflection element are measured by alternately passing infrared light through the filter and the internal light reflection element, and analyzing the light through infrared spectrophotometry to identify the particles in the sample.

  4. ARM - AIP1OGREN: AOS Intensive Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive09 I

  5. Stratospheric Albedo Modification by Aerosol Injection

    E-Print Network [OSTI]

    Katz, J I

    2009-01-01

    This paper reviews and develops the proposal, widely discussed but not examined in detail, to use stratospheric aerosols to increase the Earth's albedo to Solar radiation in order to control climate change. The potential of this method has been demonstrated by the "natural experiments" of volcanic injection of sulfate aerosols into the stratosphere that led to subsequent observed global cooling. I consider several hygroscopic oxides as possible aerosol materials in addition to oxides of sulfur. Aerosol chemistry, dispersion and transport have been the subject of little study and are not understood, representing a significant scientific risk. Even the optimal altitude of injection and aerosol size distribution are poorly known. Past attention focused on guns and airplanes as means of lofting aerosols or their chemical precursors, but large sounding rockets are cheap, energetically efficient, can be designed to inject aerosols at any required altitude, and involve little technical risk. Sophisticated, mass-opti...

  6. Stratospheric Aerosol Geoengineering ALAN ROBOCK

    E-Print Network [OSTI]

    Robock, Alan

    hydrologic responses, whitening of the skies, reduction of solar power, and impacts of diffuse radiation Project, conducting climate model experiments with standard stratospheric aerosol in- jection scenarios, which stated that ``It is extremely likely that human in- fluence has been the dominant cause

  7. Building-Level Intensities

    U.S. Energy Information Administration (EIA) Indexed Site

    . Electricity Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Electricity Consumption",,,,,,"Electricity Expenditures" ,"per Building (thousand kWh)","per...

  8. DO AEROSOLS CHANGE CLOUD COVER AND AFFECT CLIMATE?

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    IN MEXICO CITY BASIN Light scattering by aerosols decreases absorption of solar radiation. #12;AEROSOLS;AEROSOL INFLUENCES ON CLIMATE AND CLIMATE CHANGE #12;DMS #12;AEROSOL IN MEXICO CITY BASIN #12;AEROSOL AS SEEN FROM SPACE Fire plumes from southern Mexico transported north into Gulf of Mexico. #12;CLOUD

  9. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06

    of this research is to examine sea salt aerosols and their impact on polluted environments. Sea salt aerosols act as Cloud Condensation Nuclei (CCN) as well as providing a surface for heterogeneous reactions. Such reactions have implications for trace gases...

  10. THE INFLUENCE OF BENZENE AS A TRACE REACTANT IN TITAN AEROSOL ANALOGS

    SciTech Connect (OSTI)

    Trainer, Melissa G.; Sebree, Joshua A.; Heidi Yoon, Y.; Tolbert, Margaret A.

    2013-03-20

    Benzene has been detected in Titan's atmosphere by Cassini instruments, with concentrations ranging from sub-ppb in the stratosphere to ppm in the ionosphere. Sustained levels of benzene in the haze formation region could signify that it is an important reactant in the formation of Titan's organic aerosol. To date, there have not been laboratory investigations to assess the influence of benzene on aerosol properties. We report a laboratory study on the chemical composition of organic aerosol formed from C{sub 6}H{sub 6}/CH{sub 4}/N{sub 2} via far ultraviolet irradiation (120-200 nm). The compositional results are compared to those from aerosol generated by a more ''traditional Titan'' mixture of CH{sub 4}/N{sub 2}. Our results show that even a trace amount of C{sub 6}H{sub 6} (10 ppm) has significant impact on the chemical composition and production rates of organic aerosol. There are several pathways by which photolyzed benzene may react to form larger molecules, both with and without the presence of CH{sub 4}, but many of these reaction mechanisms are only beginning to be explored for the conditions at Titan. Continued work investigating the influence of benzene in aerosol growth will advance understanding of this previously unstudied reaction system.

  11. Aerosol Science and Technology, 43:641652, 2009 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 43:641­652, 2009 Copyright © American Association for Aerosol Differential Mobility Analyzer for Measurement of the Irreversibility of the Hygroscopic Growth Factor T is the irreversibility of the hygroscopic growth fac- tor of aerosol particles. The instrument uses the hysteresis

  12. Researchers Model Impact of Aerosols Over California

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Aerosols Over California Research may clarify the effectiveness of regional pollution controls May 28, 2013 | Tags: Climate Research, Hopper Contact: Linda Vu,...

  13. Aerosol Retrieval Using Remote-sensed Observations

    E-Print Network [OSTI]

    Wang, Yueqing

    2012-01-01

    4.1.2 Baltimore and the DRAGONaround Baltimore . . . . . . . . . . . . . . . . . . . 4.1.4component aerosol 1 for Baltimore-Washington region on June

  14. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    they can have either cooling or warming effects. Lighter-colored organic carbon particles cool regions of the planet by scattering sunlight back into space. Other aerosol particles...

  15. Composition and Reactions of Atmospheric Aerosol Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on high-resolution scanning transmission x-ray images obtained at the ALS have revealed chemical reactions on and in atmospheric aerosol particles that caused particle growth...

  16. Laboratory Studies of Processing of Carbonaceous Aerosols by Atmospheric Oxidants/Hygroscopicity and CCN Activity of Secondary & Processed Primary Organic Aerosols

    SciTech Connect (OSTI)

    Ziemann, P.J.; Arey, J.; Atkinson, R.; Kreidenweis, S.M.; Petters, M.D.

    2012-06-13

    The atmosphere is composed of a complex mixture of gases and suspended microscopic aerosol particles. The ability of these particles to take up water (hygroscopicity) and to act as nuclei for cloud droplet formation significantly impacts aerosol light scattering and absorption, and cloud formation, thereby influencing air quality, visibility, and climate in important ways. A substantial, yet poorly characterized component of the atmospheric aerosol is organic matter. Its major sources are direct emissions from combustion processes, which are referred to as primary organic aerosol (POA), or in situ processes in which volatile organic compounds (VOCs) are oxidized in the atmosphere to low volatility reaction products that subsequent condense to form particles that are referred to as secondary organic aerosol (SOA). POA and VOCs are emitted to the atmosphere from both anthropogenic and natural (biogenic) sources. The overall goal of this experimental research project was to conduct laboratory studies under simulated atmospheric conditions to investigate the effects of the chemical composition of organic aerosol particles on their hygroscopicity and cloud condensation nucleation (CCN) activity, in order to develop quantitative relationships that could be used to more accurately incorporate aerosol-cloud interactions into regional and global atmospheric models. More specifically, the project aimed to determine the products, mechanisms, and rates of chemical reactions involved in the processing of organic aerosol particles by atmospheric oxidants and to investigate the relationships between the chemical composition of organic particles (as represented by molecule sizes and the specific functional groups that are present) and the hygroscopicity and CCN activity of oxidized POA and SOA formed from the oxidation of the major classes of anthropogenic and biogenic VOCs that are emitted to the atmosphere, as well as model hydrocarbons. The general approach for this project was to carry out reactions of representative anthropogenic and biogenic VOCs and organic particles with ozone (O3), and hydroxyl (OH), nitrate (NO3), and chlorine (Cl) radicals, which are the major atmospheric oxidants, under simulated atmospheric conditions in large-volume environmental chambers. A combination of on-line and off-line analytical techniques were used to monitor the chemical and physical properties of the particles including their hygroscopicity and CCN activity. The results of the studies were used to (1) improve scientific understanding of the relationships between the chemical composition of organic particles and their hygroscopicity and CCN activity, (2) develop an improved molecular level theoretical framework for describing these relationships, and (3) establish a large database that is being used to develop parameterizations relating organic aerosol chemical properties and SOA sources to particle hygroscopicity and CCN activity for use in regional and global atmospheric air quality and climate models.

  17. Extending the physicochemical characterization of aerosol particles in California

    E-Print Network [OSTI]

    Zauscher, Melanie Dorothy

    2012-01-01

    Combustion Aerosol, Atmospheric Chemistry and Physics, 11 (Based Receptor Modeling, Atmospheric Chemistry and Physics,Aerosols, Journal of Atmospheric Chemistry, 22 (1-2), 19-39.

  18. Building America Webinar: Sealing of Home Enclosures with Aerosol...

    Energy Savers [EERE]

    Sealing of Home Enclosures with Aerosol Particles Building America Webinar: Sealing of Home Enclosures with Aerosol Particles This webinar was presented by research team Building...

  19. The Indirect and Semi-Direct Aerosol Campaign

    SciTech Connect (OSTI)

    Ghan, Steve

    2014-03-24

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  20. ARM - Field Campaign - Aerosol and Cloud Experiments in the Eastern...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    horizontal variabilities of aerosol, trace gases, cloud, drizzle, and atmospheric thermodynamics are critically needed for understanding and quantifying the budget of MBL aerosol,...

  1. The Indirect and Semi-Direct Aerosol Campaign

    ScienceCinema (OSTI)

    Ghan, Steve

    2014-06-12

    Research projects like the Indirect and Semi-Direct Aerosol Campaign, or ISDAC, increase our knowledge of atmospheric aerosol particles and cloud physics.

  2. Carbonaceous Aerosol Study Using Advanced Particle Instrumentation

    E-Print Network [OSTI]

    Qi, Li

    2010-01-01

    6 6.1 Introduction Biomass combustion emissions contributeEmissions of trace gases and aerosols during the open combustion of biomassbiomass burning work explored the evolution of organic aerosol emissions as a function of modified combustion efficiency with correlations drawn between levoglucosan emissions

  3. Atmospheric aerosol light scattering and polarization peculiarities

    E-Print Network [OSTI]

    Patlashenko, Zh I

    2015-01-01

    This paper considers environmental problems of natural and anthropogenic atmospheric aerosol pollution and its global and regional monitoring. Efficient aerosol investigations may be achieved by spectropolarimetric measurements. Specifically second and fourth Stokes parameters spectral dependencies carry information on averaged refraction and absorption indexes and on particles size distribution functions characteristics.

  4. Large-Scale Spray Releases: Additional Aerosol Test Results

    SciTech Connect (OSTI)

    Daniel, Richard C.; Gauglitz, Phillip A.; Burns, Carolyn A.; Fountain, Matthew S.; Shimskey, Rick W.; Billing, Justin M.; Bontha, Jagannadha R.; Kurath, Dean E.; Jenks, Jeromy WJ; MacFarlan, Paul J.; Mahoney, Lenna A.

    2013-08-01

    One of the events postulated in the hazard analysis for the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak event involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids that behave as a Newtonian fluid. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and in processing facilities across the DOE complex. To expand the data set upon which the WTP accident and safety analyses were based, an aerosol spray leak testing program was conducted by Pacific Northwest National Laboratory (PNNL). PNNL’s test program addressed two key technical areas to improve the WTP methodology (Larson and Allen 2010). The first technical area was to quantify the role of slurry particles in small breaches where slurry particles may plug the hole and prevent high-pressure sprays. The results from an effort to address this first technical area can be found in Mahoney et al. (2012a). The second technical area was to determine aerosol droplet size distribution and total droplet volume from prototypic breaches and fluids, including sprays from larger breaches and sprays of slurries for which literature data are mostly absent. To address the second technical area, the testing program collected aerosol generation data at two scales, commonly referred to as small-scale and large-scale testing. The small-scale testing and resultant data are described in Mahoney et al. (2012b), and the large-scale testing and resultant data are presented in Schonewill et al. (2012). In tests at both scales, simulants were used to mimic the relevant physical properties projected for actual WTP process streams.

  5. Small-Scale Spray Releases: Additional Aerosol Test Results

    SciTech Connect (OSTI)

    Schonewill, Philip P.; Gauglitz, Phillip A.; Kimura, Marcia L.; Brown, G. N.; Mahoney, Lenna A.; Tran, Diana N.; Burns, Carolyn A.; Kurath, Dean E.

    2013-08-01

    One of the events postulated in the hazard analysis at the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids with Newtonian fluid behavior. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and across processing facilities in the DOE complex. To expand the data set upon which the WTP accident and safety analyses were based, an aerosol spray leak testing program was conducted by Pacific Northwest National Laboratory (PNNL). PNNL’s test program addressed two key technical areas to improve the WTP methodology (Larson and Allen 2010). The first technical area was to quantify the role of slurry particles in small breaches where slurry particles may plug the hole and prevent high-pressure sprays. The results from an effort to address this first technical area can be found in Mahoney et al. (2012a). The second technical area was to determine aerosol droplet size distribution and total droplet volume from prototypic breaches and fluids, including sprays from larger breaches and sprays of slurries for which literature data are largely absent. To address the second technical area, the testing program collected aerosol generation data at two scales, commonly referred to as small-scale and large-scale. The small-scale testing and resultant data are described in Mahoney et al. (2012b) and the large-scale testing and resultant data are presented in Schonewill et al. (2012). In tests at both scales, simulants were used to mimic the relevant physical properties projected for actual WTP process streams.

  6. AEROSOL PARTICLE COLLECTOR DESIGN STUDY

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R

    2007-09-27

    A computational evaluation of a particle collector design was performed to evaluate the behavior of aerosol particles in a fast flowing gas stream. The objective of the work was to improve the collection efficiency of the device while maintaining a minimum specified air throughput, nominal collector size, and minimal power requirements. The impact of a range of parameters was considered subject to constraints on gas flow rate, overall collector dimensions, and power limitations. Potential improvements were identified, some of which have already been implemented. Other more complex changes were identified and are described here for further consideration. In addition, fruitful areas for further study are proposed.

  7. ARM Cloud Aerosol Precipitation Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation Data Management Facility PlotsProducts (VAP) VAP38 ARM6Aerosol

  8. Energy Intensity Strategy 

    E-Print Network [OSTI]

    Rappolee, D.; Shaw, J.

    2008-01-01

    Our presentation will cover how we began the journey of conserving energy at our facility. We’ll discuss a basic layout of our energy intensity plan and the impact our team has had on the process, what tools we’re using, what goals have been...

  9. AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS

    E-Print Network [OSTI]

    Graaf, Martin de

    AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS M. de Graaf, L.G. Tilstra information has become available from active space-based sensors and some dedicated field campaigns on aerosol-absorption, is the Absorbing Aerosol Index (AAI), which can indicate absorbing aerosols overlying clouds. The AAI is available

  10. Practical application of in situ aerosol measurement

    SciTech Connect (OSTI)

    O`Hern, T.J.; Rader, D.J.

    1993-09-01

    The use of in situ, real-time measurement techniques permits the characterization of airborne droplets and particles under conditions where traditional sampling methods can fail. For example, sampling method rely on the ability to sample and transport particles without biasing the properties of interest, and often are not applicable in harsh environment. Although in situ methods offer unique opportunities in these cases, these techniques introduce new concerns and must be used carefully if accurate measurement are to be made. Several in situ measurement techniques are reviewed here. As the field is rapidly evolving, the discussion is limited to those techniques which: (1) are commercially available, (2) provide real-time output, (3) measure the aerosol size distribution. Discussion is divided between single particle counters (which provide a flux-based or temporal measurement) and ensemble techniques (which provide a concentration-based or spatial measurement). Specific techniques discussed include phase Doppler, Mie scattering, and Fraunhofer diffraction, and commercial instruments based on these techniques.

  11. HI intensity mapping with FAST

    E-Print Network [OSTI]

    Bigot-Sazy, Marie-Anne; Battye, Richard A; Browne, Ian W A; Chen, Tianyue; Dickinson, Clive; Harper, Stuart; Maffei, Bruno; Olivari, Lucas C; Wilkinson, Peter N

    2015-01-01

    We discuss the detectability of large-scale HI intensity fluctuations using the FAST telescope. We present forecasts for the accuracy of measuring the Baryonic Acoustic Oscillations and constraining the properties of dark energy. The FAST $19$-beam L-band receivers ($1.05$--$1.45$ GHz) can provide constraints on the matter power spectrum and dark energy equation of state parameters ($w_{0},w_{a}$) that are comparable to the BINGO and CHIME experiments. For one year of integration time we find that the optimal survey area is $6000\\,{\\rm deg}^2$. However, observing with larger frequency coverage at higher redshift ($0.95$--$1.35$ GHz) improves the projected errorbars on the HI power spectrum by more than $2~\\sigma$ confidence level. The combined constraints from FAST, CHIME, BINGO and Planck CMB observations can provide reliable, stringent constraints on the dark energy equation of state.

  12. Clouds, aerosol, and precipitation in the Marine Boundary Layer: An ARM mobile facility deployment

    SciTech Connect (OSTI)

    Wood, Robert; Luke, Ed; Wyant, Matthew; Bretherton, Christopher S.; Remillard, Jasmine; Kollias, Pavlos; Fletcher, Jennifer; Stemmler, Jayson; deSzoeke, S.; Yuter, Sandra; Miller, Matthew; Mechem, David; Tselioudis, George; Chiu, Christine; Mann, Julia; O Connor, Ewan; Hogan, Robin; Dong, Xiquan; Miller, Mark; Ghate, Virendra; Jefferson, Anne; Min, Qilong; Minnis, Patrick; Palinkonda, Rabindra; Albrecht, Bruce; Hannay, Cecile; Lin, Yanluan

    2014-04-27

    The Clouds, Aerosol, and Precipitation in the Marine Boundary Layer (CAP-MBL) deployment at Graciosa Island in the Azores generated a 21-month (April 2009-December 2010) comprehensive dataset documenting clouds, aerosols, and precipitation using the Atmospheric Radiation Measurement Program (ARM) Mobile Facility (AMF). The scientific aim of the deployment is to gain improved understanding of the interactions of clouds, aerosols, and precipitation in the marine boundary layer. Graciosa Island straddles the boundary between the subtropics and midlatitudes in the Northeast Atlantic Ocean and consequently experiences a great diversity of meteorological and cloudiness conditions. Low clouds are the dominant cloud type, with stratocumulus and cumulus occurring regularly. Approximately half of all clouds contained precipitation detectable as radar echoes below the cloud base. Radar and satellite observations show that clouds with tops from 1-11 km contribute more or less equally to surface-measured precipitation at Graciosa. A wide range of aerosol conditions was sampled during the deployment consistent with the diversity of sources as indicated by back-trajectory analysis. Preliminary findings suggest important two-way interactions between aerosols and clouds at Graciosa, with aerosols affecting light precipitation and cloud radiative properties while being controlled in part by precipitation scavenging.The data from Graciosa are being compared with short-range forecasts made with a variety of models. A pilot analysis with two climate and two weather forecast models shows that they reproduce the observed time-varying vertical structure of lower-tropospheric cloud fairly well but the cloud-nucleating aerosol concentrations less well. The Graciosa site has been chosen to be a permanent fixed ARM site that became operational in October 2013.

  13. Clouds, aerosol, and precipitation in the Marine Boundary Layer: An ARM mobile facility deployment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wood, Robert; Luke, Ed; Wyant, Matthew; Bretherton, Christopher S.; Remillard, Jasmine; Kollias, Pavlos; Fletcher, Jennifer; Stemmler, Jayson; deSzoeke, S.; Yuter, Sandra; et al

    2014-04-27

    The Clouds, Aerosol, and Precipitation in the Marine Boundary Layer (CAP-MBL) deployment at Graciosa Island in the Azores generated a 21-month (April 2009-December 2010) comprehensive dataset documenting clouds, aerosols, and precipitation using the Atmospheric Radiation Measurement Program (ARM) Mobile Facility (AMF). The scientific aim of the deployment is to gain improved understanding of the interactions of clouds, aerosols, and precipitation in the marine boundary layer. Graciosa Island straddles the boundary between the subtropics and midlatitudes in the Northeast Atlantic Ocean and consequently experiences a great diversity of meteorological and cloudiness conditions. Low clouds are the dominant cloud type, with stratocumulusmore »and cumulus occurring regularly. Approximately half of all clouds contained precipitation detectable as radar echoes below the cloud base. Radar and satellite observations show that clouds with tops from 1-11 km contribute more or less equally to surface-measured precipitation at Graciosa. A wide range of aerosol conditions was sampled during the deployment consistent with the diversity of sources as indicated by back-trajectory analysis. Preliminary findings suggest important two-way interactions between aerosols and clouds at Graciosa, with aerosols affecting light precipitation and cloud radiative properties while being controlled in part by precipitation scavenging.The data from Graciosa are being compared with short-range forecasts made with a variety of models. A pilot analysis with two climate and two weather forecast models shows that they reproduce the observed time-varying vertical structure of lower-tropospheric cloud fairly well but the cloud-nucleating aerosol concentrations less well. The Graciosa site has been chosen to be a permanent fixed ARM site that became operational in October 2013.« less

  14. Evaluating WRF-Chem aerosol indirect effects in Southeast Pacific marine stratocumulus during VOCALS-REx

    SciTech Connect (OSTI)

    Saide P. E.; Springston S.; Spak, S. N.; Carmichael, G. R.; Mena-Carrasco, M. A.; Yang, Q.; Howell, S.; Leon, D. C.; Snider, J. R.; Bandy, A. R.; Collett, J. L.; Benedict, K. B.; de Szoeke, S. P.; Hawkins, L. N.; Allen, G.; Crawford, I.; Crosier, J.

    2012-03-29

    We evaluate a regional-scale simulation with the WRF-Chem model for the VAMOS (Variability of the American Monsoon Systems) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx), which sampled the Southeast Pacific's persistent stratocumulus deck. Evaluation of VOCALS-REx ship-based and three aircraft observations focuses on analyzing how aerosol loading affects marine boundary layer (MBL) dynamics and cloud microphysics. We compare local time series and campaign-averaged longitudinal gradients, and highlight differences in model simulations with (W) and without (NW) wet deposition processes. The higher aerosol loadings in the NW case produce considerable changes in MBL dynamics and cloud microphysics, in accordance with the established conceptual model of aerosol indirect effects. These include increase in cloud albedo, increase in MBL and cloud heights, drizzle suppression, increase in liquid water content, and increase in cloud lifetime. Moreover, better statistical representation of aerosol mass and number concentration improves model fidelity in reproducing observed spatial and temporal variability in cloud properties, including top and base height, droplet concentration, water content, rain rate, optical depth (COD) and liquid water path (LWP). Together, these help to quantify confidence in WRF-Chem's modeled aerosol-cloud interactions, especially in the activation parameterization, while identifying structural and parametric uncertainties including: irreversibility in rain wet removal; overestimation of marine DMS and sea salt emissions, and accelerated aqueous sulfate conversion. Our findings suggest that WRF-Chem simulates marine cloud-aerosol interactions at a level sufficient for applications in forecasting weather and air quality and studying aerosol climate forcing, and may do so with the reliability required for policy analysis.

  15. Evaluating WRF-Chem aerosol indirect effects in Southeast Pacific marine stratocumulus during VOCALS-REx

    SciTech Connect (OSTI)

    Saide, Pablo; Spak, S. N.; Carmichael, Gregory; Mena-Carrasco, M. A.; Yang, Qing; Howell, S. G.; Leon, Dolislager; Snider, Jefferson R.; Bandy, Alan R.; Collett, Jeffrey L.; Benedict, K. B.; de Szoeke, S.; Hawkins, Lisa; Allen, Grant; Crawford, I.; Crosier, J.; Springston, S. R.

    2012-03-30

    We evaluate a regional-scale simulation with the WRF-Chem model for the VAMOS (Variability of the American Monsoon Systems) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx), which sampled the Southeast Pacific's persistent stratocumulus deck. Evaluation of VOCALS-REx ship-based and aircraft observations focuses on analyzing how aerosol loading affects marine boundary layer (MBL) dynamics and cloud microphysics. We compare local time series and campaign averaged longitudinal gradients, and highlight differences in model simulations with (W) and without wet (NW) deposition processes. The higher aerosol loadings in the NW case produce considerable changes in MBL dynamics and cloud microphysics, in accordance with the established conceptual model of aerosol indirect effects. These include increase in cloud albedo, increase in MBL and cloud heights, drizzle suppression, increase in liquid water content, and increase in cloud lifetime. Moreover, better statistical representation of aerosol mass and number concentration improves model fidelity in reproducing observed spatial and temporal variability in cloud properties, including top and base height, droplet concentration, water content, rain rate, optical depth (COD) and liquid water path (LWP). Together, these help to quantify confidence in WRF-Chem's modeled aerosol-cloud interactions, while identifying structural and parametric uncertainties including: irreversibility in rain wet removal; overestimation of marine DMS and sea salt emissions and accelerated aqueous sulfate conversion. Our findings suggest that WRF-Chem simulates marine cloud-aerosol interactions at a level sufficient for applications in forecasting weather and air quality and studying aerosol climate forcing, including the reliability required for policy analysis and geo-engineering applications.

  16. Large-Scale Spray Releases: Initial Aerosol Test Results

    SciTech Connect (OSTI)

    Schonewill, Philip P.; Gauglitz, Phillip A.; Bontha, Jagannadha R.; Daniel, Richard C.; Kurath, Dean E.; Adkins, Harold E.; Billing, Justin M.; Burns, Carolyn A.; Davis, James M.; Enderlin, Carl W.; Fischer, Christopher M.; Jenks, Jeromy WJ; Lukins, Craig D.; MacFarlan, Paul J.; Shutthanandan, Janani I.; Smith, Dennese M.

    2012-12-01

    One of the events postulated in the hazard analysis at the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids with Newtonian fluid behavior. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and across processing facilities in the DOE complex. Two key technical areas were identified where testing results were needed to improve the technical basis by reducing the uncertainty due to extrapolating existing literature results. The first technical need was to quantify the role of slurry particles in small breaches where the slurry particles may plug and result in substantially reduced, or even negligible, respirable fraction formed by high-pressure sprays. The second technical need was to determine the aerosol droplet size distribution and volume from prototypic breaches and fluids, specifically including sprays from larger breaches with slurries where data from the literature are scarce. To address these technical areas, small- and large-scale test stands were constructed and operated with simulants to determine aerosol release fractions and generation rates from a range of breach sizes and geometries. The properties of the simulants represented the range of properties expected in the WTP process streams and included water, sodium salt solutions, slurries containing boehmite or gibbsite, and a hazardous chemical simulant. The effect of anti-foam agents was assessed with most of the simulants. Orifices included round holes and rectangular slots. The round holes ranged in size from 0.2 to 4.46 mm. The slots ranged from (width × length) 0.3 × 5 to 2.74 × 76.2 mm. Most slots were oriented longitudinally along the pipe, but some were oriented circumferentially. In addition, a limited number of multi-hole test pieces were tested in an attempt to assess the impact of a more complex breach. Much of the testing was conducted at pressures of 200 and 380 psi, but some tests were conducted at 100 psi. Testing the largest postulated breaches was deemed impractical because of the large size of some of the WTP equipment. The purpose of this report is to present the experimental results and analyses for the aerosol measurements obtained in the large-scale test stand. The report includes a description of the simulants used and their properties, equipment and operations, data analysis methodology, and test results. The results of tests investigating the role of slurry particles in plugging of small breaches are reported in Mahoney et al. 2012a. The results of the aerosol measurements in the small-scale test stand are reported in Mahoney et al. (2012b).

  17. Small-Scale Spray Releases: Initial Aerosol Test Results

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Gauglitz, Phillip A.; Kimura, Marcia L.; Brown, Garrett N.; Kurath, Dean E.; Buchmiller, William C.; Smith, Dennese M.; Blanchard, Jeremy; Song, Chen; Daniel, Richard C.; Wells, Beric E.; Tran, Diana N.; Burns, Carolyn A.

    2013-05-29

    One of the events postulated in the hazard analysis at the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids with Newtonian fluid behavior. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and across processing facilities in the DOE complex. Two key technical areas were identified where testing results were needed to improve the technical basis by reducing the uncertainty due to extrapolating existing literature results. The first technical need was to quantify the role of slurry particles in small breaches where the slurry particles may plug and result in substantially reduced, or even negligible, respirable fraction formed by high-pressure sprays. The second technical need was to determine the aerosol droplet size distribution and volume from prototypic breaches and fluids, specifically including sprays from larger breaches with slurries where data from the literature are scarce. To address these technical areas, small- and large-scale test stands were constructed and operated with simulants to determine aerosol release fractions and net generation rates from a range of breach sizes and geometries. The properties of the simulants represented the range of properties expected in the WTP process streams and included water, sodium salt solutions, slurries containing boehmite or gibbsite, and a hazardous chemical simulant. The effect of antifoam agents was assessed with most of the simulants. Orifices included round holes and rectangular slots. For the combination of both test stands, the round holes ranged in size from 0.2 to 4.46 mm. The slots ranged from (width × length) 0.3 × 5 to 2.74 × 76.2 mm. Most slots were oriented longitudinally along the pipe, but some were oriented circumferentially. In addition, a limited number of multi-hole test pieces were tested in an attempt to assess the impact of a more complex breach. Much of the testing was conducted at pressures of 200 and 380 psi, but some tests were conducted at 100 psi. Testing the largest postulated breaches was deemed impractical because of the much larger flow rates and equipment that would be required. This report presents the experimental results and analyses for the aerosol measurements obtained in the small-scale test stand. It includes a description of the simulants used and their properties, equipment and operations, data analysis methodologies, and test results. The results of tests investigating the role of slurry particles in plugging small breaches are reported in Mahoney et al. (2012). The results of the aerosol measurements in the large-scale test stand are reported in Schonewill et al. (2012) along with an analysis of the combined results from both test scales.

  18. Small-Scale Spray Releases: Initial Aerosol Test Results

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Gauglitz, Phillip A.; Kimura, Marcia L.; Brown, Garrett N.; Kurath, Dean E.; Buchmiller, William C.; Smith, Dennese M.; Blanchard, Jeremy; Song, Chen; Daniel, Richard C.; Wells, Beric E.; Tran, Diana N.; Burns, Carolyn A.

    2012-11-01

    One of the events postulated in the hazard analysis at the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids with Newtonian fluid behavior. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and across processing facilities in the DOE complex. Two key technical areas were identified where testing results were needed to improve the technical basis by reducing the uncertainty due to extrapolating existing literature results. The first technical need was to quantify the role of slurry particles in small breaches where the slurry particles may plug and result in substantially reduced, or even negligible, respirable fraction formed by high-pressure sprays. The second technical need was to determine the aerosol droplet size distribution and volume from prototypic breaches and fluids, specifically including sprays from larger breaches with slurries where data from the literature are scarce. To address these technical areas, small- and large-scale test stands were constructed and operated with simulants to determine aerosol release fractions and generation rates from a range of breach sizes and geometries. The properties of the simulants represented the range of properties expected in the WTP process streams and included water, sodium salt solutions, slurries containing boehmite or gibbsite, and a hazardous chemical simulant. The effect of anti-foam agents was assessed with most of the simulants. Orifices included round holes and rectangular slots. The round holes ranged in size from 0.2 to 4.46 mm. The slots ranged from (width × length) 0.3 × 5 to 2.74 × 76.2 mm. Most slots were oriented longitudinally along the pipe, but some were oriented circumferentially. In addition, a limited number of multi-hole test pieces were tested in an attempt to assess the impact of a more complex breach. Much of the testing was conducted at pressures of 200 and 380 psi, but some tests were conducted at 100 psi. Testing the largest postulated breaches was deemed impractical because of the large size of some of the WTP equipment. This report presents the experimental results and analyses for the aerosol measurements obtained in the small-scale test stand. It includes a description of the simulants used and their properties, equipment and operations, data analysis methodologies, and test results. The results of tests investigating the role of slurry particles in plugging small breaches are reported in Mahoney et al. (2012). The results of the aerosol measurements in the large-scale test stand are reported in Schonewill et al. (2012) along with an analysis of the combined results from both test scales.

  19. Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME, SCIAMACHY, and GOME-2

    E-Print Network [OSTI]

    Tilstra, Gijsbert

    Studying trends in biomass burning aerosol using the Absorbing Aerosol Index derived from GOME the resulting time series, we use tropospheric NO2 data as a reference in the regions dominated by biomass sensitive to desert dust aerosols (DDA) and biomass burning aerosols (BBA). See Figure 1. The AAI

  20. Aerosol characterization study using multi-spectrum remote sensing measurement techniques.

    SciTech Connect (OSTI)

    Glen, Crystal Chanea; Sanchez, Andres L.; Lucero, Gabriel Anthony; Schmitt, Randal L.; Johnson, Mark S.; Tezak, Matthew Stephen; Servantes, Brandon Lee

    2013-09-01

    A unique aerosol flow chamber coupled with a bistatic LIDAR system was implemented to measure the optical scattering cross sections and depolarization ratio of common atmospheric particulates. Each of seven particle types (ammonium sulfate, ammonium nitrate, sodium chloride, potassium chloride, black carbon and Arizona road dust) was aged by three anthropogenically relevant mechanisms: 1. Sulfuric acid deposition, 2. Toluene ozonolysis reactions, and 3. m-Xylene ozonolysis reactions. The results of pure particle scattering properties were compared with their aged equivalents. Results show that as most particles age under industrial plume conditions, their scattering cross sections are similar to pure black carbon, which has significant impacts to our understanding of aerosol impacts on climate. In addition, evidence emerges that suggest chloride-containing aerosols are chemically altered during the organic aging process. Here we present the direct measured scattering cross section and depolarization ratios for pure and aged atmospheric particulates.

  1. Typical atmospheric aerosol behavior at the Cherenkov Telescope Array candidate sites in Argentina

    E-Print Network [OSTI]

    Piacentini, Rubén D; Micheletti, María I; Salum, Graciela M; Maya, Javier; Mancilla, Alexis; García, Beatriz

    2013-01-01

    Aerosols from natural and antropogenic sources are one of the atmospheric components that have the largest spacial-temporal variability, depending on the type (land or ocean) surface, human activity and climatic conditions (mainly temperature and wind). Since Cherenkov photons generated by the incidence of a primary ultraenergetic cosmic gamma photon have a spectral intensity distribution concentrated in the UV and visible ranges [Hillas AM. Space Science Reviews, 75, 17-30, 1996], it is important to know the aerosol concentration and its contribution to atmospheric radiative transfer. We present results of this concentration measured in typical rather calm (not windy) days at San Antonio de los Cobres (SAC) and El Leoncito/CASLEO proposed Argentinean Andes range sites for the placement of the Cherenkov Telescope Array (CTA). In both places, the aerosol concentration has a peak in the 2.5-5.0$\\mu$m range of the mean aerosol diameter and a very low mean total concentration of 0.097$\\mu$g/m$^3$ (0.365$\\mu$g/m$^...

  2. Technology Solutions Case Study: Apartment Compartmentalization with an Aerosol-Based Sealing Process

    SciTech Connect (OSTI)

    2015-07-01

    Air sealing of building enclosures is a difficult and time-consuming process. Current methods in new construction require laborers to physically locate small and sometimes large holes in multiple assemblies and then manually seal each of them. This research study by Building America team Consortium for Advanced Residential Buildings demonstrated the automated air sealing and compartmentalization of buildings through the use of an aerosolized sealant developed by the Western Cooling Efficiency Center at University of California Davis. CARB demonstrated this new technology application in a multifamily building in Queens, NY. The effectiveness of the sealing process was evaluated by three methods: air leakage testing of overall apartment before and after sealing, point-source testing of individual leaks, and pressure measurements in the walls of the target apartment during sealing. Aerosolized sealing was successful by several measures in this study. Many individual leaks that are labor-intensive to address separately were well sealed by the aerosol particles. In addition, many diffuse leaks that are difficult to identify and treat were also sealed. The aerosol-based sealing process resulted in an average reduction of 71% in air leakage across three apartments and an average apartment airtightness of 0.08 CFM50/SF of enclosure area.

