Sample records for advanced pulverized coal

  1. Performance and risks of advanced pulverized-coal plants

    SciTech Connect (OSTI)

    Nalbandian, H. [IEA Clean Coal Centre, London (United Kingdom)

    2009-07-01T23:59:59.000Z

    This article is based on an in-depth report of the same title published by the IEA Clean Coal Centre, CCC/135 (see Coal Abstracts entry Sep 2008 00535). It discusses the commercial, developmental and future status of pulverized fuel power plants including subcritical supercritical and ultra supercritical systems of pulverized coal combustion, the most widely used technology in coal-fired power generation. 1 fig., 1 tab.

  2. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01T23:59:59.000Z

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  3. advanced coal combustion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  4. advanced slagging coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  5. advanced coal-combustion technology: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  6. advanced coal-combustion technologies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  7. Improving pulverized coal plant performance

    SciTech Connect (OSTI)

    Regan, J.W.; Borio, R.W.; Palkes, M.; Mirolli, M. [ABB Combustion Engineering, Inc., Windsor, CT (United States); Wesnor, J.D. [ABB Environmental Systems, Birmingham, AL (United States); Bender, D.J. [Raytheon Engineers and Constructors, Inc., New York, NY (United States)

    1995-12-31T23:59:59.000Z

    A major deliverable of the U.S. Department of Energy (DOE) project ``Engineering Development of Advanced Coal-Fired Low-Emissions Boiler Systems`` (LEBS) is the design of a large, in this case 400 MWe, commercial generating unit (CGU) which will meet the Project objectives. The overall objective of the LEBS Project is to dramatically improve environmental performance of future pulverized coal fired power plants without adversely impacting efficiency or the cost of electricity. The DOE specified the use of near-term technologies, i.e., advanced technologies that partially developed, to reduce NO{sub x}, SO{sub 2} and particulate emissions to be substantially less than current NSPS limits. In addition, air toxics must be in compliance and waste must be reduced and made more disposable. The design being developed by the ABB Team is projected to meet all the contract objectives and to reduce emission of NO{sub x}, SO{sub 2} and particulates to one-fifth to one-tenth NSPS limits while increasing net station efficiency significantly and reducing the cost of electricity. This design and future work are described in the paper.

  8. Pulverized coal burner

    DOE Patents [OSTI]

    Sivy, Jennifer L. (Alliance, OH); Rodgers, Larry W. (Canton, OH); Koslosy, John V. (Akron, OH); LaRue, Albert D. (Uniontown, OH); Kaufman, Keith C. (Canton, OH); Sarv, Hamid (Canton, OH)

    1998-01-01T23:59:59.000Z

    A burner having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO.sub.x burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO.sub.x back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing.

  9. Pulverized coal burner

    DOE Patents [OSTI]

    Sivy, J.L.; Rodgers, L.W.; Koslosy, J.V.; LaRue, A.D.; Kaufman, K.C.; Sarv, H.

    1998-11-03T23:59:59.000Z

    A burner is described having lower emissions and lower unburned fuel losses by implementing a transition zone in a low NO{sub x} burner. The improved burner includes a pulverized fuel transport nozzle surrounded by the transition zone which shields the central oxygen-lean fuel devolatilization zone from the swirling secondary combustion air. The transition zone acts as a buffer between the primary and the secondary air streams to improve the control of near-burner mixing and flame stability by providing limited recirculation regions between primary and secondary air streams. These limited recirculation regions transport evolved NO{sub x} back towards the oxygen-lean fuel pyrolysis zone for reduction to molecular nitrogen. Alternate embodiments include natural gas and fuel oil firing. 8 figs.

  10. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01T23:59:59.000Z

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  11. PARAMETRIC STUDY OF SUBMICRON PARTICULATES FROM PULVERIZED COAL COMBUSTION

    E-Print Network [OSTI]

    Pennucci, J.

    2014-01-01T23:59:59.000Z

    Chemistry of Coal during Combustion and the Emissions fromParticulates Generated by Combustion of Pulverized Coal,Particles from Coal Combustion, presented at the Eighteenth

  12. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15T23:59:59.000Z

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  13. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    Ray Chamberland; Aku Raino; David Towle

    2006-09-30T23:59:59.000Z

    For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

  14. assessing coal combustion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  15. apec coal flow: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  16. alkaline coal ash: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  17. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    Pulverized Coal Installed Capacity (GW) World - subcriticalPulverized Coal Installed Capacity (GW) U.S. - subcriticalred plants’ annual installed capacity (in GW/year) by type

  18. Pulverization Induced Charge: In-Line Dry Coal Cleaning

    SciTech Connect (OSTI)

    Schaefer, J.L.; Stencel, J.M.

    1997-05-13T23:59:59.000Z

    The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to boilers in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

  19. PULVERIZATION INDUCED CHARGE: IN-LINE DRY COAL CLEANING

    SciTech Connect (OSTI)

    JOHN M. STENCEL

    1998-07-01T23:59:59.000Z

    The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

  20. Pulverization Induced Charge: In-Line Dry Coal Cleaning

    SciTech Connect (OSTI)

    John M. Stencel

    1998-05-26T23:59:59.000Z

    The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

  1. Pulverization Induced Charge: In-Line Dry Coal Cleaning

    SciTech Connect (OSTI)

    John M. Stencel

    1998-01-21T23:59:59.000Z

    The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units will be examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler will be quantified. In addition to field charge measurements, an existing computational model will be extended to numerically simulate charged particle motion in a turbulent gas through an electric field. Results from the field tests and numerical modeling will be employed in design and construction of a laboratory scale pulverizer/classifier. This laboratory unit will be used to quantify the magnitude and differential charge imparted on bituminous and subbituminous coals during pulverization and classification at temperatures and with gaseous constituents typical to utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary design for a full-scale, (15 ton/hr) in-line, electrostatic coal cleaning device. Finally, the economic potential for application to PC units will be assessed.

  2. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30T23:59:59.000Z

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  3. Enhancement of pulverized coal combustion by plasma technology

    SciTech Connect (OSTI)

    Gorokhovski, M.A.; Jankoski, Z.; Lockwood, F.C.; Karpenko, E.I.; Messerle, V.E.; Ustimenko, A.B. [University of Rouen, Rouen (France)

    2007-07-01T23:59:59.000Z

    Plasma-assisted pulverized coal combustion is a promising technology for thermal power plants (TPP). This article reports one- and three- dimensional numerical simulations, as well as laboratory and industrial measurements of coal combustion using a plasma-fuel system (PFS). The chemical kinetic and fluid mechanics involved in this technology are analysed. The results show that a PFS, can be used to promote early ignition and enhanced stabilization of a pulverized coal flame. It is shown that this technology, in addition to enhancing the combustion efficiency of the flame, reduces harmful emissions from power coals of all ranks (brown, bituminous, anthracite and their mixtures). Data summarising the experience of 27 pulverized coal boilers in 16 thermal power plants in several countries (Russia, Kazakhstan, Korea, Ukraine, Slovakia, Mongolia and China), embracing steam productivities from 75 to 670 tons per hour (TPH), are presented. Finally, the practical computation of the characteristics of the PFS, as function of coal properties, is discussed.

  4. Hydrogen production with coal using a pulverization device

    DOE Patents [OSTI]

    Paulson, Leland E. (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method for producing hydrogen from coal is described wherein high temperature steam is brought into contact with coal in a pulverizer or fluid energy mill for effecting a steam-carbon reaction to provide for the generation of gaseous hydrogen. The high temperature steam is utilized to drive the coal particles into violent particle-to-particle contact for comminuting the particulates and thereby increasing the surface area of the coal particles for enhancing the productivity of the hydrogen.

  5. DEVELOPMENT OF A NOVEL RADIATIVELY/CONDUCTIVELY STABILIZED BURNER FOR SIGNIFICANT REDUCTION OF NOx EMISSIONS AND FOR ADVANCING THE MODELING AND UNDERSTANDING OF PULVERIZED COAL COMBUSTION AND EMISSIONS

    SciTech Connect (OSTI)

    Noam Lior; Stuart W. Churchill

    2003-10-01T23:59:59.000Z

    The primary objective of the proposed study was the study and analysis of, and design recommendations for, a novel radiatively-conductively stabilized combustion (RCSC) process for pulverized coal, which, based on our prior studies with both fluid fuels and pulverized coal, holds a high promise to reduce NO{sub x} production significantly. We have primarily engaged in continuing and improving our process modeling and analysis, obtained a large amount of quantitative information about the effects of the major parameters on NO{sub x} production, conducted an extensive exergy analysis of the process, evaluated the practicalities of employing the Radiatively-Conductively Stabilized Combustor (RCSC) to large power and heat plants, and improved the experimental facility. Prior experimental work has proven the feasibility of the combustor, but slagging during coal combustion was observed and should be dealt with. The primary outcomes and conclusions from the study are: (1) we developed a model and computer program that represents the pulverized coal combustion in the RCSC, (2) the model predicts that NO{sub x} emissions can be reduced by a number of methods, detailed in the report. (3) the exergy analysis points out at least a couple of possible ways to improve the exergetic efficiency in this combustor: increasing the effectiveness of thermal feedback, and adjusting the combustor mixture exit location, (4) because of the low coal flow rates necessitated in this study to obtain complete combustion in the burner, the size of a burner operating under the considered conditions would have to be up to an order of magnitude, larger than comparable commercial burners, but different flow configurations of the RCSC can yield higher feed rates and smaller dimensions, and should be investigated. Related to this contract, eleven papers were published in journals and conference proceedings, and ten invited presentations were given at university and research institutions, as well as at the Gordon Conference on Modern Development in Thermodynamics. The results obtained are very encouraging for the development of the RCSC as a commercial burner for significant reduction of NO{sub x} emissions, and highly warrants further study and development.

  6. Hydrothermally treated coals for pulverized coal injection. Technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Walsh, D.E.; Rao, P.D.; Ogunsola, O.; Lin, H.K.

    1995-07-01T23:59:59.000Z

    This project is investigating the suitability of hydrothermally dried low-rank coals for pulverized fuel injection into blast furnaces in order to reduce coke consumption. Coal samples from the Beluga coal field and Usibelli Coal Mine, Alaska, are being used for the study. Crushed coal samples were hydrothermally treated at three temperatures, 275, 300 and 325{degrees}C, for residence times ranging from 10 to 120 minutes. Products have been characterized to determine their suitability for pulverized coal injection. Characterization includes proximate and ultimate analyses, vitrinite reflectance, TGA reactivity and thermochemical modeling. A literature survey has been conducted.

  7. Control of cooling losses at high pulverized coal injection rates

    SciTech Connect (OSTI)

    Bonte, L.; Nieuwerburgh, H. Van [Sidmar N.V., Gent (Belgium)

    1996-12-31T23:59:59.000Z

    One of the problems which is encountered by many blast furnace operators is the appropriate control of the cooling losses of the blast furnace. This problem has been aggravated by the introduction of pulverized coal injection. Even with equal burden and coke composition, both Sidmar furnaces behave differently with respect to the cooling losses. This phenomenon is possibly attributable to the different profile and cooling circuitry of the furnaces. Among other parameters the angles of bosh and stack may favor the formation of scabs or not. Some operators experience a decrease of their cooling losses, other operators have problems to limit their cooling losses to an acceptable level. As a result, different operating practices exist with respect to the burden distribution. The increase of the ore to coke ratio with pulverized coal injection suggests that the coke and sinter quality has to be monitored very carefully in order to avoid permeability problems.

  8. Supercritical Pulverized Coal and Integrated Gasification Combined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cost and Performance Baseline for Fossil Energy Plants Supplement: Sensitivity to CO 2 Capture Rate in Coal-Fired Power Plants June 22, 2015 DOENETL-20151720 OFFICE OF FOSSIL...

  9. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal

    SciTech Connect (OSTI)

    Zauderer, B.; Fleming, E.S.

    1991-08-30T23:59:59.000Z

    This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

  10. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Nenad Sarunac; Harun Bilirgen; Wei Zhang

    2005-04-01T23:59:59.000Z

    This is the ninth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, comparative analyses were performed for lignite and PRB coals to determine how unit performance varies with coal product moisture. Results are given showing how the coal product moisture level and coal rank affect parameters such as boiler efficiency, station service power needed for fans and pulverizers and net unit heat rate. Results are also given for the effects of coal drying on cooling tower makeup water and comparisons are made between makeup water savings for various times of the year.

  11. Ash & Pulverized Coal Deposition in Combustors & Gasifiers

    SciTech Connect (OSTI)

    Goodarz Ahmadi

    1998-12-02T23:59:59.000Z

    Further progress in achieving the objectives of the project was made in the period of October 1 to December 31, 1996. In particular, the sublayer model for evaluating the particle deposition in turbulent flows was extended to include the effect of particle rebound. A new more advance flow model for the near wall vortices is also used in these analysis. The computational model for simulating particle transport in turbulent flows was used to analyze the dispersion and deposition of particles in a recirculating flow region. The predictions of the particle resuspension model is compared with the experimental data. It is shown that when the effects of the near wall flow structure, as we as the surface roughness are included the model agrees with the available experimental data. Considerable progress was also made in the direct numerical simulation of particle removal process in turbulent gas flows. Experimental data for transport and deposition of glass fiber in the aerosol wind tunnel was also obtained.

  12. Large-Eddy Simulation of Pulverized Coal Jet Flame -Effect of Oxygen Concentration on NOx formation

    E-Print Network [OSTI]

    Muto, Masaya; Watanabe, Hiroaki; Kurose, Ryoichi; Komori, Satoru; Balusamy, Saravanan; Hochgreb, Simone

    2015-01-01T23:59:59.000Z

    than those by using other fossil fuels [1]. It is therefore important to develop clean coal technology for pulverized coal fired power plants, in order to control such emissions and to reduce the environmental impact. Regarding the reduction...

  13. Ash & Pulverized Coal Deposition in Combustors & Gasifiers

    SciTech Connect (OSTI)

    Goodarz Ahmadi

    1998-12-02T23:59:59.000Z

    Further progress in achieving the objectives of the project was made in the period of July 1 to September 30, 1997. The direct numerical simulation of particle removal process in turbulent gas flows was continued. Variations of vorticity contours which are averaged over a short time duration are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. The sublayer model for evaluating the particle deposition in turbulent flows was extended to include the effect of particle rebound. A new more advance flow model for the near wall vortices is also used in these analysis. Sample particle trajectories are obtained and discussed. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity is compared with the empirical correlation and the available data and discussed. Particle resuspension process in turbulent flows are studied. The model is compared with the experimental data. It is shown that when the effects of the near wall flow structure, as well as the surface roughness are included the model agrees with the available experimental data.

  14. Ash & Pulverized Coal Deposition in Combustors & Gasifiers

    SciTech Connect (OSTI)

    Goodarz Ahmadi

    1998-12-02T23:59:59.000Z

    Further progress in achieving the objectives of the project was made in the period of October I to December 31, 1997. The direct numerical simulation of particle removal process in turbulent gas flows was continued. Variations of vorticity contours which are averaged over a short time duration are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. The sublayer model for evaluating the particle deposition in turbulent flows was extended to include the effect of particle rebound. A new more advance flow model for the near wall vortices is also used in these analysis. Sample particle trajectories are obtained and discussed. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity is compared with the empirical correlation and the available data and discussed. Particle resuspension process in turbulent flows are studied. The model is compared with the experimental data. It is shown that when the effects of the near wall flow structure, as well as the surface roughness are included the model agrees with the available experimental data.

  15. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Ursla Levy; John Sale; Nenad Sarunac

    2006-01-01T23:59:59.000Z

    This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energy extracted from boiler flue gas.

  16. Simultaneous combustion of waste plastics with coal for pulverized coal injection application

    SciTech Connect (OSTI)

    Sushil Gupta; Veena Sahajwalla; Jacob Wood [University of New South Wales, Sydney, NSW (Australia). Cooperative Research Centre for Coal in Sustainable Development, School of Materials Science and Engineering

    2006-12-15T23:59:59.000Z

    A bench-scale study was conducted to investigate the effect of simultaneous cofiring of waste plastic with coal on the combustion behavior of coals for PCI (pulverized coal injection) application in a blast furnace. Two Australian coals, premixed with low- and high-density polyethylene, were combusted in a drop tube furnace at 1473 K under a range of combustion conditions. In all the tested conditions, most of the coal blends including up to 30% plastic indicated similar or marginally higher combustion efficiency compared to those of the constituent coals even though plastics were not completely combusted. In a size range up to 600 {mu}m, the combustion efficiency of coal and polyethylene blends was found be independent of the particle size of plastic used. Both linear low-density polyethylene (LLDPE) and high-density polyethylene (HDPE) are shown to display similar influence on the combustion efficiency of coal blends. The effect of plastic appeared to display greater improvement on the combustion efficiency of low volatile coal compared to that of a high volatile coal blend. The study further suggested that the effect of oxygen levels of the injected air in improving the combustion efficiency of a coal-plastic blend could be more effective under fuel rich conditions. The study demonstrates that waste plastic can be successfully coinjected with PCI without having any adverse effect on the combustion efficiency particularly under the tested conditions. 22 refs., 12 figs., 2 tabs.

  17. Raceway behaviors in blast furnace with pulverized coal injection

    SciTech Connect (OSTI)

    Chung, J.K.; Han, J.W.; Cho, B.R. [POSCO, Cheollanamdo (Korea, Republic of)

    1995-12-01T23:59:59.000Z

    The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

  18. Detailed model for practical pulverized coal furnaces and gasifiers

    SciTech Connect (OSTI)

    Philips, S.D.; Smoot, L.D.

    1989-08-01T23:59:59.000Z

    The need to improve efficiency and reduce pollutant emissions commercial furnaces has prompted energy companies to search for optimized operating conditions and improved designs in their fossil-fuel burning facilities. Historically, companies have relied on the use of empirical correlations and pilot-plant data to make decisions about operating conditions and design changes. The high cost of collecting data makes obtaining large amounts of data infeasible. The main objective of the data book is to provide a single source of detailed three-dimensional combustion and combustion-related data suitable for comprehensive combustion model evaluation. Five tasks were identified as requirements to achieve the main objective. First, identify the types of data needed to evaluate comprehensive combustion models, and establish criteria for selecting the data. Second, identify and document available three-dimensional combustion data related to pulverized coal combustion. Third, collect and evaluate three-dimensional data cases, and select suitable cases based on selection criteria. Fourth, organize the data sets into an easy-to-use format. Fifth, evaluate and interpret the nature and quality of the data base. 39 refs., 15 figs., 14 tabs.

  19. Capacity mapping for optimum utilization of pulverizers for coal fired boilers - article no. 032201

    SciTech Connect (OSTI)

    Bhattacharya, C. [National Power Training Institute, Durgapur (India)

    2008-09-15T23:59:59.000Z

    Capacity mapping is a process of comparison of standard inputs with actual fired inputs to assess the available standard output capacity of a pulverizer. The base capacity is a function of grindability; fineness requirement may vary depending on the volatile matter (VM) content of the coal and the input coal size. The quantity and the inlet will change depending on the quality of raw coal and output requirement. It should be sufficient to dry pulverized coal (PC). Drying capacity is also limited by utmost PA fan power to supply air. The PA temperature is limited by air preheater (APH) inlet flue gas temperature; an increase in this will result in efficiency loss of the boiler. The higher PA inlet temperature can be attained through the economizer gas bypass, the steam coiled APH, and the partial flue gas recirculation. The PS/coal ratioincreases with a decrease in grindability or pulverizer output and decreases with a decrease in VM. The flammability of mixture has to be monitored on explosion limit. Through calibration, the PA flow and efficiency of conveyance can be verified. The velocities of coal/air mixture to prevent fallout or to avoid erosion in the coal carrier pipe are dependent on the PC particle size distribution. Metal loss of grinding elements inversely depends on the YGP index of coal. Variations of dynamic loading and wearing of grinding elements affect the available milling capacity and percentage rejects. Therefore, capacity mapping in necessary to ensure the available pulverizer capacity to avoid overcapacity or undercapacity running of the pulverizing system, optimizing auxiliary power consumption. This will provide a guideline on the distribution of raw coal feeding in different pulverizers of a boiler to maximize system efficiency and control, resulting in a more cost effective heat rate.

  20. Large-Eddy Simulation of Pulverized Coal Jet Flame -Effect of Oxygen Concentration on NOx formation

    E-Print Network [OSTI]

    Muto, Masaya; Watanabe, Hiroaki; Kurose, Ryoichi; Komori, Satoru; Balusamy, Saravanan; Hochgreb, Simone

    2015-01-01T23:59:59.000Z

    than those by using other fossil fuels [1]. It is therefore important to develop clean coal technology for pulverized coal fired power plants, in order to control such emissions and to reduce the environmental impact. Regarding the reduction... of environmental impact of CO2, carbon capture and sequestration (CCS) is expected as a key technology, and it is believed that oxy-fuel pulverized coal combus- tion, in which gas mixture of oxygen (O2) and CO2 are used instead of air as oxidizer, has advantages...

  1. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants 

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    pulverized coal-fired boiler equipment. These are: (1) coal cleaning to remove pyritic sulfur, (2) conventional wet, nonregenerable scrubbing with alkaline slurry and solution processes, and (3) dry processes which involve direct introduction of lime...

  2. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward K. Levy; Hugo Caram; Zheng Yao; Gu Feng

    2004-01-01T23:59:59.000Z

    This is the fourth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture, prior to firing in a pulverized coal boiler. A description is given of the equipment, instrumentation and procedures being used for the fluidized bed drying experiments. Experimental data were obtained during this last quarter on the effects of particle size on drying rate for a North Dakota lignite. Other experiments looked at drying a PRB coal. The tests comparing drying rates with lignite particles of different diameters were carried out with particle top sizes from 2 to 9.5 mm and covered a range of air velocities. The results show that drying rate increased with air velocity, but that, within the accuracy of the data, the data for all four particle size distributions follow the same curve. This suggests the higher drying rates associated with the larger particles are due to higher air velocities and not to any inherently different drying rates due to particle size. The drying data with the PRB coal show qualitatively similar behavior to that observed with lignite. However, quantitative comparisons of the drying rate data obtained so far for the two coals show the PRB dried at rates which were 14 to 20 percent lower than the lignite, for comparable process conditions. The equilibrium relationship between relative humidity and coal moisture was refined using a correction for temperature. This reduced the scatter in the coal moisture versus relative humidity data and improved the predictions made with the first principle drying model.

  3. Kinetic model for nitric oxide formation during pulverized coal combustion

    SciTech Connect (OSTI)

    Mitchell, J.W.; Tarbell, J.M.

    1982-03-01T23:59:59.000Z

    A mathematical model of NO formation during pulverised coal combustion was developed from a proposed kinetic mechanism involving 12 overall chemical reactions. Most significantly, the model describes the complex conversion of coal bound nitrogen compounds to NO during combustion. The predictions of the model compare favourably with literature data and are in qualitative agreement with trends observed in practical coal combustion.

  4. Measurement and Capture of Fine and Ultrafine Particles from a Pilot-Scale Pulverized Coal Combustor with an

    E-Print Network [OSTI]

    Li, Ying

    Combustor with an Electrostatic Precipitator Ying Li, Achariya Suriyawong, and Michael Daukoru Aerosol out in a pilot-scale pulverized coal combustor at the Energy and Environmental Re- search Center (EERC, residential combustors, and others).1 One of the largest source cate- gories is electric utility coal

  5. TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates

    SciTech Connect (OSTI)

    Veena Sahajwalla; Sushil Gupta

    2005-04-15T23:59:59.000Z

    Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

  6. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2008-10-15T23:59:59.000Z

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  7. Pilot-Scale Demonstration of ALTA for NOx Control in Pulverized Coal-Fired Boilers

    SciTech Connect (OSTI)

    Andrew Fry; Devin Davis; Marc Cremer; Bradley Adams

    2008-04-30T23:59:59.000Z

    This report describes computational fluid dynamics (CFD) modeling and pilot-scale testing conducted to demonstrate the ability of the Advanced Layered Technology Approach (ALTA) to reduce NO{sub x} emissions in a pulverized coal (PC) boiler. Testing specifically focused on characterizing NO{sub x} behavior with deep burner staging combined with Rich Reagent Injection (RRI). Tests were performed in a 4 MBtu/hr pilot-scale furnace at the University of Utah. Reaction Engineering International (REI) led the project team which included the University of Utah and Combustion Components Associates (CCA). Deep burner staging and RRI, combined with selective non-catalytic reduction (SNCR), make up the Advanced Layered Technology Approach (ALTA) for NO{sub x} reduction. The application of ALTA in a PC environment requires homogenization and rapid reaction of post-burner combustion gases and has not been successfully demonstrated in the past. Operation of the existing low-NO{sub x} burner and design and operation of an application specific ALTA burner was guided by CFD modeling conducted by REI. Parametric pilot-scale testing proved the chemistry of RRI in a PC environment with a NOx reduction of 79% at long residence times and high baseline NOx rate. At representative particle residence times, typical operation of the dual-register low-NO{sub x} burner provided an environment that was unsuitable for NO{sub x} reduction by RRI, showing no NOx reduction. With RRI, the ALTA burner was able to produce NO{sub x} emissions 20% lower than the low-NO{sub x} burner, 76 ppmv vs. 94 ppmv, at a burner stoichiometric ratio (BSR) of 0.7 and a normalized stoichiometric ratio (NSR) of 2.0. CFD modeling was used to investigate the application of RRI for NO{sub x} control on a 180 MW{sub e} wall-fired, PC boiler. A NO{sub x} reduction of 37% from baseline (normal operation) was predicted using ALTA burners with RRI to produce a NO{sub x} emission rate of 0.185 lb/MBtu at the horizontal nose of the boiler. When combined with SNCR, a NO{sub x} emission rate of 0.12-0.14 lb/MBtu can be expected when implementing a full ALTA system on this unit. Cost effectiveness of the full ALTA system was estimated at $2,152/ton NO{sub x} removed; this was less than 75% of the cost estimated for an SCR system on a unit of this size.

  8. Pulverized coal injection (PCI) at Inland`s No. 7 blast furnace

    SciTech Connect (OSTI)

    Carter, W.L.; Greenawald, P.B.; Ranade, M.G.; Ricketts, J.A.; Zuke, D.A. [Inland Steel Co., East Chicago, IN (United States)

    1995-12-01T23:59:59.000Z

    Fuel injection at the tuyeres has always been part of normal operating practice on this blast furnace. It has been used as much because of the beneficial effects on furnace operation as for the replacement of some of the coke that would otherwise be consumed. Fuel oil was used at first, but since the early 1980s it was more economical to inject natural gas. Studies in 1990 indicated that natural gas could be increased to 75 kg/tHM on No. 7 Furnace, and this would result in a coke rate of approximately 360 kg/tHM. It was apparent that coal injection offered significantly more opportunity for coke savings. Coke rate could be lowered to 300 kg/tHM with coal injected at 175 kg/tHM. Some combustion limitations were expected at that level. A coke rate of 270 kg/tHM with coal at 200 kg/tHM may be possible once these limitations are overcome. Furnace permeability was expected to limit the ability to reduce coke rate any further. In addition, the relative cost of coal would be significantly lower than the cost of coke it replaced. This lead to the decision late in 1991 to install pulverized coal injection (PCI) equipment for all of Inland`s blast furnaces. This paper will deal with PCI experience at No. 7 Blast Furnace.

  9. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

  10. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    farms with advanced coal generation facilities and operatingfarms with advanced coal generation facilities and operatingin the stand-alone coal generation option (IGCC+CCS plant)

  11. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  12. Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace

    SciTech Connect (OSTI)

    Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

    1995-12-01T23:59:59.000Z

    In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

  13. Effect of CO2 gasification reaction on oxycombustion of pulverized coal char.

    SciTech Connect (OSTI)

    Molina, Alejandro (Universidad Nacional de Colombia, Medellin, Colombia); Hecht, Ethan S.; Shaddix, Christopher R.; Haynes, Brian S. (University of Sydney, New South Wales, Australia)

    2010-07-01T23:59:59.000Z

    For oxy-combustion with flue gas recirculation, as is commonly employed, it is recognized that elevated CO{sub 2} levels affect radiant transport, the heat capacity of the gas, and other gas transport properties. A topic of widespread speculation has concerned the effect of the CO{sub 2} gasification reaction with coal char on the char burning rate. To give clarity to the likely impact of this reaction on the oxy-fuel combustion of pulverized coal char, the Surface Kinetics in Porous Particles (SKIPPY) code was employed for a range of potential CO{sub 2} reaction rates for a high-volatile bituminous coal char particle (130 {micro}m diameter) reacting in several O{sub 2} concentration environments. The effects of boundary layer chemistry are also examined in this analysis. Under oxygen-enriched conditions, boundary layer reactions (converting CO to CO{sub 2}, with concomitant heat release) are shown to increase the char particle temperature and burning rate, while decreasing the O{sub 2} concentration at the particle surface. The CO{sub 2} gasification reaction acts to reduce the char particle temperature (because of the reaction endothermicity) and thereby reduces the rate of char oxidation. Interestingly, the presence of the CO{sub 2} gasification reaction increases the char conversion rate for combustion at low O{sub 2} concentrations, but decreases char conversion for combustion at high O{sub 2} concentrations. These calculations give new insight into the complexity of the effects from the CO{sub 2} gasification reaction and should help improve the understanding of experimentally measured oxy-fuel char combustion and burnout trends in the literature.

  14. Radiation-turbulence interactions in pulverized-coal flames. Quarterly reports I and II, September 15, 1993--March 15, 1994

    SciTech Connect (OSTI)

    Menguec, M.P.; McDonough, J.M.

    1994-05-01T23:59:59.000Z

    This is the First Report of the project titled {open_quotes}Radiation-Turbulence Interactions in Pulverized-Coal Flames{close_quotes}. The report covers the period of 6 months from September 15, 1993 to March 15, 1994. During the period covered, the authors have started to modify the experimental facilities for this research and worked on the formulation. This period has been more like a planning time. They expect to have more accomplishments within the next three months.

  15. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    Renewable Energy and Energy Efficiency, DOE. LBNL 275-E Advanced Coal Wind Hybrid:Renewable Energy Laboratory), and Ryan Wiser ( LBNL). i Advanced Coal Wind Hybrid:

  16. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic21 Figure 6. Comparison of ACWH and CCGT-Wind

  17. Optimization under Uncertainty for Water Consumption in a Pulverized Coal Power Plant

    SciTech Connect (OSTI)

    Juan M. Salazar; Stephen E. Zitney; Urmila Diwekar

    2009-01-01T23:59:59.000Z

    Pulverized coal (PC) power plants are widely recognized as major water consumers whose operability has started to be affected by drought conditions across some regions of the country. Water availability will further restrict the retrofitting of existing PC plants with water-expensive carbon capture technologies. Therefore, national efforts to reduce water withdrawal and consumption have been intensified. Water consumption in PC plants is strongly associated to losses from the cooling water cycle, particularly water evaporation from cooling towers. Accurate estimation of these water losses requires realistic cooling tower models, as well as the inclusion of uncertainties arising from atmospheric conditions. In this work, the cooling tower for a supercritical PC power plant was modeled as a humidification operation and used for optimization under uncertainty. Characterization of the uncertainty (air temperature and humidity) was based on available weather data. Process characteristics including boiler conditions, reactant ratios, and pressure ratios in turbines were calculated to obtain the minimum water consumption under the above mentioned uncertainties. In this study, the calculated conditions predicted up to 12% in reduction in the average water consumption for a 548 MW supercritical PC power plant simulated using Aspen Plus. Optimization under uncertainty for these large-scale PC plants cannot be solved with conventional stochastic programming algorithms because of the computational expenses involved. In this work, we discuss the use of a novel better optimization of nonlinear uncertain systems (BONUS) algorithm which dramatically decreases the computational requirements of the stochastic optimization.

  18. Optimization Under Uncertainty for Water Consumption in a Pulverized Coal Power Plant

    SciTech Connect (OSTI)

    Juan M. Salazara; Stephen E. Zitney; Urmila M. Diwekara

    2009-01-01T23:59:59.000Z

    Pulverized coal (PC) power plants are widely recognized as major water consumers whose operability has started to be affected by drought conditions across some regions of the country. Water availability will further restrict the retrofitting of existing PC plants with water-expensive carbon capture technologies. Therefore, national efforts to reduce water withdrawal and consumption have been intensified. Water consumption in PC plants is strongly associated to losses from the cooling water cycle, particularly water evaporation from cooling towers. Accurate estimation of these water losses requires realistic cooling tower models, as well as the inclusion of uncertainties arising from atmospheric conditions. In this work, the cooling tower for a supercritical PC power plant was modeled as a humidification operation and used for optimization under uncertainty. Characterization of the uncertainty (air temperature and humidity) was based on available weather data. Process characteristics including boiler conditions, reactant ratios, and pressure ratios in turbines were calculated to obtain the minimum water consumption under the above mentioned uncertainties. In this study, the calculated conditions predicted up to 12% in reduction in the average water consumption for a 548 MW supercritical PC power plant simulated using Aspen Plus. Optimization under uncertainty for these large-scale PC plants cannot be solved with conventional stochastic programming algorithms because of the computational expenses involved. In this work, we discuss the use of a novel better optimization of nonlinear uncertain systems (BONUS) algorithm which dramatically decreases the computational requirements of the stochastic optimization.

  19. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    Alone IGCC+CCS Coal Plant The levelized cost of electricitythan advanced coal plants and hence their cost estimates areestimates of the costs of an advanced coal plant, since they

  20. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    International Energy Agency’s Clean Coal Centre CoalPower5Press; 2002. [25] IEA Clean Coal Centre. CoalPower5 (CD-from fossil fuels. In: IEA clean coal conference, Sardinia,

  1. Ash and pulverized coal deposition in combustors and gasifiers. Quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    Ahmadi, G.

    1996-10-01T23:59:59.000Z

    The general goal of this project is to provide a fundamental understanding of deposition processes of flyash and pulverized coal particles in coal combustors and coal gasifiers. In the period of April 1 to June 30, 1996, further research progress was made. The computational model for simulating particle motions in turbulent flows was applied to the dispersion and deposition analysis. The study of particle transport and deposition in a circular duct was completed and the major findings are summarized. A detailed model for particle resuspension process in a gas flow is developed. The new model accounts for the surface adhesion, surface roughness, as well as the structure of near wall turbulent flows. The model also accounts for all the relevant hydrodynamic forces and torques exerted on the particle attached to a surface. Progress was also made in the experimental study of glass fiber transport and deposition in the aerosol wind tunnel.