  3. Aerosol Condensational Growth in Cloud Formation 

    E-Print Network [OSTI]

    Geng, Jun

    2010-10-12

    A code for the quasi-stationary solution of the coupled heat and mass transport equations for aerosols in a finite volume was developed. Both mass and heat are conserved effectively in the volume, which results in a ...

  4. Aerosol remote sensing in polar regions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Wehrli, Christoph; et al

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ĺngström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i)more »a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ĺlesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.« less

  5. Aerosol remote sensing in polar regions

    SciTech Connect (OSTI)

    Tomasi, Claudio; Kokhanovsky, Alexander A.; Lupi, Angelo; Ritter, Christoph; Smirnov, Alexander; O'Neill, Norman T.; Stone, Robert S.; Holben, Brent N.; Nyeki, Stephan; Mazzola, Mauro; Lanconelli, Christian; Vitale, Vito; Stebel, Kerstin; Aaltonen, Veijo; de Leeuw, Gerrit; Rodriguez, Edith; Herber, Andreas B.; Radionov, Vladimir F.; Zielinski, Tymon; Petelski, Tomasz; Sakerin, Sergey M.; Kabanov, Dmitry M.; Xue, Yong; Mei, Linlu; Istomina, Larysa; Wagener, Richard; McArthur, Bruce; Sobolewski, Piotr S.; Kivi, Rigel; Courcoux, Yann; Larouche, Pierre; Broccardo, Stephen; Piketh, Stuart J.

    2015-01-01

    Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness ?(?) at visible and near-infrared wavelengths, from which best-fit values of Ĺngström's exponent ? were calculated. Analysing these data, the monthly mean values of ?(0.50 ?m) and ? and the relative frequency histograms of the daily mean values of both parameters were determined for winter–spring and summer–autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of ? versus ?(0.50 ?m) showed: (i) a considerable increase in ?(0.50 ?m) for the Arctic aerosol from summer to winter–spring, without marked changes in ?; and (ii) a marked increase in ?(0.50 ?m) passing from the Antarctic Plateau to coastal sites, whereas ? decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of ?(?) and ? at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterise vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ĺlesund. Satellite-based MODIS, MISR, and AATSR retrievals of ?(?) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface–atmosphere system over polar regions.

  6. Aerosol fabrication methods for monodisperse nanoparticles

    DOE Patents [OSTI]

    Jiang, Xingmao; Brinker, C Jeffrey

    2014-10-21

    Exemplary embodiments provide materials and methods for forming monodisperse particles. In one embodiment, the monodisperse particles can be formed by first spraying a nanoparticle-containing dispersion into aerosol droplets and then heating the aerosol droplets in the presence of a shell precursor to form core-shell particles. By removing either the shell layer or the nanoparticle core of the core-shell particles, monodisperse nanoparticles can be formed.

  7. Electrically Driven Technologies for Radioactive Aerosol Abatement

    SciTech Connect (OSTI)

    David W. DePaoli; Ofodike A. Ezekoye; Costas Tsouris; Valmor F. de Almeida

    2003-01-28

    The purpose of this research project was to develop an improved understanding of how electriexecy driven processes, including electrocoalescence, acoustic agglomeration, and electric filtration, may be employed to efficiently treat problems caused by the formation of aerosols during DOE waste treatment operations. The production of aerosols during treatment and retrieval operations in radioactive waste tanks and during thermal treatment operations such as calcination presents a significant problem of cost, worker exposure, potential for release, and increased waste volume.

  8. Development of plutonium aerosol fractionation system 

    E-Print Network [OSTI]

    Mekala, Malla R.

    1993-01-01

    DEVELOPMENT OF A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1993 Major Subject: Mechanical Engineering DEVELOPMENT OP A PLUTONIUM AEROSOL FRACTIONATION SYSTEM A Thesis by MALLA R. MEKALA Approved as to style and content by: A. R. McFarland (Chair of Committee) N. K. Anand (Mer toer) (', & C. B...

  9. WRF-Chem Simulations of Aerosols and Anthropogenic Aerosol Radiative Forcing in East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhao, Chun; Liu, Xiaohong; Zhang, Meigen; Leung, Lai-Yung R.

    2014-08-01

    This study aims to provide a first comprehensive evaluation of WRF-Chem for modeling aerosols and anthropogenic aerosol radiative forcing (RF) over East Asia. Several numerical experiments were conducted from November 2007 to December 2008. Comparison between model results and observations shows that the model can generally reproduce the observed spatial distributions of aerosol concentration, aerosol optical depth (AOD) and single scattering albedo (SSA) from measurements at different sites, including the relatively higher aerosol concentration and AOD over East China and the relatively lower AOD over Southeast Asia, Korean, and Japan. The model also depicts the seasonal variation and transport of pollutions over East Asia. Particulate matter of 10 um or less in the aerodynamic diameter (PM10), black carbon (BC), sulfate (SO42-), nitrate (NO3-) and ammonium (NH4+) concentrations are higher in spring than other seasons in Japan due to the pollutant transport from polluted area of East Asia. AOD is high over Southwest and Central China in winter, spring and autumn and over North China in summer while is low over South China in summer due to monsoon precipitation. SSA is lowest in winter and highest in summer. The model also captures the dust events at the Zhangye site in the semi-arid region of China. Anthropogenic aerosol RF is estimated to range from -5 to -20 W m-2 over land and -20 to -40 W m-2 over ocean at the top of atmosphere (TOA), 5 to 30 W m-2 in the atmosphere (ATM) and -15 to -40 W m-2 at the bottom (BOT). The warming effect of anthropogenic aerosol in ATM results from BC aerosol while the negative aerosol RF at TOA is caused by scattering aerosols such as SO4 2-, NO3 - and NH4+. Positive BC RF at TOA compensates 40~50% of the TOA cooling associated with anthropogenic aerosol.

  10. Aerosol-cloud radiative effects from passive satellite instruments Mar%n de Graaf

    E-Print Network [OSTI]

    Graaf, Martin de

    Satellite measurements of absorbing aerosols Reflectance Difference Method Cloud modelling Results Outlook Aerosol-Radiation Interac. Aerosol-Cloud Interac. Total anthropogenic Solar irradiance #12;Absorbing aerosols: SCIAMACHY Results Outlook #12;SCIAMACHY on ESA's Environmetal Satellite: ENVISAT Polar orbi

  11. French intensive truck garden

    SciTech Connect (OSTI)

    Edwards, T D

    1983-01-01

    The French Intensive approach to truck gardening has the potential to provide substantially higher yields and lower per acre costs than do conventional farming techniques. It was the intent of this grant to show that there is the potential to accomplish the gains that the French Intensive method has to offer. It is obvious that locally grown food can greatly reduce transportation energy costs but when there is the consideration of higher efficiencies there will also be energy cost reductions due to lower fertilizer and pesticide useage. As with any farming technique, there is a substantial time interval for complete soil recovery after there have been made substantial soil modifications. There were major crop improvements even though there was such a short time since the soil had been greatly disturbed. It was also the intent of this grant to accomplish two other major objectives: first, the garden was managed under organic techniques which meant that there were no chemical fertilizers or synthetic pesticides to be used. Second, the garden was constructed so that a handicapped person in a wheelchair could manage and have a higher degree of self sufficiency with the garden. As an overall result, I would say that the garden has taken the first step of success and each year should become better.

  12. Aerosol Science and Technology, 45:244261, 2011 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    Aerosol Science and Technology, 45:244­261, 2011 Copyright © American Association for Aerosol University, Cambridge, Massachusetts, USA The hygroscopic phase transitions and growth factors of mixed chemical composition on phase transitions. The hygroscopic growth factors of the mixed particles were

  13. Aerosol Science and Technology, 38:12061222, 2004 Copyright c American Association for Aerosol Research

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    to Combustion-Generated Soot Aerosols as a Function of Fuel Equivalence Ratio Jay G. Slowik,1 K. Stainken,1 Paul factor, size, and fractal dimension of soot aerosol particles generated in a propane/O2 flame were on the fuel equivalence ratio. Type 1: for propane/O2), dva was nearly constant and independent

  14. High intensity femtosecond enhancement cavities

    E-Print Network [OSTI]

    Abram, Gilberto

    2009-01-01

    To produce extreme ultraviolet radiation via high harmonic generation (HHG) in rare gases, light intensities in excess of 1014 W/cm 2 are required. Usually such high intensity are obtained by parametric amplification of ...

  15. Evaluating Clouds, Aerosols, and their Interactions in Three Global Climate Models using COSP and Satellite Observations

    SciTech Connect (OSTI)

    Ban-Weiss, George; Jin, Ling; Bauer, S.; Bennartz, Ralph; Liu, Xiaohong; Zhang, Kai; Ming, Yi; Guo, Huan; Jiang, Jonathan

    2014-09-23

    Accurately representing aerosol-cloud interactions in global climate models is challenging. As parameterizations evolve, it is important to evaluate their performance with appropriate use of observations. In this work we compare aerosols, clouds, and their interactions in three climate models (AM3, CAM5, ModelE) to MODIS satellite observations. Modeled cloud properties were diagnosed using the CFMIP Observations Simulator Package (COSP). Cloud droplet number concentrations (N) were derived using the same algorithm for both satellite-simulated model values and observations. We find that aerosol optical depth tau simulated by models is similar to observations. For N, AM3 and CAM5 capture the observed spatial pattern of higher values in near-coast versus remote ocean regions, though modeled values in general are higher than observed. In contrast, ModelE simulates lower N in most near-coast versus remote regions. Aerosol- cloud interactions were computed as the sensitivity of N to tau for marine liquid clouds off the coasts of South Africa and Eastern Asia where aerosol pollution varies in time. AM3 and CAM5 are in most cases more sensitive than observations, while the sensitivity for ModelE is statistically insignificant. This widely used sensitivity could be subject to misinterpretation due to the confounding influence of meteorology on both aerosols and clouds. A simple framework for assessing the N – tau sensitivity at constant meteorology illustrates that observed sensitivity can change from positive to statistically insignificant when including the confounding influence of relative humidity. Satellite simulated values of N were compared to standard model output and found to be higher with a bias of 83 cm-3.

  16. Intensity Frontier Instrumentation

    SciTech Connect (OSTI)

    Kettell S.; Rameika, R.; Tshirhart, B.

    2013-09-24

    The fundamental origin of flavor in the Standard Model (SM) remains a mystery. Despite the roughly eighty years since Rabi asked “Who ordered that?” upon learning of the discovery of the muon, we have not understood the reason that there are three generations or, more recently, why the quark and neutrino mixing matrices and masses are so different. The solution to the flavor problem would give profound insights into physics beyond the Standard Model (BSM) and tell us about the couplings and the mass scale at which the next level of insight can be found. The SM fails to explain all observed phenomena: new interactions and yet unseen particles must exist. They may manifest themselves by causing SM reactions to differ from often very precise predictions. The Intensity Frontier (1) explores these fundamental questions by searching for new physics in extremely rare processes or those forbidden in the SM. This often requires massive and/or extremely finely tuned detectors.

  17. Study of Mechanisms of Aerosol Indirect Effects on Glaciated Clouds: Progress during the Project Final Technical Report

    SciTech Connect (OSTI)

    2013-10-18

    This 3-year project has studied how aerosol pollution influences glaciated clouds. The tool applied has been an 'aerosol-cloud model'. It is a type of Cloud-System Resolving Model (CSRM) modified to include 2-moment bulk microphysics and 7 aerosol species, as described by Phillips et al. (2009, 2013). The study has been done by, first, improving the model and then performing sensitivity studies with validated simulations of a couple of observed cases from ARM. These are namely the Tropical Warm Pool International Cloud Experiment (TWP-ICE) over the tropical west Pacific and the Cloud and Land Surface Interaction Campaign (CLASIC) over Oklahoma. During the project, sensitivity tests with the model showed that in continental clouds, extra liquid aerosols (soluble aerosol material) from pollution inhibited warm rain processes for precipitation production. This promoted homogeneous freezing of cloud droplets and aerosols. Mass and number concentrations of cloud-ice particles were boosted. The mean sizes of cloud-ice particles were reduced by the pollution. Hence, the lifetime of glaciated clouds, especially ice-only clouds, was augmented due to inhibition of sedimentation and ice-ice aggregation. Latent heat released from extra homogeneous freezing invigorated convective updrafts, and raised their maximum cloud-tops, when aerosol pollution was included. In the particular cases simulated in the project, the aerosol indirect effect of glaciated clouds was twice than of (warm) water clouds. This was because glaciated clouds are higher in the troposphere than water clouds and have the first interaction with incoming solar radiation. Ice-only clouds caused solar cooling by becoming more extensive as a result of aerosol pollution. This 'lifetime indirect effect' of ice-only clouds was due to higher numbers of homogeneously nucleated ice crystals causing a reduction in their mean size, slowing the ice-crystal process of snow production and slowing sedimentation. In addition to the known indirect effects (glaciation, riming and thermodynamic), new indirect effects were discovered and quantified due to responses of sedimentation, aggregation and coalescence in glaciated clouds to changing aerosol conditions. In summary, the change in horizontal extent of the glaciated clouds ('lifetime indirect effects'), especially of ice-only clouds, was seen to be of higher importance in regulating aerosol indirect effects than changes in cloud properties ('cloud albedo indirect effects').

  18. he Impact of Primary Marine Aerosol on Atmospheric Chemistry, Radiation and Climate: A CCSM Model Development Study

    SciTech Connect (OSTI)

    Keene, William C.; Long, Michael S.

    2013-05-20

    This project examined the potential large-scale influence of marine aerosol cycling on atmospheric chemistry, physics and radiative transfer. Measurements indicate that the size-dependent generation of marine aerosols by wind waves at the ocean surface and the subsequent production and cycling of halogen-radicals are important but poorly constrained processes that influence climate regionally and globally. A reliable capacity to examine the role of marine aerosol in the global-scale atmospheric system requires that the important size-resolved chemical processes be treated explicitly. But the treatment of multiphase chemistry across the breadth of chemical scenarios encountered throughout the atmosphere is sensitive to the initial conditions and the precision of the solution method. This study examined this sensitivity, constrained it using high-resolution laboratory and field measurements, and deployed it in a coupled chemical-microphysical 3-D atmosphere model. First, laboratory measurements of fresh, unreacted marine aerosol were used to formulate a sea-state based marine aerosol source parameterization that captured the initial organic, inorganic, and physical conditions of the aerosol population. Second, a multiphase chemical mechanism, solved using the Max Planck Institute for Chemistryâ??s MECCA (Module Efficiently Calculating the Chemistry of the Atmosphere) system, was benchmarked across a broad set of observed chemical and physical conditions in the marine atmosphere. Using these results, the mechanism was systematically reduced to maximize computational speed. Finally, the mechanism was coupled to the 3-mode modal aerosol version of the NCAR Community Atmosphere Model (CAM v3.6.33). Decadal-scale simulations with CAM v.3.6.33, were run both with and without reactive-halogen chemistry and with and without explicit treatment of particulate organic carbon in the marine aerosol source function. Simulated results were interpreted (1) to evaluate influences of marine aerosol production on the microphysical properties of aerosol populations and clouds over the ocean and the corresponding direct and indirect effects on radiative transfer; (2) atmospheric burdens of reactive halogen species and their impacts on O3, NOx, OH, DMS, and particulate non-sea-salt SO42-; and (3) the global production and influences of marine-derived particulate organic carbon. The model reproduced major characteristics of the marine aerosol system and demonstrated the potential sensitivity of global, decadal-scale climate metrics to multiphase marine-derived components of Earthâ??s troposphere. Due to the combined computational burden of the coupled system, the currently available computational resources were the limiting factor preventing the adequate statistical analysis of the overall impact that multiphase chemistry might have on climate-scale radiative transfer and climate.

  19. An aerosol boomerang: Rapid around-the-world transport of smoke from the December 2006 Australian forest fires observed from space

    E-Print Network [OSTI]

    Boersma, Folkert

    forest fires observed from space Ruud J. Dirksen,1 K. Folkert Boersma,1 Jos de Laat,1 Piet Stammes,1-the-world transport of a smoke aerosol plume released by intense forest fires in southeastern Australia in December of forest fire emissions in the extratropical Southern Hemisphere. Citation: Dirksen, R. J., K. Folkert

  20. Apparatus for rapid measurement of aerosol bulk chemical composition

    DOE Patents [OSTI]

    Lee, Yin-Nan E.; Weber, Rodney J.; Orsini, Douglas

    2006-04-18

    An apparatus for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution is provided. The apparatus includes an enhanced particle size magnifier for producing activated aerosol particles and an enhanced collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical means. Methods for on-line measurement of chemical composition of aerosol particles are also provided, the method including exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; and flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

  1. Apparatus for rapid measurement of aerosol bulk chemical composition

    DOE Patents [OSTI]

    Lee, Yin-Nan E. (East Setauket, NY); Weber, Rodney J. (Atlanta, GA)

    2003-01-01

    An apparatus and method for continuous on-line measurement of chemical composition of aerosol particles with a fast time resolution are provided. The apparatus includes a modified particle size magnifier for producing activated aerosol particles and a collection device which collects the activated aerosol particles into a liquid stream for quantitative analysis by analytical methods. The method provided for on-line measurement of chemical composition of aerosol particles includes exposing aerosol carrying sample air to hot saturated steam thereby forming activated aerosol particles; collecting the activated aerosol particles by a collection device for delivery as a jet stream onto an impaction surface; flushing off the activated aerosol particles from the impaction surface into a liquid stream for delivery of the collected liquid stream to an analytical instrument for quantitative measurement.

  2. Aircraft vertical profiles of trace gas and aerosol pollution over the mid-Atlantic United States: Statistics and meteorological cluster

    E-Print Network [OSTI]

    Thompson, Anne

    measurements of O3, CO, SO2, and aerosol properties were made during summertime air pollution episodes over. Introduction [2] In 1992, in response to mounting air pollution prob- lems over the mid-Atlantic United States holistic, long-term air quality studies in the region and analyzing transboundary pollution transport

  3. Observations of Secondary Organic Aerosol Production and Soot Aging under Atmospheric Conditions Using a Novel Environmental Aerosol Chamber 

    E-Print Network [OSTI]

    Glen, Crystal

    2012-02-14

    of the processes leading to SOA production under ambient gaseous and particulate concentrations as well as the impact these aerosol types have on climate is poorly understood. Although the majority of atmospheric aerosols scatter radiation either directly...

  4. AEROSOL-PRECIPITATION INTERACTIONS IN THE SOUTHERN APPALACHIAN MOUNTAINS

    E-Print Network [OSTI]

    AEROSOL-PRECIPITATION INTERACTIONS IN THE SOUTHERN APPALACHIAN MOUNTAINS A Thesis by GINGER MARIE of the requirements for the degree of MASTER OF ARTS May 2011 Department of Geography and Planning #12;AEROSOL-PRECIPITATION and Graduate Studies #12;Copyright by Ginger Marie Kelly 2011 All Rights Reserved #12;iv ABSTRACT AEROSOL-PRECIPITATION

  5. Long-term measurements of submicrometer aerosol chemistry at the Southern Great Plains (SGP) using an Aerosol Chemical Speciation Monitor (ACSM)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parworth, Caroline; Tilp, Alison; Fast, Jerome; Mei, Fan; Shippert, Tim; Sivaraman, Chitra; Watson, Thomas; Zhang, Qi

    2015-04-01

    In this study the long-term trends of non-refractory submicrometer aerosol (NR-PM1) composition and mass concentration measured by an Aerosol Chemical Speciation Monitor (ACSM) at the Atmospheric Radiation Measurement (ARM) program's Southern Great Plains (SGP) site are discussed. NR-PM1 data was recorded at ~30 min intervals over a period of 19 months between November 2010 and June 2012. Positive Matrix Factorization (PMF) was performed on the measured organic mass spectral matrix using a rolling window technique to derive factors associated with distinct sources, evolution processes, and physiochemical properties. The rolling window approach also allows us to capture the dynamic variations ofmore »the chemical properties in the organic aerosol (OA) factors over time. Three OA factors were obtained including two oxygenated OA (OOA) factors, differing in degrees of oxidation, and a biomass burning OA (BBOA) factor. Back trajectory analyses were performed to investigate possible sources of major NR-PM1 species at the SGP site. Organics dominated NR-PM1 mass concentration for the majority of the study with the exception of winter, when ammonium nitrate increases due to transport of precursor species from surrounding urban and agricultural areas and also due to cooler temperatures. Sulfate mass concentrations have little seasonal variation with mixed regional and local sources. In the spring BBOA emissions increase and are mainly associated with local fires. Isoprene and carbon monoxide emission rates were obtained by the Model of Emissions of Gases and Aerosols from Nature (MEGAN) and the 2011 U.S. National Emissions Inventory to represent the spatial distribution of biogenic and anthropogenic sources, respectively. The combined spatial distribution of isoprene emissions and air mass trajectories suggest that biogenic emissions from the southeast contribute to SOA formation at the SGP site during the summer.« less

  6. Atmospheric aerosol optical property retrieval with scanning polarimeters

    E-Print Network [OSTI]

    scatter and absorb incident solar radiation and emitted infra-red radiation. Climate models simulate Mexico suspended over low altitude marine stratocumulus clouds in the Gulf of Mexico. These studies

  7. Cloud activating properties of aerosol observed during CELTIC

    E-Print Network [OSTI]

    2007-01-01

    the secondary organic aero- sol contribution to PM2.5 usingthe EC tracer method. Aero- sol Sci. Technol. , 38 (S1),to represent 15% of submicron aero- sol mass. The large

  8. Optical Properties of Saharan Dust and Asian Dust: Application to Radiative Transfer Simulations 

    E-Print Network [OSTI]

    Fang, Guangyang

    2012-07-16

    an important role in climate change, the majorities of aerosols are natural ones and can impact cloud properties, convective cloud dynamics, and the development of tropical storms (Jones et al. 2004). The optical properties of mineral dust aerosols... dusts from the Rayleigh regime to the geometric optics regime. A database of the optical properties of randomly oriented spheroids has been developed. 4.1 Geometry of the dust particle model The geometry of the spheroidal model used is shown...

  9. Measurement of the Optical Proper-ties of Volcanic Ash: Current status.

    E-Print Network [OSTI]

    Oxford, University of

    Measurement of the Optical Proper- ties of Volcanic Ash: Current status. Daniel M. Peters and R. G project "Opti- cal Properties of Volcanic ash". This project sets out to measure the extinction spectra and size distribution of volcanic ash aerosol. The measurements will allow the calculation of aerosol cross

  10. Flattening coefficient of aerosols collected on treated slides 

    E-Print Network [OSTI]

    Olan-Figueroa, Excel

    1981-01-01

    was found to be 1. 338, and for DOP, 1. 354. There is no apparent variation of F with particle diameter for aerosols in the 2. 7-29. 1 um range. The slightly lower value of F for oleic acid suggests that the contact angle of oleic acid with respect... monodisoerse aerosols in the 1. 5 to 50 um diameter range, the vibratino j et monodisperse aerosol generator has been used. The monodisperse aerosols generated by this device can be considered as an "aerosol standard" since the size and concentration...

  11. Near real time vapor detection and enhancement using aerosol adsorption

    DOE Patents [OSTI]

    Novick, V.J.; Johnson, S.A.

    1999-08-03

    A vapor sample detection method is described where the vapor sample contains vapor and ambient air and surrounding natural background particles. The vapor sample detection method includes the steps of generating a supply of aerosol that have a particular effective median particle size, mixing the aerosol with the vapor sample forming aerosol and adsorbed vapor suspended in an air stream, impacting the suspended aerosol and adsorbed vapor upon a reflecting element, alternatively directing infrared light to the impacted aerosol and adsorbed vapor, detecting and analyzing the alternatively directed infrared light in essentially real time using a spectrometer and a microcomputer and identifying the vapor sample. 13 figs.

  12. Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry

    E-Print Network [OSTI]

    Kroll, Jesse

    In this study we compile and present results from the factor analysis of 43 Aerosol Mass Spectrometer (AMS) datasets (27 of the datasets are reanalyzed in this work). The components from all sites, when taken together, ...

  13. Effect of Hydrophobic Primary Organic Aerosols on Secondary Organic Aerosol Formation from Ozonolysis of ?-Pinene

    SciTech Connect (OSTI)

    Song, Chen; Zaveri, Rahul A.; Alexander, M. Lizabeth; Thornton, Joel A.; Madronich, Sasha; Ortega, John V.; Zelenyuk, Alla; Yu, Xiao-Ying; Laskin, Alexander; Maughan, A. D.

    2007-10-16

    Semi-empirical secondary organic aerosol (SOA) models typically assume a well-mixed organic aerosol phase even in the presence of hydrophobic primary organic aerosols (POA). This assumption significantly enhances the modeled SOA yields as additional organic mass is made available to absorb greater amounts of oxidized secondary organic gases than otherwise. We investigate the applicability of this critical assumption by measuring SOA yields from ozonolysis of ?-pinene (a major biogenic SOA precursor) in a smog chamber in the absence and in the presence of dioctyl phthalate (DOP) and lubricating oil seed aerosol. These particles serve as surrogates for urban hydrophobic POA. The results show that these POA did not enhance the SOA yields. If these results are found to apply to other biogenic SOA precursors, then the semi-empirical models used in many global models would predict significantly less biogenic SOA mass and display reduced sensitivity to anthropogenic POA emissions than previously thought.

  14. Two Hundred Fifty Years of Aerosols and Climate: The End of the Age of Aerosols

    SciTech Connect (OSTI)

    Smith, Steven J.; Bond, Tami C.

    2014-01-20

    Carbonaceous and sulfur aerosols have a substantial global and regional influence on climate in addition to their impact on health and ecosystems. The magnitude of this influence has changed substantially over the past and is expected to continue to change into the future. An integrated picture of the changing climatic influence of black carbon, organic carbon and sulfate over the period 1850 through 2100, focusing on uncertainty, is presented using updated historical inventories and a coordinated set of emission projections. While aerosols have had a substantial impact on climate over the past century, by the end of the 21st century aerosols will likely be only a minor contributor to radiative forcing due to increases in greenhouse gas forcing and a global decrease in pollutant emissions. This outcome is even more certain under a successful implementation of a policy to limit greenhouse gas emissions as low-carbon energy technologies that do not emit appreciable aerosol or SO2 are deployed.

  15. Direct Surface Analysis of Time-Resolved Aerosol Impactor Samples with Ultrahigh-Resolution Mass Spectrometry

    E-Print Network [OSTI]

    Fuller, Stephen J.; Zhao, Yongjing; Cliff, Steven S.; Wexler, Anthony S.; Kalberer, Markus

    2012-10-18

    was assumed to be correct. Unfortunately due to the generally low peak intensities of the identified species MS-MS analysis for further structural identification was not possible. Only about 10-15% of the peaks contain a sulfur atom and are not further... 1 Direct surface analysis of time-resolved aerosol impactor samples with ultra-high resolution mass spectrometry Stephen J. Fuller 1, Yongjing Zhao2, Steven S. Cliff2, Anthony S. Wexler2, Markus Kalberer 1* 1 University of Cambridge, Department...

  16. Results from simulated upper-plenum aerosol transport and aerosol resuspension experiments

    SciTech Connect (OSTI)

    Wright, A.L.; Pattison, W.L.

    1984-01-01

    Recent calculational results published as part of the Battelle-Columbus BMI-2104 source term study indicate that, for some LWR accident sequences, aerosol deposition in the reactor primary coolant system (PCS) can lead to significant reductions in the radionuclide source term. Aerosol transport and deposition in the PCS have been calculated in this study using the TRAP-MELT 2 computer code, which was developed at Battelle-Columbus; the status of validation of the TRAP-MELT 2 code has been described in an Oak Ridge National Laboratory (ORNL) report. The objective of the ORNL TRAP-MELT Validation Project, which is sponsored by the Fuel Systems Behavior Research Branch of the US Nuclear Regulatory Commission, is to conduct simulated reactor-vessel upper-plenum aerosol deposition and transport tests. The results from these tests will be used in the ongoing effort to validate TRAP-MELT 2. The TRAP-MELT Validation Project includes two experimental subtasks. In the Aerosol Transport Tests, aerosol transport in a vertical pipe is being studied; this geometry was chosen to simulate aerosol deposition and transport in the reactor-vessel upper-plenum. To date, four experiments have been performed; the results from these tests are presented in this paper. 7 refs., 4 figs., 4 tabs.

  17. Atmospheric Radiation Measurement (ARM) Data from Shouxian, China for the Study of Aerosol Indirect Effects in China

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In a complex ARM Mobile Facility (AMF) deployment, monitoring data was collected at four locations in China during 2008. The various sites are located in regions with different climate regimes and with high aerosol loadings of different optical, physical, and chemical properties. Measurements obtained at all the AMF sites during the 8-month deployment in China will help scientists to validate satellite-based findings, understand the mechanisms of the aerosol indirect effects in the region, and examine the roles of aerosols in affecting regional climate and atmospheric circulation, with a special focus on the impact of the East Asian monsoon system. As with other collections from the ARM Mobile Facility, the datasets are available from the ARM Archive. The ARM Archive physically resides at the Oak Ridge National Laboratory.

  18. Experimental study of nuclear workplace aerosol samplers 

    E-Print Network [OSTI]

    Parulian, Antony

    1995-01-01

    consists of an inlet-elbow, a transport line, and a EL-900 CAM prototype manufactured by EG&G. Results show that only 12% of 10 []m aerodynamic diameter (AD) aerosol particles penetrate through the complete sampling system when it is operated at flow rate...

  19. Accelerators for Intensity Frontier Research

    SciTech Connect (OSTI)

    Derwent, Paul; /Fermilab

    2012-05-11

    In 2008, the Particle Physics Project Prioritization Panel identified three frontiers for research in high energy physics, the Energy Frontier, the Intensity Frontier, and the Cosmic Frontier. In this paper, I will describe how Fermilab is configuring and upgrading the accelerator complex, prior to the development of Project X, in support of the Intensity Frontier.

  20. Direct and semidirect aerosol effects of Southern African biomass burning aerosol

    SciTech Connect (OSTI)

    Sakaeda, Naoko; Wood, Robert; Rasch, Philip J.

    2011-06-21

    The direct and semi-direct radiative effects of biomass burning aerosols from Southern African fires during July-October are investigated using 20 year runs of the Community Atmospheric Model (CAM) coupled to a slab ocean model. The aerosol optical depth is constrained using observations in clear skies from MODIS and for aerosol layers above clouds from CALIPSO. Over the ocean, where the absorbing biomass burning aerosol layers are primarily located above cloud, negative top of atmosphere (TOA) semi-direct radiative effects associated with increased low cloud cover dominate over a weaker positive all-sky direct radiative effect (DRE). In contrast, over the land where the aerosols are often below or within cloud layers, reductions in cloud liquid water path (LWP) lead to a positive semi-direct radiative effect that dominates over a near-zero DRE. Over the ocean, the cloud response can be understood as a response to increased lower tropospheric stability (LTS) which is caused both by aerosol absorptive warming in overlying layers and surface cooling in response to direct aerosol forcing. The ocean cloud changes are robust to changes in the cloud parameterization (removal of the hard-wired dependence of clouds on LTS), suggesting that they are physically realistic. Over land where cloud cover changes are minimal, decreased LWP is consistent with weaker convection driven by increased static stability. Over the entire region the overall TOA radiative effect from the biomass burning aerosols is almost zero due to opposing effects over the land and ocean. However, the surface forcing is strongly negative requiring a reduction in precipitation. This is primarily realized through reductions in convective precipitation on both the southern and northern flanks of the convective precipitation region spanning the equatorial rainforest and the ITCZ in the southern Sahel. The changes are consistent with the low-level aerosol forced cooling pattern. The results highlight the importance of semi-direct radiative effects and precipitation responses for determining the climatic effects of aerosols in the African region.

  1. Non-linear photochemical pathways in laser induced atmospheric aerosol formation

    E-Print Network [OSTI]

    Mongin, Denis; Schubert, Elise; Brisset, Jean-Gabriel; Berti, Nicolas; Moret, Michel; Prévôt, André S H; Baltensperger, Urs; Kasparian, Jérôme; Wolf, Jean-Pierre

    2015-01-01

    We measured the chemical composition and the size distribution of aerosols generated by femtosecond-Terawatt laser pulses in the atmosphere using an aerosol mass spectrometer (AMS). We show that nitric acid condenses in the form of ammonium nitrate, and that oxidized volatile organics also contribute to particle growth. These two components account for two thirds and one third, respectively, of the dry laser-condensed mass. They appear in two different modes centred at 380 nm and 150 nm. The number concentration of particles between 25 and 300 nm increases by a factor of 15. Pre-existing water droplets strongly increase the oxidative properties of the laser-activated atmosphere, substantially enhancing the condensation of organics under laser illumination.

  2. Gamma radiation field intensity meter

    DOE Patents [OSTI]

    Thacker, L.H.

    1995-10-17

    A gamma radiation intensity meter measures dose rate of a radiation field. The gamma radiation intensity meter includes a tritium battery emitting beta rays generating a current which is essentially constant. Dose rate is correlated to an amount of movement of an electroscope element charged by the tritium battery. Ionizing radiation decreases the voltage at the element and causes movement. A bleed resistor is coupled between the electroscope support element or electrode and the ionization chamber wall electrode. 4 figs.

  3. Gamma radiation field intensity meter

    DOE Patents [OSTI]

    Thacker, L.H.

    1994-08-16

    A gamma radiation intensity meter measures dose rate of a radiation field. The gamma radiation intensity meter includes a tritium battery emitting beta rays generating a current which is essentially constant. Dose rate is correlated to an amount of movement of an electroscope element charged by the tritium battery. Ionizing radiation decreases the voltage at the element and causes movement. A bleed resistor is coupled between the electroscope support element or electrode and the ionization chamber wall electrode. 4 figs.

  4. Gamma radiation field intensity meter

    DOE Patents [OSTI]

    Thacker, Louis H. (Knoxville, TN)

    1995-01-01

    A gamma radiation intensity meter measures dose rate of a radiation field. The gamma radiation intensity meter includes a tritium battery emitting beta rays generating a current which is essentially constant. Dose rate is correlated to an amount of movement of an electroscope element charged by the tritium battery. Ionizing radiation decreases the voltage at the element and causes movement. A bleed resistor is coupled between the electroscope support element or electrode and the ionization chamber wall electrode.

  5. Gamma radiation field intensity meter

    DOE Patents [OSTI]

    Thacker, Louis H. (Knoxville, TN)

    1994-01-01

    A gamma radiation intensity meter measures dose rate of a radiation field. The gamma radiation intensity meter includes a tritium battery emitting beta rays generating a current which is essentially constant. Dose rate is correlated to an amount of movement of an electroscope element charged by the tritium battery. Ionizing radiation decreases the voltage at the element and causes movement. A bleed resistor is coupled between the electroscope support element or electrode and the ionization chamber wall electrode.

  6. Total aerosol effect: forcing or radiative flux perturbation?

    SciTech Connect (OSTI)

    Lohmann, Ulrike; Storelvmo, Trude; Jones, Andy; Rotstayn, Leon; Menon, Surabi; Quaas, Johannes; Ekman, Annica; Koch, Dorothy; Ruedy, Reto

    2009-09-25

    Uncertainties in aerosol forcings, especially those associated with clouds, contribute to a large extent to uncertainties in the total anthropogenic forcing. The interaction of aerosols with clouds and radiation introduces feedbacks which can affect the rate of rain formation. Traditionally these feedbacks were not included in estimates of total aerosol forcing. Here we argue that they should be included because these feedbacks act quickly compared with the time scale of global warming. We show that for different forcing agents (aerosols and greenhouse gases) the radiative forcings as traditionally defined agree rather well with estimates from a method, here referred to as radiative flux perturbations (RFP), that takes these fast feedbacks and interactions into account. Thus we propose replacing the direct and indirect aerosol forcing in the IPCC forcing chart with RFP estimates. This implies that it is better to evaluate the total anthropogenic aerosol effect as a whole.

  7. Climate Engineering with Stratospheric Aerosols and Associated Engineering Parameters

    SciTech Connect (OSTI)

    Kravitz, Benjamin S.

    2013-02-12

    Climate engineering with stratospheric aerosols, an idea inspired by large volcaniceruptions, could cool the Earth’s surface and thus alleviate some of the predicted dangerous impacts of anthropogenic climate change. However, the effectiveness of climate engineering to achieve a particular climate goal, and any associated side effects, depend on certain aerosol parameters and how the aerosols are deployed in the stratosphere. Through the examples of sulfate and black carbon aerosols, this paper examines "engineering" parameters-aerosol composition, aerosol size, and spatial and temporal variations in deployment-for stratospheric climate engineering. The effects of climate engineering are sensitive to these parameters, suggesting that a particle could be found ordesigned to achieve specific desired climate outcomes. This prospect opens the possibility for discussion of societal goals for climate engineering.

  8. How Physical and Chemical Properties Change Ice Nucleation Efficiency of Soot and Polyaromatic Hydrocarbon Particles 

    E-Print Network [OSTI]

    Suter, Katie Ann

    2012-10-19

    freezing. The mechanism by which this freezing occurs depends on the ambient conditions and composition of the IN. Aerosol properties change through chemical aging and reactions with atmospheric oxidants such as ozone. We have conducted a series...

  9. Aerosol Retrievals from ARM SGP MFRSR Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Alexandrov, Mikhail

    2008-01-15

    The Multi-Filter Rotating Shadowband Radiometer (MFRSR) makes precise simultaneous measurements of the solar direct normal and diffuse horizontal irradiances at six wavelengths (nominally 415, 500, 615, 673, 870, and 940 nm) at short intervals (20 sec for ARM instruments) throughout the day. Time series of spectral optical depth are derived from these measurements. Besides water vapor at 940 nm, the other gaseous absorbers within the MFRSR channels are NO2 (at 415, 500, and 615 nm) and ozone (at 500, 615, and 670 nm). Aerosols and Rayleigh scattering contribute atmospheric extinction in all MFRSR channels. Our recently updated MFRSR data analysis algorithm allows us to partition the spectral aerosol optical depth into fine and coarse modes and to retrieve the fine mode effective radius. In this approach we rely on climatological amounts of NO2 from SCIAMACHY satellite retrievals and use daily ozone columns from TOMS.

  10. Aerosol Retrievals from ARM SGP MFRSR Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Alexandrov, Mikhail

    The Multi-Filter Rotating Shadowband Radiometer (MFRSR) makes precise simultaneous measurements of the solar direct normal and diffuse horizontal irradiances at six wavelengths (nominally 415, 500, 615, 673, 870, and 940 nm) at short intervals (20 sec for ARM instruments) throughout the day. Time series of spectral optical depth are derived from these measurements. Besides water vapor at 940 nm, the other gaseous absorbers within the MFRSR channels are NO2 (at 415, 500, and 615 nm) and ozone (at 500, 615, and 670 nm). Aerosols and Rayleigh scattering contribute atmospheric extinction in all MFRSR channels. Our recently updated MFRSR data analysis algorithm allows us to partition the spectral aerosol optical depth into fine and coarse modes and to retrieve the fine mode effective radius. In this approach we rely on climatological amounts of NO2 from SCIAMACHY satellite retrievals and use daily ozone columns from TOMS.

  11. Design of Aerosol Face Masks for Children Using Computerized 3D Face Analysis

    E-Print Network [OSTI]

    Kimmel, Ron

    seal to the child's face, and thus may minimize aerosol leakage and dead space. Key words: inhaled supplied with valved aerosol hold- ing chambers used for aerosol therapy. (Adapted with per- mission from

  12. Formation mechanisms and quantification of organic nitrates in atmospheric aerosol

    E-Print Network [OSTI]

    Rollins, Andrew Waite

    2010-01-01

    and J. Viidanoja, Atmospheric chemistry of c 3 -c 6organic nitrates, Atmospheric Chemistry and Physics, 9 (4),organic aerosol yields, Atmospheric Chemistry and Physics

  13. Extending the physicochemical characterization of aerosol particles in California

    E-Print Network [OSTI]

    Zauscher, Melanie Dorothy

    2012-01-01

    W. T. (1997).Emissions from Smoldering Combustion of BiomassCombustion generated aerosols, including emissions from diesel and gasoline engines, biomass and

  14. Climatic effects of different aerosol types in China simulated

    E-Print Network [OSTI]

    Y. GU

    2006-01-01

    P. Shettle (1991), Atmospheric Aero- sols—Global ClimatologyEffects of stratospheric aero- sols and preliminarytypes, such as volcanic aero- sols, desert aerosols, or

  15. Relating Secondary Organic Aerosol Characteristics with Cloud Condensation Nuclei Activity

    E-Print Network [OSTI]

    Tang, Xiaochen

    2013-01-01

    by V and Ni from heavy oil combustion: Anthropogenic sourcesgeneration from heavy fuel oil (HFO) as an alternative toengines operating with heavy fuel oils. Journal of Aerosol

  16. The Radiative Role of Free Tropospheric Aerosols and Marine Clouds...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: The Radiative Role of Free Tropospheric Aerosols and Marine Clouds over the Central North Atlantic Citation Details In-Document Search Title: The Radiative Role...

  17. Impact of natural and anthropogenic aerosols on stratocumulus and precipitation in the Southeast Pacific: A regional modeling study using WRF-Chem

    SciTech Connect (OSTI)

    Yang, Qing; Gustafson, William I.; Fast, Jerome D.; Wang, Hailong; Easter, Richard C.; Wang, Minghuai; Ghan, Steven J.; Berg, Larry K.; Leung, Lai-Yung R.; Morrison, H.

    2012-09-28

    Cloud-system resolving simulations with the chemistry version of the Weather Research and Forecasting (WRF-Chem) model are used to quantify the impacts of regional anthropogenic and oceanic emissions on changes in aerosol properties, cloud macro- and microphysics, and cloud radiative forcing over the Southeast Pacific (SEP) during the VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) (15 Oct–Nov 16, 2008). The effects of oceanic aerosols on cloud properties, precipitation, and the shortwave forcing counteract those of anthropogenic aerosols. Despite the relatively small changes in Na concentrations (2-12%) from regional oceanic emissions, their net effect (direct and indirect) on the surface shortwave forcing is opposite and comparable or even larger in magnitude compared to those of regional anthropogenic emissions over the SEP. Two distinct regions are identified in the VOCALS-REx domain. The near-coast polluted region is characterized with strong droplet activation suppression of small particles by sea-salt particles, the more important role of the first than the second indirect effect, low surface precipitation rate, and low aerosol-cloud interaction strength associated with anthropogenic emissions. The relatively clean remote region is characterized with large contributions of Cloud Condensation Nuclei (CCN, number concentration denoted by NCCN) and droplet number concentrations (Nd) from non-local sources (lateral boundaries), a significant amount of surface precipitation, and high aerosol-cloud interactions under a scenario of five-fold increase in anthropogenic emissions. In the clean region, cloud properties have high sensitivity (e.g., 13% increase in cloud-top height and a 9% surface albedo increase) to the moderate increase in CCN concentration (?Nccn = 13 cm-3; 25%) produced by a five-fold increase in regional anthropogenic emissions. The increased anthropogenic aerosols reduce the precipitation amount over the relatively clean remote ocean. The reduction of precipitation (as a cloud water sink) more than doubles the wet scavenging timescale, resulting in an increased aerosol lifetime in the marine boundary layer. Therefore, the aerosol impacts on precipitation are amplified by the positive feedback of precipitation on aerosol. The positive feedback ultimately alters the cloud micro- and macro-properties, leading to strong aerosol-cloud-precipitation interactions. The higher sensitivity of clouds to anthropogenic aerosols over this region is also related to a 16% entrainment rate increase due to anthropogenic aerosols. The simulated aerosol-cloud-precipitation interactions are stronger at night over the clean marine region, while during the day, solar heating results in more frequent decoupling, thinner clouds, reduced precipitation, and reduced sensitivity to anthropogenic emissions. The simulated high sensitivity to the increased anthropogenic emissions over the clean region suggests that the perturbation of the clean marine environment with anthropogenic aerosols may have a larger effect on climate than that of already polluted marine environments.

  18. Quantifying Aerosol Direct Effects from Broadband Irradiance and Spectral Aerosol Optical Depth Observations

    SciTech Connect (OSTI)

    Creekmore, Torreon N.; Joseph, Everette; Long, Charles N.; Li, Siwei

    2014-05-16

    We outline a methodology using broadband and spectral irradiances to quantify aerosol direct effects on the surface diffuse shortwave (SW) irradiance. Best Estimate Flux data span a 13 year timeframe at the Department of Energy Atmospheric Radiation Measurement Program’s Southern Great Plains (SGP) site. Screened clear-sky irradiances and aerosol optical depth (AOD), for solar zenith angles ? 65°, are used to estimate clear-sky diffuse irradiances. We validate against detected clear-sky observations from SGP’s Basic Radiation System (BRS). BRS diffuse irradiances were in accordance with estimates, producing a root-mean-square error and mean bias errors of 4.0 W/m2 and -1.4 W/m2, respectively. Absolute differences show 99% of estimates within ±10 W/m2 (10%) of the mean BRS observations. Clear-sky diffuse estimates are used to derive quantitative estimates of aerosol radiative effects, represented as the aerosol diffuse irradiance (ADI). ADI is the contribution of diffuse SW to global SW, attributable to scattering of atmospheric transmission by natural plus anthropogenic aerosols. Estimated slope for the ADI as a function of AOD indicates an increase of ~22 W/m2 in diffuse SW for every 0.1 increase in AOD. Such significant increases in the diffuse fraction could possibly increase photosynthesis. Annual mean ADI is 28.2 W/m2, and heavy aerosol loading at SGP provides up to a maximum increase of 120 W/m2 in diffuse SW over background conditions. With regard to seasonal variation, the mean diffuse forcings are 17.2, 33.3, 39.0, and 23.6 W/m2 for winter, spring, summer, and fall, respectively.

  19. Surface Intensive Materials Processing for Multi-Functional Purposes

    SciTech Connect (OSTI)

    Ila, D.; Williams, E.K.; Muntele, C.I.; George, M.A.; Poker, D.B.; Hensley, D.K.; Larkin, D.J.

    2000-03-06

    We have chosen silicon carbide (SiC) as a multi-functional material to demonstrate the application of surface intensive processing for device fabrication. We will highlight two devices which are produced in house at the Center for Irradiation of materials of Alabama A and M university: (A) High temperature electronic gas sensor, (B) High temperature optical properties/sensor.

  20. Initial Assessment of the Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR)-Based Aerosol Retrieval: Sensitivity Study

    SciTech Connect (OSTI)

    Kassianov, Evgueni I.; Flynn, Connor J.; Redemann, Jens; Schmid, Beat; Russell, P. B.; Sinyuk, Alexander

    2012-10-24

    The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) being developed for airborne measurements will offer retrievals of aerosol microphysical and optical properties from multi-angular and multi-spectral measurements of sky radiance and direct-beam sun transmittance. In this study, we assess the expected accuracy of the 4STAR-based aerosol retrieval and its sensitivity to major sources of anticipated perturbations in the 4STAR measurements by adapting a theoretical approach previously developed for the AERONET measurements. The major anticipated perturbations are (1) an apparent enhancement of sky radiance at small scattering angles associated with the necessarily compact design of the 4STAR and (2) and an offset (i.e. uncertainty) of sky radiance calibration independent of scattering angle. The assessment is performed through application of the operational AERONET aerosol retrieval and constructed synthetic 4STAR-like data. Particular attention is given to the impact of these perturbations on the upwelling and downwelling broadband fluxes and the direct aerosol radiative forcing at the bottom and top of the atmosphere. The results from this study suggest that limitations in the accuracy of 4STAR-retrieved particle size distributions and scattering phase functions have diminished impact on the accuracy of retrieved bulk microphysical parameters, permitting quite accurate retrievals of properties including the effective radius (up to 10%, or 0.03), and the radiatively important optical properties, such as the asymmetry factor (up to 4%, or ±0.02) and single-scattering albedo (up to 6%, or ±0.04). Also, the obtained results indicate that the uncertainties in the retrieved aerosol optical properties are quite small in the context of the calculated fluxes and direct aerosol radiative forcing (up to 15%, or 3 Wm-2).

  1. Lidar Investigation of Tropical Nocturnal Boundary Layer Aerosols and Cloud Macrophysics

    SciTech Connect (OSTI)

    Manoj, M. G.; Devara, PC S.; Taraphdar, Sourav

    2013-10-01

    Observational evidence of two-way association between nocturnal boundary layer aerosols and cloud macrophysical properties under different meteorological conditions is reported in this paper. The study has been conducted during 2008-09 employing a high space-time resolution polarimetric micro-pulse lidar over a tropical urban station in India. Firstly, the study highlights the crucial role of boundary layer aerosols and background meteorology on the formation and structure of low-level stratiform clouds in the backdrop of different atmospheric stability conditions. Turbulent mixing induced by the wind shear at the station, which is associated with a complex terrain, is found to play a pivotal role in the formation and structural evolution of nocturnal boundary layer clouds. Secondly, it is shown that the trapping of energy in the form of outgoing terrestrial radiation by the overlying low-level clouds can enhance the aerosol mixing height associated with the nocturnal boundary layer. To substantiate this, the long-wave heating associated with cloud capping has been quantitatively estimated in an indirect way by employing an Advanced Research Weather Research and Forecasting (WRF-ARW) model version 2.2 developed by National Center for Atmospheric Research (NCAR), Colorado, USA, and supplementary data sets; and differentiated against other heating mechanisms. The present investigation as well establishes the potential of lidar remote-sensing technique in exploring some of the intriguing aspects of the cloud-environment relationship.

  2. Effects of NOx on the volatility of secondary organic aerosol from isoprene photooxidation

    SciTech Connect (OSTI)

    Xu, Lu; Kollman, Matthew S.; Song, Chen; Shilling, John E.; Ng, L. N.

    2014-01-28

    The effects of NOx on the volatility of the secondary organic aerosol (SOA) formed from isoprene photooxidation are investigated in environmental chamber experiments. Two types of experiments are performed. In HO2-dominant experiments, organic peroxy radicals (RO2) primarily react with HO2. In mixed experiments, RO2 reacts through multiple pathways. The volatility and oxidation state of isoprene SOA is sensitive to and displays a non-linear dependence on NOx levels. When initial NO/isoprene ratio is approximately 3 (ppbv:ppbv), SOA are shown to be most oxidized and least volatile, associated with the highest SOA yield. A High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) is applied to characterize the key chemical properties of aerosols. While the composition of SOA in mixed experiments does not change substantially over time, SOA become less volatile and more oxidized as oxidation progresses in HO2-dominant experiments. Analysis of the SOA composition suggests that the further reactions of organic peroxides and alcohols may produce carboxylic acids, which might play a strong role in SOA aging.

  3. The Radiative Role of Free Tropospheric Aerosols and Marine Clouds over the Central North Atlantic

    SciTech Connect (OSTI)

    Mazzoleni, Claudio; Kumar, Sumit; Wright, Kendra; Kramer, Louisa; Mazzoleni, Lynn; Owen, Robert; Helmig, Detlev

    2014-12-09

    The scientific scope of the project was to exploit the unique location of the Pico Mountain Observatory (PMO) located in the summit caldera of the Pico Volcano in Pico Island in the Azores, for atmospheric studies. The observatory, located at 2225m a.s.l., typically samples free tropospheric aerosols laying above the marine low-level clouds and long-range transported from North America. The broad purpose of this research was to provide the scientific community with a better understanding of fundamental physical processes governing the effects of aerosols on radiative forcing and climate; with the ultimate goal of improving our abilities to understand past climate and to predict future changes through numerical models. The project was 'exploratory' in nature, with the plan to demonstrate the feasibility of deploying for the first time, an extensive aerosol research package at PMO. One of the primary activities was to test the deployment of these instruments at the site, to collect data during the 2012 summer season, and to further develop the infrastructure and the knowledge for performing novel research at PMO in follow-up longer-term aerosol-cloud studies. In the future, PMO could provide an elevated research outpost to support the renewed DOE effort in the Azores that was intensified in 2013 with the opening of the new sea-level ARM-DOE Eastern North Atlantic permanent facility at Graciosa Island. During the project period, extensive new data sets were collected for the planned 2012 season. Thanks to other synergistic activities and opportunities, data collection was then successfully extended to 2013 and 2014. Highlights of the scientific findings during this project include: a) biomass burning contribute significantly to the aerosol loading in the North Atlantic free troposphere; however, long-range transported black carbon concentrations decreased substantially in the last decade. b) Single black carbon particles – analyzed off-line at the electron microscope – were often very compacted, suggesting cloud processing and exhibiting different optical properties from fresh emissions. In addition, black carbon was found to be sometimes mixed with mineral dust, affecting its optical properties and potential forcing. c) Some aerosols collected at PMO acted as ice nuclei, potentially contributing to cirrus cloud formation during their transport in the upper free troposphere. Identified good ice nuclei were often mineral dust particles. d) The free tropospheric aerosols studied at PMO have relevance to low level marine clouds due, for example, to synoptic subsidence entraining free tropospheric aerosols into the marine boundary layer. This has potentially large consequences on cloud condensation nuclei concentrations and compositions in the marine boundary layer; therefore, having an effect on the marine stratus clouds, with potentially important repercussions on the radiative forcing. The scientific products of this project currently include contributions to two papers published in the Nature Publishing group (Nature Communications and Scientific Reports), one paper under revision for Atmospheric Chemistry and Physics, one in review in Geophysical Research Letters and one recently submitted to Atmospheric Chemistry and Physics Discussion. In addition, four manuscripts are in advanced state of preparation. Finally, twenty-eight presentations were given at international conferences, workshops and seminars.

  4. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-01-01

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore »and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day?1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

  5. Radiative and thermodynamic responses to aerosol extinction profiles during the pre-monsoon month over South Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.

    2015-06-19

    Aerosol radiative effects and thermodynamic responses over South Asia are examined with a version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of Aerosol Optical Depth (AOD) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in the northern India. The WRF-Chem model is found to underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model low-bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AODmore »and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day?1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to respond differently between Case I and Case II underlying the importance of determining the exact portion of scattering or absorbing aerosols that lead to the underestimation of aerosol optical depth in the model. In addition, the model results suggest that both direct radiative effect and rapid thermodynamic responses need to be quantified for understanding aerosol radiative impacts.« less

  6. Absorbing Aerosol Index (AAI) The residue method for the detection of aerosols

    E-Print Network [OSTI]

    Graaf, Martin de

    and calculation Main sensitivities of residue Problems with the residue Conclusions and outlook #12;#12;o = 380 scattering and absorption #12;#12;#12;Nadir View Solar zenith angle = 45o Residue = 3.5 Rayleigh atmosphere View Solar zenith angle = 45o Residue = -1.0 Rayleigh atmosphere, As = 0.16 Scattering aerosol layer

  7. AEROSOL CHEMICAL COMPOSITION CHARACTERIZATION AT THE ARM SOUTHERN GREAT PLAINS (SGP) SITE USING AN AEROSOL CHEMICAL

    E-Print Network [OSTI]

    ) was integrated into the Aerosol Observing System (AOS) at the Atmospheric Radiation Measurement (ARM) SGP site in Oklahoma in Nov 2010. This instrument has been measuring concentrations of sulfate, ammonium, nitrate of oxygenated OA with minor contributions from hydrocarbon-like OA, indicating that the OA at the SGP site

  8. Aerosol Science and Technology, 38:555573, 2004 Copyright c American Association for Aerosol Research

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    from motor vehicles are a significant source of fine particulate matter (PM) and gaseous pollutants of their emission. This work uses an Aero- dyne aerosol mass spectrometer (AMS) to provide size instrumentation, was deployed on the Aero- dyne Research Inc. (ARI) mobile laboratory, which was used to "chase

  9. Techniques for Minimizing Aerosols (aerosols are a common source of laboratoryacquired infections)

    E-Print Network [OSTI]

    Chan, Hue Sun

    " pipettes to avoid blowing out the last drop Drain pipettes gently with the tip against the inner wall glass rod to crack the glass, allow time for air to seep into the ampoule and gently remove the top than glass (less likely to break which generates aerosols) Source: Adapted from

  10. Role of ammonia chemistry and coarse mode aerosols in global climatological inorganic aerosol distributions

    E-Print Network [OSTI]

    Moore, Keith

    , the aerosolassociated water depends on the composition of the #12;3 particles, which is determined by gas in a three dimensional chemical transport model to understand the roles of ammonia chemistry and natural precursors among modeled aerosol species selfconsistently with ambient relative humidity and natural

  11. Aerosol Science and Technology, 43:486501, 2009 Copyright American Association for Aerosol Research

    E-Print Network [OSTI]

    a NOAA research vessel during the Texas Air Quality Study 2006/Gulf of Mexico Atmospheric Composition for glutaric acid in mixed glutaric acid/NH4HSO4 test aerosols was 0.22 ng collected mass, which corresponds min­1. During TexAQS 2006/GoMACCS, signals well above the detection limit were observed at a number

  12. SCIAMACHY'S ABSORBING AEROSOL INDEX AND THE CONSEQUENCES OF INSTRUMENT DEGRADATION

    E-Print Network [OSTI]

    Graaf, Martin de

    SCIAMACHY'S ABSORBING AEROSOL INDEX AND THE CONSEQUENCES OF INSTRUMENT DEGRADATION L. G. Tilstra1- itoring the Absorbing Aerosol Index (AAI) [1] measured by the satellite instrument SCIAMACHY [2]. We find. This we conclude from straightforward calculation of the effect of instrument degradation based

  13. Global observations of desert dust and biomass burning aerosols

    E-Print Network [OSTI]

    Graaf, Martin de

    and desert dust observations from GOME and SCIAMACHY · Conclusions and Outlook #12; · Absorbing Aerosol Transfer Model Solar zenith angle = 30° Viewing zenith angle = 0° Surface albedo = 5% #12;Reflectance at TOA with absorbing aerosols Doubling-Adding KNMI Radiative Transfer Model Solar zenith angle = 30

  14. GLOBAL AEROSOL EFFECT RETRIEVAL FROM PASSIVE HYPERSPECTRAL MEASUREMENTS

    E-Print Network [OSTI]

    Graaf, Martin de

    that can be detected using UV reflectance measurements. Since the aerosol extinction optical thickness any instrument, or a combination of instruments, that measures UV, visible and SWIR reflectancesGLOBAL AEROSOL EFFECT RETRIEVAL FROM PASSIVE HYPERSPECTRAL MEASUREMENTS M. de Graaf1,2 , L. G

  15. Organic Aerosol Formation Downwind from the Deepwater Horizon Oil Spill

    E-Print Network [OSTI]

    Toohey, Darin W.

    Organic Aerosol Formation Downwind from the Deepwater Horizon Oil Spill Nicole ONeill - ATOC 3500 and aerosol composition of air over the Deepwater Horizon oil spill in the Gulf of Mexico. · The lightest chemicals in the oil evaporated within hours, as scientists expected them to do. What they didn't expect

  16. Carbonaceous aerosol particles from common vegetation in the Grand Canyon

    SciTech Connect (OSTI)

    Hallock, K.A.; Mazurek, M.A. (Brookhaven National Lab., Upton, NY (United States)); Cass, G.R. (California Inst. of Tech., Pasadena, CA (United States). Dept. of Environmental Engineering Science)

    1992-05-01

    The problem of visibility reduction in the Grand Canyon due to fine organic aerosol particles in the atmosphere has become an area of increased environmental concern. Aerosol particles can be derived from many emission sources. In this report, we focus on identifying organic aerosols derived from common vegetation in the Grand Canyon. These aerosols are expected to be significant contributors to the total atmospheric organic aerosol content. Aerosol samples from living vegetation were collected by resuspension of surface wax and resin components liberated from the leaves of vegetation common to areas of the Grand Canyon. The samples were analyzed using high-resolution gas chromatography/mass spectrometry (GC/MS). Probable identification of compounds was made by comparison of sample spectra with National Institute of Standards and Technology (NIST) mass spectral references and positive identification of compounds was made when possible by comparison with authentic standards as well as NIST references. Using these references, we have been able to positively identify the presence of n-alkane and n-alkanoic acid homolog series in the surface waxes of the vegetation sampled. Several monoterpenes, sesquiterpenes, and diterpenes were identified also as possible biogenic aerosols which may contribute to the total organic aerosol abundance leading to visibility reduction in the Grand Canyon.

  17. Supplementary Material1 Characterization of Organic Aerosol Produced during2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    mass spectra of a dominant type (coal) of ambient aerosol in Shanghai using2 ATOFMS (m/z from 1501 Supplementary Material1 Characterization of Organic Aerosol Produced during2 Pulverized Coal diagram of combustion process of a single coal particle5 6 #12;3 10 100 10 3 10 4 10 5 Oxygen/coal ratio

  18. Effects of operating conditions on a heat transfer fluid aerosol 

    E-Print Network [OSTI]

    Sukmarg, Passaporn

    2000-01-01

    fluids are used as hot liquids at elevated pressures. If loss of containment does occur, the liquid will leak under pressure and may disperse as a fine aerosol mist. Though it has been recognized that aerosol mists can explode, very little is known about...

  19. Flood or Drought: How Do Aerosols Affect Precipitation?

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    Flood or Drought: How Do Aerosols Affect Precipitation? Daniel Rosenfeld,1 * Ulrike Lohmann,2 and the initiation of precipitation. Large concentrations of human-made aerosols have been reported to both decrease hand, heavily polluted clouds evaporate much of their water before precipitation can occur, if they can

  20. ARM - Evaluation Product - MFRSR-Column Intensive Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments? WeDatastreamstps DocumentationAtlanticENA Contacts ENAProductsHSRL Corrected forCorrection

  1. Aerosol generation from sparging of molten pools of corium by gases released from core-concrete interactions. [PWR; BWR

    SciTech Connect (OSTI)

    Ginsberg, T.

    1983-02-01

    A model for calculation of the aerosol generation rate resulting from surface bubble rupture during molten core-concrete interactions is discussed. One aspect of the model, based upon previous work in the literature, considers that film rupture occurs due to growth of film oscillation disturbances in the surface liquid film. Calculations are presented for molten pools with liquid properties in the range of prototypic interest.

  2. Experiments related to the resuspension of aerosols during hydrogen burns

    SciTech Connect (OSTI)

    Nelson, L.S.; Guay, K.P.

    1987-01-01

    We have performed seven ''add-on'' experiments in two large combustion facilities to investigate the capability of hydrogen burns to remove simulated structural and fission product aerosols previously deposited on small metal discs that have surfaces prototypical of those found in nuclear reactor containments. Our results suggest that hydrogen combustion provides an especially effective mechanism for removal (and, presumably, resuspension) of sedimented aerosols produced in a hypothetical nuclear reactor core-degradation or core-melting accident. The presence of condensing steam does not seem to assure adhesion of sedimented aerosols during hydrogen burns. Differences are exhibited between different surfaces as well as between types of aerosol. In-depth studies will be required to assess the impact exposure of sedimented aerosols to hydrogen burns might have on the radiological source term.

  3. Study of Aerosol Indirect Effects in China

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect PhotovoltaicsStructure andChallenge | Department,Aerosol Indirect Effects in

  4. Laboratory Investigation of Contact Freezing and the Aerosol to Ice Crystal Transformation Process

    SciTech Connect (OSTI)

    Shaw, Raymond A.

    2014-10-28

    This project has been focused on the following objectives: 1. Investigations of the physical processes governing immersion versus contact nucleation, specifically surface-induced crystallization; 2. Development of a quadrupole particle trap with full thermodynamic control over the temperature range 0 to –40 °C and precisely controlled water vapor saturation ratios for continuous, single-particle measurement of the aerosol to ice crystal transformation process for realistic ice nuclei; 3. Understanding the role of ice nucleation in determining the microphysical properties of mixed-phase clouds, within a framework that allows bridging between laboratory and field measurements.

  5. Chemical distribution in high-solids paint overspray aerosols

    SciTech Connect (OSTI)

    D'Arcy, J.B.; Chan, T.L. )

    1990-03-01

    The chemical composition of high-solids basecoat paint overspray aerosols was determined as a function of particle size. Detailed information on the chemical composition of the overspray aerosols is important in health hazard evaluation since the composition and distribution within the airborne particles may differ significantly from the bulk paint material. This study was conducted in a typical down-draft paint booth equipped with air-atomized spray painting equipment. A fixed paint target was used to simulate typical overspray generation conditions and the aerosols were collected isokinetically with a seven-stage cascade impactor for size-fractionated analysis. The overspray aerosol from six paints consisted of organic paint binders with varying amounts of inorganic species as pigments or luster enhancers. These overspray aerosols had mass median aerodynamic diameters (MMAD) ranging from 2.9 to 9.7 microns. The size-fractionated paint samples collected on the impaction stages were analyzed by energy dispersive X-ray spectrometry on a scanning electron microscope (SEM-EDXRS) to identify the metallic elements. Atomic absorption spectrometry was used to determine the mass distribution of aluminum and iron as indicators of nonuniform distribution. Three of the aerosols containing aluminum were found to have bimodal distributions with most aluminum distributions having cumulative MMADs larger than the total aerosol. Iron in the aerosols was bimodal for three of the paints with all samples having an overall iron MMAD less than or equal to the overspray aerosol MMAD. Analysis using ultraviolet spectrometry revealed that the organic compounds present in the size-fractionated particulate samples consisted of a single, polydispersed mode with an MMAD similar to that of the total overspray aerosol.

  6. Seasonal and diurnal variations of submicron organic aerosol in Tokyo observed using the Aerodyne aerosol mass spectrometer

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    with carbon monoxide (CO) and fragments of aliphatic and oxygenated organic compounds in the AMS mass spectra. Combustion-related organic aerosol (combustion OA) is defined as the primary organic aerosol (POA) fraction the combustion OA and the background OA from the total OA. The combustion OA and excess OA show good correlation

  7. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newsom, Rob; Goldsmith, John

    1998-03-01

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  8. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  9. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2004-10-01

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  10. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  11. Investigation of Aerosol Sources, Lifetime and Radiative Forcing through Multi-Instrument Data Assimilation

    E-Print Network [OSTI]

    Rubin, Juli Irene

    2012-01-01

    of the various radiative mechanims associated with aerosolof the various radiative mechanims associated with aerosol

  12. Analysis of reflectance spectra of UV-absorbing aerosol scenes measured by SCIAMACHY

    E-Print Network [OSTI]

    Graaf, Martin de

    Analysis of reflectance spectra of UV-absorbing aerosol scenes measured by SCIAMACHY M. de Graaf,1 of reflectance spectra of UV-absorbing aerosol scenes measured by SCIAMACHY, J. Geophys. Res., 112, D02206, doi aerosol (DDA) and biomass burning aerosol (BBA) scenes over oceans are presented, measured by the space

  13. UNDERSTANDING THE INFLUENCES OF ATMOSPHERIC AEROSOLS ON CLIMATE AND CLIMATE CHANGE

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    remarks #12;DMS #12;AEROSOL IN MEXICO CITY BASIN #12;AEROSOL IN MEXICO CITY BASIN Light scattering by aerosols decreases absorption of solar radiation. #12;AEROSOLS AS SEEN FROM SPACE Fire plumes from southern Mexico transported north into Gulf of Mexico. #12;CLOUD BRIGHTENING BY SHIP TRACKS Satellite photo off

  14. Satellite observations of the seasonal cycles of absorbing aerosols in Africa

    E-Print Network [OSTI]

    Graaf, Martin de

    Satellite observations of the seasonal cycles of absorbing aerosols in Africa related to monsoon of aerosol emissions from the wet surface. 1. Introduction The main aerosol types occurring over Africa Africa can be characterized using Absorbing Aerosol Index (AAI) data from Global Ozone Monitoring

  15. A geostatistical data fusion technique for merging remote sensing and groundbased observations of aerosol optical thickness

    E-Print Network [OSTI]

    Michalak, Anna M.

    that aerosols contrib- ute significantly to reflected solar radiation (the aerosol direct effect) and modify of aerosols in climate and atmospheric chemistry. To date, however, there have been only limited attempts of the growing concentrations of CO2 and other greenhouse gases. Although the radiative forcing of aerosols

  16. ARM: 10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-second Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  17. ARM: 10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  18. ARM: 2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  19. ARM: 1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  20. Neutrino physics with an intense \

    E-Print Network [OSTI]

    R. Henning

    2010-11-16

    We study some of the physics potential of an intense $1\\,\\mathrm{MCi}$ $^{51}\\mathrm{Cr}$ source combined with the {\\sc Majorana Demonstrator} enriched germanium detector array. The {\\sc Demonstrator} will consist of detectors with ultra-low radioactive backgrounds and extremely low energy thresholds of~$\\sim 400\\,\\mathrm{eV}$. We show that it can improve the current limit on the neutrino magnetic dipole moment. We briefly discuss physics applications of the charged-current reaction of the $^{51}\\mathrm{Cr} neutrino with the $^{73}\\mathrm{Ge} isotope. Finally, we argue that the rate from a realistic, intense tritium source is below the detectable limit of even a tonne-scale HPGe experiment

  1. Effect of Terrestrial and Marine Organic Aerosol on Regional and Global Climate: Model Development, Application, and Verification with Satellite Data

    SciTech Connect (OSTI)

    Meskhidze, Nicholas; Zhang, Yang; Kamykowski, Daniel

    2012-03-28

    In this DOE project the improvements to parameterization of marine primary organic matter (POM) emissions, hygroscopic properties of marine POM, marine isoprene derived secondary organic aerosol (SOA) emissions, surfactant effects, new cloud droplet activation parameterization have been implemented into Community Atmosphere Model (CAM 5.0), with a seven mode aerosol module from the Pacific Northwest National Laboratory (PNNL)���¢��������s Modal Aerosol Model (MAM7). The effects of marine aerosols derived from sea spray and ocean emitted biogenic volatile organic compounds (BVOCs) on microphysical properties of clouds were explored by conducting 10 year CAM5.0-MAM7 model simulations at a grid resolution 1.9�������°��������2.5�������° with 30 vertical layers. Model-predicted relationship between ocean physical and biological systems and the abundance of CCN in remote marine atmosphere was compared to data from the A-Train satellites (MODIS, CALIPSO, AMSR-E). Model simulations show that on average, primary and secondary organic aerosol emissions from the ocean can yield up to 20% increase in Cloud Condensation Nuclei (CCN) at 0.2% Supersaturation, and up to 5% increases in droplet number concentration of global maritime shallow clouds. Marine organics were treated as internally or externally mixed with sea salt. Changes associated with cloud properties reduced (absolute value) the model-predicted short wave cloud forcing from -1.35 Wm-2 to -0.25 Wm-2. By using different emission scenarios, and droplet activation parameterizations, this study suggests that addition of marine primary aerosols and biologically generated reactive gases makes an important difference in radiative forcing assessments. All baseline and sensitivity simulations for 2001 and 2050 using global-through-urban WRF/Chem (GU-WRF) were completed. The main objective of these simulations was to evaluate the capability of GU-WRF for an accurate representation of the global atmosphere by exploring the most accurate configuration of physics options in GWRF for global scale modeling in 2001 at a horizontal grid resolution of 1�������° x 1�������°. GU-WRF model output was evaluated using observational datasets from a variety of sources including surface based observations (NCDC and BSRN), model reanalysis (NCEP/ NCAR Reanalysis and CMAP), and remotely-sensed data (TRMM) to evaluate the ability of GU-WRF to simulate atmospheric variables at the surface as well as aloft. Explicit treatment of nanoparticles produced from new particle formation in GU-WRF/Chem-MADRID was achieved by expanding particle size sections from 8 to 12 to cover particles with the size range of 1.16 nm to 11.6 �������µm. Simulations with two different nucleation parameterizations were conducted for August 2002 over a global domain at a 4�������º by 5�������º horizontal resolution. The results are evaluated against field measurement data from the 2002 Aerosol Nucleation and Real Time Characterization Experiment (ANARChE) in Atlanta, Georgia, as well as satellite and reanalysis data. We have also explored the relationship between ���¢��������clean marine���¢������� aerosol optical properties and ocean surface wind speed using remotely sensed data from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on board the CALIPSO satellite and the Advanced Microwave Scanning Radiometer (AMSR-E) on board the AQUA satellite. Detailed data analyses

  2. CARES Helps Explain Secondary Organic Aerosols

    ScienceCinema (OSTI)

    Zaveri, Rahul

    2014-06-02

    What happens when urban man-made pollution mixes with what we think of as pristine forest air? To know more about what this interaction means for the climate, the Carbonaceous Aerosol and Radiative Effects Study, or CARES, field campaign was designed in 2010. The sampling strategy during CARES was coordinated with CalNex 2010, another major field campaign that was planned in California in 2010 by the California Air Resources Board (CARB), the National Oceanic and Atmospheric Administration (NOAA), and the California Energy Commission (CEC). "We found two things. When urban pollution mixes with forest pollutions we get more secondary organic aerosols," said Rahul Zaveri, FCSD scientist and project lead on CARES. "SOAs are thought to be formed primarily from forest emissions but only when they interact with urban emissions. The data is saying that there will be climate cooling over the central California valley because of these interactions." Knowledge gained from detailed analyses of data gathered during the CARES campaign, together with laboratory experiments, is being used to improve existing climate models.