  2. Optimal Synthesis of a Pulverized Coal Power Plant with Carbon Capture

    SciTech Connect (OSTI)

    Prakash R. Kotecha; Juan M. Salazar; Stephen Zitney

    2009-01-01T23:59:59.000Z

    Coal constitutes an important source of fuel for the production of power in the United States. For instance, in January 2009, pulverized coal (PC) power plants alone contributed to over 45 percent of the Nation's total electric power production. However, PC power plants also contribute to increased emissions of greenhouse gases principally carbon-dioxide (CO2). Recently, various carbon capture strategies have been under active investigation so as to make these plants compete with the more environmental friendly renewable energy sources. One such technology that has received considerable success is the capture of CO2 by an amine-based solvent extraction process. However, an aqueous absorption/stripping technology when used in a PC power plant can reduce the net power output of the plant by as much as 20-40%. The energy penalty comes from heating up the solvent in the regenerator, balancing the enthalpy of reaction, and water stripping. This energy penalty poses considerable limitations on commercial viability of the solvent extraction process and, as a result, various energy-saving modifications have been proposed in the literature ranging from the use of hybrid solvents to novel stripper configurations. In this paper, we show that the energy penalty can be further reduced by heat integration of various PC plant components with the carbon capture system. In addition to the release of greenhouse gases to the environment, PC plants also consume a large amount of freshwater. It is estimated that subcritical and supercritical PC plants have water losses of 714 gal/MWh and 639 gal/MWh, respectively. Water loss is based on an overall balance of the plant source and exit streams. This includes coal moisture, air humidity, process makeup, cooling tower makeup (equivalent to evaporation plus blowdown), process losses (including losses through reactions, solids entrainment, and process makeup/blowdown) and flue gas losses. The primary source of water used in PC power plants is the closed-loop steam-based (Rankine) power cycles. These plants need to condense large quantities of low-pressure steam back to water so that it can be reused to produce high pressure steam. However, this requires the removal of large quantities of heat from the low pressure steam in the condensation process. This is usually done by transferring the heat to cooling water, which in turn transfers this heat to the environment by evaporation to the atmosphere. Also, the inclusion of a carbon capture process can increase the raw water usage by as much as 95 percent. In this work, we use heat exchanger network synthesis followed by an optimization approach to process synthesis for developing strategies for reducing water use in a supercritical PC power plant with a carbon capture and compression system. Uncertainties associated with dry bulb temperature, relative humidity, and demand will also be considered in this analysis.

  3. Revised users manual, Pulverized Coal Gasification or Combustion: 2-dimensional (87-PCGC-2): Final report, Volume 2. [87-PCGC-2

    SciTech Connect (OSTI)

    Smith, P.J.; Smoot, L.D.; Brewster, B.S.

    1987-12-01T23:59:59.000Z

    A two-dimensional, steady-state model for describing a variety of reactive and non-reactive flows, including pulverized coal combustion and gasification, is presented. Recent code revisions and additions are described. The model, referred to as 87-PCGC-2, is applicable to cylindrical axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using either a flux method or discrete ordinates method. The particle phase is modeled in a Lagrangian framework, such that mean paths of particle groups are followed. Several multi-step coal devolatilization schemes are included along with a heterogeneous reaction scheme that allows for both diffusion and chemical reaction. Major gas-phase reactions are modeled assuming local instantaneous equilibrium, and thus the reaction rates are limited by the turbulent rate mixing. A NO/sub x/ finite rate chemistry submodel is included which integrates chemical kinetics and the statistics of the turbulence. The gas phase is described by elliptic partial differential equations that are solved by an iterative line-by-line technique. Under-relaxation is used to achieve numerical stability. The generalized nature of the model allows for calculation of isothermal fluid mechanicsgaseous combustion, droplet combustion, particulate combustion and various mixtures of the above, including combustion of coal-water and coal-oil slurries. Both combustion and gasification environments are permissible. User information and theory are presented, along with sample problems. 106 refs.

  4. BioCoComb -- Gasification of biomass and co-combustion of the gas in a pulverized-coal-boiler

    SciTech Connect (OSTI)

    Anderl, H.; Zotter, T.; Mory, A.

    1999-07-01T23:59:59.000Z

    In a demonstration project supported by an European Community Thermie Fund a biomass gasifier for bark, wood chips, saw dust, etc. has been installed by Austrian Energy and Environment at the 137 MW{sub el} pulverized-coal fired power station in Zeltweg, Austria. The project title BioCoComb is an abbreviation for Preparation of Biofuel for Co-Combustion, where co-combustion means combustion together with coal in existing power plants. According to the thermal capacity of 10 MW the produced gas substitutes approx. 3% of the coal fired in the boiler. Only the coarse fraction of the biomass has to pass a shredder and is then fed together with the fine fraction without any further pretreatment into the gasifier. In the gasification process the biomass will combust in a substoichiometric atmosphere, create the necessary temperature of 820 C and partly gasify due to the lack of oxygen in the combustion chamber (autothermal operation). The gasifier uses circulating fluidized bed technology, which guarantees even relatively low temperatures in all parts of the gasifier to prevent slagging. The intense motion of the bed material also favors attrition of the biomass particles. Via a hot gas duct the produced low calorific value (LCV) gas is directly led into the furnace of the existing pulverized coal fired boiler for combustion. The gas also contains fine wood char particles, that can pass the retention cyclone and burn out in the furnace of the coal boiler. The main advantages of the BioCoComb concept are: low gas quality sufficient for co-firing; no gas cleaning or cooling; no predrying of the biomass; relatively low temperatures in the gasifier to prevent slagging; favorable effects on power plant emissions (CO{sub 2}, NO{sub x}); no severe modifications of the existing coal fired boiler; and high flexibility in arranging and integrating the main components into existing plants. The plant started its trial run in November 1997 and has been in successful commercial operation since January 1998.

  5. The fate of char-N at pulverized coal conditions Jennifer P. Spinti*, David W. Pershing

    E-Print Network [OSTI]

    Utah, University of

    of Chemical Engineering, University of Utah, Salt Lake City, UT 84112, USA Received 25 January 2002; received 1. Introduction The abundance of coal as an energy source is offset by the negative environmental-programmed gasification in 20% O2 (balance Ar) of 6 coals of varying rank and of the chars produced from the coals

  6. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S

    2007-01-01T23:59:59.000Z

    11. Average coal steam plant non-fuel O&M cost (adjusted forU.S. coal-burning power plants found that real capital costnon-fuel O&M cost 4 per kW h for coal plants fell by 32% at

  7. Coal Direct Chemical Looping Retrofit to Pulverized Coal Power Plants for In-Situ CO2 Capture

    SciTech Connect (OSTI)

    Zeng, Liang; Li, Fanxing; Kim, Ray; Bayham, Samuel; McGiveron, Omar; Tong, Andrew; Connell, Daniel; Luo, Siwei; Sridhar, Deepak; Wang, Fei; Sun, Zhenchao; Fan, Liang-Shih

    2013-09-30T23:59:59.000Z

    A novel Coal Direct Chemical Looping (CDCL) system is proposed to effectively capture CO2 from existing PC power plants. The work during the past three years has led to an oxygen carrier particle with satisfactory performance. Moreover, successful laboratory, bench scale, and integrated demonstrations have been performed. The proposed project further advanced the novel CDCL technology to sub-pilot scale (25 kWth). To be more specific, the following objectives attained in the proposed project are: 1. to further improve the oxygen carrying capacity as well as the sulfur/ash tolerance of the current (working) particle; 2. to demonstrate continuous CDCL operations in an integrated mode with > 99% coal (bituminous, subbituminous, and lignite) conversion as well as the production of high temperature exhaust gas stream that is suitable for steam generation in existing PC boilers; 3. to identify, via demonstrations, the fate of sulfur and NOx; 4. to conduct thorough techno-economic analysis that validates the technical and economical attractiveness of the CDCL system. The objectives outlined above were achieved through collaborative efforts among all the participants. CONSOL Energy Inc. performed the techno-economic analysis of the CDCL process. Shell/CRI was able to perform feasibility and economic studies on the large scale particle synthesis and provide composite particles for the sub-pilot scale testing. The experience of B&W (with boilers) and Air Products (with handling gases) assisted the retrofit system design as well as the demonstration unit operations. The experience gained from the sub-pilot scale demonstration of the Syngas Chemical Looping (SCL) process at OSU was able to ensure the successful handling of the solids. Phase 1 focused on studies to improve the current particle to better suit the CDCL operations. The optimum operating conditions for the reducer reactor such as the temperature, char gasification enhancer type, and flow rate were identified. The modifications of the existing bench scale reactor were completed in order to use it in the next phase of the project. In Phase II, the optimum looping medium was selected, and bench scale demonstrations were completed using them. Different types of coal char such as those obtained from bituminous, subbituminous, and lignite were tested. Modifications were made on the existing sub-pilot scale unit for coal injection. Phase III focused on integrated CDCL demonstration in the sub-pilot scale unit. A comprehensive ASPEN® simulations and economic analysis was completed by CONSOL t is expected that the CDCL process will be ready for further demonstrations in a scale up unit upon completion of the proposed project.

  8. Char particle fragmentation and its effects on unburned carbon during pulverized coal combustion. Quarterly report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Mitchell, R.E.

    1995-08-01T23:59:59.000Z

    This document is the tenth quarterly status report of work on a project concerned with the fragmentation of char particles during pulverized coal combustion that is being conducted at the High Temperature Gasdynamics Laboratory at Stanford University. The project is intended to satisfy, in part, PETC`s research efforts to understand the chemical and physical processes that govern coal combustion. The work is pertinent to the char oxidation phase of coal combustion and focuses on how the fragmentation of coal char particles affects overall mass loss rates and how char fragmentation phenomena influence coal conversion efficiency. The knowledge and information obtained will allow the development of engineering models that can be used to predict accurately char particle temperatures and total mass loss rates during pulverized coal combustion. The overall objectives of the project are: (1) to characterize fragmentation events as a function of combustion environment, (2) to characterize fragmentation with respect to particle porosity and mineral loadings, (3) to assess overall mass loss rates with respect to particle fragmentation, and (4) to quantify the impact of fragmentation on unburned carbon in ash. The knowledge obtained during the course of this project will be used to predict accurately the overall mass loss rates of coals based on the mineral content and porosity of their chars. The work will provide a means of assessing reasons for unburned carbon in the ash of coal fired boilers and furnaces. Accomplishments for this period are presented for Task 3, char fragmentation studies and Task 4, fragmentation modelling.

  9. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

    2005-04-29T23:59:59.000Z

    The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

  10. Measurement and capture of fine and ultrafine particles from a pilot-scale pulverized coal combustor with an electrostatic precipitator

    SciTech Connect (OSTI)

    Ying Li; Achariya Suriyawong; Michael Daukoru; Ye Zhuang; Pratim Biswas [Washington University, St. Louis, MO (United States). Aerosol and Air Quality Research Laboratory

    2009-05-15T23:59:59.000Z

    Experiments were carried out in a pilot-scale pulverized coal combustor at the Energy and Environmental Research Center (EERC) burning a Powder River Basin (PRB) subbituminous coal. A scanning mobility particle sizer (SMPS) and an electrical low-pressure impactor (ELPI) were used to measure the particle size distributions (PSDs) in the range of 17 nm to 10 m at the inlet and outlet of the electrostatic precipitator (ESP). At the ESP inlet, a high number concentration of ultrafine particles was found, with the peak at approximately 75 nm. A trimodal PSD for mass concentration was observed with the modes at approximately 80-100 nm, 1-2 {mu}m, and 10 {mu}m. The penetration of ultrafine particles through the ESP increased dramatically as particle size decreased below 70 nm, attributable to insufficient or partial charging of the ultrafine particles. Injection of nanostructured fine-particle sorbents for capture of toxic metals in the flue gas caused high penetration of the ultrafine particles through the ESP. The conventional ESP was modified to enhance charging using soft X-ray irradiation. A slipstream of flue gas was introduced from the pilot-scale facility and passed through this modified ESP. Enhancement of particle capture was observed with the soft X-ray irradiation when moderate voltages were used in the ESP, indicating more efficient charging of fine particles. 32 refs., 5 figs., 1 tab.

  11. Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program

    Broader source: Energy.gov [DOE]

    DOE has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and use and will help propel technologies for future advanced coal power systems.

  12. JV Task 106 - Feasibility of CO2 Capture Technologies for Existing North Dakota Lignite-Fired Pulverized Coal Boilers

    SciTech Connect (OSTI)

    Michael L. Jones; Brandon M. Pavlish; Melanie D. Jensen

    2007-05-01T23:59:59.000Z

    The goal of this project is to provide a technical review and evaluation of various carbon dioxide (CO{sub 2}) capture technologies, with a focus on the applicability to lignite-fired facilities within North Dakota. The motivation for the project came from the Lignite Energy Council's (LEC's) need to identify the feasibility of CO{sub 2} capture technologies for existing North Dakota lignite-fired, pulverized coal (pc) power plants. A literature review was completed to determine the commercially available technologies as well as to identify emerging CO{sub 2} capture technologies that are currently in the research or demonstration phase. The literature review revealed few commercially available technologies for a coal-fired power plant. CO{sub 2} separation and capture using amine scrubbing have been performed for several years in industry and could be applied to an existing pc-fired power plant. Other promising technologies do exist, but many are still in the research and demonstration phases. Oxyfuel combustion, a technology that has been used in industry for several years to increase boiler efficiency, is in the process of being tailored for CO{sub 2} separation and capture. These two technologies were chosen for evaluation for CO{sub 2} separation and capture from coal-fired power plants. Although oxyfuel combustion is still in the pilot-scale demonstration phase, it was chosen to be evaluated at LEC's request because it is one of the most promising emerging technologies. As part of the evaluation of the two chosen technologies, a conceptual design, a mass and energy balance, and an economic evaluation were completed.

  13. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    components of a steam-generating plant to re?ect changes incost reduction of new generating plants prior to the 1970splants may reach 46.4% (HHV) when the estimated worldwide installed coal-?red generating

  14. Effect of coal type, residence time, and combustion configuration on the submicron aerosol composition and size distribution from pulverized coal combustion

    SciTech Connect (OSTI)

    Linak, W.P.

    1985-01-01T23:59:59.000Z

    Pulverized samples of Utah bituminous, Beulah (North Dakota) low Na lignite, Deulah high Na lignite and Texas (San Miguel) lignite coals were burned at a rate of 2.5 kg/hr in a laboratory furnace under various (overall fuel lean) combustion conditions. Particle size distributions (PSD) and size segregated particle filter samples were taken at various positions within the convection section. Temperature and gas concentrations were measured throughout. The evolution of the submicron PSD within the convection section for the four coals was similar, although the location of the initial particle mode at the convection section inlet varied with coal type. While stage combustion of the Utah bituminous coal had a variable effect on the volume of submicron aerosol produced, staged combustion of two of the three lignites (Beulah low Na and Texas) caused a definite increase in the submicron aerosol volume. Chemical analysis of the size segregated particle samples show the trace elements, As, Pb, Zn, and the major elements, Na and K to be enriched in the submicron aerosol. Auger depth profiles show these small particles to be comprised of a core enriched in Fe, Si, Ca and Mg and surface layers enriched in Na and K. These results point to a mechanism of homogeneous nucleation of low vapor pressure species followed by successive layering of progressively more volatile species. Volatile species are enriched in the submicron aerosol due to the large surface areas provided. Modeling efforts show that while coagulation may be the dominant mechanism to describe the aerosol evolving within the convection section, it cannot be used solely to predict the PSD. Another mechanism, presumably surface area dependent growth (condensation) must be included.

  15. Recent advances in coal geochemistry

    SciTech Connect (OSTI)

    Chyi, L.L. (Dept. of Geology, Univ. of Akron, Akron, OH (US)); Chou, C.-L. (Illinois State Geological Survey, 615 E. Peabody Drive, Champaign, IL (US))

    1990-01-01T23:59:59.000Z

    Chapters in this collection reflect the recent emphasis both on basic research in coal geochemistry and on applied aspects related to coal utilization. Geochemical research on peat and coal generates compositional data that are required for the following reasons. First, many studies in coal geology require chemical data to aid in interpretation for better understanding of the origin and evolution of peat and coal. Second, coal quality assessment is based largely on composition data, and these data generate useful insights into the geologic factors that control the quality of coal. Third, compositional data are needed for effective utilization of coal resources and to reflect the recent emphasis on both basic research in coal geochemistry and environmental aspects related to coal utilization.

  16. Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 4, July 1, 1993--September 30, 1993

    SciTech Connect (OSTI)

    Kramlich, J.C.; Hoffman, D.A.; Butcher, E.K.

    1993-10-29T23:59:59.000Z

    Laboratory work and studies of full-scale coal-fired boilers have identified two general mechanisms for ash production. The vast majority of the ash is formed from mineral matter that coalesces as the char burns, yielding particles that are normally larger than 0.5 {mu}m. The second major mechanism is the generation of a submicron aerosol through a vaporization/condensation mechanism. Previous work has shown that pulverized bituminous coals that were treated by coal cleaning (via froth flotation) or aerodynamic sizing exhibited altered aerosol emission characteristics. Specifically, the emissions of aerosol for the cleaned and sized coals increased by as much as one order of magnitude. The goals of the present progress are to: (1) perform measurements on carefully characterized coals to identify the means by which the coal treatment increases aerosol yields; (2) investigate means by which coal cleaning can be done in a way that will not increase aerosol yields; (3) identify whether this mechanism can be used to reduce aerosol yields from systems burning straight coal. This paper discusses model description and model formulation, and reports on the progress of furnace design and construction, and coal selection.

  17. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    Advances in boiler and steam turbine technology, materialschange; Steam plant; Steam turbine; Electricity 1.housed ?ve 10,000 kW steam turbines and typically required

  18. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S

    2007-01-01T23:59:59.000Z

    Advances in boiler and steam turbine technology, materialshoused ?ve 10,000 kW steam turbines and typically requiredchange; Steam plant; Steam turbine; Electricity 1.

  19. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S.

    2007-01-01T23:59:59.000Z

    change; Steam plant; Steam turbine; Electricity 1.housed ?ve 10,000 kW steam turbines and typically requiredAdvances in boiler and steam turbine technology, materials

  20. Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 11, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Kramlich, J.C.; Chenevert, B.; Park, Jungsung

    1995-08-02T23:59:59.000Z

    Previous work has shown that pulverized bituminous coals that were treated by coal cleaning (via froth flotation) or aerodynamic sizing exhibited altered aerosol emission characteristics. Specifically, the emissions of aerosol for the cleaned and sized coals increased by as much as one order of magnitude. The goals of the present program are to: (1) perform measurements on carefully characterized coals to identify the means by which the coal treatment increases aerosol yields; (2) investigate means by which coal cleaning can be done in a way that will not increase aerosol yields; and (3) identify whether this mechanism can be used to reduce aerosol yields from systems burning straight coal. The current experimental series focuses on the use of artificial char to study sodium vaporization and aerosol formation associated with dispersed sodium and mineral inclusions. Artificial char has the advantage over natural coal in that the composition can be precisely controlled, such that the influences of specific mineral composition and content can be investigated. The study showed: the addition of calcite had no effect of the aerosol yield; increased amounts of pyrite did not lead to increased residual ash formation; in spite of the increase in mineral content, the yield of aerosol on the backup filter did not correlate with the amount of added minerals; and the general trend was for reduced aerosol yields as the amount of bentonite increased which suggested that the bentonite was effective at complexing sodium and reducing its overall vaporization.

  1. Coal surface control for advanced fine coal flotation

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

    1992-03-01T23:59:59.000Z

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  2. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    advanced coal-wind hybrid combined cycle power plant naturalwhen the wind generation drops, the power plant needs toa CSP plant, a wind plant produces power during all hours of

  3. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    G+CC+CCS IGCC+CCS FT HVAC HVDC IGCC PC advanced coal-windthan the Base Case (HVDC Only Transmission) Sensitivity toused in the FEAST model. HVDC transmission lines have lower

  4. Investigation of Fly Ash and Activated Carbon Obtained from Pulverized Coal Boilers

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely; Zheng Yao

    2006-08-31T23:59:59.000Z

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addressed the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addressed the possible connection between SCR reactors, fly ash properties and Hg capture. The project has determined the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed have also been determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control have been analyzed in an effort to determine the effects of SCR on the ash.

  5. Coal surface control for advanced fine coal flotation

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

    1990-08-15T23:59:59.000Z

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  6. advanced coal liquefaction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  7. advanced coal gasification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  8. advanced pressurized coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  9. advanced direct coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  10. advanced physical coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  11. advanced fine coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  12. Measurement and modeling of advanced coal conversion processes, Volume II

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1993-06-01T23:59:59.000Z

    A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

  13. advanced coal conversion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the coal plant is transmitted over the transmission lines, Phadke, Amol 2008-01-01 7 Clean Coal Technology Program Advanced Coal Conversion Process Demonstration CiteSeer Summary:...

  14. advanced coal preparation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 15 1.6.2 Implement advanced clean coal technologies for production of energy products ... 15 An SAIC Report Prepared...

  15. Radiation-turbulence interactions in pulverized-coal flames. Quarterly report No. III, March 15, 1994--June 15, 1994

    SciTech Connect (OSTI)

    Menguec, M.P.; McDonough, J.M.

    1994-09-01T23:59:59.000Z

    The work concerns the development of computer codes for the simulation of radiation turbulence interactions in coal flames. Experimental studies in tandem with the turbulence calculations are based on optical observation of scattered light from coal particles under combustion conditions.

  16. TRW Advanced Slagging Coal Combustor Utility Demonstration

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO[sub x] and SO[sub x] emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  17. PASSIVE CONTROL OF PARTICLE DISPERSION IN A PARTICLE-LADEN CIRCULAR JET USING ELLIPTIC CO-ANNULAR FLOW: A MEANS FOR IMPROVING UTILIZATION AND EMISSION REDUCTIONS IN PULVERIZED COAL BURNER

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2003-06-01T23:59:59.000Z

    A passive control technology utilizing elliptic co-flow to control the particle flinging and particle dispersion in a particle (coal)-laden flow was investigated using experimental and numerical techniques. Preferential concentration of particles occurs in particle-laden jets used in pulverized coal burner and causes uncontrollable NO{sub x} formation due to inhomogeneous local stoichiometry. This particular project was aimed at characterizing the near-field flow behavior of elliptic coaxial jets. The knowledge gained from the project will serve as the basis of further investigation on fluid-particle interactions in an asymmetric coaxial jet flow-field and thus is important to improve the design of pulverized coal burners where non-homogeneity of particle concentration causes increased NO{sub x} formation.

  18. advanced coal processes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Clean Coal Technology Program Advanced Coal Conversion Process Demonstration CiteSeer Summary:...

  19. Advanced Coal Wind Hybrid: Economic Analysis

    SciTech Connect (OSTI)

    Phadke, Amol; Goldman, Charles; Larson, Doug; Carr, Tom; Rath, Larry; Balash, Peter; Yih-Huei, Wan

    2008-11-28T23:59:59.000Z

    Growing concern over climate change is prompting new thinking about the technologies used to generate electricity. In the future, it is possible that new government policies on greenhouse gas emissions may favor electric generation technology options that release zero or low levels of carbon emissions. The Western U.S. has abundant wind and coal resources. In a world with carbon constraints, the future of coal for new electrical generation is likely to depend on the development and successful application of new clean coal technologies with near zero carbon emissions. This scoping study explores the economic and technical feasibility of combining wind farms with advanced coal generation facilities and operating them as a single generation complex in the Western US. The key questions examined are whether an advanced coal-wind hybrid (ACWH) facility provides sufficient advantages through improvements to the utilization of transmission lines and the capability to firm up variable wind generation for delivery to load centers to compete effectively with other supply-side alternatives in terms of project economics and emissions footprint. The study was conducted by an Analysis Team that consists of staff from the Lawrence Berkeley National Laboratory (LBNL), National Energy Technology Laboratory (NETL), National Renewable Energy Laboratory (NREL), and Western Interstate Energy Board (WIEB). We conducted a screening level analysis of the economic competitiveness and technical feasibility of ACWH generation options located in Wyoming that would supply electricity to load centers in California, Arizona or Nevada. Figure ES-1 is a simple stylized representation of the configuration of the ACWH options. The ACWH consists of a 3,000 MW coal gasification combined cycle power plant equipped with carbon capture and sequestration (G+CC+CCS plant), a fuel production or syngas storage facility, and a 1,500 MW wind plant. The ACWH project is connected to load centers by a 3,000 MW transmission line. In the G+CC+CCS plant, coal is gasified into syngas and CO{sub 2} (which is captured). The syngas is burned in the combined cycle plant to produce electricity. The ACWH facility is operated in such a way that the transmission line is always utilized at its full capacity by backing down the combined cycle (CC) power generation units to accommodate wind generation. Operating the ACWH facility in this manner results in a constant power delivery of 3,000 MW to the load centers, in effect firming-up the wind generation at the project site.

  20. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    located in Wyoming using PRB coal. These costs take intolocated in Wyoming using PRB coal and take into account the2007 forecast for coal prices for PRB coal. Transmission We

  1. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

  2. Engineering development of advanced coal-fired low-emissions boiler system. Phase II subsystem test design and plan - an addendum to the Phase II RD & T Plan

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Shortly after the year 2000 it is expected that new generating plants will be needed to meet the growing demand for electricity and to replace the aging plants that are nearing the end of their useful service life. The plants of the future will need to be extremely clean, highly efficient and economical. Continuing concerns over acid rain, air toxics, global climate changes, ozone depletion and solid waste disposal are expected to further then regulations. In the late 1980`s it was commonly believed that coal-fired power plants of the future would incorporate either some form of Integrated Gasification Combined Cycle (IGCC) or first generation Pressurized Fluidized Bed Combustion (PFBS) technologies. However, recent advances In emission control techniques at reduced costs and auxiliary power requirements coupled with significant improvements In steam turbine and cycle design have clearly indicated that pulverized coal technology can continue to be competitive In both cost and performance. In recognition of the competitive potential for advanced pulverized coal-fired systems with other emerging advanced coal-fired technologies, DOE`s Pittsburgh Energy Technology Center (PETC) began a research and development initiative In late 1990 named, Combustion 2000, with the intention of preserving and expanding coal as a principal fuel In the Generation of electrical power. The project was designed for two stages of commercialization, the nearer-term Low Emission Boiler System (LEBS) program, and for the future, the High Performance Power System (HIPPS) program. B&W is participating In the LEBS program.

  3. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28T23:59:59.000Z

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  4. Hg and Se capture and fly ash carbons from combustion of complex pulverized feed blends mainly of anthracitic coal rank in Spanish power plants

    SciTech Connect (OSTI)

    I. Surez-Ruiz; J.C. Hower; G.A. Thomas [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

    2007-01-15T23:59:59.000Z

    In this work, the petrology and chemistry of fly ashes produced in a Spanish power plant from the combustion of complex pulverized feed blends made up of anthracitic/meta-anthracitic coals, petroleum, and natural coke are investigated. It was found that the behavior of fly ash carbons derived from anthracitic coals follows relatively similar patterns to those established for the carbons from the combustion of bituminous coals. Fly ashes were sampled in eight hoppers from two electrostatic precipitator (ESP) rows. The characterization of the raw ashes and their five sieved fractions (from {gt}150 to {lt}25 {mu}m) showed that glassy material, quartz, oxides, and spinels in different proportions are the main inorganic components. As for the organic fraction, the dominant fly ash carbons are anisotropic carbons, mainly unburned carbons derived from anthracitic vitrinite. The concentration of Se and Hg increased in ashes of the second ESP row, this increase being related to the higher proportion of anisotropic unburned carbons, particularly those largely derived from anthracitic vitrinite in the cooler ashes of the ESP (second row) and also related to the decrease in the flue gas temperature. This suggests that the flue gas temperature plays a major role in the concentration of mercury for similar ratios of unburned carbons. It was also found that Hg is highly concentrated in the medium-coarser fractions of the fly ashes ({gt} 45 {mu}m), there being a positive relationship between the amount of these carbons, which are apparently little modified during the combustion process, in the medium-coarse fractions of the ashes and the Hg retention. According to the results obtained, further research on this type of fly ash could be highly productive. 28 refs., 10 figs., 8 tabs.

  5. Advanced Coal Conversion Process Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1992-04-01T23:59:59.000Z

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  6. Suppression of fine ash formation in pulverized coal flames. Final technical report, September 30, 1992--January 31, 1996

    SciTech Connect (OSTI)

    Kramlich, J.C.; Chenevert, B.; Park, Jungsung; Hoffman, D.A.; Butcher, E.K.

    1996-07-19T23:59:59.000Z

    Coal ash, and particularly fine fly ash, remain one of the principal practical and environmental problems in coal-based power generation. In particular, submicron aerosols are identified with direct inhalation risk. Submicron ash is thought to arise from mineral vaporization during char combustion, followed by nucleation, condensation and coagulation to yield an aerosol. While aerosols are predominantly made out of volatile alkali minerals, they also can include refractory oxides that are chemically reduced to more volatile forms within the char particle and vaporized. Most of the ash of size greater than 1 {mu}m is generated by agglomeration of mineral as the char particle bums out. These two principal mechanisms are thought to account for most of the ash generated in coal combustion. Previous research has shown that various forms of coal treatment can influence the yields of fine ash from combustion. The research reported here investigates various forms of treatment, including physical coal cleaning, aerodynamic sizing, degree of grinding, and combinations of these on both aerosol yields and on yields of fine residual ash (1-4 {mu}m). The work also includes results from the combustion of artificial chars that include individual mineral elements. This research shows that these various forms of coal treatment can significantly change ash characteristics. While none of the treatments affected the bulk of the residual ash size distribution significantly, the yield of the ash aerosol mode (d<0.5 {mu}m) and fine residual ash mode (1-4 {mu}m) are changed by the treatments.

  7. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    ACWH consists of a 3,000 MW coal gasification combined cycleconsists of a 3,000 MW coal gasification, combined cycleless expensive in a coal gasification, combined cycle power

  8. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    Coal Wind Hybrid: Economic Analysis additional cost of fuelWind Hybrid: Economic Analysis Levelized Generation CostCoal Wind Hybrid: Economic Analysis Notes: All Cost are in

  9. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    Hydrogen Cyanide HHV Higher Heating Value LNB Low NOx Burner PRB Powder River Basin TAMU Texas A&M University CABEL Coal And Biomass Energy Laboratory ER Equivalence Ratio VM Volatile Matter FC Fixed Carbon OFA Over Fired Air (tertiary air... ......................................... 33 5.1 Numerical model algorithm ..................................................................... 47 5.2 Pure PRB NO vs. overall ER ................................................................... 49 5.3 Oxygen concentration along...

  10. Advanced Coal-Fueled Gas Turbine Program

    SciTech Connect (OSTI)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01T23:59:59.000Z

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  11. Clean coal technologies in electric power generation: a brief overview

    SciTech Connect (OSTI)

    Janos Beer; Karen Obenshain [Massachusetts Institute of Technology (MIT), MA (United States)

    2006-07-15T23:59:59.000Z

    The paper talks about the future clean coal technologies in electric power generation, including pulverized coal (e.g., advanced supercritical and ultra-supercritical cycles and fluidized-bed combustion), integrated gasification combined cycle (IGCC), and CO{sub 2} capture technologies. 6 refs., 2 tabs.

  12. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  13. Climate VISION: Events - Advanced Clean Coal Workshop

    Office of Scientific and Technical Information (OSTI)

    Secretary Kyle McSlarrow, DOE, and Jim Rogers, CEO Chairman, Cinergy 10:15 Break 10:30 Case Studies on Clean Coal Projects Case StudiesLessons Learned on Clean Coal Plants (to...

  14. Alstom's Chemical Looping Combustion Prototype for CO{sub 2} Capture from Existing Pulverized Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Andrus, Herbert; Chiu, John; Edberg, Carl; Thibeault, Paul; Turek, David

    2012-09-30T23:59:59.000Z

    Alstom’s Limestone Chemical Looping (LCL™) process has the potential to capture CO{sub 2} from new and existing coal-fired power plants while maintaining high plant power generation efficiency. This new power plant concept is based on a hybrid combustion- gasification process utilizing high temperature chemical and thermal looping technology. This process could also be potentially configured as a hybrid combustion-gasification process producing a syngas or hydrogen for various applications while also producing a separate stream of CO{sub 2} for use or sequestration. The targets set for this technology is to capture over 90% of the total carbon in the coal at cost of electricity which is less than 20% greater than Conventional PC or CFB units. Previous work with bench scale test and a 65 kWt Process Development Unit Development (PDU) has validated the chemistry required for the chemical looping process and provided for the investigation of the solids transport mechanisms and design requirements. The objective of this project is to continue development of the combustion option of chemical looping (LCL-C™) by designing, building and testing a 3 MWt prototype facility. The prototype includes all of the equipment that is required to operate the chemical looping plant in a fully integrated manner with all major systems in service. Data from the design, construction, and testing will be used to characterize environmental performance, identify and address technical risks, reassess commercial plant economics, and develop design information for a demonstration plant planned to follow the proposed Prototype. A cold flow model of the prototype will be used to predict operating conditions for the prototype and help in operator training. Operation of the prototype will provide operator experience with this new technology and performance data of the LCL-C™ process, which will be applied to the commercial design and economics and plan for a future demonstration plant.

  15. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30T23:59:59.000Z

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  16. Technology status and project development risks of advanced coal power generation technologies in APEC developing economies

    SciTech Connect (OSTI)

    Lusica, N.; Xie, T.; Lu, T.

    2008-10-15T23:59:59.000Z

    The report reviews the current status of IGCC and supercritical/ultrasupercritical pulverized-coal power plants and summarizes risks associated with project development, construction and operation. The report includes an economic analysis using three case studies of Chinese projects; a supercritical PC, an ultrasupercritical PC, and an IGCC plant. The analysis discusses barriers to clean coal technologies and ways to encourage their adoption for new power plants. 25 figs., 25 tabs.

  17. Portfolio evaluation of advanced coal technology : research, development, and demonstration

    E-Print Network [OSTI]

    Naga-Jones, Ayaka

    2005-01-01T23:59:59.000Z

    This paper evaluates the advanced coal technology research, development and demonstration programs at the U.S. Department of Energy since the 1970s. The evaluation is conducted from a portfolio point of view and derives ...

  18. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-03-01T23:59:59.000Z

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  19. Development of a retrofit coal combustor for industrial applications

    SciTech Connect (OSTI)

    Not Available

    1987-01-01T23:59:59.000Z

    In this first quarterly technical report for DOE Contract No. DE-AC22-87PC79654, a description of the background, technology, and application is provided. The design and fabrication of advanced combustion chambers were completed during this period. Initial testing on both the bare metal and refractory lined advanced chambers were initiated. The units were tested initially with gas but primarily with coal. A Pittsburgh No. 8 pulverized coal was used for these test activities. Both advanced chambers pulsed well.

  20. advanced multi-product coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  1. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect (OSTI)

    B. K. Parekh; D. P. Patil

    2008-04-30T23:59:59.000Z

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

  2. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01T23:59:59.000Z

    TABLE 1. Pittsburgh seam coal properties, Grosshandler (content of the Pittsburgh seam coal. As the ash layer beginsfrom Pittsburgh seam pulverized coal, screened through a 35

  3. Advanced progress concepts for direct coal liquefaction

    SciTech Connect (OSTI)

    Anderson, R.; Derbyshire, F.; Givens, E. [Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)] [and others

    1995-09-01T23:59:59.000Z

    Given the low cost of petroleum crude, direct coal liquefaction is still not an economically viable process. The DOE objectives are to further reduce the cost of coal liquefaction to a more competitive level. In this project the primary focus is on the use of low-rank coal feedstocks. A particular strength is the use of process-derived liquids rather than model compound solvents. The original concepts are illustrated in Figure 1, where they are shown on a schematic of the Wilsonville pilot plant operation. Wilsonville operating data have been used to define a base case scenario using run {number_sign}263J, and Wilsonville process materials have been used in experimental work. The CAER has investigated: low severity CO pretreatment of coal for oxygen rejection, increasing coal reactivity and mg inhibiting the propensity for regressive reactions; the application of more active. Low-cost Fe and Mo dispersed catalysts; and the possible use of fluid coking for solids rejection and to generate an overhead product for recycle. CONSOL has investigated: oil agglomeration for coal ash rejection, for the possible rejection of ash in the recycled resid, and for catalyst addition and recovery; and distillate dewaxing to remove naphthenes and paraffins, and to generate an improved quality feed for recycle distillate hydrogenation. At Sandia, research has been concerned with the production of active hydrogen donor distillate solvent fractions produced by the hydrogenation of dewaxed distillates and by fluid coking via low severity reaction with H{sub 2}/CO/H{sub 2}O mixtures using hydrous metal oxide and other catalysts.