  3. Hyperspectral Aerosol Optical Depths from TCAP Flights

    SciTech Connect (OSTI)

    Shinozuka, Yohei; Johnson, Roy R.; Flynn, Connor J.; Russell, P. B.; Schmid, Beat; Redemann, Jens; Dunagan, Stephen; Kluzek, Celine D.; Hubbe, John M.; Segal-Rosenheimer, Michal; Livingston, J. M.; Eck, T.; Wagener, Richard; Gregory, L.; Chand, Duli; Berg, Larry K.; Rogers, Ray; Ferrare, R. A.; Hair, John; Hostetler, Chris A.; Burton, S. P.

    2013-11-13

    4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research), the world’s first hyperspectral airborne tracking sunphotometer, acquired aerosol optical depths (AOD) at 1 Hz during all July 2012 flights of the Two Column Aerosol Project (TCAP). Root-mean square differences from AERONET ground-based observations were 0.01 at wavelengths between 500-1020 nm, 0.02 at 380 and 1640 nm and 0.03 at 440 nm in four clear-sky fly-over events, and similar in ground side-by-side comparisons. Changes in the above-aircraft AOD across 3-km-deep spirals were typically consistent with integrals of coincident in situ (on DOE Gulfstream 1 with 4STAR) and lidar (on NASA B200) extinction measurements within 0.01, 0.03, 0.01, 0.02, 0.02, 0.02 at 355, 450, 532, 550, 700, 1064 nm, respectively, despite atmospheric variations and combined measurement uncertainties. Finer vertical differentials of the 4STAR measurements matched the in situ ambient extinction profile within 14% for one homogeneous column. For the AOD observed between 350-1660 nm, excluding strong water vapor and oxygen absorption bands, estimated uncertainties were ~0.01 and dominated by (then) unpredictable throughput changes, up to +/-0.8%, of the fiber optic rotary joint. The favorable intercomparisons herald 4STAR’s spatially-resolved high-frequency hyperspectral products as a reliable tool for climate studies and satellite validation.

  4. CARES Helps Explain Secondary Organic Aerosols

    SciTech Connect (OSTI)

    Zaveri, Rahul

    2014-03-28

    What happens when urban man-made pollution mixes with what we think of as pristine forest air? To know more about what this interaction means for the climate, the Carbonaceous Aerosol and Radiative Effects Study, or CARES, field campaign was designed in 2010. The sampling strategy during CARES was coordinated with CalNex 2010, another major field campaign that was planned in California in 2010 by the California Air Resources Board (CARB), the National Oceanic and Atmospheric Administration (NOAA), and the California Energy Commission (CEC). "We found two things. When urban pollution mixes with forest pollutions we get more secondary organic aerosols," said Rahul Zaveri, FCSD scientist and project lead on CARES. "SOAs are thought to be formed primarily from forest emissions but only when they interact with urban emissions. The data is saying that there will be climate cooling over the central California valley because of these interactions." Knowledge gained from detailed analyses of data gathered during the CARES campaign, together with laboratory experiments, is being used to improve existing climate models.

  5. Fire aerosol experiment and comparisons with computer code predictions

    SciTech Connect (OSTI)

    Gregory, W.S.; Nichols, B.D.; White, B.W.; Smith, P.R.; Leslie, I.H.; Corkran, J.R.

    1988-01-01

    Los Alamos National Laboratory, in cooperation with New Mexico State University, has carried on a series of tests to provide experimental data on fire-generated aerosol transport. These data will be used to verify the aerosol transport capabilities of the FIRAC computer code. FIRAC was developed by Los Alamos for the US Nuclear Regulatory Commission. It is intended to be used by safety analysts to evaluate the effects of hypothetical fires on nuclear plants. One of the most significant aspects of this analysis deals with smoke and radioactive material movement throughout the plant. The tests have been carried out using an industrial furnace that can generate gas temperatures to 300/degree/C. To date, we have used quartz aerosol with a median diameter of about 10 ..mu..m as the fire aerosol simulant. We also plan to use fire-generated aerosols of polystyrene and polymethyl methacrylate (PMMA). The test variables include two nominal gas flow rates (150 and 300 ft/sup 3//min) and three nominal gas temperatures (ambient, 150/degree/C, and 300/degree/C). The test results are presented in the form of plots of aerosol deposition vs length of duct. In addition, the mass of aerosol caught in a high-efficiency particulate air (HEPA) filter during the tests is reported. The tests are simulated with the FIRAC code, and the results are compared with the experimental data. 3 refs., 10 figs., 1 tab.

  6. GCM parameterization of radiative forcing by Pinatubo aerosols

    SciTech Connect (OSTI)

    Lacis, A.A.; Mishchenko, M.I.

    1996-12-31

    This paper addresses the question of whether the general circulation model (GCM) parameterization of volcanic aerosol forcing can be adequately described in terms of just two physical aerosol parameters: (1) the aerosol column optical thickness and (2) the effective radius of the aerosol size distribution. Data recorded from the eruption of Mt. Pinatubo in the Philippines in June 1991 was analyzed to attempt to answer this question. The spatial distribution of the particle size showed considerable variability and was found to increase steadily following the eruption. The time evolution of the Pinatubo aerosol particle size distribution as derived from satellite data differed significantly, particularly in the early phases of the eruption, from that assumed in the initial GCM simulation of the Pinatubo eruption. A bimodal distribution was used to examine the possibility that the actual size distribution of the volcanic aerosol was multimodal. However, results suggested that in most cases the aerosol size distribution was essentially monomodal in nature. Results from the radiative model used in the calculations are also presented. 11 refs., 6 figs.

  7. Model analysis of the anthropogenic aerosol effect on clouds over East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhang, Meigen; Liu, Xiaohong; Zhao, Chun

    2012-01-16

    A coupled meteorology and aerosol/chemistry model WRF-Chem (Weather Research and Forecast model coupled with Chemistry) was used to conduct a pair of simulations with present-day (PD) and preindustrial (PI) emissions over East Asia to examine the aerosol indirect effect on clouds. As a result of an increase in aerosols in January, the cloud droplet number increased by 650 cm{sup -3} over the ocean and East China, 400 cm{sup -3} over Central and Southwest China, and less than 200 cm{sup -3} over North China. The cloud liquid water path (LWP) increased by 40-60 g m{sup -2} over the ocean and Southeast China and 30 g m{sup -2} over Central China; the LWP increased less than 5 g m{sup -2} or decreased by 5 g m{sup -2} over North China. The effective radius (Re) decreased by more than 4 {mu}m over Southwest, Central, and Southeast China and 2 {mu}m over North China. In July, variations in cloud properties were more uniform; the cloud droplet number increased by approximately 250-400 cm{sup -3}, the LWP increased by approximately 30-50 g m{sup -2}, and Re decreased by approximately 3 {mu}m over most regions of China. In response to cloud property changes from PI to PD, shortwave (SW) cloud radiative forcing strengthened by 30 W m{sup -2} over the ocean and 10 W m{sup -2} over Southeast China, and it weakened slightly by approximately 2-10 W m{sup -2} over Central and Southwest China in January. In July, SW cloud radiative forcing strengthened by 15 W m{sup -2} over Southeast and North China and weakened by 10 W m{sup -2} over Central China. The different responses of SW cloud radiative forcing in different regions was related to cloud feedbacks and natural variability.

  8. Excitation-emission spectra and fluorescence quantum yields for fresh and aged biogenic secondary organic aerosols

    SciTech Connect (OSTI)

    Lee, Hyun Ji; Laskin, Alexander; Laskin, Julia; Nizkorodov, Sergey A.

    2013-05-10

    Certain biogenic secondary organic aerosols (SOA) become absorbent and fluorescent when exposed to reduced nitrogen compounds such as ammonia, amines and their salts. Fluorescent SOA may potentially be mistaken for biological particles by detection methods relying on fluorescence. This work quantifies the spectral distribution and effective quantum yields of fluorescence of SOA generated from two monoterpenes, limonene and a-pinene, and two different oxidants, ozone (O3) and hydroxyl radical (OH). The SOA was generated in a smog chamber, collected on substrates, and aged by exposure to ~100 ppb ammonia vapor in air saturated with water vapor. Absorption and excitation-emission matrix (EEM) spectra of aqueous extracts of aged and control SOA samples were measured, and the effective absorption coefficients and fluorescence quantum yields (~0.005 for 349 nm excitation) were determined from the data. The strongest fluorescence for the limonene-derived SOA was observed for excitation = 420+- 50 nm and emission = 475 +- 38 nm. The window of the strongest fluorescence shifted to excitation = 320 +- 25 nm and emission = 425 +- 38 nm for the a-pinene-derived SOA. Both regions overlap with the excitation-emission matrix (EEM) spectra of some of the fluorophores found in primary biological aerosols. Our study suggests that, despite the low quantum yield, the aged SOA particles should have sufficient fluorescence intensities to interfere with the fluorescence detection of common bioaerosols.

  9. Aerosol penetration through a seismically loaded shear wall

    SciTech Connect (OSTI)

    Farrar, C.R.; Girrens, S.P.

    1992-05-01

    An experimental study was performed to measure the aerosol penetration through a reinforced concrete shear wall after simulated seismic damage. Static load-cycle testing, to stress levels sufficient to induce visible shear cracking, was used to simulate the earthquake loading. Air permeability tests were performed both before and after the simulated seismic loading damaged the structure. Aerosol penetration measurements were conducted on the cracked shear wall structure using 0.10 {mu}m monodisperse particles. The measured aerosol number penetration through the cracked shear wall was 0.5%. 7 refs.

  10. Aerosol penetration through a seismically loaded shear wall

    SciTech Connect (OSTI)

    Farrar, C.R.; Girrens, S.P.

    1992-01-01

    An experimental study was performed to measure the aerosol penetration through a reinforced concrete shear wall after simulated seismic damage. Static load-cycle testing, to stress levels sufficient to induce visible shear cracking, was used to simulate the earthquake loading. Air permeability tests were performed both before and after the simulated seismic loading damaged the structure. Aerosol penetration measurements were conducted on the cracked shear wall structure using 0.10 {mu}m monodisperse particles. The measured aerosol number penetration through the cracked shear wall was 0.5%. 7 refs.

  11. Aerosol source term in high pressure melt ejection

    SciTech Connect (OSTI)

    Brockmann, J.E.; Tarbell, W.W.

    1984-11-01

    Pressurized ejection of melt from a reactor pressure vessel has been identified as an important element of a severe reactor accident. Copious aerosol production is observed when thermitically generated melts pressurized with nitrogen or carbon dioxide to 1.3 to 17 MPa are ejected into an air atmosphere. Aerosol particle size distributions measured in the tests have modes of about 0.5, 5, and > 10 ..mu..m. Mechanisms leading to formation of these multimodal size distributions are suggested. This aerosol is a potentially important fission product source term that has not been considered in previous severe accident analyses.

  12. High Intensity Polarized Electron Gun

    SciTech Connect (OSTI)

    Redwine, Robert P.

    2012-07-31

    The goal of the project was to investigate the possibility of building a very high intensity polarized electron gun for the Electron-Ion Collider. This development is crucial for the eRHIC project. The gun implements a large area cathode, ring-shaped laser beam and active cathode cooling. A polarized electron gun chamber with a large area cathode and active cathode cooling has been built and tested. A preparation chamber for cathode activation has been built and initial tests have been performed. Major parts for a load-lock chamber, where cathodes are loaded into the vacuum system, have been manufactured.

  13. Mexico City Aerosol Analysis During Milagro Using High Resolution Aerosol Mass Spectrometry at the Urban Supersite (T0) - Part 1: Fine Particle Composition and Organic Source Apportionment.

    E-Print Network [OSTI]

    Aiken, A. C.

    Submicron aerosol was analyzed during the MILAGRO field campaign in March 2006 at the T0 urban supersite in Mexico City with a High-Resolution Aerosol Mass Spectrometer (AMS) and complementary instrumentation. Positive ...

  14. Aerosol mass spectrometry systems and methods

    DOE Patents [OSTI]

    Fergenson, David P.; Gard, Eric E.

    2013-08-20

    A system according to one embodiment includes a particle accelerator that directs a succession of polydisperse aerosol particles along a predetermined particle path; multiple tracking lasers for generating beams of light across the particle path; an optical detector positioned adjacent the particle path for detecting impingement of the beams of light on individual particles; a desorption laser for generating a beam of desorbing light across the particle path about coaxial with a beam of light produced by one of the tracking lasers; and a controller, responsive to detection of a signal produced by the optical detector, that controls the desorption laser to generate the beam of desorbing light. Additional systems and methods are also disclosed.

  15. Diesel Aerosol Sampling in the Atmosphere

    SciTech Connect (OSTI)

    David Kittelson; Jason Johnson; Winthrop Watts; Qiang Wei; Marcus Drayton; Dwane Paulsen; Nicolas Bukowiecki

    2000-06-19

    The University of Minnesota Center for Diesel Research along with a research team including Caterpillar, Cummins, Carnegie Mellon University, West Virginia University (WVU), Paul Scherrer Institute in Switzerland, and Tampere University in Finland have performed measurements of Diesel exhaust particle size distributions under real-world dilution conditions. A mobile aerosol emission laboratory (MEL) equipped to measure particle size distributions, number concentrations, surface area concentrations, particle bound PAHs, as well as CO 2 and NO x concentrations in real time was built and will be described. The MEL was used to follow two different Cummins powered tractors, one with an older engine (L10) and one with a state-of-the-art engine (ISM), on rural highways and measure particles in their exhaust plumes. This paper will describe the goals and objectives of the study and will describe representative particle size distributions observed in roadway experiments with the truck powered by the ISM engine.

  16. Building America Case Study: Apartment Compartmentalization with an Aerosol-Based Sealing Process - Queens, NY; Technology Solutions for New and Existing Homes, Energy Efficiency & Renewable Energy (EERE)

    SciTech Connect (OSTI)

    2015-07-01

    Air sealing of building enclosures is a difficult and time-consuming process. Current methods in new construction require laborers to physically locate small and sometimes large holes in multiple assemblies and then manually seal each of them. The innovation demonstrated under this research study was the automated air sealing and compartmentalization of buildings through the use of an aerosolized sealant, developed by the Western Cooling Efficiency Center at University of California Davis.
    CARB sought to demonstrate this new technology application in a multifamily building in Queens, NY. The effectiveness of the sealing process was evaluated by three methods: air leakage testing of overall apartment before and after sealing, point-source testing of individual leaks, and pressure measurements in the walls of the target apartment during sealing. Aerosolized sealing was successful by several measures in this study. Many individual leaks that are labor-intensive to address separately were well sealed by the aerosol particles. In addition, many diffuse leaks that are difficult to identify and treat were also sealed. The aerosol-based sealing process resulted in an average reduction of 71% in air leakage across three apartments and an average apartment airtightness of 0.08 CFM50/SF of enclosure area.

  17. Observational Insights into Aerosol Formation from Isoprene David R. Worton,*,,

    E-Print Network [OSTI]

    Goldstein, Allen

    , Ronald C. Cohen, John H. Seinfeld, and Allen H. Goldstein,$ Department of Environmental Science, Policy and Management, Department of Chemistry, University of California, Berkeley, California 94720, United States Aerosol Dynamics Inc., Berkeley, California 94710, United States § Department of Environmental Sciences

  18. A review of Secondary Organic Aerosol (SOA) formation from isoprene

    E-Print Network [OSTI]

    Kroll, Jesse

    Recent field and laboratory evidence indicates that the oxidation of isoprene, (2-methyl-1,3-butadiene, C[subscript 5]H[subscript 8]) forms secondary organic aerosol (SOA). Global biogenic emissions of isoprene (600 Tg ...

  19. Toward a Minimal Representation of Aerosols in Climate Models...

    Office of Scientific and Technical Information (OSTI)

    carbon (BC) with other aerosol components, merging of the MAM7 fine dust and fine sea salt modes into the accumulation mode, merging of the MAM7 coarse dust and coarse sea salt...

  20. Aerosol Optical Depth Value-Added Product Report

    SciTech Connect (OSTI)

    Koontz, A; Hodges, G; Barnard, J; Flynn, C; Michalsky, J

    2013-03-17

    This document describes the process applied to retrieve aerosol optical depth (AOD) from multifilter rotating shadowband radiometers (MFRSR) and normal incidence multifilter radiometers (NIMFR) operated at the ARM Climate Research Facility’s ground-based facilities.

  1. ris-r-1075(en) Quantitative Measurement of Aerosol

    E-Print Network [OSTI]

    and implications of deposition of potentially hazardous aerosol directly onto hu- mans. This state, beta doses from skin deposition to individuals in areas of Russia, where dry deposition of Chernobyl

  2. Experimental and numerical studies of aerosol penetration through screens 

    E-Print Network [OSTI]

    Han, Tae Won

    2009-05-15

    for one particular type of screen would collapse to a single curve if the collection efficiency is expressed in terms of non-dimensional parameters. Correlations characterizing the aerosol deposition process on different types of screens were developed...

  3. Aerosol-Cloud interactions : a new perspective in precipitation enhancement

    E-Print Network [OSTI]

    Gunturu, Udaya Bhaskar

    2010-01-01

    Increased industrialization and human activity modified the atmospheric aerosol composition and size-distribution during the last several decades. This has affected the structure and evolution of clouds, and precipitation ...

  4. Aerosol optical hygroscopicity measurements during the 2010 CARES campaign

    E-Print Network [OSTI]

    Atkinson, D. B.

    Measurements of the effect of water uptake on particulate light extinction or scattering made at two locations during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) study around Sacramento, CA are ...

  5. On the relationship between stratospheric aerosols and nitrogen dioxide

    SciTech Connect (OSTI)

    Mills, M.J.; Langford, A.O.; O'Leary, T.J.; Arpag, K.; Miller, H.L.; Proffitt, M.H.; Sanders, R.W.; Solomon, S. (Aeronomy Laboratory, NOAA, Boulder, CO (United States) Univ. of Colorado, Boulder (United States))

    1993-06-18

    The authors report measurements of stratospheric column abundances of nitrogen dioxide above the Colorado mountains during Jan, Feb, and Mar 1992, following the arrival of the aerosol loading injected by Mt. Pinatubo. The column abundance data was correlated with concurrent lidar measurements which provided vertical aerosol profiles at the same site. Chemical reactions within polar stratospheric clouds have been shown to play a major role in ozone chemistry in the polar regions, and one could ask whether such clouds at mid latitudes could play a similar role. The sulfur dioxide loading due to the volcanic eruption provides an abrupt increase in sulfuric acid aerosol surface area in mid latitude areas, providing a convenient test of this question. Column NO[sub 2] densities are observed to fall, but also found to saturate at a certain stratospheric aerosol density.

  6. Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides

    E-Print Network [OSTI]

    Kharol, S. K.

    We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

  7. REPRESENTING AEROSOLS IN GLOBAL MODELS: FROM MICROMETERS TO MEGAMETERS

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    mainly from gas-to- particle conversion of low-volatility gaseous species, mainly sulfuric acid to represent aerosol processes and forcing "on-line" in climate models in order to capture the feedbacks

  8. The Statistical Evolution of Multiple Generations of Oxidation Products in the Photochemical Aging of Chemically Reduced Organic Aerosol

    SciTech Connect (OSTI)

    Wilson, Kevin R.; Smith, Jared D.; Kessler, Sean; Kroll, Jesse H.

    2011-10-03

    The heterogeneous reaction of hydroxyl radicals (OH) with squalane and bis(2-ethylhexyl) sebacate (BES) particles are used as model systems to examine how distributions of reactionproducts evolve during the oxidation of chemically reduced organic aerosol. A kinetic model of multigenerational chemistry, which is compared to previously measured (squalane) and new(BES) experimental data, reveals that it is the statistical mixtures of different generations of oxidation products that control the average particle mass and elemental composition during thereaction. The model suggests that more highly oxidized reaction products, although initially formed with low probability, play a large role in the production of gas phase reaction products.In general, these results highlight the importance of considering atmospheric oxidation as a statistical process, further suggesting that the underlying distribution of molecules could playimportant roles in aerosol formation as well as in the evolution of key physicochemical properties such as volatility and hygroscopicity.

  9. Experimental transport of intensity diffraction tomography

    E-Print Network [OSTI]

    Lee, Justin Wu

    2011-01-01

    In this thesis, I perform intensity-based tomographic phase imaging in two ways. First, I utilize the paraxial transport of intensity equation (TIE) to construct phase maps of a phase object at multiple projection angles ...

  10. Control Intensive Planning Planet 2003 Summer School

    E-Print Network [OSTI]

    Bacchus, Fahiem

    in efficiency. Why not utilize that knowledge! Control Intensive Planning/F. Bacchus ­ p.2/131 #12;Goals Control Intensive planning involves finding ways to build and utilize richer domain models so as to support more utilize Forward Chaining. B C A C C A B A B pickup(A) unstack(B) Control Intensive Planning/F. Bacchus ­ p

  11. On modification of global warming by sulfate aerosols

    SciTech Connect (OSTI)

    Mitchell, J.F.B.; Johns, T.C.

    1997-02-01

    There is increasing evidence that the response of climate to increasing greenhouse gases may be modified by accompanying increases in sulfate aerosols. In this study, the patterns of response in the surface climatology of a coupled ocean-atmosphere general circulation model forced by increases in carbon dioxide alone is compared with those obtained by increasing carbon dioxide and aerosol forcing. The simulations are run from early industrial times using the estimated historical forcing and continued to the end of the twenty-first century assuming a nonintervention emissions scenario for greenhouse gases and aerosols. The comparison is made for the period 2030-2050 when the aerosol forcing is a maximum. In winter, the cooling due to aerosols merely tends to reduce the response to carbon dioxide, whereas in summer, it weakens the monsoon circulations and reverses some of the changes in the hydrological cycle on increasing carbon dioxide. This response is in some respects similar to that found in simulations with changed orbital parameters, as between today and the middle Holocene. The hydrological response in the palaeosimulations is supported by palaeoclimatic reconstructions. The results of changes in aerosol concentrations of the magnetic projected in the scenarios would have a major effect on regional climate, especially over Europe and Southeast Asia. 74 refs., 12 figs., 6 tabs.

  12. Investigations of cloud altering effects of atmospheric aerosols using a new mixed Eulerian-Lagrangian aerosol model

    E-Print Network [OSTI]

    Steele, Henry Donnan, 1974-

    2004-01-01

    Industry, urban development, and other anthropogenic influences have substantially altered the composition and size-distribution of atmospheric aerosol particles over the last century. This, in turn, has altered cloud ...

  13. Climatic effects of 1950–2050 changes in US anthropogenic aerosols – Part 1: Aerosol trends and radiative forcing

    E-Print Network [OSTI]

    Leibensperger, Eric Michael

    We use the GEOS-Chem chemical transport model combined with the GISS general circulation model to calculate the aerosol direct and indirect (warm cloud) radiative forcings from US anthropogenic sources over the 1950–2050 ...

  14. Beam intensity upgrade at Fermilab

    SciTech Connect (OSTI)

    Marchionni, A.; /Fermilab

    2006-07-01

    The performance of the Fermilab proton accelerator complex is reviewed. The coming into operation of the NuMI neutrino line and the implementation of slip-stacking to increase the anti-proton production rate has pushed the total beam intensity in the Main Injector up to {approx} 3 x 10{sup 13} protons/pulse. A maximum beam power of 270 kW has been delivered on the NuMI target during the first year of operation. A plan is in place to increase it to 350 kW, in parallel with the operation of the Collider program. As more machines of the Fermilab complex become available with the termination of the Collider operation, a set of upgrades are being planned to reach first 700 kW and then 1.2 MW by reducing the Main Injector cycle time and by implementing proton stacking.

  15. Use of the ARM Measurements of Spectral Zenith Radiance for Better Understanding of 3D Cloud-Radiation Processes & Aerosol-Cloud Interaction

    SciTech Connect (OSTI)

    Alexander Marshak; Warren Wiscombe; Yuri Knyazikhin; Christine Chiu

    2011-05-24

    We proposed a variety of tasks centered on the following question: what can we learn about 3D cloud-radiation processes and aerosol-cloud interaction from rapid-sampling ARM measurements of spectral zenith radiance? These ARM measurements offer spectacular new and largely unexploited capabilities in both the temporal and spectral domains. Unlike most other ARM instruments, which average over many seconds or take samples many seconds apart, the new spectral zenith radiance measurements are fast enough to resolve natural time scales of cloud change and cloud boundaries as well as the transition zone between cloudy and clear areas. In the case of the shortwave spectrometer, the measurements offer high time resolution and high spectral resolution, allowing new discovery-oriented science which we intend to pursue vigorously. Research objectives are, for convenience, grouped under three themes: â?˘ Understand radiative signature of the transition zone between cloud-free and cloudy areas using data from ARM shortwave radiometers, which has major climatic consequences in both aerosol direct and indirect effect studies. â?˘ Provide cloud property retrievals from the ARM sites and the ARM Mobile Facility for studies of aerosol-cloud interactions. â?˘ Assess impact of 3D cloud structures on aerosol properties using passive and active remote sensing techniques from both ARM and satellite measurements.

  16. Ganges Valley Aerosol Experiment: Science and Operations Plan

    SciTech Connect (OSTI)

    Kotamarthi, VR

    2010-06-21

    The Ganges Valley region is one of the largest and most rapidly developing sections of the Indian subcontinent. The Ganges River, which provides the region with water needed for sustaining life, is fed primarily by snow and rainfall associated with Indian summer monsoons. Impacts of changes in precipitation patterns, temperature, and the flow of the snow-fed rivers can be immense. Recent satellite-based measurements have indicated that the upper Ganges Valley has some of the highest persistently observed aerosol optical depth values. The aerosol layer covers a vast region, extending across the Indo-Gangetic Plain to the Bay of Bengal during the winter and early spring of each year. The persistent winter fog in the region is already a cause of much concern, and several studies have been proposed to understand the economic, scientific, and societal dimensions of this problem. During the INDian Ocean EXperiment (INDOEX) field studies, aerosols from this region were shown to affect cloud formation and monsoon activity over the Indian Ocean. This is one of the few regions showing a trend toward increasing surface dimming and enhanced mid-tropospheric warming. Increasing air pollution over this region could modify the radiative balance through direct, indirect, and semi-indirect effects associated with aerosols. The consequences of aerosols and associated pollution for surface insolation over the Ganges Valley and monsoons, in particular, are not well understood. The proposed field study is designed for use of (1) the ARM Mobile Facility (AMF) to measure relevant radiative, cloud, convection, and aerosol optical characteristics over mainland India during an extended period of 9–12 months and (2) the G-1 aircraft and surface sites to measure relevant aerosol chemical, physical, and optical characteristics in the Ganges Valley during a period of 6–12 weeks. The aerosols in this region have complex sources, including burning of coal, biomass, and biofuels; automobile emissions; and dust. The extended AMF deployment will enable measurements under different regimes of the climate and aerosol abundance—in the wet monsoon period with low aerosol loading; in the dry, hot summer with aerosols dispersed throughout the atmospheric column; and in the cool, dry winter with aerosols confined mostly to the boundary later and mid-troposphere. Each regime, in addition, has its own distinct radiative and atmospheric dynamic drivers. The aircraft operational phase will assist in characterizing the aerosols at times when they have been observed to be at the highest concentrations. A number of agencies in India will collaborate with the proposed field study and provide support in terms of planning, aircraft measurements, and surface sites. The high concentration of aerosols in the upper Ganges Valley, together with hypotheses involving several possible mechanisms with direct impacts on the hydrologic cycle of the region, gives us a unique opportunity to generate data sets that will be useful both in understanding the processes at work and in providing answers regarding the effects of aerosols on climate in a region where the perturbation is the highest.

  17. An Aerosol Condensation Model for Sulfur Trioxide

    SciTech Connect (OSTI)

    Grant, K E

    2008-02-07

    This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

  18. Aerosol specification in single-column CAM5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lebassi-Habtezion, B.; Caldwell, P.

    2014-11-17

    The ability to run a global climate model in single-column mode is very useful for testing model improvements because single-column models (SCMs) are inexpensive to run and easy to interpret. A major breakthrough in Version 5 of the Community Atmosphere Model (CAM5) is the inclusion of prognostic aerosol. Unfortunately, this improvement was not coordinated with the SCM version of CAM5 and as a result CAM5-SCM initializes aerosols to zero. In this study we explore the impact of running CAM5-SCM with aerosol initialized to zero (hereafter named Default) and test three potential fixes. The first fix is to use CAM5'smore »prescribed aerosol capability, which specifies aerosols at monthly climatological values. The second method is to prescribe aerosols at observed values. The third approach is to fix droplet and ice crystal numbers at prescribed values. We test our fixes in four different cloud regimes to ensure representativeness: subtropical drizzling stratocumulus (based on the DYCOMS RF02 case study), mixed-phase Arctic stratocumulus (using the MPACE-B case study), tropical shallow convection (using the RICO case study), and summertime mid-latitude continental convection (using the ARM95 case study). Stratiform cloud cases (DYCOMS RF02 and MPACE-B) were found to have a strong dependence on aerosol concentration, while convective cases (RICO and ARM95) were relatively insensitive to aerosol specification. This is perhaps expected because convective schemes in CAM5 do not currently use aerosol information. Adequate liquid water content in the MPACE-B case was only maintained when ice crystal number concentration was specified because the Meyers et al. (1992) deposition/condensation ice nucleation scheme used by CAM5 greatly overpredicts ice nucleation rates, causing clouds to rapidly glaciate. Surprisingly, predicted droplet concentrations for the ARM95 region in both SCM and global runs were around 25 cm?3, which is much lower than observed. This finding suggests that CAM5 has problems capturing aerosol effects in this climate regime.« less

  19. Spent fuel sabotage aerosol test program :FY 2005-06 testing and aerosol data summary.

    SciTech Connect (OSTI)

    Gregson, Michael Warren; Brockmann, John E.; Nolte, O. (Fraunhofer institut fur toxikologie und experimentelle Medizin, Germany); Loiseau, O. (Institut de radioprotection et de Surete Nucleaire, France); Koch, W. (Fraunhofer institut fur toxikologie und experimentelle Medizin, Germany); Molecke, Martin Alan; Autrusson, Bruno (Institut de radioprotection et de Surete Nucleaire, France); Pretzsch, Gunter Guido (Gesellschaft fur anlagen- und Reaktorsicherheit, Germany); Billone, M. C. (Argonne National Laboratory, USA); Lucero, Daniel A.; Burtseva, T. (Argonne National Laboratory, USA); Brucher, W (Gesellschaft fur anlagen- und Reaktorsicherheit, Germany); Steyskal, Michele D.

    2006-10-01

    This multinational, multi-phase spent fuel sabotage test program is quantifying the aerosol particles produced when the products of a high energy density device (HEDD) interact with and explosively particulate test rodlets that contain pellets of either surrogate materials or actual spent fuel. This program has been underway for several years. This program provides source-term data that are relevant to some sabotage scenarios in relation to spent fuel transport and storage casks, and associated risk assessments. This document focuses on an updated description of the test program and test components for all work and plans made, or revised, primarily during FY 2005 and about the first two-thirds of FY 2006. It also serves as a program status report as of the end of May 2006. We provide details on the significant findings on aerosol results and observations from the recently completed Phase 2 surrogate material tests using cerium oxide ceramic pellets in test rodlets plus non-radioactive fission product dopants. Results include: respirable fractions produced; amounts, nuclide content, and produced particle size distributions and morphology; status on determination of the spent fuel ratio, SFR (the ratio of respirable particles from real spent fuel/respirables from surrogate spent fuel, measured under closely matched test conditions, in a contained test chamber); and, measurements of enhanced volatile fission product species sorption onto respirable particles. We discuss progress and results for the first three, recently performed Phase 3 tests using depleted uranium oxide, DUO{sub 2}, test rodlets. We will also review the status of preparations and the final Phase 4 tests in this program, using short rodlets containing actual spent fuel from U.S. PWR reactors, with both high- and lower-burnup fuel. These data plus testing results and design are tailored to support and guide, follow-on computer modeling of aerosol dispersal hazards and radiological consequence assessments. This spent fuel sabotage--aerosol test program, performed primarily at Sandia National Laboratories, with support provided by both the U.S. Department of Energy and the Nuclear Regulatory Commission, had significant inputs from, and is strongly supported and coordinated by both the U.S. and international program participants in Germany, France, and the U.K., as part of the international Working Group for Sabotage Concerns of Transport and Storage Casks, WGSTSC.

  20. Large Enhancement in the Heterogeneous Oxidation Rate of Organic Aerosols by Hydroxyl Radicals in the Presence of Nitric Oxide.