  4. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    site it operates at partial load in more hours Advanced Coalthe ACWH operates more often at partial load conditions to

  5. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01T23:59:59.000Z

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  6. Development of a retrofit coal combustor for industrial applications. Technical progress report, January--March 1987

    SciTech Connect (OSTI)

    Not Available

    1987-12-31T23:59:59.000Z

    In this first quarterly technical report for DOE Contract No. DE-AC22-87PC79654, a description of the background, technology, and application is provided. The design and fabrication of advanced combustion chambers were completed during this period. Initial testing on both the bare metal and refractory lined advanced chambers were initiated. The units were tested initially with gas but primarily with coal. A Pittsburgh No. 8 pulverized coal was used for these test activities. Both advanced chambers pulsed well.

  7. Measurement and modeling of advanced coal conversion processes

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States))

    1992-01-01T23:59:59.000Z

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This technology is important to reduce the technical and economic risks inherent in utilizing coal, a feedstock whose variable and often unexpected behavior presents a significant challenge. This program will merge significant advances made at Advanced Fuel Research, Inc. (AFR) in measuring and quantitatively describing the mechanisms in coal conversion behavior, with technology being developed at Brigham Young University (BYU) in comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors. The foundation to describe coal-specific conversion behavior is AFR's Functional Group (FG) and Devolatilization, Vaporization and Crosslinking (DVC) models, developed under previous and on-going METC sponsored programs. These models have demonstrated the capability to describe the time dependent evolution of individual gas species, and the amount and characteristics of tar and char. The combined FG-DVC model will be integrated with BYU's comprehensive two-dimensional reactor model, PCGC-2, which is currently the most widely used reactor simulation for combustion or gasification. The program includes: (i) validation of the submodels by comparison with laboratory data obtained in this program, (ii) extensive validation of the modified comprehensive code by comparison of predicted results with data from bench-scale and process scale investigations of gasification, mild gasification and combustion of coal or coal-derived products in heat engines, and (iii) development of well documented user friendly software applicable to a workstation'' environment.

  8. Measurement and modeling of advanced coal conversion processes

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. (Advanced Fuel Research, Inc., East Hartford, CT (United States)) [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. (Brigham Young Univ., Provo, UT (United States)) [Brigham Young Univ., Provo, UT (United States)

    1990-01-01T23:59:59.000Z

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This technology is important to reduce the technical and economic risks inherent in utilizing coal, a feedstock whose variable and often unexpected behavior presents a significant challenge. This program will merge significant advances made at Advanced Fuel Research, Inc. (AFR) in measuring and quantitatively describing the mechanisms in coal conversion behavior, with technology being developed at Brigham Young University (BYU) in comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors. The foundation to describe coal-specified conversion behavior is ARF's Functional Group (FG) and Devolatilization, Vaporization, and Crosslinking (DVC) models, developed under previous and on-going METC sponsored programs. These models have demonstrated the capability to describe the time dependent evolution of individual gas species, and the amount and characteristics of tar and char. The combined FG-DVC model will be integrated with BYU's comprehensive two-dimensional reactor model, PCGC-2, which is currently the most widely used reactor simulation for combustion or gasification. The program includes: (1) validation of the submodels by comparison with laboratory data obtained in this program, (2) extensive validation of the modified comprehensive code by comparison of predicted results with data from bench-scale and process scale investigations of gasification, mild gasification and combustion of coal or coal-derived products in heat engines, and (3) development of well documented user friendly software applicable to a workstation'' environment.

  9. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

    1982-10-26T23:59:59.000Z

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  10. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    ~ - - - - - ' Gri~ing Feed Coal Slurry Feed Pump Filterused to heat a coal-solvent slurry up to the tempera- turePULVERIZED COAL DISSOLVER PRODUCT SLURRY L-. 5 TJ'OON , ~ (

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal-to-hydrogen plant capital costs .Capital cost of pulverized coal plant ($/kW) Capital cost ofIGCC coal plant ($/kW) Capital cost of repowering PC plant

  12. Kinetic extruder - a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, John W. (Palo Alto, CA); Bonin, John H. (Sunnyvale, CA); Daniel, Jr., Arnold D. (Pleasanton, CA)

    1983-01-01T23:59:59.000Z

    Method and apparatus are shown for the continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up chamber to a plurality of two-stage sprues mounted in the rotor. Control nozzles downstream from the sprues meter the flow of coal through the sprues.

  13. Kinetic extruder - a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, J. W.; Bonin, J. H.; Daniel, A. D. Jr.

    1983-03-15T23:59:59.000Z

    Method and apparatus are shown for the continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up chamber to a plurality of two-stage sprues mounted in the rotor. Control nozzles downstream from the sprues meter the flow of coal through the sprues. 19 figs.

  14. Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 10, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Kramlich, J.C.; Chenevert, B.; Park, J.

    1995-06-01T23:59:59.000Z

    The production of ash particles from coal combustion limits it`s use as a fuel. On mechanism by which small ash particles are formed is the generation of submicron aerosols through a vaporization/condensation mechanism. Previous work has shown that coal cleaning can lead to increased emissions of aerosols. This research will investigate the means or aerosol formation in coals and the effects that various methods of coal cleaning have on aerosol production, and whether or not cleaning can be performed in a manner that will not lend itself to aerosol formation.

  15. GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS

    SciTech Connect (OSTI)

    Edwin S. Olson; Charles J. Moretti

    1999-11-01T23:59:59.000Z

    Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

  16. ADVANCED COAL & ENERGY RESEARCH FACILITY (ACERF) Washington University in St. Louis

    E-Print Network [OSTI]

    Subramanian, Venkat

    ADVANCED COAL & ENERGY RESEARCH FACILITY (ACERF) Washington University in St. Louis Overview The Advanced Coal and Energy Research Facility provides for pilot-scale research and development of new b d Ongoing Research Activities Oxy-coal combustion faculty and students within the U.S. and abroad

  17. Advanced coal-fired glass melting development program

    SciTech Connect (OSTI)

    Not Available

    1991-05-01T23:59:59.000Z

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  18. Advanced Development Of The Coal Fired Oxyfuel Process With CO2...

    Open Energy Info (EERE)

    Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name: Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) Place:...

  19. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect (OSTI)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01T23:59:59.000Z

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  20. Development of an advanced high efficiency coal combustor for boiler retrofit. Summary report

    SciTech Connect (OSTI)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01T23:59:59.000Z

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  1. Performance of a high efficiency advanced coal combustor

    SciTech Connect (OSTI)

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States))

    1989-12-01T23:59:59.000Z

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the primary act,'' and three further annuli for the supply of the secondary air.'' The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  2. Dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, John W. (Palo Alto, CA); Bonin, John H. (Sunnyvale, CA); Daniel, Jr., Arnold D. (Alameda, CA)

    1984-07-31T23:59:59.000Z

    Apparatus is shown for substantially increasing the feed rate of pulverized material into a pressurized container. The apparatus includes a rotor that is mounted internal to the pressurized container. The pulverized material is fed into an annular chamber defined by the center of the rotor. A plurality of impellers are mounted within the annular chamber for imparting torque to the pulverized material.

  3. Advanced Coal Conversion Process Demonstration Project. Environmental Monitoring Plan

    SciTech Connect (OSTI)

    Not Available

    1992-04-01T23:59:59.000Z

    Western Energy Company (WECO) was selected by the Department of Energy (DOE) to demonstrate the Advanced Coal Conversion Process (ACCP) which upgrades low rank coals into high Btu, low sulfur, synthetic bituminous coal. As specified in the Corporate Agreement, RSCP is required to develop an Environmental Monitoring Plan (EMP) which describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) identify monitoring activities that will be undertaken to show compliance to applicable regulations, (2) confirm the specific environmental impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base of the assessment of the environmental performance of the technology demonstrated by the project. The EMP specifies the streams to be monitored (e.g. gaseous, aqueous, and solid waste), the parameters to be measured (e.g. temperature, pressure, flow rate), and the species to be analyzed (e.g. sulfur compounds, nitrogen compounds, trace elements) as well as human health and safety exposure levels. The operation and frequency of the monitoring activities is specified, as well as the timing for the monitoring activities related to project phase (e.g. preconstruction, construction, commissioning, operational, post-operational). The EMP is designed to assess the environmental impacts and the environmental improvements resulting from construction and operation of the project.

  4. Environmental Analysis of the Coal-based Power Production with Amine-based Carbon Capture

    E-Print Network [OSTI]

    . Based on LCA methodology the study examines the operation of six coal power plants, which differ by the expected efficiency parameters for the year 2020: (1) Coal plant2005: pulverized coal power plant already operating in 2005 (2) Coal plant2010: pulverized coal power plant installed in 2010 (3) Coal plant2020

  5. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect (OSTI)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01T23:59:59.000Z

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  6. advanced coal utilization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 CONSORTIUM FOR CLEAN COAL UTILIZATION Materials Science Websites Summary: CONSORTIUM FOR CLEAN COAL...

  7. advanced coal cleaning: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 4th Annual Clean Coal CiteSeer Summary: Proceedings he emphasis of the Fourth Clean Coal Technology...

  8. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO[sub 2] per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO[sub 2] emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  9. Comparative Assessment of Coal-and Natural Gas-fired Power Plants under a

    E-Print Network [OSTI]

    Comparative Assessment of Coal- and Natural Gas-fired Power Plants under a CO2 Emission Performance standard (EPS) for pulverized coal (PC) and natural gas combined cycle (NGCC) power plants; · Evaluate · Coal-fired Power Plant: Supercritical pulverized coal (SC PC) Illinois #6 Coal Capacity Factor 75

  10. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Rawls, P. [Department of Energy, Pittsburgh, PA (United States)

    1995-11-01T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  11. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    SciTech Connect (OSTI)

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01T23:59:59.000Z

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  12. ADVANCED HETEROGENEOUS REBURN FUEL FROM COAL AND HOG MANURE

    SciTech Connect (OSTI)

    Melanie D. Jensen; Ronald C. Timpe; Jason D. Laumb

    2003-09-01T23:59:59.000Z

    This study was performed to investigate whether the nitrogen content inherent in hog manure and alkali used as a catalyst during processing could be combined with coal to produce a reburn fuel that would result in advanced reburning NO{sub x} control without the addition of either alkali or ammonia/urea. Fresh hog manure was processed in a cold-charge, 1-gal, batch autoclave system at 275 C under a reducing atmosphere in the presence of an alkali catalyst. Instead of the expected organic liquid, the resulting product was a waxy solid material. The waxy nature of the material made size reduction and feeding difficult as the material agglomerated and tended to melt, plugging the feeder. The material was eventually broken up and sized manually and a water-cooled feeder was designed and fabricated. Two reburn tests were performed in a pilot-scale combustor. The first test evaluated a reburn fuel mixture comprising lignite and air-dried, raw hog manure. The second test evaluated a reburn fuel mixture made of lignite and the processed hog manure. Neither reburn fuel reduced NO{sub x} levels in the combustor flue gas. Increased slagging and ash deposition were observed during both reburn tests. The material-handling and ash-fouling issues encountered during this study indicate that the use of waste-based reburn fuels could pose practical difficulties in implementation on a larger scale.

  13. Advanced coal conversion process demonstration. Progress report, January 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    NONE

    1993-12-01T23:59:59.000Z

    This report contains a description of the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1992, through December 31, 1992. This project demonstrates an advanced thermal coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and has been operating in an extended startup mode since that time. As with any new developing technology, a number of unforeseen obstacles have been encountered; however, Rosebud SynCoal Partnership has instituted an aggressive program to overcome these obstacles.

  14. advanced coal fired: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a possible co-firing fuel with coal. Cofiring of DB offers a technique of utilizing dairy manure for powersteam generation, reducing greenhouse gas concerns, and increasing...

  15. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect (OSTI)

    B. K. Karekh; D. Tao; J. G. Groppo

    1998-08-28T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 ? March 31, 1998.

  16. advanced clean coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clean coal First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 4th Annual Clean Coal CiteSeer Summary:...

  17. Means and apparatus for throttling a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA); Bonin, John H. (Sunnyvale, CA)

    1982-01-01T23:59:59.000Z

    Method and apparatus are shown for control of continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up zone chamber to a plurality of sprues mounted in the rotor. Control of the pressure within control nozzles downstream from the sprues adjusts the flow rate of coal through the sprues.

  18. Means and apparatus for throttling a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, J. W.; Daniel, Jr, A. D.; Bonin, J. H.

    1982-12-07T23:59:59.000Z

    Method and apparatus are shown for control of continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up zone chamber to a plurality of sprues mounted in the rotor. Control of the pressure within control nozzles downstream from the sprues adjusts the flow rate of coal through the sprues. 9 figs.

  19. Field study of disposed solid wastes from advanced coal processes

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells.

  20. Utilization of pulverized fuel ash in Malta

    SciTech Connect (OSTI)

    Camilleri, Josette [Department of Building and Civil Engineering, Faculty of Architecture and Civil Engineering, University of Malta, Msida (Malta); Sammut, Michael [Department of Pathology, St. Luke's Hospital, G'Mangia (Malta); Montesin, Franco E. [Department of Building and Civil Engineering, Faculty of Architecture and Civil Engineering, University of Malta, Msida (Malta)]. E-mail: franco.montesin@um.edu.mt

    2006-07-01T23:59:59.000Z

    In Malta all of the waste produced is mixed and deposited at various sites around the island. None of these sites were purpose built, and all of the waste is above groundwater level. The landfills are not engineered and do not contain any measures to collect leachate and gases emanating from the disposal sites. Another waste, which is disposed of in landfills, is pulverized fuel ash (PFA), which is a by-product of coal combustion by the power station. This has been disposed of in landfill, because its use has been precluded due to the radioactivity of the ashes. The aim of this study was to analyze the chemical composition of the pulverized fuel ash and to attempt to utilize it as a cement replacement in normal concrete mixes in the construction industry. The levels of radiation emitted from the ashes were measured by gamma spectrometry. The results of this study revealed that although at early ages cement replacement by PFA resulted in a reduction in compressive strength (P = 0), when compared to the reference concrete at later ages the strengths measured on concrete cores were comparable to the reference concrete (P > 0.05). The utilization of PFA up to 20% cement replacement in concrete did not raise the radioactivity of the concrete. In conclusion, utilization of PFA in the construction industry would be a better way of disposing of the ashes rather than controlling the leachate and any radioactivity emitted by the landfilled ashes.

  1. Ash & Pulverized Coal Deposition in Combustors & Gasifiers

    SciTech Connect (OSTI)

    Goodarz Ahmadi

    1998-12-02T23:59:59.000Z

    Further progress in achieving the objectives of the project was made in the period of January I to March 31, 1998. The direct numerical simulation of particle removal process in turbulent gas flows was completed. Variations of particle trajectories are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity for irregular fibrous particles is compared with the empirical correlation and the available data for glass fibers and discussed. Additional progress on the sublayer model for evaluating the particle deposition and resuspension in turbulent flows was made.

  2. THE SCALE-UP OF LARGE PRESSURIZED FLUIDIZED BEDS FOR ADVANCED COAL-FIRED POWER PROCESSES

    SciTech Connect (OSTI)

    Leon R. Glicksman; Michael Louge; Hesham F. Younis; Richard Tan; Mathew Hyre; Mark Torpey

    2003-11-24T23:59:59.000Z

    This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor an agency thereof, nor any of the their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, A combined-cycle High Performance Power System (HIPPS) capable of overall cycle efficiencies approaching 50% has been proposed and designed by Foster Wheeler Development Corporation (FWDC). A pyrolyzer in the first stage of the HIPPS process converts a coal feedstock into fuel gas and char at an elevated pressure of 1.4 Map. (206 psia) and elevated temperature of 930 C (1700 F). The generated char serves as the feedstock for a Pulverized Coal (PC) boiler operating at atmospheric pressure, and the fuel gas is directly fired in a gas turbine. The hydrodynamic behavior of the pyrolyzer strongly influences the quality of both the fuel gas and the generated char, the energy split between the gas turbine and the steam turbine, and hence the overall efficiency of the system. By utilizing a simplified set of scaling parameters (Glicksman et al.,1993), a 4/7th labscale cold model of the pyrolyzer operating at ambient temperature and pressure was constructed and tested. The scaling parameters matched include solid to gas density ratio, Froude number, length to diameter ratio; dimensionless superficial gas velocity and solid recycle rate, particle sphericity and particle size distribution (PSD).

  3. DOE/EA-1498: Advanced Coal Utilization Byproduct Beneficiation...

    Broader source: Energy.gov (indexed) [DOE]

    (fax) (412) 386-4512 lorenzi@netl.doe.gov Janice.Bell@NETL.DOE.GOV Abstract: The Clean Coal Power Initiative (CCPI) is a cost-shared partnership between the U.S. Department of...

  4. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  5. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-06-01T23:59:59.000Z

    This detailed report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project. This U.S. Department of Energy (DOE) Clean Coal Technology Project demonstrates an advanced thermal coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to high-quality, low-sulfur fuel. During this reporting period, the primary focus for the project was to expand market awareness and acceptability for the products and the technology. The use of covered hopper cars has been successful and marketing efforts have focused on this technique. Operational improvements are currently aimed at developing fines marketing systems, increasing throughput capacity, decreasing operation costs, and developing standardized continuous operator training. Testburns at industrial user sites were also conducted. A detailed process description; technical progress report including facility operations/plant production, facility testing, product testing, and testburn product; and process stability report are included. 3 figs., 8 tabs.

  6. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect (OSTI)

    Not Available

    1981-03-31T23:59:59.000Z

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  7. A review of ash in conventional and advanced coal-based power systems

    SciTech Connect (OSTI)

    Holcombe, N.T.

    1995-12-31T23:59:59.000Z

    Process conditions are briefly described for conventional and advanced power systems. The advanced systems include both combustion and gasification processes. We discuss problems in coal-based power generation systems, including deposition, agglomeration and sintering of bed materials, and ash attack are discussed. We also discuss methods of mitigating ash problems and anticipated changes anticipated in ash use by converting from conventional to advanced systems.

  8. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect (OSTI)

    Not Available

    1990-05-01T23:59:59.000Z

    This reports presents the operating results for Run 252 at the Advanced Coal Liquefaction R D Facility in Wilsonville, Alabama. This run operated in the Close-Coupled Integrated Two-Stage Liquefaction mode (CC-ITSL) using Illinois No. 6 bituminous coal. The primary run objective was demonstration of unit and system operability in the CC-ITSL mode with catalytic-catalytic reactors and with ash recycle. Run 252 began on 26 November 1986 and continued through 3 February 1987. During this period 214.4 MF tons of Illinois No. 6 coal were fed in 1250 hours of operation. 3 refs., 29 figs., 18 tabs.

  9. Measurement and modeling of advanced coal conversion processes, Volume III

    SciTech Connect (OSTI)

    Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G. [and others

    1993-08-01T23:59:59.000Z

    A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

  10. Engineering design and analysis of advanced physical fine coal cleaning technologies

    SciTech Connect (OSTI)

    Gallier, P.W.

    1990-10-20T23:59:59.000Z

    The major goal is to provide the simulation tools for modeling both conventional and advanced coal cleaning technologies. This project is part of a major research initiative by the Pittsburgh Energy Technology Center (PETC) aimed at advancing three advanced coal cleaning technologies-heavy-liquid cycloning, selective agglomeration, and advanced froth flotation through the proof-of-concept (POC) level. The ASPEN PLUS process simulation package will be extended to handle coal cleaning applications. Algorithms for predicting the process performance, equipment size, and flowsheet economics of commercial coal cleaning devices and related ancillary equipment will be incorporated into the coal cleaning simulator. The work plan for the froth quarter called for completion of the washability interpolation routine, gravity separation models, and dewatering models. As these items were completed, work in the areas of size reduction, classification and froth flotation were scheduled to begin. As each model was completed, testing and validation procedures were scheduled to begin. Costing models were also planned to be implemented and tested as each of the gravity separation models were completed. 1 tab.

  11. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  12. Overall requirements for an advanced underground coal extraction system

    SciTech Connect (OSTI)

    Goldsmith, M.; Lavin, M.L.

    1980-10-15T23:59:59.000Z

    This report presents overall requirements on underground mining systems suitable for coal seams exploitable in the year 2000, with particular relevance to the resources of Central Appalachia. These requirements may be summarized as follows: (1) Production Cost: demonstrate a return on incremental investment of 1.5 to 2.5 times the value required by a low-risk capital project. (2) Miner Safety: achieve at least a 50% reduction in deaths and disabling injuries per million man-hours. (3) Miner Health: meet the intent of all applicable regulations, with particular attention to coal dust, carcinogens, and mutagens; and with continued emphasis on acceptable levels of noise and vibration, lighting, humidity and temperature, and adequate work space. (4) Environmental Impact: maintain the value of mined and adjacent lands at the pre-mining value following reclamation; mitigation of off-site impacts should not cost more than the procedures used in contemporary mining. (5) Coal Conservation: the recovery of coal from the seam being mined should be at least as good as the best available contemporary technology operating in comparable conditions. No significant trade-offs between production cost and other performance indices were found.

  13. Sixth clean coal technology conference: Proceedings. Volume 1: Policy papers

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    The Sixth Clean Coal Technology Conference focused on the ability of clean coal technologies (CCTs) to meet increasingly demanding environmental requirements while simultaneously remaining competitive in both international and domestic markets. Conference speakers assessed environmental, economic, and technical issues and identified approaches that will help enable CCTs to be deployed in an era of competing, interrelated demands for energy, economic growth, and environmental protection. Recognition was given to the dynamic changes that will result from increasing competition in electricity and fuel markets and industry restructuring, both domestically and internationally. Volume 1 contains 38 papers arranged under the following topical sections: International business forum branch; Keynote session; Identification of the issues; CCTs--Providing for unprecedented environmental concerns; Domestic competitive pressures for CCTs; Financing challenges for CCTs; New markets for CCTs; Clean coal for the 21st century: What will it take? Conclusions and recommendations. The clean coal technologies discussed include advanced pulverized coal-fired boilers, atmospheric fluidized-bed combustion (FBC), pressurized FBC, integrated gasification combined-cycle systems, pressurized pulverized coal combustion, integrated gasification fuel cell systems, and magnetohydrodynamic power generation.

  14. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01T23:59:59.000Z

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  15. University coal research/historically black colleges and universities and other minority institutions contractors review meeting

    SciTech Connect (OSTI)

    NONE

    2006-07-01T23:59:59.000Z

    A variety of papers/posters were presented on topics concerning power generation, including solid oxide fuel cells, hydrogen production, mercury as a combustion product, carbon dioxide separation from flue gas. A total of 31 presentations in slide/overview/viewgraph form and with a separate abstract are available online (one in abstract form only) and 24 poster papers (text). In addition 41 abstracts only are available. Papers of particular interest include: Hydrogen production from hydrogen sulfide in IGCC power plants; Oxidation of mercury in products of coal combustion; Computer aided design of advanced turbine aerofoil alloys for industrial gas turbines in coal fired environments; Developing engineered fuel using flyash and biomass; Conversion of hydrogen sulfide in coal gases to elemental sulfur with monolithic catalysts; Intelligent control via wireless sensor networks for advanced coal combustion systems; and Investment of fly ash and activated carbon obtained from pulverized coal boilers (poster).

  16. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 pm) clean coal. Economical dewatering of an ultra-fine clean-coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 30, 1997.

  17. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  18. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect (OSTI)

    Alvin, M.A.

    2002-09-19T23:59:59.000Z

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  19. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  20. Evaluation of air toxic emissions from advanced and conventional coal-fired power plants

    SciTech Connect (OSTI)

    Chu, P.; Epstein, M. [Electric Power Research Institute, Palo Alto, CA (United States); Gould, L. [Department of Energy, Pittsburgh, PA (United States); Botros, P. [Department of Energy, Morgantown, WV (United States)

    1995-12-31T23:59:59.000Z

    This paper evaluates the air toxics measurements at three advanced power systems and a base case conventional fossil fuel power plant. The four plants tested include a pressurized fluidized bed combustor, integrated gasification combined cycle, circulating fluidized bed combustor, and a conventional coal-fired plant.

  1. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  2. The fate of alkali species in advanced coal conversion systems

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01T23:59:59.000Z

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  3. DOE's Advanced Coal Research, Development, and Demonstration Program to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"WaveInteractionsMaterialsDevelop Low-carbon Emission Coal Technologies

  4. New Clean Coal Cycle Optimized Using Pinch Technology 

    E-Print Network [OSTI]

    Rossiter, A. P.; O'Donnell, J. J.

    1990-01-01T23:59:59.000Z

    transport reaction technology, developed originally for Fluid Catalytic Cracking plants, is used in the coal conversion steps; and pulverized limestone is circulated with the coal to capture the sulfur that is released during this process. Both gas turbines...

  5. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01T23:59:59.000Z

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  6. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect (OSTI)

    Not Available

    1990-05-01T23:59:59.000Z

    The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star Mine coal Wyodak Clovis Point Mine coal were processed. Cobalt-molybdenum and disposable iron-oxide catalysts were used to improve coal liquefaction reactions and nickel-molybdenum catalysts were used in the hydrotreater. 28 refs., 31 figs., 13 tabs.

  7. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Aickelin, Uwe

    Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options Xi Liang, Jia supercritical pulverized coal power plant in China, using a cash flow model with Monte-Carlo simulations Defense Council) O&M (Operating & Maintenance) PC Power Plant (Pulverized Coal Fired Power Plant) ROA

  8. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  9. An analysis of cost effective incentives for initial commercial deployment of advanced clean coal technologies

    SciTech Connect (OSTI)

    Spencer, D.F. [SIMTECHE, Half Moon Bay, CA (United States)

    1997-12-31T23:59:59.000Z

    This analysis evaluates the incentives necessary to introduce commercial scale Advanced Clean Coal Technologies, specifically Integrated Coal Gasification Combined Cycle (ICGCC) and Pressurized Fluidized Bed Combustion (PFBC) powerplants. The incentives required to support the initial introduction of these systems are based on competitive busbar electricity costs with natural gas fired combined cycle powerplants, in baseload service. A federal government price guarantee program for up to 10 Advanced Clean Coal Technology powerplants, 5 each ICGCC and PFBC systems is recommended in order to establish the commercial viability of these systems by 2010. By utilizing a decreasing incentives approach as the technologies mature (plants 1--5 of each type), and considering the additional federal government benefits of these plants versus natural gas fired combined cycle powerplants, federal government net financial exposure is minimized. Annual net incentive outlays of approximately 150 million annually over a 20 year period could be necessary. Based on increased demand for Advanced Clean Coal Technologies beyond 2010, the federal government would be revenue neutral within 10 years of the incentives program completion.

  10. Advances in the development of wire mesh reactor for coal gasification studies - article no. 084102

    SciTech Connect (OSTI)

    Zeng, C.; Chen, L.; Liu, G.; Li, W.H.; Huang, B.M.; Zhu, H.D.; Zhang, B.; Zamansky, V. [GE Global Research Shanghai, Shanghai (China)

    2008-08-15T23:59:59.000Z

    In an effort to further understand the coal gasification behavior in entrained-flow gasifiers, a high pressure and high temperature wire mesh reactor with new features was recently built. An advanced LABVIEW-based temperature measurement and control system were adapted. Molybdenum wire mesh with aperture smaller than 70 {mu} m and type D thermocouple were used to enable high carbon conversion ({gt}90%) at temperatures {gt}1000 {sup o}C. Gaseous species from wire mesh reactor were quantified using a high sensitivity gas chromatography. The material balance of coal pyrolysis in wire mesh reactor was demonstrated for the first time by improving the volatile's quantification techniques.

  11. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01T23:59:59.000Z

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  12. TRW Advanced Slagging Coal Combustor Utility Demonstration. Fourth Quarterly progress report, August 1989--October 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O&R) Utility Corporation`s Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  13. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1993-02-12T23:59:59.000Z

    The Department of Energy (DOE) awarded a contract entitled Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation'', to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  14. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  15. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development's facility near Beverly, Ohio. OCDO's facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  16. Repowering flexibility of coal-based advanced power systems

    SciTech Connect (OSTI)

    Bajura, R.A.; Bechtel, T.F.; Schmidt, D.K.; Wimer, J.G.

    1995-03-01T23:59:59.000Z

    The Department of Energy`s (DOE`s) Morgantown Energy Technology Center (METC) helps enhance the economic competitiveness, environmental quality, and national well-being of the U.S. by developing advanced power-generation systems. The potential market for advanced power-generation systems is large. In the U.S., electric demand is estimated to grow at about 1 percent per year through the year 2010. The total power generation market also includes new-capacity as well as replacement of existing power plants as they age. Thus, the market for power systems over the next 15 years is estimated to be about 279,000 megawatts (MW), but could range from as much as 484,000 MW to as little as 153,000 MW. These predictions are summarized. Over the next 15 years, the replacement market is potentially much larger than the expansion market because of the large base of aging power plants in the U.S.

  17. Mesoporous Silicon Sponge as an Anti-Pulverization Structure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mesoporous Silicon Sponge as an Anti-Pulverization Structure for High-Performance Lithium-ion Battery Anodes. Mesoporous Silicon Sponge as an Anti-Pulverization Structure for...

  18. Impact of Advanced Turbine Systems on coal-based power plants

    SciTech Connect (OSTI)

    Bechtel, T.F.

    1993-12-31T23:59:59.000Z

    The advanced power-generation products currently under development in our program show great promise for ultimate commercial use. Four of these products are referred to in this paper: Integrated Gasification Combined Cycle (IGCC), Pressurized Fluidized Bed Combustion (PFBC), Externally Fired Combined Cycle (EFCC), and Integrated Gasification Fuel Cell (IGFC). Three of these products, IGCC, PFBC, and EFCC, rely on advanced gas turbines as a key enabling technology and the foundation for efficiencies in the range of 52 to 55 percent. DOE is funding the development of advanced gas turbines in the newly instituted Advanced Turbine Systems (ATS) Program, one of DOE`s highest priority natural gas initiatives. The turbines, which will have natural gas efficiencies of 60 percent, are being evaluated for coal gas compatibility as part of that program.

  19. (Pittsburgh Energy Technology Center): Quarterly technical progress report for the period ending June 30, 1987. [Advanced Coal Research and Technology Development Programs

    SciTech Connect (OSTI)

    None

    1988-02-01T23:59:59.000Z

    Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)

  20. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01T23:59:59.000Z

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  1. Coal combustion science: Task 1, Coal char combustion: Task 2, Fate of mineral matter. Quarterly progress report, July--September 1993

    SciTech Connect (OSTI)

    Hardesty, D.R. [ed.; Hurt, R.H.; Davis, K.A.; Baxter, L.L.

    1994-07-01T23:59:59.000Z

    Progress reports are presented for the following tasks: (1) kinetics and mechanisms of pulverized coal char combustion and (2) fate of inorganic material during coal combustion. The objective of Task 1 is to characterize the combustion behavior of selected US coals under conditions relevant to industrial pulverized coal-fired furnaces. In Sandia`s Coal Combustion Laboratory (CCL), optical techniques are used to obtain high-resolution images of individual burning coal char particles and to measure, in situ, their temperatures, sizes, and velocities. Detailed models of combustion transport processes are then used to determine kinetic parameters describing the combustion behavior as a function of coal type and combustion environment. Partially reacted char particles are also sampled and characterized with advanced materials diagnostics to understand the critical physical and chemical transformations that influence reaction rates and burnout times. The ultimate goal of the task is the establishment of a data base of the high temperature reactivities of chars from strategic US coals, from which important trends may be identified and predictive capabilities developed. The overall objectives for task 2 are: (1) to complete experimental and theoretical investigation of ash release mechanisms; (2) to complete experimental work on char fragmentation; (3) to establish the extent of coal (as opposed to char) fragmentation as a function of coal type and particle size; (4) to develop diagnostic capabilities for in situ, real-time, qualitative indications of surface species composition during ash deposition, with work continuing into FY94; (5) to develop diagnostic capabilities for in situ, real-time qualitative detection of inorganic vapor concentrations; and (6) to conduct a literature survey on the current state of understanding of ash deposition, with work continuing into FY94.

  2. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    of limestone to the coal slurry feed. Although not disclosedi.e. , pulverized or as a coal-water slurry The nature andform (PC), or as a coal-water slurry fuel (CWSF). The trace

  3. Performance of a high efficiency advanced coal combustor. Task 2, Pilot scale combustion tests: Final report

    SciTech Connect (OSTI)

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1989-12-01T23:59:59.000Z

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R&D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the ``primary act,`` and three further annuli for the supply of the ``secondary air.`` The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  4. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  5. Carbon dioxide capture from coal-fired power plants : a real potions analysis

    E-Print Network [OSTI]

    Sekar, Ram Chandra

    2005-01-01T23:59:59.000Z

    Investments in three coal-fired power generation technologies are valued using the "real options" valuation methodology in an uncertain carbon dioxide (CO2) price environment. The technologies evaluated are pulverized coal ...

  6. Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures

    E-Print Network [OSTI]

    Couling, David Joseph

    2012-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

  7. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10T23:59:59.000Z

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  8. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no new'' reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  9. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  10. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect (OSTI)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-03-30T23:59:59.000Z

    The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

  11. Hardgrove grindability index and petrology used as an enhanced predictor of coal feed rate

    SciTech Connect (OSTI)

    Hower, J.C. (Univ. of Kentucky, KY (US))

    1990-01-01T23:59:59.000Z

    An improved predictor of coal pulverization behavior and coal feed rate is under development at the CAER based upon the interaction between Hardgrove Grindability Index (HGI) and coal petrology. With educated attention, this interaction may be a useful tool to enhance coal feed rates if cautiously extended to the mining environment where blends of coal lithotypes are produced.

  12. advanced coal-fired gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal-fired unit at Hawthorn Station. Ultimately, KCPL decided to replace the destroyed steam generator with another coal-fired unit, and repower the existing turbinegenerator...

  13. Search for: "coal" | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    coal" Find + Advanced Search Advanced Search All Fields: "coal" Title: Full Text: Bibliographic Data: Creator Author: Name Name ORCID Search Authors Type: All Accepted...

  14. Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 2

    SciTech Connect (OSTI)

    McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

    1994-06-01T23:59:59.000Z

    The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume II contains papers presented at the following sessions: filter technology issues; hazardous air pollutants; sorbents and solid wastes; and membranes. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  15. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

  16. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Rashid Khan, M.

    1988-05-05T23:59:59.000Z

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

  17. NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS

    E-Print Network [OSTI]

    Fletcher, Thomas H.

    NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS by Haifeng Zhang DURING SECONDARY COAL PYROLYSIS Haifeng Zhang Department of Chemical Engineering Doctor of Philosophy Economical NOx control techniques used in pulverized coal furnaces, such as air/fuel staging, promote

  18. Measurement and modeling of advanced coal conversion processes. 23rd quarterly report, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

    1992-12-31T23:59:59.000Z

    The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This technology is important to reduce the technical and economic risks inherent in utilizing coal, a feedstock whose variable and often unexpected behavior presents a significant challenge. This program will merge significant advances made at Advanced Fuel Research, Inc. (AFR) in measuring and quantitatively describing the mechanisms in coal conversion behavior, with technology being developed at Brigham Young University (BYU) in comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors. The foundation to describe coal-specific conversion behavior is AFR`s Functional Group (FG) and Devolatilization, Vaporization and Crosslinking (DVC) models, developed under previous and on-going METC sponsored programs. These models have demonstrated the capability to describe the time dependent evolution of individual gas species, and the amount and characteristics of tar and char. The combined FG-DVC model will be integrated with BYU`s comprehensive two-dimensional reactor model, PCGC-2, which is currently the most widely used reactor simulation for combustion or gasification. The program includes: (i) validation of the submodels by comparison with laboratory data obtained in this program, (ii) extensive validation of the modified comprehensive code by comparison of predicted results with data from bench-scale and process scale investigations of gasification, mild gasification and combustion of coal or coal-derived products in heat engines, and (iii) development of well documented user friendly software applicable to a ``workstation`` environment.

  19. Advanced research and technoloty: University Coal Research Program. [Listed by state, organization and contract No. plus brief description

    SciTech Connect (OSTI)

    Not Available

    1980-08-01T23:59:59.000Z

    In October 1979, Congress provided a new budget line item of $5 million for a program open to universities with existing laboratories capable of performing coal research. In response, the Department of Energy developed a national and regional program focused on university work in coal conversion and utilization. The program emphasizes coal combustion, conversion of coal to synthetic oil and gases, and characterization of coals from various regions of the country, and encourages the investigation and development of pertinent, promising, or novel ideas for advancing our knowledge of coal science. The program was announced to the academic community in December 1979, inviting more than 2000 departments of chemistry, chemical engineering, and mechanical engineering as well as academic vice-presidents for research, and university faculty to submit coal research proposals. By March 1980, more than 500 proposals had been received for consideration. By June 1980, after technical review of the proposals, 41 grants were awarded to 33 universities in 24 states. Each of these projects is described by means of a single-page summary that includes pertinent technical and fiscal information. The University Coal Research Program complements other DOE Fossil Energy activities with universities consisting of more than 400 active projects with an annual funding level of about $42 million. However, the new program differs in several respects: (1) it is performed through grants, rather than contracts or cooperative agreements, thereby offering investigators greater leeway in approaches to performance of their research objectives, (2) although mission oriented, it supports somewhat longer-term and more fundamental projects, and (3) it includes the training of students as an important objective.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 16, July 1, 1992--September 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

  1. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    of deploying advanced coal power in the Chinese context,”12 2.6. International coal prices and12 III. Chinese Coal

  2. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal-Biomass Feed and Gasification The Coal-Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal...

  3. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-05-01T23:59:59.000Z

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  4. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect (OSTI)

    B.K. PAREKH; D. TAO; J.G. GROPPO

    1998-02-03T23:59:59.000Z

    The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

  5. Cyclone Boiler Reburn NOx Control Improvements via Cyclone Design Improvements and Advanced Air Staging

    E-Print Network [OSTI]

    Morabito, B.; Nee, B.; Goff, V.; Maringo, G.

    2008-01-01T23:59:59.000Z

    Eastman Kodak owns three Babcock & Wilcox coal fired cyclone boilers and one Combustion Engineering pulverized coal boiler located at Kodak Park in Rochester, New York. Duke Energy Generation Services (DEGS) operates and maintains the steam...

  6. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.

    2003-09-12T23:59:59.000Z

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  7. Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systems

    SciTech Connect (OSTI)

    Anbo Wang; Gary Pickrell

    2011-12-31T23:59:59.000Z

    This report summarizes technical progress on the program â??Multiplexed Optical Fiber Sensors for Coal Fired Advanced Fossil Energy Systemsâ?ť funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed jointly by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering and the Department of Materials Science and Engineering at Virginia Tech. This three-year project started on October 1, 2008. In the project, a fiber optical sensing system based on intrinsic Fabry-Perot Interferometer (IFPI) was developed for strain and temperature measurements for Ultra Supercritical boiler condition assessment. Investigations were focused on sensor design, fabrication, attachment techniques and novel materials for high temperature and strain measurements. At the start of the project, the technical requirements for the sensing technology were determined together with our industrial partner Alstom Power. As is demonstrated in Chapter 4, all the technical requirements are successfully met. The success of the technology extended beyond laboratory test; its capability was further validated through the field test at DOE NETL, in which the sensors yielded distributed temperature mapping of a testing coupon installed in the turbine test rig. The measurement results agreed well with prior results generated with thermocouples. In this project, significant improvements were made to the IFPI sensor technology by splicing condition optimization, transmission loss reduction, sensor signal demodulation and sensor system design.

  8. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect (OSTI)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri,; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-11-30T23:59:59.000Z

    This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grinding and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.

  9. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01T23:59:59.000Z

    or gaseous fuels, coal gasification has advanced furthestrapidly. While coal gasification may reach commercializa-5272 (1976). COal Processing - Gasification, Liguefaction,

  10. Construction Begins on First-of-its-Kind Advanced Clean Coal...

    Broader source: Energy.gov (indexed) [DOE]

    "This groundbreaking represents a significant milestone in the President's Clean Coal Power Initiative, which aims to reduce emissions and improve the efficiency of...

  11. Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect (OSTI)

    Malhotra, V.M.; Wright, M.A.

    1995-12-31T23:59:59.000Z

    The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADM unit1-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM unit1-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}0.5H{sub 2}O) phase. In the second and third quarters the focus of research has been on developing protocols for the formation of advanced brake composites and structural composites. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disks from coal combustion residues. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites.

  12. Design and fabrication of advanced materials from Illinois coal wastes. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect (OSTI)

    Malhotra, V.M.; Wright, M.A. [Southern Illinois Univ., Carbondale, IL (United States)

    1995-12-31T23:59:59.000Z

    The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first two quarters of the project, the thrust of the work directed towards characterizing the various coal combustion residues and FGD residue, i.e., scrubber sludge. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), differential thermal analysis (DTA), and transmission-Fourier transform infrared (FTIR) were conducted on PCC fly ash (Baldwin), FBC fly ash (ADK unit l-6), FBC fly ash (S.I. coal), FBC spent bed ash (ADM, unit l-6), bottom ash, and scrubber sludge (CWLP) residues to characterize their geometrical shapes, mineral phases, and thermal stability. Our spectroscopic results indicate that the scrubber sludge is mainly composed of a gypsum-like phase whose lattice structure is different from the lattice structure of conventional gypsum, and sludge does not contain hannebachite (CaSO{sub 3}.0.5H{sub 2}O) phase. Our attempts to fabricate brake frictional shoes, in the form of 1.25 inch disks, from PCC fly ash, FBC spent bed ash, scrubber sludge, coal char, iron particles, and coal tar were successful. Based on the experience gained and microscopic analyses, we have now upscaled our procedures to fabricate 2.5 inch diameter disk,- from coal combustion residues. This has been achieved. The SEM and Young`s modulus analyses of brake composites fabricated at 400 psi < Pressure < 2200 psi suggest pressure has a strong influence on the particle packing and the filling of interstices in our composites. Also, these results along with mechanical behavior of the fabricated disks lead us to believe that the combination of surface altered PCC fly ash and scrubber sludge particles, together ed ash particles are ideal for our composite materials.

  13. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  14. Illinois Coal Development Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Development Program seeks to advance promising clean coal technologies beyond research and towards commercialization. The program provides a 50/50 match with private industry...

  15. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15T23:59:59.000Z

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  16. Staged fluidized-bed coal combustor for boiler retrofit

    SciTech Connect (OSTI)

    Rehmat, A. (Institute of Gas Technology, Chicago, IL (United States)); Dorfman, L.; Shibayama, G. (Fluor-Daniels, Inc., Chicago, IL (United States)); Waibel, R. (Zink (J.) and Co., Tulsa, OK (United States))

    1991-01-01T23:59:59.000Z

    The Advanced Staged Fluidized-Bed Coal Combustion System (ASC) is a novel clean coal technology for either coal-fired repowering of existing boilers or for incremental power generation using combined-cycle gas turbines. This new technology combines staged combustion for gaseous emission control, in-situ sulfur capture, and an ash agglomeration/vitrification process for the agglomeration/vitrification of ash and spent sorbent, thus rendering solid waste environmentally benign. The market for ASC is expected to be for clean coal-fired repowering of generating units up to 250 MW, especially for units where space is limited. The expected tightening of the environmental requirements on leachable solids residue by-products could considerably increase the marketability for ASC. ASC consists of modular low-pressure vessels in which coal is partially combusted and gasified using stacked fluidized-bed processes to produce low-to-medium-Btu, high-temperature gas. This relatively clean fuel gas is used to repower/refuel existing pulverized-coal, natural gas, or oil-fired boilers using bottom firing and reburning techniques. The benefits of ASC coal-fired repowering include the ability to repower boilers without obtaining additional space while meeting the more stringent environmental requirements of the future. Low NO{sub x}, SO{sub x}, and particulate levels are expected while a nonleachable solid residue with trace metal encapsulation is produced. ASC also minimizes boiler modification and life-extension expenditures. Repowered efficiencies can be restored to the initial operating plant efficiency, and the existing boiler capacity can be increased by 10%. Preliminary cost estimates indicate that ASC will have up to a $250/kW capital cost advantage over existing coal-fired repowering options. 4 figs., 4 tabs.

  17. Second generation PFB for advanced power generation

    SciTech Connect (OSTI)

    Robertson, A.; Van Hook, J.

    1995-11-01T23:59:59.000Z

    Research is being conducted under a United States Department of Energy (USDOE) contract to develop a new type of coal-fueled plant for electric power generation. This new type of plant-called an advanced or second-generation pressurized fluidized bed combustion (APFBC) plant-offers the promise of 45-percent efficiency (HHV), with emissions and a cost of electricity that are significantly lower than conventional pulverized-coal-fired plants with scrubbers. This paper summarizes the pilot plant R&D work being conducted to develop this new type of plant. Although pilot plant testing is still underway, preliminary estimates indicate the commercial plant Will perform better than originally envisioned. Efficiencies greater than 46 percent are now being predicted.

  18. Task 3.0: Advanced power systems. Semi-annual report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    McCollor, D.P.; Zygarlicke, C.J.; Mann, M.D.; Willson, W.G.; Hurley, J.P.

    1993-07-01T23:59:59.000Z

    A variety of activities are incorporated into the Advanced Power Systems program. Tasks included are (1) fuel utilization properties, (2) pressurized combustion, (3) catalytic gasification, and (4) hot-gas cleanup. ATRAN is stochastic and combines initial coal inorganics in a random manner in order to predict the resulting fly ash particle size and composition. ASHPERT, is an expert system yielding a first-order estimate of fly ash size and composition. Both models are designed to emulate pulverized-coal combustion. Input data required include identity, chemistry, size, quantity, and mineral-to-coal associations. The pressurized combustion task has focused on the construction of a versatile reactor system to simulate pressurized fluidized-bed combustion. Both castable and monolithic refractories have been investigated in determining slag prevention under a variety of conditions. Catalytic gasification coupled with a molten carbonate fuel cell offers an extremely efficient and environmentally sound power generating system using coal. Work with an Illinois No. 6 bituminous coal has not been successful. Continued efforts will focus on using the more reactive low-rank coals to try to achieve this goal. Hot-gas cleanup is the critical issue in many of the proposed advanced power system operations on coal. The key to successful ash removal is an understanding of the properties of the ash to be collected as well as the interactions of this material with the barrier itself. The knowledge base under development will assist in assessing many of these barrier material issues for a variety of coal ashes.

  19. Financing Capture Ready Coal-Fired Power Plants in China by Issuing Capture Options

    E-Print Network [OSTI]

    Liang, Xi; Reiner, David; Gibbons, Jon; Li, Jia

    investors diversify risk, and offer global warming investors an alternative investment opportunity. As a detailed case study, we assess the value of a Capture Option and Capture Ready plant for a 600 MW supercritical pulverized coal power plant in China...

  20. Future Carbon Regulations and Current Investments in Alternative Coal-Fired Power Plant Designs

    E-Print Network [OSTI]

    Sekar, Ram C.

    This paper assesses the role of uncertainty over future U.S. carbon regulations in shaping the current choice of which type of power plant to build. The pulverized coal technology (PC) still offer the lowest cost power— ...

  1. Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

    DOE Patents [OSTI]

    Burnet, George (Ames, IA); Gokhale, Ashok J. (College Station, TX)

    1990-07-10T23:59:59.000Z

    A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste, and method for producing the same, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces.

  2. Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

    DOE Patents [OSTI]

    Burnet, G.; Gokhale, A.J.

    1990-07-10T23:59:59.000Z

    A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste and method for producing the same are disclosed, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces. 3 figs.

  3. Unraveling the Excess Air/Coal Fineness Enigma

    E-Print Network [OSTI]

    Laspe, C. G.

    1983-01-01T23:59:59.000Z

    In the use of powered coal as a boiler fuel, the factors involved in heat loss from unburnt carbon in the ash are but partially understood. More finely pulverized coal particles will result in lower carbon-in-ash losses. On the other hand, the finer...

  4. Group pyrolysis, ignition, and combustion of a spherical cloud of coal particles

    E-Print Network [OSTI]

    Ryan, William Richard

    1988-01-01T23:59:59.000Z

    , and combustion of pulverized coal. Finally, the relevance of group combustion studies to practical systems is discussed. 2. 1. Grou Combustion and Terminolo Group combustion implies the formation of a common flame around a large number of drops... of the processes involved in practical burners, these studies are useful in the prevention of dust cloud explosions. The experimental apparatus and conditions for conducting pulverized coal ignition studies are described briefly: (1. ) Transport Reactors...

  5. Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes

    E-Print Network [OSTI]

    Gong, Bo, Ph. D. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

  6. Making coal burnable: preparation and use

    SciTech Connect (OSTI)

    Rittenhouse, R.C.

    1985-06-01T23:59:59.000Z

    This paper offers several different views on the tools available to boost the burnability of coal. One view of making coal burnable and for better emissions control lies in the combustion process. One approach is fluidized bed combustion and the two choices within this technology are atmospheric (AFBC) and pressurized (PFBC). Several tests are being conducted to develop the slagging combustor technology for direct conversion from oil to coal. Some advantages listed for this method are a simple retrofit, low particulate, NO/sub x/ and SO/sub 2/ emissions, no modification for burning pulverized coal or coal/water slurry, no ash and no moving parts. Another method discussed is coal blending. The industrial and utility coal burning demand, combined with vacillating regulatory situations, reveals a need for coal users to be ever more alert to fuel price and availability. Technologies in the three areas of application -- coal preparation/cleaning, combustion, and emissions control -- offer an endless array of combinations.

  7. Capture-Ready Coal Plants -Options, Technologies and Economics Mark C. Bohm1

    E-Print Network [OSTI]

    1 Capture-Ready Coal Plants - Options, Technologies and Economics Mark C. Bohm1 , Howard J. Herzog1 be employed during the initial design and construction of a both pulverized coal and integrated gasification the Internet in the summer of 2006 [7]. Introduction Interest in the construction of coal-fired power

  8. Subtask 3.9 - Direct Coal Liquefaction Process Development

    SciTech Connect (OSTI)

    Aulich, Ted; Sharma, Ramesh

    2012-07-01T23:59:59.000Z

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha?middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright? Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  9. The Armco/B and W coal injection technology

    SciTech Connect (OSTI)

    Sexton, J.R. [AK Steel Corp., Ashland, KY (United States)

    1994-12-31T23:59:59.000Z

    A general presentation is given of the development of pulverized coal injection at the Ashland Works from the initial installation in 1963 to the present. An explanation of the flow sheets for pulverization and injection along with safety and explosion prevention will be discussed. The unique parameters of the Armco/B and W system will be explained and the operations at various steel plants presented.

  10. Integration of a high efficiency flue gas cleanup process into advanced power systems

    SciTech Connect (OSTI)

    Hoffman, J.S.; Pennline, H.W.; Yeh, J.T.; Ratafia-Brown, J.A.; Gorokhov, V.A.

    1994-12-31T23:59:59.000Z

    The Moving-Bed Copper Oxide Process, a dry, regenerable flue gas cleanup technology, can simultaneously remove sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emissions from the flue gases generated by coal combustion. While this advanced air pollution abatement process technology has only been previously considered for conventional utility system applications, its unique design characteristics make it quite advantageous for use in advanced power systems, such as those pulverized-coal-fired systems defined in the US Department of Energy`s Combustion 2000 Initiative. Integration of this flue gas cleanup process into the advanced power systems is technically and economically assessed and compared with several commercially available flue gas cleanup processes. An update on the status of the Moving-Bed Copper oxide Process development is also presented.

  11. advanced coal-based power: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . . . . 18 3.4.1 Heat Exchanger - Code description . . . . . . . . . . . . . . . 18 3.4.2 Simulation ResultsADVANCED POWER PLANT MODELING WITH APPLICATIONS TO THE ADVANCED BOILING...

  12. advanced coal-fired low-emission: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . . . . 18 3.4.1 Heat Exchanger - Code description . . . . . . . . . . . . . . . 18 3.4.2 Simulation ResultsADVANCED POWER PLANT MODELING WITH APPLICATIONS TO THE ADVANCED BOILING...

  13. advanced coal-fueled gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . . . . 18 3.4.1 Heat Exchanger - Code description . . . . . . . . . . . . . . . 18 3.4.2 Simulation ResultsADVANCED POWER PLANT MODELING WITH APPLICATIONS TO THE ADVANCED BOILING...

  14. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 16, July--September, 1996

    SciTech Connect (OSTI)

    Shields, G.L.; Moro, N.; Smit, F.J.; Jha, M.C.

    1996-10-30T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. 28 refs., 13 figs., 19 tabs.

  15. POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE

    SciTech Connect (OSTI)

    X.H. Wang; J. Wiseman; D.J. Sung; D. McLean; William Peters; Jim Mullins; John Hugh; G. Evans; Vince Hamilton; Kenneth Robinette; Tim Krim; Michael Fleet

    1999-08-01T23:59:59.000Z

    Dewatering of ultra-fine (minus 150 {micro}m) coal slurry to less than 20% moisture is difficult using the conventional dewatering techniques. The main objective of the project was to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions and surfactants in combination for the dewatering of ultra-fine clean-coal slurries using various dewatering techniques on a proof-of-concept (POC) scale of 0.5 to 2 tons per hour. The addition of conventional reagents and the application of coal surface modification technique were evaluated using vacuum filtration, hyperbaric (pressure) filtration, ceramic plate filtration and screen-bowl centrifuge techniques. The laboratory and pilot-scale dewatering studies were conducted using the fine-size, clean-coal slurry produced in the column flotation circuit at the Powell Mountain Coal Company, St. Charles, VA. The pilot-scale studies were conducted at the Mayflower preparation plant in St. Charles, VA. The program consisted of nine tasks, namely, Task 1--Project Work Planning, Task 2--Laboratory Testing, Task 3--Engineering Design, Task 4--Procurement and Fabrication, Task 5--Installation and Shakedown, Task 6--System Operation, Task 7--Process Evaluation, Task 8--Equipment Removal, and Task 9--Reporting.

  16. Field study for disposal of solid wastes from Advanced Coal Processes: Ohio LIMB Site Assessment. Final report, April 1986--November 1994

    SciTech Connect (OSTI)

    Weinberg, A.; Coel, B.J.; Butler, R.D.

    1994-10-01T23:59:59.000Z

    New air pollution regulations will require cleaner, more efficient processes for converting coal to electricity, producing solid byproducts or wastes that differ from conventional pulverized-coal combustion ash. Large scale landfill test cells containing byproducts were built at 3 sites and are to be monitored over at least 3 years. This report presents results of a 3-y field test at an ash disposal site in northern Ohio; the field test used ash from a combined lime injection-multistage burner (LIMB) retrofit at the Ohio Edison Edgewater plant. The landfill test cells used LIMB ash wetted only to control dusting in one cell, and LIMB ash wetted to optimize compaction density in the other cell. Both test cells had adequate load-bearing strength for landfill stability but had continuing dimensional instability. Heaving and expansion did not affect the landfill stability but probably contributed to greater permeability to infiltrating water. Leachate migration occurred from the base, but effects on downgradient groundwater were limited to increased chloride concentration in one well. Compressive strength of landfilled ash was adequate to support equipment, although permeability was higher and strength was lower than anticipated. Average moisture content has increased to about 90% (dry weight basis). Significant water infiltration has occurred; the model suggests that as much as 20% of the incident rainfall will pass through and exit as leachate. However, impacts on shallow ground water is minimal. Results of this field study suggest that LIMB ash from combustion of moderate to high sulfur coals will perform acceptably if engineering controls are used to condition and compact the materials, reduce water influx to the landfill, and minimize leachate production. Handling of the ash did not pose serious problems during cell construction; steaming and heat buildup were moderate.

  17. Oil shale, tar sand, coal research, advanced exploratory process technology jointly sponsored research. Quarterly technical progress report, April--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesa Verde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced recovery techniques; and menu driven access to the WDEQ Hydrologic Data Management Systems.

  18. Plasma-supported coal combustion in boiler furnace

    SciTech Connect (OSTI)

    Askarova, A.S.; Karpenko, E.I.; Lavrishcheva, Y.I.; Messerle, V.E.; Ustimenko, A.B. [Kazakh National University, Alma Ata (Kazakhstan). Dept. of Physics

    2007-12-15T23:59:59.000Z

    Plasma activation promotes more effective and environmentally friendly low-rank coal combustion. This paper presents Plasma Fuel Systems that increase the burning efficiency of coal. The systems were tested for fuel oil-free start-up of coal-fired boilers and stabilization of a pulverized-coal flame in power-generating boilers equipped with different types of burners, and burning all types of power-generating coal. Also, numerical modeling results of a plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler are discussed in this paper. Two kinetic mathematical models were used in the investigation of the processes of air/fuel mixture plasma activation: ignition and combustion. A I-D kinetic code PLASMA-COAL calculates the concentrations of species, temperatures, and velocities of the treated coal/air mixture in a burner incorporating a plasma source. The I-D simulation results are initial data for the 3-D-modeling of power boiler furnaces by the code FLOREAN. A comprehensive image of plasma-activated coal combustion processes in a furnace of a pulverized-coal-fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated.

  19. Cost and U.S. public policy for new coal power plants with carbon capture and sequestration

    E-Print Network [OSTI]

    Hamilton, Michael R.

    This paper provides a financial analysis for new supercritical pulverized coal plants with carbon capture and sequestration (CCS) that compares the effects of two relevant climate policies. First, an updated cost estimate ...

  20. The Phase Inversion-based Coal-CO? Slurry (PHICCOS) feeding system : design, coupled multiscale analysis, and technoeconomic assessment

    E-Print Network [OSTI]

    Botero, Cristina, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    The continuous conveying of a solid feedstock like pulverized coal into a pressurized environment is a challenging task required in multiple industrial processes. Plants based on pressurized, entrained-flow gasifiers (EFG) ...

  1. Advanced coal liquefaction research. Quarterly technical progress report, July 1, 1983-September 30, 1983

    SciTech Connect (OSTI)

    None

    1984-04-01T23:59:59.000Z

    Work this quarter focused on staged liquefaction. The effect of residence time on conversion in single pass experiments was found to be quite different for the subbituminous Belle Ayr Mine and bituminous Illinois No. 6 coals studied. With bituminous coal, conversion to soluble material is quite high and the limit of conversion is approached in only a few minutes. With a subbituminous coal, however, conversion is much lower and the limit of conversion is approached much more slowly. Short contact time (SCT) dissolution of Belle Ayr coal was studied as a possible first stage in a two-stage process. Conversion, hydrocarbon gas yield and hydrogen consumption were increased as residence time or temperature were increased. Conversion was also significantly increased by partial slurry recycle. Pyrite was found to be the most effective slurry catalyst for increasing conversion, followed by ammonium molybdate emulsion and finally nickel-molybdenum on alumina. Illinois No. 6 coal was liquefied in two stages. Conditions in the first stage dissolution were varied to determine the effect on upgradability in the second stage. An SCT (6 minute) coal dissolution stage is preferred over one at 30 minutes because hydrocarbon gas yield was much lower while overall oil yields for the combined dissolution and upgrading stages were nearly the same. Use of a NiMo/Al/sub 2/O/sub 3/ catalyst in a trickle-bed second stage resulted in a higher oil yield and lower product heteroatom content than use of the same catalyst in the slurry phase. The total oil yield was lower with a pyrite slurry catalyst than with a NiMo/Al/sub 2/O/sub 3/ slurry catalyst. With Belle Ayr coal and added pyrite, there was no change in total oil yield, conversion or product quality brought about by adding an 8-minute first stage at 450/sup 0/C (842/sup 0/F) to a 2-hour second stage operated at 420/sup 0/C (788/sup 0/F). 39 figures, 12 tables.

  2. Development of advanced, dry, SO{sub x}/NO{sub x} emission control technologies for high-sulfur coal. Final report, April 1, 1993--December 31, 1994

    SciTech Connect (OSTI)

    Amrhein, G.T.

    1994-12-23T23:59:59.000Z

    Dry Scrubbing is a common commercial process that has been limited to low- and medium-sulfur coal applications because high-sulfur coal requires more reagent than can be efficiently injected into the process. Babcock & Wilcox has made several advances that extend dry scrubbing technologies to higher sulfur coals by allowing deposit-free operation at low scrubber exit temperatures. This not only increases the amount of reagent that can be injected into the scrubber, but also increases SO{sub 2} removal efficiency and sorbent utilization. The objectives of this project were to demonstrate, at pilot scale, that advanced, dry-scrubbing-based technologies can attain the performance levels specified by the 1990 Clean Air Act Amendments for SO{sub 2} and NO{sub x} emissions while burning high-sulfur coal, and that these technologies are economically competitive with wet scrubber systems. The use of these technologies by utilities in and around Ohio, on new or retrofit applications, will ensure the future of markets for high-sulfur coal by creating cost effective options to coal switching.

  3. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K.

    1996-02-01T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  4. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1993-02-12T23:59:59.000Z

    Work completed produced the criteria for additional engineering analysis, computation and detailed experimental benchscale testing for areas of uncertainty. The engineering analysis, computation, bench-scale testing and component development was formulated to produce necessary design information to define a commercially operating system. In order to produce the required information by means of bench-scale testing and component development, a uniform coal sample was procured. After agreement with DOE, a selected sample of coal from those previously listed was secured. The test plan was developed in two parts. The first part listed procedures for engineering and computational analyses of those deficiencies previously identified that could be solved without bench scale testing. Likewise, the second part prepared procedures for bench-scale testing and component development for those deficiencies previously identified in Task 3.

  5. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect (OSTI)

    Kloosterman, Jeff

    2012-12-31T23:59:59.000Z

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  6. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, No. 4, July 1995--September 1995

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K.

    1995-11-06T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 29, 1995.

  7. advanced coal-gasification technical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University, Department of Engineering, Technical Report 97-25, December 1997. Based Pont, Michael J. 260 Memory Hierarchy: Advanced Concepts Computer Technologies and...

  8. Containment control in four advanced coal conversion power generation systems: Technical issues and R and D needs: Final report

    SciTech Connect (OSTI)

    DiBella, C.A.W.; Fillo, J.P.; Koraido, S.M.

    1987-03-01T23:59:59.000Z

    The objective of this study is to identify technical issues regarding gas stream contaminants and to develop suggested R and D programs to deal with the technicl issues in the following four advanced coal conversion systems for electric power generation: fixed-bed gasifier integrated combined-cycle system; fluidized-bed gasifier integrated combined-cycle system; direct coal fired turbine system; and pressurized fluidized-bed combustion/turbine system. All systems are pressurized and air-blown, use gas turbines with steam bottoming cycles, and use hot gas clean-up systems to achieve contaminant levels low enough to meet equipment protection considerations and environmental regulations. The contaminants included in this study fall into the following categories: sulfur compounds; nitrogen compounds; trace elements; particulates/solids; organic compounds, and alkali metals/halides. Although the focus of the study is principally on gas-stream contaminants, impact of contaminants on solid waste streams is considered to identify potential waste disposal issues. A total of 53 technical issues were identified, and an R an D need was developed for each issue. The issues were prioritized based on the impact on commercialization. Those issues representing significant impediments to commercialization were assigned high priority. It is recommended that current research activities be investigated in detail to determine if high priority technical issues are being addressed.

  9. Design and fabrication of advanced materials from Illinois coal wastes. [Quarterly] technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Malhotra, V.M.; Wright, M.A. [Southern Illinois Univ., Carbondale, IL (United States)

    1994-12-31T23:59:59.000Z

    The main goal of this project is to develop a bench-scale procedure to design and fabricate advanced brake and structural composite materials from Illinois coal combustion residues. During the first quarter of the project, the thrust of the work was directed towards setting up the experimental facilities and undertaking preliminary tests to gauge the ability of coal tar derived binder in fabricating the brake skeletons. In addition systematic scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and differential thermal analysis (DTA) were conducted on PCC fly ash (Baldwin), fly ash (ADM), FBC fly ash, FBC spent bed bottom ash, bottom ash (ADM), and scrubber sludge residues to characterize their geometrical shape and thermal stability. The PCC fly ash particles being highly spherical in shape and thermally inert up to 1100{degrees}C will make an excellent raw material for our composites. This is born out by fabricating brake skeletons from PCC fly ash colloids. Unlike the PCC fly ash and FBC fly ash, the scrubber sludge particles are not suitable hosts for our brake lining materials because of a whisker-like particle structure. Six different compositions of various combustion residues were tested in the fabrication of brake skeletons, and our tar derived binder shows great promise in the fabrication of composite materials.

  10. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect (OSTI)

    Geiling, D.W. [ed.

    1993-08-01T23:59:59.000Z

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  11. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  12. CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants

    SciTech Connect (OSTI)

    NONE

    2007-01-15T23:59:59.000Z

    To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

  13. [Engineering development of advanced coal-fired low-emission boiler systems]. Technical progress report, October--December 1995

    SciTech Connect (OSTI)

    Wesnor, J.D.; Bakke, E. [ABB Environmental Systems, Birmingham, AL (United States); Bender, D.J.; Kaminski, R.S. [Raytheon Engineers and Constructors, Inc., Philadelphia, PA (United States)

    1995-12-31T23:59:59.000Z

    The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emisssion boiler systems. The primary objectives are: NO{sub x} emissions, lb/million Btu; SO{sub 2} emissions, lb/million Btu; particulate emissions, lb/million Btu; and net plant efficiency, not less than 42%. The secondary objectives are: improved ash disposability; reduced waste generation; and reduced air toxics emissions. Accomplishments to date are summarized for the following tasks: task 1, project planning and management; task 7, component development and optimization; task 8, preliminary POC test facility design; task 9, subsystem test design and plan; task 10, subsystem test unit construction; and task 11, subsystem test operation and evaluation.

  14. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01T23:59:59.000Z

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  15. Utility Generation and Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    This statute establishes the state's support and incentives for the development of new energy production and generating facilities implementing advanced clean coal technology, such as coal...

  16. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 18, July--September 1993

    SciTech Connect (OSTI)

    Chow, O.K.; Hargrove, M.J.

    1993-11-01T23:59:59.000Z

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Continued with data and sample analysis from the pilot-scale tests of Upper Freeport feed coal, air-dried and mulled microagglomerate products; air-dried Pittsburgh No. 8 as-is and mulled products for upcoming Task 3 combustion testing; and prepared two abstracts for presentation for the March 1 994 Coal Utilization and Fuel Systems Conference.

  17. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08T23:59:59.000Z

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  18. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 14, January--March 1996

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-04-30T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by June 1997. During Quarter 14 (January--March 1996), parametric testing of the 30-inch Microcel{trademark} flotation column at the Lady Dunn Plant continued under Subtask 3.2. Subtask 3. 3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter with parametric testing of the batch dewatering unit. Coal product moistures of 3 to 12 percent were achieved, with higher percent solids slurry feeds resulting in lower product moistures. For a given percent solids feed, the product moisture decreased with increasing butane to dry coal ratios. Stirring time, stirring rate, and settling time were all found to have little effect on the final moisture content. Continuing Subtask 6.4 work, investigating coal-water-fuel slurry formulation for coals cleaned by selective agglomeration, indicated that pH adjustment to 10 resulted in marginally better (lower viscosity) slurries for one of the two coals tested. Subtask 6.5 agglomeration bench-scale testing results indicate that the new Taggart coal requires a grind with a d{sub 80} of approximately 33 microns to achieve the 1 lb ash/MBtu product quality specification. Also under Subtask 6.5, reductions in the various trace element concentrations accomplished during selective agglomeration were determined. Work was essentially completed on the detailed design of the PDU selective agglomeration module under Task 7 with the issuing of a draft report.

  19. Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

    DOE Patents [OSTI]

    Sheldon, Ray W. (Huntley, MT)

    2001-01-01T23:59:59.000Z

    The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

  20. Modeling Creep-Fatigue-Environment Interactions in Steam Turbine Rotor Materials for Advanced Ultra-supercritical Coal Power Plants

    SciTech Connect (OSTI)

    Shen, Chen

    2014-01-20T23:59:59.000Z

    The goal of this project is to model creep-fatigue-environment interactions in steam turbine rotor materials for advanced ultra-supercritical (A-USC) coal power Alloy 282 plants, to develop and demonstrate computational algorithms for alloy property predictions, and to determine and model key mechanisms that contribute to the damages caused by creep-fatigue-environment interactions. The nickel based Alloy 282 is selected for this project because it is one of the leading candidate materials for the high temperature/pressure section of an A-USC steam turbine. The methods developed in the project are expected to be applicable to other metal alloys in similar steam/oxidation environments. The major developments are: ? failure mechanism and microstructural characterization ? atomistic and first principles modeling of crack tip oxygen embrittlement ? modeling of gamma prime microstructures and mesoscale microstructure-defect interactions ? microstructure and damage-based creep prediction ? multi-scale crack growth modeling considering oxidation, viscoplasticity and fatigue The technology developed in this project is expected to enable more accurate prediction of long service life of advanced alloys for A-USC power plants, and provide faster and more effective materials design, development, and implementation than current state-of-the-art computational and experimental methods. This document is a final technical report for the project, covering efforts conducted from January 2011 to January 2014.