    E-Print Network [OSTI]

    Richards-Henderson, NK; Goldstein, AH; Wilson, KR

    2015-01-01

    Heterogeneous Reaction of Hydroxyl Radicals with Sub-Micronof Organic Aerosols by Hydroxyl Radicals in the Presence ofin an aerosol exposed to hydroxyl radicals (OH) is thought

  1. Intensive Observation Period Projects Scheduled

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLANIs gravityIntellectual PropertyEnergyAdvisor XESpring1

  2. ENCAPSULATION EFFECTS ON CARBONACEOUS AEROSOL LIGHT ABSORPTION

    E-Print Network [OSTI]

    of interest, soot, exhibits complex aging behavior that alters its optical properties. The consequences, wood-burning kitchen stoves, and coal-fired power plants) will increase black carbon (BC) radiative optical properties on particle mixing state and aggregate morphology, each of which changes

  3. Explosive photodissociation of methane induced by ultrafast intense laser

    SciTech Connect (OSTI)

    Kong Fanao; Luo Qi; Xu Huailiang; Sharifi, Mehdi; Song Di; Chin, See Leang

    2006-10-07

    A new type of molecular fragmentation induced by femtosecond intense laser at the intensity of 2x10{sup 14} W/cm{sup 2} is reported. For the parent molecule of methane, ethylene, n-butane, and 1-butene, fluorescence from H (n=3{yields}2), CH (A {sup 2}{delta}, B {sup 2}{sigma}{sup -}, and C {sup 2}{sigma}{sup +}{yields}X {sup 2}{pi}), or C{sub 2} (d {sup 3}{pi}{sub g}{yields}a {sup 3}{pi}{sub u}) is observed in the spectrum. It shows that the fragmentation is a universal property of neutral molecule in the intense laser field. Unlike breaking only one or two chemical bonds in conventional UV photodissociation, the fragmentation caused by the intense laser undergoes vigorous changes, breaking most of the bonds in the molecule, like an explosion. The fragments are neutral species and cannot be produced through Coulomb explosion of multiply charged ion. The laser power dependence of CH (A{yields}X) emission of methane on a log-log scale has a slope of 10{+-}1. The fragmentation is thus explained as multiple channel dissociation of the superexcited state of parent molecule, which is created by multiphoton excitation.

  4. Mechanisms of aerosol-forced AMOC variability in a state of the art climate model

    E-Print Network [OSTI]

    with a new state-of-the-art Earth system model. Anthropogenic aerosols have previously been highlighted anthropogenic aerosols force a strengthening of the AMOC by up to 20% in our state-of-the-art Earth system model

  5. Investigation of the aerosol-cloud interaction using the WRF framework 

    E-Print Network [OSTI]

    Li, Guohui

    2009-05-15

    In this dissertation, a two-moment bulk microphysical scheme with aerosol effects is developed and implemented into the Weather Research and Forecasting (WRF) model to investigate the aerosol-cloud interaction. Sensitivities ...

  6. CHASER: An Innovative Satellite Mission Concept to Measure the Effects of Aerosols on Clouds and Climate

    E-Print Network [OSTI]

    Rosenfeld, Daniel

    The formation of cloud droplets on aerosol particles, technically known as the activation of cloud condensation nuclei (CCN), is the fundamental process driving the interactions of aerosols with clouds and precipitation. ...

  7. Secondary organic aerosol formation from fossil fuel sources contribute majority of summertime organic mass at Bakersfield

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Secondary organic aerosol formation from fossil fuel sources contribute majority of summertime organic aerosol formation from fossil fuel sources contribute majority of summertime organic mass is fossil fuel combustion from gasoline- and diesel- powered vehicles and other industrial activities (e

  8. Computational fluid dynamics (CFD) simulations of aerosol in a u-shaped steam generator tube 

    E-Print Network [OSTI]

    Longmire, Pamela

    2009-05-15

    To quantify primary side aerosol retention, an Eulerian/Lagrangian approach was used to investigate aerosol transport in a compressible, turbulent, adiabatic, internal, wall-bounded flow. The ARTIST experimental project ...

  9. Variablity among electronic cigarettes in the pressure drop, airflow rate, and aerosol production

    E-Print Network [OSTI]

    Talbot, Prue

    2013-01-01

    on the Ruyan e-cigarette cartridge and inhaled aerosol (pp.drop, length of time cartridges lasted, and production ofdevice that aerosolizes cartridge fluid which is in turn

  10. Variability of aerosol parameters over Kanpur, northern India R. P. Singh,1

    E-Print Network [OSTI]

    Singh, Ramesh P.

    Variability of aerosol parameters over Kanpur, northern India R. P. Singh,1 Sagnik Dey, S. N Dynamics: Remote sensing; KEYWORDS: aerosol, remote sensing, Ganga basin Citation: Singh, R. P., S. Dey, S

  11. The impact of pathological ventilation on aerosol deposition : imaging, insight and intervention

    E-Print Network [OSTI]

    Greenblatt, Elliot (Elliot Eliyahu)

    2015-01-01

    Aerosol therapies are often used to treat lung diseases in which ventilation is distributed heterogeneously throughout the lung. As therapeutic aerosols are transported by the inhaled air, it is likely that deposition is ...

  12. Climate effects of seasonally varying Biomass Burning emitted Carbonaceous Aerosols (BBCA)

    E-Print Network [OSTI]

    Jeong, Gill-Ran

    The climate impact of the seasonality of Biomass Burning emitted Carbonaceous Aerosols (BBCA) is studied using an aerosol-climate model coupled with a slab ocean model in a set of 60-year long simulations, driven by BBCA ...

  13. Characterization of Fe–Cr alloy metallic interconnects coated with LSMO using the aerosol deposition process

    SciTech Connect (OSTI)

    Huang, Jian-Jia [Department of Mechanical Engineering, National Central University, Jhongli, Taoyuan, Taiwan (China); Fu, Yen-Pei, E-mail: ypfu@mail.ndhu.edu.tw [Department of Materials Science and Engineering, National Dong Hwa University, Shoufeng, Hualien, Taiwan (China); Wang, Jian-Yih [Department of Materials Science and Engineering, National Dong Hwa University, Shoufeng, Hualien, Taiwan (China); Cheng, Yung-Neng [Institute of Nuclear Energy Research, Longtan, Taoyuan, Taiwan (China); Lee, Shyong [Department of Mechanical Engineering, National Central University, Jhongli, Taoyuan, Taiwan (China); Hsu, Jin-Cherng [Department of Physics, Fu Jen Catholic University, Xinzhuang, New Taipei City, Taiwan (China)

    2014-03-01

    Graphical abstract: - Highlights: • Lanthanum strontium manganite (LSMO) as the protective layer for metallic interconnects was successfully prepared by aerosol deposition method (AD). • The microstructure, electrical resistance and composition for LSMO-coated Fe–Cr alloys undergoing high temperature, long-hour oxidation were investigated. • The denser protective layer prepared by AD might effectively prohibit the growth of oxidized scale after long time running at 800 °C in air. - Abstract: A Fe–Cr alloy, used for metallic interconnects, was coated with a protective layer of lanthanum strontium manganite (LSMO) using the aerosol deposition method (AD). The effects of the LSMO protective layer, which was coated on the Fe–Cr interconnects using AD, on the area specific resistance (ASR) during high temperature oxidation and the Cr evaporation behaviors were systematically investigated in this paper. The microstructures, morphologies, and compositions of the oxidized scales that appeared on the LSMO-coated Fe–Cr alloy after annealing at 800 °C for 750 h in air were examined using SEM equipped with EDS. The EPMA mapping of the LSMO-coated Fe–Cr interconnects undergoing long term, high-temperature oxidation was used to explain the formation layers of the oxidized scale, which consists of (Mn,Cr){sub 3}O{sub 4} and Cr{sub 2}O{sub 3} layers. Moreover, the experimental results revealed that the AD process is a potential method for preparing denser protective layers with highly desirable electrical properties for metallic interconnects.

  14. Transport of anthropogenic and biomass burning aerosols from Europe to the Arctic during spring 2008

    SciTech Connect (OSTI)

    Marelle, L.; Raut, Jean-Christophe; Thomas, J. L.; Law, K. S.; Quennehen, Boris; Ancellet, G.; Pelon, J.; Schwarzenboeck, A.; Fast, Jerome D.

    2015-04-10

    During the POLARCAT-France airborne campaign in April 2008, pollution originating from anthropogenic and biomass burning emissions was measured in the European Arctic. We compare these aircraft measurements with simulations using the WRF-Chem model to investigate model representation of aerosols transported from Europe to the Arctic. Modeled PM2.5 is evaluated using European Monitoring and Evaluation Programme (EMEP) measurements in source regions and POLARCAT aircraft measurements in the Scandinavian Arctic. Total PM2.5 agrees well with the measurements, although the model overestimates nitrate and underestimates organic carbon in source regions. Using WRF-Chem in combination with the Lagrangian model FLEXPART-WRF, we find that during the campaign the research aircraft sampled two different types of European plumes: mixed anthropogenic and fire plumes from eastern Europe and Russia transported below 2 km, and anthropogenic plumes from central Europe uplifted by warm conveyor belt circulations to 5–6 km. Both modeled plume types had undergone significant wet scavenging (> 50% PM10) during transport. Modeled aerosol vertical distributions and optical properties below the aircraft are evaluated in the Arctic using airborne lidar measurements. Model results show that the pollution event transported aerosols into the Arctic (> 66.6° N) for a 4-day period. During this 4-day period, biomass burning emissions have the strongest influence on concentrations between 2.5 and 3 km altitudes, while European anthropogenic emissions influence aerosols at both lower (~ 1.5 km) and higher altitudes (~ 4.5 km). As a proportion of PM2.5, modeled black carbon and SO4= concentrations are more enhanced near the surface in anthropogenic plumes. The European plumes sampled during the POLARCAT-France campaign were transported over the region of springtime snow cover in northern Scandinavia, where they had a significant local atmospheric warming effect. We find that, during this transport event, the average modeled top-of-atmosphere (TOA) shortwave direct and semi-direct radiative effect (DSRE) north of 60° N over snow and ice-covered surfaces reaches +0.58 W m?2, peaking at +3.3 W m?2 at noon over Scandinavia and Finland.

  15. Transport of anthropogenic and biomass burning aerosols from Europe to the Arctic during spring 2008

    SciTech Connect (OSTI)

    Marelle, L.; Raut, Jean-Christophe; Thomas, J. L.; Law, K. S.; Quennehen, Boris; Ancellet, G.; Pelon, J.; Schwarzenboeck, A.; Fast, Jerome D.

    2015-01-01

    During the POLARCAT-France airborne campaign in April 2008, pollution originating from anthropogenic and biomass burning emissions was measured in the European Arctic. We compare these aircraft measurements with simulations using the WRF-Chem model to investigate model representation of aerosols transported from Europe to the Arctic. Modeled PM2.5 is evaluated using European Monitoring and Evaluation Programme (EMEP) measurements in source regions and POLARCAT aircraft measurements in the Scandinavian Arctic. Total PM2.5 agrees well with the measurements, although the model overestimates nitrate and underestimates organic carbon in source regions. Using WRF-Chem in combination with the Lagrangian model FLEXPART-WRF, we find that during the campaign the research aircraft sampled two different types of European plumes: mixed anthropogenic and fire plumes from eastern Europe and Russia transported below 2 km, and anthropogenic plumes from central Europe uplifted by warm conveyor belt circulations to 5–6 km. Both modeled plume types had undergone significant wet scavenging (> 50% PM10) during transport. Modeled aerosol vertical distributions and optical properties below the aircraft are evaluated in the Arctic using airborne lidar measurements. Model results show that the pollution event transported aerosols into the Arctic (> 66.6° N) for a 4-day period. During this 4-day period, biomass burning emissions have the strongest influence on concentrations between 2.5 and 3 km altitudes, while European anthropogenic emissions influence aerosols at both lower (~ 1.5 km) and higher altitudes (~ 4.5 km). As a proportion of PM2.5, modeled black carbon and SO4= concentrations are more enhanced near the surface in anthropogenic plumes. The European plumes sampled during the POLARCAT-France campaign were transported over the region of springtime snow cover in northern Scandinavia, where they had a significant local atmospheric warming effect. We find that, during this transport event, the average modeled top-of-atmosphere (TOA) shortwave direct and semi-direct radiative effect (DSRE) north of 60° N over snow and ice-covered surfaces reaches +0.58 W m?2, peaking at +3.3 W m?2 at noon over Scandinavia and Finland.

  16. Transport of anthropogenic and biomass burning aerosols from Europe to the Arctic during spring 2008

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Marelle, L.; Raut, Jean-Christophe; Thomas, J. L.; Law, K. S.; Quennehen, Boris; Ancellet, G.; Pelon, J.; Schwarzenboeck, A.; Fast, Jerome D.

    2015-04-10

    During the POLARCAT-France airborne campaign in April 2008, pollution originating from anthropogenic and biomass burning emissions was measured in the European Arctic. We compare these aircraft measurements with simulations using the WRF-Chem model to investigate model representation of aerosols transported from Europe to the Arctic. Modeled PM2.5 is evaluated using European Monitoring and Evaluation Programme (EMEP) measurements in source regions and POLARCAT aircraft measurements in the Scandinavian Arctic. Total PM2.5 agrees well with the measurements, although the model overestimates nitrate and underestimates organic carbon in source regions. Using WRF-Chem in combination with the Lagrangian model FLEXPART-WRF, we find that duringmore »the campaign the research aircraft sampled two different types of European plumes: mixed anthropogenic and fire plumes from eastern Europe and Russia transported below 2 km, and anthropogenic plumes from central Europe uplifted by warm conveyor belt circulations to 5–6 km. Both modeled plume types had undergone significant wet scavenging (> 50% PM10) during transport. Modeled aerosol vertical distributions and optical properties below the aircraft are evaluated in the Arctic using airborne lidar measurements. Model results show that the pollution event transported aerosols into the Arctic (> 66.6° N) for a 4-day period. During this 4-day period, biomass burning emissions have the strongest influence on concentrations between 2.5 and 3 km altitudes, while European anthropogenic emissions influence aerosols at both lower (~ 1.5 km) and higher altitudes (~ 4.5 km). As a proportion of PM2.5, modeled black carbon and SO4= concentrations are more enhanced near the surface in anthropogenic plumes. The European plumes sampled during the POLARCAT-France campaign were transported over the region of springtime snow cover in northern Scandinavia, where they had a significant local atmospheric warming effect. We find that, during this transport event, the average modeled top-of-atmosphere (TOA) shortwave direct and semi-direct radiative effect (DSRE) north of 60° N over snow and ice-covered surfaces reaches +0.58 W m?2, peaking at +3.3 W m?2 at noon over Scandinavia and Finland.« less

  17. CHALLENGE TO ARM AND ASP Determine aerosol radiative forcings at ARM site(s).

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    aerosol optical thickness is 0.1: 3 W m-2 cooling. ~50 km Drone Radiometers AMF DIRECT DETERMINATION

  18. Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods

    Broader source: Energy.gov [DOE]

    Advanced aerosol analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends.

  19. Energy Intensity Baselining and Tracking Guidance

    Broader source: Energy.gov (indexed) [DOE]

    betterbuildings.energy.gov Energy Intensity Baselining and Tracking Guidance i Preface The U.S. Department of Energy's (DOE's) Better Buildings, Better Plants Program (Better...

  20. Energy Intensity Indicators: Terminology and Definitions

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Energy Intensity Indicators website uses the following terms with their associated definitions. The terms related to various definitions of energy are discussed first.

  1. Global observations of UV-absorbing aerosols from ERS-2/GOME Data

    E-Print Network [OSTI]

    Graaf, Martin de

    Absorbing Aerosol Index ­ Theory GOME AAI results Conclusions & Outlook #12; Absorbing Aerosol Index Solar zenith angle = 30° Viewing zenith angle = 0° Surface albedo = 5% #12; Reflectance at TOA with absorbing aerosols Doubling-Adding KNMI Radiative Transfer Model Solar zenith angle = 30° Viewing zenith

  2. Uncertainty and interpretation of aerosol remote sensing due to vertical inhomogeneity

    E-Print Network [OSTI]

    , and aerosol column number density. Monomodal aerosol size distribution is assumed. The Cost Function (CF radiance data at the TOA have been created assuming either one or two layers of aerosols using the vector is affected by the radiative forcing associated with various sources, including total solar irradiance

  3. Experience with Aerosol Generation During Rotary Mode Core Sampling in the Hanford Single Shell Waste Tanks

    SciTech Connect (OSTI)

    SCHOFIELD, J.S.

    2000-01-24

    This document provides data on aerosol concentrations in tank head spaces, total mass of aerosols in the tank head space and mass of aerosols sent to the exhauster during Rotary Mode Core Sampling from November 1994 through June 1999. A decontamination factor for the RMCS exhauster filter housing is calculated based on operation data.

  4. Atmospheric aerosols in Amazonia and land use change: from natural biogenic to biomass

    E-Print Network [OSTI]

    Atmospheric aerosols in Amazonia and land use change: from natural biogenic to biomass burning in Central Amazonia (TT34 North of Manaus) and at a heavily biomass burning impacted site in south-refractory PM1 aerosol loading at TT34, while biomass burning aerosols at PVH shows a 93% content of organic

  5. AEROSOL-CLOUD INTERACTIONS CONTROL OF EARTH RADIATION AND LATENT HEAT RELEASE BUDGETS

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    AEROSOL-CLOUD INTERACTIONS CONTROL OF EARTH RADIATION AND LATENT HEAT RELEASE BUDGETS D. ROSENFELD simulations show that cloud development is strongly mod- ulated by the impact of cloud-aerosol interactions on precipitation forming processes. New insights into the mechanisms by which aerosols dominate the cloud cover

  6. Aerosols and Clouds: In Cahoots to Change Climate

    ScienceCinema (OSTI)

    Berg, Larry

    2014-06-02

    Key knowledge gaps persist despite advances in the scientific understanding of how aerosols and clouds evolve and affect climate. The Two-Column Aerosol Project, or TCAP, was designed to provide a detailed set of observations to tackle this area of unknowns. Led by PNNL atmospheric scientist Larry Berg, ARM's Climate Research Facility was deployed in Cape Cod, Massachusetts for the 12-month duration of TCAP, which came to a close in June 2013. "We are developing new tools to look at particle chemistry, like our mass spectrometer used in TCAP that can tell us the individual chemical composition of an aerosol," said Berg. "Then, we'll run our models and compare it with the data that we have to make sure we're getting correct answers and make sure our climate models are reflecting the best information."

  7. Speciation of Fe in ambient aerosol and cloudwater

    SciTech Connect (OSTI)

    Siefert, L. [California Institute of Technology, Pasadena, CA (United States)

    1996-08-15

    Atmospheric iron (Fe) is thought to play an important role in cloudwater chemistry (e.g., S(IV) oxidation, oxidant production, etc.), and is also an important source of Fe to certain regions of the worlds oceans where Fe is believed to be a rate-limiting nutrient for primary productivity. This thesis focuses on understanding the chemistry, speciation and abundance of Fe in cloudwater and aerosol in the troposphere, through observations of Fe speciation in the cloudwater and aerosol samples collected over the continental United States and the Arabian Sea. Different chemical species of atmospheric Fe were measured in aerosol and cloudwater samples to help assess the role of Fe in cloudwater chemistry.

  8. Aerosols and Clouds: In Cahoots to Change Climate

    SciTech Connect (OSTI)

    Berg, Larry

    2014-03-29

    Key knowledge gaps persist despite advances in the scientific understanding of how aerosols and clouds evolve and affect climate. The Two-Column Aerosol Project, or TCAP, was designed to provide a detailed set of observations to tackle this area of unknowns. Led by PNNL atmospheric scientist Larry Berg, ARM's Climate Research Facility was deployed in Cape Cod, Massachusetts for the 12-month duration of TCAP, which came to a close in June 2013. "We are developing new tools to look at particle chemistry, like our mass spectrometer used in TCAP that can tell us the individual chemical composition of an aerosol," said Berg. "Then, we'll run our models and compare it with the data that we have to make sure we're getting correct answers and make sure our climate models are reflecting the best information."

  9. Distinguishing Aerosol Impacts on Climate Over the Past Century

    SciTech Connect (OSTI)

    Koch, Dorothy; Menon, Surabi; Del Genio, Anthony; Ruedy, Reto; Alienov, Igor; Schmidt, Gavin A.

    2008-08-22

    Aerosol direct (DE), indirect (IE), and black carbon-snow albedo (BAE) effects on climate between 1890 and 1995 are compared using equilibrium aerosol-climate simulations in the Goddard Institute for Space Studies General Circulation Model coupled to a mixed layer ocean. Pairs of control(1890)-perturbation(1995) with successive aerosol effects allow isolation of each effect. The experiments are conducted both with and without concurrent changes in greenhouse gases (GHG's). A new scheme allowing dependence of snow albedo on black carbon snow concentration is introduced. The fixed GHG experiments global surface air temperature (SAT) changed -0.2, -1.0 and +0.2 C from the DE, IE, and BAE. Ice and snow cover increased 1.0% from the IE and decreased 0.3% from the BAE. These changes were a factor of 4 larger in the Arctic. Global cloud cover increased by 0.5% from the IE. Net aerosol cooling effects are about half as large as the GHG warming, and their combined climate effects are smaller than the sum of their individual effects. Increasing GHG's did not affect the IE impact on cloud cover, however they decreased aerosol effects on SAT by 20% and on snow/ice cover by 50%; they also obscure the BAE on snow/ice cover. Arctic snow, ice, cloud, and shortwave forcing changes occur mostly during summer-fall, but SAT, sea level pressure, and long-wave forcing changes occur during winter. An explanation is that aerosols impact the cryosphere during the warm-season but the associated SAT effect is delayed until winter.

  10. Sponsored by Nanotechnology Seminar Program Engineering material properties using

    E-Print Network [OSTI]

    Fisher, Frank

    Sponsored by Nanotechnology Seminar Program Engineering material properties using block of other application opportunities in designing material properties through control of their nanostructure copolymers are under intense scrutiny by the semiconductor electronics industry for lithography enhancement

  11. Sources and composition of submicron organic mass in marine aerosol particles: Marine Aerosol Organic Mass Composition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Frossard, Amanda A.; Russell, Lynn M.; Burrows, Susannah M.; Elliott, Scott M.; Bates, Timothy S.; Quinn, Patricia K.

    2014-11-26

    Recent studies have proposed a variety of interpretations of the sources and composition of atmospheric marine aerosol particles (aMA) based on a range of physical and chemical measurements collected during open-ocean research cruises. To investigate the processes that affect marine organic particles, this study uses the characteristic functional group composition (from Fourier transform infrared (FTIR) spectroscopy) of aMAP from five ocean regions to show that: (i) The organic functional group composition of aMAP that can be identified as atmospheric primary marine (ocean-derived) aerosol (aPMA) is 65±12% hydroxyl, 21±9% alkane, 6±6% amine, and 7±8% carboxylic acid functional groups. Contributions from photochemicalmore »reactions add carboxylic acid groups (15%-25%), shipping effluent in seawater and ship emissions add additional alkane groups (up to 70%), and coastal emissions mix in alkane and carboxylic acid groups from coastal pollution sources. (ii) The organic composition of aPMA is nearly identical to model generated primary marine aerosol particles (gPMA) from bubbled seawater (55% hydroxyl, 32% alkane, and 13% amine functional groups), indicating that its overall functional group composition is the direct consequence of the organic constituents of the seawater source. (iii) While the seawater organic functional group composition was nearly invariant across all three ocean regions studied, the gPMA alkane group fraction increased with chlorophyll-a concentrations (r = 0.79). gPMA from productive seawater had a larger fraction of alkane functional groups (35%) compared to gPMA from non-productive seawater (16%), likely due to the presence of surfactants in productive seawater that stabilize the bubble film and lead to preferential drainage of the more soluble (lower alkane group fraction) organic components. gPMA has a hydroxyl group absorption peak location characteristic of monosaccharides and disaccharides, where the seawater OM hydroxyl group peak location is closer to that of polysaccharides. This may result from the larger saccharides preferentially remaining in the seawater during gPMA and aPMA production« less

  12. Sources and composition of submicron organic mass in marine aerosol particles: Marine Aerosol Organic Mass Composition

    SciTech Connect (OSTI)

    Frossard, Amanda A. [Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography; Russell, Lynn M. [Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography; Burrows, Susannah M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Atmospheric Science and Global Change Div. (ASGC); Elliott, Scott M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bates, Timothy S. [National Oceanic and Atmospheric Administration (NOAA), Seattle, WA (United States). Pacific Marine Environmental Lab. (PMEL); Quinn, Patricia K. [National Oceanic and Atmospheric Administration (NOAA), Seattle, WA (United States). Pacific Marine Environmental Lab. (PMEL)

    2014-11-26

    Recent studies have proposed a variety of interpretations of the sources and composition of atmospheric marine aerosol particles (aMA) based on a range of physical and chemical measurements collected during open-ocean research cruises. To investigate the processes that affect marine organic particles, this study uses the characteristic functional group composition (from Fourier transform infrared (FTIR) spectroscopy) of aMAP from five ocean regions to show that: (i) The organic functional group composition of aMAP that can be identified as atmospheric primary marine (ocean-derived) aerosol (aPMA) is 65±12% hydroxyl, 21±9% alkane, 6±6% amine, and 7±8% carboxylic acid functional groups. Contributions from photochemical reactions add carboxylic acid groups (15%-25%), shipping effluent in seawater and ship emissions add additional alkane groups (up to 70%), and coastal emissions mix in alkane and carboxylic acid groups from coastal pollution sources. (ii) The organic composition of aPMA is nearly identical to model generated primary marine aerosol particles (gPMA) from bubbled seawater (55% hydroxyl, 32% alkane, and 13% amine functional groups), indicating that its overall functional group composition is the direct consequence of the organic constituents of the seawater source. (iii) While the seawater organic functional group composition was nearly invariant across all three ocean regions studied, the gPMA alkane group fraction increased with chlorophyll-a concentrations (r = 0.79). gPMA from productive seawater had a larger fraction of alkane functional groups (35%) compared to gPMA from non-productive seawater (16%), likely due to the presence of surfactants in productive seawater that stabilize the bubble film and lead to preferential drainage of the more soluble (lower alkane group fraction) organic components. gPMA has a hydroxyl group absorption peak location characteristic of monosaccharides and disaccharides, where the seawater OM hydroxyl group peak location is closer to that of polysaccharides. This may result from the larger saccharides preferentially remaining in the seawater during gPMA and aPMA production

  13. Final Project Report - ARM CLASIC CIRPAS Twin Otter Aerosol

    SciTech Connect (OSTI)

    John A. Ogren

    2010-04-05

    The NOAA/ESRL/GMD aerosol group made three types of contributions related to airborne measurements of aerosol light scattering and absorption for the Cloud and Land Surface Interaction Campaign (CLASIC) in June 2007 on the Twin Otter research airplane operated by the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS). GMD scientists served as the instrument mentor for the integrating nephelometer and particle soot absorption photometer (PSAP) on the Twin Otter during CLASIC, and were responsible for (1) instrument checks/comparisons; (2) instrument trouble shooting/repair; and (3) data quality control (QC) and submittal to the archive.

  14. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, A.K.

    1984-09-07

    This disclosure relates to separation of aerosol particles from gas samples withdrawn from within a contained atmosphere, such as containment vessels for nuclear reactors or other process equipment where remote gaseous sampling is required. It is specifically directed to separation of dense aerosols including particles of any size and at high mass loadings and high corrosivity. The United States Government has rights in this invention pursuant to Contract DE-AC06-76FF02170 between the US Department of Energy and Westinghouse Electric Corporation.

  15. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, Arlin K. (Halfway, OR)

    1986-01-01

    A method for separating gaseous samples from a contained atmosphere that includes aerosol particles uses the step of repelling particles from a gas permeable surface or membrane by heating the surface to a temperature greater than that of the surrounding atmosphere. The resulting thermophoretic forces maintain the gas permeable surface clear of aerosol particles. The disclosed apparatus utilizes a downwardly facing heated plate of gas permeable material to combine thermophoretic repulsion and gravity forces to prevent particles of any size from contacting the separating plate surfaces.

  16. Fundamental Physics at the Intensity Frontier

    E-Print Network [OSTI]

    J. L. Hewett; H. Weerts; R. Brock; J. N. Butler; B. C. K. Casey; J. Collar; A. de Gouvea; R. Essig; Y. Grossman; W. Haxton; J. A. Jaros; C. K. Jung; Z. T. Lu; K. Pitts; Z. Ligeti; J. R. Patterson; M. Ramsey-Musolf; J. L. Ritchie; A. Roodman; K. Scholberg; C. E. M. Wagner; G. P. Zeller; S. Aefsky; A. Afanasev; K. Agashe; C. Albright; J. Alonso; C. Ankenbrandt; M. Aoki; C. A. Arguelles; N. Arkani-Hamed; J. R. Armendariz; C. Armendariz-Picon; E. Arrieta Diaz; J. Asaadi; D. M. Asner; K. S. Babu; K. Bailey; O. Baker; B. Balantekin; B. Baller; M. Bass; B. Batell; J. Beacham; J. Behr; N. Berger; M. Bergevin; E. Berman; R. Bernstein; A. J. Bevan; M. Bishai; M. Blanke; S. Blessing; A. Blondel; T. Blum; G. Bock; A. Bodek; G. Bonvicini; F. Bossi; J. Boyce; R. Breedon; M. Breidenbach; S. J. Brice; R. A. Briere; S. Brodsky; C. Bromberg; A. Bross; T. E. Browder; D. A. Bryman; M. Buckley; R. Burnstein; E. Caden; P. Campana; R. Carlini; G. Carosi; C. Castromonte; R. Cenci; I. Chakaberia; M. C. Chen; C. H. Cheng; B. Choudhary; N. H. Christ; E. Christensen; M. E. Christy; T. E. Chupp; E. Church; D. B. Cline; T. E. Coan; P. Coloma; J. Comfort; L. Coney; J. Cooper; R. J. Cooper; R. Cowan; D. F. Cowen; D. Cronin-Hennessy; A. Datta; G. S. Davies; M. Demarteau; D. P. DeMille; A. Denig; R. Dermisek; A. Deshpande; M. S. Dewey; R. Dharmapalan; J. Dhooghe; M. R. Dietrich; M. Diwan; Z. Djurcic; S. Dobbs; M. Duraisamy; B. Dutta; H. Duyang; D. A. Dwyer; M. Eads; B. Echenard; S. R. Elliott; C. Escobar; J. Fajans; S. Farooq; C. Faroughy; J. E. Fast; B. Feinberg; J. Felde; G. Feldman; P. Fierlinger; P. Fileviez Perez; B. Filippone; P. Fisher; B. T. Flemming; K. T. Flood; R. Forty; M. J. Frank; A. Freyberger; A. Friedland; R. Gandhi; K. S. Ganezer; A. Garcia; F. G. Garcia; S. Gardner; L. Garrison; A. Gasparian; S. Geer; V. M. Gehman; T. Gershon; M. Gilchriese; C. Ginsberg; I. Gogoladze; M. Gonderinger; M. Goodman; H. Gould; M. Graham; P. W. Graham; R. Gran; J. Grange; G. Gratta; J. P. Green; H. Greenlee; R. C. Group; E. Guardincerri; V. Gudkov; R. Guenette; A. Haas; A. Hahn; T. Han; T. Handler; J. C. Hardy; R. Harnik; D. A. Harris; F. A. Harris; P. G. Harris; J. Hartnett; B. He; B. R. Heckel; K. M. Heeger; S. Henderson; D. Hertzog; R. Hill; E. A Hinds; D. G. Hitlin; R. J. Holt; N. Holtkamp; G. Horton-Smith; P. Huber; W. Huelsnitz; J. Imber; I. Irastorza; J. Jaeckel; I. Jaegle; C. James; A. Jawahery; D. Jensen; C. P. Jessop; B. Jones; H. Jostlein; T. Junk; A. L. Kagan; M. Kalita; Y. Kamyshkov; D. M. Kaplan; G. Karagiorgi; A. Karle; T. Katori; B. Kayser; R. Kephart; S. Kettell; Y. K. Kim; M. Kirby; K. Kirch; J. Klein; J. Kneller; A. Kobach; M. Kohl; J. Kopp; M. Kordosky; W. Korsch; I. Kourbanis; A. D. Krisch; P. Krizan; A. S. Kronfeld; S. Kulkarni; K. S. Kumar; Y. Kuno; T. Kutter; T. Lachenmaier; M. Lamm; J. Lancaster; M. Lancaster; C. Lane; K. Lang; P. Langacker; S. Lazarevic; T. Le; K. Lee; K. T. Lesko; Y. Li; M. Lindgren; A. Lindner; J. Link; D. Lissauer; L. S. Littenberg; B. Littlejohn; C. Y. Liu; W. Loinaz; W. Lorenzon; W. C. Louis; J. Lozier; L. Ludovici; L. Lueking; C. Lunardini; D. B. MacFarlane; P. A. N. Machado; P. B. Mackenzie; J. Maloney; W. J. Marciano; W. Marsh; M. Marshak; J. W. Martin; C. Mauger; K. S. McFarland; C. McGrew; G. McLaughlin; D. McKeen; R. McKeown; B. T. Meadows; R. Mehdiyev; D. Melconian; H. Merkel; M. Messier; J. P. Miller; G. Mills; U. K. Minamisono; S. R. Mishra; I. Mocioiu; S. Moed Sher; R. N. Mohapatra; B. Monreal; C. D. Moore; J. G. Morfin; J. Mousseau; L. A. Moustakas; G. Mueller; P. Mueller; M. Muether; H. P. Mumm; C. Munger; H. Murayama; P. Nath; O. Naviliat-Cuncin; J. K. Nelson; D. Neuffer; J. S. Nico; A. Norman; D. Nygren; Y. Obayashi; T. P. O'Connor; Y. Okada; J. Olsen; L. Orozco; J. L. Orrell; J. Osta; B. Pahlka; J. Paley; V. Papadimitriou; M. Papucci; S. Parke; R. H. Parker; Z. Parsa; K. Partyka; A. Patch; J. C. Pati; R. B. Patterson; Z. Pavlovic; G. Paz; G. N. Perdue; D. Perevalov; G. Perez; R. Petti; W. Pettus; A. Piepke; M. Pivovaroff; R. Plunkett; C. C. Polly; M. Pospelov; R. Povey; A. Prakesh; M. V. Purohit; S. Raby; J. L. Raaf; R. Rajendran; S. Rajendran; G. Rameika; R. Ramsey; A. Rashed; B. N. Ratcliff; B. Rebel; J. Redondo; P. Reimer; D. Reitzner; F. Ringer; A. Ringwald; S. Riordan; B. L. Roberts; D. A. Roberts; R. Robertson; F. Robicheaux; M. Rominsky; R. Roser; J. L. Rosner; C. Rott; P. Rubin; N. Saito; M. Sanchez; S. Sarkar; H. Schellman; B. Schmidt; M. Schmitt; D. W. Schmitz; J. Schneps; A. Schopper; P. Schuster; A. J. Schwartz; M. Schwarz; J. Seeman; Y. K. Semertzidis; K. K. Seth; Q. Shafi; P. Shanahan; R. Sharma; S. R. Sharpe; M. Shiozawa; V. Shiltsev; K. Sigurdson; P. Sikivie; J. Singh; D. Sivers; T. Skwarnicki; N. Smith; J. Sobczyk; H. Sobel; M. Soderberg; Y. H. Song; A. Soni; P. Souder; A. Sousa; J. Spitz; M. Stancari; G. C. Stavenga; J. H. Steffen

    2012-05-11

    The Proceedings of the 2011 workshop on Fundamental Physics at the Intensity Frontier. Science opportunities at the intensity frontier are identified and described in the areas of heavy quarks, charged leptons, neutrinos, proton decay, new light weakly-coupled particles, and nucleons, nuclei, and atoms.