  1. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    1998-09-01T23:59:59.000Z

    The goals of the project are two-fold: (1) to upgrade semi-quantitative X-ray diffraction (QXRD) methods presently used in analyzing complex coal combustion by-product (CCB) systems, with the quantitative Rietveld method, and (2) to apply this method to a set of by-product materials that have been disposed or utilized for a long period (5 years or more) in contact with the natural environment, to further study the nature of CCB diagenesis. The project is organized into three tasks to accomplish these two goals: (1) thorough characterization of a set of previously analyzed disposed by-product materials, (2) development of a set of CCB-specific protocols for Rietveld QXRD, and (3) characterization of an additional set of disposed CCB materials, including application of the protocols for Rietveld QXRD developed in Task 2.

  2. Development of advanced NO[sub x] control concepts for coal-fired utility boiler

    SciTech Connect (OSTI)

    Evans, A.; Pont, J.N.; England, G.; Seeker, W.R.

    1993-02-11T23:59:59.000Z

    Hybrid technologies for the reduction of NO[sub x] emissions from coal-fired utility boilers have shown the potential to offer greater levels of NO[sub x] control than the sum of the individual technologies, leading to more cost effective emissions control strategies. Energy and Environmental Research Corporation (EER) has developed a hybrid NO[sub x] control strategy involving two proprietary concepts which has the potential to meet the US Department of Energy's NO[sub x] reduction goal at a significant reduction in cost compared to existing technology. The process has been named CombiNO[sub x]. CombiNO[sub x] is an integration of three technologies: modified reburning, promoted selective noncatalytic reduction (SNCR) and methanol injection. These technologies are combined to achieve high levels of NO[sub x] emission reduction from coal-fired power plants equipped with S0[sub x] scrubbers. The first two steps, modified reburning and promoted SNCR are linked. It has been shown that performance of the SNCR agent is dependent upon local oxidation of CO. Reburning is used to generate the optimum amount of CO to promote the SNCR agent. Approximately 10 percent reburning is required, this represents half of that required for conventional reburning. If the reburn fuel is natural gas, the combination of reburning and SNCR may result in a significant cost savings over conventional reburning. The third step, injection of methanol into the flue gas, is used to oxidize NO to N0[sub 2] which may subsequently be removed in a wet scrubber. Pilot-scale tests performed at EER's 1 MMBtu/hr Boiler Simulation Facility (BSF) have demonstrated NO[sub x] reductions up to 92%. The program's next phase entails process scale-up to a 10 MMBtu/hr furnace also located at EER's Santa Anna test site.

  3. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect (OSTI)

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01T23:59:59.000Z

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  4. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 15, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-12T23:59:59.000Z

    The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  5. Advanced CO{sub 2} Capture Technology for Low Rank Coal IGCC System

    SciTech Connect (OSTI)

    Alptekin, Gokhan

    2013-09-30T23:59:59.000Z

    The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in The overall objective of the project is to demonstrate the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low rank coals. The plant uses an integrated CO{sub 2} scrubber/Water Gas Shift (WGS) catalyst to capture over90 percent capture of the CO{sub 2} emissions, while providing a significantly lower cost of electricity (COE) than a similar plant with conventional cold gas cleanup system based on SelexolTM technology and 90 percent carbon capture. TDA’s system uses a high temperature physical adsorbent capable of removing CO{sub 2} above the dew point of the synthesis gas and a commercial WGS catalyst that can effectively convert CO in bituminous coal the net plant efficiency is about 2.4 percentage points higher than an Integrated Gasification Combined Cycle (IGCC) plant equipped with SelexolTM to capture CO{sub 2}. We also previously completed two successful field demonstrations: one at the National Carbon Capture Center (Southern- Wilsonville, AL) in 2011, and a second demonstration in fall of 2012 at the Wabash River IGCC plant (Terra Haute, IN). In this project, we first optimized the sorbent to catalyst ratio used in the combined WGS and CO{sub 2} capture process and confirmed the technical feasibility in bench-scale experiments. In these tests, we did not observe any CO breakthrough both during adsorption and desorption steps indicating that there is complete conversion of CO to CO{sub 2} and H{sub 2}. The overall CO conversions above 90 percent were observed. The sorbent achieved a total CO{sub 2} loading of 7.82 percent wt. of which 5.68 percent is from conversion of CO into CO{sub 2}. The results of the system analysis suggest that the TDA combined shift and high temperature PSA-based Warm Gas Clean-up technology can make a substantial improvement in the IGCC plant thermal performance for a plant designed to achieve near zero emissions (including greater than 90 percent carbon capture). The capital expenses are also expected to be lower than those of Selexol. The higher net plant efficiency and lower capital and operating costs result in substantial reduction in the COE for the IGCC plant equipped with the TDA combined shift and high temperature PSA-based carbon capture system.

  6. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01T23:59:59.000Z

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  7. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    SciTech Connect (OSTI)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  8. Assessment of instrumentation needs for advanced coal power plant applications: Final report

    SciTech Connect (OSTI)

    Nelson, E.T.; Fischer, W.H.; Lipka, J.V.; Rutkowski, M.D.; Zaharchuk, R.

    1987-10-01T23:59:59.000Z

    The purpose of this study was to identify contaminants, identify instrumentation needs, assess available instrumentation and identify instruments that should be developed for controlling and monitoring gas streams encountered in the following power plants: Integrated Gasification Combined Cycle, Pressurized Fluidized Bed Combustion, and Gasification Molten Carbonate Fuel Cell. Emphasis was placed on hot gas cleanup system gas stream analysis, and included process control, research and environmental monitoring needs. Commercial process analyzers, typical of those currently used for process control purposes, were reviewed for the purpose of indicating commercial status. No instrument selection guidelines were found which were capable of replacing user interaction with the process analyzer vendors. This study leads to the following conclusions: available process analyzers for coal-derived gas cleanup applications satisfy current power system process control and regulatory requirements, but they are troublesome to maintain; commercial gas conditioning systems and in situ analyzers continue to be unavailable for hot gas cleanup applications; many research-oriented gas stream characterization and toxicity assessment needs can not be met by commercially available process analyzers; and greater emphasis should be placed on instrumentation and control system planning for future power plant applications. Analyzers for specific compounds are not recommended other than those needed for current process control purposes. Instead, some generally useful on-line laser-based and inductively coupled plasma methods are recommended for further development because of their potential for use in present hot gas cleanup research and future optimization, component protection and regulation compliance activities. 48 refs., 21 figs., 26 tabs.

  9. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    The construction of the DOE POC at the OCDO facility continued through this entire quarter. By the end of the quarter approximately 90% of all of the construction had been completed. All equipment has beeninstalled, checked for mechanical and installation and operated from a local pushbutton. During this quarter a review of items to be completed for start-up was compiled. This information was then presented to the construction subcontractors and agreement was concluded that all items will be completed and operational for processing coal by February 1, 1993. There are still several items that were not on site for installation during this quarter. These items are the flocculant controls supplied by Westec Engineering, Inc., and the discharge valve for the hyperbaric filter supplied by KHD. Neither of these items will prevent start-up. The flocculants can be manually controlled and provisions are all ready provided to bypass the hyperbaric filter to the Sharpels high-G centrifuge. Both of these items are scheduled for delivery in mid-January.

  10. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 14, January 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    In order to develop additional confidence in the conceptual design of the advanced froth flotation circuit, a 2-3 TPH Proof-of-Concept (POC) facility was necessary. During operation of this facility, the ICF KE team will demonstrate the ability of the conceptual flowsheets to meet the program goals of maximum pyritic sulfur reduction coupled with maximum energy recovery on three DOE specified coals. The POC circuit was designed to be integrated into the Ohio Coal Development`s facility near Beverly, Ohio. OCDO`s facility will provide the precleaning unit operations and ICF KE will add the advanced froth flotation circuitry. The work in this task will include the POC conceptual design, flowsheet development, equipment list, fabrication and construction drawings, procurement specifications and bid packages and a facilities.

  11. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30T23:59:59.000Z

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would suffer from low throughput capacities and high maintenance requirements. In general, surface area-based separators (e.g., shaking tables, magnetic drum separator, electrodynamic separator, etc.) have lower throughput capacities than volume-based separators (e.g., flotation cell, dense-medium bath, cyclones, etc.) by an order of magnitude. Furthermore, the electrodes of the laboratory unit need to be cleaned frequently, creating a high maintenance requirement if it is scaled-up to a commercial unit. The bench-scale continuous TES unit developed at NETL, on the other hand, separates positively and negatively charged particles by splitting the gaseous stream containing these particles in an electric field by means of a flow splitter, so that the oppositely charged particles can be directed into different compartments. This device is fundamentally different from the laboratory unit in that the former is a surface area-based separator, while the latter is a volume-based separator. The bench-scale unit is referred to as an entrained flow separator by the in-house researchers at NETL. Thus, the entrained flow TES unit is a significant improvement over the laboratory unit with regard to throughput capacity. In the present work, the entrained flow separator concept will be utilized for developing a proof-of concept (POC) separator that can be scaled-up to commercial size units. To accomplish this, it is necessary to develop a bench-scale separator that can achieve high Btu recoveries while maintaining the high degree of separation efficiencies. It is the objective of the present investigation to develop an efficient separator by studying the mechanisms of triboelectrification and investigating better ways of separating the charged particles. An important criterion for developing efficient separators is that they not only provide high separation efficiencies but also have high throughput capacities, which are essential ingredients for successful commercialization.

  12. Low NOx nozzle tip for a pulverized solid fuel furnace

    DOE Patents [OSTI]

    Donais, Richard E; Hellewell, Todd D; Lewis, Robert D; Richards, Galen H; Towle, David P

    2014-04-22T23:59:59.000Z

    A nozzle tip [100] for a pulverized solid fuel pipe nozzle [200] of a pulverized solid fuel-fired furnace includes: a primary air shroud [120] having an inlet [102] and an outlet [104], wherein the inlet [102] receives a fuel flow [230]; and a flow splitter [180] disposed within the primary air shroud [120], wherein the flow splitter disperses particles in the fuel flow [230] to the outlet [104] to provide a fuel flow jet which reduces NOx in the pulverized solid fuel-fired furnace. In alternative embodiments, the flow splitter [180] may be wedge shaped and extend partially or entirely across the outlet [104]. In another alternative embodiment, flow splitter [180] may be moved forward toward the inlet [102] to create a recessed design.

  13. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  14. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Topical report, LNCFS Levels 1 and 3 test results

    SciTech Connect (OSTI)

    Not Available

    1993-08-17T23:59:59.000Z

    This report presents results from the third phase of an Innovative Clean Coal Technology (ICC-1) project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The purpose of this project was to study the NO{sub x} emissions characteristics of ABB Combustion Engineering`s (ABB CE) Low NO{sub x} Concentric Firing System (LNCFS) Levels I, II, and III. These technologies were installed and tested in a stepwise fashion at Gulf Power Company`s Plant Lansing Smith Unit 2. The objective of this report is to provide the results from Phase III. During that phase, Levels I and III of the ABB C-E Services Low NO{sub x} Concentric Firing System were tested. The LNCFS Level III technology includes separated overfire air, close coupled overfire air, clustered coal nozzles, flame attachment coal nozzle tips, and concentric firing. The LNCFS Level I was simulated by closing the separated overfire air nozzles of the LNCFS Level III system. Based upon long-term data, LNCFS Level HI reduced NO{sub x} emissions by 45 percent at full load. LOI levels with LNCFS Level III increased slightly, however, tests showed that LOI levels with LNCFS Level III were highly dependent upon coal fineness. After correcting for leakage air through the separated overfire air system, the simulated LNCFS Level I reduced NO{sub x} emissions by 37 percent. There was no increase in LOI with LNCFS Level I.

  15. Exxon Chemical's Coal-Fired Combined Cycle Power Technology

    E-Print Network [OSTI]

    Guide, J. J.

    EXXON CHEMICAL'S COAL-FIRED COMBINED CYCLE POWER TECHNOLOGY John J. Guide, P.E. Exxon Chemical Company Florham Park, New Jersey ABSTRACT Exxon Chemical's Central Engineering Divi sion has recently developed and patented CAT...-PAC for Industrial Cogeneration and Utility Power Plants. It involves the marriage of a conven tional direct pulverized coal-fired boiler radiant section with a convection section adapted ~rom our furnace experience. In particular, it 1S an open-cycle, hot air...

  16. Experimental studies on the group combustion of coal char particles

    E-Print Network [OSTI]

    Dahdah, Tarek Farid

    1988-01-01T23:59:59.000Z

    of temperatures in excess of 1200 K was built for this purpose. Although this study concerns char combustion, the apparatus can also be used for ignition Journal model is Journal of Heat Transfer. and combustion of pulverized coal particles. What is char...EXPERIMENTAL STUDIES ON THE GROUP COMBUSTION OF COAL CHAR PARTICLES A Thesis by TAREK FARID DAHDAH Submitted to the Graduate College of Texas ASSAM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May...

  17. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01T23:59:59.000Z

    for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

  18. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    application (coal gasification, coal combustion followed byversions of advanced gasification processes show promise ofFixed-Bed Low-Btu Coal Gasification Systems for Retrofitting

  19. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Electric Generation Technology Conventional Coal-Fired PowerPlants Advanced Coal-Electric Plants OperatingCharacteristics for Conventional Coal- Fired Power

  20. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-09-01T23:59:59.000Z

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  1. Development and testing of a high efficiency advanced coal combustor: Phase 3, Industrial boiler retrofit. Quarterly technical progress report No. 13, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Patel, R.L.; Borio, R. [ABB Combustion Engineering, Inc., Windsor, CT (United States); Scaroni, A.W.; Miller, B.G. [Pennsylvania State, PA (United States); McGowan, J.G. [Massachusetts Univ. (United States)

    1995-03-07T23:59:59.000Z

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. During this reporting period, activities included completing the ``Task 3 Topical Report.`` The report is being reviewed internally by the ABB CE project team. Overall, all the program goals were met except carbon conversion efficiency. Based on all the results obtained to date the ABB CE/Penn State team believes that conducting the 1000 hr demonstration (Task 5) is warranted. Since, Penn State has planned to conduct long term combustion tests on micronized coal and coal-water fuels for other DOE-funded Projects during the first quarter of 1995, the demonstration phase (Task 5) of the subject program is tentatively scheduled to begin in June 1995, pending DOE approval. Work continued under Task 4.0 to complete the ``Commercialization Plan`` with ABB CE`s cognizant Business Unit. To address the lower combustion efficiency than the original project goal (95% vs 98%) during Task 3, the data were evaluated in-detail to understand which of the key parameters might be adjusted to achieve the desired burnout. To identify reasons for this lower combustion efficiency, and to evaluate which of the key parameters (i.e, coal fineness, residence time, coal reactivities etc.) are important for maximizing the combustion efficiency, ABB CE`s proprietary mathematical model known as the Lower Furnace Program-Slice Kinetic Model (LFP-SKM) was used for simulating the combustion process in the Penn State boiler (at full load firing rate). Fuel kinetic information for this study was selected on a surrogate basis from ABB CE`s extensive in-house data base.

  2. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo (Ames, IA); Squires, Thomas G. (Gilbert, IA); Venier, Clifford G. (Ames, IA)

    1985-02-05T23:59:59.000Z

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  3. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11T23:59:59.000Z

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  4. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2009-06-30T23:59:59.000Z

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i.e. Florida) are oversupplied as well. While the total US demand for ultrafine pozzolan is currently equal to demand, there is no reason to expect a significant increase in demand. Despite the technical merits identified in the pilot plant work with regard to beneficiating the entire pond ash stream, market developments in the Ohio River Valley area during 2006-2007 were not conducive to demonstrating the project at the scale proposed in the Cooperative Agreement. As a result, Cemex withdrew from the project in 2006 citing unfavorable local market conditions in the foreseeable future at the demonstration site. During the Budget Period 1 extensions provided by the DOE, CAER has contacted several other companies, including cement producers and ash marketing concerns for private cost share. Based on the prevailing demand-supply situation, these companies had expressed interest only in limited product lines, rather than the entire ash beneficiation product stream. Although CAER had generated interest in the technology, a financial commitment to proceed to Budget Period 2 could not be obtained from private companies. Furthermore, the prospects of any decisions being reached within a reasonable time frame were dim. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007. The activities presented in this report were carried out during the Cooperative Agreement period 08 November 2004 through 31 March 2007.

  5. RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    2001-01-01T23:59:59.000Z

    Prior to the initiation of this study, understanding of the long-term behavior of environmentally-exposed Coal Combustion By-Products (CCBs) was lacking in (among others) two primary areas addressed in this work. First, no method had been successfully applied to achieve full quantitative analysis of the partitioning of chemical constituents into reactive or passive crystalline or noncrystalline compounds. Rather, only semi-quantitative methods were available, with large associated errors. Second, our understanding of the long-term behavior of various CCBs in contact with the natural environment was based on a relatively limited set of study materials. This study addressed these areas with two objectives, producing (1) a set of protocols for fully quantitative phase analysis using the Rietveld Quantitative X-ray Diffraction (RQXRD) method and (2) greater understanding of the hydrologic and geochemical nature of the long-term behavior of disposed and utilized CCBs. The RQXRD technique was initially tested using (1) mixtures of National Institute of Standards and Technology (NIST) crystalline standards, and (2) mixtures of synthetic reagents simulating various CCBs, to determine accuracy and precision of the method, and to determine the most favorable protocols to follow in order to efficiently quantify multi-phase mixtures. Four sets of borehole samples of disposed or utilized CCBs were retrieved and analyzed by RQXRD according to the protocols developed under the first objective. The first set of samples, from a Class F ash settling pond in Kentucky disposed for up to 20 years, showed little mineralogical alteration, as expected. The second set of samples, from an embankment in Indiana containing a mixture of chain-grate (stoker) furnace ash and fluidized bed combustion (FBC) residues, showed formation of the mineral thaumasite, as observed in previously studied exposed FBC materials. Two high-calcium CCBs studied, including a dry-process flue gas desulfurization (FGD) by-product disposed in the Midwest, and a mixture of Class C fly ash and wet process FGD by-product codisposed in North Dakota, appeared relatively unchanged mineralogically over the up to 5 and 17 years of emplacement, respectively. Each of these two materials contained mineralogies consistent with short-term hydration products of their respective starting (dry) materials. The hydration product ettringite persisted throughout the duration of emplacement at each site, and the diagenetic ash alteration product thaumasite did not form at either site. Explanations for the absence of thaumasite in these two sites include a lack of significant carbonate, sulfate, and alkalinity sources in the case of the North Dakota site, and a lack of sulfate, alkalinity, and sufficient moisture in the Midwest site. Potential for future thaumasite formation in these materials may exist if placed in contact with cold, wet materials containing the missing components listed above. In the presence of the sulfite scrubber mineral hannebachite, the ettringites formed had crystallographic unit cell dimensions smaller than those of pure sulfate ettringite, suggesting either incorporation of sulfite ions into the ettringite structure, or incorporation of silicon and carbonate ions, forming a solid solution towards thaumasite.

  6. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01T23:59:59.000Z

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  7. Development and testing of a high efficiency advanced coal combustor: Phase III, Industrial boiler retrofit. Quarterly technical progress report No. 14, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Patel, R.L.; Borio, R. [ABB Combustion Engineering Systems, Windsor, CT (United States). U.S. Power Plant Labs.; Scaroni, A.W.; Miller, B.G. [Pennsylvania State Univ., PA (United States); McGowan, J.G. [Massachusetts Univ., MA (United States)

    1995-04-28T23:59:59.000Z

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the fourteenth quarter (January `95 through March `95) of the program. The ABB project team met with cognizant DOE-PETC and Penn State personnel on February 15, 1995 at Penn State to discuss our ideas for a new burner (RSFC-based) to replace the HEACC burner prior to the long term ({approximately}1000 hrs) demonstration phase of this project. The main reasons for the proposed new burner were to improve combustion efficiencies and NO{sub x} reduction. Recent, experience at MIT with 5 million Btu/hr coal firing experiments on RSFC burner have shown remarkable performance. Results indicate that RSFC-based burner has the potential to produce lower NO{sub x} and higher carbon conversion efficiencies than the HEACC burner. M.I.T. developed the RSFC burner and obtained a patent for the concept. A decision was made to go with the new, RSFC-based burner during 1000 hr demonstration. ABB-CE will fund the costs ({approximately}$50K) for design/fabrication of the proposed new burner. Penn State plans to improve coal handling by installation of a gravimetric feeder and redesign/installation of a mass flow bottom on the surge bin.

  8. Development and testing of a high efficiency advanced coal combustor, Phase III industrial boiler retrofit. Quarterly technical progress report No. 15, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Scaroni, A.W.; Miller, B.G.; McGowan, J.G.

    1995-08-29T23:59:59.000Z

    The objective of this project is to retrofit a burner capable of firing microfine coal to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the fifteenth quarter (April `95 through June `95) of the program. The overall program has consisted of five major tasks: (1.0) A review of current state-of-the-art coal firing system components. (2.0) Design and experimental testing of a prototype HEACC (High Efficiency Advanced Coal Combustor) burner. (3.0) Installation and testing of a prototype HEACC system in a commercial retrofit application. (4.0) Economics evaluation of the HEACC concept for retrofit applications. (5.0) Long term demonstration under commercial user demand conditions. Task 1 through Task 4 were previously completed. Based on all the results obtained to date the ABB/Penn State team and DOE/PETC have decided to conduct a 1000 hr demonstration test (Task 5). Importantly, a decision was made to employ a new burner for the demonstration. The new burner is based on the concept called {open_quotes}Radially Stratified Flame Core (RSFC){close_quotes}, developed by MIT and licensed by ABB. Work under Task 5 of this program was started during this reporting period.

  9. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    SciTech Connect (OSTI)

    Dennis, R.A.

    1997-05-01T23:59:59.000Z

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

  10. Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks

    SciTech Connect (OSTI)

    Karmis, Michael; Luttrell, Gerald; Ripepi, Nino; Bratton, Robert; Dohm, Erich

    2014-06-30T23:59:59.000Z

    The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering design and economic feasibility of briquette production. The briquette production studies indicate that strong and durable co-firing feedstocks can be produced by co-briquetting coal and biomass resources commonly available in the United States. It is demonstrated that binderless coal-biomass briquettes produced at optimized conditions exhibit very high strength and durability, which indicates that such briquettes would remain competent in the presence of forces encountered in handling, storage and transportation. The gasification studies conducted demonstrate that coal-biomass mixtures and briquettes are exceptional gasification feedstocks, particularly with regard to the synergistic effects realized during devolatilization of the blended materials. The mixture combustion studies indicate that coal-biomass mixtures are exceptional combustion feedstocks, while the briquette combustion study indicates that the use of blended briquettes reduces NO{sub x}, CO{sub 2}, and CO emissions, and requires the least amount of changes in the operating conditions of an existing coal-fired power plant. Similar results were obtained for the physical durability of the pilot-scale briquettes compared to the bench-scale tests. Finally, the conceptual engineering and feasibility analysis study for a commercial-scale briquetting production facility provides preliminary flowsheet and cost simulations to evaluate the various feedstocks, equipment selection and operating parameters.

  11. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

    2012-01-01T23:59:59.000Z

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?˘ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?˘ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?˘ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?˘ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?˘ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?˘ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

  12. Field study of disposed solid wastes from advanced coal processes. Annual technical progress report, October 1991--September 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute`s fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison`s limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United`s mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells.

  13. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-02-03T23:59:59.000Z

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an Advanced Overfire Air (AOFA) system followed by Low NO{sub x} Burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  14. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, third quarter 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-03T23:59:59.000Z

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an Advanced Overfire Air (AOFA) system followed by Low NO{sub x} Burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency.

  15. ccpi-multi-product-coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Industrial Carbon Capture and Storage Clean Coal Power Initiative Power Plant Improvement Initiative Clean Coal Technology Demonstration Program FutureGen Advanced Multi-Product...

  16. Clean Coal Research

    Broader source: Energy.gov [DOE]

    DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled...

  17. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  18. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  19. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 12, July 1, 1991--September 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    The design criteria for each unit operation have been developed based upon a number of variables. These variables, at this time, are based upon the best engineering design information available to industry. A number of assumptions utilized in the design criteria are uncertain. The uncertainties of inert atmospheres for grinding and flotation as well as pyrite depressants were answered by the Surface Control Project. It was determined that inerting was not required and no ``new`` reagents were presented that improved the flotation results. In addition, Tasks 5 and 6 results indicated the required reagent dosage for conventional flotation and advanced flotation. Task 5 results also indicated the need for a clean coal,thickener, the flocculent dosages for both the clean coal and refuse thickeners, and final dewatering requirements. The results from Tasks 5 and 6 and summarized in Task 7 indicate several uncertainties that require continuous long duration testing. The first is the possibility of producing a grab product for both the Pittsburgh and Illinois No. 6 coals in conventional flotation. Second what does long-term recirculation of clarified water do to the product quality? The verification process and real data obtained from Tasks 5 and 6 greatly reduced the capital and operating costs for the process. This was anticipated and the test work indeed provided confirming data.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 11, April 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  1. Studies of in-situ calcium based sorbents in advanced pressurized coal conversion systems. Final report, June 1991--October 1994

    SciTech Connect (OSTI)

    Katta, S.; Shires, P.J.; Campbell, W.M.; Henningsen, G.

    1994-10-01T23:59:59.000Z

    The overall objective of this project was to obtain experimental data on the reactions of calcium-based sorbents in both air-blown coal gasification systems and second generation fluid bed coal combustion systems (partial gasification) as well as stabilization of the spent sorbent produced. The project consisted of six tasks: Tasks 1 and 2 dealt mostly with project-related activities and preparation of test equipment, Task 3 -- study on sulfidation of calcium-based sorbents, Task 4 -- kinetic studies on calcium-catalyzed carbon gasification reactions, and Task 5 -- oxidation of CaS present in LASHs and DASHs (mixtures of coal ash and limestone or dolomite respectively) to CaSO{sub 4} and absorption of SO{sub 2} on various solids, and Task 6 -- economic evaluation of the most promising CaS oxidation method developed under this program. Experimental studies were conducted primarily to address Task 5 issues, and are discussed in this report.

  2. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-11-25T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  3. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Fourth quarterly technical progress report, [October--December, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This quarterly report discusses the technical progress of a U. S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NOx control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NOx concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NOx reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. During this quarter, tests of the LNCFS Level III system were conducted to determine the effect that fuel fineness has on NOx emissions and unburned carbon levels. Results showed that changing the fineness of the fuel has almost no effect on NOx emissions; however, unburned carbon levels can be reduced significantly by increasing fuel fineness.

  4. Engineering development of advanced coal-fired low-emission boiler systems. Technical progress report No. 11, April 1995--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-30T23:59:59.000Z

    The Pittsburgh Energy Technology Center of the U.S. Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the {open_quotes}Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems{close_quotes} Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis and Phases II and III on a cost-share basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: (1) NO{sub x} emissions not greater than one-third NSPS. (2) SO{sub x} emissions not greater than one-third NSPS. (3) Particulate emissions not greater than one-half NSPS. The specific secondary objectives are: (1) Improved ash disposability and reduced waste generation. (2) Reduced air toxics emissions. (3) Increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a Commercial Generation Unit. The work in Phase I covered a 24-month period and included system analysis, RD&T Plan formulation, component definition, and preliminary Commercial Generating Unit (CGU) design. Phase II will cover a 15-month period and will include preliminary Proof-of-Concept Test Facility (POCTF) design and subsystem testing. Phase III will cover a 9-month period and will produce a revised CGU design and a revised POCTF design, cost estimate and a test plan. Phase IV, the final Phase, will cover a 36-month period and will include POCTF detailed design, construction, testing, and evaluation.

  5. Energy Systems Engineering 1 Clean Coal Technologies

    E-Print Network [OSTI]

    Banerjee, Rangan

    Energy Systems Engineering 1 Clean Coal Technologies Presentation at BARC 4th December 2007 #12/kWh) 0.14 0.03 0.6 #12;Energy Systems Engineering 9 Status of Advanced Coal Technologies Types of advanced coal technologies Supercritical Pulverised Combustion Circulating Fluidised Bed Combustion (CFBC

  6. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Final report

    SciTech Connect (OSTI)

    Patel, R.L.; Thornock, D.E.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1998-03-01T23:59:59.000Z

    Economics and/or political intervention may one day dictate the conversion from oil or natural gas to coal in boilers that were originally designed to burn oil or gas. In recognition of this future possibility the US Department of Energy, Federal Energy Technical Center (DOE-FETC) supported a program led by ABB Power Plant Laboratories with support from the Energy and Fuels Research Center of Penn State University with the goal of demonstrating the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of the overall goal the following specific objectives were targeted: develop a coal handling/preparation system that can meet the technical and operational requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; maintain boiler thermal performance in accordance with specifications when burning oil or natural gas; maintain NOx emissions at or below 0.6 lb NO{sub 2} per million Btu; achieve combustion efficiencies of 98% or higher; and determine economic payback periods as a function of key variables.

  7. Low-Rank Coal Grinding Performance Versus Power Plant Performance

    SciTech Connect (OSTI)

    Rajive Ganguli; Sukumar Bandopadhyay

    2008-12-31T23:59:59.000Z

    The intent of this project was to demonstrate that Alaskan low-rank coal, which is high in volatile content, need not be ground as fine as bituminous coal (typically low in volatile content) for optimum combustion in power plants. The grind or particle size distribution (PSD), which is quantified by percentage of pulverized coal passing 74 microns (200 mesh), affects the pulverizer throughput in power plants. The finer the grind, the lower the throughput. For a power plant to maintain combustion levels, throughput needs to be high. The problem of particle size is compounded for Alaskan coal since it has a low Hardgrove grindability index (HGI); that is, it is difficult to grind. If the thesis of this project is demonstrated, then Alaskan coal need not be ground to the industry standard, thereby alleviating somewhat the low HGI issue (and, hopefully, furthering the salability of Alaskan coal). This project studied the relationship between PSD and power plant efficiency, emissions, and mill power consumption for low-rank high-volatile-content Alaskan coal. The emissions studied were CO, CO{sub 2}, NO{sub x}, SO{sub 2}, and Hg (only two tests). The tested PSD range was 42 to 81 percent passing 76 microns. Within the tested range, there was very little correlation between PSD and power plant efficiency, CO, NO{sub x}, and SO{sub 2}. Hg emissions were very low and, therefore, did not allow comparison between grind sizes. Mill power consumption was lower for coarser grinds.

  8. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    SciTech Connect (OSTI)

    Rick Honaker; Gerald Luttrell

    2007-09-30T23:59:59.000Z

    The concept of using a dry, density-based separator to achieve efficient, near-face rock removal, commonly referred to as deshaling, was evaluated in several applications across the U.S.. Varying amounts of high-density rock exist in most run-of-mine feed. In the central Appalachian coalfields, a rock content exceeding 50% in the feed to a preparation plant is commonplace due to high amounts of out-of-seam dilution made necessary by extracting coal from thin seams. In the western U.S, an increase in out-of-seam dilution and environmental regulations associated with combustion emissions have resulted in a need to clean low rank coals and dry cleaning may be the only option. A 5 ton/hr mobile deshaling unit incorporating a density-based, air-table technology commercially known as the FGX Separator has been evaluated at mine sites located within the states of Utah, Wyoming, Texas, West Virginia, Virginia, Pennsylvania and Kentucky. The FGX technology utilizes table riffling principles with air as the medium. Air enters through the table and creates a fluidized bed of particles comprised of mostly fine, high density particles. The high density particle bed lifts the low-density coal particles to the top of the bed. The low-density coal moves toward the front of the table due to mass action and the downward slope of the table. The high-density particles settle through the fluidized particle bed and, upon making contact with the table, moves toward the back of the table with the assistance of table vibration. As a result, the low-density coal particles exit the front of the table closest to the feed whereas the high-density, high-ash content particles leave on the side and front of the table located at the farthest from the feed entry. At each test site, the run-of-mine feed was either directly fed to the FGX unit or pre-screened to remove the majority of the -6mm material. The surface moisture of the feed must be maintained below 9%. Pre-screening is required when the surface moisture of the feed coal exceeds the maximum limit. However, the content of -6mm in the feed to the FGX separator should be maintained between 10% and 20% to ensure an adequate fluidized bed. A parametric evaluation was conducted using a 3-level experimental design at each test site to identify the optimum separation performance and parameter values. The test data was used to develop empirical expressions that describe the response variables (i.e., mass yield and product ash content) as a function of the operating parameter values. From this process, it was established that table frequency and longitudinal slope are the most critical factors in controlling both mass yield and clean coal ash while the cross table slope was the least significant. Fan blower frequency is a critical parameter that controls mass yield. Although the splitter positions between product and middling streams and the middling and tailing streams were held constant during the tests, a separate evaluation indicated that performance is sensitive to splitter position within certain lengths of the table and insensitive in others. For a Utah bituminous coal, the FGX separator provided clean coal ash contents that ranged from a low of 8.57% to a high of 12.48% from a feed coal containing around 17% ash. From the 29 tests involved in the statistically designed test program, the average clean coal ash content was 10.76% while the tailings ash content averaged around 72%. One of the best separation performances achieved an ash reduction from 17.36% to 10.67% while recovering 85.9% of the total feed mass, which equated to an ash rejection value of around 47%. The total sulfur content was typically decreased from 1.61% to 1.49%. These performances were quantified by blending the middlings stream with the clean coal product. At a second Utah site, coal sources from three different bituminous coal seams were treated by the FGX deshaling unit. Three parameter values were varied based on the results obtained from Site No. 1 to obtain the optimum results shown in Table E-1. Approximately 9 tests w

  9. Basic combustion and pollutant-formation processes for pulverized fuels. Quarterly technical progress report No. 4, 1 July 1981-30 September 1981

    SciTech Connect (OSTI)

    Germane, G.J.; Smoot, L.D.

    1981-10-15T23:59:59.000Z

    This contract study of basic combustion and pollutant formation processes for pulverized solid fossil fuels includes coal-water mixtures and chars derived from coal pyrolysis, liquefaction or gasification processes. The factors that affect the physical properties of coal-water mixtures (CWM) have been identified and characterization tests initiated to determine how these variables (e.g., solids loading, particle size, particle size distribution, additives) affect the coal slurries. A bench-scale apparatus consisting of a pressure vessel and an atomizing nozzle was designed and is being fabricated. This apparatus will assist in the development of handling and atomization techniques for the combustion tests. It will also aid in comparing viscosities of slurries of different solids loadings and coal types. Chars were obtained for characterization tests. A series of potential tests to characterize the chars was identified. Grading and sizing of the chars was begun as well as elemental analysis. Samples of the chars were sent to Phillips for CO/sub 2/ reactivity tests to be performed. Coding for incorporation of swirling flows into the two-dimensional coal combustion model (PCGC-2) was completed. Debugging was initiated and sample computations are performed for a gaseous, isothermal system for low swirl numbers. Convergence problems were encountered when attempts were made to complete runs at higher swirl numbers.