  17. Fundamental Physics at the Intensity Frontier

    E-Print Network [OSTI]

    Hewett, J L; Brock, R; Butler, J N; Casey, B C K; Collar, J; de Gouvea, A; Essig, R; Grossman, Y; Haxton, W; Jaros, J A; Jung, C K; Lu, Z T; Pitts, K; Ligeti, Z; Patterson, J R; Ramsey-Musolf, M; Ritchie, J L; Roodman, A; Scholberg, K; Wagner, C E M; Zeller, G P; Aefsky, S; Afanasev, A; Agashe, K; Albright, C; Alonso, J; Ankenbrandt, C; Aoki, M; Arguelles, C A; Arkani-Hamed, N; Armendariz, J R; Armendariz-Picon, C; Diaz, E Arrieta; Asaadi, J; Asner, D M; Babu, K S; Bailey, K; Baker, O; Balantekin, B; Baller, B; Bass, M; Batell, B; Beacham, J; Behr, J; Berger, N; Bergevin, M; Berman, E; Bernstein, R; Bevan, A J; Bishai, M; Blanke, M; Blessing, S; Blondel, A; Blum, T; Bock, G; Bodek, A; Bonvicini, G; Bossi, F; Boyce, J; Breedon, R; Breidenbach, M; Brice, S J; Briere, R A; Brodsky, S; Bromberg, C; Bross, A; Browder, T E; Bryman, D A; Buckley, M; Burnstein, R; Caden, E; Campana, P; Carlini, R; Carosi, G; Castromonte, C; Cenci, R; Chakaberia, I; Chen, M C; Cheng, C H; Choudhary, B; Christ, N H; Christensen, E; Christy, M E; Chupp, T E; Church, E; Cline, D B; Coan, T E; Coloma, P; Comfort, J; Coney, L; Cooper, J; Cooper, R J; Cowan, R; Cowen, D F; Cronin-Hennessy, D; Datta, A; Davies, G S; Demarteau, M; DeMille, D P; Denig, A; Dermisek, R; Deshpande, A; Dewey, M S; Dharmapalan, R; Dhooghe, J; Dietrich, M R; Diwan, M; Djurcic, Z; Dobbs, S; Duraisamy, M; Dutta, B; Duyang, H; Dwyer, D A; Eads, M; Echenard, B; Elliott, S R; Escobar, C; Fajans, J; Farooq, S; Faroughy, C; Fast, J E; Feinberg, B; Felde, J; Feldman, G; Fierlinger, P; Perez, P Fileviez; Filippone, B; Fisher, P; Flemming, B T; Flood, K T; Forty, R; Frank, M J; Freyberger, A; Friedland, A; Gandhi, R; Ganezer, K S; Garcia, A; Garcia, F G; Gardner, S; Garrison, L; Gasparian, A; Geer, S; Gehman, V M; Gershon, T; Gilchriese, M; Ginsberg, C; Gogoladze, I; Gonderinger, M; Goodman, M; Gould, H; Graham, M; Graham, P W; Gran, R; Grange, J; Gratta, G; Green, J P; Greenlee, H; Guardincerri, E; Gudkov, V; Guenette, R; Haas, A; Hahn, A; Han, T; Handler, T; Hardy, J C; Harnik, R; Harris, D A; Harris, F A; Harris, P G; Hartnett, J; He, B; Heckel, B R; Heeger, K M; Henderson, S; Hertzog, D; Hill, R; Hinds, E A; Hitlin, D G; Holt, R J; Holtkamp, N; Horton-Smith, G; Huber, P; Huelsnitz, W; Imber, J; Irastorza, I; Jaeckel, J; Jaegle, I; James, C; Jawahery, A; Jensen, D; Jessop, C P; Jones, B; Jostlein, H; Junk, T; Kagan, A L; Kalita, M; Kamyshkov, Y; Kaplan, D M; Karagiorgi, G; Karle, A; Katori, T; Kayser, B; Kephart, R; Kettell, S; Kim, Y K; Kirby, M; Kirch, K; Klein, J; Kneller, J; Kobach, A; Kohl, M; Kopp, J; Kordosky, M; Korsch, W; Kourbanis, I; Krisch, A D; Krizan, P; Kronfeld, A S; Kulkarni, S; Kumar, K S; Kuno, Y; Kutter, T; Lachenmaier, T; Lamm, M; Lancaster, J; Lancaster, M; Lane, C; Lang, K; Langacker, P; Lazarevic, S; Le, T; Lee, K; Lesko, K T; Li, Y; Lindgren, M; Lindner, A; Link, J; Lissauer, D; Littenberg, L S; Littlejohn, B; Liu, C Y; Loinaz, W; Lorenzon, W; Louis, W C; Lozier, J; Ludovici, L; Lueking, L; Lunardini, C; MacFarlane, D B; Machado, P A N; Mackenzie, P B; Maloney, J; Marciano, W J; Marsh, W; Marshak, M; Martin, J W; Mauger, C; McFarland, K S; McGrew, C; McLaughlin, G; McKeen, D; McKeown, R; Meadows, B T; Mehdiyev, R; Melconian, D; Merkel, H; Messier, M; Miller, J P; Mills, G; Minamisono, U K; Mishra, S R; Mocioiu, I; Sher, S Moed; Mohapatra, R N; Monreal, B; Moore, C D; Morfin, J G; Mousseau, J; Moustakas, L A; Mueller, G; Mueller, P; Muether, M; Mumm, H P; Munger, C; Murayama, H; Nath, P; Naviliat-Cuncin, O; Nelson, J K; Neuffer, D; Nico, J S; Norman, A; Nygren, D; Obayashi, Y; O'Connor, T P; Okada, Y; Olsen, J; Orozco, L; Orrell, J L; Osta, J; Pahlka, B; Paley, J; Papadimitriou, V; Papucci, M; Parke, S; Parker, R H; Parsa, Z; Partyka, K; Patch, A; Pati, J C; Patterson, R B; Pavlovic, Z; Paz, G; Perdue, G N; Perevalov, D; Perez, G; Petti, R; Pettus, W; Piepke, A; Pivovaroff, M; Plunkett, R; Polly, C C; Pospelov, M; Povey, R; Prakesh, A; Purohit, M V; Raby, S; Raaf, J L; Rajendran, R; Rajendran, S; Rameika, G; Ramsey, R; Rashed, A; Ratcliff, B N; Rebel, B; Redondo, J; Reimer, P; Reitzner, D; Ringer, F; Ringwald, A; Riordan, S; Roberts, B L; Roberts, D A; Robertson, R; Robicheaux, F; Rominsky, M; Roser, R; Rosner, J L; Rott, C; Rubin, P; Saito, N; Sanchez, M; Sarkar, S; Schellman, H; Schmidt, B; Schmitt, M; Schmitz, D W; Schneps, J; Schopper, A; Schuster, P; Schwartz, A J; Schwarz, M; Seeman, J; Semertzidis, Y K; Seth, K K; Shafi, Q; Shanahan, P; Sharma, R; Sharpe, S R; Shiozawa, M; Shiltsev, V; Sigurdson, K; Sikivie, P; Singh, J; Sivers, D; Skwarnicki, T; Smith, N; Sobczyk, J; Sobel, H; Soderberg, M; Song, Y H; Soni, A; Souder, P; Sousa, A; Spitz, J; Stancari, M; Stavenga, G C; Steffen, J H; Stepanyan, S; Stoeckinger, D; Stone, S; Strait, J; Strassler, M; Sulai, I A; Sundrum, R; Svoboda, R; Szczerbinska, B; Szelc, A; Takeuchi, T; Tanedo, P

    2012-01-01

    The Proceedings of the 2011 workshop on Fundamental Physics at the Intensity Frontier. Science opportunities at the intensity frontier are identified and described in the areas of heavy quarks, charged leptons, neutrinos, proton decay, new light weakly-coupled particles, and nucleons, nuclei, and atoms.

  18. Service Assessment Intense Space Weather Storms

    E-Print Network [OSTI]

    Schrijver, Karel

    Service Assessment Intense Space Weather Storms October 19 ­ November 07, 2003 U.S. DEPARTMENT OF COMMERCE National Oceanic and Atmospheric Administration National Weather Service Silver Spring, Maryland image. #12;Service Assessment Intense Space Weather Storms October 19 ­ November 07, 2003 April 2004 U

  19. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  20. ARM: 10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol scattering ratio and backscattering coefficient profiles, from first Ferrare algorithm

  1. Modeling Data-Intensive Web Sites 259 ModelingData-Intensive

    E-Print Network [OSTI]

    Modeling Data-Intensive Web Sites 259 ChapterXII ModelingData-Intensive Web Sites-by-stepapproachtothedesign,implementation and management of a Data-Intensive Web Site (DIWS). The approach introduces five data formulation is that of "Web fragments," that is an information decomposition technique that aids design, implementation

  2. Lubricating Oil Dominates Primary Organic Aerosol Emissions from Motor Vehicles

    E-Print Network [OSTI]

    Goldstein, Allen

    Lubricating Oil Dominates Primary Organic Aerosol Emissions from Motor Vehicles David R. Worton to "fresh" lubricating oil. The gas chromatography retention time data indicates that the cycloalkane ring with lubricating oil being the dominant source from both gasoline and diesel-powered vehicles, with an additional

  3. Reduction of photosynthetically active radiation under extreme stratospheric aerosol loads

    SciTech Connect (OSTI)

    Gerstl, S.A.W.; Zardecki, A.

    1981-08-01

    The recently published hypothesis that the Cretaceous-Tertiary extinctions might be caused by an obstruction of sunlight is tested by model calculations. First we compute the total mass of stratospheric aerosols under normal atmospheric conditions for four different (measured) aerosol size distributions and vertical profiles. For comparison, the stratospheric dust masses after four volcanic eruptions are also evaluated. Detailed solar radiative transfer calculations are then performed for artificially increased aerosol amounts until the postulated darkness scenario is obtained. Thus we find that a total stratospheric aerosol mass between 1 and 4 times 10/sup 1/ g is sufficient to reduce photosynthesis to 10/sup -3/ of normal. We also infer from this result tha the impact of a 0.4- to 3-km-diameter asteroid or a close encounter with a Halley-size comet may deposit that amount of particulates into the stratosphere. The darkness scenario of Alvarez et al. is thus shown to be a possible extinction mechanism, even with smaller size asteroids of comets than previously estimated.

  4. Detection of UV-absorbing aerosols using GOME and SCIAMACHY

    E-Print Network [OSTI]

    Graaf, Martin de

    using GOME and SCIAMACHY · Conclusions and Outlook #12;Last step: Only positive residues are considered-Adding KNMI Radiative Transfer Model Solar zenith angle = 30° Viewing zenith angle = 0° Surface albedo = 5% #12; Reflectance at TOA with absorbing aerosols Doubling-Adding KNMI Radiative Transfer Model Solar

  5. The coupling of winds, aerosols and chemistry in Titan's atmosphere

    E-Print Network [OSTI]

    Hourdin, Chez Frédéric

    REVIEW The coupling of winds, aerosols and chemistry in Titan's atmosphere BY SEBASTIEN LEBONNOIS 1'Ae´ronomie, IPSL, CNRS, BP3, 91371 Verrie`res le Buisson, France The atmosphere of Titan is a complex system, where the observed atmospheric structure of Titan's lower atmosphere (mainly in the stratosphere and troposphere

  6. Soft ionization of thermally evaporated hypergolic ionic liquid aerosols

    SciTech Connect (OSTI)

    University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center; Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; L.Vaghjiani, Ghanshyam; Leone, Stephen R.

    2012-03-16

    Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1- Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?] ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

  7. Soft ionization of thermally evaporated hypergolic ionic liquid aerosols

    SciTech Connect (OSTI)

    University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center; Institute of Chemistry, Hebrew University; Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; Vaghjiani, Ghanshyam L.; Leone, Stephen R.

    2011-07-19

    Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1-Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?]ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

  8. DIESEL AEROSOL SAMPLING METHODOLOGY -CRC E-43 EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    Minnesota, University of

    ) was to develop Diesel aerosol sampling methods for the laboratory that would produce particle size distributions used to evaluate and select basic options, or to perform feasibility studies or preliminary assessments, and dilution with ambient air. A small amount of these nuclei mode particles contain solid ash from lube oil

  9. Black carbon aerosols and the third polar ice cap

    SciTech Connect (OSTI)

    Menon, Surabi; Koch, Dorothy; Beig, Gufran; Sahu, Saroj; Fasullo, John; Orlikowski, Daniel

    2010-04-15

    Recent thinning of glaciers over the Himalayas (sometimes referred to as the third polar region) have raised concern on future water supplies since these glaciers supply water to large river systems that support millions of people inhabiting the surrounding areas. Black carbon (BC) aerosols, released from incomplete combustion, have been increasingly implicated as causing large changes in the hydrology and radiative forcing over Asia and its deposition on snow is thought to increase snow melt. In India BC emissions from biofuel combustion is highly prevalent and compared to other regions, BC aerosol amounts are high. Here, we quantify the impact of BC aerosols on snow cover and precipitation from 1990 to 2010 over the Indian subcontinental region using two different BC emission inventories. New estimates indicate that Indian BC emissions from coal and biofuel are large and transport is expected to expand rapidly in coming years. We show that over the Himalayas, from 1990 to 2000, simulated snow/ice cover decreases by {approx}0.9% due to aerosols. The contribution of the enhanced Indian BC to this decline is {approx}36%, similar to that simulated for 2000 to 2010. Spatial patterns of modeled changes in snow cover and precipitation are similar to observations (from 1990 to 2000), and are mainly obtained with the newer BC estimates.

  10. Source Attribution of Light Absorbing Aerosol in Arctic Snow

    E-Print Network [OSTI]

    Source Attribution of Light Absorbing Aerosol in Arctic Snow (Preliminary analysis of 2008 Biomass/poll. Factor: all data Pollution factor: depth data #12;2009 Data set for receptor modeling with limited analytes Factor 1: biomass Factor 2: pollution Factor 3: marine Factor 4: biomass #12;Factor

  11. Design of high efficiency blowers for future aerosol applications 

    E-Print Network [OSTI]

    Chadha, Raman

    2007-04-25

    High efficiency air blowers to meet future portable aerosol sampling applications were designed, fabricated, and evaluated. A Centrifugal blower was designed to achieve a flow rate of 100 L/min (1.67 x 10^-3 m^3/s) and a pressure rise of WC " 4...

  12. Aerosol Synthesis and Growth Mechanism of Magnetic Iron Nanoparticles

    E-Print Network [OSTI]

    rapidly over the past decades, such as mechanical milling, spray drying, sol-gel, sonochemistry, etcAerosol Synthesis and Growth Mechanism of Magnetic Iron Nanoparticles D. Kim1,a , E.S. Vasilieva2,b, evaporated and transported by carrier gas flow to the preliminary heated tubular furnace for decomposition

  13. Field Trial of an Aerosol-Based Enclosure Sealing Technology

    SciTech Connect (OSTI)

    Harrington, Curtis; Springer, David

    2015-09-01

    This report presents the results from several demonstrations of a new method for sealing building envelope air leaks using an aerosol sealing process developed by the Western Cooling Efficiency Center at UC Davis. The process involves pressurizing a building while applying an aerosol sealant to the interior. As air escapes through leaks in the building envelope, the aerosol particles are transported to the leaks where they collect and form a seal that blocks the leak. Standard blower door technology is used to facilitate the building pressurization, which allows the installer to track the sealing progress during the installation and automatically verify the final building tightness. Each aerosol envelope sealing installation was performed after drywall was installed and taped, and the process did not appear to interrupt the construction schedule or interfere with other trades working in the homes. The labor needed to physically seal bulk air leaks in typical construction will not be replaced by this technology. However, this technology is capable of bringing the air leakage of a building that was built with standard construction techniques and HERS-verified sealing down to levels that would meet DOE Zero Energy Ready Homes program requirements. When a developer is striving to meet a tighter envelope leakage specification, this technology could greatly reduce the cost to achieve that goal by providing a simple and relatively low cost method for reducing the air leakage of a building envelope with little to no change in their common building practices.

  14. AEROSOLS AND CLOUDS IN CHEMICAL TRANSPORT MODELS AND CLIMATE MODELS

    E-Print Network [OSTI]

    of Earth's climate system. Clouds are highly reflective in the solar spectrum, yet strongly absorbingAEROSOLS AND CLOUDS IN CHEMICAL TRANSPORT MODELS AND CLIMATE MODELS Ulrike Lohmann1 and Stephen E Forum: Perturbed Clouds in the Climate System, Frankfurt, Germany March 2-7, 2008 Environmental Sciences

  15. Halophilic Archaea determined from geothermal steam vent aerosols

    E-Print Network [OSTI]

    Kelley, Scott

    Halophilic Archaea determined from geothermal steam vent aerosols Dean G. Ellis, Richard W. Bizzoco Hydrothermal vents, known as `fumaroles', are ubiq- uitous features of geothermal areas. Although their geology contained halophilic Archaea closely related to the Haloarcula spp. found in non-geothermal salt mats

  16. LESSONS LEARNED IN AEROSOL MONITORING WITH THE RASA

    SciTech Connect (OSTI)

    Forrester, Joel B.; Bowyer, Ted W.; Carty, Fitz; Comes, Laura; Eslinger, Paul W.; Greenwood, Lawrence R.; Haas, Derek A.; Hayes, James C.; Kirkham, Randy R.; Lepel, Elwood A.; Litke, Kevin E.; Miley, Harry S.; Morris, Scott J.; Schrom, Brian T.; Van Davelaar, Peter; Woods, Vincent T.

    2011-09-14

    The Radionuclide Aerosol Sampler/Analyzer (RASA) is an automated aerosol collection and analysis system designed by Pacific Northwest National Laboratory (PNNL) in the 1990's and is deployed in several locations around the world as part of the International Monitoring System (IMS) required under the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The RASA operates unattended, save for regularly scheduled maintenance, iterating samples through a three-step process on a 24-hour interval. In its 15-year history, much has been learned from the operation and maintenance of the RASA that can benefit engineering updates or future aerosol systems. On 11 March 2011, a 9.0 magnitude earthquake and tsunami rocked the eastern coast of Japan, resulting in power loss and cooling failures at the Daiichi nuclear power plants in Fukushima Prefecture. Aerosol collections were conducted with the RASA in Richland, WA. We present a summary of the lessons learned over the history of the RASA, including lessons taken from the Fukushima incident, regarding the RASA IMS stations operated by the United States.

  17. Impact of anthropogenic absorbing aerosols on clouds and precipitation

    E-Print Network [OSTI]

    Impact of anthropogenic absorbing aerosols on clouds and precipitation: A review of recent and precipitation: A review of recent progresses Chien Wang Massachusetts Institute of Technology, E19-439K, 77 atmospheric circulation, and hence clouds and precipitation. Recent studies have suggested that the changes

  18. IMPACT OF AEROSOLS ON CONVECTIVE CLOUDS AND PRECIPITATION

    E-Print Network [OSTI]

    Zeng, Ning

    IMPACT OF AEROSOLS ON CONVECTIVE CLOUDS AND PRECIPITATION Wei-Kuo Tao,1 Jen-Ping Chen,2 Zhanqing Li effects on clouds could further extend to precipitation, both through the formation of cloud particles mechan- isms behind these effects, in particular, the ones connected to precipitation, are not yet well

  19. Aerosol Spray Synthesis of Porous Molybdenum Sulfide

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    catalyst in the petroleum industry.[3] MoS2 has a layered structure with a repeating motif of S, the desulfurization activity of MoS2 is greatly affected by the synthetic technique employed in its production the desulfurization properties. MATERIALS · Ammonium tetrathiomolybdate (NH4)2MoS4 from Aldrich (99.97%); used

  20. Techniques for optically compressing light intensity ranges

    SciTech Connect (OSTI)

    Rushford, Michael C.

    1989-01-01

    A pin hole camera assembly for use in viewing an object having a relatively large light intensity range, for example a crucible containing molten uranium in an atomic vapor laser isotope separator (AVLIS) system is disclosed herein. The assembly includes means for optically compressing the light intensity range appearing at its input sufficient to make it receivable and decipherable by a standard video camera. A number of different means for compressing the intensity range are disclosed. These include the use of photogray glass, the use of a pair of interference filters, and the utilization of a new liquid crystal notch filter in combination with an interference filter.

  1. Techniques for optically compressing light intensity ranges

    DOE Patents [OSTI]

    Rushford, M.C.

    1989-03-28

    A pin hole camera assembly for use in viewing an object having a relatively large light intensity range, for example a crucible containing molten uranium in an atomic vapor laser isotope separator (AVLIS) system is disclosed herein. The assembly includes means for optically compressing the light intensity range appearing at its input sufficient to make it receivable and decipherable by a standard video camera. A number of different means for compressing the intensity range are disclosed. These include the use of photogray glass, the use of a pair of interference filters, and the utilization of a new liquid crystal notch filter in combination with an interference filter. 18 figs.

  2. Chemical aging of single and multicomponent biomass burning aerosol surrogate-particles by OH: Implications for cloud condensation nucleus activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thalman, R.; Thalman, R.; Wang, J.; Knopf, D. A.

    2015-01-01

    Multiphase OH and O? oxidation reactions with atmospheric organic aerosol (OA) can influence particle physicochemical properties including composition, morphology, and lifetime. Chemical aging of initially insoluble or low soluble single-component OA by OH and O? can increase their water-solubility and hygroscopicity, making them more active as cloud condensation nuclei (CCN) and susceptible to wet deposition. However, an outstanding problem is whether the effects of chemical aging on their CCN activity are preserved when mixed with other organic or inorganic compounds exhibiting greater water-solubility. In this work, the CCN activity of laboratory-generated biomass burning aerosol (BBA) surrogate-particles exposed to OH andmore »O? is evaluated by determining the hygroscopicity parameter, ?, as a function of particle type, mixing state, and OH/O? exposure applying a CCN counter (CCNc) coupled to an aerosol flow reactor (AFR). Levoglucosan (LEV), 4-methyl-5-nitrocatechol (MNC), and potassium sulfate (KS) serve as representative BBA compounds that exhibit different hygroscopicity, water solubility, chemical functionalities, and reactivity with OH radicals, and thus exemplify the complexity of mixed inorganic/organic aerosol in the atmosphere. The CCN activities of all of the particles were unaffected by O? exposure. Following exposure to OH, ? of MNC was enhanced by an order of magnitude, from 0.009 to ~0.1, indicating that chemically-aged MNC particles are better CCN and more prone to wet deposition than pure MNC particles. No significant enhancement in ? was observed for pure LEV particles following OH exposure. ? of the internally-mixed particles was not affected by OH oxidation. Furthermore, the CCN activity of OH exposed MNC-coated KS particles is similar to the OH unexposed atomized 1:1 by mass MNC: KS binary-component particles. Our results strongly suggest that when OA is dominated by water-soluble organic carbon (WSOC) or inorganic ions, chemical aging has no significant impact on OA hygroscopicity. The organic compounds exhibiting low solubility behave as if they are infinitely soluble when mixed with a sufficient amount of water-soluble compounds. At and beyond this point, the particles' CCN activity is governed entirely by the water-soluble fraction and not influenced by the oxidized organic fraction. Our results have important implications for heterogeneous oxidation and its impact on cloud formation given that atmospheric aerosol is a complex mixture of organic and inorganic compounds exhibiting a wide-range of solubilities.« less

  3. Chemical aging of single and multicomponent biomass burning aerosol surrogate particles by OH: implications for cloud condensation nucleus activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Slade, J. H.; Thalman, R.; Wang, J.; Knopf, D. A.

    2015-09-14

    Multiphase OH and O3 oxidation reactions with atmospheric organic aerosol (OA) can influence particle physicochemical properties including composition, morphology, and lifetime. Chemical aging of initially insoluble or low-soluble single-component OA by OH and O3 can increase their water solubility and hygroscopicity, making them more active as cloud condensation nuclei (CCN) and susceptible to wet deposition. However, an outstanding problem is whether the effects of chemical aging on their CCN activity are preserved when mixed with other organic or inorganic compounds exhibiting greater water solubility. In this work, the CCN activity of laboratory-generated biomass burning aerosol (BBA) surrogate particles exposed tomore »OH and O3 is evaluated by determining the hygroscopicity parameter, ?, as a function of particle type, mixing state, and OH and O3 exposure applying a CCN counter (CCNc) coupled to an aerosol flow reactor (AFR). Levoglucosan (LEV), 4-methyl-5-nitrocatechol (MNC), and potassium sulfate (KS) serve as representative BBA compounds that exhibit different hygroscopicity, water solubility, chemical functionalities, and reactivity with OH radicals, and thus exemplify the complexity of mixed inorganic/organic aerosol in the atmosphere. The CCN activities of all of the particles were unaffected by O3 exposure. Following exposure to OH, ? of MNC was enhanced by an order of magnitude, from 0.009 to ~ 0.1, indicating that chemically aged MNC particles are better CCN and more prone to wet deposition than pure MNC particles. No significant enhancement in ? was observed for pure LEV particles following OH exposure. ? of the internally mixed particles was not affected by OH oxidation. Furthermore, the CCN activity of OH-exposed MNC-coated KS particles is similar to the OH unexposed atomized 1 : 1 by mass MNC : KS binary-component particles. Our results strongly suggest that when OA is dominated by water-soluble organic carbon (WSOC) or inorganic ions, chemical aging has no significant impact on OA hygroscopicity. The organic compounds exhibiting low solubility behave as if they are infinitely soluble when mixed with a sufficient number of water-soluble compounds. At and beyond this point, the particles' CCN activity is governed entirely by the water-soluble fraction and is not influenced by the oxidized organic fraction. Our results have important implications for heterogeneous oxidation and its impact on cloud formation given that atmospheric aerosol is a complex mixture of organic and inorganic compounds exhibiting a wide range of solubilities.« less

  4. A Physically Based Framework for Modelling the Organic Fractionation of Sea Spray Aerosol from Bubble Film Langmuir Equilibria

    SciTech Connect (OSTI)

    Burrows, Susannah M.; Ogunro, O.; Frossard, Amanda; Russell, Lynn M.; Rasch, Philip J.; Elliott, S.

    2014-12-19

    The presence of a large fraction of organic matter in primary sea spray aerosol (SSA) can strongly affect its cloud condensation nuclei activity and interactions with marine clouds. Global climate models require new parameterizations of the SSA composition in order to improve the representation of these processes. Existing proposals for such a parameterization use remotely-sensed chlorophyll-a concentrations as a proxy for the biogenic contribution to the aerosol. However, both observations and theoretical considerations suggest that existing relationships with chlorophyll-a, derived from observations at only a few locations, may not be representative for all ocean regions. We introduce a novel framework for parameterizing the fractionation of marine organic matter into SSA based on a competitive Langmuir adsorption equilibrium at bubble surfaces. Marine organic matter is partitioned into classes with differing molecular weights, surface excesses, and Langmuir adsorption parameters. The classes include a lipid-like mixture associated with labile dissolved organic carbon (DOC), a polysaccharide-like mixture associated primarily with semi-labile DOC, a protein-like mixture with concentrations intermediate between lipids and polysaccharides, a processed mixture associated with recalcitrant surface DOC, and a deep abyssal humic-like mixture. Box model calculations have been performed for several cases of organic adsorption to illustrate the underlying concepts. We then apply the framework to output from a global marine biogeochemistry model, by partitioning total dissolved organic carbon into several classes of macromolecule. Each class is represented by model compounds with physical and chemical properties based on existing laboratory data. This allows us to globally map the predicted organic mass fraction of the nascent submicron sea spray aerosol. Predicted relationships between chlorophyll-\\textit{a} and organic fraction are similar to existing empirical parameterizations, but can vary between biologically productive and non-productive regions, and seasonally within a given region. Major uncertainties include the bubble film thickness at bursting and the variability of organic surfactant activity in the ocean, which is poorly constrained. In addition, marine colloids and cooperative adsorption of polysaccharides may make important contributions to the aerosol, but are not included here. This organic fractionation framework is an initial step towards a closer linking of ocean biogeochemistry and aerosol chemical composition in Earth system models. Future work should focus on improving constraints on model parameters through new laboratory experiments or through empirical fitting to observed relationships in the real ocean and atmosphere, as well as on atmospheric implications of the variable composition of organic matter in sea spray.

  5. Chemical aging of single and multicomponent biomass burning aerosol surrogate-particles by OH: implications for cloud condensation nucleus activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Slade, J. H.; Thalman, R.; Wang, J.; Knopf, D. A.

    2015-03-06

    Multiphase OH and O3 oxidation reactions with atmospheric organic aerosol (OA) can influence particle physicochemical properties including composition, morphology, and lifetime. Chemical aging of initially insoluble or low soluble single-component OA by OH and O3 can increase their water-solubility and hygroscopicity, making them more active as cloud condensation nuclei (CCN) and susceptible to wet deposition. However, an outstanding problem is whether the effects of chemical aging on their CCN activity are preserved when mixed with other organic or inorganic compounds exhibiting greater water-solubility. In this work, the CCN activity of laboratory-generated biomass burning aerosol (BBA) surrogate-particles exposed to OH andmore »O3 is evaluated by determining the hygroscopicity parameter, ?, as a function of particle type, mixing state, and OH/O3 exposure applying a CCN counter (CCNc) coupled to an aerosol flow reactor (AFR). Levoglucosan (LEV), 4-methyl-5-nitrocatechol (MNC), and potassium sulfate (KS) serve as representative BBA compounds that exhibit different hygroscopicity, water solubility, chemical functionalities, and reactivity with OH radicals, and thus exemplify the complexity of mixed inorganic/organic aerosol in the atmosphere. The CCN activities of all of the particles were unaffected by O3 exposure. Following exposure to OH, ? of MNC was enhanced by an order of magnitude, from 0.009 to ~0.1, indicating that chemically-aged MNC particles are better CCN and more prone to wet deposition than pure MNC particles. No significant enhancement in ? was observed for pure LEV particles following OH exposure. ? of the internally-mixed particles was not affected by OH oxidation. Furthermore, the CCN activity of OH exposed MNC-coated KS particles is similar to the OH unexposed atomized 1 : 1 by mass MNC : KS binary-component particles. Our results strongly suggest that when OA is dominated by water-soluble organic carbon (WSOC) or inorganic ions, chemical aging has no significant impact on OA hygroscopicity. The organic compounds exhibiting low solubility behave as if they are infinitely soluble when mixed with a sufficient amount of water-soluble compounds. At and beyond this point, the particles' CCN activity is governed entirely by the water-soluble fraction and not influenced by the oxidized organic fraction. Our results have important implications for heterogeneous oxidation and its impact on cloud formation given that atmospheric aerosol is a complex mixture of organic and inorganic compounds exhibiting a wide-range of solubilities.« less

  6. Chemical composition of dust storms in Beijing and implications for the mixing of mineral aerosol with pollution aerosol

    E-Print Network [OSTI]

    with pollution aerosol on the pathway Yele Sun,1 Guoshun Zhuang,1,2,3 Ying Wang,1 Xiujuan Zhao,1,4 Jie Li,5 Zifa direction could be seen as the ``polluted'' pathway and the north-northwesterly direction as the relatively ``less-polluted'' one. Dust storms not only delivered large amounts of mineral elements but also carried

  7. Energy Intensity Indicators: Commercial Source Energy Consumption

    Broader source: Energy.gov [DOE]

    Figure C1 below reports as index numbers over the period 1970 through 2011: 1) commercial building floor space, 2) energy use based on source energy consumption, 3) energy intensity, and 4) the...

  8. Technical Change, Investment and Energy Intensity

    E-Print Network [OSTI]

    Kratena, Kurt

    This paper analyzes the role of different components of technical change on energy intensity by applying a Translog variable cost function setting to the new EU KLEMS dataset for 3 selected EU countries (Italy, Finland and ...

  9. Absolute vs. intensity-based emission caps

    E-Print Network [OSTI]

    Ellerman, A. Denny.

    Cap-and-trade systems limit emissions to some pre-specified absolute quantity. Intensity-based limits, that restrict emissions to some pre-specified rate relative to input or output, are much more widely used in environmental ...

  10. Computational phase imaging based on intensity transport

    E-Print Network [OSTI]

    Waller, Laura A. (Laura Ann)

    2010-01-01

    Light is a wave, having both an amplitude and a phase. However, optical frequencies are too high to allow direct detection of phase; thus, our eyes and cameras see only real values - intensity. Phase carries important ...

  11. Applications in Data-Intensive Computing

    SciTech Connect (OSTI)

    Shah, Anuj R.; Adkins, Joshua N.; Baxter, Douglas J.; Cannon, William R.; Chavarría-Miranda, Daniel; Choudhury, Sutanay; Gorton, Ian; Gracio, Deborah K.; Halter, Todd D.; Jaitly, Navdeep; Johnson, John R.; Kouzes, Richard T.; Macduff, Matt C.; Marquez, Andres; Monroe, Matthew E.; Oehmen, Christopher S.; Pike, William A.; Scherrer, Chad; Villa, Oreste; Webb-Robertson, Bobbie-Jo M.; Whitney, Paul D.; Zuljevic, Nino

    2010-04-01

    This book chapter, to be published in Advances in Computers, Volume 78, in 2010 describes applications of data intensive computing (DIC). This is an invited chapter resulting from a previous publication on DIC. This work summarizes efforts coming out of the PNNL's Data Intensive Computing Initiative. Advances in technology have empowered individuals with the ability to generate digital content with mouse clicks and voice commands. Digital pictures, emails, text messages, home videos, audio, and webpages are common examples of digital content that are generated on a regular basis. Data intensive computing facilitates human understanding of complex problems. Data-intensive applications provide timely and meaningful analytical results in response to exponentially growing data complexity and associated analysis requirements through the development of new classes of software, algorithms, and hardware.

  12. Laser intensity effects in noncommutative QED

    E-Print Network [OSTI]

    Thomas Heinzl; Anton Ilderton; Mattias Marklund

    2010-02-17

    We discuss a two-fold extension of QED assuming the presence of strong external fields provided by an ultra-intense laser and noncommutativity of spacetime. While noncommutative effects leave the electron's intensity induced mass shift unchanged, the photons change significantly in character: they acquire a quasi-momentum that is no longer light-like. We study the consequences of this combined noncommutative strong-field effect for basic lepton-photon interactions.

  13. Quantifying the Uncertainties of Aerosol Indirect Effects and Impacts on Decadal-Scale Climate Variability in NCAR CAM5 and CESM1

    SciTech Connect (OSTI)

    Park, Sungsu

    2014-12-12

    The main goal of this project is to systematically quantify the major uncertainties of aerosol indirect effects due to the treatment of moist turbulent processes that drive aerosol activation, cloud macrophysics and microphysics in response to anthropogenic aerosol perturbations using the CAM5/CESM1. To achieve this goal, the P.I. hired a postdoctoral research scientist (Dr. Anna Fitch) who started her work from the Nov.1st.2012. In order to achieve the project goal, the first task that the Postdoc. and the P.I. did was to quantify the role of subgrid vertical velocity variance on the activation and nucleation of cloud liquid droplets and ice crystals and its impact on the aerosol indirect effect in CAM5. First, we analyzed various LES cases (from dry stable to cloud-topped PBL) to check whether this isotropic turbulence assumption used in CAM5 is really valid. It turned out that this isotropic turbulence assumption is not universally valid. Consequently, from the analysis of LES, we derived an empirical formulation relaxing the isotropic turbulence assumption used for the CAM5 aerosol activation and ice nucleation, and implemented the empirical formulation into CAM5/CESM1, and tested in the single-column and global simulation modes, and examined how it changed aerosol indirect effects in the CAM5/CESM1. These results were reported in the poster section in the 18th Annual CESM workshop held in Breckenridge, CO during Jun.17-20.2013. While we derived an empirical formulation from the analysis of couple of LES from the first task, the general applicability of that empirical formulation was questionable, because it was obtained from the limited number of LES simulations. The second task we did was to derive a more fundamental analytical formulation relating vertical velocity variance to TKE using other information starting from basic physical principles. This was a somewhat challenging subject, but if this could be done in a successful way, it could be directly implemented into the CAM5 as a practical parameterization, and substantially contributes to achieving the project goal. Through an intensive research for about one year, we found appropriate mathematical formulation and tried to implement it into the CAM5 PBL and activation routine as a practical parameterized numerical code. During these processes, however, the Postdoc applied for another position in Sweden, Europe, and accepted a job offer there, and left NCAR in August 2014. In Sweden, Dr. Anna Fitch is still working on this subject in a part time, planning to finalize the research and to write the paper in a near future.

  14. FY 2011 Second Quarter: Demonstration of New Aerosol Measurement Verification Testbed for Present-Day Global Aerosol Simulations

    SciTech Connect (OSTI)

    Koch, D

    2011-03-20

    The regional-scale Weather Research and Forecasting (WRF) model is being used by a DOE Earth System Modeling (ESM) project titled “Improving the Characterization of Clouds, Aerosols and the Cryosphere in Climate Models” to evaluate the performance of atmospheric process modules that treat aerosols and aerosol radiative forcing in the Arctic. We are using a regional-scale modeling framework for three reasons: (1) It is easier to produce a useful comparison to observations with a high resolution model; (2) We can compare the behavior of the CAM parameterization suite with some of the more complex and computationally expensive parameterizations used in WRF; (3) we can explore the behavior of this parameterization suite at high resolution. Climate models like the Community Atmosphere Model version 5 (CAM5) being used within the Community Earth System Model (CESM) will not likely be run at mesoscale spatial resolutions (10–20 km) until 5–10 years from now. The performance of the current suite of physics modules in CAM5 at such resolutions is not known, and current computing resources do not permit high-resolution global simulations to be performed routinely. We are taking advantage of two tools recently developed under PNNL Laboratory Directed Research and Development (LDRD) projects for this activity. The first is the Aerosol Modeling Testbed (Fast et al., 2011b), a new computational framework designed to streamline the process of testing and evaluating aerosol process modules over a range of spatial and temporal scales. The second is the CAM5 suite of physics parameterizations that have been ported into WRF so that their performance and scale dependency can be quantified at mesoscale spatial resolutions (Gustafson et al., 2010; with more publications in preparation).

  15. The Effects of Non-Uniform Electronic Properties on Thin Film Photovoltaics

    E-Print Network [OSTI]

    Brown, Gregory Ferguson

    2011-01-01

    Intensity  in  Thin  Film  Solar  Cells   3.2.1   U.  Rau,  EL)  Intensity   in  Thin  Film  Solar  Cells   3.3  properties  of  thin  film  solar  cell   absorbers,  with  

  16. EMSP Final Report: Electrically Driven Technologies for Radioactive Aerosol Abatement

    SciTech Connect (OSTI)

    DePaoli, D.W.

    2003-01-22

    The purpose of this research project was to develop an improved understanding of how electrically driven processes, including electrocoalescence, acoustic agglomeration, and electric filtration, may be employed to efficiently treat problems caused by the formation of aerosols during DOE waste treatment operations. The production of aerosols during treatment and retrieval operations in radioactive waste tanks and during thermal treatment operations such as calcination presents a significant problem of cost, worker exposure, potential for release, and increased waste volume. There was anecdotal evidence in the literature that acoustic agglomeration and electrical coalescence could be used together to change the size distribution of aerosol particles in such a way as to promote easier filtration and less frequent maintenance of filtration systems. As such, those electrically driven technologies could potentially be used as remote technologies for improved treatment; however, existing theoretical models are not suitable for prediction and design. To investigate the physics of such systems, and also to prototype a system for such processes, a collaborative project was undertaken between Oak Ridge National Laboratory (ORNL) and the University of Texas at Austin (UT). ORNL was responsible for the larger-scale prototyping portion of the project, while UT was primarily responsible for the detailed physics in smaller scale unit reactors. It was found that both electrical coalescence and acoustic agglomeration do in fact increase the rate of aggregation of aerosols. Electrical coalescence requires significantly less input power than acoustic agglomeration, but it is much less effective in its ability to aggregate/coalesce aerosols. The larger-scale prototype showed qualitatively similar results as the unit reactor tests, but presented more difficulty in interpretation of the results because of the complex multi-physics coupling that necessarily occur in all larger-scale system tests. An additional finding from this work is that low-amplitude oscillation may provide an alternative, non-invasive, non-contact means of controlling settling and/or suspension of solids. Further investigation would be necessary to evaluate its utility for radioactive waste treatment applications. This project did not uncover a new technology for radioactive waste treatment. While it may be possible that an efficient electrically driven technology for aerosol treatment could be developed, it appears that other technologies, such as steel and ceramic HEPA filters, can suitably solve this problem. If further studies are to be undertaken, additional fundamental experimentation and modeling is necessary to fully capture the physics; in addition, larger-scale tests are needed to demonstrate the treatment of flowing gas streams through the coupling of acoustic agglomeration with electrocoalescence.

  17. ON COMPUTING UPPER LIMITS TO SOURCE INTENSITIES

    SciTech Connect (OSTI)

    Kashyap, Vinay L.; Siemiginowska, Aneta [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Van Dyk, David A.; Xu Jin [Department of Statistics, University of California, Irvine, CA 92697-1250 (United States); Connors, Alanna [Eureka Scientific, 2452 Delmer Street, Suite 100, Oakland, CA 94602-3017 (United States); Freeman, Peter E. [Department of Statistics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States); Zezas, Andreas, E-mail: vkashyap@cfa.harvard.ed, E-mail: asiemiginowska@cfa.harvard.ed, E-mail: dvd@ics.uci.ed, E-mail: jinx@ics.uci.ed, E-mail: aconnors@eurekabayes.co, E-mail: pfreeman@cmu.ed, E-mail: azezas@cfa.harvard.ed [Physics Department, University of Crete, P.O. Box 2208, GR-710 03, Heraklion, Crete (Greece)

    2010-08-10

    A common problem in astrophysics is determining how bright a source could be and still not be detected in an observation. Despite the simplicity with which the problem can be stated, the solution involves complicated statistical issues that require careful analysis. In contrast to the more familiar confidence bound, this concept has never been formally analyzed, leading to a great variety of often ad hoc solutions. Here we formulate and describe the problem in a self-consistent manner. Detection significance is usually defined by the acceptable proportion of false positives (background fluctuations that are claimed as detections, or Type I error), and we invoke the complementary concept of false negatives (real sources that go undetected, or Type II error), based on the statistical power of a test, to compute an upper limit to the detectable source intensity. To determine the minimum intensity that a source must have for it to be detected, we first define a detection threshold and then compute the probabilities of detecting sources of various intensities at the given threshold. The intensity that corresponds to the specified Type II error probability defines that minimum intensity and is identified as the upper limit. Thus, an upper limit is a characteristic of the detection procedure rather than the strength of any particular source. It should not be confused with confidence intervals or other estimates of source intensity. This is particularly important given the large number of catalogs that are being generated from increasingly sensitive surveys. We discuss, with examples, the differences between these upper limits and confidence bounds. Both measures are useful quantities that should be reported in order to extract the most science from catalogs, though they answer different statistical questions: an upper bound describes an inference range on the source intensity, while an upper limit calibrates the detection process. We provide a recipe for computing upper limits that applies to all detection algorithms.

  18. Generation of Ultra-intense Gamma-ray Train by QED Harmonics

    E-Print Network [OSTI]

    Liu, Chen; Zhang, Xiaomei; Ji, Liangliang; Wang, Wenpeng; Xu, Jiancai; Zhao, Xueyan; Yi, Longqing; Shi, Yin; Zhang, Lingang; Xu, Tongjun; Pei, Zhikun; Xu, Zhizhan

    2015-01-01

    When laser intensity exceeds 10^22W/cm^2, photons with energy above MeV can be generated from high-order harmonics process in the laser-plasma interaction. We find that under such laser intensity, QED effect plays a dominating role in the radiation pattern. Contrast to the gas and relativistic HHG processes, both the occurrence and energy of gamma-ray emission produced by QED harmonics are random and QED harmonics are usually not coherent, while the property of high intensity and ultra-short duration is conserved. Our simulation shows that the period of gamma-ray train is half of the laser period and the peak intensity is 1.4e22W/cm^2. This new harmonic production with QED effects are crucial to light-matter interaction in strong field and can be verified in experiments by 10PW laser facilities in the near future.

  19. Investigation of long-period fiber gratings induced by high-intensity femtosecond UV laser pulses

    E-Print Network [OSTI]

    Nikogosyan, David N.

    efficiency with that for other existing meth- ods of recording. We studied the temperature sensing properties changes in the fiber core induced by thermal heating, were developed. They include the use of a CO2 laserInvestigation of long-period fiber gratings induced by high-intensity femtosecond UV laser pulses

  20. The impact of atmospheric aerosols on trace metal chemistry in open ocean surface seawater 3. Lead

    SciTech Connect (OSTI)

    Maring, H.B.; Duce, R.A. )

    1990-04-15

    Atmospheric aerosols collected at Enewetak Atoll in the tropical North Pacific were exposed to seawater in laboratory experiments to assess the impact of atmospheric aerosols on lead chemistry in surface seawater. The net atmospheric flux of soluble lead to the ocean is between 16 and 32 pmol cm{sup {minus}2}/yr at Enewetak. The stable lead isotopic composition of soluble aerosol lead indicates that it is of anthropogenic origin. Anthropogenic aerosol lead from Central and North America appears to be less soluble and/or to dissolve less rapidly than that from Asia. Dissolved organic matter and possibly lower pH appear to increase the nonaluminosilicate aerosol lead solubility and/or dissolution rate. The isotopic composition of lead in air, seawater and dry deposition suggests that after deposition in the ocean, nonaluminosilicate particulate lead can be reinjected into the atmosphere during sea salt aerosol production.

  1. Optical Intensity Interferometry through Atmospheric Turbulence

    E-Print Network [OSTI]

    Peng Kian Tan; Aik Hui Chan; Christian Kurtsiefer

    2015-12-29

    Conventional ground-based astronomical observations suffer from image distortion due to atmospheric turbulence. This can be minimized by choosing suitable geographic locations or adaptive optical techniques, and avoided altogether by using orbital platforms outside the atmosphere. One of the promises of optical intensity interferometry is its independence from atmospherically induced phase fluctuations. By performing narrowband spectral filtering on sunlight and conducting temporal intensity interferometry using actively quenched avalanche photon detectors (APDs), the Solar $g^{(2)}(\\tau)$ signature was directly measured. We observe an averaged photon bunching signal of $g^{(2)}(\\tau) = 1.693 \\pm 0.003$ from the Sun, consistently throughout the day despite fluctuating weather conditions, cloud cover and elevation angle. This demonstrates the robustness of the intensity interferometry technique against atmospheric turbulence and opto-mechanical instabilities, and the feasibility to implement measurement schemes with both large baselines and long integration times.

  2. Unintended consequences of atmospheric injection of sulphate aerosols.

    SciTech Connect (OSTI)

    Brady, Patrick Vane; Kobos, Peter Holmes; Goldstein, Barry

    2010-10-01

    Most climate scientists believe that climate geoengineering is best considered as a potential complement to the mitigation of CO{sub 2} emissions, rather than as an alternative to it. Strong mitigation could achieve the equivalent of up to -4Wm{sup -2} radiative forcing on the century timescale, relative to a worst case scenario for rising CO{sub 2}. However, to tackle the remaining 3Wm{sup -2}, which are likely even in a best case scenario of strongly mitigated CO{sub 2} releases, a number of geoengineering options show promise. Injecting stratospheric aerosols is one of the least expensive and, potentially, most effective approaches and for that reason an examination of the possible unintended consequences of the implementation of atmospheric injections of sulphate aerosols was made. Chief among these are: reductions in rainfall, slowing of atmospheric ozone rebound, and differential changes in weather patterns. At the same time, there will be an increase in plant productivity. Lastly, because atmospheric sulphate injection would not mitigate ocean acidification, another side effect of fossil fuel burning, it would provide only a partial solution. Future research should aim at ameliorating the possible negative unintended consequences of atmospheric injections of sulphate injection. This might include modeling the optimum rate and particle type and size of aerosol injection, as well as the latitudinal, longitudinal and altitude of injection sites, to balance radiative forcing to decrease negative regional impacts. Similarly, future research might include modeling the optimum rate of decrease and location of injection sites to be closed to reduce or slow rapid warming upon aerosol injection cessation. A fruitful area for future research might be system modeling to enhance the possible positive increases in agricultural productivity. All such modeling must be supported by data collection and laboratory and field testing to enable iterative modeling to increase the accuracy and precision of the models, while reducing epistemic uncertainties.

  3. Laboratory Testing of Aerosol for Enclosure Air Sealing

    SciTech Connect (OSTI)

    Harrington, C.; Modera, M.

    2012-05-01

    Space conditioning energy use can be significantly reduced by addressing uncontrolled infiltration and exfiltration through the envelope of a building. A process for improving the air tightness of a building envelope by sealing shell leaks with an aerosol sealing technology is presented. Both retrofit and new construction applications are possible through applying this process either in attics and crawlspaces or during rough-in stage.

  4. Characterising an Extractive Electrospray Ionisation (EESI) source for the online mass spectrometry analysis of organic aerosols

    E-Print Network [OSTI]

    Gallimore, Peter J.; Kalberer, Markus

    2013-05-28

    is dependent only on the mass of 23   aerosol and is independent of particle size. This again points to a mechanism where particles are fully 24   dissolved in the spray regardless of size. Large particles leave no undissolved “core”. Presumably 25   11... aerosol samples collected 8   onto filters or impactors.13 The disadvantage of offline techniques is that after an extended sample 9   collection period (typically hours) where the aerosol chemical composition may change due to 10   evaporation...

  5. Alveolar targeting of aerosol pentamidine. Toward a rational delivery system

    SciTech Connect (OSTI)

    Simonds, A.K.; Newman, S.P.; Johnson, M.A.; Talaee, N.; Lee, C.A.; Clarke, S.W. )

    1990-04-01

    Nebulizer systems that deposit a high proportion of aerosolized pentamidine on large airways are likely to be associated with marked adverse side effects, which may lead to premature cessation of treatment. We have measured alveolar deposition and large airway-related side effects (e.g., cough, breathlessness, and effect on pulmonary function) after aerosolization of 150 mg pentamidine isethionate labeled with {sup 99m}Tc-Sn-colloid. Nine patients with AIDS were studied using three nebulizer systems producing different droplet size profiles: the Acorn System 22, Respirgard II, and Respirgard II with the inspiratory baffle removed. Alveolar deposition was greatest and side effects least with the nebulizer producing the smallest droplet size profile (Respirgard II), whereas large airway-related side effects were prominent and alveolar deposition lowest with the nebulizer producing the largest droplet size (Acorn System 22). Values for alveolar deposition and adverse airway effects were intermediate using the Respirgard with inspiratory baffle removed, thus indicating the importance of the baffle valve in determining droplet size. Addition of a similar baffle valve to the Acorn System 22 produced a marked improvement in droplet size profile. Selection of a nebulizer that produces an optimal droplet size range offers the advantage of enhancing alveolar targeting of aerosolized pentamidine while reducing large airway-related side effects.

  6. High air volume to low liquid volume aerosol collector

    DOE Patents [OSTI]

    Masquelier, Donald A. (Tracy, CA); Milanovich, Fred P. (Lafayette, CA); Willeke, Klaus (Cincinnati, OH)

    2003-01-01

    A high air volume to low liquid volume aerosol collector. A high volume flow of aerosol particles is drawn into an annular, centripetal slot in a collector which directs the aerosol flow into a small volume of liquid pool contained is a lower center section of the collector. The annular jet of air impinges into the liquid, imbedding initially airborne particles in the liquid. The liquid in the pool continuously circulates in the lower section of the collector by moving to the center line, then upwardly, and through assistance by a rotating deflector plate passes back into the liquid at the outer area adjacent the impinging air jet which passes upwardly through the liquid pool and through a hollow center of the collector, and is discharged via a side outlet opening. Any liquid droplets escaping with the effluent air are captured by a rotating mist eliminator and moved back toward the liquid pool. The collector includes a sensor assembly for determining, controlling, and maintaining the level of the liquid pool, and includes a lower centrally located valve assembly connected to a liquid reservoir and to an analyzer for analyzing the particles which are impinged into the liquid pool.

  7. Real time in situ detection of organic nitrates in atmospheric aerosols

    E-Print Network [OSTI]

    Rollins, Andrew W.

    2011-01-01

    +NO 3 reaction. Atmospheric Chemistry and Physics 2009, 9,radicals (NO 3 ). Atmospheric Chemistry and Physics 2008, 8,aerosol yields. Atmospheric Chemistry and Physics 2009, 9,

  8. New Chemical Aerosol Characterization Methods- Examples Using Agricultural and Urban Airborne Particulate Matter 

    E-Print Network [OSTI]

    Zhou, Lijun

    2010-10-12

    This study explored different chemical characterization methods of agricultural and urban airborne particulate matter. Three different field campaigns are discussed. For the agricultural aerosols, measurement of the chemical ...

  9. Assessing the Effects of Anthropogenic Aerosols on Pacific Storm Track Using a Multiscale Global Climate Model

    SciTech Connect (OSTI)

    Wang, Yuan; Wang, Minghuai; Zhang, Renyi; Ghan, Steven J.; Lin, Yun; Hu, Jiaxi; Pan, Bowen; Levy, Misti; Jiang, Jonathan; Molina, Mario J.

    2014-05-13

    Atmospheric aerosols impact weather and global general circulation by modifying cloud and precipitation processes, but the magnitude of cloud adjustment by aerosols remains poorly quantified and represents the largest uncertainty in estimated forcing of climate change. Here we assess the impacts of anthropogenic aerosols on the Pacific storm track using a multi-scale global aerosol-climate model (GCM). Simulations of two aerosol scenarios corresponding to the present day and pre-industrial conditions reveal long-range transport of anthropogenic aerosols across the north Pacific and large resulting changes in the aerosol optical depth, cloud droplet number concentration, and cloud and ice water paths. Shortwave and longwave cloud radiative forcing at the top of atmosphere are changed by - 2.5 and + 1.3 W m-2, respectively, by emission changes from pre-industrial to present day, and an increased cloud-top height indicates invigorated mid-latitude cyclones. The overall increased precipitation and poleward heat transport reflect intensification of the Pacific storm track by anthropogenic aerosols. Hence, this work provides for the first time a global perspective of the impacts of Asian pollution outflows from GCMs. Furthermore, our results suggest that the multi-scale modeling framework is essential in producing the aerosol invigoration effect of deep convective clouds on the global scale.

  10. Do biomass burning aerosols intensify drought in equatorial Asia during El Nińo?

    E-Print Network [OSTI]

    Tosca, M. G; Randerson, J. T; Zender, C. S; Flanner, M. G; Rasch, P. J

    2010-01-01

    fication of drought-induced biomass burning in Indonesiavariability in global biomass burning emissions from 1997 toChemistry and Physics Do biomass burning aerosols intensify

  11. X-RAY ABSORPTION SPECTROSCOPY FOR THE CHEMICAL CHARACTERIZATION OF ATMOSPHERIC AEROSOLS

    E-Print Network [OSTI]

    Jaklevic, J. M.

    2011-01-01

    aerosol samples and on fly ash samples obtained from powerMajor elements present in fly ash samples obtained both in-

  12. Atmospheric Measurements of Submicron Aerosols at the California-Mexico Border and in Houston, Texas 

    E-Print Network [OSTI]

    Levy, Misti E

    2013-04-29

    as the concentration of Mexico, the submicron aerosols are heavily influenced by vehicle emissions. We observe an average single scattering albedo of 0...

  13. Beyond single particle mass spectrometry: multidimensional characterisation of individual aerosol particles

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Imre, D.

    2009-09-10

    The behavior of small aerosol particles depends on a number of their physical and chemical properties, many of which are strongly coupled. The size, internal composition, density, shape, morphology, hygroscopicity, index of refraction, activity as cloud condensation nuclei and ice nuclei, and other attributes of individual particles - all play a role in determining particle properties and their impacts. The traditional particle characterization approaches rely on separate parallel measurements that average over an ensemble of particles of different sizes and/or compositions and later attempt to draw correlations between them. As a result such studies overlook critical differences between particles and bulk and miss the fact that individual particles often exhibit major differences. Here we review the recently developed methods to simultaneously measure in-situ and in real time several of the attributes for individual particles using single particle mass spectrometer, SPLAT or its second generation SPLAT II. We also discuss novel approaches developed for classification, visualization and mining of large datasets produced by the multidimensional single particle characterization.

  14. Delivering High IntensityDelivering High Intensity Proton Beam:Proton Beam

    E-Print Network [OSTI]

    McDonald, Kirk

    11 Delivering High IntensityDelivering High Intensity Proton Beam:Proton Beam: Lessons for the NextFACT08NuFACT08 ­­ 4 July4 July S. ChildressS. Childress ­­ Proton BeamsProton Beams 22 Presentation OutlinePresentation Outline Key Proton Beam ConsiderationsKey Proton Beam Considerations The First

  15. Properties of Ice Clusters from an Analysis of Freezing Nucleation Ian J. Ford

    E-Print Network [OSTI]

    Ford, Ian

    Properties of Ice Clusters from an Analysis of Freezing Nucleation Ian J. Ford Department, and often freezing nucleation experiments are conducted using finely divided liquids, either as an emulsion5 or an aerosol.6-9 In this way, trace impurities, which might aid the freezing process, are confined

  16. Radiation Dose Measurement for High-Intensity Laser Interactions...

    Office of Scientific and Technical Information (OSTI)

    Radiation Dose Measurement for High-Intensity Laser Interactions with Solid Targets at SLAC Citation Details In-Document Search Title: Radiation Dose Measurement for High-Intensity...

  17. World Best Practice Energy Intensity Values for Selected Industrial Sectors

    E-Print Network [OSTI]

    Worrell, Ernst; Price, Lynn; Neelis, Maarten; Galitsky, Christina; Zhou, Nan

    2007-01-01

    1 2. World Best Practice Energy IntensityBrussels: IISI. Best practice energy use is also determinedalong with the best practice energy intensity value for

  18. World Best Practice Energy Intensity Values for Selected Industrial Sectors

    E-Print Network [OSTI]

    Worrell, Ernst; Price, Lynn; Neelis, Maarten; Galitsky, Christina; Zhou, Nan

    2007-01-01

    Best Practice Final and Primary Energy Intensity Values forWorld Best Practice Primary Energy Intensity Values forRecovered Pulp Note: Primary energy includes electricity

  19. 2014 call for NERSC's Data Intensive Computing Pilot Program...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC's Data Intensive Computing Pilot Program 2014 call for NERSC's Data Intensive Computing Pilot Program Due December 10 November 18, 2013 by Francesca Verdier (0 Comments)...

  20. EIA Energy Efficiency-Residential Sector Energy Intensities,...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Sector Energy Intensities RESIDENTIAL SECTOR ENERGY INTENSITIES: 1978-2005 Released Date: August 2004 Page Last Modified:June 2009 These tables provide estimates of...

  1. ITP Energy Intensive Processes: Improved Heat Recovery in Biomass...

    Broader source: Energy.gov (indexed) [DOE]

    Intensive Processes: Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Guide to Low-Emission Boiler and Combustion Equipment Selection...

  2. Enhancing the energy of terahertz radiation from plasma produced by intense femtosecond laser pulses

    SciTech Connect (OSTI)

    Jahangiri, Fazel [Advanced Research Center for Beam Science, ICR, Kyoto University, Kyoto (Japan) [Advanced Research Center for Beam Science, ICR, Kyoto University, Kyoto (Japan); Laser and Plasma Research Institute, Shahid Beheshti University, Tehran (Iran, Islamic Republic of); Hashida, Masaki; Tokita, Shigeki; Sakabe, Shuji [Advanced Research Center for Beam Science, ICR, Kyoto University, Kyoto (Japan) [Advanced Research Center for Beam Science, ICR, Kyoto University, Kyoto (Japan); Department of Physics, GSS, Kyoto University, Kyoto (Japan); Nagashima, Takeshi; Hangyo, Masanori [Department of Physics, GSS, Kyoto University, Kyoto (Japan) [Department of Physics, GSS, Kyoto University, Kyoto (Japan); Institute of Laser Engineering, Osaka University, Osaka (Japan)

    2013-05-13

    Terahertz (THz) radiation from atomic clusters illuminated by intense femtosecond laser pulses is investigated. By studying the angular distribution, polarization properties and energy dependence of THz waves, we aim to obtain a proper understanding of the mechanism of THz generation. The properties of THz waves measured in this study differ from those predicted by previously proposed mechanisms. To interpret these properties qualitatively, we propose that the radiation is generated by time-varying quadrupoles, which are produced by the ponderomotive force of the laser pulse.

  3. Improving Bulk Microphysics Parameterizations in Simulations of Aerosol Effects

    SciTech Connect (OSTI)

    Wang, Yuan; Fan, Jiwen; Zhang, Renyi; Leung, Lai-Yung R.; Franklin, Charmaine N.

    2013-06-05

    To improve the microphysical parameterizations for simulations of the aerosol indirect effect (AIE) in regional and global climate models, a double-moment bulk microphysical scheme presently implemented in the Weather Research and Forecasting (WRF) model is modified and the results are compared against atmospheric observations and simulations produced by a spectral bin microphysical scheme (SBM). Rather than using prescribed aerosols as in the original bulk scheme (Bulk-OR), a prognostic doublemoment aerosol representation is introduced to predict both the aerosol number concentration and mass mixing ratio (Bulk-2M). The impacts of the parameterizations of diffusional growth and autoconversion and the selection of the embryonic raindrop radius on the performance of the bulk microphysical scheme are also evaluated. Sensitivity modeling experiments are performed for two distinct cloud regimes, maritime warm stratocumulus clouds (SC) over southeast Pacific Ocean from the VOCALS project and continental deep convective clouds (DCC) in the southeast of China from the Department of Energy/ARM Mobile Facility (DOE/AMF) - China field campaign. The results from Bulk-2M exhibit a much better agreement in the cloud number concentration and effective droplet radius in both the SC and DCC cases with those from SBM and field measurements than those from Bulk-OR. In the SC case particularly, Bulk-2M reproduces the observed drizzle precipitation, which is largely inhibited in Bulk-OR. Bulk-2M predicts enhanced precipitation and invigorated convection with increased aerosol loading in the DCC case, consistent with the SBM simulation, while Bulk-OR predicts the opposite behaviors. Sensitivity experiments using four different types of autoconversion schemes reveal that the autoconversion parameterization is crucial in determining the raindrop number, mass concentration, and drizzle formation for warm 2 stratocumulus clouds. An embryonic raindrop size of 40 ?m is determined as a more realistic setting in the autoconversion parameterization. The saturation adjustment employed in calculating condensation/evaporation in the bulk scheme is identified as the main factor responsible for the large discrepancies in predicting cloud water in the SC case, suggesting that an explicit calculation of diffusion growth with predicted supersaturation is necessary for further improvements of the bulk microphysics scheme. Lastly, a larger rain evaporation rate below cloud is found in the bulk scheme in comparison to the SBM simulation, which could contribute to a lower surface precipitation in the bulk scheme.

  4. WHERE ARE THE MOST INTENSE THUNDERSTORMS

    E-Print Network [OSTI]

    Nesbitt, Steve

    provided unparalleled information on the global distribution of intense convective storms. T he Tropical-alti- tude, non-sun-synchronous orbit permits sampling throughout the diurnal cycle of precipitation. The cloud-top temperature of storms has been measured using infrared (IR) bright- ness temperature (Tb

  5. Energy Intensity Indicators: Transportation Energy Consumption

    Broader source: Energy.gov [DOE]

    This section contains an overview of the aggregate transportation sector, combining both passenger and freight segments of this sector. The specific energy intensity indicators for passenger and freight can be obtained from the links, passenger transportation, or freight transportation. For further detail within the transportation sector, download the appropriate Trend Data worksheet containing detailed data and graphics for specific transportation modes.

  6. Adaptive Background Estimation using Intensity Independent Features

    E-Print Network [OSTI]

    Lunds Universitet

    Adaptive Background Estimation using Intensity Independent Features Håkan Ardö, Rikard Berthilsson to rapid changes in lighting conditions. Furthermore, the features can be computed very efficiently using reliable way, also in outdoor scenes where the lighting conditions is changing rapidly due to passing

  7. Ferroplasmons: Intense Localized Surface Plasmons in Metal-Ferromagnetic Nanoparticles

    SciTech Connect (OSTI)

    Sachan, Ritesh [University of Tennessee, Knoxville (UTK); Malasi, Abhinav [ORNL; Ge, Jingxuan [Materials Science and Engineering Department, University of Tennessee, Knoxville, TN, USA; Yadavali, Sagar P [ORNL; Gangopadhyay, Anup [Washington University, St. Louis; Krishna, Dr. Hare [Washington University, St. Louis; Garcia, Hernando [Southern Illinois University; Duscher, Gerd J M [ORNL; Kalyanaraman, Ramki [University of Tennessee, Knoxville (UTK)

    2014-01-01

    Interaction of photons with matter at length scales far below their wavelengths has given rise to many novel phenomena, including localized surface plasmon resonance (LSPR). However, LSPR with narrow bandwidth (BW) is observed only in a select few noble metals, and ferromagnets are not among them. Here, we report the discovery of LSPR in ferromagnetic Co and CoFe alloy (8% Fe) in contact with Ag in the form of bimetallic nanoparticles prepared by pulsed laser dewetting. These plasmons in metal-erromagnetic nanostructures, or ferroplasmons (FP) for short, are in the visible spectrum with comparable intensity and BW to those of the LSPRs from the Ag regions. This finding was enabled by electron energy-loss mapping across individual nanoparticles in a monochromated scanning transmission electron microscope. The appearance of the FP is likely due to plasmonic interaction between the contacting Ag and Co nanoparticles. Since there is no previous evidence for materials that simultaneously show ferromagnetism and such intense LSPRs, this discovery may lead to the design of improved plasmonic materials and applications. It also demonstrates that materials with interesting plasmonic properties can be synthesized using bimetallic nanostructures in contact with each other.

  8. Aerosols and their influence on radiation partitioning and savanna productivity in northern Australia

    SciTech Connect (OSTI)

    Kanniah, K. D.; Beringer, J.; Tapper, N. J.; Long, Charles N.

    2010-05-01

    We investigated the effect of aerosols and clouds on the Net Ecosystem Productivity (NEP) of savannas in northern Australia using aerosol optical depth, clouds and radiation data from the Atmospheric Radiation Measurement (ARM) site in Darwin and carbon flux data measured from eddy covariance techniques from a site at Howard Springs, 35km southeast of Darwin. Generally we found that the concentration of aerosols in this region was relatively low than observed at other sites, therefore the proportion of diffuse radiation reaching the earths surface was only ~ 30%. As a result, we observed only a modest change in carbon uptake under aerosol laden skies and there was no significant difference for dry season Radiation Use Efficiency (RUE) between clear sky, aerosols or thin clouds. On the other hand thick clouds in the wet season produce much more diffuse radiation than aerosols or thin clouds and therefore the initial canopy quantum efficiency was seen to increase 45 and 2.5 times more than under thin clouds and aerosols respectively. The normalized carbon uptake under thick clouds is 57% and 50% higher than under aerosols and thin clouds respectively even though the total irradiance received under thick clouds was reduced 59% and 50% than under aerosols and thin clouds respectively. However, reduction in total irradiance decreases the mean absolute carbon uptake as much as 22% under heavy cloud cover compared to thin clouds or aerosols. Thus, any increase in aerosol concentration or cloud cover that can enhance the diffuse component may have large impacts on productivity in this region.

  9. The contribution of fungal spores and bacteria to regional and global aerosol number and ice nucleation immersion freezing rates

    E-Print Network [OSTI]

    Spracklen, D. V.

    Primary biological aerosol particles (PBAPs) may play an important role in aerosol–climate interactions, in particular by affecting ice formation in mixed phase clouds. However, the role of PBAPs is poorly understood because ...

  10. Effect of oxidant concentration, exposure time, and seed particles on secondary organic aerosol chemical composition and yield

    E-Print Network [OSTI]

    Lambe, A. T.

    We performed a systematic intercomparison study of the chemistry and yields of secondary organic aerosol (SOA) generated from OH oxidation of a common set of gas-phase precursors in a Potential Aerosol Mass (PAM) continuous ...

  11. Simultaneous electronic and the magnetic excitation of a ferromagnet by intense THz pulses

    E-Print Network [OSTI]

    Shalaby, Mostafa; Hauri, Christoph P

    2015-01-01

    The speed of magnetization reversal is a key feature in magnetic data storage. Magnetic fields from intense THz pulses have been recently shown to induce small magnetization dynamics in Cobalt thin film on the sub-picosecond time scale. Here, we show that at higher field intensities, the THz electric field starts playing a role, strongly changing the dielectric properties of the cobalt thin film. Both the electronic and magnetic responses are found to occur simultaneously, with the electric field response persistent on a time scale orders of magnitude longer than the THz stimulus

  12. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  13. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  14. Phase partitioning and volatility of secondary organic aerosol components formed from ?-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A.; Daumit, K.; Hunter, J.; et al

    2015-02-18

    We measured a large suite of gas and particle phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gasmore »and particle phases, the latter being detected upon temperature programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO HR-ToF-CIMS are highly correlated with, and explain at least 25–50% of, the organic aerosol mass measured by an Aerodyne Aerosol Mass Spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from large molecular weight organics and/or oligomers (i.e. multi-phase accretion reaction products). Approximately 50% of the HR-ToF-CIMS particle phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption temperature based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas–particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  15. Phase partitioning and volatility of secondary organic aerosol components formed from ?-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M.; Rubach, F.; Kleist, E.; Wildt, J.; Mentel, Th. F.; Carrasquillo, A. J.; Daumit, K. E.; Hunter, J. F.; et al

    2015-07-16

    We measured a large suite of gas- and particle-phase multi-functional organic compounds with a Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS) developed at the University of Washington. The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We focus here on results from experiments utilizing an ionization method most selective towards acids (acetate negative ion proton transfer), but our conclusions are based on more general physical and chemical properties of the SOA. Hundreds of compounds were observed in both gas andmore »particle phases, the latter being detected by temperature-programmed thermal desorption of collected particles. Particulate organic compounds detected by the FIGAERO–HR-ToF-CIMS are highly correlated with, and explain at least 25–50 % of, the organic aerosol mass measured by an Aerodyne aerosol mass spectrometer (AMS). Reproducible multi-modal structures in the thermograms for individual compounds of a given elemental composition reveal a significant SOA mass contribution from high molecular weight organics and/or oligomers (i.e., multi-phase accretion reaction products). Approximately 50 % of the HR-ToF-CIMS particle-phase mass is associated with compounds having effective vapor pressures 4 or more orders of magnitude lower than commonly measured monoterpene oxidation products. The relative importance of these accretion-type and other extremely low volatility products appears to vary with photochemical conditions. We present a desorption-temperature-based framework for apportionment of thermogram signals into volatility bins. The volatility-based apportionment greatly improves agreement between measured and modeled gas-particle partitioning for select major and minor components of the SOA, consistent with thermal decomposition during desorption causing the conversion of lower volatility components into the detected higher volatility compounds.« less

  16. Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected

    E-Print Network [OSTI]

    Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than (2006), Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected, Geophys. Res. Lett., 33, L17811, doi:10.1029/ 2006GL026899. [2] Anthropogenic air pollution poses

  17. Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of

    E-Print Network [OSTI]

    Goldstein, Allen

    Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed 19, 2012 (received for review July 22, 2012) Emissions from gasoline and diesel vehicles and diesel vehicles, and find diesel exhaust is seven times more efficient at forming aerosol than gasoline

  18. A VIBRATIONAL SPECTROSCOPIC STUDY OF AQUEOUS HYDROGEN HALIDE SOLUTIONS: APPLICATION TO ATMOSPHERIC AEROSOL CHEMISTRY

    E-Print Network [OSTI]

    Heterogeneous reactions on the surfaces of atmospheric aerosols play an important role in atmospheric chemistryA VIBRATIONAL SPECTROSCOPIC STUDY OF AQUEOUS HYDROGEN HALIDE SOLUTIONS: APPLICATION TO ATMOSPHERIC AEROSOL CHEMISTRY A Thesis Presented in Partial Fulfillment of the Requirements for the Degree Master

  19. Simulation of Aerosol-Cloud Interactions in the WRF Model at the Southern Great Plains Site 

    E-Print Network [OSTI]

    Vogel, Jonathan 1988-

    2012-08-21

    for the aerosol indirect effect and a modified Goddard shortwave radiation scheme for the aerosol direct effect. The three cases studied include a developing low pressure system, a low precipitation event of mainly cirrus clouds, and a cold frontal passage. Three...