  10. Gary No. 13 blast furnace achieves 400 lbs/THM coal injection in 9 months

    SciTech Connect (OSTI)

    Sherman, G.J.; Schuett, K.J.; White, D.G.; O`Donnell, E.M. [U.S. Steel Group, Gary, IN (United States)

    1995-12-01T23:59:59.000Z

    Number 13 Blast Furnace at Gary began injecting Pulverized Coal in March 1993. The injection level was increased over the next nine months until a level off 409 lbs/THM was achieved for the month of December 1993. Several major areas were critical in achieving this high level of Pulverized coal injection (PCI) including furnace conditions, lance position, tuyere blockage, operating philosophy, and outages. The paper discusses the modifications made to achieve this level of injection. This injection level decreased charged dry coke rate from 750 lbs/THM to about 625 lbs/THM, while eliminating 150 lbs/THM of oil and 20 lbs/THM of natural gas. Assuming a 1.3 replacement ratio for an oil/natural gas mixture, overall coke replacement for the coal is about 0.87 lbs coke/lbs coal. Gary Works anticipates levels of 500 lbs/THM are conceivable.

  11. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  12. Refining and upgrading of synfuels from coal and oil shales by advanced catalytic processes. Quarterly report, January-March 1981

    SciTech Connect (OSTI)

    Sullivan, R. F.; O'Rear, D. J.

    1981-05-01T23:59:59.000Z

    Samples of SRC-II naphtha, middle distillate, and heavy distillate were received and analyzed. These samples are part of a planned study of the potential biological hazards of synthetic crudes. These oils will be hydrotreated when DOE provides blending instructions. Five drums of EDS syncrude made from Big Brown Texas lignite were received and analyzed. The boiling range and other properties of this syncrude are very similar to the properties of the previously studied H-Coal and SRC-II syncrudes. The hydrotreating severities, which were employed to upgrade the H-Coal and SRC-II syncrudes to transportation fuels, are expected to be close to the severities needed for the EDS syncrude.

  13. An SAIC Report Prepared for The Indiana Center for Coal Technology

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    ....................................................................................................................... 15 1.6.2 Implement advanced clean coal technologies for production of energy products ........ 15

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect (OSTI)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01T23:59:59.000Z

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  15. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, second quarter 1992

    SciTech Connect (OSTI)

    Not Available

    1992-11-25T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progress report presents the LNCFS Level I short-term data collected during this quarter. In addition, a comparison of all the long-term emissions data that have been collected to date is included.

  16. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, first quarter 1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-20T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company`s Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NO{sub x} emissions and boiler performance. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO{sub x} control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO{sub x} concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO{sub x} emissions for each day of long-term testing are presented. The average NO{sub x} emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO{sub x} combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

  17. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-05-20T23:59:59.000Z

    This quarterly report discusses the technical progress of a US Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) Project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from a coal-fired boiler. The project is being conducted at Gulf Power Company's Plant Lansing Smith Unit 2 located near Panama City, Florida. The primary objective of this demonstration is to determine the long-term effects of commercially available tangentially-fired low NO[sub x] combustion technologies on NO[sub x] emissions and boiler performance. A target of achieving fifty percent NO[sub x] reduction using combustion modifications has been established for the project. The stepwise approach that is being used to evaluate the NO[sub x] control technologies requires three plant outages to successively install the test instrumentation and the different levels of the low NO[sub x] concentric firing system (LNCFS). Following each outage, a series of four groups of tests are performed. These are (1) diagnostic, (2) performance, (3) long-term, and (4) verification. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulate characteristics and boiler efficiency. This technical progess report presents the LNCFS Level III long-term data collected during this quarter. NO[sub x] emissions for each day of long-term testing are presented. The average NO[sub x] emission during long-term testing was 0.39 lb/MBtu at an average load of 155 MW. The effect of the low NO[sub x] combustion system on other combustion parameters such as carbon monoxide, excess oxygen level, and carbon carryover are also included.

  18. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  19. 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    ABB CE's Low NOx Bulk Furnace Staging (LNBFS) System and Low NOx Concentric Firing System (LNCFS) are demonstrated in stepwise fashion. These systems incorporate the concept of advanced overfire air (AOFA), clustered coal nozzles, and offset air. A complete description of the installed technologies is provided in the following section. The primary objective of the Plant Lansing Smith demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology are also being performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project.

  20. Experimental studies on group ignition of coal particles

    E-Print Network [OSTI]

    Ruiz, Miguel

    1989-01-01T23:59:59.000Z

    Page 20 Temperature Distribution without Radiation Losses 56 Temperature Distribution with Improved Insulation 57 22 Comparison Between Corrected (for rs, diation) and Uncorrected Thermocouple Readings, . 59 23 Photograph of the Pulverized Fuel Jet... - 2% nitrogen. Inorganic mineral matter (ash) as high as 50% has been observed, but 5 - 15% is more typical. Moisture levels commonly va. ry from 2 to 20%, but values as high as 70% have been observed. When a coal particle is placed in an infinite...

  1. Engineering development of advanced coal-fired low emission boil systems. Quarterly technical progress report, October 1993--December 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    The first test run of the Toroidal Vortex Combustor (TVC) was completed on December 6. Riley was unable to witness or set up independent sampling equipment for NO{sub x} and precursor measurement for this run. A second run which we witnessed, but did not sample, was completed December 17. This was conducted almost entirely near SR = 1.0 while Textron investigated temperature-load relationships to address concerns from Run 1. A third run was completed over the December holiday break on Dorchester coal to address concerns Textron had about the Illinois test coal. All subsequent tests will use the Illinois coal. Boiler, firing system design. Elevation drawings were developed for dry wall-fired, conventional U-fired slagging, and TVC fired slagging units. We are investigating the feasibility of modifying a conventional U-fired design for low-NOx operation as an alternative to the TVC. The approach taken to I date for NOx reduction in existing U-fired units is to retrofit with delayed-mixing burners with staging air at various places, similar to the approach with dry fired units. The concept of staged fuel addition or reburning for the U-fired system is being examined as a potential combustion NOx control approach. This concept has high potential due to the high temperature and long residence time available in the stagger. Some field trials with coke oven gas reburn produced very low NOx results. Modeling of this concept was identified as a priority task. The model development will include matching field data for air staging on slagging units to the predictions. Emissions control. Selection of an SO2 control process continues to be a high priority task. Sargent & Lundy completed a cost comparison of several regenerable processes, most of which have NOx control potential as well: Active coke, NOXSO, copper oxide, SNOX, ammonia (for SO only, ammonium sulfate byproduct), and a limestone scrubber for comparison.

  2. Clean coal today

    SciTech Connect (OSTI)

    none,

    1990-01-01T23:59:59.000Z

    This is the first issue of the Clean Coal Today publication. Each issue will provide project status reports, feature articles about certain projects and highlight key events concerning the US Clean Coal Technology Demonstration Program. Projects described in this publication include: Colorado-Ute Electric Association Circulating Fluidized Bed Combustor Project at Nucla, Colorado; Babcock and Wilcox coolside and limestone injection multistage burner process (dry sorbent injection); Coal Tech's Advanced Cyclone Combustor Project; and the TIDD pressurized fluidized bed combustor combined cycle facility in Brilliant, Ohio. The status of other projects is included.

  3. Performance and economics of co-firing a coal/waste slurry in advanced fluidized-bed combustion

    SciTech Connect (OSTI)

    DeLallo, M.R.; Zaharchuk, R. [Parsons Power Group, Inc., Reading, PA (United States); Reuther, R.B.; Bonk, D.L. [USDOE Morgantown Energy Technology Center, WV (United States)

    1996-09-01T23:59:59.000Z

    This study`s objective was to investigate co-firing a pressurized fluidized-bed combustor with coal and refuse-derived fuel for the production of electricity and the efficient disposal of waste. Performance evaluation of the pressurized fluidized-bed combustor (PFBC) power plant co-fired with refuse-derived fuel showed only slightly lower overall thermal efficiency than similar sized plants without waste co-firing. Capital costs and costs of electricity are within 4.2 percent and 3.2 percent, respectively, of waste-free operation. The results also indicate that there are no technology barriers to the co-firing of waste materials with coal in a PFBC power plant. The potential to produce cost-competitive electrical power and support environmentally acceptable waste disposal exists with this approach. However, as part of technology development, there remain several design and operational areas requiring data and verification before this concept can realize commercial acceptance. 3 refs., 3 figs., 4 tabs.

  4. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Public design report (preliminary and final)

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This Public Design Report presents the design criteria of a DOE Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of NO{sub x} emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 (500 MW) near Rome, Georgia. The technologies being demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NO{sub x} burner. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NO{sub x} burners, advanced overfire systems, and digital control system.

  5. Detailed investigation of a pulverized fuel swirl flame in CO{sub 2}/O{sub 2} atmosphere

    SciTech Connect (OSTI)

    Toporov, D.; Bocian, P.; Heil, P.; Kellermann, A.; Stadler, H.; Tschunko, S.; Foerster, M.; Kneer, R. [Institute of Heat and Mass Transfer, RWTH Aachen University, Eilfschornsteinstrasse 18, D-52056 Aachen (Germany)

    2008-12-15T23:59:59.000Z

    A novel approach to oxycoal flame stabilization has been developed at the Institute of Heat and Mass Transfer at RWTH Aachen University [D. Toporov, M. Foerster, R. Kneer, in: Third Int. Conf. on Clean Coal Technologies for Our Future, Cagliari, Sardinia, Italy, 15-17 May 2007]. The swirl burner design and its operating conditions have been adjusted in order to enforce CO formation thus stabilizing the flame and obtaining a full burnout at levels of O{sub 2} content in the O{sub 2}/CO{sub 2} mixture similar to those in air. The paper presents results of detailed numerical and experimental investigations of a stable oxy-fired pulverized coal swirl flame (type-2) obtained with a 21 vol% O{sub 2} concentration. The combustion tests were performed in a vertical pilot-scale furnace (100 kW{sub th}) in the framework of the OXYCOAL-AC research project aiming to develop a membrane-based oxyfuel process. The experimental results concerning gas velocities, gas and particle temperatures, and gas compositions are presented and discussed, focusing on the underlying mechanisms as well as on the aerodynamics of the oxycoal flame. A comparison between measurements and simulations has shown the validity of the numerical method used. The reported data set can be used for validation of numerical models developed for prediction of oxyfuel combustion. (author)

  6. ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH-PERFORMANCE POWER SYSTEMS

    SciTech Connect (OSTI)

    Unknown

    1999-02-01T23:59:59.000Z

    A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, AL. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. This report addresses the areas of technical progress for this quarter. A general arrangement drawing of the char transfer system was forwarded to SCS for their review. Structural steel drawings were used to generate a three-dimensional model of the char transfer system including all pressure vessels and major piping components. Experimental testing at the Combustion and Environmental Test Facility continued during this quarter. Performance of the char burner, as benchmarked by flame stability and low NOx, has been exceptional. The burner was operated successfully both without natural gas and supplemental pulverized coal.

  7. Zero Emissions Coal Syngas Oxygen Turbo Machinery

    SciTech Connect (OSTI)

    Dennis Horazak

    2010-12-31T23:59:59.000Z

    Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack growth rates in oxy-fuel environments have been proposed to build on these results and provide quantifiable assessments of the effects of oxy-fuel environments on the service lives of turbine components.

  8. Combined homo- and heterogeneous model for mercury speciation in pulverized fuel combustion flue gases

    SciTech Connect (OSTI)

    Shishir P. Sable; Wiebren de Jong; Hartmut Spliethoff [Delft University Technology, Delft (Netherlands). Section Energy Technology, Department of Process and Energy

    2008-01-15T23:59:59.000Z

    A new model is developed to predict Hg{sup 0}, Hg{sup +}, Hg{sup 2+}, and Hg{sub p} in the post-combustion zone upstream of a particulate control device (PCD) in pulverized coal-fired power plants. The model incorporates reactions of mercury with chlorinating agents (HCl) and other gaseous species and simultaneous adsorption of oxidized mercury (HgCl{sub 2}) on fly ash particles in the cooling of flue gases. The homogeneous kinetic model from the literature has been revised to understand the effect of the NO + OH + M {longleftrightarrow} HONO + M reaction on mercury oxidation. Because it is a pressure-dependent reaction, the choice of proper reaction rates was very critical. It was found that mercury oxidation reduces from 100 to 0% while going from high- to low-pressure limit rates with 100 ppmv NO. The heterogeneous model describes selective in-duct Langmuir-Hinshelwood adsorption of mercury chloride on ash particles. The heterogeneous model has been built using Fortran and linked to Chemkin 4.0. The final predictions of elemental, oxidized, and particulate mercury were compared to mercury speciation from power plant data. Information collection request (ICR) data were used for this comparison. The model results follow very similar trends compared to those of the plant data; however, quantitative deviation was considerable. These deviations are due to the errors in the measurement of mercury upstream of PCD, lack of adsorption kinetic data, accurate homogeneous reaction mechanisms, and certain modeling assumptions. The model definitely follows a new approach for the prediction of mercury speciation, and further refinement will improve the model significantly. 43 refs., 1 figs., 6 tabs.

  9. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2001-09-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  10. Advanced intelligent coordinated control of coal fired power plant based on fuzzy reasoning and auto-tuning

    SciTech Connect (OSTI)

    Li, S.Y.; Liu, H.B.; Cai, W.J.; Soh, Y.C.; Xie, L.H. [Shanghai Jiao Tong University, Shanghai (China)

    2004-07-01T23:59:59.000Z

    The load following operation of coal-fired boiler-turbine unit in power plants can lead to changes in operating points, and it results in nonlinear variations of the plant variables and parameters. As there exist strong couplings between the main steam pressure control loop and the power output control loop in the boiler-turbine unit with large time-delay and uncertainties, automatic coordinated control of the two loops is a very challenging problem. This paper presents a new coordinated control strategy (CCS) which is organized into two levels: a basic control level and a high supervision level. PID-type controllers are used in the basic level to perform basic control functions while the decoupling between two control loops can be realized in the high level. Moreover, PID-type controllers can be auto-tuned to achieve a better control performance in the whole operating range and to reject the unmeasurable disturbances. A special subclass of fuzzy inference systems, namely the Gaussian partition system with evenly spaced midpoints, is also proposed to auto-tune the PID controller in the main steam pressure loop based on the error signal and its first difference to overcome uncertainties caused by changing fuel calorific value, machine wear, contamination of the boiler heating surfaces and plant modeling errors, etc. The developed CCS has been implemented in a power plant in China, and satisfactory industrial operation results demonstrate that the proposed control strategy has enhanced the adaptability and robustness of the process.

  11. An advanced control system for fine coal flotation. Fourth quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect (OSTI)

    Adel, G.T.; Luttrell, G.H.

    1997-03-04T23:59:59.000Z

    A model-based flotation control scheme is being implemented to achieve optimal performance in the handling and treatment of fine coal. The control scheme monitors flotation performance through on-line analysis of ash content. Then, based on the economic and metallurgical performance of the circuit, variables such as reagent dosage, pulp density and pulp level are adjusted using model-based control algorithms to compensate for feed variations and other process disturbances. Recent developments in sensor technology are being applied for on-line determination of slurry ash content. During the fourth quarter of this project, a final attempt was made to calibrate a video-based ash analyzer for use in this application. It was concluded that the low ash content and the coarse particle size of the flotation tailings slurry at the Maple Meadow plant site made the video-based system unsuitable for this application. Plans are now underway to lease a nuclear-based analyzer as the primary sensor for this project.

  12. NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC.

    E-Print Network [OSTI]

    Coal-CCS integrated gasification combined cycle coal with carbon capture and sequestration Coal-IGCC integrated gasification combined cycle coal CoalNew advanced super critical coal steam plant (with SO2 and NOx controls) CoalOldScr conventional pulverized coal steam plant (with SO2 scrubber) Coal

  13. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S

    2007-01-01T23:59:59.000Z

    from the U.S. Energy Information Administration (EIA) [26] (Washington, DC: Energy Information Administration, U.S.of Energy, Energy Information Administration; 2004. See

  14. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward

    2007-01-01T23:59:59.000Z

    Whitman index for steam- generating construction costs [59]Whitman index of public utility construction costs. Whitman,

  15. Three dimension temperature field reconstruction with image processing technique on pulverized coal boiler furnace

    SciTech Connect (OSTI)

    Shen Peihua; Qi Guoshui; Ma Zengyi [and others

    1999-07-01T23:59:59.000Z

    Temperature field distribution measurement is important for combustion diagnostics. With CCD camera, the authors can obtain abundance digital data of flame image instantaneous. Every data represent radiation heat transfer along projection beam. Based on Optic geometric and heat transfer theory, they develop a 3-d flame temperature field reconstruction technique, which can calculate a 3-d zone temperature using two perspectives CCD camera. The optical geometric relation of CCD's image formation and flame radiation heat transfer model is deduced, they establish the reconstruction equation group from radiation heat transfer, and optimization is introduced to solve these equation. The result of a PC boiler is presented.

  16. A centurial history of technological change and learning curves or pulverized coal-fired utility boilers

    E-Print Network [OSTI]

    Yeh, Sonia; Rubin, Edward S

    2007-01-01T23:59:59.000Z

    cost of U.S. fossil–steam power plants from 1981 to 1997curve: the case of steam-electric power plant design andpower plant; Learning-by-doing; Technological change; Steam

  17. Enhancement of surface properties for coal beneficiation

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30T23:59:59.000Z

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  18. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

    1996-12-31T23:59:59.000Z

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  19. High performance materials in coal conversion utilization. Technical progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    NONE

    1995-01-01T23:59:59.000Z

    This is the fifth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete.

  20. Coal-fired furnace for testing of thermionic converters. Topical report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The development of thermionic converter technology has progressed to make near-term applications interesting. One of these applications is the thermionic topping of a pulverized coal-fired central station powerplant. Up to now, thermionic converters have been flame tested using natural gas as fuel. A new test furnace is required for evaluation of thermionic converters in a coal-fired environment. The design and costs of a facility which adapts a coal-fired furnace built by Foster Wheeler Development Corporation (FWDC) for thermionic converter testing are discussed. Such a facility would be exempt from air pollution regulations because of its low firing rate.

  1. Cooperative research on the combustion characteristics of cofired desulfurized Illinois coal and char with natural gas. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Buckius, R.O.; Wu, Cheng-Kang; Krier, H.; Peters, J.E. [Illinois Univ., Urbana-Champaign, IL (United States)

    1992-12-31T23:59:59.000Z

    The DTFF is extended to larger sample collecting capability and higher temperatures, resulting in the establishment of the Ash Characterization Facility and the High Temperature Drop Tube Furnace. The Ash Characterization Facility enables continuous coal injection and sampling under controlled conditions. Several hundred milligrams of char or ash can be collected in one-half hour. The High Temperature Drop Tube Furnace uses a plasma torch to preheat the gas to over 2000 K and inject it into a ceramic tube which enters a furnace designed for 1700{degrees}C (1973 K) operation, so that temperatures and heating rates encountered by pulverized coal particles in the flames of large boilers or in the advanced slagging cyclone combustors can be simulated. An aerodynamic coal feeder works well in supplying coal continuously to the drop tube. A watercooled, Helium-quench sampling probe collects the solid samples. A scanning electron microscope is used to study the morphology of ash and char particles. A sulfur determinator, a gas chromatograph provide analytical means in the laboratory, and the Illinois State Geological Survey performs other necessary analyses of the samples. Tests on cofiring coal with I to 4% methane show that sulfur retention in ash was related to temperature and residence time. The addition of methane caused changes in gas temperature profile in the tube and also changes in chemical composition of the gases. The overall effect on sulfur retention is seen to be a result of several complex interacting factors. Further detailed studies are necessary to clarify the contribution of each factor and to provide clues to the mechanism of the process.

  2. Application of Pulsed Electrical Fields for Advanced Cooling and Water Recovery in Coal-Fired Power Plant

    SciTech Connect (OSTI)

    Young Cho; Alexander Fridman

    2009-04-02T23:59:59.000Z

    The overall objective of the present work was to develop technologies to reduce freshwater consumption in a cooling tower of coal-based power plant so that one could significantly reduce the need of make-up water. The specific goal was to develop a scale prevention technology based an integrated system of physical water treatment (PWT) and a novel filtration method so that one could reduce the need for the water blowdown, which accounts approximately 30% of water loss in a cooling tower. The present study investigated if a pulsed spark discharge in water could be used to remove deposits from the filter membrane. The test setup included a circulating water loop and a pulsed power system. The present experiments used artificially hardened water with hardness of 1,000 mg/L of CaCO{sub 3} made from a mixture of calcium chloride (CaCl{sub 2}) and sodium carbonate (Na{sub 2}CO{sub 3}) in order to produce calcium carbonate deposits on the filter membrane. Spark discharge in water was found to produce strong shockwaves in water, and the efficiency of the spark discharge in cleaning filter surface was evaluated by measuring the pressure drop across the filter over time. Results showed that the pressure drop could be reduced to the value corresponding to the initial clean state and after that the filter could be maintained at the initial state almost indefinitely, confirming the validity of the present concept of pulsed spark discharge in water to clean dirty filter. The present study also investigated the effect of a plasma-assisted self-cleaning filter on the performance of physical water treatment (PWT) solenoid coil for the mitigation of mineral fouling in a concentric counterflow heat exchanger. The self-cleaning filter utilized shockwaves produced by pulse-spark discharges in water to continuously remove scale deposits from the surface of the filter, thus keeping the pressure drop across the filter at a relatively low value. Artificial hard water was used in the present fouling experiments for three different cases: no treatment, PWT coil only, and PWT coil plus self-cleaning filter. Fouling resistances decreased by 59-72% for the combined case of PWT coil plus filter compared with the values for no-treatment cases. SEM photographs showed much smaller particle sizes for the combined case of PWT coil plus filter as larger particles were continuously removed from circulating water by the filter. The x-ray diffraction data showed calcite crystal structures for all three cases.

  3. The push for increased coal injection rates -- Blast furnace experience at AK Steel Corporation

    SciTech Connect (OSTI)

    Dibert, W.A.; Duncan, J.H.; Keaton, D.E.; Smith, M.D. [AK Steel Corp., Middletown, OH (United States)

    1994-12-31T23:59:59.000Z

    An effort has been undertaken to increase the coal injection rate on Amanda blast furnace at AK Steel Corporation`s Ashland Works in Ashland, Kentucky to decrease fuel costs and reduce coke demand. Operating practices have been implemented to achieve a sustained coal injection rate of 140 kg/MT, increased from 100--110 kg/MT. In order to operate successfully at the 140 kg/MT injection rate; changes were implemented to the furnace charging practice, coal rate control methodology, orientation of the injection point, and the manner of distribution of coal to the multiple injection points. Additionally, changes were implemented in the coal processing facility to accommodate the higher demand of pulverized coal; grinding 29 tonnes per hour, increased from 25 tonnes per hour. Further increases in injection rate will require a supplemental supply of fuel.

  4. Coal as a fuel: a user's viewpoint. [Bowling Green State University, Ohio

    SciTech Connect (OSTI)

    Clodding, C.L.

    1980-01-01T23:59:59.000Z

    The problems of a university heating plant burning 25,000 tons of coal per year are described. You cannot burn pulverized coal like the large electric utilities do, but have to use stoker-fed boilers. These have very specific requirements on the coal, so detailed specifications on the coal size, sulfur, volatile matter, ashes, moisture, etc. are required. There are several materials handling problems related to delivery of the coal, stockpiling, reclaiming, feeding, ash handling, etc. Truck delivery is relatively straightforward but expensive; rail delivery of one, or a few cars of coal, which is often frozen and hard to get out of the cars, presents several problems and is also somewhat expensive. (LTN)

  5. Milliken Clean Coal Demonstration Project: A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-08-15T23:59:59.000Z

    The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal-utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage.

  6. Residues from coal conversion and utilization: Advanced mineralogical characterization and disposed byproduct diagenesis. [Semiannual report, 1 Mar 1999--31 Aug 1999

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    2000-01-01T23:59:59.000Z

    The goal of the project is to learn more about the phenomenon of coal conversion byproduct (CCB) diagenesis, first described by this group and co-workers at UND EERC seven years ago. CCB diagenesis is a change in the mineralogy that occurs after some CCBs are disposed in a landfill or utilized for a civil engineering application. Regulatory environmental tests and civil engineering tests are typically performed on as-generated CCBs, or on CCBs hydrated and cured for relatively short periods such as 7 or 28 days. One would like to know whether the results of these short-term tests will be valid years later. A change in mineralogy means a gain, loss or chemical redistribution of major, minor and trace elements, and alteration of physical properties. To attain this goal, two objectives were defined: (1) to develop improved methodology for quantitating mineralogy of these complex crystalline phase assemblages, and (2) to investigate the phenomenon of CCB diagenesis further by studying materials recovered from disposal landfills or civil engineering works. Objective 1--Hydrated CCBs are chemically and mineralogically complex, which makes quantitative mineralogy determination by conventional X-ray diffraction unusable or unreliable. The whole-pattern Rietveld quantitative X-ray diffraction (RQXRD) method, however, can overcome many of the problems and seems well suited to improve reliability. Two tasks were defined in the proposal: Task 1--Completion by October 1997. Prepare a reference set of CCBs for use in developing Rietveld QXRD. The reference materials will come primarily from in-house samples of advanced coal technology byproducts. The work will include SEM/EMPA characterization at UND EERC. Task 2--Completion by October 1997. Develop protocols for Rietveld QXRD analysis of CCBs. Make CCB structure data and protocols available on a Website. Determine levels of sensitivity, precision, and accuracy. Objective 2--Five types of CCBs disposed in landfills were studied between 1989 and 1994. Diagenesis was observed in three of the five materials. To obtain a more generic understanding of CCB diagenesis, additional materials and different environmental settings need to be studied. Task 3--Completion by end of project. Apply RQXRD protocols developed in Task 2 to core samples of utilized or disposed CCBs from at least five additional sites. Use results to gain a better understanding of CCB diagenesis.

  7. Residues from coal conversion and utilization: Advanced mineralogical characterization and disposed byproduct diagenesis. [Semiannual report, 1 Sep 1998--28 Feb 1999

    SciTech Connect (OSTI)

    Gregory J. McCarthy; Dean G. Grier

    1999-03-01T23:59:59.000Z

    The goal of the project is to learn more about the phenomenon of coal conversion byproduct (CCB) diagenesis, first described by the group and co-workers at UND EERC seven years ago. CCB diagenesis is a change in the mineralogy that occurs after some CCBs are disposed in a landfill or utilized for a civil engineering application. Regulatory environmental tests and civil engineering tests are typically performed on as-generated CCBs, or on CCBs hydrated and cured for relatively short periods such as 7 or 28 days. One would like to know whether the results of these short-term tests will be valid years later. A change in mineralogy means a gain, loss or chemical redistribution of major, minor and trace elements, and alteration of physical properties. To attain this goal, two objectives were defined: (1) to develop improved methodology for quantitating mineralogy of these complex crystalline phase assemblages, and (2) to investigate the phenomenon of CCB diagenesis further by studying materials recovered from disposal landfills or civil engineering works. Objective 1--Hydrated CCBs are chemically and mineralogically complex, which makes quantitative mineralogy determination by conventional X-ray diffraction unusable or unreliable. The whole-pattern Rietveld quantitative X-ray diffraction (RQXRD) method, however, can overcome many of the problems and seems well suited to improve reliability. Two tasks were defined in the proposal: Task 1--Completion by October 1997. Prepare a reference set of CCBs for use in developing Rietveld QXRD. The reference materials will come primarily from in-house samples of advanced coal technology byproducts. The work will include SEM/EMPA characterization at UND EERC. Task 2--Completion by October 1997. Develop protocols for Rietveld QXRD analysis of CCBs. Make CCB structure data and protocols available on a Website. Determine levels of sensitivity, precision, and accuracy. Objective 2--Five types of CCBs disposed in landfills were studied between 1989 and 1994. Diagenesis was observed in three of the five materials. To obtain a more generic understanding of CCB diagenesis, additional materials and different environmental settings need to be studied. Task 3--Completion by end of project. Apply RQXRD protocols developed in Task 2 to core samples of utilized or disposed CCBs from at least five additional sites. Use results to gain a better understanding of CCB diagenesis.

  8. MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; K.A. Davis; M.P. Heap; T.H. Fletcher; H. Zhang

    2000-04-01T23:59:59.000Z

    Coal continues to be one of the principal energy sources for electric power generation in the United States. One of the biggest environmental challenges involved with coal utilization is the reduction of nitrogen oxides (NO{sub x}) formed during coal combustion. The most economical method of NO{sub x} abatement in coal combustion is through burner modification. Air-staging techniques have been widely used in the development of low-NO{sub x} pulverized coal burners, promoting the conversion of NO{sub x} to N{sub 2} by delaying the mixing in the fuel-rich zone near the burner inlet. Previous studies have looked at the mechanisms of NO{sub x} evolution at relatively low temperatures where primary pyrolysis is dominant, but data published for secondary pyrolysis in the pulverized coal furnace are scarce. In this project, the nitrogen evolution behavior during secondary coal pyrolysis will be explored. The end result will be a complete model of nitrogen evolution and NO{sub x} precursor formation due to primary and secondary pyrolysis.

  9. advanced energy utilization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  10. arc coal process: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the system in figure 1 as an M equidistant receiver Paris-Sud XI, Universit de 8 Clean Coal Technology Program Advanced Coal Conversion Process Demonstration CiteSeer Summary:...

  11. ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

    SciTech Connect (OSTI)

    Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

    2002-12-30T23:59:59.000Z

    ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further improve NOx emissions and related combustion performance. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive Powder River Basin coal (PRB) to a moderately reactive Midwestern bituminous coal (HVB) to a less reactive medium volatile Eastern bituminous coal (MVB). Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis.

  12. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  13. Transformations of inorganic coal constituents in combustion systems

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. (PSI Technology Co., Andover, MA (United States)); Kang, Shin-Gyoo; Sarofim, A.F.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States)); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. (Arizona Univ., Tucson, AZ (United States)); Shah, N.; Huggins, F.E.; Huffman, G.P. (Kentucky Univ., Lexington, KY (United States))

    1991-09-01T23:59:59.000Z

    The technical objectives of this project are: (1) To define the partitioning of inorganic constituents associated with raw coal particles among products (including vapors, aerosols, and residual char/ash particles) formed under conditions representative of pulverized coal flames as a function of the specific (intrinsic and extrinsic) characteristics of the raw coal and the environment in which the transformations occur; and to characterize the resultant spectrum of products in detail. (2) To elucidate and quantify the fundamental processes (involving basic principles of physics, chemistry, thermodynamics) by which transformations of the inorganic constituents occur; and (3) to develop, based on the information required in (1) and (2), a tractable process'' model capable of predicting the significant features of the transformation process, most importantly, the nature and distribution of products. 26 refs., 151 figs., 51 tabs.

  14. Summary report: Trace substance emissions from a coal-fired gasification plant

    SciTech Connect (OSTI)

    Williams, A.; Wetherold, B.; Maxwell, D.

    1996-10-16T23:59:59.000Z

    The U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Louisiana Gasification Technology Inc. (LGTI) sponsored field sampling and analyses to characterize emissions of trace substances from LGTI`s integrated gasification combined cycle (IGCC) power plant at Plaquemine, Louisiana. The results indicate that emissions from the LGTI facility were quite low, often in the ppb levels, and comparable to a well-controlled pulverized coal-fired power plant.

  15. Coal based electric generation comparative technologies report

    SciTech Connect (OSTI)

    Not Available

    1989-10-26T23:59:59.000Z

    Ohio Clean Fuels, Inc., (OCF) has licensed technology that involves Co-Processing (Co-Pro) poor grade (high sulfur) coal and residual oil feedstocks to produce clean liquid fuels on a commercial scale. Stone Webster is requested to perform a comparative technologies report for grassroot plants utilizing coal as a base fuel. In the case of Co-Processing technology the plant considered is the nth plant in a series of applications. This report presents the results of an economic comparison of this technology with other power generation technologies that use coal. Technologies evaluated were:Co-Processing integrated with simple cycle combustion turbine generators, (CSC); Co-Processing integrated with combined cycle combustion turbine generators, (CCC); pulverized coal-fired boiler with flue gas desulfurization and steam turbine generator, (PC) and Circulating fluidized bed boiler and steam turbine generator, (CFB). Conceptual designs were developed. Designs were based on approximately equivalent net electrical output for each technology. A base case of 310 MWe net for each technology was established. Sensitivity analyses at other net electrical output sizes varying from 220 MWe's to 1770 MWe's were also performed. 4 figs., 9 tabs.

  16. Express quality analysis of coal concentrates by diffuse reflection IR spectroscopy

    SciTech Connect (OSTI)

    V.N. Egorov; I.I. Mel'nikov; N.A. Tarasov; V.I. Butakova; Y.M. Posokhov [ZAO RMK (Russian Federation)

    2007-07-01T23:59:59.000Z

    Ongoing quality monitoring of coal concentrates is important today on account of instability in the raw materials for coking at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK) and the variable composition of the coal batch for enrichment plants. Currently, numerous standardized methods permit the determination of the classificational and quality characteristics of coal and batch. These methods are slow, laborious, and relatively ineffective in industrial conditions. In May 2005, an automated Spektrotest express-analysis system developed by ECCI was installed in the coke laboratory at ZAO RMK in order to determine the quality of the coal concentrate and batch. The basic equipment is an IR spectrometer with a unit for Fourier transformation and a special optical module yielding the reflect on spectra of the pulverized coal. A control station based on a high-speed computer runs an algorithm for information analysis and storage and for printing out the test protocol. The Spektrotest system includes complex algorithms and software specially developed at ECCI.

  17. Advanced characterization of forms of chlorine, organic sulfur, and trace elements in available coals from operating Illinois mines. [Quarterly] technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Demir, I.; Ruch, J.M. [Illinois State Geological Survey (United States)] [and others

    1994-12-31T23:59:59.000Z

    A set of 34 as-shipped coal samples from operating Illinois mines is available for this study to determine the forms of chlorine and sulfur and leachability of chlorine during wet grinding and froth flotation. The forms of chlorine may be inorganic, ionic, and organic. The forms of organic sulfur will include organic sulfide and thiophenic sulfur. Chlorine can be leached from coal during wet grinding. The potential for removal of chlorine from the samples during fine ({minus}200 mesh) and ultrafine ({minus}400 mesh) wet-grinding and during froth flotation designed primarily for removal of pyrite and ash will be determined. In addition, the organic/inorganic affinities of trace elements in as-shipped Illinois coals will be assessed so that the current physical coal cleaning results may be better interpreted.

  18. A Synergistic Combination of Advanced Separation and Chemical Scale Inhibitor Technologies for Efficient Use of Imparied Water As Cooling Water in Coal-based Power Plants

    SciTech Connect (OSTI)

    Jasbir Gill

    2010-08-30T23:59:59.000Z

    Nalco Company is partnering with Argonne National Laboratory (ANL) in this project to jointly develop advanced scale control technologies that will provide cost-effective solutions for coal-based power plants to operate recirculating cooling water systems at high cycles using impaired waters. The overall approach is to use combinations of novel membrane separations and scale inhibitor technologies that will work synergistically, with membrane separations reducing the scaling potential of the cooling water and scale inhibitors extending the safe operating range of the cooling water system. The project started on March 31, 2006 and ended in August 30, 2010. The project was a multiyear, multi-phase project with laboratory research and development as well as a small pilot-scale field demonstration. In Phase 1 (Technical Targets and Proof of Concept), the objectives were to establish quantitative technical targets and develop calcite and silica scale inhibitor chemistries for high stress conditions. Additional Phase I work included bench-scale testing to determine the feasibility of two membrane separation technologies (electrodialysis ED and electrode-ionization EDI) for scale minimization. In Phase 2 (Technology Development and Integration), the objectives were to develop additional novel scale inhibitor chemistries, develop selected separation processes, and optimize the integration of the technology components at the laboratory scale. Phase 3 (Technology Validation) validated the integrated system's performance with a pilot-scale demonstration. During Phase 1, Initial evaluations of impaired water characteristics focused on produced waters and reclaimed municipal wastewater effluents. Literature and new data were collected and evaluated. Characteristics of produced waters vary significantly from one site to another, whereas reclaimed municipal wastewater effluents have relatively more uniform characteristics. Assessment to date confirmed that calcite and silica/silicate are two common potential cycle-limiting minerals for using impaired waters. For produced waters, barium sulfate and calcium sulfate are two additional potential cycle-limiting minerals. For reclaimed municipal wastewater effluents, calcium phosphate scaling can be an issue, especially in the co-presence of high silica. Computational assessment, using a vast amount of Nalco's field data from coal fired power plants, showed that the limited use and reuse of impaired waters is due to the formation of deposit caused by the presence of iron, high hardness, high silica and high alkalinity in the water. Appropriate and cost-effective inhibitors were identified and developed - LL99B0 for calcite and gypsum inhibition and TX-15060 for silica inhibition. Nalco's existing dispersants HSP-1 and HSP-2 has excellent efficacy for dispersing Fe and Mn. ED and EDI were bench-scale tested by the CRADA partner Argonne National Laboratory for hardness, alkalinity and silica removal from synthetic make-up water and then cycled cooling water. Both systems showed low power consumption and 98-99% salt removal, however, the EDI system required 25-30% less power for silica removal. For Phase 2, the EDI system's performance was optimized and the length of time between clean-in-place (CIP) increased by varying the wafer composition and membrane configuration. The enhanced EDI system could remove 88% of the hardness and 99% of the alkalinity with a processing flux of 19.2 gal/hr/m{sup 2} and a power consumption of 0.54 kWh/100 gal water. Bench tests to screen alternative silica/silicate scale inhibitor chemistries have begun. The silica/silicate control approaches using chemical inhibitors include inhibition of silicic acid polymerization and dispersion of silica/silicate crystals. Tests were conducted with an initial silica concentration of 290-300 mg/L as SiO{sub 2} at pH 7 and room temperature. A proprietary new chemistry was found to be promising, compared with a current commercial product commonly used for silica/silicate control. Additional pilot cooling tower testing confirmed

  19. Advances

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1BP-14Scripting for Advanced Workflows Jack

  20. Engineering Development of Coal-Fired High-Performance Power Systems

    SciTech Connect (OSTI)

    York Tsuo

    2000-12-31T23:59:59.000Z

    A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately. This report addresses the areas of technical progress for this quarter. The detail of syngas cooler design is given in this report. The final construction work of the CFB pyrolyzer pilot plant has started during this quarter. No experimental testing was performed during this quarter. The proposed test matrix for the future CFB pyrolyzer tests is given in this report. Besides testing various fuels, bed temperature will be the primary test parameter.

  1. Coal: Energy for the future

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  2. Modeling the resolution of inexpensive, novel non-seismic geophysical monitoring tools to monitor CO2 injection into coal beds

    E-Print Network [OSTI]

    Gasperikova, E.

    2010-01-01T23:59:59.000Z

    Plasynski, S. , 2008, Advancing Coal-Based Power Generationto monitor CO 2 injection into Coal Beds as a part of theanalysis for CO 2 movement in coal beds was based on the

  3. Recovery of iron oxide from coal fly ash

    DOE Patents [OSTI]

    Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

    1983-05-31T23:59:59.000Z

    A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

  4. COAL & POWER SYSTEMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r k CCLEAN9AugustCNSS PapersCOAL &

  5. Impacts of new coal-using technologies on coal markets and electric utilities

    SciTech Connect (OSTI)

    Stauffer, C.H.

    1982-06-01T23:59:59.000Z

    ICF's Coal and Electric Utilities Model (CEUM) was used to make forecasts on the impact of new coal technologies and markets and utilities. The new technologies include the gasifier/ combined cycle (GCC), the atmospheric fluidized bed combustor (AFBC), and the retrofit of synthetic coal-fluids on advanced combined cycle capacity. National production by the year 2000 will increase slightly. Impact of technology will be negligible due to the offsetting effects of GCC (it uses less coal) and synthetic coal fluids. Regional production will increase in synthetic coal fluid regions, decrease in sulphur coal regions. In utilities, coal additions by GCC are favored in the east, by AFBC in the west. SO/sub 2/ emissions will start to decline in 1995, NOx emissions will continue to rise, but not as sharply. Overall costs of utilities are expected to fall slightly by the year 2010.

  6. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    after combustion of coal in conventional and advanced clean-coal technology combustors. These include and advanced clean-coal technology combustors. Although 560 million tonnes (Mt) of fly ash, bottom ash use either pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology

  7. Maintaining Low Oxygen (O2) in Coal Fueled Utility Boilers Using CO Instrumentation

    E-Print Network [OSTI]

    Hopkins, D.; Downing, T.

    and the annual fuel savings possible from this 02 reduction. Unit til 1.8 a pulverized coal fired, 565 MW, CE boiler system placed in service July 27, 1982. Complete and safe combustion in this boiler is maintained by continuously monitoring 02 and CO...Il at Muleshoe, Texas. This is a 565 :Megawatt unit utilizing a Combustion Engineering boiler firing sub-bituminous Wyoming coal thrQugh six elevations of tilting tangential nozzles. The boiler is balanced draft with two air preheaters. Environmental...

  8. SSAB/MEFOS oxy-coal system -- 3 years of industrial experience

    SciTech Connect (OSTI)

    Wikstroem, J.O.; Skoeld, B.E. [MEFOS, Luleaa (Sweden); Kaersrud, K.

    1996-12-31T23:59:59.000Z

    SSAB, Swedish Steel AB, is the main steel producer in Sweden. MEFOS is a foundation for metallurgical research. The principals include 35 Nordic companies. SSAB and MEFOS have, in cooperation, developed a swirl type, coaxial, oxy-coal lance, that drastically improves the combustion of pulverized coal in the Blast Furnace tuyere and race way. The development was made through an extensive test work in a highly instrumented single tuyere on an industrial Blast Furnace. The technology has been in commercial use since early 1993, with excellent result.

  9. Damage and seismic velocity structure of pulverized rocks near the San Andreas Fault

    E-Print Network [OSTI]

    Ben-Zion, Yehuda

    Damage and seismic velocity structure of pulverized rocks near the San Andreas Fault Marieke Rempe south of Littlerock, California. The examined site has a strongly asymmetric damage structure with respect to the SAF core. The conglomerates to the southwest show little to no damage, whereas a ~100 m

  10. Automatic Grid Control in Adaptive BVP Solvers Gernot Pulverer Gustaf Sderlind Ewa Weinmller

    E-Print Network [OSTI]

    Weinmüller, Ewa B.

    Automatic Grid Control in Adaptive BVP Solvers Gernot Pulverer Gustaf Söderlind Ewa Weinmüller 8. April 2009 Abstract Grid adaptation in two-point boundary value problems is usually based on mapping a uniform auxiliary grid to the desired nonuniform grid. Here we combine this approach with a new control

  11. CURRICULUM VITAE Curtis K. Stimpson curtis.stimpson@psu.edu

    E-Print Network [OSTI]

    Thole, Karen A.

    in pulverized coal, advanced ultra-supercritical power plants (funded by Babcock & Wilcox). Ensign Power Systems found in pulverized coal, oxy-combustion power plants (funded by Babcock & Wilcox). Undergraduate Investigated particle deposition of coal combustion in a pilot scale combustion facility simulating conditions

  12. Accelerating the deployment of cleaner coal plants

    SciTech Connect (OSTI)

    Parkes, J.; Holt, N.; Phillips, J.

    2008-02-15T23:59:59.000Z

    The dearth of commercial operating experience for advanced coal-fired facilities is forcing their early adopters and builders to use long development cycles and pay high costs for unique engineering design studies. A broad-based industry collaborative effort fostered by EPRI to address this issue (CoalFleet for Tomorrow) is beginning to show results. 3 figs.

  13. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  14. OPTIMIZATION OF COAL PARTICLE FLOW PATTERNS IN LOW NOX BURNERS

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Gregory E. Ogden; Jennifer Sinclair; Stephanus Budilarto

    2001-08-20T23:59:59.000Z

    The proposed research is directed at evaluating the effect of flame aerodynamics on NO{sub x} emissions from coal fired burners in a systematic manner. This fundamental research includes both experimental and modeling efforts being performed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NO{sub x} burners to the kinetic emissions limit (below 0.2 lb./MMBTU). Experimental studies include both cold and hot flow evaluations of the following parameters: flame holder geometry, secondary air swirl, primary and secondary inlet air velocity, coal concentration in the primary air and coal particle size distribution. Hot flow experiments will also evaluate the effect of wall temperature on burner performance. Cold flow studies will be conducted with surrogate particles as well as pulverized coal. The cold flow furnace will be similar in size and geometry to the hot-flow furnace but will be designed to use a laser Doppler velocimeter/phase Doppler particle size analyzer. The results of these studies will be used to predict particle trajectories in the hot-flow furnace as well as to estimate the effect of flame holder geometry on furnace flow field. The hot-flow experiments will be conducted in a novel near-flame down-flow pulverized coal furnace. The furnace will be equipped with externally heated walls. Both reactors will be sized to minimize wall effects on particle flow fields. The cold-flow results will be compared with Fluent computation fluid dynamics model predictions and correlated with the hot-flow results with the overall goal of providing insight for novel low NO{sub x} burner geometry's.

  15. Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-08-31T23:59:59.000Z

    The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

  16. Air/water oxydesulfurization of coal: laboratory investigation

    SciTech Connect (OSTI)

    Warzinski, R. P.; Friedman, S.; Ruether, J. A.; LaCount, R. B.

    1980-08-01T23:59:59.000Z

    Air/water oxidative desulfurization has been demonstrated in autoclave experiments at the Pittsburgh Energy Technology Center for various coals representative of the major US coal basins. This experimentation has shown that the reaction proceeds effectively for pulverized coals at temperatures of 150 to 200/sup 0/C with air at a total system pressure of 500 to 1500 psig. Above 200/sup 0/C, the loss of coal and product heating value increases due to oxidative consumption of carbon and hydrogen. The pyritic sulfur solubilization reactions are typically complete (95 percent removal) within 15 to 40 minutes at temperature; however, significant apparent organic sulfur removal requires residence times of up to 60 minutes at the higher temperatures. The principal products of the reaction are sulfuric acid, which can be neutralized with limestone, and iron oxide. Under certain conditions, especially for high pyritic sulfur coals, the precipitation of sulfur-containing compounds from the products of the pyrite reaction may cause anomalous variations in the sulfur form data. The influence of various parameters on the efficiency of sulfur removal from coal by air/water oxydesulfurization has been studied.

  17. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01T23:59:59.000Z

    from combustion and gasification of coal – an equilibriumHolysh, M. 2005. Coke Gasification: Advanced technology forfrom a Coal-Fired Gasification Plant. Final Report, December

  18. Emissions from burning tire-derived fuel (TDF): Comparison of batch combustion of tire chips and continuous combustion of tire crumb mixed with coal

    SciTech Connect (OSTI)

    Levendis, Y.A.; Atal, A. [Northeastern Univ., Boston, MA (United States); Carlson, J.B. [Army Natick R, Natick, MA (United States)

    1998-04-01T23:59:59.000Z

    This laboratory study investigated the emissions of waste automobile tire-derived fuel (TDF). This fuel was burned in two different modes, either segmented in small pieces (tire chunks) or in pulverized form (tire crumb). Tire chunks were burned in fixed beds in batch mode in a horizontal furnace. Tire crumb was burned in a continous flow mode, dispersed in air, either alone or mixed with pulverized coal, in a verical furnace. The gas flow was laminar, the gas temperature was 1000{degrees}C in all cases, and the residence times of the combustion products in the furnaces were similar. Chunks of waste tires had dimensions in the range of 3-9 {mu}m, tire crumb was size-classified to be 180-212 {mu}m and the high volatile bituminous coal, used herein, was 63-75. The fuel mass loading in the furnaces was varied. The following emissions were monitored at the exit of the furnaces: CO, CO{sub 2}, NO{sub x} polynuclear aromatic hydrocarbon (PAH) and particulates. Results showed that combustion of TDF in fixed beds resulted in large yields (emissions per mass of fuel burned) of CO, soot and PAHs. Such yields increased with the size of the bed. CO, soot and PAHs yields from batch combustion of fixed beds of coal were lower by more than an order of magnitude than those from fixed beds of TDF. Continuous pulverized fuel combustion of TDF (tire crumb) resulted in dramatically lower yields of CO, soot and PAHs than those from batch combustion, especially when TDF was mixed with pulverized coal. To the contrary, switching the mode of combustion of coal (from fixed beds to pulverized fuel) did not result in large differences in the aforementioned emissions. CO{sub 2}, and, especially, NO{sub x} yields from batch combustion of TDF were lower than those from coal. Emissions of NO{sub x} were somewhat lower from batch combustion than from pulverized fuel combustion of TDF and coal.

  19. Coal: world energy security. The Clearwater clean coal conference

    SciTech Connect (OSTI)

    Sakkestad, B. (ed.)

    2009-07-01T23:59:59.000Z

    Topics covered include: oxy-fuel (overview, demonstrations, experimental studies, burner developments, emissions, fundamental and advanced concepts); post-combustion CO{sub 2} capture; coal conversion to chemicals and fuels; advanced materials; hydrogen production from opportunity fuels; mercury abatement options for power plants; and carbon capture and storage in volume 1. Subjects covered in volume 2 include: advanced modelling; advanced concepts for emission control; gasification technology; biomass; low NOx technology; computer simulations; multi emissions control; chemical looping; and options for improving efficiency and reducing emissions.

  20. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-08-04T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  1. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

    2003-10-20T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  2. Reconstituted polymeric materials derived from post-consumer waste, industrial scrap and virgin resins made by solid state pulverization

    DOE Patents [OSTI]

    Khait, Klementina (Skokie, IL)

    1998-09-29T23:59:59.000Z

    A method of making polymeric particulates wherein polymeric scrap material, virgin polymeric material and mixtures thereof are supplied to intermeshing extruder screws which are rotated to transport the polymeric material along their length and subject the polymeric material to solid state shear pulverization and in-situ polymer compatibilization, if two or more incompatible polymers are present. Uniform pulverized particulates are produced without addition of a compatibilizing agent. The pulverized particulates are directly melt processable (as powder feedstock) and surprisingly yield a substantially homogeneous light color product.

  3. Reconstituted polymeric materials derived from post-consumer waste, industrial scrap and virgin resins made by solid state shear pulverization

    DOE Patents [OSTI]

    Khait, Klementina (Skokie, IL)

    2001-01-30T23:59:59.000Z

    A method of making polymeric particulates wherein polymeric scrap material, virgin polymeric material and mixtures thereof are supplied to intermeshing extruder screws which are rotated to transport the polymeric material along their length and subject the polymeric material to solid state shear pulverization and in-situ polymer compatibilization, if two or more incompatible polymers are present. Uniform pulverized particulates are produced without addition of a compatibilizing agent. The pulverized particulates are directly melt processable (as powder feedstock) and surprisingly yield a substantially homogeneous light color product.

  4. Reconstituted polymeric materials derived from post-consumer waste, industrial scrap and virgin resins made by solid state pulverization

    DOE Patents [OSTI]

    Khait, K.

    1998-09-29T23:59:59.000Z

    A method of making polymeric particulates is described wherein polymeric scrap material, virgin polymeric material and mixtures thereof are supplied to intermeshing extruder screws which are rotated to transport the polymeric material along their length and subject the polymeric material to solid state shear pulverization and in-situ polymer compatibilization, if two or more incompatible polymers are present. Uniform pulverized particulates are produced without addition of a compatible agent. The pulverized particulates are directly melt processable (as powder feedstock) and surprisingly yield a substantially homogeneous light color product. 29 figs.

  5. Coal ash utilization in India

    SciTech Connect (OSTI)

    Michalski, S.R.; Brendel, G.F.; Gray, R.E. [GAI Consultants, Inc., Pittsburgh, PA (United States)

    1998-12-31T23:59:59.000Z

    This paper describes methods of coal combustion product (CCP) management successfully employed in the US and considers their potential application in India. India produces about 66 million tons per year (mty) of coal ash from the combustion of 220 mty of domestically produced coal, the average ash content being about 30--40 percent as opposed to an average ash content of less than 10 percent in the US In other words, India produces coal ash at about triple the rate of the US. Currently, 95 percent of this ash is sluiced into slurry ponds, many located near urban centers and consuming vast areas of premium land. Indian coal-fired generating capacity is expected to triple in the next ten years, which will dramatically increase ash production. Advanced coal cleaning technology may help reduce this amount, but not significantly. Currently India utilizes two percent of the CCP`s produced with the remainder being disposed of primarily in large impoundments. The US utilizes about 25 percent of its coal ash with the remainder primarily being disposed of in nearly equal amounts between dry landfills and impoundments. There is an urgent need for India to improve its ash management practice and to develop efficient and environmentally sound disposal procedures as well as high volume ash uses in ash haulback to the coalfields. In addition, utilization should include: reclamation, structural fill, flowable backfill and road base.

  6. Development and testing of a high efficiency advanced coal combustor phase III industrial boiler retrofit. Quarterly technical progress report No. 9, 1 October 1993--31 December 1993

    SciTech Connect (OSTI)

    Jennings, P.; Borio, R. [ABB/Combustion Engineering, Windsor, CT (United States); Scaroni, A.W.; Miller, B.G. [Penn State Univ., University Park, PA (United States); McGowan, J.G. [Univ. of Massachusetts, Amherst, MA (United States)

    1994-03-01T23:59:59.000Z

    This report documents the technical aspects of this project during the ninth quarter of the program. During this quarter, the natural gas baseline testing at the Penn State demonstration boiler was completed, results were analyzed and are presented here. The burner operates in a stable manner over an 8/1 turndown, however due to baghouse temperature limitations (300{degrees}F for acid dewpoint), the burner is not operated for long periods of time below 75% load. Boiler efficiency averaged 83.1% at the 100 percent load rate while increasing to 83.7% at 75% load. NO{sub x} emissions ranged from a low of 0.17 Lbs/MBtu to a high of 0.24 Lbs/MBtu. After the baseline natural gas testing was completed, work continued on hardware optimization and testing with the goal of increasing carbon conversion efficiency on 100% coal firing from {approx}95% to 98%. Several coal handling and feeding problems were encountered during this quarter and no long term testing was conducted. While resolving these problems several shorter term (less than 6 hour) tests were conducted. These included, 100% coal firing tests, 100% natural gas firing tests, testing of air sparges on coal to simulate more primary air and a series of cofiring tests. For 100% coal firing, the carbon conversion efficiency (CCE) obtained this quarter did not exceed the 95-96% barrier previously reached. NO{sub x} emissions on coal only ranged from {approx} 0.42 to {approx} 0.78 Lbs/MBtu. The burner has not been optimized for low NO{sub x} yet, however, due to the short furnace residence time, meeting the goals of 98% CCE and <0.6 Lbs/MBtu NO{sub x} simultaneously will be difficult. Testing on 100% natural gas in the boiler after coal firing indicated no changes in efficiency due to firing in a `dirty` boiler. The co-firing tests showed that increased levels of natural gas firing proportionately decreased NO{sub x}, SO{sub 2}, and CO.

  7. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2005-03-30T23:59:59.000Z

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

  8. Enhancement of surface properties for coal beneficiation. Final report

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30T23:59:59.000Z

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  9. Fossil Energy Program. Progress report for November 1979. [35 Wt % Illinois No. 6 coal with Wilsonville recycle solvent

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report - the sixty-fourth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, materials engineering, a coal equipment test program, an atmospheric fluid bed combustor for cogeneration, engineering studies and technical support, process and program analysis, environmental assessment studies, magnetic beneficiation of dry pulverized coal, technical support to the TVA fluid bed combustion program, coal cogeneration/district heating plant assessment, chemical research and development, and technical support to major liquefaction projects.

  10. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  11. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 13, October 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1993-02-12T23:59:59.000Z

    Work completed produced the criteria for additional engineering analysis, computation and detailed experimental benchscale testing for areas of uncertainty. The engineering analysis, computation, bench-scale testing and component development was formulated to produce necessary design information to define a commercially operating system. In order to produce the required information by means of bench-scale testing and component development, a uniform coal sample was procured. After agreement with DOE, a selected sample of coal from those previously listed was secured. The test plan was developed in two parts. The first part listed procedures for engineering and computational analyses of those deficiencies previously identified that could be solved without bench scale testing. Likewise, the second part prepared procedures for bench-scale testing and component development for those deficiencies previously identified in Task 3.

  12. Engineering development of advanced coal-fired low-emission boiler systems. Quarterly technical progress report, January 1--March 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-04-28T23:59:59.000Z

    This project is concerned with the development of an a coal-fired low-emission boiler system. During march, separate kick-off meetings were held with PSI Powerserve, Raytheon and B&W`s Environmental Equipment Division to begin work on Phase I Task 5, the Commercial Plant Design. In addition, a meeting was held with MIT to discuss and review work completed and schedule work remaining on the project.

  13. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semi-annual technical progress report, February 1996--July 1996

    SciTech Connect (OSTI)

    Banovic, S.W.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1996-08-01T23:59:59.000Z

    Present coal-fired boiler environments remain hostile to the materials of choice since corrosion and erosion can be a serious problem in certain regions of the boiler. Recently, the Clean Air Act Amendment is requiring electric power plants to reduce NO{sub x}, emissions to the environment. To reduce NO{sub x}, emissions, new low NO{sub x}, combustors are utilized which burn fuel with a substoichiometric amount of oxygen (i.e., low oxygen partial pressure). In these low NO{sub x} environments, H{sub 2}S gas is a major source of sulfur. Due to the sulfidation process, corrosion rates in reducing parts of boilers have increased significantly and existing boiler tube materials do not always provide adequate corrosion resistance. Combined attack due to corrosion and erosion is a concern because of the significantly increased operating costs which result in material failures. One method to combat corrosion and erosion in coal-fired boilers is to apply coatings to the components subjected to aggressive environments. Thermal spray coatings, a cermet composite comprised of hard ceramic phases of oxide and/or carbide in a metal binder, have been used with some success as a solution to the corrosion and erosion problems in boilers. However, little is known on the effect of the volume fraction, size, and shape of the hard ceramic phase on the erosion and corrosion resistance of the thermally sprayed coatings. It is the objective of this research to investigate metal matrix composite (cermet) coatings in order to determine the optimum ceramic/metal combination that will give the best erosion and corrosion resistance in new advanced coal-fired boilers.

  14. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion of coal in conventional and advanced clean-coal technology combustors. These include fly ash clean-coal technology combustors. Although 560 million tonnes (Mt) of fly ash, bottom ash, and boiler furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces

  15. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  16. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    NONE

    1996-04-30T23:59:59.000Z

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  17. 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report second quarter, 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    ABB CE`s Low NOx Bulk Furnace Staging (LNBFS) System and Low NOx Concentric Firing System (LNCFS) are demonstrated in stepwise fashion. These systems incorporate the concept of advanced overfire air (AOFA), clustered coal nozzles, and offset air. A complete description of the installed technologies is provided in the following section. The primary objective of the Plant Lansing Smith demonstration is to determine the long-term effects of commercially available tangentially-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology are also being performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications has been established for the project.

  18. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    None

    1982-10-21T23:59:59.000Z

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  19. SUBTASK 3.11 – PRODUCTION OF CBTL-BASED JET FUELS FROM BIOMASS-BASED FEEDSTOCKS AND MONTANA COAL

    SciTech Connect (OSTI)

    Sharma, Ramesh

    2014-06-01T23:59:59.000Z

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used interchangeably without any special requirements and thus provides a pathway to energy security to the U.S. military and the entire nation. This subtask was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26- 08NT43291. Nonfederal funding was provided by Accelergy Corporation.

  20. Development of Computational Capabilities to Predict the Corrosion Wastage of Boiler Tubes in Advanced Combustion Systems

    SciTech Connect (OSTI)

    Kung, Steven; Rapp, Robert

    2014-08-31T23:59:59.000Z

    A comprehensive corrosion research project consisting of pilot-scale combustion testing and long-term laboratory corrosion study has been successfully performed. A pilot-scale combustion facility available at Brigham Young University was selected and modified to enable burning of pulverized coals under the operating conditions typical for advanced coal-fired utility boilers. Eight United States (U.S.) coals were selected for this investigation, with the test conditions for all coals set to have the same heat input to the combustor. In addition, the air/fuel stoichiometric ratio was controlled so that staged combustion was established, with the stoichiometric ratio maintained at 0.85 in the burner zone and 1.15 in the burnout zone. The burner zone represented the lower furnace of utility boilers, while the burnout zone mimicked the upper furnace areas adjacent to the superheaters and reheaters. From this staged combustion, approximately 3% excess oxygen was attained in the combustion gas at the furnace outlet. During each of the pilot-scale combustion tests, extensive online measurements of the flue gas compositions were performed. In addition, deposit samples were collected at the same location for chemical analyses. Such extensive gas and deposit analyses enabled detailed characterization of the actual combustion environments existing at the lower furnace walls under reducing conditions and those adjacent to the superheaters and reheaters under oxidizing conditions in advanced U.S. coal-fired utility boilers. The gas and deposit compositions were then carefully simulated in a series of 1000-hour laboratory corrosion tests, in which the corrosion performances of different commercial candidate alloys and weld overlays were evaluated at various temperatures for advanced boiler systems. Results of this laboratory study led to significant improvement in understanding of the corrosion mechanisms operating on the furnace walls as well as superheaters and reheaters in coal-fired boilers resulting from the coexistence of sulfur and chlorine in the fuel. A new corrosion mechanism, i.e., “Active Sulfidation Corrosion Mechanism,” has been proposed to account for the accelerated corrosion wastage observed on the furnace walls of utility boilers burning coals containing sulfur and chlorine. In addition, a second corrosion mechanism, i.e., “Active Sulfide-to-Oxide Corrosion Mechanism,” has been identified to account for the rapid corrosion attack on superheaters and reheaters. Both of the newly discovered corrosion mechanisms involve the formation of iron chloride (FeCl2) vapor from iron sulfide (FeS) and HCl, followed by the decomposition of FeCl2 via self-sustaining cycling reactions. For higher alloys containing sufficient chromium, the attack on superheaters and reheaters is dominated by Hot Corrosion in the presence of a fused salt. Furthermore, two stages of the hot corrosion mechanism have been identified and characterized in detail. The initiation of hot corrosion attack induced by molten sulfate leads to Stage 1 “acidic” fluxing and re-precipitation of the protective scale formed initially on the deposit-covered alloy surfaces. Once the protective scale is penetrated, Stage 2 Hot Corrosion is initiated, which is dominated by “basic” fluxing and re-precipitation of the scale in the fused salt. Based on the extensive corrosion information generated from this project, corrosion modeling was performed using non-linear regression analysis. As a result of the modeling efforts, two predictive equations have been formulated, one for furnace walls and the other for superheaters and reheaters. These first-of-the-kind equations can be used to estimate the corrosion rates of boiler tubes based on coal chemistry, alloy compositions, and boiler operating conditions for advanced boiler systems.

  1. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  2. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  3. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  4. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  5. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  6. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman

    2002-10-15T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  7. BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS

    SciTech Connect (OSTI)

    R. Viswanathan; K. Coleman

    2003-01-20T23:59:59.000Z

    The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

  8. 4th Annual Clean Coal

    E-Print Network [OSTI]

    Ferriter John P

    Proceedings he emphasis of the Fourth Clean Coal Technology Conference wm the marketability of clean coal projects both domestically and abroad. The success rate of clean coal projects in the U.S. for coalfired electricity generation is a beacon to foreign governments that are working toward effectively using advanced NO, and SO2 technology to substantially reduce flue-gas emissions for a cleaner environment. There is a continuing dialogue between U.S. Government, North American private industry, and the electricity producing governmental ministries and the private sector abroad. The international community was well represented at this conference. The Administration is determined to move promising, near-term technologies from the public to the private sector a ~ well a8 into the international marketplace.

  9. Trace elements in Illinois coals before and after conventional coal preparation

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-12-31T23:59:59.000Z

    Responding to recent technological advances and renewed environmental concerns requires improved characterization of Illinois and other US coals. Much of the existing trace element data on Illinois coals are on channel samples; these data need to be supplemented with data on an-shipped coals. Such data will provide a factual basis for the assessment of noxious emissions at coal-fired electric power plants. The purpose of this study was to determine the trace element concentration in as-shipped coals from Illinois mines, and compare the results to data on channel samples thast represent coal in place prior to mining. Radioactivity of the as-shipped samples was calculated from concentrations of uranium, thorium, and potassium in the samples.

  10. New coal dewatering technology turns sludge to powder

    SciTech Connect (OSTI)

    NONE

    2009-03-15T23:59:59.000Z

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  11. Properties of concrete containing wood/coal fly ash mixtures

    SciTech Connect (OSTI)

    Boylan, D.M.; Larrimore, C.L.; Fouad, F.

    1999-07-01T23:59:59.000Z

    Utilities are increasingly interested in co-firing wood with coal in existing pulverized coal units. The co-firing technology is a means of developing a relatively low-cost renewable energy resource, as well as of supporting customers and community by making energy with biomass that might otherwise have been land-filled. However, recent changes in the ASTM C618 standard for fly ash as cement replacement restrict the definition of fly ash that includes non-coal sources. As a result, wood co-firing could affect the market for the fly ash, reducing ash sales revenue, increasing ash disposal costs, and overall substantially increasing the cost of the co-firing technology. In order to address concerns about the effect of wood ash/coal ash mixtures on concrete properties, a study was conducted by University of Alabama at Birmingham, Southern Company, EPRI, and the State of Alabama. This study compared the effects on properties of concrete made with fly ash from coal and made with fly ash from co-firing up to 30% wood with coal. Fly ashes from three plants were used, with two of the ashes from actual co-firing experience and the third an artificial blend of wood and coal ash. Concrete test cylinders were made of several cement/fly ash mixes, and enough were made to allow testing periodically over a one year time period. Test measurements included workability, setting time, air content, compressive and flexural strength, rapid chloride permeability and freeze thaw. It was concluded on the basis of these tests that the wood ash content had no detrimental effect on the plastic and hardened properties of the concrete.

  12. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  13. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  14. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  15. High performance materials in coal conversion utilization. Technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This is the seventh quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete and the analysis of the data is reported in a thesis which was submitted toward a M.S. degree.

  16. High performance materials in coal conversion utilization. Technical progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    This is the ninth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the U.S. Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C-ring sections of the exposed production composite is complete. The development of a technique to laser coat the material has been the major activity while awaiting an innovatively produced new test sample. This sample will be tested and compared to the production tubes tested at UTSI.

  17. High performance materials in coal conversion utilization. Technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    This is the third quarterly report concerning this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed one third of the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOS{sup TM} ceramic composite material. The upgrade of the MTS testing machine is underway and the strength testing (at temperature) of C-ring sections of the composite will begin next quarter.

  18. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.; Carpenter, R.L.; Newton, G.J.

    1983-02-01T23:59:59.000Z

    Fluidized bed coal combustion is a promising technology for using coal in an environmentally acceptable manner. Trace elemental constituents in fly ash from an experimental atmospheric pressure fluidized bed combustor (AFBC) are reported and compared with pulverized-coal combustor (PCC) ash data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed by using spark source mass spectrometry.Fluidized bed combustor ash was similar to PCC ash in minor and trace element composition. However, AFBC ash showed less size dependence of elemental composition than has been reported for PCC ash. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  19. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30T23:59:59.000Z

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  20. Health effects of coal technologies: research needs

    SciTech Connect (OSTI)

    Not Available

    1980-09-01T23:59:59.000Z

    In this 1977 Environmental Message, President Carter directed the establishment of a joint program to identify the health and environmental problems associated with advanced energy technologies and to review the adequacy of present research programs. In response to the President's directive, representatives of three agencies formed the Federal Interagency Committee on the Health and Environmental Effects of Energy Technologies. This report was prepared by the Health Effects Working Group on Coal Technologies for the Committee. In this report, the major health-related problems associated with conventional coal mining, storage, transportation, and combustion, and with chemical coal cleaning, in situ gasification, fluidized bed combustion, magnetohydrodynamic combustion, cocombustion of coal-oil mixtures, and cocombustion of coal with municipal solid waste are identified. The report also contains recommended research required to address the identified problems.

  1. Repowering with clean coal technologies

    SciTech Connect (OSTI)

    Freier, M.D. [USDOE Morgantown Energy Technology Center, WV (United States); Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N. [Parsons Power Group, Inc., Reading, PA (United States)

    1996-02-01T23:59:59.000Z

    Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

  2. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Third quarterly progress report, 1992: Innovative Clean Coal Technology (ICCT)

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulatecharacteristics and boiler efficiency. Baseline, AOFA, and LNB without AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO{sub x} emission levels to be approximately 0.65 lb/MBtu. Flyash LOI values for the LNB configuration are approximately 8 percent at full-load. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. Abbreviated diagnostic tests for the LNB+AOFA configuration indicate that at 500 MWe, NO{sub x} emissions are approximately 0.55 lb/MBtu with corresponding flyash LOI values of approximately 11 percent. For comparison, the long-term full-load, baseline NO{sub x} emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing of the LNB+AOFA configuration will be performed when the stackparticulate emissions issue is resolved. Testing of a process optimization package on Plant Hammond Unit 4 was performed during this quarter. The software was configured to minimize NO{sub x} emissions using total combustion air flow and advanced overfire air distribution as the controlled parameters. Preliminary results from this testing indicate that this package shows promise in reducing NO{sub x} emissions while maintaining or improving other boiler performance parameters.

  3. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  4. Advanced In-Furnace NOx Control for Wall and Cyclone-Fired Boilers

    SciTech Connect (OSTI)

    Hamid Sarv

    2009-02-28T23:59:59.000Z

    A NO{sub x} minimization strategy for coal-burning wall-fired and cyclone boilers was developed that included deep air staging, innovative oxygen use, reburning, and advanced combustion control enhancements. Computational fluid dynamics modeling was applied to refine and select the best arrangements. Pilot-scale tests were conducted by firing an eastern high-volatile bituminous Pittsburgh No.8 coal at 5 million Btu/hr in a facility that was set up with two-level overfire air (OFA) ports. In the wall-fired mode, pulverized coal was burned in a geometrically scaled down version of the B and W DRB-4Z{reg_sign} low-NO{sub x} burner. At a fixed overall excess air level of 17%, NO{sub x} emissions with single-level OFA ports were around 0.32 lb/million Btu at 0.80 burner stoichiometry. Two-level OFA operation lowered the NO{sub x} levels to 0.25 lb/million Btu. Oxygen enrichment in the staged burner reduced the NO{sub x} values to 0.21 lb/million Btu. Oxygen enrichment plus reburning and 2-level OFA operation further curbed the NO{sub x} emissions to 0.19 lb/million Btu or by 41% from conventional air-staged operation with single-level OFA ports. In the cyclone firing arrangement, oxygen enrichment of the cyclone combustor enabled high-temperature and deeply staged operation while maintaining good slag tapping. Firing the Pittsburgh No.8 coal in the optimum arrangement generated 112 ppmv NO{sub x} (0.15 lb/million Btu) and 59 ppmv CO. The optimum emissions results represent 88% NO{sub x} reduction from the uncontrolled operation. Levelized costs for additional NO{sub x} removal by various in-furnace control methods in reference wall-fired or cyclone-fired units already equipped with single-level OFA ports were estimated and compared with figures for SCR systems achieving 0.1 lb NO{sub x}/10{sup 6} Btu. Two-level OFA ports could offer the most economical approach for moderate NO{sub x} control, especially for smaller units. O{sub 2} enrichment in combination with 2-level OFA was not cost effective for wall-firing. For cyclone units, NO{sub x} removal by two-level OFA plus O{sub 2} enrichment but without coal reburning was economically attractive.