  20. Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes

    E-Print Network [OSTI]

    Goldstein, Allen

    Gas-phase products and secondary aerosol yields from the ozonolysis of ten different terpenes Anita to examine the gas-phase oxidation product and secondary organic aerosol (SOA) yields from these reactions spectrometer (PTR-MS) was used to monitor the evolution of gas-phase products, identified by their mass

  1. Surface aerosol radiative forcing derived from collocated ground-based radiometric

    E-Print Network [OSTI]

    Liou, K. N.

    Surface aerosol radiative forcing derived from collocated ground-based radiometric observations-Filter Rotating Shadowband Radiometer data match closely with those from the Cimel sun- photometer data for two of the sunphotometer to retrieve aerosol optical depths, a, along with observed surface flux data from field campaigns

  2. Aerosol Optical Depth Prediction from Satellite Observations by Multiple Instance Regression

    E-Print Network [OSTI]

    Vucetic, Slobodan

    Aerosol Optical Depth Prediction from Satellite Observations by Multiple Instance Regression airborne particles that both reflect and absorb incoming solar radiation and whose effect on the Earth the satellite measure- ments, the common objective is prediction of Aerosol Opti- cal Depth (AOD). An important

  3. Determination of aerosol optical depth using a Micro Total Ozone Spectrometer II (MICROTOPS II) sunphotometer

    E-Print Network [OSTI]

    of Energy, the Office of Educational Program, the National Science Foundation and the Louis Stokes Alliances solar radiation. These effects are quantified by the aerosol optical depth (AOD), which is the exponential decrease in solar radiation, due to the presence of aerosols. We performed the retrievals of AOD

  4. Heterogeneous freezing of ice on atmospheric aerosols containing ash, soot, and soil

    E-Print Network [OSTI]

    Heterogeneous freezing of ice on atmospheric aerosols containing ash, soot, and soil Adam P. Fornea in the atmosphere often occurs through heterogeneous freezing processes in which an atmospheric aerosol acts, heterogeneous nucleation may occur through one of several freezing mechanisms, including contact and immersion

  5. Three-dimensional simulations of inorganic aerosol distributions in east Asia during spring 2001

    E-Print Network [OSTI]

    . The Asian outflow during March and April of 2001 is heavily polluted with high aerosol loadings. Under size and gas-aerosol distributions along air mass trajectories, a situation that is analyzed in detail, University of Hawaii, Honolulu, Hawaii, USA. Copyright 2004 by the American Geophysical Union. 0148

  6. Evaluating aerosol direct radiative effects on global terrestrial ecosystem carbon dynamics from

    E-Print Network [OSTI]

    Zhuang, Qianlai

    loading normally induces lower solar energy arriving at the land surface whereas plant photosynthesis of diffuse solar radiation for plant carbon uptake. Comparing with direct-beam solar radiation, diffuse solar to quantify aerosol effects on downward solar radiation. Simulations with and without considering the aerosol

  7. Spectral absorption of solar radiation by aerosols during ACE-Asia R. W. Bergstrom,1

    E-Print Network [OSTI]

    slightly with wavelength in the visible region. We interpret these results in light of the two absorbing by black carbon mixed with nonabsorbing pollution aerosols. For the 12 April case we attempt to estimate a relatively complicated aerosol mixture of both industrial pollution (including black carbon) and mineral dust

  8. MEASUREMENT BASED DETERMINATION OF AEROSOL FORCINGS AT ARM SITES: PROPOSED JOINT ASP-ARM STUDY

    E-Print Network [OSTI]

    MEASUREMENT BASED DETERMINATION OF AEROSOL FORCINGS AT ARM SITES: PROPOSED JOINT ASP-ARM STUDY Stephen E. Schwartz For presentation at the Atmospheric Radiation Measurement (ARM) Program Science Team) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site. There are numerous aerosol forcings

  9. Organic nitrogen in aerosols and precipitation at Barbados and Miami: Implications regarding sources, transport

    E-Print Network [OSTI]

    Hansell, Dennis

    Organic nitrogen in aerosols and precipitation at Barbados and Miami: Implications regarding time series sites: Barbados and Miami. WSON total deposition rates ranged from 17.9 mmol m-2 yr-1 to 49), Organic nitrogen in aerosols and precipitation at Barbados and Miami: Implications regarding sources

  10. Ultra-Fast Absorption of Amorphous Pure Drug Aerosols Via Deep Lung Inhalation

    E-Print Network [OSTI]

    Rabinowitz, Joshua D.

    Ultra-Fast Absorption of Amorphous Pure Drug Aerosols Via Deep Lung Inhalation JOSHUA D. RABINOWITZ. A promising means of accelerating drug action is through rapid systemic drug administration via deep lung inhalation. The speed of pulmonary drug absorption depends on the site of aerosol deposition within the lung

  11. Statistical analysis of aerosol species, trace gasses, and meteorology in Chicago

    E-Print Network [OSTI]

    O'Brien, Timothy E.

    ) and principal component analysis (PCA) were applied to atmospheric aerosol and trace gas concentrations and Schmeling 2006, 2007; Shen et al. 2009). The composition of aerosols is region-specific and encompasses inorganic and organic species of natural and anthropogenic ori- gin, present due to primary emission

  12. Cloud/Aerosol Parameterizations: Application and Improvement of General Circulation Models

    SciTech Connect (OSTI)

    Penner, Joyce

    2012-06-30

    One of the biggest uncertainties associated with climate models and climate forcing is the treatment of aerosols and their effects on clouds. The effect of aerosols on clouds can be divided into two components: The first indirect effect is the forcing associated with increases in droplet concentrations; the second indirect effect is the forcing associated with changes in liquid water path, cloud morphology, and cloud lifetime. Both are highly uncertain. This project applied a cloud-resolving model to understand the response of clouds under a variety of conditions to changes in aerosols. These responses are categorized according to the large-scale meteorological conditions that lead to the response. Meteorological conditions were sampled from various fields, which, together with a global aerosol model determination of the change in aerosols from present day to pre-industrial conditions, was used to determine a first order estimate of the response of global cloud fields to changes in aerosols. The response of the clouds in the NCAR CAM3 GCM coupled to our global aerosol model were tested by examining whether the response is similar to that of the cloud resolving model and methods for improving the representation of clouds and cloud/aerosol interactions were examined.

  13. SUPPLEMENTARY INFORMATION FOR:1 Chemically-Resolved Aerosol Volatility Measurements from Two Megacity Field

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    SUPPLEMENTARY INFORMATION FOR:1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Chemically-Resolved Aerosol from factor analysis of AMS spectra in several studies. 2 / 13 #12;BBOA: Biomass burning organic aerosol. In Mexico City BBOA originated mostly from wildfire and agricultural burning, but wood-fired

  14. Atmospheric Environment 41 (2007) 73897400 Fire and biofuel contributions to annual mean aerosol mass

    E-Print Network [OSTI]

    Jacob, Daniel J.

    2007-01-01

    Atmospheric Environment 41 (2007) 7389­7400 Fire and biofuel contributions to annual mean aerosol estimate the contributions from biomass burning (summer wildfires, other fires, residential biofuel, and industrial biofuel) to seasonal and annual aerosol concentrations in the United States. Our approach

  15. Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey components

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey December 2013 A method for separating the three components of the marine stratocumulus (MSC) aerosol cloud interactions radiative effects, i.e., the cloud cover, liquid water path (LWP) and cloud drop radius (Twomey

  16. Cloud seeding as a technique for studying aerosol-cloud interactions in marine stratocumulus

    E-Print Network [OSTI]

    Miami, University of

    Cloud seeding as a technique for studying aerosol-cloud interactions in marine stratocumulus hygroscopic aerosols were introduced into a solid marine stratocumulus cloud (200 m thick) by burning hygroscopic flares mounted on an aircraft. The cloud microphysical response in two parallel seeding plumes

  17. Storage-Intensive Supercomputing Benchmark Study

    SciTech Connect (OSTI)

    Cohen, J; Dossa, D; Gokhale, M; Hysom, D; May, J; Pearce, R; Yoo, A

    2007-10-30

    Critical data science applications requiring frequent access to storage perform poorly on today's computing architectures. This project addresses efficient computation of data-intensive problems in national security and basic science by exploring, advancing, and applying a new form of computing called storage-intensive supercomputing (SISC). Our goal is to enable applications that simply cannot run on current systems, and, for a broad range of data-intensive problems, to deliver an order of magnitude improvement in price/performance over today's data-intensive architectures. This technical report documents much of the work done under LDRD 07-ERD-063 Storage Intensive Supercomputing during the period 05/07-09/07. The following chapters describe: (1) a new file I/O monitoring tool iotrace developed to capture the dynamic I/O profiles of Linux processes; (2) an out-of-core graph benchmark for level-set expansion of scale-free graphs; (3) an entity extraction benchmark consisting of a pipeline of eight components; and (4) an image resampling benchmark drawn from the SWarp program in the LSST data processing pipeline. The performance of the graph and entity extraction benchmarks was measured in three different scenarios: data sets residing on the NFS file server and accessed over the network; data sets stored on local disk; and data sets stored on the Fusion I/O parallel NAND Flash array. The image resampling benchmark compared performance of software-only to GPU-accelerated. In addition to the work reported here, an additional text processing application was developed that used an FPGA to accelerate n-gram profiling for language classification. The n-gram application will be presented at SC07 at the High Performance Reconfigurable Computing Technologies and Applications Workshop. The graph and entity extraction benchmarks were run on a Supermicro server housing the NAND Flash 40GB parallel disk array, the Fusion-io. The Fusion system specs are as follows: SuperMicro X7DBE Xeon Dual Socket Blackford Server Motherboard; 2 Intel Xeon Dual-Core 2.66 GHz processors; 1 GB DDR2 PC2-5300 RAM (2 x 512); 80GB Hard Drive (Seagate SATA II Barracuda). The Fusion board is presently capable of 4X in a PCIe slot. The image resampling benchmark was run on a dual Xeon workstation with NVIDIA graphics card (see Chapter 5 for full specification). An XtremeData Opteron+FPGA was used for the language classification application. We observed that these benchmarks are not uniformly I/O intensive. The only benchmark that showed greater that 50% of the time in I/O was the graph algorithm when it accessed data files over NFS. When local disk was used, the graph benchmark spent at most 40% of its time in I/O. The other benchmarks were CPU dominated. The image resampling benchmark and language classification showed order of magnitude speedup over software by using co-processor technology to offload the CPU-intensive kernels. Our experiments to date suggest that emerging hardware technologies offer significant benefit to boosting the performance of data-intensive algorithms. Using GPU and FPGA co-processors, we were able to improve performance by more than an order of magnitude on the benchmark algorithms, eliminating the processor bottleneck of CPU-bound tasks. Experiments with a prototype solid state nonvolative memory available today show 10X better throughput on random reads than disk, with a 2X speedup on a graph processing benchmark when compared to the use of local SATA disk.

  18. Passive, Noiseless, Intensity Amplification of Repetitive Signals

    E-Print Network [OSTI]

    Maram, R; Li, M; Azańa, J

    2014-01-01

    Amplification of signal intensity is essential for initiating physical processes, diagnostics, sensing, communications, and scientific measurement. During traditional amplification, the signal is amplified by multiplying the signal carriers through an active gain process using an external power source. However, for repetitive waveforms, sufficient energy for amplification often resides in the signal itself. In such cases, the unneeded external power is wasted, and the signal is additionally degraded by noise and distortions that accompany active gain processes. We show noiseless, intensity amplification of repetitive optical pulse waveforms with a gain from 2 to ~20 without using active gain, by recycling energy already stored in the input repetitive signal. This "green" method uses dispersion-induced self-imaging (Talbot) effects to precisely re-distribute the original signal energy into fewer replica waveforms. This approach simply requires a suitable manipulation of the input signal's phase profile along t...

  19. Flammability and Combustion Behaviors in Aerosols Formed by Industrial Heat Transfer Fluids Produced by the Electrospray Method 

    E-Print Network [OSTI]

    Lian, Peng

    2012-10-19

    in aerosols and the influence of the presence of fuel droplets in the system are studied in the aerosol ignition tests. Flames in aerosols are characterized by non-uniform shapes and discrete flame fronts. Flames were observed in different burning modes...

  20. Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core-Shell Morphologies

    E-Print Network [OSTI]

    Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core of oleic acid aerosol particles with ozone are studied below 1% relative humidity. The particles have inert of the organic layer is monitored with increasing ozone exposure by using an aerosol mass spectrometer

  1. Intensive Variables & Nanostructuring in Magnetostructural Materials

    SciTech Connect (OSTI)

    Lewis, Laura

    2014-08-13

    Over the course of this project, fundamental inquiry was carried out to investigate, understand and predict the effects of intensive variables, including the structural scale, on magnetostructural phase transitions in the model system of equiatomic FeRh. These transitions comprise simultaneous magnetic and structural phase changes that have their origins in very strong orbital-lattice coupling and thus may be driven by a plurality of effects.

  2. Nuclear astrophysics with intense photon beam

    SciTech Connect (OSTI)

    Shizuma, Toshiyuki [Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan)

    2012-07-09

    Quasi-monochromatic photon beams generated by inverse Compton scattering of laser light with high energy electrons can be used for precise measurements of photoneutrons and resonant scattered {gamma} rays. Extremely high intensity and small energy spreading width of the photon beam expected at the ELI Nuclear Physics facility would increase the experimental sensitivities considerably. Possible photonuclear reaction measurements relevant to the p-process nucleosynthesis are discussed.

  3. Pre-Cloud Aerosol, Cloud Droplet Concentration, and Cloud Condensation Nuclei from the VAMOS Ocean-Cloud-Atmosphere Land Study (VOCALS) Field Campaign First Quarter 2010 ASR Program Metric Report

    SciTech Connect (OSTI)

    Kleinman, LI; Springston, SR; Daum, PH; Lee, Y-N; Sedlacek, AJ; Senum, G; Wang, J

    2011-08-31

    In this, the first of a series of Program Metric Reports, we (1) describe archived data from the DOE G-1 aircraft, (2) illustrate several relations between sub-cloud aerosol, CCN, and cloud droplets pertinent to determining the effects of pollutant sources on cloud properties, and (3) post to the data archive an Excel spreadsheet that contains cloud and corresponding sub-cloud data.

  4. Electron mean free path from angle-dependent photoelectron spectroscopy of aerosol particles

    SciTech Connect (OSTI)

    Goldmann, Maximilian; Miguel-Sánchez, Javier; West, Adam H. C.; Yoder, Bruce L.; Signorell, Ruth

    2015-06-14

    We propose angle-resolved photoelectron spectroscopy of aerosol particles as an alternative way to determine the electron mean free path of low energy electrons in solid and liquid materials. The mean free path is obtained from fits of simulated photoemission images to experimental ones over a broad range of different aerosol particle sizes. The principal advantage of the aerosol approach is twofold. First, aerosol photoemission studies can be performed for many different materials, including liquids. Second, the size-dependent anisotropy of the photoelectrons can be exploited in addition to size-dependent changes in their kinetic energy. These finite size effects depend in different ways on the mean free path and thus provide more information on the mean free path than corresponding liquid jet, thin film, or bulk data. The present contribution is a proof of principle employing a simple model for the photoemission of electrons and preliminary experimental data for potassium chloride aerosol particles.

  5. Apparatus having reduced background for measuring radiation activity in aerosol particles

    DOE Patents [OSTI]

    Rodgers, John C. (Santa Fe, NM); McFarland, Andrew R. (College Station, TX); Oritz, Carlos A. (Bryan, TX); Marlow, William H. (College Station, TX)

    1992-01-01

    Apparatus having reduced background for measuring radiation activity in aerosol particles. A continuous air monitoring sampler is described for use in detecting the presence of alpha-emitting aerosol particles. An inlet fractionating screen has been demonstrated to remove about 95% of freshly formed radon progeny from the aerosol sample, and approximately 33% of partially aged progeny. Addition of an electrical condenser and a modified dichotomous virtual impactor are expected to produce considerable improvement in these numbers, the goal being to enrich the transuranic (TRU) fraction of the aerosols. This offers the possibility of improving the signal-to-noise ratio for the detected alpha-particle energy spectrum in the region of interest for detecting TRU materials associated with aerosols, thereby enhancing the performance of background-compensation algorithms for improving the quality of alarm signals intended to warn personnel of potentially harmful quantities of TRU materials in the ambient air.

  6. Direct Aerosol Forcing: Sensitivity to Uncertainty in Measurements of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent BondingMeetingDifferences BetweenDirac Charge DynamcsAerosol

  7. Modeling aerosol growth by aqueous chemistry in nonprecipitating stratiform cloud

    SciTech Connect (OSTI)

    Ovchinnikov, Mikhail; Easter, Richard C.

    2010-07-29

    A new microphysics module based on a two-dimensional (2D) joint size distribution function representing both interstitial and cloud particles is developed and applied to studying aerosol processing in non-precipitating stratocumulus clouds. The module is implemented in a three-dimensional dynamical framework of a large-eddy simulation (LES) model and in a trajectory ensemble model (TEM). Both models are used to study the modification of sulfate aerosol by the activation - aqueous chemistry - resuspension cycle in shallow marine stratocumulus clouds. The effect of particle mixing and different size-distribution representations on modeled aerosol processing are studied in a comparison of the LES and TEM simulations with the identical microphysics treatment exposes and a comparison of TEM simulations with a 2D fixed and moving bin microphysics. Particle mixing which is represented in LES and neglected in the TEM leads to the mean relative per particle dry mass change in the TEM simulations being about 30% lower than in analogous subsample of LES domain. Particles in the final LES spectrum are mixed in from different “parcels”, some of which have experienced longer in-cloud residence times than the TEM parcels, all of which originated in the subcloud layer, have. The mean relative per particle dry mass change differs by 14% between TEM simulations with fixed and moving bin microphysics. Finally, the TEM model with the moving bin microphysics is used to evaluate assumptions about liquid water mass partitioning among activated cloud condensation nuclei (CCN) of different dry sizes. These assumptions are used in large-scale models to map the bulk aqueous chemistry sulfate production, which is largely proportional to the liquid water mass, to the changes in aerosol size distribution. It is shown that the commonly used assumptions that the droplet mass is independent of CCN size or that the droplet mass is proportional to the CCN size to the third power do not perform well in the considered case. The explicitly predicted water partitioning indicates that the mean mass of droplets participating in the models aqueous chemistry calculations is proportional to the dry CCN size.

  8. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, T.

    1987-07-14

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

  9. Dosimeter for monitoring vapors and aerosols of organic compounds

    DOE Patents [OSTI]

    Vo-Dinh, Tuan (625 Gulfwood Rd., Knoxville, TN 37923)

    1987-01-01

    A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique.

  10. ARM - Publications: Science Team Meeting Documents: A decade long aerosol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better AnodeThe Influence of Clouds, Aerosols,Comparison of Cloud-RadiativeMidlatitudeandModel

  11. ARM - Publications: Science Team Meeting Documents: Aerosol Research at the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better AnodeThe Influence of Clouds, Aerosols,Comparison ofTropicalState BestDecomposition inArctic

  12. ARM - Publications: Science Team Meeting Documents: Effects of Aerosol Size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better AnodeThe Influence of Clouds, Aerosols,Comparisonat the ARM Climatefraction

  13. ARM - Publications: Science Team Meeting Documents: Impacts of aerosols and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better AnodeThe Influence of Clouds, Aerosols,Comparisonat the ARMCarlo IndependentMomentsthe

  14. ARM - Publications: Science Team Meeting Documents: The SGP Aerosol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better AnodeThe Influence of Clouds, Aerosols,Comparisonatvariability:Best-Estimate Value-Added

  15. ARM - Field Campaign - Aerosol Life Cycle IOP at BNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See22, 2012III ARMgovCampaignsAbsolutegovCampaignsAerosol

  16. Observed Aerosol Radiative Forcings: Comparison for Natural and Anthropogenic Sources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access to scienceSpeedingLightweight MaterialsGasObservation oftheAerosol

  17. PNNL-MILAGRO Aerosol Modeling in Mexico | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly Smart GridNorth Carolina: Energy ResourcesLLC JumpMILAGRO Aerosol

  18. 5.12 Ocean-Derived Aerosol and Its Climate Impacts PK Quinn and TS Bates, NOAA Pacific Marine Environmental Laboratory, Seattle, WA, USA

    E-Print Network [OSTI]

    5.12 Ocean-Derived Aerosol and Its Climate Impacts PK Quinn and TS Bates, NOAA Pacific Marine Environmental Laboratory, Seattle, WA, USA Published by Elsevier Ltd. 5.12.1 Introduction 317 5.12.2 Ocean-Derived Aerosol Production Mechanisms 317 5.12.3 Radiative Effects of Ocean-Derived Aerosol 319 5.12.3.1 Aerosol

  19. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Hildebrandt Ruiz, L.; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2015-01-12

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), and organic mass-to-organic carbon (OM : OC) ratios, and of carbon oxidation state (OS C) for a vastly expanded laboratory data set of multifunctional oxidized OA standards. For the expanded standard data set, the method introduced by Aiken et al. (2008), which uses experimentally measured ionmore »intensities at all ions to determine elemental ratios (referred to here as "Aiken-Explicit"), reproduces known O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12%, respectively. The more commonly used method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions (referred to here as "Aiken-Ambient"), reproduces O : C and H : C of multifunctional oxidized species within 28 and 14% of known values. The values from the latter method are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and especially H2O+ produced from many oxidized species. Combined AMS–vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method uses specific ion fragments as markers to correct for molecular functionality-dependent systematic biases and reproduces known O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C (H : C) values is smaller for theoretical standard mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OS C values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OS C units). This indicates that OS C is a more robust metric of oxidation than O : C, likely since OS C is not affected by hydration or dehydration, either in the atmosphere or during analysis.« less

  20. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Hildebrandt Ruiz, L.; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2014-07-31

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), organic mass-to-organic carbon (OM : OC), and carbon oxidation state (OSC) for a vastly expanded laboratory dataset of multifunctional oxidized OA standards. For the expanded standard dataset, the "Aiken-Explicit" method (Aiken et al., 2008), which uses experimentally measured ion intensities at all ions to determine elementalmore »ratios, reproduces known molecular O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12% respectively. The more commonly used "Aiken-Ambient" method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions, reproduces O : C and H : C of multifunctional oxidized species within 28% and 14% of known values. These values are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and H2O+ produced from many oxidized species. Combined AMS-vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method reduces the systematic biases and reproduces O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C and H : C values is smaller (12% and 4% respectively) for synthetic mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OSC values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OSC units). This indicates that OSC is a more robust metric of oxidation than O : C, likely since OSC is not affected by hydration or dehydration, either in the atmosphere or during analysis.« less

  1. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: Characterization, improved calibration, and implications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canagaratna, M. R.; Jimenez, J. L.; Kroll, J. H.; Chen, Q.; Kessler, S. H.; Massoli, P.; Ruiz, L. Hildebrandt; Fortner, E.; Williams, L. R.; Wilson, K. R.; et al

    2015-01-12

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), and organic mass-to-organic carbon (OM : OC) ratios, and of carbon oxidation state (OS C) for a vastly expanded laboratory data set of multifunctional oxidized OA standards. For the expanded standard data set, the method introduced by Aiken et al. (2008), which uses experimentally measured ionmore »intensities at all ions to determine elemental ratios (referred to here as "Aiken-Explicit"), reproduces known O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12%, respectively. The more commonly used method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions (referred to here as "Aiken-Ambient"), reproduces O : C and H : C of multifunctional oxidized species within 28 and 14% of known values. The values from the latter method are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and especially H2O+ produced from many oxidized species. Combined AMS–vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method uses specific ion fragments as markers to correct for molecular functionality-dependent systematic biases and reproduces known O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C (H : C) values is smaller for theoretical standard mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OS C values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OS C units). This indicates that OS C is a more robust metric of oxidation than O : C, likely since OS C is not affected by hydration or dehydration, either in the atmosphere or during analysis.« less

  2. Measurements of the chemical, physical, and optical properties of single aerosol particles

    E-Print Network [OSTI]

    Moffet, Ryan Christopher

    2007-01-01

    Index and Density Analytical Chemistry 77, 6535-6541.mass spectrometer, Analytical Chemistry, 78 (24), 8281-8289,instrumentation, Analytical Chemistry, 77 (12), 3861-3885,

  3. Chemistry of atmospheric aerosol particles and their resulting warm cloud-nucleation properties

    E-Print Network [OSTI]

    Moore, Meagan Julia Kerry

    2011-01-01

    detection efficiency, Analytical Chemistry, 76, 712-719,Portable ATOFMS, Analytical Chemistry, 69, 4083-4091, 1997.Network, ART-2A, Analytical Chemistry, 71 (4), 860-865,

  4. The Evolution of the Physicochemical Properties of Aerosols in the Atmosphere 

    E-Print Network [OSTI]

    Tomlinson, Jason

    2011-02-22

    with an average kappa?between 0.01 and 0.05 for all dry particle diameters. Cloud condensation nuclei closure was attained at a supersaturation of 0.2 percent for all particles within the free troposphere by either assuming a pure ammonium bisulfate composition...

  5. Chemistry of atmospheric aerosol particles and their resulting warm cloud-nucleation properties

    E-Print Network [OSTI]

    Moore, Meagan Julia Kerry

    2011-01-01

    for CCN activation, Atmospheric Chemistry and Physics, 10,and precipitation, Atmospheric Chemistry and Physics, 9,dust particles. Atmospheric Chemistry and Physics, 2009, 9,

  6. Measurements of the chemical, physical, and optical properties of single aerosol particles

    E-Print Network [OSTI]

    Moffet, Ryan Christopher

    2007-01-01

    and M.J. Molina: Mexico City basin wind circulation duringDistinct wind convergence patterns in the Mexico City basinMexico City was strongly influenced by continually changing emission sources and strong winds

  7. Variability of aerosol optical properties derived from in situ aircraft measurements during ACE-Asia

    E-Print Network [OSTI]

    Clarke, Antony

    , and Cameron S. McNaughton Department of Oceanography, University of Hawaii, Honolulu, Hawaii, USA Received 29 and artifacts are characterized using in-flight measurements of particle-free air and measurements dominant components, fine-mode pollution and coarse-mode mineral dust, were observed to vary independently

  8. Fuel and diluent property effects during wet compression of a fuel aerosol under RCM conditions

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    to either greater compositional (Leg > 1) or thermal (Leg stratification. For large hydrocarbons diffusivity, qgDg, which controls the rate of gas phase mass diffusion, and thus compositional stratification stratification could be significant; this characteristic has the potential to complicate interpretation

  9. Correlations between Optical, Chemical and Physical Properties of Biomass Burn Aerosols

    E-Print Network [OSTI]

    2008-01-01

    laboratory measurements of biomass-burning emissions: 1.tar balls: Particles from biomass and biofuel burning, J.Eleuterio (2005), A review of biomass burning emissions part

  10. Chemistry of atmospheric aerosol particles and their resulting warm cloud-nucleation properties

    E-Print Network [OSTI]

    Moore, Meagan Julia Kerry

    2011-01-01

    CCN activation, Atmospheric Chemistry and Physics, 10, 5241-precipitation, Atmospheric Chemistry and Physics, 9, 3223-particles. Atmospheric Chemistry and Physics, 2009, 9, A. P.

  11. REPRESENTING AEROSOL DYNAMICS AND PROPERTIES IN CHEMICAL TRANSPORT MODELS BY THE METHOD OF MOMENTS

    E-Print Network [OSTI]

    shortwave (solar) radiation, affecting climate (Charlson et al., 1992; Schwartz, 1996) and visibility this distribution and its evolution in chemical transport models. Atmospheric chemical transport models to date

  12. Moment-based simulation of microphysical properties of sulfate aerosols in the eastern United States

    E-Print Network [OSTI]

    and time series variations of sulfate mass concentrations. The model successfully captured the observed, doi:10.1029/2002JD002890, 2003. 1. Introduction [2] The sulfur cycle over North America has been sim

  13. Aerosol Radiative Effects and Single-Scattering Properties in the Tropical Western Pacific

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TA I N P A T T E R N A NA LY S IDOE Office2

  14. Investigation of Absorption Properties of Submicron Aerosol in the Troposphere Over West Siberia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATIONIntroducing the Richard P.Schmidt UnitInvestigation of

  15. Aerosol optical hygroscopicity measurements during the 2010 CARES campaign

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Atkinson, D. B.; Radney, J. G.; Lum, J.; Kolesar, K. R.; Cziczo, D. J.; Pekour, M. S.; Zhang, Q.; Setyan, A.; Zelenyuk, A.; Cappa, C. D.

    2015-04-17

    Measurements of the effect of water uptake on particulate light extinction or scattering made at two locations during the 2010 Carbonaceous Aerosols and Radiative Effects Study (CARES) study around Sacramento, CA are reported. The observed influence of water uptake, characterized through the dimensionless optical hygroscopicity parameter ?, is compared with calculations constrained by observed particle size distributions and size-dependent particle composition. A closure assessment has been carried out that allowed for determination of the average hygroscopic growth factors (GFs) at 85% relative humidity and the dimensionless hygroscopicity parameter ? for oxygenated organic aerosol (OA) and for supermicron particles (defined heremore »as particles with aerodynamic diameters between 1 and 2.5 microns), yielding ? = 0.1–0.15 and 0.9–1.0, respectively. The derived range of oxygenated OA ? values are in line with previous observations. The relatively large values for supermicron particles is consistent with substantial contributions of sea-salt-containing particles in this size range. Analysis of time-dependent variations in the supermicron particle hygroscopicity suggest that atmospheric processing, specifically chloride displacement by nitrate and the accumulation of secondary organics on supermicron particles, can lead to substantial depression of the observed GF.« less

  16. Amine-Amine Exchange in Aminium-Methanesulfonate Aerosols

    SciTech Connect (OSTI)

    Dawson, Matthew L.; Varner, Mychel E.; Perraud, Veronique M.; Ezell, Michael J.; Wilson, Jacqueline M.; Zelenyuk, Alla; Gerber, Robert B.; Finlayson-Pitts, Barbara J.

    2014-12-18

    Aerosol particles are ubiquitous in the atmosphere and have been shown to impact the Earth’s climate, reduce visibility, and adversely affect human health. Modeling the evolution of aerosol systems requires an understanding of the species and mechanisms involved in particle growth, including the complex interactions between particle- and gas-phase species. Here we report studies of displacement of amines (methylamine, dimethylamine or trimethylamine) in methanesulfonate salt particles by exposure to a different gas-phase amine, using a single particle mass spectrometer, SPLAT II. The variation of the displacement with the nature of the amine suggests that behavior is dependent on water in or on the particles. Small clusters of methanesulfonic acid with amines are used as a model in quantum chemical calculations to identify key structural elements that are expected to influence water uptake, and hence the efficiency of displacement by gas-phase molecules in the aminium salts. Such molecular-level understanding of the processes affecting the ability of gas-phase amines to displace particle-phase aminium species is important for modeling the growth of particles and their impacts in the atmosphere.

  17. Discrete-element modeling of particulate aerosol flows

    SciTech Connect (OSTI)

    Marshall, J.S. [School of Engineering, University of Vermont, 33 Colchecter Avenue, Burlington, Vermont 05405 (United States)], E-mail: jeffm@cems.uvm.edu

    2009-03-20

    A multiple-time step computational approach is presented for efficient discrete-element modeling of aerosol flows containing adhesive solid particles. Adhesive aerosol particulates are found in numerous dust and smoke contamination problems, including smoke particle transport in the lungs, particle clogging of heat exchangers in construction vehicles, industrial nanoparticle transport and filtration systems, and dust fouling of electronic systems and MEMS components. Dust fouling of equipment is of particular concern for potential human occupation on dusty planets, such as Mars. The discrete-element method presented in this paper can be used for prediction of aggregate structure and breakup, for prediction of the effect of aggregate formation on the bulk fluid flow, and for prediction of the effects of small-scale flow features (e.g., due to surface roughness or MEMS patterning) on the aggregate formation. After presentation of the overall computational structure, the forces and torques acting on the particles resulting from fluid motion, particle-particle collision, and adhesion under van der Waals forces are reviewed. The effect of various parameters of normal collision and adhesion of two particles are examined in detail. The method is then used to examine aggregate formation and particle clogging in pipe and channel flow.

  18. Aerosol chemical vapor deposition of metal oxide films

    DOE Patents [OSTI]

    Ott, K.C.; Kodas, T.T.

    1994-01-11

    A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

  19. Aerosol analysis for the regional air pollution study. Final report

    SciTech Connect (OSTI)

    Jaklevic, J.M.; Gatti, R.C.; Goulding, F.S.; Loo, B.W.; Thompson, A.C.

    1980-05-01

    The design and operation of an aerosol sampling and analysis program implemented during the 1975 to 1977 St. Louis Regional Air Pollution Study is described. A network of ten samplers were operated at selected sites in the St. Louis area and the total mass and elemental composition of the collected particulates were determined. Sampling periods of 2 to 24 hours were employed. The samplers were capable of collecting aerosol particles in two distinct size ranges corresponding to fine (< 2.4 ..mu..m diameter) and coarse (> 2.4 ..mu..m diameter) particles. This unique feature allowed the separation of the particulate samples into two distinct fractions with differing chemical origins and health effects. The analysis methods were also newly developed for use in the St. Louis RAPS study. Total particulate mass was measured by a beta-particle attenuation method in which a precision of +- 5 ..mu..m/cm/sup 2/ could be obtained in a one minute measurement time. Elemental compositions of the samples were determined using an energy dispersive x-ray fluorescence method in which detectable limits of 5 ng/cm/sup 2/ or less were routinely achieved for elements ranging in atomic number from Al to Pb. The advantages of these analytical methods over more conventional techniques arise from the ability to automate the measurements. During the course of the two year study, a total of more than 35,000 individual samples were processed and a total of 28 concentrations measured for each sample.

  20. Deposition of biological aerosols on HVAC heat exchangers

    SciTech Connect (OSTI)

    Siegel, Jeffrey; Walker, Ian

    2001-09-01

    Many biologically active materials are transported as bioaerosols 1-10 {micro}m in diameter. These particles can deposit on cooling and heating coils and lead to serious indoor air quality problems. This paper investigates several of the mechanisms that lead to aerosol deposition on fin and tube heat exchangers. A model has been developed that incorporates the effects of several deposition mechanisms, including impaction, Brownian and turbulent diffusion, turbophoresis, thermophoresis, diffusiophoresis, and gravitational settling. The model is applied to a typical range of air velocities that are found in commercial and residential HVAC systems 1 - 6 m/s (200 - 1200 ft/min), particle diameters from 1 - 8 {micro}m, and fin spacings from 3.2 - 7.9 fins/cm (8 - 16 fins/inch or FPI). The results from the model are compared to results from an experimental apparatus that directly measures deposition on a 4.7 fins/cm (12 FPI) coil. The model agrees reasonably well with this measured data and suggests that cooling coils are an important sink for biological aerosols and consequently a potential source of indoor air quality problems.