  5. Radiation turbulence interactions in pulverized coal flames. Technical progress report, third year, second quarter, December 15, 1995--March 15, 1996

    SciTech Connect (OSTI)

    Menguec, M.P.; McDonough, J.M.; Manickavasagam, S.; Mukerji, S.; Swabb, S.; Ghosal, S.

    1996-09-01T23:59:59.000Z

    In this paper, the authors discuss an experimental and theoretical methodology to characterize soot volume fraction fluctuations in turbulent diffusion flames via chaotic maps. The approach is based on the hypothesis that the fluctuations of properties in turbulent flames is deterministic in nature, rather than statistical. To this extent, the authors measured the time series of soot scattering coefficient in an ethylene diffusion flame from light scattering experiments. Following this, corresponding power spectra and delay maps were calculated. It was shown that if the data were averaged, the characteristics of the fluctuations were almost completely washed out. The psds from experiments were successfully modeled using a series of logistic maps.

  6. Ash & pulverized coal deposition in combustors & gasifiers. Quarterly technical progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Ahmadi, G.

    1996-06-01T23:59:59.000Z

    In the period of October 1, 1995 to December 31, 1995, additional progress was made in accomplishing the tasks of the project. In particular, the procedure for analyzing the dispersion of elongated particles was developed. The dispersion of ellipsoidal particles in an isotropic turbulent flow was analyzed. It was shown that the simulation data for the particle fluctuation velocity and diffusivity were in good agreement with the theoretical model predictions. The computational model for simulating particle motions in turbulent duct flows was further developed. The model was applied to the dispersion analysis of particles in a circular duct. Progress was also made in the experimental study of glass fiber transport and deposition in the aerosol wind tunnel.

  7. Ash and pulverized coal deposition in combustors and gasifiers. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Ahmadi, G.

    1995-12-31T23:59:59.000Z

    During this quarter, further progress has been made in accomplishing the objectives of the project. The computational model for simulating particle motions in turbulent flows has been further developed. The model was applied to the analysis of particle transport and deposition processes in a circular duct and in a plane recirculating region. A model for evaluating particle deposition rate in the presence of gravitational and electrical forces in turbulent flows formulated. Results concerning the deposition velocity of particles under various conditions were obtained. It is shown that the model predictions are in good agreement with the available experimental and digital simulation data. Experimental study of glass fiber transport and deposition rate is also being planned.

  8. Ash and pulverized coal deposition in combustors and gasifiers. Quarterly technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Ahmadi, G.

    1996-08-01T23:59:59.000Z

    In the period of January 1, 1995 to March 31, 1995, further progress was made on the analysis of particle transport and deposition processes in a circular duct and in a plane recirculating region. The experimental data for the mean velocity and turbulence intensity fields, as well as those obtained from the STARPIC-RATE code were used in these simulations. A physical-based model for evaluating particle deposition rate in the presence of gravitational and electrical forces in turbulent flows was also formulated. Experimental study of particle transport and deposition rate is also initiated.

  9. Ash & pulverized coal deposition in combustors & gasifiers. Quarterly technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Ahmadi, G.

    1995-12-01T23:59:59.000Z

    In the period of April 1, 1995 to June 30, 1995, a computational model for simulating particle motions turbulent flow condition is developed. The model was applied to the analysis of particle transport and deposition processes in a circular duct and in a plane recirculating region. The mean gas velocity and turbulence intensity fields were first estimated using the available experimental data, as well as those obtained from an earlier developed CFD code. A model for evaluating particle deposition rate in the presence of gravitational and electrical forces in turbulent flows was also formulated. Results concerning the deposition velocity of particles under various conditions were obtained. It was shown that the model predictions are in good agreement with the available experimental and digital simulation data. Experimental study of glass fiber transport and deposition rate is also initiated.

  10. Modeling The NOx Emissions In A Low NOx Burner While Fired With Pulverized Coal And Dairy Biomass Blends 

    E-Print Network [OSTI]

    Uggini, Hari

    2012-07-16T23:59:59.000Z

    by themselves already require cleanup technology; newer regulations will require development of new and economical technologies. Using a blend of traditional fuels & biomass is a promising technology to reduce NOX emissions. Experiments conducted previously...

  11. Ash and pulverized coal deposition in combustors and gasifiers. Quarterly technical progress report, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Ahmadi, G.

    1996-07-01T23:59:59.000Z

    During this report period, additional progress was made in accomplishing the tasks of the project. In particular, the computational model for simulating particle motions in turbulent flows was further developed. The model was applied to the dispersion analysis of particles in a circular duct and the transport and deposition of particles in a recirculating region. A model for resuspension of particles from various surfaces in a gas flow is also being developed. The new model accounts for the surface adhesion, as well as the hydrodynamic forces and torques. In addition, the model includes the effect of surface roughness and the structure of near wall turbulent flow. Progress was also made in the experimental study of glass fiber transport and deposition in the aerosol wind tunnel.

  12. Ash and pulverized coal deposition in combustors and gasifiers. Quarterly technical progress report, July 1, 1996--September 30, 1996

    SciTech Connect (OSTI)

    Ahmadi, G.

    1996-12-31T23:59:59.000Z

    The computational model for simulating particle motions in turbulent flows was further developed and used to analyze the transport and dispersion of particles in a recirculating flow region. The model for resuspension of particles from surfaces in a gas flow is also further developed; it accounts for the surface adhesion as well as hydrodynamic forces and torques. It includes effects of the structure of near wall turbulent flows as well as surface roughness. In addition, a direct numerical simulation procedure for analyzing the particle removal process in turbulent gas flows is also developed. The sublayer model for evaluating the particle deposition in turbulent flows is being extended to include the effect of particle rebound. Further progress was also made in the experimental study of glass fiber transport and deposition in the aerosol wind tunnel.

  13. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01T23:59:59.000Z

    Over the past decade increasing concern over the potential environmental impact associated with the emissions of both gaseous and particulate pollutants has resulted in the promulgation of strict regulatory standards governing such emissions...

  14. Supercritical Pulverized Coal and Integrated Gasification Combined Cycle Partial CO2 Capture Cases - Updated Performance and Cost Effects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructure of All-Polymer.SupercomputingSuperconductivity at DawnCost

  15. Demonstration of coal reburning for cyclone boiler NO{sub x} control. Final project report

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    As part of the US Department of Energy`s (DOE`s) Innovative Clean Coal Technology Program, under Round 2, a project for Full Scale Demonstration of Coal Reburning for Cyclone Boiler Nitrogen Oxide (NO{sub x},) Control was selected. DOE sponsored The Babcock & Wilcox (B&W) Company, with Wisconsin Power & Light (WP&L) as the host utility, to demonstrate coal reburning technology at WP&L`s 110 MW{sub c}, cyclone-fired Unit No.2 at the Nelson Dewey Generating Station in Cassville, Wisconsin. The coal reburning demonstration was justified based on two prior studies. An Electric Power Research Institute (EPRI) and B&W sponsored engineering feasibility study indicated that the majority of cyclone-equipped boilers could successfully apply reburning technology to reduce NO{sub x}, emissions by 50 to 70%. An EPRI/Gas Research Institute (GRI)/B&W pilot-scale evaluation substantiated this conclusion through pilot-scale testing in B&W`s 6 million Btu/hr Small Boiler Simulator. Three different reburning fuels, natural gas, No. 6 oil, and pulverized coal were tested. This work showed that coal as a reburning fuel performs nearly as well as gas/oil without deleterious effects of combustion efficiency. Coal was selected for a full scale demonstration since it is available to all cyclone units and represents the highest level of technical difficulty-in demonstrating the technology.

  16. Development of high energy density fuels from mild gasification of coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-12-01T23:59:59.000Z

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  17. Development of high energy density fuels from mild gasification of coal

    SciTech Connect (OSTI)

    Greene, Marvin

    1991-12-01T23:59:59.000Z

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily skimmed'' from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  18. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenterDioxide CaptureSee the Foundry'sMcGuireNETLCareersCoal

  19. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t zManufacturing:DOECoach Compliance Form MyCoal

  20. Cermet composite thermal spray coatings for erosion and corrosion protection in combustion environments of advanced coal-fired boilers. Semiannual technical report, January 14, 1997--August 14, 1997

    SciTech Connect (OSTI)

    Schorr, B.S.; Levin, B.F.; DuPont, J.N.; Marder, A.R.

    1997-08-31T23:59:59.000Z

    Research is presently being conducted to determine the optimum ceramic/metal combination in thermally sprayed metal matrix composite coatings for erosion and corrosion resistance in new coal-fired boilers. The research will be accomplished by producing model cermet composites using powder metallurgy and electrodeposition methods in which the effect of ceramic/metal combination for the erosion and corrosion resistance will be determined. These results will provide the basis for determining the optimum hard phase constituent size and volume percent in thermal spray coatings. Thermal spray coatings will be applied by our industrial sponsor and tested in our erosion and corrosion laboratories. Bulk powder processed Ni-Al{sub 2}O{sub 3} composites were produced at Idaho National Engineering Laboratory. The composite samples contained 0, 21, 27, 37, and 45 volume percent Al{sub 2}O{sub 3} with an average particle size of 12 um. Also, to deposit model Ni-Al{sub 2}O{sub 3} coatings, an electrodeposition technique was developed and coatings with various volume fractions (0-35%) of Al{sub 2}O{sub 3} were produced. The powder and electrodeposition processing of Ni-Al{sub 2}O{sub 3} Composites provide the ability to produce two phase microstructure without changing the microstructure of the matrix material. Therefore, the effect of hard second phase particles size and volume fraction on erosion resistance could be analyzed.

  1. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 17, August 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    The construction of the DOE POC at the OCDO facility continued through this entire quarter. By the end of the quarter approximately 90% of all of the construction had been completed. All equipment has beeninstalled, checked for mechanical and installation and operated from a local pushbutton. During this quarter a review of items to be completed for start-up was compiled. This information was then presented to the construction subcontractors and agreement was concluded that all items will be completed and operational for processing coal by February 1, 1993. There are still several items that were not on site for installation during this quarter. These items are the flocculant controls supplied by Westec Engineering, Inc., and the discharge valve for the hyperbaric filter supplied by KHD. Neither of these items will prevent start-up. The flocculants can be manually controlled and provisions are all ready provided to bypass the hyperbaric filter to the Sharpels high-G centrifuge. Both of these items are scheduled for delivery in mid-January.

  2. Respirable aerosols from fluidized bed coal combustion. 3. Elemental composition of fly ash

    SciTech Connect (OSTI)

    Weissman, S.H.

    1983-02-01T23:59:59.000Z

    Trace element constituents in fly ash from an experimental atmospheric fluidized bed combustor (AFBC) are reported and compared with pulverized coal combustor (PCC) data and those from other fluidized bed combustors. Bulk and size-separated particles were collected and analyzed using spark source mass spectrometry. Fluidized bed combustion ash was similar to PCC ash in minor and trace element composition, but AFBC ash showed less size dependence of elemental composition. Bulk particle elemental composition varied with sampling position within the effluent stream. Penetration of elements through each cleanup stage and elemental enrichment were a function of the cleanup stage and the element under consideration.

  3. Transformations of inorganic coal constituents in combustion systems

    SciTech Connect (OSTI)

    Boni, A.A.; Helble, J.J.; Srinivasachar, S. (PSI Technology Co., Andover, MA (USA)); Flagan, R.C. (California Inst. of Tech., Pasadena, CA (USA)); Huffman, G.P.; Huggins, F.E. (Kentucky Univ., Lexington, KY (USA)); Peterson, T.W.; Wendt, J.O.L. (Arizona Univ., Tucson, AZ (USA)); Sarofim, A.F. (Massachusetts Inst. of Tech., Cambridge, MA (USA))

    1989-05-01T23:59:59.000Z

    The technical objectives of this project are: (a) To (1) define the partitioning of inorganic constituents associated with raw coal particles among products (including vapors, aerosols, and residual char/ash particles) formed under conditions representative of pulverized coal flames as a function of the specific (intrinsic and extrinsic) characteristics of the raw coal and the environment in which the transformations occur; and (2) to characterize the resultant spectrum of products in detail; (b) To elucidate and quantify the fundamental processes (involving basic principles of physics, chemistry, thermodynamics) by which transformations of the inorganic constituents occur; and (c) To develop, based on the information required in a. and b. above, a tractable process model capable of predicting the significant features of the transformation process, most importantly, the distribution and nature of products. This report represents work accomplished in the tenth quarter of performance on the contract. The authors specifically highlight work accomplished: at the California Institute of Technology (CalTech) on developing and constructing a thermophoretic sampling probe, for submicron fume particle sampling; at MIT on (1) completion of the baseline ash particle size distribution measurements for seven program coals (five US and two Australian), and (2) analysis of the fragmentation model results in terms of a closed-form solution for a simplified case; at the University of Arizona, on obtaining detailed ash particle and submicron fume chemistry for four program coals; and at PSI Technology Company (PSIT) on concluding data analysis and describing mineral interaction trends observed during combustion of two program coals. Individual progress reports have been indexed separately for inclusion on the data base.

  4. Coal systems analysis

    SciTech Connect (OSTI)

    Warwick, P.D. (ed.)

    2005-07-01T23:59:59.000Z

    This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.

  5. Abstracts and research accomplishments of university coal research projects

    SciTech Connect (OSTI)

    Not Available

    1991-06-01T23:59:59.000Z

    The Principal Investigators of the grants supported by the University Coal Research Program were requested to submit abstracts and highlight accomplishments of their projects in time for distribution at a grantees conference. This book is a compilation of the material received in response to the request. Abstracts discuss the following area: coal science, coal surface science, reaction chemistry, advanced process concepts, engineering fundamentals and thermodynamics, environmental science.

  6. Underground coal gasification: A near-term alternate fuel

    SciTech Connect (OSTI)

    Avasthi, J.; Singleton, A.M.

    1984-06-01T23:59:59.000Z

    Since the beginning of this century underground coal gasification has been considered as an alternative to mining as a means of utilizing the coal resources not recoverable by conventional methods. The energy crunch of the seventies gave a new impetus to it, and several tests were conducted in the U.S. to demonstrate the feasibility of this method in both horizontal and steeply dipping coal resources. Gulf Research and Development Company has conducted two successful underground coal gasification tests near Rawlins, Wyoming, in steeply dipping coal beds. The results of these tests indicate that the present state of the art is advanced enough for utilization of this technique for commercial purposes. A right combination of resource, consumer, and economic factors will dictate future commercialization of underground coal gasification for the U.S. coal resources.

  7. Electronic Surface Structures of Coal and Mineral Particles

    SciTech Connect (OSTI)

    M.K. Mazumder; D.A. Lindquist; K.B. Tennal; Steve Trigwell; Steve Farmer; Albert Nutsukpul; Alex Biris

    2001-04-01T23:59:59.000Z

    Surface science studies related to tribocharging and charge separation studies were performed on electrostatic beneficiation of coal. In contrast to other cleaning methods, electrostatic beneficiation is a dry cleaning process requiring no water or subsequent drying. Despite these advantages, there is still uncertainty in implementing large scale commercial electrostatic beneficiation of coal. The electronic surface states of coal macerals and minerals are difficult to describe due to their chemical complexity and variability [1]. The efficiency in separation of mineral particles from organic macerals depends upon these surface states. Therefore, to further understand and determine a reason for the bipolar charging observed in coal separation, surface analysis studies using Ultra-violet Photoelectron Spectroscopy (UPS) and X-ray Photoelectron Spectroscopy (XPS) were performed on coal samples and several materials that are used or considered for use in tribocharging. Electrostatic charging is a surface phenomenon, so the electronic surface states of the particles, which are influenced by the environmental conditions, determine both polarity and magnitude of tribocharging. UPS was used to measure the work function of the materials as typically used in ambient air. XPS was used to determine the surface chemistry in the form of contamination and degree of oxidation under the same environmental conditions. Mineral bearing coals are those amenable to electrostatic beneficiation. Three types of coal, Illinois No. 6, Pittsburgh No. 8, and Kentucky No. 9 were investigated in this study. Pulverized coal powder was tribocharged against copper. Pyritic and other ashes forming minerals in coal powders should charge with a negative polarity from triboelectrification, and organic macerals should acquire positive charge, according to the relative differences in the surface work functions between the material being charged and the charging medium. Different types of minerals exhibit different magnitudes of negative charge and some may also charge positively against copper [2]. Only the mineral sulfur fraction of the total sulfur content is accessible by the electrostatic method since organic sulfur is covalently bound with carbon in macerals. The sizes of mineral constituents in coal range from about 0.1 to 100 {micro}m, but pyrites in many coals are on the lower end of this scale necessitating fine grinding for their liberation and separation. A ready explanation for coal powder macerals to charge positively by triboelectrification is found in the large numbers of surface carbon free radicals available to release electrons to form aromatic carbocations. There is evidence that these cationic charges are delocalized over several atoms [3]. Only perhaps one in one hundred thousand of the surface atoms is charged during triboelectrification [4], making it difficult to predict charging levels since the data depends upon the surface chemical species involved in charging. Based on the high electron affinity of oxygen atoms, oxidation is expected to decrease the extent of a coal particle to charge positively. Also, ion transfer may contribute to the increasingly negative charging character of oxidized coal carbons. A variety of oxidized surface functional groups may influence charge properties. For example, carboxylic acid functions can lose protons to form carboxylate anions. The samples of coal investigated in this study showed differing degrees of beneficiation, consistent with a more extensively oxidized Illinois No. 6 coal sample relative to that of Pittsburgh No. 8. Even though oxygen in air is deleterious to coal stored prior to beneficiation, other gases might favorably influence charge properties. To this end, coal exposed to vapors of acetone, ammonia, and sulfur dioxide also were beneficiated and analyzed in this study.

  8. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    is produced via coal gasification, then, depending on thenot be amenable to coal gasification and, thus, Eastern coalto represent a coal-to- hydrogen gasification process that

  9. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t zManufacturing:DOECoach Compliance Form MyCoalCoal

  10. advanced byproduct recovery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik") UTILIZING CLEAN-COAL ASH 1 This project was for the...

  11. advanced hydrogen utilization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik") UTILIZING CLEAN-COAL ASH 1 This project was for the...

  12. Healy clean coal project

    SciTech Connect (OSTI)

    Not Available

    1992-08-01T23:59:59.000Z

    The objective of the Healy Clean Coal Project is to demonstrate the integration of an advanced combustor and a heat recovery system with both high and low temperature emission control processes. Resulting emission levels of SO[sub 2], NO[sub x], and particulates are expected to be significantly better than the federal New source Performance standards. During this past quarter, engineering and design continued on the boiler, combustion flue gas desulfurization (FGD), and turbine/generator systems. Balance of plant equipment procurement specifications continue to be prepared. Construction activities commenced as the access road construction got under way. Temporary ash pond construction and drilling of the supply well will be completed during the next quarter.

  13. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  14. Transforming coal for sustainability: a strategy for China

    E-Print Network [OSTI]

    energy, and ``modernized'' coal. By aggressively pursu- ing the advanced technology strategy now refers to the use of gasification technology to produce synthetic gas for power, clean fuelsTransforming coal for sustainability: a strategy for China Report by the Task Force on Energy

  15. PFB coal fired combined cycle development program. Advanced hot gas cleanup concept evaluation (Task 4. 3). Volume B. Developmental cyclone evaluation

    SciTech Connect (OSTI)

    Not Available

    1980-02-01T23:59:59.000Z

    This report summarizes the results of cold flow model testing of a conventional reverse-flow cyclone containing several developmental features designed to improve its separative performance. The four advanced features evaluated were: Outlet Scroll Skimming - to remove particles from the high dust concentration region at the periphery of the outlet dust; Base Purge - to reduce reentrainment of dust from the disengagement hopper; Increased Outlet Duct Engagement - to reduce short-circuiting of the inlet dust into the outlet; and Vortex Shield - to stabilize the point of vortex attachment at the cyclone base and thus reduce base pickup. A schematic of the advanced cyclone, showing the various developmental features, is provided. The results of the cold flow experiments showed that substantial improvement (approximately 30% reduction in exhaust emission) could be obtained from outlet skimming or from increased engagement of the exhaust dust. Furthermore, the effects of these features are additive so that about 60% overall reduction in emissions could be achieved by incorporating both of these elements. On the other hand, the vortex shield and the base purge had little effect on the separative performance. Almost all of the experimental results exhibited strong electrostatic influence. At high flowrates, the separative performance of the cyclone decreased as the flowrate was reduced, as expected from cyclone theory. Although the improvements obtained with the developmental cyclone are significant, further improvements appear possible with the Air Shield cyclone and the Electrocyclone. Consequently, subsequent efforts under the CFCC program were focused on these concepts.

  16. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  17. coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Technologies for Coal Storage and Feed Preparation AlternativesSupplements to Coal - Feedstock Flexibility DOE Supported R&D for CoalBiomass Feed and Gasification...

  18. Self-scrubbing coal{sup TM}: An integrated approach to clean air. A proposed Clean Coal Technology Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    This environmental assessment (EA) was prepared by the U.S.Department of Energy (DOE), with compliance with the National Environmental Policy Act (NEPA) of 1969, Council on Environmental Quality (CE) regulations for implementating NEPA (40 CFR 1500-1508) and DOE regulations for compliance with NEPA (10 CFR 1021), to evaluate the potential environmental impacts associated with a proposed demonstration project to be cost-shared by DOE and Custom Coals International (CCI) under the Clean Coal Technology (CCT) Demonstration Program of DOE`s Office of Fossil Energy. CCI is a Pennsylvania general partnership located in Pittsburgh, PA engaged in the commercialization of advanced coal cleaning technologies. The proposed federal action is for DOE to provide, through a cooperative agreement with CCI, cost-shared funding support for the land acquisition, design, construction and demonstration of an advanced coal cleaning technology project, {open_quotes}Self-Scrubbing Coal: An Integrated Approach to Clean Air.{close_quotes} The proposed demonstration project would take place on the site of the presently inactive Laurel Coal Preparation Plant in Shade Township, Somerset County, PA. A newly constructed, advanced design, coal preparation plant would replace the existing facility. The cleaned coal produced from this new facility would be fired in full-scale test burns at coal-fired electric utilities in Indiana, Ohio and PA as part of this project.

  19. Coal Particle Flow Patterns for O2 Enriched, Low NOx Burners

    SciTech Connect (OSTI)

    Jennifer Sinclair Curtis

    2005-08-01T23:59:59.000Z

    This project involved a systematic investigation examining the effect of near-flame burner aerodynamics on standoff distance and stability of turbulent diffusion flames and the resultant NO{sub x} emissions from actual pulverized coal diffusion flames. Specifically, the scope of the project was to understand how changes in near-flame aerodynamics and transport air oxygen partial pressure can influence flame attachment and coal ignition, two properties essential to proper operation of low NO{sub x} burners. Results from this investigation utilized a new 2M tall, 0.5m in diameter combustor designed to evaluate near-flame combustion aerodynamics in terms of transport air oxygen partial pressure (Po{sub 2}), coal fines content, primary fuel and secondary air velocities, and furnace wall temperature furnish insight into fundamental processes that occur during combustion of pulverized coal in practical systems. Complementary cold flow studies were conducted in a geometrically similar chamber to analyze the detailed motion of the gas and particles using laser Doppler velocimetry. This final technical report summarizes the key findings from our investigation into coal particle flow patterns in burners. Specifically, we focused on the effects of oxygen enrichment, the effect of fines, and the effect of the nozzle velocity ratio on the resulting flow patterns. In the cold flow studies, detailed measurements using laser Doppler velocimetry (LDV) were made to determine the details of the flow. In the hot flow studies, observations of flame stability and measurements of NO{sub x} were made to determine the effects of the flow patterns on burner operation.

  20. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01T23:59:59.000Z

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  1. Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains

    SciTech Connect (OSTI)

    Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

    1987-04-01T23:59:59.000Z

    Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

  2. Application of Multivariable Control to Oil and Coal Fired Boilers

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, hydrocarbon, opacity...

  3. The suitability of coal gasification in India's energy sector

    E-Print Network [OSTI]

    Simpson, Lori Allison

    2006-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

  4. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO[sub x]) emissions from coal-fired boilers

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO[sub x] burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO[sub x] reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as particulatecharacteristics and boiler efficiency. Baseline, AOFA, and LNB without AOFA test segments have been completed. Analysis of the 94 days of LNB long-term data collected show the full-load NO[sub x] emission levels to be approximately 0.65 lb/MBtu. Flyash LOI values for the LNB configuration are approximately 8 percent at full-load. Corresponding values for the AOFA configuration are 0.94 lb/MBtu and approximately 10 percent. Abbreviated diagnostic tests for the LNB+AOFA configuration indicate that at 500 MWe, NO[sub x] emissions are approximately 0.55 lb/MBtu with corresponding flyash LOI values of approximately 11 percent. For comparison, the long-term full-load, baseline NO[sub x] emission level was approximately 1.24 lb/MBtu at 5.2 percent LOI. Comprehensive testing of the LNB+AOFA configuration will be performed when the stackparticulate emissions issue is resolved. Testing of a process optimization package on Plant Hammond Unit 4 was performed during this quarter. The software was configured to minimize NO[sub x] emissions using total combustion air flow and advanced overfire air distribution as the controlled parameters. Preliminary results from this testing indicate that this package shows promise in reducing NO[sub x] emissions while maintaining or improving other boiler performance parameters.

  5. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  6. MHD coal combustor technology. Final report, phase II

    SciTech Connect (OSTI)

    Not Available

    1980-09-01T23:59:59.000Z

    The design, performance, and testing of a 20-MW coal combustor for scaleup to 50 MW for use in an MHD generator are described. The design incorporates the following key features: (1) a two-stage combustor with an intermediate slag separator to remove slag at a low temperture, thus minimizing enthalpy losses required for heating and vaporizing the slag; (2) a first-stage pentad (four air streams impinging on one coal stream) injector design with demonstrated efficient mixing, promoting high carbon burnout; (3) a two-section first-stage combustion chamber; the first stage using a thin slag-protected refractory layer and the second section using a thick refractory layer, both to minimize heat losses; (4) a refractory lining in the slag separator to minimize heat losses; (5) a second-stage combustor, which provided both de-swirl of the combustion products exiting from the slag separator and simple mixing of the vitiated secondary air and seed; (6) a dense-phase coal feed system to minimize cold carrier gas entering the first-stage combustors; (7) a dry seed injection system using pulverized K/sub 2/CO/sub 3/ with a 1% amorphous, fumed silicon dioxide additive to enhance flowability, resulting in rapid vaporization and ionization and ensuring maximum performance; and (8) a performance evaluation module (PEM) of rugged design based on an existing, successfully-fired unit. (WHK)

  7. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was carried out during August at the Advanced Photon Source (APS), the new synchrotron facility at Argonne National Laboratory, Chicago, IL. Further analysis of small-scale combustion experiments conducted at PSI in Phase I was completed this quarter. The results of these experiments for the first time suggest almost complete vaporization of certain trace elements (Se, Zn) from coal combustion in the flame zone, in accordance with theoretical equilibrium predictions. Other elements (As, Sb, Cr) appeared considerably less volatile and may react with constituents in the bulk ash at combustion temperatures. The combustion section of the University of Arizona's Downflow Combustor was completely rebuilt. The University of Utah worked on setting up EPA Method 26A to give the capability to measure chlorine in flue gas. The chlorine kinetic calculations performed as part of the Phase I program were found to have an error in the initial conditions. Therefore, the calculations were re-done this quarter with the correct starting conditions. Development of a quasi-empirical emissions model based on reported emissions of particulate matter from field measurements was continued this quarter. As a first step in developing the ToPEM, we developed a sub-model that calculates the evaporation of major elements (Na, K, Fe, Si, Al, Ca and Mg) from both inherent and extraneous minerals of coal. During this quarter, this sub-model was included into EMAF, which formed the ToPEM. Experimental data from the Phase I program were used to test and modify the sub-model and the ToPEM.

  8. Coal Severance Tax (North Dakota)

    Broader source: Energy.gov [DOE]

    The Coal Severance Tax is imposed on all coal severed for sale or industrial purposes, except coal used for heating buildings in the state, coal used by the state or any political subdivision of...

  9. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    SciTech Connect (OSTI)

    Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

    2001-05-10T23:59:59.000Z

    The following are proposed activities for quarter 3 (12/15/00-3/14/01): (1) Conduct TGA and fuel characterization studies - Task 1; (2) Continue to perform re-burn experiments. - Task 2; (3) Design fixed bed combustor. - Task 3; and (4) Modify the PCGC2 code to include moisture evaporation model - Task 4. The following were achieved During Quarter 3 (12/15/0-3/14/01): (1) Conducted TGA and Fuel Characterization studies (Appendix I). A comparison of -fuel properties, TGA traces etc is given in Appendix I. Litter has 3 and 6 times more N compared to coal on mass and heat basis. The P of litter is almost 2 % (Task 1). Both litter biomass (LB) and feedlot biomass (FB) have been pulverized. The size distributions are similar for both litter and FB in that 75 % pass through 150 {micro}m sieve while for coal 75 % pass through 60 {micro}m sieve. Rosin Rammler curve parameters are given. The TGA characteristics of FB and LB are similar and pyrolysis starts at 100 C below that of coal; (2) Reburn experiments with litter and with FB have been performed (Appendix II) -Task 2. Litter is almost twice effective (almost 70--90 % reduction) compared to coal in reducing the NOx possibly due to presence of N in the form of NH{sub 3}; (3) Designed fixed bed gasifier/combustor (Appendix III) - Task 3; and (4) Modified PCGC2 to include moisture evaporation model in coal and biomass particles. (Appendix IV) - Task 4.

  10. Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

  11. International perspectives on coal preparation

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  12. Managing Carbon Regulatory Risk in Utility Resource Planning: Current Practices in the Western United States

    E-Print Network [OSTI]

    Barbose, Galen

    2008-01-01T23:59:59.000Z

    sub-critical pulverized coal generation, representing thecontaining new pulverized coal generation without CCS. Ofthe operating cost of coal-fired generation without CCS, and

  13. Managing Carbon Regulatory Risk in Utility Resource Planning: Current Practices in the Western United States

    E-Print Network [OSTI]

    Barbose, Galen

    2009-01-01T23:59:59.000Z

    sub-critical pulverized coal generation, representing thecontaining new pulverized coal generation without CCS. Ofthe operating cost of coal-fired generation without CCS, and

  14. Combustion properties of coal-char blends: NO{sub x} emission characteristics. Interim final technical report, September 1, 1992--August 31, 1993

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Khan, L.; Khan, S. [Illinois State Geological Survey, Champaign, IL (United States); Smoot, L.D.; Germane, G.J.; Eatough, C.N. [Brigham Young Univ., Provo, UT (United States). Advanced Combustion Engineering Research Center

    1993-12-31T23:59:59.000Z

    Under pulverized coal combustion conditions, NO{sub x} formed during the release of volatile matter far exceed NO{sub x} formed from combustion of the resulting char. It is believed that interactions of NO{sub x} with char is responsible for the reduced NO{sub x} formation from the combustion of char. The goal of this research is to assess the potential technical and economical benefits of co-firing coal-char blends in pulverized coal boilers to reduce NO{sub x}. The rationale for the proposed research is that the presence of char in the flame during the initial stages of combustion may provide catalytic activity for reduction of NO{sub x} produced from volatile nitrogen. This project is a cooperative effort between the Illinois State Geological Survey (ISGS) and BYU/ACERC. Seven hundred and fifty pounds of three coal-char blends containing 12.5%, 25%, and 50% char and 125 pounds of a coal-activated carbon blend containing 12.5% activated carbon were prepared. The volatile matter contents of the blends ranged from 27.3 to 35.6% (dry basis). Char (16.2 wt% volatile matter) was made from an Illinois No. 6 coal (Peabody Coal Company) in a continuous feed charring oven under mild gasification conditions. Nine combustion tests will be performed with the coal and blends in a 0.5--1.0 MBtu/hr combustor located at BYU. Combustion data will be analyzed to determine the effect of blend type, stoichiometry, and flame temperature on NO{sub x} formation, ignition characteristics, flame stability, and combustion efficiency. A four month no-cost extension has been requested for the project. The results of the combustion tests will be reported in the final technical report in December 1993.

  15. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect (OSTI)

    Jost O.L. Wendt

    2003-01-31T23:59:59.000Z

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO{sub 2} control, NO{sub x} control, and inorganic fine particle and toxic metal emissions will be determined. Previous research results have demonstrated that the inhalation of coal/MSS ash particles cause an increase in lung permeability than coal ash particles alone. Elemental analysis of the coal/MSS ash particles showed that Zn was more abundant in these ash particles than the ash particles of coal ash alone.

  16. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15T23:59:59.000Z

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  17. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01T23:59:59.000Z

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  18. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  19. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect (OSTI)

    Not Available

    1990-08-01T23:59:59.000Z

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  20. NOx, FINE PARTICLE AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect (OSTI)

    Jost O.L. Wendt

    2002-08-15T23:59:59.000Z

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and coal. The objective is to determine the relationship between (1) fraction sludge in the sludge/coal mixture, and (2) combustion conditions on (a) NOx concentrations in the exhaust, (b) the size segregated fine and ultra-fine particle composition in the exhaust, and (c) the partitioning of toxic metals between vapor and condenses phases, within the process. The proposed study will be conducted in concert with an existing ongoing research on toxic metal partitioning mechanisms for very well characterized pulverized coals alone. Both high NOx and low NOx combustion conditions will be investigated (unstaged and staged combustion). Tradeoffs between CO2 control, NOx control, and inorganic fine particle and toxic metal emissions will be determined. Previous research has yielded data on trace metal partitioning for MSS by itself, with natural gas assist, for coal plus MSS combustion together, and for coal alone. We have re-evaluated the inhalation health effects of ash aerosol from combustion of MSS both by itself and also together with coal. We have concluded that ash from the co-combustion of MSS and coal is very much worse from an inhalation health point of view, than ash from either MSS by itself or coal by itself. The reason is that ZnO is not the ''bad actor'' as had been suspected before, but the culprit is, rather, sulfated Zn. The MSS supplies the Zn and the coal supplies the sulfur, and so it is the combination of coal and MSS that makes that process environmentally bad. If MSS is to be burned, it should be burned without coal, in the absence of sulfur.